GT 8
GT 8
I I
       What is the rate of change of electric flux through plane in middle of capacitor with
                                 d
       respect to time (i.e.          )–
                                 dt
            2I                         I                               4I                            6I
       A)                       B)                                C)                            D)
            0                        0                               0                            0
2.     A particle is moving in a circular path. The acceleration and momentum of the particle at
                                                       2         
       a certain moment are        a  (4î  3 ĵ) m/s     and   p  (8î  6 ĵ) kg-m/s.   The motion of the particle at
       that instant is
3. A block starts moving up a fixed inclined plane of inclination 60° with a velocity of
20 m/s and stops after 2 sec. The approximate value of coefficient of friction is
(g = 10 m/s2)
6.   An ideal gas is expanded so that amount of heat given is equal to the decrease in internal
     energy. The gas undergoes the process TV1/5 = constant. The adiabatic compressibility of
     gas when pressure is P, is –
           7                          5                    2                      7
     A)                      B)                     C)                      D)
          5P                         7P                   5P                     3P
7.   An ideal gas is held in a container of volume V at pressure P. The average speed of a gas
     molecule under these conditions is v. If now the volume and pressure are changed to 2V
     and 2P, the average speed of a molecule will be
     A) 1/2 v                B) v                       C) 2v                D) 4v
8.   A wire is 4 m long and has a mass 0.2 kg. The wire is kept horizontally. A transverse
     pulse is generated by plucking one end of the taut (tight) wire. The pulse makes four
     trips back and forth along the cord in 0.8 sec. The tension in the cord will be -
     A) 80 N               B) 160 N                C) 240 N                 D) 320 N
9.   Two identical simple pendulums A and B are fixed at same point. They are displaced by
     very small angles  and  (    ) and released from rest. Find the time after which B
     reaches its initial position for the first time. Collisions are elastic and length of strings is
     .
 
A B
                                                                       2 
     A)                   B)   2                 C)                  D)
               g                     g                    g                  g
                                       06-01-24_JEE-MAIN_Q’P
10.   The figure shows a charge q placed inside a cavity C in an uncharged conductor. Now if
      an external electric field is switched on then :
                                                   C
                                               q
11. STATEMENT – 1
      If potential difference between two points is zero and the resistance between the same
      two points is also zero, then current may flow between those two points
STATEMENT – 2
A) B)
Time Time
Rate Rate
C) D)
Time Time
15.   When an object is at distance x and y from a lens, a real image and a virtual image is
      formed respectively having same magnification. The focal length of the lens is –
            xy
      A)                    B) x – y            C)     xy                 D) x + y
             2
16.   If the zero of the Vernier lies on the right hand side of zero of the main scale and fourth
      division coincide with the main scale division when the jaws are in contact, the zero
      correction will be __ (assume standard Vernier Calipers)
A) RL B) RL
– –
                  Rs                                               Rs
           +                                                +
C) RL D) RL
– –
                          R    
18.   The graph of log        
                                   versus log A (R = radius of a nucleus and A = mass number) is -
                          R0   
Column I Column II
A) A – R; B – P; C – Q ; D – S B) A – R; B – P; C – S ; D – Q
      C) A – Q; B – S; C – R ; D – P                   D) A – Q; B – S; C – P ; D – R
                                               06-01-24_JEE-MAIN_Q’P
20.    In a YDSE experiment, I0 is given to be the intensity of the central bright fringe &  is the
       fringe width. Then, at a distance y from central bright fringe, the intensity will be -
(y is very small)
                    y                       y                      2y                      y 
       A) I0 cos         B)   I 0 cos 2           C)   I 0 cos        D)   I 0 cos 2  
                                                                                            2 
                                          SECTION-II
                                (NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21.    A particle of mass 10–2 kg is moving along the positive x-axis under the influence of a
       force F(x) = – K/(2x2) where K = 10–2 Nm2. At time t = 0 it is at x = 1.0 m and its
       velocity is v = 0. Find its velocity when it reaches x = 0.50 m. (in m/s)
22.    A uniform ball of radius R = 10 cm rolls without slipping between two rails such that the
       horizontal distance is d = 16 cm between two contact points of the rail to the ball. If the
       angular velocity is
       5 rad/s, then find the velocity of centre of mass of the ball in cm/s.
23.    A disc of radius '5cm' rolls on a horizontal surface with linear velocity v = 1 î m/s and
       angular velocity 50 rad/sec. Height of particle from ground on rim of disc which has
       velocity in vertical direction is (in cm) -
                                                                y
                                                       
                                                           v              x
24.    A liquid flows out drop by drop from a vessel through a vertical tube with an internal
       diameter of 2 mm, then the total number of drops that flows out during 10 grams of the
       liquid flow out: [Assume that the diameter of the neck of a drop at the moment it breaks
       away is equal to the internal diameter of tube and surface tension is 0.02 N/m,
       g = 9.8 m/s2]
                                       06-01-24_JEE-MAIN_Q’P
25.   A tuning fork is in unison with a sonometer wire vibrating in its fourth overtone. Mass
hanged with wire is 9 kg. When additional mass is hanged wire vibrates in unison with
26. Two conducting concentric spherical shells are present. If the electric potential at the
centre is 2000 V and the electric potential of the outer shell is 1500 V. then the potential
27. A series LCR circuit containing a resistance of 120 has angular resonance frequency
4 × 105rads–1. At resonance the voltage across resistance and inductance are 60 V & 40
V respectively. At what frequency the current in the circuit lags the voltage by 45°. Give
29.   A thin prism P1 with angle 4º and made from glass of refractive index 1.54 is combined
      with another thin prism P2 made from glass of refractive index 1.72 to produce
      dispersion without deviation. The angle of prism in degrees is
30.   An experiment with convex lens gives certain result which is represented by a student in
      the shown graph. The power of the lens in diopters is
                                                         0.2
                                                             1 –1
                                                               cm
                                                         0.1 v
                                        0.2       0.1
                                              1
                                                  cm–1
                                              u
                                             06-01-24_JEE-MAIN_Q’P
CHEMISTRY                                                                                   MAX.MARKS: 100
                                               SECTION – I
                                     (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31.     The element with  Xe  4f 14 5d1 6s 2 belongs to
C) T  In  Ga  A D) A  Ga  In  T
A) Yb 3  Pm 3  Ce 3  La 3 B) Ce3  Yb 3  Pm 3  La 3
       C) Yb 3  Pm 3  La 3  Ce 3                   D) Pm3  La 3  Ce 3  Yb 3
                                             06-01-24_JEE-MAIN_Q’P
36.   Which one of the following does not contain electrons in 5f subshell?
      A) Lr  Z  103          B) U  Z  92           C) Cm  Z  96    D) Th  Z  90 
      Reason (R) : Transparent bead  NaBO2  B2O3  forms coloured bead with coloured
      cation.
HO
                                                                      OH
                                              para  coumaricacid
      A) 1               B) 2                     C) 3              D) 4
                                    06-01-24_JEE-MAIN_Q’P
42.   Which of the following reaction produces anisole as a major product?
A) B)
      C)                                        D) All
43.   The oxidation of toluene with hot KMnO 4 gives
      A) [R] & [S] on treatment with excess of dil NaOH gives same compound
      B) Position of double bond in [P] & [Q] in same as per IUPAC
      C) [U] & [V] on treatment with excess of dilute NaOH gives different product as [R] &
      [S] on same treatment
      D) [U] & [R] are constitutional isomers
                                                   06-01-24_JEE-MAIN_Q’P
46.   A 10cm sample of an unknown gaseous hydrocarbon was mixed with 70cm3 of oxygen
                           3
      and the mixture was set on fire by means of an electric spark. When the reaction was
      over and water vapours were liquefied, the final volume of gases decreased to 65cm3 .
      This mixture then reacted with a potassium hydroxide solution and the volume of gases
      decreased to 45cm3 . Find the molar mass of hydrocarbon in gm/mol, if volumes of
      gases were measured at standard temperature and pressure (STP) conditions ?
      A) 26                              B) 36              C) 16                        D) 46
47.   Radial wave function for 2s orbital of hydrogen – like atoms is given as
                                  3
                                              zr
               z 2  zr 
                      3
        2 2    2   e 2a 0
               a0   a0 
                               VNaOH                                          VNaOH 
      A)                                                    B)
        Conductance
Conductance
                               VNaOH                                          VNaOH 
      C)                                                    D)
                                                        06-01-24_JEE-MAIN_Q’P
50.    Consider the reaction 2 H 2  g   2 NO  g   N 2  g   2 H 2O  g  . The rate law for this
       reaction is: rate = k  H 2  NO  under what conditions could these steps represents the
                                                    2
mechanism?
Step: 2 N 2O2  H 2  N 2O  H 2O
Step: 3 N 2O  H 2  N 2  H 2O
                                                      SECTION-II
                                            (NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
51.    How many of these elements have lower electron affinity than fluorine ?
Cl , S , O, N , P, Br , I , C
52.
       Complex                                                    Spin-only magnetic moment
        Fe  CO 4  C 2 O 4  
                                                                 a
        FeCl4                                                   b
                  
        Fe  CN 6 
                          3
                                                                  c
        Cu  NH 3 4 
                               2
                                                                  d
(i) In manganate and permanganate ions. The  - bonding takes place by overlap of p-
(ii) Manganate ion is green in colour and permanganate ion in purple in colour
54. The total number of chiral compound/s from the following is____________
OH
                                             OH
                                 OH                    OH              CH2
                             HO                        OH
                                             OH
55. How many of the following reactions will give an alcohol as the major product ?
                           i  mCPBA
                         
                           ii  LiAlH   4
                             iii  H 
      (iv)
Br
                            aq 
                             AgNO         3
(v)
OH
                        NH 2 
                               HC 
                              NaNO            2
(vi)
                     OH OH
                                   i  H SO
              CH3  C  C  CH3 
                                  ii  NaBH 
                                                         2     4
                                                               4
                                                   ii  H
                    CH 3 CH 3
      (vii)
OH OH O  CH 2  H
(v) H 3C  C  C  CH 3 (vi) Ph  SO 3H
                                                                                       CH 3
                                              H  C  OH                        H 3C  C  H
                                                        O                              CH 3
                                   (vii)                               (viii)                   (ix) H 3C  C  CH
                                                   06-01-24_JEE-MAIN_Q’P
57.   Among the following oxides
                   
      If the  0m Co  NH3 4 C 2   50 1cm2mol1   0m  CO 4  70  1cm 2 mol1 and the
                                               
59.   How many of following ethers are difficult to make or cannot be synthesized as a major
      product by S N 2 reaction ?
60.   At what pH given molecules doesnot migrate towards any electrode when electric field
                                 is applied. (give answer in nearest integer. )
      p   ka1
                  2;p ka  3.90;p ka  10.0 
                        2             3
NH 3
      HOOC  CH 2  CH  COOH
                                               06-01-24_JEE-MAIN_Q’P
MATHEMATICS                                                                                MAX.MARKS: 100
                                                  SECTION – I
                                        (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
61. Let z1 , z2 , z3 be three distinct complex numbers lying in a circle with a centre at the origin
       such that z1  z2 z3 , z2  z3 z1 and z3  z1 z2 are real numbers, then z1 z2 z3 equals to
A) -1 B) 0 C) 1 D) None of these
A) 0 B) 2 C) 4 D) 11
63.    If H1 , H 2 ,.....H n are n harmonic means between a and b,  b  a  , then the value
        H1  a H n  b
                      is equal to
        H1  a H n  b
A) n  1 B) n  1 C ) 2n D) 2n  3
                      1        1                                               12 12  22 12  2 2  32
64.    Let H n  1     then the sum to n terms of the series                                     .... is
                      2        n                                               13 13  23 13  23  33
            4                           4      1               4                               4      2 n
       A)     Hn 1                B)     Hn             C)     Hn                       D)     Hn 
            3                           3      n               3                               3      3 n 1
A) 0 B) 4 C) 1 D) 6
66. The number of ordered pairs  m, n  , m, n {1, 2....100} such that 7m  7n is divided by 5 is
A) 96 B) 97 C) 98 D) 99
17.   A letter is taken at random from the letters of the word ‘STATICSTICS’ and another
      letter is taken at random from the letters of the word ‘ASSISTANT’. The probability that
      they are the same letter is
           1                                13                                 19                            3
      A)                              B)                                C)                             D)
           45                               90                                 90                           16
      in the ratio 1:2 at G2 , G2 A4 is divided in the ratio 1:3 at G3 , G3 A5 is divided in the ratio 1:4
      at G4 , and so on until all n points are exhausted. The coordinates of the final point G so
      obtained are
A)  n  x1  x2  ...  xn  , n  y1  y2  .... yn  
           x  x  ...  xn y1  y2  ....  yn 
      B)  1 2            ,                    
                     n                       n            
D) None of these
                                             PQ  RS                           2PQ  RS                      PQ 2  RS 2
      A) PQ.RS                        B)                                C)                             D)
                                                2                              PQ  RS                            2
                                                    06-01-24_JEE-MAIN_Q’P
                                                                                  a3 x 2 a 2 x
74.   The locus of the vertices of the family of parabolas y                                  2a is
                                                                                   3      2
                  105                           3                      35                                    64
      A) xy                       B) xy                    C) xy                               D) xy 
                   64                           4                      16                                   105
75.   A triangle ABC is placed so that the mid-point of its sides are on the x, y and z axes
      respectively. Lengths of the intercepts made by the plane containing the triangle on these
      axes are respectively  ,  ,  , then the coordinates of the centroid of the triangle ABC are
A)   / 3,  / 3,  / 3 B)  / 3,  / 3,  / 3
C)  / 3,  / 3,  / 3 D)  / 3,  / 3,  / 3
                                                                    e| x|  e  x
76.   Let f : R  R be a function defined by f  x  =                            .Then
                                                                    e x  e x
                                                                                           f ''  0  f '''  0          f n  0
      If f  x   1  x   n  N, x  R  , then the value of f  0   f '  0  
                          n
78.                                                                                                                          is
                                                                                             2!          2!                 n!
               dx
79.   x 1/2
                x1/3
                      
      A) y    B / A e Ax  C 
                                     1
                                                             B) y   B / A   Ce Ax
      C) y  e Ax   B / A e Ax  C                      D) y  e Ax   B / A  e Ax  C 
                                           1                                                     1
                                                             06-01-24_JEE-MAIN_Q’P
                                                         SECTION-II
                                               (NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
81. If tan 1  x    tan 1  x    tan 1 then the value of 250 x4 +320 x2 +137 is equal to
                      2                2           4
                     x              x          x
82.    If O is the origin and the coordinates of A and B are (51, 65) and (75, 81) respectively.
       Then OA  OB cos AOB is equal to
                                                       k
                                                                         k                         k
83.    Let 0   r  1  r  1, 2,  and            cos  r =           for any k  1 and A   (  r ) r ,then
                                                      r 1                2                       r 1
       lim
              498.
                   1  x   2 1/3
                                      1  2 x 
                                                1/4
       x A
                                x  x2
                                                                                           7      1
                                                                                       dx  e1   e2  1 is
                                                                  1
                                                                  e  x  1
                                                                      2 x 1       n
84.    A positive integer n  5 such that                        0                         4     16
                                                                                              
                                                                               2                     3
86.    The maximum value of f  x                              4  x2  3            4  x 2  1 is
              50       n
87.    Let U X i  U Yi  T , where each X i contains 10 elements and each Yi contains 5 elements. If
              i 1    i 1
       each elements of the set Tis an element of exactly 20 of sets X i ' s and exactly 6 of sets
       Yi ' s then n is equal to
88.    If A  4, 3,5 , B  0,6, 0  , C  8,1, 4  are three consecutive vertices of parallelogram ABCD . If
        is the angle between AC and BD the sum of digits of 3025 sec 2  is
89.    Let x1 , x2 ...., x100 be in an arithmetic progression with x1  2 and their mean equal to 200.If
       yi  i  xi  i  ,1  i  100. Let y be the mean of y1 , y2 ,.... y100 . Then y  9000.5
KEY SHEET
                                PHYSICS
      1      B     2    B      3     C     4    D     5       A
      6      B     7    C      8     A     9    B     10      A
      11     B     12   B     13     A    14    A     15      A
      16     C     17   A     18     D    19    B     20      B
      21      1    22   30    23     3    24   780    25      16
      26    2000   27    8    28     3    29    3     30      20
                              CHEMISTRY
      31      B    32    D    33    A     34    B     35      A
      36      D    37    C    38    C     39    D     40      A
      41      D    42    B    43    A     44    A     45      A
      46      A    47    C    48    D     49    B     50      C
      51      7    52   11    53    3     54    2     55      4
      56      5    57    2    58    50    59    2     60      3
                             MATHEMATICS
      61     C     62    C    63   C     64     D     65     C
      66     C     67    B    68   B     69     B     70     C
      71     D     72    B    73   A     74     A     75     D
      76     D     77    B    78   B     79     A     80     D
      81    1777   82   9090  83  249    84      3    85     64
      86     28    87    30   88   31    89    1049   90     6
                                                       06-01-24_JEE-MAIN_KEY&SOL
                                                            SOLUTIONS
                                                             PHYSICS
1.    = Q A
        A 0
         Q
     =
        0
        d     1    dQ      I
           = ×           =
        dt     0     dt   0
                             
2.   Angle between a and p is :
     
     p    
            
            a
                           
                           a.p
      = cos–1  
                        | a || p |
                                     
                                32  18
     = cos-                       
                                      
                (16  9) (64  36) 
         cos–1  
                  14
     =
                 50 
      = 73.73°
     Since 0° < 90°, the motion is an acceleration one.
3.   Retardation = g (sin  +  cos ) = 5 ( 3  )
     Now       v = u – at
                            u
                   a=          as v = 0
                            t
                   5 ( 3  )       = 10  = 0.27
     4 m/s                           v
4.
                    1 m/s                     1 m/s
6.        Dq = – Du
                                                                   06-01-24_JEE-MAIN_KEY&SOL
                                   –R         R        P dV
      C = –CV =                           =           +
                                   –1         –1      n dT
              P dV   2R
          –        
              n dT  – 1
      T5V = const.
                      const.
      V=
                       T5
      dV    const
         =–5 6
      dT     T
      PV = Nrt
      P/n = RT/V
         RT 5       const     2R
      +        T × –5 6  =
        const.         T      –1
      5     1
        =         – 1 = 2/5
      2    –1
       = 7/5
      adiabatic compressibility
            1      5
      =        =
           P     7P
              1
7.    PV = m o Nv 2rms
              3
                     1
      (2P) (2V) = m o Nv 2rms
                     3
      rms = 2vrms = 2v
8.    4 trips means 32 m
                            v
                            4m
                  d                           d       32
      t=                         v=              =        =   40 m/s
                  v                           t       0 .8
                       T
      v=
                       
      T v2
                           0 .2                   2 16  10
              T=                  × (40)2 =
                            4                         4
              T = 80 N
                                                                         
9.    Time period of both A and B T = 2
                                                                         g
      After first collision, B acquires amplitude of A and after second collision it acquires its own
      amplitude in this process time taken is
              T         T         T       T                    
      =           +         +         +       = T = 2
              4         4         4       4                    g
10.   The distribution of charge on the outer surface, depends only on the charges outside, and it distributes
      itself such that the net electric field inside the outer surface due to the charge on outer surface and all
      the outer charges is zero. Similarly the distribution of charge on the inner surface, depends only on the
      charges inside the inner surface, and it distributes itself such that the net, electric field outside the inner
      surface due to the charge on inner surface and all the inner charges is zero.
      Also the force on charge inside the cavity is due to the charge on the inner surface. Hence answer is
      option (A).
11.   Conceptual
                                       06-01-24_JEE-MAIN_KEY&SOL
12.   Point A shall record zero magnetic field (due to -particle) is at position P and Q as shown in figure.
      The time taken by -particle to go from P to Q is –
                P
        
                O 60º
                                            A
                  60º
            12          2
      t=        or  =
            3           3t
13.   Curie temperature is temperature above which Ferromagnetic materials obey Curie’s law.
           1 2
14.   U=     LI
           2
                 = LI  
              dU         dI
      Rate =
              dt        dt 
      At t = 0 , I = 0
       Rate = 0
                                   dI
      At t = , I = I0 but              = 0, therefore, rate = 0
                                   dt
15.   The given lens is a convex lens. Let the magnification be m, then for real image
       1  1  1
         + =                                        ... (i)
      mx x   f
                                          1  1  1
      and for virtual image                  =           ... (ii)
                                         my y  f
      From Eq. (i) and Eq. (ii), we get
            xy
      f=
             2
16.   e = 4 × LC = 4 × 0.01 cm = 0.04 cm
      c = –0.04 cm
17.   Zener diode is in parallel to load resistance and
       is connected in reverse bias.
                              R
18.   R = R0 A1/3                 = A1/3
                              R0
            R  1
      log   = log A
             R0        3
               1
      or   y= x
               3
      a straight line passing through origin with slope 1/3.
19.   Conceptual
20. S1
S2
                y             2        2y
      x =            =      × x =
                                       
      Inet = I + I + 2I cos 
                                                                          06-01-24_JEE-MAIN_KEY&SOL
                           2y                                       y 
           = 2I 1  cos                     = 4I cos2              
                                                                     
                          y 
           =    I0 cos2                                             [ I0 = 4I]
                           
                    k                 10 2
21.       F=                F  =   
                    2x 2               2x 2
                             2
                    F    10                   1                             dv
          a=          =              a= 2                          =v
                    m (10  2 )2 x 2         2x                              dx
            0.5                   v                      0.5
                  dx                                 1                       v2
          –                 =  vdv  –                    x  2 dx    =
            1
                  2x 2            0
                                                     2
                                                         1
                                                                             2
                                  0.5           2
                   1   1                               v2
                                                 1 =
                                            v   1 1
                                       =
                  2  x 1                 2  2  0 .5  2
                            v = 1 m/s
22.
                R
                         y
                     d
                                        2
          y2 = R2 –  
                      d
                                 2
                                                     vCM/g
          × y
          vCM/g = × y
                = 30 cm/s
23.       v = Rcos
                                   v            2
           cos=                          =       cm
                                  R            5
           h = R(1 – cos) = 3 cm.
      Potential to centre is same as potential at the inner surface of the spherical shell.
27.   At resonance reactance = 0
           V         60           1
      I=        =           =         Amp.
           R        120           2
      VL = I × XL = I × L
                VL
      L=                                         ………(i)
                 I
                1
      0 =
                LC
                1
      C=                              ……….(ii)
             L 0 2
      Calculate L & C from (1) & (2) current will lag
      the applied voltage by 45°
                                             1
                                      L –
      if       tan 45° =                     c
                                        R
      Solve for       = 8 × 105 rad/sec
28.   Energy present in 3  108 m is 10 Mj, hence energy in 90 cm is
         90  102  10  103
      E                        3  10 11 J
               3 10  8
29.
           4º
                      Aº
      deviation = 0
      (µ1 – 1) 4 – (µ2 – 1)A = 0
      (1.54 – 1) 4 – (1.72 – 1) A = 0
           0.54  4
      A=                   = 3º
             0.72
                           1
30.   From graph              0.2cm 1
                           f
       f  5cm
       Power of lens equal to 20 D.
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                                                  CHEMISTRY
31.    Xe 4f   14     1   2
                      5d 6s ----------- Lu
32.   INERT PAIR effect NCERT (Physical properties of group 13 elements )
33.                                 K 2SO 4  Cr2  SO 4 3  H 2O
      K 2 Cr2O 7  SO 2  H 2SO 4 
34.   X : NaC O
      Y : NaC O3 .
35.   By using Lanthanoid contraction concept we get correct answer.
36.   Th  Z  90  : 86  Rn  6d 2 7s 2
37.   y  4, x  6
38.   PC 5  sp3  TBP  ; AsH 4  sp 3  Tetrahedral  ; XeF4  sp 3d 2 -Square planar;
      XeO 2 F2  sp3d  Seesaw 
39.   synergic bond concept in complex compounds
40.   Conceptual
41.   Product is
                 OH
Br Br
                  HC  CH  COOH
                   |    |
                   Br  Br
43.
                                                            
44.   Hinsberg’s test is used for separation of 1 , 2 and 3 Amines.
46.   2  n  3  2   0        n  4
                          y                          y
      C x H y  g   x   O 2  g  
                                         xCO 2  g   H 2O   
                          4                          2
      10                70                      -         -
                             y                                5
      -        70  10  x              10x      -70  10x  y  10x  65
                             4                                2
      5y  5  2 y  210 x  20           x2
      C x H y  C 2 H 2 Molar mass  26g / mol
47.   At r  a 0   0  4r 2 2  0
48.   In liquid phase
      PT  PB0 . B  PT0 .T  120  0.6  50  0.4
      = 72 + 20 = 92 mmHg
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                                              PToluene 20
      In vapour phase  T                                 0.22
                                               PTotal 92
49.   C3H5COOH  NaOH 
                        C6 H5COONa  H 2O
                     WA             SB                  Salt 
                                                D
      Conductance
A C
                             B
                                                    VNaOH
50.
51.   NCERT data
52.   a  3;b  35;c  3;d  3
                                2
53.   Option i) Manganate  MnO 4
      Permanganate  MnO 4
             O               O
                     Mn                             Mn
       O                         O           O             O
                             
                        O                            O
        hybridisation                          hybridisation
        of Mn  d s              3
                                               of Mn  d 3s
After excitation
      2 × 2p   3d 
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      2 × 2p   3d 
      1 × 2p   4p 
                2
      (ii) MnO 4  green
      MnO 4  purple / violet
      (iii) Manganate contains I unpaired electron hence it is paramagnetic Where as permanganetic
      contains no unpaired electrons hence it is diamagnetic.
                       3
      (iv) Both have d s hybridization hence both have tetrahedral geometry.
54.
55.
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56.   (i), (ii), (vi), (vii),(ix) can evolve H 2 on reaction with Na metal.
57.   X:3
      Y:3
      Z:3
58.    M  50  70  120 1 cm 2 mol1
            C.C 0.2 1 1            K  1000    0.2  1000
      K                cm                M             0.4975mol / t
             R     33.5                 M        120  33.5
      M  49.75milli mol / t
60.   Average of pK1 and pK 2
      pH = 2.95 is isoelectric point
                                                  MATHS
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63.
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65.
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67.
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69.   CONCEPTUAL
70.
71.
72.CONCEPTUAL
73.
74.
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75.
76.
77.
78.
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79.
80.   conceptual
81.
82.
83.
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84.
85.