Wilhelm Ostwald
Wilhelm Ostwald
Ostwald entered the University of Dorpat (now the Known for See list
University of Tartu, Estonia) in 1872. He completed Founding of physical
his Kandidatenschrift examinations there in 1875.[2][3] chemistry
During his time at Dorpat, Ostwald had significant Ostwald coefficient
exposure to the humanities, the arts, and philosophy,
Ostwald color system
which became a focus of his endeavors after his 1906
Ostwald dilution law
retirement from academia.[3]
Ostwald process
Ostwald ripening
Academic career Ostwald's rule
Ostwald viscometer
Ostwald began his career as an independent unpaid
Ostwald–Freundlich equation
investigator at the University of Dorpat in 1875. He
worked in the laboratory of Carl Schmidt, along with Ostwald–Folin pipette
his contemporary Johann Lemberg. Lemberg taught Ostwald–de Waele
Ostwald many of the basics of the analysis of inorganic relationship
compounds and measurements of equilibria and Ostwald–Liesegang rings
chemical reaction rates. Lemberg also taught Ostwald Catalysis
the chemical basis of many geologic phenomena.
Colligative properties
These endeavors formed part of the subjects of
Ostwald's later research efforts.[3] In addition to his Energeticism
work in Carl Schmidt's laboratory, Ostwald also HSL and HSV
studied in the university's physics institute with Arthur Coining the term mole
von Oettingen.[2]
Awards Faraday Lectureship Prize
Around 1877, still continuing his work as an unpaid (1904)
investigator in the Chemistry Laboratory at the Nobel Prize in Chemistry
University of Dorpat, Ostwald became a paid assistant (1909)
in the Physics Institute, after Oettingen's assistant Wilhelm Exner Medal (1923)
moved to Riga.[3][6] He also supported himself for a
Scientific career
time by teaching mathematics and science at a Dorpat
high school.[7] Fields Chemistry
Institutions University of Dorpat
Ostwald was deeply interested in questions of chemical
Riga Polytechnical Institution
affinity and the reactions that formed chemical
Leipzig University
compounds. This was the central theoretical question
facing chemists at the time. As part of his early work, Doctoral Arthur Amos Noyes
Ostwald developed a three-dimensional affinity table students Georg Bredig
that took into account the effects of temperature as Paul Walden
well as the affinity constants of acids and bases.[3]
Frederick G. Donnan
Ostwald also investigated mass action,
electrochemistry, and chemical dynamics. [2] Louis Albrecht Kahlenberg
James Walker
Ostwald completed his Magisterial degree at the Willis Rodney Whitney
University of Dorpat in 1877, enabling him to give
lectures and charge for teaching.[8] Ostwald published
his doctoral dissertation at the University of Dorpat in 1878, with Carl Schmidt as his thesis advisor. His
doctoral thesis was entitled Volumchemische und Optisch-Chemische Studien ("Volumetric and Optical-
Chemical Studies").[4] In 1879, he became a paid assistant to Carl Schmidt.[9]
In 1881, Ostwald became a Professor of Chemistry at the Riga Polytechnicum (now Riga Technical
University). In 1887, he moved to Leipzig University where he became Professor of Physical
Chemistry.[5] Ostwald remained on the faculty at Leipzig University until his retirement in 1906. He also
served as the first "exchange professor" at Harvard University in 1904 and 1905.[2][10]
During Ostwald's academic career, he had many research students who became accomplished scientists in
their own right. These included future Nobel Laureates Svante Arrhenius, Jacobus Henricus van 't Hoff,
and Walther Nernst. Other students included Arthur Noyes, Willis Rodney Whitney and Kikunae Ikeda.
All of these students became notable for their contributions to physical chemistry.[2][11]
In 1901, Albert Einstein applied for a research position in Ostwald's laboratory. This was four years
before Einstein's publication on special relativity. Ostwald rejected Einstein's application, although later
the two developed strong mutual respect.[12] Subsequently, Ostwald nominated Einstein for the Nobel
Prize in 1910 and again in 1913.[13]
Following his 1906 retirement, Ostwald became active in philosophy, politics, and other humanities.[2]
During the course of his academic career, Ostwald published more than 500 original research papers for
the scientific literature and approximately 45 books.[9]
Scientific contributions
Catalysis
Through his research on chemical reaction rates and velocities and his studies of acids and bases, Ostwald
found that the concentration of acid or the concentration of base in a solution of certain chemical
reactants can have a strong influence of the rate of chemical processes. He realized that this is
manifestation of the concept of chemical catalysis first articulated by Berzelius. Ostwald articulated the
idea that a catalyst is a substance that accelerates the rate of a chemical reaction without being a part of
either the reactants or the products. Ostwald's advances in the understanding of chemical catalysis were
widely applicable in biological processes such as enzymatic catalysis and also in many industrial
processes. A catalyst is used in the nitric acid process that Ostwald invented.[18]
Crystallization
Ostwald studied the crystallization behavior of solids, especially those solids that are capable of
crystallizing in different forms, in the phenomenon known as polymorphism. He discovered that solids do
not necessarily crystallize in their most thermodynamically stable form but instead sometimes crystallize
preferentially in other forms dependent on the relative rates of crystallization of each polymorphic form.
Ostwald found that the relative rates were dependent on the surface tension between the solid polymorph
and the liquid form. Many common materials exhibit this type of behavior, including minerals and
various organic compounds. This finding came to be known as Ostwald's rule.[20]
Ostwald realized that solid or liquid solutions can continue to evolve over time. While the a non-
thermodynamically preferred polymorph may crystallize first, more thermodynamically stable forms can
continue to develop as the solution ages. Often this results in large crystals forming, since they are more
thermodynamically stable than are large numbers of small crystals. This phenomenon came to be known
as Ostwald Ripening and is observed in many situations. An everyday example is the gritty texture that
ice cream develops as it ages. On a geologic timescale, many minerals exhibit Ostwald Ripening as their
crystal forms evolve as the mineral ages.[21]
Related to solubility and crystallization was Ostwald's finding that dissolution of a solid depends on the
size of the crystal. When the crystals are small, typically less than a micron, the solubility of the solid in
the solution phase is increased. Ostwald quantified this effect mathematically in a relationship that
became known as the Ostwald-Freundlich equation. Ostwald first published his finding in 1900, and his
mathematical equation was refined by German chemist Herbert Freundlich in 1909. This mathematical
relationship also applies to the partial pressure of substance in the system. The Ostwald-Freundlich
equation takes into account the surface tension of the particle in the system, in addition to curvature and
temperature. The size dependence of solubility is sometimes utilized in the formulation of
pharmaceuticals that have low solubility so as to enhance their uptake by the patient. The size
dependence also has a role in Ostwald Ripening.[22]
Collaborating with German chemist Raphael E. Liesegang, Ostwald recognized that substances can
crystallize in a periodic fashion wherein the crystallization behavior follows a spatial or temporal pattern.
In certain circumstances, the result of this periodic crystallization behavior is easily visually observed, for
example, in various geologic formations. Liesegang had previously investigated this phenomenon in
specific laboratory experiments, showing his results to Ostwald. Ostwald then developed a mathematical
model for the phenomenon that served to explain the observations and realized how widespread is the
periodic crystallization behavior. These observations came to be known as Liesegang rings.[23]
Atomic theory
Ostwald introduced the word mole into the lexicon of chemistry around 1900. He defined one mole as the
molecular weight of a substance in units of mass grams. The concept was linked to the ideal gas,
according to Ostwald. Ironically, Ostwald's development of the mole concept was directly related to his
theory of energeticism, in
philosophical opposition to atomic
theory, against which he (along with
Ernst Mach) was one of the last
holdouts. He explained in a
conversation with Arnold
Sommerfeld that he was convinced
by Jean Perrin's experiments on
Brownian motion.[24][25]
Ostwald viscometer
Scientific measurements
As part of Ostwald's investigations in to chemical equilibria, chemical
affinity, and acid-base interactions, he recognized that many established analytical methods disturb the
chemical systems under investigation. He therefore turned to physical measurements as surrogate
methods to understand these important basic phenomena. One such physical measurement is the
measurement of the viscosity, or resistance to flow, of a liquid. Ostwald invented a device for this purpose
consisting of bulbs that act as reservoirs for a liquid with a capillary, or thin tube, in between the
reservoirs. The time that it takes for the liquid to flow through the capillary from one reservoir to the
other is an indication of the viscosity of the liquid. Using a reference solution, the viscosity of the liquid
can be quantified. Ostwald typically used this device to study the behavior of solutes in water solutions.
These devices came to be known as Ostwald viscometers and are in widespread use in contemporary
times for research and quality control purposes.[27]
Ostwald designed a pipette that could be used to transfer and measure liquids, especially serous fluids.
This design was later improved by Otto Folin. This type of pipette has a bulb at the lower end as a
particular design feature. It became known as the Ostwald-Folin pipette and is widely used in
contemporary times.[28]
Color science
Following his 1906 retirement from academia, Ostwald became interested in the systematization of
colors, which could be useful both scientifically and in the arts. He published The Color Primer and also
The Color Atlas during the period of 1916–8. These publications established relationships between the
various visual colors.[4]
The Color Primer, The Color Primer, The Color Primer, The Color Primer,
page 33 page 44 page 50 page 56
Ostwald represented these as a three dimensional representation of color space that is a topological solid
consisting of two cones. One apex of the cone is pure white while the other is pure black. The eight
primary colors are represented along the circumference or curved surfaces of the two cones. In this
representation, each color is a mixture of white, black, and the eight primary colors. In this way, there are
three degrees of freedom that represent each color.[29]
As part of his interest in philosophy, in 1902 Ostwald started the journal Annalen der Naturphilosophie
(Annales of Natural Philosophy). In 1927, he initiated the journal Die Farbe (Colour).[4]
Ostwald was one of the directors of the Die Brücke institute in Munich, and he played a role in its
founding in 1911. The institute was sponsored, significantly, from Ostwald's Nobel Prize money. Through
the institute, Ostwald's intention was to develop a standardized system for scholarly publications.[31] In
1911, Ostwald founded the Association of Chemical Societies, which sought to organize and improve the
efficiency of various chemical societies. The association is an example of a scientific society. Ostwald
served as the first president of the Association of Chemical Societies.[3][32]
Among his other interests, Ostwald was a passionate amateur painter who made his own pigments.[34] He
left more than 1,000 paintings along with 3,000 pastels and color studies.[35] For Ostwald, science and the
arts were mutually supportive areas of engagement.[35]
"Poetry, music and painting have given me refreshment and new courage, when exhausted by
scientific work I have been obliged to lay my tools aside."–Ostwald[35]
Ostwald regarded science and the arts as having a common aim, that of "coping with the infinite diversity
of appearances through the formation of appropriate concepts"[35]... Towards this aim, science builds
"intellectual ideas; art constructs visual ones."[35]
Ostwald developed a strong interest in color theory in the later decades of his life. He wrote several
publications in the field, such as his Malerbriefe (Letters to a Painter, 1904) and Die Farbenfibel (The
Color Primer, 1916). His work in color theory was influenced by that of Albert Henry Munsell, and in
turn influenced Piet Mondrian and other members of De Stijl[36] and Paul Klee and other members of the
Bauhaus school.[34] Ostwald's theories also influenced Americans Faber Birren and Egbert Jacobson.[35]
He was also interested in the international language movement, first learning Esperanto, then later
supporting Ido. He was a member of a Committee of the Delegation for the Adoption of an International
Auxiliary Language.[37][38][39] Ostwald donated half the proceedings of his 1909 Nobel prize to the Ido
movement,[40] funding the Ido magazine Progreso which he had proposed in 1908.[41] Ostwald later went
on to create his own language Weltdeutsch in a period of extreme nationalism during the First World War.
One of Ostwald's continuing interests was unification through systematization. In particular, Ostwald
perceived that energy efficiency was a unifying theme in all facets of society and culture. In political
matters, Ostwald's interest in energy efficiency extended to such political matters as the need for
organization of labor.[3]
Ostwald's interest in unification through systematization led to his adaptation of the philosophy of
Monism.[42] Initially, Monism was liberal, pacifist, and international, seeking in science a basis of values
to support social and political reforms. Ostwald himself developed a system of ethics based on science,
around the core idea that one should "not waste energy, but convert it into its most useful form."[43][44]
in 1911, Ostwald became President of the Deutscher Monistenbund (Monist Association), founded by
Ernst Haeckel.[45] Ostwald (and other Monists) promoted eugenics and euthanasia, but only as voluntary
choices with the intention of preventing suffering. Monist promotion of such ideas is suggested to have
indirectly facilitated acceptance of the later Social Darwinism of the National Socialists. Ostwald died
before the Nazis adopted and enforced the use of eugenics and euthanasia as involuntary government
policies, to support their racist ideological positions.[43][3] Ostwald's Monism also influenced Carl G.
Jung's identification of psychological types.[46]
In 1923, Ostwald was awarded the Wilhelm Exner Medal, which recognized the economic impact of
Ostwald's scientific contributions.[51]
In 1904 he was elected a foreign member of the Royal Netherlands Academy of Arts and Sciences.[52] He
became an honorary member of scientific societies in Germany, Sweden, Norway, the Netherlands,
Russia, Great Britain, and the United States. Ostwald received honorary doctorates from various
universities in Germany, Great Britain and the United States. In 1899 he was made a Geheimrat by the
King of Saxony, which by that time was a recognition of Ostwald's scholarly contributions.[2]
There is a Wilhelm Ostwald Park and Museum in Grimma, Germany, at the site of Ostwald's vacation
home. This institution also houses many of Ostwald's scholarly works.[4][53]
Ostwald crater, which is on the far side of the Earth's moon, was named in honor of Wilhelm Ostwald.[54]
Personal life
On 24 April 1880 Ostwald married Helene von Reyher (1854–1946), with whom he had five children.
These were: Grete, (1882–1960) born in Riga and died in Großbothen; Wolfgang (1883–1943) born 1883
in Riga and died in Dresden; Elisabeth (1884– 1968) born in Riga and died in Großbothen; Walter (1886–
1958) born in Riga and died in Freiburg im Breisgau; and Carl Otto (1890–1958) born in Leipzig and
died in Leipzig. Wolfgang Ostwald became a notable scientist in the area of colloid chemistry.[55][56][57]
Ostwald was initiated to the Scottish Rite Masonry and became Grand Master of the Grand Lodge "Zur
Aufgehenden Sonne" in Bayreuth.[58][59]
In 1887, he moved to Leipzig where he worked for the rest of his life. At the time of his retirement, he
moved to a country estate near Groβbothen, Saxony, which he named "Landhaus Energie". He lived at the
country estate for most of the remainder of his life.[8]
On his religious views, Ostwald was an atheist.[60] Ostwald died in a hospital in Leipzig on 4 April
1932,[2] and was buried at his country estate in Großbothen, near Leipzig[61]
In fiction
Ostwald appears as a character in Joseph Skibell's 2010 novel, A Curable Romantic.[62]
He is also mentioned in Italo Svevo's 1923 novel, La coscienza di Zeno, translated as Zeno's
Conscience.[63]
Representative publications
Grundriss der allgemeinen Chemie (https://gutenberg.bei
c.it/webclient/DeliveryManager?pid=6560168) (in
German). Leipzig: Wilhelm Engelmann. 1899.
Ostwald, W. (1906). Process of manufacturing nitric acid.
Patent.
Ostwald, W. (1909). Energetische Grundlagen der
Kulturwissenschaft (https://archive.org/details/energetisc
hegru00ostwgoog) (1st ed.). Leipzig: Leipzig, W.
Klinkhardt.
Couturat, L.; Jespersen O.; Lorenz R.; Ostwald W.;
Pfaundler L. (1910). International language and science:
Considerations on the introduction of an international
language into science (https://archive.org/details/internat
ionallan029658mbp). London: Constable and Company
Limited.
Entwicklung der Elektrochemie (https://gutenberg.beic.it/
webclient/DeliveryManager?pid=6561905) (in French).
Paris: Alcan. 1912.
Ostwald, W. (1917). Grundriss der allgemeinen Chemie
(5th ed.). Dresden: Steinkopff. Grundriss der allgemeinen Chemie,
1899
Books
Lehrbuch der allgemeinen Chemie. Leipzig: W. Engelmann, 1896–1903. (2 vols.)[7]
Leitlinien der Chemie: 7 gemeinverständliche Vorträge aus der Geschichte der Chemie.
Leipzig : Akad. Verl.-Ges., 1906. Digital edition (http://nbn-resolving.de/urn:nbn:de:hbz:061:2
-169620) of the University and State Library Düsseldorf.
The Scientific foundations of analytical chemistry London: Macmillan, 1908.
OCLC 35430378 (https://www.worldcat.org/oclc/35430378)
Colour science, London: Winsor & Newton, 1933. OCLC 499690961 (https://www.worldcat.o
rg/oclc/499690961)
The color primer: A basic treatise on the color system of Wilhelm Ostwald, New York, N.Y.:
Van Nostrand Reinhold, 1969. OCLC 760593331 (https://www.worldcat.org/oclc/760593331)
Electrochemistry: History and theory : Elektrochemie: Ihre Geschichte und Lehre. New
Delhi: Amerind Publishing Co. 1980. OCLC 702695546 (https://www.worldcat.org/oclc/7026
95546)
Lebenslinien. Eine Selbstbiographie von Wilhelm Ostwald. Zweiter Teil, Leipzig 1887–1905
(3 vols). (Klasing & Co., g.m.b.H., Berlin 1927.)[30] Translated as Wilhelm Ostwald: The
Autobiography by Robert Jack. Springer, 2017.[64]
See also
Colligative properties
Electrode potential
Energeticism
List of Baltic German scientists
Timeline of hydrogen technologies
Wilhelm Ostwald Institute
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External links
Works by Wilhelm Ostwald (https://www.gutenberg.org/ebooks/author/42408) at Project
Gutenberg
Works by or about Wilhelm Ostwald (https://archive.org/search.php?query=%28%28subjec
t%3A%22Ostwald%2C%20Wilhelm%22%20OR%20subject%3A%22Wilhelm%20Ostwald%
22%20OR%20creator%3A%22Ostwald%2C%20Wilhelm%22%20OR%20creator%3A%22
Wilhelm%20Ostwald%22%20OR%20creator%3A%22Ostwald%2C%20W%2E%22%20O
R%20title%3A%22Wilhelm%20Ostwald%22%20OR%20description%3A%22Ostwald%2C%
20Wilhelm%22%20OR%20description%3A%22Wilhelm%20Ostwald%22%29%20OR%20%
28%221853-1932%22%20AND%20Ostwald%29%29%20AND%20%28-mediatype:softwar
e%29) at the Internet Archive
Works by Wilhelm Ostwald (https://librivox.org/author/1376) at LibriVox (public domain
audiobooks)
Newspaper clippings about Wilhelm Ostwald (http://purl.org/pressemappe20/folder/pe/0228
55) in the 20th Century Press Archives of the ZBW
Wilhelm Ostwald Park and Museum (https://www.wilhelm-ostwald-park.de/en/)
Wilhelm Ostwald (https://www.nobelprize.org/laureate/168) on Nobelprize.org including the
Nobel Lecture*, 12 December 1909 On Catalysis