CLASS IX - SCIENCE
ATOMS AND
MOLECULES
    PRASHANT KIRAD
      PK HITS
Formula making
Molecular mass
Laws of chemical reaction
                                     HISTORY
  Around 500 B.C., Indian philosopher                            Antoine L. Lavoisier laid the
Maharishi Kanad, postulated the theory Ancient Greek philosophers foundation of chemical
if we go on dividing matter (padarth),     – Democritus and       sciences by establishing two
 we will obtain smallest particle beyond Leucippus called these important laws of chemical
 which further division can't be possible  particles atoms.              combination.
     which is known as 'parmanu'.
                             ATOMS
Atoms are building blocks of all matter.
According to modern atomic theory, an atom is the smallest
particle of an element which takes part in chemical reaction.
Atoms are very small and which can’t be seen even through very
powerful microscope.
         Laws of Chemical Combination
Law of Conservation                  Law of Constant
      of Mass                          Proportions
           Lavoisier and Joseph L. Proust.
        LAW OF CONSERVATION OF MASS
The Law of Conservation of Mass states that mass is
neither created nor destroyed in a chemical reaction.
The total mass of the reactants equals the total mass
of the products.
  Total Mass of Reactants =
   Total Mass of Products
                        NCERT ACTIVITY
                                     Solution Y in flask, Solution X in ignition tube.
                                            Weigh flask with both solutions.
                                                Tilt flask to mix X and Y.
                                            Re-weigh the flask after mixing.
                                             Check for any change in mass.
Set X: Copper sulphate (or barium
                                                Mass remains constant
chloride, or lead nitrate)
Set Y: Sodium carbonate (or sodium          (Law of Conservation of Mass).
sulphate, or sodium chloride)
  LAW OF CONSTANT PROPORTIONS
The Law of Constant Proportions (also known as the Law of Definite Proportions) is a
fundamental chemical law that states a chemical compound always contains the
same elements in the same fixed proportion by mass, regardless of the source,
method of preparation, or the amount of the compound.
For example,
(i) 18 gm of H₂O = 2 gm of hydrogen + 16 gm of oxygen
    mass of hydrogen : mass of oxygen = 2:16 = 1:8
(ii) 36 gm of H₂O = 4 gm of hydrogen + 32 gm of oxygen
    mass of hydrogen : mass of oxygen = 4:32 = 1:8
(iii) In water, the ratio of the mass of hydrogen to the mass of oxygen is always 1 : 8
respectively.
        DALTON’S ATOMIC THEORY
In 1808 John Dalton, was the first
scientist to describe the nature and
behavior of atoms.
Dalton’s theory laid the foundation for
modern chemistry and it helps us
understand the basic structure and
properties of matter.
Key Postulates of Dalton’s Atomic Theory are:
  All matter is made of very tiny particles called atoms.
  Atoms are indivisible particles, which cannot be created or destroyed in a chemical
  reaction.
  Atoms of a given element are identical in mass and chemical properties. (Law of
  conservation of mass)
  Atoms of different elements have different masses and chemical properties.
  Atoms combine in the ratio of small whole numbers to form compounds. (Law of
  constant proportion)
  The relative number and kinds of atoms are constant in a given compound.
Drawbacks of Dalton’s Atomic Theory:
  No Subatomic Particles: Dalton's theory said atoms were indivisible, but we now
  know about electrons, protons, and neutrons.
  Isotopes Not Defined: Dalton stated all atoms of an element have the same mass,
  but isotopes of elements have different masses.
  No Isobars: Dalton said atoms of different elements have different masses, but
  isobars have the same mass number.
  No Whole-Number Ratios Always: Complex compounds like sugar (C12H22O11)) do
  not always follow simple whole-number ratios.
  No Allotropes Defined: Allotropes like graphite and diamond have different
  properties that Dalton's theory can't explain.
          SYMBOLS OF ELEMENTS
John Dalton (1808), in his atomic theory, attempted to create a
   set of symbols for elements based on simple circles with
    different patterns or dots to represent different atoms.
Dalton: First scientist to use symbols for elements.
Berzelius: Suggested using one or two letters from the element's name for
its symbol.
Element Naming: Initially, elements were named after their discovery
locations (e.g., Copper from Cyprus).
IUPAC: Now responsible for approving element names, symbols, and units.
Symbols typically use one or two letters from the element's English name
(e.g., H for Hydrogen, Al for Aluminium).
Special Cases: Some symbols are derived from Latin, German, or Greek
names (e.g., Fe for Ferrum, Na for Natrium, K for Kalium).
  MODERN SYMBOLS OF ELEMENTS
                          First Letter - Capital   IUPAC : International Union of
Steps to Write Symbols:
                          Second Letter - Small     Pure and Applied Chemistry
Trick to Rememeber First 20 Elements of Periodic Table
   1. Hydrogen (H)             11. Sodium (Na)
   2. Helium (He)              12. Magnesium (Mg)
   3. Lithium (Li)             13. Aluminum (Al)
   4. Beryllium (Be)           14. Silicon (Si)
   5. Boron (B)                15. Phosphorus (P)
   6. Carbon (C)               16. Sulfur (S)
   7. Nitrogen (N)             17. Chlorine (Cl)
   8. Oxygen (O)               18. Argon (Ar)
   9. Fluorine (F)             19. Potassium (K)
   10. Neon (Ne)               20. Calcium (Ca)
The standard reference element for measuring atomic mass is
                         Carbon-12
Carbon-12 (or C-12) is an isotope of carbon, where the nucleus contains 6 protons
     and 6 neutrons, giving it an atomic mass of 12 atomic mass units (u).
                                        1/12 of C-12
                                    1 Atomic mass unit
                                         (AMU)
          ATOMIC MASS UNIT (amu)
Defined as 1/12th the mass of a carbon-12
atom.
This unit is often used to express atomic
masses.
12 Amu = Mass of a Carbon atom
                ATOMS EXISTENCE
Most elements' atoms are highly reactive and do not exist freely.
Only noble gas atoms (He, Ne, Ar, Kr, Xe, Rn) are chemically inert and
can exist as single atoms.
Atoms of all other elements combine together to form molecules or
ions.
            Ion (electrically charged)
Atom
            Molecules (electrically neutral)
                                         IONS
Ions are atoms or groups of atoms that carry an electric charge, either
positive or negative.
Ions are formed when atoms gain or lose electrons to achieve a stable
electron configuration
 Type of Ion           Charge                    Formation                  Examples
                                         Formed when an atom loses   Sodium ion (Na⁺),
Cations        Positively charged ions
                                         one or more electrons       Calcium ion (Ca²⁺)
               Negatively charged        Formed when an atom gains   Chloride ion (Cl⁻), Oxide
Anions
               ions                      one or more electrons       ion (O²⁻)
                     Ions
 Simple Ions                Polyatomic Ions
Ions made up of               Ions made up of
  single atoms.               group of atoms.
EX: Na⁺, N³⁻, Ca²⁺          EX: NH₄⁺, OH⁻, SO₄²⁻
Names and symbols of some ions
                       MOLECULES
A molecule is the smallest particle of a substance that can exist
independently and retains the chemical properties of that substance.
Molecules are formed by two or more atoms bonded together, and
they can be of the same element or different elements.
                           Molecules
   Molecules of Elements           Molecules of Compounds
         MOLECULES OF ELEMENTS
Molecules of elements are composed of two or more atoms of
the same element bonded together.
They represent the smallest independent unit of an element that
retains the element’s chemical properties.
These molecules are formed by atoms of the same element and
can exist as single atoms or bonded groups.
                     ATOMICITY
Atomicity is the number of atoms in a molecule of an element or
  compound. It indicates how many atoms of the element are
             bonded together in a single molecule.
For example, in an O₂ molecule, there are 2 atoms of oxygen, so
                       its atomicity is 2.
                                             Achha to yeh baat hai!!!
Types of Atomicity:
   Monoatomic – Molecules with a single atom .
Example: Helium (He), Neon (Ne), and Argon (Ar) have atomicity 1.
   Diatomic – Molecules with two atoms of same element.
Example: Oxygen (O₂), Nitrogen (N₂), and Hydrogen (H₂) have atomicity 2.
   Triatomic – Molecules with three atoms of same element.
Example: Ozone (O₃) has atomicity 3.
   Tetratomic – Molecules with four atoms of same element.
Example: Phosphorus (P₄) has atomicity 4.
   Polyatomic – Molecules with more than four atoms of same element.
Example: Sulfur (S₈) has atomicity 8.
Name of the Class         Atomicity   Examples
                                      i) Noble gases: Helium (He), Argon (Ar), Neon
                                      (Ne), Krypton (Kr)
Monatomic                 1           ii) Metals: Sodium (Na), Magnesium (Mg),
                                      Aluminium (Al)
                                      iii) Carbon (C)
                                      Hydrogen (H₂), Oxygen (O₂), Chlorine (Cl₂),
Diatomic                  2
                                      Fluorine (F₂), Nitrogen (N₂)
Triatomic                 3           Ozone (O₃)
Tetratomic / Polyatomic   4 or more   Phosphorus (P₄), Sulphur (S₈), Fullerenes (C₆₀)
Compound                  Combining Elements   Atomicity    Ratio by Mass
Hydrogen chloride (HCl)   Hydrogen, Chlorine   Diatomic     1 : 35.5
Water (H₂O)               Hydrogen, Oxygen     Triatomic    1:8
Ammonia (NH₃)             Hydrogen, Nitrogen   Tetratomic   1 : 4.67
Carbon dioxide (CO₂)      Carbon, Oxygen       Triatomic    1 : 2.67
Q1. Who proposed the Law of Conservation of Mass?
a) Dalton
b) Lavoisier
c) Democritus
d) Rutherford
Q2.What is the atomicity of phosphorus in P₄?
a) 2
b) 3
c) 4
d) 5
Q3. What is the atomic mass unit? (Amu) equal to ?
a)1/12 the mass of a carbon - 12atoms
b) 1/6 the mass of a carbon - 12atoms
c) 1/2 the mass of a carbon - 12atoms
d) 1 the mass of a carbon - 12atoms
Q4.Which of the following is the correct pair of atom and its atomic symbol?
(a) Sulphur – Su
(b) Potassium – P
(c) Phosphorus -P
(d) Sodium- S
Q5. Which of the following has the highest atomic mass?
a) Hydrogen
b) Carbon
c) Oxygen
d) Uranium
Q6. Which organisation approves the names of elements all ober the world? Write
symbol of gold?
Answer:
International union of Pure and applied chemistry (IUPAC)
Q7. What are the two laws of chemical combination? Explain with examples.
Answer:
   Law of Conservation of Mass: Mass is neither created nor destroyed in a
   chemical reaction. Example: In the reaction H₂ + Cl₂  2HCl, the total mass
   of reactants equals the total mass of products.
   Law of Constant Proportions: A compound always contains the same
   elements in the same ratio by mass. Example: Water (H₂O) always contains
   hydrogen and oxygen in a 1:8 ratio by mass.
Q. A sample of magnesium oxide contains 2.4 g of magnesium and 1.6 g of
oxygen. Calculate the percentage composition of magnesium and oxygen in the
compound. If the Law of Constant Proportion is true, what weight of magnesium
and oxygen will be present in 5 g of magnesium oxide?
(Atomic masses: Mg = 24 u, O = 16 u)
Answer. Percentage composition: Mg=60%, O=40%
In 5 g of MgO, Mg=3.0 g and O=2.0 g
Q. A compound contains 2.4 g of magnesium and 3.2 g of oxygen. Show that this
data obeys the law of constant proportions.
Answer: Ratio of magnesium to oxygen = 2.4/3.2=3/4
     This is consistent with the fixed ratio of Mg to O in MgO (3:4).