SDS Report
Ningbo Xiangfeng Imp. & Exp. Co., Ltd.
50# ,Jinji Road , Xiaogang, Ningbo
Sample Name : CORRECTION FLUID , CORRECTION PEN
End Uses : Stationery, office product
Composition/ Ingredient of
Sample (as per client submission) : See Section 3 Composition/information on ingredients
on the SDS report
Job Receiving Date : Feb 04, 2021
Last Information Date : Feb 12, 2021
SDS Preparation Period : Feb 04 - Feb 12, 2021
Service Requested : Preparation of Safety Data Sheet (SDS) for the sample
with submitted information.
Summary : As per request, the contents and formats of the SDS are
prepared in accordance with European (EC) No
1272/2008 and Regulation (EU) No 2015/830, and is
provided per attached.
Safety data sheet
Regulation (EC) No.1907/2006 and 1272/2008
Version number 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name: CORRECTION FLUID , CORRECTION PEN
1.2 Relevant identified uses of the substance or mixture and uses advised against
Application of the substance/ the mixture : Stationary , office product
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq.2 H225 Highly flammable liquid and vapour.
GHS09 environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315Causes skin irritation.
STOT SE 3 H336May cause drowsiness or dizziness.
Information concerning particular hazards for human and environment:
The product has to be labeled due to the calculation procedure of Regulation 1272/2008/EC.
Classification system:
The classification is according to the latest edition of EU Regulation 1272/2008/EC, and extended by
company and literature data.
2.2 Label elements
Labeling according to Regulation (EC) No 1272/2008
The product is classified and labeled according to CLP Regulation.
Hazard pictograms
GHS02 GHS07 GHS09
Signal word Danger
Hazard-determining components of labeling:
Methylcyclohexane
Safety data sheet
Regulation (EC) No.1907/2006 and 1272/2008
Version number 1
Trade name: CORRECTION FLUID, CORRECTION PEN
Hazard statements
H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H304 May be fatal if swallowed and enters airways.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water or shower.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable
vPvB: Not applicable
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description:
Mixture of the substances listed below with nonhazardous additions.
For the wording of the listed hazard statements refer to section 16.
Composition:
CAS: 108-87-2 Methylcyclohexane 51.0%
EINECS: 203-624-3
Index number: 601-018-00-7 Flam.Liq. 2, H225;
Aquatic Chronic 2,
H411;
Skin Irrit. 2,,H315;
STOT SE 3, H336
CAS: 13463-67-7 titanium dioxide 40.0%
EINECS: 236-675-5 substance with a Community
workplace exposure limit
CAS: 24969-06-0 Polyepichlorohydrin 9.0%
SECTION 4: First aid measures
4.1 Description of first aid measures
General information : Immediately remove any clothing soiled by the product
After inhalation:In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:
Rinse out mouth with water.
Never give anything by mouth to an unconscious person.
Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayedNo further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Safety data sheet
Regulation (EC) No.1907/2006 and 1272/2008
Version number 1
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents:
CO2 , powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents:Water with full jet
5.2 Special hazards arising from the substance or mixture No further relevant information
available.
5.3 Advice for firefighters
Protective equipment:
Wear fully protective suit.
Mouth respiratory protective device.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation.
Keep away from ignition sources.
Use respiratory protective device against the effects of fumes/dust/aerosol.
Avoid breathing vapors, mist or gas.
Avoid contact with eyes.
Avoid contact with skin.
6.2 Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Keep receptacles tightly sealed.
Keep away from heat and direct sunlight.
Prevent formation of aerosols.
Avoid contact with skin and eyes.
For the general occupational hygienic measures refer to section 8.
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
7.2 Conditions for safe storage, including any incompatibilities:
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Store only in the original receptacle.
Information about storage in one common storage facility:
Store away from foodstuffs.
Keep away from ignition sources.
Store away from oxidising agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
108-87-2methylcyclohexane (51.0%)
AGW (Germany) Long-term value: 810 mg/m³, 200 ppm
2(II);DFG
TWA (Italy) Long-term value: 1606 mg/m³, 400 ppm
13463-67-7titanium dioxide (40.0%)
AGW (Germany) Long-term value: 1.25* 10** mg/m³
2(II);*alveolengängig**einatembar; AGS, DFG
TWA (Italy) Long-term value: 10 mg/m³
Regulatory information
AGM (Germany): TRGS 900
VME(France): ED 984,10.2016
DNELs:Data not available
PNECs:Data not available
Additional information:The lists valid during the making were used as basis.
8.2 Exposure controls
Based on composition shown in Section 3, the following messures are suggested for occupational
safety measure:
Appropriate engineering controls:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
See Section 7 for information about design of technical facilities.
Personal protective equipment:
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
· Protection of hands:
Protective gloves :
]The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
· Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection:
Tightly sealed goggles
· Environmental exposure controls:
Control measures must be made in accordance with Community environmental protection legislation.
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties
· Appearance:
Form: Liquid
Colour: White
· Odour: Weak odor
· Odour threshold: Data not available.
· pH-value: Data not available.
· Change in condition
Melting point/freezing point: Data not available.
Initial boiling point and boiling range: Data not available
· Flash point: -7 °C
· Flammability (solid, gas): Not applicable
· Auto-Ignition temperature: Data not available
· Decomposition temperature: Date not available.
· Self-igniting: Product is not selfigniting.
· Explosive properties: Product does not present an explosion hazard
· Explosion limits:
Lower: Data not available.
Upper: Data not available.
· Oxidising properties Data not available
· Vapour pressure: Data not available.
· Density: Data not available.
· Relative density Data not available.
· Vapour density Data not available.
· Evaporation rate Data not available.
· Solubility in / Miscibility with water: Data not available
· Partition coefficient: n-octanol/water: Data not available.
· Viscosity:
Dynamic: Data not available.
Kinematic at 40 degrees Celsius >20.5mm^2/s
· 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 Reactivity No decomposition if used according to specification.
· 10.2 Chemical stability Stable under recommended storage conditions.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid Heat, flames and sparks
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
108-87-2methylcyclohexane
Oral LD5 2250 mg/kg (mouse)
13463-67-7titanium dioxide
Oral LD50 >20000 mg/kg (rat)
Dermal LD50 >10000 mg/kg (rabbit)
· Skin corrosion/irritation:
Causes skin irritation.
· Serious eye damage/irritation: Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity: Based on available data, the classification criteria are not met.
· Reproductive toxicity: Based on available data, the classification criteria are not met.
· STOT-single exposure:
May cause drowsiness or dizziness.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB:Not applicable.
· 12.6 Other adverse effects No further relevant information available.
· 12.7 Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
SECTION 14: Transport information
· 14.1 UN-Number
· ADR/RID/ADN, IMDG, IATA UN1993
· 14.2 UN proper shipping name
· ADR/RID/ADN FLAMMABLE LIQUID, N.O.S. mixture,
ENVIRONMENTALLY HAZARDOUS
· IMDG FLAMMABLE LIQUID, N.O.S. mixture, MARINE
POLLUTANT
· IATA FLAMMABLE LIQUID, N.O.S. mixture
· 14.3 Transport hazard class(es)
· ADR/RID/ADN, IMDG
· Class 3 Flammable liquids.
· Label 3
· IATA
· Class 3 Flammable liquids.
· Label 3
· 14.4 Packing group
· ADR/RID/ADN, IMDG, IATA II
· 14.5 Environmental hazards Product contains environmentally hazardous
substances:methylcyclohexane
· Marine pollutant: Symbol (fish and tree)
· Special marking (ADR/RID/ADN): Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 33
· EMS Number: F-E,S-E
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· 14.8 Transport/Additional information:
Remarks: Special marking with the symbol (fish and tree)
· ADR/RID/ADN
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code:E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500ml
· Transport category 2
· Tunnel restriction code D/E
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500ml
· UN "Model Regulation": UN 1993 FLAMMABLE LIQUID, N.O.S. MIXTURE,
ENVIRONMENTALLY HAZARDOUS, 3, II,
ENVIRONMENTALLY HAZARDOUS
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· MAK (German Maximum Workplace Concerntration
13463-67-7 titanium dioxide 3A
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category
E2 Hazardous to the Aquatic Environment
P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements200 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements500 t
· National regulations:
· Waterhazard class:Water hazard class 2 (Self-assessment): hazardous for water.
· Other regulations, limitations and prohibitive regulations
· SVHC Candidate List of REACH Regulation Annex XIV Authorisation (12/1/2017)
None of the ingredients is listed.
· REACH Regulation Annex XVII Restriction (13/6/2017)
See Section 16 for information about restriction of use.
None of the ingredients is listed.
· REACH Regulation Annex XIV Authorization List (13/6/2017)
None of the ingredients is listed.
· 15.2 Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
· Relevant hazard statements
H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
Classification according to Regulation (EC) No 1272/2008
Flammable liquid Bridging principles
Skin corrosion/irritation The classification of the mixture is generally
Specific target organ toxicity-single exposure based on the calculation method using
Hazardous to the aquatic environment- substance data according to Regulation(EC)
chronic hazard No 1272/2008
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The contents and format of this SDS are in accordance with Regulation (EC) No 1907/2006,
1272/2008 and Regulation (EU) No 2015/830.
DISCLAIMER OF LIABILITY
The information in this SDS was obtained from sources which we believe are reliable. However,
the information is provided without any warranty, express or implied, regarding its correctness.
The conditions or methods of handling, storage, use or disposal of the product are beyond our
control and may be beyond our knowledge. For this and other reasons, we do not assume
responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any
way connected with the handling, storage, use or disposal of the product. This SDS was prepared
and is to be used only for this product. If the product is used as a component in another product,
this SDS information may not be applicable.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Skin Irrit. 2: Skin corrosion/irritation – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Asp. Tox. 1: Aspiration hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
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End of document