MATERIAL SAFETY DATA SHEET

Revision: 05 In accordance with Regulation (EU) No 453/2010 Page 1 of 6

Date: 27/03/18 Code: FSFGI5005E

SECTION 1: Identification of the substance/mixture and of the company

1.1. Product identifier

FRUITGARD-I-50
1.2. Relevant identified uses of the substance or mixture and uses advised against
Fungicide concentrate for treatment of citrus fruits (post-harvest treatment)
1.3. Details of the supplier of the safety data sheet
Manufacturer of the product:
FOMESA FRUITECH S.L.
Camí del Racó, 10 - Pol. Industrial Norte
46469 Beniparrell (Valencia – Spain)
Tel.: (0034) 96 121 18 62 Fax: (0034) 96 121 41 13
E-mail: info@fomesafruitech.net
1.4. Emergency telephone number
(0034) 96 121 18 62 (FOMESA FRUITECH S.L.)

SECTION 2: Hazards identification

2.1. Classification of the mixture

Carc. 2, Acute Tox. 4, Eye Dam. 1, Aquatic chronic 1.
2.2. Label elements

Signal word: Danger

Hazard statements:H351, H302+H332, H318, H410
Precautionary statements:P201+P202, P261, P280, P304+P340, P305+P351+P338, P273, P391,
P501, EUH401
Additional indications:SPo5

2.3. Other hazards

Not applicable.

SECTION 3: Composition/information on ingredients

3.1. Mixtures
Hazardous components

Substance name Chemical Name CAS-No. EC-No. % W/V Classification

Reg. 1272/2008
Acute Tox. 4 * - H302
1[2-(2,4-dichlorophenyl)-2-(2- Acute Tox. 4 * - H332
Imazalil propenyloxy)ethyl]-1H- 35554-44-0 252-615-0 50 % Aquatic Chronic 1 - H410
imidazole Eye Dam. 1 - H318
Aquatic Acute 1 - H400
Dodecyl 85536-14-7 or
C10-13 benzenesulfonic
benzenesulfonic 27176-87-0 287-494-3 7 – 8% Acute Tox. 4 H302
acid-alkyl derivatives.
acid

FRUITGARD-I-50

FOMESA FRUITECH, S.L. - Cami del Raco, 10 Pol. Ind. Norte, 46469 Beniparrell, Valencia (SPAIN)
Tel.: (34) 96 121 18 62 - Fax: (34) 96 121 41 13 - E-Mail: info@fomesafruitech.net
 MATERIAL SAFETY DATA SHEET
Revision: 05 In accordance with Regulation (EU) No 453/2010 Page 2 of 6
Date: 27/03/18 Code: FSFGI5005E

SECTION 4: First aid measures

4.1. Description of first aid measures

General measures: Remove the person of the contaminated area. Remove contaminated clothing
immediately. Keep the patient at rest. Keep body temperature. If the person is unconscious, lay it on
its side with the head lower than the rest of the body and knees semi-flexed. If necessary, transfer
the intoxicated person to a hospital center and, wherever possible, carry the label or the container.
Do not leave the intoxicated alone in any case.
If inhaled: Control the respiration. Artificial respiration may be necessary.
In case of skin contact: Remove stained and splashed clothes and wash the skin with water and
soap, without rubbing.
In case of eye contact:Rinse immediately with plenty of water for at least 15 minutes. (Do not forget
remove contact lenses).
If swallowed: Rinse mouth. Do not induce vomiting and do not give anything by mouth.
4.2. Most important symptoms and effects, both acute and delayed
Irritation and allergic dermatitis.
4.3. Indication of any immediate medical attention and special treatment needed
Specific antidote is unknown. Symptomatic treatment. In case of methemoglobinemia, administer
1% Methylene Blue.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media: Water (not spray jet), Carbon Dioxide (CO2), dry powder foam or
sand.
5.2. Special hazards arising from the substance or mixture
THIS PRODUCT IN NOT FLAMMABLE NEITHER FORM EXPLOSIVE MIXTURES IN THE AIR.
5.3. Advice for firefighters
In the event of fire, wear fire resistant personal protective equipment and clothing (including
breathing apparatus).

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate the danger zone. Provide sufficient ventilation. Wear adequate personal protection (see
section 8).
6.2. Environmental precautions
Avoid that the product reaches the drains and surface and underground waters.
6.3. Methods and materials for containment and cleaning up
Absorb spilled liquid with sand or other absorbent material. Pick it up and move the product to a
safe place for later disposal in accordance with current local legislation. Clean the affected area with
plenty of water, avoiding contact with the surface water.
6.4. Reference to other sections See the sections 8 and 13
6.5. Additional information.
No information available.

FRUITGARD-I-50

FOMESA FRUITECH, S.L. - Cami del Raco, 10 Pol. Ind. Norte, 46469 Beniparrell, Valencia (SPAIN)
Tel.: (34) 96 121 18 62 - Fax: (34) 96 121 41 13 - E-Mail: info@fomesafruitech.net
 MATERIAL SAFETY DATA SHEET
Revision: 05 In accordance with Regulation (EU) No 453/2010 Page 3 of 6
Date: 27/03/18 Code: FSFGI5005E

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Open and handle the containers carefully. Do not eat or drink in work areas.
7.2. Conditions for safe storage, including any incompatibilities
Do not handle containers and store away from direct sunlight and other sources of heat. Store in
ventilated places and always above 5ºC.
7.3. Specific end use(s)
Product intended for use in wax application equipment (post-harvest application in horticultural
plants). Reserved use to professional applicators.
Mitigation of risks in handling:
Applicator safety: During the loading, cleaning and maintenance of the application equipment, work
clothes and chemical protection gloves should be worn.
Worker safety: Chemical protection gloves should be used.
It is understood as work clothes: long sleeves, long pants and appropriate footwear.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters.

Components with environmental limit values for professional exposure: Not applicable
8.2. Exposure controls
Individual protection measures, such as personal protective equipment:
Protection of face and eyes: Use closed safety glasses or face shield.
Protection of skin (hands and others)
• APPLICATOR SAFETY (product loading and cleaning and equipment maintenance):
Work clothes (long sleeves, long pants and appropriate footwear) and chemical protection gloves.
• WORKER SAFETY: Chemical protection gloves.
Respiratory protection: During the handling of the product it is advisable to use masks with filter for
vapors (filter AX). In case of emergency, autonomous breathing equipment.
Environmental exposure controls: Prevent the product from reaching surface waters or the sewage
system.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties:

Appearance: Orange-brown liquid
pH: Approx. 7
Density (20 ° C): 1.075 – 1.175 g/ml
Viscosity (20 º C) (cP): Not available
Boiling point/range (° C): Not available
Flash point: > 110ºC
Explosive properties: Not explosive
Oxidizing properties: Not oxidizing.
9.2. Physical hazards: :Not classified.
9.3. Other information: Emulsifiable product in water

FRUITGARD-I-50

FOMESA FRUITECH, S.L. - Cami del Raco, 10 Pol. Ind. Norte, 46469 Beniparrell, Valencia (SPAIN)
Tel.: (34) 96 121 18 62 - Fax: (34) 96 121 41 13 - E-Mail: info@fomesafruitech.net
 MATERIAL SAFETY DATA SHEET
Revision: 05 In accordance with Regulation (EU) No 453/2010 Page 4 of 6
Date: 27/03/18 Code: FSFGI5005E

SECTION 10: Stability and reactivity

10.1. Reactivity
Stable for transport operations and storage under the recommended conditions
10.2. Chemical stability
Stable at normal temperatures and pressures.
10.3. Possibility of hazardous reactions
No dangerous reaction known under conditions of normal transport operations and storage.
10.4.Conditions to avoid
Avoid extreme temperatures (<5ºC or >50ºC). Keep away from direct sunlight.
10.5. Incompatible materials
Avoid alkaline products and acids.
10.6. Hazardous decomposition products
No hazardous decomposition products are formed under conditions of normal use and storage
provided that the directions for use are followed.

SECTION 11: Toxicological information

11.1. Toxicokinetics, metabolism and distribution: Not available.

11.2. Information on toxicological effects
Possibility of sensitization as a result of the contact of the product with the skin.
(Data relating to the active ingredient imazalil).
Acute toxicity:
LD50 (Oral, rat): (M) 343 mg / kg; (F) 227 mg / kg
LD50 (dermal, rabbit):> 2000 mg / kg.
CL50 (inhalation, rat): 1.84 mg / L of air.
Skin corrosion /irritation:Non-irritating to the skin
Serious eye damage/eye irritation: Very irritating to the eyes
Respiratory or skin sensitization: Non-sensitizing.
Germ cell mutagenicity:Non-mutagenic.
Carcinogenicity:Not carcinogenic.
Reproduction Toxicity Development:No data available.
STOT - single exposure: No data available.
STOT - repeated exposure:No data available.
Aspiration risk: No data available.

SECTION 12: Ecological information

(Data relating to the active ingredient imazalil).

12.1. Toxicity
Toxicity to fish: Salmo gairdneri: CL50 (96h): 1.48 mg / l; Brachydanio rerio: LC50 (96h): 2.75 mg / l
Toxicity to Daphnia: Daphnia magna: CE50 (48h): 3.5 mg / l
Toxicity to algae: Selenastrum capricornutum: CE50 (72h): 0.87 mg / l
Toxicity to bacteria: No data.
12.2. Persistence and degradability:No data available.
12.3. Bioaccumulative potential:BCF: 48.7-63.8
12.4. Mobility in soil: Surface tension: 46.6 mN / m (saturated solution of imazalil (90%) in water).
Absorption / desorption: Koc: 2080-8150 mg / l.
12.5. Results of PBT and vPvB assessment.No data available.
12.6. Other adverse effects: No data available.

FRUITGARD-I-50

FOMESA FRUITECH, S.L. - Cami del Raco, 10 Pol. Ind. Norte, 46469 Beniparrell, Valencia (SPAIN)
Tel.: (34) 96 121 18 62 - Fax: (34) 96 121 41 13 - E-Mail: info@fomesafruitech.net
 MATERIAL SAFETY DATA SHEET
Revision: 05 In accordance with Regulation (EU) No 453/2010 Page 5 of 6
Date: 27/03/18 Code: FSFGI5005E

SECTION 13: Disposal considerations

13.1.Waste treatment methods

Avoid contact of spilled material with soil and surface water.
The waste shall be disposed of in accordance with the provisions of the current national or regional
provisions.
Do not pour the remains of the product.

SECTION 14: Transport information

14.1. UN number: 3082

14.2. Proper shipping name: Liquid substance dangerous for the environment NEP (Imazalil).
14.3. Transport hazard class: 9
14.4. Packing group:III
14.5. Environmental hazards: Liquid substance dangerous for the environment.
14.6. Special precautions for user: Not applicable
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable.

SECTION 15: Regulatory information

Product registered in the Official Registry of Phytosanitary Products with nº 24360.

SECTION 16: Other information

Full text of H-Statements referring to point 2:

H351: Suspected of causing cancer <state route of exposure if it is conclusively proven that no
other routs of exposure cause the hazard>.
H302+332: Harmful if swallowed or inhaled.
H318: Causes serious eye damage
H410: Very toxic to aquatic life with long lasting effects.

Full text of P- Statements referring to point 2:

P201+P202: Obtain special instructions before use and do not handle until all safety precautions
have been read and understood.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P280: Wear protective gloves / clothing / eye protection / face protection.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P273: Avoid release to the environment.
P391: Collect spillage.
P501: Dispose of contents/container in accordance with the regulations on hazardous waste.
EUH 401: To avoid risks to human health and the environment, comply with the instructions for
use.
Full text of the additional indications referred to in point 2:
SPo5: Ventilate well treated areas before re-entering.

Full text of the abbreviated classifications referred to in point 2:

FRUITGARD-I-50

FOMESA FRUITECH, S.L. - Cami del Raco, 10 Pol. Ind. Norte, 46469 Beniparrell, Valencia (SPAIN)
Tel.: (34) 96 121 18 62 - Fax: (34) 96 121 41 13 - E-Mail: info@fomesafruitech.net
 MATERIAL SAFETY DATA SHEET
Revision: 05 In accordance with Regulation (EU) No 453/2010 Page 6 of 6
Date: 27/03/18 Code: FSFGI5005E

Carc. 2: Carcinogenicity, category 2

Acute Tox. 4: Acute toxicity (oral, inhalation), category 4
Eye Dam. 1: Serious eye injuries, category 1

The information provided is given in good faith and corresponds to our present knowledge. Compliance with the
indications contained in this safety data sheet does not exempt the user of the product from observing all legal,
regulatory and administrative procedures relating to the product, safety and hygiene and the environment, which is
the user’s exclusive responsibility. In the case of mixtures and combinations with other substances, ensure that no
other risks are generated.

END OF DOCUMENT

FRUITGARD-I-50

FOMESA FRUITECH, S.L. - Cami del Raco, 10 Pol. Ind. Norte, 46469 Beniparrell, Valencia (SPAIN)
Tel.: (34) 96 121 18 62 - Fax: (34) 96 121 41 13 - E-Mail: info@fomesafruitech.net