the magnesium combines with oxygen to form
magnesium oxide. Magnesium has been oxidised.
2Mg(s) + O2(g) 2MgO(s)
A simple definition of reduction is loss of oxygen. When
copper(II) oxide reacts with hydrogen, this is the equation
for the reaction:
CuO(s) + H2(g) Cu(s) + H2O(l)
Copper(II) oxide loses its oxygen. Copper(II) oxide has
been reduced.
But if we look carefully at the copper oxide/hydrogen
equation, we can see that oxidation is also taking place.
The hydrogen is gaining oxygen to form water. The
hydrogen has been oxidised. We can see that reduction
and oxidation have taken place together.
Oxidation and reduction always take place together.
We call the reactions in which this happens redox
reactions. Redox reactions are very important. For
example, one redox reaction – photosynthesis – provides
food for the entire planet, and another one – respiration –
keeps you alive. both are redox reactions.
We can also define reduction as addition of hydrogen to
a compound and oxidation as removal of hydrogen from
a compound. This is often seen in the reaction of organic
compounds (see page 237).
There are two other ways of finding out whether or
not a substance has been oxidised or reduced during a
chemical reaction:
■■ electron transfer
■■ changes in oxidation number.
Introduction
Some types of reactions can cost a lot of money due
to the damage they cause. Rusting is an oxidation
reaction that destroys about 20% of iron and steel
every year. Rust is hydrated iron(III) oxide. This forms
when iron reacts with oxygen in the presence of water.
Another costly example of oxidation is the reaction
between hydrogen and oxygen that is used to propel
some types of rockets into space. In this reaction, the
hydrogen is oxidised – but the oxygen is also reduced.
In fact, oxidation and reduction always take place
together, in what we call redox reactions.
Figure 7.1 A redox reaction is taking place when the fuel in
the Space Shuttle’s rockets burns.
1 a In each of the following equations, state which
reactant has been oxidised:
i PbO + H2 Pb + H2O
ii CO + Ag2O 2Ag + CO2
iii 2Mg + CO2 2MgO + C
b In each of the following equations, state which
reactant has bee