IRON
-The metal is never in a free state in nature. It naturally occurs in Zimbabwe mainly as
haematite, hydrated iron (III) oxide. Large deposits are at Redcliff and at Buchwa in
Mberengwa. Presently mining operations at Buchwa are at a standstill.
Raw Materials Used
-Near the bottom of the furnace, the carbon in coke burns in hot air, forming carbon
dioxide and producing temperature up to 1700C. Further up the furnace, the carbon
dioxide is reduced to carbon monoxide.
C (s) + O2(g) → CO2(g) + heat
CO2(g) + C(s) → 2CO(g)
Carbon + oxygen → carbon dioxide.
-As carbon dioxide rises up the furnace it reacts with coke, forming carbon monoxide, the
major reducing agent.
Carbon dioxide + carbon (coke) → carbon monoxide
Carbon monoxide reduces iron (III) oxide to iron
Carbon monoxide + iron (III) oxide → iron + carbon dioxide
- Limestone (calcium carbonate) decomposes into calcium oxide (lime) and carbon dioxide at
the high temperatures of the blast furnace.
Calcium carbonate heat calcium oxide + carbon dioxide
-Calcium oxide reacts with sand impurities to form a slag. Slag floats on top of molten iron.
- They are tapped from different holes.
-Calcium oxide reacts with sand impurities to form a slag. Slag floats on top of molten iron
Slag is less dense compared to molten iron so it is collected from a tap hole above the molten iron.
The iron produced is called cast iron
Cast iron
- Contains impurities such as phosphorus and Sulphur.
-Is brittle, it breaks easily.
- Rusts easily when exposed to air and water.
- Cast iron is put through the basic oxygen process, which is also called the oxygen lance process.
ALLOYS OF IRON
- An alloy is a mixture of metals or metals and non-metals to improve its properties.
- They are harder, more resistant to corrosion and have a more attractive appearance than
the metals they are formed from.