AP Chemistry Class Notes
1. Atomic Structure & Periodicity
Subatomic particles; mass number vs. atomic number; isotopes & mass spectrometry.
Electron configurations: Aufbau, Hund, Pauli; core vs. valence; periodic trends (Z_eff, IE, EA,
EN, atomic radius).
2. Bonding & Molecular Structure
Ionic vs. covalent vs. metallic; lattice energy; Coulomb’s Law.
Lewis structures & exceptions (octet, expanded valence, radicals).
VSEPR geometries, polarity, and IMF strength hierarchy: London < dipole-dipole < H-bonding <
ion-dipole.
Hybridization & molecular orbitals; σ vs. π bonds; resonance; formal charge.
3. Intermolecular Forces & Properties
States of matter, phase changes & diagrams (critical point, triple point).
Solutions: factors affecting solubility; concentration units (M, m, ppm, mole fraction).
Chromatography & distillation as separation techniques.
4. Chemical Reactions
Stoichiometry, limiting reactant, percent yield.
Reaction types: synthesis, decomposition, single-replacement, double-replacement,
combustion, redox.
Titrations: endpoint vs. equivalence; indicators; volumetric analysis; pH curves (strong/weak
combinations).
5. Kinetics
Rate laws (differential / integrated), determining order graphically.
Arrhenius equation; activation energy; catalysis; collision model; reaction mechanisms &
rate-determining step.
6. Thermodynamics
Enthalpy (ΔH): calorimetry (q = m c ΔT), Hess’s Law, bond enthalpies.
Entropy (ΔS) & Gibbs free energy (ΔG = ΔH – TΔS); spontaneity, coupling reactions.
Heat vs. temperature; phase change enthalpies.
7. Equilibrium
K_eq expressions; Le Châtelier shifts (concentration, pressure, temp).
Solubility product (K_sp) and common-ion effect.
Acid–base: Ka, Kb, pKa, pH = –log[H⁺]; polyprotic acids; buffers (Henderson–Hasselbalch).
Indicators and titration curves; hydrolysis of salts.
8. Electrochemistry
Galvanic vs. electrolytic cells: anode/ cathode signage, cell notation.
Nernst equation; ΔG° = –nF E°.
Faraday’s laws (m = ItM/nF); corrosion and prevention.