Carcinogen

Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi; N
(+/-)-(R*,R*)-6-Fluoro-3,4-dihydro-2-oxiranyl-2H-1- R43 R: 43-51/53
benzopyran [6-Fluoro-2-(2-oxiranyl)chromane] N; R51-53 S: (2-)36/37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
(±)-4-(3-Chlorophenyl)-6-[(4-chlorophenyl)hydroxy(1- Xi; N
methyl-1H-imidazol-5-yl)methyl]-1-methyl-2(1H)- Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
quinolin N; R50-53 S: (2-)22-26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
(1alpha5alpha6alpha)-6-Nitro-3-benzyl-3- Xi; R41 R: 22-41-51/53 >=10%Conc<25%: Xi; R41
azabicyclo[3,1,0]hexane methanesulfonate salt N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi
(1R,3S,7R,8R,10R,13R)-5,5,7,9,9,13-Hexamethyl-4,6- R: 38
dioxatetracyclo[6.5.1.01,10.03,7]tetradecane Xi; R38 S: (2-)37 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xi; N
(1R,4R)-4-Methoxy-2,2,7,7- Xi; R38 R: 38-51/53
tetramethyltricyclo(6.2.1.0(1,6))undec-5-ene N; R51-53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
N
(1S,1'R)-[1-(3',3'-Dimethyl-1'- R: 51/53
cyclohexyl)ethoxycarbonyl]methyl propanoate N; R51-53 S: 61 Eu - - - - - - - -

(2-Hydroxy-3-(3,4-dimethyl-9-oxo-10-thiaanthracen-2- R: 52/53
yloxy)propyl)trimethylammonium chloride R52-53 S: 61 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
(2R*,3S*)-2-(2,4-Difluorophenyl)-3-(5-fluoro-4- Xi; R41 Xn >=10%Conc<25%: Xi; R41; R43
pyrimidinyl)-1-(1H-1,2,4-triazol-1-yl)butan-2-ol (1R)-10 R43 R: 22-41-43-52/53 >=5%Conc<10%: Xi; R36; R43
camphorsulfonate R52-53 S: (2-)22-24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R48/22
Xi; R41 Xn; N Conc>=10%: Xn; R48/22; R41; R43
(2R,3S)-N-(3-Amino-2-hydroxy-4-phenylbutyl)-N- R43 R: 41-43-48/22-51/53 >=5%Conc<10%: Xi; R36; R43
isobutyl-4-nitrobenzenesulfonamide hydrochloride N; R51-53 S: (2-)22-26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
(3S—trans)-Phenyl-3-[(1,3-benzodioxol-5-
yloxy)methyl]-4-(4-fluorophenyl)-1- R: 53
piperidinecarboxylate R53 S: 22-61 Eu - - - - - - - -
(4-(6-Diethylamino-2-methylpyridin-3-yl)imino-4,5-
dihydro-3-methyl-1-(4-methylphenyl)-1H-pyrazol-5- R: 53
one R53 S: 61 Eu - - - - - - - -
(C16 or C18-N-Alkyl)(C16 or C18-N-alkyl)ammonium- Xi; R38
2-((C16 or C18-N-alkyl)(C16 or C18-N- R43 Xi ; R: 38 - 43 - 53 , Conc>=20%: Xi; R38; R43
alkyl)carbamoyl)benzenesulfonate R53 S: (2) - 24 - 37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
N ; R: 50/53 ,
(Chlorophenyl)(chlorotolyl)methane, mixed isomers N; R50-53 S: 60 - 61 Eu - - - - - - - -
Xi
(E)-(7R,11R)-3,7,11,15-Tetramethylhexadec-2-ene-1- Xi; R38 R: 38-53
ol R53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xi; N
R43 R: 43-50/53
(E)-3-Methyl-5-cyclopentadecen-1-one N; R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
C; N
(Ethyl-1,2-ethanediyl)[-2-[[[(2- C; R34 R: 34-43-51/53 Conc>=10%: C; R34; R43
hydroxyethyl)methylamino]acetyl]-propyl]omega- R43 S: (1/2-)26-28-36/37/39-45- >=5%Conc<10%: Xi; R36/38; R43
(nonylphenoxy)poly]oxy-(methyl-1,2-ethanediyl) N; R51-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
(Methylenebis(4,1-phenylenazo(1-(3-
(dimethylamino)propyl)-1,2-dihydro-6-hydroxy-4- T; N
methyl-2-oxopyridine-5,3-diyl)))-1,1'-dipyridinium Carc.Cat.2; R45 R: 45-51/53
dichloride dihydrochloride N; R51-53 S: 53-45-61 Conc>=0.1%: T; R45 Eu - - - - - - - -

C; R34 C; N Conc>=25%: C; R34; R22

(N-Benzyl-N,N,N-tributyl)ammonium 4- Xn; R22 R: 22-34-51/53 >=10%Conc<25%: C; R34
dodecylbenzenesulfonate N; R51-53 S: (1/2-)26-36/37/39-45-61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xn
(R)-1-Cyclohexa-1,4-dienyl-1-methoxycarbonyl- R: 22
methylammoniumchloride Xn; R22 S: (2-) Conc>=25%: Xn; R22 Eu - - - - - - - -

Page 1
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R22 Conc>=25%: Xn; R22; R41; R43
Xi; R41 Xn >=10%Conc<25%: Xi; R41; R43
(R,S)-1-[2-Amino-1(4- R43 R: 22-41-43-52/53 >=5%Conc<10%: Xi; R36; R43
methoxyphenyl)ethyl]cyclohexanol acetate R52-53 S: (2-)22-24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
(R,S)-4-(4-Dimethylamino-1-(4-fluorophenyl)-1- Xi; R41 Xn; N >=10%Conc<25%: Xi; R41; R43
hydroxybutyl)-3-(hydroxymethyl)benzonitrile R43 R: 22-41-43-51/53 >=5%Conc<10%: Xi; R36; R43
hemisulfate N; R51-53 S: (2-)22-26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
R: 52/53
(S)-1,1-Diphenyl-1,2-propanediol R52-53 S: 22-61 Eu - - - - - - - -
Xn; R22 Xn
(S)-Azetidine-2-carboxylic acid 4-cyanobenzylamide R43 R: 22-43-52/53 Conc>=25%: Xn; R22; R43
hydrochloride R52-53 S: (2-)22-36/37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

Xn; R22-48/22 Xn; N Conc>=25%: Xn; R22; R48/22; R41; R43

Xi; R41 R: 22 - 41 - 43 - 48/22 - >=10%Conc<25%: Xn; R48/22; R41; R43
(Z)-1-Benzo[b]thien-2-ylethanone oxime R43 51/53 >=5%Conc<10%: Xi; R36; R43
hydrochloride N; R51-53 S: (2)22 - 26 - 36/37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi
± -alpha-[(2-Acetyl-5-methylphenyl)-amino]-2,6- R43 R: 43-53
dichlorobenzene-aceto-nitrile R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
N
±(R*,S*)-6-Fluoro-3,4-dihydro-2-oxiranyl-2H-1- R: 51/53
benzopyran N; R51-53 S: 24-61 Eu - - - - - - - -
Xi; N
±[(R*,R*)and(R*,S*)]-6-Fluoro-3,4-dihydro-2-oxiranyl- R43 R: 43-51/53
2H-1-benzopyran N; R51-53 S: (2-)24-28-36/37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
R: 43
1-(4-(trans-4-Ethylcyclohexyl)phenyl)ethanone R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
N
R: 51/53
1-(4-Morpholinophenyl)butan-1-one N; R51-53 S: 61 Eu - - - - - - - -
1,1'-(1,3-Phenylenedioxy)bis(3-(2-(prop-2- R43 Xi ; N ; R: 43 - 50/53,
enyl)phenoxy)propan-2-ol) N; R50-53 S: (2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
1,3-Bis(4-benzoyl-3-hydroxyphenoxy)prop-2-yl N ; R: 51/53
acetate N; R51-53 S: 61 Eu - - - - - - - -
Xi
1,3-Bis[12-hydroxy-octadecamide-N-methylene]- R43 R: 43-53
benzene R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
1,4-Benzenedicarboxylic acid, dimethyl ester,
polymer with 1,4-butanediol, alpha-hydro-omega-
hydroxypoly(oxy-1,4-butanediyl), dodecanedioic acid,
1,6-hexanediol and 1,1'-methylenebis[4- Xn Isocyanates, all
isocyanatobenzene] Xn; R42 R: 42 Conc>=1%: Xn; R42 N; A (as-NCO) - 0.02 - 0.07 - Sen -

1,4-Benzenedicarboxylic acid, polymer with 1,2-

ethanediol, hexanedioic acid, 1,3-
isobenzofurandione, 1,3-benzenedicarboxylic acid,
dimethyl 1,4-benzenedicarboxylate, 2,2-dimethyl-1,3-
propanediol, 3-hydroxy-2,2-dimethylpropyl 3-hydroxy-
2,2-dimethylpropanoate, 1,6-hexanediol and 1,1'- Xn
methylenebis[4-isocyanatobenzene] Xn; R42 R: 42 Conc>=1%: Xn; R42 N - - - - - - - -

1,4-Benzenedicarboxylic acid, polymer with 1,2-

ethanediol, hexanedioic acid, 1,3-
isobenzofurandione, 1,3-benzenedicarboxylic acid,
dimethyl 1,4-benzenedicarboxylate, 2,2-dimethyl-1,3-
propanediol, 3-hydroxy-2,2-dimethylpropyl 3-hydroxy- Xn
2,2-dimethylpropanoate, 1,6-hexanediol and 1,1'- R: 42
methylenebis[isocyanatobenzene] Xn; R42 S: 23-28-36/37-38-45 Conc>=1%: Xn; R42 N - - - - - - - -

Page 2
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Xn; R21/22-48/21 C; N Conc>=25%: C; R34; R21/22; R48/21; R43

C; R34 R: 21/22-34-43-48/21-50/53 >=10%Conc<25%: C; R34; R48/21; R43
1,6-Bis(3,3-bis((1- R43 S: (1/2-)7-26-36/37/39-45-60- >=5%Conc<10%: Xi; R36/38; R43
methylpentylidenimino)propyl)ureido)hexane N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn
Xn; R22 R: 22-52/53
1-Ethyl-5,6,7,8-tetrahydroquinolinium tosylate R52-53 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi
R43 R: 43-53
1-Imidazol-1-yl-octadecan-2-ol R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
2-(4-(5,6(or 6,7)-Dichloro-1,3-benzothiazol-2-ylazo)-N- Xi; R: 43,
methyl-m-toluidino)ethyl acetate Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

2-(4,4-Dimethyl-2,5-dioxooxazolidin-1-yl)-2-chloro-5-
(2-(2,4-di-tert-pentylphenoxy)butyramido)-4,4- R: 53
dimethyl-3-oxovaleranilide R53 S: 61 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
Xi; R41 Xn >=10%Conc<25%: Xi; R41; R43
2-(4-Methyl-2-phenyl-1-piperazinyl)benzenemethanol R43 R: 22-41-43-52/53 >=5%Conc<10%: Xi; R36; R43
monohydrochloride R52-53 S: (2-)22-26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
2-(Trimethylammonium)ethoxycarboxybenzene-4- Xi ; R: 43 ,
sulfonate Xi; R43 S: (2) - 22 - 36/ 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
2,2'-[3,3'-(Piperazine-1,4-diyl)dipropyl]bis (1h-
benzimidazo[2,1-b]benzo[1,m,n][3,88]phenanthroline- R: 53
1,3,6-trione R53 S: 61 Eu - - - - - - - -

2,2-Dialkyl-4-hydroxymethyl-1,3-dioxolane; reaction R19 Xi; N

products with ethylene oxide (alkyl is C1-12 and the Xi; R38 R: 19-38-51/53
sum to C13, average degree of ethoxylation is 3.5) N; R51-53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 22 - 50/53,
2,2'-Dichloro-4,4-methylenedianiline, salts of [4,4'- Xn; R22 S: 53 - 45 - 60 - 61 ; Conc>=25%: T; R45; R22
Methylenebis(2-chloroaniline), salts of] N; R50-53 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -

Xn; R22 Xn; N

2,2'-Dithio di(ethylammonium)- R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
bis(dibenzyldithiocarbamate) N; R50-53 S: (2-)15-22-29-36/37-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 36/37/38 -
2,4,5-T, salts and esters of [2,4,5- Xi; R36/37/38 50/53, Conc>=25%: Xn; R22; R36/37/38
Trichlorophenoxyacetic acid, salts and esters of] N; R50-53 S: (2) - 24 - 60 - 61 >=20%Conc<25%; Xi; R36/37/38 Eu - - - - - - - -
Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
2,4-Bis(((2-(dimethylammonio)ethyloxy)carbonyl)phen-Xi; R41 R: 22-41-51/53 >=10%Conc<25%: Xi; R41
2-ylazo)benzene-1,3-diol sulfate N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
2,4-Bis(((2-(dimethylammonio)ethyloxy)carbonyl)phen-Xi; R41 R: 22-41-51/53 >=10%Conc<25%: Xi; R41
2-ylazo)benzene-1,3-diolbis(methanesulfonate) N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N ; R: 50/53
2,4-Bis[N'-(4-methylphenyl)ureido]toluene N; R50-53 S: 60 - 61 Eu - - - - - - - -
Xn; N
Xn; R22 R: 22 - 41 - 43 - 51/53 Conc>=25%: Xn; R22; R41; R43
Xi; R41 S: (2) - 24/25 - 26 - 36/37/39 >=10%Conc<25%: Xi; R41; R43
R43 - 46 - 61 ; >=5%Conc<10%: Xi; R36; R43
2,4-D, salts of N; R51-53 Note: A >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; N
R: 22 - 41 - 51/53
Xn; R22 S: (2) - 26 - 29 - 39 - 46 - 61 Conc>=25%: Xn; R22; R41
Xi; R41 ; >=10%Conc<25%: Xi; R41
2,4-DB, salts of N; R51-53 Note: A >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; R38
R43 Xi ; N ; R: 38 - 43 - 50/53 Conc>=20%: Xi; R38; R43
2,4-Dimethyl-6-(1-methyl-pentadecyl)phenol N; R50-53 S: (2)24 - 37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn; R48/22 Xn Conc>=10%: Xn; R41; R48/22; R43
2,5-Dioxopyrrolidin-1-yl N-{[methyl[[2-(1-methylethyl)- Xi; R41 R: 41-43-48/22 >=5%Conc<10%: Xi; R36; R43
4-thiazolyl]methyl]amino]carbonyl}-L-valinate R43 S: (2-)22-26-36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Page 3
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi Conc>=20%: Xi; R38; R41
2,6,6,7,8,8-Hexamethyldecahydro-2H-indeno[4,5- Xi; R38-41 R: 38-41-53 >=10%Conc<20%: Xi; R41
b]furan R53 S: (2-)26-37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
E; R2 E; N
2,6-Bis(2,3,4-trihydroxybenzyl)-p-cresol ester with 6- F; R11 R: 2-11-51/53
diazo-5,6-dihydro-5-oxo-1-naphthalenesulfonate N; R51-53 S: (2-)22-61 Eu - - - - - - - -

2:1 Mixture of tris(3,5,5-trimethylhexylammonium) 4-

amino-3-(4-(4-(2-amino-4-hydroxyphenylazo)anilino)-
3-sulfonatophenylazo)-5,6-dihydro-5-oxo-6-
phenylhydrazononaphthalene-2,7-disulfonate and
tris(3,5,5-trimethylhexylammonium) 4-amino-3-(4-(4-
(4-amino-2-hydroxyphenylazo)anilino)-3-
sulfonatophenylazo)-5,6-dihydro-5-oxo-6- Xi; R41 Xi ; N ; R: 41 - 51/53 Conc>=10%: Xi; R41
phenylhydrazononaphthalene-2,7-disulfonate N; R51-53 S: (2)26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

2:1:1 Mixture of: trisodium N(1')-N(2):N(1''')-N(2'')-n6-

[2-amino-4-(or 6)-hydroxy-(or 4-amino-2-
hydroxy)phenylazo]-6''-(1-carbaniloyl-2-hydroxyprop-1
enylazo)-5',5'''-disulfamoyl-3,3''-
disulfonatobis(naphtha-lene-2,1'-azobenzene-
1,2'diolato-O(1),O(2'))-chromate; with trisodium N(1')-
N(2):N(1''')-N(2'')-n-6,6''-bis(1-carbaniloyl-2-
hydroxyprop-1-eny-lazo)-5',5'''-disulfamoyl-3,3''-
disulfonato-bis(naphthalene-2,1'azobenzene-1,2'-
diolato-O(1),O(2'))-chromate; with trisodium N(1')-
N(2):N(1''')-N(2'')-n-6,6''-bis[2-amino-4-(or 6)-hydroxy-
(or 4-amino-2-hydroxy)phenylazo]5,5'''-disulfamoyl- Xi
3,3''-disulfonatobis(naphthalene-2,1'asobenzene- Xi; R41 R: 41 - 52/53 Conc>=10%: Xi; R41
1,2'diolato-O(1),O(2'))-chromate 52-53 S(2)26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

2-[2-Hydroxy-3-(2-chlorophenyl)carbamoyl-1- T
naphthylazo]-7-[2-hydroxy-3-(3- Repr.Cat.2; R61 R: 61-53
methylphenyl)carbamoyl-1-naphthylazo]fluoren-9-one R 53 S: 53-45-61 Conc>=0.5%: T; R61 Eu - - - - - - - -
2-[4-[n-(4-Acetoxybutyl)-N-ethyl]amino-2- R: 53
methylphenylazo]-3-acetyl-5-nitrothiophene R53 S: 61 Eu - - - - - - - -
2-{4-(2-Ammoniopropylamino)-6-[4-hydroxy-3-(5-
methyl-2-methoxy-4-sulfamoylphenylazo)-2- Repr.Cat.3; R62 Xn; N
sulfonatonaphth-7-ylamino]-1,3,5-triazin-2-ylamino}-2- Xi; R41 R: 41-62-51/53 Conc>=10%: Xn; R62; R41
aminopropyl formate N; R51-53 S: (2-)22-26-36/37/39-61 >=5%Conc<10%: Xn; R62; R36 Eu - - - - - - - -

2-Alkoyloxyethyl hydrogen maleate, where alkoyl Conc>=20%: Xi; R38; R41; R43
represents (by weight) 70 to 85% unsaturated Xi; R38-41 Xi; N >=10%Conc<20%: Xi; R41; R43
octadecoyl, 0.5 to 10% saturated octadecoyl, and 2 R43 R: 38-41-43-50/53 >=5%Conc<10%: Xi; R36; R43
to 18% saturated hexadecoyl N; R50-53 S: (2-)24-26-37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi
Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
2-Amino-4-bromo-5-chlorobenzoic acid R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
2'-Anilino-3'-methyl-6'-
dipentylaminospiro(isobenzofuran-1(1H),9'-xanthen)- R: 53
3-one R53 S: 61 Eu - - - - - - - -
Xi; R36/38 Xi
R43 R: 36/38-43-52/53 Conc>=20%: Xi; R36/38; R43
2-Chloro-5-sec-hexadecylhydroquinone R52-53 S: (2-)24-26-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
N
2-Dodec-1-enylbutanedioic acid, 4-methyl ester zinc R: 51/53
salt N; R51-53 S: 61 Eu - - - - - - - -
2-Ethoxyethyl 2-(4-(2,6-dihydro-2,6-dioxo-7-phenyl- Xi; R43 Xi ; R: 43 - 53,
1,5-dioxaindacen-3-yl)phenoxy)acetate R53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
R: 52/53
2-Ethyl-1-(2-(1,3-dioxanyl)ethyl)-pyridinium bromide R52-53 S: 61 Eu - - - - - - - -

Page 4
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi; N Conc>=20%: Xi; R38; R41
2-Hydroxy-3-(2-ethyl-4-methylimidazoyl)propyl Xi; R38-41 R: 38-41-50/53 >=10%Conc<20%: Xi; R41
neodecanoate N; R50-53 S: (2-)26-28-37/39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
O; R8
Xn; R22 O ; C ; N ; R: 8 - 22 - 35 - 43 Conc>=25%: C; R35; R22; R43
C; R35 - 50 >=10%Conc<25%: C; R35; R43
R43 S: (1/2) - 3/7 - 14 - 26 - >=5%Conc<10%: C; R34; R43
2-Hydroxyethylammonium perbromide N; R50 36/37/39 - 45 - 60 - 61 >=1%Conc<5%: Xi; R36/38; R43 Eu - - - - - - - -
R10
Repr.Cat.3; R63 Conc>=20%: Xn; R63; R48/20/22; R65;
Xn; R48/20/22-65 R36/38; R43
Xi; R36/38 Xn; N >=10%Conc<20%: Xn; R63; R48/20/22; R65;
R43 R: 10-36/38-43-48/20/22-63- R43
R67 65-67-50/53 >=5%Conc<10%: Xn; R63; R43
2-Methyl-5-tert-butylthiophenol N; R50-53 S: (2-)26-36/37-62-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R48/22 Xn ; N ; R: 43 - 48/22 -
R43 51/53 Conc>=10%: Xn; R48/22; R43
2-Naphthylamino-6-sulfomethylamide N; R51-53 S: (2)22 - 36/37 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
C; N
C; R34 R: 34-43-50/53 Conc>=10%: C; R34; R43
R43 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: Xi; R36/38; R43
2-n-Butyl-benzo[d]isothiazol-3-one N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R48/22
Xi; R38 Conc>=20%: Xi; R48/22; R43; R38
R43 Xn ; R: 38 - 43 - 48/22 - 53 >=10%Conc<20%: Xn; R48/22; R43
2-n-Hexadecylhydroquinone R53 S: (2)22 - 36/37 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
Xi
R: 43
3-(4-Aminophenyl)-2-cyano-2-propenoic acid R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
R14
R29 Conc>=25%: C; R35; R22
C; R35 C >=10%Conc<25%: C; R35
Xn; R22 R: 14-22-29-35-52/53 >=5%Conc<10%: C; R34
3-(4-Fluorophenyl)-2-methylpropionylchloride R52-53 S: (1/2-)26-36/37/39-45-61 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

3,3,8,8,10,10-Hexamethyl-9-[1-(4-oxiranylmethoxy- R: 53
phenyl)-ethoxy]-1,5-dioxa-9-aza-spiro[5.5]undecane R53 S: 61 Eu - - - - - - - -
3,3'-Bis(dioctyloxyphosphinothioylthio)-N,N'- R: 52/53
oxybis(methylene)dipropionamide R52-53 S: 61 Eu - - - - - - - -
T ; R: 45 - 22 ,
3,3'-Dimethoxybenzidine, salts of [o-Dianisidine, salts Carc. Cat. 2; R45 S: 53 - 45 ; Conc>=25%: T; R45; R22
of] Xn; R22 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
3,4-Dichloro-N-[5-chloro-4-[2-[4-
(hexadecyloxy)phenylsulfonyl]butyramido]-2- R: 53
hydroxyphenyl]benzamide R53 S: 61 Eu - - - - - - - -
3,4-Dichloro-N-[5-chloro-4-[2-[4-
dodecyloxyphenylsulfonyl]butyramido]-2- R: 53
hydroxyphenyl]benzamide R53 S: 61 Eu - - - - - - - -
3:1 Mixture of 1-deoxy-1-[methyl-(1-
oxododecyl)amino]-D-glucitol and 1-deoxy-1-[methyl- Xi ; R: 41 , Conc>=10%: Xi; R41
(1-oxotetradecyl)amino]-D-glucitol Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N
3-[(4'-Acetoxy-3'-methoxyphenyl) R: 51/53
propyl]trimethoxysilane N; R51-53 S: 61 Eu - - - - - - - -
O; R7 O ; Xi ; N
R10 R: 7 - 10 - 38 - 50/53
3-Hydroxy-1,1-dimethylbutyl 2-ethyl-2- Xi; R38 S: (2)7/47 - 14 - 36/37/39 -
methylheptaneperoxoate N; R50-53 60 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xn; R48/22 Xn; N
Xi; R36/38 R: 36/38-48/22-50/53 Conc>=20%: Xn; R48/22; R36/38
3-Tridecyloxy-propyl-ammonium 9-octadecenoate N; R50-53 S: (2-)23-26-37/39-60-61 >=10%Conc<20%: Xn; 48/22 Eu - - - - - - - -
4-(2-Carboxymethylthio)ethoxy-1-hydroxy-5- N
isobutyloxycarbonylamino-N-(3-dodecyloxypropyl)-2- R: 50/53
naphthamide N; R50-53 S: 60-61 Eu - - - - - - - -

Page 5
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

4-(5-(5-[1-(4-Carboxyphenyl)hexahydro-2,4,6-
trioxopyrimidin-5-ylidene]penta-1,3-dienyl)-1,2,3,4- Xi
tetrahydro-6-hydroxy-2,4-dioxopyrimidin-1-yl)benzoic Xi; R37 R: 37-52/53
acid-triethylamine salt R52-53 S: (2-)61 Conc>=20%: Xi; R37 Eu - - - - - - - -
Carc. Cat. 3; R40 Xn ; N ; R: 22 - 36 - 40 -
Xn; R22 51/53, Conc>=25%: Xn; R40; R22; R36
Xi; R36 S: (2) - 36/37 - 61; >=20%Conc<25%: Xn; R40; R36
4,4'-Carbonimidoylbis [N,N-dimethylaniline], salt of N; R51-53 Note: A >=1%Conc<20%: Xn; R40 Eu - - - - - - - -
Xn
4,4'-Methylene bis(3-chloro-2,6-di- R42/43 R: 42/43-53 Isocyanates, all
ethylphenylisocyanate) R53 S: (2-)23-24-37-45-61 Conc>=1%: Xn; R42/43 Eu;A (as-NCO) - 0.02 - 0.07 - Sen -
4,7-Methanooctahydro-1H-indene-diyldimethyl bis(2- R: 53
carboxybenzoate) R53 S: 61 Eu - - - - - - - -
4-Benzyloxy-4'-(2,3-epoxy-2-methylprop-1- R: 53
yloxy)diphenylsulfone R53 S: 61 Eu - - - - - - - -
Xi
R43 R: 43-53
4-Hexadecyl-1-phenylpyrazolidin-3-one R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
4-Nonylphenol, reaction products with formaldehyde Xi; R43 Xi ; R: 43 - 53 ,
and dodecane-1-thiol R53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
5-(2-Amino-5-cyano-6-[2-(2- Xi
hydroxyethoxy)ethylamino]-4-methylpyridin-3-ylazo)-3- R: 43
methyl-2,4-dicarbonitrilethiophene R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
R10 Xn; N
Xn; R22 R: 10-22-51/53
5-(2-Bromophenyl)-2-tert-butyl-2H-tetrazole N; R51-53 S: (2-)16-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
5-(4-[4-[4-(3,5-Dicarboxy-phenyl-azo)phenylamino]-6-
morpholin-4-yl-1,3,5-triazin-2- Xi Conc>=10%: Xi; R41; R43
ylamino]phenylazo)isophthalic acid, mixed Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
monosodium and diammonium salt R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
6,6'-Bis(diazo-5,5',6,6'-tetrahydro-5,5'-
dioxo)[methylene-bis(5-(6-diazo-5,6-dihydro-5-oxo-1- E; R2 E; Xn
naphthylsulphonyloxy)-6-methyl-2- F; R11 R: 2-11-40
phenylene]di(naphthalene-1-sulfonate) Carc. Cat. 3; R40 S: (2-)7-22-36/37 Conc>=1%: Xn R40 Eu - - - - - - - -
Conc>=20%: Xi; R38; R41; R43
Xi; R38-41 Xi ; N ; R: 38 - 41 - 43 - >=10%Conc<20%: Xi; R41; R43
R43 51/53 >=5%Conc<10%: Xi; R36; R43
6-Fluoro-2-methyl-3-(4-methylthiobenzyl)indene N; R51-53 S: (2)26 - 36/37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
6-tert-Butyl-4-butyl-7-(6-diethylamino-2-methyl-3- N
pyridylimino)-3-(3-methylphenyl)pyrazolo[3,2- R: 50/53
c][1,2,4]triazole N; R50-53 S: 60-61 Eu - - - - - - - -

7-Amino-4-hydroxy-2-naphthalenesulfonic acid,
coupled with 5 (or 8) -amino-8 (or 5)-[[4-[[4-[[4-amino-
6(or 7)-sulfo-1-naphthyl]azo]phenyl]amino]-3-
sulfophenyl]azo]-2-naphthalenesulfonic acid and 4- Xi
hydroxy-7-(phenylamino)-2-naphthalenesulfonic acid, R: 41 Conc>=10%: Xi; R41
sodium salt Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T+ ; R: 26/28 , Conc>=7%: T+; R26/28
S: (1/2) - 24 - 45 ; >=1%Conc<7%: T; R23/25
Aconitine, salts of T+; R26/28 Note: A >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -

Acrylic acid, monoalkyl or monoaryl or monoalkylaryl Xi; N

esters of, with the exception of those specified Xi; R36/37/38 R: 36/37/38-51/53
elsewhere in HSIS N; R51-53 S: (2-)26-28-61; Note: A Conc>=10%: Xi; R36/37/38 Eu - - - - - - - -
C; N Conc>=25%: C; R35; R22
Xn; R22 R: 22-35-50/53 >=10%Conc<25%: C; R35
Alkyl(rapeseed oil), bis(2-hydroxyethyl)ammonium C; R35 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: C; R34
fluoride N; R50-53 61 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
alpha-[3-(1-Oxoprop-2-eny)l-1-
oxypropyl]dimethoxysilyloxy-omega-[3(1-oxoprop-2- Xi R:
enyl)-1-oxypropyl]dimethoxysilyl 43 S: (2-
poly(dimethylsiloxane) R43 )24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 6
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
C ; N ; R: 21/22 - 34 - 51/53
Xn; R21/22 , Conc>=25%: C; R34; R21/22
alpha-Hydroxypoly(methyl-(3-(2,2,6,6- C; R34 S: (1/2) - 26 - 36/37/39 - 45 - >=10%Conc<25%: C; R34
tetramethylpiperidin-4-yloxy)propyl)siloxane) N; R51-53 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
R14 F ; C ; R: 14 - 17 - 34,
F; R17 S: (1/2) - 16 - 43 - 45; Conc>=10%: C; R34 Aluminium, alkyls
Aluminium alkyls C; R34 Note: A >=5%Conc<10%: Xi; R36/38 Eu; A (NOC) (as Al) - 2 - - - - -

Aluminium, soluble
Aluminium salts (soluble) A salts (as Al) - 2 - - - - -
N
Aluminium-magnesium-carbonate-hydroxide- R: 50/53
perchlorate-hydrate N; R50-53 S: 60-61 Eu - - - - - - - -
Ammonium (eta-6-2-(2-(1,2- N
dicarboxylatoethylamino)ethylamino)butane-1,4- R: 51/53
dioato(4-))iron(3+) monohydrate N; R51-53 S: 61 Eu - - - - - - - -
Xi Conc>=20%: Xi; R38; R41
R: 38-41 >=10%Conc<20%: Xi; R41
Ammonium 2-cocoyloxyethanesulfonate Xi; R38-41 S: (2-)26-37/39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
F; N
Ammonium bis(1-(3,5-dinitro-2-oxidophenylazo)-3-(N- F; R11 R: 11-50/53
phenylcarbamoyl)-2-naphtholato)chromate(1-) N; R50-53 S: (2-)33-60-61 Eu - - - - - - - -
Ammonium-7-(2,6-dimethyl-8-(2,2-
dimethylbutyryloxy)-1,2,6,7,8,8a-hexahydro-1- R: 52/53
naphthyl)-3,5-dihydroxyheptanoate R52-53 S: 61 Eu - - - - - - - -
Amylases, with the exception of those elsewhere Xn; R: 42,
specified Xn; R42 S: 2 - 22 - 24 - 36/37 Conc>=1%: Xn; R42 Eu - - - - - - - -
Conc>=25%: T; R40; R68; R23/24/25;
Carc. Cat. 3; R40 R48/23/24/25; R41;R43
Muta. Cat. 3; R68 T; N >=10%Conc<25%: T; R40; R68; R48/23/24/25;
T; R23/24/25-48/23/24/25 R: 23/24/25-40-41-43- R20/21/22; R41; R43
Xi; R41 48/23/24/25-68-50 >=1% Conc<10%: T; R40; R68; R48/23/24/25;
R43 S: (1/2-)26-27-36/37/39-45- R20/21/22; R43
Aniline, salts of N; R50 61-63; Note: A >=0.2%Conc<1%: Xn; R48/20/21/22 Eu - - - - - - - -
Antimony compounds, with the exception of the
tetroxide (Sb2O4), pentoxide (Sb2O5), trisulphide Xn; N Antimony &
(Sb2S3), pentasulphide (Sb2S5) and those specified Xn; R20/22 R: 20/22-51/53 compounds (as
elsewhere in HSIS N; R51-53 S: (2-)61; Note: A Conc>=0.25%: Xn; R20/22 Eu; A Sb) - 0.5 - - - - -
Arsenic acid and its salts with the exception of those T; N
specified elsewhere in HSIS(Note: Pb and Ca Carc. Cat. 1; R45 R: 45-23/25-50/53 Conc>=25%: T; R45; R23/25
arsenates are largely insoluble in water; Na and K T; R23/25 S: 53-45-60-61 >=3%Conc<25%: T:; R45; R20/22
soluble) N; R50-53 Notes: A ; E >=0.1%Conc<3%: T; R45 Eu - - - - - - - -
T; N
Arsenic compounds, with the exception of those R: 23/25-50/53 Arsenic & soluble
specified elsewhere in HSIS (Note: check solubility T; R23/25 S: (1/2-)20/21-28-45-60-61; Conc>=0.2%: T; R23/25 compounds (as
for exposure standard) N; R50-53 Note: A >=0.1%Conc<0.2%: Xn; R20/22 Eu; A As) - 0.05 - - 1 - -
T+ ; R: 26/28 , Conc>=7%: T+; R26/28
S: (1/2) - 25 - 45 ; >=1%Conc<7%: T; R23/25
Atropine, salts of T+; R26/28 Note: A >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Carc. Cat. 2; R45. Conc>=20%: T; R45; R65; R38
Xn; R65 >=10%Conc<20%: T; R45; R65
Avgas Xi; R38 T+ ; R: 45 - 65 - 38 >=0.1%Conc<10%: T; R45 P - - - - - - - -
Xn; R65 Conc>=20%: Xn; R65; R38
Aviation turbine fuel Xi; R38 Xn ; R: 65 - 38 >=10%Conc<20%: Xn; R65 P - - - - - - - -

Barium salts, with the exception of barium sulphate, Xn ; R: 20/22 ,

salts of 1-azo-2-hydroxynaphthalenyl aryl sulphonic S: (2) - 28 ;
acid, and of salts elsewhere specified Xn; R20/22 Note: A Conc>=1%: Xn; R20/22 Eu - - - - - - - -
Benzidine based azo dyes [4,4'-Diarylazobiphenyl T ; R: 45,
dyes, with the exception of those elsewhere S:53 - 45
specified] Carc. Cat. 2; R45 Note: A Conc>=0.1%: T; R45 Eu - - - - - - - -
Conc>=20%: Xi; R38; R41
Benzyldimethyloctadecylammonium 3- Xi; R38-41 Xi ; N ; R: 38 - 41 - 50/53 >=10%Conc<20%: Xi; R41
nitrobenzenesulfonate N; R50-53 S: (2) - 26 - 37/39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 7
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R49; R26; R25; R48/23;

R36/37/38; R43
>=20%Conc<25%: T+; R49; R26; R22; R48/23;
R36/37/38; R43
>=10%Conc<20%: T+; R49; R26; R22; R48/23;
R43
Carc. Cat. 2; R49 >=7%Conc<10%: T+; R49; R26; R22; R48/20;
T+; R26 T+; N R43
T; R25-48/23 R: 49 - 25 - 26 - 36/37/38 - >=3%Conc<7%: T; R49; R23; R22; R48/20;
Beryllium compounds, with the exception of Xi; R36/37/38 43 - 48/23 - 51/53 R43
aluminium beryllium silicates, and those elsewhere R43 S: 53 - 45 - 61 ; >=1%Conc<3%: T; R49; R23; R48/20; R43 Beryllium &
specified N; R51-53 Note: A ; E >=0.1%Conc<1%: Xn; R49; R20 Eu compounds - 0.002 - - 2 - -
T ; R: 45 - 22 ,
Biphenyl-4-ylamine, salts of [Xenylamine, salts of; 4- Carc. Cat. 1; R45 S: 53 - 45 ; Conc>=25%: T; R45; R22
Aminobiphenyl, salts of] Xn; R22 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
Xn; R48/22 Xn; N
Bis-(6-hydroxy-4-methyl-5-(3-methylimidazolium-1-yl)- Xi; R41 R: 41-48/22-51/53 Conc>=10%: Xn; R48/22; R41
3-(4-phenylazo)-1H-pyridin-2-one)ethylene dilactate N; R51-53 S: (2-)22-26-36/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; R41 Xi; N Conc>=10%: Xi; R41; R43
Bis(dimethyl-(2-hydroxyethyl)ammonium) 1,2- R43 R: 41-43-51/53 >=5%Conc<10%: Xi; R36; R43
ethanediyl-bis(2-hexadecenylsuccinate) N; R51-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi
R43 R: 43-53
Bis(hydrogenated tallow C16-18-alkyl)hydroxylamine R53 S: (2-)36/37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=20%: Xi; R38; R41
Bis[(1-methylimidazol)-(2-ethyl-hexanoate)], zinc Xi; R38-41 Xi ; N ; R: 38 - 41 - 50/53, >=10%Conc<20%: Xi; R41
complex N; R50-53 S: (2) - 26 - 37/39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Bis[[2,2',2''-nitrilotris[ethanolato]]-1-N,O]bis[2-(2- Xi; R41 Xi ; N ; R: 41 - 51/53 , Conc>=10%: Xi; R41
methoxyethoxy)ethoxy]-titanium N; R51-53 S: (2) - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R20/22 Xn; N Conc>=25%: Xn; R20/22; R41
Bis[tributyl 4-(methylbenzyl)ammonium] 1,5- Xi; R41 R: 20/22-41-50/53 >=10%Conc<25%: Xi; R41
naphthalenedisulfonate N; R50-53 S: (2-)26-36/39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N
Branched, octyl 3-[3,5-di(trans-butyl)-4- R: 50/53
hydroxyphenyl]propanoate N; R50-53 S: 60-61 Eu - - - - - - - -

F; R11 F ; Xi ; N
Butyl(dialkyloxy(dibutoxyphosphoryloxy))titanium Xi; R36 R: 11 - 36 - 51/53 ,
(trialkyloxy)titanium phosphate N; R51-53 S: (2) - 7/9 - 16 - 26 - 43 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
C12-14-tert-alkyl ammonium 1-amino-9,10-dihydro- Xi; N
9,10-dioxo-4-(2,4,6-trimethylanilino)-anthracen-2- Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
sulfonate N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

C8-10 Alkyl dimethyl hydroxyethyl ammoniumchloride Xn

(chain < C8: <3 %, chain = C8: 15 %-70 %, chain = Xn; R21/22 R: 21/22-38 Conc>=25%: Xn; R21/22; R38
C10: 30 %-85 %, chain > C10: <3 %) Xi; R38 S: (2-)25-36/37 >=20%Conc<25%: Xi; R38 Eu - - - - - - - -

Cadmium compounds, with the exception of

cadmium sulphoselenide (xCdS.yCdSe), mixture of
cadmium sulphide with zinc sulphide (xCdS.yZnS), Xn; N Cadmium and
mixture of cadmium sulphide with mercury sulphide Xn; R20/21/22 R: 20/21/22-50/53 compounds (as
(xCdS.yHgS), and those specified elsewhere in HSIS N; R50-53 S: (2-)60-61; Note: A Conc>=0.1%: Xn; R20/21/22 Eu; A Cd) - 0.01 - - 2 - -
Xi; N
Calcium 2,2,bis[(5-tetrapropylene-2- Xi; R38 R: 38-50/53
hydroxy)phenyl]ethanoate N; R50-53 S: (2-)37-60-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
E
R: 2
S: (2-)35
Calcium iodoxybenzoate E; R2 Note: C Eu - - - - - - - -
E
R: 3
Cellulose nitrate [Nitrocellulose] E; R3 S: (2-)35 Eu - - - - - - - -
R: 53
Cerium oxide isostearate R53 S: 61 Eu - - - - - - - -

Page 8
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
C Conc>=10%: C; R35
Chloro(3-(3-chloro-4- R: 35 >=5%Conc<10%: C; R34
fluorophenyl)propyl)dimethylsilane C; R35 S: (1/2-)26-36/37/39-45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
T; N
T; R23/24/25 R: 23/24/25-33-50/53 Conc>=25%: T; R23/24/25; R33
Chloroanilines (with exception of those specified R33 S: (1/2-)28-36/37-45-60-61; >=3%Conc<25%: Xn; R20/21/22; R33
elsewhere in HSIS) N; R50-53 Note: C >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
T+ ; N
R: 26/27/28 - 33 - 51/53,
T+; R26/27/28 S: (1/2) - 28 - 36/37 - 45 - Conc>=7%: T+; R26/27/28; R33
Chloronitroanilines, with the exception of those R33 61 ; >=1%Conc<7%: T; R23/24/25; R33
elsewhere specified N; R51-53 Note: C >=0.1%Conc<1%; Xn; R20/21/22 Eu - - - - - - - -

Chromium (II)
Chromium (II) compounds (as Cr) A compounds (as Cr) - 0.5 - - - - -

Chromium (III)
Chromium (III) compounds (as Cr) A compounds (as Cr) - 0.5 - - - - -

Chromium (VI)
compounds (as
Cr), certain water
Chromium (VI) compounds, certain water insoluble A insoluble (h) - 0.05 - - 1 Sen -

Chromium (VI)
compounds (as
Chromium (VI) compounds, water soluble A Cr), water soluble - 0.05 - - - Sen -

Chromium (VI)
Chromium (VI) compounds, with the exception of Carc. Cat. 2; R49 T ; N ; R: 49 - 43 - 50/53, compounds (as
barium chromate and of compounds elsewhere R43 S: 53 - 45 - 60 - 61; Conc>=1%: T; R49; R43 Cr), certain water
specified N; R50 - 53 Notes: A; E >=0.1%Conc<1%: T; R49 Eu; A insoluble (h) - 0.05 - - 1 Sen -

Chromium (VI) compounds, with the exception of Carc. Cat. 2; R49 T ; N ; R: 49 - 43 - 50/53, Chromium (VI)
barium chromate and of compounds elsewhere R43 S: 53 - 45 - 60 - 61; Conc>=1%: T; R49; R43 compounds (as
specified N; R50 - 53 Notes: A; E >=0.1%Conc<1%: T; R49 Eu; A Cr), water soluble - 0.05 - - - Sen -
Coal dust
(containing < 5%
quartz) (respirable
Coal dust (respirable dust) A dust) - 3 - - - - -

Complex of cobalt(III)-bis(N-phenyl-4-(5-ethylsulfonyl- Xi
2-hydroxyphenylazo)-3-hydroxynaphthylamide), R: 43
hydrated (n H2O, 2 < n<3) R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Condensation product of 3-(7-carboxyhept-1-yl)-6- Xn; R22 C ; N ; R: 22 - 34 - 43 - Conc>=25%: C; R34; R22; R43
hexyl-4-cyclohexene-1,2-dicarboxylic acid with C; R34 50/53 >=10%Conc<25%: C; R34; R43
polyamines (primarily aminoethylpiperazine and R43 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%: Xi; R36/38; R43
triethylenetetramine) N; R50-53 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Cotton dust, raw
Cotton dust A (c) - 0.2 - - - - -
R: 52/53
Cyanomethyltrimethylammoniummethylsulfate R52-53 S: 61 Eu - - - - - - - -

Conc>=25%: T; R23; R37/38: R42/43

Cyclohexanamine, N,N-dimethyl-, compds. with 3- T; R23 >=20%Conc<25%: Xn; R20; R37/38; R42/43
(cyclohexylamino)-1-propanesulfonic acid-blocked Xn; R42/43 T >=3%Conc<20%: Xn; R20; R42/43 Isocyanates, all
1,6-diisocyanatohexane homopolymer Xi; R37/38 R: 23-37/38-42/43 >=1%Conc<3%: Xn; R42/43 N; A (as-NCO) - 0.02 - 0.07 - Sen -
Xi; N
Xi; R38 R: 38-50/53
Cyclopentyl 2-phenylethyl ether N; R50-53 S: (2-)37-60-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
R: 53
Di(C9-11-alkyl) cyclohexane-1,4-dicarboxylate R53 S: 61 Eu - - - - - - - -

Page 9
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Di(tetramethylammonium)(29H,31H-phthalocyanin- Xn; N
N29,N30,N31,N32)disulfonamide disulfonate, Xn; R22-48/22 R: 22-48/22-51/53 Conc>=25%: Xn; R22; R48/22
cuprate(2-)complex, derivates N; R51-53 S: (2-)22-36-61 >=10%Conc<25%: Xn; 48/22 Eu - - - - - - - -
Repr. Cat. 3; R62 Conc>=25%: T; R62; R25; R48/22
Diammonium 1-hydroxy-2-(4-(4-carboxyphenylazo)- T; R25 T; N >=10%Conc<25%: Xn; R62; R22; R48/22
2,5-dimethoxyphenylazo)-7-amino-3- Xn; R48/22 R: 25-48/22-62-50/53 >=5%Conc<10%: Xn; R62; R22
naphthalenesulfonate N; R50-53 S: (1/2-)36/37-45-60-61 >=3%Conc<5%: Xn; R22 Eu - - - - - - - -
C Conc>=10%: C; R35
Dichloro-(3-(3-chloro-4- R: 35 >=5%Conc<10%: C; R34
fluorophenyl)propyl)methylsilane C; R35 S: (1/2-)26-36/37/39-45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Xn
R: 20/21/22 ,
S: (2) - 13 ;
Dichlorprop, salts of Xn; R20/21/22 Note: A Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Diesel oils Carc. Cat. 3; R40 Xn ; R: 40 Conc>=1%: Xn; R40 P - - - - - - - -
Xn ; R: 22 ,
Diethanolamine salt of 4-CPA Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi; R38 Xi; N
R43 R: 38-43-50/53 Conc>=20%: Xi; R38; R43
Di-L-para-menthene N; R50-53 S: (2-)23-24-37-60-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Dimethyl-1-{[2-methoxy-5-(2-methyl-
butoxycarbonyl)phenylcarbamoyl]-[2-octadecyl-1,1-
dioxo-1,2,4-benzothiadiazin-3-yl]methyl} imidazole- R: 53
4,5-dicarboxylate R53 S: 61 Eu - - - - - - - -

T; N
R: 23/24/25 - 50/53
T; R23/24/25 S: (1/2) - 13 - 45 - 60 - 61; Conc>=25%: T; R23/24/25
Dinex, salts and esters of N; R50-53 Note: A >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -

T; R23/24/25 T ; N ; R: 23/24/25 - 33 - Conc>=25%: T; R23/24/25; R33

Dinitrophenol, salts of(Note: see also CAS No 6-56-8; R33 51/53 >=3%Conc<25%: Xn; R20/21/22; R33
329-71-5; 573-56-8 & 577-71-9) N; R50-53 S: (1/2) - 28 - 37 - 45 - 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -

T; N
R: 23/24/25 - 50/53
T; R23/24/25 S: (1/2) - 13 - 45 - 60 - 61 Conc>=25%: T; R23/24/25
Dinosam, salts and esters of N; R50-53 Note: A >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
R44
Repr. Cat. 2; R61 T; N Conc>=25%: T; R61; R62; R24/25; R36
Repr. Cat. 3; R62 R: 61 - 62 - 24/25 - 36 - 44 - >=20%Conc<25%: T; R61; R62; R21/22; R36
T; R24/25 50/53 >=5%Conc<20%: T; R61; R62; R21/22
Dinoseb, salts and esters of with the exception of Xi; R36 S: 53 - 45 - 60 - 61 >=3%Conc<5%: T; R61; R21/22
those elsewhere specified N; R50-53 Note: A ; E >=0.5%Conc<3%: T; R61 Eu - - - - - - - -
Conc>=25%: T+; R28; R61; R24
>=7%Conc<25%: T+; R28; R61; R21
Repr. Cat. 2; R61 T+ ; N ; R: 61 - 24 - 28 - >=3%Conc<7%: T; R61; R25; R21
T+; R28 50/53 >=1%Conc<3%: T; R61; R25
T; R24 S: 45 - 53 - 60 - 61 >=0.5%Conc<1%: T; R61; R22
Dinoterb, salts and esters of N; R50-53 Notes: A ; E >=0.1%Conc<0.5%: Xn; R22 Eu - - - - - - - -

Disodium- (3-methyl-4-(5-nitro-2-oxidophenylazo)-1- Xn; R20 Conc>=25%: Xn; R20, R41

phenylpyrazolato)(1-(3-nitro-2-oxido-5- Xi; R41 Xn ; N ; R: 20 - 41 - 51/53 , >=10%Conc<25%: Xi; R41
sulfonatophenylazo)-2-naphtolato)chromate(1-) N; R51-53 S: (2) - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Disodium 2-[[4-(2-chloroethylsulfonyl)phenyl]-[(2-
hydroxy-5-sulfo-3-[3-[2-(2- Xi
(sulfooxy)ethylsulfonyl)ethylazo]-4-sulfobenzoato(3- R: 43
)cuprate(1-) R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 10
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Disodium 3,3'-[iminobis[sulfonyl-4,1-phenylene-(5-
hydroxy-3-methylpyrazole-1,4-diyl)azo-4,1-
phenylenesulfonylimino-(4-amino-6-
hydroxypyrimidine-2,5-diyl)azo-4,1- Xi
phenylenesulfonylimino(4-amino-6-hydroxypyrimidine- R: 41 Conc>=10%: Xi; R41
2,5-diyl)azo]bis(benzenesulfonate)] Xi; R41 S: (2-)22-26-39 >=5%Conc<10% : Xi; R36 Eu - - - - - - - -
Disodium 4-amino-6-((4-((4-(2,4-
diaminophenyl)azo)phenylsulfamoyl)phenyl)azo)-5- Xi
hydroxy-3-((4-nitrophenyl)azo)naphthalene-2,7- Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
disulfonate R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Disodium 5-[5-[4-(5-chloro-2,6-difluoropyrimidin-4- Conc>=10%: Xi; R41; R43

ylamino)benzamido]-2-sulfonatophenylazo]-1-ethyl-6- Xi; R41 Xi ; R: 41 - 43 >=5%Conc<10%: Xi; R36; R43
hydroxy-4-methyl-2-oxo-3-pyridylmethylsulfonate R43 S: (2)22 - 24 - 26 - 37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Disodium 7-(4,6-dichloro-1,3,5-triazin-2-ylamino)-4-
hydroxy-3-(4-(2-
(sulfonatooxy)ethylsulfonyl)phenylazonapthalene-2- Xi ; R: 43 ,
sulfonate Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Disodium 7-[4-chloro-6-(N-ethyl-o-toluidino)-1,3,5-
triazin-2-ylamino]-4-hydroxy-3-(4-methoxy-2- Xi ; R: 41 Conc>=10%: Xi; R41
sulfonatophenylazo)-2-naphthalenesulfonate Xi; R41 S: (2)22 - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Disodium S,S-hexane-1,6-diyldi(thiosulphate) Xi; R43 Xi ; R: 43 - 52/53 ,
dihydrate R52-53 S: (2) - 22 - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Disodium salt of 1-hydroxy-4-(beta-(4-(1-hydroxy-3,6- N

disulfo-8-acetylamino-2-naphthylazo)phenoxy)ethoxy)- R: 50/53
N-dodecyl-2-naphthamide N; R50-53 S: 60-61 Eu - - - - - - - -
Xn ; R: 22 ,
S: (2) - 22 - 25 ;
Ephedrine, salt of Xn; R22 Note: A Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn ; N ; R: 22 - 43 - 50/53
Xn; R22 S: (2)26 - 29 - 36/37 - 46 -
R43 60 - 61; Conc>=25%: Xn; R22; R43
Esters of 2,4-D N; R50-53 Note: A >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn; N
R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
Esters of mecoprop and of mecoprop-P N; R50-53 S: (2-)13-36/37-60-61 >=1%Conc<25%: Xi R43 Eu - - - - - - - -
R: 52/53
Ethoxylated bis phenol A di-(norbornene carboxylate) R52-53 S: 61 Eu - - - - - - - -
Xn
Ethyl 4-((4-diethylamino-2-methylphenyl)imino)-4,5- Xn; R22-48/22 R: 22-48/22-53 Conc>=25%: Xn; R22; R48/22
dihydro-1-isopropyl-5-oxo-1H-pyrazole-3-carboxylate R53 S: (2-)36-61 >=10%Conc<25%: Xn; 48/22 Eu - - - - - - - -
C;F
R: 14/15-35 Conc>=10%: C; R35
C; R35 S: (1/2-)16-23-26-30- >=5%Conc<10%: C; R34
Ethyl propoxy aluminium chloride F; R14/15 36/37/39-43-45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Xi; R38 Xi ; N ; R: 38 - 51/53
Ethyl trans-2,2,6-trimethylcyclohexanecarboxylate N; R51-53 S: (2)37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
C; R34 C ; N ; R: 22 - 34 - 50/53, Conc>=25%: C; R34; R22
Ethylenediammonium O,O- Xn; R22 S: (1/2) - 24/25 - 26 - 28 - >=10%Conc<25%: C; R34
bis(octyl)phosphorodithioate, mixed isomers N; R50-53 39 - 45 - 60 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Conc>=10%: Xi; R41
Extract of lemon eucalyptus Xi; R41 Xi; R: 41 >=5%Conc<10%: Xi; R36 V - - - - - - - -
Xi
Fatty acid, C8-C10, esters with polyglycerol R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Fatty acids, tall oil, reaction products with Xi; R38 Xi ; N ; R: 38 - 51/53 ,
imminodiethanol and boric acid N; R51-53 S: (2) - 28 - 37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -

Xn ; N ; R: 20/21/22 - 50/53,
Fenoprop, salt of [2-(2,4,5- Xn; R20/21/22 S: (2) - 13 - 60 - 61;
Trichlorophenoxy)propionic acid, salts of] N; R50-53 Note: A Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -

Page 11
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T+ ; N ; R: 28 - 50,
S: (1/2) - 20 - 22 - 26 - 45 - Conc>=7%: T+; R28
T+; R28 61; >=1%Conc<7%: T; R25
Fluoroacetates, soluble N; R50 Note: A >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
Xn ; R: 22 ,
Fluorosilicates, with the exception of those elsewhere S: (2) - 13 - 24/25 ;
specified Xn; R22 Note: A Conc>=10%: Xn; R22 Eu - - - - - - - -
Fuel oil Carc. Cat. 2; R45 T ; R: 45 Conc>=0.1%: T; R45 P - - - - - - - -
Conc>=25%: T+; R26; R34; R22
>=10%Conc<25%: T+; R26; R34
T+; R26 T+; N >=7%Conc<10%: T+; R26; R36/38
Xn; R22 R: 22-26-34-50 >=5%Conc<7%: T; R23; R36/38
Glutamic acid, reaction products with N-(C12-14- C; R34 S: (1/2-)26-36/37/39-38-45- >=1%Conc<5%: T; R23
alkyl)propylenediamine N; R50 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
Grain dust
(oats,wheat,
Grain dust (oats, wheat, barley) A barley) - 4 - - - - -
Xn; R65 Conc>=20%: Xn; R65; R38
Heating oil Xi; 38 Xn; R 65 - 38 >=10%Conc<20%: Xn; R65 P - - - - - - - -
T Conc>=25%: T; R25; R41; R42/43
R: 25 - 41 - 42/43 >=10%Conc<25%: Xn; R22; R41; R42/43
T; R25 S: (1/2) - 22 - 26 - 36/37/39 - >=5%Conc<10%: Xn; R22; R36; R42/43
Hexachloroplatinates, with the exception of those Xi; R41 45; >=3%Conc<5%: Xn; R22; R42/43
elsewhere specified R42/43 Note: A >=1%Conc<3%: Xn; R42/43 Eu - - - - - - - -
R: 53
Hexadecyl 3-amino-4-isopropoxybenzoate R53 S: 35-61 Eu - - - - - - - -
Muta. Cat. 3; R68
Xn; R22
Xi; R36 Xn ; N ; R: 22 - 36 - 43 - 68 - Conc>=25%: Xn; R68; R22; R36; R43
Hexahydrocyclopenta[c]pyrrole-1-(1H)-ammonium N- R43 51/53 >=20%Conc<25%: Xn; R68; R36; R43
ethoxycarbonyl-N-(p-tolylsulfonyl)azanide N; R51-53 S: (2)26 - 36/37 - 61 >=1%Conc<20%: Xn; R68; R43 Eu - - - - - - - -
Hexanedioic acid, polymer with 1,3-
diisocyanatomethylbenzene, 1,2-ethanediol, Xn Isocyanates, all
methyloxirane, oxirane and 1,2-propanediol Xn; R42 R: 42 Conc>=1%: Xn; R42 N; A (as-NCO) - 0.02 - 0.07 - Sen -
Hexanedioic acid, polymer with 1,6-hexanediol, 1,4-
benzenedicarb, and 1,1'-methylenebis[4- Xn
isocyanatobenzene] Xn; R42 R: 42 Conc>=1%: Xn; R42 N - - - - - - - -
Hexanedioic acid, polymer with 1,6-hexanediol, 1,4-
benzenedicarboxylic acid, 1,2-ethanediol, 1,3-
isobenzofurandione, and 1,1'- Xn
methylenebis[isocyanatobenzene] Xn; R42 R: 42 Conc>=1%: Xn; R42 N - - - - - - - -
Hexasodium 4,4'-dihydroxy-3,3'-bis[2-sulfonato-4-(4-
sulfonatophenylazo)phenylazo]-7,7'[p- Xi
phenylenebis[imino(6-chloro-1,3,5-triazine-4,2- R: 41 Conc>=10%: Xi; R41
diyl)imino]]dinaphthalene-2-sulfonate Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
E; R3
O; R8 E; T Conc>=25%: T; R45; R23/25; R43
Carc. Cat. 2; R45 R: 45 - 3 - 8 - 23/25 - 43 >=3%Conc<25%: T; R45; R20/22; R43
T; R23/25 S: 53 - 45; >=1%Conc<3%: T; R45; R43
Hydrazine trinitromethane R43 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 23/24/25 - 43 - Conc>=25%: T; R45, R23/24/25, R43
T; R23/24/25. 50/53, >=3%Conc<25%: T; R45, R20/21/22, R43
R43 S: 53 - 45 - 60 - 61; >=1%Conc<3%: T; R45, R43
Hydrazine, salts of N; R50-53 Notes: A ; E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
C ; R: 34 ,
S: (1/2) - 26 - 45 ; Conc>=25%: C; R34
Hydriodic acid ...% C; R34 Note: B >=10%Conc<25%: Xi; R36/38 Eu - - - - - - - -
C ; R: 34 - 37 ,
C; R34 S: (1/2) - 7/9 - 26 - 45; Conc>=40%: C; R34; R37
Hydrobromic acid % Xi; R37 Note: B >=10%Conc<40%: Xi; R36/37/38 Eu - - - - - - - -
C ; R: 34 - 37 ,
C; R34 S: (1/2) - 26 - 45; Conc>=25%: C; R34; R37
Hydrochloric acid % Xi; R37 Note: B >=10%Conc<25%: Xi; R36/37/38 Eu - - - - - - - -

Page 12
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi; N
Hydrogen sodium N-carboxylatoethyl-N-octadec-9- Xi; R43 R: 43 - 51/53
enylmaleamate N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
T+ ; R: 26/27/28 , Conc>=7%: T+; R26/27/28
S: (1/2) - 25 - 45 ; >=1%Conc<7%: T; R23/24/25
Hyoscine, salt of T+; R26/27/28 Note: A >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
T+ ; R: 26/28 , Conc>=7%: T+; R26/28
S: (1/2) - 24 - 45 ; >=1%Conc<7%: T; R23/25
Hyoscyamine, salt of T+; R26/28 Note: A >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Iron salts, soluble
Iron salts soluble (as Fe) A (as Fe) - 1 - - - - -

Iron, complexes with diazotised 4-

aminobenzenesulfonamide,diazotised 3-
aminobenzenesulfonic acid, diazotised 3-amino-4-
hydroxybenzenesulfonamide,diazotised 3-amino-4-
hydroxy-N-phenylbenzenesulfonamide, diazotised 5- N
amino-2-(phenylamino)benzenesulfonic acid and R: 51/53
resorcinol, sodium salts N; R51-53 S: 22-61 Eu - - - - - - - -
Isocyanates, all
Isocyanates, all (as NCO) A (as-NCO) - 0.02 - 0.07 - Sen -
F; R11,
Isoparaffinic fraction (150/220)(Note: see petroleum S: (2) - 9 - 16 - 29 - 33
substances low boiling point modified naphtha CAS Note; C
No 64741-65-7) F; R11 Eu - - - - - - - -
Isopentyl 4-{2-[5-cyano-1,2,3,6-tetrahydro-1-(2-
isopropoxyethoxy-carbonylmethyl)-4-methyl-2,6-dioxo- R: 53
3-pyridylidene]hydrazino}benzoate R 53 S: 61 Eu - - - - - - - -
Conc>=25%: T; R25; R48/25; R21; R41
T; R25-48/25 T; N >=10%Conc<25%: T; R48/25; R22; R41
Xn; R21 R: 21-25-41-48/25-50/53 >=5%Conc<10%: Xn; R22; R48/22; R36
Xi; R41 S: (1/2-)22-26-36/37/39-45- >=3%Conc<5%: Xn; R22; R48/22
Isopropylammonium 2-(3-benzoylphenyl)propionate N; R50-53 60-61 >=1%Conc<3%: Xn; R48/22 Eu - - - - - - - -
Xi; N
Xi; R38 R: 38-51/53
Isostearic acid monoisopropanolamide N; R51-53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xn; R65 Conc>=20%: Xn; R65; R38
Kerosine Xi; R38 Xn ; R: 65 - 38 >=10%Conc<20%: Xn; R65 P - - - - - - - -

Repr. Cat. 1; R61

Repr. Cat. 3; R62 T+; N Conc>=5%: T+; R61; R62; R26/27/28; R33
T+; R26/27/28 R: 61-26/27/28-33-62-50/53 >=0.5%Conc<5%: T+; R61; R26/27/28; R33
R33 S: 53-45-60-61; Notes: A; >=0.1%Conc<0.5%: T; R61; R23/24/25; R33
Lead alkyls N; R50-53 E >=0.05%Conc<0.1%: Xn; R20/21/22; R33 Eu - - - - - - - -
Repr. Cat. 1; R61
Repr. Cat. 3; R62 T; N
Xn; R20/22 R: 61-20/22-33-62-50/53 Conc>=2.5%: T; R61; R62; R20/22; R33
Lead compounds with the exception of those R33 S: 53-45-60-61; Notes: >=1%Conc<2.5%: T; R61; R20/22; R33
specified elsewhere in HSIS N; R50-53 A; E >=0.5%Conc<1%: T; R61; R33 Eu - - - - - - - -
Lithium potassium sodium N,N''-bis{6-[7-[4-(4-chloro-
1,3,5-triazin-2-yl)amino-4-(2- Xi
ureidophenylazo)]naphthalene-1,3,6-trisulfonato]}-N'- R: 43
(2-aminoethyl)piperazine R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
R14 F ; C ; R: 14 - 17 - 34,
F; R17 S: (1/2) - 16 - 43 - 45; Conc>=10%: C; R34
Magnesium alkyls C; R34 Note: A >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41; R43
>=20%Conc<25%: Xi; R38; R41; R43
Xn; R22 >=10%Conc<20%: Xi; R41; R43
Magnesium bis((R)-2-(2,4- Xi; R38-41 Xn ; R: 22 - 38 - 41 - 43 >=5%Conc<10%: Xi; R36; R43
dichlorophenoxy)propionate) R43 S: (2)22 - 26 - 36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Magnesium salts, fatty acids, C16-18 and C18 R: 53
unsaturated, branched and linear R53 S: 61 Eu - - - - - - - -

Page 13
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn
R: 48/20
Magnesium sodium fluoride silicate Xn; R48/20 S: (2-)22-36 Conc>=10%: Xn; R48/20 Eu - - - - - - - -
F; R11 - 15,
Magnesium, powder or turnings F; R11-15 S: (2) - 7/8 - 43 Eu - - - - - - - -

Main component 1 (isomer 1): 2-{6-fluoro-4-[3-(2,5-

disulfo-phenylazo)-4-hydroxy-2-sulfonapht-7-ylamino]-
1,3,5-triazin-2-ylamino}-3-{6-fluoro-4-[3-(1,5-
disulfonaphth-2-ylazo)-4-hydroxy-2-sulfonaphth-7-
ylamino]-1,3,5-triazin-2-ylamino}-propane sodium
salt;
main component 1 (isomer 2): 2-{6-fluoro-4-[3-(2,5-
disulfo-phenylazo)-4-hydroxy-2-sulfonaphth-7-
ylamino]-1,3,5-triazin-2-ylamino}-3-{6-fluoro-4-[3-(2,5-
disulfo-phenylazo)-4-hydroxy-2-sulfonaphth-7-
ylamino]-1,3,5-triazin-2-ylamino}-propane sodium
salt;
main component 2: 2,3-bis-{6-fluoro-4-[3-(2,5-disulfo-
phenylazo)-4-hydroxy-2-sulfonaphth-7-ylamino]-1,3,5-
triazin-2-ylamino}-propane sodium salt;
main component 3: 2,3-bis-{6-fluoro-4-[3-(1,5- Xi
disulfonaphth-2-ylazo)-4-hydroxy-2-sulfonaphth-7- R: 41 Conc>=10%: Xi; R41
ylamino]-1,3,5-triazin-2-ylamino}-propane sodium salt Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Main component: acetoacetic acid anilide / 3-amino-1-

hydroxybenzene (ATAN-MAP): trisodium {6-[(2 or 3
or 4)-amino-(4 or 5 or 6)-hydroxyphenylazo]-5'-
(phenylsulfamoyl)-3-sulfonatonaphthalene-2-
azobenzene-1,2'-diolato}-{6''-[1-
(phenylcarbamoyl)ethylazo]-5'''-(phenylsulfamoyl)-3''-
sulfonatonaphthalene-2''-azobenzene-1'',2'''-
diolato}chromate (III) by-product 1: acetoacetic acid
anilide / acetoacetic acid anilide (ATAN-ATAN):
trisodium bis{6-[1-(phenylcarbamoyl)ethylazo]-5'-
(phenylsulfonyl)-3-sulfonatonaphthalene-2-
azobenzene-1,2'-diolato}chromate (III) by-product 2:
3-amino-1-hydroxybenzene / 3-amino-1-
hydroxybenzene (MAP-MAP): trisodium bis{6-[(2 or 3
or 4)-amino-(4 or 5 or 6)-hydroxyphenylazo]-5'- Xi
(phenylsulfamoyl)-3-sulfonatonaphthalene-2- R43 R: 43-52/53
azobenzene-1,2'-diolato} chromate (III) R52-53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; N
R: 20/21/22-50/53
Xn; R20/21/22 S: (2-)13-60-61
MCPA, salts and esters of N; R50-53 Note: A Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Xn ; R: 22 ,
S: (2) - 24/25 ;
MCPB, salts and esters of Xn; R22 Note: A Conc>=25%: Xn; R22 Eu - - - - - - - -
T+ ; N ; R: 26/27/28 - 33 -
50/53,
T+; R26/27/28 S: (1/2) - 13 - 28 - 36 - 45 - Conc>=1%: T+; R26/27/28; R33 Mercury, alkyl
Mercury alkyl compounds (as Hg) with the exception R33 60 - 61; >=0.5%Conc<1%: T; R23/24/25; R33 compounds (as
of those elsewhere specified N; R50-53 Note: A >=0.05%Conc<0.5%: Xn; R20/21/22; R33 Eu; A Hg) - 0.01 - 0.03 - Sk -
T+ ; N ; R: 26/27/28 - 33 -
50/53,
T+; R26/27/28 S: (1/2) - 13 - 28 - 36- 45 - Conc>=1%: T+; R26/27/28; R33 Mercury, aryl
Mercury aryl compounds (as Hg) with the exception R33 60 - 61; >=0.5%Conc<1%: T; R23/24/25; R33 compounds (as
of those elsewhere specified N; R50-53 Note: A >=0.05%Conc<0.5%: Xn; R20/21/22; R33 Eu; A Hg) - 0.1 - - - Sk -

Page 14
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

T+; N Mercury, inorganic

Mercury, inorganic compounds with the exception of T+; R26/27/28 R: 26/27/28-33-50/53 Conc>=2%: T+; R26/27/28; R33 divalent
mercuric sulphide and those specified elsewhere in R33 S: (1/2-)13-28-45-60-61; >=0.5%Conc<2%: T; R23/24/25; R33 compounds (as
HSIS N; R50-53 Note: A >=0.1%Conc<0.5%: Xn; R20/21/22; R33 Eu; A Hg) 0.003 0.025 - - - - -

T+; N Mercury, inorganic

Mercury, inorganic compounds with the exception of T+; R26/27/28 R: 26/27/28-33-50/53 Conc>=2%: T+; R26/27/28; R33 monovalent
mercuric sulphide and those specified elsewhere in R33 S: (1/2-)13-28-45-60-61; >=0.5%Conc<2%: T; R23/24/25; R33 compounds (as
HSIS N; R50-53 Note: A >=0.1%Conc<0.5%: Xn; R20/21/22; R33 Eu; A Hg) - 0.1 - - - Sk -
T+; N
T+; R26/27/28 R: 26/27/28-33-50/53 Conc>=1%: T+; R26/27/28; R33 Mercury, alkyl
Mercury, organic compounds with the exception of R33 S: (1/2-)13-28-36-45-60-61; >=0.5%Conc<1%: T; R23/24/25; R33 compounds (as
those specified elsewhere in HSIS N; R50-53 Note: A >=0.05%Conc<0.5%: Xn; R20/21/22; R33 Eu; A Hg) - 0.01 - 0.03 - Sk -
T+; N
T+; R26/27/28 R: 26/27/28-33-50/53 Conc>=1%: T+; R26/27/28; R33 Mercury, aryl
Mercury, organic compounds with the exception of R33 S: (1/2-)13-28-36-45-60-61; >=0.5%Conc<1%: T; R23/24/25; R33 compounds (as
those specified elsewhere in HSIS N; R50-53 Note: A >=0.05%Conc<0.5%: Xn; R20/21/22; R33 Eu; A Hg) - 0.1 - - - Sk -
Xi
Methacrylic acid, monoalkyl or monoaryl or R: 36/37/38
monoalkyaryl esters of, with the exception of those S: (2) - 26 - 28;
elsewhere specified Xi; R36/37/38 Note: A Conc>=10%: Xi; R36/37/38 Eu - - - - - - - -
N
Methyl 2-(4- R: 50/53
butanesulfonamidophenoxy)tetradecanoate N; R50-53 S: 60-61 Eu - - - - - - - -
Xn
Xn; R22 R: 22-36 Conc>=25%: Xn; R22; R36
Methyl-2-[(aminosulfonyl)methyl]benzoate Xi; R36 S: (2-)22-26 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
E; R2
O; R7
Xn; R65 E; Xn Conc>=20%: Xn; R65; R38; R43
Xi; R38 R: 2-7-38-43-65 >=10%Conc<20%: Xn; R65; R43
Methylethylketone peroxide trimer R43 S: (2-)3/7-14-23-36/37/39-62 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R45; R62; R68; R25; R21;

R48/22; R36; R43
Carc. Cat. 2; R45 >=20%Conc<25%: T; R45; R62; R68; R22;
Muta. Cat. 3; R68 R48/22; R36; R43
Repr. Cat. 3; R62 >=10%Conc<20%: T; R45; R62; R68; R22;
T; R25 T; N R48/22; R43
Methyl-phenylene diamine [Diaminotoluene](Note: Xn; R21-48/22 R: 45-21-25-36-43-48/22-62- >=5%Conc<10%: T; R45; R62; R68; R22; R43
technical product - mixture of 4-methyl-m-phenylene Xi; R36 68-51/53 >=3%Conc<5%: T; R45; R68; R22; R43
diamine (CAS No 95-80-7) and 2-methyl-m- R43 S: 53-45-61 >=1%Conc<3%: T; R45; R68; R43
phenylene diamine (CAS No 823-40-5)) N; R51-53 Note: E >=0.1%conc<1%: T; R45 Eu - - - - - - - -
Milbemectin (ISO)(Note: mixture of milbemycin A3 Xn; N
(CAS No 51596-10-2) and milbemycin A4 (CAS No Xn; R20/22 R: 20/22-50/53
51596-11-3) (30:70)) N; R50-53 S: (2-)46-60-61 Conc>=25%: Xn; R20/22 Eu - - - - - - - -

[Glass wool, rock (see

(stone) wool, slag Workplace
Mineral wool, with the exception of those specified wool and Exposure
elsewhere in HSIS [Synthetic mineral fibres (SMF); continuous glass Standards for
Glasswool; MMVF](Note: Man-made vitreous filament](i)(k) Airborne
(silicate) fibres with random orientation with alkaline Xn and Contaminants
oxide and alkali earth oxide R: 40 Low 2 mg/m3 for meaning
(Na2O+K2O+CaO+MgO+BaO) content greater than S: (2-)36/37 Biopersistence (inhalable of (i) (j) (k)
18 % by weight) Carc. Cat. 3; R40 Notes: A ; Q ; R Conc>=1%: Xn; R40 Eu;A MMVF(m) - dust)(j) - - - - (m))

Mixed triesters of 2,2-bis(hydroxymethyl)butanol with R: 53

C7-alkanoic acids and 2-ethylhexanoic acid R 53 S: 61 Eu - - - - - - - -

Page 15
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture (1:1) of 2-[N-ethyl-4-[(5,6-

dichlorobenzothiazol-2-yl)azo]-m-toludino]ethyl T; R48/25 T ; N ; R: 43 - 48/25 - 51/53
acetate and 2-[N-ethyl-4-[(6,7-dichlorobenzothiazol-2- R43 S: (1/2) - 22 - 36/37 - R45 - Conc>=10%: T; R48/25; R43
yl)azo]-m-toludino]ethyl acetate N; R51/53 61 >=1%Conc<10%: Xn; R48/22; R43 Eu - - - - - - - -
Mixture (1:2:1) of bis(N-cyclohexyl-N'-
phenyleneureido)methylene, bis(N-octadecyl-N'-
phenyleneureido)methylene and bis(N-dicyclohexyl-N' R43 Xi ; R: 43 - 53
phenyleneureido)methylene R53 S: (2)22 - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture of O,O-di(1-methylethyl)trithio-bis-
thioformate; O,O-di(1-methylethyl)tetrathio-bis- Xn; R22
thioformate; O,O-di(1-methylethyl)pentathio-bis- R43 Xn ; N ; R: 22 - 43 - 50/53 , Conc>=25%: Xn; R22; R43
thioformate N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<25%: Xi; R43 - - - - - - - -
Mixture of (1,3-dioxo-2H-benz(de)isoquinolin-2-
ylpropyl)hexadecyldimethylammonium 4-
toulenesulfonate and (1,3-dioxo-2H-
benz(de)isoquinolin-2- Xi; R41 Xi ; N ; R: 41 - 50/53 , Conc>=10%: Xi; R41
ylpropyl)hexadecyldimethylammonium bromide N; R50-53 S: (2) - 22 - 26 - 39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of (1'alpha,3'alpha,6'alpha)-2,2,3',7',7'-
pentamethylspiro(1,3-dioxane-5,2'-norcarane) and Xi; N
(1'alpha,3'beta,6'alpha)-2,2,3',7',7'- Xi; R38 R: 38-51/53
pentamethylspiro(1,3-dioxane-5,2'-norcarane) N; R51-53 S: (2-)36/37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Mixture of (1R*,2S*)-2-acetyl-1,2,3,4,5,6,7,8-
octahydro-1,2,8,8-tetramethylnaphthalene and N
(2R*,3S*)-2-acetyl-1,2,3,4,5,6,7,8-octahydro-2,3,8,8- R: 50/53
tetramethylnaphthalene N; R50-53 S: 60-61 Eu - - - - - - - -

Mixture of (1RS,2RS,3SR,6RS,9SR)-9-
methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde
and (1RS,2RS,3RS,6RS,8SR)-8-
methoxytricyclo[5.2.1.0(2,6)]decane-3-carbaldehyde Xi; N
and (1RS,2RS,4SR,6RS,8SR)-8- R43 R: 43-51/53
methoxytricyclo[5.2.1.0(2,6)]decane-4-carbaldehyde N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture of (1RS,2SR,7SR,8SR,E) 9 and 10-
ethylidene-3-oxatricyclo[6.2.1.0(2,7)]undecan-4-one
and (1RS,2SR,7SR,8SR,Z)-10-ethylidene-3-
oxatricyclo[6.2.1.0(2,7)]undecan-4-one and Xn; N
(1RS,2SR,7SR,8SR,Z)-9-ethylidene-3- Xn; R22 R: 22-51/53
oxatricyclo[6.2.1.0(2,7)]undecan-4-one N; R51-53 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Mixture of (3-methoxy)propylammonium/[tris-(2-
hydroxyethyl)]ammonium 2-(2-(bis(2-
hydroxyethyl)amino)ethoxycarbonylmethyl)hexadec-4-
enoate, (3-methoxy)propylammonium/[tris-(2-
hydroxyethyl)]ammonium 2-(2-(bis(2-
hydroxyethyl)amino)ethoxycarbonylmethyl)tetradec-4-
enoate, (3-methoxy)propylammonium/[tris-(2-
hydroxyethyl)]ammonium 2-(3-
methoxypropylcarbamoylmethyl)hexadec-4-enoate
and (3-methoxy)propylammonium/[tris-(2- Conc>=20%: Xi; R38; R41
hydroxyethyl)]ammonium 2-(3- Xi; R38-41 Xi ; N ; R: 38 - 41 - 51/53 >=10%Conc<20%: Xi; R41
methoxypropylcarbamoylmethyl)tetradec-4-enoate N; R51-53 S: (2)26 - 37/39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of (R,R)-1,1,1,2,2,3,4,5,5,5-
decafluoropentane and (S,S)-1,1,1,2,2,3,4,5,5,5- R: 52/53
decafluoropentane R52-53 S: 61 Eu - - - - - - - -
Mixture of [1-(methoxymethyl)-2-(C12-alkoxy)- Conc>=20%: Xi; R38; R41
ethoxy]acetic acid and [1-(methoxymethyl)-2-(C14- Xi; R38-41 Xi ; N ; R: 38 - 41 - 50/53, >=10%Conc<20%: Xi; R41
alkoxy)-ethoxy]acetic acid N; R50-53 S: (2) - 26 - 37/39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 16
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of 1-(1-(3-dimethylaminopropyl)-5-(3-((4-(1-(3-
dimethylaminopropyl)-1,6-dihydro-2-hydroxy-4-methyl-
6-oxo-5-pyridino-3-pyridylazo)phenylazo)-2,4(or2,6
or3,5)-dihydroxyphenylazo)phenylazo)-1,2-dihydro-6-
hydroxy-4-methyl-2-oxo-3-pyridyl)pyridinium
dichloride and 1,1'-((dihydroxyphenylene)bis(azo-3,1-
phenylenazo(1-(3-dimethylaminopropyl)-1,2-dihydro-6-
hydroxy-4-methyl-2-oxopyridine-5,3-diyl)))dipyridinium Xi ; R: 43 ,
dichloride dihydrochloride Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture of 1-(1,1-dimethylpropyl)-4-ethoxy-cis- Xi; N
cyclohexane and 1-(1,1-dimethylpropyl)-4-ethoxy- Xi; R38 R: 38-50/53
trans-cyclohexane N; R50-53 S: (2-)24-37-60-61 Conc>=20%: Xi; R38 Eu - - - - - - - -

Mixture of 1,1'-(methylenebis(4,1-
phenylene))dipyrOxo-2H-2- Xi; R43 Xi ; N ; R: 43 - 50/53 ,
furylideneamino)benzyl)phenyl)pyrrole-2,5-dione N; R50-53 S: (2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
O; R7
Xn; R22 O; C; N Conc>=25%: C; R34; R22 R43
C; R34 R: 7-22-34-43-51/53 >=10%Conc<25%: C; R34; R43
Mixture of 1,2-dimethylpropylidene dihydroperoxide R43 S: (1/2-)3/7-14-26-36/37/39- >=5%Conc<10%: Xi; R36/38; R43
and dimethyl 1,2-benzenedicarboxylate N; R51-53 45-50-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of 1,2-naphthoquinonediazide-5-
sulfonylchloride (or sulfonic acid)monoester with 4,4'-
(1-(4-(1-(4-hydroxyphenyl)-1-
methylethyl)phenyl)ethylidene)bisphenol and 1,2-
naphthoquinonediazide-5-sulfonylchloride (or sulfonic
acid)diester with 4,4'-(1-(4-(1-(4-hydroxyphenyl)-1-
methylethyl)phenyl)ethylidene)bisphenol and 1,2-
naphthoquinonediazide-5-sulfonylchloride (or sulfonic F; R17 F
acid)triester with 4,4'-(1-(4-(1-(4-hydroxyphenyl)-1- R44 R: 17-44-53
methylethyl)phenyl)ethylidene)bisphenol R53 S: (2-)15-22-61 Eu - - - - - - - -
Mixture of 1,3-dihex-5-en-1-yl-1,1,3,3-
tetramethyldisiloxane and 1,3-dihex-n-en-1-yl-1,1,3,3- N ; R: 51/53,
tetramethyldisiloxane N; R51-53 S: 61 Eu - - - - - - - -

Mixture of 1,7-dimethyl-2-[(3-methylbicyclo[2.2.1]hept- C; N
2-yl)methyl]bicyclo[2.2.1]heptane and 2,3-dimethyl-2- R: 34-50/53
[(3-methylbicyclo[2.2.1]hept-2- C; R34 S: (1/2-)23-26-36/37/39-45- Conc>=10%: C; R34
yl)methyl]bicyclo[2.2.1]heptane N; R50-53 57-60-61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Mixture of 1-[di(4-octylphenyl)aminomethyl]-5-methyl-
1H-benzotriazole and 1-[di(4-
octylphenyl)aminomethyl]-4-methyl-1H-benzotriazole
[Mixture of N-[(5-methyl-1H-benzotriazol-1-yl)methyl]-
4-octyl-N-(4-octylphenyl)aniline and N-[(4-methyl-1H-
benzotriazol-1-yl)methyl]-4-octyl-N-(4- R: 53
octylphenyl)aniline] R53 S: 22-61 Eu - - - - - - - -
Mixture of 1-deoxy-1-[methyl-(1-oxohexadecyl)amino]-
D-glucitol and 1-deoxy-1-[methyl-(1- Xi ; R: 41 , Conc>=10%: Xi; R41
oxooctadecyl)amino]-D-glucitol Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of 1-ethoxy-1,1,2,3,3,3-hexafluoro-2-
(trifluoromethyl)propane and 1-ethoxy- R: 53
1,1,2,2,3,3,4,4,4-nonafluorobutane R53 S: 21-23-61 Eu - - - - - - - -

Mixture of 2-(2-((oxo(phenyl)acetyl)oxy)ethoxy)ethyl Xi
oxo(phenyl)acetate and (2-(2-hydroxyethoxy)ethyl) R: 43
oxo(phenyl)acetate R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 17
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Mixture of 2-(3-(2,6-dichloro-4-
nitrophenylazo)carbazol-9-yl)ethanol and 2-(2-(3-(2,6-
dichloro-4-nitro-phenylazo)-carbazol-9-yl)- Xi; N
ethoxy)ethanol and 3-(2,6-dichloro-4- R43 R: 43-50/53
nitrophenylazo)carbazol N; R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture of 2-(9-methyl-1,3,8,10-tetraoxo-2,3,9,10-
tetrahydro-(1H,8H)-anthra[2,1,9-def: 6,5,10-
d'e'f']diisoquinolin-2-ylethansulfonic acid and
potassium 2-(9-methyl-1,3,8,10-tetraoxo-2,3,9,10-
tetrahydro-(1H,8H)-anthra[2,1,9-def: 6,5,10- Xi ; R: 41 Conc>=10%: Xi; R41
d'e'f']diisoquinolin-2-ylethansulfate Xi; R41 S: (2)26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
Xi; R41 Xn ; N ; R: 22 - 41 - 43 - >=10%Conc<25%: Xi; R41; R43
Mixture of 2-(hexylthio)ethylamine hydrochloride and R43 51/53 , >=5%Conc<10%: Xi; R36; R43
sodium propionate N; R51-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of 2,2'-(heptane-1,7-diyl)bis-1,3-dioxolane R: 52/53

and 2,2'-(heptane-1,6-diyl)bis-1,3-dioxolane R52-53 S: 61 Eu - - - - - - - -

Mixture of 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-
diyl)bis(azo)]bis[N-(2,4-dimethylphenyl)]-3-oxo-
butanamide and 2-[[3,3'-dichloro-4'-[[1[[(2,4-
dimethylphenyl)amino]carbonyl]-2-oxopropyl]azo][1,1'-
biphenyl]-4-yl]azo]-N-(2-methylphenyl)-3-oxo-
butanamide and 2-[[3,3'-dichloro-4'-[[1[[(2,4-
dimethylphenyl)amino]carbonyl]-2-oxopropyl]azo][1,1'- Carc. Cat. 3; R40 Xn
biphenyl]-4-yl]azo]-N-(2-carboxylphenyl)-3-oxo- R43 R: 40-43-53
butanamide R53 S: (2-)36/37-61 Conc>=1%: Xn; R40; R43 Eu - - - - - - - -

Mixture of 2,2'-dimethyl-2,2'-azobutanenitrile and 2-

methylpentanenitrile-2-azo-2'-(2'- R10
methylpropanenitrile) and 2,2'-dimethyl-2,2'- R32
azoheptanenitrile and 2-methylheptanenitrile-2-azo-2'- R44 Xn; N
(2'-methylpropanenitrile) and 2-methylheptanenitrile-2- Xn; R22 R: 10-22-32-44-51/53
azo-2'-(2'-methylbutanenitrile) N; R51-53 S: (2-)12-15-16-47-51-61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Mixture of 2-{3,6-bis-[(2-ethylphenyl)-methylamino]-
xanthylium-9-yl}-benzenesulfonate (2-10 %) and 2-
{3,6-bis-[(2,3-dimethylphenyl)-methylamino]-
xanthylium-9-yl}-benzenesulfonate (2-10 %) and 2-
{3,6-bis-[(2,4-dimethylphenyl)-methylamino]-
xanthylium-9-yl}-benzenesulfonate (2-10 %) and 2-
{3,6-bis-[(2,5-dimethylphenyl)-methylamino]-
xanthylium-9-yl}-benzenesulfonate (2-10 %) and 2-{3-
[(2,3-dimethylphenyl)-methylamino]-6-[(2-ethylphenyl)-
methylamino]-xanthylium-9-yl}-benzenesulfonate (7-
20 %) and 2-{3-[(2,4-dimethylphenyl)-methylamino]-6-
[(2-ethylphenyl)-methylamino]-xanthylium-9-yl}-
benzenesulfonate (7-20 %) and 2-{3-[(2,5-
dimethylphenyl)-methylamino]-6-[(2-ethylphenyl)-
methylamino]-xanthylium-9-yl}-benzenesulfonate (7-
20 %) and 2-{3-[(2,3-dimethylphenyl)-methylamino]-6-
[(2,4-dimethylphenyl)-methylamino]-xanthylium-9-yl}-
benzenesulfonate (7-20 %) and 2-{3-[(2,3-
dimethylphenyl)-methylamino]-6-[(2,5-
dimethylphenyl)-methylamino]-xanthylium-9-yl}-
benzenesulfonate (7-20 %) and 2-{3-[(2,4-
dimethylphenyl)-methylamino]-6-[(2,5- Xi; N
dimethylphenyl)-methylamino]-xanthylium-9-yl}- Xi; R38 R: 38-51/53
benzenesulfonate (7-20 %) N; R51-53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -

Page 18
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=20%: Xi; R38; R41; R43
Mixture of 2-acryloyloxyethyl hydrogen cyclohexane- Xi; R38-41 >=10%Conc<20%: Xi; R41; R43
1,2-dicarboxylate and 2-methacryloyloxyethyl R43 Xi ; R: 38 - 41 - 43 - 52/53 , >=5%Conc<10%: Xi; R36; R43
hydrogen cyclohexane-1,2-dicarboxylate R52-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of 2-chloro-5-sec-tetradecylhydroquinones
where sec-tetradecyl= 1-methyltridecyl, 1- Xi; R38
ethyldodecyl, 1-propylundecyl, 1-butyldecyl, 1- R43 Xi ; R: 38 - 43 - 52/53 Conc>=20%: Xi; R38; R43
pentylnonyl and 1-hexyloctyl R52-53 S: (2)24 - 37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Mixture of 2-chloroethyl chloropropyl 2-
chloroethylphosphonate, mixture of isomers and 2-
chloroethyl chloropropyl 2-chloropropylphosphonate, Xn ; R: 22 ,
mixture of isomers Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi; N
Mixture of 2-ethylhexyl 2,3,4,5-tetrabromobenzoate R43 R: 43-50/53
and bis(2-ethylhexyl)3,4,5,6-tetrabromo phthalate N; R50-53 S: (2-)36/37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of 2-hydroxy-3-(methacryloyloxy)propyl (2-

benzoyl)benzoate and 1-hydroxymethyl-2-
(methacryloyloxy)ethyl (2-benzoyl)benzoate and x- Xi; N
hydroxy-y-(methacryloyloxy)propyl(or -ethyl) (2- R43 R: 43-51/53
benzoyl)benzoate N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of 2-methoxy-4-(tetrahydro-4-methylene-2H-
pyran-2-yl)-phenol and 4-(3,6-dihydro-4-methyl-2H- Xi; R43 Xi ; R: 43 - 52/53 ,
pyran-2-yl)-2-methoxyphenol R52-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of 2-methylnonanedioic acid and 2,4-dimethyl-

4-methoxycarbonylundecanedioic acid and 2,4,6-
trimethyl-4,6-dimethoxycarbonyltridecanedioic acid Xi Conc>=10%: Xi; R41; R43
and 8,9-dimethyl-8,9- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
dimethoxycarbonylhexadecanedioic acid R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of 3-((5-cyano-1,6-dihydro-1,4-dimethyl-2-
hydroxy-6-oxo-3-pyridinyl)azo)-benzoyloxy-2-
phenoxyethane and 3-((5-cyano-1,6-dihydro-1,4-
dimethyl-2-hydroxy-6-oxo-3-pyridinyl)azo)-benzoyloxy- R: 53
2-ethyloxy-2-(ethylphenol) R53 S: 61 Eu - - - - - - - -
Mixture of 3-(4-ethylphenyl)-2,2-
dimethylpropanenitrile, 3-(2-ethylphenyl)-2,2-
dimethylpropanenitrile and 3-(3-ethylphenyl)-2,2- N ; R: 51/53
dimethylpropanenitrile N; R51-53 S: 61 Eu - - - - - - - -

Mixture of 3-(N-(3-dimethylaminopropyl)-(C4-
8)perfluoroalkylsulfonamido)propionic acid, N-
[dimethyl-3-(C4-8-
perfluoroalkylsulfonamido)propylammonium
propionate and 3-(N-(3-dimethyl-propylammonium)-
(C4-8)perfluoroalkylsulfonamido)propionic acid Xn ; R: 48/22
propionate Xn; R48/22 S: (2)21 - 22 - 36/37 Conc>=10%: Xn; R48/22 Eu - - - - - - - -

Mixture of 3,3'-dicyclohexyl-1,1'-methylenebis(4,1-
phenylene)diurea,3-cyclohexyl-1-(4-(4-(3-
octadecylureido)benzyl)phenyl)urea and 3,3'- R: 53
dioctadecyl-1,1'-methylenebis(4,1-phenylene)diurea R53 S: 22 - 61 Eu - - - - - - - -

Mixture of 3-[(4-amino-2-chloro-5-nitrophenyl)amino]-
propane-1,2-diol and 3,3'-(2-chloro-5-nitro-1,4- Xn; R22 Xn ; R: 22 - 52/53,
phenylenediimino)bis(propan-1,2-diol) R52-53 S: (2) - 22 - 36 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Page 19
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of 3-[[4-chloro-6-[[7-[(1,5-disulfo-2-
naphthalenyl)azo]-8-hydroxy-3,6-disulfo-1-
naphthalenyl]amino]-1,3,5-triazin-2-yl]amino]-5-[[4-
chloro-6-[[8-hydroxy-3,6-disulfo-7-[(2-sulfophenyl)azo]-
1-naphthalenyl]amino]-1,3,5-triazin-2-
yl]amino]benzoic acid and 3,5-bis[[4-chloro-6-[[7-[(1,5-
disulfo-2-naphthalenyl)azo]-8-hydroxy-3,6-disulfo-1- Xi
naphthalenyl]amino]-1,3,5-triazin-2-yl]amino]benzoic R: 41 Conc>=10%: Xi; R41
acid Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of 3-[3-carbamoyl-5-(5-{4-chloro-6-[4-(2-
sulfonatooxyethylsulfonyl)anilino]-1,3,5-triazin-2-
ylamino}-2-sulfonatophenylazo)-1,2-dihydro-6-
hydroxy-4-methyl-2-oxo-1-pyridyl]propanoic acid,
trisodium salt and 3-[3-carbamoyl-5-(5-{4-chloro-6-[4-
(vinylsulfonyl)anilino]-1,3,5-triazin-2-ylamino}-2- Xi Conc>=10%: Xi; R41; R43
sulfonatophenylazo)-1,2-dihydro-6-hydroxy-4-methyl- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
2-oxo-1-pyridyl]propanoic acid, disodium salt R43 S: (2-)22-26-36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of 3-{5-[3-(4-{1,6-dihydro-2-hydroxy-4-methyl-
1-[3-(methylammonio)propyl]-6-oxo-3-
pyridylazo}benzamido)phenylazo]-1,2-dihydro-6-
hydroxy-4-methyl-2-oxo-1-
pyridyl}propyl(methyl)ammonium di(acetate) and 3-{5-
[4-(3-{1,6-dihydro-2-hydroxy-4-methyl-1-[3-
(methylammonio)propyl]-6-oxo-3-
pyridylazo}benzamido]phenylazo]-1,2-dihydro-6-
hydroxy-4-methyl-2-oxo-1-
pyridyl}propyl(dimethyl)ammonium di(acetate) and 3-
{5-[3-(4-{1-[3-(dimethylammonio)propyl]-1,6-dihydro-2-
hydroxy-4-methyl-6-oxo-3-
pyridylazo}benzamido)phenylazo]-1,2-dihydro-6- Xi; N
hydroxy-4-methyl-2-oxo-1- Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
pyridyl}propyl(dimethyl)ammonium di(acetate) N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of 3a,4,5,6,7,7a-hexahydro-4,7-methano-1H-
indene-6-carboxaldehyde and 3a,4,5,6,7,7a- Xi; R43 Xi ; N ; R: 43 - 51/53 ,
hexahydro-4,7-methano-1H-indene-5-carboxaldehyde N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of 3-cyano-5-(2-cyano-4-nitrophenylazo)-2-(2-
hydroxyethylamino)-4-methyl-6-[3-(2-
phenoxyethoxy)propylamino]pyridine; 3-cyano-5-(2-
cyano-4-nitrophenylazo)-6-(2-hydroxyethylamino)-4-
methyl-2-[3-(2-phenoxyethoxy)propylamino]pyridine,
3-cyano-5-(2-cyano-4-nitrophenylazo)-2-amino-4-
methyl-6-[3-(3-hydroxypropoxy)propylamino]pyridine
and 3-cyano-5-(2-cyano-4-nitrophenylazo)-6-amino-4- R43 Xi ; N ; R: 43 - 51/53
methyl-2-[3-(3-methoxypropoxy)propylamino]pyridine N; R51-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of 4 diastereoisomers of 2,7-dimethyl-10-(1- Xi; R38 Xi ; N ; R: 38 - 51/53

methylethyl)-1-oxaspiro[4.5]deca-3,6-diene N; R51-53 S: (2)37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -

Page 20
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of 4-(1,3a,4,6,7,7a-hexahydro-4,7-
methanoinden-5-ylidene)-3-methylbutan-2-ol and 4-
(3,3a,4,6,7,7a-hexahydro-4,7-methanoinden-5-
ylidene)-3-methylbutan-2-ol and 1-(1,3a,4,6,7,7a-
hexahydro-4,7-methanoinden-5-ylidene)pentan-3-ol
and 1-(3,3a,4,6,7,7a-hexahydro-4,7-methanoinden-5-
ylidene)pentan-3-ol and (E)-4-(3a,4,5,6,7,7a-
hexahydro-1H-4,7-methanoinden-5-yl)-3-methylbut-3- N
en-2-ol and (E)-4-(3a,4,5,6,7,7a-hexahydro-3H-4,7- R: 51/53
methanoinden-5-yl)-3-methylbut-3-en-2-ol N; R51-53 S: 61 Eu - - - - - - - -
Mixture of 4,7-bis(mercaptomethyl)-3,6,9-trithia-1,11-
undecanedithiol and 4,8-bis(mercaptomethyl)-3,6,9- Repr. Cat. 3; R62
trithia-1,11-undecanedithiol and 5,7- Xi; R38 Xn; N Conc>=20%: Xn; R62; R38; R43
bis(mercaptomethyl)-3,6,9-trithia-1,11- R43 R: 38-43-62-50/53 >=5%Conc<20%: Xn; R62; R43
undecanedithiol N; R50-53 S: (2-)36/37-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of 4-[(3-decyloxypropyl)(3-isobutoxy-1-
isobutoxycarbonyl-3-oxopropyl)amino]-4-oxobutyric Xi; N
acid and 4-[(3-isobutoxy-1-isobutoxycarbonyl-3- Xi; R36 R: 36-51/53
oxopropyl)(3-octyloxypropyl)amino]-4-oxobutyric acid N; R51-53 S: (2-)26-61 Conc>=20%: Xi; R36 Eu - - - - - - - -

Carc. Cat. 3; R40

Mixture of 4-[[bis-(4-fluorophenyl)methylsilyl]methyl]- Repr. Cat. 2; R61 T ; N; R: 61 - 22 - 40 - 51/53 Conc>=25%: T; R61; R40; R22
4H-1,2,4-triazole and 1-[[bis-(4- Xn; R22 S: 53 - 45 - 61; >=1%Conc<25%: T; R61; R40
fluorophenyl)methylsilyl]methyl]-1H-1,2,4-triazole N; R51-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -

Mixture of 4-allyl-2,6-bis(2,3-epoxypropyl)phenol, 4-
allyl-6-[3-[6-[3-[6-[3-(4-allyl-2,6-bis(2,3-
epoxypropyl)phenoxy)-2-hydroxypropyl]-4-allyl-2-(2,3-
epoxypropyl)phenoxy]-2-hydroxypropyl]-4-allyl-2-(2,3-
epoxypropyl)phenoxy]-2-hydroxypropyl]-2-(2,3-
epoxypropyl)phenol, 4-allyl-6-[3-(4-allyl-2,6-bis(2,3-
epoxypropyl)phenoxy)-2-hydroxypropyl]-2-(2,3-
epoxypropyl)phenol and 4-allyl-6-[3-[6-[3-(4-allyl-2,6-
bis(2,3-epoxypropyl)phenoxy)-2-hydroxypropyl]-4-allyl-
2-(2,3-epoxypropyl)phenoxy]-2-hydroxypropyl]-2-(2,3- Muta. Cat. 3; R68 Xn ; R: 43 - 68
epoxypropyl)phenol R43 S: (2)36/37 Conc>=1%: Xn; R68; R43 Eu - - - - - - - -

Mixture of 5-(2-cyano-4-nitrophenylazo)-2-(2-(2-
hydroxyethoxy)ethylamino)-4-methyl-6-
phenylaminonicotinonitrile and 5-(2-cyano-4-
nitrophenylazo)-6-(2-(2-hydroxyethoxy)ethylamino)-4- R: 53
methyl-2-phenylaminonicotinonitrile R53 S: 61 Eu - - - - - - - -
Xn; R65 Xn; N
Mixture of 5-endo-butyl-bicyclo[2.2.1]hept-2-ene and Xi; R38 R: 38-65-50/53 Conc>=20%: Xn; R65; R38
5-exo-butyl-bicyclo[2.2.1]hept-2-ene (80:20) N; R50-53 S: (2-)37-62-60-61 >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
Xn; R22
Mixture of 5-heptyl-1,2,4-triazol-3-ylamine and 5- Xi; R36 Xn ; N ; R: 22 - 36 - 51/53 , Conc>=25%: Xn; R22; R36
nonyl-1,2,4-triazol-3-ylamine N; R51-53 S: (2) - 22 - 26 - 61 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
Mixture of 6,7-epoxy-1,2,3,4,5,6,7,8-octahydro-
1,1,2,4,4,7-hexamethylnaphthalene and 7,8-epoxy- N
1,2,3,4,6,7,8,8a-octahydro-1,1,2,4,4,7- R: 50/53
hexamethylnaphthalene N; R50-53 S: 60-61 Eu - - - - - - - -
Mixture of 7-(((3-aminophenyl)sulfonyl)amino)-
naphthalene-1,3-disulfonic acid and sodium 7-(((3-
aminophenyl)sulfonyl)amino)-naphthalene-1,3-
disulfonate and potassium 7-(((3-
aminophenyl)sulfonyl)amino)-naphthalene-1,3- Xi ; R43,
disulfonate R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 21
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of 9-nonyl-10-octyl-19-
carbonyloxyhexadecylnonadecanoic acid and 9-nonyl-
10-octyl-19-carbonyloxyoctadecylnonadecanoic acid
and dihexadecyl 9-nonyl-10-octylnonadecandioate
and 1-octadecyl,19-hexadecyl 9-nonyl-10-
octylnonadecandioate and dioctadecyl 9-nonyl-10- R: 53
octylnonadecandioate R53 S: 61 Eu - - - - - - - -
Mixture of alpha-3-(3-(2H-benzotriazol-2-yl)-5-tert-
butyl-4-hydroxyphenyl)propionyl-omega-
hydroxypoly(oxyethylene) and alpha-3-(3-(2H-
benzotriazol-2-yl)-5-tert-butyl-4-
hydroxyphenyl)propionyl-omega-3-(3-(2H-
benzotriazol-2-yl)-5-tert-butyl-4- Xi; R43 Xi ; N ; R: 43 - 51/53 ,
hydroxyphenyl)propionyloxypoly(oxyethylene) N; R51-53 S: (2) - 36/37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture of ammonium 1-C14-C18-alkyloxycarbonyl-2-
(3-allyloxy-2-hydroxypropoxycarbonyl)ethane-1-
sulfonate and ammonium 2-C14-C18-
alkyloxycarbonyl-1-(3-allyloxy-2- Xi; R38
hydroxypropoxycarbonyl)ethane-1-sulfonate (ratio not R43 Xi ; N ; R:38 - 43 - 50/53, Conc>=20%: Xi; R38; R43
known) N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Mixture of and N-[5-[bis-(2-methoxyethyl)amino]-2-(2-

butyl-4,6-dicyano-1,3-dioxo-2,3-dihydro-1H-isoindol-5-
yl-azo)phenyl]acetamide and N-[2-(2-butyl-4,6-
dicyano-1,3-dioxo-2,3-dihydro-1H-isoindol-5-ylazo)5- R: 53
diethylaminophenyl]acetamide R53 S: 61 Eu - - - - - - - -

Mixture of bis(2,2,6,6-tetramethyl-1-octyloxypiperidin-
4-yl)-1,10-decanedioate and1,8-bis[(2,2,6,6-
tetramethyl-4-((2,2,6,6-tetramethyl-1-octyloxypiperidin- R: 53
4-yl)-decan-1,10-dioyl)piperidin-1-yl)oxy]octane R53 S: 23 - 61 Eu - - - - - - - -
Mixture of bis(5-dodecyl-2-hydroxybenzaldoximate)
copper (II) C12-alkyl group is branched; 4- R: 53
dodecylsalicylaldoxime R53 S: 61 Eu - - - - - - - -

Mixture of bis(isotridecylammonium)mono(di-(4-
methylpent-2-
yloxy)thiophosphorothionylisopropyl)phosphate and R10 C ; N ; R: 10 - 34 - 51/53
isotridecylammonium bis(di-(4-methylpent-2- C; R34 S: (1/2) - 23 - 26 - 28 - Conc>=10%: C; R34
yloxy)thiophosphorothionylisopropyl)phosphate N; R51-53 36/37/39 - 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Mixture of bis(tris(2-(2-hydroxy(1-
methyl)ethoxy)ethyl)ammonium) 7-anilino-4-hydroxy-
3-(2-methoxy-5-methyl-4-(4-
sulfonatophenylazo)phenylazo)naphthalene-2-
sulfonate and bis(tris(2-(2-hydroxy(2-
methyl)ethoxy)ethyl)ammonium) 7-anilino-4-hydroxy-
3-(2-methoxy-5-methyl-4-(4- Xn
sulfonatophenylazo)phenylazo)naphthalene-2- Xn; R22 R: 22-52/53
sulfonate R52-53 S: (2-)22-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Mixture of bis[(2-ethyl-1-oxohexyl)oxy]dioctyl
stannane and bis[((2-ethyl-1-
oxohexyl)oxy)dioctylstannyl]oxide and bis(1-phenyl-
1,3-decanedionyl)dioctyl stannane and ((2-ethyl-1- Xn; N Tin, organic
oxohexyl)oxy)-(1-phenyl-1,3-decanedionyl)dioctyl Xn; R48/22 R: 48/22-50/53 compounds (as
stannane N; R50-53 S: (2-)23-36-60-61 Conc>=10%: Xn; R48/22 Eu;A Sn) - 0.1 - 0.2 - Sk -
Conc>=20%: Xi; R38; R41; R43
Xi; R38-41 Xi ; N ; R: 38 - 41 - 43 - >=10%Conc<20%: Xi; R41; R43
Mixture of C12-14-tert-alkylammonium diphenyl R43 51/53 , >=5%Conc<10%: Xi; R36; R43
phosphorothioate and dinonyl sulphide (or disulphide) N; R51-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Page 22
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of Ca salicylates (branched C10-14 and C18-

30 alkylated) and Ca phenates (branched C10-14 Xn
and C18-30 alkylated) and Ca sulfurised phenates Repr. Cat. 3; R62 R: 43-62 Conc>=5%: Xn; R62; R43
(branched C10-14 and C18-30 alkylated) R43 S: (2-)23-36/37 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of calcium bis(C10-14 branched alkyl

salicylate) and calcium bis(C18-30-alkyl salicylate)
and calcium C10-14 branched alkylsalicylato-C18-30-
alkyl salicylate and calcium bis (C10-14 branched
alkyl phenolate) and calcium bis (C18-30-alkyl
phenolate) and calcium C10-14 branched Xi; N
alkylphenolato-C18-30-alkyl phenolate and C10-14 Xi; R38 R: 38-51/53
branched alkyl phenol and C18-30-alkyl phenol N; R51-53 S: (2-)24-37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Mixture of carbonato-bis-N-ethyl-2-isopropyl-1,3-
oxazolidine and methyl carbonato-N-ethyl-2-isopropyl- Xi; R41 Xi Conc>=10%: Xi; R41; R43
1,3-oxazolidine and 2-isopropyl-N-hydroxyethyl 1,3- R43 R: 41-43-52/53 >=5%Conc<10%: Xi; R36; R43
oxazolidine R52-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of cis-9-octadecenedioic acid and cis-9-cis- Xi; N

12-octadecadienedioic acid and hexadecanedioic Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
acid and octadecanedioic acid N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of complexes of: titanium and 2,2'- N
oxydiethanol and ammonium lactate and nitrilotris(2- R: 51/53
propanol) and ethylene glycol N; R51-53 S: 61 Eu - - - - - - - -

Mixture of copper(I) O,O-bis(4-methylpent-2-yl)

phosphorodithioate and copper(I) O,O-diisopropyl
phosphorodithioate and copper(I) O-isopropyl O-(4- N; R50/53,
methylpent-2-yl) phosphorodithioate N; R50-53 S: 60 - 61 Eu - - - - - - - -

Mixture of copper(I) O,O-diisopropyl

phosphorodithioate and copper(I) O-isopropyl O-(4-
methylpent-2-yl) phosphorodithioate and copper(I) N ; R: 50/53,
O,O-bis(4-methylpent-2-yl) phosphorodithioate N; R50-53 S: 60 - 61 Eu - - - - - - - -

Mixture of copper(I) O-isopropyl O-(4-methylpent-2-yl)

phosphorodithioate and copper(I) O,O-diisopropyl
phosphorodithioate and copper(I) O,O-bis(4- N; R50/53,
methylpent-2-yl) phosphorodithioate N; R50-53 S: 60 - 61 Eu - - - - - - - -

Mixture of di-(1-octane-N,N,N-trimethylammonium)
octylphosphate, 1-octane-N,N,N-trimethylammonium Conc>=25%: C; R34; R21/22
di-octylphosphate and 1-octane-N,N,N- Xn; R21/22 C ; R: 21/22 - 34 >=10%Conc<25%: C; R34
trimethylammonium octylphosphate C; R34 S: (1/2) - 26 - 36/37/39 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Mixture of didecyl dimethyl ammonium carbonate and

didecyl dimethyl ammonium bicarbonate(Note:
Didecyl dimethyl ammonium carbonate - CAS No. Conc>=25%: C; R34; R22
148788-55-0 and didecyl dimethyl ammonium Xn; R22 >=10%Conc<25%: C; R34
bicarbonate - CAS No. 148812-65-1) C; R34 C; R: 22-34 >=5%Conc<10%: Xi; R36/38 V - - - - - - - -

Mixture of diester of 4,4'-methylenebis[2-(2-hydroxy-5-

methylbenzyl)-3,6-dimethylphenol] and 6-diazo-5,6-
dihydro-5-oxonaphthalene-1-sulfonic acid (1:2); and
triester of 4,4'-methylenebis[2-(2-hydroxy-5- Xn
methylbenzyl)-3,6-dimethylphenol] and 6-diazo-5,6- R: 40
dihydro-5-oxonaphthalene-1-sulfonic acid (1:3) Carc. Cat. 3; R40 S: (2-)36/37 Conc>=1%: Xn; R40 Eu - - - - - - - -
Mixture of dimethyl (2-
(hydroxymethylcarbamoyl)ethyl)phosphonate and
diethyl (2-
(hydroxymethylcarbamoyl)ethyl)phosphonate and Carc.Cat.2; R45 T
methyl ethyl (2- Muta.Cat.2; R46 R: 45-46-43 Conc>=1%: T; R45; R46; R43
(hydroxymethylcarbamoyl)ethyl)phosphonate R43 S: 53-45 >=0.1%Conc<1%: T; R45; R46 Eu - - - - - - - -

Page 23
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of disodium (6-(4-anisidino)-3-sulfonato-2-

(3,5-dinitro-2-oxidophenylazo)-1-naphtholato)(1-(5-
chloro-2-oxidophenylazo)-2-naphtholato)chromate(1-)
and trisodium bis(5-(4-anisidino)-3-sulfonato-2-(3,5- R43 Xi ; N ; R: 43 - 50/53
dinitro-2-oxidophenylazo)-1-naphtholato)chromate(1-) N; R50-53 S: (2)24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of disodium 6-(2,4-dihydroxyphenylazo)-3-(4-

(4-(2,4-dihydroxyphenylazo)anilino)-3-
sulphonatophenylazo)-4-hydroxynaphthalene-2-
sulphonate and disodium 6-(2,4-diaminophenylazo)-3-
(4-(4-(2,4-diaminophenylazo)anilino)-3-
sulphonatophenylazo)-4-hydroxynaphthalene-2-
sulphonate and trisodium 6-(2,4-dihydroxyphenylazo)-
3-(4-(4-(7-(2,4-dihydroxyphenylazo)-1-hydroxy-3-
sulphonato-2-naphthylazo)anilino)-3-
sulphonatophenylazo)-4-hydroxynaphthalene-2- Xi ; R: 36 ,
sulphonate Xi; R36 S: (2) - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -
Mixture of disodium 7-(2,4-difluoropyrimidin-6-
ylamino)-4-hydroxy-3-(4-methoxy-2-
sulfonatophenylazo)naphthalene-2-sulfonate and
disodium 7-(4,6-difluoropyrimidin-2-ylamino)-4- Xi
hydroxy-3-(4-methoxy-2- R: 41 Conc>=10%: Xi; R41
sulfonatophenylazo)naphthalene-2-sulfonate Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; R38 Conc>=20%: Xi; R38; R41; R43
Xi; R41 Xi ; N ; R: 38 - 41 - 43 - >=10%Conc<20%: Xi; R41; R43
Mixture of dodecanoic acid and poly(1-7)lactate R43 51/53 , >=5%Conc<10%: Xi; R36; R43
esters of dodecanoic acid N; R51-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of dodecyl 3-(2,2,4,4-tetramethyl-21-oxo-7-

oxa-3,20-diazadispiro(5.1.11.2)henicosan-20-
yl)propionate and teradecyl 3-(2,2,4,4-tetramethyl-21-
oxo-7-oxa-3,20-diazadispiro(5,1,11,2)henicosan-20-
yl)propionate(Note: Dodecyl 3-(2,2,4,4-tetramethyl-21-
oxo-7-oxa-3,20-diazadispiro(5.1.11.2)henicosan-20-
yl)propionate - CAS No. 85099-51-0 and teradecyl 3-
(2,2,4,4-tetramethyl-21-oxo-7-oxa-3,20-
diazadispiro(5,1,11,2)henicosan-20-yl)propionate - Xi; R38 Xi ; N ; R: 38 - 51/53 ,
CAS No. 85099-50-9) N; R51-53 S: (2) - 28 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
C ; N ; R: 22 - 34 - 48/22 -
Mixture of dodecyl N-(2,2,6,6-tetramethylpiperidin-4- Xn; R22-48/22 50/53 Conc>=25%: C; R34; R22; R48/22
yl)-beta-alaninate and tetradecyl N-(2,2,6,6- C; R34 S: (1/2) - 26 - 36/37/39 - 45 - >=10%Conc<25%: C; R34; R48/22
tetramethylpiperidin-4-yl)-beta-alaninate N; R50-53 60 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Mixture of dodecyloxy-1-methyl-1-[oxy-poly-(2-
hydroxymethylethanoxy)]pentadecane and
dodecyloxy-1-methyl-1-[oxy-poly-(2- R: 52/53
hydroxymethylethanoxy)]heptadecane R52-53 S: 61 Eu - - - - - - - -
Mixture of dodecylphenyl
dodecylhydroxybenzenecarboxylate and
bis(dodecylphenyl)dodecyl R: 53
hydroxybenzenedicarboxylate R53 S: 61 Eu - - - - - - - -

Mixture of endo-2-methyl-exo-3-methyl-exo-2-[(exo-3-
methylbicyclo[2.2.1]hept-exo-2-
yl)methyl]bicyclo[2.2.1]heptane and exo-2-methyl-exo- Xi; N Conc>=20%: Xi; R38; R41
3-methyl-endo-2-[(endo-3-methylbicyclo[2.2.1]hept- Xi; R38-41 R: 38-41-50/53 >=10%Conc<20%: Xi; R41
exo-2-yl)methyl]bicyclo[2.2.1]heptane N; R50-53 S: (2-)23-26-37/39-57-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of esters of 5,5',6,6',7,7'-hexahydroxy- E
3,3,3',3'-tetramethyl-1,1'-spirobiindan and 2-diazo-1,2- E; R2 F; R11 R: 2-11-53
dihydro-1-oxo-5-sulfonaphthalene R 53 S: (2-)33-35-40-61 Eu - - - - - - - -

Page 24
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of ethyl (2R,3R)-3-isopropylbicyclo[2.2.1]hept- Xi; N

5-ene-2-carboxylate and ethyl (2S,3S)-3- R43 R: 43-51/53
isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate N; R51-53 S: (2-)23-25-36/37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of isomers of 2-(2H-benzotriazol-2-yl)-4-

methyl-(n)-dodecylphenol, isomers of 2-(2H-
benzotriazol-2-yl)-4-methyl-(n)-tetracosylphenol and
isomers of 2-(2H-benzotriazol-2-yl)-4-methyl-5,6- N ; R: 51/53
didodecyl-phenol. n=5 or 6 N; R51-53 S: 61 Eu - - - - - - - -

Mixture of isomers of alpha-((dimethyl)biphenyl)- Xn; R22 Xn ; R: 22 - 52/53,

omega-hydroxypoly(oxyethylene) R52-53 S: (2) - 39 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Mixture of isomers of dibenzylbenzene,

dibenzyl(methyl)benzene, dibenzyl(dimethyl)benzene N ; R: 50/53
and dibenzyl(trimethyl)benzene N; R50-53 S: 60 - 61 Eu - - - - - - - -

Mixture of isomers of iron (1:2) complexes of a

mixture of isomers of 1,3-dihydroxy-4-[(5-
phenylaminosulfonyl)-2-hydroxyphenylazo]-n-(5-
amino-sulfonyl-2-hydroxyphenylazo)benzene
(n=2,5,6) and isomers of 1,3-dihydroxy-4-[(5-
phenylaminosulfonyl)-2-hydroxyphenylazo]-n-[4-(4-
nitro-2-sulfophenylamino)phenylazo]benzene R43 Xi ; N ; R: 43 - 51/53
(n=2,5,6) N; R51-53 S: (2)22 - 24 - 37 - 61 Conc>=1%: Xi; R43 - - - - - - - -
Mixture of isomers of sodium [(2-
hydroxyethylsulfamoyl){[2-(2-piperazin-1-
ylethylamino)ethylsulfamoyl][2-(4-
aminoethylpiperazine-1- Xi
yl)ethylsulfamoyl](sulfamoyl)}(sulfonatophthalocyanin R: 41 Conc>=10%: Xi; R41
ato)]copper(II) Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of isomers of sodium Xi; R41 Conc>=10%: Xi; R41; R43
phenethylnaphthalenesulfonate and sodium R43 Xi ; R: 41 - 43 - 52/53, >=5%Conc<10%: Xi; R36; R43
naphthylethylbenzenesulfonate R52-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; N
Mixture of isomers of: methyldiphenylmethane and Xi; R38 N; R: 38-50/53
dimethyldiphenylmethane R50-53 S: (2-)37-60-61 Conc>=20%: Xi; R38 Eu - - - - - - - -

Mixture of methyl 1,4-

dimethylcyclohexanecarboxylate ("para-isomer"
including cis- and trans- isomers) and methyl 1,3-
dimethylcyclohexanecarboxylate ("meta-isomer" R: 52/53
including cis- and trans-isomers) R52-53 S: 61 Eu - - - - - - - -
Mixture of methyl 3-((1E)-2-methylprop-1-enyl)-2,2-
dimethylcyclopropanecarboxylate and methyl 3-((1Z)- Xi; N
2-methylprop-1-enyl)-2,2- R43 R: 43-51/53
dimethylcyclopropanecarboxylate (20:80) N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of mono- and di-glycerols of canola oil and

canola oil acid amide of branched 1,3- Xi; N
propanediamine,N-[3-(tridecyloxy)-propyl] and N,N- R43 R: 43-51/53
diorgano dithiocarbamate molybdenum complex N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 25
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of mono to tetra(lithium and/or sodium)3-

amino-10-[4-(4-amino-3-sulfonatoanilino)-6-[methyl-(2-
sulfonatoethyl)amino]-1,3,5-triazin-2-ylamino]-6-13-
dichlorobenzo[1,2-B:4,5-B']di[1,4]benzoxazine-4,11-
disulfonate and mono to tetra(lithium and/or sodium)3-
amino-10-[4,6-bis(4-amino-3-sulfonatoanilino)-1,3,5-
triazin-2-ylamino]-6-13-dichlorobenzo[1,2-B:4,5-
B']di[1,4]benzoxazine-4,11-disulfonate and mono to
penta(lithium and/or sodium)10,10'-diamino-
6,6',13,13'-tetrachloro-3,3'-[6-[methyl-(2-
sulfonatoethyl)amino]-1,3,5-triazin-2,4-
diyldiimino]bis[benzo[1,2-B:4,5-B']di[1,4]benzoxazine-
4,11-disulfonate and mono to hepta(lithium and/or
sodium)10-amino-6,6',13,13'-tetrachloro-10'[4-(4-
amino-3-sulfonatoanilino)-[6-methyl-(2-
sulfonatoethl)amino]-1,3,5-triazin-2,4-
diimino]bis[benzo[1,2-B:4,5-B']di[1,4]benzoxazine-
4,11-disulfonate and mono to hepta(lithium and/or
sodium)10,10'-diamino-6,6',3,3'[(2-sulfonato)-1,4-
phenylenediiminobis[6-methyl-(2-
sulfonatoethyl)amino]-1,3,5-triazin-2,4- Xi
diyldiimino]bis[benzo[1,2-B:4,5-B']di[1,4]benzoxazine- Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
4,11-disulfonate R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of N-(3-
(trimethoxysilyl)propyl)ethylenediamine and N-benzyl-
N-(3-(trimethoxysilyl)propyl)ethylenediamine and N-
benzyl-N'-[3-(trimethoxysilyl)propyl]ethylenediamine Conc>=25%: Xn; R20/21/22; R68/20/21/22;
and N,N'-bis-benzyl-N'-[3- R10 R41; R43
(trimethoxysilyl)propyl]ethylenediamine and N,N,N'- Xn; R20/21/22-68/20/21/22 Xn >=10%Conc<25%: Xn; R68/20/21/22; R41;
tris-benzyl-N'-[3- Xi; R41 R: 10-20/21/22-41-43- R43
(trimethoxysilyl)propyl]ethylenediamine and N,N-bis- R43 68/20/21/22-52/53 >=5%Conc<10%: Xi; R36; R43
benzyl-N'-[3-(trimethoxysilyl)propyl]ethylenediamine R52-53 S: (2-)26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Mixture of N,N"-(methylenedi-4,1-phenylene)bis[N'-
phenylurea] and N-(4-[[4-
[[(phenylamino)carbonyl]amino]phenylmethyl]phenyl]-
N'-cyclohexylurea and N,N"-(methylenedi-4,1- R: 53
phenylene)bis[N'-cyclohexylurea] R53 S: 61 Eu - - - - - - - -
Mixture of N,N-di(hydrogenated alkyl C14-
C18)phthalamic acid and dihydrogenated alkyl (C14- R: 53
C18)amine R53 S: 61 Eu - - - - - - - -

Mixture of N,N'-ethane-1,2-diylbis(hexanamide) and

12-hydroxy-N-[2-[(1- Xi
oxyhexyl)amino]ethyl]octadecanamide and N,N'- R43 R: 43-53
ethane-1,2-diylbis(12-hydroxyoctadecanamide) R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of N-[3-hydroxy-2-(2-
methylacryloylaminomethoxy)propoxymethyl]-2-
methylacrylamide, N-[2,3-bis-(2-
methylacryloylaminomethoxy)propoxymethyl]-2-
methylacrylamide, methacrylamide, 2-methyl-N-(2- Carc. Cat. 2; R45 Conc>=10%: T; R45; R68; R48/22
methylacryloylaminomethoxymethyl)-acrylamide and Muta. Cat. 3; R68 T ; R: 45 - 48/22 >=1%Conc<10%: T; R45; R68
N-(2,3-dihydroxypropoxymethyl)-2-methylacrylamide Xn; R48/22 S: 53 - 45 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Mixture of N-aminoethylpiperazonium mono-2,4,6-
trimethylnonyldiphenyl ether di-sulfonate and N- Xi; R41 Conc>=10%: Xi; R41; R43
aminoethylpiperazonium di-2,4,6- R43 Xi ; N ; R: 41 - 43 - 51/53, >=5%Conc<10%: Xi; R36; R43
trimethylnonyldiphenyl ether di-sulfonate N; R51-53 S: (2) - 26 - 36/37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Page 26
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of n-octadecylaminodiethyl
bis(hydrogenmaleat) and n-octadecylaminodiethyl Xi; R43 Xi ; N ; R: 43 - 51/53 ,
hydrogen maleate hydrogenphthalate N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
Mixture of O,O',O",O'''-silanetetrayl tetrakis(4-methyl- R: 41 Conc>=10%: Xi; R41
2-pentanone oxime) (3 stereoisomers) Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi R36 Eu - - - - - - - -
Xn
Mixture of O,O',O''-(methylsilanetriyl)tris(4-methyl-2- Xn; R48/22 R: 48/22-53
pentanone oxime) (3 stereoisomers) R53 S: 2-36-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Xn; R22
Mixture of O,O'-diisopropyl (pentathio)dithioformate Xi; R38 Xn ; N ; R: 22 - 38 - 43 - Conc>=25%: Xn; R22; R38; R43
and O,O'-diisopropyl (tetrathio)dithioformate and O,O'- R43 50/53 , >=20%Conc<25%: Xi; R38; R43
diisopropyl (trithio)dithioformate N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Mixture of pentaerythriol tetraesters with heptanoic R: 53
acid and 2-ethylhexanoic acid R53 S: 61 Eu - - - - - - - -

Mixture of pentasodium 2-[[8-[[4-chloro-6-[[4-(2-

sulfonato ethylsulfonyl)]phenyl]amino]-1,3,5-triazin-2-
yl]amino-1- hydroxy-3,6-disulfonato-2-
naphthalenyl]azo]naphthalene-1,5-disulfonate and 2-
[[8-[[4-chloro-6-[[4-[[2-ethenyl]sulfonyl]phenyl]amino]- Xi Conc>=10%: Xi; R41; R43
1,3,5-triazin-2-yl]amino]-1-hydroxy-3,6-disulfonato-2- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
naphthalenyl]azo]naphthalene-1,5-disulfonate R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of pentasodium 3-(4-(4-(7-(2,4-diamino-5-

sulfonato-3-(4-sulfonatophenylazo)phenylazo)-1-
hydroxy-3-sulfonatonaphthalen-2-ylazo)-2-
sulfonatophenylamino)phenylazo)-4-hydroxy-6-(2-oxo-
1-phenylcarbamoylpropylazo)naphthalene-2-
sulfonate and pentasodium 6-((2,4-diamino-5-
sulfonatophenyl)azo)-3-((4-((4-((7-((2,4-diamino-5-
sulfonatophenyl)azo)-1-hydroxy-3-
sulfonatonaphthalen-2-yl)azo)phenyl)amino)-2-
sulfonatophenyl)azo)-4-hydroxynaphthalene-2-
sulfonate and pentasodium 6-((2,4-diamino-5-
sulfonato-3-((4-sulfonatophenyl)azo)phenyl)azo)-3-((4-
((4-((1,7-dihydroxy-3-sulfonatonaphthalen-2-yl)azo)-2-
sulfonatophenyl)amino)phenyl)azo)-4-
hydroxynaphthalene-2-sulfonate and hexasodium 6-
((2,4-diamino-5-sulfonatophenyl)azo)-3-((4-((4-((7-
((2,4-diamino-5-sulfonato-3-((4-
sulfonatophenyl)azo)phenyl)azo)-1-hydroxy-3-
sulfonatonaphthalen-2-yl)azo)-2- N
sulfonatophenyl)amino)phenyl)azo)-4- R: 51/53
hydroxynaphthalene-2-sulfonate N; R51-53 S: 61 Eu - - - - - - - -

Page 27
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of pentasodium 4-amino-5-hydroxy-3-{(E)-4-

[2-(sulfonatooxy)ethylsulfonyl]phenylazo}-6-{(E)-2-
sulfonato-4-[2-
(sulfonatooxy)ethylsulfonyl]phenylazo}naphthalene-
2,7-disulfonate and tetrasodium 4-amino-5-hydroxy-3-
{(E)-4-[2-(sulfonatooxy)ethylsulfonyl]phenylazo}-6-[(E)-
2-sulfonato-4-(vinylsulfonyl)phenylazo]naphthalene-
2,7-disulfonate and tetrasodium 4-amino-5-hydroxy-6-
[(E)-2-sulfonato-4-[2-
(sulfonatooxy)ethylsulfonyl]phenylazo}-3-[(E)-4-
(vinylsulfonyl)phenylazo]naphthalene-2,7-disulfonate
and trisodium 4-amino-5-hydroxy-3-[(E)-4-
(vinylsulfonyl)phenylazo]-6-[(E)-2-sulfonato-4-
(vinylsulfonyl)phenylazo]naphthalene-2,7-disulfonate
and trisodium 4-amino-5-hydroxy-3-[(2-
hydroxyethylsulfonyl)-phenylazo]-6-[(E)-2-sulfonato-4-
(vinylsulfonyl)phenylazo]naphthalene-2,7-disulfonate
and trisodium 4-amino-5-hydroxy-3-[(E)-4-
(vinylsulfonyl)phenylazo]-6-[-2-sulfonato-4-(2- Xi; R41 Xi Conc>=10%: Xi; R41; R43
hydroxyethylsulfonyl)phenylazo]naphthalene-2,7- R43 R: 41-43-52/53 >=5%Conc<10%: Xi; R36; R43
disulfonate R52-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of pentasodium 4-amino-5-hydroxy-3-{(E)-4-

[2-(sulfonatooxy)ethylsulfonyl]phenylazo}-6-{(E)-2-
sulfonato-4-[2-
(sulfonatooxy)ethylsulfonyl]phenylazo}naphthalene-
2,7-disulfonate and tetrasodium 4-amino-5-hydroxy-3-
{(E)-4-[2-(sulfonatooxy)ethylsulfonyl]phenylazo}-6-[(E)-
2-sulfonato-4-(vinylsulfonyl)phenylazo]naphthalene-
2,7-disulfonate and tetrasodium 4-amino-5-hydroxy-6-
{(E)-2-sulfonato-4-[2- Xi
(sulfonatooxy)ethylsulfonyl]phenylazo}-3-[(E)-4- Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
(vinylsulfonyl)phenylazo]naphthalene-2,7-disulfonate R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 28
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of pentasodium 7-amino-3-[[4-[[4-[[4-[[4-[(6-

amino-1-hydroxy-3-sulfonato-2-naphthyl)azo]-7-
sulfonato-1-naphthyl]azo]phenyl]amino]-3-
sulfonatophenyl]azo]-6-sulfonato-1-naphthyl]azo]-4-
hydroxynaphthalen-2-sulfonate and pentasodium 7-
amino-8-[4-[4-[4-[4-(2-amino-5-hydroxy-7-sulfonato-
naphthalen-1-ylazo)-7-sulfonatonaphthalen-1-ylazo]-
phenylamino]-3-sulfonato-phenylazo]-6-sulfonato-
naphthalen-1-ylazo]-4-hydroxy-naphthalene-2-
sulfonate and pentasodium 7-amino-8-[4-[4-[4-[4-(6-
amino-1-hydroxy-3-sulfonato-naphthalen-1-ylazo)-7-
sulfonatonaphthalen-1-ylazo]-phenylamino]-3-
sulfonato-phenylazo]-6-sulfonato-naphthalen-1-ylazo]-
4-hydroxy-naphthalene-2-sulfonate and tetrasodium 7-
amino-4-hydroxy-3-[4-[4-[4-(4-hydroxy-7-sulfonato-
naphthalen-1-ylazo)-2-sulfonato-
phenylamino]phenylazo]-6-sulfonato-naphthalen-1-
ylazo]naphthalene-2-sulfonate and tetrasodium 7-
amino-4-hydroxy-3-[4-[4-[4-(4-amino-7-sulfonato-
naphthalen-1-ylazo)-2-sulfonato- Xi
phenylamino]phenylazo]-6-sulfonato-naphthalen-1- Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
ylazo]naphthalene-2-sulfonate R52-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of pentasodium bis(1-(3(or 5)-(4-anilino-3-

sulfonatophenylazo)-4-hydroxy-2-oxidophenylazo)-6-
nitro-4-sulfonato-2-naphtholato)ferrate(1-) and
pentasodium [(1-(3-(4-anilino-3-sulfonatophenylazo)-
4-hydroxy-2-oxidophenylazo)-6-nitro-4-sulfonato-2-
naphtholato)-(5-(4-anilino-3-sulfonatophenylazo)-4-
hydroxy-2-oxidophenylazo)-6-nitro-4-sulfonato-2- N ; R: 51/53
naphtholato]ferrate(1-) N; R51-53 S: 61 Eu - - - - - - - -
Mixture of potassium N-[3-
(dimethyloxidoamino)propyl]-
1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-
heptadecafluorooctane sulfonamidate and N-[3-
(dimethyloxidoamino)propyl]- Xn
1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8- R: 48/22
heptadecafluorooctane sulfonamide Xn; R48/22 S: (2-)22-36 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Mixture of potassium o-toluenephosphonate and Xi; R36 Xi
potassium m-toluenephosphonate and potassium p- R43 R: 36-43-52/53 Conc>=20%: Xi; R36; R43
toluenephosphonate R52-53 S: (2-)24-26-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Mixture of sec-butylphenyl(phenyl)methane, mixed
isomers and 1-(sec-butylphenyl(phenyl)-2- N
phenylethane, mixed isomers and 1-(sec-butylphenyl- R: 50/53
1-phenylethane, mixed isomers N; R50-53 S: 60-61 Eu - - - - - - - -
Mixture of sodium 2-(C12-18-n-alkyl)amino-1,4-
butandioate and sodium 2-octadecenyl-amino-1,4- Xi ; R: 43
butandioate R43 S: (2)24 - 26 - 37/39 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of sodium 2-amino-4-(2,6-difluoropyrimidin-4- Xi

ylamino)benzenesulfonate and sodium 2-amino-4- R: 43
(4,6-difluoropyrimidin-4-ylamino)benzenesulfonate R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of sodium 4,5-dihydro-2-[(propionato)(C6-

18)alkyl]-3H-imidazolium-N-ethylphosphate and Xi Conc>=10%: Xi; R41; R43
disodium 4,5-dihydro-2-[(dipropionato)(C6-18)alkyl]- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
3H-imidazolium-N-ethylphosphate R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Page 29
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of sodium/potassium (3-(4-(5-(5-chloro-2,6-

difluoropyrimidin-4-ylamino)-2-methoxy-3-
sulfonatophenylazo)-2-oxidophenylazo)-2,5,7-
trisulfonato-4-naphtholato)copper(II) and
sodium/potassium (3-(4-(5-(5-chloro-4,6-
difluoropyrimidin-2-ylamino)-2-methoxy-3-
sulfonatophenylazo)-2-oxidophenylazo)-2,5,7- Xi ; R: 43
trisulfonato-4-naphtholato)copper(II) R43 S: (2)22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of substituted dodecyl and/or tetradecyl,

diphenyl ethers. The substance is produced by the
Friedel Crafts reaction. The catalyst is removed from
the reaction product. Diphenyl ether is substituted by
C1-C10 alkyl groups. The alkyl groups are bonded
randomly between C1 and C6. Linear C12 and C14, R: 53
50/50 used. R53 S: 61 Eu - - - - - - - -

Mixture of succinic acid and monopersuccinic acid

and dipersuccinic acid and monomethyl ester of
succinic acid and monomethyl ester of persuccinic
acid and dimethyl succinate and glutaric acid and
monoperglutaric acid and diperglutaric acid and
monomethyl ester of glutaric acid and monomethyl
ester of perglutaric acid and dimethyl glutarate and
adipic acid and monoperadipic acid and diperadipic
acid and monomethyl ester of adipic acid and Conc>=25%: C; R68; R34; R20/21/22
monomethyl ester of peradipic acid and dimethyl Muta. Cat. 3; R68 C >=10%Conc<25%: C; R68; R34
adipate and hydrogen peroxide and methanol and C; R34 R: 20/21/22-34-68 >=5%Conc<10%: Xn; R68; R36/38
water Xn; R20/21/22 S: (1/2-)26-28-36/37/39-45 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -
Xi; R38 Conc>=20%: Xi; R38; R41; R43
Xi; R41 Xi ; N ; R: 38 - 41 - 43 - >=10%Conc<20%: Xi; R41; R43
Mixture of tetradecanoic acid and poly(1-7)lactate R43 51/53 , >=5%Conc<10%: Xi; R36; R43
ester of tetradecanoic acid N; R51-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of tetrasodium 3-(1,5-disulfonatonaphthalene-

2-ylazo)-4-hydroxy-7-{4-chloro-6-[4-(2-
sulfoxyethylsulfonyl)phenylamino]-1,3,5-triazine-2-
ylamino}naphthalene-2-sulfonate and 3-(2,5-
disulfophenylazo)-4-hydroxy-7-{4-chloro-6-[4-(2- Xi
sulfoxyethylsulfonyl)phenylamino]-1,3,5-triazine-2- R: 41 Conc>=10%: Xi; R41
ylamino}naphthalene-2-sulfonic acid, sodium salt Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of tetrasodium 4-amino-6-(5-(2,6-

difluoropyrimidin-4-ylamino)-2-sulfonatophenylazo)-5-
hydroxy-3-(4-
(sulfatoethylsulfonyl)phenylazo)naphthalene-2,7-
disulfonate and tetrasodium 4-amino-6-(5-(4,6-
difluoropyrimidin-2-ylamino)-2-sulfonatophenylazo)-5-
hydroxy-3-(4-(2-
sulfatoethylsulfonyl)phenylazo)naphthalene-2,7- R: 52/53
disulfonate R52-53 S: 61 Eu - - - - - - - -

Mixture of tetrasodium 7-(4-(4-fluoro-6-(4-(2-

sulfonatoethylsulfonyl)phenylamino)-1,3,5-triazin-2-
ylamino)-2-ureidophenylazo)naphthalene-1,3,6-
trisulfonate and tetrasodium 7-(4-(4-hydroxy-6-(4-(2-
sulfonatoethylsulfonyl)phenylamino)-1,3,5-triazin-2-
ylamino)-2-ureidophenylazo)naphthalene-1,3,6- R: 52/53
trisulfonate R52-53 S: 22-61 Eu - - - - - - - -
Mixture of tetrasodium phosphonoethane-1,2-
dicarboxylate and hexasodium phosphonobutane- R43 Xi ; N ; R: 43 - 51/53
1,2,3,4-tetracarboxylate N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 30
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Mixture of thiobis(4,1-phenylene)-S,S.S',S'-
tetraphenyldisulfoniumbishexafluorophosphate and
diphenyl(4-phenylthiophenyl)sulfonium Xi; R41 Xi ; N ; R: 41 - 50/53 , Conc>=10%: Xi; R41
hexafluorophosphate N; R50-53 S: (2 ) - 15 - 26 - 39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of trans-2,4-dimethyl-2-(5,6,7,8-tetrahydro-
5,5,8,8-tetramethyl-naphthalene-2-yl)-1,3-dioxolane
and cis-2,4-dimethyl-2-(5,6,7,8-tetrahydro-5,5,8,8- N ; R: 50/53
tetramethyl-naphthalene-2-yl)-1,3-dioxolane N; R50-53 S: 60 - 61 Eu - - - - - - - -
Xi; R38 Xi
Mixture of trans–trans-cyclohexadeca-1,9-diene and R43 R: 38-43-53 Conc>=20%: Xi; R38; R43
cis–trans-cyclohexadeca-1,9-diene R53 S: (2-)24-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Mixture of triammonium 6-amino-3-((2,5-diethoxy-4-(3-

phosphonophenyl)azo)phenyl)azo-4-hydroxy-2- E; R2
naphthalenesulfonate and diammonium 3-((4-((7- Repr. Cat. 3; R62 E; Xn Conc>=25%: Xn; R62; R22; R48/22
amino-1-hydroxy-3-sulfo-naphthalen-2-yl)azo)-2,5- Xn; R22-48/22 R: 2-22-48/22-62-52/53 >=10%Conc<25%: Xn; R62; R48/22
diethoxyphenyl)azo)benzoate R52-53 S: (2-)22-35-36/37-61 >=5%Conc<10%: Xn; R62 Eu - - - - - - - -
Xi; N
Mixture of trihexadecylmethylammonium chloride; Xi; R41 R: 41 - 50/53 Conc>=10%: Xi; R41
dihexadecyldimethylammonium chloride N; R50-53 S: (2)26 - 39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of trihexyl citrate and dihexyloctyl citrate and R: 53

dioctylhexyl citrate and dihexyldecyl citrate R53 S: 61 Eu - - - - - - - -

Mixture of trilithium 4-amino-3-((4-((4-((2-amino-4-

hydroxyphenyl)azo)phenyl)amino)-3-sulfophenyl)azo)-
5-hydroxy-6-(phenylazo)naphthalene-2,7-disulfonate
and trilithium 4-amino-3-((4-((4-((4-amino-2- Xn; R22 Conc>=25%: Xn; R22; R41
hydroxyphenyl)azo)phenyl)amino)-3-sulfophenyl)azo)- Xi; R41 Xn ; R: 22 - 41 - 52/53 >=10%Conc<25%: Xi; R41
5-hydroxy-6-(phenylazo)naphthalene-2,7-disulfonate R52-53 S: (2)22 - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of trioctylphosphineoxide and C ; N ; R: 34 - 50/53 ,
hexyldioctylphosphineoxide and C; R34 S: (1/2 ) - 26 - 36/37/39 - 45 - Conc>=10%: C; R34
dihexyloctylphosphineoxide N; R50-53 60 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

T; R48/25 Conc>=25%: T; R48/25; R22; R38; R41; R43

Xn; R22 T; N >=20%Conc<25%: T; R48/25; R38; R41; R43
Xi; R38-41 R: 22-38-41-43-48/25-50/53 >=10%Conc<20%: T; R48/25; R41; R43 Tin, organic
Mixture of tri-p-tolyltin hydroxide and hexa-p-tolyl- R43 S: (1/2-)22-26-36/37/39-45- >=5%Conc<10%: Xn; R48/22; R36; R43 compounds (as
distannoxane N; R50-53 60-61 >=1%Conc<5%: Xn; R48/22; R43 Eu;A Sn) - 0.1 - 0.2 - Sk -

Mixture of trisodium 2-((1-(2-hydroxy-kappa-O-5-(2-

sulfonatoethansulfonyl)phenylazo-kappa-N2)-1-
phenylmethyl)azo-kappa-N1)-4-sulfonatobenzoate(5-)-
kappa-O)cuprate(II) and disodium 2-((1-(5-
ethenesulfonyl-2-hydroxy-kappa-O-phenylazo-kappa-
N2)-1-phenylmethyl)azo-kappa-N1)-4- R: 52/53
sulfonatobenzoate-kappa-O-(5-))cuprate(II) R52-53 S: 22-61 Eu - - - - - - - -

Mixture of trisodium 2-(2-[alpha-(2-carboxylato-kappa-

O-4-sulfonatophenylazo)benzylidene]hydrazino-
kappa-N')-6-(2,6-difluoropyrimidin-4-ylamino)-4-
sulfonatophenolatocuprate (II) and trisodium 2-(2-
[alpha-(2-carboxylato-kappa-O-4-
sulfonatophenylazo)benzylidene]hydrazino-kappa-N')- Xi
6-(4,6-difluoropyrimidin-2-ylamino)-4- R: 41 Conc>=10%: Xi; R41
sulfonatophenolatocuprate (II) Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 31
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of trisodium 3-(5-(2,6-difluoropyrimidin-4-

ylamino)-2-sulfonatophenylazo)-5-(4-fluoro-6-
morpholin-4-yl-1,3,5-triazin-2-ylamino)-4-hydroxy-2,7-
naphthalenedisulfonate and trisodium 3-(5-(4,6-
difluoropyrimidin-2-ylamino)-2-sulfonatophenylazo)-5- Xi
(4-fluoro-6-morpholin-4-yl-1,3,5-triazin-2-ylamino)-4- Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
hydroxy-2,7-naphthalenedisulfonate R52-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of trisodium 5-(4-fluoro-6-morpholin-4-yl-1,3,5-
triazin-2-ylamino)-4-hydroxy-3-(4-(2-
sulfooxyethanesulfonyl)phenylazo)naphthalene-2,7-
disulfonate and disodium 3-(4-
ethenesulfonylphenylazo)-5-(4-fluoro-6-morpholin-4-yl- Xi
1,3,5-triazin-2-ylamino)-4-hydroxynaphthalene-2,7- R: 41 Conc>=10%: Xi; R41
disulfonate Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of trisodium 5-{4-chloro-6-[N-ethyl-(3-(2-

sulfonatooxy)ethylsulfonyl)anilino]-1,3,5-triazin-2-
ylamino}-4-hydroxy-3-[4-
(vinylsulfonyl)phenylazo]naphthalene-2,7-disulfonate
and trisodium 5-{4-chloro-6-[N-ethyl-3-
(vinylsulfonyl)anilino]-1,3,5-triazin-2-ylamino}-4-
hydroxy-3-[4-(2-
(sulfonatooxy)ethylsulfonyl)phenylazo]naphthalene-
2,7-disulfonate and disodium 5-{4-chloro-6-[N-ethyl-3-
(vinylsulfonyl)anilino]-1,3,5-triazin-2-ylamino}-4-
hydroxy-3-[(4-vinylsulfonyl)phenylazo]naphthalene-
2,7-disulfonate and tetrasodium 5-{4-chloro-6-[N-ethyl-
3-(2-(sulfonatooxy)ethylsulfonyl)anilino]-1,3,5-triazin-2-
ylamino}-3-[4-(2- Xi
(sulfonatooxy)ethylsulfonyl)phenylazo]-4- Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
hydroxynaphthalene-2,7-disulfonate R52-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of: ((Z)-3,7-dimethyl-2,6-

octadienyl)oxycarbonylpropanoic acid and di-((E)-3,7-
dimethyl-2,6-octadienyl) butandioate and di-((Z)-3,7-
dimethyl-2,6-octadienyl) butandioate and (Z)-3,7- Xi
dimethyl-2,6-octadienyl butandioate and ((E)-3,7- R: 43
dimethyl-2,6-octadienyl)oxycarbonylpropanoic acid R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of: (3R)-[1S-(1alpha, 2alpha, 6beta-((2S)-2-

methyl-1-oxo-butoxy)-8a.gamma.)hexahydro-2,6- Xi
dimethyl-1-naphthalene]-3,5-dihydroxyheptanoic acid R43 R: 43-52/53
inert biomass from Aspergillus terreus R 52-53 S: (2-)36/37-61 Conc>=1%: Xi, R43 Eu - - - - - - - -

Mixture of: 1-(1'H,1'H,2'H,2'H-tridecafluorooctyl)-12-

(1''H,1''H,2''H,2''H-tridecafluorooctyl)dodecanedioate
and 1-(1'H,1'H,2'H,2'H-tridecafluorooctyl)-12-
(1''H,1''H,2''H,2''H-
heptdecafluorodecyl)dodecanedioate and 1-
(1'H,1'H,2'H,2'H-tridecafluorooctyl)-12-
(1''H,1''H,2''H,2''H-
heneicosafluorododecyl)dodecanedioate and 1-
(1'H,1'H,2'H,2'H-tridecafluorooctyl)-12-
(1''H,1''H,2''H,2''H-
pentacosafluorotetradecyl)dodecanedioate and 1-
(1'H,1'H,2'H,2'H-heptadecafluorodecyl)-12-
(1''H,1''H,2''H,2''H-
heptadecafluorodecyl)dodecanedioate and 1-
(1'H,1'H,2'H,2'H-heptadecafluorodecyl)-12- Xn
(1''H,1''H,2''H,2''H- R: 48/22
heneicosafluorododecyl)dodecanedioate Xn; R48/22 S: (2-)36 Conc>=10%: Xn; R48/22 Eu - - - - - - - -

Page 32
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of: 1,1,1-tris(phenyl-4'-(3”-diazo-3”,4”-dihydro-

4”-oxo-naphthalene-1”-sulfonato)ethane; 1,1,1-
tris(phenyl-4'-(6”-diazo-5”,6”-dihydro-5”-oxo-
naphthalene-1”-sulfonato)ethane; reaction product of
1,1,1-tris(p-hydroxyphenyl)ethane with 6-diazo-5,6-
dihydro-5-oxo-1-naphthylsulfonylchloride and 3-diazo-
3,4-dihydro-4-oxo-1-naphthylsulfonylchloride (2:1);
and reaction product of 1,1,1-tris(p-
hydroxyphenyl)ethane with 6-diazo-5,6-dihydro-5-oxo- F
1-naphthylsulfonylchloride and 3-diazo-3,4-dihydro-4- F; R11 R: 11-53
oxo-1-naphthylsulfonylchloride (1:2) R53 S: (2-)3-12-33-61 Eu - - - - - - - -

Mixture of: 1,3,5-tris(3-aminomethylphenyl)-1,3,5-

(1H,3H,5H)-triazine-2,4,6-trione and a mixture of
oligomers of 3,5-bis(3-aminomethylphenyl)-1-poly[3,5- Carc.Cat.2; R45
bis(3-aminomethylphenyl)-2,4,6-trioxo-1,3,5- Repr.Cat.2; R61 T Conc>=1%: T; R45; R61; R43
(1H,3H,5H)-triazin-1-yl]-1,3,5-(1H,3H,5H)-triazine- R43 R 52- R: 45-61-43-52/53 >=0.5%Conc<1%; T; R45; R61
2,4,6-trione 53 S: 53-45-61 >=0.1%Conc<0.5%: T; R45 Eu - - - - - - - -

Mixture of: 1-methyl-3-hydroxypropyl 3,5-[1,1-

dimethylethyl]-4-hydroxydihydro-cinnamate and/or 3-
hydroxybutyl 3,5-[1,1-dimethylethyl]-4-
hydroxydihydrocinnamate and 1,3-butanediol bis[3-(3'-
(1,1-dimethylethyl)4'-hydroxy-phenyl)propionate] N
isomers and 1,3-butanediol bis[3-(3',5'-(1,1- R: 51/53
dimethylethyl)-4'-hydroxyphenyl)propionate] isomers N; R51-53 S: 61 Eu - - - - - - - -

Mixture of: 2,2',2'',2'''-(ethylenedinitrilotetrakis-N,N- Xi

di(C16) alkylacetamide; 2,2',2'',2'''- R: 43
ethylenedinitrilotetrakis-N,N-di(C18)alkylacetamide R43 S: (2)24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture of: 2,2'-[[(2-
hydroxyethyl)imino]bis(methylene)bis[4-
dodecylphenol] formaldehyde, oligomer with 4-
dodecyl phenol and 2-aminoethanol(n = 2) Xi; N Conc>=20%: Xi; R38; R41
formaldehyde, oligomer with 4-dodecyl phenol and 2- Xi; R38-41 R: 38-41-50/53 >=10%Conc<20%: Xi; R41
aminoethanol(n = 3, 4 and higher) N; R50-53 S: (2-)26-37/39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of: 2,2-dimethoxyethanal (Note: this
component is considered to be anhydrous in terms of
identity, structure and composition. However, 2,2-
dimethoxyethanal will exist in a hydrated form. 60%
anhydrous is equivalent to 70.4% hydrate) Xi
water(Including free water and water in hydrated 2,2- R: 43
dimethoxyethanal) R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of: 2,4-bis(N'-(4-methylphenyl)-ureido)- R: 53

toluene; 2,6-bis(N'-(4-methylphenyl)-ureido)-toluene R53 S: 61 Eu - - - - - - - -

Mixture of: 2-ethyl-[2,6-dibromo-4-[1-[3,5-dibromo-4-

(2-hydroxyethoxy)phenyl]-1-
methylethyl]phenoxy]propenoate and 2,2'-diethyl-[4,4'-
bis(2,6-dibromophenoxy)-1-methylethylidene] N
dipropenoate and 2,2'-[(1-methylethylidene)bis[[2,6- R: 51/53
dibromo-4,1-phenylene)oxy]ethanol]] N; R51-53 S: 61 Eu - - - - - - - -
Xi
Mixture of: 2-ethylhexyl mono-D-glucopyranoside and R: 41 Conc>=10%: Xi; R41
2-ethylhexyl di-D-glucopyranoside Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 33
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of: 4-(2,2,3-trimethylcyclopent-3-en-1-yl)-1-

methyl-2-oxabicyclo[2.2.2]octane and 1-(2,2,3-
trimethylcyclopent-3-en-1-yl)-5-methyl-6-
oxabicyclo[3.2.1]octane and spiro[cyclohex-3-en-1-yl-
[(4,5,6,6a-tetrahydro-3,6',6',6'a-tetramethyl)-1,3'(3'aH)-
[2H]cyclopenta[b]furan] and spiro[cyclohex-3-en-1-yl- Xi; N
[4,5,6,6a-tetrahydro-4,6',6',6'a-tetramethyl)-1,3'(3'aH)- Xi; R36/38 N; R: 36/38-51/53
[2H]cyclopenta[b]]furan] R51-53 S: (2-)26-37-61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -

Mixture of: 4,4',4''-[(2,4,6-trioxo-1,3,5(2H,4H,6H)-

triazine-1,3,5-triyl)tris[methylene(3,5,5-trimethyl-3,1-
cyclohexanediyl)iminocarbonyloxy-2,1-
ethanediyl(ethyl)amino]]trisbenzenediazoniumtri[bis(2-
methylpropyl)naphthalenesulfonate] and 4,4',4'',4'''-
[[5,5'-[carbonylbis[imino(1,5,5-trimethyl-3,1-
cyclohexanediyl)methylene]]-2,4,6-trioxo-
1,3,5(2H,4H,6H)-triazine-1,1',3,3'-
tetrayl]tetrakis[methylene(3,5,5-trimethyl-3,1-
cyclohexanediyl)iminocarbonyloxy-2,1- E; R2 E; Xi; N
ethanediyl(ethyl)amino]]tetrakisbenzenediazoniumtetr R43 R: 2-43-50/53
a[bis(2-methylpropyl)naphthalenesulfonate] N; R50-53 S: (2-)24-35-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture of: 5-(N-
methylperfluorooctylsulfonamido)methyl-3-octadecyl-
1,3-oxazolidin-2-one and 5-(N- Xn; N
methylperfluoroheptylsulfonamido)methyl-3-octadecyl- Xn; R48/22 R: 48/22-50/53
1,3-oxazolidin-2-one N; R50-53 S: (2-)36-60-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -

Mixture of: alpha-[3-(3-

mercaptopropanoxycarbonylamino)methylphenylamin
ocarbonyl]-omega-[3-(3-
mercaptopropanoxycarbonylamino)methylphenylamin
ocarbonyloxy]-poly-(oxyethylene-co-oxypropylene)
and 1,2-(or 1,3-)bis[alpha-(3-
mercaptopropanoxycarbonylamino)methylphenylamin
ocarbonyl)-omega-oxy-poly(oxyethylene-co-
oxypropylene)]-3-(or 2-)propanol and 1,2,3-tris[alpha-
(3-mercaptopropanoxycarbonyl- Xi; N
amino)methylphenylaminocarbonyl)-omega-oxy-poly- R43 R: 43-51/53
(oxyethylene-co-oxypropylene)]propane] N; R51-53 S: (2-)36/37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of: ammonium-1,2-

bis(hexyloxycarbonyl)ethanesulfonate and
ammonium-1-hexyloxycarbonyl-2- Xi Conc>=20%: Xi; R38; R41
octyloxycarbonylethane sulfonate and ammonium-2- Xi; R38-41 R: 38-41-52/53 >=10%Conc<20%: Xi; R41
hexyloxycarbonyl-1-octyloxycarbonylethanesulfonate R 52-53 S: (2-)26-37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of: bis(1S,2S,4S)-(1-benzyl-4-tert- Xn; R48/22 Xn; N

butoxycarboxamido-2-hydroxy-5-phenyl) and Xi; R41 R: 41-48/22-50/53 Conc>=10%: Xn; R48/22; R41
pentylammonium succinate and isopropyl alcohol N; R50-53 S: (2-)22-26-36/39-60-61 >=5%Conc<10%:Xi; R36 Eu - - - - - - - -
Mixture of: dicalcium (bis(2-hydroxy-5-tetra-
propenylphenylmethyl)methylamine)dihydroxide and
tri-calcium (tris(2-hydroxy-5-tetra-
propenylphenylmethyl)methylamine)tri-hydroxide and Xi
poly[calcium ((2-hydroxy-5-tetra-propenyl- Xi; R36/38 R: 36/38-43 Conc>=20%: Xi; R36/38; R43
phenylmethyl)methylamine)hydroxide] R43 S: (2-)24-26-37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Page 34
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of: disodium 4-(3-ethoxycarbonyl-4-(5-(3-

ethoxycarbonyl-5-hydroxy-1-(4-
sulfonatophenyl)pyrazol-4-yl)penta-2,4-dienylidene)-
4,5-dihydro-5-oxopyrazol-1-yl)benzenesulfonate and
trisodium 4-(3-ethoxycarbonyl-4-(5-(3-ethoxycarbonyl-
5-oxido-1-(4-sulfonatophenyl)pyrazol-4-yl)penta-2,4- T
dienylidene)-4,5-dihydro-5-oxopyrazol-1- Repr.Cat.2; R61 R: 61-52/53
yl)benzenesulfonate R52-53 S: 53-45-61 Conc>=0.5%: T; R61 Eu - - - - - - - -

Mixture of: Disodium 6-[3-carboxy-4,5-dihydro-5-oxo-

4-sulfonatophenyl)pyrazolin-4-yl-azo]-3-[2-oxido-4-
(ethensulfonyl)-5-methoxyphenylazo]-4-
oxidonaphthalene-2-sulfonate copper (II) complex
and Disodium 6-[3-carboxy-4,5-dihydro-5-oxo-4-
sulfonatophenyl)pyrazolin-4-yl-azo]-3-[2-oxido-4-(2- Xi; N
hydroxyethylsulfonyl)-5-methoxyphenylazo]-4- Xi; R41 N; R: 41-51/53 Conc>=10%: Xi; R41
oxidonaphthalene-2-sulfonate copper (II) complex R51-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of: monosodium 4-((4-(5-sulfonato-2-

methoxyphenylamino)-6-chloro-1,3,5-triazine-2-
yl)amino)-2-((1,4-dimethyl-6-oxido-2-oxo-5-
sulfonatomethyl-1,2-dihydropyridine-3-
yl)azo)benzenesulfonate and disodium 4-((4-(5-
sulfonato-2-methoxyphenylamino)-6-chloro-1,3,5-
triazine-2-yl)amino)-2-((1,4-dimethyl-6-oxido-2-oxo-5-
sulfonatomethyl-1,2-dihydropyridine-3-
yl)azo)benzenesulfonate and trisodium 4-((4-(5-
sulfonato-2-methoxyphenylamino)-6-chloro-1,3,5-
triazine-2-yl)amino)-2-((1,4-dimethyl-6-oxido-2-oxo-5-
sulfonatomethyl-1,2-dihydropyridine-3-
yl)azo)benzenesulfonate and tetrasodium 4-((4-(5-
sulfonato-2-methoxyphenylamino)-6-chloro-1,3,5-
triazine-2-yl)amino)-2-((1,4-dimethyl-6-oxido-2-oxo-5- Xi
sulfonatomethyl-1,2-dihydropyridine-3- R: 43
yl)azo)benzenesulfonate R43 S: (2-)22-24-37 Conc>=1% : Xi; R43 Eu - - - - - - - -
Mixture of: N-(3-dimethylamino-4-methyl-phenyl)-
benzamide and N-(3-dimethylamino-2-methyl-phenyl)- Xn; N
benzamide and N-(3-dimethylamino-3-methyl-phenyl)- Xn; R48/22 R: 48/22-51/53
benzamide N; R51-53 S: (2-)36/37-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -

Mixture of: N,N'-Ethane-1,2-diylbis(decanamide) and

12-Hydroxy-N-[2-[1- Xi; N
oxydecyl)amino]ethyl]octadecanamide and N,N'- R43 R: 43-51/53
Ethane-1,2-diylbis(12-hydroxyoctadecanamide) N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of: pentasodium 2-{4-{3-methyl-4-[6-sulfonato-

4-(2-sulfonato-phenylazo)-naphthalen-1-ylazo]-
phenylamino}-6-[3-(2-sulfato-thanesulfonyl)-
phenylamino]-1,3,5-triazin-2-ylamino}-benzene-1,4-
disulfonate and pentasodium 2-{4-{3-methyl-4-[7-
sulfonato-4-(2-sulfonato-henylazo)-naphthalen-1-
ylazo]-phenylamino}-6-[3-(2-sulfatoethanesulfonyl)-
phenylamino]-1,3,5-triazin-2-ylamino}-benzene-1,4- R: 52/53
disulfonate R 52-53 S: 61 Eu - - - - - - - -

Mixture of: phenol, 6-(1,1-dimethylethyl)-4-tetrapropyl-

2-[(2-hydroxy-5-tetra-propylphenyl)methyl (C41-
compound) and methane, 2,2'-bis[6-(1,1-dimethyl-
ethyl)-1-hydroxy-4-tetrapropyl-phenyl)]- (C45- N
compound); 2,6-bis(1,1-dimethylethyl)-4-tetra-propyl- R: 50/53
phen N; R50-53 S: 60-61 Eu - - - - - - - -

Page 35
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of: phenyl 1-(1-[2-chloro-5-

(hexadecyloxycarbonyl)phenylcarbamoyl]-3,3-
dimethyl-2-oxobutyl)-1H-2,3,3a,7a-
tetrahydrobenzotriazole-5-carboxylate and phenyl 2-
(1-(2-chloro-5-
(hexadecyloxycarbonyl)phenylcarbamoyl)-3,3-
dimethyl-2-oxobutyl)-1H-2,3,3a,7a-
tetrahydrobenzotriazole-5-carboxylate and phenyl 3-
(1-(2-chloro-5-
(hexadecyloxycarbonyl)phenylcarbamoyl)-3,3- N
dimethyl-2-oxobutyl)-1H-2,3,3a,7a- R: 51/53
tetrahydrobenzotriazole-5-carboxylate N; R51-53 S: 37/39-61 Eu - - - - - - - -

Mixture of: reaction product of 4,4'-methylenebis[2-(4-

hydroxybenzyl)-3,6-dimethylphenol] and 6-diazo-5,6-
dihydro-5-oxo-naphthalenesulfonate (1:2) and
reaction product of 4,4'-methylenebis[2-(4- F; Xn
hydroxybenzyl)-3,6-dimethylphenol] and 6-diazo-5,6- F; R11 R: 11-40
dihydro-5-oxo-naphthalenesulfonate (1:3) Carc.Cat.3; R40 S: (2-)7-36/37 Conc>=1%: Xn; R40 Eu - - - - - - - -

Mixture of: sodium 1-tridecyl-4-allyl-(2 or 3)- C; R34 C; N Conc>=10%: C; R34; R43

sulfobutanedioate and sodium 1-dodecyl-4allyl-(2 or R43 R: 34-43-51/53 >=5%Conc<10%: Xi; R36/38; R43
3)-sulfobutanedioate N; R51-53 S: (1/2-)26-36/37/39-45-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of: sodium 5-[8-[4-[4-[4-[7-(3,5-

dicarboxylatophenylazo)-8-hydroxy-3,6-
disulfonatonaphthalen-1-ylamino]-6-hydroxy-1,3,5-
triazin-2-yl]-2,5-dimethylpiperazin-1-yl]-6-hydroxy-
1,3,5-triazin-2-ylamino]-1-hydroxy-3,6-
disulfonatonaphthalen-2-ylazo]-isophthalate and
ammonium 5-[8-[4-[4-[4-[7-(3,5-
dicarboxylatophenylazo)-8-hydroxy-3,6-
disulfonatonaphthalen-1-ylamino]-6-hydroxy-1,3,5-
triazin-2-yl]-2,5-dimethylpiperazin-1-yl]-6-hydroxy-
1,3,5-triazin-2-ylamino]-1-hydroxy-3,6-
disulfonatonaphthalen-2-ylazo]-isophthalate and 5-[8-
[4-[4-[4-[7-(3,5-dicarboxylatophenylazo)-8-hydroxy-
3,6-disulfonatonaphthalen-1-ylamino]-6-hydroxy-1,3,5-
triazin-2-yl]-2,5-dimethylpiperazin-1-yl]-6-hydroxy- Xi
1,3,5-triazin-2-ylamino]-1-hydroxy-3,6- R: 41 Conc>=10%: Xi; R41
disulfonaphthalen-2-ylazo]-isophthalic acid Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi;R36 Eu - - - - - - - -
Mixture of: tetrasodium(((2-
hydroxyethyl)imino)bis(methylene))bisphosphonate,
N-oxide and trisodium ((tetrahydro-2-hydroxy-4H- Xi; N
1,4,2-oxazaphosphorin-4-yl)-methyl)phosphonate, N- Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
oxide, P-oxide N; R51-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of: trans-2-(1-methylethyl)-1,3-dioxane-5- Xi
carboxylic acid and cis-2-(1-methylethyl)-1,3-dioxane- Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
5-carboxylic acid R52-53 S: (2-)25-26-39-61 >=5%Conc<10% : Xi; R36 Eu - - - - - - - -
Mixture of: triphenylthiophosphate and tertiary R: 53
butylated phenyl derivatives R53 S: 61 Eu - - - - - - - -

Page 36
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of: trisodium (2,4(or 2,6 or 4,6)-bis(3,5-dinitro-

2-oxidophenylazo)-5-hydroxyphenolato)(2(or 4or 6)-
(3,5-dinitro-2-oxidophenylazo)-5-hydroxy-4(or 2or 6)-
(4-(4-nitro-2-
sulfonatoanilino)phenylazo)phenolato)ferrate(1-
)trisodium bis(2,4(or 2,6 or 4,6)-bis(3,5-dinitro-2-
oxidophenylazo)-5-hydroxyphenolato)ferrate(1-) and
trisodium (2,4(or 2,6 or 4,6)-bis(3,5-dinitro-2-
oxidophenylazo)-5-hydroxyphenolato)(2(or 4 or 6)-
(3,5-dinitro-2-oxidophenylazo)-5-hydroxy-4(or 2 or 6)-
(4-nitro-2-sulfonatophenylazo)phenolato)-ferrate(1-)
and trisodium (2,4(or 2,6 or 4,6)-bis(3,5-dinitro-2-
oxidophenylazo)-5-hydroxyphenolato)(2(or 4 or 6)-
(3,5-dinitro-2-oxidophenylazo)-5-hydroxy-4(or 2 or 6)-
(3-sulfonatophenylazo)phenolato)-ferrate(1-) and Xi; N
disodium 3,3'-(2,4-dihydroxy-1,3(or 1,5 or 3,5)- R43 N; R: 43-51/53
phenylenediazo)dibenzenesulfonate R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of: tri-sodium [29H, 31H-phthalocyanine-

C,C,C-trisulfonato (6-)-N29,N30,N31,N32]
manganate (3-) and tetrasodium [29H,31H-
phthalocyanine-C,C,C,C-tetrasulfonato (6-)-
N29,N30,N31,N32], manganate (3-) and pentasodium N
[29H,31H-phthalocyanine-C,C,C,C,C-pentasulfonato R: 50/53
(6-)-N29,N30,N31,N32] manganate (3-) N; R50-53 S: 60-61 Eu - - - - - - - -

Mixture of: Trisodium 4-benzoylamino-6-(6-

ethenesulfonyl-1-sulfato-naphthalen-2-ylazo)-5-
hydroxynaphthalene-2,7-disulfonate and 5-
(benzoylamino)-4-hydroxy-3-((1-sulfo-6-((2-
(sulfooxy)ethyl)sulfonyl)-2-naphtyl)azo)naphthalene-
2,7-disulfonic acid sodium salt and 5-(benzoylamino)- Xi; R41 Xi Conc>=10%: Xi; R41; R43
4-hydroxy-3-((1-sulfo-6-((2-(sulfooxy)ethyl)sulfonyl)-2- R43 R: 41-43-52/53 >=5%Conc<10%: Xi R36; R43
naphtyl)azo)naphthalene-2,7-disulfonic acid R52-53 S: 22-26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of: trisodium 5-{4-chloro-6-[2-(2,6-dichloro-5-

cyanopyrimidin-4-ylamino)-propylamino]-1,3,5-triazin-
2-ylamino}-4-hydroxy-3-(1-sulfonatonaphthalene-2-
ylazo)-naphthalene-2,7-disulfonate and trisodium 5-{4-
chloro-6-[2-(2,6-dichloro-5-cyanopyrimidin-4-ylamino)-
1-methyl-ethylamino]-1,3,5-triazin-2-ylamino}-4-
hydroxy-3-(1-sulfonatonaphthalene-2-ylazo)-
naphthalene-2,7-disulfonate and trisodium 5-{4-chloro-
6-[2-(4,6-dichloro-5-cyanopyrimidin-2-ylamino)-
propylamino]-1,3,5-triazin-2-ylamino}-4-hydroxy-3-(1-
sulfonatonaphthalen-2-ylazo)-naphthalene-2,7-
disulfonate and trisodium 5-{4-chloro-6-[2-(4,6-
dichloro-5-cyanopyrimidin-2-ylamino)-1-methyl-
ethylamino]-1,3,5-triazin-2-ylamino}-4-hydroxy-3-(1- Xi Conc>=10%: Xi; R41; R43
sulfonatonaphthalen-2-ylazo)-naphthalene-2,7- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
disulfonate R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of:[2-(anthraquinon-1-ylamino)-6-[(5-
benzoylamino)-anthraquinone-1-ylamino]-4-phenyl]- Xn
1,3,5-triazine and 2,6-bis-[(5-benzoylamino)- Xn; R48/22 R: 48/22-53
anthraquinon-1-ylamino]-4-phenyl-1,3,5-triazine R53 S: (2-)22-36-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Mono-(tetrapropylammonium) hydrogen 2,2'- R: 52/53
dithiobisbenzoate R52-53 S: 61 Eu - - - - - - - -

Page 37
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Mono[2-(dimethylamino)ethyl]monohydrogen-2- Conc>=20%: Xi; R38; R41; R43
(hexadec-2-enyl)butanedioate and/or mono[2- Xi; R38-41 Xi; N >=10%Conc<20%: Xi; R41; R43
(dimethylamino)ethyl]monohydrogen-3-(hexadec-2- R43 R: 38-41-43-50/53 >=5%Conc<10%: Xi; R36; R43
enyl)butanedioate N; R50-53 S: (2-)24-26-37/39-60-61 >=1%Conc<5%:Xi; R43 Eu - - - - - - - -
Mono-2-[2-(4-dibenzo[b,f][1,4]thiazepin-11- Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
yl)piperazinium-1-yl]ethoxy)ethanol trans- Xi; R41 R: 22-41-51/53 >=10%Conc<25%: Xi; R41
butenedioate N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Monolithium 5-[[2,4-dihydroxy-5-[(2-hydroxy-3,5-
dinitrophenyl)azo]phenyl]azo]-2- R: 52/53
naphthalenesulfonate], iron complex, monohydrate R52-53 S: 61 Eu - - - - - - - -
Xi
Monosodium 3-cyano-5-fluoro-6-hydroxypyridine-2- R: 43
olate R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Monosodium aqua-[5-[[2,4-dihydroxy-5-[(2-hydroxy-
3,5-dinitrophenyl)azo]phenyl]azo]-2- R: 52/53
naphthalensulfonate], iron complex R52-53 S: 61 Eu - - - - - - - -
N
n-(2-(6-Chloro-7-methylpyrazolo(1,5-b)-1,2,4-triazol-4- R: 50/53
yl)propyl)-2-(2,4-di-tert-pentylphenoxy)octanamide N; R50-53 S: 60 - 61 Eu - - - - - - - -
N
N-(3,5-Dichloro-4-ethyl-2-hydroxyphenyl)-2-(3- R: 51/53
pentadecylphenoxy)-butanamide N; R51-53 S: 61 Eu - - - - - - - -
N-(4-Dimethylaminopyridinium)-3-methoxy-4-(1-
methyl-5-nitroindol-3-ylmethyl)-N-(o-
tolylsulfonyl)benzamidate R53 R: 53 S: 61 Eu - - - - - - - -

Xi; R41 Xn; N Conc>=10%: Xn; R41; R42

R42 R: 41-42-50/53 >=5%Conc<10%: Xn; R36; R42
N,N"-(Methylenedi-4,1-phenylene)bis[N'-octyl]urea N; R50-53 S: (2-)22-26-39-45-60-61 >=1%Conc<5%: Xn; R42 Eu - - - - - - - -

N,N,N',N'-Tetramethyl-3,3'-
(propylenebis(iminocarbonyl-4,1-phenylenazo(1,6-
dihydro-2-hydroxy-4-methyl-6-oxopyridine-3,1- Xi; R41 Xi ; N ; R: 41 - 51/53 , Conc>=10%: Xi; R41
diyl))di(propylammonium)dilactate N; R51-53 S: (2) - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N
N,N,N-Trimethyl-2,3- R: 51/53
bis(stearoyloxy)propylammonium chloride N;R51-53 S: 61 Eu - - - - - - - -
C; N
C; R35 R: 35-43-50/53 Conc>=10%: C; R35; R43
N,N-Bis(cocoyl-2-oxypropyl)-N,N-dibutylammonium R43 S: (1/2-)26-28-36/37/39-45- >=5%Conc<10%: C; R34; R43
bromide N; R50-53 60-61 >=1%Conc<5%: Xi; R36/38; R43 Eu - - - - - - - -

N,N-Di-[poly(oxyethylene)-co-poly(oxypropylene)]-4- N ; R: 51/53
[(3,5-dicyano-4-methyl-2-thienyl)azo)]-3-methylaniline N; R51-53 S: 61 Eu - - - - - - - -
Xi; N
N-[(Benzotriazole-1-yl)methyl)]-4- Xi; R36 R: 36-51/53
carboxybenzenesulfonamide N; R51-53 S: (2-)26-61 Conc>=20%: Xi; R36 Eu - - - - - - - -
Repr.Cat.3; R62 Xn; N
N-[2-(3-Acetyl-5-nitrothiophen-2-ylazo)-5- R43 R: 43-62-50/53 Conc>=5%: Xn; R62; R43
diethylaminophenyl]acetamide N; R50-53 S: (2-)22-36/37-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi Conc>=10%: Xi; R41; R43
N-[2-Hydroxy-3-(C12-16-alkyloxy)propyl]-N-methyl Xi; R41 R: 41-43 >=5%Conc< 10%: Xi; R36; R43
glycinate R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
N-[Ethyl(3-methylbutyl)amino]-3-methyl-1-phenyl-
spiro[[1]benzo-pyrano[2,3-c]pyrazole-4(1H),1'(3'H)- R: 53
isobenzofuran]-3'-one R53 S: 61 Eu - - - - - - - -
N-Hexadecyl(or octadecyl)-N-hexadecyl(or Xi; R38 Xi ; R: 38 - 43 , Conc>=20%: Xi; R38; R43
octadecyl)benzamide R43 S: (2) - 24 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Nickel, soluble
Nickel, soluble compounds A compounds (as Ni) - 0.1 - - - Sen -

Page 38
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

T+ ; N ; R: 26/27/28 - 51/53, Conc>=7%: T+; R26/27/28

T+; R26/27/28 S: (1/2) - 13 - 28 - 45 - 61; >=1%Conc<7%: T; R23/24/25
Nicotine, salts of N; R51-53 Note: A >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
Xi
Nitrilotriethyleneammoniopropane-2-ol 2- Xi; R36 R: 36-43 Conc>=20%: Xi; R36; R43
ethylhexanoate R43 S: (2-)24-26-37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T; R23/24/25; R33
T; N >=3%Conc<25%: Xn; R20/21/22; R33
T; R23/24/25 R: 23/24/25-33-51/53 >=1%Conc<3%: Xn; R33
Nitrotoluidines, with the exception of those specified R33 S: (1/2-)28-36/37-45-61;
elsewhere in HSIS N; R51-53 Note: C Eu - - - - - - - -
Xn; R22 Xn; N
N-Methylbenzene-1,2-diammonium hydrogen R43 R: 22-43-51/53 Conc>=25%: Xn; R22; R43
phosphate N; R51-53 S: (2-)22-25-36/37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xn Conc>=25%: Xn; R22; R41
Xn; R22 R: 22-41 >=10%Conc<25%: Xi; R41
N-Methyl-N-cyanomethylmorpholiniummethylsulfate Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T; N
n-Pentyl-isopentylphthalate (Note: see also CAS Repr. Cat. 2; R60-61 R: 60-61-50
No, 131-18-0; 605-50-5 and 84777-06-0) N; R50 S: 53-45-61 Conc>=0.5%: T; R60; R61 Eu - - - - - - - -
Xn Conc>=25%: Xn; R62; R22; R48/22
O,O'-(Ethenylmethylsilylene)di[(4-methylpentan-2- Repr.Cat.3; R62 R: 22-48/22-62 >=10%Conc<25%: Xn; R62; R48/22
one)oxime] Xn; R22-48/22 S: (2-)36/37 >=5%Conc<10%: Xn; R62 Eu - - - - - - - -
O,O,O-Tris(2(or 4)-C9-10-isoalkylphenyl) N ; R: 51/53
phosphorothioate N; R51-53 S: 61 Eu - - - - - - - -

Octasodium 2-(8-(4-chloro-6-(3-((4-chloro-6-(3,6-
disulfonato-2-(1,5-disulfonatonaphthalen-2-ylazo)-1-
hydroxynaphthalen-8-ylamino)-1,3,5-triazin-2-
yl)aminomethyl)phenylamino)-1,3,5-triazin-2-ylamino)- Conc>=20%: Xi; R38; R41
3,6-disulfonato-1-hydroxynaphthalen-2- Xi ; R: 38 - 41 >=10%Conc<20%: Xi; R41
ylazo)naphthalene-1,5-disulfonate Xi; R38-41 S: (2)22 - 26 - 37/39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
o-Dianisidine based azo dyes [4,4’-Diarylazo-3,3’- T ; R: 45,
dimethoxybiphenyl dyes, with the exception of those S: 53 - 45
elsewhere specified] Carc. Cat. 2; R45 Notes: A; H Conc>=0.1%: T; R45 Eu - - - - - - - -

Carc. Cat. 2; R45

Muta. Cat. 2; R46 T; N Conc>=25%: T; R45; R46; R22; R48/22; R43
Xn; R22-48/22 R: 45-46-22-43-48/22-51/53 >=10%Conc<25%: T; R45; R46; R48/22; R43
R43 S: 53-45-61 >=1%Conc<10%: T; R45; R46; R43
O-Hexyl-N-ethoxycarbonylthiocarbamate N; R51-53 Note: E >=0.1%Conc<1%: T; R45; R46 Eu - - - - - - - -
Conc>=20%: C; R35, R37
R14 C ; R: 14 - 35 - 37 , >=10%Conc<20%: C; R35
C; R35 S: (1/2) - 26 - 30 - 45; >=5%Conc<10%: C; R34
Oleum ... % SO3 Xi; R37 Note: B >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

O'-Methyl-O-(1-methyl-2-methacryloyloxyethyl)1,2,3,6- R: 52/53
tetrahydrophthalate R52-53 S: 61 Eu - - - - - - - -
o-Tolidine based dyes [4,4’-Diarylazo-3,3’- T ; R: 45,
dimethylbiphenyl dyes, with the exception of those S: 53 - 45;
elsewhere specified] Carc. Cat. 2; R45 Notes: A; H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 22 ,
S: (2) - 22 ;
Papaverine , salt of Xn; R22 Note: A Conc>=25%: Xn; R22 Eu - - - - - - - -
T ; R: 24/25 - 36/37/38,
S: (1/2) - 22 - 36/37/39 - 45 Conc>=25%: T; R24/25; R36/37/38
T; R24/25 ; >=20%Conc<25%: Xn; R21/22; R36/37/38 Paraquat
Paraquat, salts of Xi; R36/37/38 Note: A >=3%Conc<20%: Xn; R21/22 Eu (respirable sizes) - 0.1 - - - - -

Page 39
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Pentakis[3-(dimethylammonio)propylsulfamoyl]-[(6-
hydroxy-4,4,8,8-tetramethyl-4,8-diazoniaundecane- N
1,11-diyldisulfamoyl)di[phthalocyaninecopper(II)]] R: 51/53
heptalactate N; R51-53 S: 61 Eu - - - - - - - -
Pentapotassium 2-(4-(5-[1-(2,5-disulfonatophenyl)-
4,5-dihydro-3-methylcarbamoyl-5-oxopyrazol-4-
ylidene]-3-methyl-1,3-pentadienyl)-3- Xi
methylcarbamoyl-5-oxidopyrazol-1-yl)benzene-1,4- R43 R: 43-52/53
disulfonate R52-53 S: (2-)24-37-47-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Pentapotassium 2-(4-{5-[1-(2,5-disulfophenyl)-4,5-
dihydro-3-methylcarbamoyl-5-oxopyrazol-4-ylidene]-3-
(2-pyrrolidinone-1-yl)-1,3-pentadienyl}-3- N
methylcarbamoyl-5-oxopyrazol-1-yl)benzene-1,4- R: 50/53
disulfonate N; R50-53 S: 60-61 Eu - - - - - - - -

Pentasodium 4-amino-6-(5-(4-(2-ethyl-phenylamino)-
6-(2-sulfatoethanesulfonyl)-1,3,5-triazin-2-ylamino)-2-
sulfonatophenylazo)-5-hydroxy-3-(4-(2- Xi Conc>=10%: Xi; R41; R43
sulfatoethanesulfonyl)phenylazo)naphthalene-2,7- R5 Xi; R41 R: 5-41-43-52/53 >=5%Conc<10%: Xi; R36; R43
disulfonate R43 R 52-53 S: (2-)22-26-36/37/39-41-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Pentasodium bis{7-[4-(1-butyl-5-cyano-1,2-dihydro-2-
hydroxy-4-methyl-6-oxo-3-
pyridylazo)phenylsulfonylamino]-5'-nitro-3,3'- Xi
disulfonatonaphthalene-2-azobenzene-1,2'-diolato} Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
chromate (III) R 52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Pentasodium monohydrogen 6-chloro-3,10-bis[2-[4-

chloro-6-(2,4-disulfophenylamino)-1,3,5-triazin-2-yl- Xi Conc>=10%: Xi; R41; R43
amino]ethylamino]-13-ethylbenzo[5.6][1.4]oxazino[2,3- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
b]phenoxazine-4,11-disulfonate R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 2; R45. Conc>=20%: T; R45; R65; R38
Xn; R65 >=10%Conc<20%: T; R45; R65 (see Chapter
Petrol (leaded & unleaded) Xi; R38 T ; R: 45 - 65 - 38 >=0.1%Conc<10%: T; R45 A, P Petrol (gasoline) - 900 - - - - 16)

Phenol, 4,4'-(1-methylethylidene)bis-, polymer with

N1,N2-bis(2-aminoethyl)-1,2-ethanediamine, 2-
(chloromethyl)oxirane, 2-
[(methylphenoxy)methyl]oxirane and Conc>=25%: Xn; R22; R41
alpha,alpha',alpha''-1,2,3-propanetriyltris[omega- Xn; R22 Xn >=10%Conc<25%: Xi; R41
hydroxypoly[oxy(methyl-1,2-ethanediyl)]] Xi; R41 R: 22-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
T+ ; R: 26/28 , Conc>=7%: T+; R26/28
S: (1/2) - 25 - 45 ; >=1%Conc<7%: T; R23/25
Physostigmine, salts of T+; R26/28 Note: A >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -

E ; T ; R: 3 - 23/24/25 ,
E; R3 S: (1/2) - 28 - 35 - 37 - 45; Conc>=25%: T; R23/24/25
Picric acid, salts of T; R23/24/25 Note: A >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
T+ ; R: 26/28 , Conc>=7%: T+; R26/28
S: (1/2) - 25 - 45 ; >=1%Conc<7%: T; R23/25
Pilocarpine, salts of T+; R26/28 Note: A >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
C; N
R: 35-50/53 Conc>=10%: C; R35
C; R35 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: C; R34 Platinum, soluble
Platinum(IV) nitrate/nitric acid solution N; R50-53 61 >=1%Conc<5%: Xi; R36/38 Eu;A salts (as Pt) - 0.002 - - - Sen -

Poly-(methyl methacrylate)-co-(butylmethacrylate)-co- F; Xi
(4-acryloxybutyl-isopropenyl-alpha,alpha- F; R11 R: 11-43
dimethylbenzyl carbamate)-co-(maleicanhydride) R43 S: (2-)24-37-43 Conc>=1%: Xi; R43 Eu - - - - - - - -
Poly(oxypropylenecarbonyl-co-
oxy(ethylethylene)carbonyl), containing 27% Xi ; R: 43 ,
hydroxyvalerate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 40
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R21/22 C; N Conc>=25%: C; R34; R21/22; R43
C; R34 R: 21/22-34-43-50/53 >=10%Conc<25%: C; R34; R43
Polyethylenepolyamines with the exception of those R43 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: Xi; R36/38; R43
specified elsewhere in HSIS N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Polymeric reaction product of bicyclo[2.2.1]hepta-2,5- Xi

diene, ethene, 1,4-hexadiene, 1-propene with N,N-di- R43 R: 43-53
2-propenylformamide R 53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
N
Polyphosphoric acid, copper, sodium, magnesium, R: 50/53
calcium, silver and zinc salt N; R50-53 S: 60-61 Eu - - - - - - - -
Polyphosphoric acids, polymers with dihydro-3-
(octadecen-1-yl)-2,5-furandione, ethylene glycol,
ethylene oxide and 3-(hexadecen-1-yl) dihydro-2,5- Xi Conc>=10%: Xi; R41
furandione Xi; R41 R: 41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Xn Conc>=25%: Xn; R22; R41
Xn; R22 R: 22-41 S: (2- >=10%Conc<25%:Xi; R41
Potassium 2,5-dichlorobenzoate Xi; R41 )26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
Potassium 3-iodo-6-methylbenzenesulfonate Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi
Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
Potassium 4-iodo-2-sulfonato-benzoic acid R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Potassium iron(III) 1,3-propanediamine-N,N,N',N'- E; R2 E ; N ; R: 2 - 51/53,
tetraacetatehemihydrate N; R51-53 S: (2) - 35 - 61 Eu - - - - - - - -
Xn; R48/22
Xi; R41 Xn Conc>=10%: Xn; R48/22; R41; R43
R43 R: 41-43-48/22-52/53 >=5%Conc<10%: Xi; R36; R43
Potassium N-(4-fluorophenyl)glycinate R 52-53 S: (2-)22-26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Potassium sodium 4-(4-chloro-6-(3,6-disulfonato-7-

(5,8-disulfonato-naphthalen-2-ylazo)-8-hydroxy-
naphthalen-1-ylamino)-1,3,5-triazin-2-ylamino)-5- Xi
hydroxy-6-(4-(2-sulfatoethanesulfonyl)-phenylazo)- R: 43
naphthalene-1,7-disulfonate R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Potassium sodium 6,13-dichloro-3,10-bis{2-[4-[3-(2-

hydroxysulphonyloxyethanesulfonyl)phenylamino]-6-
(2,5-disulfonatophenylamino)-1,3,5-triazin-2- Xi
ylamino]ethylamino}benzo[5,6][1,4]oxazino[2,3- Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
b]phenoxazine-4,11-disulfonate R52-53 S: (2-)39-22-26-61 >=5% Conc < 10% : Xi; R36 Eu - - - - - - - -
Potassium tetrasodium bis[(N,N'-n)-1'- Xi
(phenylcarbamoyl)-3,5-disulfonatobenzeneazo-1'- R: 41 Conc>=10%: Xi; R41
prop-1'-ene-2,2'-diolato]chromate(III) Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Product by process iron complex of azo dyestuffs

obtained by coupling a mixture of diazotized 2-amino-
1-hydroxybenzene-4-sulfanilide and 2-amino-1-
hydroxybenzene-4-sulfonamide with resorcin, the
obtained mixture being subsequently submitted to a
second coupling reaction with a mixture of diazotized
3-aminobenzene-1-sulfonic acid (metanilic acid) and Xi; N
4'-amino-4-nitro-1,1'-diphenylamine-2-sulfonic acid Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
and metallization with ferric chloride, sodium salt N; R51-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 41
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Product-by-process definition polyazodyestuff

obtained by coupling 4-[4-(1-amino-8-hydroxy-3,6-
disulfo-2-
naphthylazo)phenylsulfonylamino]benzenediazonium
with a mixture of 4-carboxybenzenediazonium and
diphenylamine-3-sulfo-4,4'-bisdiazonium, and further
coupling of the obtained compounds with a mixture of Xi
naphth-2-ol and 3-aminophenol, sodium salts; Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
sodium chloride R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N R:
50/53
Propoxycarbazone-sodium N; R50-53 S: 60-61 Eu - - - - - - - -

Proteases, with the exception of those specified Xi: R 36/37/38 Xn ; R:36/37/38 - 42 Conc>=20%: Xn; R42; R36/37/38
elsewhere Xn; R42 S: (2) - 22 - 24 - 26 - 36/37 >=1%Conc<20%: Xn; R42 Eu - - - - - - - -

p-Toluenesulphonic acid (containing more than 5% C ; R: 34 , Conc>=25%: C; R34

H2SO4) C; R34 S: (1/2 - ) - 26 - 37/39 - 45 >=10%Conc<25%: Xi; R36/38 Eu - - - - - - - -
Pyraclostrobin (ISO) [Methyl N-{2-[1-(4-chlorophenyl)- T; R23 T; N Conc>=25%: T; 23; R38
1H-pyrazol-3-yloxymethyl]phenyl}(N- Xi; R38 R: 23-38-50/53 >=20%Conc<25%: Xn; R20; R38
methoxy)carbamate] N; R50-53 S: (1/2-)45-60-61-63 >=3%Conc<20%: Xn; R20 Eu - - - - - - - -

Xn; R20/21/22 Xn ; N ; R: 20/21/22 - 50/53,

Pyrethrins including cinerins N; R50-53 S: (2) - 13 - 60 - 61 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Reaction mixture of 2,3,4,2',3',4'-hexahydroxy-5,5'-
diacethyl-diphenylmethane and 6-diazo-5,6-dihydro-5-
oxo-1-naphthalenesulfonylchloride and 3-diazo-3,4- F
dihydro-6-methoxy-4-oxo-1- F; R11 R: 11-53
naphthalenesulfonylchloride R53 S: (2-)3-12-16-33-61 Eu - - - - - - - -

Reaction mixture of saturated, monounsaturated and

multiple unsaturated long-chained partly estrified
alcohols of vegetable origin (Brassica napus L.,
Brassica rapa L., Helianthus annuus L., Glycine
hispida, Gossypium hirsutum L., Cocos nucifera L.,
Elaeis guineensis) with O,O- Xi
diisobutyldithiophosphate and 2-ethylhexylamine and R: 43
hydrogen peroxide R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Reaction product of (2-hydroxy-4-(3-propenoxy) F; R11 F ; T ; R: 11 - 20/21/22 - Conc>=25%: T; R39/23/24/25; R20/21/22

benzophenone and triethoxysilane) with (hydrolysis T; R39/23/24/25 39/23/24/25 >=10%Conc<25%: T; R39/23/24/25
product of silica and methyltrimethoxysilane) Xn; R20/21/22 S: (1/2) - 16 - 29 - 36/37 - 45 >=1%Conc<10%: Xn; R68/20/21/22 Eu - - - - - - - -
Xi; R38
Reaction product of ammonium molybdate and C12- R43 Xi ; N ; R: 38 - 43 - 51/53 Conc>=20%: Xi; R38; R43
C24-diethoxylated alkylamine (1:5-1:3) N; R51-53 S: 24/25 - 37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Reaction product of amorphous silica (50-85 %),
butyl (1-methylpropyl) magnesium (3-15 %), F; R11 F; Xi Conc>=20%: Xi; R37/38; R41
tetraethyl orthosilicate (5-15 %) and titanium Xi; R37/38-41 R: 11-37/38-41-52/53 >=10%Conc<20%: Xi; R41
tetrachloride (5-20 %) R52-53 S: (2-)6-26-36/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; N
Reaction product of C.I. Leuco Sulfur Black 1 with (3- Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
chloro-2-hydroxypropyl)trimethylammonium chloride N; R51-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Reaction product of C.I. LeucoSulfur Black 1 and a

mixture of disodium 4-{4-[8-amino-1-hydroxy-7-(4-
sulfamoylphenylazo)-3,6-disulfonato-2-
naphthylazo]phenylsulfonylamino}benzenediazonium
chloride and disodium 4-{4-[2,6-dihydroxy-3-(8-
hydroxy-3,6-disulfonato-1-
naphthylazo)phenylazo]phenylsulfonylamino}benzene R: 52/53
diazonium chloride R52-53 S: 61 Eu - - - - - - - -

Page 42
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Reaction product of cocoalkyldiethanolamides and N

cocoalkylmonoglycerides and molybdenumtrioxide R: 51/53
(1.75-2.2: 0.75-1.0:0.1-1.1) N; R51-53 S: 61 Eu - - - - - - - -
Xi; R38 Xi
Reaction product of diphenylamine, phenothiazine, R43 R: 38-43-53 Conc>=20%: Xi; R38; R43
and alkenes, branched (C8-10, C9-rich) R53 S: (2-)24-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Reaction product of diphenylmethanediisocyanate, R: 53

octylamine and oleylamine (molar ratio 1:1.86:0.14) R53 S: 61 Eu - - - - - - - -

Reaction product of diphenylmethanediisocyanate,

octylamine, 4-ethoxyaniline and ethylenediamine R: 53
(1:0.37:1.53:0.05) R53 S: 61 Eu - - - - - - - -

Reaction product of diphenylmethanediisocyanate,

octylamine, oleylamine and cyclohexylamine R: 53
(1:1.58:0.32:0.097) R53 S: 61 Eu - - - - - - - -

Reaction product of diphenylmethanediisocyanate,

toluenediisocyanate (mixture of isomers: 65 % 2,4-
and 35 % 2,6-diisocyanate), octylamine and R: 53
oleylamine (molar ratio 4:1:9:1) R53 S: 61 Eu - - - - - - - -

Reaction product of diphenylmethanediisocyanate,

toluenediisocyanate (mixture of isomers: 65 % 2,4-
and 35 % 2,6-diisocyanate), octylamine, oleylamine
and 4-ethoxyaniline (molar ratio R: 53
3.88:1:6.38:0.47:2.91) R53 S: 61 Eu - - - - - - - -

Reaction product of diphenylmethanediisocyanate,

toluenediisocyanate (mixture of isomers: 65 % 2,4-
and 35 % 2,6-diisocyanate), octylamine, oleylamine R: 53
and 4-ethoxyaniline (molar ratio 4:1:7:1:2) R53 S: 61 Eu - - - - - - - -
Reaction product of thioglycerol and mercaptoacetic T; R23 Conc>=25%: T; R23; R22; R36; R43
acid consisting mainly of 3-mercapto-1,2- Xn; R22 T >=20%Conc<25%: Xn; R20; R36; R43
bismercaptoacetoxypropane and oligomers of this Xi; R36 R: 22-23-36-43 >=3%Conc<20%: Xn; R20; R43
substance R43 S: (1/2-)24-26-37-45 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Reaction product of toluenediisocyanate (mixture of
isomers: 65 % 2,4- and 35 % 2,6-diisocyanate) and R: 53
aniline (molar ratio 1:2) R53 S: 61 Eu - - - - - - - -
Reaction product of: 1,2,3-propanetricarboxylic acid, F; R11 F; Xi; N Conc>=20%: Xi; R38; R41
2-hydroxy, diethyl ester, 1-propanol and zirconium Xi; R38-41 R: 11-38-41-51/53 >=10%Conc<20%: Xi; R41
tetra-n-propanolate N; R51-53 S: (2-)9-16-26-37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Reaction product of: 2-[[4-amino-2-ureidophenylazo]-

5-[(2-(sulfooxy)ethyl)sulfonyl]]benzenesulfonic acid
with 2,4,6-trifluoropyrimidine and partial hydrolysis to Xi
the corresponding vinylsulfonyl derivative,mixed Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
potassium/sodium salt R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; N
Reaction product of: 3,5-bis-tert-butylsalicylic acid Xn; R22 R: 22-50/53
and aluminiumsulfate N; R50-53 S: (2-)22-56-60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
O; R7 O; C; N Conc>=25%: C; R35; R20/21/22
Xn; R20/21/22 R: 7-20/21/22-35-50 >=10%Conc<25%: C; R35
Reaction product of: borax, hydrogen peroxide, acetic C; R35 S: (1/2-)3/7-14-26-36/37/39- >=5%Conc<10%: C; R34
acid anhydride and acetic acid N; R50 45-61 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Reaction product of: copper, (29H,31H-
phthalocyaninato(2-)-N29,N30,N31,N32)-, Xi
chlorosulfuric acid and 3-(2- R: 41 Conc>=10%: Xi; R41
sulfooxyethylsulfonyl)aniline, sodium salts Xi; R41 S: (2-)22-26-39 >=5%Conc<10%; Xi; R36 Eu - - - - - - - -

Page 43
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Reaction product of: polyethylene-polyamine-(C16- Xi; R36/38 Xi
C18)-alkylamides with monothio-(C2)-alkyl R43 R: 36/38-43-52/53 Conc>=20%: Xi; R36/38; R43
phosphonates R52-53 S: (2-)24-26-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
F; R11
Xn; R20 F ; C ; N ; R: 11 - 20 - 34 - Conc>=25%: C; R34; R20; R43
Reaction products of tungsten hexachloride with 2- C; R34 43 - 50/53 >=10%Conc<25%: C; R34; R43
methylpropan-2-ol, nonylphenol and pentane-2,4- R43 S: (1/2) - 16 - 26 - 29 - 33 - >=5%Conc<10%: Xi; R36/38; R43
dione N; R50-53 36/37/39 - 45 - 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Reaction products of: copper(II) sulfate and
tetrasodium 2,4-bis[6-(2-methoxy-5-
sulfonatophenylazo)-5-hydroxy-7-sulfonato-2- N
naphthylamino]-6-(2-hydroxyethylamino)-1,3,5- R: 51/53
triazine (2:1) N; R51-53 S: 61 Eu - - - - - - - -
Reaction products of: trimethylhexamethylene
diamine (a mixture of 2,2,4-trimethyl-1,6-
hexanediamine and 2,4,4-trimethyl-1,6- C; N
hexanediamine, EINECS listed), Epoxide 8 Xn; R22 R: 22 - 34 - 50/53 Conc>=25%: C; R34; R22
(mono[(C10-C16-alkyloxy)methyl]oxirane derivatives) C; R34 S: (1/2) - 23 - 26 - 36/37/39 - >=10%Conc<25%:C; R34
and p-toluene-sulfonic acid N; R50-53 45 - 60 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Refractory
Ceramic Fibres (see
Refractory Ceramic Fibres, Special Purpose Fibres, (RCF),(h) Special Workplace
with the exception of those specified elsewhere in Purpose Glass Exposure
HSIS [Synthetic mineral fibres (SMF); MMVF](Note: Fibres(i) Standards for
Man-made vitreous (silicate) fibres with random T and Airborne
orientation with alkaline oxide and alkali earth oxide R: 49 High 2 mg/m3 Contaminants
(Na2O+K2O+CaO+ MgO+BaO) content less or equal S: 53-45 Biopersistence 0.5 f/mL (inhalable for meaning
to 18 % by weight) Carc. Cat. 2; R49 Notes: A ; R Conc>=0.1%: T; R49 Eu;A MMVF(l) (respirable) dust)(j) - - - - of (h) (i) (j) (l))
Rhodium, soluble
compounds (as
Rhodium, soluble compounds (as Rh) A Rh) - 0.01 - - - - -

Rosin core solder

Rosin core solder pyrolysis products, as pyrolysis products
formaldehyde A (as formaldehyde) - 0.1 - - - - -

S-(Tricyclo(5.2.1.0'2,6)deca-3-en-8(or 9)-yl O-
(isopropyl or isobutyl or 2-ethylhexyl) O-(isopropyl or N ; R: 50/53,
isobutyl or 2-ethylhexyl) phosphorodithioate N; R50-53 S: 60 - 61 Eu - - - - - - - -
Carc. Cat. 3; R40 Xn ; N ; R: 22 - 36 - 40 -
Xn; R22 51/53, Conc>=25%: Xn; R40; R22; R36
Salts of 4,4'- carbonimidoylbis N,N-dimethylaniline Xi; R36 S: (2) - 36/37 - 61; >=20%Conc<25%: Xn; R40; R36
[Salt of auramine] N; R51-53 Note: A >=1%Conc<20%: Xn; R40 Eu - - - - - - - -
N
Salts of glyphosate, with the exception of those R51/53
specified elsewhere in HSIS N; R51-53 S:61 Eu - - - - - - - -

Salts of hydrogen cyanide with the exception of T+; N

complex cyanides such as ferrocyanides, T+; R26/27/28 R: 26/27/28-32-50/53 Conc>=7%: T+; R26/27/28
ferricyanides and mercuric oxycyanide and those R32 S: (1/2-)7-28-29-45-60-61 >=1%Conc<7%: T; R23/24/25
specified elsewhere in HSIS N; R50-53 Note: A >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
Xn
R: 21/22
Salts of oxalic acid with the exception of those S: (2-)24/25
specified elsewhere in HSIS Xn; R21/22 Note: A Conc>=5%: Xn; R21/22 Eu - - - - - - - -

Selenium compounds with the exception of cadmium

sulphoselenide and those specified elsewhere in T; N
HSIS(Note: These UN No.s refer to selenium T; R23/25 R: 23/25-33-50/53 Conc>=25%: T; R23/25; R33
compounds except selenic acid, selenates, selenites, R33 S: (1/2-)20/21-28-45-60-61 >=3%Conc<25%: Xn; R20/22; R33 Hydrogen selenide
selenium disulfide and selenium oxychloride) N; R50-53 Note: A >=1%Conc<3%: Xn; R33 Eu;A (as Se) 0.05 0.16 - - - - -

Page 44
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Selenium compounds with the exception of cadmium

sulphoselenide and those specified elsewhere in T; N Selenium
HSIS(Note: These UN No.s refer to selenium T; R23/25 R: 23/25-33-50/53 Conc>=25%: T; R23/25; R33 compounds (as
compounds except selenic acid, selenates, selenites, R33 S: (1/2-)20/21-28-45-60-61 >=3%Conc<25%: Xn; R20/22; R33 Se) excluding
selenium disulfide and selenium oxychloride) N; R50-53 Note: A >=1%Conc<3%: Xn; R33 Eu;A hydrogen selenide - 0.1 - - - - -

Selenium compounds with the exception of cadmium

sulphoselenide and those specified elsewhere in T; N
HSIS(Note: These UN No.s refer to selenium T; R23/25 R: 23/25-33-50/53 Conc>=25%: T; R23/25; R33 Selenium
compounds except selenic acid, selenates, selenites, R33 S: (1/2-)20/21-28-45-60-61 >=3%Conc<25%: Xn; R20/22; R33 hexafluoride (as
selenium disulfide and selenium oxychloride) N; R50-53 Note: A >=1%Conc<3%: Xn; R33 Eu;A Se) 0.05 0.16 - - - - -

Silica, Fumed (respirable dust) [Fume (thermally Fumed silica (see Silica -
generated) (respirable dust)] A (respirable dust) - 2 - - - - Amorphous)
N
R: 50/53
Silver sodium zirconium hydrogenphosphate N; R50-53 S: 60-61 Eu - - - - - - - -
Silver, soluble
compounds (as
Silver, soluble compounds (as Ag) A Ag) - 0.01 - - - - -
(see also
Soapstone Soapstone
Soapstone, respirable dust A (respirable dust) - 3 - - - - (a))
Conc>=20%: Xi; R38; R41; R43
Xi; R38-41 Xi; N >=10%Conc<20%: Xi; R41; R43
Sodium (Z)-3-chloro-3-(4-chlorophenyl)-1-hydroxy-2- R43 R: 38-41-43-50/53 >=5%Conc<10%: Xi; R36; R43
propene-1-sulfonate N; R50-53 S: (2-)24-26-37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi ; R: 43
Sodium 2-benzoyloxy-1-hydroxyethane-sulfonate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
Sodium 3-(methoxycarbonyl)-4-oxo-3,4,5,6-tetrahydro- R: 36
2-pyridinolate Xi; R36 S: (2-)26 Conc>=20%: Xi; R36 Eu - - - - - - - -

Sodium 3,5-bis(3-(2,4-di-tert- Xi; R38 Xi ; R: 38 - 43 , Conc>=20%: Xi; R43, R38

pentylphenoxy)propylcarmbamoyl)benzenesulfonate R43 S: (2) - 24 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Sodium 4-hydroxy-3-(N'-(2-(2- Xi
hydroxyethylenesulfonyl)ethylene)ureido)-5- R43 R: 43-52/53
nitrobenzenesulfonate R52-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Sodium 5-(2-carboxyphenylazo)-6- R: 52/53
hydroxynaphthalene-2-sulfonate R52-53 S: 61 Eu - - - - - - - -
Sodium bis[tris(2-hydroxyethyl)ammonium][6-anilino-
4'-(4,8-disulfonato-2-naphthylazo)-5'-methyl-3-
sulfonatonaphthalene-2-azobenzene-1,2'- R: 52/53
diolato]cuprate(II) R52-53 S: 61 Eu - - - - - - - -
F; R11
R14/15 F; C Conc>=25%: C; R35; R20
R 17 R: 11-14/15-17-20-35 >=10% Conc<25%: C; R35
Sodium((n-butyl)x(ethyl)y-1,5-dihydro)aluminate) x = Xn; R20 S: (1/2-)6-16-26-30-36/37/39- >=5%Conc<10%: C; R34
0.5 y = 1.5 C; R35 43-45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

Page 45
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Spinosad (ISO) (a mixture of spinosyn A and

spinosyn D in rations between 95:5 to 50:50) [Mixture
of 50-95 % of
(2R,3aS,5aR,5bS,9S,13S,14R,16aS,16bR)-2-(6-
deoxy-2,3,4-tri-O-methyl-alpha-L-
mannopyranosyloxy)-13-(4-dimethylamino-2,3,4,6-
tetradeoxy-beta-D-erythropyranosyloxy)-9-ethyl-
2,3,3a,5a,5b,6,7,9,10,11,12,13,14,15,16a,16b-
hexadecahydro-14-methyl-1H-8-oxacyclododeca[b]as-
indacene-7,15-dione and 50-5 %
(2S,3aR,5aS,5bS,9S,13S,14R,16aS,16bS)-2-(6-
deoxy-2,3,4-tri-O-methyl-alpha-L-
mannopyranosyloxy)-13-(4-dimethylamino-2,3,4,6-
tetradeoxy-beta-D-erythropyranosyloxy)-9-ethyl-
2,3,3a,5a,5b,6,7,9,10,11,12,13,14,15,16a,16b-
hexadecahydro-4,14-dimethyl-1H-8- N
oxacyclododeca[b]as-indacene-7,15-dione](Note: see R: 50/53
also CAS No. 131929-60-7 & 131929-63-0) N; R50-53 S: 60-61 Eu - - - - - - - -
Xi
Strontium 2-[(2-hydroxy-6-sulfonato-1- R: 43
naphthyl)azo]naphthalene-1-sulfonate R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
T+ ; N ; R: 26/28 - 50/53,
S: (1/2) - 13 - 28 - 45 - 60 - Conc>=7%: T+; R26/28
T+; R26/28 61; >=1%Conc<7%: T; R23/25
Strychnine, salts of N; R50-53 Note: A >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
R: 53
Tall oil 2-[(tetrahydro-2H-pyran-2-yl) thio]ethyl esters R53 S: 61 Eu - - - - - - - -

tert-(Dodecyl/tetradecyl)-ammonium bis(3-(4-((5-(1,1-
dimethyl-propyl)-2-hydroxy-3-nitrophenyl)azo)-3-
methyl-5-hydroxy-(1H)pyrazol-1- N ; R: 51/53
yl)benzenesulfonamidato)chromate N; R51-53 S: 61 Eu - - - - - - - -

tert-Butyl(6-{2-[4-(4-fluorophenyl)-6-isopropyl-2-
[methyl(methylsulfonyl)amino]pyrimidin-5- R: 53
yl]vinyl}(4S,6S)-2,2-dimethyl[1,3]dioxan-4-yl)acetate R53 S: 61 Eu - - - - - - - -

Tetraammonium 5-(4-(7-amino-1-hydroxy-3-sulfonato- Xi ; R: 43 ,
2-naphthylazo)-6-sulfonato-1-napthylazo)isophthalate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Tetrabutylammonium butyl tris-(4-trans- R: 53
butylphenyl)borate R53 S: 61 Eu - - - - - - - -
T Conc>=25%: T; R25; R41; R42/43
R: 25 - 41 - 42/43 >=10%Conc<25%: Xn; R22; R41; R42/43
T; R25 S: (2) - 22 - 26 - 36/37/39 - >=5%Conc<10%: Xn; R22; R36; R42/43
Tetrachloroplatinates, with the exception of those Xi; R41 45; >=3%Conc<5%: Xn; R22; R42/43
elsewhere specified R42/43 Note: A >=1%Conc<3%: Xn; R42/43 Eu - - - - - - - -

Tetrahydro-2-isobutyl-4-methylpyran-4-ol mixed
isomers (cis and trans)(Note: cis isomer CAS No. Xi ; R: 36 ,
65418-69-1 and trans isomer CAS No. 65418-70-4) Xi; R36 S: (2) - 25 - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -
Tetralithium 2-[6-[7-[2-(carboxylato)phenylazo]-8- Xi
hydroxy-3,6-disulfonato-1-naphthylamino]-4-hydroxy- Xi; R36 R: 36-52/53
1,3,5-triazine-2-ylamino]benzoate R52-53 S: (2-)26-39-61 Conc>=20%: Xi; R36 Eu - - - - - - - -

Tetrapotassium 2-(4-(5-(1-(2,5-disulfonatophenyl)-3-
ethoxycarbonyl-5-hydroxypyrazol-4-yl)penta-2,4-
enylidene)-3-ethoxycarbonyl-5-oxo-2-pyrazolin-1- Xi ; R: 43 ,
yl)benzene-1,4-disulfonate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 46
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Tetrapotassium 4-[5-[3-carboxylato-4,5-dihydro-5-oxo-
1-(4-sulfonatophenyl)pyrazol-4-ylidene]-3- Xn
(piperidinocarbonyl)penta-1,3-dienylidene]-5-hydroxy- Xn; R20 R: 20-52/53
1-(4-sulfonatophenyl)pyrazole-3-carboxylate R52-53 S: (2-)25-61 Conc>=25%: Xn; R20 Eu - - - - - - - -

Tetrasodium 4,4'-bis{4-[4-(2-hydroxyethylamino)-6-(4- Xi
sulfonatoanilino)-1,3,5-triazin-2- R: 41 Conc>=10%: Xi; R41
ylamino]phenylazo}stilbene-2,2'-disulfonate Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Tetrasodium 4-amino-3,6-bis(5-(6-chloro-4-(2-
hydroxyethylamino)-1,3,5-triazin-2-ylamino)-2-
sulfonatophenylazo)-5-hydroxynaphthalene-2,7- Conc>=10%: Xi; R41, R43
sulfonate (containing > 35% sodium chloride and Xi; R41. Xi ; R: 41 - 43 , >=5%Conc<10%: Xi; R36, R43
sodium acetate) R43 S: (2) - 22 - 24 - 26 - 37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Tetrasodium 4-hydroxy-5-[4-[3-(2-
sulfatoethanesulfonyl)phenylamino]-6-morpholin-4-yl- Xi
1,3,5-triazin-2-ylamino]-3-(1-sulfonatonaphthalen-2- R: 43
ylazo)naphthalene-2,7-disulfonate R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
N
R: 51/53
Tetrazinc(2+)bis(hexacyanocobalt(3+))diacetate N; R51-53 S: 61 Eu - - - - - - - -

T+ ; N ; R: 26/28 - 33 -
T+; R26/28 51/53, Conc>=7%: T+; R26/28; R33
Thallium compounds, with the exception of those R33 S: (1/2) - 13 - 28 - 45 - 61; >=1%Conc<7%: T; R23/25; R33
elsewhere specified N; R51-53 Note: A >= 0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -

Thallium soluble compounds (as Tl)(Note: Except for Conc>=7%: T+; R26/28; R33
Thallous chlorate and Thallous nitrate which have T+; R26/28 T+ ; R: 26/28 - 33 , >=1%Conc<7%: T; R23/25; R33
their own specific UN numbers.) R33 S: (1/2) - 13 - 28 - 45 >= 0.1%Conc<1%: Xn; R20/22 Eu; A - - - - - - - -
Xn
Thiocyanic acid, alkali salts and alkali earth salts of, Xn; R20/21/22 R: 20/21/22-32-52/53
with the exception of those specified elsewhere in R32 S: (2-)13-36/37-46-61
HSIS R52-53 Note: A Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Xn; N
Xn; R20/21/22 R: 20/21/22-32-50/53
Thiocyanic acid, metal salts of, with the exception of R32 S: (2-)13-36/37-46-60-61
those specified elsewhere in HSIS N; R50-53 Note: A Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Xn
Xn; R20/21/22 R: 20/21/22-32-52/53
Thiocyanic acid, salts of, with the exception of those R32 S: (2-)13-36/37-46-61
specified elsewhere in HSIS R52-53 Note: A Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Thionyl chloride, reaction products with 1,3,4- Xi; R38
thiadiazol-2,5-dithiol, tert-nonanethiol and C12-14-tert- R43 Xi ; R: 38 - 43 - 52/53 , Conc>=20%: Xi; R38; R43
alkylamine R52-53 S: (2) - 36/37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Tin, organic
compounds (as
Tin, organic compounds (as Sn) A Sn) - 0.1 - 0.2 - Sk -
F ; C ; R: 17 - 34 ,
S: (1/2 ) - 7 - 23 - 26 -
F; R17 36/37/39 - 43 - 45 ; Conc>=10%: C; R34
Trialkylboranes C; R34 Note: A >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

T; N
T; R25-48/23/25 R: 21-25-36/38-48/23/25-
Xn; R21 50/53 Tin, organic
Tributyltin compounds, with the exception of those Xi; R36/38 S: (1/2-)36/37/39-45-60-61 Conc>=1%: T; R25; R48/23/25; R21; R36/38 compounds (as
specified elsewhere in HSIS N; R50-53 Note: A >=0.25%Conc<1%: Xn; R22; R48/20/22 Eu;A Sn) - 0.1 - 0.2 - Sk -
T+; N
R: 26/27/28-50/53 Conc>=0.5%: T+; R26/27/28 Tin, organic
Triethyltin compounds, with the exception of those T+; R26/27/28 S: (1/2-)26-27-28-45-60-61; >=0.1%Conc<0.5%: T; R23/24/25 compounds (as
specified elsewhere in HSIS N; R50-53 Note: A >=0.05%Conc<0.1%: Xn; R20/21/22 Eu; A Sn) - 0.1 - 0.2 - Sk -

Page 47
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T+; N
R: 26/27/28-50/53 Conc>=0.5%: T+; R26/27/28 Tin, organic
Trimethyltin compounds, with the exception of those T+; R26/27/28 S: (1/2-)26-27-28-45-60-61; >=0.1%Conc<0.5%: T; R23/24/25 compounds (as
specified elsewhere in HSIS N; R50-53 Note: A >=0.05%Conc<0.1%: Xn; R20/21/22 Eu; A Sn) - 0.1 - 0.2 - Sk -
Xi Tin, organic
Trioctyltin compounds, with the exception of those Xi; R36/37/38 R: 36/37/38-53 compounds (as
specified elsewhere in HSIS R53 S: (2-)61; Note: A Conc>=1%: Xi; R36/37/38 Eu; A Sn) - 0.1 - 0.2 - Sk -

T; N
R: 23/24/25-50/53 Tin, organic
Triphenyltin compounds, with the exception of those T; R23/24/25 S: (1/2-)26-27-28-45-60-61 Conc>=1%: T; R23/24/25 compounds (as
specified elsewhere in HSIS N; R50-53 Note: A >=0.25%Conc<1%: Xn; R20/21/22 Eu;A Sn) - 0.1 - 0.2 - Sk -
T; N
R: 23/24/25-50/53 Tin, organic
Tripropyltin compounds, with the exception of those T; R23/24/25 S: (1/2-)26-27-28-45-60-61; Conc>=0.5%: T; R23/24/25 compounds (as
specified elsewhere in HSIS N; R50-53 Note: A >=0.1%Conc<0.5%: Xn; R20/21/22 Eu; A Sn) - 0.1 - 0.2 - Sk -
Tris(2-(2-hydroxyethoxy)ethyl)ammonium-3- Xi ; R: 43 ,
acetoacetamido-4-methoxybenzenesulfonate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

tris(2-Hydroxyethyl)ammonium 7-{4-[4-(2-cyanoamino-
4-hydroxy-6-oxidopyrimidin-5-ylazo)benzamido]-2- R: 52/53
ethoxy-phenylazo}naphthalene-1,3-disulfonate R 52-53 S: 61 Eu - - - - - - - -
N ; R: 51/53,
Tris(isopropyl/tert-butylphenyl) phosphate N; R51-53 S: 61 Eu - - - - - - - -
Tris(octadec-9-enylammonium) Xi; R41 Xi ; N ; R: 41 - 51/53 , Conc>=10%: Xi; R41
(trisulfonatophthalocyaninato)copper(II) N; R51-53 S: (2) - 22 - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Trisodium (1-(3-carboxylato-2-oxido-5- Xi; R41 Xi; N Conc>=10%: Xi; R41; R43
sulfonatophenylazo)-5-hydroxy-7-sulfonatonaphthalen R43 R: 41-43-51/53 >=5%Conc<10%: Xi; R36; R43
2-amido)nickel(II) N; R51-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Trisodium [1,2'-(2-(8-amino-3,5-
disulfonatonaphthalene)azo)-(4'-nitrobenzene)diolato- Xi
O,O,N][(Z)-2,2-((phenylcarbamoylprop-1'-enyl)azo)-5- R: 41 Conc>=10%: Xi; R41
sulfamoylbenzene)diolato-O,O,N]chromate(III) Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Trisodium [2-(5-chloro-2,6-difluoropyrimidin-4-
ylamino)-5-(b-sulfamoyl-c,d-sulfonatophthalocyanin-a-
yl-K4,N29,N30,N31,N32-sulfonylamino)benzoato(5- Xi Conc>=10%: Xi; R41; R43
)]cuprate(II) where a=1,2,3,4 b=8,9,10,11 Xi; R41 R: 41 - 43 >=5%Conc<10%: Xi; R36; R43
c=15,16,17,18 d=22,23,24,25 R43 S: (2) - 26 - 36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Trisodium 1-hydroxynaphthalene-2-azo-4(5',5"-
dimethylbiphenyl)-4"-azo(4"- Xi; R: 36,
phenylsulfonyloxybenzene)- 2',2",4-trisulfonate Xi; R36 S: (2) - 25 - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -
Trisodium 2-{alpha[2-hydroxy-3-[4-chloro-6-[4-(2,3-
dibromopropionylamino)-2-sulfonatophenylamino]-
1,3,5-triazin-2-ylamino]-5-sulfonatophenylazo]- Xi; N
benzylidenehydrazino}-4-sulfonatobenzoate, copper Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
complex N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Trisodium 4-hydroxy-6-(sulfonatomethylamino)-5-(2- Xi
(2-sulfatoethylsulfonyl)phenylazo)naphthalene-2- R: 43
sulfonate R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Trisodium bis[(3'-nitro-5'-sulfonato(6-amino-2-[4-(2- Xi
hydroxy-1-naphtylazo)phenylsulfonylamino]pyrimidin- R43 R: 43-52/53
5-azo)benzene-2',4-diolato)]chromate(III) R52-53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

T+; N
T+; R26/28 R: 26/28-33-51/53 Conc>=7%: T+; R26/28; R33 Uranium (natural),
Uranium compounds with the exception of those R33 S: (1/2-)20/21-45-61 >=1%Conc<7%: T; R23/25; R33 soluble & insoluble
specified elsewhere in HSIS N; R51-53 Note: A >=0.1%Conc<1%: Xn; R20/22 Eu;A compounds (as H) - 0.2 - 0.6 - - -

Page 48
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Vanadium(IV) oxide hydrogen phosphate Xn; R20-48/22 Xn ; N ; R: 20 - 41 - 48/22 - Conc>=25%: Xn; R20; R48/22; R41
hemihydrate, lithium, zinc, molybdenum, iron and Xi; R41 51/53, >=10%Conc<25%: Xn; R48/22; R41
chlorine-doped N; R51-53 S: (2) - 22 - 26 - 36/39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Welding fumes
(not otherwise (see Chapter
Welding fumes (not otherwise classified) A classified) - 5 - - - - 17)
White spirit Xn; R65 Xn ; R: 65 Conc>=10%: Xn; R65 P - - - - - - - -

Wood dust (certain

Wood dust ( certain hardwoods such as beech and hardwoods such
oak) A as beech & oak) - 1 - - - Sen -
Wood dust (soft
Wood dust ( soft wood) A wood) - 5 - 10 - Sen -
T; N
R: 23/24/25 - 33 - 51/53
Xylidines, with the exception of those elsewhere T; R23/24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R23/24/25; R33
specified [Dimethyl anilines, with the exception of R33 61; >=3%Conc<25%: Xn; R20/21/22; R33
those elsewhere specified] N; R51-53 Note: C >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
Xi; R36/38 Xi; N ; R: 36/38 - 51/53 ,
Zinc 2-hydroxy-5-C13-18 alkylbenzoate N; R51-53 S: (2) – 26 - 61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
Carc. Cat. 1; R45 T ; N ; R: 45 - 22 - 43 -
Xn; R22 50/53, Conc>=25%: T; R45, R22, R43
R43 S: 53 - 45 - 60 - 61; >=1%Conc<25%: T; R45, R43
Zinc chromates including zinc potassium chromate N; R50-53 Notes: A ; E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Xi; N
Zinc hexacyanocobaltate(III), tertiary butyl Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
alcohol/polypropylene glycol complex N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Zinc salts, fatty acids, C16-18 and C18 unsaturated, R: 53
branched and linear R53 S: 61 Eu - - - - - - - -
Xi; N
Zinc-bis(4-(n-octyloxycarbonylamino)salicylate) Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
dihydrate N; R51-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Zirconium
Zirconium compounds (as Zr) A compounds (as Zr) - 5 - 10 - - -
F; R15,
Zirconium powder (non pyrophoric) F; R15 S: (2) - 7/8 - 43 Eu - - - - - - - -

Conc>=25%: T; R49; R23/24/25; R34; R43

>=10%Conc<25%: T; R49; R34; R20/21/22;
R43
T ; R: 49 - 23/24/25 - 34 - 43 >=5%Conc<10%: T; R49; R20/21/22;
Carc. Cat. 2; R49 , R36/37/38; R43
T; R23/24/25 S: (1/2) - 26 - 36/37 - 45 - >=3%Conc<5%: T; R49; R20/21/22; R43
C; R34 51 ; >=0.2%Conc<3%: T; R49; R43
50-00-0 Formaldehyde ...% R43 Notes: B ; D >=0.1%Conc<0.2%: T; R49 N/Eu; A Formaldehyde (h) 1 1.2 2 2.5 2 Sen -
Xn; R22 Xn ; R: 22 - 36/38 , Conc>=25%: Xn; R22; R36/38
50-01-1 Guanidinium chloride [Guanadine hydrochloride] Xi; R36/38 S: (2) - 22 >=20%Conc<25%; Xi; R36/38 Eu - - - - - - - -

Conc>=25%: T+; R26; 24/25;R48/25

>=10%Conc<25%: T+; R26; R21/22; R48/25
>=7%Conc<10%: T+; R26; R21/22;R48/22
T+ >=3%Conc<7%: T; R23; R21/22; R48/22
T+; R26 R: 24/25-26-48/25 >=1%Conc<3%: T: R23; R48/22
50-14-6 Ergocalciferol [Vitamin D2] T; R24/25-48/25 S: (1/2-)28-36/37-45 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
DDT (common name not adopted by ISO) T ; N ; R: 25 - 40 - 48/25 - Conc>=25%: T; R40; R25-48/25
[Clofenotane (INN); Dicophane; 1,1,1-Trichloro-2,2- T; R25-48/25 50/53 , >=10%Conc<25%: T; R40; R48/25; R22 DDT
bis(4-chlorophenyl)ethane; Carc. Cat. 3; R40 S: (1/2) - 22 - 36/37 - 45 - >=3%Conc<10%: Xn; R40; R22; R48/22 (Dichlorodiphenyl-
50-29-3 Dichlorodiphenyltrichloroethane] N; R50-53 60 - 61 >=1%Conc<3%: Xn; R40; R48/22 Eu; A trichloroethane) - 1 - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53,
50-31-7 2,3,6-TBA (ISO) [2,3,6-Trichlorobenzoic acid] N; R51-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Page 49
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 2; R45
Muta. Cat. 2; R46 Conc>=1%: T; R45; R46; R60/61; R43
Repr. Cat. 2; R60-61 T; N >=0.5%Conc<1%: T; R45; R46; R60/61
R43 R: 45-46-60-61-43-50/53 >=0.1%Conc<0.5%: T; R45; R46 Benzo(a)pyrene
50-32-8 Benzo[a]pyrene [Benzo[def]chrysene] N; R50-53 S: 53-45-60-61 >=0.01%Conc<0.1%: T; R45 Eu; A (d) - - - - 2 - -

50-78-2 Acetylsalicylic acid [Aspirin] A Acetylsalicylic acid - 5 - - - - -

5-(3,6,9-Trioxa-2-undecyloxy)benzo(d)-1,3-dioxolane Xn ; R: 22 ,
51-14-9 [Sesamex] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -

T; R23/24/25 Conc>=25%: T; R23/24/25; R33

R33 T ; N ; R: 23/24/25 - 33 - 50 >=3%Conc<25%: Xn; R20/21/22; R33
51-28-5 2,4-Dinitrophenol N; R50-R53 S: (1/2) - 28 - 37 - 45 - 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
Conc>=7%: T+; R26/27/28
T+ ; R: 26/27/28 , >=1%Conc<7%: T; R23/24/25
51-34-3 Hyoscine T+; R26/27/28 S: (1/2) - 25 - 45 >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
Conc>=7%: T+; R26/28
T+ ; R: 26/28 , >=1%Conc<7%: T; R23/25
51-55-8 Atropine T+; R26/28 S: (1/2) - 25 - 45 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
T ; R: 45,
51-79-6 Urethane (INN) [Ethyl carbamate] Carc. Cat. 2; R45 S: 53 – 45 Conc>=0.1%: T; R45 Eu - - - - - - - -
Conc>=25%: Xn; R21/22; R37/38; R41
Xn; R21/22 Xn; N >=20%Conc<25%: Xi; R37/38; R41
Xi; R37/38-41 R: 21/22-37/38-41-50 >=10%Conc<20%: Xi; R41
52-51-7 Bronopol (INN) [2-Bromo-2-nitropropane-1,3-diol] N; R50 S: (2-)26-36/37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Trichlorfon (ISO) Xn; R22 Xn; N

R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
52-68-6 [Dimethyl 2,2,2-trichloro-1-hydroxyethylphosphonate] N; R50-53 S: (2-)24-37-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
T; N
Carc. Cat. 2; R45 R: 45-50/53
53-70-3 Dibenz[a,h]anthracene N; R50-53 S: 53-45-60-61 Conc>=0.01%: T; R45 Eu - - - - - - - -
Conc>=25%: T+; R27; R25
>=7%Conc<25%: T+; R27; R22
T+; R27 >=3%Conc<7%: T; R24; R22
T; R25 T+ ; N ; R: 25 - 27 - 51/53, >=1%Conc<3%: T; R24
54-11-5 3-(N-Methyl-2-pyrrolidinyl)pyridine [Nicotine (ISO)] N; R51-53 S: (1/2) - 36/37 - 45 - 61 >=0.1%Conc<1%: Xn; R21 Eu; A Nicotine - 0.5 - - - Sk -
Benzoic acid, 2-hydroxy-, monosodium salt [Sodium Xn
54-21-7 salicylate] Xn; R22 R: 22 Conc>=25%: Xn; R22 N - - - - - - - -
Muta. Cat. 3; R68 Conc>=25%: T; R68; R23; R48/25; R21/22
T; R23-48/25 T; N >=10%Conc<25%: T; R68; R48/25; R20
Fenthion (ISO) [O,O-Dimethyl-O-(4-methylthion-m- Xn; R21/22 R: 21/22-23-48/25-68-50/53 >=3%Conc<10%: Xn; R68; R20; R48/22
55-38-9 tolyl) phosphorothioate] N; R50-53 S: (1/2-)36/37-45-60-61 >=1%Conc<3%: Xn; R68; R48/22 Eu;A Fenthion - 0.2 - - - Sk -

Xn; R22-48/22 Xn ; N ; R: 22 - 43 - 48/22 - Conc>=25%: Xn; R22; R48/22; R43.

R43 50/53, >=10%Conc<25%: Xn; R48/22; R43
55-55-0 Bis(4-hydroxy-N-methylanilinium)sulphate N; R50-53 S: (2) - 36/37 - 46 - 60 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
E; R3 E ; T+ ; N ; R: 3 - 26/27/28 -
T+; R26/27/28 33 - 51/53, Conc>=7%: T+; R26/27/28; R33
R33 S: (1/2) - 33 - 35 - 36/37 - >=1%Conc<7%: T; R23/24/25; R33
55-63-0 Nitroglycerin [Glycerol trinitrate] N; R51-53 45 - 61 >= 0.1%Conc<1%: Xn; R20/21/22 Eu; A Nitroglycerin (NG) 0.05 0.46 - - - Sk -

Conc>=25%: T; R25; R48/24/25; R34

T ; N ; R: 25 - 34 - 48/24/25 - >=10%Conc<25%: T; R48/24/25; R34; R22
T; R25-48/24/25 50/53, >=5%Conc<10%: Xn; R22; R48/21/22; R36/38
Phenylmercury nitrate(Note: see also CAS No 100-57- C; R34 S: (1/2) - 23 - 24/25 - 37 - >=3%Conc<5%: Xn; R22; R48/21/22
55-68-5 2 & 8003-05-2) N; R50-53 45 - 60 - 61 >=1%Conc<3%: Xn; R48/21/22 Eu - - - - - - - -

Page 50
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: T+; R26; R35; R24; R22; R43
>=10%Conc<25%: T+;R26; R35; R21; R43
T+; R26 >=7%Conc<10%: T+: R26; R34; R21; R43
T; R24 T+ ; C ; R: 26 - 24 - 22 - 35 - >=5%Conc<7%: T; R23; R34; R21; R43
Xn; R22 43 , >=3%Conc<5%: T; R23; R21; R36/38; R43
3,3'-Iminodi(propylamine) [1,3-Propanediamine, N-(3- C; R35 S: (1/2) - 26 - 28 - 36/37/39 - >=1%Conc<3%: T; R23; R36/38; R43
56-18-8 aminopropyl)] R43 45 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -

Carc. Cat. 3; R40 T; N

T; R23/24/25-48/23 R: 23/24/25-40-48/23-59-
R52-53 52/53 Conc>=1%: T; R40; R23/24/25; R48/23 Carbon
56-23-5 Tetrachloromethane [Carbon tetrachloride] N; R59 S: (1/2-)23-36/37-45-59-61 >=0.2%Conc<1%: Xn; R20/21/22; R48/20 Eu; A tetrachloride 0.1 0.63 - - 2 Sk -

Conc>=25%: T+; R26/28; R24; R48/25

>=10%Conc<25%: T+; R26/28; R21; R48/25
>=7%Conc<10%: T+; R26/28; R21; R48/22
T+; R26/28 T+; N >=3%Conc<7%: T; R23/25; R21; R48/22
Parathion (ISO) [O,O-Diethyl O-4-nitrophenyl T; 24-48/25 R: 24-26/28-48/25-50/53 >=1%Conc<3%: T; R23/25; R48/22
56-38-2 phosphorothioate] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=0.1%Conc<1%: Xn; R20/22 Eu; A Parathion - 0.1 - - - Sk -
T; N
Carc. Cat. 2; R45 R: 45-50/53
56-55-3 Benz[a]anthracene N; R50-53 S: 53-45-60-61 Conc>=0.1%: T; R45 Eu - - - - - - - -
Conc>=25%: T+; R28; R21
T+; R28 T+ ; N ; R: 21 - 28 - 50/53 , >=7%Conc<25%: T+; R28
Coumaphos (ISO) [O-3-Chloro-4-methylcoumarin-7-yl Xn; R21 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R25
56-72-4 O,O-diethyl phosphorothioate] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
F; R11 Conc>=25%: T; R45; R23/25; R34
Carc. Cat. 2; R45 F ; T ; N ; R: 45 - 11 - 23/25 - >=10%Conc<25%: T; R45; R34; R20/22
T; R23/25 34 - 51/53, >=5%Conc<10%: T; R45; R20/22; R36/38
C; R34 S: 53 - 45 - 61; >=3%Conc<5%: T; R45; R20/22 1,1-
57-14-7 N,N-Dimethylhydrazine [1,1-Dimethylhydrazine] N; R51-53 Note: E >=0.1%Conc<3%: T; R45 Eu; A Dimethylhydrazine 0.01 0.025 - - 2 Sk -
T+ ; N ; R: 27/28 - 50/53, Conc>=7%: T+; R27/28
T+; R27/28 S: (1/2) - 36/37 - 45 - 60 - >=1%Conc<7%: T; R24/25
57-24-9 Strychnine N; R50-53 61 >=0.1%Conc<1%: Xn; R21/22 Eu; A Strychnine - 0.15 - - - - -
Conc>=7%: T+; R26/28
T+ ; R: 26/28 , >=1%Conc<7%: T; R23/25
57-47-6 Physostigmine T+; R26/28 S: (1/2) - 25 - 45 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Propane-1,2-diol:
57-55-6 Propane-1,2-diol: particulates only A particulates only - 10 - - - - -
Propane-1,2-diol
total: (vapour &
57-55-6 Propane-1,2-diol: total (vapour and particulates) A particulates) 150 474 - - - - -
Conc>=20%: T+; R45; R26; R36/38
Carc. Cat. 2; R45 T+ ; R: 45 - 26 - 36/38 , >=7%Conc<20%: T+; R45; R26
beta-Propiolactone [3-Propanolide; 1,3- T+; R26 S: 53 - 45 ; >=1%Conc<7%: T; R45; R23
57-57-8 Propiolactone] Xi; R36/38 Note: E >=0.1%Conc<1%: T; R45; R20 Eu; A beta-Propiolactone 0.5 1.5 - - 2 - -
Carc. Cat. 3; R40 Xn ; N ; R: 21/22 - 40 -
Chlordane (ISO) [1,2,4,5,6,7,8,8-Octachloro- Xn; R21/22 50/53 , Conc>=25%: Xn; R40; R21/22
57-74-9 3a,4,7,7a-tetrahydro-4,7-methanoindan] N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<25%: Xn; R40 Eu; A Chlordane - 0.5 - - 3 Sk -
Xn ; R: 22 ,
58-08-2 Caffeine Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn ; R: 22 ,
58-74-2 Papaverine Xn; R22 S: (2) - 22 Conc>=25%: Xn; R22 Eu - - - - - - - -
T; R25 Conc>=25%: T; R25; R20/21; R48/22; R64
Xn; R20/21-48/22 T; N >=10%Conc<25%: Xn; R22; R48/22; R64
Lindane [gamma-BHC or gamma-HCH; gamma- R64 R: 20/21-25-48/22-64-50/53 >=3%Conc<10%: Xn; R22; R64
58-89-9 1,2,3,4,5,6-Hexachlorocyclohexane] N; R50-53 S: (1/2-)36/37-45-60-61 >=1%Conc<3%: Xn; R64 Eu; A Lindane 0.008 0.1 - - - Sk -

T; R25 T; N
Xi; R36/38 R: 25-36/38-50/53 Conc>=5%: T; R25; R36/38
58-90-2 2,3,4,6-Tetrachlorophenol N; R50-53 S: (1/2-)26-28-37-45-60-61 >=0.5%Conc<5%: Xn; R22 Eu - - - - - - - -

Page 51
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R21/22
Xi; R41 Xn; N Conc>=10%: Xn; R21/22; R41; R43
Chlorocresol [4-Chloro-m-cresol; 4-Chloro-3- R43 R: 21/22-41-43-50 >=5%Conc<10%: Xn; R21/22; R36; R43
59-50-7 methylphenol] N; R50 S: (2-)26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R45; R68; R23/24/25;

R48/23/24/25; R36/38; R43
>=20%Conc<25% : T; R45; R68;
R48/23/24/25; R20/21/22; R36/38; R43
>=10%Conc<20%: T; R45; R68; R48/23/24/25;
Carc. Cat. 2; R45 R20/21/22; R43
Muta. Cat. 3; R68 T; N >=3%Conc<10%: T; R45; R68; R20/21/22;
T; R23/24/25-48/23/24/25 R: 45-23/24/25-36/38-43- R48/20/21/22; R43
Xi; R36/38 48/23/24/25-68-50 >=1%Conc<3%: T; R45; R68; R48/20/21/22;
Phenylhydrazinium chloride (Note: see also CAS R43 S: 53-45-61; R43
59-88-1 No. 100-63-0, 27140-08-5 and 52033-74-6) N; R50 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Xi
R: 36
60-00-4 Edetic acid (EDTA) Xi; R36 S: (2-)26 Conc>=20%: Xi; R36 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 50/53,
60-09-3 4-Aminoazobenzene [4-Phenylazoaniline] N; R50-53 S: 53 - 45 - 60 - 61 Conc>=0.1%: T; R45 Eu - - - - - - - -
F+; R12 R19
Xn; R22 F+; Xn
R66 R: 12-19-22-66-67
60-29-7 Diethyl ether [Ether; Ethyl ether] R67 S: (2-)9-16-29-33 Conc>=25%: Xn; R22 Eu;A Ethyl ether 400 1210 500 1520 - - -
60-34-4 Methyl hydrazine A Methyl hydrazine 0.01 0.019 - - 3 Sk -
Xn ; R: 40 ,
60-35-5 Acetamide Carc. Cat. 3; R40 S: (2) - 36/37 Conc>=1%: Xn; R40 Eu - - - - - - - -

Conc>=25%: T; R24/25; R48/25; R20; R43

T; R24/25; R48/25 >=10%Conc<25%: T; R48/25; R21/22; R43
Dimethoate (ISO) [O,O-Dimethyl Xn; R20 T ; R: 20 - 24/25 - 43 - 48/25 >=3%Conc<10%: Xn; R21/22; R48/22; R43
60-51-5 methylcarbamoylmethyl phosphorodithioate] R43 S: (2) - 36/37 >=1%Conc<3%: Xn; R48/22; R43 Eu/V - - - - - - - -
Repr. Cat. 2; R61 Conc>=10%: T; R61; R64; R48/22
Xn; R48/22 >=1%Conc<10%: T; R61; R64
60-56-0 Thiamazole R64 T; R: 61-48/22-64 >=0.5%Conc<1%: T; R61 V - - - - - - - -

Conc>=25%: T+; R40; R27; R25-48/25

>=10%Conc<25%: T+; R40; R27; R22; R48/25
T+; R27 T+ ; N ; R: 25 - 27 - 40 - >=7%Conc<10%: T+; R40; R27; R22-48/22
T; R25-48/25 48/25 - 50/53 , >=3%Conc<7%: T; R40; R24; R22-48/22
Carc. Cat. 3; R40 S: (1/2) - 22 - 36/37 - 45 - >=1%Conc<3%: T; R40; R24-48/22
60-57-1 Dieldrin (ISO) N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R21 Eu; A Dieldrin - 0.25 - - - Sk -
Repr.Cat.3; R63 Xn; N
Amitrole (ISO) [Aminotriazole; 1,2,4-Triazol-3- Xn; R48/22 R: 48/22-63-51/53 Conc>=10%: Xn; R48/22; R63
61-82-5 ylamine] N; R51-53 S: (2-)13-36/37-61 >=5%Conc<10%: Xn; R63 Eu; A Amitrole - 0.2 - - 3 - -

Conc>=25%: T; R25; R48/24/25; R34

T ; N ; R: 25 - 34 - 48/24/25 - >=10%Conc<25%: T; R48/24/25; R34; R22
T; R25-48/24/25 50/53, >=5%Conc<10%: Xn; R22; R48/21/22; R36/38
C; R34 S: (1/2) - 23 - 24/25 - 37 - >=3%Conc<5%: Xn; R22; R48/21/22
62-38-4 Phenylmercury acetate N; R50-53 45 - 60 - 61 >=1%Conc<3%: Xn; R48/21/22 Eu - - - - - - - -
Conc>=25%: T; R40; R68; R23/24/25;
Carc. Cat. 3; R40 R48/23/24/25; R41;R43
Muta.Cat.3; R68 T; N >=10%Conc<25%: T; R40; R68; R48/23/24/25;
T; R23/24/25-48/23/24/25 R: 23/24/25-40-41-43- R20/21/22; R41; R43
Xi; R41 48/23/24/25-68-50 >=1% Conc<10%: T; R40; R68; R48/23/24/25;
R43 S: (1/2-)26-27-36/37/39-45- R20/21/22; R43 Aniline &
62-53-3 Aniline N; R50 46-61-63 >=0.2%Conc<1%: Xn; R48/20/21/22 Eu; A homologues 2 7.6 - - - Sk -

Page 52
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 2; R45. T ; R: 45 - 22 - 36/38 -
Xn; R22. 52/53 , Conc>=25%: T; R45; R22; R36/38
Xi; R36/38 S: 53 - 45 - 61; >=20%Conc<25%: T; R45; R36/38
62-55-5 Thioacetamide R52-53 Note: E >=0.1%Conc<20%: T; R45 Eu - - - - - - - -
Carc. Cat. 3; R40
Repr. Cat. 3; R63 Xn ; N ; R: 22 - 40 - 63 - Conc>=25%: Xn; R40; R63; R22
Xn; R22 51/53 , >=5%Conc<25%: Xn; R40; R63
62-56-6 Thiourea [Thiocarbamide] N; R51-53 S: (2) - 36/37 - 61 >=1%Conc<5%: Xn; R40 Eu - - - - - - - -
Conc>=25%: T+; R26; R24/25; R43
T+; R26 >=7%Conc<25%: T+; R26; R21/22; R43
T; R24/25 T+; N >=3%Conc<7%: T; R23; R21/22; R43
Dichlorvos (ISO) [2,2-Dichlorovinyl dimethyl R43 R: 24/25-26-43-50 >=1%Conc<3%: T; R23; R43
62-73-7 phosphate] N; R50 S: (1/2-)28-36/37-45-61 >=0.1%Conc<1%: Xn; R20 Eu;A Dichlorvos (DDVP) 0.1 0.9 - - - Sk -
T + ; N ; R: 26/27/28 - 50, Conc>=7%: T+; R26/27/28
T+; R26/27/28 S: (1/2) - 13 - 22 - 36/37 - >=1%Conc<7%: T; R23/24/25 Sodium
62-74-8 Sodium fluoroacetate N; R50 45 - 61 >=0.1%Conc<1%: Xn; R20/21/22 Eu; A fluoroacetate - 0.05 - 0.15 - Sk -

Conc>=25%: T+; R45; R26; R25; R48/25

>=10%Conc<25%: T+; R45; R26; R48/25; R22
>=7%Conc<10%: T+; R45; R26; R22; R48/22
Carc. Cat. 2; R45 >=3%Conc<7%: T; R45; R23; R22; R48/22
T+; R26 T+; N >=1%Conc<3%: T; R45; R23; R48/22 N-
Dimethylnitrosoamine [N-Nitrosodimethylamine; T; R25-48/25 R: 45-25-26-48/25-51/53 >=0.1%Conc<1%: T; R45; R20 Nitrosodimethylami
62-75-9 Methanamine; N-Methyl-N-nitroso] N; R51-53 S: 53-45-61; Note: E >=0.001%Conc<0.1%; T; R45 Eu; A ne (d) - - - - 2 Sk -
Carc. Cat. 3; R40 Xn; N
Xn; R20/22 R: 20/22-40-50 Conc>=25%: Xn; R40; R20/22
63-25-2 Carbaryl (ISO) [1-Naphthyl methylcarbamate] N; R50 S: (2-)36/37-46-61 >=1%Conc<25%: Xn; R40 Eu;A Carbaryl - 5 - - - - -
Xn Conc>=25%: Xn; R22; R41
Xn; R22 R: 22-41 >=10%Conc<25%: Xi; R41
64-02-8 Tetrasodium ethylene diamine tetraacetate Xi; R41 S: (2-)26-39-46 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
F; R11 F; Xi
64-17-5 Ethanol [Ethyl alcohol] Xi; R36 R: 36 Conc>=20%: Xi; R36 N/Eu; A Ethyl alcohol 1000 1880 - - - - -
Conc>=25%: C; R35; R20/22; R37
>=20%Conc<25%: C; R35; R37
Xn; R20/22 >=10%Conc<20%: C; R35
C; R35 C >=5%Conc<10%: C; R34
64-18-6 Formic acid … % Xi; R37 R: 20/22-35-37 >=1%Conc<5%: Xi; R36/38 N; A Formic acid 5 9.4 10 19 - - -
C ; R: 10 - 35 , Conc>=90%: C; R35
R10. S: (1/2) - 23 - 26 - 45; >=25%Conc<90%: C; R34
64-19-7 Acetic acid ... % C; R35 Note: B >=10%Conc<25%: Xi; R36/38 Eu; A Acetic acid 10 25 15 37 - - -
Carc. Cat. 2; R45 T ; R: 45 - 46 - 20/21/22 - 34 Conc>=25%: T; R45; R46; R34; R20/21/22
Muta. Cat. 2; R46 , >=10%Conc<25%: T; R45; R46; R34
Xn; R20/21/22 S: 53 - 45 ; >=5%Conc<10%: T; R45; R46; R36/38
64-67-5 Diethyl sulphate C; R34 Note: E >=0.1%Conc<5%: T; R45; R46 Eu - - - - - - - -
Conc>=25%: T; R25; R35
>=10%Conc<25%: C; R35; R22
>=5%Conc<10%: C; R34; R22
T; R25 T ; C ; R: 25 - 35 , >=3%Conc<5%: Xn; R22; R36/38
64-69-7 Iodoacetic acid C; R35 S: (1/2) - 22 - 36/37/39 - 45 >=1%Conc<3%: Xi; R36/38 Eu - - - - - - - -
T+
R: 46-28 Conc>=7%: T+; R46; R28
Muta. Cat. 2; R46 S: 53-45 >=1%Conc<7%: T; R46; R25
64-86-8 Colchicine T+; R28 Note: E >=0.1%Conc<1%: T; R46; R22 Eu - - - - - - - -
Conc>=20%: Xi; R37/38; R41
Xi >=10%Conc<20%: Xi; R41
65-85-0 Benzoic acid Xi; R37/38-41 R: 37/38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

T; R23/24/25 T ; N ; R: 23/24/25 - 33 - Conc>=25%: T; R23/24/25; R33

2,3-Dinitrophenol(Note: see also CAS No 329-71-5; R33 51/53 >=3%Conc<25%: Xn; R20/21/22; R33
66-56-8 573-56-8; 577-71-9; & dinitrophenol, salts of) N; R50-53 S: (1/2) - 28 - 37 - 45 - 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
T; R25 T ; N ; R: 25 - 50/53, Conc>=25%: T; R25
66-71-7 1,10-Phenanthroline N; R50-53 S: (1/2) - 45 - 60 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T; R48/25 Conc>=25%: T; R48/25; R22
Dicoumarol [3,3'-Methylene bis(4-hydroxycoumarin); Xn; R22 T ; N ; R: 22 - 48/25 - 51/53, >=10%Conc<25%: T; R48/25
66-76-2 4,4'-Dihydroxy-3,3'-methylenebis(2H-chromen-2-one)] N; R51-53 S: (1/2) - 37 - 45 - 61 >=1%Conc<10%: Xn; R48/22 Eu - - - - - - - -
Muta. Cat. 3; R68 T+ ; N ; R: 61 - 28 - 51/53 - Conc>=7%: T+; R61; R68; R28
Repr. Cat. 2; R61 68, >=1%Conc<7%: T; R61; R68; R25
T+; R28 S: 53 - 45 - 61; >=0.5%Conc<1%: T; R61; R22
66-81-9 Cycloheximide N; R51-53 Note: E >=0.1%Conc<0.5%:Xn; R22 Eu - - - - - - - -

F; R11 F ; T ; R: 11 - 23/24/25 - Conc>=20%: T; R23/24/25; R39/23/24/25

T; R23/24/25 39/23/24/25, >=10%Conc<20%: T; R20/21/22; R39/23/24/25
67-56-1 Methyl alcohol [Methanol] T; R39/23/24/25 S: (1/2) - 7 - 16 - 36/37 - 45 >=3%Conc<10%: Xn; R20/21/22; R68/20/21/22 Eu; A Methyl alcohol 200 262 250 328 - Sk -
F; R11 F; Xi
Xi; R36 R: 11-36-67
67-63-0 Propan-2-ol [Isopropyl alcohol; Isopropanol] R67 S: (2-)7-16-24/25-26 Conc>=20%: Xi; R36 Eu;A Isopropyl alcohol 400 983 500 1230 - - -
F; R11
Xi; R36 F; Xi
R66 R: 11-36-66-67
67-64-1 Acetone [Propan-2-one; Propanone] R67 S: (2-)9-16-26-46 Conc>=20%: Xi; R36 Eu;A Acetone 500 1185 1000 2375 - - -
Xn; R22-48/20/22 Xn ; R: 22 - 38 - 40 - Conc>=20%: Xn; R40; R22-48/20/22; R38
Xi; R38 48/20/22 , >=5%Conc<20%: Xn; R40; R22-48/20/22
67-66-3 Trichloromethane [Chloroform] Carc. Cat. 3; R40 S: (2) - 36/37 >=1%Conc<5%: Xn; R40 Eu; A Chloroform 2 10 - - 3 Sk -

67-72-1 Hexachloroethane A Hexachloroethane 1 9.7 - - 3 - -

Conc>=25%: T+; R26; 24/25;R48/25

>=10%Conc<25%: T+; R26; R21/22; R48/25
>=7%Conc<10%: T+; R26; R21/22;R48/22
T+ >=3%Conc<7%: T; R23; R21/22; R48/22
T+; R26 R: 24/25-26-48/25 >=1%Conc<3%: T: R23; R48/22
67-97-0 Colecalciferol [Vitamin D3] T; R24/25-48/25 S: (1/2-)28-36/37-45 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -

Conc>25%: T; R23/25; R34; R21; R43

T; R23/25 >=10%Conc<25%: C; R20/22; R34; R43
Xn; R21 >=5%Conc<10%: Xn; R20/22; R36/38; R43
C; R34 T >=3%Conc<5%: Xn; R20/22; R43
68-11-1 Acetic acid, mercapto- [Thioglycolic acid] R43 R: 21-23/25-34-43 >=1%Conc<3%: Xi; R43 N; A Thioglycolic acid 1 3.8 - - - Sk -
Repr. Cat. 2; R61 T ; R: 61 - 20/21 - 36 , Conc>=25%: T; R61; R20/21; R36
Xn; R20/21 S: 53 - 45 ; >=20%Conc<25%: T; R61; R36 Dimethylformamid
68-12-2 Dimethyl formamide Xi; R36 Note: E >=0.5%Conc<20%: T; R61 Eu; A e 10 30 - - - Sk -
Conc>=25%: Xn; R22; R41
Xn; R22 Xn >=10%Conc<25%: Xi; R41
69-72-7 Benzoic acid, 2-hydroxy- Xi; R41 R: 22-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Carc. Cat. 2; R45 T; N
Xn; R20 R: 45-20-36/38-51/53 Conc>=25%: T; R45; R20; R36/38
Xi; R36/38 S: 53-45-61 >=20%Conc<25%: T; R45; R36/38
70-25-7 1-Methyl-3-nitro-1-nitrosoguanidine N; R51-53 Note: E >=0.01%Conc<20%: T; R45 Eu - - - - - - - -
T; N
2,2'-Methylenebis-(3,4,6-trichlorophenol) T; R24/25 R: 24/25-50/53 Conc>=2%: T; R24/25
70-30-4 [Hexachlorophene] N; R50-53 S: (1/2-)20-37-45-60-61 >=0.2%Conc<2%: Xn; R21/22 Eu - - - - - - - -
F; R11
Xi; R41
1-Propanol [Propan-1-ol; n-Propanol; R66 F; Xi Conc>=10%: Xi; R41
71-23-8 n-Propyl alcohol] R67 R: 11-41-66-67 >=5%Conc<10%: Xi; R36 N/Eu; A Propyl alcohol 200 492 250 614 - Sk -
R10 Conc>=25%: Xn; R22; R37/38; R41
Xn; R22 Xn >=20%Conc<25%: Xi; R37/38; R41
Xi; R37/38-41 R: 10-22-37/38-41-67 >=10%Conc<20%: Xi; R41 50 Peak 152 Peak
71-36-3 Butan-1-ol [n-Butanol; n-Butyl alcohol] R67 S: (2-)7/9-13-26-37/39-46 >=5%Conc<10%: Xi; R36 Eu;A n-Butyl alcohol limitation limitation - - - Sk -
R10 Xn
Xn; R20 R: 10-20-37/38 Conc>=25%: Xn; R20; R37/38
71-41-0 1-Pentanol(Note: see also CAS No. 584-02-1) Xi; R37/38 S: (1/2-)36/37-46 >=20%Conc<25%: Xi; R37/38 Eu - - - - - - - -

Page 54
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

F; R11 Conc>=10%: T; R45; R46; R48/23/24/25;

Carc. Cat. 1; R45 R36/38; R65
Muta. Cat. 2; R46 F; T >=5%Conc<10%: T; R45; R46; R48/23/24/25;
T; R48/23/24/25 R: 45-46-11-36/38- R36/38
Xn; R65 48/23/24/25-65 >=0.5%Conc<5%: T; R45; R46; R48/20/21/22
71-43-2 Benzene (gas) Xi; R36/38 S: 53-45; Note: E >=0.1%Conc<0.5%: T; R45; R46 Eu; A Benzene 1 3.2 - - 1 - -

F; R11 Conc>=20%: T; R45; R46; R48/23/24/25; R65;

Carc. Cat. 1; R45 R36/38
Muta. Cat. 2; R46 F; T >=10%Conc<20%: T; R45; R46; R48/23/24/25;
T; R48/23/24/25 R: 45-46-11-36/38- R65
Xn; R65 48/23/24/25-65 >=1%Conc<10%: T; R45; R46; R48/20/21/22
71-43-2 Benzene (liquid) Xi; R36/38 S: 53-45; Note: E >=0.1%Conc<1%: T; R45; R46 Eu; A Benzene 1 3.2 - - 1 - -
Carc. Cat. 2; R49
Muta. Cat. 3; R68
Repr. Cat. 2; R60 T; N Conc>=1%: T; R49; R60; R68; R42/43
R42/43 R: 49-60-42/43-68-50/53 >=0.5%Conc<1%: T; R49; R60
71-48-7 Cobalt acetate N; R50-53 S: 53-45-60-61 >=0.01%Conc<0.5%: T; R49 Eu - - - - - - - -
Xn ; N ; R: 20 - 59 ,
Xn; R20 S: (2) - 24/25 - 59 - 61 ; 1,1,1-
71-55-6 1,1,1-Trichloroethane [Methyl chloroform] N; R59 Note: F Conc>=25%: Xn; R20 Eu; A Trichloroethane 100 555 200 1110 - - -
Conc>=25%: T; R23/25; R33
T; R23/25 T ; R: 23/25 - 33 , >=3%Conc<25%: Xn; R20/22; R33
71-63-6 Digitoxin R33 S: (1/2) - 45 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
Endrin (ISO) [1,2,3,4,10,10-Hexachloro-6,7-epoxy- T+; R28 T+ ; N ; R: 24 - 28 - 50/53 , >=3%Conc<7%: T; R25; R21
1,4,4a,5,6,7,8,8a-octahydro-1,4:5,8- T; R24 S: (1/2) - 22 - 36/37 - 45 - >=1%Conc<3%: T; R25
72-20-8 dimethanonaphthalene] N, R50-53 60 - 61 >=0.1%Conc<1%: Xn; R22 Eu; A Endrin - 0.1 - - - Sk -
72-43-5 Methoxychlor A Methoxychlor - 10 - - - - -
N,N'-Diphenyl-p-phenylenediamine [N,N'-Diphenyl-l,4- Xi; R43 Xi ; R: 43 - 52/53,
74-31-7 benzenediamine] R52-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Asphyxiant
F+; R12, (see Chapter
74-82-8 Methane F+; R12 S: (2) - 9 - 16 - 33 Eu Methane - - - - - - 10)
Muta. Cat. 3; R68
T; R23/25
Xn; R48/20 T ; N ; R: 23/25 - 36/37/38 - Conc>=5%: T; R68; R23/25; R48/20;
Xi; R36/37/38 48/20 - 50 – 59 - 68 , R36/37/38
N; R50 S: (1/2) - 15 - 27 - 36/39 - >=1%Conc<5%: Xn; R68; R20/22
74-83-9 Bromomethane (Gas) [Methyl bromide] (Gas)] N; R59 38 - 45 - 59 - 61 >=0.5%Conc<1%: Xn; R20/22 Eu; A Methyl bromide 5 19 - - - Sk -

Conc>=25%: T; R68; R23/25; R48/20;

Muta. Cat. 3; R68 R36/37/38
T; R23/25 >=20%Conc<25%: Xn; R68; R20/22; R48/20;
Xn; R48/20 T ; N ; R: 23/25 - 36/37/38 - R36/37/38
Xi; R36/37/38 48/20 - 50 – 59 - 68 , >=10%Conc<20%: Xn; R68; R20/22; R48/20
N; R50 S: (1/2) - 15 - 27 - 36/39 - >=3%Conc<10%: Xn; R68; R20/22
74-83-9 Bromomethane (Liquid) [Methyl bromide (Liquid)] N; R59 38 - 45 - 59 - 61 >=1%Conc<3%: Xn; R68 Eu; A Methyl bromide 5 19 - - - Sk -
Asphyxiant
F+; R12, (see Chapter
74-84-0 Ethane F+; R12 S: (2) - 9 - 16 - 33 Eu Ethane - - - - - - 10)
F+
F+; R12 R: 12-67
74-85-1 Ethylene R67 S: (2-)9-16-33-46 Eu - - - - - - - -
R5 Asphyxiant
R6 F+; R5 - 6 – 12, (see Chapter
74-86-2 Acetylene [Ethyne] F+; R12 S: (2) - 9 - 16 - 33 Eu Acetylene - - - - - - 10)
F+; R12
Carc. Cat. 3; R40 F+ ; Xn ; R: 12 - 40 - 48/20 , Conc>=5%: Xn; R40; R48/20
74-87-3 Chloromethane [Methyl chloride] Xn; R48/20 S: (2) - 9 - 16 - 33 >=1%Conc<5%: Xn; R40 Eu; A Methyl chloride 50 103 100 207 - - -

Page 55
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Carc. Cat. 3; R40 Conc>=25%: T; R40; R23/25; R21; R37/38

Xn; R21 T ; R: 21 - 23/25 - 37/38 - 40 >=20%Conc<25%: Xn; R40; R20/22; R37/38
T; R23/25 , >=3%Conc<20%: Xn: R40; R20/22
74-88-4 Methyl iodide [Iodomethane] Xi; R37/38 S: (1/2) - 36/37 - 38 - 45 >=1%Conc<3%: Xn; R40 Eu; A Methyl iodide 2 12 - - 3 Sk -
F+; R12
Xn; R20 F+ ; Xn ; R: 12 - 20 - 37/38 -
Methylamine, in aqueous solution(Note: see also Xi; R37/38 41, Conc>=5%: Xn; R20; R37/38; R41
74-89-5 CAS No 75-50-3 & 124-40-3) R41 S: (2) - 16 - 26 - 39 >=0.5%Conc<5%: Xi; R36 Eu; A Methylamine (h) 10 13 - - - - -
T+; N
R: 26/27/28-50/53 Conc>=7%: T+; R26/27/28
T+; R26/27/28 S: (1/2-)7/9-16-36/37-38-45- >=1%Conc<7%: T; R23/24/25 Hydrogen cyanide 10 Peak 11 Peak
74-90-8 Hydrocyanic acid…% [Hydrogen cyanide…%] N; R50-53 60-61; Note: B >=0.1%Conc<1%: Xn; R20/21/22 Eu; A (h) limitation limitation - - - Sk -
F+ ; T+ ; N ; R: 12 - 26 -
F+; R12 50/53, Conc>=7%: T+; R26
T+; R26 S: (1/2) - 7/9 - 16 - 36/37 - >=1%Conc<7%: T; R23 Hydrogen cyanide 10 Peak 11 Peak
74-90-8 Hydrogen cyanide [Hydrocyanic acid] N; R50-53 38 - 45 - 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu; A (h) limitation limitation - - - Sk -
F+; R12 F+; T; N
T; R23 R: 12-23-50/53 Conc>=5%: T; R23
74-93-1 Methanethiol [Methyl mercaptan] N; R50-53 S: (2-)16-25-60-61 >=0.5%Conc<5%: Xn; R20 Eu; A Methyl mercaptan 0.5 0.98 - - - - -
Xn
Xn; R20 R: 20-52/53
74-95-3 Dibromomethane [Methane, dibromo] R52-53 S: (2-)24-61 Conc>=12.5%: Xn; R20 Eu - - - - - - - -
F; R11
Carc. Cat. 3; R40 F ; Xn ; R: 11 - 20/22 - 40, Conc>=25%: Xn; R40; R20/22
74-96-4 Bromoethane [Ethyl bromide] Xn; R20/22 S: (2) - 36/37 >=1%Conc<25%: Xn; R40 Eu; A Ethyl bromide 5 22 - - 3 Sk -
Chlorobromometh
74-97-5 Chlorobromomethane A ane 200 1060 - - - - -
Asphyxiant
F+; R12; (see Chapter
74-98-6 Propane F+; R12 S: (2) - 9 - 16 Eu Propane - - - - - - 10)
74-99-7 Methyl acetylene A Methyl acetylene 1000 1640 - - - - -

F+; R12 F+ ; Xn; R: 12 - 40 - 52/53,

Carc. Cat. 3; R40 S: (2) - 9 - 16 - 33 - 36/37 -
75-00-3 Chloroethane [Ethane, chloro; Ethyl chloride] R52-53 61: Conc>=1%: Xn; R40 Eu; A Ethyl chloride 1000 2640 - - - - -
F+; R12
Muta. Cat. 3; R68 F+; T Conc>=1%: T; R45; R68 Vinyl chloride,
75-01-4 Ethene, chloro [Vinyl chloride; Chloroethylene] Carc. Cat. 1; R45 R: 12-45-68 >=0.1%Conc<1%: T; R45 N/Eu; A monomer 5 13 - - 1 - -
F+; R12 F+ ; Xi ; R: 12 - 36/37 ,
75-04-7 Ethylamine Xi; R36/37 S: (2) - 16 - 26 - 29 Conc>=20%: Xi; R36/37 Eu; A Ethylamine 2 3.8 6 11 - - -
F; R11 F; Xn
Xn; R20/21/22 R: 11 - 20/21/22 - 36 Conc>=25%: Xn; R20/21/22; R36
75-05-8 Acetonitrile [Cyanomethane] Xi; R36 S: (1/2) - 16 - 36/37 >=20%Conc<25%: Xi; R36 Eu; A Acetonitrile 40 67 60 101 - Sk -
F+; R12
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: Xn; R40; R68; R22; R36/37
Xn; R22 Xn >=20%Conc<25%: Xn; R40; R68; R36/37
75-07-0 Acetaldehyde [Ethanal] Xi; R36/37 R: 12-22-36/37-40-68 >=1%Conc<20%: Xn; R40; R68 N/Eu; A Acetaldehyde 20 36 50 91 - - -
F; R11 F ; Xn ; N ; R: 11 - 20 -
Xn; R20 50/53,
75-08-1 Ethanethiol [Ethyl mercaptan] N; R50-53 S: (2) - 16 - 25 - 60 - 61 Conc>=25%: Xn; R20 Eu; A Ethyl mercaptan 0.5 1.3 - - - - -

Xn ; R: 40 ,
75-09-2 Dichloromethane [Methylene chloride] Carc. Cat. 3; R40 S: (2) - 23 - 24/25 - 36/37 Conc>=1%: Xn; R40 Eu; A Methylene chloride 50 174 - - 3 Sk -
Repr. Cat. 2; R61 T Conc>=5%: T; R61; R62
75-12-7 Formamide Repr. Cat. 3; R62 R 61-62 >=0.5%Conc<5%: T; R61 N; A Formamide 10 18 - - - Sk -
F; R11 F ; T ; R: 11 - 36/38 - 48/23 -
Repr. Cat. 3; R62-63 62 - 63 , Conc>=20%: T; R62; R63; R48/23; R36/38
T; R48/23 S: (1/2) - 16 - 33 - 36/37 - >=1%Conc<20%: T; R62; R63; R48/23
75-15-0 Carbon disulphide Xi; R36/38 45 >=0.2%Conc<1%: Xn; R48/20 Eu; A Carbon disulphide 10 31 - - - Sk -
F+; R12,
75-19-4 Cyclopropane F+; R12 S: (2) - 9 - 16 - 33 Eu - - - - - - - -

Page 56
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F; R15,
75-20-7 Calcium carbide F; R15 S: (2) - 8 - 43 Eu - - - - - - - -
F+; R12 R6
Carc. Cat. 2; R45 F+; T
Muta. Cat. 2; R46 R: 45-46-6-12-23-36/37/38 Conc>=5%: T; R45; R46; R23; R36/37/38
T; R23 S: 53-45 >=0.5%Conc<5%: T; R45; R46; R20
75-21-8 Ethylene oxide [Oxirane] Xi; R36/37/38 Note: E >=0.1%Conc<0.5%: T; R45; R46 Eu;A Ethylene oxide 1 1.8 - - 2 - -
T; R23
Xn; R22 T; N Conc>=25%: T; R23; R22; R36/38
Xi; R36/38 R: 22-23-36/38-51/53 >=20%Conc<25%: Xn; R20; R36/38
75-25-2 Bromoform [Tribromomethane] N; R51-53 S: (1/2-)28-45-63-61 >=3%Conc<20%: Xn; R20 Eu;A Bromoform 0.5 5.2 - - - Sk -
F; R11
Repr. Cat. 1; R60 F ; T ; R: 60 - 11 - 48/20 - 66
Xn; R48/20 S: 16 - 53 - 45; Conc>=10%: T; R60; R48/20
75-26-3 2-Bromopropane R66 Note: E >=0.5%Conc<10%: T; R60 Eu - - - - - - - -
F+; T
F+; R12 R: 45 - 46 - 12
Isobutane, (containing >=0.1% butadiene (203-450- Carc. Cat. 1; R45 S: 53 - 45
75-28-5 8))(Note: see also CAS No 106-97-8) Muta. Cat. 2; R46 Notes: C Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
F ; Xn ; R: 11 - 20/21/22,
F; R11 S: (2) - 9 - 29 ;
75-29-6 2-Chloropropane(Note: see also CAS No 540-54-5) Xn; R20/21/22 Note: C Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
F+; R12 F+; Xi ; R: 12 - 36/37/38 ,
75-31-0 2-Aminopropane [Isopropylamine] Xi; R36/37/38 S: (2) - 16 - 26 - 29 Conc>=20%: Xi; R36/37/38 Eu; A Isopropylamine 5 12 10 24 - - -
F; R11
Xn; R22 F; Xn
Xi; R36/37 R: 11-22-36/37-52/53 Conc>=20%: Xn; R22; R36/37
75-34-3 1,1-Dichloroethane [Ethane, 1,1-dichloro] R52-53 S: (2-)16-23-61 >=12.5%Conc<20%: Xn; R22 Eu; A 1,1-Dichloroethane 100 412 - - - Sk -
F+; Xn
F; R12 R: 12-20-40
Carc.Cat.3; R40 S: (2-)7-16-29-36/37-46; Conc>=12.5%: Xn; R40; R20
75-35-4 1,1-Dichloroethylene [Vinylidene chloride] Xn; R20 Note: D >=1%Conc<12.5%: Xn; R40 Eu; A Vinylidene chloride 5 20 20 79 - - -
F; R11
R14 F ; C ; R: 11 - 14 - 34, Conc>=10%: C; R34
75-36-5 Acetyl chloride C; R34 S: (1/2) - 9 - 16 - 26 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Dichlorofluorometh
75-43-4 Dichlorofluoromethane [FC-21] A ane 10 42 - - - - -
Conc>=5%: T+; R26; R34
>=1%Conc<5%: T+; R26; R36/37/38
T+ ; R: 26 - 34, >=0.5%Conc<1%: T; R23; R36/37/38
T+; R26 S: (1/2) - 9 - 26 - 36/37/39 - >=0.2%Conc<0.5%: T; R23
75-44-5 Phosgene [Carbonyl chloride] C; R34 45 >=0.02%Conc<0.2%: Xn; R20 Eu; A Phosgene 0.02 0.08 0.06 0.25 - - -
Chlorodifluorometh
75-45-6 Chlorodifluoromethane A ane 1000 3540 - - - - -
75-47-8 Iodoform A Iodoform 0.6 10 - - - - -

F+ ; C ; R: 12 - 20/22 - 34,
F+; R12 S: (1/2) - 3 - 16 - 26 - 29 - Conc>=15%: C; R34; R20/22
Trimethylamine ....% (Note: see also CAS No 74-89- Xn; R20/22 36/37/39 - 45; >=10%Conc<15%: C; R34
75-50-3 5 & 124-40-3) C; R34 Note: B >=5%Conc<10%: Xi; R36/37/38 Eu; A Trimethylamine (h) 10 24 15 36 - - -
F+; R12
Xn; R20 F+ ; Xn ; R: 12 - 20 - 37/38 -
Trimethylamine(Note: see also CAS No 74-89-5 & Xi; R37/38 41, Conc>=5%: Xn; R20; R37/38; R41
75-50-3 124-40-3) R41 S: (2) - 16 - 26 - 39 >=0.5%Conc<5%: Xi; R36 Eu; A Trimethylamine (h) 10 24 15 36 - - -
R5-10 Xn ; R: 5 - 10 - 22 ,
75-52-5 Nitromethane Xn; R22 S: (2) - 41 Conc>=12.5%: Xn; R22 Eu; A Nitromethane 20 50 - - - - -

Conc>=10%: T+; R45; R26/27/28; R41

F; R11 >=7%Conc<10%: T+; R45; R26/27/28; R36
Carc. Cat. 2; R45 >=5%Conc<7%: T; R45; R23/24/25; R36
T+; R26/27/28 F; T+; N >=1%Conc<5%: T; R45; R23/24/25
Xi; R41 R: 45-11-26/27/28-41-51/53 >=0.1%Conc<1%: T; R45; R20/21/22
75-55-8 2-Methylaziridine [Propyleneimine] N; R51-53 S: 53-45-61; Note: E >=0.01%Conc<0.1%: T; R45 Eu; A Propylene imine 2 4.7 - - 2 Sk -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F+; R12 Conc>=25%: T; R45; R46; R34; R20/21/22;
Carc. Cat. 2; R45 R37
Muta. Cat. 2; R46 >=20%Conc<25%: T; R45; R46; R34; R37
Oxirane, methyl- [Propylene oxide; 1,2- Xn; R20/21/22 >=10%Conc<20%: T; R45; R46; R34
Epoxypropane; C; R34 F+; T >=5%Conc<10%: T; R45; R46; R36/38
75-56-9 Methyloxirane] Xi; R37 R: 12-45-46-20/21/22-34-37 >=0.1%Conc<5%: T; R45; R46 N/Eu; A Propylene oxide 20 48 - - 2 - -
Difluorodibromome
75-61-6 Difluorodibromomethane [Dibromodifluoromethane] A thane 100 858 - - - - -
Trifluorobromomet
75-63-8 Bromotrifluoromethane [Trifluorobromomethane] A hane 1000 6090 - - - - -
Conc>=25%: Xn; R20; R37; R41
F; R11 >=20%Conc<25%: Xi; R37; R41
2-Propanol, 2-methyl- [2-Methylpropan-2-ol; tert-Butyl Xn; R20 F; Xn >=10%Conc<20%: Xi; R41
75-65-0 alcohol] Xi; R37-41 R: 11-20-37-41 >=5%Conc<10%: Xi; R36 N/Eu; A tert-Butyl alcohol 100 303 150 455 - - -
Trichlorofluoromet 1000 Peak 5620 Peak
75-69-4 Trichlorofluoromethane A hane limitation limitation - - - - -
Dichlorodifluorome
75-71-8 Dichlorodifluoromethane A thane 1000 4950 - - - - -

Conc>=10%: T+; R40; R61; R62; R26/27/28;

R48/23/25
>=7%Conc<10%: T+; R40; R61; R62;
R26/27/28; R48/20/22
>=5%Conc<7%: T; R40; R61; R62; R23/24/25;
Carc. Cat. 3; R40 R48/20/22
Repr. Cat. 1; R61 >=1%Conc<5%: T; R40; R61; R23/24/25;
Repr. Cat. 3; R62 T+ R48/20/22
T+; R26/27/28 R: 61-26/27/28-40-48/23/25- >=0.5%Conc<1%: T; R61; R20/21/22 Tetramethyl lead
75-74-1 Plumbane, tetramethyl- T; R48/23/25 62 >=0.1%Conc<0.5%: X N (as Pb) - 0.15 - - - Sk -
C ; R: 34 , Conc>=10%: C; R34
75-75-2 Methanesulphonic acid C; R34 S: (1/2) - 26 - 36 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
F; R11 F ; Xi ; R: 11 - 36/37/38,
75-78-5 Dimethyldichlorosilane Xi; R36/37/38 S: (2) Conc>=20%: Xi; R36/37/38 Eu - - - - - - - -
R14
F; R11 F; Xi ; R: 11 - 14 - 36/37/38 ,
75-79-6 Trichloro(methyl)silane [Methyltrichlorosilane] Xi; R36/37/38 S: (2) - 26 - 39 Conc>=1%: Xi; R36/37/38 Eu - - - - - - - -
F; R11
Xn; R65 F; Xn; N
Xi; R38 R: 11-38-65-67-51/53
2,2-Dimethylbutane(Note: see also CAS No. 107-83- R67 S: (2-)9-16-29-33-61-62 Conc>=20%: Xn; R65; R38 Hexane, other
75-83-2 5, 96-14-0 & 79-29-8) N; R51-53 Note: C >=10%Conc<20%: Xn; R65 Eu;A isomers 500 1760 1000 3500 - - -
F; R11 F; Xn
Xn; R20 R: 11-20-37/38 Conc>=25%: Xn; R20; R37/38
75-85-4 2-Methylbutan-2-ol [tert-Pentanol] Xi; R37/38 S: (2-)46 >=20%Conc<25%: Xi; R37/38 Eu - - - - - - - -

T+ ; N ; R: 26/27/28 - 50/53, Conc>=7%: T+; R26/27/28

2-Cyanopropan-2-ol [Acetone cyanohydrin; 2-Hydroxy T+; R26/27/28 S: (1/2) - 7/9 - 27 - 45 - 60 - >=1%Conc<7%: T; R23/24/25
75-86-5 2-methylpropionitrile] N; R50-53 61 >= 0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
Xi Conc>=20%: Xi; R41; R38 2,2-
Dalapon [2,2-Dichloropropionic acid](Note: see also Xi; R38-41 R: 38-41-52/53 >=10%Conc<20%: Xi; R41 Dichloropropionic
75-99-0 CAS No. 127-20-8) R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu;A acid 1 5.8 - - - - -
Carc. Cat. 3; R40 T; N
T; R48/23 R: 40-48/23-51/53 Conc>=1%: T; R40; R48/23
76-01-7 Pentachloroethane N; R51-53 S: (1/2-)23-36/37-45-61 >=0.2%Conc<1%: Xn; R48/20 Eu - - - - - - - -
C; N
R: 35-50/53 Conc>=10%: C; R35
C; R35 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: C; R34 Trichloroacetic
76-03-9 Trichloroacetic acid N; R50-53 61 >=1%Conc<5%: Xi; R36/37/38 Eu; A acid 1 6.7 - - - - -
C
Xn; R20 R: 20-35-52/53 Conc>=10%: C; R20; R35
C; R35 S: (1/2-)9-26-27-28-45-61; >=5%Conc<10%: C; R34
76-05-1 Trifluoroacetic acid . . . % R52-53 Note: B >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R26; R48/23; R22; R36/37/38

>=20%Conc<25%: T+; R26; R48/23;
R36/37/38
T+; R26 >=10%Conc<20%: T+; R26; R48/23
T; R48/23 T+ ; R: 22 - 26 – 36/37/38 - >=7%Conc<10%: T+; R26; R48/20
Xn; R22 48/23 >=1%Conc<7%: T; R23; R48/20
76-06-2 Trichloronitromethane [Chloropicrin] Xi; R36/37/38 S: (1/2) - 36/37 - 38 - 45 >=0.1Conc<1%: Xn; R20 V/Eu; A Chloropicrin 0.1 0.67 - - - - -

1,1,1,2-Tetrachloro-
76-11-9 1,1,1,2-Tetrachloro-2,2-difluoroethane A 2,2-difluoroethane 500 4170 - - - - -

1,1,2,2-Tetrachloro-
76-12-0 1,1,2,2-Tetrachloro-1,2-difluoroethane A 1,2-difluoroethane 500 4170 - - - - -
1,1,2-Trichloro-
1,2,2-
76-13-1 1,1,2-Trichloro-1,2,2-trifluoroethane A trifluoroethane 1000 7670 1250 9590 - - -
Dichlorotetrafluoro
76-14-2 Dichlorotetrafluoroethane [Cryofluorane] A ethane 1000 6990 - - - - -
Chloropentafluoroe
76-15-3 Chloropentafluoroethane A thane 1000 6320 - - - - -
Camphor,
76-22-2 Camphor, synthetic [Bornan-2-one] A synthetic 2 12 3 19 - - -
T; R24/25 T ; N ; R: 24/25 - 33 - 40 -
Carc. Cat. 3; R40 50/53 , Conc>=25%: T; R40; R24/25; R33
Heptachlor (ISO) [1,4,5,6,7,8,8-Heptachloro- R33 S: (1/2) - 36/37 - 45 - 60 - >=3%Conc<25%: Xn: R40; R21/22; R33
76-44-8 3a,4,7,7a-tetrahydro-4,7-methanoindene] N; R50-53 61 >=1%Conc<3%: Xn; R40; R33 Eu; A Heptachlor (h) - 0.5 - - - Sk -

Conc>=25%: T+; R40; R63; R26; R24/25;

R48/23; R37/38; R41
>=20%Conc<25%: T+; R40; R63; R26; R48/23;
R21/22; R37/38; R41
>=10%Conc<20%: T+; R40; R63; R26; R48/23;
R21/22; R41
>=7%Conc<10%: T+; R40; R63; R26; R21/22;
Carc. Cat. 3; R40 R48/20; R36
Repr. Cat. 3; R63 T+; N >=5%Conc<7%: T; R40; R63; R23; R21/22;
T+; R26 R: 24/25-26-37/38-40-41- R48/20; R36
T; R24/25-48/23 48/23-63-50/53 >=3%Conc<5%: T; R40; R23; R21/22; R48/20 Tin, organic
Xi; R37/38-41 S: (1/2-)26-28-36/37/39-45- >=1%Conc<3%: T; R40; R23; R48/20 compounds (as
76-87-9 Fentin hydroxide (ISO) [Triphenyltin hydroxide] N; R50-53 60-61 >=0.1%Conc<1%: Xn; R20 Eu;A Sn) - 0.1 - 0.2 - Sk -
Carc. Cat. 2; R45 T
Muta. Cat. 3; R68 R: 45-62-68 Conc>=5%: T; R45; R62; R68
77-09-8 Phenolphthalein Repr. Cat. 3; R62 S: 53-45 >=1%Conc<5%: T; R45; R68 Eu - - - - - - - -
Conc>=25%: T+; R26; R24; R34; R22
>=10%Conc<25%: T+: R26; R21; R34
T+; R26 >=7%Conc<10%: T+; R26; R21; R36/38
T; R24 T+ ; N ; R: 22 - 24 - 26 - 34 - >=5%Conc<7%: T; R23; R21; R36/38
Xn; R22 50/53, >=3%Conc<5%: T; R23; R21
Hexachlorocyclopentadiene [1,3-Cyclopentadiene, C; R34 S: (1/2) - 25 - 39 - 45 - 53 - >=1%Conc<3%: T; R23 Hexachlorocyclope
77-47-4 1,2,3,4,5,5-hexachloro] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu; A ntadiene 0.01 0.11 - - - - -
F; R11
3a,4,7,7a-Tetrahydro-4,7-methanoindene [4,7- Xn; R20/22 F ; Xn ; N ; R: 11 - 20/22 -
Methano-1H-indene, 3a,4,7,7a-tetrahydro; Xi; R36/37/38 36/37/38 - 51/53, Conc>=25%: Xn; R20/22; R36/37/38
77-73-6 Dicyclopentadiene] N; R51-53 S: (2) - 36/37 - 61 >=20% Conc<25%: Xi; R36/37/38 Eu; A Dicyclopentadiene 5 27 - - - - -

Page 59
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R45; R68; R26; R25; R34;

R43
>=10%Conc<25%: T+; R45; R68; R26; R22;
R34; R43
>=7%Conc<10%:T+; R45; R68; R26; R22;
R36/37/38; R43
Carc. Cat. 2; R45 >=5%Conc<7%:T; R45; R68; R23; R22;
Muta. Cat. 3; R68 R36/37/38; R43
T+; R26 >=3%Conc<5%:T; R45; R68; R23; R22; R43
T; R25 T+ >=1%Conc<3%:T; R45; R68; R23; R43
C; R34 R: 45-25-26-34-43-68 >=0.1%Conc<1%: T; R45; R68; R20
77-78-1 Dimethyl sulphate R43 S: 53-45; Note: E >=0.01%Conc<0.1%:T; R45-68 Eu; A Dimethyl sulphate 0.1 0.52 - - 2 Sk -
Xi
77-92-9 1,2,3-Propanetricarboxylic acid, 2-hydroxy- Xi; R36/37/38 R: 36/37/38 Conc>=20%: Xi; R36/37/38 N - - - - - - - -

Conc>=10%: T+; R40; R61; R62; R26/27/28;

R48/23/25
>=7%Conc<10%: T+; R40; R61; R62;
R26/27/28; R48/20/22
>=5%Conc<7%: T; R40; R61; R62; R23/24/25;
Carc. Cat. 3; R40 R48/20/22
Repr. Cat. 1; R61 >=1%Conc<5%: T; R40; R61; R23/24/25;
Repr. Cat. 3; R62 T+ R48/20/22
T+; R26/27/28 R: 61-26/27/28-40-48/23/25- >=0.5%Conc<1%: T; R61; R20/21/22 Tetraethyl lead (as
78-00-2 Plumbane, tetraethyl- T; R48/23/25 62 >=0.1%Conc<0.5%: X N Pb) - 0.1 - - - Sk -
R10
Xn; R20 Xn ; R: 10 - 20 - 36/37, Conc>=25%: Xn; R20; R36/37
78-10-4 Ethyl silicate [Tetraethyl orthosilicate] Xi; R36/37 S: (2) >=20%Conc<25%: Xi; R36/37 Eu; A Ethyl silicate 10 85 - - - - -
E; R3,
78-11-5 Pentaerythritol tetranitrate [PETN] E; R3 S: (2) - 35 Eu - - - - - - - -

E; R3 E; C
1-Hydroperoxycyclohexyl 1-hydroxycyclohexyl O; R7 R: 3-7-22-34 Conc>=25%: C; R34; R22;
peroxide(Note: see also CAS No. 2407-94-5, 2699-11-C; R34 S: (1/2-)3/7-14-36/37/39-45 >=10%Conc<25%: C; R34
78-18-2 8 & 12262-58-7) Xn; R22 Note: C >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -
Tricresyl phosphate (o-o-o, o-o-m, o-o-p, o-m-m, o-m-
p, o-p-p) [Triorthocresyl phosphate; Tritolyl T; N
phosphate](Note: For Tricresyl phosphate to have UN R: 39/23/24/25-51/53
No. 2574 there must be present greater than 3% of T; R39/23/24/25 S: (1/2-)20/21-28-45-61; Conc>=1%: T; R39/23/24/25 Triorthocresyl
78-30-8 the ortho-isomer) N; R51-53 Note: C >=0.2%Conc<1%: Xn; R68/20/21/22 Eu; A phosphate - 0.1 - - - Sk -
Xn; N
Tricresyl phosphate Xn; R21/22 R: 21/22-51/53
78-32-0 (m-m-m, m-m-p, m-p-p, p-p-p) [Tritolyl phosphate] N; R51-53 S: (2-)28-61; Note: C Conc>=5%: Xn; R21/22 Eu - - - - - - - -
Conc>=25%: T+; R26/28; R24
>=7%Conc<25 %: T+; R26/28; R21
T+; R26/28 T+; N >=3%Conc<7%: T; R23/25; R21
Dioxathion (ISO) [1,4-Dioxan-2,3-diyl-O,O,O',O'- T; R24 R: 24-26/28-50/53 >=1%Conc<3%: T; R23/25
78-34-2 tetraethyl di(phosphorodithioate)] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=0.1% Conc<1%: Xn; R20/22 Eu; A Dioxathion - 0.2 - - - Sk -
Xn ; R: 22 ,
78-40-0 Triethyl phosphate Xn; R22 S: (2) - 25 Conc>=25%: Xn; R22 Eu - - - - - - - -

Conc>=25%: T; R48/23/24; R20/21/22; R38

T; R48/23/24 >=20%Conc<25%: T; R48/23/24; R38
Xn; R20/21/22 T ; R: 20/21/22 - 38 - >=10%Conc<20%: T; R48/23/24
78-48-8 S,S,S Tributyl phosphorotrithioate Xi; R38 48/23/24 >=1%Conc<10%: Xn; R48/20/21 V - - - - - - - -

Menazon [Phosphorodithioic acid, S-[(4,6-diamino- Xn; R22 Xn ; R: 22 - 52/53

78-57-9 1,3,5-triazin-2-yl)methyl] O,O-dimethyl ester] R52-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Carc. Cat. 3; R40 Xn ; R: 21/22 - 36/37 - 40, Conc>=25%: Xn; R40; R21/22; R36/37
Xn; R21/22 S: (2) - 13 - 23 - 36/37/39 - >=10%Conc<25%: Xn; R40; R36/37 5 Peak 28 Peak
78-59-1 Isophorone [3,5,5-Trimethylcyclohex-2-enone] Xi; R36/37 46 >=1%Conc<10%: Xn; R40 Eu; A Isophorone limitation limitation - - - - -

Page 60
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
E; R2
F; R11 E ; Xn ; R: 2 - 11 - 20/22 -
Xn; R20/22 52/53,
78-67-1 2,2'-Dimethyl-2,2'-azodipropiononitrile [ADZN] R52-53 S: (2) - 39 - 41 - 47 - 61 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
F+; R12
Xn; R65 F+; Xn; N
R66 R: 12-65-66-67-51/53
Isopentane [2-Methylbutane](Note: see also CAS No. R67 S: (2-)9-16-29-33-61-62
78-78-4 109-66-0) N; R51-53 Note: C Conc>=10%: Xn; R65 Eu - - - - - - - -
F+; R12
Carc. Cat. 2; R45
Muta. Cat. 3; R68 Conc>=20%: T; R45; R62; R63; R68; R37
Repr. Cat. 3; R62-63 >=5%Conc<20%: T; R45; R62; R63; R68
1,3-Butadiene, 2-methyl- [Isoprene (stabilized); 2- Xi; R37 F+; T >=1%Conc<5%: T; R45; R68
78-79-5 Methyl-1,3-butadiene] R52-53 R: 12-45-37-62-63-68-52-53 >=0.1%Conc<1%: T; R45 N/Eu - - - - - - - -

R10 Xi Conc>=20%: Xi; R37/38; R41

Xi; R37/38-41 R: 10-37/38-41-67 >=10%Conc<20%: Xi; R41
78-83-1 2-Methylpropan-1-ol [Iso-butanol; Isobutyl alcohol] R67 S: (2-)7/9-13-26-37/39-46 >=5%Conc<10%: Xi; R36 Eu;A Isobutyl alcohol 50 152 - - - - -
F; R11 F ; Xn ; R: 11 - 20/22, Propylene
78-87-5 1,2-Dichloropropane [Propylene dichloride] Xn; R20/22 S: (2) - 16 - 24 Conc>=25%: Xn; R20/22 Eu; A dichloride 75 347 110 508 - - -

F; R11 Conc>=25%: Xn; R68; R20/21/22; R37/38; R41

Muta. Cat. 3; R68 F ; Xn ; R: 11 - 20/21/22 - >=20%Conc<25%: Xn; R68; R37/38; R41
Xn; R20/21/22 37/38 - 41 - 52/53 - 68, >=10%Conc<20%: Xn; R68; R41
Xi; R37/38-41 S: (2) - 9 - 16 - 23 - 26 - >=5%Conc<10%: Xn; R68; R36
78-88-6 2,3-Dichloropropene [2,3-Dichloropropylene] R52-53 36/37/39 - 61 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -
Conc>=25%: C; R35; R21/22
R10. >=10%Conc<25%: C; R35
Xn; R21/22. C ; R: 10 - 21/22 - 35 , >=5%Conc<10%: C; R34
78-90-0 1,2-Propylene diamine C; R35 S: (1/2) - 26 - 37/39 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

Xi
R10 R: 10-36/37-67
Butan-2-ol [sec-Butyl alcohol](Note: see also CAS Xi; R36/37 S: (2-)7/9-13-24/25-26-46
78-92-2 No. 4221-99-2, 14898-79-4 & 15892-23-6) R67 Note: C Conc>=20%: Xi; R36/37 Eu;A sec-Butyl alcohol 100 303 - - - - -
F; R11
Xi; R36 F; Xi
R66 R: 11-36-66-67 Methyl ethyl
78-93-3 Butanone [Ethyl methyl ketone; Methyl ethyl ketone] R67 S: (2-)9-16 Conc>=20%: Xi; R36 Eu;A ketone (MEK) 150 445 300 890 - - -
1 Peak 3.8 Peak
78-95-5 Chloroacetone A Chloroacetone limitation limitation - - - Sk -
Conc>=25%: C; R34; R21/22
2-Propanol, 1-amino- [1-Aminopropan-2-ol; Xn; R21/22 C >=10%Conc<25%: C; R34
78-96-6 Isopropanolamine] C; R34 R: 21/22-34 >=5%Conc<10%: Xi; R36/38 N - - - - - - - -
Carc.Cat.3; R40 Xn Conc>=5%: Xn; R20/21/22; R40
Xn; R20/21/22 R: 20/21/22-40-66 >=1%Conc<5%: Xn; R40 1,1,2-
79-00-5 1,1,2-Trichloroethane R66 S: (2-)9-36/37-46 Eu; A Trichloroethane 10 55 - - - Sk -
Carc. Cat. 2; R45
Muta. Cat. 3; R68 T
R67 R: 45 - 36/38 - 52/53 - 67 - Conc>=20%: T; R45; R68; R36/38
Xi; R36/38 68 >=1%Conc<20%: T; R45; R68
79-01-6 Ethene, trichloro [Trichloroethylene; Trichloroethene] R52-53 S: 23 - 36/37 - 53 - 45 - 61 >=0.1%Conc<1%: T; R45 Eu/N; A Trichloroethylene 10 54 40 216 - Sk -
F; R11
R14 F ; C ; R: 11 - 14 - 34, Conc>=10%: C; R34
79-03-8 Propionyl chloride [Propanoyl chloride] C; R34 S: (1/2) - 9 - 16 - 26 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R23/24/25; R48/23; R35; R29

>=10%Conc<25%: T; R48/23; R35; R20/21/22;
R14 R29
R29 >=5%Conc<10%: C; R34; R20/21/22; R48/20;
T; R23/24/25 T ; C ; N ; R: 14 - 29 - R29
T; R48/23 23/24/25 - 35 - 48/23 - 50, >=3%Conc<5%: Xn; R20/21/22; R48/20;
C; R35 S: (1/2) - 7/8 - 9 - 26 - R36/38; R29 Chloroacetyl
79-04-9 Chloroacetyl chloride N; R50 36/37/39 - 45 - 61 >=1%Conc<3%: Xn; R48/20; R36/38; R29 Eu; A chloride 0.05 0.23 0.15 0.69 - Sk -

Conc>=25%: T; R45; R46; R62; R25; R21;

R48/25; R48/20/21; R36/38; R43
>=20%Conc<25%: T; R45; R46; R62; R22;
R48/25; R48/20/21; R36/38; R43
>=10%Conc<20%: T; R45; R46; R62; R22;
Carc. Cat. 2; R45 R48/25; R48/20/21; R43
Muta. Cat. 2; R46 >=5%Conc<10%: T; R45; R46; R62; R22;
Repr. Cat. 3; R62 T R48/22; R43
T; R25-48/25 R: 45 - 46 - 21 - 25 - 36/38 - >=3%Conc<5%: T; R45; R46; R22; R48/22;
Xn; R21-48/20/21 43 - 48/20/21 - 48/25 - 62 R43
Xi; R36/38 S: 53 - 45 ; >=1%Conc<3%: T; R45; R46; R48/22; R43
79-06-1 Acrylamide [Prop-2-enamide] R43 Notes: D; E >=0.1%Conc<1%: T; R45; R46 Eu/N; A Acrylamide - 0.03 - - 2 Sk -
Conc>=25%: T; R62; R25; R43
Repr. Cat. 3; R62 >=5%Conc<25%; Xn; R62; R22; R43
T; R25 T ; R: 25 - 43 - 62, >=3%Conc <5%: Xn; R22; R43
79-07-2 2-Chloroacetamide R43 S: (1/2) - 22 - 36/37 - 45 >=0.1%Conc <3%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R23/24/25; R35; R43

T; R23/24/25 >=10%Conc<25%: C; R35; R20/21/22; R43
C; R35 T; C; N >=5%Conc<10%: C; R34; R20/21/22; R43
R43 R: 23/24/25-35-43-50 >=3%Conc<5%: Xn; R20/21/22; R36/38; R43
79-08-3 Bromoacetic acid N; R50 S: (1/2-)26-36/37/39-45-61 >=1%Conc<3%: Xi; R36/38; R43 Eu - - - - - - - -
C ; R: 34 ,
S: (1/2) - 23 - 36 - 45; Conc>=25%: C; R34
79-09-4 Propionic acid ... % C; R34 Note: B >=10%Conc<25%: Xi; R36/37/38 Eu; A Propionic acid 10 30 - - - - -
R10 C; N Conc>=25%: C; R35; R20/21/22
Xn; R20/21/22 R: 10-20/21/22-35-50 >=10%Conc<25%: C; R35
C; R35 S: (1/2-)26-36/37/39-45-61; >=5%Conc<10%: C; R34
79-10-7 Acrylic acid [Prop-2-enoic acid] N; R50 Note: D >=1%Conc<5%: Xi; R36/37/38 Eu; A Acrylic acid 2 5.9 - - - Sk -

T; N Conc>=25%: T; R23/24/25; R34

T; R23/24/25 R: 23/24/25-34-50 >=10%Conc<25%: C; R34; R20/21/22
C; R34 S: (1/2-)26-36/37/39-45-61- >=5%Conc<10%: Xn; R20/21/22; R36/37/38 Monochloroacetic
79-11-8 Chloroacetic acid N; R50 63 >=3%Conc<5%: Xn; R20/21/22 Eu;A acid 0.3 1.2 - - - Sk -
C: R34 Conc>=25%: C; R34; R20/22; R41; R37
Xn; R20/22 C ; R: 20/22 - 34 - 37 - 41 >=20%Conc<25%:Xi; R36/37/38
79-14-1 Glycolic acid Xi; R41; R36/38; R37 S7 - 36/37/39 >=10%Conc<20%: Xi; R36/38 N - - - - - - - -
T ; R: 61
79-16-3 N-Methylacetamide Repr. Cat. 2; R61 S: 53 - 45 Conc>=0.5%: T; R61 Eu - - - - - - - -
F; R11
Xi; R36 F; Xi
R66 R: 11-36-66-67
79-20-9 Methyl acetate R67 S: (2-)16-26-29-33 Conc>=20%: Xi; R36 Eu;A Methyl acetate 200 606 250 757 - - -
R10
O; R7
Xn; R20/21/22 O; C; N
C; R35 R: 7-10-20/21/22-35-50 Conc>=10%: C; R35; R20/21/22
N; R50 S: (1/2-)3/7-14-36/37/39-45- >=5%Conc<10%: C; R34
79-21-0 Peracetic acid . . . % 61 >=1%Conc<5%: Xi; R36/37/38 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: T+; R26; R34; R21/22
>=10%Conc<25%: T+; R26; R34
F; R11 F; T+ >=7%Conc<10%: T+; R26; R36/38
T+; R26 R: 11-21/22-26-34 >=5%Conc<7%: T; R23; R36/38
Xn; R21/22 S: (1/2)-14-26-28-36/37/39- >=1%Conc<5%: T; R23
79-22-1 Methyl chloroformate C; R34 45-46-63 >=0.1% Conc<1%: Xn; R20 Eu - - - - - - - -
R10. Xn ; R: 10 - 20/22 ,
79-24-3 Nitroethane Xn; R20/22 S: (2) - 9 - 25 - 41 Conc>=12.5%: Xn; R20/22 Eu; A Nitroethane 100 307 - - - - -
Conc>=20%: T+; R26; R36
T+; R26 T+ >=7%Conc<20%: T+; R26
1,1,2,2-Tetrabromoethane [Ethane 1,1,2,2- Xi; R36 R: 26-36-52/53 >=1%Conc<7%: T; R23 1,1,2,2-
79-27-6 tetrabromo] R52-53 S: (1/2-)24-27-45-61 >=0.1%Conc<1%: Xn; R20 Eu; A Tetrabromoethane 1 14 - - - - -
F; R11
Xn; R65 F; Xn; N
Xi; R38 R: 11-38-65-67-51/53
2,3-Dimethylbutane(Note: see also CAS No. 107-83- R67 S: (2-)9-16-29-33-61-62 Conc>=20%: Xn; R65; R38 Hexane, other
79-29-8 5, 96-14-0 & 75-83-2) N; R51-53 Note: C >=10%Conc<20%: Xn; R65 Eu;A isomers 500 1760 1000 3500 - - -
F ; C ; R: 11 - 35 , Conc>=10%: C; R35
F; R11 S: (1/2) - 16 - 23 - 26 - 36 - >=5%Conc<10%: C; R34
79-30-1 Isobutyryl chloride C; R35 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Xn ; R: 21/22 ,
79-31-2 Isobutyric acid Xn; R21/22 S: (2) Conc>=25%: Xn; R21/22 Eu - - - - - - - -
T+; N Conc>=7%: T+; R26/27
T+; R26/27 R: 26/27-51/53 >=1%Conc<7%: T; R23/24 1,1,2,2-
79-34-5 1,1,2,2-Tetrachloroethane N; R51-53 S: (1/2-)38-45-61 >=0.1%Conc<1%: Xn; R20/21 Eu; A Tetrachloroethane 1 6.9 - - - Sk -
Conc>=10%: C; R35
C; R35 C ; N ; R: 35 - 50, >=5%Conc<10%: C; R34
79-36-7 Dichloroacetyl chloride N; R50 S: (1/2) - 9 - 26 - 45 - 61 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

C Conc>=25%: C; R21/22; R35

R: 21/22 - 35 >=10%Conc<25%: C; R35
Xn; R21/22 S: (1/2) - 26 - 36/37/39 - 45; >=5%Conc<10%: C; R34
79-41-4 Methacrylic acid [2-Methylpropenoic acid] C; R35 Note: D >=1%Conc<5%: Xi; R36/37/38 Eu; A Methacrylic acid 20 70 - - - - -
Conc>=10%: C; R35
C; R35 C ; N ; R: 35 - 50, >=5%Conc<10%: C; R34
79-43-6 Dichloroacetic acid N; R50 S: (1/2) - 26 - 45 - 61 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

Carc. Cat. 2; R45 T Conc>=25%: T; R45; R23; R22; R36/37/38

T; R23 R: 45 - 22 - 23 - 36/37/38 >=20%Conc<25%: T; R45; R20; R36/37/38 Dimethyl
Xn; R22 S: 53 - 45 ; >=3%Conc<20%: T; R45; R20 carbamoyl chloride
79-44-7 Dimethylcarbamoyl chloride Xi; R36/37/38 Note: E >=0.001%Conc<3%: T; R45 Eu; A (d) - - - - 2 - -
R10
Carc. Cat. 2; R45 Conc>=25%: T; R45; R68; R20/22
Muta. Cat. 3; R68 T >=1%Conc<25%: T; R45; R68
79-46-9 Propane, 2-nitro- [2-Nitropropane] Xn; R20/22 R: 10-45-20/22-68 >=0.1%Conc<1%: T; R45 N/Eu; A 2-Nitropropane 10 36 - - 2 - -
N
Tetrabromobisphenol-A [2,2',6,6'-Tetrabromo-4,4'- R: 50/53
79-94-7 isopropylidenediphenol] N; R50-53 S: 60-61 Eu - - - - - - - -
Repr. Cat. 3; R62 Conc>=20%: Xn; R62; R37; R41; R43
Xi; R37-41 Xn >=10%Conc<20%: Xn; R62; R41; R43
R43 R: 37-41-43-62-52 >=5%Conc<10%: Xn; R62; R36; R43
80-05-7 Bisphenol A [4,4'-Isopropylidenediphenol] R52 S: (2-)26-36/37-39-46-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; N
Xn; R22 R: 22 - 51/53
80-06-8 Chlorfenethol (ISO) [1,1-Bis (4-chlorophenyl) ethanol] N; R51-53 S: (2) - 36 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn ; R: 22 ,
80-08-0 Dapsone [4,4'-Diamino diphenyl sulfone] Xn; R22 S: (2) - 22 Conc>=25%: Xn; R22 Eu - - - - - - - -

O; R7 O; T; N
T; R23 R: 7-21/22-23-34-48/20/22- Conc>=25%: T; R23; R21/22; R48/20/22; R34
Cumene hydroperoxide Xn; R21/22-48/20/22 51/53 >=10%Conc<25%: C; R34; R20; R48/20/22
[alpha, alpha-Dimethylbenzyl hydroperoxide; Cumyl C; R34 S: (1/2-)3/7-14-36/37/39-45- >=3%Conc<10%: Xn; R20; R37/38; R41
80-15-9 hydroperoxide] N; R51-53 50-61 >=1%Conc<3%: Xi; R36/37 Eu - - - - - - - -

Page 63
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R22
Chlorfenson (ISO) [4-Chlorophenyl 4- Xi; R38 Xn ; N ; R: 22 - 38 - 50/53, Conc>=25%: Xn; R22; R38
80-33-1 chlorobenzenesulphonate] N; R50-53 S: (2) - 37 - 60 - 61 >=20%Conc<25%; Xi; R38 Eu - - - - - - - -
Xn; R22
Xi; R36 Xn ; N ; R: 22 - 36 - 51/53, Conc>=25%: Xn; R22; R36
80-38-6 Fenson [4-Chlorophenyl benzenesulphonate] N; R51-53 S: (2) - 24 - 26 - 61 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
O ; Xi ; N ; R: 7 - 36/38 -
O; R7 51/53,
Bis (alpha,alpha-dimethylbenzyl) peroxide [Dicumyl Xi; R36/38 S: (2) - 3/7 - 14 - 36/37/39 -
80-43-3 peroxide] N; R51-53 61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
O; R7 O ; C ; R: 7 - 20 - 34 , Conc>=25%: C; R34; R20
8-p-Menthyl hydroperoxide [p-Menthane C; R34 S: (1/2) - 3/7 - 14 - 36/37/39 >=10%Conc<25%: C; R34
80-47-7 hydroperoxide] Xn; R20 - 45 >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -
F; Xi
F; R11 R: 11 - 37/38 - 43
Methyl methacrylate [Methyl 2-methylprop-2-enoate; Xi; R37/38 S: (2) - 24 - 37 - 46; Conc>=20%: Xi; R37/38; R43 Methyl
80-62-6 Methyl 2-methylpropenoate] R43 Note: D >=1%Conc<20%: Xi; R43 Eu; A methacrylate 50 208 100 416 - - -
Musk ketone [3,5-Dinitro-2,6-dimethyl-4-tert- Xn; N
butylacetophenone; 4'-tert-Butyl-2',6'-dimethyl-3',5'- Carc. Cat. 3; R40 R: 40-50/53
81-14-1 dinitroacetophenone] N; R50-53 S: (2-)36/37-46-60-61 Conc>=1%: Xn; R40 Eu - - - - - - - -
Carc. Cat. 3; R40 E; Xn; N
E; R2 R: 2-40-50/53
81-15-2 Musk xylene [5-tert-Butyl-2,4,6-trinitro-m-xylene] N; R50-53 S: (2-)36/37-46-60-61 Conc>=1%: Xn; R40 Eu - - - - - - - -
Warfarin [4-Hydroxy-3-(3-oxo-1- Repr. Cat. 1; R61 T ; R: 61 - 48/25 - 52/53, Conc>=10%: T; R61; R48/25
phenylbutyl)coumarin](Note: see also CAS No 5543- T; R48/25 S: 53 - 45 - 61; >=1%Conc<10%: T; R61; R48/22
81-81-2 57-7 & 5543-58-8) R52-53 Note: E >=0.5%Conc<1%: T; R61 Eu; A Warfarin - 0.1 - - - - -
Coumachlor (ISO) [3-(1-(4-Chlorophenyl)-3-oxobutyl)- Xn; R48/22 Xn ; R: 48/22 - 52/53,
81-82-3 4-hydroxycoumarin] R:52-53 S: (2) - 37 - 61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Conc>=10%: T+; R28; R48/23/24/25
>=7%Conc<10%: T+; R28; R48/20/21/22
T+; R28 T+ ; R: 28 - 48/23/24/25, >=1%Conc<7%: T; R25; R48/20/21/22
82-66-6 Diphacinone (ISO) [2-Diphenylacetylindan-1,3-dione] T; R48/23/24/25 S: (1/2) - 36/37 - 45 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
Xi; N
R43 R: 43-50/53 Pentachloronitrobe
82-68-8 Quintozene (ISO) [Pentachloronitrobenzene] N; R50-53 S: (2-)13-24-37-60-61 Conc>=1%: Xi; R43 Eu; A nzene - 0.5 - - - - -
E; Xn
E; R3 R4 R: 3-4-20/21/22
82-71-3 2,4,6-Trinitroresorcinol [Styphnic acid] Xn; R20/21/22 S: (2-)35-36/37 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Conc>=25%: T; R25; R48/25
>=10%Conc<25%: T; R48/25; R22
T; R25-48/25 T ; N ; R: 25 - 48/25 - 50/53, >=3%Conc<10%: Xn; R22; R48/22
83-26-1 Pindone (ISO) [2-Pivaloylindan-1,3-dione] N; R50-53 S: (1/2) - 37 - 45 - 60 - 61 >=1%Conc<3%: Xn; R48/22 Eu; A Pindone - 0.1 - - - - -
T; R24 T ; N ; R: 22 - 24 - 50/53,
Dipropyl 6,7-methylenedioxy-1,2,3,4-tetrahydro-3- Xn; R22 S: (1/2) - 36/37 - 45 - 60 - Conc>=25%: T; R24; R22
83-59-0 methylnaphthalene-1,2-dicarboxylate [Propylisome] N; R50-53 61 >=3%Conc<25%: Xn; R21 Eu - - - - - - - -
T ; N ; R: 25 - 36/37/38 -
(2R,6aS,12aS)-1,2,6,6a,12,12a-Hexahydro-2- T; R25 50/53, Conc>=25%: T; R25; R36/37/38
isopropenyl-8,9-dimethoxychromeno[3,4-b]furo[2,3- Xi; R36/37/38 S: (1/2) - 22 - 24/25 - 36 - >=20%Conc<25%: Xn; R22; R36/37/38 Rotenone
83-79-4 h]chromen-6-one [Derris; Rotenone] N; R50-53 45 - 60 - 61 >=3%Conc<20%: Xn; R22 Eu; A (commercial) - 5 - - - - -
84-66-2 Diethyl phthalate A Diethyl phthalate - 5 - - - - -
T
Repr. Cat. 2; R61 R: 61-62 Conc>=25%: T; R61; R62
84-69-5 Diisobutyl phthalate Repr. Cat. 3; R62 S: 53-45 >=5%Conc<25%: Xn; R62 Eu - - - - - - - -
Repr. Cat. 2; R61
Repr. Cat. 3; R62 T ; N ; R: 61 - 50 - 62 Conc>=5%: T; R61; R62
84-74-2 Dibutyl phthalate [DBP] N; R50 S: 53 - 45 - 61 >=0.5%Conc<5%: T; R61 Eu; A Dibutyl phthalate - 5 - - - - -

Page 64
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R26; R48/25; R22;

R36/37/38; R43
T+; R26 >=20%Conc<25%: T+; R26; R48/25;
T; R48/25 T+ ; N ; R: 22 - 26 - R36/37/38; R43
Xn; R22 36/37/38 - 43 - 48/25 - >=10%Conc<20%: T+; R26; R48/25; R43
Xi; R36/37/38 50/53, >=7%Conc<10%: T+; R26; R48/22; R43
Diquat dibromide(Note: see also CAS No 4032-26-2 R43 S: (1/2) - 28 - 36/37/39 - 45 - >=1%Conc<7%: T; R23; R48/22; R43
85-00-7 & 94021-76-8) N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu; A Diquat - 0.5 - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53,
85-34-7 Chlorfenac (ISO) [2,3,6-Trichlorophenylacetic acid] N; R51-53 S: (2) - 36 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Cyclohexane-1,2-dicarboxylic anhydride Xn ; R: 41 - 42/43 , Conc>=10%: Xn; R42/43; R41

[Hexahydrophthalic anhydride](Note: see also CAS Xi; R41 S: (2) - 23 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
85-42-7 No 13149-00-3 & 14166-21-3) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -

1,2,3,6-Tetrahydrophthalic anhydride [1,3-

Isobenzofurandione; Cyclohex-4-ene-1,2-dicarboxylic
anhydride](Note: see also CAS No 935-79-5 , 2426- Xn ; R: 41 - 42/43 - 51/53 ,
02-0 & 26266-63-7. To use UN No. 2698 requires Xi; R41 S: (2) - 22 - 24 - 26 - 37/39 - Conc>=10%: Xn; R42/43; R41
the 1,2,3,6-tetrahydrophthalic anhydride to have more Xn; R42/43 61; >=5%Conc<10%: Xn; R42/43; R36
85-43-8 than 0.05% maleic anhydride present) R51-53 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -

Conc>=25%: Xn; R22; R42/43; R41; R37/38

Xn; R22 Xn ; R: 22 - 37/38 - 41 - >=20%Conc<25%: Xn; R42/43; R41; R37/38
Phthalic anhydride(Note: To use UN No. 2214 Xi; R37/38 42/43, >=10%Conc<20%: Xn; R42/43; R41
requires the phthalic anyhydride to have more than R41 S: (2) - 23 - 24/25 - 26 - >=5%Conc<10%: Xn; R42/43; R36
85-44-9 0.05% of maleic anyhydride present.) Xn; R42/43 37/39 - 46 >=1%Conc<5%: Xn; R42/43 Eu; A Phthalic anhydride 1 6.1 - - - Sen -
Repr. Cat. 2; R61 T; N
Repr. Cat. 3; R62 R: 61-62-50/53 Conc>=5%: T; R61; R62
85-68-7 Benzyl butyl phthalate [BBP] N; R50-53 S: 53-45-60-61 >=0.5%Conc<5%: T; R61 Eu - - - - - - - -
Conc>=25%: T+; R26/28; R24; R43
T+; R26/28 T+ ; N ; R: 24 - 26/28 - 43 - >=7%Conc<25%: T+: R26/28; R21; R43
T; R24 50/53, >=3%Conc<7%: T; R23/25; R21; R43
Azinphos methyl (ISO) [O,O-Dimethyl 4- Xi; R43 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<3%: T; R23/25; R43
86-50-0 oxobenzotriazin-3-ylmethyl phosphorodithioate] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu; A Azinphos-methyl - 0.2 - - - Sk -
Conc>=7%: T+; R40, R28
T+; R28 T+ ; R: 28 - 40 , >=1%Conc<7%: T; R40, R25
86-88-4 ANTU (ISO) [1-Naphthylthiourea] Carc. Cat. 3; R40 S: (1/2) - 25 - 36/37 - 45 >=0.1%Conc<1%: Xn; R22 Eu; A ANTU - 0.3 - - - - -
Carc. Cat. 3; R40
Xn; R20/21/22 Xn ; N ; R: 20/21/22 - 37/38 - Conc25>=%: Xn; R40; R20/21/22; R37/38
Xi; R37/38 40 - 51/53 >=20%Conc<25%: Xn; R40; R37/38
87-62-7 2,6-Xylidine [2,6-Dimethylaniline] N; R51-53 S: (2)23 - 25 - 36/37 - 61 >=1%Conc<20%: Xn; R40 Eu - - - - - - - -
Muta. Cat. 3; R68 Xn
Xn; R20/21/22 R: 20/21/22-68-52/53 Conc>=10%: Xn; R68; R20/21/22
87-66-1 1,2,3-Trihydroxybenzene [Pyrogallol] R52-53 S: (2-)36/37-61 >=1%Conc<10%: Xn; R68 Eu - - - - - - - -
Hexachlorobutadie
87-68-3 Hexachlorobutadiene A ne 0.02 0.21 - - 3 Sk -

Conc>=25%: T+; R40; R26; R24/25; R36/37/38

>=20%Conc<25%: T+; R40; R26; R21/22;
Carc. Cat. 3; R40 R36/37/38
T+; R26 T+ ; N ; R: 24/25 - 26 - >=7%Conc<20%: T+; R40; R26; R21/22
T; R24/25 36/37/38 - 40 - 50/53 , >=3%Conc<7%: T; R40; R23; R21/22
Xi; R36/37/38 S: (1/2) - - 22 - 36/37 - 45 - >=1%Conc<3%: T; R40; R23
87-86-5 Pentachlorophenol N; R50-53 52 - 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu; A Pentachlorophenol - 0.5 - - - Sk -
O; R8
Xn; R22
R31 O ; Xn ; N ; R: 8 - 22 - 31 -
Symcloe [Trichloroisocyanuric acid; Trichloro-1,3,5- Xi; R36/37 36/37 - 50/53, Conc>=25%: Xn; R22; R36/37; R31
87-90-1 triazinetrione] N; R50-53 S: (2) - 8 - 26 - 41 - 60 - 61 >=20%Conc<25%: Xi; R36/37; R31 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R36/38; R43
4-Chloro-3,5-dimethylphenol [Chloroxylenol](Note: Xi; R36/38 R: 22 - 36/38 - 43 >=20%Conc<25%: Xi; R36/38; R43
88-04-0 see also CAS No 1321-23-9) R43 S: (2) - 24 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Xn; R22 Xn ; N ; R: 22 - 36/38 - 40 - Conc>=25%: Xn; R40; R22; R36/38
Xi; R36/38 50/53, >=20% Conc<25%: Xn; R40; R36/38
88-06-2 2,4,6-Trichlorophenol N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<20%: Xn; R40 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=25%: Xn; R40, R20/22; R36/37/38
Diethylcarbamoyl chloride [Carbamic chloride, Xn; R20/22 Xn; R: 20/22 - 36/37/38 - 40, >=20%Conc<25%: Xn; R40; R36/37/38
88-10-8 diethyl] Xi; R36/37/38 S: (2) - 26 - 36/37 >=1%Conc<20%: Xn; R40 Eu - - - - - - - -

Conc>=25%: Xn; R40; R20/21/22; R48/20;

R37; R41
Xn ; R: 20/21/22 - 37 - 40 - >=20%Conc<25%: Xn; R40; R48/20; R37; R41
Carc. Cat. 3; R40 41 - 48/20 >=10%Conc<20%: Xn; R40; R48/20; R41
Xn; R20/21/22-48/20 S: 25 - 36/37/39 - 41 - 51; >=5%Conc<10%: Xn; R40; R36
88-12-0 1-Vinyl-2-pyrrolidone Xi; R37-41 Note: D >=1%Conc<5%: Xn; R40 N - - - - - - - -
Carc. Cat. 2; R45
Muta. Cat. 2; R46
Repr. Cat. 3; R62 T; N Conc>=25%: T; R45; R46; R62; R22
Xn; R22 R: 45-46-22-62-51/53 >=5%Conc<25%: T; R45; R46; R62
88-72-2 2-Nitrotoluene N; R51-53 S: 53-45-61; Note: E >=0.1%Conc<5%: T; R45; R46 Eu; A Nitrotoluene 2 11 - - - Sk -
Carc. Cat. 2; R45
Muta. Cat. 2; R46
Repr. Cat. 3; R62 T; N Conc>=25%: T; R45; R46; R62; R22
Xn; R22 R: 45-46-22-62-51/53 >=5%Conc<25%: T; R45; R46; R62
88-72-2 2-Nitrotoluene N; R51-53 S: 53-45-61; Note: E >=0.1%Conc<5%: T; R45; R46 Eu; A Nitrotoluene 2 11 - - - Sk -
Carc. Cat. 2; R45
Muta. Cat. 2; R46
Repr. Cat. 3; R62 T; N Conc>=25%: T; R45; R46; R62; R22
Xn; R22 R: 45-46-22-62-51/53 >=5%Conc<25%: T; R45; R46; R62
88-72-2 2-Nitrotoluene N; R51-53 S: 53-45-61; Note: E >=0.1%Conc<5%: T; R45; R46 Eu; A Nitrotoluene 2 11 - - - Sk -

T ; R: 23/24/25 - 33 - 52/53 ,
T; R23/24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R23/24/25; R33
o-Nitroaniline(Note: see also CAS No 99-09-2 & 100- R33 61 ; >=3%Conc<25%: Xn; R20/21/22; R33
88-74-4 01-6) R52-53 Note: C >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
R44
T; R24/25 Conc>=25%: T; R61; R62; R24/25; R36
Repr. Cat. 2; R61 T ; N ; R: 61 - 62 - 24/25 - >=20%Conc<25%: T; R61; R62; R21/22; R36
Repr. Cat. 3; R62 36 - 44 - 50/53, >=5%Conc<20%: T; R61; R62; R21/22
Xi; R36 S: 53 - 45 - 60 - 61 ; >=3%Conc<5%: T; R61; R21/22
88-85-7 Dinoseb [6-sec-Butyl-2,4-dinitrophenol] N; R50-53 Note: E >=0.5%Conc<3%: T; R61 Eu - - - - - - - -
E ; T+ ; N ; R: 2 - 26/27/28 -
E; R2 50/53, Conc>=7%: T+; R26/27/28
T+; R26/27/28 S: (1/2) - 28 - 35 - 36/37 - >=1%Conc<7%: T; R23/24/25
88-88-0 2-Chloro-1,3,5-trinitrobenzene N; R50-53 45 - 60 - 61 >=0.1%Conc<1%; Xn; R20/21/22 Eu - - - - - - - -
E; T
E; R3 R4 R: 3-4-23/24/25 Conc>=25%: T; R23/24/25
88-89-1 2,4,6-Trinitrophenol [Picric acid] T; R23/24/25 S: (1/2-)28-35-36/37-45 >=3%Conc<25%: Xn; R20/21/22 Eu;A Picric acid - 0.1 - - - - -
Conc>=10%: Xn; R42/43; R41
Benzene-1,2:4,5-tetracarboxylic dianhydride Xi; R41 Xn ; R: 41 - 42/43 , >=5%Conc<10%: Xn; R42/43; R36
89-32-7 [Pyromellitic dianhydride] Xn; R42/43 S: (2) - 22 - 24 - 26 - 37/39 >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -

89-72-5 o-sec-Butyl phenol A o-sec-Butylphenol 5 31 - - - Sk -

Xn; R22 C ; R: 22 - 34 - 51/53, Conc>=25%: C; R34; R22
C; R34 S: (1/2) - 2 - 26 - 28 - >=10%Conc<25%: C; R34
89-83-8 Thymol [2-Isopropyl-5-methylphenol] N; R51-53 36/37/39 - 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
C ; R: 34 , Conc>=10%: C; R34
89-98-5 2-Chlorobenzaldehyde [o-Chlorobenzaldehyde] C; R34 S: (1/2) - 26 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Conc>=25%: T; R45; R68; R23/24/25
>=3%Conc<25%: T; R45; R68; R20/21/22
Carc. Cat. 2; R45 T >=1%Conc<3%: T; R45; R68
Muta Cat. 3; R68 R: 45-23/24/25-68 >=0.1%Conc<1%: T; R45
90-04-0 o-Anisidine [2-Methoxyaniline] T; R23/24/25 S: 53-45; Note: E Eu - - - - - - - -
Xn; R22. Xn ; R: 22 - 36/38 , Conc>=25%: Xn; R22; R36/38
90-05-1 Guaiacol Xi; R36/38 S: (2) - 26 >=20% Conc<25%: Xi; R36/38 Eu - - - - - - - -

Page 66
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: Xn; R21/22; R37/38; R41
>=20%Conc<25%: Xi; R37/38; R41
Xn; R21/22 Xn ; R: 21/22 - 37/38 - 41 , >=10%Conc<20%: Xi; R41
90-15-3 1-Naphthol Xi; R37/38-41 S: (2) - 22 - 26 - 37/39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Carc. Cat. 3; R40
Xn; R22 Xn ; R: 22 - 40 - 52/53, Conc>=25%: Xn; R40; R22
90-41-5 Biphenyl-2-ylamine [2-Aminobiphenyl] R52-53 S: (2) - 36/37 - 61 >=1%Conc<25%: Xn; R40 Eu - - - - - - - -
Biphenyl-2-ol [2-Hydroxybiphenyl; 2-Phenylphenol Xi; R36/37/38 Xi ; N ; R: 36/37/38 - 50 ,
90-43-7 (ISO)] N; R50 S: (2) - 22 - 61 Conc>=20%: Xi; R36/37/38 Eu - - - - - - - -
Conc>=25%: Xn; R22; R36/38
Xn; R22 Xn ; R: 22 - 36/38 , >=20% Conc<25%: Xi; R36/38
90-72-2 2,4,6-Tris(dimethylaminomethyl)phenol Xi; R36/38 S: (2) - 26 - 28 Eu - - - - - - - -
Conc>=10%: T;R45; R68; R41
Carc.Cat.2; R45 T >=5%Conc<10% : T; R45; R68; R36
4,4'Bis(dimethylamino)benzophenone Muta.Cat.3; R68 R: 45-41-68 >=1%Conc<5%: T; R45; R68
90-94-8 [Michler's Ketone] Xi; R41 S: 53-45 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Carc. Cat. 3; R40
T+; R26 T+ Conc>=20%: T+; R40; R26; R36/37/38; R42/43
Toluene-2,6-di-isocyanate [2-Methyl-m-phenylene Xi; R36/37/38 R: 26-36/37/38-40-42/43- >=7%Conc<20%: T+; R40; R26; R42/43
diisocyanate](Note: see also CAS No. 584-84-9 and R42/43 52/53 >=1% Conc<7%: T; R40; R23; R42/43 Isocyanates, all
91-08-7 26471-62-5) R52-53 S: (1/2-)23-36/37-45-61 >=0.1%Conc<1%: Xn; R20; R42 Eu; A (as-NCO) - 0.02 - 0.07 - Sen -
Carc. Cat.3; R40 Xn; N
Xn; R22 R: 22-40-50/53 Conc>=25%: Xn; R40; R22
91-20-3 Naphthalene N; R50-53 S: (2-)36/37-46-60-61 >=1%Conc<25%: Xn; R40 Eu; A Naphthalene 10 52 15 79 - - -
Carc. Cat. 2; R45
Muta. Cat. 3; R68 T; N Conc>=25%: T; R45; R68; R21/22; R36/38
Xn; R21/22 R: 45-21/22-36/38-68-51/53 >=20%Conc<25%: T; R45; R68; R36/38
Xi; R36/38 S: 53-45-61 >=1%Conc<20%: T; R45; R68
91-22-5 Quinoline N; R51-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
T ; R: 45 - 22 ,
Carc. Cat. 2; R45 S: 53 - 45 ; Conc>=25%: T; R45; R22
91-23-6 2-Nitroanisole Xn; R22 Note: E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
Ethoxyquin [6-Ethoxy-1,2-dihydro-2,2,4- Xn ; R: 22 ,
91-53-2 trimethylquinoline] Xn; R22 S: (2 ) - 24 Conc>=25%: Xn; R22 Eu - - - - - - - -

Carc. Cat. 1; R45 T; N

Xn; R22 R: 45-22-51/53 Conc>=25%: T; R45; R22
91-59-8 2-Naphthylamine [2-Napthalenamine] N; R51-53 S: 53-45-61; Note: E >=0.01%Conc<25%: T; R45 Eu; A 2-Naphthylamine - (P) - - - 1 - -
T; R23/24/25 T; N
R33 R: 23/24/25-33-51/53 Conc>=5%: T; R23/24/25; R33
91-66-7 N,N-Diethylaniline [Biphenyl-4,4'-ylenediamine] N; R51-53 S: (1/2-)28-37-45-61 >=1%Conc<5%: Xn; R20/21/22; R33 Eu - - - - - - - -
6-Phenyl-1,3,5-triazine-2,4-diamine
[Benzoguanamine; 6-Phenyl-1,3,5-triazine-2,4- Xn; R22 Xn ; R: 22 - 52/53,
91-76-9 diyldiamine] R52-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dichloro- [3,3'- Carc. Cat. 2; R45 3,3'-
Dichlorobenzidine; 3,3'-Dichlorobiphenyl-4,4'- Muta. Cat. 3; R68 T; N Conc>=1%: T; R45; R68 Dichlorobenzidine
91-94-1 ylenediamine]] N; R50-53 R: 45-68-50-53 >=0.1%Conc<1%: T; R45 N/Eu; A (d) - - - - 2 Sk -
T
Biphenyl-3,3',4,4'-tetrayltetraamine Carc. Cat. 2; R45 R: 45-68 Conc>=1%: T;R45; R68
91-95-2 [Diaminobenzidine] Muta. Cat. 3; R68 S: 53-45 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Conc>=7%: T+; R26/28
T+ ; R: 26/28 , >=1%Conc<7%: T; R23/25
92-13-7 Pilocarpine T+; R26/28 S: (1/2) - 25 - 45 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53,
92-43-3 1-Phenyl-3-pyrazolidone N; R51-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Xi; R36/37/38 Xi ; N ; R: 36/37/38 - 50/53 ,

92-52-4 Diphenyl [Biphenyl] N; R50-53 S: (2) - 23 - 60 - 61 Conc>=20%: Xi; R36/37/38 Eu; A Biphenyl 0.2 1.3 - - - - -
T ; R: 45 - 22 ,
Carc. Cat. 1; R45 S: 53 - 45 ; Conc>=25%: T; R45; R22
92-67-1 Biphenyl-4-ylamine [Xenylamine; 4-Aminobiphenyl] Xn; R22 Note: E >=0.1%Conc<25%: T; R45 Eu; A 4-Aminodiphenyl (P) - - - 1 Sk -
92-84-2 Phenothiazine A Phenothiazine - 5 - - - Sk -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Carc. Cat. 1; R45 T; N

Benzidine [1,1'-Biphenyl-4,4'-xydiamine; 4,4'- Xn; R22 R: 45-22-50/53 Conc>=25%: T; R45; R22
92-87-5 Diaminobiphenyl; Biphenyl-4,4'-ylenediamine] N; R50-53 S: 53-45-60-61; Note: E >=0.01%Conc<25%: T; R45 Eu; A Benzidine -(P) - - - 1 Sk -
Carc. Cat. 2; R45 T ; N ; R: 45 - 51/53,
92-93-3 4-Nitrobiphenyl [4-Nitrodiphenyl] N; R51-53 S: 53 - 45 - 61 Conc>=0.1%: T; R45 Eu; A 4-Nitrodiphenyl - (P) - - - 1 - -
Conc>=25%: T; R25; R34
>=10%Conc<25%: C; R34; R22
4-Amino-N,N-diethylaniline [N,N-Diethyl-p- T; R25 T ; R: 25 - 34 , >=5%Conc<10%: Xn; R22; R36/38
93-05-0 phenylendiamine] C; R34 S: (1/2) - 26 - 36 - 45 >=3%Conc<5%: Xn; R22 Eu - - - - - - - -
Conc>=25 %: Xn; R22; R38; R41
Mecoprop (ISO) [2-(4-Chloro-o-tolyoxy)propionic Xn; R22 Xn; N >=20%Conc<25%: Xi; R38; R41
acid; 2-(4-Chloro-2-methylphenoxy)-propionic Xi; R38-41 R: 22-38-41-50/53 >=10%Conc<20%: Xi; R41
93-65-2 acid](Note: see also CAS No. 7085-19-0) N; R50-53 S: (2-)13-26-37/39-60-61 >=5%Conc<10 %: Xi; R36 Eu - - - - - - - -
Xn; N
Xn; R21/22 R: 21/22 - 36/38 - 51/53
Xi; R36/38 S: (2) - 26 - 28 - 36/37/39 - Conc>=25%: Xn; R21/22; R36/38
93-71-0 Allidochlor (ISO) [N,N-Diallylchloroacetamide] N; R51-53 61 >=20%Conc<25%: Xi; R36/38 Eu - - - - - - - -
Xn; R22
Fenoprop (ISO) [2-(2,4,5-Trichlorophenoxy)propionic Xi; R38 Xn ; N ; R: 22 - 38 - 50/53, Conc>=25%: Xn; R22; R38
93-72-1 acid] N; R50-53 S: (2) - 37 - 60 - 61 >=20%Conc<25%: Xi; R38 Eu - - - - - - - -
Xn ; R: 22 ,
93-75-4 Thioquinox [2-Thio-1,3-dithiolo[4,5,B)quinoxaline] Xn; R22 S: (2) - 24 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 36/37/38 -
Xi; R36/37/38 50/53, Conc>=25%: Xn; R22; R36/37/38
93-76-5 2,4,5-T (ISO) [2,4,5-Trichlorophenoxy acetic acid] N; R50-53 S: (2) - 24 - 60 - 61 >=20%Conc<25%: Xi; R36/37/38 Eu; A 2,4,5-T - 10 - - - - -
E; R3
O; R7 E; Xi
Xi; R36 R: 3-7-36-43 Conc>=20%: Xi; R36; R43
94-36-0 Dibenzoyl peroxide [Benzoyl peroxide] R43 S: (2-)3/7-14-36/37/39 >=1%Conc<20%: Xi; R43 Eu;A Benzoyl peroxide - 5 - - - - -
Bis(piperidinothiocarbonyl) disulphide [Piperidine, 1,1'- Xi; R36/37/38 Xi ; R: 36/37/38 - 43, Conc>=20%: Xi; R36/37/38; R43
94-37-1 (dithiodicarbonothioyl)bis] R43 S: (2) - 24 - 26 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Carc. Cat. 2; R45 T Conc>=25%: T; R45; R68; R22

Safrole [5-Allyl-1,3-Benzodioxole; 1,3-Benzodioxole, Muta. Cat. 3; R68 R: 45-22-68 >=1%Conc<25%: T; R45; R68
94-59-7 5-(2-propenyl)] Xn; R22 S: 53-45; Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
T
R: 23/24/25-33 Conc>=25%: T; R23/24/25; R33
T; R23/24/25 S: (1/2-)28-36/37-45; Note: >=3%Conc<25%: Xn; R20/21/22; R33
94-70-2 2-Ethoxyaniline [o-Phenetidine] R33 C >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
Xn; R22 Xn; N >=20%Conc<25%: Xi; R38; R41
Xi; R38-41 R: 22-38-41-50/53 >=10%Conc<20%: Xi; R41
94-74-6 MCPA (ISO) [4-Chloro-o-tolyloxyacetic acid] N; R50-53 S: (2-)26-37-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Conc>=25%: Xn; R22; R37; R41; R43
Xn; R22 Xn >=20%Conc<25%: Xi; R37; R41; R43
Xi; R37-41 R: 22 - 37 - 41 - 43 - 52/53 >=10%Conc<20%: Xi; R41; R43
R43 S: (2) - 24/25 - 26 - 36/37/39 >=5%Conc<10%: Xi; R36; R43
94-75-7 2,4-D (ISO) [2,4-Dichlorophenoxyacetic acid] R52-53 - 46 - 61 >=1%Conc<5%: Xi; R43 Eu; A 2,4-D - 10 - - - - -
N
R: 50/53
94-81-5 MCPB (ISO) [4-(4-Chloro-o-tolyloxy) butyric acid] N; R50-53 S: 60-61 Eu - - - - - - - -
Xn; N
Xn; R22 R: 22 - 51/53
94-82-6 2,4-DB (ISO) [4-(2,4-Dichlorophenoxy) butyric acid] N; R51-53 S: (2) - 25 - 29 - 46 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi ; R: 41 , Conc>=10%: Xi; R41
94-96-2 2-Ethylhexane-1,3-diol [Octylene glycol; Ethoexadiol] Xi; R41 S: (2) - 25 - 26 - 39 - 46 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 22 - 50/53,
Sulfallate (ISO) [2-Chlorallyl N,N- Xn; R22 S: 53 - 45 - 60 - 61; Conc>=25%: T; R45, R22
95-06-7 dimethyldithiocarbamate] N; R50-53 Note: E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
95-13-6 Indene A Indene 10 48 - - - - -
Xi; R43 Xi ; N ; R: 43 - 50/53,
95-33-0 N-Cyclohexylbenzothiazole-2-sulphenamide N; R50-53 S: (2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 68
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
R10
Xn; R20/21 Xn Conc>=25%: Xn; R20/21; R37/38 Xylene (o-, m-, p-
95-47-6 Benzene, 1,2-dimethyl- [o-Xylene] Xi; R37/38 R: 10-20/21-37/38 >=20%Conc<25%: Xi; R37/38 N isomers) 80 350 150 655 - - -
T ; R: 24/25 - 34 ,
o-Cresol(Note: see also CAS No 1319-77-3, 108-39-4 T; R24/25 S: (1/2 ) - 36/37/39 - 45; Conc>=5%: T; R24/25; R34
95-48-7 & 106-44-5) C; R34 Note: C >=1%Conc<5%: Xn; R21/22; R36/38 Eu - - - - - - - -
Xn ; N ; R: 20 - 51/53
2-Chlorotoluene [o-Chlorotoluene](Note: see also Xn; R20 S: (2) - 24/25 - 61
95-49-8 CAS No 25168-05-2, 108-41-8 & 106-43-4) N; R51-53 Note: C Conc>=25%: Xn; R20 Eu; A o-Chlorotoluene 50 259 - - - - -
Xn; R22 Xn; N
Xi; R36/37/38 R: 22-36/37/38-50/53 Conc>=20%: Xn; R22; R36/37/38
95-50-1 1,2-Dichlorobenzene [o-Dichlorobenzene] N; R50-53 S: (2-)23-60-61 >=5%Conc<20%: Xn; R22 Eu; A o-Dichlorobenzene 25 150 50 301 - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 23/25 - 36 - Conc>=25%: T; R45; R23/25; R36
T; R23/25 50, >=20%Conc<25%: T; R45; R20/22; R36
Xi; R36 S: 53 - 45 - 61; >=3%Conc<20%: T; R45; R20/22
95-53-4 o-Toluidine [Benzenamine, 2-methyl] N; R50 Note: E >=0.1%Conc<3%: T; R45 Eu; A o-Toluidine 2 8.8 - - 2 Sk -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R68; R25; R20/21; R36;
T; R25 R43
Xn; R20/21 T ; N ; R: 20/21 - 25 - 36 - >=20%Conc<25%: Xn; R40; R68; R22; R36;
Xi; R36 40 - 43 - 50/53 - 68, R43
R43 S: (1/2) - 28 - 36/37 - 45 - >=3%Conc<20%: Xn; R40; R68; R22; R43 o-
95-54-5 o-Phenylenediamine N; R50-53 60 - 61 >=1%Conc<3%: Xn; R40; R68; R43 Eu; A Phenylenediamine - 0.1 - - 3 Sen -
Xn; R20/22 Xn ; R: 20/22 - 68 , Conc>=25%: Xn; R68; R20/22
95-55-6 2-Aminophenol [Phenol, 2-amino] Muta. Cat. 3; R68 S: (2) - 28 - 36/37 >=1%Conc<25%: Xn; R68 Eu - - - - - - - -

Xn ; N ; R: 20/21/22 - 51/53,
2-Chlorophenol(Note: see also CAS No 106-48-9, Xn; R20/21/22 S: (2) - 28 - 61;
95-57-8 108-43-0 & 25167-80-0) N; R51-53 Note: C Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
R10.
Xn; R20. Xn ; N ; R: 10 - 20 -
1,2,4-Trimethylbenzene [Benzene, 1,2,4-trimethyl; Xi; R36/37/38 36/37/38 - 51/53, Conc>=25%: Xn; R20; R36/37/38
95-63-6 Pseudocumene] N; R51-53 S: (2) - 26 - 61 >=20% Conc<25%: Xi; R36/37/38 Eu - - - - - - - -

T ; N ; R: 24/25 - 34 - 51/53, Conc>=25%: T; R24/25; R34

3,4-Xylenol [3,4-Dimethylphenol](Note: see also CAS T; R24/25 S: (1/2) - 26 - 36/37/39 - 45 - >=10%Conc<25%: C; R34; R21/22
No 95-87-4, 105-67-9, 526-75-0, 576-26-1, 1300-71-6 C; R34 61; >=5%Conc<10%: Xn; R21/22; R36/38
95-65-8 & 71975-58-1) N; R51-53 Note: C >=3%Conc<5%: Xn; R21/22 Eu - - - - - - - -
Carc.Cat.2; R45 T; N Conc>=25%: T; R45; R68; R23/24/25
Muta.Cat.3; R68 R: 45-23/24/25-68-50/53 >=3%Conc<25%: T: R45; R68; R20/21/22
4-Chloro-o-toluidine (Note: see also CAS No. T; R23/24/25 S: 53-45-60-61 >=1%Conc<3%: T; R45; R68
95-69-2 3165-93-3) N; R50-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -

Conc>=25%: T; R25; R20/21; R48/22; R36;

T; R25 R43
Xn; R20/21-48/22 >=20%Conc<25%: Xn; R22; R48/22; R36; R43
Xi; R36 T; N >=10%Conc<20%: Xn; R22; R48/22; R43
1,4-Benzenediamine, 2-methyl- [2,5-Toluenediamine; R43 R: 20/21-25-36-43-48/22-51- >=3%Conc<10%: Xn; R22; R43
95-70-5 2-Methyl-p-phenylenediamine] N; R51-53 53 >=1%Conc<3%: Xi; R43 N/Eu - - - - - - - -

Conc>=25%: T; R23/24/25;R41; R43

T; R23/24/25 T; N >=10%Conc<25%: Xn; R20/21/22; R41; R43
Xi; R41 R: 23/24/25-41-43-50/53 >=5%Conc<10%: Xn;R20/21/22; R36; R43
R43 S: (1/2-)26-36/37/39-45-60- >=3% Conc<5%: Xn; R20/21/22; R43
95-76-1 3,4-Dichloroaniline N; R50-53 61 >=1% Conc<3%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R45; R68; R62; R25; R21;

Carc. Cat. 2; R45 R48/22; R43
Muta. Cat. 3; R68 >=10%Conc<25%: T; R45; R62; R68; R22;
Repr. Cat. 3; R62 T; N R48/22; R43
T; R25 R: 45-21-25-43-48/22-62-68- >=5%Conc<10%: T; R45; R62; R68; R22; R43
Xn; R21-48/22 51/53 >=3%Conc<5%: T; R45; R68; R22; R43
4-Methyl-m-phenylenediamine [2,4-Toluenediamine; R43 S: 53-45-61 >=1%Conc<3%: T; R45; R68; R43
95-80-7 1,3-Benzenediamine, 4-methyl] N; R51-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

T ; N ; R: 24/25 - 34 - 51/53, Conc>=25%: T; R24/25; R34

2,5-Xylenol [2,5-Dimethylphenol](Note: see also CAS T; R24/25 S: (1/2) - 26 - 36/37/39 - 45 - >=10%Conc<25%: C; R34; R21/22
No 95-65-8, 105-67-9, 526-75-0, 576-26-1, 1300-71-6 C; R34 61; >=5%Conc<10%: Xn; R21/22; R36/38
95-87-4 & 71975-58-1) N; R51-53 Note: C >=3%Conc<5%: Xn; R21/22 Eu - - - - - - - -
Xn; R22. Xn ; R: 22 - 36 , Conc>=25%: Xn; R22; R36
95-92-1 Oxalic acid diethylester [Diethyl oxalate] Xi; R36 S: (2) - 23 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
Xn; R22 Xn; N
Xi; R36/38 R: 22-36/38-50/53 Conc>=20%: Xn; R22; R36/38
95-95-4 2,4,5-Trichlorophenol N; R50-53 S: (2-)26-28-60-61 >=5%Conc<20%: Xi; R36/38 Eu - - - - - - - -
R10
T; R23 T ; N ; R: 10 - 21/22 - 23 -
Allyl methacrylate [2-Methyl-2-propenoic acid 2- Xn; R21/22 50 Conc>=25%: T; R23; R21/22
96-05-9 propenyl ester] N; R50 S: (1/2) - 36/37 - 45 - 61 >=3%Conc<25%: Xn; R20 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; R: 45 - 21 - 36, Conc>=25%: T; R45; R21; R36
Xn; R21 S: 53 - 45 ; >=20%Conc<25%: T; R45; R36
96-09-3 Styrene oxide [(Eepoxyethyl)benzene; Phenyloxirane] Xi; R36 Note: E >=0.1%Conc<20%: T; R45 Eu - - - - - - - -
Conc>=25%: T; R45; R46; R60; R25;
Carc. Cat. 2; R45 R48/20/22
Muta. Cat. 2; R46 >=10%Conc<25%: T; R45; R46; R60;
Repr. Cat. 1; R60 T ; R: 45 - 46 - 60 - 25 - R48/20/22; R22
T; R25 48/20/22 - 52/53, >=3%Conc<10%: T; R45; R46; R60; R22
1,2-Dibromo-3-chloropropane [Propane,1,2-dibromo- Xn; R48/20/22 S: 53 - 45 - 61; >=0.5%Conc<3%: T; R45; R46; R60
96-12-8 3-chloro] R52-53 Note: E >=0.1%Conc<0.5%: T; R45; R46 Eu - - - - - - - -
Carc. Cat. 2; R45
Repr. Cat. 3; R62 T ; R: 45 - 20/22 - 24 - 52/53 Conc>=25%: T; R45; R62; R24; R20/22
T; R24 - 62 >=5%Conc<25%: T; R45; R62; R21
Xn; R20/22 S: 53 - 45 - 61; >=3%Conc<5%: T; R45; R21
96-13-9 2,3-Dibromopropan-1-ol [2,3-Dibromo-1-propanol] R52-53 Note: E >=0.1%Conc<3%: T; R45 Eu - - - - - - - -
F; R11
Xn; R65 F; Xn; N
Xi; R38 R: 11-38-65-67-51/53
3-Methylpentane(Note: see also CAS No. 107-83-5, R67 S: (2-)9-16-29-33-61-62 Conc>=20%: Xn; R65; R38 Hexane, other
96-14-0 75-83-2 & 79-29-8) N; R51-53 Note: C >=10%Conc<20%: Xn; R65 Eu;A isomers 500 1760 1000 3500 - - -
T
Carc. Cat. 2; R45 R: 45-60-20/21/22 Conc>=25%: T; R45; R60; R20/21/22
Repr. Cat. 2; R60 S: 53-45; Note: >=0.5%Conc<25%: T; R45; R60 1,2,3-
96-18-4 1,2,3-Trichloropropane Xn; R20/21/22 D >=0.1%Conc<0.5%: T; R45 Eu; A Trichloropropane 10 60 - - - Sk -
F; R11
Xi; R37 F; Xi
R66 R: 11-37-66-67
96-22-0 Pentan-3-one [Diethyl ketone] R67 S: (2-)9-16-25-33 Conc>=20%: Xi; R37 Eu;A Diethyl ketone 200 705 - - - - -
Carc. Cat. 2; R45 T ; R: 45 - 21 - 25 , Conc>=25%: T; R45; R25; R21
T; R25 S: 53 - 45 ; >=3%Conc<25%: T; R45; R22
96-23-1 1,3-Dichloro-2-propanol Xn; R21 Note: E >=0.1%Conc<3%: T; R45 Eu - - - - - - - -
Carc. Cat. 3; R40 Xn Conc>=25%: Xn; R40; R21; R41; R43
Xn; R21 R: 21 - 40 - 41 - 43 >=10%Conc<25%: Xn; R40; R41; R43
2-Butanone oxime [Ethyl methyl ketoxime; Ethyl Xi; R41 S: (2) - 13 - 23 - 26 - >=5%Conc<10%: Xn; R40; R36; R43
96-29-7 methyl ketone oxime] R43 36/37/39 >=1%Conc<5%: Xn; R40; R43 Eu - - - - - - - -
T; R48/22 T
Mixture of: butan-2-one oxime and syn-O,O'-di(butan- R43 R: 43-48/25-52/53 Conc>=10%: Xn; R48/22; R43
96-29-7 2-one oxime)diethoxysilane R52-53 S: (1/2-)25-36/37-45-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
F ; Xn ; R: 11 - 20/21/22 -
F; R11 36/37/38 - 43,
Xn; R20/21/22 S: (2) - 9 - 25 - 26 - 33 - Conc>=25%: Xn; R20/21/22; R36/37/38; R43
Xi; R36/37/38 36/37 - 43; >=20%Conc<25%: Xi; R36/37/38; R43
96-33-3 Methyl acrylate [Methyl propenoate] R43 Note: D >=1%Conc<20%: Xi; R43 Eu; A Methyl acrylate 10 35 - - - Sk;Sen -

Conc>=25%: T; R23/25; R37/38; R41

>=20%Conc<25%: Xn; R20/22; R37/38; R41
R10 T ; R: 10 - 23/25 - 37/38 - 41 >=10%Conc<20%: Xn; R20/22; R41
T; R23/25. , >=5%Conc<10%: Xn; R20/22; R36
96-34-4 Methyl chloroacetate Xi; R37/38-41 S: (1/2) - 26 - 37/39 - 45 >=3%Conc<5%: Xn; R20/22 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 61 - 22 ,
Ethylene thiourea [Imidazolidine-2-thione; 2- Repr. Cat. 2; R61 S: 53 - 45 ; Conc>=25%: T; R61; R22
96-45-7 Imidazoline-2-thiol] Xn; R22 Note: E >=0.5%Conc<25%: T; R61 Eu - - - - - - - -

4,4-Thiobis(6-tert-butyl-m-cresol) [6,6'-Di-tert-butyl- 4,4'-Thiobis (6-tert-

96-69-5 4,4'-thiodi-m-cresol] A butyl-m-cresol) - 10 - - - - -
E; R2 E; Xn
Xn; R20/21/22 R: 2-20/21/22-52/53
96-91-3 2-Amino-4,6-dinitrophenol [Picramic acid] R52-53 S: (2-)35-36/37-46-61 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
T+ ; R: 26/27/28 - 33 -
T+; R26/27/28 52/53 , Conc>=7%: T+; R26/27/28; R33
4-Methoxy-2-nitroaniline [2-Nitro-p-anisidine; R33 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R23/24/25; R33
96-96-8 Benzenamine, 4-methoxy-2-nitro] R52-53 61 >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
T+ ; N ; R: 26/27/28 - 33 -
T+; R26/27/28 51/53 , Conc>=7%: T+; R26/27/28; R33
R33 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R23/24/25; R33
97-02-9 2,4-Dinitroaniline [Benzenamine, 2,4-dinitro] N; R51-53 61 >= 0.1%Conc<1%; Xn; R20/21/22 Eu - - - - - - - -
Dichlofenthion (ISO) [O-2,4-Dichlorophenyl O,O- Xn; R22 Xn ; N ; R: 22 - 50/53 ,
97-17-6 diethyl phosphorothioate] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Dichlorophen (ISO) [4,4'-Dichloro-2,2'- Xn; R22
methylenediphenol; 2,2'-Methylenebis[4- Xi; R36 Xn ; N ; R: 22 - 36 - 50/53, Conc>=25%: Xn; R22; R36
97-23-4 chlorophenol]] N; R50-53 S: (2) - 26 - 60 - 61 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=25%: Xn; R40; R22
97-54-1 Isoeugenol Xn; R22 Xn; R: 22-40 >=1%Conc<25%: Xn; R40 V - - - - - - - -
4-o-Tolylazo-o-toluidine [4-Amino-2',3-
dimethylazobenzene; Fast garnet GBC base; AAT; o- Carc. Cat. 2; R45 T ; R: 45 - 43 , Conc>=1%: T; R45; R43
97-56-3 Aminoazotoluene] R43 S: 53 - 45 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
F ; Xi ; R: 11 - 36/37/38 - 43
F; R11 ,
Xi; R36/37/38 S: (2) - 9 - 16 - 29 - 33 ; Conc>=20%: Xi; R36/37/38; R43
97-63-2 Ethyl methacrylate R43 Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
R10 Xi ; R: 10 - 37 - 41, Conc>=20%: Xi; R41; R37
Ethyl lactate [Ethyl DL-lactate](Note: see also CAS Xi; R37 S: (2) - 24 - 26 - 39; >=10%Conc<20%: Xi; R41
97-64-3 No 687-47-8) Xi; R41 Note: C >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22
R43 Xn ; N ; R: 22 - 43 - 51/53, Conc>=25%: Xn; R22; R43
97-74-5 Tetramethylthiuram monosulphide N; R51-53 S: (2) - 24 - 26 - 37 - 61 >=1%Conc<25%: Xn; R43 Eu - - - - - - - -
Xn; R22-48/22 Xn ; N ; R: 22 - 43 - 48/22 - Conc>=25%: Xn; R22; R48/22; R43
R43 50/53, >=10%Conc<25%: Xn; R48/22; R43
97-77-8 Disulfiram [Tetraethylthiuramdisulfide] N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<10%: Xi; R43 Eu; A Disulfiram - 2 - - - - -
R10
Xi; R36/37/38 Xi; N
R43 R: 10-36/37/38-43-50 Conc>=20%: Xi; R36/37/38; R43
97-86-9 Isobutyl methacrylate N; R50 S: (2-)24-37-61; Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
R10 Xi ; R: 10 - 36/37/38 - 43,
Xi; R36/37/38 S: (2) ; Conc>=20%: Xi; R36/37/38; R43
97-88-1 n-Butyl methacrylate R43 Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xi ; R: 37 - 43,
Ethylene dimethacrylate [Ethylene glycol Xi; R37 S: (2) - 24 - 37; Conc>=10%: Xi; R37; R43
97-90-5 dimethacrylate] R43 Note: D >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
Xn ; R: 21/22 ,
97-95-0 2-Ethylbutan-1-ol Xn; R21/22 S: (2) Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Tetrahydro-2-furylmethanol [Tetrahydrofurfuryl Xi ; R: 36 ,
97-99-4 alcohol] Xi; R36 S: (2) - 39 Conc>=10%: Xi; R36 Eu - - - - - - - -
Conc>=25%: T; R40; R23; R21/22;
R48/20;R36/37
>=20%Conc<25%: Xn; R40; R20; R48/20;
Carc. Cat. 3; R40 R36/37
T; R23 T >=10%Conc<20%: Xn; R40; R20; R48/20
Xn; R21/22-48/20 R: 21/22-23-36/37-40-48/20 >=3%Conc<10%: Xn; R40; R20
98-00-0 Furfuryl alcohol Xi; R36/37 S: (1/2-)36/37-45-63 >=1%Conc<3%: Xn; R40 Eu;A Furfuryl alcohol 10 40 15 60 - Sk -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>25%: T; R40; R23/24/25; R36/37/38
>=20%Conc<25%: Xn; R40; R20/21/22;
Carc. Cat. 3; R40 R36/37/38
2-Furancarboxaldehyde [2-Furaldehyde; Furfural; T; R23/24/25 T >=3%Conc<20%: Xn; R40; R20/21/22
98-01-1 Furfuraldehyde] Xi; R36/37/38 R: 23/24/25-36/37/38-40 >=1%Conc<3%: Xn; R40 N; A Furfural 2 7.9 - - - Sk -

Conc>=25%: T; R45; R23; R22; R37/38; R41

>=20%Conc<25%: T; R45; R20; R37/38; R41
Carc. Cat. 2; R45 T ; R: 45 - 22 - 23 - 37/38 - >=10% Conc<20%: T; R45; R20; R41
T; R23 41 , >=5%Conc<10%: T; R45; R20; R36
Xn; R22 S: 53 - 45 ; >=3%Conc<5%: T; R45; R20
98-07-7 alpha,alpha,alpha-Trichlorotoluene [Benzotrichloride] Xi; R37/38-41 Note: E >=0.1%Conc<3%: T; R45 Eu - - - - - - - -
F; R11 F - N; R11 - 51/53,
98-08-8 Benzotrifluoride [Trifluorotoluene] N; R51-53 S: (2) - 16 - 23 - 61 Eu - - - - - - - -
p-tert-Butyltoluene
98-51-1 p-tert-Butyltoluene A (h) 10 61 20 121 - - -
Conc>=25%: T; R60; R48/23/24/25; R22
Repr. Cat. 2; R60 >=10%Conc<25%: T; R60; R48/23/24/25
Benzoic acid, 4-(1,1-dimethylethyl)- [4-tert- T; R48/23/24/25 T >=1%Conc<10%: T; R60; R48/20/21/22
98-73-7 Butylbenzoic acid] Xn; R22 R: 22-48/23/24/25-60 >=0.5%Conc<1%: T; R60 N - - - - - - - -
R10
Xn; R65 Xn ; N ; R: 10 - 37 - 65 -
Cumene [Isopropylbenzene](Note: see also CAS No Xi; R37 51/53, Conc>=20%: Xn; R65; R37
98-82-8 103-65-1) N; R51-53 S: (2) - 24 - 37 - 61 - 62 >=10%Conc<20%: Xn; R65 Eu; A Cumene 25 125 75 375 - Sk -
R10 Xi; N
Isopropenylbenzene [alpha-Methylstyrene; 2- Xi; R36/37 R: 10-36/37-51/53 alpha-Methyl
98-83-9 Phenylpropene] N; R51-53 S: (2-)61 Conc>=25%: Xi; R36/37 Eu; A styrene 50 242 100 483 - - -
C ; R: 21/22 - 34 , Conc>=25%: C; R34; R21/22
1-Phenylethylamine [Benzenemethanamine, alpha- Xn; R21/22 S: (1/2) - 26 - 28 - 36/37/39 - >=10%Conc<25%: C; R34
98-84-0 methyl](Note: see also CAS No 618-36-0) C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 36 , Conc>=25%: Xn; R22; R36
98-86-2 Acetophenone Xi; R36 S: (2) - 26 >=20%Conc<25%: Xi: R36 Eu - - - - - - - -

Conc>=25%: T; R40; R23; R22; R37/38; R41

>=20%Conc<25%: Xn; R40; R20; R37/38; R41
Carc. Cat. 3; R40 >=10% Conc<20%: Xn; R40; R20; R41
T; R23 T ; R: 22 - 23 - 37/38 - 40 - >=5%Conc<10%: Xn; R40; R20; R36
alpha, alpha-Dichlorotoluene [Benzylidene chloride; Xn; R22 41 , >=3%Conc<5%: Xn; R40; R20
98-87-3 Benzal chloride] Xi; R37/38-41 S: (1/2) - 36/37 - 38 - 45 >=1%Conc<3%: Xn; R40 Eu - - - - - - - -
Conc>=25%: C; R34; R20/21/22; R43
Xn; R20/21/22 C >=10%Conc<25%: C; R34; R43
C; R34 R: 20/21/22-34-43 >=5%Conc<10%: Xi; R36/38; R43
98-88-4 Benzoyl chloride R43 S: (1/2-)26-36/37/39-45 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R40; R62; R23/24/25;

R48/23/24
>=10%Conc<25%: T; R40; R62; R48/23/24;
R20/21/22
Carc. Cat. 3; R40 >=5%Conc<10%: Xn; R40; R62; R20/21/22;
Repr. Cat. 3 R62 T ; N ; R: 40 - 23/24/25 - R48/20/21
T; R23/24/25. 48/23/24 - 62 - 51/53 >=3%Conc<5%: Xn; R40; R20/21/22;
T; R48/23/24 S: (1/2 ) - 28 - 36/37 - 45 - R48/20/21
98-95-3 Nitrobenzene [Benzene, nitro] N; R51-53 61 >=1%Conc<3%: Xn; R40; R48/20/21 Eu; A Nitrobenzene 1 5 - - - Sk -
99-08-1 3-Nitrotoluene A Nitrotoluene 2 11 - - - Sk -
99-08-1 3-Nitrotoluene A Nitrotoluene 2 11 - - - Sk -
99-08-1 3-Nitrotoluene A Nitrotoluene 2 11 - - - Sk -

T ; R: 23/24/25 - 33 - 52/53 ,
T; R23/24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R23/24/25; R33
m-Nitroaniline(Note: see also CAS No 88-74-4 & 100- R33 61 ; >=3%Conc<25%: Xn; R20/21/22; R33
99-09-2 01-6) R52-53 Note: C >=1%Conc<3%: Xn; R33 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
E; R3
T+; R26/27/28 E; T+; N Conc>=7%: T+; R26/27/28; R33
R33 R: 3-26/27/28-33-50/53 >=1%Conc<7%: T; R23/24/25; R33
99-35-4 1,3,5-Trinitrobenzene [Trinitrobenzene] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
Xn Conc>=25%: Xn; R22; R48/20/21/22
99-54-7 Benzene, 1,2-dichloro-4-nitro- Xn; R22-48/20/21/22 R: 22-48/20/21/22 >=10%Conc<25%: Xn; R48/20/21/22 N - - - - - - - -
Carc.Cat.3; R40 T Conc>=25%: T; R40; R23/24/25
5-Nitro-o-toluidine (Note: see also CAS No. 51085- T; R23/24/25 R: 23/24/25-40-52/53 >=3%Conc<25%: Xn; R40; R20/21/22
99-55-8 52-0) R52-53 S: (1/2-)36/37-45-61 >=1%Conc<3%: Xn; R40 Eu - - - - - - - -
T+ ; N ; R: 26/27/28 - 33 -
T+; R26/27/28 50/53 , Conc>=7%: T+; R26/27/28; R33
1,3-Dinitrobenzene [m-Dinitrobenzene](Note: see R33. S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R23/24/25; R33
99-65-0 also CAS No 528-29-0, 100-25-4 & 25154-54-5) N; R50-53 60 - 61 >= 0.1%Conc<1%; Xn; R20/21/22 Eu; A m-Dinitrobenzene 0.15 1 - - - Sk -
T
T; R23/24/25 R: 23/24/25-33-52/53
N,N-Dimethyl-p-toluidine (Note: see also CAS No. R33 S: (1/2-)28-36/37-45-61; Conc>=5%: T; R23/24/25; R33
99-97-8 121-72-2 and 609-72-3) R52-53 Note: C >=1%Conc<5%: Xn; R20/21/22; R33 Eu - - - - - - - -
T ; R: 23/24/25 ,
4-Amino-N,N-dimethylaniline [N,N-Dimethylbenzene- S: (1/2) - 28 - 45 ; Conc>=25%: T; R23/24/25
99-98-9 1,4-diamine](Note: see also CAS No 2836-04-6) T; R23/24/25 Note: C >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
T; N
T; R23/24/25 R: 23/24/25-33-51/53 Conc>=25%: T; R23/24/25; R33
R33 S: (1/2-)28-37-45-61; Note: >=3%Conc<25%: Xn; R20/21/22; R33
99-99-0 4-Nitrotoluene N; R51-53 C >=1%Conc<3%: Xn; R33 Eu; A Nitrotoluene 2 11 - - - Sk -
T; N
T; R23/24/25 R: 23/24/25-33-51/53 Conc>=25%: T; R23/24/25; R33
R33 S: (1/2-)28-37-45-61; Note: >=3%Conc<25%: Xn; R20/21/22; R33
99-99-0 4-Nitrotoluene N; R51-53 C >=1%Conc<3%: Xn; R33 Eu; A Nitrotoluene 2 11 - - - Sk -
T; N
T; R23/24/25 R: 23/24/25-33-51/53 Conc>=25%: T; R23/24/25; R33
R33 S: (1/2-)28-37-45-61; Note: >=3%Conc<25%: Xn; R20/21/22; R33
99-99-0 4-Nitrotoluene N; R51-53 C >=1%Conc<3%: Xn; R33 Eu; A Nitrotoluene 2 11 - - - Sk -

Conc>=25%: T; R40; R68; R23/24/25;

Carc.Cat.3;R40 R48/20/21/22
Mut.Cat.3;R68 T; N >=10%Conc<25%: Xn; R40; R68; R20/21/22;
T; R23/24/25 R: 23/24/25-40-48/20/21/22- R48/20/21/22 p-
Xn; R48/20/21/22 68-51/53 >=3%Conc<10%: Xn; R40; R68; R20/21/22 Nitrochlorobenzen
100-00-5 1-Chloro-4-nitrobenzene N; R51-53 S: (1/2-)28-36/37-45-61 >=1%Conc<3%: Xn; R40; R68 Eu; A e 0.1 0.64 - - - Sk -

T ; R: 23/24/25 - 33 - 52/53 ,
T; R23/24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R23/24/25; R33
p-Nitroaniline(Note: see also CAS No 88-74-4 & 99- R33 61 ; >=3%Conc<25%: Xn; R20/21/22; R33
100-01-6 09-2) R52-53 Note: C >=1%Conc<3%: Xn; R33 Eu; A p-Nitroaniline - 3 - - - Sk -
Xn; R20/21/22. Xn ; R: 20/21/22 - 33 , Conc>=25%: Xn; R20/21/22; R33
100-02-7 4- Nitrophenol [p-Nitrophenol] R33 S: (2) - 28 >=1%Conc<25%: Xn; R33 Eu - - - - - - - -
Xn ; R: 20/21/22 ,
100-22-1 NNN'N'-Tetramethyl-p-phenylenediamine Xn; R20/21/22 S: (2) - 28 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
T+ ; N ; R: 26/27/28 - 33 -
T+; R26/27/28 50/53 , Conc>=7%: T+; R26/27/28; R33
1,4-Dinitrobenzene [p-Dinitrobenzene](Note: see also R33. S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R23/24/25; R33
100-25-4 CAS No 528-29-0, 99-65-0 & 25154-54-5) N; R50-53 60 - 61 >= 0.1%Conc<1%; Xn; R20/21/22 Eu; A p-Dinitrobenzene 0.15 1 - - - Sk -
R10 C ; R: 10 - 20/21/22 - 34, Conc>=25%: C; R34; R20/21/22 2-
Xn; R20/21/22 S: (1/2) - 25 - 26 - 36/37/39 - >=10%Conc<25%: C; R34 Diethylaminoethan
100-37-8 2-Diethylaminoethanol [N, N-Diethylethanolamine] C; R34 45 >=5%Conc<10%: Xi; R36/37/38 Eu; A ol (h) 10 48 - - - Sk -
Xi ; R: 36/37/38 ,
100-39-0 alpha-Bromotoluene [Benzyl bromide] Xi; R36/37/38 S: (2) - 39 Conc>=20%: Xi; R36/37/38 Eu - - - - - - - -
F; R11
Xn; R20 F; Xn Conc>=25%: Xn; R20; R36/38
100-41-4 1175Benzene, ethyl- [Ethyl benzene] Xi; R36/38 R: 11-20-36/38 >=20%Conc<25%: Xi; R36/38 N/Eu; A Ethyl benzene 100 434 125 543 - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: Xn; R40; R20; R48/20; R36/37/38

R10 >=20%Conc<25%: Xn; R40; R48/20;
Carc. Cat. 3; R40 R36/37/38
Xn; R20-48/20 Xn >=10%Conc<20%: Xn; R40; R48/20
100-42-5 Benzene, ethenyl- [Styrene monomer] Xi; R36/37/38 R: 10-20-36/37/38-40-48/20 >=1%Conc<10%: Xn; R40 N/Eu; A Styrene, monomer 50 213 100 426 - - -

Conc>=25%: T; R45; R23; R22; R48/22;

R37/38; R41; R43
>=20%Conc<25%: T; R45; R20; R48/22;
R37/38; R41; R43
>=10%Conc<20%: T; R45; R20; R48/22; R41;
Carc. Cat. 2; R45 R43
T; R23 >=5%Conc<10%: T; R45; R20; R36; R43
Xn; R22-48/22 T >=3%Conc<5%: T; R45; R20; R43
Benzene, (chloromethyl)- [alpha-Chlorotoluene; Xi; R37/38-41 R: 45-22-23-37/38-41-43- >=1%Conc<3%: T; R45; R43
100-44-7 Benzyl chloride] R43 48/22 >=0.1%Conc<1 N; A Benzyl chloride 1 5.2 - - - - -
Conc>=25%: C; R34; R21/22
C; R34 C ; R: 21/22 - 34 , >=10%Conc<25%: C; R34
100-46-9 Benzylamine [Benzenemethanamine] Xn; R21/22 S: (1/2) - 26 - 36/37/39 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xn ; R: 21/22 ,
100-47-0 Benzonitrile Xn; R21/22 S: (2) - 23 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Xn ; R: 20/22 ,
100-51-6 Benzyl alcohol Xn; R20/22 S: (2) - 26 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Xn ; R: 22 ,
100-52-7 Benzaldehyde Xn; R22 S: (2) - 24 Conc>=25%: Xn; R22 Eu - - - - - - - -

Conc>=25%: T; R25; R48/24/25; R34

T ; N ; R: 25 - 34 - 48/24/25 - >=10%Conc<25%: T; R48/24/25; R34; R22
T; R25-48/24/25 50/53, >=5%Conc<10%: Xn; R22; R48/21/22; R36/38
Phenylmercury hydroxide(Note: see also CAS No 55- C; R34 S: (1/2) - 23 - 24/25 - 37 - >=3%Conc<5%: Xn; R22; R48/21/22
100-57-2 68-5 & 8003-05-2) N; R50-53 45 - 60 - 61 >=1%Conc<3%: Xn; R48/21/22 Eu - - - - - - - -
T ; N ; R: 23/24/25 - 33 -
T; R23/24/25 50/53, Conc>=25%: T; R23/24/25; R33
R33 S: (1/2 - ) - 28 - 36/37 - 45 - >=3%Conc<25%: Xn; R20/21/22; R33
100-61-8 N-Methylaniline [Benzenamine, N-methyl] N; R50-53 60 - 61 >=1%Conc<3%: Xn; R33 Eu; A N-Methyl aniline 0.5 2.2 - - - Sk -

Conc>=25%: T; R45; R68; R23/24/25;

R48/23/24/25; R36/38; R43
>=20%Conc<25% : T; R45; R68;
R48/23/24/25; R20/21/22; R36/38; R43
>=10%Conc<20%: T; R45; R68; R48/23/24/25;
Carc. Cat. 2; R45 R20/21/22; R43
Muta. Cat. 3; R68 T; N >=3%Conc<10%: T; R45; R68; R20/21/22;
T; R23/24/25-48/23/24/25 R: 45-23/24/25-36/38-43- R48/20/21/22; R43
Xi; R36/38 48/23/24/25-68-50 >=1%Conc<3%: T; R45; R68; R48/20/21/22;
Phenylhydrazine (Note: see also CAS No. 59-88-1, R43 S: 53-45-61; R43
100-63-0 27140-08-5 and 52033-74-6) N; R50 Note: E >=0.1%conc<1%: T; R45 Eu; A Phenylhydrazine 0.1 0.44 - - 2 Sk;Sen -

100-74-3 N-Ethylmorpholine A N-Ethylmorpholine 5 24 - - - Sk -

1,3,5,7-Tetraazatricyclo[3.3.1.13,7]decane F; R11 F; Xn
100-97-0 [Methenamine; Hexamethylenetetramine] R42/43 R: 11-42/43 Conc>=1%: Xn; R42/43 N/Eu - - - - - - - -
Xi; N
Xi; R36/38 R: 36/38-50/53
101-02-0 Triphenyl phosphite N; R50-53 S: (2-)28-60-61 Conc>=5%: Xi; R36/38 Eu - - - - - - - -
Anilazine (ISO) [2-Chloro-N-(4,6-dichloro-1,3,5-triazin- Xi; R36/38 Xi ; N ; R: 36/38 - 50/53,
101-05-3 2-yl)aniline] N; R50-53 S: (2) - 22 - 60 - 61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 22 - 50/53, 4,4'-Methylene
4,4'-Methylene bis(2-chloroaniline) [MOCA; 2,2'- Xn; R22 S: 53 - 45 - 60 - 61 ; Conc>=25%: T; R45; R22 bis(2-chloroaniline)
101-14-4 Dichloro-4,4'-methylenedianiline] N; R50-53 Note: E >=0.1%Conc<25%: T; R45 Eu; A (h) 0.02 0.22 - - 2 Sk -
Carc. Cat. 3; R40 Xn; N
Xn; R48/22 R: 40-48/22-51/53 Conc>=10%: Xn; R40; R48/22
101-21-3 Chlorpropham (ISO) [Isopropyl 3-chlorocarbanilate] N; R51-53 S: (2-)36/37-61 >=1%Conc<10%: Xn; R40 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Xn; R22
Barban (ISO) [4-Chlorbut-2-ynyl N-(3- R43 Xn ; N ; R: 22 - 43 - 50/53 , Conc>=25%: Xn; R22, R43
101-27-9 chlorophenyl)carbamate] N; R50-53 S: (2) - 24 - 36/37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Conc>=7%: T+; R26/28
T+ ; R: 26/28 , >=1%Conc<7%: T; R23/25
101-31-5 Hyoscyamine T+; R26/28 S: (1/2) - 24 - 45 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R43
101-54-2 1,4-Benzenediamine, N-phenyl- R43 R: 22-43 >=1%Conc<25%: Xi; R43 N - - - - - - - -
T; N
Carc.Cat.2; R45 R: 45-50/53
101-61-1 N,N,N',N'-Tetramethyl-4,4'-methylendianiline N; R50-53 S: 53-45-60-61 Conc>=0.1%: T; R45 Eu - - - - - - - -

Conc>=25%: T; R40; R23; R48/23; R36/37/38;

R42/43
>=20%Conc<25%: T; R40; R48/23; R20;
R36/37/38; R42/43
>=10%Conc<20%: T; R40; R48/23; R20;
Benzene, 1,1'-methylenebis[4-isocyanato- [4,4'- Carc. Cat. 3; R40 R42/43
Methylenediphenyl diisocyanate; Diphenylmethane- T; R23-R48/23 T >=3%Conc<10%: Xn; R40; R20; R48/20; Methylene (see
4,4'-diisocyanate; Xi; R36/37/38 R: 23-36/37/38-40-42/43- R42/43 bisphenyl Isocyanates,
101-68-8 Methylene bisphenyl isocyanate (MDI)] R42/43 48/23 >=1%Conc<3%: Xn; R40; R48/20; R42/43 N/Eu; A isocyanate (MDI) - - - - - - all)
Xn; R22 Xn; N
R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
101-72-4 N-Isopropyl-N'-phenyl-p-phenylenediamine N; R50-53 S: (2-)24-37-60-61 >=0.1%Conc<25%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 2; R45
Muta. Cat. 3; R68 T; N Conc>=10%: T; R45; R68; R39/23/24/25;
T; R39/23/24/25 R: 45-39/23/24/25-43- R48/20/21/22; R43
Xn; R48/20/21/22 48/20/21/22-68-51/53 >=1%Conc<10%: T; R45; R68; R68/20/21/22;
4,4'-Diaminodiphenylmethane [4,4'- R43 S: 53-45-61; R43 4,4'-Methylene
101-77-9 Methylenedianiline] N; R51-53 Note: E >=0.1%Conc<1%: T; R45 Eu; A dianiline 0.1 0.81 - - 2 Sk -
Carc.Cat.2; R45
Muta.Cat.2; R46 T; N Conc>=25%: T; R45; R46; R62; R23/24/25
Repr.Cat.3; R62 R: 45-46-23/24/25-62-51/53 >=5%Conc<25%: T; R45; R46; R62; R20/21/22
4,4'-Oxydianiline and its salts [p- Aminophenyl T; R23/24/25 S: 53-45-61 >=3%Conc<5%: T; R45; R46; R20/21/22
101-80-4 ether] N; R51-53 Note: E >=0.1%Conc<3%: T; R45; R46 Eu - - - - - - - -
C; N
Xn; R22 R: 22-34-50/53 Conc>=25%: C; R34; R22
C; R34 S: (1/2-)26-36/37/39-45-60- >=10%Conc<25%: C; R34
101-83-7 Dicyclohexylamine [Cyclohexanamine, N-Cyclohexyl] N; R50-53 61 >=2%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Phenyl ether
101-84-8 Phenyl ether (vapour) [Diphenyl ether] A (vapour) 1 7 2 14 - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Xn; R21/22 Xn Conc>=25%: Xn; R40; R68; R21/22; R36/38;
Xi; R36/38 R: 21/22 - 36/38 - 40 - 43 - R43
1,3-Bis(2,3-epoxypropoxy)benzene [Resorcinol R43 52/53 - 68 >=20%Conc<25%: Xn; R40; R68; R36/38; R43
101-90-6 diglycidyl ether] R52-53 S: (2) - 23 - 36/37 - 61 >=1%Conc<20%: Xn; R40; R68; R43 Eu - - - - - - - -
Repr. Cat. 3; R62
Xn; R22 Xn ; N ; R: 22 - 36/37/38 - Conc>=25%: Xn; R62; R22; R36/37/38
Xi; R36/37/38 62 - 51/53; >=20%Conc<25%: Xn; R62; R36/37/38
102-06-7 1,3-Diphenylguanidine N; R51-53 S: (2) - 26 - 36/37/39 - 61 >=5%Conc<20%: Xn; R62 Eu - - - - - - - -
Dicyclopentadienyl
102-54-5 Ferrocene [Dicyclopentadienyl iron] A iron - 10 - - - - -
Xi
102-71-6 Ethanol, 2,2',2''-nitrilotris- [Triethanolamine] Xi; R37/38 R: 37/38 Conc>=20%: Xi; R37/38 N; A Triethanolamine - 5 - - - Sen -
Xi; R36/38
R43 Xi ; N ; R: 36/38 - 43 - 51/53, Conc>=20%: Xi; R36/38; R43
102-77-2 2-(Morpholinothio)benzothiazole N; R51-53 S: (2) - 24 - 26 - 37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
2-N-
Dibutylaminoethan
102-81-8 2-N-Dibutylaminoethanol A ol (h) 2 14 - - - Sk -
Xi Conc>=20%: Xi; R37/38; R43
Xi; R37/38 R: 37/38-43 >=1%Conc<20%: Xi; R43
103-11-7 2-Ethylhexyl acrylate R43 S: (2-)36/37-46; Note: D Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Monobenzone [4-Hydroxyphenyl benzyl ether; Xi; R36 Xi ; R: 36 - 43, Conc>=20%: Xi; R36, R43
103-16-2 Hydroquinone monobenzyl ether] R43 S: (2) - 24/25 - 26 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T; R45; R68; R20/22; R48/22
Carc. Cat. 2; R45 >=10%Conc<25%: T; R45; R68; R48/22
Muta. Cat. 3; R68 T; N >=1%Conc<10%: T; R45; R68
Xn; R20/22-48/22 R: 45-20/22-48/22-68-50/53 >=0.1%Conc<1%: T; R45
103-33-3 Azobenzene N; R50-53 S: 53-45-60-61; Note: E Eu - - - - - - - -
R10
Xn; R65 Xn ; N ; R: 10 - 37 - 65 -
Xi; R37 51/53, Conc>=20%: Xn; R65; R37
103-65-1 n-Propylbenzene(Note: see also CAS No 98-82-8) N; R51-53 S: (2) - 24 - 37 - 61 - 62; >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
Conc>=25%: T; R23/24/25; R33
T; R23/24/25 T ; R: 23/24/25 - 33 , >=3%Conc<25%: Xn; R20/21/22; R33
103-69-5 N-Ethylaniline R33 S: (1/2) - 28 - 37 - 45 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
R10
Xn; R20/21/22 C ; R: 10 - 20/21/22 - 34 - Conc>=25%: C; R34; R20/21/22
Benzyldimethylamine [Benzenemethanamine, N,N- C; R34 52/53, >=10%Conc<25%: C; R34
103-83-3 dimethyl] R52-53 S: (1/2) - 26 - 36 - 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Conc>=25%: T+; R26; R22; R37/38; R41; R42

>=20%Conc<25%: T+; R26; R37/38; R41; R42
T+; R26 >=10%Conc<20%: T+; R26; R41; R42
Xn; R22 T+; N >=7%Conc<10%: T+; R26; R36; R42
Xi; R37/38-41 R: 22-26-37/38-41-42-50/53 >=5%Conc<7%: T; R23; R36; R42
R42 S: (1/2-)26-28-36/37/39-45- >=1%Conc<5%: T; R23; R42 Isocyanates, all
104-12-1 4-Chlorophenylisocyanate N; R50-53 63-60-61 >=0.1%Conc<1%: Xn; R20 Eu;A (as-NCO) - 0.02 - 0.07 - Sen -
p-Toluenesulphonic acid (containing a maximum of Xi ; R: 36/37/38 ,
104-15-4 5% H2SO4) Xi; R36/37/38 S: (2) - 26 - 37 Conc>=20%: Xi; R36/37/38 Eu - - - - - - - -
Repr. Cat. 3; R63 Conc>=25%: C; R63; R34; R20
Xn; R20 C >=10%Conc<25%: C; R63; R34
104-76-7 1-Hexanol, 2-ethyl- C; R34 R: 20-34-63 >=5%Conc<10%: Xn; R63; R36/38 N - - - - - - - -
R10 Conc>=25%: C; R34; R21/22; R43
Xn; R21/22 >=10%Conc<25%: C; R34; R43
3-Aminopropyldiethylamine [N,N-Diethyl-1,3- C; R34 C ; R: 10 - 21/22 - 34 - 43 , >=5%Conc<10%: Xi; R36/38; R43
104-78-9 diaminopropane; 3-(Diethylamino)propylamine] Xi; R43 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi ; R: 36/37/38 ,
104-80-3 Tetrahydrofuran-2,5-diyldimethanol Xi; R36/37/38 S: (2) - 39 Conc>=10%: Xi; R36/37/38 Eu - - - - - - - -
Muta. Cat. 3; R68 Xn ; N ; R: 22 - 41 - 51/53 - Conc>=25%: Xn; R68; R22; R41
Xn; R22 68, >=10%Conc<25%: Xn; R68; R41
Xi; R41 S: (2) - 26 - 36/37/39 - 47 - >=5%Conc<10%: Xn; R68; R36
104-91-6 4-Nitrosophenol N; R51-53 49 - 61 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -
T+ ; N ; R: 26/27/28 - 33 -
T+; R26/27/28 50 , Conc>=7%: T+; R26/27/28; R33
R33 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R23/24/25; R33
104-94-9 p-Anisidine [4-Methoxyaniline] N; R50 61 >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
Xi Conc>=10%: Xi; R41
105-08-8 1,4-Cyclohexanedimethanol Xi; R41 R: 41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Xn; R20 Xn ; R: 20 - 36/38 - 43 , Conc>=25%: Xn; R20; R36/38; R43
Xi; R36/38 S: (2) - 26 ; >=10%Conc<25%: Xi; R36/38; R43
105-16-8 2-Diethylaminoethyl methacrylate R43 Note: D >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
Conc>=7%: T+; R26/27/28
T+ ; R: 26/27/28 , >=1%Conc<7%: T; R23/24/25
105-36-2 Ethyl bromoacetate T+; R26/27/28 S: (1/2) - 7/9 - 26 - 45 >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
F ; R: 11
S: (2) - 16 – 23 – 24 – 29 -
105-37-3 Ethyl propionate F; R11; 33 Eu - - - - - - - -
T; R23/24/25 T ; N ; R: 23/24/25 - 50, Conc>=25%: T; R23/24/25
105-39-5 Ethyl chloroacetate N; R50 S: (1/2) - 7/9 - 45 - 61 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
Xi ; R: 36 ,
105-45-3 Methyl acetoacetate Xi; R36 S: (2) - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

F ; R: 11 - 66,
sec-Butyl acetate(Note: see also CAS No 110-19-0 & F; R11 S: (2) - 16 - 23 - 25 - 29 - 33;
105-46-4 540-88-5) R66 Note: C Eu; A sec-Butyl acetate 200 950 - - - - -
R10 Conc>=25%: T; R25; R36/37/38
T; R25 T ; R: 10 - 25 - 36/37/38, >=20%Conc<25%; Xn; R22; R36/37/38
105-48-6 Isopropyl chloroacetate Xi; R36/37/38 S: (1/2) - 26 - 37/39 - 45 >=3%Conc <20%: Xn; R22 Eu - - - - - - - -
F; R11 F ; Xi ; R: 11 - 36/38 ,
105-57-7 1,1-Diethoxyethane [Acetal] Xi; R36/38 S: (2) - 9 - 16 - 33 Conc>=10%: Xi; R36/38 Eu - - - - - - - -
Xi ; R: 36 ,
105-59-9 2,2''-(Methylimino)diethanol [N-Methyldiethanolamine] Xi; R36 S: (2) - 24 Conc>=20%: Xi; R36 Eu - - - - - - - -
Xn; R20/22 Xn ; R: 20/22 - 36/37/38, Conc>=25%: Xn; R20/22; R36/37/38
105-60-2 Caprolactam (dust, vapour) [epsilon Caprolactam] Xi; R36/37/38 S: (2) >=20%Conc<25%: Xi; R36/37/38 Eu; A Caprolactam (dust) - 1 - 3 - - -

Xn; R20/22 Xn ; R: 20/22 - 36/37/38, Conc>=25%: Xn; R20/22; R36/37/38 e-Caprolactam

105-60-2 Caprolactam (dust, vapour) [epsilon Caprolactam] Xi; R36/37/38 S: (2) >=20%Conc<25%: Xi; R36/37/38 Eu; A (dust and vapour) - 10 - 20 - - -

T ; N ; R: 24/25 - 34 - 51/53, Conc>=25%: T; R24/25; R34

2,4-Xylenol [2,4-Dimethylphenol](Note: see also CAS T; R24/25 S: (1/2) - 26 - 36/37/39 - 45 - >=10%Conc<25%: C; R34; R21/22
No 95-65-8, 95-87-4, 526-75-0, 576-26-1, 1300-71-6 C; R34 61; >=5%Conc<10%: Xn; R21/22; R36/38
105-67-9 & 71975-58-1) N; R51-53 Note: C >=3%Conc<5%: Xn; R21/22 Eu - - - - - - - -
O; R7,
S: (1/2) - 3/7 - 14 - 36 -
105-74-8 Dilauroyl peroxide O; R7 37/39 Eu - - - - - - - -
Conc>=25%: T; R23/24; R34; R22
T; R23/24 >=10%Conc<25%: C; R34; R20/21
Xn; R22 T ; R: 22 - 23/24 - 34 , >=5%Conc<10%: Xn; R20/21; R36/38
105-83-9 N,N-Bis(3-aminopropyl)methylamine C; R34 S: (1/2) - 26 - 36/37/39 - 45 >=3%Conc<5%: Xn; R20/21 Eu - - - - - - - -
Xi; R38 Xi: Conc>=20%: Xi; R38; R43
106-26-3 2,6-Octadienal, 3,7-dimethyl-, (Z)- R43 R: 38-43 >=1%Conc<20%: Xi; R43 N - - - - - - - -
R10
Xn; R20 Xn ; R: 10 - 20 - 36 , Conc>=25%: Xn; R20; R36
106-35-4 Heptan-3-one [Ethyl butyl ketone] Xi; R36 S: (2) - 24 >=20% Conc<25%: Xi; R36 Eu; A Ethyl butyl ketone 50 234 - - - - -
R10 Xn ; R: 10 - 20
106-36-5 Propyl propionate Xn; R20 S: (2) - 24 Conc>=25%: Xn; R20 Eu - - - - - - - -
R10
Xn; R20/21 Xn Conc>=25%: Xn; R20/21; R37/38 Xylene (o-, m-, p-
106-42-3 Benzene, 1,4-dimethyl- [p-Xylene] Xi; R37/38 R: 10-20/21-37/38 >=20%Conc<25%: Xi; R37/38 N/Eu; A isomers) 80 350 150 655 - - -
Xn ; N ; R: 20 - 51/53
4-Chlorotoluene [p-Chlorotoluene](Note: see also Xn; R20 S: (2) - 24/25 - 61
106-43-4 CAS No 25168-05-2, 108-41-8 & 95-49-8) N; R51-53 Note: C Conc>=25%: Xn; R20 Eu - - - - - - - -
T ; R: 24/25 - 34 ,
p-Cresol(Note: see also CAS No 1319-77-3, 108-39- T; R24/25 S: (1/2 ) - 36/37/39 - 45; Conc>=5%: T; R24/25; R34
106-44-5 4, & 95-48-7) C; R34 Note: C >=1%Conc<5%: Xn; R21/22; R36/38 Eu - - - - - - - -
Carc. Cat. 3; R40 Xn; N Conc>=20%: Xn; R40; R36
Xi; R36 R: 36-40-50/53 >=1%Conc<20%: Xn; R40
106-46-7 1,4-Dichlorobenzene [p-Dichlorobenzene] N; R50-53 S: (2-)36/37-46-60-61 Eu; A p-Dichlorobenzene 25 150 50 300 - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 23/24/25 - 43 - Conc>=25%: T; R45; R23/24/25; R43
T; R23/24/25 50/53, >=3%Conc<25%: T; R45; R20/21/22; R43
R43 S: 53 - 45 - 60 - 61; >=1%Conc<3%: T; R45; R43
106-47-8 p-Chloroaniline [4-Chloroaniline] N; R50-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -

Xn ; N ; R: 20/21/22 - 51/53,
4-Chlorophenol(Note: see also CAS No 95-57-8, 108- Xn; R20/21/22 S: (2) - 28 - 61;
106-48-9 43-0 & 25167-80-0) N; R51-53 Note: C Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -

Carc. Cat. 3; R40 Conc>=25%: T; R40; R23/24/25; R36; R43

T; R23/24/25 >=20%Conc<25%: Xn; R40; R20/21/22; R36;
Xi; R36 T ; N ; R: 23/24/25 - 36 - 40 - R43
p-Toluidine [4-Aminotoluene](Note: see also CAS No R43 43 - 50 >=3%Conc<20%: Xn; R40; R20/21/22; R43
106-49-0 540-23-8 & 540-25-0) N; R50 S: (1/2) - 28 - 36/37 - 45 - 61 >=1%Conc<3%: Xn; R40; R43 Eu; A p-Toluidine 2 8.8 - - 2 Sk -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

T; R23/24/25 T ; N ; R: 23/24/25 - 36 - 43 - Conc>=25%: T; R23/24/25; R36; R43

Xi; R36 50/53, >=20%Conc<25%: Xn; R20/21/22; R36; R43
R43 S: (1/2) - 28 - 36/37 - 45 - >=3%Conc<20%: Xn; R20/21/22; R43 p-
106-50-3 p-Phenylenediamine N; R50-53 60 - 61 >=1%Conc<3%: Xi; R43 Eu; A Phenylenediamine - 0.1 - - - Sen -
T; R23/25 T; N Conc>=25%: T; R23/25; R36/37/38
Xi; R36/37/38 R: 23/25-36/37/38-50 >=20%Conc<25%: Xn; R20/22; R36/37/38
106-51-4 p-Benzoquinone [Quinone] N; R50 S: (1/2-)26-28-45-61 >=3%Conc<20%: Xn; R20/22 Eu;A Quinone 0.1 0.44 - - - - -
R10
Xn; R20/21 Xn ; R: 10 - 20/21 - 38 - 43 , Conc>=25%: Xn; R20/21; R38; R43
Xi; R38 S: (2) - 9 - 24 - 37 ; >=10%Conc<25%: Xi; R38; R43
106-63-8 Isobutyl acrylate R43 Note: D >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R38; R41
Xi; R38 Xn ; N ; R: 22 - 38 - 41 - >=20%Conc<25%: Xi; R38; R41
R41 51/53, >=10%Conc<20%: Xi; R41
106-75-2 Oxydiethylene-bis(chloroformate) N; R51-53 S: (2) - 23 - 26 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T
1,2-Epoxy-4-epoxyethylcyclohexane [4- Carc. Cat. 3; R40 R: 23/24/25-40 Conc>=1%: T; R40; R23/24/25 Vinyl cyclohexene
106-87-6 Vinylcyclohexene diepoxide] T; R23/24/25 S: (1/2-)36/37-45-63 >=0.1%Conc<1%: Xn; R20/21/22 Eu;A dioxide 10 57 - - 3 Sk -
F; R11
Carc. Cat. 3; R40 F ; Xn ; R: 11 - 20/21/22 -
Xn; R20/21/22 36/37/38 - 40 - 52/53, Conc>=25%: Xn; R40; R20/21/22; R36/37/38
Xi; R36/37/38 S: (2) - 9 - 16 - 29 - 36/37 - >=20%Conc<25%: Xn; R40; R36/37/38
106-88-7 1,2-Epoxybutane R52-53 61 >=1%Conc<20%: Xn; R40 Eu - - - - - - - -

Conc>=25%: T; R45; R46; R62; R23/24/25;

R10 R34; R37; R43
Carc. Cat. 2; R45 >=20%Conc<25%: T; R45; R46; R62; R34;
Muta. Cat. 2; R46 R20/21/22; R37; R43
Repr. Cat. 3; R62 >=10%Conc<20%: T; R45; R46; R62; R34;
T; R23/24/25 R20/21/22; R43
C; R34 T >=5%Conc<10%: T; R45; R46; R62;
Oxirane, (chloromethyl)- [1-Chloro-2,3-epoxypropane; Xi; R37 R: 10-45-46-23/24/25-34-37- R20/21/22; R36/38; R43
106-89-8 Epichlorhydrin] R43 43-62 >=3%Conc<5%: T; R45; R46; R20/21/22 N/Eu; A Epichlorohydrin 2 7.6 - - 2 Sk -

T ; R: 23/24/25 - 34 - 43, Conc>=10%: T; R23/24/25; R34; R43

T; R23/24/25 S: (1/2) - 26 - 36/37/39 - 45 >=5%Conc<10%: T; R23/24/25; R36/38; R43
C; R34 ; >=2%Conc<5%: T; R23/24/25; R43
106-90-1 2,3-Epoxypropyl acrylate [Glycidyl acrylate] R43 Note: D >=0.2%Conc<2%: Xn; R20/21/22; R43 Eu - - - - - - - -
Xn ; R: 20/21/22 - 36/38 - 43
Xn; R20/21/22 , Conc>=25%: Xn; R20/21/22; R36/38; R43
Xi; R36/38 S: (2) - 26 - 28 ; >=10%Conc<25%: Xi; R36/38; R43
106-91-2 2,3-Epoxypropyl methacrylate [Glycidyl methacrylate] R43 Note: D >=1%Conc<10%: Xi; R43 Eu - - - - - - - -

Conc>=25%: Xn; R40; R68; R62; R20/22;

R10 R37/38; R41; R43
Carc. Cat. 3; R40 >=20%Conc<25%: Xn; R40; R68; R62; R37/38;
Muta. Cat. 3; R68 R41; R43
Repr. Cat. 3; R62 Xn >=10%Conc<20%: Xn; R40; R68; R62; R41;
Xn; R20/22 R: 10 - 20/22 - 37/38 - 40 - R43
Xi; R37/38-41 41 - 43 - 52/53 - 62 - 68 >=5%Conc<10%: Xn; R40; R68; R62; R36;
Allyl 2,3-epoxypropyl ether [Prop-2-en-1-yl 2,3- R43 S: (2) - 24/25 - 26 - 36/37/39 R43 Allyl glycidyl ether
106-92-3 epoxypropyl ether; Allyl glycidyl ether] R52-53 - 61 >=1%Conc<5%: Xn; R40; R68; R43 Eu; A (AGE) 5 23 10 47 - Sk;Sen -

Conc>=25%: T; R45; R62; R68; R23/24/25;

R36/37/38
Carc. Cat. 2; R45 >=20%Conc<25%: T; R45; R62; R68;
Muta. Cat. 3; R68 R20/21/22; R36/37/38
Repr. Cat. 3; R62 >=5%Conc<20%: T; R45; R62; R68; R20/21/22
T; R23/24/25 T; N >=3%Conc<5%: T; R45; R68; R20/21/22
Ethane, 1,2-dibromo- [1,2-Dibromoethane; Ethylene Xi; R36/37/38 R: 45-23/24/25-36/37/38-62- >=1%Conc<3%: T; R45; R68 Ethylene
106-93-4 dibromide] N; R51-53 68-51-53 >=0.1%Conc<1%: T; R45 N/Eu; A dibromide (d) - - - - 2 Sk -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F; R11
Carc. Cat. 3; R40 Conc>=20%: T; R40; R60; R63; R48/20;
Repr. Cat. 2; R60 R36/37/38
Repr. Cat. 3; R63 >=10%Conc<20%: T; R40; R60; R63; R48/20
Xn; R48/20 T; F >=5%Conc<10%: T; R40; R60; R63
Propane, 1-bromo- [1-Bromopropane; n-Propyl Xi; R36/37/38 R: 11-60-36/37/38-40-48/20- >=1%Conc<5%: T; R40; R60
106-94-5 bromide] R67 63-67 >=0.5%Conc<1%: T; R60 N/Eu - - - - - - - -
F+; R12,
S: (2) - 9 - 16
106-97-8 Butane F+; R12 Note: C Eu; A Butane 800 1900 - - - - -
F+; R12,
S: (2) - 9 - 16 - 33
106-98-9 But-1-ene [1-Butene; n-Butylene] F+; R12 Note; C Eu - - - - - - - -
F+; T
F+; R12 R: 45 - 46 - 12
Carc. Cat. 1; R45 S: 53 - 45
106-99-0 1,3-Butadiene [Buta-1,3-diene] Muta. Cat. 2; R46 Note: D Conc>=0.1%: T; R45; R46 Eu; A 1,3-Butadiene (h) 10 22 - - 2 - -
F+; R12,
S: (2) - 9 - 16 - 33
107-01-7 But-2-ene [2-Butene] F+; R12 Note; C Eu - - - - - - - -

Conc>=25%: T+; R26; R24/25; R34

>=10%Conc<25%: T+; R26; R34; R21/22
F; R11 F; T+; N >=7%Conc<10%: T+; R26; R21/22; R36/38
T+; R26 R: 11 - 24/25 - 26 - 34 - 50 >=5%Conc<7%: T; R23; R21/22; R36/38
T; R24/25 S: 23 - 26 - 28 - 36/37/39 - >=3%Conc<5%: T; R23; R21/22
C; R34 45 - 61; >=1%Conc<3%: T; R23
107-02-8 Acrylaldehyde [Prop-2-enal; Acrolein] N; R50 Note: D >=0.1%Conc<1%: Xn; R20 Eu; A Acrolein 0.1 0.23 0.3 0.69 - - -

Conc>=25%: Xn; R40; R62; R68; R20/21/22;

F; R11 R48/20/21/22; R36/37/38
Carc. Cat. 3; R40 >=20%Conc<25%: Xn; R40; R62; R68;
Muta. Cat. 3; R68 R48/20/21/22; R36/37/38
Repr. Cat. 3; R62 >=10%Conc<20%: Xn; R40; R62; R68;
Xn; R20/21/22-48/20/21/22 F; Xn; N R48/20/21/22
Xi; R36/37/38 R: 11-20/21/22-36/37/38-40- >=5%Conc<10%: Xn; R40; R62; R68
107-05-1 1-Propene, 3-chloro- [3-Chloropropene; Allyl chloride] N; 50 48/20/21/22-62-68-50 >=1%Conc<5%: Xn; R40; R68 N/Eu; A Allyl chloride 1 3 2 6 - - -

Carc. Cat. 2; R45 Conc>=25%: T; R45; R68; R20/22; R36/37/38

Muta. Cat. 3; R68 >=20%Conc<25%: T; R45; R68; R36/37/38
Ethane, 1,2-dichloro- [1,2-Dichloroethane; Ethylene Xn; R20/22 F; T >=1%Conc<20%: T; R45; R68
107-06-2 dichloride] Xi; R36/37/38 R: 11-45-20/22-36/37/38-68 >=0.1%Conc<1%: T; R45 N/Eu; A Ethylene dichloride 10 40 - - - - -
Conc>=7%: T+; R26/27/28
T+ ; R: 26/27/28 , >=1%Conc<7%: T; R23/24/25 Ethylene 1 Peak 3.3 Peak
107-07-3 2-Chloroethanol [Ethylene chlorohydrin] T+; R26/27/28 S: (1/2) - 7/9 - 28 - 45 >=0.1%Conc<1%: Xn; R20/21/22 Eu; A chlorohydrin limitation limitation - - - Sk -
F; T ; N ; R: 11 - 23/24/25 -
F; R11. 51/53 ,
T; R23/24/25 S: (1/2) - 9 - 16 - 24/25 - 45 - Conc>=25%: T; R23/24/25
107-11-9 Allylamine [2-Propen-1-amine] N; R51-53 61 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -

Conc>=20%: T; R45; R23/24/25; R37/38; R41;

R43
F; R11 >=10%Conc<20%: T; R45; R23/24/25; R41;
Carc. Cat. 2; R45 F; T; N R43
T; R23/24/25 R: 45-11-23/24/25-37/38-41- >=5%Conc<10%: T; R45; R23/24/25; R36; R43
Xi; R37/38-41 43-51/53 >=1%Conc<5%: T; R45; R23/24/25; R43
R43 S: 9-16-53-45-61; >=0.2%Conc<1%: T; R45; R20/21/22
107-13-1 Acrylonitrile N; R51-53 Notes: D; E >=0.1%Conc<0.2%: T; R45 Eu; A Acrylonitrile 2 4.3 - - 2 Sk -

T; R23/24/25 T ; N ; R: 23/24/25 - 51/53, Conc>=25%: T; R23/24/25

107-14-2 Chloroacetonitrile N; R51-53 S: (1/2) - 45 - 61 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
R10 C ; R: 10 - 21/22 - 34 - 42/43 Conc>=25%: C; R34; R21/22; R42/43
C; R34 , >=10%Conc<25%: C; R34; R42/43
Xn; R21/22 S: (1/2) - - 23 - 26 - >=2%Conc<10%: Xn; R36/38; R42/43
107-15-3 Ethylenediamine [1,2-Diaminoethane] R42/43 36/37/39 - 45 >=1%Conc<2%: Xn; R42/43 Eu; A Ethylenediamine 10 25 - - - Sen -
R10 T ; N ; R: 10 - 23/24/25 -
T; R23/24/25 36/37/38 - 50 , Conc>=25%: T; R23/24/25; R36/37/38
Xi; R36/37/38 S: (1/2) - 36/37/39 - 38 - 45 - >=20%Conc<25%: Xn; R20/21/22; R36/37/38
107-18-6 Allyl alcohol N; R50 61 >=3%Conc<20%: Xn; R20/21/22 Eu; A Allyl alcohol 2 4.8 4 9.5 - Sk -
R10 T ; N ; R: 10 - 23/24/25 - 34 - Conc>=25%: T; R23/24/25; R34
T; R23/24/25 51/53, >=10%Conc<25%: C; R34; R20/21/22
C; R34 S: (1/2) - 26 - 28 - 36 - 45 - >=5%Conc<10%: Xn; R20/21/22; R36/38
107-19-7 Prop-2-yn-1-ol [Propargyl alcohol] N; R51-53 61 >=3%Conc<5%: Xn; R20/21/22 Eu; A Propargyl alcohol 1 2.3 - - - Sk -

Conc>=25%: T+; R40; R26; R24/25; R34

>=10%Con<25%: T+; R40; R26; R21/22; R34
>=7%Conc<10%: T+; R40; R26; R21/22;
R36/37/38
Carc. Cat. 3; R40 >=5%Conc<7%: T; R40; R23; R21/22;
T+; R26 T+; N R36/37/38
T; R24/25 R: 24/25-26-34-40-50 >=3%Conc<5%: T; R40; R23; R21/22
C; R34 S: (1/2-)26-28-36/37/39-45- >=1%Conc<3%: T; R40; R23 Chloroacetaldehyd 1 Peak 3.2 Peak
107-20-0 Chloroacetaldehyde N; R50 61 >=0.1%Conc<1%: Xn; R20 Eu; A e limitation limitation - - - - -
Xn ; R: 22 , Ethylene glycol
107-21-1 Ethanediol [Ethylene glycol] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu; A (vapour) 20 52 40 104 - Sk -
Xn ; R: 22 , Ethylene glycol
107-21-1 Ethanediol [Ethylene glycol] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu; A (particulate) - 10 - - - Sk -
Muta. Cat. 3; R68
Xn; R20 Xn
Xi; R36/38 R: 20-36/38-43-68 Conc>=10%: Xn; R68; R20; R36/38; R43
107-22-2 Ethandial...% [Glyoxal …%] R43 S: (2-)36/37; Note: B >=1%Conc<10%: Xn; R68; R43 Eu - - - - - - - -
F+; R12,
S: (2) - 9 - 16 - 33
107-25-5 Methyl vinyl ether F+; R12 Note; D Eu - - - - - - - -

F; R11 F ; T ; R: 45 - 11 - 20/21/22 ,
Carc. Cat. 1; R45 S: 53 - 45 ; Conc>=25%: T; R45; R20/21/22 Chloromethyl
107-30-2 Chloromethyl methyl ether [Chlorodimethyl ether] Xn; R20/21/22 Note: E >=0.1%Conc<25%: T; R45 Eu; A methyl ether (d) - - - - 2 - -

F+; R12 F+ ; Xn ; R: 12 - 20/22 -

Xn; R20/22 36/37, Conc>=25%: Xn; R20/22; R36/37
107-31-3 Methyl formate Xi; R36/37 S: (2) - 9 - 16 - 24 - 26 - 33 >=20%Conc<25%: Xi; R36/37 Eu; A Methyl formate 100 246 150 368 - - -

F; R11 F ; N ; R: 11 - 51/53,
107-39-1 2,4,4-Trimethylpent-1-ene N; R51-53 S: (2) - 9 - 16 - 29 - 33 - 61 Eu - - - - - - - -
Xi ; R: 36/38 , 25 Peak 121 Peak
107-41-5 2-Methylpentane-2,4-diol [Hexylene glycol] Xi; R36/38 S: (2) Conc>=10%: Xi; R36/38 Eu; A Hexylene glycol limitation limitation - - - - -
T+ ; N ; R: 27/28 - 50 , Conc>=7%: T+; R27/28
T+; R27/28 S: (1/2) - 36/37/39 - 38 - 45 - >=1%Conc<7%: T; R24/25
107-49-3 Tetraethyl pyrophosphate [TEPP (ISO)] N; R50 61 >=0.1%Conc<1%: Xn; R21/22 Eu; A TEPP 0.004 0.047 - - - Sk -
Xi ; N ; R: 41 - 50/53
Xi; R41 S: (2)24 - 26 - 39 - 46 - 60 - Conc>=10%: Xi; R41
107-64-2 Dimethyldioctadecylammonium chloride [DODMAC] N; R50-53 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

107-66-4 Dibutyl phosphate [Dibutyl hydrogen phosphate] A Dibutyl phosphate 1 8.6 2 17 - - -

R10 Xn ; R: 10 - 20,
107-70-0 4-Methoxy-4-methylpentan-2-one Xn; R20 S: (2) - 23 - 24/25 Conc>=25%: Xn; R20 Eu - - - - - - - -
F; R11
Xn; R65 F; Xn; N
Hexane [2-Methylpentane](Note: containing < 5 % n- Xi; R38 R: 11-38-65-67-51/53
hexane, CAS No. 110-54-3. See also CAS No. 96-14- R67 S: (2-)9-16-29-33-61-62 Conc>=20%: Xn; R65; R38 Hexane, other
107-83-5 0, 75-83-2 & 79-29-8) N; R51-53 Note: C >=10%Conc<20%: Xn; R65 Eu;A isomers 500 1760 1000 3500 - - -
Methyl propyl
107-87-9 Methyl propyl ketone [2- Pentanone] A ketone 200 705 250 881 - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
C ; R: 34 , Conc>=10%: C; R34
107-92-6 Butyric acid C; R34 S: (1/2) - 26 - 36 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

1-Methoxy-2-propanol [Monopropylene glycol methyl R10 R: 10-67 Propylene glycol

107-98-2 ether] R67 S: (2-) Eu;A monomethyl ether 100 369 150 553 - - -
Conc>=25%: C; R35; R21/22
F; R11 F ; C ; R: 11 - 21/22 - 35, >=10%Conc<25%: C; R35
2-Aminoethyldimethylamine [2- Xn; R21/22 S: (1/2) - 16 - 23 - 26 - 28 - >=5%Conc<10%: C; R34
108-00-9 Dimethylaminoethylamine] C; R35 36 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
R10 Conc>=25%: C; R34; R20/21/22; R43
Xn; R20/21/22 >=10%Conc<25%: C; R34; R43
Ethanol, 2-(dimethylamino)- [2- C; R34 C >=5%Conc<10%: Xi; R36/38; R43 Dimethylaminoeth
108-01-0 Dimethylaminoethanol; N, N-Dimethylethanolamine] R43 R: 10-20/21/22-34-43 >=1%Conc<5%: Xi; R43 N/Eu; A anol 2 7.4 6 22 - - -
R10. Xn ; R: 10 - 20/21/22 ,
108-03-2 1-Nitropropane Xn; R20/21/22 S: (2) - 9 Conc>=5%: Xn; R20/21/22 Eu; A 1-Nitropropane 25 91 - - - - -
F ; R: 11,
S: (2) - 16 - 23 - 29 - 33;
108-05-4 Vinyl acetate F; R11 Note: D Eu; A Vinyl acetate (h) 10 35 20 70 - - -
F; R11
Xn; R65 F; Xn; N
2,4-Dimethylpentane(Note: see also CAS No. 142-82- Xi; R38 R: 11-38-65-67-50/53
5, 464-06-2, 562-49-2, 565-59-3, 589-34-4,590-35-2, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
108-08-7 591-76-4, 617-78-7 & 31394-54-4) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; 11
Carc. Cat. 3; R40
Xn; R20 Conc>=25%: Xn; R40; R20; R36/37
2-Pentanone, 4-methyl- [Isobutyl methyl ketone; 4- Xi; R36/37 F; Xn >=20%Conc<25%: Xn; R40; R36/37 Methyl isobutyl
108-10-1 Methylpentan-2-one] R66 R: 11-20-36/37-40-66 >=1%Conc<20%: Xn; R40 N/Eu; A ketone 50 205 75 307 - - -
R10
2-Pentanol, 4-methyl- [Methyl isobutyl carbinol; 4- Xn; R20 Xn Conc>=25%: Xn; R20; R36/37/38 Methyl isobutyl
108-11-2 Methylpentan-2-ol] Xi; R36/37/38 R: 10-20-36/37/38 >=20%Conc<25%: Xi; R36/37/38 N/Eu; A carbinol 25 104 40 167 - Sk -
R10 Conc>=25%: C; R34; R22
Xn; R22 C ; R: 10 - 22 - 34 , >=10%Conc<25%: C; R34
108-16-7 1-Dimethylaminopropan-2-ol [Dimepranol (INN)] C; R34 S: (1/2) - 23 - 26 - 36 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
F; R11 F ; C ; R: 11 - 20/22 - 34, Conc>=25%: C; R34; R20/22
Xn; R20/22 S: (1/2) - 16 - 26 - 36/37/39 >=10%Conc<25%: C; R34
108-18-9 Diisopropylamine [2-Propanamine, N-(1-methylethyl)] C; R34 - 45 >=5%Conc<10%: Xi; R36/37/38 Eu; A Diisopropylamine 5 21 - - - Sk -
F; R11 F
R19 R: 11-19-66-67
Diisopropyl ether [Isopropyl ether](Note: see also R66 S: (2-)9-16-29-33
108-20-3 CAS No. 111-43-3) R67 Note: C Eu;A Isopropyl ether 250 1040 310 1300 - - -
F; R11
Xi; R36
R66 F; Xi
108-21-4 Acetic acid, 1-methylethyl ester [Isopropyl acetate] R67 R: 11-36-66-67 Conc>=20%: Xi; R36 N/Eu; A Isopropyl acetate 250 1040 310 1290 - - -
R10 Conc>=25%: C; R34; R20/22
Xn; R20/22 C ; R: 10 - 20/22 - 34, >=5%Conc<25%: Xi; R37/38; R41 5 Peak 21 Peak
108-24-7 Acetic anhydride C; R34 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<5%: Xi; R36 Eu; A Acetic anhydride limitation limitation - - - - -
Xn
Xn; R22 R: 22-36/37 Conc>=5%: Xn; R22; R36/37
108-30-5 Succinic anhydride Xi; R36/37 S: (2-)25-46 >=1%Conc<5%: Xi; R36/37 Eu - - - - - - - -
Conc>=25%: C; R34; R22; R42/43
Xn; R22 C ; R: 22 - 34 - 42/43, >=10%Conc<25%: C; R34; R42/43
C; R34 S: (2) - 22 - 23 - 36/37/39 - >=5%Conc<10%: Xn; R42/43; R36/38
108-31-6 Maleic anhydride R42/43 45 >=1%Conc<5%: Xn; R42/43 Eu; A Maleic anhydride 0.25 1 - - - Sen -
Xi ; R: 36 ,
108-32-7 Propylene carbonate Xi; R36 S: (2) Conc>=20%: Xi; R36 Eu - - - - - - - -
Conc>=7%: T+; R26/27/28
T+ ; R: 26/27/28 , >=1%Conc<7%: T; R23/24/25
108-34-9 Pyrazoxon [Diethyl 3-methylpyrazol-5-yl phosphate] T+; R26/27/28 S: (1/2) - 13 - 28 - 45 >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
R10
Xn; R20/21 Xn Conc>=25%: Xn; R20/21; R37/38 Xylene (o-, m-, p-
108-38-3 Benzene, 1,3-dimethyl- [m-Xylene] Xi; R37/38 R: 10-20/21-37/38 >=20%Conc<25%: Xi; R37/38 N/Eu; A isomers) 80 350 150 655 - - -

Page 81
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 24/25 - 34 ,
m-Cresol(Note: see also CAS No 1319-77-3, 95-48- T; R24/25 S: (1/2 ) - 36/37/39 - 45; Conc>=5%: T; R24/25; R34
108-39-4 7& 106-44-5) C; R34 Note: C >=1%Conc<5%: Xn; R21/22; R36/38 Eu - - - - - - - -
Xn ; N ; R: 20 - 51/53
3-Chlorotoluene [m-Chlorotoluene](Note: see also Xn; R20 S: (2) - 24/25 - 61
108-41-8 CAS No 25168-05-2, 95-49-8 & 106-43-4) N; R51-53 Note: C Conc>=25%: Xn; R20 Eu - - - - - - - -

Xn ; N ; R: 20/21/22 - 51/53,
3-Chlorophenol(Note: see also CAS No 95-57-8, 106- Xn; R20/21/22 S: (2) - 28 - 61;
108-43-0 48-9 & 25167-80-0) N; R51-53 Note: C Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
T; N
R: 23/24/25 - 33 - 50
T; R23/24/25 S: (1/2) - 28 - 36/37 - 45 - 61 Conc>=25%: T; R23/24/25; R33
R33 ; >=3%Conc<25%: Xn R20/21/22; R33
108-44-1 m-Toluidine [3-Aminotoluene] N; R50 Note: C >=1%Conc<3%: Xn; R33 Eu; A m-Toluidine 2 8.8 - - - Sk -

Muta. Cat. 3; R68 Conc>=25%: T; R68; R23/24/25; R36; R43

T; R23/24/25 T ; N ; R: 23/24/25 - 36 - 43 - >=20%Conc<25%: Xn; R68; R20/21/22; R36;
Xi; R36 50/53 - 68, R43
R43 S: (1/2) - 28 - 36/37 - 45 - >=3%Conc<20%: Xn; R68; R20/21/22; R43 m-
108-45-2 m-Phenylenediamine N; R50-53 60 - 61 >=1%Conc<3%: Xn; R68; R43 Eu; A Phenylenediamine - 0.1 - - - Sk;Sen -
Xn; R22 Xn; N
Xi; R36/38 R: 22-36/38-50 Conc>=20%: Xn; R22; R36/38
108-46-3 1,3-Benzenediol [Resorcinol] N; R50 S: (2-)26-61 >=10%Conc<20%: Xn; R22 Eu; A Resorcinol 10 45 20 90 - - -
F; Xn
2,4,6,8-Tetramethyl-1,3,5,7-tetraoxacyclooctane F; R11 R: 11-22
108-62-3 [Metaldehyde] Xn; R22 S: (2-)13-16-25-46 Conc>=25%: Xn; R22 Eu - - - - - - - -
R: 10 1-Methoxy-2-
108-65-6 2-Methoxy-1-methylethyl acetate R10 S: (2-) Eu;A propanol acetate 50 274 100 548 - Sk -
R10 Xi; N
1,3,5-Trimethylbenzene [Benzene, 1,3,5-trimethyl; Xi; R37 R: 10-37-51/53
108-67-8 Mesitylene] N; R51-53 S: (2-)61 Conc>=25%: Xi; R37 Eu - - - - - - - -
Conc>=25%: T; R24/25; R34
T; R: 24/25 - 34 >=10%Conc<25%: C; R34; R21/22
T; R24/25 S: (1/2) - 26 - 28 - 36/37/39 - >=5%Conc<10%: Xn; R21/22; R36/38
108-68-9 3,5-Xylenol [3,5-Dimethylphenol] C; R34 45 >=3%Conc<5%: Xn; R21/22 Eu - - - - - - - -

Conc>=25%: T+; R26; R22; R34; R43

T+; R26 >=10%Conc<25%: T+; R26; R34; R43
Xn; R22 T+; C >=7%Conc<10%: T+; R26; R36/37/38; R43
C; R34 R: 14-22-26-34-43 >=5%Conc<7%: T; R23; R36/37/38; R43
R43 S: (1/2-)26-28-36/37/39-45- >=1%Conc<5%: T; R23; R43
108-77-0 2,4,6-Trichloro-1,3,5-triazine [Cyanuric chloride] R14 46-63 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
R10. Xi ; R: 10 - 37 ,
108-83-8 Diisobutyl ketone [2,6-Dimethylheptan-4-one] Xi; R37 S: (2) - 24 Conc>=10%: Xi; R37 Eu; A Diisobutyl ketone 25 145 - - - - -

108-84-9 sec-Hexyl acetate A sec-Hexyl acetate 50 295 - - - - -

R10
Xi; R38 Xi ; N ; R: 10 - 38 - 51/53,
108-86-1 Bromobenzene [Benzene, bromo] N; R51-53 S: (2) - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
F; R11
Xn; R65
Xi; R38 F; Xn; N
R67 R: 11-38-65-67-51/53 Conc>=20%: Xn; R65; R38
108-87-2 Methylcyclohexane N; R51-53 S: (2-)9-16-33-61-62 >=10%Conc<20%: Xn; R65 Eu; A Methylcyclohexane 400 1610 - - - - -
F; R11
Repr. Cat. 1; R60-61 Conc>=20%: T; R60; R61; R48/20; R38
Xn; R48/20 F; T >=10%Conc<20%: T; R60; R61; R48/20
108-88-3 Benzene, methyl- [Toluene] Xi; R38 R: 11-60-61-38-48/20 >=0.5%Conc<10%: T; R60; R61 N/Eu; A Toluene 50 191 150 574 - Sk -
R10
T; R24 T ; R: 10 - 20/22 - 24 - Conc>=25%: T; R24; R20/22; R36/37/38
Xn; R20/22 36/37/38 , >=20%Conc<25%: Xn; R21; R36/37/38
108-89-4 4-Methylpyridine [4-Picoline] Xi; R36/37/38 S: (1/2) - 26 - 36 - 45 >=3%Conc<20%: Xn; R21 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
R10 Xn; N
Xn; R20 R: 10-20-51/53
108-90-7 Chlorobenzene [Benzene, chloro] N; R51-53 S: (2-)24/25-61 Conc>=5%: Xn; R20 Eu; A Chlorobenzene 10 46 - - - - -
R10 Conc>=25%: C; R62; R34; R21/22
Repr. Cat. 3; R62 C >=10%Conc<25%: C; R62; R34
Xn; R21/22 R: 10-21/22-34-62 >=5%Conc<10%: Xn; R62; R36/38
108-91-8 Cyclohexylamine C; R34 S: (1/2-)26-36/37/39-45 >=2%Conc<5%: Xi; R36/38 Eu;A Cyclohexylamine 10 41 - - - - -
Xn; R20/22 Xn ; R: 20/22 - 37/38 , Conc>=25%: Xn; R20/22; R37/38
108-93-0 Cyclohexanol Xi; R37/38 S: (2) - 24/25 >=20%Conc<25%: Xi; R37/38 Eu; A Cyclohexanol 50 206 - - - Sk -
R10 Xn ; R: 10 - 20 ,
108-94-1 Cyclohexanone Xn; R20 S: (2) - 25 Conc>=25%: Xn; R20 Eu; A Cyclohexanone 25 100 - - - Sk -
T; C
Muta.Cat.3; R68 R: 23/24/25-34-48/20/21/22- Conc>=10%: T; R68; R23/24/25; R48/20/21/22;
T; R23/24/25 68 R34
Phenol [Carbolic acid; Monohydroxybenzene; Xn; R48/20/21/22 S: (1/2-)24/25-26-28- >=3%Conc<10%: C; R68; R34; R20/21/22
108-95-2 Phenylalcohol] C; R34 36/37/39-45 >=1%Conc<3%: Xn; R68; R36/38 Eu; A Phenol 1 4 - - - Sk -

108-98-5 Phenyl mercaptan [Bezenethiol] A Phenyl mercaptan 0.5 2.3 - - - - -

R10 Xn ; R: 10 - 20/21/22 - 36/37
Xn; R20/21/22 , Conc>=25%: Xn; R20/21/22; R36/37
109-06-8 2-Methylpyridine [2-Picoline] Xi; R36/37 S: (2) - 26 - 36 >=20%Conc<25%: Xi; R36/37 Eu - - - - - - - -
R10,
S: (2)
109-21-7 Butyl butyrate R10 Note C Eu - - - - - - - -

C; R34 C ; R: 34 - 52/53, Conc>=10%: C; R34

109-52-4 Valeric acid R52-53 S: (1/2) - 26 - 36 - 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
R10 Conc>=25%: C; R34; R22; R43
Xn; R22 >=10%Conc<25%: C; R34; R43
3-Aminopropyldimethylamine [N,N-Dimethyl-1,3- C; R34 C ; R: 10 - 22 - 34 - 43, >=5%Conc<10%: Xi; R36/38; R43
109-55-7 diaminopropane] R43 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Ethanol, 2-(1-methylethoxy)- [2-Isopropoxyethanol; Xn; R20/21 Xn Conc>=25%: Xn; R20/21; R36

109-59-1 Ethylene glycol monoisopropyl ether] Xi; R36 R: 20/21-36 >=20%Conc<25%: Xi; R36 N; A Isopropoxyethanol 25 106 - - - - -
F; R11
Xi; R36
R66 F; Xi
109-60-4 Acetic acid, propyl ester [Propyl acetate] R67 R: 11-36-66-67 Conc>=20%: Xi; R36 N/Eu; A n-Propyl acetate 200 835 250 1040 - - -
F; R11 F; Xi
Xi; R36 R: 11-36-66-67
R66 S: (2-)16-26-29-33
109-60-4 Propyl acetate(Note: see also CAS No. 108-21-4) R67 Note: C Conc>=20%: Xi; R36 Eu;A n-Propyl acetate 200 835 250 1040 - - -
Conc>=25%: T; R23; R34
F; R11 F; T >=10%Conc<25%: C; R34; R20
Propyl chloroformate [Chloroformic acid propylester; T; R23 R: 11-23-34 >=5%Conc<10%: Xn; R20; R36/38
109-61-5 n-Propyl chloroformate] C; R34 S: (1/2-)16-26-36-45 >=3%Conc<5%: Xn; R20 Eu - - - - - - - -
F+; R12
Xn; R65 F+; Xn; N
R66 R: 12-65-66-67-51/53
R67 S: (2-)9-16-29-33-61-62
109-66-0 Pentane(Note: see also CAS No. 78-78-4) N; R51-53 Note: C Conc>=10%: Xn; R65 Eu;A Pentane 600 1770 750 2210 - - -
F; R11,
109-69-3 Butyl chloride [1-Chlorobutane] F; R11 S: (2) - 9 - 16 - 29 Eu - - - - - - - -
F ; C ; R: 11 - 35; R20/21/22 Conc>=25%: C; R35; R20/21/22
F; R11 , >=10%Conc<25%: C; R35
C; R35 S: (1/2 ) - 3 - 16 - 26 - 29 - >=5%Conc<10%: C; R34 5 Peak 15 Peak
109-73-9 Butylamine [1-Butanamine] Xn; R20/21/22 36/37 - 38 - 45 >=1%Conc<5%: Xi; R36/37/38 Eu; A Butylamine limitation limitation - - - Sk -
F; T
F; R11 R: 11-23/24/25 Conc>=25%: T; R23/24/25
109-74-0 n-Butyronitrile T; R23/24/25 S: (1/2-)16-36/37-45-63 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -

T ; N ; R: 23/24/25 - 50/53,
T; R23/24/25 S: (1/2) - 23 - 27 - 45 - 60 - Conc>=25%: T; R23/24/25
109-77-3 Malononitrile N; R50-53 61 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -

Page 83
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
109-79-5 Butyl mercaptan A Butyl mercaptan 0.5 1.8 - - - - -
2-Methylaminoethanol [N-Methyl-2-ethanolamine; N- Conc>=25%: C; R34; R21/22
Methyl-2-amino ethanol; N-Methylethanolamine; 2- Xn; R21/22 C ; R: 34 - 21/22 , >=10%Conc<25%: C; R34
109-83-1 (Methylamino)ethanol] C; R34 S: (1/2) - 26 - 36/37/39 - 45 >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -
T ; R: 60 - 61 - 10 - 20/21/22
R10 ,
Repr. Cat. 2; R60-61 S: 53 - 45 ; Conc>=25%: T; R60; R61; R20/21/22
109-86-4 2-Methoxyethanol [Ethylene glycol monomethyl ether] Xn; R20/21/22 Note: E >=0.5%Conc<25%: T; R60; R61 Eu; A 2-Methoxyethanol 5 16 - - - Sk -
109-87-5 Methylal [Dimethoxymethane] A Methylal 1000 3110 - - - - -
Conc>=25%: C; R35; R20/21/22
F; R11 F ; C ; R: 11 - 20/21/22 - 35, >=10%Conc<25%: C; R35
Xn; R20/21/22 S: (1/2) - 3 - 16 - 26 - 29 - >=5%Conc<10%: C; R34
109-89-7 Diethylamine [Ethanamine, N-ethyl] C; R35 36/37/39 - 45 >=1%Conc<5%: Xi; R36/37/38 Eu; A Diethylamine (h) 10 30 25 75 - - -

F; R11 F ; Xn ; R: 11 - 20/22 -
Xn; R20/22 36/37, Conc>=25%: Xn; R20/22; R36/37
109-94-4 Ethyl formate Xi; R36/37 S: (2) - 9 - 16 - 24 - 26 - 33 >=20%Conc<25%: Xi; R36/37 Eu; A Ethyl formate 100 303 - - - - -
E; R2. E ; Xn ; R: 2 - 20/21/22,
109-95-5 Ethyl nitrite Xn; R20/21/22 S: (2) Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
F; R11-19 Xi
109-99-9 Furan, tetrahydro- [Tetrahydrofuran] Xi; R36/37/38 R: 36/37/38 Conc>=20%: Xi; R36/37/38 N/Eu; A Tetrahydrofuran 100 295 - - - Sk -

F+; R12 Conc>=25%: T; R45; R68; R20/22; R48/22;

R19 R38
Carc. Cat. 2; R45 >=20%Conc<25%: T; R45; R68; R48/22; R38
Muta. Cat. 3; R68 F+; T >=10%Conc<20%: T; R45; R68; R48/22
Xn; R20/22-48/22 R: 45-12-19-20/22-38-48/22- >=1%Conc<10%: T; R45; R68
Xi; R38 68-52/53 >=0.1%Conc<1%: T; R45
110-00-9 Furan R52-53 S: 53-45-61 Note: E Eu - - - - - - - -
F; R11
Xn; R20/21/22 F ; Xn ; R: 11 - 20/21/22 -
Xi; R36/38 36/38 - 52/53, Conc>=25%: Xn; R20/21/22; R36/38
110-01-0 Tetrahydrothiophene R52-53 S: (2) - 16 - 23 - 36/37 - 61 >=20%Conc<25%: Xi; R36/38 Eu - - - - - - - -

O; R7 O; F; Xn
F; R11 R: 7-11-68
110-05-4 Di-tert-butyl peroxide Muta. Cat. 3, R68 S: (2-)3/7-14-16-23-36/37/39 Conc>=1%: Xn; R68 Eu - - - - - - - -
Isoamyl methyl ketone [5-Methylhexan-2-one; Methyl R10 Xn ; R: 10 - 20, Methyl isoamyl
110-12-3 isoamyl ketone] Xn; R20 S: (2) - 23 - 24/25 Conc>=25%: Xn; R20 Eu; A ketone 50 234 - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R36/37/38; R43
Xi; R36/37/38 R: 22-36/37/38-43 >=20%Conc<25%: Xi; R36/37/38; R43
110-16-7 Maleic acid R43 S: (2-)24-26-28-37-46 >=0.1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xi ; R: 36 ,
110-17-8 Fumaric acid Xi; R36 S: (2) - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -
F; R11 F ; C ; R: 11 - 20/22 - 34 , Conc>=25%: C; R34; R20/22
N,N,N',N'-Tetramethylethylenediamine [1,2- Xn; R20/22 S: (1/2) - 16 - 26 - 36/37/39 - >=10%Conc<25%: C; R34
110-18-9 Bis(dimethylamino)ethane] C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
F; R11
R66 F
110-19-0 Acetic acid, 2-methylpropyl ester [Isobutyl acetate] R67 R: 11-66-67 N/Eu; A Isobutyl acetate 150 713 - - - - -

F ; R: 11 - 66,
Isobutyl acetate(Note: see also CAS No 105-46-4 & F; R11 S: (2) - 16 - 23 - 25 - 29 - 33;
110-19-0 540-88-5) R66 Note: C Eu; A Isobutyl acetate 150 713 - - - - -
R10 Xn ; R: 10 - 20/22 , Methyl n-amyl
110-43-0 Heptan-2-one [n-Amyl methyl ketone] Xn; R20/22 S: (2) - 24/25 Conc>=25%: Xn; R20/22 Eu; A ketone 50 233 - - - - -
Xi; R: 10 - 36/37,
Isoamyl formate [Isopentyl formate](Note: see also R10 S: (2) - 24;
110-45-2 CAS No 638-49-3 & 35073-27-9]) Xi; R36/37 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
Amyl nitrite, mixed isomers(Note: see also CAS No F; R11 F ; Xn ; R: 11 - 20/22 ,
110-46-3 463-04-7) Xn; R20/22 S: (2) - 16 - 24 - 46 Conc>=25%: Xn; R20/22 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 60 - 61 - 20/21/22,
Repr. Cat. 2; R60-61 S: 53 - 45 ; Conc>=25%: T; R60; R61; R20/21/22 2-Methoxyethyl
110-49-6 2-Methoxyethyl acetate [Methylglycol acetate] Xn; R20/21/22 Note: E >=0.5%Conc<25%: T; R60; R61 Eu; A acetate 5 24 - - - Sk -
F; R11
Repr. Cat. 3; R62 F; Xn; N
Xn; R48/20-65 R: 11-38-48/20-62-65-67-
Xi; R38 51/53
R67 S: (2-)9-16-29-33-36/37-61- Conc>=20%: Xn; R62; R48/20; R38 Hexane (n-
110-54-3 n-Hexane N; R51-53 62 >=5%Conc<20%: Xn; R62; R48/20 Eu;A Hexane) 20 72 - - - - -
110-62-3 n-Valeraldehyde A n-Valeraldehyde 50 176 - - - - -

Conc>=50%: T; R23/25; R21; R48/22; R34;

R43
>=25%Conc<50%: T; R23/25; R21; R48/22;
C; R34 C; T R36/38; R43
T; R23/25 R: 21-23/25-34-43-48/22 >=10%Conc<25%: Xn; R20/22; R48/22; R43
Xn; R21-48/22 S: (1/2-)25-26-36/37/39-45- >=3%Conc<10%: Xn; R20/22; R43
110-65-6 But-2-yne-1,4-diol [1,4-Butynediol; 2-Butyne-1,4-diol] R43 46; Note: D >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
T; R24 Conc>=25%: T; R24; R22; R36
Xn; R22 T ; R: 22 - 24 - 36 , >=20%Conc<25%: Xn; R21; R36
110-69-0 Butyraldehyde oxime [Butyraldoxime] Xi; R36 S: (1/2) - 23 - 36 - 45 >=3%Conc<20%: Xn; R21 Eu - - - - - - - -
Repr.Cat.2; R60
Repr.Cat.2; R61
F; R11 F; T
1,2-Dimethoxyethane [Ethylene glycol dimethyl R19 R: 60-61-11-19-20 Conc>=25%: T; R60; R61; R20
110-71-4 ether; EGDME] Xn; R20 S: 53-45 >=0.5%Conc<25%: T; R60; R61 Eu - - - - - - - -
F; Xi
F; R11 R: 11-36/37-67
Xi; R36/37 S: (2-)9-16-24-33
110-74-7 Propyl formate(Note: see also CAS No. 625-55-8) R67 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
T
R10 R: 60-61-10-20/22
2-Ethoxyethanol [EGEE; Ethylene glycol monoethyl Repr. Cat. 2; R60-61 S: 53-45 Conc>=25%: T; R60; R61; R20/22
110-80-5 ether] Xn; R20/22 Note: E >=0.5%Conc<25%: T; R60; R61 Eu; A 2-Ethoxyethanol 5 18 - - - Sk -
F; R11
Xn; R65 F; Xn; N
Xi; R38 R: 11-38-65-67-50/53
R67 S: (2-)9-16-25-33-51-60-61- Conc>=20%: Xn; R65; R38
110-82-7 Cyclohexane N; R50-53 62 >=10%Conc<20%: Xn; R65 Eu;A Cyclohexane 100 350 300 1050 - - -
110-83-8 Cyclohexene A Cyclohexene 300 1010 - - - - -
Conc>=10%: C; R62; R63; R34; R42/43
Repr. Cat. 3; R62-63 Xn; C >=5%Conc<10%: Xn; R62; R63; R36/38;
Piperazine C; R34 R: 34-42/43-62-63 R42/43
110-85-0 [liquid] R42/43 S: (1/2-)23-26-36/37/39-45 >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Conc>=10%: C; R62; R63; R34; R42/43
Repr. Cat. 3; R62-63 Xn; C >=5%Conc<10%: Xn; R62; R63; R36/38;
C; R34 R: 34-42/43-62-63 R42/43
110-85-0 Piperazine[solid] R42/43 S: (1/2-)22-26-36/37/39-45 >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
F; R11 F ; Xn ; R: 11 - 20/21/22,
110-86-1 Pyridine Xn; R20/21/22 S: (2) - 26 - 28 Conc>=5%: Xn; R20/21/22 Eu; A Pyridine 5 16 - - - - -
F; R11 F; Xn Conc>=20%: Xn; R63; R37
Repr.Cat.3; R63 R: 11-37-63 >=5%Conc<20%: Xn; R63
110-88-3 1,3,5-Trioxan [Trioxymethylene] Xi; R37 S: (2-)36/37-46 Eu - - - - - - - -
F; R11
T; R23/24 F ; T ; R: 11 - 23/24 - 34 , Conc>=5%: T; R23/24; R34
110-89-4 Piperidine C; R34 S: (1/2) - 16 - 26 - 27 - 45 >=1%Conc<5%: Xn; R20/21; R36/38 Eu; A Piperidine 1 3.5 - - - Sk -
R10 Conc>=25%: C; R34; R20/21/22
Xn; R20/21/22 C ; R: 10 - 20/21/22 - 34, >=10%Conc<25%: C; R34
110-91-8 Morpholine C; R34 S: (1/2) - 23 - 36 - 45 >=1%Conc<10%: Xi; R36/38 Eu; A Morpholine 20 71 - - - Sk -
Xi ; R: 36 ,
110-97-4 1,1'-Iminodipropan-2-ol [Diisopropanolamine] Xi; R36 S: (2) - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
C ; R: 34 ,
S: (1/2) - 26 - 28 - 36/37/39 - Conc>=10%: C; R34
111-14-8 Heptanoic acid C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
T
R10 R: 60-61-10-20/21/22
Repr. Cat. 2; R60-61 S: 53-45 Conc>=25%: T; R60; R61; R20/21/22 2-Ethoxyethyl
111-15-9 2-Ethoxyethyl acetate [Ethylglycol acetate; EGEEA] Xn; R20/21/22 Note: E >=0.5%Conc<25%: T; R60; R61 Eu;A acetate 5 27 - - - Sk -
Xn; R22 Xn Conc>=25%: Xn; R22; R36/38
111-27-3 1-Hexanol [Hexan-1-ol] Xi; R36/38 R: 22-36/38 >=20%Conc<25%: Xi; R36/38 N - - - - - - - -

Conc>=50%: T; R23/25; R34; R42/43

>=25%Conc<50%: T; R23; R22; R34; R42/43
>=10%Conc<25%: C; R34; R20/22; 42/43
T; R23/25 >=2%Conc<10%: Xn; R20/22; R37/38; R41;
C; R34 T; N R42/43
R42/43 R: 23/25-34-42/43-50 >=1%Conc<2%: Xn; R42/43; R36/37/38 0.1 Peak 0.41 Peak
111-30-8 Glutaraldehyde [1,5-Pentanedial; Glutaral] N; R50 S: (1/2-)26-36/37/39-45-61 >=0.5%Conc<1%: Xi; R36/37/38; R43 Eu; A Glutaraldehyde limitation limitation - - - Sen -
Conc>=25%: C; R34; R21/22; R43
Xn; R21/22 >=10%Conc<25%: C; R34; R43
C; R34 C ; R: 21/22 - 34 - 43 , >=5%Conc<10%: Xi; R36/38; R43 Diethylene
111-40-0 Diethylenetriamine [2,2'-Iminodiethylamine] R43 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<5%: Xi; R43 Eu; A triamine 1 4.2 - - - Sk -

Repr. Cat. 2; R61 Conc>=10%: T; R61; R62; R34; R43;

Repr. Cat. 3; R62 T >=5%Conc<10%: T; R61; R62; R36/37/38; R43
C; R34 R: 61-34-43-62 >=1%Conc<5%: T; R61; R43
111-41-1 2-(2-Aminoethylamino)ethanol (AEEA) R43 S: 53-45 >=0.5%Conc<1%: T; R61 Eu - - - - - - - -

Conc>=25%: Xn; R22; R48/21/22; R37/38; R41

>=20%Conc<25%: Xn; R48/21/22; R37/38;
R41
Ethanol, 2,2'-iminobis- [Diethanolamine; 2,2'- Xn; R22-48/21/22 Xn >=10%Conc<20%: Xn; R48/21/22; R41
111-42-2 Iminodiethanol] Xi; R37/38-41 R: 22-48/21/22-37/38-41 >=5%Conc<10%: Xi; R36 N; A Diethanolamine (h) 3 13 - - - - -
F; R11 F
R19 R: 11-19-66-67
R66 S: (2-)9-16-29-33
111-43-3 Dipropyl ether(Note: see also CAS No. 108-20-3) R67 Note: C Eu - - - - - - - -

T+ Conc>=7%: T+; R40; R26/27/28

Bis(2-chloroethyl) ether [2,2'-Dichlorodiethyl ether; Carc. Cat. 3; R40 R: 26/27/28-40 >=1%Conc<7%: T; R40; R23/24/25
111-44-4 Dichloroethyl ether] T+; R26/27/28 S: (1/2-)7/9-27-28-36/37-45 >=0.1%Conc<1%: Xn; R20/21/22 Eu;A Dichloroethyl ether 5 29 10 58 - Sk -
Xn ; R: 22 2,2'-
111-46-6 2,2' -Oxybisethanol [Diethylene glycol] Xn; R22 S: (2)46 Conc>=25%: Xn; R22 Eu; A Oxybis[ethanol] 23 100 - - - - -
Xi ; R: 36 ,
111-48-8 2,2'-Thiodiethanol [Thiodiglycol] Xi; R36 S: (2) Conc>=20%: Xi; R36 Eu - - - - - - - -
Octane [n-Octane](Note: see also CAS No. 540-84-1, F; R11
560-21-4, 563-16-6, 564-02-3, 565-75-3, 583-48-2, Xn; R65 F; Xn; N
584-94-1, 589-43-5, 589-53-7, 589-81-1, 590-73-8, Xi; R38 R: 11-38-65-67-50/53
592-13-2, 592-27-8, 594-82-1, 609-26-7, 619-99-8, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
111-65-9 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu;A Octane 300 1400 375 1750 - - -
Xi
111-70-6 1-Heptanol Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
Xn
2-Butoxyethanol [EGBE; Ethylene glycol monobutyl Xn; R20/21/22 R: 20/21/22 - 36/38 Conc>=25%: Xn; R20/21/22; R36/38
111-76-2 ether; Butyl cellosolve] Xi; R36/38 S: (2) - 36/37 - 46 >=20%Conc<25%: Xi; R36/38 Eu; A 2-Butoxyethanol 20 96.9 50 242 - Sk -
2-(2-Methoxyethoxy)ethanol [Diethylene glycol Xn ; R: 63,
111-77-3 monomethyl ether] Repr. Cat. 3; R63 S: (2) - 36/37 Conc>=5%: Xn; R63 Eu - - - - - - - -
111-84-2 Nonane A Nonane 200 1050 - - - - -
Xi
111-87-5 1-Octanol Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
R10 Xn ; R: 10 - 20/21/22 ,
111-92-2 Di-n-butylamine(Note: see also CAS No 626-23-3) Xn; R20/21/22 S: (2) Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
R10
R19 T ; R: 60 - 61 - 10 - 19
111-96-6 Bis(2-methoxyethyl) ether Repr. Cat. 2; R60-61 S: 53 - 45 Conc>=0.5%: T; R60; R61 Eu - - - - - - - -
C ; R: 34 ,
S: (1/2) - 26 - 28 - 36/37/39 - Conc>=10%: C; R34
112-05-0 Nonanoic acid C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Ethanol, 2-butoxy-, acetate [2-Butoxyethyl acetate; Xn 2-Butoxyethyl
112-07-2 Butylglycol acetate] Xn; R20/21/22 R: 20/21/22 Conc>=25%: Xn; R20/21/22 N; A acetate 20 133 50 333 - Sk -
Xn; R21 Conc>=25%: C; R34; R21; R43
C; R34 C >=10%Conc<25%: C; R34; R43
R43 R: 21-34-43-52/53 >=5%Conc<10%: Xi; R36/38; R43
112-24-3 3,6-Diazaoctanethylenediamin [Triethylenetetramine] R52-53 S: (1/2-)26-36/37/39-45-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn C Conc>=25%: C; R34; R21/22
2-Hexyloxyethanol R21/22 R: 21/22-34 >=10%Conc<25%: C; R34
112-25-4 [Ethylene glycol monohexyl ether; n-Hexylglycol] C; R34 S: (1/2-)26-36/37/39-45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
2-(2-Butoxyethoxy)ethanol [Diethylene glycol Xi ; R: 36 ,
112-34-5 monobutyl ether] Xi; R36 S: (2) - 24 - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -
R19 T
1,2-Bis(2-methoxyethoxy)ethane [TEGDME; Repr. Cat.2; R61 R: 61-19-62 Conc>=5%: T; R61; R62
112-49-2 Triethylene glycol dimethyl ether; Triglyme] Repr. Cat.3; R62 S: 53-45 >=0.5%Conc<5%: T; R61 Eu - - - - - - - -
R10 T ; R: 10 - 24/25 , Conc>=25%: T; R24/25
112-56-1 2-(2-Butoxyethoxy)ethyl thiocyanate T; R24/25 S: (1/2) - 13 - 36/37 - 45 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
Xn; R21/22 Conc>=25%: C; R34; R21/22; R43
C; R34 C; N >=10%Conc<25%: C; R34; R43
3,6,9-Triazaundecamethylenediamine R43 R: 21/22-34-43-51/53 >=5%Conc<10%: Xi; R36/38; R43
112-57-2 [Tetraethylenepentamine] N; R51-53 S: (1/2-)26-36/37/39-45-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

2-(2-Hexyloxyethoxy)ethanol [DEGHE; Diethylene Conc>=25%: Xn; R21; R41

glycol monohexyl ether; 3,6-Dioxa-1-dodecanol; Xn R: 21-41 >=10%Conc<25%: Xi; R41
112-59-4 Hexyl carbitol; 3,6-Dioxadodecan-1-ol] Xn; R21 Xi; R41 S: (2-)26-36/37-46 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Propoxur (ISO) [2-Isopropyloxyphenyl N-
methylcarbamate; 2-Isopropoxyphenyl T; R25 T ; N ; R: 25 - 50/53, Conc>=25%: T; R25
114-26-1 methylcarbamate] N; R50-53 S: (1/2) - 37 - 45 - 60 - 61 >=3%Conc<25%: Xn; R22 Eu; A Propoxur - 0.5 - - - - -
Asphyxiant
F+; R12, (see Chapter
115-07-1 Propene [Propylene] F+; R12 S: (2) - 9 - 16 - 33 Eu Propylene - - - - - - 10)
F+; R12,
115-10-6 Dimethyl ether F+; R12 S: (2) - 9 - 16 - 33 Eu; A Dimethyl ether 400 760 500 950 - - -
F+; R12,
S: (2) - 9 - 16 - 33
115-11-7 2-Methylpropene [Isobutene; Isobutylene] F+; R12 Note; C Eu - - - - - - - -
T+ ; R: 27/28 , Conc>=7%: T+; R27/28
Dimefox (ISO) [Tetramethylphosphorodiamidic S: (1/2) - 23 - 28 - 36/37 - >=1%Conc<7%: T; R24/25
115-26-4 fluoride] T+; R27/28 38 - 45 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -

1,4,5,6,7,7-Hexachlorobicyclo [2.2.1]hept-5-ene-2,3- Xi ; R: 36/37/38 ,

115-27-5 dicarboxylicanhydride chlorendic anhydride Xi; R36/37/38 S: (2) - 25 Conc>=1%: Xi; R36/37/38 Eu - - - - - - - -
Endosulfan (ISO) [1,2,3,4,7,7-Hexachloro-8,9,10- T+; N Conc>=25%: T+; R26/28; R21
trinorborn-2-en-5,6-ylenedimethyl sulfite; 1,4,5,6,7,7- T+; R26/28 R: 21-26/28-50/53 >=7%Conc<25%: T+; R26/28
Hexachloro-8,9,10-trinorborn-5-en-2,3- Xn; R21 S: (1/2-)28-36/37-45-60-61- >=1%Conc<7%: T; R23/25
115-29-7 ylenedimethylene) sulfite] N; R50-53 63 >=0.1%Conc<1%: Xn; R20/22 Eu;A Endosulfan - 0.1 - - - Sk -
Xn; N
1,7,7-Trimethylbicyclo(2,2,1)hept-2-yl Xn; R22 R: 22-50/53
115-31-1 thiocyanatoacetate [Isobornyl thiocyanoacetate] N; R50-53 S: (2-)24/25-60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R21/22
Xi; R38 Xn; N Conc>=25%: Xn; R21/22; R43; R38
Dicofol (ISO) [2,2,2-Trichloro-1,1-bis(4- R43 R: 21/22 - 38 - 43 - 50/53 >=20%Conc<25%: Xi; R43; R38
115-32-2 chlorophenyl)ethanol] N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
T; R25 Conc>=25%: T; R25; R21; R36/38
Chlorphonium chloride (ISO) [Tributyl (2,4- Xn; R21 T ; R: 21 - 25 - 36/38 , >=20%Conc<25%: Xn; R22; R36/38
115-78-6 dichlorobenzyl) phosphonium chloride] Xi; R36/38 S: (1/2) - 36/37/39 - 45 >=3%Conc<20%: Xn; R22 Eu - - - - - - - -
Triphenyl
115-86-6 Triphenyl phosphate A phosphate - 3 - - - - -

Page 87
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T+ ; N ; R: 27/28 - 50/53, Conc>=7%: T+; R27/28
O,O-Diethyl O-4-methylsulfinylphenyl T+; R27/28 S: (1/2) - 23 - 28 - 36/37 - >=1%Conc<7%: T; R24/25
115-90-2 phosphorothioate [Fensulfothion (ISO)] N; R50-53 45 - 60 - 61 >=0.1%Conc<1%: Xn; R21/22 Eu; A Fensulfothion - 0.1 - - - - -
Carc. Cat. 3; R40 T; N
Repr. Cat. 2; R60 R: 60-22-40-51/53 Conc>=25%: T; R40; R60; R22
Xn; R22 S: 53-45-61 >=1%Conc<25%: T; R40; R60
115-96-8 Tris(2-chloroethyl)phosphate N; R51-53 Note: E >=0.5%Conc<1%: T; R60 Eu - - - - - - - -
Ethoate methyl (ISO) [Ethylcarbamoylmethyl o,o- Xn ; R: 21/22 ,
116-01-8 dimethyl phosphorodithioate] Xn; R21/22 S: (2) - 36/37 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Conc>=25%: T+; R26/28; R24
Aldicarb (ISO) [2-Methyl-2- T+ ; N ; R: 26/28 - 24 - >=7%Conc<25%: T+; R26/28; R21
(methylthio)propionaldehyde O-(methylcarbamoyl) T+; R26/28 50/53, >=3%Conc<7%: T; R23/25; R21
oxime; 2-Methyl-2-(methylthio)propanal-O-(N- T; R24 S: (1/2) - 22 - 36/37 - 45 - >=1%Conc<3%: T; R23/25
116-06-3 methylcarbamoyl)oxime] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Xn; R20 Xn ; R: 20 - 37 , Conc>=25%: Xn; R20; R37
116-15-4 Hexafluoropropene [Hexafluoropropylene] Xi; R37 S: (2) - 41 >=20%Conc<25%: Xi; R37 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53,
116-16-5 Hexachloroacetone N; R51-53 S: (2) - 24/25 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn ; N ; R: 41 - 42/43 -
Xi; R41 50/53, Conc>=10%: Xn; R42/43; R41
Xn; R42/43 S: (2) - 22 - 24 - 26 - 37/39 - >=5%Conc<10%: Xn; R42/43; R36
117-08-8 Tetrachlorophthalic anhydride N; R50-53 60 - 61 >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Xn; R22
Tecnazene (ISO) [1,2,4,5-Tetrachloro-3- Xi; R43 Xn ; N ; R: 22 - 43 - 50/53 Conc>=25%: Xn; R22; R43
117-18-0 nitrobenzene] N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T; R25; R48/25
Fumarin [4-Hydroxy-3-[3-oxo-1-(2- >=10%Conc<25%: T; R48/25; R22
furyl)butyl]coumarin; Coumafuryl; (RS)-3-(1-(2-Furyl)- T; R25-48/25 T ; R: 25 - 48/25 - 52/53, >=3%Conc<10%: Xn; R22; R48/22
117-52-2 3-oxobutyl)4-hydroxycoumarin] R52-53 S: (1/2) - 37 - 45 - 61 >=1%Conc<3%: Xn; R48/22 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 36/38 -
Xi; R36/38 50/53, Conc>=25%: Xn; R22; R36/38
117-80-6 Dichlone (ISO) [2,3-Dichloro-1,4-naphthoquinone] N; R50-53 S: (2) - 26 - 60 - 61 >=20%Conc<25%: Xi; R36/38 Eu - - - - - - - -
1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester
[Bis(2-ethylhexyl) phthalate; DEHP; Di-(2-ethylhexyl) Carc. Cat. 2; R45 T Conc>=0.5%: T; R45; R60; R61 Di-sec-octyl
117-81-7 phthalate] Repr. Cat. 2; R60-61 R: 45-60-61 >=0.1%Conc<0.5%: T; R45 N; A phthalate - 5 - 10 - - -

Bis(2-methoxyethyl) phthalate [1,2- Repr. Cat. 2; R 61 T ; R 61 - 62 Conc>=5%: T; R61; R62

117-82-8 Benzenedicarboxylic acid, bis(2-methoxyethyl) ester] Repr. Cat. 3; R 62 S: 53 - 45 >=0.5%Conc<5%: T; R61 Eu - - - - - - - -
Xi; R36 Xi ; R: 36 - 43, Conc>=20%: Xi; R36; R43
118-48-9 4H-3,1-Benzoxazine-2,4(1H)-dione R43 S: (2) - 24 - 26 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

1,3-Dichloro-5,5-
118-52-5 1,3-Dichloro-5,5-dimethyl hydantoin A dimethyl hydantoin - 0.2 - 0.4 - - -
T ; N ; R: 45 - 48/25 - 50/53
Carc. Cat. 2; R45 , Conc>=10%: T: R45, R48/25
T; R48/25 S: 53 - 45 - 60 - 61; >=1%Conc<10%: T; R45, R48/22
118-74-1 Hexachlorobenzene [Benzene, hexachloro] N; R50-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Tetrachloro-p-benzoquinone [2,5-Cyclohexadiene-1,4- Xi; R36/38 Xi ; N ; R: 36/38 - 50/53,
118-75-2 dione, 2,3,5,6-tetrachloro] N; R50-53 S: (2) - 37 - 60 - - 61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
E; R2
T; R23/24/25 E ; T ; N ; R: 2 - 23/24/25 - Conc>=25%: T; R23/24/25: R33 2,4,6-
R33 33 - 51/53, >=3%Conc<25%: Xn; R20/21/22; R33 Trinitrotoluene
118-96-7 2,4,6-Trinitrotoluene [TNT] N; R51-53 S: (1/2) - 35 - 45 - 61 >=1%Conc<3%: Xn; R33 Eu; A (TNT) - 0.5 - - - Sk -
Conc>=7%: T+; R27/28
1-Isopropyl-3-methylpyrazol-5-yl dimethylcarbamate T+ ; R: 27/28 , >=1%Conc<7%: T; R24/25
119-38-0 [Isolan] T+; R27/28 S: (1/2) - 28 - 36/37/39 - 45 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
Xi; R36/38
R19 Xi ; N ; R: 19 - 36/38 - 51/53,
119-64-2 1,2,3,4-Tetrahydronaphthalene N; R51-53 S: (2) - 26 - 28 - 61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
Carc. Cat. 2; R45 Conc>=25%: T; R45; R68; R22
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethoxy- [3,3'- Muta. Cat. 3; R68 T >=1%Conc<25%: T; R45; R68
119-90-4 Dimethoxybenzidine; o-Dianisidine] Xn; R22 R: 45-22-68 >=0.1%Conc<1%: T; R45 N - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 45 - 22 ,
Carc. Cat. 2; R45 S: 53 - 45 ; Conc>=25%: T; R45; R22
119-90-4 3,3'-Dimethoxybenzidine [o-Dianisidine] Xn; R22 Note: E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
Carc. Cat. 2; R45
Muta. Cat. 3; R68 Conc>=25%: T; R45; R68; R22
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethyl- [3,3'- Xn; R22 T; N >=1%Conc<25%: T; R45; R68
119-93-7 Dimethylbenzidine; o-Tolidine; 4,4'-bi-o-Toluidine] N; R51-53 R: 45-22-68-51-53 >=0.1%Conc<1%: T; R45 N/Eu; A o-Tolidine (d) - - - - 2 Sk -
Conc>=25%: Xn; R21/22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Dichlorprop (ISO) [2-(2,4-Dichlorophenoxy) propionic Xn; R21/22 Xn ; R: 21/22 - 38 - 41 , >=10%Conc<20%: Xi; R41
120-36-5 acid] Xi; R38-41 S: (2) - 26 - 36/37 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; N
Xn; R22 R: 22-51/53
120-51-4 Benzyl benzoate N; R51-53 S: (2-)25-46-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
T
R: 45-22
Carc.Cat.2; R45 S: 53-45 Conc>=25%: T; R45; R22
120-71-8 6-Methoxy-m-toluidine [p- Cresidine] Xn; R22 Note: E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
R31
Xi; R43 Xi ; N ; R: 31 - 43 - 50/53,
120-78-5 di(Benzothiazol-2-yl) disulphide N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=1%: Xi; R43; R31 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: Xn; R40; R68; R21/22; R36/38;
Xn; R21/22 R43
1,2-Benzenediol [1,2-Dihydroxybenzene; Catechol; Xi; R36/38 Xn >=20%Conc<25%: Xn; R40; R68; R36/38; R43
120-80-9 Pyrocatechol] R43 R: 21/22-36/38-40-43-68 >=1%Conc<20%: Xn; R40; R68; R43 N; A Catechol 5 23 - - - - -
Xn; R22
Xi; R38 Xn ; N ; R: 22 - 38 - 50/53 Conc>=25%: C; R22; R38 1,2,4- 5 Peak 37 Peak
120-82-1 1,2,4-Trichlorobenzene N; R50-53 S: (2)23 - 37/39 - 60 - 61 >=20%Conc<25%: Xi; R38 Eu; A Trichlorobenzene limitation limitation - - - - -
T; R24 T; N Conc>=25%: T; R24; R22; R34
Xn; R22 R: 22 - 24 - 34 - 51/53 >=10%Conc<25%: C; R21; R34
C; R34 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%: Xn; R21; R36/38
120-83-2 2,4-Dichlorophenol [Phenol, 2,4-dichloro] N; R51-53 61 >=3%Conc<5%: Xn; R21 Eu - - - - - - - -
R10 Xi ; R: 10 - 36/38 ,
120-92-3 Cyclopentanone Xi; R36/38 S: (2) - 23 Conc>=20%: Xi; R36/38 Eu - - - - - - - -

Conc>=25%: T; R45; R62; R68; R23/24/25;

R48/22
Carc. Cat. 2; R45 >=10%Conc<25%: R45; R62; R68; R20/21/22;
Muta. Cat. 3; R68 T; N R48/22
Repr. Cat. 3; R62 R: 45-23/24/25-48/22-62-68- >=5%Conc<10%: T; R45; R62; R68; R20/21/22
T; R23/24/25 50/53 >=3%Conc<5%: T; R45; R68; R20/21/22
2,4-Dinitrotoluene(Note: see also CAS No. 25321-14- Xn; R48/22 S: 53-45-60-61 >=1%Conc<3%: T; R45; R68
121-14-2 6) N; R50-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
3-(But-2-enyl)-2-methyl-4-oxocyclopent-2-enyl-2,2- Xn; N
dimethyl-3-(3-methoxy-2-methyl-3-oxoprop-1- Xn; R22 R: 22 - 50/53
121-20-0 enyl)cyclopropanecarboxylate [Cinerin-II] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Pyrethrin-I [2-Methyl-4-oxo-3-(penta-2,4-
dienyl)cyclopent-2-enyl [1R-[1alpha[S*(Z)],3beta]]- Xn; R20/21/22 Xn ; N ; R: 20/21/22 - 50/53,
121-21-1 chrysanthemate] N; R50-53 S: (2) - 13 - 60 - 61 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -

Pyrethrin-II [2-Methyl-4-oxo-3-(penta-2,4-
dienyl)cyclopent-2-enyl[1R-[1alpha[S*(Z)](3beta)]]-3-
(3-methoxy-2-methyl-3-oxoprop-1-enyl)-2,2- Xn; R20/21/22 Xn ; N ; R: 20/21/22 - 50/53,
121-29-9 dimethylcyclopropanecarboxylate] N; R50-53 S: (2) - 13 - 60 - 61 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
R10 Xn ; R: 10 - 21 ,
121-43-7 Trimethyl borate Xn; R21 S: (2) - 23 - 25 Conc>=25%: Xn; R21 Eu - - - - - - - -
Conc>=25% C; R35; R20/21/22
F; R11 F ; C ; R: 11 - 35 - 20/21/22, >=10%Conc<25%: C; R35
C; R35 S: (1/2) - 3 - 16 - 26 - 29 - >=5%Conc<10%: C; R34
121-44-8 Triethylamine [Ethanamine, N,N-diethyl] Xn; R20/21/22 36/37/39 - 45 >=1%Conc<5%: Xi; R36/37/38 Eu; A Triethylamine 2 8 4 17 - - -
Trimethyl
121-45-9 Trimethyl phosphite A phosphite 2 10 - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn ; R: 20/21/22 ,
121-47-1 3-Aminobenzene sulphonic acid [Metanilic acid] Xn; R20/21/22 S: (2) - 25 - 28 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Xi; R36/38 Xi ; R: 36/38 - 43, Conc>=20%: Xi; R36/38; R43
121-57-3 4-Aminobenzenesulphonic acid [Sulphanilic acid] R43 S: (2) - 24 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
T ; N ; R: 40 - 23/24/25 -
Carc. Cat. 3; R40 51/53 ,
T; R23/24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=5%: T; R40; R23/24/25 N,N-
121-69-7 N,N-Dimethylaniline [Benzenamine, N,N-dimethyl] N; R51-53 61 >=1%Conc<5%: Xn; R40; R20/21/22 Eu; A Dimethylaniline 5 25 10 50 - Sk -
T
T; R23/24/25 R: 23/24/25-33-52/53
N,N-Dimethyl-m-toluidine (Note: see also CAS No. R33 S: (1/2-)28-36/37-45-61; Conc>=5%: T; R23/24/25; R33
121-72-2 99-97-8 and 609-72-3) R52-53 Note: C >=1%Conc<5%: Xn; R20/21/22; R33 Eu - - - - - - - -
Malathion (ISO) [1,2-Bis(ethoxycarbonyl)ethyl O,O- Xn; R22 Xn; N
dimethyl phosphorodithioate](Note: containing <= R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
121-75-5 0.03 % isomalathion) N; R50-53 S: (2-)24-37-46-60-61 >=1%Conc<25%: Xi; R43 Eu; A Malathion - 10 - - - Sk -
Xn; R22 Xn ; R: 22 - 43 , Conc>=25%: Xn; R22; R43
121-79-9 Propyl 3,4,5-trihydroxybenzoate Xi; R43 S: (2) - 24 - 37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

121-82-4 Cyclonite [Hexahydro-1,3,5-trinitro-1,3,5-trazine] A Cyclonite - 1.5 - - - Sk -

2-Chloro-4-nitroaniline [Benzenamine, 2-chloro-4- Xn; R22 Xn ; N ; R: 22 - 51/53,
121-87-9 nitro] N; R51 - 53 S: (2) - 22 - 24 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Fenitrothion (ISO) [Fenitrothion (ISO); O,O-Dimethyl Xn; R22 Xn ; N ; R: 22 - 50/53 ,
122-14-5 O-4-nitro-m-tolyl phosphorothioate] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

5,5-Dimethyl-3-oxocyclohex-1-enyl
dimethylcarbamate 5,5-dimethyldihydroresorcinol T ; R: 25 , Conc>=25%: T; R25
122-15-6 dimethylcarbamate [Dimetan] T; R25 S: (1/2) - 36/37 - 45 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Conc>=20%: Xi; R37/38; R41
2-Propanol, 1,1',1''-nitrilotris- [1,1',1''-Nitrilotripropan-2- Xi; R37/38-41 Xi >=10%Conc<20%: Xi; R41
122-20-3 ol; Triisopropanolamine] R52-53 R: 37/38-41-52-53 >=5%Conc<10%: Xi; R36 N/Eu - - - - - - - -

Xn; N
Simazine (ISO) [6-Chloro-N,N'-diethyl-1,3,5-triazine- Carc. Cat. 3; R40 R: 40 - 50/53
122-34-9 2,4-diamine] N; R50-53 S: (2) - 36/37 - 46 - 60 - 61 Conc>=1%: Xn; R40 Eu - - - - - - - -
T ; N ; R: 23/24/25 - 33 -
T; R23/24/25 50/53, Conc>=25%: T; R23/24/25; R33
R33 S: (1/2 ) - 28 - 36/37 - 45 - >=3%Conc<25%: Xn; R20/21/22; R33
122-39-4 Diphenylamine [Benzenamine, N-phenyl] N; 50-53 60 - 61 >=1%Conc<3%: Xn; R33 Eu; A Diphenylamine - 10 - - - - -
Carc. Cat. 2; R45 Conc>=25%: T; R45; R68; R20; R36/37/38;
Muta. Cat. 3; R68 R43;
Xn; R20 >=20%Conc<25%: T; R45; R68; R36/37/38;
Oxirane, (phenoxymethyl)- [1,2-Epoxy-3- Xi; R36/37/38 T R43;
phenoxypropane; 2,3-Epoxypropyl phenyl ether; R43 R: 45-20-36/37/38-43-68-52- >=1%Conc<20%: T; R45; R68; R43 Phenyl glycidyl
122-60-1 Phenyl glycidyl ether (PGE)] R52-53 53 >=0.1%Conc<1%: T; R45 N/Eu; A ether (PGE) 1 6.1 - - - Sen -
Carc. Cat. 2; R45 T ; N ; R: 45 - 22 - 50/53,
Xn; R22 S: 53 - 45 - 60 - 61; Conc>=25%: T; R45; R22
122-66-7 Hydrazobenzene [1, 2-Diphenylhydrazine] N; R50-53 Note: E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
Xn ; R: 22 ,
122-88-3 4-CPA Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 36 , Conc>=25%: Xn; R22; R36
122-99-6 2-Phenoxyethanol Xi; R36 S: (2) - 26 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
R10 Xn ; R: 10 - 20,
123-19-3 Dipropyl ketone [Di-n-propyl ketone; Heptan-4-one] Xn; R20 S: (2) - 24/25 Conc>=25%: Xn; R20 Eu; A Dipropyl ketone 50 233 - - - - -

Muta. Cat. 3; R68 Xn ; N ; R: 20/22 - 50/53 -

Xn; R20/22 68, Conc>=25%: Xn; R68; R20/22
123-30-8 4-Aminophenol [Phenol, 4-amino] N; R50-53 S:(2) - 28 - 36/37 - 60 - 61 >=1%Conc<25%: Xn; R68 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Xn; R22 Conc>=25%: Xn; R40; R68; R22; R41; R43
Xi; R41 Xn; N >=10%Conc<25%: Xn; R40; R68; R41; R43
R43 R: 22-40-41-43-68-50 >=5%Conc<10%: Xn; R40; R68; R36; R43
123-31-9 1,4-Dihydroxybenzene [Hydroquinone; Quinol] N; R50 S: (2-)26-36/37/39-61 >=1%Conc<5%: Xn; R40; R68; R43 Eu;A Hydroquinone - 2 - - - - -

Page 90
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F; R11 F ; Xi ; R: 11 - 36/37/38,
123-38-6 Propanal [Propionaldehyde] Xi; R36/37/38 S: (2) - 9 - 16 - 29 Conc>=20%: Xi; R36/37/38 Eu - - - - - - - -
T ; R: 61 - 21
Repr. Cat. 2; R61 S: 53 - 45; Conc>=25%: T; R61; R21
123-39-7 N-Methylformamide Xn; R21 Note: E 0.5>=%Conc<25%: T; R61 Eu - - - - - - - -
Xi ; R: 36 ,
123-42-2 4-Hydroxy-4-methylpentan-2-one [Diacetone alcohol] Xi; R36 S: (2) - 24/25 Conc>=10% : Xi; R36 Eu; A Diacetone alcohol 50 238 - - - - -
Isoamyl alcohol [3-Methylbutyl alcohol; 3-Methyl-1-
123-51-3 butanol] A Isoamyl alcohol 100 361 125 452 - - -
R10 Xn ; R: 10 - 22 ,
123-54-6 Pentane-2,4-dione [Acetylacetone] Xn; R22 S: (2) - 21 - 23 - 24/25 Conc>=25% : Xn; R22 Eu - - - - - - - -
C ; R: 34 , Conc>=25%: C; R34
123-62-6 Propionic anhydride C; R34 S: (1/2) - 26 - 45 >=10%Conc<25%: Xi; R36/37/38 Eu - - - - - - - -
R: 10
123-63-7 2,4,6-Trimethyl-1,3,5-trioxane [Paraldehyde] R10 S: (2-)29 Eu - - - - - - - -
F; R11,
123-72-8 Butyraldehyde F; R11 S: (2) - 9 - 29 - 33 Eu - - - - - - - -

Conc>=25%: T+; R68; R26; R24/25; R48/22;

R37/38; R41
>=20%Conc<25%: T+; R68; R26; R21/22;
R48/22; R37/38; R41
F; R11 >=10%Conc<20%: T+; R68; R26; R21/22;
Muta. Cat. 3; R68 R48/22; R41
T+; R26 F; T+; N >=7%Conc<10%: T+; R68; R26; R21/22; R36
T; R24/25 R: 11 - 24/25 - 26 - 37/38 - >=5%Conc<7%: T; R68; R23; R21/22; R36
Xn; R48/22 41 - 48/22 - 50 - 68 >=3%Conc<5%: T; R68; R21/22; R23
(E)-2-Butenal [(E)-Crotonaldehyde](Note: see also Xi; R37/38-41 S: (1/2) - 26 - 28 - 36/37/39 - >=1%Conc<3%: T; R68; R23
123-73-9 CAS No 4170-30-3) N; R50 45 - 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
E; Xn
E; R2 R: 2-42
123-77-3 C,C'-Azodi(formamide) R42 S: (2-)22-24-37 Conc>=1%: Xn; R42 Eu - - - - - - - -
R10
R66
123-86-4 Acetic acid, butyl ester [n-Butyl acetate] R67 R: 10-66-67 N/Eu; A n-Butyl acetate 150 713 200 950 - - -

Conc>=25%: T; R25; R48/25; R34

T ; N ; R: 25 - 34 - 48/25 - >=10%Conc<25%: T; R48/25; R34; R22
T; R25-48/25 50/53, >=5%Conc<10%: Xn; R22; R48/22; R36/38
C; R34 S: (1/2) - 36/37/39 - 45 - 60 - >=3%Conc<5%: Xn; R22; R48/22
123-88-6 2-Methoxyethylmercury chloride N; R50-53 61 >=1%Conc<3%: Xn; R48/22 Eu - - - - - - - -

F; R11-19 F; Xn
Carc. Cat. 3; R40 R: 11 - 19 - 36/37 - 40 - 66
Xi; R36/37 S: (2) - 9 - 16 - 36/37 - 46; Conc>=20%: Carc. Cat 3; Xn: R40; R36/37
123-91-1 1,4-Dioxane [Dioxane] R66 Note: D >=1%Conc<20%: Xn; Carc. Cat 3; R40 Eu; A 1,4-Dioxane 10 36 - - - Sk -
R: 10 - 66,
Isopentyl acetate [Isoamyl acetate](Note: see also R10 S: (2) - 23 - 25;
123-92-2 CAS No 628-63-7, 626-38-0, 624-41-9 & 84145-37-9) R66 Note: C Eu, A Isoamyl acetate 50 270 100 541 - - -
Conc>=20%: Xi; R37; R41
Xi >=10%Conc<20%: Xi; R41
124-04-9 Hexanedioic acid [Adipic acid] Xi; R37-41 R: 37-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Conc>=25%: C; R34; R21/22; R37
Xn; R21/22 C ; R: 21/22 - 34 - 37 , >=20%Conc<25%: C; R34; R37
Xi; R37 S: (1/2) - 22 - 26 - 36/37/39 - >=10%Conc<20%: C; R34
124-09-4 Hexamethylenediamine C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Carbon dioxide in
124-38-9 Carbon dioxide in coal mines A coal mines 12500 22500 30000 54000 - - -
124-38-9 Carbon dioxide A Carbon dioxide 5000 9000 30000 54000 - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

F+ ; C ; R: 12 - 20/22 - 34,
F+; R12 S: (1/2) - 3 - 16 - 26 - 29 - Conc>=15%: C; R34; R20/22
Dimethylamine ....%(Note: see also CAS No 74-89-5 Xn; R20/22 36/37/39 - 45; >=10%Conc<15%: C; R34
124-40-3 & 75-50-3) C; R34 Note: B >=5%Conc<10%: Xi; R36/37/38 Eu; A Dimethylamine 2 3.8 6 11 - - -
F+; R12
Xn; R20 F+ ; Xn ; R: 12 - 20 - 37/38 -
Dimethylamine(Note: see also CAS No 74-89-5 & 75- Xi; R37/38 41, Conc>=5%: Xn; R20; R37/38; R41
124-40-3 50-3) R41 S: (2) - 16 - 26 - 39 >=0.5%Conc<5%: Xi; R36 Eu; A Dimethylamine 2 3.8 6 11 - - -
Sodium methanolate [Sodium methoxide; Sodium F; R11 F ; C ; R: 11 - 14 - 34,
methylate](Note: see also CAS No 865-33-8 & 865- R14 S: (1/2) - 8 - 16 - 26 - 43 - Conc>=10%: C; R34
124-41-4 34-9) C; R34 45 >=5%Conc<10% Xi; R36/38 Eu - - - - - - - -
Xi
Xi; R36/38 R: 36/38-52/53
124-68-5 2-Amino-2-methylpropanol R52-53 S: (2-)61 Conc>=10%: Xi; R36/38 Eu - - - - - - - -
Xn ; R: 22 ,
126-33-0 Tetrahydrothiophene-1,1-dioxide [Sulpholane] Xn; R22 S: (2) - 25 Conc>=25%: Xn; R22 Eu - - - - - - - -
tris(2,3-dibromopropyl) phosphate [TBPP; 2,3-
dibromo-1-propanol-phosphate (3:1); tris(2,3-
dibromopropyl) phosphoric acid ester; phosphoric
acid, tris(2,3-dibromo-propyl) ester; Carc. Cat. 2; R45 T; R: 45-68 Conc>=1%: T;R45; R68
126-72-7 tris(dibromopropyl) phosphate] Muta. Cat. 3; R68 S: 45-53-60 >=0.1% Conc <1%: T;R45 N - - - - - - - -
Carc. Cat. 3; R40 Conc>=25%: Xn; R40; R20/22; R38
Xn; R20/22 Xn >=20%Conc<25%: Xn; R40; R38
126-73-8 Phosphoric acid, tributyl ester [Tributyl phosphate] Xi; R38 R: 20/22-38-40 >=1%Conc<20%: Xn; R40 N; A Tributyl phosphate 0.2 2.2 - - - - -
Conc>=7%: T+; R27/28
Demeton-S (ISO) [Diethyl-S-2-ethylthioethyl T+ ; R: 27/28 , >=1%Conc<7%: T; R24/25
126-75-0 phosphorothioate] T+; R27/28 S: (1/2) - 28 - 36/37 - 45 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
F; T
F; R11 R: 11-23/24/25-43
alpha-Methacrylonitrile [2-Methyl-2-propene nitrile; T; R23/24/25 S: (1/2-)9-16-18-29-45; Conc>=1%: T; R23/24/25; R43
126-98-7 Methylacrylonitrile] R43 Note: D >=0.2%Conc<1%: Xn; R20/21/22; R43 Eu; A Methylacrylonitrile 1 2.7 - - - Sk -

F; T Conc>=25%: T; R45; R20/22; R48/20;

F; R11 R: 45-11-20/22-36/37/38- R36/37/38
Carc. Cat. 2; R45 48/20 >=20%Conc<25%: T; R45; R48/20; R36/37/38
Xn; R20/22-48/20 S: 53-45; Notes: >=10%Conc<20%: T; R45; R48/20
126-99-8 2-Chlorobuta-1,3-diene [Chloroprene (stabilised)] Xi; R36/37/38 D; E >=0.1%Conc<10%: T; R45 Eu; A b-Chloroprene 10 36 - - - Sk -
Tetrachloroethylene [Ethene, tetrachloro; Carc. Cat. 3; R40 Xn ; N ; R: 40 - 51/53,
127-18-4 Perchloroethylene] N; R51-53 S: (2) - 23 - 36/37 - 61 Conc>=1%: Xn; R40 Eu; A Perchloroethylene 50 340 150 1020 3 - -
Conc>=25%: T; R61; R20/21; R48/20/21
Repr. Cat. 2; R61 T >=10%Conc<25%: T; R61; R48/20/21 Dimethyl
127-19-5 Acetamide, N,N-dimethyl- [N,N-Dimethylacetamide] Xn; R20/21-48/20/21 R: 61-20/21-48/20/21 >=0.5%Conc<10%: T; R61 N; A acetamide 10 36 - - - Sk -
Xi Conc>=20%: Xi; R41; R38
Dalapon-sodium [Sodium 2,2- Xi; R38-41 R: 38-41-52/53 >=10%Conc<20%: Xi; R41
127-20-8 dichloropropionate](Note: see also CAS No. 75-99-0) R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22 Conc>=25%: C; R34; R22; R42; R31
R31 C ; R: 22 - 31 - 34 - 42, >=10%Conc<25%: C; R34; R42; R31
C; R34 S: (1/2) - 7 - 22 - 26 - >=5%Conc<10%: Xn; R42; R36/38; R31
127-65-1 Chloramine T [Tosylchloramide sodium] R42 36/37/39 - 45 >=1%Conc<5%: Xn; R42; R31 Eu - - - - - - - -
Sodium 3-nitrobenzenesulphonate [Benzenesulfonic Xi, R36 Xi ; R: 36 - 43 Conc>=20%: Xi; R36; R43
127-68-4 acid, 3-nitro, sodium salt] R43 S: (2) - 24 - 26 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
2,6-Di-tert-butyl-p-
128-37-0 2,6-Di-tert-butyl-p-cresol A cresol - 10 - - - - -

8,9,10-Trinorborn-5-ene-2,3-dicarboxylic anhydride Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

[cis-Himic anhydride](Note: see also CAS No 826-62- Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
129-64-6 0 & 2746-19-2) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
T; R25 Conc>=25%: T; R25; R21; R36/37/38
Endothal sodium (ISO) [Disodium 7- Xn; R21 T ; R: 21 - 25 - 36/37/38, >=20%Conc<25%: Xn; R22; R36/37/38
129-67-9 oxabicyclo(2.2.1)heptane-2,3-dicarboxylate] Xi; R36/37/38 S: (1/2) - 36/37/39 - 45 >=3%Conc<20%: Xn; R22 Eu - - - - - - - -
Xn
Leucomalachite green [N,N,N',N'-Tetramethyl-4,4'- Carc. Cat. 3; R40 R: 40-68
129-73-7 benzylidenedianiline] Muta. Cat. 3; R68 S: (2-)36/37 Conc>=1%: Xn; R40; R68 Eu - - - - - - - -

Page 92
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Menadione sodium bisulfite [2-Naphthalenesulfonic Xi; N
acid,1,2,3,4-tetrahydro-2-methyl-1,4-dioxo-, sodium Xi; R36/38 R: 36/38-50/53
130-37-0 salt] N; R50-53 S: (2-)24/25-60-61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -

131-11-3 Dimethyl phthalate A Dimethylphthalate - 5 - - - - -

Xn; N
Xn; R22 R: 22-50/53
131-17-9 Diallyl phthalate N; R50-53 S: (2-)24/25-60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Di-n-Pentyl phthalate (Note: see also CAS No. T; N
84777-06-0; 605-50-5 and n-Pentyl- Repr. Cat. 2; R60-61 R: 60-61-50
131-18-0 isopentylphthalate) N; R50 S: 53-45-61 Conc>=0.5%: T; R60; R61 Eu - - - - - - - -

Conc>=25%: T+; R40; R26; R24/25; R36/37/38

>=20%Conc<25%: T+; R40; R26; R21/22;
Carc. Cat. 3; R40 R36/37/38
T+; R26 T+ ; N ; R: 24/25 - 26 - >=7%Conc<20%: T+; R40; R26; R21/22
Sodium pentachlorophenolate [Sodium T; R24/25 36/37/38 - 40 - 50/53, >=3%Conc<7%: T; R40; R23; R21/22
pentachlorophenate](Note: see also CAS No 7778-73- Xi; R36/37/38 S: (1/2) - 22 - 28 - 36/37 - >=1%Conc<3%: T; R40; R23
131-52-2 6) N; R50-53 45 - 52 - 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
E; R3 E; T+; N
T+; R26/27/28 R: 3-26/27/28-33-51/53 Conc>=7%: T+; R26/27/28; R33
R33 S: (1/2-)27/28-35-36/37-45- >=1%Conc<7%: T; R23/24/25; R33
131-73-7 Bis(2,4,6-trinitrophenyl)amine [Hexyl] N; R51-53 61-63 >=0.1%Conc<1%; Xn; R20/21/22 Eu - - - - - - - -

T; N
T; R23/24/25 R: 23/24/25 - 50/53 Conc>=25%: T; R23/24/25
131-89-5 Dinex [2-Cyclohexyl-4,6-dinitrophenol] N; R50-53 S: (1/2) - 13 - 45 - 60 - 61 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
Conc>=25%: Xn; R22; R37/38; R41
Xn; R22 Xn; N >=20%Conc<25%: Xi; R37/38; R41
Xi; R37/38-41 R: 22 - 37/38 - 41 - 50 >=10%Conc<20%: Xi; R41
132-27-4 Sodium 2-biphenylate [2-Phenylphenol, sodium salt] N; R50 S: (2) - 22 - 26 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T
R: 45
3-Amino-9-ethyl carbazole [9-Ethylcarbazol-3- S: 53-45
132-32-1 ylamine] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Naptalam-sodium [Sodium N-naphth-1- Xn; R: 22,
132-67-2 ylphthalamate] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -

Carc. Cat. 3; R40 Conc>=25%: T; R40; R23; R41; R43

T; R23 T; N >=10%Conc<25%: Xn; R40; R20; R41; R43
Xi; R41 R: 23-40-41-43-50 >=5%Conc<10%: Xn; R40; R20; R36; R43
Captan (ISO) [1,2,3,6-Tetrahydro-N- R43 S: (1/2-)26-29-36/37/39-45- >=3%Conc<5%: Xn; R40; R20; R43
133-06-2 (trichloromethylthio)phthalimide] N; R50 61 >=1%Conc<3%: Xn; R40; R43 Eu;A Captan - 0.5 - - 2 Sk;Sen -
Carc. Cat. 3; R40
Xn; R20
Xi; R36 Xn; N Conc>=25%: Xn; R40; R20; R36; R43
R43 R: 20-36-40-43-50 >=20%Conc<25%: Xn; R40; R36; R43
133-07-3 Folpet (ISO) [N-(Trichloromethylthio)phthalimide] N; R50 S: (2-)36/37-46-61 >=1%Conc<20%: Xn; R40; R43 Eu - - - - - - - -
Xn ; R: 22 ,
134-31-6 Bis(8-hydroxyquinolinium) sulphate Xn; R22 S: (2) - 36 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53,
134-32-7 1-Naphthylamine [1-Naphthalenamine] N; R51-53 S: (2) - 24 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn
Xi; R36/38 R: 22 - 36/38 - 52/53 Conc>=25%: Xn; R22; R36/38
134-62-3 N,N-Diethyl-m-toluamide [DEET] R52-53 S: (2) - 61 >=20%Conc<25%: Xi; R36/38 Eu - - - - - - - -
Xn; R20/22 Xn ; N ; R: 20/22 - 50,
135-19-3 2-Naphthol [beta-Naphthol] N; R50 S: (2) - 24/25 - 61 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Carc. Cat. 3; R40
Xi; R36/38 Xn ; N ; R: 36/38 - 40 - 43 -
N-Phenyl-2-naphtylamine [N-2-Naphthylaniline; N- R43 51/53, Conc>=20%: Xn; R40, R36/38, R43 n-Phenyl-beta-
135-88-6 Phenyl-beta-naphtylamine] N; R51-53 S: (2) - 26 - 36/37 - 61 >=1%Conc<20%: Xn; R40, R43 Eu; A naphthylamine (d) - - - - 2 - -
Xi; R36/37/38 Xi ; N ; R: 36/37/38 - 43 -
R43 50/53, Conc>=20%: Xi; R36/37/38; R43
136-23-2 Zinc bis(dibutyldithiocarbamate) N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Page 93
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Erbon (ISO) [2-(2,4,5-Trichlorophenoxy)ethyl 2,2- Xn; R22 Xn ; N ; R: 22 - 51/53,
136-25-4 dichloropropionate] N; R51-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Sesone [Sodium2-(2,4-dichlorophenoxy-ethyl
136-78-7 sulphate] A Sesone - 10 - - - - -
Xi ; R: 36/37/38, Methyl 2-
137-05-3 Methyl 2-cyanoacrylate [Mecrilate] Xi; R36/37/38 S: (2) - 23 - 24/25 - 26 Conc>=10%: Xi; R36/37/38 Eu; A cyanoacrylate 2 9.1 4 18 - - -
T; N
Carc.Cat.2; R45 R: 45-23/24/25-51/53 Conc>=25%: T; R45; R23/24/25
2,4,5-Trimethylaniline (Note: see also CAS T; R23/24/25 S: 53-45-61 >=3%Conc<25%; T; R45; R20/21/22
137-17-7 No. 21436-97-5) N; R51-53 Note: E >=0.1%Conc<3%: T; R45 Eu - - - - - - - -

Conc>=25 %: Xn; R20/22; R48/22; R36/38;

Xn; R20/22-48/22 Xn; N R43
Xi; R36/38 R: 20/22-36/38-43-48/22- >=20%Conc<25%: Xn; R48/22; R36/38; R43
R43 50/53 >=10%Conc<20%: Xn; R48/22; R43
137-26-8 Thiram [Tetramethylthiuram disulphide] N; R50-53 S: (2-)26-36/37-60-61 >=1%Conc<10%: Xi; R43 Eu; A Thiram - 1 - - - - -

Conc>=25%: T+; R26; R22; R48/22; R37; R41;

R43
>=20%Conc<25%: T+; R26; R48/22; R37; R41;
R43
T+; R26 T+; N >=10%Conc<20%: T+; R26; R48/22; R41; R43
Xn; R22-48/22 R: 22-26-37-41-43-48/22- >=7%Conc<10%: T+; R26; R36; R43
Xi; R37-41 50/53 >=5%Conc<7%: T; R23; R36; R43
R43 S: (1/2-)22-26-28-36/37/39- >=1%Conc<5%: T; R23; R43
137-30-4 Ziram (ISO) [Zinc bis dimethyldithiocarbamate] N; R50-53 45-60-61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
Xn; R22
C ; R34 C ; N ; R: 34 - 22 - 31 - 43 - Conc>=25%: C; R34; R22, R43; R31
R43 50/53 , >=10%Conc<25%: C; R34; R43; R31
Metam sodium (ISO) [Sodium R31 S: (1/2 - ) - 26 - 36/37/39 - >=5%Conc<10%: Xn; R43; R36/38; R31
137-42-8 methyldithiocarbamate] N ; R50-53 45 - 60 - 61 >=1%Conc<5%: Xi; R43; R31 Eu - - - - - - - -
138-22-7 n-Butyl lactate A n-Butyl lactate 5 30 - - - - -

N,N,N-Trimethylanilinium chloride [Benzenaminium, T ; R: 24/25; Conc>=25%: T; R24/25

138-24-9 N,N,N-trimethyl, chloride] T: R24/25 S: (1/2) - 25 - 39 - 45 - 53 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
R10 Xi ; N ; R: 10 - 38 - 43 -
p-Mentha-1,8(9)-diene [Limonene; Dipentene; trans-1- Xi; R38 50/53,
Methyl-4-(1-methylvinyl)cyclohexene](Note: see also R43 S: (2) - 24 - 37 - 60 - 61; Conc>=20%: Xi; R38; R43
138-86-3 CAS No 5989-27-5 & 5989-54-8) N; R50-53 Note: C >=1%Conc<20%: Xi; R43 Eu/N - - - - - - - -
Propazine [2-Chloro-4,6-bis(isopropylamino)-1,3,5- Carc. Cat. 3; R40 Xn ; N ; R: 40 - 50/53,
139-40-2 triazine] N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=1%: Xn; R40 Eu - - - - - - - -
T; N
Carc.Cat.2; R45 R: 45-22-51/53
Xn; R22 N; S: 53-45-61 Conc>=25%: T; R45; R22
139-65-1 4,4'-Thiodianiline and its salts R51-53 Note: E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
Xn; R21/22 C ; R: 21/22 - 34 - 43 - Conc>=25%: C; R34; R21/22; R43
C; R34 52/53, >=10%Conc<25%: C; R34; R43
2-Piperazine-1-ylethylamine [1-Piperazine R43 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%: Xi; R36/38; R43
140-31-8 ethanamine] R52-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 3; R40 Xn ; N ; R: 36/38 - 40 -
Monuron - TCA [3-(4-Chlorophenyl)-1,1- Xi; R36/38 50/53, Conc>=20%: Xn; R40, R36/38
140-41-0 dimethyluronium trichloroacetate] N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<20%: Xn; R40 Eu - - - - - - - -
T; R25 T
Fenaminosulf (ISO) [Sodium 4- Xn; R21 R: 21 - 25 - 52/53 Conc>=25%: T; R25; R21
140-56-7 dimethylaminobenzenediazosulphonate] R52-53 S: (1/2) - 36/37 - 45 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Xi; N Conc>=20%: Xi; R38; R41
4-(1,1,3,3-Tetramethylbutyl)phenol [4-tert- Xi; R38-41 R: 38-41-50/53 >=10%Conc<20%: Xi; R41
140-66-9 Octylphenol] N; R50-53 S: (2-)26-37/39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

F; R11 F ; Xn ; R: 11 - 20/21/22 -
Xn; R20/21/22 36/37/38 - 43 , Conc>=25%: Xn; R20/21/22; R36/37/38; R43
Xi; R36/37/38 S: (2) - 9 - 16 - 33 - 36/37; >=5%Conc<25%: Xi; R36/37/38; R43 5 Peak 20 Peak
140-88-5 Ethyl acrylate R43 Note: D >=1%Conc<5%: Xi; R43 Eu; A Ethyl acrylate limitation limitation - - - Sen -

Page 94
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
R15/29 Xn ; R: 15 - 29 - 21/22 -
Xn; R21/22 36/38 Conc>=25%: Xn; R21/22; R36/38
140-90-9 Sodium ethylxanthate [Sodium xanthogenate] Xi; R36/38 S: 3/9 - 24/25 - 36/37/39 >=20%Conc<25%: Xi; R36/38 N - - - - - - - -
Xn; R22 Xn; N
Proxan sodium (ISO) [Sodium isopropylxanthate; Xi; R38 R: 22 - 38 - 51/53 Conc>=25%: Xn; R22; R38
140-93-2 Sodium O-isopropyldithiocarbamate] N; R51-53 S: (2) - 13 - 61 >=20%Conc<25%: Xi; R38 Eu - - - - - - - -
Xi; R38 Xi Conc>=20%: Xi; R38; R43
141-27-5 2,6-Octadienal, 3,7-dimethyl-, (E)- R43 R: 38-43 >=1%Conc<20%: Xi; R43 N - - - - - - - -
R10 Xi ; R: 10 - 36/37/38 - 43,
Xi; R36/37/38 S: (2) - 9 ; Conc>=20%: Xi; R36/37/38; R43
141-32-2 n-Butyl acrylate R43 Note: D >=1%Conc<20%: Xi; R43 Eu; A n-Butyl acrylate 1 5 5 26 - - -
C Conc>=25%: C; R34; R20/21/22
Xn; R20/21/22 R: 20/21/22-34 >=10%Conc<25%: C; R34
141-43-5 2-Aminoethanol [Ethanolamine] C; R34 S: (1/2-)26-36/37/39-45 >=5%Conc<10%: Xi; R36/37/38 Eu; A Ethanolamine 3 7.5 6 15 - - -
F; R11 F ; C ; R: 11 - 14 - 34 ,
Sodium ethanolate [Sodium ethoxide](Note: see also R14 S: (1/2) - 8 - 16 - 26 - 43 - Conc>=10%: C; R34
141-52-6 CAS No 917-58-8) C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
T+; R28 T+ ; N ; R: 24 - 28 - 50/53 , >=3%Conc<7%: T; R25; R21
Dicrotophos (ISO) [(Z)-2-Dimethylcarbamoyl-1- T; R24 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<3%: T; R25
141-66-2 methylvinyl dimethyl phosphate] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R22 Eu; A Dicrotophos - 0.25 - - - Sk -
F ; C ; R: 11 - 34 ,
F; R11 S: (1/2) - 16 - 23 - 26 - 36 - Conc>=10%: C; R34
141-75-3 Butyryl chloride C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
F; R11
Xi; R36
R66 F; Xi
141-78-6 Acetic acid, ethyl ester [Ethyl acetate] R67 R: 11-36-66-67 Conc>=20%: Xi; R36 N/Eu; A Ethyl acetate 200 720 400 1440 - - -
R10 Xn ; R: 10 - 20/21/22,
141-79-7 4-Methylpent-3-en-2-one [Mesityl oxide] Xn; R20/21/22 S: (2) - 25 Conc>=5%: Xn; R20/21/22 Eu; A Mesityl oxide 15 60 25 100 - - -
Xn; R22. Xn ; N ; R: 22 - 37 - 43 -
Xi; R37 50/53 , Conc>=25%: Xn; R22; R37; R43
Nabam (ISO) [Disodium ethylenebis(N,N'- R43 S: (2 - ) - 8 - 24/25 - 46 - 60 - >=20%Conc<25%: Xi; R37; R43
142-59-6 dithiocarbamate)] N ; R50-53 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Repr. Cat. 3; R62-63

Xi; R36/38 Xn Conc>=20%: Xn; R62; R63; R36/38; R42/43
Piperazine dihydrochloride(Note: see also CAS No. R42/43 R: 36/38-42/43-62-63-52/53 >=5%Conc<20%: Xn; R62; R63; R42/43 Piperazine
142-64-3 6094-40-2, 1951-97-9) R52-53 S: (1/2-)22-36/37-45-63-61 >=1%Conc<5%: Xn; R42/43 Eu;A dihydrochloride - 5 - - - - -
F; R11
Xn; R65 F; Xn; N
Heptane [n-Heptane](Note: see also CAS No. 108-08- Xi; R38 R: 11-38-65-67-50/53
7, 464-06-2, 562-49-2, 565-59-3, 589-34-4,590-35-2, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38 Heptane (n-
142-82-5 591-76-4, 617-78-7 & 31394-54-4) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu;A Heptane) 400 1640 500 2050 - - -
F ; C ; R: 11 - 20/21/22 - 35 Conc>=25%: C; R35; R20/21/22
F; R11 , >=10%Conc<25%: C; R35
Xn; R20/21/22 S: (1/2) - 16 - 26 - 36/37 - >=5%Conc<10%: C; R34
142-84-7 Dipropylamine [1-Propanamine, n-propyl] C; R35 38 - 45 >=1%Conc<5%: Xi; R36/37/38 Eu - - - - - - - -
Xi; 36/37/38 Xi; N
N; R50-53 R: 36/37/38-50/53
142-90-5 Dodecyl methacrylate S: (2-)26-28-60-61 Conc>=10%: Xi; R36/37/38 Eu - - - - - - - -
R10 Xi
Xi; R36/37/38 R: 10-36/37/38-52/53
142-96-1 di-n-Butyl ether [Dibutyl ether] R52-53 S: (2-)61 Conc>=10%: Xi; R36/37/38 Eu - - - - - - - -
2-[2-(2-Butoxyethoxy)ethoxy]ethanol [TEGBE; Xi
Triethylene glycol monobutyl ether; Butoxytriethylene R: 41 Conc>=30%: Xi; R41
143-22-6 glycol] Xi; R41 S: (2-)26-39-46 >=20%Conc<30%: Xi; R36 Eu - - - - - - - -
Conc>=20%: T+; R26/27/28; R38
T+; R26/27/28 >=7%Conc<20%: T+; R26/27/28
Xi; R38 >=1%Conc<7%: T; R23/24/25
143-33-9 Sodium cyanide(Note: see also CAS No. 151-50-8) R32 T+; R: 26/27/28-32-38 >=0.1%Conc<1%: Xn; R20/21/22 V Cyanides (as CN) - 5 - - - Sk -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Chlordecone (ISO)
[Perchloropentacyclo[5,3,0,02,6,03,9,04,8}decan-5- T; R24/25 T ; N ; R: 24/25 - 40 - 50/53, Conc>=25%: T; R40; R24/25
one; Decachloropentacyclo Carc. Cat. 3; R40 S: (1/2) - 22 - 36/37 - 45 - >=3%Conc<25%: Xn; R40; R21/22
143-50-0 (5.2.1.02,6,03,9,05,8)decan-4-one] N; R50-53 60 - 61 >=1%Conc<3%: Xn; R40 Eu - - - - - - - -

Morphothion [O,O-Dimethyl-S- T; R23/24/25 T ; N ; R: 23/24/25 - 50/53 , Conc>=25%: T; R23/24/25

144-41-2 (morpholinocarbonylmethyl)phosphorodithioate] N; R50-53 S: (1/2) - 13 - 45 - 60 - 61 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
T+ ; N ; R: 28 - 50, Conc>=7%: T+; R28
T+; R28 S: (1/2) - 20 - 22 - 26 - 45 - >=1%Conc<7%: T; R25
144-49-0 Fluoroacetic acid N; R50 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
Xn ; R: 21/22 ,
144-62-7 Oxalic acid Xn; R21/22 S: (2) - 24/25 Conc>=5%: Xn; R21/22 Eu; A Oxalic acid - 1 - 2 - - -
T; R25 Conc>=25%: T; R25; R21; R36/37/38
Endothal [7-Oxabicyclo(2.2.1)heptane-2,3- Xn; R21 T ; R: 21 - 25 - 36/37/38, >=20%Conc<25%: Xn; R22; R36/37/38
145-73-3 dicarboxylic acid] Xi; R36/37/38 S: (1/2) - 36/37/39 - 45 >=3%Conc<20%: Xn; R22 Eu - - - - - - - -
148-01-6 Dinitolmide A Dinitolmide - 5 - - - - -
N ; R: 50/53
148-79-8 Thiabendazol (ISO) [2-(Thiazole-4-yl)benzimidazole] N; R50-53 S: 60 - 61 Eu - - - - - - - -
Conc>=25%: Xn; R22; R41; R38
>=20%Conc<25%: Xi; R41; R38
Disul [2-(2,4- Dichlorophenoxy)ethyl Xn; R22 Xn ; R: 22 - 38 - 41 , >=10%Conc<20%: Xi; R41
149-26-8 hydrogensulphate; 2,4-Des] Xi; R38-41 S: (2) - 26 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; R43 Xi ; N ; R: 43 - 50/53,
149-30-4 Benzothiazole-2-thiol [2(3H)-Benzothiazolethione] N; R50 - 53 S:(2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Repr. Cat. 3; R62-63 Xn Conc>=20% Xn; R62; R63; R38
149-57-5 Hexanoic acid, 2-ethyl- [2-Ethylhexanoic acid] Xi; R38 R: 38-62-63 >=5%Conc<20%: Xn; R62; R63 N - - - - - - - -
Xn; R22
Carc. Cat. 3; R40 Xn ; N ; R: 22 - 40 - 50/53, Conc>=25%: Xn; R40, R22
150-68-5 Monuron (ISO) [3-(4-Chlorophenyl)-1,1-dimethylurea] N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<25%: Xn; R40 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 36 - 43, Conc>=25%: Xn; R22; R36; R43
Mequinol [4-Methoxyphenol; Hydroquinone Xi; R36 S: (2) - 24/25 - 26 - 37/39 - >=20%Conc<25%: Xi; R36; R43
150-76-5 monomethyl ether] R43 46 >=1%Conc<20%: Xi; R43 Eu; A 4-Methoxyphenol - 5 - - - - -
Conc>=25%: Xn; R21/22; R37/38; R41
>=20%Conc<25%: Xi; R37/38; R41
Xn; R21/22 >=10%Conc<20%: Xi; R41
151-21-3 Sodium lauryl sulphate Xi; R37/38-41 Xn; R: 21/22-37/38-41 >=5%Conc<10%: Xi; R36 V - - - - - - - -

151-50-8 Cyanides (as CN) A Cyanides (as CN) - 5 - - - Sk -

Conc>=20%: T+; R26/27/28; R38
T+; R26/27/28 >=7%Conc<20%: T+; R26/27/28
Potassium cyanide(Note: see also CAS No. 143-33- Xi; R38 >=1%Conc<7%: T; R23/24/25
151-50-8 9) R32 T+; R: 26/27/28-32-38 >=0.1%Conc<1%: Xn; R20/21/22 V Cyanides (as CN) - 5 - - - Sk -

Conc>=10%: T+; R45; R46; R26/27/28; R34

F; R11 >=7%Conc<10%: T+; R45; R46; R26/27/28;
Carc. Cat. 2; R45 R36/38
Muta. Cat. 2; R46 F ; T+ ; N ; R: 45 - 46 - 11 - >=5%Conc<7%: T; R45; R46; R23/24/25;
T+; R26/27/28 26/27/28 - 34 - 51/53 , R36/38
C; R34 S: 53 - 45 - 61 ; >=1%Conc<5%: T; R45; R46; R23/24/25
151-56-4 Ethyleneimine [Aziridine] N; R51-53 Notes: D; E >=0.1%Conc<1%: T; R45; R46; R20/21/22 Eu; A Ethylenimine 0.5 0.88 - - 3 Sk -
151-67-7 Halothane A Halothane 0.5 4.1 - - - - -
Conc>=7%: T+; R27/28
T+ ; R: 27/28 , >=1%Conc<7%: T; R24/25
152-16-9 Schradan (ISO) [Octamethylpyrophosphoramide] T+; R27/28 S: (1/2) - 36/37 - 38 - 45 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
Muta. Cat. 3; R68
Xn; R20/21/22 Xn Conc>=25%: Xn; R68; R20/21/22; R36; R43
Xi; R36 R: 68-20/21/22-36-43 >=20%Conc<25%: Xn; R68; R36; R43
156-43-4 4-Ethoxyaniline [p-Phenetidine] R43 S: (2-)36/37-46 >=1%Conc<20%:Xn; R68; R43 Eu - - - - - - - -

F; R11 F; Xn
cis-Dichloroethylene (Note: see also CAS No. Xn; R20 R: 11-20-52/53
156-59-2 540-59-0 and 156-60-5) R52-53 S: (2-)7-16-29-61; Note: C Conc>=12.5%: Xn; R20 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F; Xn
F; R11 R: 11-20-52/53
trans-Dichloroethylene (Note: see also CAS No. Xn; R20 S: (2-)7-16-29-61;
156-60-5 540-59-0 and 156-59-2) R52-53 Note: C Conc>=12.5%: Xn; R20 Eu - - - - - - - -
Conc>=25%: Xn; R22; R37; R41
>=20%Conc<25%: Xi; R37; R41
Xn; R22 Xn ; R: 22 - 37 - 41 , >=10%Conc<20%: Xi; R41 Calcium
156-62-7 Calcium cyanamide Xi; R37-41 S: (2) - 22 - 26 - 36/37/39 >=5%Conc<10%: Xi; R36 Eu; A cyanamide - 0.5 - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 50/53,
192-97-2 Benzo[e]pyrene N; R50-53 S: 53 – 45 - 60 - 61 Conc>=0.1%: T; R45 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 50/53,
205-82-3 Benzo[j]fluoranthene N; R50-53 S: 53 – 45 - 60 - 61 Conc>=0.1%: T; R45 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 50/53,
205-99-2 Benzo[b]fluoranthene [Benzo[e]acephenanthrylene] N; R50-53 S: 53 – 45 - 60 - 61 Conc>=0.1%: T; R45 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 50/53,
207-08-9 Benzo[k]fluoranthene N; R50-53 S: 53 – 45 - 60 - 61 Conc>=0.1%: T; R45 Eu - - - - - - - -
Carc. Cat. 2; R45 T; N
Muta. Cat. 3; R68 R: 45-68-50/53 Conc>=1%: T; R45; R68
218-01-9 Chrysene N; R50-53 S: 53-45-60-61 >=0.1%Conc<1%: T: R45 Eu; A Chrysene (d) - - - - 3 - -

F; R11 F ; R: 11 - 52/53 ,
287-92-3 Cyclopentane R52-53 S: (2) - 9 - 16 - 29 - 33 - 61 Eu; A Cyclopentane 600 1720 - - - - -
Repr. Cat. 3; R63 Conc>=25%: Xn; R22; R63; R36
Xn; R22 Xn; R: 22 - 36 - 63, >=20%Conc<25%: Xn; R63; R36
288-88-0 1,2,4-Triazole Xi; R36 S: (2) - 36/37 >=5%Conc<20%: Xn; R63 Eu - - - - - - - -
C; N
C; R34 R: 21/22-34-50/53 Conc>=25%: C; R34; R21/22
Xn; R21/22 S: (1/2-)22-26-36/37/39-45- >=10%Conc<25%: C; R34
294-90-6 1,4,7,10-Tetraazacyclododecane N; R50-53 60-61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
T+ ; N ; R: 27/28 - 50 , Conc>=7%: T+; R27/28
Isobenzan (ISO) [1,3,4,5,6,7,8,8-Octachloro- T+; R27/28 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R24/25
297-78-9 1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran] N; R50 61 >= 0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
Conc>=7%: T+; R27/28
O,O-Diethyl O-pyrazin-2-yl phosphorothioate T+ ; R: 27/28 , >=1%Conc<7%: T; R24/25
297-97-2 [Thionazin] T+; R27/28 S: (1/2) - 36/37/39 - 38 - 45 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -

R5 Conc>=25%: T+; R26/28; R24; R48/22

R10 >=10%Conc<25%: T+; R26/28; R21; R48/22
T+; R26/28 T+; N >=7%Conc<10%: T+; R26/28; R21
T; R24 R: 5-10-24-26/28-48/22- >=3%Conc<7%: T; R23/25; R21
Parathion - methyl (ISO) [O,O-Dimethyl O-4- Xn; R48/22 50/53 >=1%Conc<3%: T; R23/25
298-00-0 nitrophenyl phosphorothioate; Methyl parathion] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=0.1%Conc<1%: Xn; R20/22 Eu; A Methyl parathion - 0.2 - - - Sk -

T+; N Conc>=7%: T+; R27/28

Phorate (ISO) [O,O-Diethyl ethylthiomethyl T+; R27/28 R: 27/28-50/53 >=1%Conc<7%: T; R24/25
298-02-2 phosphorodithioate] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=0.1%Conc<1%: Xn; R21/22 Eu; A Phorate - 0.05 - 0.2 - Sk -
T+ ; N ; R: 27/28 - 50 , Conc>=7%: T+; R27/28
Demeton-O (ISO) [O,O-Diethyl-O-2-ethylthioethyl T+; R27/28 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R24/25
298-03-3 phosphorothioate] N; R50 61 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
T+ ; N ; R: 27/28 - 50/53, Conc>=7%: T+; R27/28
Disulfoton (ISO) [O,O-Diethyl 2-ethylthioethyl T+; R27/28 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R24/25
298-04-4 phosphorodithioate] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R21/22 Eu; A Disulfoton - 0.1 - - - - -
Xn ; R: 22
299-42-3 Ephedrine Xn; R22 S: (2) - 22 - 25 Conc>=25%: Xn; R22 Eu - - - - - - - -
T+; N Conc>=7%: T+; R26/27/28
Potasan [O,O-Diethyl O-(4-methylcoumarin-7-yl) T+; R26/27/28 R: 26/27/28-50/53 >=1%Conc<7 %: T; R23/24/25
299-45-6 phosphorothioate] N; R50-53 S: (1/2-)13-28-45-60-61 >=0.1%Conc<1 %: Xn; R20/21/22 Eu - - - - - - - -
Xn; N
Fenchlorphos (ISO) [O,O-Dimethyl O-2,4,5- Xn; R21/22 R: 21/22-50/53
299-84-3 trichlorophenyl phosphorothioate; Ronnel] N; R50-53 S: (2-)25-36/37-60-61 Conc>=25%: Xn; R21/22 Eu; A Ronnel - 10 - - - - -
Crufomate (ISO) [4-tert-Butyl-2-chlorophenyl methyl Xn; R21/22 Xn ; N ; R: 21/22 - 50/53,
299-86-5 methylphosphoramidate] N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=25%: Xn; R21/22 Eu; A Crufomate - 5 - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R21/22 Xn; N
Naled (ISO) [1,2-Dibromo-2,2-dichloroethyl dimethyl Xi; R36/38 R: 21/22-36/38-50 Conc>=25%: Xn; R21/22; R36/38
300-76-5 phosphate] N; R50 S: (2-)36/37-61 >=20%Conc<25 %: Xi; R36/38 Eu; A Naled - 3 - - - Sk -

Carc. Cat. 3; R40 Conc>=25%: T; R40; R61; R62; R68; R20;

Muta. Cat. 3; R68 R48/22; R33
Repr. Cat. 1; R61 >=10%Conc<25%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R48/22; R33
Xn; R20-48/22 T; N >=5%Conc<10%: T; R40; R61; R62; R68; R33
R33 R: 45-23/24/25-43-48/25-68- >=1%Conc<5%: T; R40; R61; R68; R33
301-04-2 Acetic acid, lead(2+) salt [Lead di(acetate)] N; R50-53 50-53 >=0.5%Conc<1%: T; R61 N/Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
301-08-6 Hexanoic acid, 2-ethyl-, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
T ; N ; R: 24/25 - 50 ,
Oxydemeton methyl [S-2-(Ethylsulphinyl)ethyl O,O- T; R24/25 S: (1/2) - 23 - 36/37 - 45 - Conc>=25%: T; R24/25
301-12-2 dimethyl phosphorothioate] N; R50 61 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -

Conc>=25%: T; R45; R68; R23/24/25;

R48/23/25; R34; R43
R10 >=10%Conc<25%: T; R45; R68; R48/23/25;
Carc. Cat. 2; R45 R34; R20/21/22; R43
Muta. Cat. 3; R68 >=5%Conc<10%: T; R45; R68; R20/21/22;
T; R23/24/25-48/23/25 R48/20/22; R36/38; R43
C; R34 T; N >=3%Conc<5%: T; R45; R68; R20/21/22;
R43 R: 10-45-23/24/25-34-43- R48/20/22; R43
302-01-2 Hydrazine N; R50-53 48/23/25-68-50-53 >=1%Conc<3%: T; R45; R68; R4 N/Eu Hydrazine 0.01 0.013 - - 2 Sk;Sen -
Conc>=25%: T; R25; R36/38
T; R25 T ; R: 25 - 36/38 , >=20%Conc<25%; Xn; R22; R36/38
302-17-0 Chloral hydrate [2,2,2-Trichloroethane-1,1-diol] Xi; R36/38 S: (1/2) - 25 - 45 >=3%Conc <20%: Xn; R22 Eu - - - - - - - -
Conc>=7%: T+; R26/28
T+ ; R: 26/28 , >=1%Conc<7%: T; R23/25
302-27-2 Aconitine T+; R26/28 S: (1/2) - 24 - 45 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Xn
Repr. Cat. 3; R62 R: 62-53
302-97-6 3-Oxoandrost-4-ene-17-beta-carboxylic acid R53 S: (2-)36/37-61 Conc>=5%: Xn; R62 Eu - - - - - - - -
Carc. Cat. 3; R40
HCFC-123 (gas) [Ethane, 2,2-dichloro-1,1,1-trifluoro R64 Xn; R40; R64; R48/20 Conc>=5%: Xn; R40; R64; R48/20
306-83-2 (gas)] Xn; R48/20 S: 3/9; 23; 38; 41 >=1%Conc<5%: Xn; R40; R64 N - - - - - - - -
Carc. Cat. 3; R40
HCFC-123 (liquid) [Ethane, 2,2-dichloro-1,1,1-trifluoro R64 Xn; R40; R64; R48/20 Conc>=10%: Xn; R40; R64; R48/20
306-83-2 (liquid)] Xn; R48/20 S: 3/9; 23; 38; 41 >=1%Conc<10%: Xn; R40; R64 N - - - - - - - -

T ; N ; R: 24/25 - 40 - Conc>=25%: T; R40; R24/25-48/24/25

T; R24/25-48/24/25 48/24/25 - 50/53 , >=10%Conc<25%: T; R40; R48/24/25; R21/22
Carc. Cat. 3; R40 S: (1/2) - 22 - 36/37 - 45 - >=3%Conc<10%: Xn; R40; R21/22; R48/21/22
309-00-2 Aldrin (ISO) N; R50-53 60 - 61 >=1%Conc<3%: Xn; R40; R48/21/22 Eu; A Aldrin - 0.25 - - 3 Sk -
314-40-9 Bromacil A Bromacil 1 11 - - - - -
Conc>=25%: T+; R28; R21
Mexacarbate (ISO) [4-Dimethylamino-3,5-xylyl T+; R28 T+ ; N ; R: 21 - 28 - 50/53, >=7%Conc<25%: T+; R28
methylcarbamate; 3,5-Dimethyl-4- Xn; R21 S: (1/2) - 36/37 - 45 - 60 - >=1%Conc<7%: T; R25
315-18-4 dimethylaminophenyI N-methylcarbamate] N; R50-53 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
T+; R28 T+ ; N ; R: 24 - 28 - 50/53 , >=3%Conc<7%: T; R25; R21
Trichloronate (ISO) [O-Ethyl O-2,4,5-trichlorophenyl T; R24 S: (1/2) - 23 - 28 - 36/37 - >=1%Conc<3%: T; R25
327-98-0 ethylphosphonothioate] N; R50-53 45 - 60 - 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

T; R23/24/25 T ; N ; R: 23/24/25 - 33 - Conc>=25%: T; R23/24/25; R33

2,5-Dinitrophenol(Note: see also CAS No 66-56-8; R33 51/53 >=3%Conc<25%: Xn; R20/21/22; R33
329-71-5 573-56-8; 577-71-9; & dinitrophenol, salts of) N; R50-53 S: (1/2) - 28 - 37 - 45 - 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40 Xn; N Conc>=25%: Xn; R40; R22; R48/22
Diuron (ISO) [3-(3,4-Dichlorophenyl)-1,1- Xn; R22-48/22 R: 22-40-48/22-50/53 >=10%Conc<25%: Xn; R40; R48/22
330-54-1 dimethylurea] N; R50-53 S: (2-)13-36/37-46-60-61 >=1%Conc<10%: Xn; R40 Eu;A Diuron - 10 - - - - -

Repr. Cat. 2; R61 Conc>=25%: T; R61; R40; R62; R22; R48/22

Repr. Cat. 3; R62 >=10%Conc<25%: R61; R40; R62; R48/22
Linuron (ISO) Carc. Cat. 3; R40 T; N >=5%Conc<10%: T; R61; R40; R62
Xn; R22-48/22 R: 61-22-40-48/22-62-50/53 >=1%Conc<5%: T; R61; R40
330-55-2 [3-(3,4-Dichlorophenyl)-1-methoxy-1-methylurea] N; R50-53 S: 53-45-60-61; Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Xn; R22 Xn ; T; N ; R: 22 - 48/25 -
Diazinon (ISO) [O,O-Diethyl O-2-isopropyl-6- T; R48/25 50/53 ,
333-41-5 methylpyrimidin-4-yl phosphorothioate] N; R50-53 S: (2) - 24/25 - 60 - 61 Conc>=25%: Xn; R22 Eu; A Diazinon - 0.1 - - - Sk -
T ; R: 45,
334-88-3 Diazomethane Carc. Cat. 2; R45 S: 53 - 45 Conc>=0.1%: T; R45 Eu; A Diazomethane 0.2 0.34 - - 3 - -
353-50-4 Carbonyl fluoride A Carbonyl fluoride 2 5.4 5 13 - - -
Conc>=7%: T+; R26/28
T+; R26/28 T+ ; R: 26/28 - 52/53, >=1%Conc<7%: T; R23/25
357-57-3 Brucine [2,3-Dimethoxystrychnine] R52-53 S: (1/2) - 13 - 45 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
N
R: 51/53
362-03-8 3-(Phenothiazin-10-yl)propionic acid N; R51-53 S: 24/25-61 Eu - - - - - - - -

Conc>=25%: T; R23/25; R21; R36/37/38; R43

T; R23/25 >=20%Conc<25%: Xn; R20/22; R36/37/38;
Xn; R21 R43
Xi; R36/37/38 T >=3%Conc<20%: Xn; R20/22; R43
367-51-1 Acetic acid, mercapto-, monosodium salt R43 R: 21-23/25-36/37/38-43 >=1%Conc<3%: Xi; R43 N - - - - - - - -
Conc>=10%: T+; R39/26/27/28
T+ ; R: 39/26/27/28 , >=1%Conc<10%: T; R39/23/24/25
371-86-8 Mipafox [NN'-di-Isopropylphosphorodiamidic fluoride] T+; R39/26/27/28 S: (1/2) - 13 - 45 >=0.1%Conc<1%: Xn; R68/20/21/22 Eu - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
373-02-4 Acetic acid, nickel(2+) salt R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
Perfluoroisobutylen 0.01 Peak 0.082 Peak
382-21-8 Perfluoroisobutylene A e limitation limitation - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 22 - 43 -
Xn; R22 51/53 , Conc>=25%: T; R45; R22; R43
Xi; R43 S: 53 - 45 - 61 ; >=1%Conc<25%: T; R45; R43
399-95-1 4-Amino-3-fluorophenol N; R51-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
F
R: 11
406-58-6 1,1,1,3,3-Pentafluorobutane F; R11 S: (2-)3-9-16-41 Eu - - - - - - - -
T; R25 Conc>=25%: T; R25; R21; R36/38; R43
Xn; R21 >=20%Conc<25%: Xn; R22; R36/38; R43
Xi; R36/38 T ; R: 21 - 25 - 36/38 - 43 , >=3%Conc<20%: Xn; R22; R43
420-04-2 Cyanamide [Carbanonitril] R43 S: (1/2) - 3 - 22 - 36/37 - 45 >=1%Conc<3%: Xi; R43 Eu; A Cyanamide - 2 - - - - -
Xn; N
Xn; R22 R: 22-51/53
444-14-4 2-Bromo-4,6-difluoroaniline N; R51-53 S: (2-)25-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
F+; T; N
F+; R12 R: 12-23-50/53
T; R23 S: (1/2-)9-16-23-33-45-63- Conc>=5%: T; R23
460-19-5 Oxalonitrile [Cyanogen] N; R50-53 60-61 >=0.5%Conc<5%: Xn; R20 Eu;A Cyanogen 10 21 - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
R10
Xn; R22-48/22 Conc>=25%: Xn; R22-48/22; R38; R43
Xi; R38 Xn; N >=20%Conc<25%: Xn; R48/22; R38; R43
R43 N; R: 10-22-38-43-48/22-50/53 >=10%Conc<20%: Xn; R48/22; R43
461-96-1 1-Bromo-3,5-difluorobenzene R50-53 S: (2-)24-36/37-60-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
F; R11 F ; Xn ; R: 11 - 20/22 ,
463-04-7 Pentyl nitrite(Note: see also CAS No 110-46-3) Xn; R20/22 S: (2) - 16 - 24 - 46 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
463-51-4 Ketene A Ketene 0.5 0.86 1.5 2.6 - - -
Xn; R20/21/22 Xn ; R: 20/21/22 - 32 -
R32 52/53,
463-56-9 Thiocyanic acid R52-53 S: (2) - 13 - 61 Conc>=25%: Xn; R20/21/22; R32 Eu - - - - - - - -
T; R23 Conc>=25%: T; R23; R22; R36/37/38
Xn; R22 T ; R: 22 - 23 - 36/37/38, >=20%Conc<25%: Xn; R20; R36/37/38
463-71-8 Thiocarbonyl chloride [Thiophosgene] Xi; R36/37/38 S: (1/2) - 7 - 9 - 36/37 - 45 >=3%Conc<20%: Xn; R20 Eu - - - - - - - -
F+; N
F+; R12 R: 12 - 51/53
463-82-1 Neopentane [2,2-Dimethylpropane] N; R51-53 S: (2) - 9 - 16 - 33 - 61 Eu - - - - - - - -
F; R11
Xn; R65 F; Xn; N
2,2,3-Trimethylbutane(Note: see also CAS No. 142- Xi; R38 R: 11-38-65-67-50/53
82-5, 108-08-7, 562-49-2, 565-59-3, 589-34-4,590-35- R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
464-06-2 2, 591-76-4, 617-78-7 & 31394-54-4) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -

Isodrin [(1alpha,4alpha,4abeta,5beta,8beta,8abeta)-
1,2,3,4,10,10-Hexachloro-1,4,4a,5,8,8a-hexahydro-
1,4:5,8-dimethanonaphthalene; 1,4:5,8- T+; N
Dimethanonaphthalene, 1,2,3,4,10,10-hexachloro- R: 26/27/28-50/53 Conc>=7%: T+; R26/27/28
1,4,4a,5,8,8a-hexahydro, T+; R26/27/28 S: (1/2-)13-28-36/37-45-60- >=1%Conc<7%: T; R23/24/25
465-73-6 (1alpha,4alpha,4abeta,5beta,8beta,8abeta)] N; R50-53 61 >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
N ; R: 51/53,
467-69-6 Flurenol [9-Hydroxy-9H-fiuorene-9-carboxylic acid] N: R51-53 S: 61 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
T+; R28 T+ ; N ; R: 24 - 28 - 50/53 , >=3%Conc<7%: T; R25; R21
Chlorfenvinphos (ISO) [2-Chloro-1-(2,4 T; R24 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<3%: T; R25
470-90-6 dichlorophenyl) vinyl diethyl phosphat] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
E; R3 E; T Conc>=25%: T; R23/24/25; R33
T; R23/24/25 R: 3-23/24/25-33 >=3%Conc<25%: Xn; R20/21/22; R33
479-45-8 N-Methyl-N-2,4,6-tetranitroaniline [Tetryl] R33 S: (1/2-)35-36/37-45-63 >=1%Conc<3%: Xn; R33 Eu;A Tetryl - 1.5 - - - Sen -
N
1-(4-Methoxy-5-benzofuranyl)-3-phenyl-1,3- R: 50/53
484-33-3 propanedione N; R50-53 S: 60-61 Eu - - - - - - - -
T; N
Repr. Cat. 2; R61 R: 61 - 21/22 - 50/53
Binapacryl (ISO) [2-sec-Butyl-4,6-dinitrophenyl-3- Xn; R21/22 S: 53 - 45 - 60 - 61 ; Conc>=25%: T; R61; R21/22
485-31-4 methylcrotonate] N; R50-53 Note: E >=0.5%Conc<25%: T; R61 Eu - - - - - - - -
Carc. Cat. 3; R40
4,4'-Carbonimidoylbis N,N-dimethylaniline Xn; R22 Xn ; N ; R: 22 - 36 - 40 - Conc>=25%: Xn; R40; R22; R36
[Benzenamine, 4,4'-carbonimidoylbis[N,N-dimethyl; Xi; R36 51/53, >=20%Conc<25%: Xn; R40; R36
492-80-8 Auramine] N; R51-53 S: (2) - 36/37 - 61 >=1%Conc<20%: Xn; R40 Eu - - - - - - - -
Xn ; R: 20/22 ,
495-48-7 Azoxybenzene Xn; R20/22 S: (2) - 28 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Muta. Cat. 3; R68
Xn; R22 Xn; N Conc>=25%: Xn; R68; R22; R38
Xi; R38 R: 22-38-68-50/53 >=20%Conc<25%: Xn; R68; R38
495-54-5 Chrysoidine [4-(Phenylazo)benzene-1,3-diamine] N; R50-53 S: (2-)23-26-36/37-46-60-61 >=1%Conc<20%: Xn; R68 Eu - - - - - - - -
Benquinox (ISO) [p-Benzoquinone 1- T; R25 T ; R: 21 - 25 , Conc>=25%: T; R25; R21
495-73-8 benzoylhydrazone 4-oxime] Xn; R21 S: (1/2) - 36/37 - 45 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Conc>=20%: Xi; R41; R37
Xi >=10%Conc<20%: Xi; R41
497-19-8 Carbonic acid, disodium salt [Sodium carbonate] Xi; R37-41 R: 37-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Chlorthion [O-(3-chloro-4-nitrophenyl) O,O-Dimethyl Xn; N
phosphorothioate](Note: Common name not adopted Xn; R20/21/22 R: 20/21/22-50/53
500-28-7 by ISO) N; R50-53 S: (2-)13-60-61 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
C; N
C; R34 R: 34-50/53 Conc>=10%: C; R34
501-53-1 Benzyl chloroformate N; R50-53 S: (1/2-)26-45-60-61 >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -
Xn ; R: 22 ,
502-55-6 Dixanthogen [O,O-Diethyl dithiobis(thioformate)] Xn; R22 S: (2) - 24 Conc>=25%: Xn; R22 Eu - - - - - - - -
F; R11 F ; Xn ; R: 11 - 20/21/22,
503-30-0 1,3-Propylene oxide Xn; R20/21/22 S: (2) - 9 - 16 - 26 - 29 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
504-29-0 2-Aminopyridine A 2-Aminopyridine 0.5 2 - - - - -
0.3 Peak 0.75 Peak
506-77-4 Cyanogen chloride A Cyanogen chloride limitation limitation - - - - -
Bufa-4,20,22-trienolide,6-(acetyloxy)-3-(beta-D- Conc>=7%: T+; R28
glucopyranosyloxy)-8,14-dihydroxy, (3beta 6beta) T+ ; R: 28 , >=1%Conc<7%: T; R25
507-60-8 [Red squill; Scilliroside] T+; R28 S: (1/2) - 36/37 - 45 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
Tetranitromethane
509-14-8 Tetranitromethane A (h) 1 8 - - - - -

Chlorobenzilate (ISO) [Ethyl 4,4'-dichlorobenzilate; Xn; R22 Xn ; N ; R: 22 - 50/53,

510-15-6 Ethyl 2,2-di(4-chlorophenyl)-2-hydroxyacetate] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, lead(2+) Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
512-26-5 salt (2:3) R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
F ; C ; N ; R: 11 - 20/22 - 35 -
F; R11 50 , Conc>=25%: C; R35; R20/22
Xn; R20/22 S: (1/2) - 9 - 16 - 26 - 28 - >=10%Conc<25%: C; R35
(S)-sec-Butylamine [(S)-2-Aminobutane](Note: see C; R35 36/37/39 - 45 - 61; >=5%Conc<10%: C; R34
513-49-5 also CAS No 13250-12-9 & 13952-84-6) N; R50 Note: C >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Xn ; R: 22 ,
513-77-9 Barium carbonate Xn; R22 S: (2) - 24/25 Conc>=25%: Xn; R22 Eu - - - - - - - -
Carc. Cat. 2; R49
Muta. Cat. 3; R68
Repr. Cat. 2; R60 T; N Conc>=1%: T; R49; R60; R68; R42/43
R42/43 R: 49-60-42/43-68-50/53 >=0.5%Conc<1%: T; R49; R60
513-79-1 Cobalt carbonate N; R50-53 S: 53-45-60-61 >=0.01%Conc<0.5%: T; R49 Eu - - - - - - - -

Xi; R43
This substance has only been
assessed against the single
endpoint of skin sensitisation.
1-Phenanthrenecarboxylic acid, This substance has not been
1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7- subject to a complete assessment
(1-methylethyl)-, [1R- for hazard classification in
(1.alpha.,4a.beta.,4b.alpha.,10a.alpha.)]- [Abietic accordance with the approved
514-10-3 acid] criteria Xi; R:43 Conc>=1%: Xi; R43 N - - - - - - - -
3-Acetyl-6-methyl-2H-pyran-2,4(3H)-dione Xn ; R: 22 ,
520-45-6 [Dehydracetic acid] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
525-66-6 Propranolol A Propranolol 0.188 2 0.565 6 - - -

T ; N ; R: 24/25 - 34 - 51/53, Conc>=25%: T; R24/25; R34

2,3-Xylenol [2,3-Dimethylphenol](Note: see also CAS T; R24/25 S: (1/2) - 26 - 36/37/39 - 45 - >=10%Conc<25%: C; R34; R21/22
No 95-65-8, 95-87-4, 105-67-9, 576-26-1, 1300-71-6 C; R34 61; >=5%Conc<10%: Xn; R21/22; R36/38
526-75-0 & 71975-58-1) N; R51-53 Note: C >=3%Conc<5%: Xn; R21/22 Eu - - - - - - - -
T+ ; N ; R: 26/27/28 - 33 -
T+; R26/27/28 50/53 , Conc>=7%: T+; R26/27/28; R33
1,2-Dinitrobenzene [o-Dinitrobenzene](Note: see also R33. S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R23/24/25; R33
528-29-0 CAS No 25154-54-5, 99-65-0 & 100-25-4) N; R50-53 60 - 61 >= 0.1%Conc<1%; Xn; R20/21/22 Eu; A o-Dinitrobenzene 0.15 1 - - - Sk -
Benzidine, salt of [Benzidine dihydrochloride](Note: Carc. Cat. 1; R45 T ; N ; R: 45 - 22 - 50/53,
see also CAS No 36341-27-2, 531-86-2 & 21136-70- Xn; R22 S: 53 - 45 - 60 - 61; Conc>=25%: T; R45; R22
531-85-1 9) N; R50-53 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -

Page 101
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 1; R45 T ; N ; R: 45 - 22 - 50/53,
Benzidine, salt of Benzidine sulphate (1:1)(Note: see Xn; R22 S: 53 - 45 - 60 - 61; Conc>=25%: T; R45; R22
531-86-2 also CAS No 531-85-1, 36341-27-2 & 21136-70-9) N; R50-53 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
a-
Chloroacetopheno
532-27-4 alpha-Chloroacetophenone A ne 0.05 0.32 - - - - -
Chrysoidine monohydrochloride [4- Conc>=25%: Xn; R68; R22; R38; R41
Phenylazophenylene-1,3-diamine Muta. Cat. 3; R68 Xn; N >=20%Conc<25%: Xn; R68; R38; R41
monohydrochloride](Note: see also CAS No. 75660- Xn; R22 R: 22-38-41-68-50/53 >=10%Conc<20%: Xn; R68; R41
25-2, 79234-33-6, 63681-54-9, 83968-67-6 & 84196- Xi; R38-41 S: (2-)23-26-36/37/39-46-60- >=5%Conc<10%: Xn; R68; R36
532-82-1 22-5) N; R50-53 61 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -

Xn; R22
Dazomet (ISO) [Tetrahydro-3,5-dimethyl-1,3,5- Xi; R36 Xn ; N ; R: 22 - 36 - 50/53, Conc>=25%: Xn; R22; R36
533-74-4 thiadiazine-2-thione] N; R50-53 S: (2) - 15 - 22 - 24 - 60 - 61 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
F; R11,
534-15-6 1,1-Dimethoxyethane [Dimethyl acetal] F; R11 S: (2) - 9 - 16 - 33 Eu - - - - - - - -

Conc>=20%: T+; R68; R26/27/28; R41; R43;

R38
>=10%Conc<20%: T+; R68; R26/27/28; R41;
Muta. Cat. 3; R68 R43
T+; R26/27/28 >=7%Conc<10%: T+; R68; R26/27/28; R43;
Xi; R38-41 T+ ; N ; R: 26/27/28 - 38 - R36
R43 41 - 43 - 44 - 50/53 - 68, >=5%Conc<7%: T; R68; R23/24/25; R43; R36
R44 S: (1/2) - 36/37 - 45 - 60 - >=1%Conc<5%: T; R68; R23/24/25; R43
534-52-1 DNOC [4,6-Dinitro-o-cresolate] N; R50-53 61 >= 0.1%Conc<1%: Xn; R20/21/22 Eu; A Dinitro-o-cresol - 0.2 - - - Sk -
Conc>=7%: T+; R28
Crimidine (ISO) [2-Chloro-6-methylpyrimidin-4- T+ ; R: 28 , >=1%Conc<7%: T; R25
535-89-7 yldimethylamine] T+; R28 S: (1/2) - 36/37 - 45 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
Conc>=25%: T; R24; R22; R41; R43
T; R24 >=10%Conc<25%: Xn; R21; R41; R43
Xn; R22 T ; R: 22 - 24 - 41 - 43, >=5%Conc<10%: Xn; R21; R36; R43
Dicyclohexylcarbodiimide [Cyclohexanamine, N,N'- Xi; R41 S: (1/2) - 24 - 26 - 37/39 - >=3%Conc<5%: Xn; R21; R43
538-75-0 methanetetraylbis] R43 45 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -

Carc. Cat. 3; R40 Conc>=25%: T; R40; R23/24/25; R36; R43

T; R23/24/25 >=20%Conc<25%: Xn; R40; R20/21/22; R36;
Xi; R36 T ; N ; R: 23/24/25 - 36 - 40 - R43
Toluidinium chloride(Note: see also CAS No 106-49- R43 43 - 50 >=3%Conc<20%: Xn; R40; R20/21/22; R43
540-23-8 0 & 540-25-0) N; R50 S: (1/2) - 28 - 36/37 - 45 - 61 >=1%Conc<3%: Xn; R40; R43 Eu - - - - - - - -

Carc. Cat. 3; R40 Conc>=25%: T; R40; R23/24/25; R36; R43

T; R23/24/25 >=20%Conc<25%: Xn; R40; R20/21/22; R36;
Xi; R36 T ; N ; R: 23/24/25 - 36 - 40 - R43
Toluidine sulphate (1:1)(Note: see also CAS No 106- R43 43 - 50 >=3%Conc<20%: Xn; R40; R20/21/22; R43
540-25-0 49-0 & 540-23-8) N; R50 S: (1/2) - 28 - 36/37 - 45 - 61 >=1%Conc<3%: Xn; R40; R43 Eu - - - - - - - -
R10,
S: (2)
540-42-1 Isobutyl propionate R10 Note; C Eu - - - - - - - -
F ; Xn ; R: 11 - 20/21/22,
1-Chloropropane [Propyl chloride](Note: see also F; R11 S: (2) - 9 - 29 ;
540-54-5 CAS No 75-29-6) Xn; R20/21/22 Note: C Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
F; Xn
F; R11 R: 11-20-52/53
1,2-Dichloroethylene (Note: see also CAS No. Xn; R20 S: (2-)7-16-29-61; 1,2-
540-59-0 156-59-2 and 156-60-5) R52-53 Note: C Conc>=12.5%: Xn; R20 Eu; A Dichloroethylene 200 793 - - - - -
F+; R12,
540-67-0 Ethyl methyl ether F+; R12 S: (2) - 9 - 16 - 33 Eu - - - - - - - -
T ; N ; R: 45 - 23/24/25 -
Carc. Cat. 2; R45 51/53, Conc>=25%: T; R45; R23/24/25
T; R23/24/25 S: 53 - 45 - 61; >=3%Conc<25%: T; R45; R20/21/22
540-73-8 N,N'-Dimethylhydrazine [1,2-Dimethylhydrazine] N; R51-53 Note: E >=0.01%Conc<3%: T; R45 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F; R11 F; Xn ; R: 11 - 20/22 ,
540-80-7 tert-Butyl nitrite Xn; R20/22 S: (2) - 16 - 24 - 46 Conc>=25%: Xn; R20/22 Eu - - - - - - - -

2,2,4-Trimethylpentane(Note: see also CAS No. 111- F; R11

65-9, 560-21-4, 563-16-6, 564-02-3, 565-75-3, 583- Xn; R65 F; Xn; N
48-2, 584-94-1, 589-43-5, 589-53-7, 589-81-1, 590- Xi; R38 R: 11-38-65-67-50/53
73-8, 592-13-2, 592-27-8, 594-82-1, 609-26-7, 619- R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
540-84-1 99-8, 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; R11
Acetic acid, 1,1-dimethylethyl ester [tert-Butyl R66 F
540-88-5 acetate] R67 R: 11-66-67 N/Eu; A tert-Butyl acetate 200 950 - - - - -
Conc>=25%: T+; R26; R34; R22
>=10%Conc<25%: T+; R26; R34
F; R11 >=7%Conc<10%: T+; R26; R36/38
T+; R26 F ; T+ ; R: 11 - 22 - 26 - 34, >=5%Conc<7%: T; R23; R36/38
Ethyl chloroformate [Carbonochloridic acid, ethyl C; R34 S: (1/2) - 9 - 16 - 26 - 28 - >=1%Conc<5%: T; R23
541-41-3 ester] Xn; R22 33 - 36/37/39 - 45 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -

Muta. Cat. 3; R68 Conc>=25%: T; R68; R23/24/25; R36; R43

T; R23/24/25 T ; N ; R: 23/24/25 - 36 - 43 - >=20%Conc<25%: Xn; R68; R20/21/22; R36;
Xi; R36 50/53 - 68, R43
m-Phenylenediamine, dihydrochloride [1,3- R43 S: (1/2) - 28 - 36/37 - 45 - >=3%Conc<20%: Xn; R68; R20/21/22; R43
541-69-5 Benzenediamine, dihydrochloride] N; R50-53 60 - 61 >=1%Conc<3%: Xn; R68; R43 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53,
541-73-1 1,3-Dichlorobenzene [Benzene, 1,3-dichloro] N; R51-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
R10 Xi ; R: 10 - 36/37 , 5-Methylheptan-3-
541-85-5 Ethyl amyl ketone [5-Methylheptan-3-one] Xi; R36/37 S: (2) - 23 Conc>=10%: Xi; R36/37 Eu; A one 10 53 20 107 - - -
F ; Xi ; R: 11 - 36/37,
Isobutyl formate(Note: see also CAS No 592-84-7 & F; R11 S: (2) - 9 - 16 - 24 - 33;
542-55-2 762-75-4) Xi; R36/37 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
F; R11 Conc>=25%: T; R45; R68; R20/22
Xn; R20/22 F; T >=1%Conc<25%: T; R45; R68
Carc. Cat. 2; R45 R: 11-20/22-45-68 >=0.1%Conc<1%: T; R45
542-56-3 Isobutyl nitrite Muta. Cat. 3; R68 S: 53-45; Note: E Eu - - - - - - - -
Conc>=25%: T; R24/25; R20; R65; R36/37/38;
R10 R43
T; R24/25 T; N >=20%Conc<25%: Xn; R21/22; R65;
Xn; R20-65 R: 10-20-24/25-36/37/38-43- R36/37/38; R43
Xi; R36/37/38 65-50/53 >=10%Conc<20%: Xn; R21/22; R65; R43
1,3-Dichloropropene [1-Propene, 1,3-dichloro](Note: R43 S: (1/2-)36/37-45-60-61 >=3%Conc<10%: Xn; R21/22; R43
542-75-6 see also CAS No. 10061-01-5) N; R50-53 Notes: C ; D >=1%Conc<3%: Xi; R43 Eu;A Dichloropropene 1 4.5 - - 3 Sk -
T+; R26/27/28
R32
R33 T+; N Conc>=7%: T+; R26/27/28; R32; R33; R68 Cadmium and
Xn; R68 R: 26/27/28-32-33-68-50/53 >=1%Conc<7%: T; R23/24/25; R32; R33; R68 compounds (as
542-83-6 Cadmium cyanide N; R50-53 S: (1/2-)7-28-29-45-60-61 >=0.1%Conc<1%: Xn; R20/21/22; R33 Eu; A Cd) - 0.01 - - 2 - -
Conc>=25%: T+; R45; R26; R24; R22
F; R11 >=7%Conc<25%: T+; R45; R26; R21
Carc. Cat. 1; R45 F; T+ >=3%Conc<7%: T; R45; R23; R21
T+; R26 R: 45-11-22-24-26 >=1%Conc<3%: T; R45; R23
Bis(chloromethyl) ether [Dichlorodimethyl ether T; R24 S: 53-45 >=0.1%Conc<1%: T; R45; R20 bis(Chloromethyl)
542-88-1 symmetrical; BCME; Oxybis(chloromethane)] Xn; R22 Note: E >=0.001%Conc<0.1%: T; R45 Eu;A ether .001(P) 0.005 - - 1 - -
542-92-7 Cyclopentadiene A Cyclopentadiene 75 203 - - - - -
F ; Xn ; R: 11 - 20/21/22,
1-Chloropentane(Note: see also CAS No 616-20-5 & F; R11 S: (2) - 9 - 29 ;
543-59-9 625-29-6) Xn; R20/21/22 Note: C Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -

Page 103
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 1; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
543-90-8 Acetic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
F; R11 F ; T ; R: 11 - 23/25 , Conc>=25%: T; R23/25
544-16-1 Butyl nitrite T; R23/25 S: (1/2) - 16 - 24 - 45 >=3%Conc<25%: Xn; R20/22 Eu - - - - - - - -
R14 F ; C ; N ; R: 14 - 17 - 34 -
F; R17 50/53,
C; R34 S: (1/2) - 16 - 43 - 45 - 60 - Conc>=10%: C; R34
544-97-8 Dimethylzinc(Note: see also CAS No 557-20-0) N; R50-53 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

T; R23/24/25 T ; N ; R: 23/24/25 - 51/53, Conc>=25%: T; R23/24/25

545-06-2 Trichloroacetonitrile N; R51-53 S: (1/2) - 45 - 61 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
546-67-8 Acetic acid, lead(4+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xi ; R: 10 - 36/37
Methyl lactate(Note: see also CAS No 2155-30-8; R10 S: (2) - 24;
547-64-8 17392-83-5 & 27871-49-4) Xi; R36/37 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
Carc.Cat.3; R40 Conc>=25%: Xn; R40; R22; R41
C.I Basic Violet 3 [4-[4,4'-Bis(dimethylamino) Xn; R22 Xn; N >=10%Conc<25%: Xn; R40; R41
benzhydrylidene]cyclohexa-2,5-dien-1- Xi; R41 R: 22-40-41-50/53 >=5%Conc<10%: Xn; R40; R36
548-62-9 ylidene]dimethylammonium chloride] N; R50-53 S: (2-)26-36/37/39-46-60-61 >=1%Conc<5%: Xn; R40 Eu - - - - - - - -
Carc.Cat.2; R45 T; N Conc>=25%: T; R45; R22; R41
Xn; R22 R: 45-22-41-50/53 >=10%Conc<25%: T; R45; R41
C.I. Basic Violet 3 with >= 0.1% of Michler's ketone Xi; R41 S: 53-45-60-61 >=5%Conc<10%: T; R45; R36
548-62-9 (CAS No. 90-94-8) N; R50-53 Note: E >=0.1%Conc<5%: T ; R45 Eu - - - - - - - -
Conc>=20%: Xn; R42/43; R37; R41
Xi; R37 >=10%Conc<20%: Xn; R42/43; R41
Benzene-1,2,4-tricarboxylic acid 1,2-anhydride Xi; R41 Xn ; R: 37 - 41 - 42/43, >=5%Conc<10%: Xn; R42/43; R36 Trimellitic
552-30-7 [Trimellitic anhydride] Xn; R42/43 S: (2) - 22 - 26 - 36/37/39 >=1%Conc<5%: Xi; R36 Eu; A anhydride 0.005 0.039 - - - Sen -
Carc. Cat. 1; R45 T ; N ; R: 45 - 22 - 51/53,
2-Naphthylammonium acetate, salt of(Note: see also Xn; R22 S: 53 - 45 - 61; Conc>=25%: T; R45; R22
553-00-4 CAS No 612-52-2) N; R51-53 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
F; R11 F ; Xn ; R: 11 - 20,
554-12-1 Methyl propionate Xn; R20 S: (2) - 16 - 24 - 29 - 33 Conc>=25%: Xn; R20 Eu - - - - - - - -
F; R11,
555-31-7 Aluminium-tri-isopropoxide F; R11 S (2) - 8 - 16 Eu - - - - - - - -

Conc>=25%: T; R45; R60; R68; R23; R21/22;

R36/37/38
Carc. Cat. 2; R45 >=20%Conc<25%: T; R45; R60; R68; R20;
Muta. Cat. 3; R68 T R36/37/38
Repr. Cat. 2; R60 R: 45-60-21/22-23-36/37/38- >=3%Conc<20%: T;R45; R60; R68; R20
T; R23 68 >=1%Conc<3%: T; R45; R60; R68
Xn; R21/22 S: 53-45; Note: >=0.5%Conc<1%: T; R45; R60
556-52-5 2,3-Epoxypropan-1-ol [Glycidol; Oxiranemethanol] Xi; R36/37/38 E >=0.1%Conc<0.5%: T; R45 Eu; A Glycidol 25 76 - - - - -
F; C
F; R11 R: 11-34 Conc>=10%: C; R34
556-56-9 3-Iodpropene [Allyl iodide] C; R34 S: (1/2-)7-16-26-45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Conc>=25%: T; R23/25; R34; R43

T; R23/25 T ; N ; R: 23/25 - 34 - 43 - >=10%Conc<25%: C; R34; R20/22; R43
C; R34 50/53, >=5%Conc<10%: Xn; R20/22; R36/38; R43
R43 S: (1/2) - 36/37 - 38 - 45 - >=3%Conc<5%: Xn; R20/22; R43
556-61-6 Methyl isothiocyanate N; R50-53 60 - 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -

Page 104
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Repr. Cat. 3; R62 Xn ; R: 53 - 62
556-67-2 Octamethylcyclotetrasiloxane R53 S: (2)36/37 - 46 - 51 - 61 Conc>=5%: Xn; R62 Eu - - - - - - - -
R14 F ; C ; N ; R: 14 - 17 - 34 -
F; R17 50/53,
C; R34 S: (1/2) - 16 - 43 - 45 - 60 - Conc>=10%: C; R34
557-20-0 Diethylzinc(Note: see also CAS No 544-97-8) N; R50-53 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Carbon
558-13-4 Carbon tetrabromide A tetrabromide 0.1 1.4 0.3 4.1 - - -

2,3,3-Trimethylpentane(Note: see also CAS No. 111- F; R11

65-9, 540-84-1, 563-16-6, 564-02-3, 565-75-3, 583- Xn; R65 F; Xn; N
48-2, 584-94-1, 589-43-5, 589-53-7, 589-81-1, 590- Xi; R38 R: 11-38-65-67-50/53
73-8, 592-13-2, 592-27-8, 594-82-1, 609-26-7, 619- R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
560-21-4 99-8, 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; R11
Xn; R65 F; Xn; N
3,3-Dimethylpentane(Note: see also CAS No. 142-82- Xi; R38 R: 11-38-65-67-50/53
5, 108-08-7, 464-06-2, 565-59-3, 589-34-4,590-35-2, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
562-49-2 591-76-4, 617-78-7 & 31394-54-4) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -

T; R25 T; N
Ethion (ISO) [O,O,O',O'-Tetraethyl S,S'-methylenedi Xn; R21 R: 21-25-50/53 Conc>=25 %: T; R25; R21
563-12-2 (phosphorodithioate) diethion] N; R50-53 S: (1/2-)25-36/37-45-60-61 >=3%Conc<25 %: Xn; R22 Eu; A Ethion - 0.4 - - - Sk -

3,3-Dimethylhexane(Note: see also CAS No. 111-65- F; R11

9, 540-84-1, 560-21-4, 564-02-3, 565-75-3, 583-48-2, Xn; R65 F; Xn; N
584-94-1, 589-43-5, 589-53-7, 589-81-1, 590-73-8, Xi; R38 R: 11-38-65-67-50/53
592-13-2, 592-27-8, 594-82-1, 609-26-7, 619-99-8, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
563-16-6 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; R11
Xn; R20/22 F ; C ; N ; R: 11 - 20/22 - 34 - Conc>=25%: C; R34; R20/22; R43
C; R34 43 - 51/53 , >=10%Conc<25%: C; R34; R43
3-Chloro-2-methylpropene [1-Propene, 3-chloro-2- R43 S: (2) - 9 - 16 - 26 - 29 - >=5%Conc<10%: Xi; R36/38; R43
563-47-3 methyl] N; R51-53 36/37 - 38 - 45 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
F; R11 F ; T ; R: 11 - 25 - 52/53,
T; R25 S: (1/2) - 16 - 29 - 33 - 45 - Conc>=25%: T; R25
563-58-6 1,1-Dichloropropene [1-Propene, 1,1-dichloro] R52-53 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
F; R11, Methyl isopropyl
563-80-4 3-Methylbutan-2-one [Methyl isopropyl ketone] F; R11 S: (2) - 9 - 16 - 33 Eu; A ketone 200 705 - - - - -

2,2,3-Trimethylpentane(Note: see also CAS No. 111- F; R11

65-9, 540-84-1, 560-21-4, 563-16-6, 565-75-3, 583- Xn; R65 F; Xn; N
48-2, 584-94-1, 589-43-5, 589-53-7, 589-81-1, 590- Xi; R38 R: 11-38-65-67-50/53
73-8, 592-13-2, 592-27-8, 594-82-1, 609-26-7, 619- R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
564-02-3 99-8, 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; R11
Xn; R65 F; Xn; N
2,3-Dimethylpentane(Note: see also CAS No. 142-82- Xi; R38 R: 11-38-65-67-50/53
5, 108-08-7, 464-06-2, 562-49-2, 589-34-4,590-35-2, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
565-59-3 591-76-4, 617-78-7 & 31394-54-4) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -

2,3,4-Trimethylpentane(Note: see also CAS No. 111- F; R11

65-9, 540-84-1, 560-21-4, 563-16-6, 564-02-3, 583- Xn; R65 F; Xn; N
48-2, 584-94-1, 589-43-5, 589-53-7, 589-81-1, 590- Xi; R38 R: 11-38-65-67-50/53
73-8, 592-13-2, 592-27-8, 594-82-1, 609-26-7, 619- R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
565-75-3 99-8, 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; R11 F ; Xn ; R: 11 - 20,
565-80-0 2,4-Dimethylpentan-3-one [Di-isopropyl ketone] Xn; R20 S: (2) - 9 - 16 - 24/25 Conc>=25%: Xn; R20 Eu - - - - - - - -

4,4'-(4-Iminocyclohexa-2,5-dienylidene- T ; R: 45,
569-61-9 methyIene)dianiline hydrochloride [C.I. Basic Red 9] Carc. Cat. 2; R45 S: 53 - 45 Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 105
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R22
Xi; R41 Xn; N Conc>=25%: Xn; R63; R22; R41
Malachite green hydrochloride (Note: see also CAS Repr. Cat. 3; R63 R: 22-41-63-50/53 >=10%Conc< 25%: Xn; R63; R41
569-64-2 No.18015-76-4 ) N; R50-53 S: (2-)26-36/37-39-46-60-61 >=5%Conc<10%: Xn; R63; R36 Eu - - - - - - - -
Coumithoate (ISO) [O,O-Diethyl O-7,8,9,10-
tetrahydro-6-oxo-benzo(c)chromen-3-yl T ; R: 25 , Conc>=25%: T; R25
572-48-5 phosphorothioate] T; R25 S: (1/2) - 28 - 36/37 - 45 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -

T; R23/24/25 T ; N ; R: 23/24/25 - 33 - Conc>=25%: T; R23/24/25; R33

2,6-Dinitrophenol(Note: see also CAS No 66-56-8; R33 51/53 >=3%Conc<25%: Xn; R20/21/22; R33
573-56-8 329-71-5; 577-71-9; & dinitrophenol, salts of) N; R50-53 S: (1/2) - 28 - 37 - 45 - 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
1-Naphthalenesulfonic acid, 3,3'-[[1,1'-biphenyl]-4,4'-
diylbis(azo)]bis[4-amino-, disodium salt [C.I. Direct Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
573-58-0 red 28] Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -

T ; N ; R: 24/25 - 34 - 51/53, Conc>=25%: T; R24/25; R34

2,6-Xylenol [2,6-Dimethylphenol](Note: see also CAS T; R24/25 S: (1/2) - 26 - 36/37/39 - 45 - >=10%Conc<25%: C; R34; R21/22
No 95-65-8, 95-87-4, 105-67-9, 526-75-0, 1300-71-6 C; R34 61; >=5%Conc<10%: Xn; R21/22; R36/38
576-26-1 & 71975-58-1) N; R51-53 Note: C >=3%Conc<5%: Xn; R21/22 Eu - - - - - - - -

T; R23/24/25 T ; N ; R: 23/24/25 - 33 - Conc>=25%: T; R23/24/25; R33

3,4-Dinitrophenol(Note: see also CAS No 66-56-8; R33 51/53 >=3%Conc<25%: Xn; R20/21/22; R33
577-71-9 329-71-5; 573-56-8 & dinitrophenol, salts of) N; R50-53 S: (1/2) - 28 - 37 - 45 - 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
Xn
578-36-9 Benzoic acid, 2-hydroxy-, monopotassium salt Xn; R22 R: 22 Conc>=25%: Xn; R22 N - - - - - - - -
Xn ; R: 22 ,
579-66-8 2,6-Diethylaniline Xn; R22 S: (2) - 23 - 24 Conc>=25%: Xn; R22 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 51/53,
581-89-5 2-Nitronaphthalene N; R51-53 S: 53 - 45 - 61 Conc>=0.1%: T; R45 Eu - - - - - - - -

3,4-Dimethylhexane(Note: see also CAS No. 111-65- F; R11

9, 540-84-1, 560-21-4, 563-16-6, 564-02-3, 565-75-3, Xn; R65 F; Xn; N
584-94-1, 589-43-5, 589-53-7, 589-81-1, 590-73-8, Xi; R38 R: 11-38-65-67-50/53
592-13-2, 592-27-8, 594-82-1, 609-26-7, 619-99-8, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
583-48-2 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
Xn ; R: 20 ,
2-Methylcyclohexanol, mixed isomers(Note: see also S: (2) - 24/25;
583-59-5 CAS No 7443-52-9 & 7443-70-1) Xn; R20 Note: C Conc>=25%: Xn; R20 Eu - - - - - - - -
o-
R10 Xn ; R: 10 - 20 , Methylcyclohexano
583-60-8 2-Methylcyclohexanone [o-Methylcyclohexanone] Xn; R20 S: (2) - 25 Conc>=25%: Xn; R20 Eu; A ne 50 229 75 344 - Sk -
R10 Xn
Xn; R20 R: 10-20-37/38 Conc>=25%: Xn; R20; R37/38
584-02-1 3-Pentanol(Note: see also CAS No. 71-41-0) Xi; R37/38 S: (1/2-)36/37-46 >=20%Conc<25%: Xi; R37/38 Eu - - - - - - - -
Conc>=20%: Xi; R41; R37
Xi >=10%Conc<20%: Xi; R41
584-08-7 Carbonic acid, dipotassium salt Xi; R37-41 R: 37-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Allethrin [Bioallethrin; (RS)-3-allyl-2-methyl-4-

oxocyclopent-2-enyl (1R,3R)-2,2-di-methyl-3-(2-
methylprop-1-enyl)cyclopropanecarboxylate; (RS)-3-
allyl-2-methyl-4-oxocyclopent-2-enyl
(1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1- Xn ; N ; R: 20/22 - 50/53,
enyl)cyclopropanecarboxylate](Note: see also CAS Xn; R20/22 S: (2) - 36 - 60 - 61;
584-79-2 28434-00-6 & 84030-86-4) N; R50-53 Note: C Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Carc. Cat. 3; R40
T+; R26 T+ Conc>=20%: T+; R40; R26; R36/37/38; R42/43
Toluene-2,4-di-isocyanate [4-Methyl-m-phenylene Xi; R36/37/38 R: 26-36/37/38-40-42/43- >=7%Conc<20%: T+; R40; R26; R42/43
diisocyanate; TDI](Note: see also CAS No. 91-08-7 R42/43 52/53 >=1% Conc<7%: T; R40; R23; R42/43 Isocyanates, all
584-84-9 and 26471-62-5) R52-53 S: (1/2-)23-36/37-45-61 >=0.1%Conc<1%: Xn; R20; R42 Eu; A (as-NCO) - 0.02 - 0.07 - Sen -

Page 106
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
T+; R26 T+ Conc>=20%: T+; R40; R26; R36/37/38; R42/43
Toluene-2,4-di-isocyanate [4-Methyl-m-phenylene Xi; R36/37/38 R: 26-36/37/38-40-42/43- >=7%Conc<20%: T+; R40; R26; R42/43 (see
diisocyanate; TDI](Note: see also CAS No. 91-08-7 R42/43 52/53 >=1% Conc<7%: T; R40; R23; R42/43 Toluene-2,4- Isocyanates,
584-84-9 and 26471-62-5) R52-53 S: (1/2-)23-36/37-45-61 >=0.1%Conc<1%: Xn; R20; R42 Eu; A diisocyanate (TDI) - - - - - - all)

2,3-Dimethylhexane(Note: see also CAS No. 111-65- F; R11

9, 540-84-1, 560-21-4, 563-16-6, 564-02-3, 565-75-3, Xn; R65 F; Xn; N
583-48-2, 589-43-5, 589-53-7, 589-81-1, 590-73-8, Xi; R38 R: 11-38-65-67-50/53
592-13-2, 592-27-8, 594-82-1, 609-26-7, 619-99-8, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
584-94-1 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; R11
Xn; R65 F; Xn; N
3-Methylhexane(Note: see also CAS No. 142-82-5, Xi; R38 R: 11-38-65-67-50/53
108-08-7, 464-06-2, 562-49-2, 565-59-3,590-35-2, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
589-34-4 591-76-4, 617-78-7 & 31394-54-4) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; R11,
S: (2) - 9 - 16 - 33
589-40-2 sec-Butyl formate F; R11 Note; C Eu - - - - - - - -

2,4-Dimethylhexane(Note: see also CAS No. 111-65- F; R11

9, 540-84-1, 560-21-4, 563-16-6, 564-02-3, 565-75-3, Xn; R65 F; Xn; N
583-48-2, 584-94-1, 589-53-7, 589-81-1, 590-73-8, Xi; R38 R: 11-38-65-67-50/53
592-13-2, 592-27-8, 594-82-1, 609-26-7, 619-99-8, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
589-43-5 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
4-Methylheptane(Note: see also CAS No. 111-65-9, F; R11
540-84-1, 560-21-4, 563-16-6, 564-02-3, 565-75-3, Xn; R65 F; Xn; N
583-48-2, 584-94-1, 589-43-5, 589-81-1, 590-73-8, Xi; R38 R: 11-38-65-67-50/53
592-13-2, 592-27-8, 594-82-1, 609-26-7, 619-99-8, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
589-53-7 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
3-Methylheptane(Note: see also CAS No. 111-65-9, F; R11
540-84-1, 560-21-4, 563-16-6, 564-02-3, 565-75-3, Xn; R65 F; Xn; N
583-48-2, 584-94-1, 589-43-5, 589-53-7, 590-73-8, Xi; R38 R: 11-38-65-67-50/53
592-13-2, 592-27-8, 594-82-1, 609-26-7, 619-99-8, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
589-81-1 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; R11
Xn; R65
Xi; R38 F; Xn; N
R67 R: 11-38-65-67-51/53 Conc>=20%: Xn; R65; R38
589-90-2 1,4-Dimethylcyclohexane N; R51-53 S: (2-)9-16-33-61-62 >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
R10,
S: (2)
590-01-2 n-Butyl propionate R10 Note; C Eu - - - - - - - -
Xn ; R: 22 ,
590-28-3 Potassium cyanate Xn; R22 S: (2) - 24/25 Conc>=25%: Xn; R22 Eu - - - - - - - -
F; R11
Xn; R65 F; Xn; N
2,2-Dimethylpentane(Note: see also CAS No. 142-82- Xi; R38 R: 11-38-65-67-50/53
5, 108-08-7, 464-06-2, 562-49-2, 565-59-3,589-34-4, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
590-35-2 591-76-4, 617-78-7 & 31394-54-4) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -

2,2-Dimethylhexane(Note: see also CAS No. 111-65- F; R11

9, 540-84-1, 560-21-4, 563-16-6, 564-02-3, 565-75-3, Xn; R65 F; Xn; N
583-48-2, 584-94-1, 589-43-5, 589-53-7, 589-81-1, Xi; R38 R: 11-38-65-67-50/53
592-13-2, 592-27-8, 594-82-1, 609-26-7, 619-99-8, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
590-73-8 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
Xn; R20/22 Xn ; N ; R: 20/22 - 50/53,
591-27-5 3-Aminophenol [Phenol, 3-amino] N; R50-53 S: (2) - 28 - 61 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
R10,
S: (2)
591-34-4 sec-Butyl propionate R10 Note; C Eu - - - - - - - -

Page 107
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F; R11
Xn; R65 F; Xn; N
2-Methylhexane(Note: see also CAS No. 142-82-5, Xi; R38 R: 11-38-65-67-50/53
108-08-7, 464-06-2, 562-49-2, 565-59-3,589-34-4, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
591-76-4 590-35-2, 617-78-7 & 31394-54-4) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
R10
Repr. Cat. 3; R62 T Conc>=10%: T; R62; R48/23
Hexan-2-one [Methyl butyl ketone; Butyl methyl T; R48/23 R: 10-48/23-62-67 >=5%Conc<10%: Xn; R62; R48/20 Methyl n-butyl
591-78-6 ketone; Methyl-n-butyl ketone] R67 S: (1/2-)36/37-45 >=1%Conc<5%: Xn; R48/20 Eu;A ketone 5 20 - - - Sk -
T+; N
T+; R28 R: 28 - 32 - 50/53 Conc>=7%: T+; R28; R32
R32 S: (1/2) - 7/8 - 23 - 36/37 - >=1%Conc<7%: T; R25; R32
592-01-8 Calcium cyanide N; R50-53 45 - 60 - 61 >=0.1%Conc<1%: Xn; R22; R32 Eu - - - - - - - -

2,5-Dimethylhexane(Note: see also CAS No. 111-65- F; R11

9, 540-84-1, 560-21-4, 563-16-6, 564-02-3, 565-75-3, Xn; R65 F; Xn; N
583-48-2, 584-94-1, 589-43-5, 589-53-7, 589-81-1, Xi; R38 R: 11-38-65-67-50/53
590-73-8, 592-27-8, 594-82-1, 609-26-7, 619-99-8, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
592-13-2 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
2-Methylheptane(Note: see also CAS No. 111-65-9, F; R11
540-84-1, 560-21-4, 563-16-6, 564-02-3, 565-75-3, Xn; R65 F; Xn; N
583-48-2, 584-94-1, 589-43-5, 589-53-7, 589-81-1, Xi; R38 R: 11-38-65-67-50/53
590-73-8, 592-13-2, 594-82-1, 609-26-7, 619-99-8, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
592-27-8 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
Conc>=25%: T; R23; R34
R10. >=10%Conc<25%: C; R34; R20
T; R23. T ; R: 10 - 23 - 34 , >=5%Conc<10%: Xn; R20; R36/38
592-34-7 Butyl chloroformate [Chloroformic acid butyl ester] C; R34 S: (1/2) - 26 - 36 - 45 >=3%Conc<5%: Xn; R20 Eu - - - - - - - -
Methyl ONN azoxymethyl acetate [Methyl azoxy Carc. Cat. 2; R45 T ; R: 45 - 61 , Conc>=0.5%: T; R45; R61
592-62-1 methyl acetate] Repr. Cat. 2; R61 S: 53 - 45 >=0.1%Conc<0.5%: T; R45 Eu - - - - - - - -
F ; Xi ; R: 11 - 36/37,
Butyl formate(Note: see also CAS No 542-55-2 & 762- F; R11 S: (2) - 9 - 16 - 24 - 33;
592-84-7 75-4) Xi; R36/37 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
F+; R12 F+ ; T ; R: 12 - 45,
593-60-2 Bromoethylene [Ethene, bromo; Vinyl bromide] Carc. Cat. 2; R45 S: 53 - 45 Conc>=0.1%: T; R45 Eu; A Vinyl bromide 5 22 - - 2 - -

T+; R26/27/28 T+; N Conc>=0.5%: T+; R26/27/28; R33

R33 R: 26/27/28-33-50/53 >=0.1%Conc<0.5%: T; R23/24/25; R33
593-74-8 Dimethylmercury (Note: see also CAS No. 627-44-1) N; R50-53 S: (1/2-)13-28-36-45-60-61 >=0.05%Conc<0.1%: T; R20/21/22; R33 Eu - - - - - - - -
Perchloromethyl
594-42-3 Perchloromethyl mercaptan A mercaptan 0.1 0.76 - - - - -
T ; R: 23/24/25 , Conc>=25%: T; R23/24/25 1,1-Dichloro-1-
594-72-9 1,1-Dichloro-1-nitroethane T; R23/24/25 S: (1/2) - 26 - 45 >=3%Conc<25%: Xn; R20/21/22 Eu; A nitroethane 2 12 - - - - -

2,2,3,3-Tetramethylbutane(Note: see also CAS No. F; R11

111-65-9, 540-84-1, 560-21-4, 563-16-6, 564-02-3, Xn; R65 F; Xn; N
565-75-3, 583-48-2, 584-94-1, 589-43-5, 589-53-7, Xi; R38 R: 11-38-65-67-50/53
589-81-1, 590-73-8, 592-13-2, 592-27-8, 609-26-7, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
594-82-1 619-99-8, 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; R11 F; C Conc>=25%: C; R34; R20/22 N,N-
Xn; R20/22 R: 11-20/22-34 >=10%Conc<25%: C; R34 Dimethylethylamin
598-56-1 Ethyldimethylamine C; R34 S: (1/2-)3-16-26-36-45 >=5%Conc<10%: Xi; R36/38 Eu;A e 10 30 15 45 - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Repr. Cat. 1; R61 Conc>=25%: T; R40; R61; R62; R68; R20; R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20 T >=1%Conc<5%: T; R40; R61; R68; R33
598-63-0 Carbonic acid, lead(2+) salt (1:1) R33 R: 61-20-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Conc>=25%: C; R35; R22
C ; R: 22 - 35 , >=10%Conc<25%: C; R35
Xn; R22 S: (1/2) - 23 - 26 - 28 - 36 - >=5%Conc<10%: C; R34 2-Chloropropionic
598-78-7 2-Chloroproprionic acid C; R35 45 >=1%Conc<5%: Xi; R36/38 Eu; A acid 0.1 0.44 - - - Sk -
Xn ; R: 20/22 , 1-Chloro-1-
600-25-9 1-Chloro-1-nitropropane Xn; R20/22 S: (2) Conc>=5%: Xn; R20/22 Eu; A nitropropane 2 10 - - - - -

Page 108
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R45; R62; R68; R23/24/25;

R48/22
Carc. Cat. 2; R45 >=10%Conc<25%: T; R45; R62; R68;
Muta. Cat. 3; R68 T; N R20/21/22; R48/22
Repr. Cat. 3; R62 R: 45-23/24/25-48/22-62-68- >=5%Conc<10%: T; R45; R62; R68; R20/21/22
T; R23/24/25 50/53 >=3%Conc<5%: T; R45; R68; R20/21/22
Xn; R48/22 S: 53-45-60-61; >=1%Conc<3%: T; R45; R68
602-01-7 2,3-Dinitrotoluene N; R50-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
602-87-9 5-Nitroacenaphthene Carc. Cat. 2; R45 S: 53 - 45 Conc>=0.1%: T; R45 Eu - - - - - - - -
E; R2.
R4. E ; Xn ; R: 2 - 4 - 20/21/22 ,
602-99-3 2,4,6-Trinitro-m-cresol Xn; R20/21/22 S: (2) - 35 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
603-34-9 Triphenyl amine A Triphenyl amine - 5 - - - - -
Diisopentylphthalate (Note: see also CAS No. T; N
84777-06-0; 605-50-5 and n-Pentyl- Repr. Cat. 2; R60-61 R: 60-61-50
605-50-5 isopentylphthalate) N; R50 S: 53-45-61 Conc>=0.5%: T; R60; R61 Eu - - - - - - - -

Conc>=25%: T; R45; R62; R68; R23/24/25;

R48/22
Carc. Cat. 2; R45 >=10%Conc<25%: T; R45; R62; R68;
Muta. Cat. 3; R68 R20/21/22; R48/22
Repr. Cat. 3; R62 T >=5%Conc<10%: T; R45; R62; R68; R20/21/22
T; R23/24/25 R: 45-23/24/25-48/22-62-68- >=3%Conc<5%: T; R45; R68; R20/21/22
Xn; R48/22 52/53 >=1%Conc<3%: T; R45; R68
606-20-2 2,6-Dinitrotoluene R52-53 S: 53-45-61; Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
E; R2 E ; Xn ; N ; R: 2 - 20/21/22 -
Xn; R20/21/22 51/53,
606-35-9 2,4,6-Trinitroanisole N; R51-53 S: (2) - 35 - 61 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
T ; N ; R: 21 - 25 - 40 -
Carc. Cat. 3; R40 50/53,
T; R25 S: (1/2 - ) - 22 - 36/37 - 45 - Conc>=25%: T; R40; R25; R21
1,2,3,4,5,6-Hexachlorocyclohexanes, with the Xn; R21 60 - 61; >=3%Conc<25%: Xn; R40; R22
608-73-1 exception of those elsewhere specified N; R50-53 Note: C >=1%Conc<3%: Xn; R40 Eu - - - - - - - -

F; R11 F ; Xn ; N ; R: 11 - 22 -
Xn; R22 50/53,
608-93-5 Pentachlorobenzene [Benzene, pentachloro] N; R50-53 S: (2) - 41 - 46 - 50 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

3-Ethyl-2-methylpentane(Note: see also CAS No. 111- F; R11

65-9, 540-84-1, 560-21-4, 563-16-6, 564-02-3, 565- Xn; R65 F; Xn; N
75-3, 583-48-2, 584-94-1, 589-43-5, 589-53-7, 589- Xi; R38 R: 11-38-65-67-50/53
81-1, 590-73-8, 592-13-2, 592-27-8, 594-82-1, 619- R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
609-26-7 99-8, 1067-08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
T
T; R23/24/25 R: 23/24/25-33-52/53
N,N-Dimethyl-o-toluidine (Note: see also CAS No. 99- R33 S: (1/2-)28-36/37-45-61; Conc>=5%: T; R23/24/25; R33
609-72-3 97-8 and 121-72-2) R52-53 Note: C >=1%Conc<5%: Xn; R20/21/22; R33 Eu - - - - - - - -

Conc>=25%: T; R45; R62; R68; R23/24/25;

R48/22
>=10%Conc<25%: T; R45; R62; R68;
Carc. Cat. 2; R45 R20/21/22; R48/22
Muta. Cat. 3; R68 T; N >=5%Conc<10%: T; R45; R62; R68; R20/21/22
Repr. Cat. 3; R62 R: 45-23/24/25-48/22-62-68- >=3%Conc<5%: T; R45; R68; R20/21/22
T; R23/24/25 51/53 >=1%Conc<3%: T; R45; R68
Xn; R48/22 S: 53-45-61; >=0.1%Conc<1%: T; R45
610-39-9 3,4-Dinitrotoluene N; R51-53 Note: E Eu - - - - - - - -
Xn; N
Xn; R20 R: 20-51/53
611-15-4 2-Methylstyrene [2-Vinyltoluene] N; R51-53 S: (2-)24-61 Conc>=25%: Xn; R20 Eu - - - - - - - -

Page 109
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; N ; R: 23/24/25 - 33 -
52/53,
N-Methyl-o-toluidine [Benzenamine, N,2- T; R23/24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R23/24/25; R33
dimethyl](Note: see also CAS No 623-08-5 & 696-44- R33 61; >=3%Conc<25%: Xn; R20/21/22; R33
611-21-2 6) N; R52-53 Note: C >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
Carc. Cat. 1; R45 T ; N ; R: 45 - 22 - 51/53,
2-Naphthylammonium chloride, salt of(Note: see also Xn; R22 S: 53 - 45 - 61; Conc>=25%: T; R45; R22
612-52-2 CAS No 553-00-4) N; R51-53 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
4,4'-bi-o-Toluidine dihydrochloride [4,4'-bi-o-Toluidine,
salts of; o-Tolidine, salts of; 3,3'-Dimethylbenzidine Carc. Cat. 2; R45 T ; N ; R: 45 - 22 - 51/53,
dihydrochloride](Note: see also CAS No 64969-36-4 Xn; R22 S: 53 - 45 - 61; Conc>=25%: T; R45; R22
612-82-8 & 74753-18-7) N; R51-53 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -

[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dichloro-,
dihydrochloride [3,3'-Dichlorobenzidine Carc. Cat. 2; R45
dihydrochloride, salts of; 3,3'-Dichloro(1,1'-biphenyl)- Muta. Cat. 3; R68 Conc>=20%: T; R45; R68; R36
4,4'-diamine dihydrochloride; 3,3'-Dichlorobiphenyl- Xi; R36 T; N >=1%Conc<20%: T; R45; R68
612-83-9 4,4'-ylenediamine dihydrochloride, salts of] N; R50-53 R: 45-36-68-50-53 >=0.1%Conc<1%: T; R45 N - - - - - - - -
T
Carc. Cat. 2; R45 R: 45-20/21/22-68 Conc>=25%: T; R45; R68; R20/21/22
Muta. Cat. 3; R68 S: 53-45 >=1%Conc<25%: T; R45; R68
613-35-4 N,N'-Diacetylbenzidine Xn; R20/21/22 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
R: 53,
613-62-7 2-(Phenylmethoxy)naphthalene R53 S: 61 Eu - - - - - - - -
Carc.Cat.2; R45
Muta.Cat.3; R68 T; N Conc>=25%: T; R45; R68; R22
2,4-Diaminoanisole 4-methoxy-m-phenylenediamine Xn; R22 R: 45-22-68-51/53 >=1%Conc<25%: T; R45; R68
615-05-4 (Note: see also CAS No. 39156-41-7) N; R51-53 S: 53-45-61 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R68; R25; R20/21; R36;
T; R25 R43
Xn; R20/21 T ; N ; R: 20/21 - 25 - 36 - >=20%Conc<25%: Xn; R40; R68; R22; R36;
Xi; R36 40 - 43 - 50/53 - 68, R43
o-Phenylenediamine, dihydrochloride [1,2- R43 S: (1/2) - 28 - 36/37 - 45 - >=3%Conc<20%: Xn; R40; R68; R22; R43
615-28-1 Benzenediamine dihydrochloride] N; R50-53 60 - 61 >=1%Conc<3%: Xn; R40; R68; R43 Eu - - - - - - - -
T; R25
2-Methyl-p-phenylenediamine sulphate [2,5- Xn; R20/21 T ; N ; R: 25 - 20/21 - 43 - Conc>=25%: T; R25; R20/21; R43
Toluenediamine sulfate (1:1)](Note: see also CAS No R43 51/53, >=3%Conc<25%: Xn; R22; R43
615-50-9 6369-59-1) N; R51-53 S: (1/2) - 24 - 37 - 45 - 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
F ; Xn ; R: 11 - 20/21/22,
3-Chloropentane(Note: see also CAS No 543-59-9 & F; R11 S: (2) - 9 - 29 ;
616-20-6 625-29-6) Xn; R20/21/22 Note: C Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
F; R11,
616-38-6 Dimethyl carbonate F; R11 S: (2) - 9 - 16 Eu - - - - - - - -
Conc>=25%: C; R34; R21/22
Xn; R21/22 C ; R: 21/22 - 34 , >=10%Conc<25%: C; R34
616-47-7 1-Methylimidazole C; R34 S: (1/2) - 26 - 36 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
R10 Xi Conc>=10%: Xi; R41; R43
Xi; R41 R: 10-41-43 >=5%Conc<10%: Xi; R36; R43
617-55-0 Dimethyl (2S)-2-hydroxysuccinate R43 S: (2-)24-26-37/39-43 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
F; R11
Xn; R65 F; Xn; N
3-Ethylpentane(Note: see also CAS No. 142-82-5, Xi; R38 R: 11-38-65-67-50/53
108-08-7, 464-06-2, 562-49-2, 565-59-3,589-34-4, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
617-78-7 590-35-2, 591-76-4 & 31394-54-4) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
F; R11
T; R48/25
Xn; R22 F; T; N Conc>=25%: T; R48/25; R22; R41; R43
Xi; R41 R: 11-22-41-43-48/25-50/53 >=10%Conc<25%: T; R48/25;R41; R43
R43 S: (1/2-)22-26-33-36/37/39- >=5%Conc<10%: Xn; R48/22; R36; R43
618-26-8 Bis(N-methyl-N-phenylhydrazine)sulfate N; R50-53 45-60-61 >=1%Conc<5%: Xn; R48/22; R43 Eu - - - - - - - -
C ; R: 21/22 - 34 , Conc>=25%: C; R34; R21/22
DL-alpha-Methylbenzylamine [Benzenemethanamine, Xn; R21/22 S: (1/2 ) - 26 - 28 - 36/37/39 - >=10%Conc<25%: C; R34
618-36-0 alpha-methyl, (+ -)](Note: see also CAS No 98-84-0) C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R45; R62; R68; R23/24/25;

R48/22
Carc. Cat. 2; R45 >=10%Conc<25%: T; R45; R62; R68;
Muta. Cat. 3; R68 R20/21/22; R48/22
Repr. Cat. 3; R62 T >=5%Conc<10%: T; R45; R62; R68; R20/21/22
T; R23/24/25 R: 45-23/24/25-48/22-62-68- >=3%Conc<5%: T; R45; R68; R20/21/22
Xn; R48/22 52/53 >=1%Conc<3%: T; R45; R68
618-85-9 3,5-Dinitrotoluene R52-53 S: 53-45-61; Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -

Conc>=25%: T; R45; R62; R68; R23/24/25;

R48/22
Carc. Cat. 2; R45 >=10%Conc<25%: T; R45; R62; R68;
Muta. Cat. 3; R68 T; N R20/21/22; R48/22
Repr. Cat. 3; R62 R: 45-23/24/25-48/22-62-68- >=5%Conc<10%: T; R45; R62; R68; R20/21/22
T; R23/24/25 51/53 >=3%Conc<5%: T; R45; R68; R20/21/22
Xn; R48/22 S: 53-45-61; >=1%Conc<3%: T; R45; R68
619-15-8 2,5-Dinitrotoluene N; R51-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
3-Ethylhexane(Note: see also CAS No. 111-65-9, 540-F; R11
84-1, 560-21-4, 563-16-6, 564-02-3, 565-75-3, 583- Xn; R65 F; Xn; N
48-2, 584-94-1, 589-43-5, 589-53-7, 589-81-1, 590- Xi; R38 R: 11-38-65-67-50/53
73-8, 592-13-2, 592-27-8, 594-82-1, 609-26-7, 1067- R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
619-99-8 08-9 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
T; N
Carc. Cat. 2; R45 R: 45-22-51/53
Nitrosodipropylamine [1-Propanamine, N-nitroso-N- Xn; R22 S: 53-45-61 Conc>=25%: T; R45; R22
621-64-7 propyl] N; R51-53 Note: E >=0.001%Conc<25%: T; R45 Eu - - - - - - - -
T ; N ; R: 23/24/25 - 33 -
52/53,
N-Methyl-p-toluidine [Benzenamine, N,4- T; R23/24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R23/24/25; R33
dimethyl](Note: see also CAS No 611-21-2 & 696-44- R33 61; >=3%Conc<25%: Xn; R20/21/22; R33
623-08-5 6) N; R52-53 Note: C >=1%Conc<3%: Xn; R33 Eu - - - - - - - -

T; R23/24/25 T ; N ; R: 23/24/25 - 36 - 43 - Conc>=25%: T; R23/24/25; R36; R43

Xi; R36 50/53, >=20%Conc<25%: Xn; R20/21/22; R36; R43
p-Phenylenediamine, dihydrochloride [Benzene-1,4- R43 S: (1/2) - 28 - 36/37 - 45 - >=3%Conc<20%: Xn; R20/21/22; R43
624-18-0 diamine, dihydrochloride] N; R50-53 60 - 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
R: 10 - 66,
2-Methylbutyl acetate(Note: see also CAS No 123-92- R10 S: (2) - 23 - 25;
624-41-9 2, 626-38-0, 628-63-7 & 84145-37-9) R66 Note: C Eu; A - - - - - - - -
R10,
S: (2) – 23 - 24
624-54-4 Amyl propionate [Pentyl propionate] R10 Note; C Eu - - - - - - - -

Conc>=25%: T+; R63; R26; R24/25; R37/38;

R41; R42/43
>=20%Conc<25%: T+; R63; R26; R21/22;
R37/38; R41; R42/43
>=10%Conc<20%: T+; R63; R26; R21/22; R41;
R42/43
>=7%Conc<10%: T+; R63; R26; R21/22; R36;
F; R11 R42/43
Repr. Cat. 3; R63 F; T+ >=5%Conc<7%: T; R63; R23; R21/22; R36;
T+; R26 R: 11-24/25-26-37/38-41- R42/43
T; R24/25 42/43-63 >=3%Conc<5%: T; R23; R21/22; R42/43 (see
R42/43 S: (1/2-)16-26-27/28- >=1%Conc<3%: T; R23; R42/43 Isocyanates,
624-83-9 Methyl isocyanate Xi; R37/38-41 36/37/39-45-63 >=0.1%Conc<1%: Xn; R20 Eu;A Methyl isocyanate - - - - - - all)

Page 111
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R23/24/25; R48/23; R36; R43

F; R11 F; T; N >=20%Conc<25%: T; R20/21/22; R48/23; R36;
T; R23/24/25-48/23 R: 11 - 23/24/25 - 36 - 43 - R43
Xi; R36 48/23 - 50 >=10%Conc<20%: T; R20/21/22; R48/23; R43
R43 S: (1/2) - 16 - 26 - 36/37/39 - >=3%Conc<10%: Xn; R20/21/22; R48/20; R43
624-86-2 o-Ethylhydroxylamine N; R50 45 - 60 - 61 >=1%Conc<3%: Xn; R48/20; R43 Eu - - - - - - - -
624-92-0 Dimethyl disulfide Xi; R36/38 Xi ; R: 36/38 Conc>=20%: Xi; R36/38 V - - - - - - - -
F ; Xn ; R: 11 - 20/21/22,
2-Chloropentane(Note: see also CAS No 543-59-9 & F; R11 S: (2) - 9 - 29 ;
625-29-6 616-20-5) Xn; R20/21/22 Note: C Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Conc>=25%: T; R60; R61; R22; R34
Repr. Cat. 2; R60-61 T ; R: 60 - 61 - 22 - 34 >=10%Conc<25%: T; R60; R61; R34
Xn; R22 S: 53 - 45; >=5%Conc<10%: T; R60; R61; R36/37/38
625-45-6 Methoxyacetic acid C; R34 Note: E >=0.5%Conc<5%: T; R60; R61 Eu - - - - - - - -
F; Xi
F; R11 R: 11-36/37-67
Xi; R36/37 S: (2-)9-16-24-33
625-55-8 Isopropyl formate(Note: see also CAS No. 110-74-7) R67 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
E
R: 3
625-58-1 Ethyl nitrate E; R3 S: (2-)23-24/25 Eu - - - - - - - -
626-17-5 m-Phthalodinitrile A m-Phthalodinitrile - 5 - - - - -
R10 Xn ; R: 10 - 20/21/22 ,
626-23-3 Di-sec-butylamine(Note: see also CAS No 111-92-2) Xn; R20/21/22 S: (2) Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
2-Pentyl acetate [1-Methylbutyl acetate; sec-Amyl R: 10 - 66,
acetate](Note: see also CAS No 123-92-2, 628-63-7, R10 S: (2) - 23 - 25;
626-38-0 624-41-9 & 84145-37-9) R66 Note: C Eu; A sec-Amyl acetate 50 270 100 541 - - -
627-13-4 n-Propyl nitrate A n-Propyl nitrate 25 107 40 172 - - -

T+; R26/27/28 T+; N Conc>=0.5%: T+; R26/27/28; R33

R33 R: 26/27/28-33-50/53 >=0.1%Conc<0.5%: T; R23/24/25; R33
627-44-1 Diethylmercury (Note: see also CAS No. 593-74-8) N; R50-53 S: (1/2-)13-28-36-45-60-61 >=0.05%Conc<0.1%: T; R20/21/22; R33 Eu - - - - - - - -

Conc>=25%: T; R23; R22; R48/22; R38; R41;

R43
>=20%Conc<25%: Xn; R20; R48/22; R38; R41;
R43
T; R23 >=10%Conc<20%: Xn; R20; R48/22; R41; R43
Xn; R22-48/22 T >=5%Conc<10%: Xn; R20; R36; R43
Xi; R38-41 R: 22-23-38-41-43-48/22 >=3%Conc<5%: Xn; R20; R43
628-11-5 3-Chloropropyl chloroformate R43 S: (1/2-)26-36/37/39-45 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
R: 10 - 66,
n-Amyl acetate [Pentyl acetate](Note: see also CAS R10 S: (2) - 23 - 25;
628-63-7 No 123-92-2, 624-41-9, 626-38-0 & 84145-37-9) R66 Note: C Eu; A n-Amyl acetate 50 270 100 541 - - -
E; R3 E ; T ; N ; R: 3 - 23/24/25 -
T; R23/24/25 33 - 50/53, Conc>=25%: T; R23/24/25; R33
Mercuric fulminate [Fulminate of mercury; Mercury R33 S: (1/2) - 3 - 35 - 45 - 60 - >=3%Conc<25%: Xn; R20/21/22; R33
628-86-4 difulminate] N; R50-53 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
E; T+
E; R3 R: 3-26/27/28-33 Conc>=7%: T+; R26/27/28; R33
T+; R26/27/28 S: (1/2-)27/28-33-35-36/37- >=1%Conc<7%: T; R23/24/25; R33 Ethylene glycol
628-96-6 Ethylene dinitrate [Ethylene glycol dinitrate] R33 45 >=0.1%Conc<1%: Xn; R20/21/22 Eu;A dinitrate 0.05 0.31 - - - Sk -
F; R11
R19
Repr. Cat. 2; R61 F; T Conc>=20%: T; R61; R62; R36
Repr. Cat. 3; R62 R: 61-11-19-36-62 >=5%Conc<20%: T; R61; R62
629-14-1 1,2-Diethoxyethane Xi; R36 S: 53-45 >=0.5%Conc<5%: T; R61 Eu - - - - - - - -

Page 112
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F+ ; T ; R: 61 - 12 - 23 -
F+; R12 48/23 , Conc>=5%: T; R61; R23-48/23
Repr. Cat. 1; R61 S: 53 - 45 ; >=0.5%Conc<5%: T; R61; R20-48/20 Carbon monoxide (see footnote
630-08-0 Carbon monoxide T; R23-48/23 Note: E >=0.2%Conc<0.5%: T; R61 Eu; A (e) 30 34 - - - - (e))
Conc>=25%: T; R23/25; R33
T; R23/25 T ; R: 23/25 - 33 , >=3%Conc<25%: Xn; R20/22; R33
630-60-4 Ouabain R33 S: (1/2) - 45 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
E; R2
Xn; R20/21/22 E ; Xn ; R: 2 - 20/21/22 - 33 , Conc>=25%: Xn; R20/21/22; R33
632-92-8 2,4,6-Trinitro-m-xylene R33 S: (2) - 35 >=1%Conc<25%: Xn; R33 Eu - - - - - - - -
F; R: 11 -
S: (2) - 16 – 23 – 24 - 29 -
637-78-5 Isopropyl propionate F; R11 33 Eu - - - - - - - -
0.05 Peak 0.23 Peak
638-21-1 Phenylphosphine A Phenylphosphine limitation limitation - - - - -
Xi; R: 10 - 36/37,
Pentyl formate [n-Amyl formate](Note: see also CAS R10 S: (2) - 24;
638-49-3 No 110-45-2 & 35073-27-9]) Xi; R36/37 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
Thiometon (ISO) [S-2-Ethylthioethyl O,O-dimethyl T; R25 T ; R: 21 - 25 , Conc>=25%: T; R25; R21
640-15-3 phosphorodithioate] Xn; R21 S: (1/2) - 36/37 - 45 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
>=3%Conc<7%: T; R25; R21
T+; R28 T+ ; R: 24 - 28 , >=1%Conc<3%: T; R25
640-19-7 2-Fluoroacetamide T; R24 S: (1/2) - 36/37 - 45 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
T; R25 T ; N ; R: 21 - 25 - 50/53,
1-Dimethylcarbamoyl-5-methylpyrazol-3-yl Xn; R21 S: (1/2) - 36/37 - 45 - 60 - Conc>=25%: T; R25; R21
644-64-4 dimethylcarbamate [Dimetilan (ISO)] N; R50-53 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
F; R11,
646-06-0 1,3-Dioxolane F; R11 S: (2) - 16 Eu - - - - - - - -
Xi; N
Xi; R37 R: 37 - 50/53
650-51-1 TCA-sodium (ISO) [Sodium trichloroacetate] N; R50/53 S: (2) - 46 - 60 - 61 Conc>=20%: Xi; R37 Eu - - - - - - - -
Xi Conc>=20%: Xi; R38; R41
R: 38-41 >=10%Conc< 20%: Xi; R41
652-18-6 2,3,5,6-Tetrafluorobenzoic acid Xi; R38-41 S: (2-)22-26-37/39 >=5% Conc<10%: Xi; R36 Eu - - - - - - - -
Xn ; R: 20/21/22 ,
659-49-4 4-Nitrosoaniline Xn; R20/21/22 S: (2) - 25 - 28 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Xn ; R: 10 - 20 ,
R10 S: (2) - 3 ;
674-82-8 Diketene [Diketen] Xn; R20 Note: D Conc>=25%: Xn; R20 Eu - - - - - - - -
T
Hexamethyl phosphoramide [Hexamethylphosphoric Carc. Cat. 2; R45 R: 45 - 46 Conc>=0.1%: T; R45; R46 Hexamethyl
680-31-9 triamide] Muta. Cat. 2; R46 S: 53 - 45 >=0.001%Conc<0.1%: T; R45 Eu; A phosphoramide (d) - - - - 2 Sk -
Methyl silicate [Tetramethyl orthosilicate; Methyl
681-84-5 orthosilicate] A Methyl silicate 1 6 - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
>=3%Conc<7%: T; R25; R21
Demephion-O (ISO) [O,O-Dimethyl O-2- T+; R28 T+ ; R: 24 - 28 , >=1%Conc<3%: T; R25
682-80-4 methylthioethyl phosphorothioate] T; R24 S: (1/2) - 28 - 36/37 - 45 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

Page 113
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R60; R61; R68; R26; R25;

R48/25; R34; R21
>=10%Conc<25%: T+; R60; R61; R68; R26;
R48/25; R34; R22
>=7%Conc<10%: T+; R60; R61; R68; R26;
R22; R48/22; R36/38
Mut. Cat. 3; R68 >=3%Conc<7%: T; R60; R61; R68; R23; R22;
Repr. Cat. 2; R60-61 R48/22; R36/38
T+; R26 T+; C; N >=1%Conc<3%: T; R60; R61; R68; R23;
T; R25-48/25 R: 60-61-21-25-26-34-48/25- R48/22; R36/38
C; R34 68-50/53 >=0.5%Conc<1%: T; R60; R61; R20; R36/38 Tin, organic
Xn; R21 S: 53-45-60-61 >=0.1%Conc<0.5%: Xn; R20; R36/38 compounds (as
683-18-1 Dibutyltin dichloride(DBTC) N; R50-53 Note: E >=0.01%Conc<0.1%: Xi; R36/38 Eu;A Sn) - 0.1 - 0.2 - Sk -

684-16-2 Hexafluoroacetone A Hexafluoroacetone 0.1 0.68 - - - Sk -

R10 Xi ; R: 10 - 37 - 41, Conc>=20%: Xi; R41; R37
Ethyl L-lactate [Ethyl-(S)-lactate; Ethyl (S)-2- Xi; R37 S: (2) - 24 - 26 - 39; >=10%Conc<20%: Xi; R41
687-47-8 hydroxypropionate](Note: see also CAS No 97-64-3) Xi; R41 Note: C >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
E; R3 E ; T+ ; R: 3 - 26/27/28 - 33 -
T+; R26/27/28 52/53, Conc>=7%: T+; R26/27/28; R33
Diethylene glycol dinitrate [Digol dinitrate; R33 S: (1/2) - 33 - 35 - 36/37 - >=1%Conc<7%: T; R23/24/25; R33
693-21-0 Oxydiethylene dinitrate] R52-53 45 - 61 >= 0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
Xi; R41 Xn ; N ; R: 22 - 41 - 43 - >=10%Conc<25%: Xi; R41; R43
R43 51/53 >=5%Conc<10%: Xi; R36; R43
694-64-4 2,2-Ethylmethylthiazolidine N; R51-53 S: (2)24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
E
R: 2
696-33-3 Iodoxybenzene E; R2 S: (2-)35 Eu - - - - - - - -
T ; N ; R: 23/24/25 - 33 -
52/53,
N-Methyl-m-toluidine [Benzenamine, N,3- T; R23/24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R23/24/25; R33
dimethyl](Note: see also CAS No 611-21-2 & 623-08- R33 61; >=3%Conc<25%: Xn; R20/21/22; R33
696-44-6 5) N; R52-53 Note: C >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
Conc>=25%: Xn; R20; R37/38; R41; R43
Xn; R20 Xn ; N ; R: 20 - 37/38 - 41 - >=20%Conc<25%: Xi; R37/38; R41; R43
Xi; R37/38-41 43 - 50/53, >=10%Conc<20%: Xi; R41; R43
R43 S: (2) - 24 - 26 - 37/39 - 60 - >=5%Conc<10%: Xi; R36; R43
700-13-0 2,3,5-Trimethylhydroquinone N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; N
Xn; R22 R: 22-50
709-98-8 Propanil (ISO) [3',4'-Dichloropropionanilide] N; R50 S: (2-)22-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; N
Xn; R48/22 R: 48/22-51/53
719-86-8 3-Acetyl-1-phenyl-pyrrolidine-2,4-dione N; R51-53 S: (2-)22-36/37-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
N-(Dichlorofluoromethylthio)phthalimide [N- Xi ; R: 38 ,
719-96-0 (Fluorodichloromethylthio)phthalimide] Xi; R38 S: (2) - 28 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xi; R41 Conc>=10%: Xi; R41; R43
R43 Xi ; N ; R: 41 - 43 - 51/53, >=5%Conc<10%: Xi; R36; R43
723-38-6 2-Methyl-5-(1,1,3,3-tetramethylbutyl)hydroquinone N; R51-53 S: (2) - 24/25 - 26 - 37 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Tolylfluanid (ISO) [Dichloro-N-
[(dimethylamino)sulphonyl]fluoro-N-(p-
tolyl)methanesulphenamide](Note: containing < 0.1 Xi; R36/37/38 Xi; N
% (w/w) of particles with an aerodynamic diameter of R43 R: 36/37/38-43-50 Conc>=20%: Xi; R36/37/38; R43
731-27-1 below 50 micrometres) N; R50 S: (2-)25-36/37-46-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Tolylfluanid (ISO) [Dichloro-N- T+; R26 Conc>=20%: T+; R26; R48/23; R36/37/38; R43
[(dimethylamino)sulphonyl]fluoro-N-(p- T; R48/23 T+; N >=10%Conc<20%: T+; R26; R48/23; R43
tolyl)methanesulphenamide](Note: containing >= 0.1 Xi; R36/37/38 R: 26-36/37/38-43-48/23-50 >=7%Conc<10%: T+; R26; R48/20; R43
% (w/w) of particles with an aerodynamic diameter of R43 S: (1/2-)28-36/37/39-45-63- >=1%Conc<7%: T; R23; R48/20; R43
731-27-1 below 50 micrometres) N; R50 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; N
Phosmet (ISO) [O,O-Dimethyl phthalimidomethyl S- Xn; R21/22 R: 21/22-50/53
732-11-6 phosphorodithioate] N; R50-53 S: (2-)22-36/37-60-61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Xn; N
Bensulide (ISO) [O,O-Diisopropyl 2- Xn; R22 R: 22-50/53
741-58-2 phenylsulphonylaminoethyl phosphorodithioate] N; R50-53 S: (2-)24-36-60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
1,1,1,2,2,4,5,5,5-Nonafluoro-4-(trifluoromethyl)- 3- R: 52/53
756-13-8 pentanone R52-53 S: 61 Eu - - - - - - - -
Xn ; R: 22 ,
759-94-4 EPTC (ISO) [S-Ethyl dipropylthiocarbamate] Xn; R22 S: (2) - 23 Conc>=25%: Xn; R22 Eu - - - - - - - -
F ; Xi ; R: 11 - 36/37,
tert-Butyl formate(Note: see also CAS No 542-55-2 & F; R11 S: (2) - 9 - 16 - 24 - 33;
762-75-4 592-84-7) Xi; R36/37 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -

Conc>=25%: T+; R45; R26; R24/25; R34

>=10%Conc<25%: T+; R45; R26; R21/22; R34
>=7%Conc<10%: T+; R45; R26; R21/22;
R36/37/38
>=5%Conc<7%: T; R45; R23; R21/22;
Carc. Cat. 2; R45 R36/37/38
T+; R26 T+; N >=3%Conc<5%: T; R45; R23; R21/22
T; R24/25 R: 45-24/25-26-34-50/53 >=1%Conc<3%: T; R45; R23
C; R34 S: 53-45-60-61; >=0.1%Conc<1%: T; R45; R20
764-41-0 1,4-Dichlorobut-2-ene [2-Butene, 1,4-dichloro] N; R50-53 Note: E >=0.01%Conc<0.1%: T; R45 Eu - - - - - - - -

768-52-5 N-Isopropylaniline A N-Isopropylaniline 2 11 - - - Sk -

Xi; R38 Xi ; N ; R:38 - 51/53,
768-56-9 4-Phenylbut-1-ene N; R51-53 S: (2) - 37 - 61 Conc>=20%: Xn; R38 Eu - - - - - - - -
O; R7 O; C; N
Xn; R22 R: 7-22-34-50/53 Conc>=25%: C;34; R22
1,2,3,4-Tetrahydro-1-naphthyl hydroperoxide [Teralin C; R34 S: (1/2-)3/7-14-26-36/37/39- >=10%Conc<25%: C; R34
771-29-9 hydroperoxide] N; R50-53 45-60-61 >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -
T ; N ; R: 24/25 - 50/53,
Carbophenothion (ISO) [4-Chlorophenylthiomethyl T; R24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R24/25
786-19-6 O,O-diethyl phosphorodithioate] N; R50-53 60 - 61 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
811-54-1 Formic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

1,1,1,2-
811-97-2 1,1,1,2-Tetrafluoroethane [HFC 134a] A Tetrafluoroethane 1000 4240 - - - - -

Conc>=25%: T; R23/25; R21; R36/37/38; R43

T; R23/25 >=20%Conc<25%: Xn; R20/22; R36/37/38;
Xn; R21 R43
Xi; R36/37/38 T >=3%Conc<20%: Xn; R20/22; R43
814-71-1 Acetic acid, mercapto-, calcium salt (2:1) R43 R: 21-23/25-36/37/38-43 >=1%Conc<3%: Xi; R43 N - - - - - - - -
T; R24 T; N Conc>=10%: T; R24; R34; R43
C; R34 R: 24-34-43-50 >=5%Conc<10%: T; R24; R36/38; R43
R43 S: (1/2-)26-36/39-45-61; >=2%Conc<5%: T; R24; R43
818-61-1 2-Hydroxyethyl acrylate N; R50 Note: D >=0.2%Conc<2%: Xn; R21; R43 Eu - - - - - - - -

T; R23 Conc>=20%: T; R23; R36/37/38; R42/43 (see

Xi; R36/37/38 T ; R: 23 - 36/37/38 - 42/43 , >=2%Conc<20%: T; R23; R42/43 Hexamethylene Isocyanates,
822-06-0 Hexamethylene-diisocyanate R42/43 S: (1/2) - 26 - 28 - 38 - 45 >=0.5%Conc<2%: Xn; R20; R42/43 Eu, A diisocyanate - - - - - - all)
Muta. Cat. 3; R68
Xn; R21/22 Xn; N
2-Methyl-m-phenylene diamine [1,3- Xi; R43 R: 21/22-43-68-51/53 Conc>=25%: Xn; R68; R21/22; R43
823-40-5 Benzenediamine,2-methyl; 2,6-Toluene diamine] N; R51-53 S: (2-)24-36/37-61 >=1%Conc<25%: Xn; R68; R43 Eu - - - - - - - -
Xn
824-35-1 Benzoic acid, 2-hydroxy-, calcium salt (2:1) Xn; R22 R: 22 Conc>=25%: Xn; R22 N - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R22 Xn; Conc>=25%: Xn; R22; R36
824-39-5 Sodium ortho-nitrophenolate Xi; R36 R: 22-36 >=20%Conc<25%: Xi; R36 V - - - - - - - -
Xn; R22 Xn; Conc>=25%: Xn; R22; R36
824-78-2 Sodium para-nitrophenolate Xi; R36 R: 22-36 >=20%Conc<25%: Xi; R36 V - - - - - - - -

1,2,3,6-Tetrahydro-3,6-methanophthalic anhydride Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

[Himic anhydride](Note: see also CAS No 129-64-6 & Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
826-62-0 2746-19-2) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Xn; N
Ametryn (ISO) [2-Ethylamino-4-isopropylamino-6- Xn; R22 R: 22-50/53
834-12-8 methylthio-1,3,5-triazine] N; R50-53 S: (2-)36-60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 22 - 43 -
Xn; R22 50/53, Conc>=25%: T; R45; R22; R43
4,4'-Methylenedi-o-toluidine [Benzenamine, 4,4'- R43 S: 53 - 45 - 60 - 61; >=1%Conc<25%: T; R45; R43
838-88-0 methylenebis(2-methyl] N; R50-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68
R43 Xn ; R: 40 - 43 - 53 - 68
842-07-9 C.I. Solvent Yellow 14 [1-Phenylazo-2-naphthol] R53 S: (2)22 - 36/37 - 46 - 61 Conc>=1%: Xn; R40; R68; R43 Eu - - - - - - - -
F; R11 F ; C ; R: 11 - 14 - 34,
Potassium methanolate [Potassium methoxide](Note: R14 S: (1/2) - 8 - 16 - 26 - 43 - Conc>=10%: C; R34
865-33-8 see also CAS No 124-41-4 & 865-34-9) C; R34 45 >=5%Conc<10% Xi; R36/38 Eu - - - - - - - -
F; R11 F ; C ; R: 11 - 14 - 34,
Lithium methanolate [Lithium methoxide](Note: see R14 S: (1/2) - 8 - 16 - 26 - 43 - Conc>=10%: C; R34
865-34-9 also CAS No 124-41-4 & 865-33-8) C; R34 45 >=5%Conc<10% Xi; R36/38 Eu - - - - - - - -
Demeton-O-methyl (ISO) [O-2-Ethylthioethyl O,O- T ; R: 25 , Conc>=25%: T; R25
867-27-6 dimethyl phosphorothioate] T; R25 S: (1/2) - 24 - 36/37 - 45 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Xi ; R: 36/38 - 43 ,
Xi; R36/38. S: (2) - 26 - 28 ; Conc>=20%: Xi; R36/38; R43
868-77-9 2-Hydroxyethyl methacrylate R43 Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
T; R48/25 Conc>=20%: T; R48/25; R38 Tin, organic
Xi; R38 T ; R: 38 - 48/25 - 53 >=10%Conc<20%: T; R48/25 compounds (as
869-59-0 Trioctylstannane R53 S: (1/2) - 23 - 36/37 - 45 - 61 >=1%Conc<10%: Xn; R48/22 Eu Sn) - 0.1 - 0.2 - Sk -
T
Repr. Cat. 2; R61 R: 61-36/37/38 Conc>=10%: T; R61; R36/37/38 1-Methyl-2-
872-50-4 N-Methyl-2-pyrrolidone [1-Methyl-2-pyrrolidone] Xi; R36/37/38 S: 53-45 >=5%Conc<10%: T; R61 Eu;A pyrrolidone 25 103 75 309 - Sk -
Xn; R21/22 Xn ; R: 21/22 - 36 , Conc>=25%: Xn; R21/22; R36
873-32-5 2-Chlorobenzonitrile Xi; R36 S: (2) - 23 >=20%Conc<25%; Xi; R36 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
873-54-1 Benzoic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
E; N
E; R2 R: 2 - 7 - 50/53
O; R7 S: (2)7 - 14 - 36/37/39 - 47 -
895-85-2 Bis(4-methylbenzoyl)peroxide N; R50-53 60 - 61 Eu - - - - - - - -

Conc>=25%: T+; R40; R63; R26; R24/25;

R48/23; R37/38; R41
>=20%Conc<25%: T+; R40; R63; R26; R48/23;
R21/22; R37/38; R41
>=10%Conc<20%: T+; R40; R63; R26; R48/23;
R21/22; R41
>=7%Conc<10%: T+; R40; R63; R26; R21/22;
Carc. Cat. 3; R40 R48/20; R36
Repr. Cat. 3; R63 T+; N >=5%Conc<7%: T; R40; R63; R23; R21/22;
T+; R26 R: 24/25-26-37/38-40-41- R48/20; R36
T; R24/25-48/23 48/23-63-50/53 >=3%Conc<5%: T; R40; R23; R21/22; R48/20 Tin, organic
Xi; R37/38-41 S: (1/2-)26-28-36/37/39-45- >=1%Conc<3%: T; R40; R23; R48/20 compounds (as
900-95-8 Fentin acetate (ISO) [Triphenyltin acetate] N; R50-53 60-61 >=0.1%Conc<1%: Xn; R20 Eu;A Sn) - 0.1 - 0.2 - Sk -

Page 116
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F; R11 F ; C ; R: 11 - 14 - 34 ,
Potassium ethanolate [Potassium ethoxide](Note: R14 S: (1/2) - 8 - 16 - 26 - 43 - Conc>=10%: C; R34
917-58-8 see also CAS No 141-52-6) C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 52/53,
917-61-3 Sodium cyanate R52-53 S: (2) - 24/25 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: C; R34; R22
Xn; R22 C ; R: 22 - 34 , >=10%Conc<25%: C; R34
919-30-2 3-Aminopropyltriethoxysilane C; R34 S: (1/2) - 26 - 36/37/39 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Amidithion (ISO) [2-Methoxyethylcarbamoylmethyl Xn ; R: 22 ,

919-76-6 O,O-dimethyl phosphorodithioate] Xn; R22 S: (2) - 24 - 36 Conc>=25%: Xn; R22 Eu - - - - - - - -
T ; N ; R: 24/25 - 51/53,
Demeton-S-methyl (ISO) [S-2-Ethylthioethyl dimethyl T; R24/25 S: (1/2 ) - 28 - 36/37 - 45 - Conc>=25%: T; R24/25
919-86-8 phosphorothioate] N; R51-53 61 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
F; R15-17 R14 F; C; N
C; R35 R: 14/15-17-35-67-50/53 Conc>=10%: C; R35
R67 S: (1/2-)6-16-26-30-33- >=5%Conc<10%: C; R34
920-36-5 (2-Methylpropyl)lithium [Isobutyllithium] N; R50-53 36/37/39-43-45-60-61 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

Xi ; R: 36 - 43,
2-Hydroxypropyl methacrylate(Note: see also CAS Xi; R36 S: (2) - 24/25 - 26 - 37/39; Conc>=20%: Xi; R36, R43
923-26-2 No 2761-09-3) R43 Notes: C ; D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
F; R11 F ; Xn ; R: 11 - 20/22 ,
924-43-6 sec-Butyl nitrite Xn; R20/22 S: (2) - 16 - 24 - 46 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Xi ; R: 43 ,
924-99-2 Ethyl trans-3-dimethylaminoacrylate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Xn ; R: 41 - 42/43 - 51/53 ,
cis-1,2,3,6-Tetrahydrophthalic anhydride [1,3- Xi; R41 S: (2) - 22 - 24 - 26 - 37/39 - Conc>=10%: Xn; R42/43; R41
Isobenzofurandione, 3a,4,7,7a-tetrahydro-cis](Note: Xn; R42/43 61; >=5%Conc<10%: Xn; R42/43; R36
935-79-5 see also CAS No 85-43-8, 2426-02-0 & 26266-63-7) R51-53 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
T+ ; N ; R: 27/28 - 50/53, Conc>=7%: T+; R27/28
Fonofos (ISO) [o-Ethyl phenyl T+; R27/28 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R24/25
944-22-9 ethylphosphonodithioate] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R21/22 Eu; A Fonofos - 0.1 - - - Sk -
Conc>=7%: T+; R27/28
Phosfolan (ISO) [Diethyl 1,3-dithiolan-2- T+ ; R: 27/28 , >=1%Conc<7%: T; R24/25
947-02-4 ylidenephosphoramidate] T+; R27/28 S: (1/2) - 28 - 36/37 - 45 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
Conc>=7%: T+; R27/28
Mephosfolan (ISO) [Diethyl 4-methyl-1,3-dithiolan-2- T+; R27/28 T+ ; N ; R: 27/28 - 51/53, >=1%Conc<7%: T; R24/25
950-10-7 ylidenephosphoramidate] N; R51-53 S: (1/2) - 36/37/39 - 45 - 61 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
Conc>=25%: T+; R28; R21
Methidathion (ISO) [2,3-Dihydro-5-methoxy-2-oxo- T+; R28 T+ ; N ; R: 21 - 28 - 50/53 , >=7%Conc<25%: T+; R28
1,3,4-thiadiazol-3-ylmethyl-O,O- Xn; R21 S: (1/2) - 22 - 28 - 36/37 - >=1%Conc<7%: T; R25
950-37-8 dimethylphosphorodithioate] N; R50-53 45 - 60 - 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

T; N
Methylcarbophenothione [S-(Chlorophenylthiomethyl) T; R24/25 R: 24/25-50/53 Conc>=25%: T; R24/25
953-17-3 O,O-dimethylphosphorodithioate] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
Xn; R22
Xi; R36 Xn ; N ; R: 22 - 36 - 50/53 , Conc>=25%: Xn; R22; R36
954-16-5 2,4,6-Trimethylbenzophenone N: R50-53 S: (2) - 26 - 60 - 61 >=20%Conc<25%: Xi: R36 Eu - - - - - - - -
Xn
Diphenamid (ISO) [N,N-Dimethyl-2,2- Xn; R22 R: 22 - 52/53
957-51-7 diphenylacetamide] R52-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Dinobuton (ISO) [2-sec-Butyl-4,6-dinitrophenyl
isopropyl carbonate; 2-(1-Methylpropyl)-4,6- T; R25 T ; N ; R: 25 - 50/53 , Conc>=25%: T; R25
973-21-7 dinitrophenyl isopropyl carbonate] N: R50-53 S: (1/2) - 37 - 45 - 60 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Norbormide (ISO) [5-(alpha-Hydroxy-alpha-2-
pyridylbenzyl)-7-(alpha-2-pyridylbenzylidene) Xn ; R: 22 ,
991-42-4 bicyclo[2.2.1] hept-5-ene-2,3-dicarboximide] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
F; R11 F; Xn
Xn; R22 R: 11-22-67
994-05-8 2-Methoxy-2-methylbutane [tert-Amyl methyl ether] R67 S: (2-)9-16-23-33 Conc>=25%: Xn; R22 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=10%: T; R23/24/25; R34; R43

T; R23/24/25 T ; R: 23/24/25 - 34 - 43, >=5%Conc<10%: T; R23/24/25; R36/38; R43
2-Hydroxypropyl acrylate(Note: see also CAS No C; R34 S: (1/2) - 26 - 36/37/39 - 45; >=2%Conc<5%: T; R23/24/25; R43 2-Hydroxypropyl
999-61-1 2918-23-2 & 25584-83-2) R43 Notes: C ; D >=0.2%Conc<2%: Xn; R20/21/22; R43 Eu; A acrylate 0.5 2.8 - - - Sk -
Chlormequat chloride (ISO) [2- Xn ; R: 21/22 ,
999-81-5 Chloroethyltrimethylammonium chloride] Xn; R21/22 S: (2) - 36/37 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
N,N'-(2,2- Xi; R38 Xi ; R: 38 - 43 , Conc>=20%: Xi; R38; R43
1000-78-8 Dimethylpropylidene)hexamethylenediamine R43 S: (2) - 24 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Desmetryne (ISO) [6-Isopropylamino-2-methylamino- Xn; R21/22 Xn ; N ; R: 21/22 - 50/53,
1014-69-3 4-methylthio-1,3,5-triazine] N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Simetryn (ISO) [2,4-Bis(ethylamino)-6-methylthio- Xn; R22 Xn ; N ; R: 22 - 50/53,
1014-70-6 1,3,5-triazine] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Carc. Cat. 3; R40 T ; N ; R: 25 - 33 - 40 -
T; R25 50/53 , Conc>=25%: T; R40; R25; R33
Heptachlor epoxide [2,3-Epoxy-1,4,5,6,7,8,8- R33 S: (1/2) - 36/37 - 45 - 60 - >=3%Conc<25%: Xn: R40; R22; R33
1024-57-3 heptachloro-3a,4,7,7a-tetrahydro-4,7-methanoindane] N; R50-53 61 >=1%Conc<3%: Xn; R40; R33 Eu - - - - - - - -
Conc>=25%: Xn; R21/22; R38; R41
Xn; R21/22 Xn; N >=20%Conc<25%: Xi; R38; R41
Xi; R38-41 R: 21/22-38-41-51/53 >=10%Conc<20%: Xi; R41
1031-15-8 Methyltriphenylphosphonium chloride N; R51-53 S: (2-)22-26-36/37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T+ ; R: 27/28 , Conc>=7%: T+; R27/28
Triamiphos (ISO) [5-Amino-3-phenyl-1,2,4-triazol-1-yl- S: (1/2) - 22 - 28 - 36/37 - >=1%Conc<7%: T; R24/25
1031-47-6 N,N,N',N'-tetramethylphosphonic diamide] T+; R27/28 45 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 43 , Conc>=25%: Xn; R22; R43
1034-01-1 Octyl 3,4,5-trihydroxybenzoate R43 S: (2) - 24 - 37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

3-Ethyl-3-methylpentane(Note: see also CAS No. 111- F; R11

65-9, 540-84-1, 560-21-4, 563-16-6, 564-02-3, 565- Xn; R65 F; Xn; N
75-3, 583-48-2, 584-94-1, 589-43-5, 589-53-7, 589- Xi; R38 R: 11-38-65-67-50/53
81-1, 590-73-8, 592-13-2, 592-27-8, 594-82-1, 609- R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
1067-08-9 26-7, 619-99-8 & 26635-64-3) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
Xi; N
R43 R: 43-51/53
1070-64-0 Ethyl 6,8-dichlorooctanoate N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
C ; R: 21 - 34 - 43 , Conc>=25%: C; R34; R21; R43
Xn; R21 S: (1/2) - 26 - 36/37/39 - 45 >=10%Conc<25%: C; R34; R43
Tetramethylene diacrylate [1,4-Butyleneglycol C; R34 ; >=5%Conc<10%: Xi; R36/38; R43
1070-70-8 diacrylate] R43 Note: D >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; R41 Xi ; N ; R: 41 - 51/53 Conc>=10%: Xi; R41
1071-83-6 Glyphosate (ISO) [N-(Phosphonomethyl)glycine] N; R51-53 S: (2)26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
1072-35-1 Octadecanoic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
T; N
T; R25 R: 25-51/53 Conc>=25%: T; R25
1075-89-4 8-Azaspiro[4.5]decane-7,9-dione N; R51-53 S: (1/2-)22-36-45-61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Xn; R20
Xi; R36 Xn; N Conc>=25%: Xn; R20; R36; R43
Dichlofluanid (ISO) [N-Dichlorofluoromethylthio-N',N'- R43 R: 20-36-43-50 >=20%Conc<25%: Xi; R36; R43
1085-98-9 dimethyl-N-phenylsulfamide] N; R50 S: (2-)24-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
1111-67-7 Cuprous thiocyanate Xi; R36/38 Xi ; R: 36/38 Conc>=20%: Xi R36/38 V - - - - - - - -
T; R25 T ; N ; R: 21 - 25 - 50 ,
Omethoate (ISO) [O,O-Dimethyl S- Xn; R21 S: (1/2) - 23 - 36/37 - 45 - Conc>=25%: T; R25; R21
1113-02-6 methylcarbamoylmethyl phosphorothioate] N; R50 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -

Pebulate (ISO) [S-Propyl butyl (ethyl) thiocarbamate; Xn; R22 Xn ; N ; R: 22 - 51/53,

1114-71-2 N-Butyl-N-ethyl-S-propylthiocarbamate] N; R51-53 S: (2) - 23 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
T: R: 45,
1116-54-7 2,2''-(Nitrosoimino)bisethanol Carc. Cat. 2; R45 S: 53 - 45 Conc>=0.1%: T; R45 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
1120-46-3 9-Octadecenoic acid, lead(2+) salt, (Z)- R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
T ; R: 45 - 21/22 ,
1,3-Propanesultone [1,2-Oxathiolane 2,2-dioxide; Carc. Cat. 2; R45 S: 53 - 45 ; Conc>=25%: T; R45; R21/22 Propane sultone
1120-71-4 Propane sultone] Xn; R21/22 Note: E >=0.01%Conc<25%: T; R45 Eu; A (d) - - - - 2 - -
Xn; R22 Xn ; N ; R: 22 - 51/53,
1129-41-5 Metolcarb (ISO) [m-Tolyl methylcarbamate; MTMC] N; R51-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

C
R: 34 Conc>=10%: C; R34
1132-95-2 1,1-Diisopropoxycyclohexane C; R34 S: (1/2-)23-26-36/37/39-45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
R43 Xi ; N ; R: 43 - 51/53
1134-94-7 2-Phenylthioaniline N; R51-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi ; R: 43 ,
1166-52-5 Dodecyl 3,4,5-trihydroxybenzoate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
1184-64-1 Copper carbonate Xn; R22 Xn ; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -

tert-Butyl chromate 0.1 Peak

1189-85-1 tert-Butyl chromate (as CrO3) A (as CrO3) - limitation - - - Sk -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
1191-79-3 Octadecanoic acid, barium cadmium salt (4:1:1) Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Xn; N
Xn; R21 R: 21 - 51/53
1194-65-6 Dichlobenil (ISO) [2,6-Dichlorobenzonitrile] N; R51-53 S: (2) - 36/37 - 61 Conc>=25%: Xn; R21 Eu - - - - - - - -
N
1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8- R: 50/53
1222-05-5 hexamethylindeno[5,6-c]pyran [Galaxolide (HHCB)] N; R50-53 S: 60-61 Eu - - - - - - - -
Conc>=25%: T+; R68; R26; R22
Muta. Cat. 3; R68 T+ >=7%Conc<25%: T+; R68; R26
Ethidium bromide [3,8-Diamino-1-ethyl-6- T+; R26 R: 22-26-68 >=1%Conc<7%: T; R68; R23
1239-45-8 phenylphenantridinium bromide] Xn; R22 S: (1/2-)28-36/37-45-63 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -

T ; N ; R: 24/25 - 34 - 51/53, Conc>=25%: T; R24/25; R34

Xylenol [Dimethylphenol](Note: see also CAS No 95- T; R24/25 S: (1/2) - 26 - 36/37/39 - 45 - >=10%Conc<25%: C; R34; R21/22
65-8, 95-87-4, 105-67-9, 526-75-0, 576-26-1 & 71975- C; R34 61; >=5%Conc<10%: Xn; R21/22; R36/38
1300-71-6 58-1) N; R51-53 Note: C >=3%Conc<5%: Xn; R21/22 Eu - - - - - - - -
Xi
1300-72-7 Benzenesulfonic acid, dimethyl-, sodium salt Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
T ; N ; R: 23/24/25 - 33 -
51/53,
T; R23/24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R23/24/25; R33
R33 61; >=3%Conc<25%: Xn; R20/21/22; R33
1300-73-8 Xylidine N; R51-53 Note: C >=1%Conc<3%: Xn; R33 Eu; A Xylidine 0.5 2.5 - - 2 Sk -

Conc>=25%: T; R45; R60; R23; R48/23

>=10%Conc<25%: T; R45; R60; R48/23; R20;
>=3%Conc<10%: T; R45; R60; R20; R48/20
Carc. Cat. 2; R45 >=1%Conc<3%: T; R45; R60; R48/20
Repr. Cat. 2; R60 T >=0.5%Conc<1%: T; R45; R60
1303-00-0 Gallium arsenide (GaAs) T; R23-48/23 R: 45-60-23-48/23 >=0.1%Conc<0.5%: T; R45 N - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R45; R68; R23/25; R34; R21;

R48/20/21/22
Carc. Cat. 1; R45 >=10%Conc<25%: T; R45; R68; R34; R20/22;
Muta. Cat. 3; R68 R48/20/21/22
T; R23/25 >=5%Conc<10%: T; R45; R68; R20/22; R36/38
Xn; R21-48/20/21/22 T; N >=3%Conc<5%: T; R45; R68; R20/22
Arsenic oxide (As2O5) [Arsenic pentoxide; Diarsenic C; R34 R: 45-21-23/25-34- >=1%Conc<3%: T; R45; R68
1303-28-2 pentaoxide] N; R50-53 48/20/21/22-68-50-53 >=0.1%Conc<1%: T; R45 N - - - - - - - -

Conc>=25%: T+; R45; R68; R28; R23;

R48/23/25
>=10%Conc<25%: T+; R45; R68; R28;
R48/23/25; R20
>=7%Conc<10%: T+; R45; R68; R28; R20;
R48/20/22
Carc. Cat. 1; R45 >=3%Conc<7%: T; R45; R68; R25; R20;
Muta. Cat. 3; R68 R48/20/22
T+; R28 T+ >=1%Conc<3%: T; R45; R68; R25; R48/20/22
1303-36-2 Arsenic selenide (As2Se3) T; R23-48/23/25 R: 45-48/23/25-23-28-68 >=0.1%Conc<1%: T; R45; R22 N - - - - - - - -
T
R: 60-61
1303-86-2 Diboron trioxide [Boric oxide] Repr. Cat. 2; R60-61 S: 53-45 Conc>=3.1%: T; R60; R61 Eu;A Boron oxide - 10 - - - - -
T Borates, tetra,
Disodium tetraborate decahydrate [Borax R: 60-61 sodium salts
1303-96-4 decahydrate] Repr. Cat. 2; R60-61 S: 53-45 Conc>=8.5%: T; R60; R61 Eu;A (decahydrate) - 5 - - - - -
O; R8 O ; Xn ; R: 8 - 20/22 ,
1304-29-6 Barium peroxide Xn; R20/22 S: (2) - 13 - 27 Conc>=25%: Xn; R20/22 Eu - - - - - - - -

Conc>=25%: T+; R49; R26; R25; R48/23;

R36/37/38; R43
>=20%Conc<25%: T+; R49; R26; R22; R48/23;
R36/37/38; R43
>=10%Conc<20%: T+; R49; R26; R22; R48/23;
R43
>=7%Conc<10%: T+; R49; R26; R22; R48/20;
Carc. Cat. 2; R49 R43
T+; R26 T+ ; R: 49 - 25 - 26 - >=3%Conc<7%: T; R49; R23; R22; R48/20;
T; R25-48/23 36/37/38 - 43 - 48/23 R43
Xi; R36/37/38 S: 53 - 45; >=1%Conc<3%: T; R49; R23; R48/20; R43 Beryllium &
1304-56-9 Beryllium oxide R43 Note: E >=0.1%Conc<1%: T; R49; R20 Eu compounds - 0.002 - - 2 - -
Bismuth telluride undoped [Bismuth telluride Se-
1304-82-1 doped] A Bismuth telluride - 10 - - - - -
Bismuth telluride undoped [Bismuth telluride Se- Bismuth telluride,
1304-82-1 doped] A Se-doped - 5 - - - - -

1305-62-0 Calcium hydroxide A Calcium hydroxide - 5 - - - - -

1305-78-8 Calcium oxide A Calcium oxide - 2 - - - - -
F; T+; N
F; R15/29 R: 15/29-28-50 Conc>=7%: T+; R28
T+; R28 S: (1/2-)22-28-36/37-43-45- >=1%Conc<7%: T; R25
1305-99-3 Calcium phosphide [Tricalcium diphosphide] N; R50 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

Conc>=25%: T+; R45; R62; R63; R68; R26;

R25; R48/23/25
>=10%Conc<25%: T+; R45; R62; R63; R68;
Carc. Cat. 2; R45 R26; R48/23/25; R22
Muta. Cat. 3; R68 >=7%Conc<10%: T+; R45; R62; R63; R68;
Repr. Cat. 3; R62-63 R26; R22; R48/20/22
T+; R26 T+; N >=5%Conc<7%: T; R45; R62; R63; R68; R23; Cadmium and
T; R25-48/23/25 R: 45-25-26-48/23/25-62-63- R22; R48/20/22 compounds (as
1306-19-0 Cadmium oxide (CdO) (non-pyrophoric) N; R50-53 68-50-53 >=3%Conc<5%: T; R45; R68; R N/Eu; A Cd) - 0.01 - - 2 - -

Page 120
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 2; R45 Conc>=10%: T; R45; R68; R62/63; R48/23/25;
Muta. Cat. 3; R68 R22
Repr. Cat. 3; R62-63 T; N >=5%Conc<10%: T; R45; R68; R62/63;
T; R48/23/25 R: 45-22-48/23/25-62-63-68- R48/20/22 Cadmium and
Xn; R22 53 >=1%Conc<5%: T; R45; R68; R48/20/22 compounds (as
1306-23-6 Cadmium sulphide R53 S: 53-45-61; Note: E >=0.1%Conc<1%: T; R45; R48/20/22 Eu; A Cd) - 0.01 - - 2 - -
Xn; R22 Xn; N
R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
1307-96-6 Cobalt oxide N; R50-53 S: (2-)24-37-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Iron oxide fume (see Chapter
1309-37-1 Iron oxide fume (as Fe) A (Fe2O3) (as Fe) - 5 - - - - 17)
Magnesium oxide
1309-48-4 Magnesium oxide (fume) A (fume) - 10 - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Repr. Cat. 1; R61 Conc>=5%: T; R40; R61; R62; R68; R33
Repr. Cat. 3; R62 T >=1%Conc<5%: T; R40; R61; R68; R33
1309-60-0 Lead oxide (PbO2) R33 61-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Antimony trioxide,
Antimony trioxide,handling and use (as Sb) Xn ; R: 40 , handling and use
1309-64-4 production Carc. Cat. 3; R40 S: (2) - 22 - 36/37 Conc>=1%: Xn; R40 Eu; A (as Sb) - 0.5 - - - - -

Antimony trioxide,handling and use (as Sb) Xn ; R: 40 , Antimony trioxide,

1309-64-4 production Carc. Cat. 3; R40 S: (2) - 22 - 36/37 Conc>=1%: Xn; R40 Eu; A production (d) - - - - 2 - -
Conc>=25%: C; R35; R22
>=5%Conc<25%: C; R35
Xn; R22 C ; R: 22 - 35 , >=2%Conc<5%: C; R34 Potassium 2 Peak
1310-58-3 Potassium hydroxide [Caustic potash] C; R35 S: (1/2) - 26 - 36/37/39 - 45 >=0.5%Conc<2%: Xi; R36/38 Eu; A hydroxide - limitation - - - - -
Conc>=5%: C; R35
C ; R: 35 , >=2%Conc<5%: C; R34 2 Peak
1310-73-2 Sodium hydroxide C; R35 S: (1/2) - 26 - 37/39 - 45 >=0.5%Conc<2%: Xi; R36/38 Eu; A Sodium hydroxide - limitation - - - - -
R31
C; R34 C ; N ; R: 31 - 34 - 50, Conc>=10%: C; R34; R31
1312-73-8 Potassium sulphide [Dipotassium sulphide] N; R50 S: (1/2) - 26 - 45 - 61 >=5%Conc<10%: Xi; R36/38; R31 Eu - - - - - - - -
Xn ; R: 20/22 ,
1313-13-9 Manganese dioxide Xn; R20/22 S: (2) - 25 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Carc. Cat. 3; R40 Xn Conc>=20%: Xn; R40; R36/37
1313-27-5 Molybdenum oxide (MoO3) [Molybdenum trioxide] Xi; R36/37 R: 36/37-40 >=1%Conc<20%: Xn; R40 N - - - - - - - -
Conc>=10%: C; R35
O; R8 O ; C ; R: 8 - 35 , >=5%Conc<10%: C; R34
1313-60-6 Sodium peroxide C; R35 S: (1/2) - 8 - 27 - 39 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
T; R24
Xn; R22 Conc>=25%: T; R34; R24; R22
C; R34 T; C; N >=10%Conc<25%: C; R34; R21
R31 R: 22-24-31-34-50 >=5%Conc<10%: Xn; R21; R36/38
1313-82-2 Disodium sulfide [Sodium sulfide] N; R50 S: (1/2-)26-36/37/39-45-61 >=3%Conc<5%: Xn; R21 Eu - - - - - - - -
Carc. Cat. 1; R49 Conc>=10%: T; R49; R48/23; R43
T; R48/23 T >=1%Conc<10%: T; R49; R48/20; R43
1313-99-1 Nickel oxide, (NiO) [Nickel monoxide] R43 R: 49-43-48/23 >=0.1%Conc<1%: T; R49 N/Eu - - - - - - - -
Carc. Cat. 1; R49 T
R43 R: 49 - 43 - 53 Conc>=1%: T; R49; R43
1314-06-3 Dinickel trioxide R53 S: 53 - 45 - 61 >=0.1%Conc<1%: T; R49 Eu - - - - - - - -
Zinc oxide (dust)
1314-13-2 Zinc oxide (dust) A (a) - 10 - - - - -

Zinc oxide (fume) A Zinc oxide (fume) - 5 - 10 - - -

N
R: 50/53 Zinc oxide (dust)
1314-13-2 Zinc oxide N; R50-53 S: 60-61 Eu; A (a) - 10 - - - - -
N
R: 50/53
1314-13-2 Zinc oxide N; R50-53 S: 60-61 Eu; A Zinc oxide (fume) - 5 - 10 - - -

Page 121
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Repr. Cat. 1; R61 Conc>=5%: T; R40; R61; R62; R68; R33
Repr. Cat. 3; R62 T >=1%Conc<5%: T; R40; R61; R68; R33
1314-27-8 Lead oxide (Pb2O3) R33 61-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Repr. Cat. 1; R61 Conc>=5%: T; R40; R61; R62; R68; R33
Repr. Cat. 3; R62 T >=1%Conc<5%: T; R40; R61; R68; R33
1314-41-6 Lead oxide (Pb3O4) R33 61-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Conc>=10%: C; R35
C ; R: 35 , >=5%Conc<10%: C; R34
1314-56-3 Phosphorus pentoxide C; R35 S: (1/2) - 22 - 26 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

Muta. Cat. 3; R68 Conc>=25%: T; R68; R48/23; R63; R20/22;

Repr. Cat. 3; R63 R37
Vanadium pentoxide [Vanadium (asV2O5), respirable T; R48/23 T ; N ; R: 20/22 - 37 - 48/23 >=20%Conc<25%: T; R68; R48/23; R63; R37
dust &amp; fume; Divanadium pentaoxide](Note: The Xn; R20/22 - 63 - 51/53 - 68, >=5%Conc<20%: T; R68; R48/23; R63 Vanadium (as
UN No. 2862 can only be used for the non-fused form Xi; R37 S: (1/2) - 36/37 - 38 - 45 - >=1%Conc<5%: Xn; R68; R48/20 V2O5), (respirable
1314-62-1 of vanadium pentoxide) N; R51-53 61 >=0.5%Conc<1%: Xn; R48/20 Eu; A dust & fume) - 0.05 - - - - -
F; R11
R29 F; Xn ; N ; R: 11 - 20/22 - 29
Phosphorus pentasulphide [Diphosphorus Xn; R20/22 - 50, Phosphorus
1314-80-3 pentasulphide] N; R50 S: (2) - 61 Conc>=25%: Xn; R20/22; R29 Eu; A pentasulphide - 1 - 3 - - -
F; R15/29 F; T+; N
T+; R28 R: 15/29-28-32-50/53 Conc>=7%: T+; R28
R32 S: (1/2-)28-30-36/37-43-45- >=1%Conc<7%: T; R25
1314-84-7 Trizinc diphosphide [Zinc phosphide] N; R50-53 60-61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

F; R11
Phosphorus sesquisulphide [Tetraphosphorus Xn; R22 F ; Xn ; N ; R: 11 - 22 - 50,
1314-85-8 trisulphide] N; R50 S: (2) - 7 - 16 - 24/25 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Repr. Cat. 1; R61 Conc>=5%: T; R40; R61; R62; R68; R33
Repr. Cat. 3; R62 T >=1%Conc<5%: T; R40; R61; R68; R33
1317-36-8 Lead oxide (PbO) R33 61-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xn; N
Xn; R22 R: 22-50/53
1317-39-1 Dicopper oxide [Copper (I) oxide] N; 50-53 S: (2-)22-60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi; N
R43 R: 43-50/53
1317-42-6 Cobalt sulfide N; R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
(see Silica -
1317-95-9 Silica crystalline [Tripoli] A Tripoli - - - - - - Crystalline)
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Repr. Cat. 1; R61 Conc>=25%: T; R40; R61; R62; R68; R20; R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20 T >=1%Conc<5%: T; R40; R61; R68; R33
1319-46-6 Lead, bis(carbonato(2-))dihydroxytri- R33 R: 61-20-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
T ; R: 24/25 - 34 ,
Cresol, all isomers(Note: see also CAS No 108-39-4, T; R24/25 S: (1/2 ) - 36/37/39 - 45; Conc>=5%: T; R24/25; R34
1319-77-3 95-48-7& 106-44-5) C; R34 Note: C >=1%Conc<5%: Xn; R21/22; R36/38 Eu; A Cresol, all isomers 5 22 - - - Sk -
Xn; R22 Xn Conc>=25%: Xn; R22; R36/38; R43
Xi; R36/38 R: 22 - 36/38 - 43 >=20%Conc<25%: Xi; R36/38; R43
1321-23-9 Chloroxylenol(Note: see also CAS No 88-04-0) R43 S: (2) - 24 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn ; N ; R: 21/22 - 36/38 -
Xn; R21/22 50/53 ,
Xi; R36/38 S: (2) - 35 - 60 - 61 ; Conc>=25%: Xn; R21/22; R36/38 Pentachloronaphth
1321-64-8 Pentachloronaphthalene N; R50-53 Note: C >=20%Conc<25%: Xi: R36/38 Eu; A alene - 0.5 - - - - -
Trichloronaphthale
1321-65-9 Trichloronaphthalene A ne - 5 - - - Sk -

Page 122
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
1321-74-0 Divinyl benzene A Divinyl benzene 10 53 - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Xn; R22 Xn >=10%Conc<20%: Xi; R41
1322-98-1 Benzenesulfonic acid, decyl-, sodium salt Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Conc>=25%: T+; R45; R68; R28; R23;

R48/23/25; R34
>=10%Conc<25%: T+; R45; R68; R28;
Carc. Cat. 1; R45 R48/23/25; R34; R20
Muta. Cat. 3; R68 >=7%Conc<10%: T+; R45; R68; R28; R20;
T+; R28 R48/20/22; R36/38
T; R23-48/23/25 T+; N >=5%Conc<7%: T; R45; R68; R25; R20; Arsenic trioxide
Arsenic oxide (As2O3) [Arsenic trioxide; Diarsenic C; R34 R: 23-28-34-45-48/23/25-68- R48/20/22; R36/38 production (as As)
1327-53-3 trioxide] N; R50-53 50-53 >=3%Conc<5%: T; R45; R68; R25; R20; R48/2 N/Eu; A (d) - - - - 1 - -
R10
Xn; R20/21 Xn Conc>=25%: Xn; R20/21; R37/38 Xylene (o-, m-, p-
1330-20-7 Benzene, dimethyl- [Xylene] Xi; R37/38 R: 10-20/21-37/38 >=20%Conc<25%: Xi; R37/38 N/Eu; A isomers) 80 350 150 655 - - -
Disodium tetraborate, anhydrous [Boric acid, T Borates, tetra,
disodium salt](Note: see also CAS No. 12267-73-1 & R: 60-61 sodium salts
1330-43-4 13840-56-7) Repr. Cat. 2; R60-61 S: 53-45 Conc>=4.5%: T; R60; R61 Eu;A (anhydrous) - 1 - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Xn; R22 Xn >=10%Conc<20%: Xi; R41
1331-61-9 Benzenesulfonic acid, dodecyl-, ammonium salt Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
1332-40-7 Copper oxychloride Xn; R22 Xn ; R: 22 Conc>=25%:Xn; R22 V - - - - - - - -
Asphyxiant
F+; R12, (see Chapter
1333-74-0 Hydrogen F+; R12 S: (2) - 9 - 16 - 33 Eu Hydrogen - - - - - - 10)

O; R9 Conc>=25%: T+; R45; R60; R61; R26; R24/25;

Carc. Cat. 1; R45 R48/23; R35; R42/43
Repr. Cat. 2; R60-61 >=10%Conc<25%: T+; R45; R60; R61; R26;
T+; R26 R48/23; R35; R21/22; R42/43
T; R24/25-48/23 >=7%Conc<10%: T+; R45; R60; R61; R26;
C; R35 O; T+; C R34; R21/22; R48/20; R42/43
Chromium oxide (CrO3) [Chromium (VI) trioxide; R42/43 R: 9-45-60-61-24/25-26-35- >=5%Conc<7%: T; R45; R60; R61; R23; R34;
1333-82-0 Chromium oxide (CrO3) (Cr VI)] N; R50-53 42/43-48/23-50-53 R21/22; R48/20; R4 N/Eu - - - - - - - -
Conc>=10%: T; R25; R34
T; R25 T ; C ; R: 25 - 34 , >=1%Conc<10%: C; R22; R34
1333-83-1 Sodium bifluoride [Sodium hydrogen difluoride] C; R34 S: (1/2) - 22 - 26 - 37 - 45 >=0.1%Conc<1%: Xi; R36/38 Eu - - - - - - - -
1333-86-4 Carbon black A Carbon black - 3 - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Repr. Cat. 1; R61 Conc>=5%: T; R40; R61; R62; R68; R33
Repr. Cat. 3; R62 T >=1%Conc<5%: T; R40; R61; R68; R33
1335-25-7 Lead oxide R33 61-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
E; R2
T; R23/24/25 E; T; N Conc>=25%: T; R23/24/25, R33
R33 R: 2-23/24/25-33-50/53 >=3%Conc<25%: Xn; R20/21/22; R33
1335-31-5 Dimercury dicyanide oxide [Mercuric oxycyanide] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
Carc. Cat. 3; R40
Repr. Cat. 1; R61
Repr. Cat. 3; R62 T ; N ; R: 61 - 62 - 33 - 40 - Conc>=10%: T; R61; R62; R40; R48/22; R33
Xn; R48/22 48/22 - 50/53, >=5%Conc<10%: T; R61; R62; R40; R33
R33 S: 53 - 45 - 60 - 61; >=1%Conc<5%: T; R61; R40; R33
1335-32-6 Lead acetate [Lead acetate, basic] N; R50-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -

Page 123
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Carc. Cat. 3; R40 Conc>=25%: T; R40; R61; R62; R68; R20/22;

Muta. Cat. 3; R68 R48/22; R33
Repr. Cat. 1; R61 >=10%Conc<25%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R48/22; R33
Xn; R20/22-48/22 T; N >=5%Conc<10%: T; R40; R61; R62; R68; R33
Lead, bis(acetato-O)tetrahydroxytri- [Lead acetate; R33 R: 61-20/22-33-40-48/22-62- >=1%Conc<5%: T; R40; R61; R68; R33
1335-32-6 Lead acetate, basic] N; R50-53 68-50-53 >=0.5%Conc<1%: T; R61 N/Eu - - - - - - - -
Hexachloronaphth
1335-87-1 Hexachloronaphthalene A alene - 0.2 - - - Sk -
Tetrachloronaphth
1335-88-2 Tetrachloronaphthalene A alene - 2 - - - - -
C ; N ; R: 34 - 50,
S: (1/2) - - 26 - 36/37/39 -
Ammonia, aqueous solution [Ammonium hydroxide C; R34 45 - 61; Conc>=10%: C; R34
1336-21-6 (NH4OH)] N; R50 Note: B >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -

Xn; N
Polychlorobiphenyls [PCB; Polychlorinated R33 R: 33-50/53
1336-36-3 biphenyls] N; R50-53 S: (2-)35-60-61; Note: C Conc>=0.005%: Xn; R33 Eu - - - - - - - -
R10
Xn; R22 Xn ; N ; R: 10 - 22 - 50/53 ,
1338-02-9 Copper naphthenate [Naphthenic acids, copper salts] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Methyl ethyl 0.2 Peak 1.5 Peak
1338-23-4 Methyl ethyl ketone peroxide [2-Butanone, peroxide] A ketone peroxide limitation limitation - - - - -
Conc>=10%: T; R25; R34
Ammonium bifluoride [Ammonium hydrogen T; R25 T ; C ; R: 25 - 34 , >=1%Conc<10%: C; R34; R22
1341-49-7 difluoride] C; R34 S: (1/2) - 22 - 26 - 37 - 45 >=0.1%Conc<1%: Xi; R36/38 Eu - - - - - - - -
R31 Conc>=25%: T; R25; R34; R31
T; R25 T ; N ; R: 25 - 31 - 34 - 50, >=10%Conc<25%: C; R34; R22; R31
C; R34 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%; Xn; R22; R36/38; R31
1344-08-7 Sodium polysulphides N; R50 61 >=3%Conc <5%: Xn; R22; R31 Eu - - - - - - - -

Conc>=25%: T; R45; R61; R62; R68; R23;

Carc. Cat. 2; R45 R48/20; R43; R33
Muta. Cat. 3; R68 >=10%Conc<25%: T; R45; R61; R62; R68;
Repr. Cat. 1; R61 R20; R48/20; R43; R33
Repr. Cat. 3; R62 >=5%Conc<10%: T; R45; R61; R62; R68; R20;
T; R23 R43; R33
Xn; R48/20 >=3%Conc<5%: T; R45; R61; R68; R20; R43;
R33 T; N R33
R43 R: 45-61-23-33-43-48/20-62- >=1%Conc<3%: T; R45; R61; R68; R43; R33
1344-37-2 C.I. Pigment Yellow 34 [Lead sulfochromate yellow] N; R50-53 68-50-53 >=0 N/Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Lead oxide phosphonate (Pb3O2(HPO3)), Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
1344-40-7 hemihydrate R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
R31 Xi; N
Xi; R36/37/38 R: 31 - 36/37/38 - 50
1344-81-6 Calcium polysulphides N; R50 S: (2) - 28 - 61 Conc>=20%: Xi; R36/37/38; R31 Eu - - - - - - - -

Subtilisins
(Proteolytic
enzymes as 100% 0.00006
Subtilisins [(Proteolytic enzymes as 100% pure pure crystalline Peak
1395-21-7 crystalline enzyme )] A enzyme) - limitation - - - Sen -
Xn; R22 Xn ; N ; R: 22 - 50/53,
1420-06-0 Trifenmorph (ISO) [4-Tritylmorpholine] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Page 124
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: T+; R28; R61; R24
Repr. Cat. 2; R61 >=7%Conc<25%: T+; R28; R61; R21
T+; R28 T+ ; N ; R: 61 - 24 - 28 - 44 - >=3%Conc<7%: T; R61; R25; R21
T; R24 50/53, >=1%Conc<3%: T; R61; R25
R44 S: 53 - 45 - 60 - 61; >=0.5%Conc<1%: T; R61; R22
1420-07-1 Dinoterb (ISO) [2-tert-Butyl-4,6-dinitrophenol] N; R50-53 Note: E >=0.1%Conc<0.5%: Xn; R22 Eu - - - - - - - -
Xn; R22-48/20/22 Xn ; N ; R: 22 - 38 - Conc>=25%: Xn; R22; R48/20/22; R38
Xi; R38 48/20/22 - 51/53 >=20%Conc<25%: Xn; R48/20/22; R38
1435-48-9 1,3-Dichloro-4-fluorobenzene N; R51-53 S: (2)36/37 - 61 >=10%Conc<20%: Xn; R48/20/22 Eu - - - - - - - -
4,4'(4-(4-Methoxyphenyl)-1,3,5-triazin-2,4- R: 52/53
1440-00-2 diyl)bisbenzene-1,3-diol R52-53 S: 61 Eu - - - - - - - -

Xn; N Tin, organic

Tetracyclohexylstannane (Note: see also CAS No. Xn; R20/21/22 R: 20/21/22-50/53 compounds (as
1449-55-4 3091-32-5 and 7067-44-9) N; R50-53 S: (2-)26-28-60-61; Note: A Conc>=1%: Xn; R20/21/22 Eu; A Sn) - 0.1 - 0.2 - Sk -

Conc>=25%: T+; R45; R46; R26; R24/25; R34

>=10%Conc<25%: T+; R45; R46; R26; R34;
R21/22
>=7%Conc<10%: T+; R45; R46; R26; R21/22;
R36/38
Carc. Cat. 2; R45 >=5%Conc<7%: T; R45; R46; R23; R21/22;
Muta. Cat. 2; R46 T+ ; R: 45 - 46 - 24/25 - 26 - R36/38
T+; R26 34, >=3%Conc<5%: T; R45; R46; R23; R21/22
1,2,3,4-Diepoxybutane [Butadiene diepoxide; 2,2'- T; R24/25 S: 53 - 45; >=1%Conc<3%: T; R45; R46; R23
1464-53-5 Bioxirane] C; R34 Note: E >=0.1%Conc<1%: T; R45; R46; R20 Eu - - - - - - - -
Dimexano (ISO) [Bis(methoxythiocarbonyl) Xn; R22 Xn ; N ; R: 22 - 50/53,
1468-37-7 disulphide; Di(methoxythiocarbonyl) disulfide] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

m-Xylene-a,a'- 0.1 Peak

1477-55-0 m-Xylene a,a'-diamine A diamine - limitation - - - Sk -
Muta. Cat. 3; R68
Xn; R21/22
Xi; R38 Xn; N Conc>=25%: Xn; R68; R21/22; R38; R43
R43 R: 21/22-38-43-68-50/53 >=20%Conc<25%: Xn; R68; R38; R43
1484-13-5 9-Vinylcarbazole N; R50-53 S: (2-)22-23-36/37-60-61 >=1%Conc<20%: Xn; R68; R43 Eu - - - - - - - -
T+ ; R: 26/28 - 50/53, Conc>=7%: T+; R26/28
Carbofuran (ISO) [2,3-Dihydro-2,2- T+; R26/28 S: (1/2) - 36/37 - 45 - 60 - >=1%Conc<7%: T; R23/25
1563-66-2 dimethylbenzofuran-7-yl N-methylcarbamate] N; R50-53 61 >=0.1%Conc<1%: Xn; R20/22 Eu; A Carbofuran - 0.1 - - - - -
Decarbofuran [2,3-Dihydro-2-methylbenzofuran-7-yl T ; R: 23/24/25 , Conc>=25%: T; R23/24/25
1563-67-3 methylcarbamate] T; R23/24/25 S: (1/2) - 13 - 36/37 - 45 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
1-Ethoxypropan-2-ol [2PG1EE; 1-Ethoxy-2-
propanol; Propylene glycol monoethyl ether](Note: R10 R: 10-67
1569-02-4 see also CAS No. 54839-24-6) R67 S: (2-)24 Eu - - - - - - - -
Conc>=25%: T; R23-35
>=10%Conc<25%: C; R35; R20
T; R23 T; C; N >=5%Conc<10%: C; R34; R20
C; R35 R: 23-35-50 >=3%Conc<5%: Xn; R20; R36/37/38
1570-64-5 4-Chloro-o-cresol [4-Chloro-2-methyl phenol] N; R50 S: (1/2-)26-36/37/39-45-61 >=1%Conc<3%: Xi; R36/37/38 Eu - - - - - - - -
Xi ; R: 41 Conc>=10%: Xi; R41
1570-95-2 2-Phenyl-1,3-propanediol Xi; R41 S: (2)26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N
R: 50/53
1571-75-1 1,1-Bis(4-hydroxyphenyl)-1-phenylethane N; R50-53 S: 25-60-61 Eu - - - - - - - -

Trifluralin (ISO) (containing < 0.5 ppm NPDA)

[alpha,alpha,alpha-Trifluoro-2,6-dinitro-N,N-dipropyl-p-
toluidine (containing &lt; 0.5 ppm NPDA); 2,6-Dinitro-
N,N-dipropyl-4-trifluoromethylaniline (containing &lt; Carc. Cat. 3; R40 Xn; N
0.5 ppm NPDA); N,N-Dipropyl-2,6-dinitro-4- R43 R: 40-43-50/53
1582-09-8 trifluoromethylaniline (containing &lt; 0.5 ppm NPDA)] N; R50-53 S: (2-)36/37-46-60-61 Conc>=1%: Xn; R40; R43 Eu - - - - - - - -

Page 125
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
R10 Conc>=20%: T; R61; R41; R37/38
Repr. Cat. 2; R61 >=10%Conc<20%: T; R61; R41
Xi; R37/38 T ; R: 61 - 10 - 37/38 - 41, >=5%Conc<10%: T; R61; R36
1589-47-5 2-Methoxypropanol Xi; R41 S: 53 - 45 >=0.5%Conc<5%: T; R61 Eu - - - - - - - -

Dodemorph (ISO) [4-Cyclododecyl-2,6- Xi; R36/37/38 Xi ; N ; R: 36/37/38 - 51/53,

1593-77-7 dimethylmorpholine] N; R51-53 S: (2) - 26 - 61 Conc>=20%: Xi; R36/37/38 Eu - - - - - - - -
F; Xi
tert-Butyl methyl ether [MTBE; 2-Methoxy-2- F; R11 R: 11-38 Methyl-tert butyl
1634-04-4 methylpropane; Methyl-tert butyl ether] Xi; R38 S: (2-)9-16-24 Conc>=20%: Xi; R38 Eu; A ether 25 92 75 275 - - -
Xn; R48/22 Xn
2,7,11-Trimethyl-13-(2,6,6-trimethylcyclohex-1-en-1- R43 R: 43-48/22-52/53 Conc>=10%: Xn; R48/22; R43
1638-05-7 yl)tridecahexaen-2,4,6,8,10,12-al R 52-53 S: (2-)22-36/37-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
F; R11 F; Xn; N
Xn; R20/21/22 R: 11-20/21/22-37/38-43-
Xi; R37/38 51/53 Conc>=25%: Xn; R20/21/22; R37/38; R43
R43 S: (2-)16-25-37-61 >=20%Conc<25%: Xi; R37/38; R43
1663-39-4 tert-Butyl acrylate N; R51-53 Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
(4aR*,8aR*)-4a,5,9,10,11,12-Hexahydro-3-methoxy- Xn; R22 Xn
11-methyl-6H-benzofuro[3a,3,2-ef][2]benzazepin-6- Xi; R36 R: 22-36-52/53 Conc>=25%: Xn; R22; R36
1668-86-6 one R52-53 S: (2-)22-26-61 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
Repr. Cat. 3; R62
Xn; R22 Xn Conc>=25%: Xn; R62; R22; R43
R43 R: 22-43-62-52/53 >=5%Conc<25%: Xn; R62; R43
1671-49-4 4-Mesyl-2-nitrotoluene R52-53 S: (2-)22-36/37-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; R36/38 Xi ; R: 36/38 - 43 , Conc>=5%: Xi; R36/38; R43
1675-54-3 Bis[4-(2,3-epoxypropoxy)phenyl]propane R43 S: (2) - 28 - 37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi ; R: 36/38 - 43 ,
2,2''-(Ethylenedioxy)diethyl diacrylate [Triethylene Xi; R36/38 S: (2) - 26 - 28 ; Conc>=20%: Xi; R36/38; R43
1680-21-3 glycol diacrylate] R43 Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R63; R23/25; R21; R48/22;

R36
Repr. Cat. 3; R63 >=20%Conc<25%: Xn; R63; R20/22; R48/22;
T; R23/25 T; N R36
Xn; R21-48/22 R: 21-23/25-36-48/22-63- >=10%Conc<20%: Xn; R63; R20/22; R48/22
Ioxynil (ISO) and its salts [4-Hydroxy-3,5- Xi; R36 50/53 >=5%Conc<10%: Xn; R63; R20/22
1689-83-4 diiodobenzonitrile] N; R50-53 S: (1/2-)36/37-45-60-61-63 >=3%Conc<5%: Xn; R20/22 Eu - - - - - - - -
Conc>=25%: T+; R63; R26; R25; R43
Repr. Cat. 3; R63 >=7%Conc<25%: T+; R63; R26; R22; R43
T+; R26 T+; N >=5%Conc<7%: T; R63; R23; R22; R43
T; R25 R: 25-26-43-63-50/53 >=3%Conc<5%: T; R23; R22; R43
Bromoxynil (ISO) and its salts [3,5-Dibromo-4- R43 S: (1/2-)27/28-36/37-45-63- >=1%Conc<3%: T; R23; R43
1689-84-5 hydroxybenzonitrile; Bromoxynil phenol] N; R50-53 60-61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
Repr. Cat. 3; R63
T; R23 Conc>=25%: T; R63; R23; R22; R43
Xn; R22 T; N >=5%Conc<25%: Xn; R63; R20; R43
Bromoxynil octanoate (ISO) [2,6-Dibromo-4- R43 R: 22-23-43-63-50/53 >=3%Conc<5%: Xn; R20; R43
1689-99-2 cyanophenyl octanoate] N; R50-53 S: (1/2-)36/37-45-63-60-61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -

Benzyl violet 4B [alpha-[4-(4-Dimethylamino-alpha-{4-

[ethyl(3-
sodiosulphonatobenzyl)amino]phenyl}benzylidene)cy
clohexa-2,5-dienylidene(ethyl)ammonio]toluene-3- Xn ; R: 40 ,
1694-09-3 sulphonate] Carc. Cat. 3; R40 S: (2) - 36/37 Conc>=1%: Xn; R40 Eu - - - - - - - -
cis-1,2,3,6-Tetrahydro-4-methylphthalic
anhydride(Note: see also CAS No 3425-89-6; 5333- Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41
84-6; 11070-44-3; 26590-20-5; 34090-76-1 & 42498- Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
1694-82-2 58-80) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
5-Amino-4-chloro-2-phenylpyridazine-3(2H)-one Xi; R43 Xi ; N ; R: 43 - 50/53,
1698-60-8 [Pyrazon; Chloridazon] N; R50-53 S: (2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
Clopyralid (ISO) [3,6-Dichloropyridine-2-carboxylic R: 41 Conc>=10%: Xi; R41
1702-17-6 acid] Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
N
R52-53 R: 52/53 - 59
1717-00-6 1,1-Dichloro-1-fluoroethane N; R59 S: 59 - 61 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Xn; R22 Xn ; R: 22 - 38 - 41 , >=10%Conc<20%: Xi; R41
1739-84-0 1,2-Dimethylimidazole Xi; R38-41 S: (2) - 24 - 26 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
C Conc>=10%: C; R34
1745-89-7 Phenol, 4,4'-(1-methylethylidene)bis[2-(2-propen-1-yl)- C; R34 R: 34 >=5%Conc<10%: Xi; R36/38 N - - - - - - - -
Xn; N
Monolinuron (ISO) [3-(4-Chlorophenyl)-1-methoxy-1- Xn; R22-48/22 R: 22 - 48/22 - 50/53 Conc>=25%: Xn; R22; R48/22
1746-81-2 methylurea] N; R50-53 S: (2) - 22 - 60 - 61 >=10%Conc<25%: Xn; R48/22 Eu - - - - - - - -

Conc>=10%: T+; R40; R61; R62; R26/27/28;

R48/23/25
>=7%Conc<10%: T+; R40; R61; R62;
R26/27/28; R48/20/22
>=5%Conc<7%: T; R40; R61; R62; R23/24/25;
Carc. Cat. 3; R40 R48/20/22
Repr. Cat. 1; R61 >=1%Conc<5%: T; R40; R61; R23/24/25;
Repr. Cat. 3; R62 T+ R48/20/22
T+; R26/27/28 R: 61-26/27/28-40-48/23/25- >=0.5%Conc<1%: T; R61; R20/21/22
1762-26-1 Plumbane, ethyltrimethyl- T; R48/23/25 62 >=0.1%Conc<0.5%: X N - - - - - - - -

Conc>=10%: T+; R40; R61; R62; R26/27/28;

R48/23/25
>=7%Conc<10%: T+; R40; R61; R62;
R26/27/28; R48/20/22
>=5%Conc<7%: T; R40; R61; R62; R23/24/25;
Carc. Cat. 3; R40 R48/20/22
Repr. Cat. 1; R61 >=1%Conc<5%: T; R40; R61; R23/24/25;
Repr. Cat. 3; R62 T+ R48/20/22
T+; R26/27/28 R: 61-26/27/28-40-48/23/25- >=0.5%Conc<1%: T; R61; R20/21/22
1762-27-2 Plumbane, diethyldimethyl- T; R48/23/25 62 >=0.1%Conc<0.5%: X N - - - - - - - -

Conc>=10%: T+; R40; R61; R62; R26/27/28;

R48/23/25
>=7%Conc<10%: T+; R40; R61; R62;
R26/27/28; R48/20/22
>=5%Conc<7%: T; R40; R61; R62; R23/24/25;
Carc. Cat. 3; R40 R48/20/22
Repr. Cat. 1; R61 >=1%Conc<5%: T; R40; R61; R23/24/25;
Repr. Cat. 3; R62 T+ R48/20/22
T+; R26/27/28 R: 61-26/27/28-40-48/23/25- >=0.5%Conc<1%: T; R61; R20/21/22
1762-28-3 Plumbane, triethylmethyl- T; R48/23/25 62 >=0.1%Conc<0.5%: X N - - - - - - - -

Carc. Cat. 3; R40

Repr. Cat. 2; R61 T; N Conc>=25%: T; R40; R61; R64; R20/22;
T; R48/25 R: 61-20/22-40-48/25-64- R48/25
Perfluorooctane sulfonic acid [Heptadecafluorooctane- Xn; R20/22 51/53 >=10%Conc<25%: T; R40; R61; R64; R48/25
1-sulfonic acid](Note: see also CAS No. 2795-39-3, R64 S: 53-45-61 >=1%Conc<10%: T; R40; R61; R64; R48/22
1763-23-1 70225-14-8, 29081-56-9, 29457-72-5) N; R51-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
T ; R: 25 , Conc>=25%: T; R25
1786-03-4 Naphthylindandione [2-(1-Naphthyl)indan-1,3-dione] T; R25 S: (1/2) - 13 - 45 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
R: 52/53
1823-59-2 4,4'-Oxydiphthalic anhydride R52-53 S: 61 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 61 - 22 -
Repr. Cat. 2; R61 50/53, Conc>=25%: T; R45; R61; R22
Nitrofen (ISO) [2,4-Dichlorophenyl 4-nitrophenyl Xn; R22 S: 53 - 45 - 60 - 61; >=0.5%Conc<25%: T; R45; R61
1836-75-5 ether] N; R50-53 Note: E >=0.1%Conc<0.5%: T; R45 Eu - - - - - - - -
R: 53
1854-15-5 N-Dodecyl-4-methoxybenzamide R53 S: 61 Eu - - - - - - - -
Xn; R22 C ; R: 22 - 34 - 52/53, Conc>=25%: C; R34; R22
C; R34 S: (1/2) - 26 - 36/37/39 - 45 - >=10%Conc<25%: C; R34
1862-07-3 6-Dimethylaminohexan-1-ol R52-53 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn
Xn; R20 R: 20-53
1873-90-1 3-Hexylheptamethyltrisiloxane R53 S: (2-)61 Conc>=25%: Xn; R20 Eu - - - - - - - -
Tetrachloroterephthalonitrile [1,4-Dicyano-2,3,5,6- Xi; R43 Xi ; R: 43 - 50/53 ,
1897-41-2 tetra-cloro-benzene] R50-53 S: (2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Conc>=20%: T+; R40; R26; R37; R41; R43

Carc. Cat. 3; R40 >=10%Conc<20%: T+; R40; R26; R41; R43
T+; R26 T+; N >=7%Conc<10%: T+; R40; R26; R36; R43
Xi; R37-41 R: 26-37-40-41-43-50/53 >=5%Conc<7%: T; R40; R23; R36; R43
R43 S: (1/2-)28-36/37/39-45-60- >=1%Conc<5%: T; R40; R23; R43
1897-45-6 Chlorothalonil (ISO) [Tetrachloroisophthalonitrile] N; R50-53 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -

Conc>=25%: T+; R26; R24/25; R48/25;

R36/37/38
>=20%Conc<25%: T+; R26; R21/22; R48/25;
R36/37/38
T+; N >=10%Conc<20%: T+; R26; R21/22; R48/25
T+; R26 R: 24/25 - 26 - 36/37/38 - >=7%Conc<10%: T+; R26; R21/22; R48/22
Paraquat dichloride [1,1-Dimethyl-4,4’-bipyridinium T; R24/25-48/25 48/25 - 50/53 >=3%Conc<7%: T; R23; R21/22; R48/22
dichloride](Note: see also CAS No 2074-50-2 Xi; R36/37/38 S: (1/2) - 22 - 28 - 36/37/39 - >=1%Conc<3%: T; R23; R48/22 Paraquat
1910-42-5 ) N; R50-53 45 - 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu (respirable sizes) - 0.1 - - - - -
Xn; R48/22 Xn; N
Atrazine (ISO) [2-Chloro-4-ethylamine-6- R43 R: 43 - 48/22 - 50/53 Conc>=10%: Xn; R48/22; R43
1912-24-9 isopropylamine-1,3,5-triazine] N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<10%: Xi; R43 Eu; A Atrazine - 5 - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R;41
Dicamba (ISO) [2,5-Dichloro-6-methoxybenzoic acid; Xi; R41 R: 22 - 41 - 52/53 >=10%Conc<25%: Xi; R41
1918-00-9 3,6-Dichloro-2-methoxybenzoic acid] R52-53 S: (2) - 26 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
1918-02-1 Picloram A Picloram - 10 - - - - -
Xn ; R: 22 ,
1918-13-4 Chlorthiamid (ISO) [2,6-Dichloro (thiobenzamide)] Xn; R22 S: (2) - 36 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22
Xi; R36 Xn; N Conc>=25%: Xn; R22; R36; R43
Propachlor (ISO) [2-Chloro-N-isopropylacetanilide; R43 R: 22 - 36 - 43 - 50/53 >=20%Conc<25%: Xi; R36; R43
1918-16-7 alpha-Chloro-N-isopropylacetanilide] N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn ; R: 22 ,
1918-18-9 Methyl 3,4-dichlorophenylcarbanilate [SWEP] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53,
1929-77-7 S-Propyl dipropylthiocarbamate [Vernolate] N; R51-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Carc. Cat. 3; R40
Xn; R22
Xi; R36 Xn; N Conc>=25%: Xn; R22; R36; R40; R43
Nitrapyrin (ISO) [Pyridine, 2-chloro-6-(trichloromethyl)- R43 R: 22-36-40-43-51/53 >=20%Conc<25%: Xn; R36; R40; R43
1929-82-4 ; 2-Chloro-6-trichloromethylpyridine] N; R51-53 S: (2)-36/37-61 >=1%Conc<20%: Xn; R40; R43 N/Eu; A Nitrapyrin - 10 - 20 - - -
Benzthiazuron (ISO) [1-Benzothiazol-2-yl-3- Xn ; R: 22 ,
1929-88-0 methylurea] Xn; R22 S: (2) - 24/25 Conc>=25%: Xn; R22 Eu - - - - - - - -

2,7-Naphthalenedisulfonic acid, 4-amino-3-[[4'-[(2,4-

diaminophenyl)azo][1,1'-biphenyl]-4-yl]azo]-5-hydroxy- Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
1937-37-7 6-(phenylazo)-, disodium salt [C.I. Direct Black 38] Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Xn; N
Xn; R48/22 R: 48/22 - 51/53
1939-27-1 3'-Trifluoromethylisobutyranilide N; R51-53 S: (2)22 - 36 - 61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Xn Conc>=25%: Xn; R22; R41
Xn; R22 R: 22-41 >=10%Conc<25%: Xi; R41
1939-36-2 Trimethylenediaminetetraacetic acid Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T; R23 Conc>=25%: T; R23; R35; R22; R42/43
Xn; R22 T ; C ; N ; R: 22 - 23 - 35 - >=10%Conc<25%: C; R35; R20; R42/43
C; R35 42/43 - 51/53 >=5%Conc<10%: C; R34; R20; R42/43
R42/43 S: (1/2) - 23 - 26 - 36/37/39 - >=3%Conc<5%: Xn; R20; R36/38; R42/43 Isocyanates, all
1943-82-4 2-Phenylethylisocyanate N; R51-53 43 - 45 - 61 >=1%Conc<3%: Xn; R36/38; R42/43 Eu; A (as-NCO) - 0.02 - 0.07 - Sen -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Repr. Cat. 3; R62-63

Xi; R36/38 Xn Conc>=20%: Xn; R62; R63; R36/38; R42/43
Piperazine phosphate(Note: see also CAS No. 6094- R42/43 R: 36/38-42/43-62-63-52/53 >=5%Conc<20%: Xn; R62; R63; R42/43
1951-97-9 40-2, 142-64-3) R52-53 S: (1/2-)22-36/37-45-63-61 >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Sodium 3,6-dichloro-o-anisate(Note: see also CAS R: 52/53,
1982-69-0 No 25059-78-3 & 53404-28-7) R52-53 S: 61 Eu - - - - - - - -
T ; N ; R: 24/25 - 50/53,
Aminocarb (ISO) [4-Dimethylamino-3-tolyl T; R24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R24/25
2032-59-9 methylcarbamate] N; R50-53 60 - 61 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
T ; N ; R: 25 - 50/53,
Mercaptodimethur (ISO) [Methiocarb; 3,5-Dimethyl-4- T; R25 S: (1/2) - 22 - 37 - 45 - 60 - Conc>=25%: T; R25
2032-65-7 methytthiophenyl N-methylcarbamate] N; R50-53 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
R10 R14 C Conc>=25%: C; R35; R22; R43
C; R35 R: 10-14-22-35-43 >=10%Conc<25%: C; R35; R43
Xn; R22 S: (1/2-)7/8-23-26-36/37/39- >=5%Conc<10%: C; R34; R43
2032-75-9 2,2-Dichloro-1,3-benzodioxol R43 45 >=1%Conc<5%: Xi; R36/38; R43 Eu - - - - - - - -
2039-87-4 o-Chlorostyrene A o-Chlorostyrene 50 283 75 425 - - -
Muta.Cat.2; R46
Repr.Cat.3; R62 Conc>=25%: T; R46; R62; R34; R22; R43
Xn; R22 T; N >=10%Conc<25%: T; R46; R62; R34; R43
C; R34 R: 46-22-34-43-62-51/53 >=5%Conc<10%: T; R46; R62; R36/38; R43
R43 S: 53-45-61 >=1%Conc<5%: T; R46; R43
2040-90-6 2-Chloro-6-fluoro-phenol N; R51-53 Note: E >=0.1%Conc<1%: T; R46 Eu - - - - - - - -
T; R25 T ; N ; R: 25 - 36 - 43 - Conc>=25%: T; R25; R36; R43
N5,N5-Diethyltoluene-2,5-diamine Xi; R36 50/53, >=20%Conc<25%: Xn; R22; R36; R43
monohydrochloride [4-Diethylamino-2-methylaniline R43 S: (1/2) - 24 - 26 - 37 - 45 - >=3%Conc<20%: Xn; R22; R43
2051-79-8 monohydrochloride] N; R50-53 60 - 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Xn Conc>=25%: Xn; R22; R41
Xn; R22 R: 22-41 >=10%Conc<25%: Xi; R41
2065-75-0 2-Bromomalonaldehyde Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Conc>=25%: T+; R26; R24/25; R48/25;

R36/37/38
>=20%Conc<25%: T+; R26; R21/22; R48/25;
R36/37/38
T+; N >=10%Conc<20%: T+; R26; R21/22; R48/25
T+; R26 R: 24/25 - 26 - 36/37/38 - >=7%Conc<10%: T+; R26; R21/22; R48/22
Paraquat dimethylsulfate [1,1-Dimethyl-4,4’- T; R24/25-48/25 48/25 - 50/53 >=3%Conc<7%: T; R23; R21/22; R48/22
bipyridinium dimethyl sulphate](Note: see also CAS Xi; R36/37/38 S: (1/2) - 22 - 28 - 36/37/39 - >=1%Conc<3%: T; R23; R48/22 Paraquat
2074-50-2 No 1910-42-5) N; R50-53 45 - 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu (respirable sizes) - 0.1 - - - - -

3-(3-Amino-5-(1-methylguanidino)-1-oxopentylamino- Conc>=7%: T+; R28

6-(4-amino-2-oxo-2,3-dihydro-pyrimidin-1-yl)-2,3- T+ ; R: 28 , >=1%Conc<7%: T; R25
2079-00-7 dihydro-(6H)-pyran-2-carboxylic acid [Blasticidin-S] T+; R28 S: (1/2) - 24/25 - 36/37 - 45 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

T+; R26 Conc>=10%: T+; R26, R34, R42/43, R48/20

C; R34 T+ ; N ; R: 26 - 34 - 42/43 - >=7%Conc<10%: T+; R26, R42/43, R36/38
Xn; R48/20 48/20 - 50/53 , >=5%Conc<7%: T; R23, R42/43, R36/38
R42/43 S: (1/2) - 7 - 15 - 28 - >=1%Conc<5%: T; R23, R42/43 Isocyanates, all
2094-99-7 2-(3-(Prop-1-en-2-yl)phenyl)prop-2-yl isocyanate N; R50/53. 36/37/39 - 38 - 45 - 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu; A (as-NCO) - 0.02 - 0.07 - Sen -
Xn ; N ; R: 21/22 - 36 -
Xn; R21/22 48/22 - 50/53,
2,6-Diamino-3,5-diethyltoluene [4,6-Diethyl-2-methyl- Xn; R48/22 S: (2) - 26 - 28 - 36/37/39 - Conc>=25%: Xn; R21/22; R48/22; R36
1,3-benzenediamine](Note: see also CAS No 2095- Xi; R36 60 - 61; >=20%Conc<25%: Xn; R48/22; R36
2095-01-4 02-5 & 68479-98-1) N; R50-53 Note: C >=10%Conc<20%: Xn; R48/22 Eu - - - - - - - -
Xn ; N ; R: 21/22 - 36 -
Xn; R21/22 48/22 - 50/53,
2,4-Diamino-3,5-diethyltoluene [2,4-Diethyl-6-methyl- Xn; R48/22 S: (2) - 26 - 28 - 36/37/39 - Conc>=25%: Xn; R21/22; R48/22; R36
1,3-benzenediamine](Note: see also CAS No 2095- Xi; R36 60 - 61; >=20%Conc<25%: Xn; R48/22; R36
2095-02-5 01-4 & 68479-98-1) N; R50-53 Note: C >=10%Conc<20%: Xn; R48/22 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T+ ; N ; R: 27/28 - 50/53, Conc>=7%: T+; R27/28
O-Ethyl O-4-nitrophenyl phenylphosphonothioate T+; R27/28 S: (1/2) - 22 - 36/37 - 45 - >=1%Conc<7%: T; R24/25
2104-64-5 [EPN] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R21/22 Eu; A EPN (h) - 0.5 - - - Sk -
Xn; N
Bromophos (ISO) [O-4-Bromo-2,5-dichlorophenyl Xn; R22 R: 22-50/53
2104-96-3 O,O-dimethyl phosphorothioate] N; R50-53 S: (2-)36-60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
R43 Xi ; N ; R: 43 - 51/53
2109-22-0 2-Cyclohexylpropanal N; R51-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Repr. Cat. 3; R63 Xn
Xn; R22 R: 22 - 52/53 - 63 Conc>=25%: Xn; R63; R22
2122-19-2 Propylenethiourea R52-53 S: (2) - 36/37 - 46 - 61 >=5%Conc<25%: Xn; R63 Eu - - - - - - - -
Xi ; R: 10 - 36/37
Methyl (+/-)-lactate(Note: see also CAS No 547-64-8 R10 S: (2) - 24;
2155-30-8 ; 17392-83-5 & 27871-49-4) Xi; R36/37 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
Noruron (ISO) [1,1-Dimethyl-3-(perhydro-4,7- Xn ; R: 22 ,
2163-79-3 methanoinden-5-yl)urea] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
Allyl propyl
2179-59-1 Allyl propyl disulfide A disulfide 2 12 3 18 - - -
Muta. Cat. 3; R68 Xn ; N ; R: 38 - 43 - 51/53 -
Xi; R38 68,
[(p-Tolyloxy)methyl]oxirane(Note: see also CAS No R43 S: (2) - 36/37 - 61; Conc>=20%:Xn; R68; R38; R43
2186-24-5 2186-25-6; 2210-79-9 & 26447-14-3) N; R51-53 Note: C >=1%Conc<20%: Xn; R68; R43 Eu - - - - - - - -
Muta. Cat. 3; R68 Xn ; N ; R: 38 - 43 - 51/53 -
Xi; R38 68,
[(m-Tolyloxy)methyl]oxirane(Note: see also CAS No R43 S: (2) - 36/37 - 61; Conc>=20%:Xn; R68; R38; R43
2186-25-6 2186-24-5; 2210-79-9 & 26447-14-3) N; R51-53 Note: C >=1%Conc<20%: Xn; R68; R43 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
2191-10-8 Octanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R43
2198-59-6 1,4-Benzenediamine, N-phenyl-, monohydrochloride R43 R: 22-43 >=1%Conc<25%: Xi; R43 N - - - - - - - -
Muta. Cat. 3; R68 Xn ; N ; R: 38 - 43 - 51/53 -
Xi; R38 68,
2,3-Epoxypropyl o-tolyl ether(Note: see also CAS No R43 S: (2) - 36/37 - 61; Conc>=20%:Xn; R68; R38; R43
2210-79-9 2186-24-5; 2186-25-6 & 26447-14-3) N; R51-53 Note: C >=1%Conc<20%: Xn; R68; R43 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Xn; R22 Xn >=10%Conc<20%: Xi; R41
2211-98-5 Benzenesulfonic acid, 4-dodecyl-, sodium salt Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Carc.Cat3; R40
Repr.Cat3; R62 Conc>=25 %: Xn; R40; R62; R20/22; R48/22;
Xn; R20/22 T; N R43
Molinate (ISO) [S-Ethyl 1- Xn; R48/22 R: 20/22-40-43-48/22-63- >=10%Conc<25%: Xn; R40; R62; R48/22; R43
perhydroazepinecarbothioate; S-Ethyl R43 50/53 >=5%Conc<10%: Xn; R40; R62; R43
2212-67-1 perhydroazepine-1-carbothioate] N; R50-53 S: (2-)36/37-46-60-61 >=1%Conc<5%: Xn; R40; R43 Eu - - - - - - - -
Conc>=20%: T; R24; R36/38; R43
T; R24 T ; R: 24 - 36/38 - 43 , >=5%Conc<20%: T; R24; R43
2,2-Dimethyltrimethylene diacrylate [Neopentyl glycol Xi; R36/38 S: (1/2) - 28 - 39 - 45; >=1%Conc<5%: Xn; R21; R43
2223-82-7 diacrylate] R43 Note: D >=0.2%Conc<1%: Xn; R21 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
2223-93-0 Octadecanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
2223-95-2 Octadecanoic acid, nickel(2+) salt R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
Octachloronaphtha
2234-13-1 Octachloronaphthalene A lene - 0.1 - 0.3 - Sk -
Conc>=25%: Xn; R21/22; R37/38; R41
>=20%Conc<25%: Xi; R37/38; R41
Xn; R21/22 Xn >=10%Conc<20%: Xi; R41
2235-54-3 Sulfuric acid, monododecyl ester, ammonium salt Xi; R37/38-41 R: 21/22-37/38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Diglycidyl ether
2238-07-5 Diglycidyl ether (DGE) [Bis(2,3-epoxypropyl) ether] A (DGE) 0.1 0.53 - - - - -
Carc. Cat. 3; R40 Xn ; N ; R: 40 - 50/53 ,
2243-62-1 1,5-Naphthylenediamine [1,5-Naphthalenediamine] N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=1%: Xn; R40 Eu - - - - - - - -
E; R2
O; R8
Xn; R22
Troclosene potassium [Dichloroisocyanuric acid, Xi; R36/37 E; Xn; N
potassium salt of; Dichloro-1,3,5-triazinetrione, R31 R: 2-8-22-31-36/37-50/53
2244-21-5 potassium salt](Note: see also CAS No. 2893-78-9) N; R50-53 S: (2-)8-26-41-45-60-61 Conc>=10%: Xn; R22; R31; R36/37 Eu - - - - - - - -

Phenkapton [S-(2,5-Dichlorophenylthiomethyl) OO- T; R23/24/25 T ; N ; R: 23/24/25 - 50/53 , Conc>=25%: T; R23/24/25

2275-14-1 diethyl phosphorodithioate] N; R50-53 S: (1/2) - 13 - 45 - 61 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
Prothoate (ISO)
T+ Conc>=7%: T+; R27/28
[O,O-Diethyl isopropylcarbamoylmethyl T+; R27/28 R: 27/28-52/53 >=1%Conc<7%: T; R24/25
2275-18-5 phosphorodithioate] R52-53 S: (1/2-)28-36/37-45-61 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
T; R25
Vamidothion (ISO) [O,O-Dimethyl S-2-(1- Xn; R21 T ; N ; R: 21 - 25 - 50, Conc>=25%: T; R25; R21
2275-23-2 methylcarbamoylethylthio) ethyl phosphorothioate] N; R50 S: (1/2) - 36/37 - 45 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
3,6-Dichloro-o-anisic acid, compound with
dimethylamine (1:1)(Note: see also CAS No 10007- Xi; R36 Xi ; R36 - 52/53,
2300-66-5 85-9) R52-53 S: (2) - 26 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -

Xn; R22
Di-allate (ISO) [S-2,3-Dichloroallyl Carc. Cat. 3; R40 Xn ; N ; R: 22 - 40 - 50/53 , Conc>=25%: Xn; R40, R22
2303-16-4 diisopropylthiocarbamate] N; R50-53 S: (2) - 25 - 36/37 - 60 - 61 >=1%Conc<25%: Xn; R40 Eu - - - - - - - -
Xn; R22-48/22 Xn ; N ; R: 22 - 43 - 48/22 - Conc>=25%: Xn; R22; R48/22; R43
Triallate (ISO) [S-2,3,3-Trichloroallyl R43 50/53, >=10%Conc<25%: Xn; R48/22; R43
2303-17-5 diisopropylthiocarbamate] N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
T; R25
Xn; R20/21 T; N Conc>=25%: T; R25; R20/21; R43
Phosalone (ISO) [S-(6-Chloro-2-oxobenzoxazolin-3- R43 R: 20/21-25-43-50/53 >=3%Conc<25%: Xn; R22; R43
2310-17-0 ylmethyl) O,O-diethyl phosphorodithioate] N; R50-53 S: (1/2-)36/37-45-60-61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R40; R23; R38; R41

>=20%Conc<25%: Xn; R40; R20; R38; R41
Carc.Cat.3; R40 T; N >=10%Conc<20%: Xn; R40; R20; R41
T; R23 R: 23-38-40-41-50/53 >=5%Conc<10%: Xn; R40; R20; R36
Propargite (ISO) [2-(4-tert-Butylphenoxy) cyclohexyl Xi; R38-41 S: (1/2-)26-36/37/39-45-60- >=3%Conc<5%: Xn; R40; R20
2312-35-8 prop-2-ynyl sulphite] N; R50-53 61 >=1%Conc<3%: Xn; R40 Eu - - - - - - - -

T; R23/24/25 T; N Conc>=25%: T; R23/24/25; R33

DNOC, sodium salt of [Sodium 4,6-dinitro-o- R33 R: 23/24/25 - 33 - 50/53 >=3%Conc<25%: Xn; R20/21/22; R33
2312-76-7 cresolate](Note: see also CAS No 5787-96-2) N; R50-53 S: (1/2) - 13 - 45 - 60 - 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
Xn ; R: 68
2314-97-8 Trifluoroiodomethane [Trifluoromethyl iodide] Muta. Cat. 3; R68 S: (2)36/37 Conc>=1%: Xn; R68 Eu - - - - - - - -

Page 131
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: C; R35; R22
>=10%Conc<25%: C; R35
Xn; R22 >=5%Conc<10%: C; R34
2372-82-9 N-Bis(3 aminopropyl) dodecylamine C; R35 C ; R: 22 - 35 >=1%Conc<5%: Xi; R36/38 V - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
Xi; R41 Xn; N >=10%Conc<25%: Xi; R41; R43
R43 R: 22-41-43-51/53 >=5%Conc<10%: Xi; R36; R43
2380-86-1 6-Hydroxyindole N; R51-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 3; R40
Repr. Cat. 3; R62
Repr. Cat. 3; R63 Xn ; N ; R: 21/22 - 40 - 62 -
Mirex R64 63 - 64 - 50/53 , Conc>=25%: Xn; R40; R62; R63; R21/22; R64
[Dodecachloropentacyclo[5.2.1.0(2,6).0(3,9).0(5,8)]de Xn; R21/22 S: (2) - 13 - 36/37 - 46 - 60 - >=5%Conc<25%: Xn; R40; R62; R63; R64
2385-85-5 cane] N; R50-53 61 >=1%Conc<5%: Xn; R40; R64 Eu - - - - - - - -

E; R3 E; C
O; R7 R: 3-7-22-34 Conc>=25%: C; R34; R22;
1,1'-Dioxybiscyclohexan-1-ol(Note: see also CAS No. C; R34 S: (1/2-)3/7-14-36/37/39-45 >=10%Conc<25%: C; R34
2407-94-5 78-18-2, 2699-11-8 & 12262-58-7) Xn; R22 Note: C >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
2420-98-6 Hexanoic acid, 2-ethyl-, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

Benzophenone-3,3',4,4'-tetracarboxylic dianhydride Xi ; R: 36/37 ,

2421-28-5 [4,4'-Carbonyldi(phthalic anhydride)] Xi; R36/37 S: (2) - 25 Conc>=1%: Xi; R36/37 Eu - - - - - - - -
Carc. Cat. 2; R45
Captafol (ISO) [1,2,3,6-Tetrahydro-N-(1,1,2,2- Xi; R43 T ; N ; R: 45 - 43 - 50/53, Conc>=1%: T; R45; R43
2425-06-1 tetrachloroethylthio)phthalimide] N; R50-53 S: 53 - 45 - 60 - 61 >=0.1%Conc<1%: T; R45 Eu; A Captafol - 0.1 - - - Sk -
Xylylcarb (ISO) [3,4-Xylyl methylcarbamate; 3,4- Xn; R22 Xn ; N ; R: 22 - 50/53,
2425-10-7 Dimethylphenyl N-methylcarbamate; MPMC] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R20/21 Conc>=25%: Xn; R20/21; R36/38; R43
1,4-Bis(2,3-epoxypropoxy)butane Xi; R36/38 Xn ; R: 20/21 - 36/38 - 43 , >=20%Conc<25%: Xi; R36/38; R43
2425-79-8 [Butanedioldiglycidyl ether] R43 S: (2) - 26 - 28 - 37/39 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Xn ; R: 41 - 42/43 - 51/53 ,
Xi; R41 S: (2) - 22 - 24 - 26 - 37/39 - Conc>=10%: Xn; R42/43; R41
3,4,5,6-Tetrahydrophthalic anhydride(Note: see also Xn; R42/43 61; >=5%Conc<10%: Xn; R42/43; R36
2426-02-0 CAS No 85-43-8, 935-79-5 & 26266-63-7) R51-53 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
R10
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Xn; R20/22 Xn
Xi; R37 R: 10 - 20/22 - 37 - 40 - 43 - Conc>=25%: Xn; R40; R68; R20/22; R37; R43
Butyl 2,3-epoxypropyl ether [n-Butyl glycidyl ether R43 52/53 - 68 >=20%Conc<25%: Xn; R40; R68; R37; R43 n-Butyl glycidyl
2426-08-6 (BGE)] R52-53 S: (2) - 24/25 - 36/37 - 61 >=1%Conc<20%: Xn; R40; R68; R43 Eu; A ether (BGE) 25 133 - - - Sen -

2,7-Naphthalenedisulfonic acid, 5-amino-3-[[4'-[(7-

amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo][1,1'- Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
2429-73-4 biphenyl]-4-yl]azo]-4-hydroxy-, trisodium salt Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Benzoic acid, 5-[[4'-[(7-amino-1-hydroxy-3-sulfo-2-
naphthalenyl)azo][1,1'-biphenyl]-4-yl]azo]-2-hydroxy-, Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
2429-82-5 disodium salt Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Carc. Cat. 3; R40
T; R23 Conc>=25%: T; R40; R23; R22; R36/37/38
Xn; R22 T; N >=20%Conc<25%: Xn; R40; R20; R36/37/38
Xi; R36/37/38 R: 22-23-36/37/38-40-50/53 >=3%Conc<20%: Xn; R40; R20
2431-50-7 2,3,4-Trichlorobut-1-ene [1-Butene, 2,3,4-trichloro] N; R50-53 S: (1/2-)36/37-45-60-61 >=0.1%Conc<3%: Xn; R40 Eu - - - - - - - -

Page 132
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: Xn; R62; R20/21/22; R48/22;

Repr. Cat. 3; R62 R36; R43
Xn; R20/21/22-48/22 >=20%Conc<25%: Xn; R62; R48/22; R36; R43
Xi; R36 Xn ; N ; R: 20/21/22 - 36 - >=10%Conc<20%: Xn; R62; R48/22; R43
6-Methyl-1,3-dithiolo(4,5-b)quinoxalin-2-one Xi; R43 43 - 48/22 - 50/53 - 62, >=5%Conc<10%: Xn; R62; R43
2439-01-2 [Quinomethionate; Chinomethionat (ISO)] N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 36/38 -
Xi; R36/38 50/53, Conc>=25%: Xn; R22; R36/38
2439-10-3 Dodine (ISO) [Dodecylguanidinium acetate] N; R50-53 S: (2) - 26 - 60 - 61 >=20%Conc<25%: Xi; R36/38 Eu - - - - - - - -
Xi ; R: 41 , Conc>=10%: Xi; R41
2439-99-8 Glyphosine (ISO) [N,N-Bis(phosphonomethyl)glycine] Xi; R41 S: (2) - 26 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Conc>=25%: T; R46; R23/25; R48/22; R41;

R42/R43;
Muta. Cat. 2; R46 >=10%Conc<25%: T; R46; R20/22; R48/22;
T; R23/25 T ; R: 46 - 23/25 - 41 - 42/43 R41; R42/R43
Triglycidylisocyanurate (TGIC) [1,3,5-Triazine- Xn; R48/22 - 48/22 - 52/53, >=5%Conc<10%; T; R46; R20/22; R36; R42/43
2,4,6(1H,3H,5H)-trione, 1,3,5-tris(oxiranylmethyl); Xi; R41 S: 22 - 24/25 - 26 - 28 - >=3%Conc<5%: T; R46; R20/22; R42/43;
1,3,5-Tris(oxiranylmethyl)-1,3,5-triazine- R42/43 36/37/39 - 38 - 45 - 53 - 61; >=1%Conc<3%: T; R46; R42/43 Triglycidylisocyanu
2451-62-9 2,4,6(1H,3H,5H)-trione] R52-53 Note; E >=0.1%Conc<1%: T; R46 Eu/N; A rate (TGIC) - 0.08 - - - Sen -
Conc>=20%: T; R45; R38; R41; R43
>=10%Conc<20%: T; R45; R41; R43
Carc. Cat. 2; R45 >=5%Conc<10%: T; R45; R36; R43
C.I. Disperse Blue 1 [1,4,5,8- Xi; R38-41 T ; R: 45 - 38 - 41 - 43, >=1%Conc<5%: T; R45; R43
2475-45-8 Tetraaminoanthraquinone] R43 S: 53 - 45 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Medinoterb acetate (ISO) [6-tert-Butyl-3-methyl-2,4- T; R25 T ; R: 21 - 25 , Conc>=25%: T; R25; R21
2487-01-6 dinitrophenyl acetate] Xn; R21 S: (1/2) - 36/37 - 45 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
T+; R28 T+; N >=3% Conc<7%: T; R25; R21
Oxydisulfoton [O O-Diethyl S-[2-(ethylsulphinyl)ethyl] T; R24 R: 24-28-50/53 >=1% Conc<3%: T; R25
2497-07-6 phosphorodithioate] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=0.1% Conc<1%: Xn; R22 Eu - - - - - - - -
Xi; R36/37/38 Xi ; N ; R: 36/37/38 - 43 -
R43 51/53 Conc>=20%: Xi; R36/37/38; R43
2499-95-8 Hexyl acrylate N; R51-53 S: (2) - 24 - 26 - 37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
N ; R: 51/53
2511-00-4 Ethyl 2-cyclohexylpropionate N; R51-53 S: 61 Eu - - - - - - - -
Xi ; R: 38 ,
2514-53-6 Ethylene bis(trichloroacetate) Xi; R38 S: (2) Conc>=20%: Xi; R38 Eu - - - - - - - -
Conc>=25%: T; R25; R34; R21; R43
T; R25 >=10%Conc<25%: C; R34; R22; R43
Xn; R21 >=5%Conc<10%: Xn; R22; R36/38; R43
C; R34 T >=3%Conc<5%: Xn; R22; R43
2527-66-4 1,2-Benzisothiazol-3(2H)-one, 2-methyl- R43 R: 21-25-34-43 >=1%Conc<3%: Xi; R43 N - - - - - - - -
Dibutyl phenyl
2528-36-1 Dibutyl phenyl phosphate A phosphate 0.3 3.5 - - - Sk -
3-Methylpyrazol-5-yl-dimethylcarbamate T ; R: 23/24/25 , Conc>=25%: T; R23/24/25
2532-43-6 [Monometilan] T; R23/24/25 S: (1/2) - 13 - 45 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -

Conc>=25%: T; R40; R23; R48/23; R36/37/38;

R42/43
>=20%Conc<25%: T; R40; R48/23; R20;
R36/37/38; R42/43
>=10%Conc<20%: T; R40; R48/23; R20;
Carc. Cat. 3; R40 R42/43
Benzene, 1,1'-methylenebis[2-isocyanato- [2,2'- T; R23-R48/23 T >=3%Conc<10%: Xn; R40; R20; R48/20;
Methylenediphenyl diisocyanate; Diphenylmethane- Xi; R36/37/38 R: 23-36/37/38-40-42/43- R42/43 Isocyanates, all
2536-05-2 2,2'-diisocyanate] R42/43 48/23 >=1%Conc<3%: Xn; R40; R48/20; R42/43 N/Eu; A (as-NCO) - 0.02 - 0.07 - Sen -
Formothion (ISO) [N-Formyl-N-
methylcarbamoylmethyl O,O-dimethyl Xn ; R: 21/22 ,
2540-82-1 phosphorodithioate] Xn; R21/22 S: (2) - 36/37 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
R: 53
2550-52-9 Cyclohexadecanone R53 S: 61 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Sulphur
2551-62-4 Sulphur hexafluoride [Sulfur hexafluoride] A hexafluoride 1000 5970 - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
>=3%Conc<7%: T; R25; R21
Demephion-S (ISO) [O,O-Dimethyl S-2- T+; R28 T+ ; R: 24 - 28 , >=1%Conc<3%: T; R25
2587-90-8 methylthioethyl phosphorothioate] T; R24 S: (1/2) - 28 - 36/37 - 45 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
E
1-Hydroxybenzotriazole, anhydrous(Note: see also R: 2
2592-95-2 CAS No. 123333-53-9) E; R2 S: 16-35 Eu - - - - - - - -
Carc. Cat. 3; R40 T ; N ; R: 21/22 - 23 - 40 -
T; R23 50/53, Conc>=25%: T; R40; R23; R21/22
5-Ethoxy-3-trichloromethyl-1,2,4-thiadiazole Xn; R21/22 S: (1/2) - 36/37 - 38 - 45 - >=3%Conc<25%: Xn; R40; R20
2593-15-9 [Etridiazole] N; R50-53 60 - 61 >=1%Conc<3%: Xn; R40 Eu - - - - - - - -
Mecarbam (ISO) [N-Ethoxycarbonyl-N- T ; N ; R: 24/25 - 50/53,
methylcarbamoylmethyl O,O-diethyl T; R24/25 S: (1/2) - 36/37 - 45 - 60 - Conc>=25%: T; R24/25
2595-54-2 phosphorodithioate] N; R50-53 61 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
Phenthoate (ISO)
Xn; N
[Ethyl 2-(dimethoxyphosphinothioylthio)-2- Xn; R21/22 R: 21/22-50/53
2597-03-7 phenylacetate] N; R50-53 S: (2-)22-36/37-60-61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
2,7-Naphthalenedisulfonic acid, 3,3'-[[1,1'-biphenyl]-
4,4'-diylbis(azo)]bis[5-amino-4-hydroxy-, tetrasodium Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
2602-46-2 salt [C.I. Direct Blue 6] Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
2605-44-9 Dodecanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Promecarb (ISO) [5-Isopropyl-3-tolyl T ; N ; R: 25 - 50/53,
methylcarbamate; 3-Isopropyl-5-methylphenyI-N- T; R25 S: (1/2) - 24 - 37 - 45 - 60 - Conc>=25%: T; R25
2631-37-0 methylcarbamate] N; R50-53 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Isoprocarb (ISO) [o-Cumenyl methylcarbamate; 2- Xn; R22 Xn ; N ; R: 22 - 50/53,
2631-40-5 Isopropylphenyl N-methylcarbamate] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Conc>=20%: Xi; R41; R38; R43
>=10%Conc<20%: Xi; R43; R41
Xi; R38-41 Xi ; R: 38 - 41 - 43 , >=5%Conc<10%: Xi; R36; R43
2633-67-2 Styrene-4-sulfonyl chloride R43 S: (2) - 24 - 26 - 37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn, N; R22; R38; R41;R43
Xn; R22 >=20%Conc<25%: Xi; R38; R41; R43
Xi; R38-41 Xn; N >=10%Conc<20%: Xi; R41; R43
1,2-Benzisothiazol-3(2H)-one [1,2-Benzisothiazolin-3- R43 R: 22-38-41-43-50 >=5%Conc<10%: Xi; R36; R43
2634-33-5 one] N; R50 S: (2-)24-26-37/39-61 >=0.05%Conc<5%: Xi; R43 Eu - - - - - - - -
S-[2-(Isopropylsulphinyl)ethyl] O,O-dimethyl T ; R: 23/24/25 , Conc>=25%: T; R23/24/25
2635-50-9 phosphorothioate T; R23/24/25 S: (1/2) - 13 - 45 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
Cyanophos (ISO) [O-4-Cyanophenyl O,O-dimethyl Xn; R21/22 Xn ; N ; R: 21/22 - 50/53,
2636-26-2 phosphorothioate] N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
T+; R28 T+; N >=3%Conc<7%: T; R25; R21
Azinphos-ethyl (ISO) [O,O-Diethyl 4-oxobenzotriazin- T; R24 R: 24-28-50/53 >=1%Conc<3%: T; R25
2642-71-9 3-ylmethyl phosphorodithioate] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
Xn ; R: 22 ,
2655-14-3 XMC [3,5-Xylyl methylcarbamate] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
C ; R: 34 - 51/53,
C; R34; S: (1/2) - 23 - 26 - 36/37/39 - Conc>=10%: C; R34
2687-94-7 1-Octyl-2-pyrrolidone [N-(n-octyl-2-pyrrolidinone}] N; R51-53 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
C; R34 C ; N ; R: 34 - 43 - 50/53, Conc>=10%: C; R34; R43
R43 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%: Xi; R36/38; R43
2687-96-9 1-Dodecyl-2-pyrrolidone N; R50-53 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
o-
Chlorobenzylidene 0.05 Peak 0.39 Peak
2698-41-1 o-Chlorobenzylidene malononitrile A malononitrile limitation limitation - - - Sk -

E; R3 E; C
O; R7 R: 3-7-22-34 Conc>=25%: C; R34; R22;
Cyclohexylidene hydroperoxide(Note: see also CAS C; R34 S: (1/2-)3/7-14-36/37/39-45 >=10%Conc<25%: C; R34
2699-11-8 No. 78-18-2, 2407-94-5 & 12262-58-7) Xn; R22 Note: C >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -
T; R23 T; N Conc>=25%: T; R23; R48/20
Xn; R48/20 R: 23-48/20-50 >=10%Conc<25%: Xn; R20; R48/20
2699-79-8 Sulphuryl difluoride N; R50 S: (1/2-)45-63-60-61 >=3%Conc<10%: Xn; R20 Eu; A Sulphuryl fluoride 5 21 10 42 - - -
T+; N Conc>=7%: T+; R26/27/28
S-[2-(Ethylsulphinyl)ethyl] O,O-dimethyl T+; R26/27/28 R: 26/27/28-51/53 >=1%Conc<7%: T; R23/24/25
2703-37-9 phosphorodithioate N; R51-53 S: (1/2-)13-28-45-61 >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
(1alpha,2alpha,3ß,6ß)-1,2,3,6-Tetrahydro-3,6-
methanophthalic anhydride [cis-exo-Himic Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41
anhydride](Note: see also CAS No 129-64-6 & 826- Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
2746-19-2 62-0) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -

Xi ; R: 36 - 43,
3-Hydroxypropyl methacrylate(Note: see also CAS Xi; R36 S: (2) - 24/25 - 26 - 37/39; Conc>=20%: Xi; R36, R43
2761-09-3 No 923-26-2) R43 Notes: C ; D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T; R24/25; R36/37/38
Diquat ion [9,10-Dihydro-8a,10a- T; R24/25 T ; R: 24/25 - 36/37/38, >=20%Conc<25%: Xn; R21/22; R36/37/38
2764-72-9 diazoniaphenanthrene ion] Xi; R36/37/38 S: (1/2 ) - 22 - 36/37/39 - 45 >=3%Conc<20%: Xn; R21/22 Eu - - - - - - - -
Endothion (ISO) [S-5-Methoxy-4-oxopyran-2-ylmethyl T ; R: 24/25 , Conc>=25%: T; R24/25
2778-04-3 dimethyl phosphorothioate] T; R24/25 S: (1/2) - 36/37 - 45 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
O; R8
Xn; R22
R31 O ; Xn ; N ; R: 8 - 22 - 31 -
Dichloroisocyanuric acid [Dichloro-1,3,5- Xi; R36/37 36/37 - 50/53, Conc>=25%: Xn; R22; R36/37; R31
2782-57-2 triazinetrione] N; R50-53 S: (2) - 8 - 26 - 41 - 60 - 61 >=20%Conc<25%: Xi; R36/37; R31 Eu - - - - - - - -
Xn; R22 Xn
R43 R: 22-43-52/53 Conc>=25%: Xn; R22; R43
2788-74-1 4-Ethylamino-3-nitrobenzoic acid R 52-53 S: (2-)22-24-37-61 >=1%Conc<25%: Xi R43 Eu - - - - - - - -

Carc. Cat. 3; R40

Repr. Cat. 2; R61 T; N Conc>=25%: T; R40; R61; R64; R20/22;
Potassium perfluorooctanesulfonate [Potassium T; R48/25 R: 61-20/22-40-48/25-64- R48/25
heptadecafluorooctane-1-sulfonate](Note: see also Xn; R20/22 51/53 >=10%Conc<25%: T; R40; R61; R64; R48/25
CAS No. 1763-23-1, 70225-14-8, 29081-56-9, 29457- R64 S: 53-45-61 >=1%Conc<10%: T; R40; R61; R64; R48/22
2795-39-3 72-5) N; R51-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Xn
Xn; R21 R: 21-36 Conc>=25%: Xn; R21; R36
2807-30-9 2-(Propyloxy)ethanol [EGPE] Xi; R36 S: (2-)26-36/37-46 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
Conc>=25%: Xn; R22; R41
Xn; R22 Xn >=10%Conc<25%: Xi; R41
2809-21-4 Phosphonic acid, (1-hydroxyethylidene)bis- Xi; R41 R: 22-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Xn ; R: 20/21/22 ,
2810-74-4 N,N'-Dimethylbenzidine Xn; R20/21/22 S: (2) - 22 - 36 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R41
Xi; R41 R: 22-41-52/53 >=10%Conc<25%: Xi; R41
2820-37-3 3,4-Dimethyl-1H-pyrazole R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
C.I. Disperse Yellow 3 [N-[4-[(2-Hydroxy-5- Carc. Cat. 3; R40 Xn ; R: 40 - 43
2832-40-8 methylphenyl)azo]phenyl]acetamide] R43 S: (2)22 - 36/37 - 46 Conc>=1%: Xn; R40; R43 Eu - - - - - - - -
Conc>=25%: C; R34; R21/22; R48/22; R43
C; R34 C >=10%Conc<25%: C; R34; R48/22; R43
Xn; R21/22-48/22 R: 21/22-34-43-48/22 >=5%Conc<10%: Xi; R36/38; R43
2833-30-9 5-Ethoxy-5H-furan-2-one R43 S: (1/2-)23-26-36/37/39-45 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
T ; R: 23/24/25 ,
3-Amino-N,N-dimethylaniline [N,N-Dimethylbenzene- S: (1/2) - 28 - 45 ; Conc>=25%: T; R23/24/25
2836-04-6 1,3-diamine](Note: see also CAS No 99-98-9) T; R23/24/25 Note: C >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
Xn; R21/22 Xn ; N ; R: 21/22 - 51/53
2840-00-8 3,5-Dichloro-2,6-difluoropyrdine-4-amine N; R51-53 S: (2)36/37 - 61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
E; R3 E; T+; N
T+; R26/27/28 R: 3-26/27/28-33-51/53 Conc>=7%: T+; R26/27/28; R33
Dipicrylamine, ammonium salt [Benzenamine, 2,4,6- R33 S: (1/2-)27/28-36/37-45-61- >=1%Conc<7%: T; R23/24/25; R33
2844-92-0 trinitro-N-(2,4,6-trinitrophenyl), ammonium salt] N; R51-53 63 >=0.1%Conc<1%; Xn; R20/21/22 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
2847-16-7 Decanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Xn; R21/22 Conc>=25%: C; R34; R21/22; R43
C; R34 C >=10%Conc<25%: C; R34; R43
3-Aminomethyl-3,5,5-trimethylcyclohexylamine R43 R: 21/22-34-43-52/53 >=5%Conc<10%: Xi; R36/38; R43
2855-13-2 [Cyclohexanemethanamine, 5-amino-1,3,3-trimethyl] R52-53 S: (1/2-)26-36/37/39-45-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Xn; R21/22 Xn ; R: 21/22 - 36/38 - 43 , Conc>=25%: Xn; R21/22; R36/38; R43

Xi; R36/38 S: (2) - 26 - 28 ; >=10%Conc<25%: Xi; R36/38; R43
2867-47-2 2-Dimethylaminoethyl methacrylate R43 Note: D >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
E; R2
O; R8
Xn; R22
Troclosene sodium [Dichloroisocyanuric acid, sodium Xi; R36/37 E; Xn; N
salt of; Dichloro-1,3,5-triazinetrione, sodium salt R31 R: 2-8-22-31-36/37-50/53
2893-78-9 of](Note: see also CAS No. 2244-21-5) N; R50-53 S: (2-)8-26-41-45-60-61 Conc>=10%: Xn; R22; R31; R36/37 Eu - - - - - - - -

Conc>=10%: T; R23/24/25; R34; R43

2-Hydroxy-1-methylethyl acrylate [Hydroxypropyl T; R23/24/25 T ; R: 23/24/25 - 34 - 43, >=5%Conc<10%: T; R23/24/25; R36/38; R43
acrylate](Note: see also CAS No 999-61-1 & 25584- C; R34 S: (1/2) - 26 - 36/37/39 - 45; >=2%Conc<5%: T; R23/24/25; R43
2918-23-2 83-2) R43 Notes: C ; D >=0.2%Conc<2%: Xn; R20/21/22; R43 Eu - - - - - - - -
T; N
Chlorpyrifos (ISO) [O,O-Diethyl O-3,5,6-trichloro-2- T; R25 R: 25-50/53 Conc>=25%: T; R25
2921-88-2 pyridyl phosphorothioate] N; R50-53 S: (1/2-)45-60-61 >=3%Conc<25%: Xn; R22 Eu; A Chlorpyrifos - 0.2 - - - Sk -
2971-90-6 Clopidol A Clopidol - 10 - - - - -
Xi; N
R43 R: 43-51/53
2973-59-3 2-Bromo-5-hydroxy-4-methoxybenzaldehyde N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
T+; N
T+; R26/27/28 R: 26/27/28 - 33 - 50/53 Conc>=7%: T+; R26/27/28; R33
DNOC, ammonium salt of [Ammonium dinitro-o- R33 S: (1/2) - 13 - 28 - 45 - 60 - >=1%Conc<7%: T; R23/24/25; R33
2980-64-5 cresolate; Ammonium 4,6-dinitro-o-tolyl oxide] N; R50-53 61 >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 43 Conc>=25%: Xn; R22; R43
2997-92-4 2,2'-Azobis[2-methylpropionamidine] dihydrochloride R43 S: (2)24 - 37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 1; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
3026-22-0 Benzoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Conc>=25%: T; R24; R34; R22
T; R24 >=10%Conc<25%: C; R34; R21
Xn; R22 T ; R: 22 - 24 - 34 , >=5%Conc<10%: Xn; R21; R36/38
3030-47-5 Bis(2-dimethylaminoethyl)(methyl)amine C; R34 S: (1/2) - 26 - 36/37/39 - 45 >=3%Conc<5%: Xn; R21 Eu - - - - - - - -

Page 136
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Carc. Cat. 2; R45 Conc>=25%: T; R45; R62; R68; R21/22;

Muta. Cat. 3; R68 R48/22; R41; R43
Repr. Cat. 3; R62 T >=10%Conc<25%: T; R45; R62; R68; R48/22;
Xn; R21/22-48/22 R: 45-21/22-41-43-48/22-62- R41; R43
Xi; R41 68-52/53 >=5%Conc<10%: T; R45; R62; R68; R36; R43
2,3-Epoxypropyltrimethylammonium chloride … % R43 S: 53-45-61 >=1%Conc<5%: T; R45; R68; R43
3033-77-0 [Glycidyl trimethylammonium chloride … %] R52-53 Notes: B ; E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -

Xi; N
Xi; R37/38 R: 37/38-51/53
3066-71-5 Cyclohexyl acrylate N; R51-53 S: (2-)61; Note: D Conc>=10%: Xi; R37/38 Eu - - - - - - - -
Ethanol, 2-[2-(dodecyloxy)ethoxy]-, hydrogen sulfate, Xn; R22 Xn Conc>=25%: Xn; R22; R36/38
3088-31-1 sodium salt Xi; R36/38 R: 22-36/38 >=20%Conc<25%: Xi; R36/38 N - - - - - - - -

Xn; N Tin, organic

Chlorotricyclohexylstanne (Note: see also CAS No. Xn; R20/21/22 R: 20/21/22-50/53 compounds (as
3091-32-5 1449-55-4 and 7067-44-9) N; R50-53 S: (2-)26-28-60-61; Note: A Conc>=1%: Xn; R20/21/22 Eu; A Sn) - 0.1 - 0.2 - Sk -
N ; R: 50/53,
3100-36-5 Mixture of cis- and trans-cyclohexadec-8-en-1-one N; R50-53 S: 60 - 61 Eu - - - - - - - -
Xn ; R: 20/22 ,
3129-91-7 Dicyclohexylammonium nitrite Xn; R20/22 S: (2) - 15 - 41 Conc>=10%: Xn; R20/22 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
Xi; R41 Xn ; N ; R: 22 - 41 - 51/53 >=10%Conc<25%: Xi; R41
3131-52-0 5,6-Dihydroxyindole N; R51-53 S: (2)22 - 26 - 36/37/39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
R: 53
3147-77-1 2-(2-Hydroxy-4-octyloxyphenyl)-2H-benzotriazole R53 S: 61 Eu - - - - - - - -
Carc.Cat.2; R45 T; N Conc>=25%: T; R45; R68; R23/24/25
Muta.Cat.3; R68 R: 45-23/24/25-68-50/53 >=3%Conc<25%: T: R45; R68; R20/21/22
4-Chloro-o-toluidine hydrochloride (Note: see also T; R23/24/25 S: 53-45-60-61 >=1%Conc<3%: T; R45; R68
3165-93-3 CAS No. 95-69-2) N; R50-53 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Xn; R20
Xi; R36/37/38 Xn ; R: 20 - 36/37/38 - 42 - Conc>=25%: Xn; R20; R42; R36/37/38
R42 52/53, >=20%Conc<25%: Xn; R42; R36/37/38 Isocyanates, all
3173-72-6 1,5-Naphthylene diisocyanate R52-53 S: (2) - 26 - 28 - 38 - 45 - 61 >=1%Conc<20%: Xn; R42 Eu; A (as-NCO) - 0.02 - 0.07 - Sen -
1,2,5,6,9,10-Hexabromocyclododecane [HBCD; Xn
Cyclododecane, hexabromo](Note: see also CAS No R: 63-64 Conc>=5%: Xn; R63; R64
3194-55-6 25637-99-4) Repr. Cat. 3; R63 R64 S: 22-53-60-61 >=1%Conc<5%: Xn; R64 Eu/N - - - - - - - -
Xi; R36-38 Xi ; N ; R: 36/38 - 50/53
3236-71-3 9,9-Bis(4-hydroxyphenyl)fluorene N; R50-53 S: (2)26 - 37 - 60 - 61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
Xn; R21/22 Xn ; N ; R: 21/22 - 50/53,
3244-90-4 O,O,O',O'-Tetrapropyl dithiopyrophosphate N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
3249-61-4 Docosanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
3250-74-6 3-(2H-Tetrazol-5-yl)pyridine Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Conc>=7%: T+; R27/28
T+ ; R: 27/28 , >=1%Conc<7%: T; R24/25
3254-63-5 Dimethyl 4-(methylthio)phenyl phosphate T+; R27/28 S: (1/2) - 28 - 36/37 - 45 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
Xn
R: 40-52/53
(3-Chloro-2-hydroxypropyl) trimethylammonium Carc. Cat. 3, R40 S: 36/37-61
3327-22-8 chloride … % R52-53 Note: B Conc>=1%: Xn; R40 Eu - - - - - - - -
Tetramethyl
3333-52-6 Tetramethyl succinonitrile A succinonitrile 0.5 2.8 - - - Sk -
Xn ; N ; R: 22 - 40 - 43 -
Carc. Cat. 3; R40 Xn; R22 R43 N; 50/53, S: (2) - 22 - 36/37 - Conc>=25%: Xn; R40; R22; R43
3333-67-3 Nickel carbonate R50-53 60 - 61 >=1%Conc<25%: Xn; R40; R43 Eu - - - - - - - -

Page 137
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Dithianon (ISO) [5,10-Dihydro-5,10-dioxonaphtho(2,3- Xn; R22 Xn ; N ; R: 22 - 50/53,

3347-22-6 b)(1,4)dithiazine-2,3-dicarbonitrile] N; R50-53 S: (2) - 24 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
3349-06-2 Formic acid, nickel(2+) salt R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
Xi ; R: 43
3353-51-3 1-(p-Methoxyphenyl) acetaldehyde oxime R43 S: (2)24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; N
Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
3380-30-1 5-Chloro-2-(4-chlorophenoxy)phenol N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Triclosan [2,4,4'- T; R23 Conc>=25%: T; R23; R36/37/38
Trichloro-2'-hydroxy-diphenyl-ether; 5-Chloro-2-(2,4- Xi; R36/37/38 T; N R: 23-36/37/38-50/53 >=20%Conc<25%: Xn; R20; R36/37/38
3380-34-5 dichlorophenoxy)phenol] N; R50-53 S: 22-26-37-38-39-45-60 >=3%Conc<20%: Xn; R20 N/Eu - - - - - - - -
3383-96-8 Temephos A Temephos - 10 - - - - -

1,2,3,6-Tetrahydro-4-methylphthalic anhydride(Note: Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

see also CAS No 1694-82-2; 5333-84-6; 11070-44-3; Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
3425-89-6 26590-20-5; 34090-76-1 & 42498-58-80) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -

O; R7 O ; Xi ; N ; R: 7 - 38 - 51/53,
tert-Butyl alpha alpha-dimethylbenzyl peroxide [tert- Xi; R38 S: (2) - 3/7 - 14 - 36/37/39 -
3457-61-2 Butyl cumyl peroxide] N; R51-53 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
R: 10
3459-83-4 1,3-Diethoxypropane R10 S: (2)9 - 24 Eu - - - - - - - -
Xn; N
Xn; R22 R: 22-50/53
3508-98-3 2-Phenylhexanenitrile N; R50-53 S: (2-)23-60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi ; R: 36/38 - 43 ,
Xi; R36/38 S: (2) - 39 ; Conc>=20%: Xi; R36/38; R43
3524-68-3 Pentaerythritol triacrylate R43 Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
1,3-Naphthalenedisulfonic acid, 8-[[4'-[(4-
ethoxyphenyl)azo][1,1'-biphenyl]-4-yl]azo]-7-hydroxy-, Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
3530-19-6 disodium salt Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
T+; R26/28
Xn; R21 Conc>=25%: T+; R26/28; R21; R33
R32 T+; N >=7%Conc<25%: T+; R26/28; R33
R33 R: 21-26/28-32-33-51/53 >=1%Conc<7%: T; R23/25; R33
3535-84-0 Thallium thiocyanate N; R51-53 S: (1/2-)13-28-36/37-45-61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Conc>=25%: T; R23; R48/25
T >=10%Conc<25%: T; R20; R48/25 Tin, organic
T; R23-48/25 R: 23-48/25-53 >=3%Conc<10%: Xn; R20; R48/22 compounds (as
3542-36-7 Dichlorodioctyl stannane R53 S: (1/2-)38-45-61 >=1%Conc<3%: Xn; R48/22 Eu;A Sn) - 0.1 - 0.2 - Sk -
Xi ; R: 41 , Conc>=10%: Xi; R41
3547-33-9 2-(Octylthio)ethanol [2-Hydroxyethyl octyl sulphide] Xi; R41 S: (2) - 26 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

1,3-Naphthalenedisulfonic acid, 7-hydroxy-8-[[4'-[[4-

[[(4-methylphenyl)sulfonyl]oxy]phenyl]azo][1,1'- Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
3567-65-5 biphenyl]-4-yl]azo]-, disodium salt Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -

2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-3-

[[4'-[(4-hydroxyphenyl)azo][1,1'-biphenyl]-4-yl]azo]-6- Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
3626-28-6 (phenylazo)-, disodium salt Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Xi
Xi; R38 R: 38-53
3681-73-0 (E)-3,7-Dimethyl-2,6-octadienylhexadecanoate R53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -

Page 138
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Lead arsenate (as Pb3(AsO4)2)(Note: see Arsenate Lead arsenate (as

3687-31-8 compounds, see Lead compounds) A Pb3(AsO4)2) - 0.15 - - - - -
T+; N
R: 27/28-50/53 Conc>=7%: T+; R27/28
Sulfotep (ISO) [O,O,O,O-Tetraethyl T+; R27/28 S: (1/2-)23-28-36/37-45-60- >=1%Conc<7%: T; R24/25
3689-24-5 dithiopyrophosphate; TEDP] N; R50-53 61 >=0.1%Conc<1%: Xn; R21/22 Eu; A Sulfotep 0.007 0.1 - - - Sk -

Conc>=25%: T+; R27/28; R23; R48/24/25

>=10%Conc<25%: T+; R27/28; R48/24/25;
R20
T+ ; N ; R: 23 - 27/28 - >=7%Conc<10%: T+; R27/28; R20; R48/21/22
T+; R27/28 48/24/25 - 50/53, >=3%Conc<7%: T; R24/25; R20; R48/21/22
Chlorophacinone (ISO) [2-(2-(4-Chlorophenyl)- T; R23-48/24/25 S: (1/2) - 36/37 - 45 - 60 - >=1%Conc<3%: T; R24/25; R48/21/22
3691-35-8 phenylacetyl)indan-1,3-dione] N; R50-53 61 >=0.1%Conc<1%; Xn; R21/22 Eu - - - - - - - -
Conc>=25%: T; R61; R35; R22
R14 T; C >=10%Conc<25%: T; R61; R35
Repr. Cat. 2; R61 R: 61-14-22-35 >=5%Conc<10%: T; R61; R34
Xn; R22 S: 53-45 >=1%Conc<5%: T; R61; R36/38
3724-43-4 Chloro-N,N-dimethylformiminium chloride C; R35 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
Cyanthoate (ISO) [S-(N-(1-Cyano-1- >=3%Conc<7%: T; R25; R21
methylethyl)carbamoylmethyl) O,O-diethyl T+; R28 T+ ; R: 24 - 28 , >=1%Conc<3%: T; R25
3734-95-0 phosphorothioate] T; R24 S: (1/2) - 36/37 - 45 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
N-(1,1-Dimethylethyl)bis(2- N ; R: 50/53
3741-80-8 benzothiazolesulfen)amide N; R50-53 S: 60 - 61 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 50/53,
3766-81-2 2-Butylphenyl methylcarbamate [Fenobucarb] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi ; R: 36/38 - 43 ,
Xi; R36/38 S: (2) - 26 ; Conc>=20%: Xi; R36/38; R43
3775-90-4 2-tert-Butylaminoethyl methacrylate R43 Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Phosphonic acid, (1-hydroxyethylidene)bis-, Xn; R22 Xn Conc>=25%: Xn; R22; R36
3794-83-0 tetrasodium salt Xi; R36 R: 22-36 >=20%Conc<25%: Xi; R36 N - - - - - - - -
O; R9 O; Xn; N
Xn; R20/22 R: 9-20/22-51/53
3811-04-9 Potassium chlorate N; R51-53 S: (2-)13-16-27-61 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
T ; N ; R: 24/25 - 39/25 - Conc>=25%: T; R24/25; R39/25
T; R24/25 51/53, >=10%Conc<25%: T; R39/25; R21/22
Dioxabenzofos [2-Methoxy-4H-1,3,2- T; R39/25 S: (1/2) - 36/37 - 38 - 45 - >=3%Conc<10%: Xn; R21/22; R68/22
3811-49-2 benzodioxaphosphorin 2-sulphide] N; R51 - 53 61 >=1%Conc<3%: Xn; R68/22 Eu - - - - - - - -
Benazolin (ISO) [4-Chloro-2-oxobenzothiazolin-3-
ylacetic acid; 4-Chloro-2,3-dihydro-2-oxo-1,3- Xi; R36/38 Xi ; R: 36/38 - 52/53,
3813-05-6 benzothiazol-3-ylacetic acid] R52-53 S: (2) - 22 - 61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
Ammonium
perfluorooctanoate
3825-26-1 Ammonium perfluorooctanoate A (h) - 0.1 - - - - -
Xn; R22 C ; N ; R: 22 - 34 - 43 - Conc>=25%: C; R34; R22; R43
C; R34 50/53 >=10%Conc<25%: C; R34; R43
R43 S: (1/2) - 22 - 26 - 28 - >=5%Conc<10%: Xi; R36/38; R43
3847-58-3 3-Chloro-2,4-difluoronitrobenzene N; R50-53 36/37/39 - 45 - 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Repr. Cat. 3; R63 Conc>=25%: T; R63; R25; R36; R43

T; R25 >=20%Conc<25%: Xn; R63; R22; R36; R43
Xi; R36 T; N >=5%Conc<20%: Xn; R63; R22; R43
Ioxynil octanoate (ISO) [4-Cyano-2,6-diiodophenyl R43 R: 25-36-43-63-50/53 >=3%Conc<5%: Xn; R22; R43
3861-47-0 octanoate; 2,6-Dibromo-4-cyanophenyl octanoate] N; R50-53 S: (1/2-)26-36/37-45-60-61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R21/22-48/22; R38; R41
Xn; R21/22-48/22 Xn; N >=20%Conc<25%: Xn; R48/22; R38; R41
Xi; R38-41 R: 21/22-38-41-48/22-51/53 >=10%Conc<20%: Xn; R48/22; R41
3862-73-5 2,3,4-Trifluoroaniline N; R51-53 S: (2-)23-26-36/37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 139
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Xn; R48/22
Xn; R22 Xn; N Conc>=25%: Xn; R40; R22; R48/22; R43
Fuberidazole (ISO) [2-(2-Furyl)benzimidazole; 2-(2- Xi; R43 R: 40-48/22-22-43-50/53 >=10%Conc<25%: Xn; R40; R48/22; R43
3878-19-1 Furyl)-1H-benzimidazole] N; R50-53 S: (2)-22-36/37-60-61 >=1%Conc<10%: Xn; R40; R43 Eu - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
3906-55-6 Cyclohexanebutanoic acid, nickel(2+) salt R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
T; R25 Conc>=25%: T; R25; R38
Sodium salt of chloroacetic acid [Sodium Xi; R38 T ; N ; R: 25 - 38 - 50, >=20%Conc<25%; Xn; R22; R38
3926-62-3 chloroacetate] N; R50 S: (1/2) - 22 - 37 - 45 - 61 >=3%Conc <20%: Xn; R22 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
3971-28-6 1,3-Cyclohexanedimethanol Xi; R41 S: 26-39 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Isopropyl glycidyl ether (IGE) [2,3-Epoxypropyl Isopropyl glycidyl

4016-14-2 isopropyl ether] A ether (IGE) 50 238 75 356 - - -
Xn; R22-48/22 Conc>=25%: Xn; R22; R48/22; R41; R43
Xi; R41 Xn >=10%Conc<25%: Xn; R48/22; R41; R43
R43 R: 22-41-43-48/22-52/53 >=5%Conc<10%: Xi; R36; R43
4023-02-3 Pyrazole-1-carboxamidine monohydrochloride R52-53 S: (2-)22-26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T+; R26; R48/25; R22;

R36/37/38; R43
T+; R26 >=20%Conc<25%: T+; R26; R48/25;
T; R48/25 T+ ; N ; R: 22 - 26 - R36/37/38; R43
Xn; R22 36/37/38 - 43 - 48/25 - >=10%Conc<20%: T+; R26; R48/25; R43
Xi; R36/37/38 50/53, >=7%Conc<10%: T+; R26; R48/22; R43
Diquat dichloride(Note: see also CAS No 85-00-7 & R43 S: (1/2) - 28 - 36/37/39 - 45 - >=1%Conc<7%: T; R23; R48/22; R43
4032-26-2 94021-76-8) N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
C; N
C; R34 R: 34-43-50/53 Conc>=10%: C; R34; R43
3,6,9,12-tetra-Azatetradecamethylenediamine R43 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: Xi; R36/38; R43
4067-16-7 [Pentacthylenehexamine] N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
T; R24 T ; R: 24 - 36/38 - 43 , Conc>=20%: T; R24; R36/38; R43
2,2'-Oxydiethyl diacrylate [Diethylene glycol Xi; R36/38 S: (1/2) - 28 - 39 - 45; >=2%Conc<20%: T; R24; R43
4074-88-8 diacrylate] R43 Note: D >=0.2%Conc<2%: Xn; R21; R43 Eu - - - - - - - -
R14
Xi; R36/37/38 Xn ; R: 14 - 36/37/38 - 42 , Conc>=5%: Xn; R42.; R36/37/38 Isocyanates, all
4083-64-1 4-Isocyanatosulphonyltoluene [Tosyl isocyanate] Xn; R42 S: (2) - 26 - 28 - 30 >=1%Conc<5%: Xn; R42 Eu; A (as-NCO) - 0.02 - 0.07 - Sen -
Xn; R22 Xn Conc>=25%: Xn; R22; R36; R43
Xi; R36 R: 22-36-43 >=20%Conc<25%: Xi; R36; R43
4084-38-2 (2,3,5,6-Tetrafluorophenyl)methanol R43 S: (2-)26-36/37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

T; N
T; R23/24/25 R: 23/24/25 - 50/53 Conc>=25%: T; R23/24/25
4097-36-3 Dinosam [2-(1-Methylbutyl)-4,6-dinitrophenol] N; R50-53 S: (1/2) - 13 - 45 - 60 - 61 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
T; R23
Xi; R36/37/38 T; N Conc>=20%: T; R23; R36/37/38; R42/43 (see
3-Isocyanatomethyl-3,5,5-trimethylcyclohexyl R42/43 R: 23-36/37/38-42/43-51/53 >=2% Conc<20%: T; R23; R42/43 Isophorone Isocyanates,
4098-71-9 isocyanate [Isophorone di-isocyanate] N; R51-53 S: (1/2-)26-28-38-45-61 >=0.5%Conc<2%: Xn; R20; R42/43 Eu; A diisocyanate - - - - - - all)
T+ ; N ; R: 27/28 - 50/53, Conc>=7%: T+; R27/28
Phosacetim (ISO) [O,O-Bis(4-chlorophenyl)-N- T+; R27/28 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R24/25
4104-14-7 acetimidoylphosphoramidothioate] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -

Page 140
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R68; R26; R24/25; R48/22;

R37/38; R41
>=20%Conc<25%: T+; R68; R26; R21/22;
R48/22; R37/38; R41
F; R11 >=10%Conc<20%: T+; R68; R26; R21/22;
Muta. Cat. 3; R68 R48/22; R41
T+; R26 F; T+; N >=7%Conc<10%: T+; R68; R26; R21/22; R36
T; R24/25 R: 11 - 24/25 - 26 - 37/38 - >=5%Conc<7%: T; R68; R23; R21/22; R36
Xn; R48/22 41 - 48/22 - 50 - 68 >=3%Conc<5%: T; R68; R21/22; R23
Crotonaldehyde [2-Butenal](Note: see also CAS No Xi; R37/38-41 S: (1/2) - 26 - 28 - 36/37/39 - >=1%Conc<3%: T; R68; R23
4170-30-3 123-73-9) N; R50 45 - 61 >=0.1%Conc<1%: Xn; R20 Eu; A Crotonaldehyde 2 5.7 - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53,
4186-71-4 N-Ethyl-N-methylpiperidinium iodide N; R51-53 S: (2) - 22 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Xi
R10 R: 10-36/37-67
(S)-Butan-2-ol(Note: see also CAS No. 78-92-2, Xi; R36/37 S: (2-)7/9-13-24/25-26-46
4221-99-2 14898-79-4 & 15892-23-6) R67 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
Xi
(3beta, 5alpha, 6beta)-3-(Acetyloxy)-5-bromo-6- R43 R: 43-52/53
4229-69-0 hydroxy-androstan-17-one R52-53 S: (2-)22-36/37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Kelevan (ISO) [Ethyl 5-(1,2,3,5,6,7,8,9,10,10-
decachloro-4-hydroxypentacyclo
(5,2,1,02,6,03,9,05,8)dec-4-yl)-4-oxovalerate; Ethyl 5-
(perchloro-5- T; R24
hydroxypentacyclo[5,3,0,02,6,03,9,04,8]decan-5-yl)-4- Xn; R22 T ; N ; R: 22 - 24 - 51/53, Conc>=25%: T; R24; R22
4234-79-1 oxopentanoate] N; R51-53 S: (1/2) - 36/37 - 45 - 61 >=3%Conc<25%: Xn; R21 Eu - - - - - - - -
F ; T+ ; R: 17 - 26 Conc>=7%: T+; R26
F; R17 S: (1/2) - 9 - 28 - 36/37 - 43 - >=1%Conc<7%: T; R23
4262-43-5 tert-Butylarsine T+; R26 45 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -

C; R34 Conc>=25%: C; R34; R20/21/22; R48/22; R43

Xn; R20/21/22-48/22 C; N >=10%Conc<25%: C; R34; R48/22; R43
2-Amino-4-(trifluoromethyl)benzenethiol R43 R: 20/21/22-34-43-48/22-50 >=5%Conc<10%: Xi; R36/38; R43
4274-38-8 hydrochloride N; R50 S: (1/2-)26-36/37/39-45-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; R38 Xi
R43 R: 38-43-53 Conc>=20%: Xi; R38; R43
4277-06-9 Cyclohexadeca-1,9-diene R53 S: (2-)36/37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Conc>=7%: T+; R27/28
T+; R: 27/28 , >=1%Conc<7%: T; R24/25
4301-50-2 Fluenetil (ISO) [2-Fluoroethyl biphenyl-4-ylacetate] T+; R27/28 S: (1/2) - 28 - 36/37 - 45 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
Xn ; R: 21/22 ,
4312-97-4 Sodium 3-chloroacrylate Xn; R21/22 S: (2) - 36/37 Conc>=25%: Xn; R21/22 Eu - - - - - - - -

2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-6-

[[4'-[(4-hydroxyphenyl)azo][1,1'-biphenyl]-4-yl]azo]-3- Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
4335-09-5 [(4-nitrophenyl)azo]-, disodium salt Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Xn; R20 Conc>=25%: C; R34; R20; R43
C; R34 C >=10%Conc<25%: C; R34; R43
R43 R: 20-34-43-52/53 >=5%Conc<10%: Xi; R36/38; R43
4369-14-6 Acrylic acid, 3-(trimethoxysilyl)propyl ester R52-53 S: (1/2-)26-36/37/39-45-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R22 C ; N ; R: 22 - 34 - 51/53 Conc>=25%: C; R34; R22
C; R34 S: (1/2) - 22 - 26 - 36/37/39 - >=10%Conc<25%:C; R34
4403-70-7 3-Aminobenzylamine N; R51-53 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Sodium 1-(3,4-dihydro-6-methyl-2,4-dioxo-2H-pyran-3- Xn ; R: 22 ,
4418-26-2 ylidene)ethonolate [Sodium dehydracetate] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi ; R: 36 ,
4435-53-4 3-Methoxybutyl acetate Xi; R36 S: (2) - 25 Conc>=20%: Xi; R36 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R49; R61; R62; R68; R48/23;

Carc. Cat. 1; R49 R20/22; R38; R42/43
Muta. Cat. 3; R68 >=20%Conc<25%: T; R49; R61; R62; R68;
Repr. Cat. 2; R61 R48/23; R38; R42/43
Repr. Cat. 3; R62 >=10%Conc<20%: T; R49; R61; R62; R68;
T; R48/23 R48/23; R42/43
Xn; R20/22 T >=5%Conc<10%: T; R49; R61; R62; R68;
Xi; R38 R: 49-61-20/22-38-42/43- R48/20; R42/43
4454-16-4 Hexanoic acid, 2-ethyl-, nickel(2+) salt R42/43 48/23-62-68 >=1%Conc<5%: T; R49; R61; R68; N - - - - - - - -
Xn; R22 Xn ; R: 22 - 52/53 ,
4463-59-6 2-(2-Bromoethoxy)anisole R52-53 S: (2) - 22 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
T; R23/25
R33 T; N Conc>=10%: T; R68; R23/25; R33 Cadmium and
Xn; R68 R: 23/25-33-68-50/53 >=1%Conc<10%: Xn; R68; R20/22; R33 compounds (as
4464-23-7 Cadmium diformate [Cadmium formate] N; R50-53 S: (1/2-)22-45-60-61 >=0.25%Conc<1%: Xn; R20/22; R33 Eu; A Cd) - 0.01 - - 2 - -
1,1-Dimethyl-3-phenyluronium trichloroacetate Xi; R38 Xi ; N ; R: 38 - 50/53,
4482-55-7 [Fenuron TCA] N; R50-53 S: (2) - 60 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -

R10 C ; R: 10 - 21/22 - 34 - 48/20 Conc>=25%: C; R34; R21/22; R48/20

Xn; R21/22-48/20 S: (1/2) - 16 - 26 - 36/37/39 - >=10%Conc<25%: C; R34; R48/20
4524-95-2 2-Methyl-2-azabicyclo[2.2.1]heptane C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 36/37/38 -
Xi; 36/37/38 52/53, Conc>=25%: Xn; R22; R36/37/38
4636-83-3 Morfamquat dichloride R52-53 S: (2) - 22 - 36 - 61 >=20%Conc<25%: Xi; R36/37/38 Eu - - - - - - - -
Conc>=25%: T; R24/25; R36/37/38
T; R24/25 T ; R: 24/25 - 36/37/38, >=20%Conc<25%: Xn; R21/22; R36/37/38 Paraquat
4685-14-7 Paraquat (ISO) [1,1'-Dimethyl-4,4'-bipyridinium] Xi; R36/37/38 S: (1/2) - 22 - 36/37/39 - 45 >=3%Conc<20%: Xn; R21/22 Eu; A (respirable sizes) - 0.1 - - - - -
Conc>=25%: Xn; R21/22; R37/38; R41
>=20%Conc<25%: Xi; R37/38; R41
Xn; R21/22 Xn >=10%Conc<20%: Xi; R41
4706-78-9 Sulfuric acid, monododecyl ester, potassium salt Xi; R37/38-41 R: 21/22-37/38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

1,3,5-Tris(2-hydroxyethyl)hexahydro-1,3,5-triazine Xn; R22 Xn; R: 22 - 43 Conc>=25%: Xn; R22; R43

4719-04-4 [2,2',2''-(Hexahydro-1,3,5-triazine-1,3,5-triyl)triethanol] Xi; R43 S: (2) - 24 - 37 >=0.1% Conc<25%: Xi; R43 Eu - - - - - - - -
T; R25 T ; N ; R: 21 - 25 - 50/53 ,
Bromophos ethyl (ISO) [O-4-Bromo-2,5- Xn; R21 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R25; R21
4824-78-6 dichlorophenyl O,O-diethyl phosphorothioate] N; R50-53 60 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Conc>=7%: T+; R26/28
Brucine sulphate(Note: see also CAS No 5786-97-0, T+; R26/28 T+ ; R: 26/28 - 52/53, >=1%Conc<7%: T; R23/25
4845-99-2 68239-26-9 & 68310-42-9) R52-53 S: (1/2) - 13 - 45 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Xi ; R: 36/38 - 43 ,
Xi; R36/38 S: (2) - 26 - 39 ; Conc>=20%: Xi; R36/38; R43
4986-89-4 Pentaerythritol tetraacrylate R43 Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
4995-91-9 Octanoic acid, nickel(2+) salt R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
Carc. Cat. 3; R40 Xn Conc>=25%: Xn; R40; R22; R36
Xn; R22 R: 22-36-40 >=20%Conc<25%: Xn; R40; R36
5064-31-3 Trisodium nitrilotriacetate Xi; R36 S: (2-)26-36/37-46 >=5%Conc<20%: Xn; R40 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
5112-16-3 Nonanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Conc>=25%: Xn; R22; R48/22; R41; R43
Xn; R22-48/22 Xn >=10%Conc<25%: Xn; R48/22; R41; R43
Xi; R41 R: 22-41-43-48/22 >=5%Conc<10%: Xi; R36; R43
5117-12-4 4-(1-Oxo-2-Propenyl)-morpholine R43 S:(2-)23-26-36/37/39 >=1%Conc<5%:Xi; R43 Eu - - - - - - - -

4,4'-Methylenedi(cyclohexylisocyanate) T; R23 Conc>=20%: T; R23; R36/37/38; R42/43 Methylene bis(4- (see

[Dicyclohexylmethane-4,4'-diisocyanate; Methylene Xi; R36/37/38 T ; R: 23 - 36/37/38 - 42/43 , >=2%Conc<20%: T; R23; R42/43 cyclo- Isocyanates,
5124-30-1 bis(4-cyclohexylisocyanate)] R42/43 S: (1/2) - 26 - 28 - 38 - 45 >=0.5%Conc<2%: Xn; R20; R42/43 Eu; A hexylisocyanate) - - - - - - all)
O,O-Diethyl phthalimidophosphonothioate Xi; R38 Xi ; R: 38 - 43 , Conc>=20%: Xi; R38; R43
5131-24-8 [Ditalimfos] R43 S: (2) - 36/37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
3-Butoxypropan-2-ol [Propylene glycol monobutyl Xi ; R: 36/38 ,
5131-66-8 ether] Xi; R36/38 S: (2) Conc>=20% : Xi; R36/38 Eu - - - - - - - -

Conc>=25%: T; R45; R62; R48/23; R21/22;

R37/38
>=20%Conc< 25%: T; R45; R62; R48/23;
Carc.Cat.2; R45 R37/38 >=10%Conc<20%: T; R45; R62;
Repr.Cat.3; R62 T R48/23
T; R48/23 R: 45-21/22-37/38-48/23-62 >=5%Conc<10%: T; R45; R48/20; R62
alpha,alpha,alpha,4-Tetrachlorotoluene [p- Xn; R21/22 Xi; S: 53-45 >=1%Conc<5%: T; R45; R48/20
5216-25-1 Chlorobenzotrichloride] R37/38 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Xn ; R: 22 - 48/22 , Conc>=25%: Xn; R22-48/22
5248-39-5 4-Methoxy-N,6-dimethyl-1,3,5-triazin-2-ylamine Xn; R22-48/22 S: (2) - 22 - 36 >=10%Conc<25%: Xn; R48/22 Eu - - - - - - - -

Oxycarboxin (ISO) [5,6-Dihydro-2-methyl-1,4-oxathi-

in-3-carboxanilide 4,4-dioxide; 2,3-Dihydro-6-methyl-5-Xn; R22 Xn ; R: 22 - 52/53,
5259-88-1 (N-phenylcarbamoyl)-1,4-oxathiine- 4,4-dioxide] R52-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: Xn; R21/22; R38; R41
Xn; R21/22 Xn >=20%Conc<25%: Xi; R38; R41
Xi; R38-41 R: 21/22-38-41-52/53 >=10%Conc<20%: Xi; R41
5271-27-2 1-Methyl-3-phenyl-1-piperazine R52-53 S: (2-)26-36/37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Xi; R43
This substance has only been
assessed against the single
endpoint of skin sensitisation.
This substance has not been
subject to a complete assessment
for hazard classification in
1,4-Benzenediamine, 2-nitro- [2-Nitro-4- accordance with the approved
5307-14-2 phenylenediamine] criteria Xi; R:43 Conc>=1%: Xi; R43 N - - - - - - - -
Xi; R36/38 Xi ; R: 36/38 - 52/53,
5329-14-6 Sulphamic acid [Sulfamic acid; Sulphamidic acid] R52-53 S: (2) - 26 - 28 - 61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -

1,2,3,6-Tetrahydro-3-methylphthalic anhydride(Note: Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

see also CAS No 1694-82-2; 3425-89-6; 11070-44-3; Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
5333-84-6 26590-20-5; 34090-76-1 & 42498-58-80) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -

Conc>=25%; T; R45; R68; R23/24/25; R48/25;

R43
>=10%Conc<25%; T; R45; R68; R48/25;
R20/21/22; R43
Carc. Cat. 2; R45 >=3%Conc<10%; T; R45; R68; R20/21/22;
Muta. Cat. 3; R68 R48/22; R43
T; R23/24/25-48/25 T >=1%Conc<3%; T; R45; R68; R48/22; R43
5341-61-7 Hydrazine, dihydrochloride R43 R: 45-23/24/25-43-48/25-68 >=0.1%Conc<1%; T; R45 N - - - - - - - -
Xi; R38 Xi Conc>=20%: Xi; R38; R43
5392-40-5 2,6-Octadienal, 3,7-dimethyl- [Citral] R43 R: 38-43 >=1%Conc<20%: Xi; R43 N/Eu - - - - - - - -

Page 143
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Repr. Cat. 3; R62
Xn; R48/22 Xn ; N ; R: 41 - 48/22 - 62 -
Xi; R41 51/53 Conc>=10%: Xn; R62; R48/22; R41
5406-86-0 2-(4-tert-Butylphenyl)ethanol N; R51-53 S: (2)26 - 36/37/39 - 61 >=5%Conc<10%: Xn; R62; R36 Eu - - - - - - - -

Conc>=25%: T; R23/25; R21; R36/37/38; R43

T; R23/25 >=20%Conc<25%: Xn; R20/22; R36/37/38;
Xn; R21 R43
Xi; R36/37/38 T >=3%Conc<20%: Xn; R20/22; R43
5421-46-5 Acetic acid, mercapto-, monoammonium salt R43 R: 21-23/25-36/37/38-43 >=1%Conc<3%: Xi; R43 N - - - - - - - -
Conc>=25%: T; R39/25; R48/25; R21/22; R41;
R43
T; R39-48/25 >=10%Conc<25%: T; R39/25; R48/25; R41;
Xn; R21/22 R43
Xi; R41 T ; N ; R: 21/22-39-41-43- >=5%Conc<10%: Xn; R68/22; R48/22; R36;
R43 48/25-51/53 R43
5428-02-4 2-Nitro-2-phenyl-1,3-propanediol N; R51-53 S: 53-45-61 >=1%Conc<5%: Xn; R68/22; R48/22; R43 Eu - - - - - - - -
E; R2 Conc>=25%: Xn; R40; R21/22; R48/22;
Carc. Cat. 3; R40 R36/38; R43
Xn; R21/22-48/22 E; Xn; N >=20%Conc<25%: Xn; R40; R48/22; R36/38;
Hydroxylammonium chloride [Hydroxylamine Xi; R36/38 R: 2-21/22-36/38-40-43- R43
hydrochloride](Note: see also CAS No. 10039-54-0 & R43 48/22-50 >=10%Conc<20%: Xn; R40; R48/22; R43
5470-11-1 10046-00-1) N; R50 S: (2-)36/37-61 >=1%Conc<10%: Xn; R40; R43 Eu - - - - - - - -
Xn; R21/22 Xn ; N ; R: 21/22 - 43 -
R43 51/53 Conc>=25%: Xn; R21/22; R43
5470-82-6 8-Amino-7-methylquinoline N; R51/53 S: (2)36/37 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
5521-55-1 5-Methylpyrazine-2-carboxylic acid Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
(S)-4-Hydroxy-3-(3-oxo-1-phenylbutyl)-2- Repr. Cat. 1; R61 T ; R: 61 - 48/25 - 52/53, Conc>=10%: T; R61; R48/25
benzopyrone(Note: see also CAS No 81-81-2 & 5543- T; R48/25 S: 53 - 45 - 61; >=1%Conc<10%: T; R61; R48/22
5543-57-7 58-8) R52-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
(R)-4-Hydroxy-3-(3-oxo-1-phenylbutyl)-2- Repr. Cat. 1; R61 T ; R: 61 - 48/25 - 52/53, Conc>=10%: T; R61; R48/25
benzopyrone(Note: see also CAS No 81-81-2 & 5543- T; R48/25 S: 53 - 45 - 61; >=1%Conc<10%: T; R61; R48/22
5543-58-8 57-7) R52-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
T; N
Repr. Cat. 2; R60 R: 60-48/22-51/53
Cyclic 3-(1,2-ethanediylacetale)-estra-5(10),9(11)- Xn; R48/22 S: 53-45-61 Conc>=10%: T; R60; R48/22
5571-36-8 diene-3,17-dione N; R51-53 Note: E >=0.5%Conc<10%: T; R60 Eu - - - - - - - -
Xi; N
R43 R: 43-50/53
5598-13-0 Chlorpyrifos-methyl N; R50-53 S: (2-)36/37-60-61 Conc>=1%: R43 Eu - - - - - - - -
T ; N ; R: 25 - 50/53,
Drazoxolon (ISO) [4-(2-Chlorophenylhydrazone)-3- T; R25 S: (1/2) - 22 - 24 - 36/37 - Conc>=25%: T; R25
5707-69-7 methyl-5-isoxazolone] N; R50-53 45 - 60 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Sulphur pentafluoride [Disulphur decafluoride; Sulphur 0.01 Peak 0.1 Peak
5714-22-7 Disulfur pentafluoride; Disulfur decafluoride] A pentafluoride limitation limitation - - - - -
Xn
R:22
5734-64-5 2-Amino-4-chloro-6-methoxypyrimidine Xn; R22 S:(2)22 Conc>=25%: Xn; R22 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 1; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
5743-04-4 Acetic acid, cadmium salt, dihydrate Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Conc>=7%: T+; R26/28
Brucine nitrate(Note: see also CAS No 4845-99-2, T+; R26/28 T+ ; R: 26/28 - 52/53, >=1%Conc<7%: T; R23/25
5786-97-0 68239-26-9 & 68310-42-9) R52-53 S: (1/2) - 13 - 45 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -

Page 144
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

T; R23/24/25 T; N Conc>=25%: T; R23/24/25; R33

DNOC, potassium salt of [Potassium 4,6-dinitro-o- R33 R: 23/24/25 - 33 - 50/53 >=3%Conc<25%: Xn; R20/21/22; R33
5787-96-2 cresolate](Note: see also CAS No 2312-76-7) N; R50-53 S: (1/2) - 13 - 45 - 60 - 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -
Xi ; R: 43
5788-17-0 Methyl-3-methoxyacrylate R43 S: (2)24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Phosnichlor [O-4-Chloro-3-nitrophenyl O,O-dimethyl Xn ; R: 20/21/22 ,
5826-76-6 phosphorothioate] Xn; R20/21/22 S: (2) - 13 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Conc>=25%: T+; R27; R25
IPSP >=7%Conc<25%: T+; R27; R22
T+; R27 T+; N >=3%Conc<7%: T; R24; R22
[S-Ethylsulphinylmethyl O,O- T; R25 R: 25-27-50/53 >=1%Conc<3%: T; R24
5827-05-4 diisopropylphosphorodithioate] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=0.1%Conc<1%: Xn; R21 Eu - - - - - - - -
Azothoate [O-4-(4-Chlorophenylazo)phenyl O,O- Xn ; R: 20/22 ,
5834-96-8 dimethyl phosphorothioate] Xn; R20/22 S: (2) - 13 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
T+ ; R: 27/28 - 48/24/25 - Conc>=10%: T+; R27/28; R48/24/25
T+; R27/28 52/53, >=7%Conc<10%: T+; R27/28; R48/21/22
Coumatetralyl (ISO) [4-Hydroxy-3-(1,2,3,4-tetrahydro- T; R48/24/25 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R24/25; R48/21/22
5836-29-3 1-naphthyl)coumarin] R52-53 61 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
Conc>=7%: T+; R28
T+ ; R: 28 , >=1%Conc<7%: T; R25
5836-73-7 1-(3,4-Dichlorophenylimino) thiosemicarbazide T+; R28 S: (1/2) - 22 - 36/37 - 45 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

Conc>=25%: T; R40; R23; R48/23; R36/37/38;

R42/43
>=20%Conc<25%: T; R40; R48/23; R20;
R36/37/38; R42/43
>=10%Conc<20%: T; R40; R48/23; R20;
Benzene, 1-isocyanato-2-[(4- Carc. Cat. 3; R40 R42/43
isocyanatophenyl)methyl]- [o-(p- T; R23-R48/23 T >=3%Conc<10%: Xn; R40; R20; R48/20;
Isocyanatobenzyl)phenyl isocyanate; Xi; R36/37/38 R: 23-36/37/38-40-42/43- R42/43 Isocyanates, all
5873-54-1 Diphenylmethane-2,4'-diisocyanate] R42/43 48/23 >=1%Conc<3%: Xn; R40; R48/20; R42/43 N/Eu; A (as-NCO) - 0.02 - 0.07 - Sen -
5915-41-3 Terbuthylazine Xn; R22 Xn ; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -
(1-Methylethylidene)di-4,1-phenylenetetraphenyl R: 53
5945-33-5 diphosphate R53 S: 61 Eu - - - - - - - -
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, Xi
5949-29-1 monohydrate Xi; R36/37/38 R: 36/37/38 Conc>=20%: Xi; R36/37/38 N - - - - - - - -
R10 Xi ; N ; R: 10 - 38 - 43 -
(R)-p-Mentha-1,8-diene [Dipentene; Limonene; d- Xi; R38 50/53,
Limonene](Note: see also CAS No 138-86-3 & 5989- R43 S: (2) - 24 - 37 - 60 - 61; Conc>=20%: Xi; R38; R43
5989-27-5 54-8) N; R50-53 Note: C >=1%Conc<20%: Xi; R43 Eu/N - - - - - - - -
R10 Xi ; N ; R: 10 - 38 - 43 -
(S)-p-Mentha-1,8-diene [Dipentene; Limonene; l- Xi; R38 50/53,
Limonene](Note: see also CAS No 138-86-3 & 5989- R43 S: (2) - 24 - 37 - 60 - 61; Conc>=20%: Xi; R38; R43
5989-54-8 27-5) N; R50-53 Note: C >=1%Conc<20%: Xi; R43 Eu/N - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
6018-89-9 Acetic acid, nickel(2+) salt, tetrahydrate R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
6018-92-4 nickel(2+) salt (2:3) R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi ; R: 36/37 ,
6053-68-5 Cyclopentane-1,2,3,4-tetracarboxylic dianhydride Xi; R36/37 S: (2) - 25 Conc>=1%: Xi; R36/37 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
6080-56-4 Acetic acid, lead(2+) salt, trihydrate R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Repr. Cat. 3; R62-63

Xi; R36/38 Xn Conc>=20%: Xn; R62; R63; R36/38; R42/43
Piperazine hydrochloride(Note: see also CAS No. R42/43 R: 36/38-42/43-62-63-52/53 >=5%Conc<20%: Xn; R62; R63; R42/43
6094-40-2 142-64-3, 1951-97-9) R52-53 S: (1/2-)22-36/37-45-63-61 >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, lead(2+) Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
6107-83-1 salt (2:3), trihydrate R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Carc. Cat. 3; R40 Xn ; N ; R: 21/22 - 40 -

Chlordimeform (ISO) [N2-(4-Chloro-o-tolyl)-N1,N1- Xn; R21/22 50/53, Conc>=25%: Xn; R40; R21/22
6164-98-3 dimethylformamidine] N; R50-53 S: (2) - 22 - 36/37 - 60 - 61 >=1%Conc<25%: Xn; R40 Eu - - - - - - - -
Xi
R43 R: 43-53
6195-20-6 Dodecyl 3-amino-4-chlorobenzoate R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
E; Xn
E; R2 R: 2-20/21/22
6202-15-9 1,2,3,4-Tetranitrocarbazole Xn; R20/21/22 S: (2-)35-36/37 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Xi Conc>=20%: Xi; R38; R41
2-Cyclopentylidene cyclopentanol [1,1'- Xi; R38-41 R: 38-41-52/53 >=10%Conc<20%: Xi; R41
6261-30-9 Bi(cyclopentyliden)-2-ol] R52-53 S: (2-)26-37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Conc>=25%: T+; R26; R25; R34; R43

>=10%Conc<25%: T+; R26; R34; R22; R43
T+; R26 >=7%Conc<10%: T+; R26; R22; R36/38; R43
T; R25 T+ ; N ; R: 25 - 26 - 34 - 43 - >=5%Conc<7%: T; R23; R22; R36/38; R43
C; R34 50, >=3%Conc<5%: T; R23; R22; R43
Methylene dithiocyanate [Thiocyanic acid, methylene R43 S: (1/2) - 26 - 28 - 36/37/39 - >=1%Conc<3%: T; R23; R43
6317-18-6 ester] N; R50 45 - 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
Xn; R22-48/22 Xn; N Conc>=25%: Xn; R22; R48/22; R43
R43 R: 22-43-48/22-50/53 >=10%Conc<25%: Xn; R48/22; R43
6364-17-6 2,3-Dihydro-2,2-dimethyl-1H-perimidine N; R50-53 S: (2-)28-36/37-60-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
T; R25
2-Methyl-p-phenylenediamine sulphate [2,5- Xn; R20/21 T ; N ; R: 25 - 20/21 - 43 - Conc>=25%: T; R25; R20/21; R43
Toluenediamine sulfate](Note: see also CAS No 615- R43 51/53, >=3%Conc<25%: Xn; R22; R43
6369-59-1 50-9) N; R51-53 S: (1/2) - 24 - 37 - 45 - 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Methyl 3-(3-tert-butyl-4-hydroxy-5- Xn; R22 Xn ; N ; R: 22 - 51/53 ,
6386-39-6 methylphenyl)propionate N; R51-53 S: (2) - 36 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
R: 53
6390-69-8 3,3',5,5'-Tetra-tert-butylbiphenyl-2,2'-diol R 53 S: 61 Eu - - - - - - - -
Conc>=10%: T+; R26; R41; R43
>=7%Conc<10%: T+; R26; R36; R43
T+; R26 >=5%Conc<7%: T; R23; R36; R43
1H-Pyrrole-2,5-dione, 1,1'-(4-methyl-1,3- Xi; R41 T+ >=1%Conc<5%: T; R23; R43
6422-83-9 phenylene)bis- R43 R: 26-41-43 >=0.1%Conc<1%: Xn; R20 N - - - - - - - -
Propylene glycol
6423-43-4 Propylene glycol dinitrate A dinitrate 0.05 0.34 - - - Sk -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
6427-86-7 Hexadecanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Xi
6484-52-2 Nitric acid, ammonium salt Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
Xi
Xi; R36 R: 36-43 Conc>=20%: Xi; R36; R43
6485-67-2 (2R)-2-Amino-2-phenylacetamide R43 S: (2-)22-26-36/37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Disodium 5-((4-((4-chloro-3-sulfonatophenyl)azo)-1-
naphthyl)azo)-8-(phenylamino)-1- R: 52/53
6527-62-4 naphthalenesulfonate R 52-53 S: 61 Eu - - - - - - - -
Xi
R43 R: 43-52/53
6563-83-3 (6beta)-6,19-Epoxyandrost-4-ene-3,17-dione R52-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=10%: C; R34; R43
C; R34 C ; R: 34 - 43 >=5%Conc<10%: Xi; R36/38; R43
6613-44-1 3,5-Dimethylbenzoyl chloride R43 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
F; R11
R4 F; Xi Conc>=20%: Xi; R38; R41
Xi; R38-41 R: 4-11-38-41-52/53 >=10%Conc<20%: Xi; R41
6746-94-7 Ethynyl cyclopropane R52-53 S: (2-)9-16-26-33-37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn
R: 22
6777-05-5 1-Benzylimidazolidine-2,4-dione Xn; R22 S: (2-)22 Conc>=25%: Xn; R22 Eu - - - - - - - -
Carbadox (INN) [Methyl 3-(quinoxalin-2-
ylmethylene)carbazate 1,4-dioxide; 2- F; R11 F ; T ; R: 45 - 11 - 22 ,
(Methoxycarbonylhydrazonomethyl)quinoxaline 1,4- Carc. Cat. 2; R45 S: 53 - 45 ; Conc>=25%: T; R45; R22
6804-07-5 dioxide] Xn; R22 Note: E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
Xi; R36. Xi ; N ; R: 36 - 50/53 ,
6807-17-6 4,4'-Isobutylethylidenediphenol N; R50-53 S: (2) - 26 - 60 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
C ; R: 34 - 37 , Conc>=20%: C; R34; R37
C; R34 S: (1/2) - 13 - 24/25 - >=10%Conc<20%: C; R34
6834-92-0 Disodium metasilicate Xi; R37 36/37/39 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
6838-85-3 1,2-Benzenedicarboxylic acid, lead(2+) salt (1:1) R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Conc>=25%: T; R23/24; R35; R22
T; R23/24 T ; C ; N ; R: 22 - 23/24 - 35 - >=10%Conc<25%: C; R35; R20/21
Xn; R22 51/53, >=5%Conc<10%: C; R34; R20/21
2,2'-Dimethyl-4,4'-methylenebis(cyclohexylamine) C; R35 S: (1/2) - 26 - 36/37/39 - 45 - >=3%Conc<5%: Xn; R20/21; R36/38
6864-37-5 [Cyclohexanamine, 4,4'-methylenebis[2-methyl] N; R51-53 61 >=1%Conc<3%: Xi; R36/38 Eu - - - - - - - -
Conc>=25 %: Xn; R22; R38; R41
Xn; R22 Xn >=20%Conc<25%: Xi; R38; R41
Xi; R38-41 R: 22-38-41-52/53 >=10%Conc<20%: Xi; R41
6903-18-0 3-(2'-Phenoxyethoxy)propylamine R52-53 S: (2-)23-26-37/39-61 >=5%Conc<10 %: Xi; R36 Eu - - - - - - - -
R: 52/53
6914-71-2 Dimethylcyclopropane-1,1-dicarboxylate R 52-53 S: 61 Eu - - - - - - - -
Conc>=25%: T+; R68; R26/28; R24
Muta. Cat. 3; R68 T+ ; N ; R: 24 - 26/28 - >=7%Conc<25%: T+; R68; R26/28; R21
T+; R26/28 50/53 - 68 , >=3%Conc<7%: T; R68; R23/25; R21
Dimethyl-1-methyl-2-(methylcarbamoyl)vinyl T; R24 S: (1/2) - 23 - 36/37 - 45 - >=1%Conc<3%: T; R68; R23/25
6923-22-4 phosphate [Monocrotophos (ISO)] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu; A Monocrotophos - 0.25 - - - - -
Dioxacarb (ISO) [2-(1,3-Dioxolan-2-yl)phenyl N- T; R25 T ; N ; R: 25 - 51/53, Conc>=25%: T; R25
6988-21-2 methylcarbamate] N; R51-53 S: (1/2) - 37 - 45 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -

Page 147
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R22-48/22 Xn ; R: 22 - 43 - 48/22 - Conc>=25%: Xn; R22; R48/22; R43
R43 52/53 >=10%Conc<25%: Xn; R48/22; R43
7027-11-4 3-Cyano-3,5,5-trimethylcyclohexanone R52-53 S: (2)36/37 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -

Xn; N Tin, organic

Butyltricyclohexylstanne (Note: see also CAS No. Xn; R20/21/22 R: 20/21/22-50/53 compounds (as
7067-44-9 1449-55-4 and 3091-32-5) N; R50-53 S: (2-)26-28-60-61; Note: A Conc>=1%: Xn; R20/21/22 Eu; A Sn) - 0.1 - 0.2 - Sk -
2,2-Dichlorovinyl 2-ethylsulphinylethyl methyl T ; R: 23/24/25 , Conc>=25%: T; R23/24/25
7076-53-1 phosphate T; R23/24/25 S: (1/2) - 13 - 45 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
Xi
2,6-Bis(1,1-dimethylethyl)-4- R43 R: 43-53
7078-98-0 (phenylenemethylene)cyclohexa-2,5-dien-1-one R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25 %: Xn; R22; R38; R41
Mecoprop (ISO) and its salts [2-(4-Chloro-o-tolyloxy) Xn; R22 Xn; N >=20%Conc<25%: Xi; R38; R41
propionic acid; (RS)-2-(4-Chloro-o-tolyloxy)propionic Xi; R38-41 R: 22-38-41-50/53 >=10%Conc<20%: Xi; R41
7085-19-0 acid](Note: see also CAS No. 93-65-2) N; R50-53 S: (2-)13-26-37/39-60-61 >=5%Conc<10 %: Xi; R36 Eu - - - - - - - -
Xi ; R: 36/37/38,
7085-85-0 Ethyl 2-cyanoacrylate Xi; R36/37/38 S: (2) - 23 - 24/25 - 26 Conc>=10%: Xi; R36/37/38 Eu - - - - - - - -
R: 53
7093-55-2 Pregn-5-ene-3,20-dione bis(ethylene ketal) R 53 S: 61 Eu - - - - - - - -
Conc>=25%: C; R34; R22
Xn; R22 C ; R: 22 - 34, >=10%Conc<25%: C; R34
7173-51-5 Didecyidimethylammonium chloride C; R34 S: (2) - 26 - 36/37 - 38 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Repr. Cat. 3; R62 Xn Conc>=25%: Xn; R62; R22; R41
Tetrahydro-1,3-dimethyl-1H-pyrimidin-2-one Xn; R22 R: 22-41-62 >=10%Conc<25%: Xn; R62; R41
7226-23-5 [Dimethyl propyleneurea] Xi; R41 S: 26-36/37/39 >=5%Conc<10%: Xn; R62; R36 Eu - - - - - - - -
Tris(1-dodecyl-3-methyl-2- Xn ; R: 22 ,
7276-58-6 phenylbenzimidazolium)hexacyanoferrate Xn; R22 S: (2) - 24 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; N
Xn; R22-48/22 R: 22-48/22-50/53 Conc>=25%: Xn; R22; R48/22
7305-71-7 2-Amino-5-methylthiazole N; R50-53 S: (2-)22-36-60-61 >=10%Conc<25%: Xn; R48/22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
7319-86-0 Octanoic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xi
R: 43
7331-52-4 (S)-3-Hydroxy-gamma-butyrolactone R43 S: (2-)23-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
F; R17 F; C
Xn; R20/21/22-48/22 R: 17-20/21/22-34-43-48/22- Conc>=25%: C; R34; R20/21/22; R48/22; R43
C; R34 53 >=10%Conc<25%: C; R34; R48/22; R43
R43 S: (1/2-)6-26-36/37/39-43-45- >=5%Conc<10%: Xi; R36/38; R43
7397-46-8 Diethylmethoxyborane R53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Morfamquat (ISO) [1,1'-Bis(3,5- Xn; R22 Xn ; R: 22 - 36/37/38 -
dimethylmorpholinocarbonylmethyl)-4,4'-bipyridilium Xi; 36/37/38 52/53, Conc>=25%: Xn; R22; R36/37/38
7411-47-4 ion] R52-53 S: (2) - 22 - 36 - 61 >=20%Conc<25%: Xi; R36/37/38 Eu - - - - - - - -
Phosphonic acid, (1-hydroxyethylidene)bis-, disodium Xn; R22 Xn Conc>=25%: Xn; R22; R36
7414-83-7 salt Xi; R36 R: 22-36 >=20%Conc<25%: Xi; R36 N - - - - - - - -
Xn
R: 63
7425-14-1 2-Ethylhexyl-2-ethylhexanoate Repr. Cat. 3; R63 S: (2-)36/37 Conc>=5%: Xn; R63 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
7428-48-0 Octadecanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
F ; R: 15 - 17 Aluminium (metal
7429-90-5 Aluminium (metal dust)(elemental) F; R15-17 S: (2) - 7/8 - 43 Eu; A dust) - 10 - - - - -
Aluminium
F ; R: 15 - 17 (welding fumes)
7429-90-5 Aluminium (welding fumes) F; R15-17 S: (2) - 7/8 - 43 A (as Al) - 5 - - - - -

Page 148
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F; R15 - 17,
7429-90-5 Aluminium powder (pyrophoric) F; R15-17 S: (2) - 7/8 - 43 Eu; A - - - - - - - -
F
R: 11-15
7429-90-5 Aluminium powder (stabilised) F; R11-15 S: (2-)7/8-43 Eu - - - - - - - -
F ; R: 15 - 17 Aluminium, pyro
7429-90-5 Aluminium pyro powders F; R15-17 S: (2) - 7/8 - 43 Eu; A powders (as Al) - 5 - - - - -
Lead, inorganic
dusts & fumes (as
7439-92-1 Lead, inorganic dusts & fumes (as Pb) A Pb) - 0.15 - - - - -
F; R14/15 F ; C ; R: 14/15 - 34 , Conc>=10%: C; R34
7439-93-2 Lithium C; R34 S: (1/2) - 8 - 43 - 45 >=5%Conc<10% Xi; R36/38 Eu - - - - - - - -
F; R15 - 17,
7439-95-4 Magnesium powder (pyrophoric) F; R15-17 S: (2) - 7/8 - 43 Eu - - - - - - - -

Manganese, dust
& compounds (as
7439-96-5 Manganese dust and compounds (as Mn) A Mn) - 1 - - - - -
Manganese, fume
7439-96-5 Manganese dust and compounds (as Mn) A (as Mn) - 1 - 3 - - -
Conc>=10%: T+; R61; R26; R48/23
Repr. Cat. 2; R61 T+; N >=7%Conc<10%: T+; R61; R26; R48/20
T+; R26 R: 61-26-48/23-50/53 >=1%Conc<7%: T; R61; R23; R48/20
T; R48/23 S: 53-45-60-61 >=0.5%Conc<1%: T; R61; R20 Mercury, elemental
7439-97-6 Mercury N; R50-53 Note: E >=0.1%Conc<0.5%; Xn; R20 Eu;A vapour (as Hg) 0.003 0.025 - - - - -
Molybdenum,
soluble
compounds (as
7439-98-7 Molybdenum, soluble compounds (as Mo) A Mo) - 5 - - - - -
Molybdenum,
insoluble
compounds (as
7439-98-7 Molybdenum [insoluble compounds (as Mo)] A Mo) - 10 - - - - -
Carc. Cat. 3; R40
T; R48/23 T
R43 R: 40-43-48/23-52/53 Conc>=10%: T; R40; R48/23; R43
7440-02-0 Nickel powder(Note: particle diameter < 1 mm) R52-53 S: (2-)36/37/39-45-61 >=1%Conc<10%: Xn; R40; R48/20; R43 Eu;A Nickel, metal - 1 - - - Sen -
Carc. Cat. 3; R40 T
T; R48/23 R: 40-43-48/23 Conc>=10%: T; R40; R48/23; R43
7440-02-0 Nickel R43 S: (2-)36/37/39-45 >=1%Conc<10%: Xn; R40; R48/20; R43 Eu;A Nickel, metal - 1 - - - Sen -
7440-06-4 Platinum, metal A Platinum, metal - 1 - - - - -
F ; C ; R: 14/15 - 34
S: (1/2) – 5* - 8 – 45
*S5 is not necessary when
F; R14/15 an alternative safe Conc>=10%: C; R34
7440-09-7 Potassium C; R34 packaging is used >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Rhodium, metal [Rhodium,insoluble compounds (as
7440-16-6 Rh)] A Rhodium, metal - 1 - - - - -

Rhodium, insoluble
Rhodium, metal [Rhodium,insoluble compounds (as compounds (as
7440-16-6 Rh)] A Rh) - 1 - - - - -
7440-22-4 Silver, metal A Silver, metal - 0.1 - - - - -

F ; C ; R: 14/15 - 34 ,
S: (1/2) - 5* - 8 - 43 – 45
*S5 is not necessary when
F; R14/15 an alternative safe Conc>=10%: C; R34
7440-23-5 Sodium C; R34 packaging is used >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Tantalum, metal &
7440-25-7 Tantalum, metal & oxide dusts A oxide dusts - 5 - - - - -

Page 149
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

T+; R26/28 T+ Conc>=7%: T+; R26/28; R33

R33 R: 26/28 - 33 - 53 >=1%Conc<7%: T; R23/25; R33 Thallium, soluble
7440-28-0 Thallium R53 S: (1/2) - 13 - 28 - 45 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu compounds (as Tl) - 0.1 - - - Sk -
Tin metal [Tin, oxide &amp; inorganic compounds,
7440-31-5 except SnH4] A Tin, metal - 2 - - - - -
Tin, oxide &
inorganic
compounds,
Tin metal [Tin, oxide &amp; inorganic compounds, except SnH4 (as
7440-31-5 except SnH4] A Sn) - 2 - - - - -

Tungsten,
insoluble
7440-33-7 Tungsten, insoluble compounds (as W) A compounds (as W) - 5 - 10 - - -

Tungsten, soluble
7440-33-7 Tungsten, soluble compounds (as W) A compounds (as W) - 1 - 3 - - -
Antimony &
compounds (as
7440-36-0 Antimony & compounds (as Sb) A Sb) - 0.5 - - - - -

T; N Arsenic & soluble

T; R23/25 R: 23/25-50/53 Conc>=25%: T; R23/25 compounds (as
7440-38-2 Arsenic N; R50-53 S: (1/2-)20/21-28-45-60-61 >=3%Conc<25%: Xn; R20/22 Eu; A As) - 0.05 - - 1 - -

Arsenic & soluble

compounds (as
7440-38-2 Arsenic and soluble compounds (as As) A As) - 0.05 - - 1 - -
Conc>=25%: T; R45; R68; R23/25;
R48/20/21/22
Carc. Cat. 1; R45 >=10%Conc<25%: T; R45; R68; R20/22;
Muta. Cat. 3; R68 R48/20/21/22
T; R23/25 T; N >=3%Conc<10%: T; R45; R68; R20/22 Arsenic & soluble
Xn; R48/20/21/22 R: 45-23/25-48/20/21/22-68- >=1%Conc<3%: T; R45; R68 compounds (as
7440-38-2 Arsenic N; R50-53 50-53 >=0.1%Conc<1%: T; R45 N/Eu; A As) - 0.05 - - 1 - -
Barium, soluble
compounds (as
7440-39-3 Barium soluble compounds (as Ba) A Ba) - 0.5 - - - - -

Conc>=25%: T+; R49; R26; R25-48/23;

R36/37/38; R43
>=20%Conc<25%: T+; R49; R26; R22; R48/23;
R36/37/38; R43
>=10%Conc<20%: T+; R49; R26; R22; R48/23;
R43
Carc. Cat. 2; R49 >=7%Conc<10%: T+; R49; R26; R22-48/20;
T+; R26 T+ ; R: 49 - 25 - 26 - R43
T; R25-48/23 36/37/38 - 43 - 48/23 , >=3%Conc<7%: T; R49; R23; R22-48/20; R43
Xi; R36/37/38 S: 53 - 45 ; >=1%Conc<3%: T; R49; R23; R48/20; R43 Beryllium &
7440-41-7 Beryllium R43 Note: E >=0.1%Conc<1%: T; R49; R20 Eu; A compounds - 0.002 - - 2 - -

Conc>=10%: T+; R45; R68; R62-63; R26;

R48/23/25
Carc. Cat. 2; R45 >=7%Conc<10%: T+; R45; R68; R62-63; R26;
Muta. Cat. 3; R68 R48/20/22
Repr. Cat. 3; R62-63 T+; N >=5%Conc<7%: T; R45; R68; R62-63; R23;
T+; R26 R: 45-26-48/23/25-62- R48/20/22 Cadmium and
Cadmium (non-pyrophoric) (Note: see also CAS No. T; R48/23/25 63-68-50/53 >=1%Conc<5%: T; R45; R68; R23; R48/20/22 compounds (as
7440-43-9 1306-19-0) N; R50-53 S: 53-45-60-61; Note: E >=0.1%Conc<1%: T; R45; R20 Eu; A Cd) - 0.01 - - 2 - -

Page 150
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=10%: T+; R45; R68; R62-63; R26;

Carc. Cat. 2; R45 R48/23/25
Muta. Cat. 3; R68 >=7%Conc<10%: T+; R45; R68; R62-63; R26;
Repr. Cat. 3; R62-63 F; T+; N R48/20/22
T+; R26 R: 45-17-26-48/23/25- >=5%Conc<7%: T; R45; R68; R62-63; R23;
T; R48/23/25 62-63-68-50/53 R48/20/22 Cadmium and
F; R17 S: 53-45-7/8-43-60-61; Note: >=1%Conc<5%: T; R45; R68; R23; R48/20/22 compounds (as
7440-43-9 Cadmium (pyrophoric) N; R50-53 E >=0.1%Conc<1%: T; R45; R20 Eu; A Cd) - 0.01 - - 2 - -
Cadmium and
compounds (as
7440-43-9 Cadmium A Cd) - 0.01 - - 2 - -

7440-47-3 Chromium metal A Chromium (metal) - 0.5 - - - - -

Xn
R42/43 R: 42/43 - 53 Cobalt, metal dust
7440-48-4 Cobalt (incl metal dust & fume as Co) R53 S: (2) - 22 - 24 - 37 - 61 Conc>=1%: Xn; R42/43 Eu; A & fume (as Co) (h) - 0.05 - - - Sen -
Copper, dusts &
7440-50-8 Copper (dust & mist) (as Cu) [Copper (fume)] A mists (as Cu) - 1 - - - - -
7440-50-8 Copper (dust & mist) (as Cu) [Copper (fume)] A Copper (fume) - 0.2 - - - - -
7440-58-6 Hafnium A Hafnium - 0.5 - - - - -

T+; R26/28 T+ Conc>=7%: T+; R26/28; R33 Uranium (natural),

R33 R: 26/28 - 33 - 53 >=1%Conc<7%: T; R23/25; R33 soluble & insoluble
7440-61-1 Uranium R53 S: (1/2) - 20/21 - 45 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu; A compounds (as H) - 0.2 - 0.6 - - -

Yttrium, metal &

7440-65-5 Yttrium, metal and compounds (as Y) A compounds (as Y) - 1 - - - - -
F; N
F; R15-17 R: 15-17-50/53
7440-66-6 Zinc powder - zinc dust (pyrophoric) N; R50-53 S: (2-)43-46-60-61 Eu - - - - - - - -
N
R: 50/53
7440-66-6 Zinc powder - zinc dust (stabilized) N; R50-53 S: 60-61 Eu - - - - - - - -

F; R15 - 17, Zirconium

7440-67-7 Zirconium powder (pyrophoric) F; R15-17 S: (2) - 7/8 - 43 Eu compounds (as Zr) - 5 - 10 - - -
F; R15,
7440-70-2 Calcium F; R15 S: (2) - 8 - 24/25 - 43 Eu - - - - - - - -

Indium &
7440-74-6 Indium & compounds (as In) A compounds (as In) - 0.1 - - - - -
Xn ; R: 20 ,
trans-2-Methylcyclohexanol(Note: see also CAS No S: (2) - 24/25;
7443-52-9 583-59-5 & 7443-70-1) Xn; R20 Note: C Conc>=25%: Xn; R20 Eu - - - - - - - -
Xn ; R: 20 ,
cis-2-Methylcyclohexanol(Note: see also CAS No 583- S: (2) - 24/25;
7443-70-1 59-5 & 7443-52-9) Xn; R20 Note: C Conc>=25%: Xn; R20 Eu - - - - - - - -
T
R: 23 - 34 Conc>=20%: T; R23; R34
T; R23 S: (1/2) - 9 - 26 - 36/37/39 - >=5%Conc<20%: C; R20; R34
7446-09-5 Sulfur dioxide [Sulphur dioxide] C; R34 45 >=0.5%Conc<5%: Xi; R36/37/38 Eu; A Sulphur dioxide 2 5.2 5 13 - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
7446-14-2 Sulfuric acid, lead(2+) salt (1:1) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -

Page 151
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=20%: T+; R28; R48/25; R38
T+; R28 T+ ; N ; R: 28 - 38 - 48/25 - >=10%Conc<20%: T+; R28, R48/25
T; R48/25 51/53, >=7%Conc<10%: T+; R28; R48/22
Xi; R38 S: (1/2) - 13 - 36/37 - 45 - >=1%Conc<7%: T; R25; R48/22
7446-18-6 Dithallium sulphate [Thallic sulphate] N; R51-53 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

Xn; R22 Xn; N Conc>=25%: Xn; R22; R41

Zinc sulphate (hydrous) (mono-, hexa- and hepta R41 R: 22-41-50/53 >=10%Conc<25%: Xi; R41
7446-19-7 hydrate) (Note: see also CAS No. 7733-02-0) N; R50-53 S: (2-)22-26-39-46-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc>=10%: T; R40; R61; R62; R68;
Xn; R48/22 T; N R33
Phosphoric acid, lead(2+) salt (2:3) [Trilead- R33 R: 61-33-40-48/22-62-68-50- >=1%Conc>=5%: T; R40; R61; R68; R33
7446-27-7 bis(orthophosphate)] N; R50-53 53 >=0.5%Conc>=1%: T; R61 N/Eu - - - - - - - -
C ; R: 34 , Conc>=10%: C; R34
7446-70-0 Aluminium chloride, anhydrous C; R34 S: (1/2) - 7/8 - 28 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
E; R3
F; R11 E; Xn; N
Xn; R48/22 R: 3-11-48/22-50/53
7456-68-0 4,4'-Oxybis(benzenesulfonylazide) N; R50-53 S: (2-)14-22-33-35-36-60-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Xi; R41 Xi Conc>=10%: Xi; R41; R43
R43 R: 41-43-52/53 >=5%Conc<10%: Xi; R36; R43
7480-35-5 cis-1-Amino-2,3-dihydro-1H-inden-2-ol R52-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Conc>=10%: T+; R62; R68; R28; R48/24/25;

R34
Muta. Cat. 3; R68 >=7%Conc<10%: T+; R62; R68; R28;
Repr. Cat. 3; R62 T+; N R48/21/22; R36/38
T+; R28 R: 28-34-48/24/25-62-68- >=5%Conc<7%: T; R62; R68; R25; R48/21/22; Mercury, inorganic
T; R48/24/25 50/53 R36/38 divalent
C; R34 S: (1/2-)26-36/37/39-45-60- >=1%Conc<5%: T; R68; R25; R48/21/22 compounds (as
7487-94-7 Mercury dichloride [Mercuric chloride] N; R50-53 61 >=0.1%Conc<1%: Xn; R22 Eu;A Hg) 0.003 0.025 - - - - -
C ; R: 14 - 34 ,
R14 S: (1/2) - 7/8 - 26 - Conc>=10%: C; R34
7550-45-0 Titanium tetrachloride C; R34 36/37/39 - 45 >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -
Xn; R20/21 Xn ; N ; R: 20/21 - 50, 0.1 Peak 1 Peak
7553-56-2 Iodine N; R50 S: (2) - 23 - 25 - 61 Conc>=25%: Xn; R20/21 Eu; A Iodine limitation limitation - - - - -
E; R2
Carc. Cat. 3; R40 E ; Xn ; R: 2 - 40 - 48/20 , Conc>=10%: Xn; R40; R48/20 0.1 Peak 0.39 Peak
7572-29-4 Dichloroacetylene Xn; R48/20 S: (2) - 36/37 >=1%Conc<10%: Xn; R40 Eu; A Dichloroacetylene limitation limitation - - 3 - -

Conc>=25%: T; R49; R61; R62; R68; R48/23;

Carc. Cat. 1; R49 R20/22; R38; R42/43
Muta. Cat. 3; R68 >=20%Conc<25%: T; R49; R61; R62; R68;
Repr. Cat. 2; R61 R48/23; R38; R42/43
Repr. Cat. 3; R62 >=10%Conc<20%: T; R49; R61; R62; R68;
T; R48/23 R48/23; R42/43
Xn; R20/22 T >=5%Conc<10%: T; R49; R61; R62; R68;
Xi; R38 R: 49-61-20/22-38-42/43- R48/20; R42/43
7580-31-6 Hexanoic acid, 2-ethyl-, nickel salt R42/43 48/23-62-68 >=1%Conc<5%: T; R49; R61; R68; N - - - - - - - -
7580-67-8 Lithium hydride A Lithium hydride - 0.025 - - - - -

R14 F ; C ; N ; R: 14 - 17 - 34 -
F; R17 50/53
C; R34 S: (1/2) - 6 - 16 - 26 - Conc>=10%: C; R34
7585-14-0 Di-n-octylaluminium iodide N; R50-53 36/37/39 - 43 - 45 - 60 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
O; R9 O ; Xn ; R: 9 - 22 ,
7601-89-0 Sodium perchlorate Xn; R22 S: (2) - 13 - 22 - 27 Conc>=25%: Xn; R22 Eu - - - - - - - -

R5 O ; C ; R: 5 - 8 - 35 , Conc>=50%: C; R35
O; R8 S: (1/2) - 23 - 26 - 36 - 45 ; >=10%Conc<50%: C; R34
7601-90-3 Perchloric acid ... % C; R35 Note: B >=1%Conc<10%: Xi; R36/38 Eu - - - - - - - -

7616-94-6 Perchloryl fluoride A Perchloryl fluoride 3 13 6 25 - - -

Page 152
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R45; R63; R68; R23/25; R21;

R48/20/21/22
>=10%Conc<25%: T; R45; R63; R68; R20/22;
Carc. Cat. 1; R45 R48/20/21/22
Muta. Cat. 3; R68 >=5%Conc<10%: T; R45; R63; R68; R20/22
Repr. Cat. 3; R63 T >=3%Conc<5%: T; R45; R68; R20/22
T; R23/25 R: 45-21-23/25-48/20/21/22- >=1%Conc<3%: T; R45; R68
7631-89-2 Arsenic acid (H3AsO4), sodium salt Xn; R21-48/20/21/22 63-68 >=0.1%Conc<1%: T; R45 N - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
Sulfurous acid, monosodium salt [Sodium R31 Xn >=10%Conc<25%: Xi; R41
7631-90-5 hydrogensulphite ….%; Sodium bisulphite….%] Xi; R41 R: 22-31-41 >=5%Conc<10%: Xi; R36 N; A Sodium bisulphite - 5 - - - - -
O; R8
T; R25 O ; T ; N ; R: 8 - 25 - 50, Conc>=5%: T; R25
7632-00-0 Sodium nitrite N; R50 S: (1/2) - 45 - 61 >=1%Conc<5%: Xn; R22 Eu - - - - - - - -
Conc>=25%: T; R61; R62; R22; R37; R41
Sodium peroxometaborate [Sodium O; R8 >=22%Conc<25%: T; R61; R62; R37; R41
peroxoborate](Note: containing < 0.1 % (w/w) of Repr. Cat. 2; R61 O; T >=20%Conc<22%: T; R61; R62; R36/37
particles with an aerodynamic diameter of below 50 Repr. Cat. 3; R62 R: 61-8-22-37-41-62 >=14%Conc<20%: T; R61; R62; R36
micrometres. See also CAS No. 15120-21-5, 11138- Xn; R22 S: 53-45 >=9%Conc<14%: T; R61; R62
7632-04-4 47-9, 12040-72-1 & 10332-33-9) Xi; R37-41 Note: E >=6.5%Conc<9%: T; R61 Eu - - - - - - - -

Conc>=25%: T; R61; R62; R23; R22; R37; R41

>=22%Conc<25%: T; R61; R62; R20; R37;
O; R8 R41
Sodium peroxometaborate [Sodium Repr. Cat. 2; R61 >=20%Conc<22%: T; R61; R62; R20; R36/37
peroxoborate](Note: containing >= 0.1 % (w/w) of Repr. Cat. 3; R62 O; T >=14%Conc<20%: T; R61; R62; R20; R36
particles with an aerodynamic diameter of below 50 T; R23 R: 61-8-22-23-37-41-62 >=9%Conc<14%: T; R61; R62; R20
micrometres. See also CAS No. 15120-21-5, 11138- Xn; R22 S: 53-45 >=6.5%Conc<9%: T; R61; R20
7632-04-4 47-9, 12040-72-1 & 10332-33-9) Xi; R37-41 Note: E >=3%Conc<6.5%: Xn; R20 Eu - - - - - - - -
R14 T+ ; C ; R: 14 - 26 - 35, Conc>=1%: T+; R26; R35
T+; R26 S: (1/2) - 9 - 26 - 28 - >=0.2%Conc<1%: T; R23; R34 1 Peak 2.8 Peak
7637-07-2 Boron trifluoride [Trifluoroborane] C; R35 36/37/39 - 45 >=0.02%Conc<0.2%: Xn; R20; R37 Eu; A Boron trifluoride limitation limitation - - - - -
F; R15
7646-69-7 Sodium hydride F; R15 S: (2) - 7/8 - 24/25 - 43 Eu - - - - - - - -
Tin, oxide &
inorganic
C compounds,
C; R34 R: 34-52/53 Conc>=10%: C; R34 except SnH4 (as
7646-78-8 Stannic chloride [Tin tetrachloride] R52-53 S: (1/2-)7/8-26-45-61 >=5%Conc<10 %: Xi; R36/37/38 Eu; A Sn) - 2 - - - - -
Carc. Cat. 2; R49
Muta. Cat. 3; R68
Repr. Cat. 2; R60 T; N Conc>=25%: T; R49; R60; R68; R22; R42/43
Xn; R22 R: 49-60-22-42/43-68-50/53 >=1%Conc<25%: T; R49; R60; R68; R42/43
R42/43 S: 53-45-60-61 >=0.5%Conc<1%: T; R49; R60
7646-79-9 Cobalt dichloride N; R50-53 Note: E >=0.01%Conc<0.5%: T; R49 Eu - - - - - - - -
C; N
Xn; R22 R: 22-34-50/53 Conc>=25%: C; R34; R22
C; R34 S: (1/2-)26-36/37/39-45-60- >=10%Conc<25%: C; R34 Zinc chloride
7646-85-7 Zinc chloride N; R50-53 61 >=5%Conc<10%: Xi; R36/37/38 Eu; A (fume) - 1 - 2 - - -
Conc>=20%: C; R34, R37
C; R34. C ; R: 34 - 37 , >=10%Conc<20%: C; R34
7646-93-7 Potassium hydrogensulphate Xi; R37 S: (1/2) - 26 - 36/37/39 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Conc>=5%:T; R23, R35
>=1%Conc<5%: C; R35; R20
T ; C ; R: 23 - 35 , >=0.5%Conc<1%: C; R34; R20
C; R35 S: (1/2) - 9 - 26 - 36/37/39 - >=0.2%Conc<0.5%: C; R34 5 Peak 7.5 Peak
7647-01-0 Hydrogen chloride T; R23 45 >=0.02%Conc<0.2%: Xi; R36/37/38 Eu; A Hydrogen chloride limitation limitation - - - - -
C; N Antimony &
C; R34 R: 34-51/53 Conc>=10%: C; R34 compounds (as
7647-18-9 Antimony pentachloride N; R51-53 S: (1/2-)26-45-61 >=5%Conc<10%: Xi; R36/37/38 Eu; A Sb) - 0.5 - - - - -

Page 153
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
C ; R: 34 ,
S: (1/2) - 26 - 45 ; Conc>=25%: C; R34
7664-38-2 Orthophosphoric acid ... % [Phosphoric acid ... %] C; R34 Note: B >=10%Conc<25%: Xi; R36/38 Eu; A Phosphoric acid - 1 - 3 - - -
T+ ; C ; R: 26/27/28 - 35
S: (1/2) - 7/9 - 26 - 36/37 - Conc>=7%: T+; R26/27/28; R35
T+; R26/27/28 45 >=1%Conc<7%: T; R23/24/25; R34 Hydrogen fluoride 3 Peak 2.6 Peak
7664-39-3 Hydrofluoric acid % C;R35 Note: B >=0.1%Conc<1%: Xn; R20/21/22; R36/37/38 Eu; A (as F) limitation limitation - - - - -

T+ ; C ; R: 26/27/28 - 35, Conc>=7%: T+; R26/27/28; R35

T+; R26/27/28 S: (1/2) - 7/9 - 26 - 36/37 - >=1%Conc<7%: T; R23/24/25; R34 Hydrogen fluoride 3 Peak 2.6 Peak
7664-39-3 Hydrogen fluoride C; R35 39 - 45 >=0.1%Conc<1%: Xn; R20/21/22; R36/37/38 Eu/N; A (as F) limitation limitation - - - - -
R10 T; N
T; R23 R: 10-23-34-50
C; R34 S: (1/2-)9-16-26-36/37/39-45- Conc>= 5%: T; R23; R34
7664-41-7 Ammonia, anhydrous N; R50 61 >=0.5%Conc<5%:Xn; R20; R36/37/38 Eu; A Ammonia 25 17 35 24 - - -
C ; R: 35 ,
S: (1/2) - 26 - 30 - 45; Conc>=15%: C; R35
7664-93-9 Sulphuric acid ... % [Sulfuric acid ... %] C; R35 Note: B >=5%Conc<15%: Xi; R36/38 Eu; A Sulphuric acid - 1 - 3 - - -
Sodium hydrogensulphate [Sodium bisulphate](Note:
UN2837 only refers to the aqueous solution of this Xi ; R: 41, Conc>=10%: Xi; R41
7681-38-1 salt.) Xi; R41 S: (2) - 24 - 26 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T; R25 Conc>=25%: T; R25, R36/38; R32
Xi; R36/38 T ; R: 25 - 32 - 36/38 , >=20%Conc<25%: Xn; R22, R36/38; R32
7681-49-4 Sodium fluoride R32 S: (1/2) - 22 - 36 - 45 >=3%Conc<20%: Xn; R22; R32 Eu - - - - - - - -
C; N
C; R34 R: 31-34-50
R31 S: (1/2-)28-45-50-61; Note: Conc>=10%: C; R34; R31
7681-52-9 Sodium hypochlorite, solution ... % Cl active N; R50 B >=5%Conc<10%: Xi; R36/38; R31 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
Disulfurous acid, disodium salt [Sodium R31 Xn >=10%Conc<25%: Xi; R41 Sodium
7681-57-4 metabisulphite] Xi; R41 R: 22-31-41 >=5%Conc<10%: Xi; R36 N; A metabisulphite - 5 - - - - -
N
4-Decyloxazolidin-2-one [4-Decyl-1,3-oxazolidin-2- R: 50/53
7693-82-5 one] N; R50-53 S: 22-24-60-61 Eu - - - - - - - -

O ; C ; R: 8 - 35 , Conc>=20%: C; R35.
O; R8 S: (1/2) - 23 - 26 - 36 - 45; >=5%Conc<20%: C; R34
7697-37-2 Nitric acid ... % C; R35 Note: B >=1%Conc<5%: Xi; R36/38 Eu; A Nitric acid 2 5.2 4 10 - - -

T; N
Crotoxyphos (ISO) [1-Phenylethyl 3- T; R24/25 R: 24/25-50/53 Conc>=25%: T; R24/25
7700-17-6 (dimethoxyphosphinyloxy) isocrotonate] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
Xi
R: 38
7704-34-9 Sulfur Xi; R38 S: (2-)46 Conc>=20%: Xi; R38 Eu - - - - - - - -

Conc>=25%: T; R49; R61; R68; R23; R48/23;

Carc. Cat. 1; R49 R22; R38; R42/43
Muta. Cat. 3; R68 >=20%Conc<25%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R20; R38; R42/43
T; R23-48/23 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Xn; R22 R20; R42/43
Xi; R38 T; N >=3%Conc<10%: T; R49; R61; R68; R48/20;
R42/43 R: 49-61-22-23-38-42/43- R20; R42/43 Nickel, soluble
7718-54-9 Nickel chloride (NiCl2) [Nickel dichloride] N; R50-53 48/23-68-50-53 >=1%Conc<3%: T; R49; R61; R68; R4 N/Eu; A compounds (as Ni) - 0.1 - - - Sen -
R14 Conc>=25%: C; R35; R20/22; R29
R29 >=10%Conc<25%: C; R35; R29
Xn; R20/22 C ; R: 14 - 20/22 - 29 - 35 >=5%Conc<10%: C; R34; R29 1 Peak 4.9 Peak
7719-09-7 Thionyl chloride [Thionyl dichloride] C; R35 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<5%: Xi; R36/37/38; R29 Eu; A Thionyl chloride limitation limitation - - - - -

R14 Conc>=10%: T+; R26/28; R35; R48/20; R29

R29 T+ ; C ; R: 14 - 29 - 26/28 - >=7%Conc<10%: T+; R26/28; R34; R29
T+; R26/28 35 - 48/20 , >=5%Conc<7%: T; R23/25; R34; R29
Xn; R48/20 S: (1/2) - 7/8 - 26 - 36/37/39 >=1%Conc<5%: T; R23/25; R36/38; R29 Phosphorus
7719-12-2 Phosphorus trichloride C; R35 - 45 >=0.1%Conc<1%: Xn; R20/22; R29 Eu; A trichloride 0.2 1.1 0.5 2.8 - - -

Page 154
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn
Xn; R22 R: 22-36/38 Conc>=25%: Xn; R22; R36/38 Iron salts, soluble
7720-78-7 Iron (II) sulfate Xi; R36/38 S: (2-)46 >=20%Conc<25%: Xi; R36/38 Eu;A (as Fe) - 1 - - - - -
O; R8
Xn; R22 O ; Xn ; N ; R: 8 - 22 - 50/53,
7722-64-7 Potassium permanganate N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Conc>=70%: C; R35; R20/22
R5 O; C >=50%Conc<70%: C; R20/22; R34
O; R8 R: 5-8-20/22-35 >=35%Conc<50%: Xn; R22; R37/38; R41
C; R35 S: (1/2-)17-26-28-36/37/39- >=8%Conc<35%: Xn; R22; R41
7722-84-1 Hydrogen peroxide solution ... % Xn; R20/22 45; Note: B >=5%Conc<8%: Xi; R36 Eu; A Hydrogen peroxide 1 1.4 - - - - -
Tetrasodium
7722-88-5 Tetrasodium pyrophosphate A pyrophosphate - 5 - - - - -
Phosphorus
7723-14-0 Phosphorus, yellow A (yellow) - 0.1 - - - - -
F; R11 F
R16 R: 11-16-52/53
7723-14-0 Red phosphorus R52-53 S: (2-)7-43-61 Eu - - - - - - - -
Conc>=10%: T+; R26; R35
>=7%Conc<10%: T+; R26; R34
T+; R26 >=5%Conc<7%: T; R23; R34
C; R35 T+ ; C ; N ; R: 26 - 35 - 50, >=1%Conc<5%: T; R23; R36/38
7726-95-6 Bromine N; R50 S: (1/2) - 7/9 - 26 - 45 - 61 >=0.1%Conc<1%: Xn; R20 Eu; A Bromine 0.1 0.66 0.3 2 - - -
O; R8 O; Xn ; R: 8 - 22 - R36/37/38
Xn; R22 - 42/43, Conc>=25%: Xn; R22; R42/43; R36/37/38 0.1
Potassium persulphate [Dipotassium Xi; R36/37/38 S: (2) - 3 - 7 - 17 - 22 - 24 - >=20%Conc<25%: Xn; R42/43; R36/37/38 Potassium Peak
7727-21-1 peroxodisulphate] R42/43 26 - 37 - 51 >=1%Conc<20%: Xn; R42/43 Eu/N Persulfate - Limitation - - - - -
O; R8 O; Xn ; R: 8 - 22 - R36/37/38
Xn; R22 - 42/43, Conc>=25%: Xn; R22; R42/43; R36/37/38 0.1
Ammonium persulphate [Diammonium Xi; R36/37/38 S: (2) - 3 - 7 - 17 - 22 - 24 - >=20%Conc<25%: Xn; R42/43; R36/37/38 Ammonium Peak
7727-54-0 peroxodisulphate] R42/43 26 - 37 - 51 >=1%Conc<20%: Xn; R42/43 Eu/N Persulfate - Limitation - - - - -

Xn; R22 Xn; N Conc>=25%: Xn; R22; R41

Zinc sulphate (anhydrous)(Note: see also CAS No. R41 R: 22-41-50/53 >=10%Conc<25%: Xi; R41
7733-02-0 7446-19-7) N; R50-53 S: (2-)22-26-39-46-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Conc>=25%: T+; R45; R60; R61; R26; R24/25;

R48/23; R35; R42/43
Carc. Cat. 1; R45 >=10%Conc<25%: T+; R45; R60; R61; R26;
Repr. Cat. 2; R60-61 R48/23; R35; R21/22; R42/43
T+; R26 >=7%Conc<10%: T+; R45; R60; R61; R26;
T; R24/25-48/23 T+; C R34; R21/22; R48/20; R42/43
C; R35 R: 45-60-61-24/25-26-35- >=5%Conc<7%: T; R45; R60; R61; R23; R34;
7738-94-5 Chromic acid (H2CrO4) R42/43 42/43-48/23 R21/22; R48/20; R4 N - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
R31 Xn >=10%Conc<25%: Xi; R41
7757-74-6 Disulfurous acid, disodium salt Xi; R41 R: 22-31-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
R31 Xn >=10%Conc<25%: Xi; R41
7757-83-7 Sulfurous acid, disodium salt Xi; R41 R: 22-31-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
O; R9 T ; O ; R: 45 - 9 - 25 , Conc>=25%: T; R45; R25
Carc. Cat. 2; R45 S: 53 - 45 ; >=3%Conc<25%: T; R45; R22
7758-01-2 Potassium bromate T; R25 Note: E >=0.1%Conc<3%: T; R45 Eu - - - - - - - -
O; R8
T; R25 O ; T ; N ; R: 8 - 25 - 50, Conc>=5%: T; R25
7758-09-0 Potassium nitrite N; R50 S: (1/2) - 45 - 61 >=1%Conc<5%: Xn; R22 Eu - - - - - - - -
Xn; N
Copper (I) chloride [Copper chloride; Cuprous Xn; R22 R: 22 - 50/53,
7758-89-6 chloride] N; R50-53 S: (2) - 22 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Page 155
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R45; R61; R62; R68; R23;

Carc. Cat. 2; R45 R48/20; R43; R33
Muta. Cat. 3; R68 >=10%Conc<25%: T; R45; R61; R62; R68;
Repr. Cat. 1; R61 R20; R48/20; R43; R33
Repr. Cat. 3; R62 >=5%Conc<10%: T; R45; R61; R62; R68; R20;
T; R23 R43; R33
Xn; R48/20 >=3%Conc<5%: T; R45; R61; R68; R20; R43;
R33 T; N R33
Chromic acid (H2CrO4), lead(2+) salt (1:1) [Lead R43 R: 45-61-23-33-43-48/20-62- >=1%Conc<3%: T; R45; R61; R68; R43; R33 Lead chromate (as
7758-97-6 chromate] N; R50-53 68-50-53 >=0 N/Eu Cr) (h) - 0.05 - - 2 - -
Xn; R22 Xn ; N ; R: 22 - 36/38 -
Xi; R36/38 50/53 , Conc>=25%: Xn; R22, R36/38
7758-98-7 Copper sulphate N; R50-53 S: (2) - 22 - 60 - 61 >=20%Conc<25%: Xi; R36/38 Eu - - - - - - - -
O; C; N
O; R8 R: 8-34-50/53 Silver, soluble
C; R34 S: (1/2-)26-36/37/39-45-60- Conc>=10%: C; R34 compounds (as
7761-88-8 Silver nitrate N; R50-53 61 >=5%Conc<10%: Xi; R36/38 Eu;A Ag) - 0.01 - - - - -
Ammonium
7773-06-0 Ammonium sulfamate A sulphamate - 10 - - - - -
O; R9 O; Xn; N
Xn; R22 R: 9-22-51/53
7775-09-9 Sodium chlorate N; R51-53 S: (2-)13-17-46-61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Carc. Cat. 1; R45

Muta. Cat. 2; R46 Conc>=25%: T+; R45; R46; R60; R61; R26;
Repr. Cat. 2; R60-61 R25; R48/23; R34; R21; R42/43
T+; R26 >=10%Conc<25%: T+; R45; R46; R60; R61;
T; R25-48/23 R26; R48/23; R34; R22; R42/43
C; R34 >=7%Conc<10%: T+; R45; R46; R60; R61;
Xn; R21 T+ R26; R22; R48/20; R36/38; R42/43
Chromic acid (H2CrO4), disodium salt [Sodium R42/43 R: 45-46-60-61-21-25-26-34- >=5%Conc<7%: T; R45; R46; R60; R61; R23;
7775-11-3 chromate (VI)] N; R50-53 42/43-48/23-50-53 R22; N/Eu - - - - - - - -
R7.
R31 Xn ; R: 7 - 22 - 31 ,
7775-14-6 Sodium dithionite [Sodium hydrosulphite] Xn; R22 S: (2) - 7/8 - 26 - 28 - 43 Conc>=25%: Xn; R22; R31 Eu - - - - - - - -
O; R8 O; Xn ; R: 8 - 22 - R36/37/38
Xn; R22 - 42/43, Conc>=25%: Xn; R22; R42/43; R36/37/38
Xi; R36/37/38 S: (2) 3 - 7 - 17 - 22 - 24 - 26 >=20%Conc<25%: Xn; R42/43; R36/37/38 0.1 Peak
7775-27-1 Sodium persulphate [Sodium peroxodisulphate] R42/43 - 37 - 51 >=1%Conc<20%: Xn; R42/43 N Sodium Persulfate - limitation - - - - -

Conc>=25%: T; R45; R68; R23/25; R34; R21;

R48/20/21/22
>=10%Conc<25%: T; R45; R68; R34; R20/22;
Carc. Cat. 1; R45 R48/20/21/22
Muta. Cat. 3; R68 >=5%Conc<10%: T; R45; R68; R20/22; R36/38
T; R23/25 T >=3%Conc<5%: T; R45; R68; R20/22
Xn; R21-48/20/21/22 R: 45-21-23/25-34- >=1%Conc<3%: T; R45; R68
7778-39-4 Arsenic acid (H3AsO4) C; R34 48/20/21/22-68 >=0.1%Conc<1%: T; R45 N - - - - - - - -

Conc>=25%: T; R45; R63; R68; R23/25; R21;

R48/20/21/22
>=10%Conc<25%: T; R45; R63; R68; R20/22;
Carc. Cat. 1; R45 R48/20/21/22
Muta. Cat. 3; R68 >=5%Conc<10%: T; R45; R63; R68; R20/22
Repr. Cat. 3; R63 T >=3%Conc<5%: T; R45; R68; R20/22
T; R23/25 R: 45-21-23/25-48/20/21/22- >=1%Conc<3%: T; R45; R68
7778-43-0 Arsenic acid (H3AsO4), disodium salt Xn; R21-48/20/21/22 63-68 >=0.1%Conc<1%: T; R45 N - - - - - - - -

Page 156
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

O; R8
Carc. Cat. 1; R45
Muta. Cat. 2; R46 Conc>=25%: T+; R45; R46; R60; R61; R26;
Repr. Cat. 2; R60-61 R25; R48/23; R34; R21; R42/43
T+; R26 >=10%Conc<25%: T+; R45; R46; R60; R61;
T; R25-48/23 R26; R48/23; R34; R22; R42/43
C; R34 >=7%Conc<10%: T+; R45; R46; R60; R61;
Xn; R21 O; T+; N R26; R22; R48/20; R36/38; R42/43
Chromic acid (H2Cr2O7), dipotassium salt R42/43 R: 8-45-46-60-61-21-25-26- >=5%Conc<7%: T; R45; R46; R60; R61; R23;
7778-50-9 [Potassium dichromate] N; R50-53 34-42/43-48/23-50-53 R22; N/Eu - - - - - - - -
O; R8
C; R34 Conc>=25%: C; R34; R22
Xn; R22 O; C; N >=10%Conc<25%: C; R34
R31 R: 8-22-31-34-50 >=3%Conc<10%: Xi; R37/38; R41
7778-54-3 Calcium hypochlorite N; R50 S: (1/2-)26-36/37/39-45-61 >=0.5%Conc<3%: Xi; R36 Eu - - - - - - - -

Conc>=25%: T+; R40; R26; R24/25; R36/37/38

>=20%Conc<25%: T+; R40; R26; R21/22;
Carc. Cat. 3; R40 R36/37/38
T+; R26 T+ ; N ; R: 24/25 - 26 - >=7%Conc<20%: T+; R40; R26; R21/22
Potassium pentachlorophenate [Potassium T; R24/25 36/37/38 - 40 - 50/53, >=3%Conc<7%: T; R40; R23; R21/22
pentachlorophenolate](Note: see also CAS No 131- Xi; R36/37/38 S: (1/2) - 22 - 28 - 36/37 - >=1%Conc<3%: T; R40; R23
7778-73-6 52-2) N; R50-53 45 - 52 - 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
O; R9 O ; Xn ; R: 9 - 22 ,
7778-74-7 Potassium perchlorate Xn; R22 S: (2) - 13 - 22 - 27 Conc>=25%: Xn; R22 Eu - - - - - - - -

F; R11 F; R11 - 19,

7778-85-0 1,2-Dimethoxypropane R, 19 S: (2) - 9 - 16 - 24/25 - 33 Eu - - - - - - - -
N
R: 50/53
7779-90-0 Trizinc bis(orthophosphate) N; R50-53 S: 60-61 Eu - - - - - - - -

O; R8 O; T+; C Conc>=1%: T+; R26; R35

T+; R26 R: 8-26-35 >=0.2%Conc<1%: T; R23; R34
7782-41-4 Fluorine C; R35 S: (1/2-)9-26-28-36/37/39-45 >=0.02%Conc<0.2%: Xn; R20; R36/37/38 Eu;A Fluorine 1 1.6 2 3.1 - - -

Graphite (all forms

except fibres)
(respirable
dust)(g)(natural & (see Chapter
7782-42-5 Graphite (all forms except fibres) (respirable dust) A synthetic) - 3 - - - - 14)
O; R8,
7782-44-7 Oxygen O; R8 S: (2) - 17 Eu - - - - - - - -

Selenium
T; R23/25 T Conc>=25%: T; R23/25; R33 compounds (as
R33 R: 23/25 - 33 - 53 >=3%Conc<25%: Xn; R20/22; R33 Se) excluding
7782-49-2 Selenium R53 S: (1/2) - 20/21 - 28 - 45 - 61 >=1%Conc<3%: Xn; R33 Eu; A hydrogen selenide - 0.1 - - - - -
T; R23 T; N
Xi; R36/37/38 R: 23-36/37/38-50 Conc>=5%: T; R23; R36/37/38 1 Peak 3 Peak
7782-50-5 Chlorine N; R50 S: (1/2-)9-45-61 >=0.5%Conc<5%: Xn; R20 Eu;A Chlorine limitation limitation - - - - -
Iron (II) sulfate (1:1) heptahydrate [Sulfuric acid, Xn
iron(II) salt (1:1), heptahydrate; Ferrous sulfate Xn; R22 R: 22-36/38 Conc>=25%: Xn; R22; R36/38 Iron salts, soluble
7782-63-0 heptahydrate] Xi; R36/38 S: (2-)46 >=20%Conc<25%: Xi; R36 Eu (as Fe) - 1 - - - - -
Germanium
7782-65-2 Germanium tetrahydride A tetrahydride 0.2 0.63 - - - - -
Carc. Cat. 3; R40 Xn Conc>=20%: Xn; R40; R36/37
7782-91-4 Molybdate (MoO42-), dihydrogen, (T-4)- Xi; R36/37 R: 36/37-40 >=1%Conc<20%: Xn; R40 N - - - - - - - -
Conc>=1%: T+; R26
F+; R12 F+; T+; N >=0.2%Conc<1%: T; R23
T+; R26 R: 12-26-50 >=0.02%Conc<0.2%: Xn; R20
7783-06-4 Hydrogen sulphide N; R50 S: (1/2-)9-16-36-38-45-61 Eu; A Hydrogen sulphide 10 14 15 21 - - -

Page 157
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; N ; R: 23/25 - 33 -
50/53,
T; R23/25 S: (1/2) - 20/21 - 28 - 45 - Conc>=25%: T; R23/25, R33
R33 60 - 61; >=3%Conc<25%: Xn; R20/22, R33 Hydrogen selenide
7783-07-5 Hydrogen selenide (as Se) N; R50-53 Note: A >=1%Conc<3%: Xn; R33 Eu; A (as Se) 0.05 0.16 - - - - -
7783-18-8 Ammonium thiosulphate Xn; R20 Xn ; R: 20 Conc>=25%: Xn; R20 V - - - - - - - -
0.05 Peak 0.11 Peak
7783-41-7 Oxygen difluoride A Oxygen difluoride limitation limitation - - - - -

7783-54-2 Nitrogen trifluoride A Nitrogen trifluoride 10 29 - - - - -

T; R23/24/25 T ; N ; R: 23/24/25 - 51/53, Conc>=25%: T; R23/24/25

7783-56-4 Antimony trifluoride N; R51-53 S: (1/2) - 7 - 26 - 45 - 61 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
Sulphur 0.1 Peak 0.44 Peak
7783-60-0 Sulphur tetrafluoride [Sulfur tetrafluoride] A tetrafluoride limitation limitation - - - - -
T ; N ; R: 23/25 - 33 -
50/53,
T; R23/25 S: (1/2) - 20/21 - 28 - 45 - Conc>=25%: T; R23/25, R33 Selenium
R33 60 - 61; >=3%Conc<25%: Xn; R20/22, R33 hexafluoride (as
7783-79-1 Selenium hexafluoride (as Se) N; R50-53 Note: A >=1%Conc<3%: Xn; R33 Eu; A Se) 0.05 0.16 - - - - -
Tellurium
hexafluoride (as
7783-80-4 Tellurium hexafluoride A Te) 0.02 0.1 - - - - -

Conc>=25%: T+; R45; R68; R28; R23;

R48/23/25; R35
>=10%Conc<25%: T+; R45; R68; R28;
R48/23/25; R35; R20
>=7%Conc<10%: T+; R45; R68; R28; R34;
Carc. Cat. 1; R45 R20; R48/20/22
Muta. Cat. 3; R68 >=5%Conc<7%: T; R45; R68; R25; R34; R20;
T+; R28 R48/20/22
T; R23-48/23/25 T+ >=3%Conc<5%: T; R45; R68; R25; R20;
7784-34-1 Arsenous trichloride C; R35 R: 45-23-28-35-48/23/25-68 R48/20/22; N - - - - - - - -

Conc>=25%: T; R45, R61; R23/25; R62; R33

Carc. Cat. 1; R45 >=5%Conc<25%: T; R45; R61; R62; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 T ; N ; R: 45 - 61 - 62 - >=3%Conc<5%: T; R45; R61; R20/22; R33
T; R23/25 23/25 - 33 - 50/53, >=1%Conc<3%: T; R45; R61; R33
R33 S: 53 - 45 - 60 - 61; >=0.5%Conc<1%: T; R45; R61
7784-40-9 Lead hydrogen arsenate N; R50-53 Note: E >=0.1%Conc<0.5%: T; R45 Eu - - - - - - - -

Conc>=25%: T; R45; R63; R68; R23/25; R21;

R48/20/21/22
>=10%Conc<25%: T; R45; R63; R68; R20/22;
Carc. Cat. 1; R45 R48/20/21/22
Muta. Cat. 3; R68 >=5%Conc<10%: T; R45; R63; R68; R20/22
Repr. Cat. 3; R63 T >=3%Conc<5%: T; R45; R68; R20/22
T; R23/25 R: 45-21-23/25-48/20/21/22- >=1%Conc<3%: T; R45; R68
7784-41-0 Arsenic acid (H3AsO4), monopotassium salt Xn; R21-48/20/21/22 63-68 >=0.1%Conc<1%: T; R45 N - - - - - - - -
F+; R12
Carc. Cat. 1; R45 Conc>=10%: T+; R45; R26; R48/23
T+; R26 >=7%Conc<10%: T+; R45; R26; R48/20
T; R48/23 F+; T+; N >=1%Conc<7%: T; R45; R23; R48/20
7784-42-1 Arsine N; R50-53 R: 12-45-26-48/23-50-53 >=0.1%Conc<1%: T; R45; R20 N/Eu; A Arsine 0.05 0.16 - - - - -

Page 158
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R45; R68; R28; R23;

R48/23/25; R34
>=10%Conc<25%: T+; R45; R68; R28;
R48/23/25; R34; R20
Carc. Cat. 1; R45 >=7%Conc<10%: T+; R45; R68; R28; R20;
Muta. Cat. 3; R68 R48/20/22; R36/38
T+; R28 >=5%Conc<7%: T; R45; R68; R25; R20;
T; R23-48/23/25 T+ R48/20/22; R36/38
7784-46-5 Arsenenous acid, sodium salt C; R34 R: 23-28-34-45-48/23/25-68 >=3%Conc<5%: T; R45; R68; R25; R20; R48/2 N - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Sulfuric acid, ammonium nickel(2+) salt (2:2:1), Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
7785-20-8 hexahydrate R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -

Xn; R48/20/22 Xn ; N ; R: 48/20/22 - 51/53,

7785-87-7 Manganese sulphate N; R51-53 S: (2) - 22 - 61 Conc>=10%: Xn; R48/20/22 Eu - - - - - - - -
T+; N
R: 27/28-50/53 Conc>=7%: T+; R27/28
Mevinphos (ISO) [2-Methoxycarbonyl-1-methylvinyl T+; R27/28 S: (1/2-)23-28-36/37-45-60- >=1%Conc<7%: T; R24/25
7786-34-7 dimethyl phosphate] N; R50-53 61 >=0.1%Conc<1%: Xn; R21/22 Eu; A Mevinphos 0.01 0.092 0.03 0.27 - Sk -

Conc>=25%: T; R49; R61; R68; R48/23;

Carc. Cat. 1; R49 R20/22; R38; R42/43
Muta. Cat. 3; R68 >=20%Conc<25%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R38; R42/43
T; R48/23 T; N >=1%Conc<20%: T; R49; R61; R68; R48/23;
Xn; R20/22 R: 49-61-20/22-38-42/43- R42/43
Xi; R38 48/23-68-50/53 >=0.5%Conc<1%: T; R49; R61; R48/20; R43
R42/43 S: 53-45-60-61 >=0.1%Conc<0.5%: T; R49; R48/20; R43
7786-81-4 Nickel sulfate N; R50-53 Note: E >=0.01%Conc<0.1%: Xi; R43 Eu - - - - - - - -

Carc. Cat. 1; R45 Conc>=25%: T+; R45; R46; R60; R61; R26;
Muta. Cat. 2; R46 R25; R48/23; R34; R21; R42/43
Repr. Cat. 2; R60-61 >=10%Conc<25%: T+; R45; R46; R60; R61;
T+; R26 R26; R48/23; R34; R22; R42/43
T; R25-48/23 >=7%Conc<10%: T+; R45; R46; R60; R61;
C; R34 T+ R26; R22; R48/20; R36/38; R42/43
Xn; R21 R: 45-46-60-61-21-25-26-34- >=5%Conc<7%: T; R45; R46; R60; R61; R23;
7788-98-9 Chromic acid (H2CrO4), diammonium salt R42/43 42/43-48/23 R22; N - - - - - - - -

Carc. Cat. 1; R45

Muta. Cat. 2; R46 Conc>=25%: T+; R45; R46; R60; R61; R26;
Repr. Cat. 2; R60-61 R25; R48/23; R34; R21; R42/43
T+; R26 >=10%Conc<25%: T+; R45; R46; R60; R61;
T; R25-48/23 R26; R48/23; R34; R22; R42/43
C; R34 >=7%Conc<10%: T+; R45; R46; R60; R61;
Xn; R21 T+ R26; R22; R48/20; R36/38; R42/43
Chromic acid (H2CrO4), dipotassium salt [Potassium R42/43 R: 45-46-60-61-21-25-26-34- >=5%Conc<7%: T; R45; R46; R60; R61; R23;
7789-00-6 chromate] N; R50-53 42/43-48/23-50-53 R22; N/Eu - - - - - - - -

Carc. Cat. 1; R45 Conc>=25%: T; R45; R23; R22; R48/20; R43

T; R23 >=10%Conc<25%: T; R45; R20; R48/20; R43
Xn; R22-48/20 >=3%Conc<10%: T; R45; R20; R43
Chromic acid (H2CrO4), strontium salt (1:1) R43 T; M >=1%Conc<3%: T; R45; R43
7789-06-2 [Strontium chromate] N; 50-53 R: 45-22-23-43-48/20-50/53 >=0.1%Conc<1%: T; R45 N/Eu - - - - - - - -

Page 159
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

E; R2
O; R8
Carc. Cat. 1; R45
Muta. Cat. 2; R46 Conc>=25%: T+; R45; R46; R60; R61; R26;
Repr. Cat. 2; R60-61 R25; R48/23; R34; R21; R42/43
T+; R26 >=10%Conc<25%: T+; R45; R46; R60; R61;
T; R25-48/23 R26; R48/23; R34; R22; R42/43
C; R34 >=7%Conc<10%: T+; R45; R46; R60; R61;
Xn; R21 E; T+; N R26; R22; R48/20; R36/38; R42/43
Chromic acid (H2Cr2O7), diammonium salt R42/43 R: 2-8-45-46-60-61-21-25-26 >=5%Conc<7%: T; R45; R46; R60; R61; R23;
7789-09-5 [Ammonium Dichromate] N; 50-53 34-42/43-48/23-50-53 R22; N/Eu - - - - - - - -

Carc. Cat. 1; R45 Conc>=25%: T+; R45; R46; R60; R61; R26;
Muta. Cat. 2; R46 R25; R48/23; R34; R21; R42/43
Repr. Cat. 2; R60-61 >=10%Conc<25%: T+; R45; R46; R60; R61;
T+; R26 R26; R48/23; R34; R22; R42/43
T; R25-48/23 >=7%Conc<10%: T+; R45; R46; R60; R61;
C; R34 T+ R26; R22; R48/20; R36/38; R42/43
Xn; R21 R: 45-46-60-61-21-25-26-34- >=5%Conc<7%: T; R45; R46; R60; R61; R23;
7789-12-0 Chromic acid (H2Cr2O7), disodium salt, dihydrate R42/43 42/43-48/23 R22; N - - - - - - - -
Conc>=25%: C; R35; R20
>=10%Conc<25%: C; R35
Xn; R20 C ; R: 20 - 35 , >=5%Conc<10%: C; R34
7789-21-1 Fluorosulphonic acid C; R35 S: (1/2) - 26 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
T ; R: 23/24/25 , Conc>=25%: T; R23/24/25
7789-23-3 Potassium fluoride T; R23/24/25 S: (1/2) - 26 - 45 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
Conc>=10%: T; R25; R34
T; R25 T ; C ; R: 25 - 34 , >=1%Conc<10%: C; R34; R22
7789-29-9 Potassium bifluoride [Potassium hydrogen difluoride] C; R34 S: (1/2) - 22 - 26 - 37 - 45 >= 0.1%Conc<1%: Xi; R36/38 Eu - - - - - - - -
Bromine
7789-30-2 Bromine pentafluoride A pentafluoride 0.1 0.72 - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
7789-49-3 Nickel bromide (NiBr2), trihydrate R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
R14 Conc>=20%: C; R34; R37
C; R34 C ; R: 14 - 34 - 37 , >=10%Conc<20%: C; R34
7789-60-8 Phosphorus tribromide Xi; R37 S: (1/2) - 26 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
F; R15,
7789-78-8 Calcium hydride F; R15 S: (2) - 7/8 - 24/25 - 43 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
7790-78-5 Cadmium chloride, hydrate (2:5) Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

Page 160
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=10%: T+; R45; R46; R60/61; R26; R25;

R48/23/25
>=7%Conc<10%: T+; R45; R46; R60/61; R26;
R48/23/25; R22
>=1%Conc<7%: T; R45; R46; R60/61; R23;
Carc. Cat. 2; R45 R22; R48/20/22
Muta. Cat. 2; R46 T+; N >=0.5%Conc<1%: T; R45; R46; R60/61;
Repr. Cat. 2; R60-61 R: 45-46-60-61-25-26- R20/22; R48/20/22
T+; R26 48/23/25-50/53 >=0.1%Conc<0.5%: T; R45; R46; R20/22; Cadmium and
T; R25-48/23/25 S: 53-45-60-61; Note: R48/20/22 compounds (as
7790-79-6 Cadmium fluoride N; R50-53 E >=0.01%Conc<0.1%: T; R45 Eu; A Cd) - 0.01 - - 2 - -
T; R23/25
R33 T; N Conc>=10%: T; R23/25; R33; R68 Cadmium and
Xn; R68 R: 23/25-33-68-50/53 >=1%Conc<10%: Xn; R20/22; R33; R68 compounds (as
7790-80-9 Cadmium iodide N; R50-53 S: (1/2-)22-45-60-61 >=0.1%Conc<1%: Xn; R20/22; R33 Eu; A Cd) - 0.01 - - 2 - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
7790-84-3 Sulfuric acid, cadmium salt (1:1), hydrate (3:8) Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
0.1 Peak 0.38 Peak
7790-91-2 Chlorine trifluoride A Chlorine trifluoride limitation limitation - - - - -
Conc>=20%: C; R35, R37
R14 >=10%Conc<20%: C; R35
C; R35 C ; R: 14 - 35 - 37 , >=5%Conc<10%: C; R34 Chlorosulphonic
7790-94-5 Chlorosulphonic acid Xi; R37 S: (1/2) - 26 - 45 >=1%Conc<5%: Xi; R36/38 Eu; A acid 0.209 1 - - - - -
E
Ammonium perchlorate(Note: containing < 80 % of 0- E; R2 R: 2-9
7790-98-9 30 micrometre particles) O; R9 S: (2-)14-16-36/37 Eu - - - - - - - -
E
Ammonium perchlorate(Note: containing >= 80 % of E; R3 R: 3-9
7790-98-9 0-30 micrometre particles) O; R9 S: (2-)14-16-36/37 Eu - - - - - - - -

Xn; R42
Xi; R43
This substance has only been
assessed against the endpoint of
sensitisation. This substance has
not been subject to a complete
assessment for hazard
Cobalt(II) chloride, hexahydrate [Cobaltous chloride, classification in accordance with
7791-13-1 hexahydrate] the approved criteria. Xn; R:42/43 Conc>=1%:Xn; R42/43 N - - - - - - - -

Conc>=25%: T; R49; R61; R68; R23; R48/23;

R22; R38; R42/43
Carc. Cat. 1; R49 >=20%Conc<25%: T; R49; R61; R68; R48/23;
Muta. Cat. 3; R68 R20; R38; R42/43
Repr. Cat. 2; R61 >=10%Conc<20%: T; R49; R61; R68; R48/23;
T; R23-48/23 R20; R42/43
Xn; R22 T >=3%Conc<10%: T; R49; R61; R68; R48/20;
Xi; R38 R: 49-61-22-23-38-42/43- R20; R42/43
7791-20-0 Nickel chloride (NiCl2), hexahydrate R42/43 48/23-68 >=1%Conc<3%: T; R49; R61; R68; R4 N - - - - - - - -
R14 Conc>=20%: C; R34, R37
C; R34 C ; R: 14 - 34 - 37 , >=10%Conc<20%: C; R34
7791-25-5 Sulphuryl chloride [Sulfuryl chloride] Xi; R37 S: (1/2) - 26 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Page 161
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: Xn; R40; R21/22; R48/22;

R5 R37/38; R41; R43
Carc. Cat. 3; R40 Xn; N >=20%Conc<25%: Xn; R40; R48/22; R37/38;
Xn; R21/22-48/22 R: 5-21/22-37/38-40-41-43- R41; R43
Xi; R37/38-41 48/22-50 >=10%Conc<20%: Xn; R40; R48/22; R41; R43
R43 S: (2-)26-36/37/39-46-61 >=5%Conc<10%: Xn; R40; R36; R43
7803-49-8 Hydroxylamine ...% [<= 55 % in aqueous solution] N; R50 Note: B >=1%Conc<5%: Xn; R40; R43 Eu - - - - - - - -

Conc>=25%: Xn; R40; R21/22; R48/22;

E; R2 R37/38; R41; R43
Carc. Cat. 3; R40 E; Xn; N >=20%Conc<25%: Xn; R40; R48/22; R37/38;
Xn; R21/22-48/22 R: 2-21/22-37/38-40-41-43- R41; R43
Xi; R37/38-41 48/22-50 >=10%Conc<20%: Xn; R40; R48/22; R41; R43
R43 S: (2-)26-36/37/39-61 >=5%Conc<10%: Xn; R40; R36; R43
7803-49-8 Hydroxylamine .... % [> 55 % in aqueous solution] N; R50 Note: B >=1%Conc<5%: Xn; R40; R43 Eu - - - - - - - -
Conc>=10%: T+; R26, R34
>=7%Conc<10%: T+; R26; R36/38
F+; R12 R17 F+; T+; N >=5%Conc<7%: T; R23; R36/38
T+; R26 C; R34 R: 12-17-26-34-50 >=1%Conc<5%: T; R23
7803-51-2 Phosphine N; R50 S: (1/2-)28-36/37-45-61-63 >=0.1%Conc<1%: Xn; R20 Eu; A Phosphine 0.3 0.42 1 1.4 - - -
7803-52-3 Stibine A Stibine 0.1 0.51 - - - - -

Conc>=25%: T; R45; R68; R23/24/25;

R48/23/25; R34; R43
>=10%Conc<25%: T; R45; R68; R48/23/25;
R34; R20/21/22; R43
Carc. Cat. 2; R45 >=5%Conc<10%: T; R45; R68; R20/21/22;
Muta. Cat. 3; R68 R48/20/22; R36/38; R43
T; R23/24/25-48/23/25 T >=3%Conc<5%: T; R45; R68; R20/21/22;
C; R34 R: 45-23/24/25-34-43- R48/20/22; R43
7803-57-8 Hydrazine, monohydrate R43 48/23/25-68 >=1%Conc<3%: T; R45; R68; R4 N - - - - - - - -

7803-62-5 Silicon tetrahydride [Silane] A Silicon tetrahydride 5 6.6 - - - - -

Carc. Cat. 3; R40
T; R25 T ; N ; R: 21 - 25 - 37/38 - Conc>=25%: T; R40; R25; R21; R37/38
Xn; R21 40 - 50/53, >=20%Conc<25%: Xn; R40; R22; R37/38
Xi; R37/38 S: (1/2) - 36/37 - 45 - 60 - >=3%Conc<20%: Xn; R40; R22 Chlorinated
8001-35-2 Camphechlor [Toxaphene; Chlorinated camphene] N; R50-53 61 >=1%Conc<3%: Xn; R40 Eu; A camphene - 0.5 - 1 - Sk -

Creosote [Wash Oil](Note: The distillate of coal tar

produced by the high temperature carbonization of T
bituminous coal. It consists primarily of aromatic R: 45
8001-58-9 hydrocarbons, tar acids and tar bases) Carc. Cat. 2; R45 S: 53-45; Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
8002-05-9 Petroleum Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Paraffin wax
8002-74-2 Paraffin wax (fume) A (fume) - 2 - - - - -

Conc>=25%: T; R25; R48/24/25; R34

T ; N ; R: 25 - 34 - 48/24/25 - >=10%Conc<25%: T; R48/24/25; R34; R22
T; R25-48/24/25 50/53, >=5%Conc<10%: Xn; R22; R48/21/22; R36/38
Phenylmercury nitrate, basic(Note: see also CAS No C; R34 S: (1/2) - 23 - 24/25 - 37 - >=3%Conc<5%: Xn; R22; R48/21/22
8003-05-2 55-68-5 & 100-57-2) N; R50-53 45 - 60 - 61 >=1%Conc<3%: Xn; R48/21/22 Eu - - - - - - - -
8003-34-7 Pyrethrum A Pyrethrum - 5 - - - Sen -

Page 162
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Gasoline, natural [Petrol, natural; Low boiling point

naphtha](Note: A complex combination of
hydrocarbons separated from natural gas by
processes such as refrigeration or absorption. It
consists predominantly of saturated aliphatic
hydrocarbons having carbon numbers predominantly T
in the range of C4 through C8 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately minus 20 °C to 120 °C (-4 °F Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65 (see Chapter
8006-61-9 to 248 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu;A Petrol (gasoline) - 900 - - - - 16)

Turpentine, oil [Turpentine (wood)](Note: Any of the

volatile predominately terpenic fractions or distillates
resulting from the solvent extraction of, gum
collection from, or pulping of softwoods. Composed
primarily of the C10H16 terpene hydrocarbons:
(alpha-pinene, beta-pinene, limonene, 3-carene, R10
camphene. May contain other acyclic, monocyclic, or Xn; R20/21/22
bicyclic terpenes, oxygenated terpenes, and Xn; R65 Conc>=25%: Xn; R20/21/22; R65; R36/38; R43
anethole. Exact composition varies with refining Xi; R36/38 Xn ; N ; R: 10 - 20/21/22 - >=20%Conc<25%: Xn; R65; R36/38; R43
methods and the age, location, and species of the R43 36/38 - 43 - 65 - 51/53, >=10%Conc<20%: Xn; R65; R43
8006-64-2 softwood source) N; R51-53 S: (2) - 36/37 - 46 - 61 - 62; >=1%Conc<10%: Xi; R43 Eu; A Turpentine (wood) 100 557 - - - Sen -
T ; R: 45 ,
S: 53 - 45 ;
8007-45-2 Tar, coal [Coal tar] Carc. Cat. 1; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Kerosine (petroleum) [Straight run kerosine; S: (2) - 23 - 24 - 62 ;
8008-20-6 Kerosene] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
8009-03-8 Petrolatum [Petrolatum] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
Oil mist, refined
8012-95-1 Oil mist, refined mineral A mineral - 5 - - - - -
Mancozeb (ISO) [Manganese Repr. Cat. 3; R63 Xn; N
ethylenebis(dithiocarbamate) (polymeric) complex R43 R: 43-63-50 Conc>=5%: Xn; R63; R43
8018-01-7 with zinc salt] N; R50 S: (2-)36/37-46-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
8022-00-2 Methyl demeton A Methyl demeton - 0.5 - - - Sk -

Naphtha [Low boiling point naphtha](Note: Refined,

partly refined, or unrefined petroleum products
produced by the distillation of natural gas. It consists
of hydrocarbons having carbon numbers T
predominantly in the range of C5 through C6 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately 100 °C to 200 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
8030-30-6 °C (212 °F to 392 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Ligroine [Low boiling point naphtha; Petroleum

ether](Note: A complex combination of hydrocarbons T
obtained by the fractional distillation of petroleum. Carc. Cat. 2; R45 R: 45-46-65
This fraction boils in a range of approximately 20 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
8032-32-4 to 135 °C (58 °F to 275 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Xi
8050-09-7 Rosin [Colophony] R43 R: 43 Conc>=1%: Xi; R43 N/Eu - - - - - - - -
Xi ; R: 36/37/38 ,
8051-02-3 Sabadilla (ISO) [Veratrine] Xi; R36/37/38 S: (2) - 36/37/39 Conc>=20%: Xi; R36/37/38 Eu - - - - - - - -
Tall oil rosin(Note: see also CAS No 8050-09-7 &
8052-10-6 73138-82-6) Xi; R43 Xi ; R: 43 , S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Stoddard solvent [White spirits; Low boiling point
naphtha — unspecified](Note: A colorless, refined
petroleum distillate that is free from rancid or T
objectionable odors and that boils in a range of Carc. Cat. 2; R45 R: 45-46-65
approximately 148.8 °C to 204.4 °C. (300 °F to 400 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65 (see Chapter
8052-41-3 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu;A White spirits - 790 - - - - 16)
8052-42-4 Asphalt, petroleum fumes [Bitumen fumes] A Bitumen fumes - 5 - - - - -

Page 163
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Bufencarb (ISO) [Mixture of 3-(1-methylbutyl)phenyl T ; N ; R: 24/25 - 50/53,
N-methylcarbamate and 3-(1-ethylpropyl) phenyl N- T; R24/25 S: (1/2) - 28 - 36/37 - 45 - Conc>=25%: T; R24/25
8065-36-9 methylcarbamate] N; R50-53 60 - 61 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
T+ ; N ; R: 27/28 - 50 , Conc>=7%: T+; R27/28
T+, R27/28 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R24/25
8065-48-3 Demeton N; R50 61 >=0.1%Conc<1%: Xn; R21/22 Eu; A Demeton 0.01 0.11 - - - Sk -
Mixture of 4,6-dinitro-2-(3-octyl)phenyl methyl Xn; N
carbonate and 4,6-dinitro-2-(4-octyl)phenyl methyl Xn; R22 R: 22 - 50/53
8069-76-9 carbonate [Dinocton-6] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R: 42,
9000-90-2 Amylase, alpha Xn; R42 S: 2 - 22 - 24 - 36/37 Conc>=1%: Xn; R42 Eu - - - - - - - -

Xi; R36/37/38 Xn ; R: 36/37/38 - 42, Conc>=20%: Xn; R42; R36/37/38

9001-00-7 Bromelain, juice Xn; R42 S: (2) - 22 - 24 - 26 - 36/37 >=1%Conc<20%: Xn; R42 Eu - - - - - - - -
Xn: R: 42;
9001-22-3 Glucosidase, beta Xn; R42 S: (2) - 22 - 24 - 36/37 Conc>=1%: Xn; R42 Eu - - - - - - - -

Xi; R36/37/38 Xn ; R: 36/37/38 - 42, Conc>=20%: Xn; R42; R36/37/38

9001-33-6 Ficin Xn; R42 S; (2) - 22 - 24 - 26 - 36/37 >=1%Conc<20%: Xn; R42 Eu - - - - - - - -

Xi; R36/37/38 Xn; R: 36/37/38 - 42 Conc>=20%: Xn; R42; R36/37/38

9001-73-4 Papain Xn; R42 S: (2) - 22 - 24 - 26 - 36/37 >=1%Conc<20%: Xn; R42 Eu - - - - - - - -

Xi: R 36/37/38 Xn ; R: 36/37/38 - 42 Conc>=20%: Xn; R42; R36/37/38

9001-75-6 Pepsin-A Xn; R42 S: (2) - 22 - 24 - 26 - 36/37 >=1%Conc<20%: Xn; R42 Eu - - - - - - - -

Xi; R36/37/38 Xn; R: 36/37/38 - 42 Conc>=20%: Xn; R42; R36/37/38

9001-98-3 Rennin Xn; R42 S: (2) - 22 - 24 - 26 - 36/37 >=1%Conc<20%: Xn; R42 Eu - - - - - - - -

Xi: R 36/37/38 Xn; R: 36/37/38 - 42, Conc>=20%: Xn; R42; R36/37/38

9002-07-7 Trypsin Xn; R42 S: (2) - 22 - 24 - 26 - 36/37 >=1%Conc<20%: Xn; R42 Eu - - - - - - - -

Xi; R 36/37/38 Xn ; R: 36/37/38 - 42, Conc>=20%: Xn; R42, R36/37/38

9004-07-3 Chymotrypsin Xn; R42 S: (2) - 22 - 24 - 26 - 36/37 >=1%Conc<20%: Xn; R42 Eu - - - - - - - -
Poly(oxy-1,2-ethanediyl), .alpha.-sulfo-.omega.- Xn; R22 Xn Conc>=25%: Xn; R22; R36/38
9004-82-4 (dodecyloxy)-, sodium salt (1:1) Xi; R36/38 R: 22-36/38 >=20%Conc<25%: Xi; R36/38 N - - - - - - - -
Xn; R65 Conc>=20%: Xn; R65; R38 (see Chapter
9005-90-7 Mineral turpentine Xi; R38 Xn ; R: 65 - 38 >=10%Conc<20%: Xn; R65 A, P Mineral turpentine - 480 - - - - 16)
Xi
9007-13-0 Resin acids and rosin acids, calcium salts R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Xn ; R42,
9012-54-8 Cellulase Xn; R42 S: (2) - 22 - 24 - 36/37 Conc>=1%: Xn; R42 Eu - - - - - - - -
Conc>=20%: Xn; R42; R37/38; R41
Xi; R 37/38 Xn ; R: 37/38 - 41 - 42, >=10%Conc<20%: Xn; R42; R41
R41 S: (2) - 22 - 24 - 26 - >=5%Conc<10%: Xn; R42; R36
9014-01-1 Subtilisins [(Proteolytic enzymes)] Xn; R42 36/37/39 >=1%Conc<5%: Xn; R42 Eu - - - - - - - -
Xn; R20-48/20/22 Xn; N Conc>=25%: Xn; R20; R48/20/22; R43
Propineb (ISO) [Polymeric zinc R43 R: 20-43-48/20/22-50 >=10%Conc<25%: Xn; R48/20/22; R43
9016-72-2 propylenebis(dithiocarbamate)] N; R50 S: (1/2-)24-37-46-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R40; R23; R48/23; R36/37/38;

R42/43
>=20%Conc<25%: T; R40; R48/23; R20;
R36/37/38; R42/43
>=10%Conc<20%: T; R40; R48/23; R20;
Carc. Cat. 3; R40 R42/43
T; R23-R48/23 T >=3%Conc<10%: Xn; R40; R20; R48/20;
Xi; R36/37/38 R: 23-36/37/38-40-42/43- R42/43
9016-87-9 Isocyanic acid, polymethylenepolyphenylene ester R42/43 48/23 >=1%Conc<3%: Xn; R40; R48/20; R42/43 N - - - - - - - -

Carc. Cat. 3; R40 Conc>=20%: T+; R40; R26; R36/37/38; R42/43

T+; R26 >=7%Conc<20%: T+; R40; R26; R42/43
Xi; R36/37/38 T+ >=1%Conc<7%: T; R40; R23; R42/43
9017-01-0 Benzene, 1,3-diisocyanatomethyl-, homopolymer R42/43 R: 26-36/37/38-40-42/23 >=0.1%Conc<1%: Xn; R20 N - - - - - - - -

Page 164
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Xi: R 36/37/38 Xn ; R:36/37/38 - 42 Conc>=20%: Xn; R42; R36/37/38

9068-59-1 Proteinase, microbial neutral Xn; R42 S: (2) - 22 - 24 - 26 - 36/37 >=1%Conc<20%: Xn; R42 Eu - - - - - - - -
R31 C; N
C; R34 R: 31-34-50 Conc>=5%: C; R34; R31
9080-17-5 Ammonium polysulphides N; R50 S: (1/2-)26-45-61 >=1%Conc<5%: Xi; R36/38; R31 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
Xi; R41 Xn ; R: 22 - 41 - 52/53, >=10%Conc<25%: Xi; R41
10004-44-1 3-Hydroxy-5-methylisoxazole [Hymexazol] R52-53 S: (2) - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Potassium 3,6-dichloro-o-anisate(Note: see also CAS Xi; R36 Xi ; R36 - 52/53,
10007-85-9 No 2300-66-5) R52-53 S: (2) - 26 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 1; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
10022-68-1 Nitric acid, cadmium salt, tetrahydrate Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
10024-97-2 Nitrous oxide [Nitrogen oxide] A Nitrous oxide 25 45 - - - - -
R14
T; R25 Conc>=25%: T; R25; R35; R20
Xn; R20 >=10%Conc<25%: C; R35; R22
R29 T; C; N >=5%Conc<10%: C; R34; R22
Disulphur dichloride [Sulfur monochloride; Sulphur C; R35 R: 14-20-25-29-35-50 >=3%Conc<5%: Xn; R22; R36/37/38 Sulphur 1 Peak 5.5 Peak
10025-67-9 monochloride] N; R50 S: (1/2-)26-36/37/39-45-61 >=1%Conc<3%: Xi; R36/37/38 Eu; A monochloride limitation limitation - - - - -
F+; R12
R14
F; R17 F+; C ; R: 12 - 14 - 17 - 35 -
Xn; R20/22 20/22 - 29, Conc>=10%: C; R35; R20/22; R29
R29 S: (2) - 7/9 - 16 - 26 - >=5%Conc<10%: C; R34; R29
10025-78-2 Trichlorosilane C; R35 36/37/39 - 43 - 45 >=1%Conc< 5%: Xi; R36/37/38; R29 Eu - - - - - - - -

R14 Conc>=25%: T+; R26; R35; R48/23; R22; R29

R29 >=10%Conc<25%: T+; R26; R35; R48/23; R29
T+; R26 T+ ; C ; R: 14 - 22 - 26 - 29 - >=7%Conc<10%: T+; R26; R34; R48/20; R29
T; R48/23 35 - 48/23, >=5%Conc<7%: T; R23; R34; R48/20; R29
Xn; R22 S: (1/2) - 7/8 - 26 - 36/37/39 >=1%Conc<5%: T; R23; R48/20; R36/38; R29 Phosphorus
10025-87-3 Phosphorus oxychloride [Phosphoryl trichloride] C; R35 - 45 >=0.1%Conc<1%: Xn; R20; R29 Eu; A oxychloride 0.1 0.63 - - - - -
C; R34 C ; N ; R: 34 - 51/53 , Conc>=10%: C; R34
10025-91-9 Antimony trichloride N; R51-53 S: (1/2) - 26 - 45 - 61 >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -

Conc>=25%: T; R25; R42/43; R38; R41

>=20%Conc<25%: Xn; R22; R42/43; R38; R41
>=10%Conc<20%: Xn; R22; R42/43; R41
T; R25 T ; R: 25 - 38 - 41 - 42/43, >=5%Conc<10%: Xn; R22; R42/43; R36
Xi; R38-41 S: (2) - 22 - 26 - 36/37/39 - >=3%Conc<5%: Xn; R22; R42/43
10025-99-7 Dipotassium tetrachloroplatinate R42/43 45 >=1%Conc<3%: Xn; R42/43 Eu - - - - - - - -

Conc>=25%: T; R25; R42/43; R38; R41

>=20%Conc<25%: Xn; R22; R42/43; R38; R41
>=10%Conc<20%: Xn; R22; R42/43; R41
T; R25 T ; R: 25 - 38 - 41 - 42/43, >=5%Conc<10%: Xn; R22; R42/43; R36
Xi; R38-41 S: (2) - 22 - 26 - 36/37/39 - >=3%Conc<5%: Xn; R22; R42/43
10026-00-3 Disodium tetrachloroplatinate R42/43 45 >=1%Conc<3%: Xn; R42/43 Eu - - - - - - - -
R14. Xi ; R: 14 - 36/37/38 ,
10026-04-7 Silicon tetrachloride Xi; R36/37/38 S: (2) - 7/8 - 26 Conc>=20%: Xi; R36/37/38 Eu - - - - - - - -

Page 165
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

R14 Conc>=25%: T+; R26; R34; R22; R48/20; R29

R29 >=10%Conc<25%: T+; R26; R34; R48/20;R29
T+; R26 T+ ; C ; R: 14 - 22 - 26 - 29 - >=7%Conc<10%: T+; R26; R36/38; R29
Xn; R22 34 - 48/20, >=5%Conc<7%: T; R23; R36/38; R29
Xn; R48/20 S: (1/2) - 7/8 - 26 - 36/37/39 >=1%Conc<5%: T; R23; R29 Phosphorus
10026-13-8 Phosphorus pentachloride C; R34 - 45 >=0.1%Conc<1%: Xn; R20; R29 Eu; A pentachloride 0.1 0.85 - - - - -
Xn; R21 Xn ; R: 21 - 38 - 43 , Conc>=25%: Xn; R21; R38; R43
Xi; R38 S: (2) - 28 ; >=10%Conc<25%: Xi; R38; R43
10027-06-2 8,9,10-Trinorborn-2-yl acrylate R43 Note: D >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
0.1 Peak 0.2 Peak
10028-15-6 Ozone A Ozone limitation limitation - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R41; R42/43
Carc. Cat. 1; R49 >=20%Conc<25%: T; R49; R61; R68; R48/23;
Muta. Cat. 3; R68 R38; R41; R42/43
Repr. Cat. 2; R61 >=10%Conc<20%: T; R49; R61; R68; R48/23;
T; R48/23 R41; R42/43
Xn; R20/22 T >=5%Conc<10%: T; R49; R61; R68; R48/20;
Xi; R38-41 R: 49-61-20/22-38-41-42/43- R36; R42/43
10028-18-9 Nickel fluoride (NiF2) R42/43 48/23-68 >=1%Conc<5%: T; R49; R61; R68; N - - - - - - - -

Carc. Cat. 1; R45 Conc>=25%: T+; R45; R46; R60; R61; R26;
Muta. Cat. 2; R46 R25; R48/23; R34; R21; R42/43
Repr. Cat. 2; R60-61 >=10%Conc<25%: T+; R45; R46; R60; R61;
T+; R26 R26; R48/23; R34; R22; R42/43
T; R25-48/23 >=7%Conc<10%: T+; R45; R46; R60; R61;
C; R34 T+ R26; R22; R48/20; R36/38; R42/43
Xn; R21 R: 45-46-60-61-21-25-26-34- >=5%Conc<7%: T; R45; R46; R60; R61; R23;
10034-82-9 Chromic acid (H2CrO4), disodium salt, tetrahydrate R42/43 42/43-48/23 R22; N - - - - - - - -
C ; R: 35 , Conc>=10%: C; R35
S: (1/2) - 9 - 26 - 36/37/39 - >=0.2%Conc<10%: C; R34
10034-85-2 Hydrogen iodide [Hydriodic acid] C; R35 45 >=0.02%Conc<0.2%: Xi; R36/37/38 Eu - - - - - - - -

Conc>=25%; T; R45; R68; R23/24/25; R48/25;

R43
>=10%Conc<25%; T; R45; R68; R48/25;
R20/21/22; R43
Carc. Cat. 2; R45 >=3%Conc<10%; T; R45; R68; R20/21/22;
Muta. Cat. 3; R68 R48/22; R43
T; R23/24/25-48/25 T >=1%Conc<3%; T; R45; R68; R48/22; R43
10034-93-2 Hydrazine, sulfate (1:1) R43 R: 45-23/24/25-43-48/25-68 >=0.1%Conc<1%; T; R45 N - - - - - - - -
Conc>=1%: C; R35; R37
C; R35 C ; R: 35 - 37 , >=0.2%Conc<1%: C; R34; R37 3 Peak 9.9 Peak
10035-10-6 Hydrogen bromide [Hydrobromic acid] Xi; R37 S: (1/2) - 7/9 - 26 - 45 >=0.02%Conc<0.2%: Xi; R37 Eu; A Hydrogen bromide limitation limitation - - - - -
E; R2 Conc>=25%: Xn; R40; R21/22; R48/22;
Carc. Cat. 3; R40 R36/38; R43
Xn; R21/22-48/22 E; Xn; N >=20%Conc<25%: Xn; R40; R48/22; R36/38;
Bis(hydroxylammonium) sulfate [Hydroxylamine Xi; R36/38 R: 2-21/22-36/38-40-43- R43
sulfate (2:1)](Note: see also CAS No. 5470-11-1 & R43 48/22-50 >=10%Conc<20%: Xn; R40; R48/22; R43
10039-54-0 10046-00-1) N; R50 S: (2-)36/37-61 >=1%Conc<10%: Xn; R40; R43 Eu - - - - - - - -
T
R: 60-61
10043-35-3 Boric acid(Note: see also CAS No. 11113-50-1) Repr. Cat. 2; R60-61 S: 53-45 Conc>=5.5%: T; R60; R61 Eu - - - - - - - -
Xi ; R: 36 ,
10043-52-4 Calcium chloride Xi; R36 S: (2) - 22 - 24 Conc>=20%: Xi; R36 Eu - - - - - - - -
E; R2 Conc>=25%: Xn; R40; R21/22; R48/22;
Carc. Cat. 3; R40 R36/38; R43
Xn; R21/22-48/22 E; Xn; N >=20%Conc<25%: Xn; R40; R48/22; R36/38;
Hydroxylammonium hydrogensulfate [Hydroxylamine Xi; R36/38 R: 2-21/22-36/38-40-43- R43
sulfate(1:1)](Note: see also CAS No. 20845-01-6, R43 48/22-50 >=10%Conc<20%: Xn; R40; R48/22; R43
10046-00-1 19098-16-9 & 53933-48-5) N; R50 S: (2-)36/37-61 >=1%Conc<10%: Xn; R40; R43 Eu - - - - - - - -

Page 166
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R45; R63; R68; R23/25; R21;

R48/20/21/22
>=10%Conc<25%: T; R45; R63; R68; R20/22;
Carc. Cat. 1; R45 R48/20/21/22
Muta. Cat. 3; R68 >=5%Conc<10%: T; R45; R63; R68; R20/22
Repr. Cat. 3; R63 T >=3%Conc<5%: T; R45; R68; R20/22
T; R23/25 R: 45-21-23/25-48/20/21/22- >=1%Conc<3%: T; R45; R68
10048-95-0 Arsenic acid (H3AsO4), disodium salt, heptahydrate Xn; R21-48/20/21/22 63-68 >=0.1%Conc<1%: T; R45 N - - - - - - - -
T; N
R: 25-34-50 Conc>=25%: T; R25; R34
T; R25 S: (1/2-)23-26-28-36/37/39- >=10%Conc<25%: C; R34; R22
C; R34 45-61; >=3%Conc<10%: Xn; R22; R36/37/38
10049-04-4 Chlorine dioxide ... % N; R50 Note: B >=0.3%Conc<3%: Xi; R36 Eu;A Chlorine dioxide 0.1 0.28 0.3 0.83 - - -
O; R8 Conc>=5%: T+; R26; R34
R6 O; T+; N >=1%Conc<5%: T+; R26; R36/37/38
T+; R26 R: 6-8-26-34-50 >=0.5%Conc<1%: T; R23; R36/37/38
C; R34 S: (1/2-)23-26-28-36/37/39- >=0.2%Conc<0.5%: T; R23
10049-04-4 Chlorine dioxide N; R50 38-45-61 >=0.02%Conc<0.2%: Xn; R20 Eu;A Chlorine dioxide 0.1 0.28 0.3 0.83 - - -
Conc>=25%: T; R24/25; R20; R65; R36/37/38;
R10 R43
T; R24/25 T; N >=20%Conc<25%: Xn; R21/22; R65;
Xn; R20-65 R: 10-20-24/25-36/37/38-43- R36/37/38; R43
Xi; R36/37/38 65-50/53 >=10%Conc<20%: Xn; R21/22; R65; R43
(Z)-1,3-Dichloropropene [cis-1,3- R43 S: (1/2-)36/37-45-60-61 >=3%Conc<10%: Xn; R21/22; R43
10061-01-5 Dichloropropene](Note: see also CAS No. 542-75-6) N; R50-53 Notes: C ; D >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Xi
Xi; R41 R52- R: 41-52/53 Conc>=10%: Xi; R41
10097-02-6 2,2-Bis(hydroxymethyl)butanoic acid 53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
10099-76-0 Silicic acid (H2SiO3), lead(2+) salt (1:1) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat 1; R49 R38; R42/43
Repr. Cat 2; R61 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Muta. Cat 3; R68 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-68-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
10101-98-1 Sulfuric acid, nickel(2+) salt (1:1), heptahydrate R42/43 48/23 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
Conc>=25%: T+; R28; R23; R43; R31
T+; R28 >=7%Conc<25%: T+; R28; R20; R43; R31
T; R23 T+; N >=3%Conc<7%: T; R25; R20; R43; R31
R31 R43 R: 23-28-31-43-51/53 >=1%Conc<3%: T; R25; R43; R31
10102-18-8 Sodium selenite N; R51-53 S: (1/2-)28-36/37-45-61 >=0.1%Conc<1%: Xn; R22; R31 Eu - - - - - - - -
10102-43-9 Nitric oxide [Nitrogen monoxide] A Nitric oxide 25 31 - - - - -
Conc>=10%: T+; R26; R34
>=5%Conc<10%: T; R23; R34
O; R8 O; T+ >=1%Conc<5%: T; R23; R36/37/38
Nitrogen dioxide(Note: see also CAS No. 10544-72- T+; R26 R: 8-26-34 >=0.5%Conc<1%: Xn; R20; R36/37/38
10102-44-0 6) C; R34 S: (1/2-)9-26-28-36/37/39-45 >=0.1%Conc<0.5%: Xn; R20 Eu;A Nitrogen dioxide 3 5.6 5 9.4 - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=10%: T+; R45; R46; R60/61; R26; R25;

R48/23/25
>=7%Conc<10%: T+; R45; R46; R60/61; R26;
R48/23/25; R22
>=1%Conc<7%: T; R45; R46; R60/61; R23;
Carc. Cat. 2; R45 R22; R48/20/22
Muta. Cat. 2; R46 T+; N >=0.5%Conc<1%: T; R45; R46; R60/61;
Repr. Cat. 2; R60-61 R: 45-46-60-61-25-26- R20/22; R48/20/22
T+; R26 48/23/25-50/53 >=0.1%Conc<0.5%: T; R45; R46; R20/22; Cadmium and
T; R25-48/23/25 S: 53-45-60-61; Note: R48/20/22 compounds (as
10108-64-2 Cadmium chloride N; R50-53 E >=0.01%Conc<0.1%: T; R45 Eu; A Cd) - 0.01 - - 2 - -
Xn ; N ; R: 22 - 36/37/38 -
Xn; R22 50/53,
Xi; R36/37/38 S: (2) - 13 - 24/25 - 46 - 60 - Conc>=25%: Xn; R22; R36/37/38
10112-91-1 Dimercury dichloride [Calomel; Mercurous chloride] N; R50-53 61 >=20%Conc<25%; Xi; R36/37/38 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
R31 Xn >=10%Conc<25%: Xi; R41
10117-38-1 Sulfurous acid, dipotassium salt Xi; R41 R: 22-31-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Conc>=10%: T+; R45; R46; R60/61; R26; R25;

R48/23/25
>=7%Conc<10%: T+; R45; R46; R60/61; R26;
R48/23/25; R22
Carc. Cat. 2; R45 >=1%Conc<7%: T; R45; R46; R60/61; R23;
Muta. Cat. 2; R46 R22; R48/20/22
Repr. Cat. 2; R60-61 T+; N >=0.5%Conc<1%: T; R45; R46; R60/61;
T; R48/23/25 R: 45-46-60-61-25-26- R20/22; R48/20/22
T+; R26 48/23/25-50/53 >=0.1%Conc<0.5%: T; R45; R46; R20/22; Cadmium and
T; R25 S: 53-45-60-61; Note: R48/20/22 compounds (as
10124-36-4 Cadmium sulphate N; R50-53 E >=0.01%Conc<0.1%: T; R45 Eu; A Cd) - 0.01 - - 2 - -
Carc. Cat. 2; R49
Muta. Cat. 3; R68
Repr. Cat. 2; R60 T; N Conc>=25%: T; R49; R60; R68; R22; R42/43
Xn; R22 R: 49-60-22-42/43-68-50/53 >=1%Conc<25%: T; R49; R60; R68; R42/43
R42/43 S: 53-45-60-61 >=0.5%Conc<1%: T; R49; R60
10124-43-3 Cobalt sulfate N; R50-53 Note: E >=0.01%Conc<0.5%: T; R49 Eu - - - - - - - -
Xi
Bis(2-ethylhexyl)-4,5-epoxycyclohexane-1,2- R: 43
10138-36-0 dicarboxylate R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 2; R49
Muta. Cat. 3; R68
Repr. Cat. 2; R60 T; N Conc>=1%: T; R49; R60; R68; R42/43
R42/43 R: 49-60-42/43-68-50/53 >=0.5%Conc<1%: T; R49; R60
10141-05-6 Cobalt nitrate N; R50-53 S: 53-45-60-61 >=0.01%Conc<0.5%: T; R49 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
10190-55-3 Molybdic acid (H2MoO4), lead(2+) salt (1:1) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
R31 Xn >=10%Conc<25%: Xi; R41
10192-30-0 Sulfurous acid, monoammonium salt Xi; R41 R: 22-31-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
R31 Xn >=10%Conc<25%: Xi; R41
10196-04-0 Sulfurous acid, diammonium salt Xi; R41 R: 22-31-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
10196-67-5 Tetradecanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Cobalt carbonyl
10210-68-1 Cobalt carbonyl (as Co) A (as Co) - 0.1 - - - Sen -
Xi
R43 R: 43-52/53
10217-34-2 2-(3,4-Epoxycyclohexyl)ethyltriethoxy silane R52-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn
Xn; R22 R: 22-38 Conc>=25%: Xn; R22; R38
10218-17-4 1,3-Dimethyl-1,3-bis(trimethylsilyl)urea Xi; R38 S: (2-)36/37 >=20%Conc<25%: Xi; R38 Eu - - - - - - - -
F; R11 F ; R: 11 - 19
10221-57-5 1,2-Diethoxypropane R19 S: (2)9 - 16 - 24 - 33 Eu - - - - - - - -
Conc>=25%: T+; R26/28; R24
>=7%Conc<25%: T+; R26/28; R21
>=3%Conc<7%: T; R23/25; R21
T+; R26/28 T+; N >=1%Conc<3%: T; R23/25
Methamidophos (ISO) [O,S-Dimethyl T; R24 R: 24-26/28-50 >=0.1%Conc<1%: Xn; R20/22
10265-92-6 phosphoramidothioate] N; R50 S: (1/2-)28-36/37-45-61 Eu - - - - - - - -
Conc>=10%: T+; R26/28; R35
>=7%Conc<10%: T+; R26/28; R34
R14 T+ ; C ; R: 14 - 26/28 - 35 , >=5%Conc<7%: T; R23/25; R34
T+; R26/28 S: (1/2) - 9 - 26 - 28 - >=1%Conc<5%: T; R23/25; R36/38 1 Peak 10 Peak
10294-33-4 Boron tribromide [Tribromoborane] C; R35 36/37/39 - 45 >=0.1%Conc<1%: Xn; R20/22 Eu; A Boron tribromide limitation limitation - - - - -
Conc>=5%: T+; R26/28; R34
>=1%Conc<5%: T+; R26/28; R37
R14 T+ ; R: 14 - 26/28 - 34 , >=0.5%Conc<1%: T; R23/25; R37
T+; R26/28 S: (1/2) - 9 - 26 - 28 - >=0.2%Conc<0.5%: T; R23/25
10294-34-5 Boron trichloride [Trichloroborane] C; R34 36/37/39 - 45 >=0.02%Conc<0.2%: Xn; R20/22 Eu - - - - - - - -

Conc>=25%: T; R45; R23; R22; R48/20; R43

Carc. Cat. 1; R45 >=10%Conc<25%: T; R45; R20; R48/20; R43
T; R23 >=3%Conc<10%: T; R45; R20; R43
Xn; R22-48/20 T >=1%Conc<3%: T; R45; R43
10294-40-3 Chromic acid (H2CrO4), barium salt (1:1) R43 R: 45-22-23-43-48/20 >=0.1%Conc<1%: T; R45 N - - - - - - - -

Conc>=25%: T; R45; R23; R22; R48/20; R43

Carc. Cat. 1; R45 >=10%Conc<25%: T; R45; R20; R48/20; R43
T; R23 >=3%Conc<10%: T; R45; R20; R43
Xn; R22-48/20 T >=1%Conc<3%: T; R45; R43
10294-52-7 Chromic acid (H2CrO4), iron(3+) salt (3:2) R43 R: 45-22-23-43-48/20 >=0.1%Conc<1%: T; R45 N - - - - - - - -
Conc>=25%: C; R22; R35
C >=10%Conc<25%: C; R35
Xn; R22 R: 22 - 35 >=5%Conc<10%: C; R34
10294-56-1 Phosphorous acid [Phosphonic acid see 13598-36-2] C; R35 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
T+; R28 T+ ; N ; R: 24 - 28 - 50/53 , >=3%Conc<7%: T; R25; R21
Dialifos (ISO) [2-Chloro-1-phthalimidoethyl o,o-diethyl T; R24 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<3%: T; R25
10311-84-9 phosphorodithioate] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 1; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
10325-94-7 Nitric acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Conc>=25%: T; R61; R62; R22; R37; R41
Perboric acid (HBO(O2)), sodium salt, monohydrate O; R8 >=22%Conc<25%: T; R61; R62; R37; R41
[Sodium peroxoborate](Note: containing < 0.1 % Repr. Cat. 2; R61 O; T >=20%Conc<22%: T; R61; R62; R36/37
(w/w) of particles with an aerodynamic diameter of Repr. Cat. 3; R62 R: 61-8-22-37-41-62 >=14%Conc<20%: T; R61; R62; R36
below 50 micrometres. See also CAS No. 15120-21- Xn; R22 S: 53-45 >=9%Conc<14%: T; R61; R62
10332-33-9 5, 11138-47-9, 12040-72-1 & 7632-04-4) Xi; R37-41 Note: E >=6.5%Conc<9%: T; R61 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R61; R62; R23; R22; R37; R41

>=22%Conc<25%: T; R61; R62; R20; R37;
O; R8 R41
Perboric acid (HBO(O2)), sodium salt, monohydrate Repr. Cat. 2; R61 >=20%Conc<22%: T; R61; R62; R20; R36/37
[Sodium peroxoborate](Note: containing >= 0.1 % Repr. Cat. 3; R62 O; T >=14%Conc<20%: T; R61; R62; R20; R36
(w/w) of particles with an aerodynamic diameter of T; R23 R: 61-8-22-23-37-41-62 >=9%Conc<14%: T; R61; R62; R20
below 50 micrometres. See also CAS No. 15120-21- Xn; R22 S: 53-45 >=6.5%Conc<9%: T; R61; R20
10332-33-9 5, 11138-47-9, 12040-72-1 & 7632-04-4) Xi; R37-41 Note: E >=3%Conc<6.5%: Xn; R20 Eu - - - - - - - -
Xn; R48/22 Xn ; N ; R: 43 - 48/22 -
N,N-Dimethyl-2-(3-(4-chlorophenyl)-4,5- R43 51/53 , Conc>=10%: Xn; R48/22; R43
10357-99-0 dihydropyrazol-1-ylphenylsulphonyl)ethylamine N; R51-53 S: (2) - 24 - 37 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
T; R25 T ; R: 20 - 25, Conc>=25%: T; R25, R20
10361-37-2 Barium chloride [Barium chloride (BaCl2)] Xn; R20 S: (1/2) - 45 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: T; R23
10380-28-6 Copper oxine T; R23 T ; R: 23 >=3%Conc<25%: Xn; R20 V - - - - - - - -
N
R: 50/53
10403-74-4 1,2-Bis(phenoxymethyl)benzene N; R50-53 S: 22-60-61 Eu - - - - - - - -
Xn; N
Resmethrin (ISO) [5-Benzyl-3-furylmethyl (±)-cis- Xn; R22 R: 22-50/53
10453-86-8 trans-chrysanthemate] N; R50-53 S: (2-)60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; N
Xn; R22 R; 22-51/53
10461-98-0 2-Cyclohexylidene-2-phenylacetonitrile N; R51-53 S: (2-)46-61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
10468-30-1 9-Octadecenoic acid, cadmium salt, (Z)- Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

Perboric acid (HBO(O2)), sodium salt, tetrahydrate Conc>=36%: T; R61; R62; R37; R41
[Sodium peroxoborate hexahydrate](Note: containing >=22%Conc<36%: T; R61; R62; R36/37
< 0.1 % (w/w) of particles with an aerodynamic Repr. Cat. 2; R61 T >=20%Conc<22%: T; R61; R62; R37
diameter of below 50 micrometres. See also CAS No. Repr. Cat. 3; R62 R: 61-37-41-62 >=14%Conc<20%: T; R61; R62
10486-00-7 13517-20-9 & 37244-98-7) Xi; R37-41 S: 53-45-47 >=10%Conc<14%: T; R61 Eu - - - - - - - -

Conc>=36%: T; R61; R62; R20; R37; R41

Perboric acid (HBO(O2)), sodium salt, tetrahydrate >=25%Conc<36%: T; R61; R62; R20; R36/37
[Sodium peroxoborate hexahydrate](Note: containing Repr. Cat. 2; R61 T >=22%Conc<25%: T; R61; R62; R36/37
>= 0.1 % (w/w) of particles with an aerodynamic Repr. Cat. 3; R62 R: 61-20-37-41-62 >=20%Conc<22%: T; R61; R62; R37
diameter of below 50 micrometres. See also CAS No. Xn; R20 S: 53-45-47 >=14%Conc<20%: T; R61; R62
10486-00-7 13517-20-9 & 37244-98-7) Xi; R37-41 Note: E >=10%Conc<14%: T; R61 Eu - - - - - - - -
Conc>=10%: T+; R26; R34
>=5%Conc<10%: T; R23; R34
O; R8 O; T+ >=1%Conc<5%: T; R23; R36/37/38
Dinitrogen tetraoxide(Note: see also CAS No. 10102- T+; R26 R: 8-26-34 >=0.5%Conc<1%: Xn; R20; R36/37/38
10544-72-6 44-0) C; R34 S: (1/2-)9-26-28-36/37/39-45 >=0.1%Conc<0.5%: Xn; R20 Eu - - - - - - - -
R14
C; R34 C; N
Xi; R37 R: 14-34-37-50 Conc>=10%: C; R34
10545-99-0 Sulphur dichloride [Sulfur dichloride] N; R50 S: (1/2-)26-45-61 >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -
Xn; R22
Xi; R36 Xn ; R: 22 - 36 - 52/53, Conc>=25%: Xn; R22, R36
10551-42-5 1-(3-Phenylpropyl)-2-methylpyridinium bromide R52-53 S: (2) - 26 - 36/37 - 61 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

O; R8
Carc. Cat. 1; R45
Muta. Cat. 2; R46 Conc>=25%: T+; R45; R46; R60; R61; R26;
Repr. Cat. 2; R60-61 R25; R48/23; R34; R21; R42/43
T+; R26 >=10%Conc<25%: T+; R45; R46; R60; R61;
T; R25-48/23 R26; R48/23; R34; R22; R42/43
C; R34 >=7%Conc<10%: T+; R45; R46; R60; R61;
Xn; R21 O; T+; N R26; R22; R48/20; R36/38; R42/43 Chromium (VI)
Chromic acid (H2Cr2O7), disodium salt [Sodium R42/43 R: 8-45-46-60-61-21-25-26- >=5%Conc<7%: T; R45; R46; R60; R61; R23; compounds (as
10588-01-9 dichromate] N; R50-53 34-42/43-48/23-50-53 R22; N/Eu; A Cr), water soluble - 0.05 - - - Sen -
R: 53
10591-85-2 Tetrakis(phenylmethyl)thioperoxydi(carbothioamide) R53 S: 61 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R36; R43
Xi; R36 R: 22-36-43 >=20%Conc<25%: Xi; R36; R43
10596-22-2 Tetraisopropyldichloromethylenebisphosphonate R43 S: (2-)24-26-37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Muta. Cat. 2; R46 T; N
Carbendazim (ISO) [Methyl benzimidazol-2- Repr.Cat.2; R60-61 R: 46-60-61-50/53 Conc>=0.5%: T; R60; R61; R46
10605-21-7 ylcarbamate] N; R50-53 S: 53-45-60-61 >=0.1%Conc<0.5%: T; R46 Eu - - - - - - - -
Conc>=25%: T; R23/25; R33
T; R23/25 T ; R: 23/25 - 33 , >=3%Conc<25%: Xn; R20/22; R33
11005-63-3 Strophantin-K R33 S: (1/2) - 45 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -

Tetrahydromethylphthalic anhydride(Note: see also Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

CAS No 1694-82-2; 3425-89-6; 5333-84-6; 26590-20- Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
11070-44-3 5; 34090-76-1 & 42498-58-80) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Chlorodiphenyl (54% Chlorine) [PCBs (54% PCBs (54%
11097-69-1 Chlorine); PCB-1254] A Chlorine) - 0.5 - 1 2 Sk -
Carc. Cat. 1; R49 Conc>=10%: T; R49; R48/23; R43
T; R48/23 T >=1%Conc<10%: T; R49; R48/20; R43
11099-02-8 Nickel oxide R43 R: 49-43-48/23 >=0.1%Conc<1%: T; R49 N - - - - - - - -

Carc. Cat. 1; R45 Conc>=25%: T; R45; R23; R22; R48/20; R43

T; R23 >=10%Conc<25%: T; R45; R20; R48/20; R43
Xn; R22-48/20 >=3%Conc<10%: T; R45; R20; R43
Chromate(1-), hydroxyoctaoxodizincatedi-, potassium R43 T; N >=1%Conc<3%: T; R45; R43 Zinc chromate (as
11103-86-9 [Zinc potassium chromate] N; R50-53 R: 45-22-23-43-48/20-50-53 >=0.1%Conc<1%: T; R45 N/Eu; A Cr) - 0.01 - - 1 - -

Carc. Cat. 1; R45 Conc>=25%: T; R45; R23; R22; R48/20; R43

T; R23 >=10%Conc<25%: T; R45; R20; R48/20; R43
Xn; R22-48/20 >=3%Conc<10%: T; R45; R20; R43
Chromate(1-), hydroxyoctaoxodizincatedi-, potassium R43 T; N >=1%Conc<3%: T; R45; R43 Zinc chromate (as
11103-86-9 [Zinc potassium chromate] N; R50-53 R: 45-22-23-43-48/20-50-53 >=0.1%Conc<1%: T; R45 N/Eu; A Cr) - 0.01 - - 1 - -

Carc. Cat. 1; R45 Conc>=25%: T; R45; R23; R22; R48/20; R43

T; R23 >=10%Conc<25%: T; R45; R20; R48/20; R43
Xn; R22-48/20 >=3%Conc<10%: T; R45; R20; R43
Chromate(1-), hydroxyoctaoxodizincatedi-, potassium R43 T; N >=1%Conc<3%: T; R45; R43 Zinc chromate (as
11103-86-9 [Zinc potassium chromate] N; R50-53 R: 45-22-23-43-48/20-50-53 >=0.1%Conc<1%: T; R45 N/Eu; A Cr) - 0.01 - - 1 - -
Carc. Cat. 1; R45 T ; N ; R: 45 - 22 - 43 -
Xn; R22 50/53, Conc>=25%: T; R45, R22, R43
R43 S: 53 - 45 - 60 - 61; >=1%Conc<25%: T; R45, R43 Zinc chromate (as
11103-86-9 Zinc potassium chromate N; R50-53 Notes: A ; E >=0.1%Conc<1%: T; R45 Eu; A Cr) - 0.01 - - 1 - -
Carc. Cat. 1; R45 T ; N ; R: 45 - 22 - 43 -
Xn; R22 50/53, Conc>=25%: T; R45, R22, R43
R43 S: 53 - 45 - 60 - 61; >=1%Conc<25%: T; R45, R43 Zinc chromate (as
11103-86-9 Zinc potassium chromate N; R50-53 Notes: A ; E >=0.1%Conc<1%: T; R45 Eu; A Cr) - 0.01 - - 1 - -
Carc. Cat. 1; R45 T ; N ; R: 45 - 22 - 43 -
Xn; R22 50/53, Conc>=25%: T; R45, R22, R43
R43 S: 53 - 45 - 60 - 61; >=1%Conc<25%: T; R45, R43 Zinc chromate (as
11103-86-9 Zinc potassium chromate N; R50-53 Notes: A ; E >=0.1%Conc<1%: T; R45 Eu; A Cr) - 0.01 - - 1 - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Boric acid, crude natural, containing not more than 85 T

per cent of H3BO3 calculated on the dry weight(Note: R: 60-61
11113-50-1 see also CAS No. 10043-35-3) Repr. Cat. 2; R60-61 S: 53-45 Conc>=5.5%: T; R60; R61 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
11120-22-2 Silicic acid, lead salt R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
Conc>=25%: T; R61; R62; R22; R37; R41
Perboric acid, sodium salt [Sodium O; R8 >=22%Conc<25%: T; R61; R62; R37; R41
peroxoborate](Note: containing < 0.1 % (w/w) of Repr. Cat. 2; R61 O; T >=20%Conc<22%: T; R61; R62; R36/37
particles with an aerodynamic diameter of below 50 Repr. Cat. 3; R62 R: 61-8-22-37-41-62 >=14%Conc<20%: T; R61; R62; R36
micrometres. See also CAS No. 15120-21-5, 12040- Xn; R22 S: 53-45 >=9%Conc<14%: T; R61; R62
11138-47-9 72-1, 7632-04-4 & 10332-33-9) Xi; R37-41 Note: E >=6.5%Conc<9%: T; R61 Eu - - - - - - - -

Conc>=25%: T; R61; R62; R23; R22; R37; R41

>=22%Conc<25%: T; R61; R62; R20; R37;
O; R8 R41
Perboric acid, sodium salt [Sodium Repr. Cat. 2; R61 >=20%Conc<22%: T; R61; R62; R20; R36/37
peroxoborate](Note: containing >= 0.1 % (w/w) of Repr. Cat. 3; R62 O; T >=14%Conc<20%: T; R61; R62; R20; R36
particles with an aerodynamic diameter of below 50 T; R23 R: 61-8-22-23-37-41-62 >=9%Conc<14%: T; R61; R62; R20
micrometres. See also CAS No. 15120-21-5, 12040- Xn; R22 S: 53-45 >=6.5%Conc<9%: T; R61; R20
11138-47-9 72-1, 7632-04-4 & 10332-33-9) Xi; R37-41 Note: E >=3%Conc<6.5%: Xn; R20 Eu - - - - - - - -
2.5
12001-26-2 Mica A Mica - (inspirable) - - - - -
T
Asbestos, crocidolite(Note: see also CAS No 132207- R: 45 - 48/23 Conc>=10%: T; R45; R48/23
32-0, 12172-73-5, 77536-66-4, 77536-67-5, 77536-68-Carc. Cat. 1; R45 S: 53 - 45; >=1%Conc<10%: T; R45; R48/20
12001-28-4 6, & 12001-29-5) T; R48/23 Note: E >=0.1%Conc<1%: T; R45 Eu; A Crocidolite (b) 0.1 f/mL (P) - - - 1 - -
T
Asbestos, chrysotile(Note: see also CAS No 132207- R: 49 - 48/23 Conc>=10%: T; R49; R48/23
32-0, 12172-73-5, 77536-66-4, 77536-67-5, 77536-68-Carc. Cat. 1; R49 S: 22 - 53 - 45; >=1%Conc<10%: T; R49; R48/20
12001-29-5 6 & 12001-28-4) T; R48/23 Note: E >=0.1%Conc<1%: T; R49 Eu/N; A Chrysotile (b) 0.1 f/mL - - - 1 - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Repr. Cat. 1; R61 Conc>=5%: T; R40; R61; R62; R68; R33
Repr. Cat. 3; R62 T >=1%Conc<5%: T; R40; R61; R68; R33
12013-69-3 Plumbate (PbO44-), calcium (1:2), (T-4)- R33 61-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 1; R49 T
R43 R: 49 - 43 - 53 Conc>=1%: T; R49; R43
12035-36-8 Nickel dioxide R53 S: 53 - 45 - 61 >=0.1%Conc<1%: T; R49 Eu - - - - - - - -
Carc. Cat. 1; R49 T; N
R43 R: 49 - 43 - 51/53 Conc>=1%: T; R49; R43
12035-72-2 Nickel subsulphide [Trinickel disulphide] N; R51-53 S: 53 - 45 - 61 >=0.1%Conc<1%: T; R49 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
12036-31-6 Lead tin oxide (PbSnO3) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
12036-76-9 Lead oxide sulfate (Pb2O(SO4)) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: T; R61; R62; R22; R37; R41
Perboric acid, sodium salt, monohydrate [Sodium O; R8 >=22%Conc<25%: T; R61; R62; R37; R41
peroxoborate](Note: containing < 0.1 % (w/w) of Repr. Cat. 2; R61 O; T >=20%Conc<22%: T; R61; R62; R36/37
particles with an aerodynamic diameter of below 50 Repr. Cat. 3; R62 R: 61-8-22-37-41-62 >=14%Conc<20%: T; R61; R62; R36
micrometres. See also CAS No. 15120-21-5, 11138- Xn; R22 S: 53-45 >=9%Conc<14%: T; R61; R62
12040-72-1 47-9, 7632-04-4 & 10332-33-9) Xi; R37-41 Note: E >=6.5%Conc<9%: T; R61 Eu - - - - - - - -

Conc>=25%: T; R61; R62; R23; R22; R37; R41

>=22%Conc<25%: T; R61; R62; R20; R37;
O; R8 R41
Perboric acid, sodium salt, monohydrate [Sodium Repr. Cat. 2; R61 >=20%Conc<22%: T; R61; R62; R20; R36/37
peroxoborate](Note: containing >= 0.1 % (w/w) of Repr. Cat. 3; R62 O; T >=14%Conc<20%: T; R61; R62; R20; R36
particles with an aerodynamic diameter of below 50 T; R23 R: 61-8-22-23-37-41-62 >=9%Conc<14%: T; R61; R62; R20
micrometres. See also CAS No. 15120-21-5, 11138- Xn; R22 S: 53-45 >=6.5%Conc<9%: T; R61; R20
12040-72-1 47-9, 7632-04-4 & 10332-33-9) Xi; R37-41 Note: E >=3%Conc<6.5%: Xn; R20 Eu - - - - - - - -

Carc. Cat. 1; R49

Muta. Cat. 3; R68 Conc>=25%: T; R49; R68; R48/23; R20/22;
T; R48/23 R43
Xn; R20/22 T; N >=10%Conc<25%: T; R49; R68; R48/23; R43
R43 R: 20/22-43-48/23-49-68-50- >=1%Conc<10%: T; R49; R68; R48/20; R43
12054-48-7 Nickel hydroxide (Ni(OH)2) [Nickel dihydroxide] N; R50-53 53 >=0.1%Conc<1%: T; R49 N/Eu - - - - - - - -
Xn
R: 40
12056-51-8 Potassium titanium oxide (K2Ti6O13) Carc.Cat.3; R40 S: (2-)22-36/37 Conc>=1%: Xn; R40 Eu - - - - - - - -
F; R15/29 F; T+; N Conc>=7%: T+; R28
T+; R28 R: 15/29-28-50 >=1%Conc<7%: T; R25
12057-74-8 Magnesium phosphide [Trimagnesium diphosphide] N; R50 S: (1/2-)22-28-43-45-61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
12060-00-3 Lead titanium oxide (PbTiO3) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
12065-90-6 Lead oxide sulfate (Pb5O4(SO4)) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -

Manganese
cyclopenta-dienyl
12079-65-1 Manganese cyclopenta dienyl tricarbonyl (as Mn) A tricarbonyl (as Mn) - 0.1 - - - Sk -
F ; C ; R: 11 - 14/15 - 20 - Conc>=25%: C; R35; R20
F; R11-14/15 35 , >=10%Conc<25%: C; R35
C; R35 S: (1/2) - 16 - 30 - 36/39 - >=5%Conc<10%: C; R34
12091-08-6 Potassium mu-fluoro bis(triethylaluminium) Xn; R20 43 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

Conc>=25%: T+; R26/28; R24; R48/23

>=10%Conc<25%: T+; R26/28; R21; R48/23
>=7%Conc<10%: T+; R26/28; R21; R48/20
Methylcyclopentadienyl manganese tricarbonyl >=3%Conc<7%: T; R23/25; R21; R48/20 Methylcyclopentadi
[Manganese tricarbonyl [(1,2,3,4,5-eta)-1-methyl-2,4- T+; R26/28 >=1%Conc<3%: T; R23/25; R48/20 enyl manganese
12108-13-3 cyclopentadien-1-yl] T; R24-48/23 T+ ; R: 24 - 26 - 28 - 48/23 >=0.1%Conc<1%: Xn; R20/22 N; A tricarbonyl (as Mn) - 0.2 - - - Sk -
Xi; R37 Xi ; R: 37 - 43 , Conc>=20%: Xi; R43, R37
12122-67-7 Zineb R43 S: (2) - 8 - 24/25 - 46 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
T ; R: 23/24/25 , Conc>=25%: T; R23/24/25
12125-01-8 Ammonium fluoride T; R23/24/25 S: (1/2) - 26 - 45 >=3%Conc<25%: Xn; R20/21/22 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 36 , Conc>=25%: Xn; R22, R36 Ammonium
12125-02-9 Ammonium chloride Xi; R36 S: (2) - 22 >=20%Conc<25%: Xi; R36 Eu; A chloride (fume) - 10 - 20 - - -

Page 173
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
12141-20-7 Lead oxide phosphonate (Pb3O2(HPO3)) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
Xi; R41 Xn ; R: 22 - 41 - 52/53 >=10%Conc<25%: Xi; R41
12141-67-2 Hexasodium dihydrogen-dodecawolframate R52-53 S: (2)22 - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Conc>=10%: C; R34; R43
Xi; R43 >=5%Conc<10%: Xi; R36/38; R43
12160-30-4 Potassium ferrite (K2Fe10O16) C; R34 C; R: 34 - 43 >=1%Conc<5%: Xi; R43 N - - - - - - - -
C
R: 34-43 Conc>=10%: C; R34; R43
C; R34 S: (1/2-)22-26-36/37/39-40- >=5%Conc<10%: Xi; R36/38; R43
12160-44-0 Potassium ferrite R43 45 >=1%Conc<5%: Xi; R43 Eu/N - - - - - - - -
Asbestos, amosite [Grunerite](Note: see also CAS T ; R: 45 - 48/23 , Conc>=10%: T; R45; R48/23
No 132207-32-0, 77536-66-4, 77536-67-5, 77536-68- Carc. Cat. 1; R45 S: 53 - 45; >=1%Conc<10%: T; R45; R48/20
12172-73-5 6, 12001-28-4, & 12001-29-5) T; R48/23 Note: E >=0.1%Conc<1%: T; R45 Eu Amosite (b) 0.1 f/mL (P) - - - 1 - -
T Borates, tetra,
Disodium tetraborate pentahydrate [Borax R: 60-61 sodium salts
12179-04-3 pentahydrate] Repr. Cat. 2; R60-61 S: 53-45 Conc>=6.5%: T; R60; R61 Eu;A (pentahydrate) - 1 - - - - -
Conc>=10%: T+; R26/28; R35
F; R17 F ; T+ ; C ; N ; R: 17 - 26/28 - >=7%Conc<10%: T+; R26/28; R34
T+; R26/28 35 - 50, >=5%Conc<7%: T; R23/25; R34
C; R35 S: (1/2) - 5 - 26 - 28 - 45 - >=1%Conc<5%: T; R23/25; R36/38
12185-10-3 Phosphorus, white N; R50 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
12202-17-4 Lead oxide sulfate (Pb4O3(SO4)) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -

Xi; R43 This substance has only

been assessed against the single
C.I. Basic Red 46 [3(or5)-((4- endpoint of skin sensitisation.
(Benzylmethylamino)phenyl)azo)-1,2-(or1,4)-dimethyl- This substance has not been
1H-1,2,4-triazolium bromide; Basic Red 46; Synacril subject to a complete assessment
Red; Anilan Red; Astrazon Red; Kayacryl Red; for hazard classification in
Maxilon Red](Note: also distributed under CAS No. accordance with the approved
12221-69-1 89959-98-8) criteria. Xi; R:43 Conc>=1%: Xi; R43 N - - - - - - - -
Mixture of: 1,4-diamino-2-chloro-3-
phenoxyanthraquinone and 1,4-diamino-2,3-bis- R: 53
12223-77-7 phenoxyanthraquinone R53 S: 61 Eu - - - - - - - -

E; R3 E; C
O; R7 R: 3-7-22-34 Conc>=25%: C; R34; R22;
Cyclohexanone peroxide(Note: see also CAS No. 78- C; R34 S: (1/2-)3/7-14-36/37/39-45 >=10%Conc<25%: C; R34
12262-58-7 18-2, 2407-94-5 & 2699-11-8) Xn; R22 Note: C >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -
T
Tetraboron disodium heptaoxide, hydrate(Note: see R: 60-61
12267-73-1 also CAS No. 1330-43-4 & 13840-56-7) Repr. Cat. 2; R60-61 S: 53-45 Conc>=4.5%: T; R60; R61 Eu - - - - - - - -
12280-03-4 Disodium octaborate tetrahydrate Repr. Cat. 2; R60-61 T ; R: 60-61 Conc>=5%: T; R60; R61 V - - - - - - - -
Repr. Cat. 3; R63
Xn; R20 Conc>=25%: Xn; R63; R20; R36; R43
Xi; R36 Xn; N >=20%Conc<25%: Xn; R63; R36; R43
Maneb (ISO) [Manganese R43 R: 20-36-43-63-50/53 >=5%Conc<20%: Xn; R63; R43
12427-38-2 ethylenebis(dithiocarbamate) (polymeric)] N; R50-53 S: (2-)36/37-46-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
T ; R: 45,
12510-42-8 Erionite Carc. Cat. 1; R45 S: 53 - 45 Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 174
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
12578-12-0 Lead, bis(octadecanoato)dioxotri- R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Ferrovanadium
12604-58-9 Ferrovanadium dust A dust - 1 - 3 - - -

Conc>=25%: T; R45; R61; R62; R68; R23;

Carc. Cat. 2; R45 R48/20; R43; R33
Muta. Cat. 3; R68 >=10%Conc<25%: T; R45; R61; R62; R68;
Repr. Cat. 1; R61 R20; R48/20; R43; R33
Repr. Cat. 3; R62 >=5%Conc<10%: T; R45; R61; R62; R68; R20;
T; R23 R43; R33
Xn; R48/20 >=3%Conc<5%: T; R45; R61; R68; R20; R43;
R33 T; N R33
C.I. Pigment Red 104 [Lead chromate molybdate R43 R: 45-61-23-33-43-48/20-62- >=1%Conc<3%: T; R45; R61; R68; R43; R33
12656-85-8 sulfate red] N; R50-53 68-50-53 >=0 N/Eu - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
13001-15-5 9-Octadecenoic acid, nickel(2+) salt, (Z)- R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
Xi; R38 Xi ; N ; R: 38 - 51/53 ,
13019-04-0 2,4-Di-tert-butylcyclohexanone N; R51-53 S: (2) - 37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xi ; R: 36/38 - 43 ,
Hexamethylene diacrylate [Hexane-1,6-diol Xi; R36/38 S: (2) - 39 ; Conc>=20%: Xi; R36/38; R43
13048-33-4 diacrylate] R43 Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T; R25; R39/25; R21; R36
T; R25-39/25 >=20%Conc<25%: T; R39/25; R22; R36
Xn; R21 T; N >=10%Conc<20%: T; R39/25; R22
Cyanofenphos (ISO) [O-4-Cyanophenyl O-ethyl Xi; R36 R: 21-25-36-39/25-51/53 >=3%Conc<10%: Xn; R22; R68/22
13067-93-1 phenylphosphonothioate] N; R51-53 S: (1/2-)36/37-45-61 >=1%Conc< 3%: Xn; R68/22 Eu - - - - - - - -
T+; N Conc>=7%: T+; R27/28
Terbufos (ISO) [S-tert-Butylthiomethyl O,O- T+; R27/28 R: 27/28-50/53 >=1%Conc<7%: T; R24/25
13071-79-9 diethylphosphorodithioate] N; R50-53 S: (1/2-)36/37-45-60-61 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
9-Octadecenoic acid, 12-hydroxy-, lead(2+) salt (2:1), Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
13094-04-7 [R-(Z)]- R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xn; R21/22 Conc>=25%: Xn; R21/22; R36; R43
Methyl-2,3,5,6-tetrachloro-4-pyridylsulphone [2,3,5,6- Xi; R36 Xn ; R: 21/22 - 36 - 43 , >=20%Conc<25%: Xi; R36; R43
13108-52-6 Tetrachloro-4-(methylsulphonyl)pyridine] R43 S: (2) - 26 - 28 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn; N Tin, organic
Cyhexatin (ISO) [Hydroxytricyclohexylstannane; Xn; R20/21/22 R: 20/21/22-50/53 compounds (as
13121-70-5 Tri(cyclohexyl)tin hydroxide] N; R50-53 S: (2-)13-60-61 Conc>=25%: Xn; R20/21/22 Eu;A Sn) - 0.1 - 0.2 - Sk -

Erythromycin A9-oxime (E)

[(3R,4S,5S,6R,7R,9R,11R,12R,13S,14R)-4-((2,6-
Didesoxy-3-C-methyl-3-O-methyl-alpha-L-ribo-
hexopiranosyl)oxy)-14-ethyl-7,12,13-trihydroxy-
3,5,7,9,11,13-hexamethyl-6-((3,4,6-tridesoxy-3-
dimethylamino-beta-D- N
xylohexapiranosyl)oxy)oxacyclotetradecan-2-ona-10- R: 51/53
13127-18-9 oxime (E)] N; R51-53 S: 61 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

O; R8 Conc>=25%: T; R49; R61; R68; R48/23;

Carc. Cat. 1; R49 R20/22; R38; R41; R42/43
Muta. Cat. 3; R68 >=20%Conc<25%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R38; R41; R42/43
T; R48/23 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Xn; R20/22 R41; R42/43
Xi; R38-41 O; T; N >=5%Conc<10%: T; R49; R61; R68; R48/20;
R42/43 R: 8-49-61-20/22-38-41- R36; R42/43 Nickel, soluble
13138-45-9 Nitric acid, nickel(2+) salt [Nickel dinitrate] N; R50-53 42/43-48/23-68-50-53 >=1%Conc<5%: T; R49; R61; R68; N/Eu; A compounds (as Ni) - 0.1 - - - Sen -

Xn ; R: 41 - 42/43 , Conc>=10%: Xn; R42/43; R41

cis-Cyclohexane-1,2-dicarboxylic anhydride(Note: Xi; R41 S: (2) - 23 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
13149-00-3 see also CAS No 85-42-7 & 14166-21-3) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Ethanol, 2-[2-[2-(dodecyloxy)ethoxy]ethoxy]-, Xn; R22 Xn Conc>=25%: Xn; R22; R36/38
13150-00-0 hydrogen sulfate, sodium salt Xi; R36/38 R: 22-36/38 >=20%Conc<25%: Xi; R36/38 N - - - - - - - -
Conc>=25%: T+; R68; R28; R24
T+; R28 T+ ; N ; R: 24 - 28 - 50/53 - >=7%Conc<25%: T+: R68; R28; R21
T; R24 68 , >=3%Con<7%: T; R68; R25; R21
Phosphamidon [2-Chloro-2-diethylcarbamoyl-1- Muta. Cat. 3; R68 S: (1/2) - - 23 - 36/37 - 45 - >=1%Conc<3%: T; R68; R25
13171-21-6 methylvinyl dimethyl phosphate] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
Xn; N
Bromofenoxim (ISO) [3,5-Dibromo-4- Xn; R22 R: 22 - 50/53
13181-17-4 hydroxybenzaldehyde-O-(2,4-dinitrophenyl)oxime] N; R50-53 S: (2) - 25 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: T+; R26/27; R25; R43
T+; R26/27 T+; N >=7%Conc<25%: T+; R26/27; R22; R43
T; R25 R: 25-26/27-43-50/53 >=3%Conc<7%: T; R23/24; R22; R43
Ethoprophos (ISO) [Ethyl-S,S-dipropyl R43 S: (1/2-)27/28-36/37/39-45- >=1%Conc<3%: T; R23/24; R43
13194-48-4 phosphorodithioate] N; R50-53 60-61 >=0.1%Conc<1%: Xn; R20/21 Eu - - - - - - - -
1-Dodecanaminium, N-(2-hydroxy-3-sulfopropyl)-N,N- Xi
13197-76-7 dimethyl-, inner salt Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
F ; C ; N ; R: 11 - 20/22 - 35 -
F; R11 50 , Conc>=25%: C; R35; R20/22
Xn; R20/22 S: (1/2) - 9 - 16 - 26 - 28 - >=10%Conc<25%: C; R35
(R)-sec-Butylamine [(R)-2-Aminobutane](Note: see C; R35 36/37/39 - 45 - 61; >=5%Conc<10%: C; R34
13250-12-9 also CAS No 513-49-5 & 13952-84-6) N; R50 Note: C >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
N
17-spiro(5,5-Dimethyl-1,3-dioxan-2-yl)androsta-1,4- R: 50/53
13258-43-0 diene-3-one N; R50-53 S: 22-60-61 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R41
Xi; R41 R: 22-41-52/53 >=10%Conc<25%: Xi; R41
13335-71-2 (2,6-Xylyloxy) acetic acid R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T+ ; N ; R: 26 - 36/38 - Conc>=20%: T+; R26; R36/38
T+; R26 50/53, >=7%Conc<20%: T+; R26 Tin, organic
Fenbutatin oxide (ISO) [Bis(tris(2-methyl-2- Xi; R36/38 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R23 compounds (as
13356-08-6 phenylpropyl)tin)oxide] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu Sn) - 0.1 - 0.2 - Sk -
Conc>=25%: T+; R45; R26; R34; R21/22
>=10%Conc<25%: T+; R45; R26; R34
Carc. Cat. 2; R45 >=7%Conc<10%: T+; R45; R26; R36/38
T+; R26 T+ ; R: 45 - 21/22 - 26 - 34 , >=5%Conc<7%: T; R45; R23; R36/38
Xn; R21/22 S: 53 - 45 ; >=1%Conc<5%: T; R45; R23
13360-57-1 Dimethylsulfamoyl chloride C; R34 Note: E >=0.1%Conc<1%: T; R45; R20 Eu - - - - - - - -

Selenium
Conc >=25%: T; R23/25, R33 compounds (as
T; R23/25 >=3%Conc<25%: Xn; R20/22, R33 Se) excluding
13410-01-0 Sodium selenate R33 T ; R: 23/25 - 33 >=1% Conc<3%: Xn; R33 V hydrogen selenide - 0.1 - - - - -

Carc. Cat. 1; R45 Conc>=25%: T+; R45; R46; R60; R61; R26;
Muta. Cat. 2; R46 R25; R48/23; R34; R21; R42/43
Repr. Cat. 2; R60-61 >=10%Conc<25%: T+; R45; R46; R60; R61;
T+; R26 R26; R48/23; R34; R22; R42/43
T; R25-48/23 >=7%Conc<10%: T+; R45; R46; R60; R61;
C; R34 T+ R26; R22; R48/20; R36/38; R42/43
Xn; R21 R: 45-46-60-61-21-25-26-34- >=5%Conc<7%: T; R45; R46; R60; R61; R23;
13423-61-5 Chromic acid (H2CrO4), magnesium salt (1:1) R42/43 42/43-48/23 R22; N - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
E; R3
Repr. Cat. 1; R61
Repr. Cat. 3; R62. E ; T ; N ; R: 61 - 62 - 3 - Conc>=25%: T; R61; R62; R20/22 ; R33
Xn; R20/22 20/22 - 33 - 50/53, >=5%Conc<25%: T; R61; R62; R33
R33 S: 53 - 45 - 60 - 61; >=1%Conc<5%: T; R61; R33
13424-46-9 Lead azide [Lead diazide] N; R50-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
R14 C; N
C; R34 R: 14-34-50 Conc>=10%: C; R34
13451-08-6 Sulphur tetrachloride [Sulfur tetrachloride] N; R50 S: (1/2-)26-45-61 >=5%Conc<10%: Xi; R36/37/38 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
13453-65-1 Phosphonic acid, lead(2+) salt (1:1) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
13453-66-2 Diphosphoric acid, lead(2+) salt (1:2) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -

Pyrazophos (ISO) [O,O-Diethyl O-(6-ethoxycarbonyl- Xn; N

5-methylpyrazolo(2,3-a) pyrimidin-2-yl) Xn; R20/22 R: 20/22 - 50/53
13457-18-6 phosphorothioate] N; R50-53 S: (2) - 36/37 - 46 - 60 - 61 Conc>=25%: Xn; R20/22 Eu - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
13462-88-9 Nickel bromide (NiBr2) R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
F; R11
Carc. Cat. 3; R40 F ; T+ ; N ; R: 61 - 11 - 26 - Conc>=7%: T+; R40; R61; R26
Repr. Cat. 2; R61 40 - 50/53, >=1%Conc<7%: T; R40; R61; R23
T+; R26 S: 53 - 45 - 60 - 61 >=0.5%Conc<1%: T; R61; R20 Nickel carbonyl (as
13463-39-3 Nickel carbonyl [Nickel tetracarbonyl] N; R50-53 Note: E >=0.1%Conc<0.5%: Xn; R20 Eu; A Ni) 0.05 0.12 - - - - -

Iron pentacarbonyl
13463-40-6 Iron pentacarbonyl (as Fe) [Pentacarbonyliron] A (as Fe) 0.1 0.23 0.2 0.45 - - -
Conc>=25%: T+; R26; R22; R41
>=10%Conc<25%: T+; R26; R41
>=7%Conc<10%: T+; R26; R36
T+; R26 >=5%Conc<7%: T; R23; R36
Xn; R22 >=1%Conc<5%: T; R23
13463-41-7 Zinc pyrithione Xi; R41 T+ ; R22 - 26 - 41 >=0.1%Conc<1%: Xn; R20 V - - - - - - - -

Conc>=25%: T; R45; R63; R68; R23/25; R21;

R48/20/21/22
>=10%Conc<25%: T; R45; R63; R68; R20/22;
Carc. Cat. 1; R45 R48/20/21/22
Muta. Cat. 3; R68 >=5%Conc<10%: T; R45; R63; R68; R20/22
Repr. Cat. 3; R63 T >=3%Conc<5%: T; R45; R68; R20/22
T; R23/25 R: 45-21-23/25-48/20/21/22- >=1%Conc<3%: T; R45; R68
13464-38-5 Arsenic acid (H3AsO4), trisodium salt Xn; R21-48/20/21/22 63-68 >=0.1%Conc<1%: T; R45 N - - - - - - - -

Page 177
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%; T; R45; R68; R23/24/25; R48/25;

R43
>=10%Conc<25%; T; R45; R68; R48/25;
R20/21/22; R43
Carc. Cat. 2; R45 >=3%Conc<10%; T; R45; R68; R20/21/22;
Muta. Cat. 3; R68 R48/22; R43
T; R23/24/25-48/25 T >=1%Conc<3%; T; R45; R68; R48/22; R43
13464-80-7 Hydrazine, sulfate (2:1) R43 R: 45-23/24/25-43-48/25-68 >=0.1%Conc<1%; T; R45 N - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 1; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
13464-92-1 Cadmium bromide, tetrahydrate Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

E; R2 Conc>=25%: T; R40; R24; R22; R48/22;

Carc. Cat. 3; R40 R36/38; R43
T; R24 >=20%Conc<25%: Xn; R40; R21; R48/22;
Xn; R22-48/22 E; T; N R36/38; R43
Xi; R36/38 R: 2-22-24-36/38-40-43- >=10%Conc<20%: Xn; R40; R21; R48/22; R43
R43 48/22-50 >=3%Conc<10%: Xn; R40; R21; R43
13465-08-2 Hydroxylammonium nitrate N; R50 S: (1/2-)26-36/37-45-61 >=1%Conc<3%: Xn; R40; R43 Eu - - - - - - - -
O; R9 O ; Xn ; R: 9 - 20/22 ,
13465-95-7 Barium perchlorate Xn; R20/22 S: (2) - 27 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Conc>=25%: C; R35; R22; R48/22
Xn; R22-48/22 C ; R: 22 - 35 - 48/22 - 52/53 >=10%Conc<25%: C; R35; R48/22
C; R35 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%: C; R34
13474-64-1 4,4'-Methylenebis(N,N'-dimethylcyclohexanamine) R52-53 61 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
O; R9 O; Xn; N
Xn; R20/22 R: 9-20/22-51/53
13477-00-4 Barium chlorate N; R51-53 S: (2-)13-27-61 Conc>=25%: Xn; R20/22 Eu - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R41; R42/43
Carc. Cat. 1; R49 >=20%Conc<25%: T; R49; R61; R68; R48/23;
Muta. Cat. 3; R68 R38; R41; R42/43
Repr. Cat. 2; R61 >=10%Conc<20%: T; R49; R61; R68; R48/23;
T; R48/23 R41; R42/43
Xn; R20/22 T >=5%Conc<10%: T; R49; R61; R68; R48/20;
Xi; R38-41 R: 49-61-20/22-38-41-42/43- R36; R42/43
13478-00-7 Nitric acid, nickel(2+) salt, hexahydrate R42/43 48/23-68 >=1%Conc<5%: T; R49; R61; R68; N - - - - - - - -
Tellurium &
compounds (as
13494-80-9 Tellurium & compounds (as Te) A Te) - 0.1 - - - - -

Conc>=25%: T+; R26; R21/22; R37/38; R41

>=20%Conc<25%: T+; R26 R37/38; R41
>=10%Conc<20%: T+; R26; R41
T+; R26 T+; N >=7%Conc<10%: T+; R26; R36
Xn; R21/22 R: 21/22-26-37/38-41-50/53 >=5%Conc<7%: T; R23; R36
Guazatine [Guanidine, N,N'''-(iminodi-8,1- Xi; R37/38-41 S: (1/2-)26-28-36/37/39-38- >=1%Conc<5% : T; R23
13516-27-3 octanediyl)bis}] N; R50-53 45-46-60-61-63 >=0.1%Conc<1% Xn; R20 Eu - - - - - - - -

Perboric acid (H3BO2(O2)), monosodium salt Conc>=36%: T; R61; R62; R37; R41
trihydrate [Sodium peroxoborate hexahydrate](Note: >=22%Conc<36%: T; R61; R62; R36/37
containing < 0.1 % (w/w) of particles with an Repr. Cat. 2; R61 T >=20%Conc<22%: T; R61; R62; R37
aerodynamic diameter of below 50 micrometres. See Repr. Cat. 3; R62 R: 61-37-41-62 >=14%Conc<20%: T; R61; R62
13517-20-9 also CAS No. 37244-98-7 & 10486-00-7) Xi; R37-41 S: 53-45-47 >=10%Conc<14%: T; R61 Eu - - - - - - - -

Page 178
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=36%: T; R61; R62; R20; R37; R41

Perboric acid (H3BO2(O2)), monosodium salt >=25%Conc<36%: T; R61; R62; R20; R36/37
trihydrate [Sodium peroxoborate hexahydrate](Note: Repr. Cat. 2; R61 T >=22%Conc<25%: T; R61; R62; R36/37
containing >= 0.1 % (w/w) of particles with an Repr. Cat. 3; R62 R: 61-20-37-41-62 >=20%Conc<22%: T; R61; R62; R37
aerodynamic diameter of below 50 micrometres. See Xn; R20 S: 53-45-47 >=14%Conc<20%: T; R61; R62
13517-20-9 also CAS No. 37244-98-7 & 10486-00-7) Xi; R37-41 Note: E >=10%Conc<14%: T; R61 Eu - - - - - - - -

Conc>=25%: T; R45; R23; R22; R48/20; R43

Carc. Cat. 1; R45 >=10%Conc<25%: T; R45; R20; R48/20; R43
T; R23 >=3%Conc<10%: T; R45; R20; R43
Chromic acid (H2CrO4), zinc salt (1:1) [Zinc Xn; R22-48/20 T >=1%Conc<3%: T; R45; R43 Zinc chromate (as
13530-65-9 chromate] R43 R: 45-22-23-43-48/20 >=0.1%Conc<1%: T; R45 N; A Cr) - 0.01 - - 1 - -

Conc>=25%: T; R45; R23; R22; R48/20; R43

Carc. Cat. 1; R45 >=10%Conc<25%: T; R45; R20; R48/20; R43
T; R23 >=3%Conc<10%: T; R45; R20; R43
Chromic acid (H2CrO4), zinc salt (1:1) [Zinc Xn; R22-48/20 T >=1%Conc<3%: T; R45; R43 Zinc chromate (as
13530-65-9 chromate] R43 R: 45-22-23-43-48/20 >=0.1%Conc<1%: T; R45 N; A Cr) - 0.01 - - 1 - -

Conc>=25%: T; R45; R23; R22; R48/20; R43

Carc. Cat. 1; R45 >=10%Conc<25%: T; R45; R20; R48/20; R43
T; R23 >=3%Conc<10%: T; R45; R20; R43
Chromic acid (H2CrO4), zinc salt (1:1) [Zinc Xn; R22-48/20 T >=1%Conc<3%: T; R45; R43 Zinc chromate (as
13530-65-9 chromate] R43 R: 45-22-23-43-48/20 >=0.1%Conc<1%: T; R45 N; A Cr) - 0.01 - - 1 - -

Conc>=25%: T+; R45; R60; R61; R26; R24/25;

R48/23; R35; R42/43
Carc. Cat. 1; R45 >=10%Conc<25%: T+; R45; R60; R61; R26;
Repr. Cat. 2; R60-61 R48/23; R35; R21/22; R42/43
T+; R26 >=7%Conc<10%: T+; R45; R60; R61; R26;
T; R24/25-48/23 T+; C R34; R21/22; R48/20; R42/43
C; R35 R: 45-60-61-24/25-26-35- >=5%Conc<7%: T; R45; R60; R61; R23; R34;
13530-68-2 Chromic acid (H2Cr2O7) R42/43 42/43-48/23 R21/22; R48/20; R4 N - - - - - - - -

Quinalphos (ISO) T; R25 T; N

Xn; R21 R: 21-25-50/53 Conc>=25%: T; R25; R21
13593-03-8 [O,O-Diethyl-O-quinoxalin-2-yl phosphorothioate] N; R50-53 S: (1/2-)22-36/37-45-60-61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Repr.Cat.3; R62 Xn; N
4,4'-(1,3-Phenylene-bis(1-methylethylidene))bis- R43 R: 43-62-51/53 Conc>=5%: Xn; R62; R43
13595-25-0 phenol N; R51-53 S: (2-)22-36/37-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Conc>=25%: C; R22; R35
C >=10%Conc<25%: C; R35
Xn; R22 R: 22 - 35 >=5%Conc<10%: C; R34
13598-36-2 Phosphonic acid [Phosphorous acid see 10294-56-1] C; R35 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Xn
R: 40
13674-87-8 Tris[2-chloro-1-(chloromethyl)ethyl] phosphate Carc. Cat. 3; R40 S: (2-)36/37 Conc>=1%: Xn; R40 Eu - - - - - - - -
N
Desmedipham [Ethyl 3- R: 50/53
13684-56-5 phenylcarbamoyloxyphenylcarbamate] N; R50-53 S: 60-61 Eu - - - - - - - -
N
Phenmedipham [Methyl 3-(3- R: 50/53
13684-63-4 methylcarbaniloyloxy)carbanilate (ISO)] N; R50-53 S: 60-61 Eu - - - - - - - -

Carc. Cat. 1; R45 Conc>=25%: T; R45; R23; R22; R48/20; R43

T; R23 >=10%Conc<25%: T; R45; R20; R48/20; R43
Xn; R22-48/20 >=3%Conc<10%: T; R45; R20; R43
Chromic acid (H2CrO4), calcium salt (1:1) [Calcium R43 T; N >=1%Conc<3%: T; R45; R43
13765-19-0 chromate] N; R50-53 R: 45-22-23-43-48/20-50-53 >=0.1%Conc<1%: T; R45 N/Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
13770-89-3 Sulfamic acid, nickel(2+) salt (2:1) R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
Trisodium hexafluoroaluminate [Aluminate(3-),
hexafluoro-trisodium, (OC-6-11); Sodium Xn; R20 T; N Conc>=25%: T; R48/23/25; R20
hexafluoroaluminate](Note: see also CAS No 15096- T; R48/23/25 R: 20-48/23/25-51/53 >=10%Conc<25%: T; R48/23/25
13775-53-6 52-3) N; R51-53 S: (1/2-)22-37-45-61 >=1%Conc<10%: Xn; R48/20/22 Eu - - - - - - - -

Conc>=25%; T; R45; R68; R23/24/25; R48/25;

R43
>=10%Conc<25%; T; R45; R68; R48/25;
R20/21/22; R43
Carc. Cat. 2; R45 >=3%Conc<10%; T; R45; R68; R20/21/22;
Muta. Cat. 3; R68 R48/22; R43
T; R23/24/25-48/25 T >=1%Conc<3%; T; R45; R68; R48/22; R43
13775-80-9 Hydrazine, monohydrobromide R43 R: 45-23/24/25-43-48/25-68 >=0.1%Conc<1%; T; R45 N - - - - - - - -

Conc>=25%: T; R25; R42/43; R41; R38

>=20%Conc<25%: Xn; R22; R42/43; R41; R38
>=10%Conc<20%: Xn; R22; R42/43; R41
T; R25 T ; R: 25 - 38 - 41 - 42/43, >=5%Conc<10%: Xn; R22; R42/43; R36
Ammonium tetrachloroplatinate [Diammonium Xi; R38-41 S: (2) - 22 - 26 - 36/37/39 - >=3%Conc<5%: Xn; R22; R42/43
13820-41-2 tetrachloroplatinate] R42/43 45 >=1%Conc<3%: Xn; R42/43 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
9-Octadecenoic acid, 12-hydroxy-, cadmium salt T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
13832-25-2 (2:1), [R-(Z)]- Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
13838-16-9 Enflurane A Enflurane 0.5 3.8 - - - - -
T
Orthoboric acid, sodium salt(Note: see also CAS No. R: 60-61
13840-56-7 1330-43-4 & 12267-73-1) Repr. Cat. 2; R60-61 S: 53-45 Conc>=4.5%: T; R60; R61 Eu - - - - - - - -
Xn
Xn; R22-48/22 R: 22-48/22-52/53 Conc>=25%: Xn; R22; R48/22
13909-63-2 1-Phenyl-3-(p-toluenesulfonyl)urea R52-53 S: (2-)22-36-61 >=10%Conc<25%: Xn; R48/22 Eu - - - - - - - -

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R41; R42/43
Carc. Cat. 1; R49 >=20%Conc<25%: T; R49; R61; R68; R48/23;
Muta. Cat. 3; R68 R38; R41; R42/43
Repr. Cat. 2; R61 >=10%Conc<20%: T; R49; R61; R68; R48/23;
T; R48/23 R41; R42/43
Xn; R20/22 T >=5%Conc<10%: T; R49; R61; R68; R48/20;
Xi; R38-41 R: 49-61-20/22-38-41-42/43- R36; R42/43
13940-83-5 Nickel fluoride (NiF2), tetrahydrate R42/43 48/23-68 >=1%Conc<5%: T; R49; R61; R68; N - - - - - - - -
F ; C ; N ; R: 11 - 20/22 - 35 -
F; R11 50 , Conc>=25%: C; R35; R20/22
Xn; R20/22 S: (1/2) - 9 - 16 - 26 - 28 - >=10%Conc<25%: C; R35
sec-Butylamine [2-Aminobutane](Note: see also CAS C; R35 36/37/39 - 45 - 61; >=5%Conc<10%: C; R34
13952-84-6 No 13250-12-9 & 513-49-5) N; R50 Note: C >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

Xn ; R: 41 - 42/43 , Conc>=10%: Xn; R42/43; R41

trans-Cyclohexane-1,2-dicarboxylic anhydride(Note: Xi; R41 S: (2) - 23 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
14166-21-3 see also CAS No 85-42-7 & 13149-00-3) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R41; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
R38; R41; R42/43
O; R8 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R41; R42/43
Muta. Cat. 3; R68 >=5%Conc<10%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R36; R42/43
T; R48/23 O; T; N >=1%Conc<5%: T; R49; R61; R68; R48/23;
Xn; R20/22 R: 49-61-8-20/22-38-41- R42/43
Xi; R38-41 42/43-48/23-68-50/53 >=0.5%Conc<1%: T; R49; R61; R48/20; R43
Nitric acid, nickel salt(Note: see also CAS No. 13138- R42/43 S: 53-45-60-61 >=0.1%Conc<0.5%: T; R49; R48/20; R43 Nickel, soluble
14216-75-2 45-9) N; R50-53 Note: E >=0.01%Conc<0.1%: Xi; R43 Eu;A compounds (as Ni) - 0.1 - - - Sen -
Fenazaflor (ISO) [Phenyl 5,6-dichloro-2- Xn; R21/22 Xn ; N ; R: 21/22 - 50/53,
14255-88-0 trifluoromethylbenzimidazole-1-carboxylate] N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -

Carc. Cat. 1; R45 Conc>=25%: T+; R45; R46; R60; R61; R26;
Muta. Cat. 2; R46 R25; R48/23; R34; R21; R42/43
Repr. Cat. 2; R60-61 >=10%Conc<25%: T+; R45; R46; R60; R61;
T+; R26 R26; R48/23; R34; R22; R42/43
T; R25-48/23 >=7%Conc<10%: T+; R45; R46; R60; R61;
C; R34 T+ R26; R22; R48/20; R36/38; R42/43
Xn; R21 R: 45-46-60-61-21-25-26-34- >=5%Conc<7%: T; R45; R46; R60; R61; R23;
14307-35-8 Chromic acid (H2CrO4), dilithium salt R42/43 42/43-48/23 R22; N - - - - - - - -
Xn; R22
Xi; R36/37/38 Xn ; N ; R: 22 - 36/37/38 - Conc>=25%: Xn; R22; R36/37/38; R43
R43 43 - 50/53, >=20%Conc<25%: Xi; R36/37/38; R43
14324-55-1 Zinc bis(diethyldithiocarbanate) N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Chlorfenprop methyl (ISO) [Methyl 2-chloro-3-(4- Xn; R21/22 Xn ; N ; R: 21/22 - 50/53,
14437-17-3 chlorophenyl)propionate] N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
14450-60-3 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Cristobalite (see Silica -
14464-46-1 Silica crystalline [Cristobalite] A (respirable dust) - 0.1 - - - - Crystalline)

Xi; R36/37/38 Xi ; N ; R: 36/37/38 - 50/53,

14484-64-1 Iron tris(dimethyldithiocarbamate) [Ferbam (ISO)] N; R50-53 S: (2) - 60 - 61 Conc>=20%: Xi; R36/37/38 Eu; A Ferbam - 10 - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 1; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
14486-19-2 Borate(1-), tetrafluoro-, cadmium (2:1) Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Conc>=25%: Xn; R22; R37; R41
Xn >=20%Conc<25%: Xi; R37; R41
Xn; R22 R: 22-37-41 >=10%Conc<20%: Xi; R41
14653-91-9 4-Methyl-N-(methylsulfonyl)benzenesulfonamide Xi; R37-41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi ; R: 41, Conc>=10%: Xi; R41
14657-64-8 3-(Hydroxyphenylphosphinyl)propanoic acid Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N-(2,2,6,6-Tetramethyl-1-oxylpiperidin-4-yl)acetamide Xn
[(4-Acetamido-2,2,6,6-tetramethyl-1- R: 22
14691-89-5 piperidinyl)oxidanyl] Xn; R22 S: (2-)22 Conc>=25%: Xn; R22 Eu - - - - - - - -

Page 181
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R49; R61; R68; R48/23;

R20/22; R38; R42/43
>=20%Conc<25%: T; R49; R61; R68; R48/23;
Carc. Cat. 1; R49 R38; R42/43
Muta. Cat. 3; R68 >=10%Conc<20%: T; R49; R61; R68; R48/23;
Repr. Cat. 2; R61 R42/43
T; R48/23 >=1%Conc<10%: T; R49; R61; R68; R48/20;
Xn; R20/22 T R42/43
Xi; R38 R: 49-61-20/22-38-42/43- >=0.5%Conc<1%: T; R49; R61
14708-14-6 Borate(1-), tetrafluoro-, nickel(2+) (2:1) R42/43 48/23-68 >=0.1%Conc<0.5%: T; R49 N - - - - - - - -
14769-73-4 Levamisole Xn; R22 Xn ; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -

Talc, (containing
14807-96-6 Talc, containing no asbestos fibres A no asbestos fibres) - 2.5 - - - - -
Quartz (respirable (see Silica -
14808-60-7 Quartz [Silica Crystalline] A dust) - 0.1 - - - - Crystalline)
Repr. Cat. 3; R62
Xn; R22 Xn; N Conc>=25%: Xn; R62; R22; R43
Phoxim (ISO) [alpha-(Diethoxyphosphinothioylimino) R43 R: 22-43-62-50/53 >=5%Conc<25%: Xn; R62; R43
14816-18-3 phenylacetonitrile] N; R50-53 S: (2-)36/37-46-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Phosphonic acid, (1-hydroxyethylidene)bis-, Xn; R22 Xn Conc>=25%: Xn; R22; R36
14860-53-8 tetrapotassium salt Xi; R36 R: 22-36 >=20%Conc<25%: Xi; R36 N - - - - - - - -

Xi
R10 R: 10-36/37-67
(R)-Butan-2-ol(Note: see also CAS No. 78-92-2, 4221- Xi; R36/37 S: (2-)7/9-13-24/25-26-46
14898-79-4 99-2 & 15892-23-6) R67 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
Conc>=25%: T+; R26; R22; R41
>=10%Conc<25%: T+; R26; R41
>=7%Conc<10%: T+; R26; R36
T+; R26 >=5%Conc<7%: T; R23; R36
Xn; R22 T+ >=1%Conc<5%: T; R23
14915-37-8 Copper pyrithione Xi; R41 R: 22-26-41 >=0.1%Conc<1%: Xn; R20 V - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
14923-81-0 Eicosanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

O; R8 Conc>=25%: T+; R45; R60; R61; R26; R24/25;

Carc. Cat. 1; R45 R48/23; R35; R42/43
Repr. Cat. 2; R60-61 >=10%Conc<25%: T+; R45; R60; R61; R26;
T+; R26 R48/23; R35; R21/22; R42/43
T; R24/25-48/23 >=7%Conc<10%: T+; R45; R60; R61; R26;
C; R35 O; T+; C; N R34; R21/22; R48/20; R42/43
Chromium, dichlorodioxo- [Chromic oxychloride; R42/43 R: 8-45-60-61-24/25-26-35- >=5%Conc<7%: T; R45; R60; R61; R23; R34;
14977-61-8 Chromium, dichlorodioxo, (T-4); Chromyl dichloride] N; R50-53 42/43-48/23-50-53 R21/22; R48/20; R4 N/Eu - - - - - - - -
R43 Xi ; N ; R: 43 - 50/53
15024-10-9 p-Tolyl 4-chlorobenzoate N; R50-53 S: (2)24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Cryolite [Trisodium hexafluoroaluminate; Sodium Xn; R20 T; N Conc>=25%: T; R48/23/25; R20
aluminum fluoride](Note: see also CAS No 13775-53- T; R48/23/25 R: 20-48/23/25-51/53 >=10%Conc<25%: T; R48/23/25
15096-52-3 6) N; R51-53 S: (1/2-)22-37-45-61 >=1%Conc<10%: Xn; R48/20/22 Eu - - - - - - - -

Conc>=25%: T; R45; R63; R68; R23/25; R21;

R48/20/21/22
>=10%Conc<25%: T; R45; R63; R68; R20/22;
Carc. Cat. 1; R45 R48/20/21/22
Muta. Cat. 3; R68 >=5%Conc<10%: T; R45; R63; R68; R20/22
Repr. Cat. 3; R63 T >=3%Conc<5%: T; R45; R68; R20/22
T; R23/25 R: 45-21-23/25-48/20/21/22- >=1%Conc<3%: T; R45; R68
15120-17-9 Arsenenic acid, sodium salt Xn; R21-48/20/21/22 63-68 >=0.1%Conc<1%: T; R45 N - - - - - - - -

Page 182
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: T; R61; R62; R22; R37; R41
Sodium perborate [Sodium peroxoborate](Note: O; R8 >=22%Conc<25%: T; R61; R62; R37; R41
containing < 0.1 % (w/w) of particles with an Repr. Cat. 2; R61 O; T >=20%Conc<22%: T; R61; R62; R36/37
aerodynamic diameter of below 50 micrometres. See Repr. Cat. 3; R62 R: 61-8-22-37-41-62 >=14%Conc<20%: T; R61; R62; R36
also CAS No. 11138-47-9, 12040-72-1, 7632-04-4 & Xn; R22 S: 53-45 >=9%Conc<14%: T; R61; R62
15120-21-5 10332-33-9) Xi; R37-41 Note: E >=6.5%Conc<9%: T; R61 Eu - - - - - - - -

Conc>=25%: T; R61; R62; R23; R22; R37; R41

>=22%Conc<25%: T; R61; R62; R20; R37;
O; R8 R41
Sodium perborate [Sodium peroxoborate](Note: Repr. Cat. 2; R61 >=20%Conc<22%: T; R61; R62; R20; R36/37
containing >= 0.1 % (w/w) of particles with an Repr. Cat. 3; R62 O; T >=14%Conc<20%: T; R61; R62; R20; R36
aerodynamic diameter of below 50 micrometres. See T; R23 R: 61-8-22-23-37-41-62 >=9%Conc<14%: T; R61; R62; R20
also CAS No. 11138-47-9, 12040-72-1 & 7632-04-4, Xn; R22 S: 53-45 >=6.5%Conc<9%: T; R61; R20
15120-21-5 10332-33-9) Xi; R37-41 Note: E >=3%Conc<6.5%: Xn; R20 Eu - - - - - - - -
Conc>=25%: Xn; R21/22; R38; R41; R43
Xn; R21/22 Xn ; N ; R: 21/22 - 38 - 41 - >=20%Conc<25%: Xi; R38; R41; R43
Xi; R38-41 43 - 50/53, >=10%Conc<20%: Xi; R41; R43
R43 S: (2) - 26 - 36/37/39 - 60 - >=5%Conc<10%: Xi; R36; R43
15121-89-8 e-Ethyl-4-oxo-4-phenylcrotonate N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
R14
Carc. Cat. 3; R40 Xn ; R: 14 - 36/38 - 40 , Conc>=20%: Xn; R40; R36/38
15159-40-7 Morpholine-4-carbonyl chloride Xi; R36/38 S: (2) - 26 - 30 - 36 - 38 >=1%Conc<20%: Xn; R40 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41; R43
>=20%Conc<25%: Xi; R38; R41; R43
Xn; R22. >=10%Conc<20%: Xi; R41; R43
Xi; R38-41 Xn ; R: 22 - 38 - 41 - 43 , >=5%Conc<10%: Xi; R36; R43
15165-67-0 (+)-R-2-(2,4-Dichlorophenoxy)propionic acid R43 S: (2) - 24 - 26 - 37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Conc>=7%: T+; R28; R43
T+; R28 T+ >=1%Conc<7%: T; R25; R43
15233-47-3 1,4-Benzenediamine, N1-(1-methylheptyl)-N4-phenyl- R43 R: 28-43 >=0.1%Conc<1%: Xn; R22 N - - - - - - - -
E; R3
Repr. Cat. 1; R61
Repr. Cat. 3; R62 E ; T ; N ; R: 61 - 62 - 3 - Conc>=25%: T; R61; R62; R20/22; R33
Xn; R20/22 20/22 - 33 - 50/53, >=5%Conc<25%: T; R61; R62; R33
Lead 2,4,6-trinitroresorcinoxide [Lead styphnate; R33 S: 53 - 45 - 60 - 61; >=1%Conc<5%: T; R61; R33
15245-44-0 Lead 2,4,6-trinitro-m-phenylene dioxide] N; R50-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Xn; N
Xn; R21/22 R: 21/22 - 50/53
15263-52-2 Cartap hydrochloride N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
N
Cartap [1,3-Bis(carbamoylthio)-2- R: 50/53
15263-53-3 (dimethylamino)propane] N; R50-53 S: 60-61 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
T+; R28 T+ ; N ; R: 24 - 28 - 51/53, >=3%Conc<7%: T; R25; R21
3-Chloro-6-cyano-bicyclo(2,2,1)heptan-2-one-O-(N- T; R24 S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<3%: T; R25
15271-41-7 methylcarbamoyl)oxime [Triamid] N; R51-53 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
R: 52/53
15290-77-4 1,1,2,2,3,3,4-Heptafluorocyclopentane R52-53 S: 61 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
15306-30-6 Dodecanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Page 183
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
15337-60-7 Dodecanoic acid, barium cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
15347-55-4 9-Octadecenoic acid, lead salt, (Z)- R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xn
R: 62
15375-21-0 Androsta-1,4,9(11)-triene-3,17-dione Repr. Cat.3; R62 S: (2-)22-36/37 Conc>=5%: Xn; R62 Eu - - - - - - - -
Conc>=25%: T; R45; R46; R34; R20/21/22;
Carc. Cat. 2; R45 R37
Muta. Cat. 2; R46 >=20%Conc<25%: T; R45; R46; R34; R37
Xn; R20/21/22 >=10%Conc<20%: T; R45; R46; R34
C; R34 T >=5%Conc<10%: T; R45; R46; R36/38
15448-47-2 Oxirane, methyl-, (R)- Xi; R37 R: 45-46-20/21/22-34-37 >=0.1%Conc<5%: T; R45; R46 N - - - - - - - -
Tridymite (see Silica -
15468-32-3 Silica crystalline [Tridymite] A (respirable dust) - 0.1 - - - - Crystalline)
F; R11,
15506-53-3 Cyclobutane-1,3-dione F; R11 S: (2) - 9 - 16 - 33 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
15521-60-5 Phosphonic acid, lead(2+) salt (2:1) R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
Diphosphoric acid, compd. With 1,3,5-triazine-2,4,6- Xi
15541-60-3 triamine (1:?) Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
Carc. Cat. 3; R40 Xn; N
Chlorotoluron [3-(3-Chloro-p-tolyl)-1,1-dimethylurea Repr. Cat. 3; R63 R: 40-63-50/53 Conc>=5%: Xn; R63; R40
15545-48-9 ] N; R50-53 S: (2-)36/37-26-46-60-61 >=1%Conc<5%: Xn; R40 Eu - - - - - - - -
Carc.Cat.1; R45 T; N Conc>=25%: T; R45; R23/25
T; R23/25 R: 45-23/25-50/53 >=3%Conc<25%: T; R45; R20/R22
15606-95-8 Triethyl arsenate N; R50-53 S: 53-45-60-61 >=0.1%Conc<3%: T; R45 Eu - - - - - - - -
Xi ; R: 36/38 - 43 ,
2,2-Bis(acryloyloxymethyl)butyl acrylate Xi; R36/38 S: (2) - 39 ; Conc>=20%: Xi; R36/38; R43.
15625-89-5 [Trimethylolpropane triacrylate] R43 Note: D >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

T; R23 T ; R: 23 - 36/37/38 - 42, Conc>=20%: T; R23; R36/37/38; R42.

2,4,4-Trimethylhexamethylene-1,6-diisocyanate(Note: Xi; R36/37/38 S: (1/2) - 26 - 28 - 38 - 45; >=2%Conc<20%: T; R23; R42. Isocyanates, all
15646-96-5 see also CAS No 16938-22-0) R42 Note: C >=0.5%Conc<2%: Xn; R20; R42 Eu; A (as-NCO) - 0.02 - 0.07 - Sen -

6-(1-alpha,5a-beta,8a-beta,9-Pentahydroxy-7-beta-
isopropyl-2-beta, 5-beta,8-beta-trimethylperhydro-8b-
alpha, 9-epoxy-5,8-ethanocyclopenta (1,2- Xn; R21/22 Xn ; N ; R: 21/22 - 50/53,
15662-33-6 b)indenyl)pyrrole-2-carboxylate [Ryania] N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
15696-43-2 Octanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Page 184
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
15739-80-7 Sulfuric acid, lead salt R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
15748-73-9 Lead, bis(2-hydroxybenzoato-O1,O2)-, (T-4)- R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xi; N
Xi; R36/38 R: 36/38-51/53
15768-07-7 Methyl 2-benzylidene-3-oxobutyrate N; R51-53 S: (2-)26-37/39-61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
15773-52-1 Decanoic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
15773-55-4 Dodecanoic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
15773-56-5 Hexadecanoic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
E; R3,
15825-70-4 Mannitol hexanitrate [Nitromannite] E; R3 S: (2) - 35 Eu - - - - - - - -
Ethanol, 2-(dodecyloxy)-, hydrogen sulfate, sodium Xn; R22 Xn Conc>=25%: Xn; R22; R36/38
15826-16-1 salt Xi; R36/38 R: 22-36/38 >=20%Conc<25%: Xi; R36/38 N - - - - - - - -
Chloralose (INN) [(R)-1,2-o-(2,2,2-
Trichloroethylidene)-alpha-D-glucofuranose; Xn ; R: 20/22 ,
15879-93-3 Glucochloralose; Anhydroglucochloral] Xn; R20/22 S: (2) - 16 - 24/25 - 28 Conc>=25%: Xn; R20/22 Eu - - - - - - - -

Xi
R10 R: 10-36/37-67
(±)-Butan-2-ol(Note: see also CAS No. 78-92-2, 4221- Xi; R36/37 S: (2-)7/9-13-24/25-26-46
15892-23-6 99-2 & 14898-79-4) R67 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
Carc. Cat. 3; R40
Xn; R22 Xn; N
Alachlor (ISO) [2-Chloro-2',6'-diethyl-N- R43 R: 22-40-43-50/53 Conc>=25%: Xn; R40; R22; R43
15972-60-8 (methoxymethyl)acetanilide] N; R50-53 S: (2-)36/37-46-60-61 >=1%Conc<25%: Xn; R40; R43 Eu - - - - - - - -
E; R2 E ; Xn ; R: 2 - 41 - 43 -
Xn; R48/22 48/22 , Conc>=10%: Xn; R48/22; R41; R43
Xi; R41 S: (2) - 22 - 26 - 35 - >=5%Conc<10%: Xi; R36; R43
15980-11-7 3-Azidosulfonylbenzoic acid R43 36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
16038-76-9 Phosphonic acid, lead salt R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
R: 52/53
16063-70-0 2,3,5-Trichloropyridine R52-53 S: 61 Eu - - - - - - - -

Page 185
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Cuprate(2-), [5-[[4'-[[2,6-dihydroxy-3-[(2-hydroxy-5-
sulfophenyl)azo]phenyl]azo][1,1'-biphenyl]-4-yl]azo]-2-
hydroxybenzoato(4-)]-, disodium [C.I. Direct Brown Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
16071-86-6 95] Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Conc>=25%: T; R45; R46; R34; R20/21/22;
Carc. Cat. 2; R45 R37
Muta. Cat. 2; R46 >=20%Conc<25%: T; R45; R46; R34; R37
Xn; R20/21/22 >=10%Conc<20%: T; R45; R46; R34
C; R34 T >=5%Conc<10%: T; R45; R46; R36/38
16088-62-3 Oxirane, methyl-, (S)- Xi; R37 R: 45-46-20/21/22-34-37 >=0.1%Conc<5%: T; R45; R46 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
16183-12-3 1,2-Benzenedicarboxylic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Ethylidene 5 Peak 25 Peak
16219-75-3 Ethylidene norbornene A norbornene limitation limitation - - - - -
Xn; N
Xn; R48/22 R: 48/22-51/53
16298-38-7 4,4'-Methylenebis(2-isopropyl-6-methylaniline) N; R51-53 S: (2-)36-61 Conc>=10%; Xn; R48/22 Eu - - - - - - - -
Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
Mecoprop-P (CAS No. 16484-77-8) and its salts [(R)- Xi; R41 R: 22-41-51/53 >=10%Conc<25%; Xi; R41
16484-77-8 2-(4-Chloro-2-methylphenoxy)propionic acid] N; R51-53 S: (2-)13-26-37/39-46-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T; R24 Conc>=25%: T; R24; R22; R36/38
Xn; R22 >=20%Conc<25%: Xn; R21; R36/38
16595-80-5 Levamisole hydrochloride Xi; R36/38 T ; R: 22 - 24 - 36/38 >=3%Conc<20%: Xn; R21 V - - - - - - - -
C; N
R: 34-50/53
C; R34 S: (1/2-)26-36/37/39-45-60- Conc>=10%: C; R34
16610-63-2 (1-Hydroxydodecylidene)diphosphonic acid N; R50-53 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Xi; R41 Xi; N Conc>=10%: Xi; R41; R43

R43 R: 41-43-50/53 >=5%Conc<10%: Xi; R36; R43
16634-82-5 2-Chloro-N-(4-methylphenyl)acetamide N; R50-53 S: (2-)22-26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
C
Xn; R20/21 R: 20/21-34-52/53 Conc>=25%: C; R34; R20/21
C; R34 S: (1/2-)26-28-36/37/39-45- >=10%Conc<25 %: C; R34
16672-87-0 Ethephon [2-Chloroethylphosphonic acid] R52-53 61 >=5%Conc<10 %: Xi; R36/37/38 Eu - - - - - - - -
N,N-Bis(2-(p-toluenesulfonyloxy)ethyl)-p- R43 Xi ; R: 43 - 53
16695-22-0 toluenesulfonamide R53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
R31 Xn >=10%Conc<25%: Xi; R41
16731-55-8 Disulfurous acid, dipotassium salt Xi; R41 R: 22-31-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

T+; N Conc>=7%: T+; R28

Methomyl (ISO) [1-(Methylthio)ethylideneamino N- T+; R28 R: 28-50/53 >=1%Conc<7%: T; R25
16752-77-5 methylcarbamate] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=0.1%Conc<1%: Xn; R22 Eu;A Methomyl - 2.5 - - - - -
Carc. Cat. 1; R49 T; N Nickel sulphide
R43 R: 49 - 43 - 50/53 Conc>=1%: T; R49; R43 roasting (fume &
16812-54-7 Nickel sulphide N; R50-53 S: 53 - 45 - 60 - 61 >=0.1%Conc<1%: T; R49 Eu; A dust) (as Ni) - 1 - - 1 Sen -
Cobalt
hydrocarbonyl (as
16842-03-8 Cobalt hydrocarbonyl (as Co) A Co) - 0.1 - - - Sen -
F; C
R: 15-35 Conc>=10%: C; R35
F; R15 S: (1/2-)7/8-26-36/37/39-43- >=5%Conc<10%: C; R34
16853-85-3 Aluminium lithium hydride C; R35 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Fluorosilicates, alkali ( K) [Potassium T ; R: 23/24/25 ,
silicofluoride](Note: see also CAS No 16893-85-9 & S: (1/2) - 26 - 45 ; Conc>=10%: T; R23/24/25
16871-90-2 16919-19-0) T; R23/24/25 Note: A >=1%Conc<10%: Xn; R20/21/22 Eu - - - - - - - -
C ; R: 34 ,
S: (1/2) - 26 - 27 - 45; Conc>=25%: C; R34
16872-11-0 Fluoroboric acid ... % C; R34 Note: B >=10%Conc<25%: Xi; R36/38 Eu - - - - - - - -

Page 186
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Fluorosilicates, alkali (Na) [Sodium T ; R: 23/24/25 ,
silicofluoride](Note: see also CAS No 16871-90-2 & S: (1/2) - 26 - 45 ; Conc>=10%: T; R23/24/25
16893-85-9 16919-19-0) T; R23/24/25 Note: A >=1%Conc<10%: Xn; R20/21/22 Eu - - - - - - - -
Fluorosilicates, alkali (NH4) [Ammonium T ; R: 23/24/25 ,
silicofluoride](Note: see also CAS No 16893-85-9 & S: (1/2) - 26 - 45 ; Conc>=10%: T; R23/24/25
16919-19-0 16871-90-2) T; R23/24/25 Note: A >=1%Conc<10%: Xn; R20/21/22 Eu - - - - - - - -
Conc>=25%: T; R25; R42/43; R41
>=10%Conc<25%: Xn; R22; R42/43; R41
T; R25 T ; R: 25 - 41 - 42/43, >=5%Conc<10%: Xn; R22; R42/43; R36
Xi; R41 S: (1/2) - 22 - 26 - 36/37/39 - >=3%Conc<5%: Xn; R22; R42/43
16919-58-7 Diammonium hexachloroplatinate Xn; R42/43 45 >=1%Conc<3%: Xn; R42/43 Eu - - - - - - - -
Conc>=25%: T; R25; R42/43; R41
>=10%Conc<25%: Xn; R22; R42/43; R41
T; R25 T ; R: 25 - 41 - 42/43, >=5%Conc<10%: Xn; R22; R42/43; R36
Xi; R41 S: (1/2) - 22 - 26 - 36/37/39 - >=3%Conc<5%: Xn; R22; R42/43
16921-30-5 Dipotassium hexachloroplatinate R42/43 45 >=1%Conc<3%: Xn; R42/43 Eu - - - - - - - -
Conc>=25%: T; R25; R42/43; R41
>=10%Conc<25%: Xn; R22; R42/43; R41
T; R25 T ; R: 25 - 41 - 42/43, >=5%Conc<10%: Xn; R22; R42/43; R36
Xi; R41 S: (1/2) - 22 - 26 - 36/37/39 - >=3%Conc<5%: Xn; R22; R42/43
16923-58-3 Disodium hexachloroplatinate R42/43 45 >=1%Conc<3%: Xn; R42/43 Eu - - - - - - - -

T; R23 T ; R: 23 - 36/37/38 - 42, Conc>=20%: T; R23; R36/37/38; R42.

2,2,4-Trimethylhexamethylene-1,6-diisocyanate(Note: Xi; R36/37/38 S: (1/2) - 26 - 28 - 38 - 45; >=2%Conc<20%: T; R23; R42. Isocyanates, all
16938-22-0 see also CAS No 15646-96-5) R42 Note: C >=0.5%Conc<2%: Xn; R20; R42 Eu; A (as-NCO) - 0.02 - 0.07 - Sen -

Conc>=25%: T; R25; R34; R42/43

>=10%Conc<25%: C; R34; R22; R42/43
T; R25 T ; R: 25 - 34 - 42/43, >=5%Conc<10%: Xn; R22; R42/43; R36/38
C; R34 S: (1/2) - 22 - 26 - 36/37/39 - >=3%Conc<5%: Xn; R22; R42/43
16941-12-1 Hexachloroplatinic acid R42/43 45 >=1%Conc<3%: Xn; R42/43 Eu - - - - - - - -
T ; R: 25, Conc>=10%: T; R25
16949-65-8 Magnesium hexafluorosilicate T; R25 S: (1/2) - 24/25 - 45 >=1%Conc<10%: Xn; R22 Eu - - - - - - - -
C ; R: 34 ,
S: (1/2) - 26 - 27 - 45; Conc>=10%: C; R34
16961-83-4 Fluorosilicic acid ... % C; R34 Note: B >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
16984-48-8 Fluorides (as F) A Fluorides (as F) - 2.5 - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 1; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
16986-83-7 Propanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
16996-40-0 Hexanoic acid, 2-ethyl-, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
16996-51-3 9,12-Octadecadienoic acid, (Z,Z)-, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
T; R23/25
R33 T; N Conc>=10%: T; R23/25; R33; R68 Cadmium and
Cadmium fluorosilicate [Cadmium Xn; R68 R: 23/25-33-68-50/53 >=1%Conc<10%: Xn; R20/22; R33; R68 compounds (as
17010-21-8 hexafluorosilicate(2-)] N; R50-53 S: (1/2-)22-45-60-61 >=0.1%Conc<1%: Xn; R20/22; R33 Eu; A Cd) - 0.01 - - 2 - -

Page 187
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Demeton-S-methylsulphone T; R25 T; N
Xn; R21 R: 21-25-51/53 Conc>=25%: T; R25; R21
17040-19-6 [S-2-Ethylsulphonylethyl dimethyl phosphorothioate] N; R51-53 S: (1/2-)22-28-36/37-45-61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Xi; R38 Xi ; N ; R: 38 - 51/53 ,
17092-80-7 m-Mentha-1,3(8)-diene N; R51-53 S: (2) - 37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
T; R23/25
Xn; R21 T; N Conc>=25%: T; R23/25; R21; R43
Edifenphos (ISO) [O-Ethyl S,S-diphenyl R43 R: 21 - 23/25 - 43 - 50/53 >=3%Conc<25%: Xn; R20/22; R43
17109-49-8 phosphorodithioate] N; R50-53 S: (1/2) - 36/37 - 45 - 60 - 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T; R48/25; R22; R41
T; R48/25 T >=10%Conc<25%: T; R48/25; R41
Xn; R22 R: 22-41-48/25 >=5%Conc<10%: Xn; R48/22; R36
17193-28-1 1-Aminocyclopentanecarboxamide Xi; R41 S: (1/2-)22-26-36/39-45 >=1%Conc<5%: Xn; R48/22 Eu - - - - - - - -
17321-77-6 Clomipramine hydrochloride Xn; R22 Xn; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -
Xn; R22
Xi; R36 Xn; N Conc>=25%: Xn; R22; R36; R43
N,N,N',N'-Tetramethyldithiobis(ethylene)diamine R43 R: 22-36-43-50/53 >=20%Conc<25%: Xi; R36; R43
17339-60-5 dihydrochloride N; R50-53 S: (2-)26-36/37-60-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
R43 Xi ; N ; R: 43 - 51/53
17351-75-6 1,4-Bis[(vinyloxy)methyl]cyclohexane N; R51-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi ; R: 10 - 36/37
Methyl (R)-lactate(Note: see also CAS No 2155-30-8; R10 S: (2) - 24;
17392-83-5 547-64-8 & 27871-49-4) Xi; R36/37 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
N
R: 50/53
17417-32-2 4'-Methyldodecane-1-sulfonanilide N; R50-53 S: 60-61 Eu - - - - - - - -
Xi
17517-01-0 1-Propanamine, N,N-dimethyl-3-(octadecyloxy)- Xi; R36/38 R: 36/38 Conc>=20%: Xi; R36/38 N - - - - - - - -
Xi; R38 Xi ; R: 38 - 43 , Conc>=20%: Xi; R38; R43
17557-23-2 1,3-Bis(2,3-epoxypropoxy)-2,2-dimethylpropane R43 S: (2) - 24 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R61; R62; R20/22-48/20/22;

R41; R38; R33
>=20%Conc<25%: T; R61; R62; R48/20/22;
Repr. Cat. 1; R61 R41; R38; R33
Repr. Cat. 3; R62 >=10%Conc<20%: T; R61; R62; R48/20/22;
Xn; R20/22-48/20/22 T ; N ; R: 61 - 62 - 20/22 - R41; R33
Xi; R38-41 33 - 38 - 41 - 48/20/22 - 58 , >=5%Conc<10%: T; R61; R62; R36; R33
R33 S: 53 - 45 - 57 - 61 ; >=1%Conc<5%: T; R61; R33
17570-76-2 Lead (II) methanesulphonate N; R58 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -

Conc>=25%: T; R40; R23; R48/23; R36/37/38;

R42/43
>=20%Conc<25%: T; R40; R48/23; R20;
R36/37/38; R42/43
>=10%Conc<20%: T; R40; R48/23; R20;
Carc. Cat. 3; R40 R42/43
T; R23-R48/23 T >=3%Conc<10%: Xn; R40; R20; R48/20;
1,3-Diazetidine-2,4-dione, 1,3-bis[4-[(4- Xi; R36/37/38 R: 23-36/37/38-40-42/43- R42/43
17589-24-1 isocyanatophenyl)methyl]phenyl]- R42/43 48/23 >=1%Conc<3%: Xn; R40; R48/20; R42/43 N - - - - - - - -
1,3-Bis(phenylsulfonylthio)-2-(N,N- Xn; R22 Xn ; N ; R: 22 - 50/53,
17606-31-4 dimethylamino)propane [Bensultap] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Repr. Cat. 3; R62
Xn; R22 Conc>=25%: Xn; R62; R22 R43
R43 Xn ; R: 22 - 43 - 62 - 52/53 >=5%Conc<25%: Xn; R62; R43
17630-75-0 5-Chloro-1,3-dihydro-2H-indol-2-one R52-53 S: (2)22 - 36/37 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
17702-41-9 Decaborane A Decaborane 0.05 0.25 0.15 0.75 - Sk -
T; R25 T ; N ; R: 25 - 51/53 , Conc>=25%: T; R25
17742-69-7 2,6-Dichloro-4-nitroanisole N; R51-53 S: (1/2) - 36/37 - 45 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Muta. Cat. 2; R46
Repr.Cat.2; R60-61 Conc>=20%: T; R46; R60/61; R37/38;R43
Xi; R37/38 T; N >=1%Conc<20%: T; R46; R60/61; R43
Benomyl (ISO) [Methyl 1- R43 R: 46-60-61-37/38-43-50/53 >=0.5%Conc<1%: T; R46; R60/61
17804-35-2 (butylcarbamoyl)benzimidazol-2-ylcarbamate] N; R50-53 S: 53-45-60-61 >=0.1%Conc<0.5%: T; R46 Eu; A Benomyl (f) 0.84 10 - - - - -

Page 188
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi; R38 Xi ; N ; R: 38 - 51/53 ,
17865-32-6 Cyclohexyldimethoxymethylsilane N; R51-53 S: (2) - 24 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xi ; R: 38 ,
17980-47-1 Triethoxyisobutylsilane Xi; R38 S: (2) - 24 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xn; R22
Xi; R41 Xn; N Conc>=25%: Xn; R63; R22; R41
Malachite green oxalate (Note: see also CAS Repr. Cat. 3; R63 R: 22-41-63-50/53 >=10%Conc<25%: Xn; R63; R41
18015-76-4 No. 569-64-2) N; R50-53 S: (2-)26-36/37-39-46-60-61 >=5%Conc<10%: Xn; R63; R36 Eu - - - - - - - -
Xn
R: 22
18085-02-4 1,2-Diacetoxybut-3-ene Xn; R22 S: (2-) Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn
Xn; R22 R: 22-36 Conc>=25%: Xn; R22; R36
18087-70-2 Imidazo[1,2-b]pyridazin hydrochloride Xi; R36 S: (2-)26 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
R 10 Xi;
R38 Xi
R43 R: 10-38-43-52/53 Conc>=20%: Xi; R38; R43
18230-61-0 Bis(1-methylethyl)-dimethoxysilane R 52-53 S: (2-)24-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn; R21/22 Xn
Xi; R38 R: 21/22-38-52/53 Conc>=25%: Xn; R21/22; R38
18368-64-4 2-Chloro-5-methyl-pyridine R52-53 S: (2-)23-25-36/37-61 >=20%Conc<25%: Xi; R38 Eu - - - - - - - -

Conc>=25%: T; R45; R61; R62; R68; R23;

R48/20; R43; R33
Carc. Cat. 2; R45 >=10%Conc<25%: T; R45; R61; R62; R68;
Muta. Cat. 3; R68 R20; R48/20; R43; R33
Repr. Cat. 1; R61 >=5%Conc<10%: T; R45; R61; R62; R68; R20;
Repr. Cat. 3; R62 R43; R33
T; R23 >=3%Conc<5%: T; R45; R61; R68; R20; R43;
Xn; R48/20 T R33
R33 R: 45-61-23-33-43-48/20-62- >=1%Conc<3%: T; R45; R61; R68; R43; R33
18454-12-1 Lead chromate oxide (Pb2(CrO4)O) R43 68 >=0 N - - - - - - - -
Xi R:
R43 43-53
18600-59-4 2,2-(1,4-Phenylene)bis((4H-3,1-benzoxazine-4-one) R 53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
18608-34-9 1,2-Benzenedicarboxylic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Methabenzthiazuron (ISO) [1-(1,3-Benzothiazol-2- N; R: 50/53,
18691-97-9 yl)1,3-dimethylurea] N; R50-53 S: 60 - 61 Eu - - - - - - - -
C; N Conc>=25%: C; R21/22; R34; R43
Xn; R21/22 C; R: 21/22-34-43-50/53 >=10%Conc<25%: C; R34;R21/22; R43
R34 R43 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: Xi; R36/38; R43
18759-96-1 3-Methylaminomethylphenylamine N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

T; N
Isoxathion (ISO) [O,O-Diethyl O-5-phenylisoxazol-3- T; R24/25 R: 24/25-50/53 Conc>=25%: T; R24/25
18854-01-8 ylphosphorothioate] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -
Xn
18934-00-4 Oxetane, 3,3'-[oxybis(methylene)]bis[3-ethyl- Xn; R22 R: 22 Conc>=25%: Xn; R22 N - - - - - - - -
Xn; R22 Conc>=25%: C; R34; R22; R43
C; R34 C ; R: 22 - 34 - 43 - 52/53 >=10%Conc<25%: C; R34; R43
R43 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%: Xi; R36/38; R43
19060-15-2 4,4-Dimethoxybutylamine R52-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
E; R2 Conc>=25%: Xn; R40; R21/22; R48/22;
Carc. Cat. 3; R40 R36/38; R43
Xn; R21/22-48/22 E; Xn; N >=20%Conc<25%: Xn; R40; R48/22; R36/38;
Xi; R36/38 R: 2-21/22-36/38-40-43- R43
Hydroxylamine dihydrogenphosphate(Note: see also R43 48/22-50 >=10%Conc<20%: Xn; R40; R48/22; R43
19098-16-9 CAS No. 10046-00-1, 20845-01-6 & 53933-48-5) N; R50 S: (2-)36/37-61 >=1%Conc<10%: Xn; R40; R43 Eu - - - - - - - -

Page 189
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn
19234-20-9 Ethanol, 2-(1-methylethoxy)-, acetate Xn; R20/21 R: 20/21 Conc>=25%: Xn; R20/21 N - - - - - - - -
T; R25 T ; R: 25 - 43 - 48/22 - 52/53 Conc>=25%: T; R25; R48/22; R43
Xn; R48/22 , >=10%Conc<25%: Xn; R22; R48/22; R43
R43 S: (1/2) - 26 - 36/37/39 - 45 - >=3%Conc<10%: Xn; R22; R43
19247-05-3 N,N-Hydrazinodiacetic acid R52-53 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
19287-45-7 Diborane A Diborane 0.1 0.11 - - - - -

Carc. Cat. 3; R40

T; R48/25
Xn; R22 T; N Conc>=25%: T; R40; R48/25; R22; R41; R43
Xi; R41 R: 22-40-41-43-48/25-50/53 >=10%Conc<25%: T; R40; R48/25; R41; R43
R43 S: (1/2-)22-26-36/37/39-45- >=5%Conc<10%: Xn; R40; R48/22; R36; R43
19398-06-2 2-Ethylphenylhydrazine hydrochloride N; R50-53 60-61 >=1%Conc<5%: Xn; R40; R48/22; R43 Eu - - - - - - - -

Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

Hexahydro-4-methylphthalic anhydride(Note: see also Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
19438-60-9 CAS No 25550-51-0; 48122-14-1 & 57110-29-9) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Xi
1-Amino-1-cyanamino-2,2-dicyanoethylene, sodium R43 R: 43-52/53
19450-38-5 salt R52-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
C ; R: 21 - 34 - 43 , Conc>=25%: C; R34; R21; R43
Xn; R21 S: (1/2) - 26 - 36/37/39 - 45 >=10%Conc<25%: C; R34; R43
1-Methyltrimethylene diacrylate [1,3-Butylene glycol C; R34 ; >=5%Conc<10%: Xi; R36/38; R43
19485-03-1 diacrylate] R43 Note: D >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
19528-55-3 Hexadecanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
S-Ethyl N-
(dimethylaminopropyl)thiocarbamatehydrochloride Xn; R22 Xn ; N ; R: 22 - 51/53,
19622-19-6 [Prothiocarb hydrochloride] N; R51-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
19624-22-7 Pentaborane A Pentaborane 0.005 0.013 0.015 0.039 - - -

Oxadiazon [3-[2,4-Dichloro-5-(1-methylethoxy)phenyl]- N; R50/53,

19666-30-9 5-(1,1-dimethylethyl)-1,3,4-oxadiazol-2(3H)-one] N; R50-53 S: 60 - 61 Eu - - - - - - - -
Chlordimeform hydrochloride [N2-(4-Chloro-o-tolyl)-
N1,N1-dimethylformamidine hydrochloride; N'-(4- Carc. Cat. 3; R40
Chloro-o-tolyl)-N,N-dimethylformamidine Xn; R22 Xn ; N ; R: 22 - 40 - 50/53, Conc>=25%: Xn; R40; R22
19750-95-9 monohydrochloride] N; R50-53 S: (2) - 22 - 36/37 - 60 - 61 >=1%Conc<25%: Xn; R40 Eu - - - - - - - -
Carc. Cat. 3; R40
4,4'-Methylenebis(2-ethylaniline) [4,4’-Methylenebis(2- Xn; R22 Xn ; N ; R: 22 - 40 - 50/53, Conc>=25%: Xn; R40; R22
19900-65-3 ethylbenzeneamine)] N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<25%: Xn; R40 Eu - - - - - - - -
Metoxuron (ISO) [3-(3-Chloro-4-methoxyphenyl)-1,1- N ; R: 50/53,
19937-59-8 dimethylurea] N; R50-53 S: 60 - 61 Eu - - - - - - - -
Repr. Cat. 3; R62 Xn Conc>=20%: Xn; R62; R36; R43
Xi; R36 R: 36 - 43 - 62 >=5%Conc<20%: Xn; R62; R43
20108-78-5 Valinamide R43 S: (2) - 26 - 36/37 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; N Tin, organic
Fluorotripentylstannane (Note: see also CAS No. Xn; R20/21/22 R: 20/21/22-50/53 compounds (as
20153-49-5 25637-27-8) N; R50-53 S: (2-)26-28-60-61 Conc>=1%: Xn; R20/21/22 Eu; A Sn) - 0.1 - 0.2 - Sk -
Xn; N Tin, organic
Xn; R20/21/22 R: 20/21/22-50/53 compounds (as
20153-50-8 Fluorotrihexylstannane N; R50-53 S: (2-)26-28-60-61 Conc>=1%: Xn; R20/21/22 Eu; A Sn) - 0.1 - 0.2 - Sk -
Xn; R21/22 Xn ; N ; R: 21/22 - 36/38 -
2-(3,4-Dichlorophenyl)-4-methyl-1,2,4- Xi; R36/38 51/53, Conc>=25%: Xn; R21/22; R36/38
20354-26-1 oxadiazolidinedione [Methazole] N; R51-53 S: (2) - 36/37 - 61 >=20%Conc<25%: Xi; R36/38 Eu - - - - - - - -

Page 190
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
20403-41-2 Tetradecanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
20403-42-3 Decanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
R10,
S: (2)
20487-40-5 tert-Butyl propionate R10 Note; C Eu - - - - - - - -
R31 Xi; N
Xi; R36/37/38 R: 31 - 36/37/38 - 50
20548-54-3 Calcium sulphide N; R50 S: (2) - 28 - 61 Conc>=20%: Xi; R36/37/38; R31 Eu - - - - - - - -
Xi; N
R43 R: 43-51/53
20627-73-0 1-Dimethoxymethyl-2-nitro-benzene N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=10%: T+; R26/27/28; R34
>=7%Conc<10%: T+; R26/27/28; R36/38
>=5%Conc<7%: T; R23/24/25; R36/38
T+; R26/27/28 T+ ; R: 26/27/28 - 34 , >=1%Conc<5%: T; R23/24/25 Osmium tetroxide
20816-12-0 Osmic acid [Osmium tetroxide] C; R34 S: (1/2) - 7/9 - 26 - 45 >=0.1%Conc<1%: Xn; R20/21/22 Eu; A (as Os) 0.0002 0.0016 0.0006 0.0047 - - -
E; R2 Conc>=25%: Xn; R40; R21/22; R48/22;
Carc. Cat. 3; R40 R36/38; R43
Xn; R21/22-48/22 E; Xn; N >=20%Conc<25%: Xn; R40; R48/22; R36/38;
Xi; R36/38 R: 2-21/22-36/38-40-43- R43
Hydroxylamine phosphate(Note: see also CAS No. R43 48/22-50 >=10%Conc<20%: Xn; R40; R48/22; R43
20845-01-6 10046-00-1, 19098-16-9 & 53933-48-5) N; R50 S: (2-)36/37-61 >=1%Conc<10%: Xn; R40; R43 Eu - - - - - - - -
F; R15/29 F; T+; N
T+; R28 R: 15/29-28-32-50 Conc>=7%: T+; R28
R32 S: (1/2-)3/9/14-28-30-36/37- >=1%Conc<7%: T; R25
20859-73-8 Aluminium phosphide N; R50 43-45-61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
20936-32-7 Benzoic acid, 2,4-dihydroxy-, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Metribuzin (ISO) [4-Amino-6-tert-butyl-3-methylthio- Xn; N

1,2,4-triazin-5(4H)-one; 4-Amino-4,5-dihydro-6-(1,1- Xn; R22 R: 22-50/53
21087-64-9 dimethylethyl)-3-methylthio-1,2,4-triazin-5-one] N; R50-53 S: (2-)60-61 Conc>=25%: Xn; R22 Eu;A Metribuzin - 5 - - - - -

Conc>=25%: T; R45; R63; R68; R23/25; R21;

R48/20/21/22
>=10%Conc<25%: T; R45; R63; R68; R20/22;
Carc. Cat. 1; R45 R48/20/21/22
Muta. Cat. 3; R68 >=5%Conc<10%: T; R45; R63; R68; R20/22
Repr. Cat. 3; R63 T >=3%Conc<5%: T; R45; R68; R20/22
T; R23/25 R: 45-21-23/25-48/20/21/22- >=1%Conc<3%: T; R45; R68
21093-83-4 Arsenic acid (H3AsO4), dipotassium salt Xn; R21-48/20/21/22 63-68 >=0.1%Conc<1%: T; R45 N - - - - - - - -
R31 Xn; N
Xn; R20/22 R: 20/22 - 31 - 50
21109-95-5 Barium sulphide N; R50 S: (2) - 28 - 61 Conc>=25%: Xn; R20/22; R31 Eu - - - - - - - -
Carc. Cat. 1; R45 T ; N ; R: 45 - 22 - 50/53,
Benzidine, salt of Benzidine sulphate(Note: see also Xn; R22 S: 53 - 45 - 60 - 61; Conc>=25%: T; R45; R22
21136-70-9 CAS No 531-85-1, 531-86-2 & 236341-27-2) N; R50-53 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -

21351-79-1 Caesium hydroxide [Cesium hydroxide] A Caesium hydroxide - 2 - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F ; C ; R: 14/15 - 17 - 35 , Conc>=10%: C; R35
F; R14/15-17. S: (1/2) - 6 - 16 - 26 - 30 - >=5%Conc<10%: C; R34
21369-64-2 n-Hexyllithium C; R35 36/37/39 - 43 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
T; N
Carc.Cat.2; R45 R: 45-23/24/25-51/53 Conc>=25%: T; R45; R23/24/25
2,4,5-Trimethylaniline hydrochloride T; R23/24/25 S: 53-45-61 >=3%Conc<25%; T; R45; R20/21/22
21436-97-5 (Note: see also CAS No. 137-17-7) N; R51-53 Note: E >=0.1%Conc<3%: T; R45 Eu - - - - - - - -
Conc>=7%: T+; R27/28
Diethyl 1,3-dithietan-2-ylidenephosphoramidate T+ ; R: 27/28 , >=1%Conc<7%: T; R24/25
21548-32-3 [Fosthietan] T+; R27/28 S: (1/2) - 36/37 - 45 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
T+; R26 Conc>=25%: T+; R26; R22; R36/38; R43
Xn; R22 T+; N ; R: 22 - 26 - 36/38 - >=20%Conc<25%: T+; R26; R36/38; R43
Xi; R36/38 43 - 50/53, >=7%Conc<20%: T+; R26; R43
R43 S: (1/2) - 28 - 36/37 - 38 - >=1%Conc<7%: T; R23; R43
21564-17-0 TCMTB [(Benzothiazol-2-ylthio)methyl thlocyanate] N; R50-53 45 - 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
T ; N ; R: 21 - 25 - 39/25 - Conc>=25%: T; R25; R39/25; R21
T; R25-39/25 50/53 , >=10%Conc<25%: T; R39/25; R22
Leptophos (ISO) [O-4-Bromo-2,5-dichlorophenyl O- Xn; R21. S: (1/2) - 25 - 36/37/39 - 45 - >=3%Conc<10%: Xn; R22-68/22
21609-90-5 methyl phenylphosphorothioate] N; R50-53 60 - 61 >=1%Conc<3%: Xn; R68/22 Eu - - - - - - - -
Cyanazine (ISO) [2-(4-Chloro-6-ethylamino-1,3,5- Xn; R22 Xn ; N ; R: 22 - 50/53,
21725-46-2 triazine-2-ylamino)-2-methylpropionitrile] N; R50-53 S: (2) - 37 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
N
R: 51/53
21873-52-9 5,7-Dichloro-4-hydroxyquinoline N; R51-53 S: 61 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
>=7%Conc<25%: T+; R28; R21
Chlorthiophos (ISO)(Note: isomeric reaction mixture T+; R28 T+; N >=3%Conc<7%: T; R25; R21
in which O-2,5-dichlorophenyl-4-methylthiophenyl T; R24 R: 24-28-50/53 >=1%Conc<3%: T; R25
21923-23-9 O,O-diethyl phosphorothioate predominates) N; R50-53 S: (1/2-)28-36/37-45-60-61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
R43 Xi ; R: 43 - 52/53
21983-80-2 4'-Fluoro-2,2-dimethoxyacetophenone R52-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R65 Xn
Xi; R38 R: 38-65-53 Conc>=20%: Xn; R65; R38
22094-83-3 5-endo-Hexyl-bicyclo[2.2.1]hept-2-ene R53 S: (2-)37-62-61 >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
Benzoylprop ethyl (ISO) [Ethyl N-benzoyl-N-(3,4- Xn; R22 Xn ; N ; R: 22 - 50/53,
22212-55-1 dichlorophenyl)-DL-alaninate] N; R50-53 S: (2) - 24 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: T+; R28; R24
T+; N >=7%Conc<25%: T+; R28; R21
T+; R28 R: 24-28-50/53 >=3%Conc<7%: T; R25; R21
Fenamiphos (ISO) [Ethyl-4-methylthio-m-tolyl T; R24 S: (1/2-)23-28-36/37-45-60- >=1%Conc<3%: T; R25
22224-92-6 isopropyl phosphoramidate] N; R50-53 61 >=0.1% Conc<1%: Xn; R22 Eu; A Fenamiphos - 0.1 - - - Sk -
Repr. Cat. 2; R61 Conc>=10%: T; R61; R64; R48/22
Xn; R48/22 >=1%Conc<10%: T; R61; R64
22232-54-8 Carbimazole R64 T; R: 61-48/22-64 >=0.5%Conc<1%: T; R61 V - - - - - - - -
T+ ; N ; R: 26/28 - 43 -
Formetanate [3-(N,N- T+; R26/28 50/53, Conc>=7%: T+; R26/28; R43
Dimethylaminomethyleneamino)phenyl N- R43 S: (1/2) - 24 - 28 - 37/39 - >=1%Conc<7%: T; R23/25; R43
22259-30-9 methylcarbamate] N; R50-53 45 - 60 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
F; R11
O; R7 F; O; Xi; N
Xi; R38 R: 7-11-38-43-51/53
R43 S: (2-)7-14-16-36/37/39-47- Conc>=20%: Xi; R38; R43
22288-41-1 1,1,3,3-Tetramethylbutylperoxypivalate N; R51-53 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
T
Carc. Cat. 2; R45 R: 45–48/23–62 Conc>=5%: T; R45; R62; R48/23
Repr. Cat. 3; R62 S: 45- 53 >=0.1%Conc<5%: T; R45; R48/23
22398-80-7 Indium phosphide T; R48/23 Note: E >=0.01%Conc<0.1%: T; R45; R48/20 Eu - - - - - - - -
Conc>=10%: Xi; R41; R43
Xi; R41 Xi ; R: 41 - 43 >=5%Conc<10%: Xi; R36; R43
22411-22-9 Hafnium tetra-n-butoxide R43 S: (2)24/25 - 26 - 37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Page 192
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: T+; R26; R34; R22
>=10%Conc<25%: T+; R26; R34
>=7%Conc<10%: T+; R26; R36/38
T+; R26 T+ ; R: 22 - 26 - 34 , >=5%Conc<7%: T; R23; R36/38
Xn; R22 S: (1/2) - 9 - 26 - 28 - >=1%Conc<5%: T; R23
22432-68-4 4,4,5,5-Tetrachloro-1,3-dioxolan-2-one C; R34 36/37/39 - 45 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
T; N
T; R23/25 R: 21 - 23/25 - 50/53,
Bendiocarb (ISO) [2,2-Dimethyl-1,3-benzodioxol-4-yl Xn; R21 S: (1/2) - 22 - 36/37 - 45 - Conc>=25%: T; R23/25, R21
22781-23-3 N-methylcarbamate] N; R50-53 60 - 61 >=3%Conc<25%: Xn; R20/22 Eu - - - - - - - -
Xi ; R: 41 , Conc>=10%: Xi; R41
22961-82-6 2,2-Dimethyl-1,3-benzodioxol-4-ol Xi; R41 S: (2) - 24 - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Prallethrin
[2-Methyl-4-oxo-3-(prop-2-ynyl)cyclopent-2-en-1-yl T; R23 T; N
2,2-dimethyl-3-(2-methylprop-1- Xn; R22 R: 22-23-50/53 Conc>=25%: T; R23; R22
23031-36-9 enyl)cyclopropanecarboxylate; ETOC] N; R50-53 S: (1/2-)45-60-61 >=3%Conc<25%: Xn; R20 Eu - - - - - - - -
Repr. Cat. 3; R62 Xn ; N ; R: 38 - 43 - 62 -
Xi; R38 50/53 Conc>=20%: Xn; R62; R38; R43
R43 S: (2)23 - 36/37 - 41 - 60 - >=5%Conc<20%: Xn; R62; R43
23085-60-1 Benzyl 2,4-dibromobutanoate N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Pirimicarb [2-Dimethylamino-5,6-dimethylpyrimidin-4- T ; N ; R: 25 - 50/53,

yl dimethylcarbamate; 5,6-Dimethyl-2-dimethylamino- T; R25 S: (1/2) - 22 - 37 - 45 - 60 - Conc>=25%: T; R25
23103-98-2 pyrimidin-4-yI N,N-dimethylcarbamate] N; R50-53 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: T+; R26/28; R21
T+; R26/28 T+ ; N ; R: 21 - 26/28 - >=7%Conc<25%: T+; R26/28
N',N'-Dimethylcarbamoyl(methylthio)methylenamine Xn; R21 51/53, >=1%Conc<7%: T; R23/25
23135-22-0 N-methylcarbamate [Oxamyl] N; R51-53 S: (1/2) - 36/37 - 45 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -

Conc>=25%; T; R45; R68; R23/24/25; R48/25;

R43
>=10%Conc<25%; T; R45; R68; R48/25;
R20/21/22; R43
Carc. Cat. 2; R45 >=3%Conc<10%; T; R45; R68; R20/21/22;
Muta. Cat. 3; R68 R48/22; R43
T; R23/24/25-48/25 T >=1%Conc<3%; T; R45; R68; R48/22; R43
23268-00-0 Hydrazine, dihydrobromide R43 R: 45-23/24/25-43-48/25-68 >=0.1%Conc<1%; T; R45 N - - - - - - - -
T+ ; N ; R: 26/28 - 43 -
Formetanate hydrochloride [3-(N,N- T+; R26/28 50/53, Conc>=7%: T+; R26/28; R43
Dimethylaminomethyleneamino)phenyl N- R43 S: (1/2) - 24 - 28 - 37/39 - >=1%Conc<7%: T; R23/25; R43
23422-53-9 methylcarbamate] N; R50-53 45 - 60 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
T; R25 T ; N ; R: 21 - 25 - 50/53,
Pirimiphos ethyl (ISO) [O,O-Diethyl O-2-diethylamino- Xn; R21 S: (1/2) - 23 - 36/37 - 45 - Conc>=25%: T; R25; R21
23505-41-1 6-methylpyrimidin-4-yl phosphorothioate] N; R50-53 60 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -

T; N
Heptenophos (ISO) [7-Chlorobicyclo(3.2.0)hepta-2,6- T; R25 R: 25-50/53 Conc>=25%: T; R25
23560-59-0 dien-6-yl dimethyl phosphate] N; R50-53 S: (1/2-)23-28-37-45-60-61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Muta. Cat. 3; R68
Thiophanate methyl (ISO) [Dimethyl 4,4'-(O- Xn; R20 Xn; N
phenylene)-bis-(3-thioallophanate); 1,2-di-(3- R43 R: 20 - 43 - 50/53 - 68 Conc>=25%: Xn; R68; R20; R43
23564-05-8 Methoxycarbonyl-2-thioureido)benzene] N; R50-53 S: (2) - 36/37 - 46 - 60 - 61 >=1%Conc<25%: Xn; R68, R43 Eu - - - - - - - -
23593-75-1 Clotrimazole Xn; R22 Xn ; R: 22 Conc>=25%; Xn; R22 V - - - - - - - -
Conc>=25%: C; R34; R22; R48/22; R43
Xn; R22-48/22 C ; R: 22 - 34 - 43 - 48/22, >=10%Conc<25%: C; R34; R48/22; R43
C; R34 S: (1/2) - 22 - 26 - 36/37/39 - >=5%Conc<10%: Xi; R36/38; R43
23783-26-8 Hydroxyphosphonoacetic acid R43 45 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
2,2''-Dihydroxy-4,4''-(2-hydroxy-propane-1,3- R: 53
23911-85-5 diyldioxy)dibenzophenone R53 S: 61 Eu - - - - - - - -
Ethirimol (ISO) [5-Butyl-2-ethylamino-6- Xn ; R: 21 ,
23947-60-6 methylpyrimidin-4-ol] Xn; R21 S: (2) - 36/37 Conc>=25%: Xn; R21 Eu - - - - - - - -
Propyzamide (ISO) [3,5-Dichloro-N-(1,1-dimethylprop- Carc. Cat. 3; R40 Xn ; N ; R: 40 - 50/53
23950-58-5 2-ynyl)benzamide] N; R50-53 S: (2)36/37 - 60 - 61 Conc>=1%: Xn; R40 Eu - - - - - - - -

Page 193
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T; R23/25 T; N
Triazophos (ISO) [O,O-Diethyl-O-1-phenyl-1H-1,2,4- Xn; R21 R: 21-23/25-50/53 Conc>=25%: T; R23/25; R21
24017-47-8 triazol-3-yl phosphorothioate] N; R50-53 S: (1/2-)36/37-45-60-61 >=3%Conc<25%: Xn; R20/22 Eu - - - - - - - -
Xn ; R: 21/22 ,
24083-03-2 1-(2-Butoxypropoxy)propan-2-ol Xn; R21/22 S: (2) Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Xn; R22-48/22 Conc>=25%: Xn; R22; R48/22; R41; R43
Xi; R41 Xn; N >=10%Conc<25%: Xn; R48/22; R41; R43
R43 R: 22-41-43-48/22-50/53 >=5%Conc<10%: Xi; R36; R43
24085-06-1 2-Acetoxymethylene-4-acetylphenylacetate N; R50-53 S: (2-)22-26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Piperophos (ISO) [S-2- Xn; N
Methylpiperidinocarbonylmethyl-O,O-dipropyl Xn; R22 R: 22-50/53
24151-93-7 phosphorodithioate] N; R50-53 S: (2-)60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
4,4'-Thiodi-o-cresol [Bis(4-hydroxy-3- Xi; R41 Xi ; N ; R: 41 - 50/53 , Conc>=10%: Xi; R41
24197-34-0 methylphenyl)sulfide] N; R50-53 S: (2) - 26 - 39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R20/22
Xi; R38 Xn; N Conc>=25%: Xn; R20/22; R38; R43
R43 R: 20/22-38-43-50/53 >=20%Conc<25%; Xi; R38; R43
24279-39-8 2,6-Dichloro-4-trifluoromethylaniline N; R50-53 S: (2-)24-37-60-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn
Xn; R22 R: 22-52/53
24294-01-7 3-N,N-Bis(methoxyethyl)aminoacetanilide R52-53 S: (2-)22-24-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn; R: 22 - 52/53,
24307-26-4 1,1-Dimethylpiperidinium chloride [Mepiquat chloride] R52-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
R10,
24342-03-8 Isobutyl but-3-enoate R10 S: (2) Eu - - - - - - - -

T; R24 Conc>=25%: T; R24; R34; R22; R48/22; R43

Xn; R22-48/22 T ; N ; R: 22 - 24 - 34 - 43 - >=10%Conc<25%: C; R34; R21; R48/22; R43
C; R34 48/22 - 50/53 >=5%Conc<10%: Xn; R21; R36/38; R43
R43 S: (1/2) - 26 - 36/37/39 - 45 - >=3%Conc<5%: Xn; R21; R43
24403-04-1 2-Bromo-2-nitropropanol N; R50-53 60 - 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Repr. Cat. 2; R61 T ; N ; R: 61 - 20/22 - 38 -
Xn; R20/22 50/53, Conc>=25%: T; R61; R20/22; R38
Xi; R38 S: 53 - 45 - 60 - 61; >=20%Conc<25%: T; R61; R38
24602-86-6 Tridemorph (ISO) [2,6-Dimethyl-4-tridecylmorpholine] N; R50-53 Note; E >=0.5%Conc<20%: T; R61 Eu - - - - - - - -

O; R8
Carc. Cat. 1; R45
Muta. Cat. 2; R46 Conc>=25%: T+; R45; R46; R60; R61; R26;
Repr. Cat. 2; R60-61 R25; R48/23; R34; R21; R42/43
T+; R26 >=10%Conc<25%: T+; R45; R46; R60; R61;
T; R25-48/23 R26; R48/23; R34; R22; R42/43
C; R34 >=7%Conc<10%: T+; R45; R46; R60; R61;
Xn; R21 O; T+; N R26; R22; R48/20; R36/38; R42/43
Chromic acid (H2CrO4), chromium(3+) salt (3:2) R42/43 R: 45-46-60-61-21-25-26-34- >=5%Conc<7%: T; R45; R46; R60; R61; R23;
24613-89-6 [Chromium-III-chromate] N; R50-53 42/43-48/23-50-53 R22; N/Eu - - - - - - - -
O; R8
Carc. Cat. 2; R45 Conc>=10%: T; R45; R35; R43
C; R35 O ; T ; C ; N ; R: 45 - 8 - 35 - >=5%Conc<10%: T; R45; R34; R43
Chromium-III-chromate [Dichromium tris(chromate); R43 43 - 50/53, >=1%Conc<5%: T; R45; R36/38; R43
24613-89-6 Chromic acid (H2CrO4), chromium(3+) salt (3:2)] N; R50-53 S: 53 - 45 - 60 - 61 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Pyracarbolid [3,4-Dihydro-6-methyl-2H-pyran-5- R: 52/53,
24691-76-7 carboxanilide] R52-53 S: 61 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
24824-71-3 Phosphonic acid, lead(2+) salt R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -
Xn; R22
R43 Xn ; N ; R: 22 - 43 - 50/53 Conc>=25%: Xn; R22; R43
24856-00-6 5-Bromo-8-naphtholactam N; R50-53 S: (2)22 - 24 - 37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T+; N
R: 27/28-50/53 Conc>=7%: T+; R27/28
Chlormephos (ISO) [S-Chloromethyl O,O-diethyl T+; R27/28 S: (1/2-)27-28-36/37-45-60- >=1%Conc<7%: T; R24/25
24934-91-6 phosphorodithioate] N; R50-53 61 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
25013-15-4 Methyl styrene, all isomers [Vinyl toluene] A Vinyl toluene 50 242 100 483 - - -
Xn; R22
Xi; R36 Conc>=25%: Xn; R22; R36; R43
Bentazone (ISO) [3-Isopropyl-2,1,3-benzothiadiazine- R43 Xn ; R: 22 - 36 - 43 - 52/53, >=20%Conc<25%: Xi; R36; R43
25057-89-0 4-one-2,2-dioxide] R52-53 S: (2) - 24 - 37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
3,6-Dichloro-o-anisic acid, compound with 2,2’-
iminodiethanol (1:1)(Note: see also CAS No 1982-69- R: 52/53,
25059-78-3 0 & 53404-28-7) R52-53 S: 61 Eu - - - - - - - -
Benazolin-ethyl [Ethyl 4-chloro-2-oxo-2H- N ; R: 51/53
25059-80-7 benzothiazole-3-acetate] N; R51-53 S: 61 Eu - - - - - - - -
Bisphenol-A-(epichlorhydrin), reaction product
Xi; R36/38 Xi; N
[Epoxy resin (number average molecular weight R43 R: 36/38-43-51/53 Conc>=5%: Xi; R36/38; R43
25068-38-6 =&lt; 700)] N; R51-53 S: (2-)28-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Repr.Cat.3; R62
Repr.Cat.3; R63 C; N
Xn; R22 R: 22-34-62-63-50/53 Conc>=25%: C; R62; R63; R34; R22
Nonylphenol (Note: see also CAS C; R34 S: (1/2-)26-36/37/39-45-46- >=10%Conc<25%: C; R62; 63; R34
25154-52-3 No. 84852-15-3) N; R50-53 60-61 >=5%Conc<10%: Xn; R62; R63; R36/38 Eu - - - - - - - -
T+ ; N ; R: 26/27/28 - 33 -
T+; R26/27/28 50/53 , Conc>=7%: T+; R26/27/28; R33
Dinitrobenzene(Note: see also CAS No 528-29-0, 99- R33. S: (1/2) - 28 - 36/37 - 45 - >=1%Conc<7%: T; R23/24/25; R33
25154-54-5 65-0 & 100-25-4) N; R50-53 60 - 61 >= 0.1%Conc<1%; Xn; R20/21/22 Eu - - - - - - - -
T
R: 60
25155-23-1 Trixylyl phosphate Repr. Cat. 2; R60 S: 53-45 Conc>=0.5%: T; R60 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, dodecyl-, sodium salt [Sodium Xn; R22 Xn >=10%Conc<20%: Xi; R41
25155-30-0 dodecyl benzene sulphonate] Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Xn ; N ; R: 20/21/22 - 51/53,
Chlorophenol(Note: see also CAS No 95-57-8, 106- Xn; R20/21/22 S: (2) - 28 - 61;
25167-80-0 48-9 & 108-43-0) N; R51-53 Note: C Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Xn ; N ; R: 20 - 51/53
Chlorotoluene(Note: see also CAS No 95-49-8, 108- Xn; R20 S: (2) - 24/25 - 61
25168-05-2 41-8 & 106-43-4) N; R51-53 Note: C Conc>=25%: Xn; R20 Eu - - - - - - - -
Isofenphos (ISO) [O-Ethyl O-2- T; N
isopropoxycarbonylphenyl- T; R24/25 R: 24/25-50/53 Conc>=25%: T; R24/25
25311-71-1 isopropylphosphoramidothioate] N; R50-53 S: (1/2-)36/37-45-60-61 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -

Conc>=25%: T; R45; R62; R68; R23/24/25;

R48/22
Carc. Cat. 2; R45 >=10%Conc<25%: R45; R62; R68; R20/21/22;
Muta. Cat. 3; R68 T; N R48/22
Repr. Cat. 3; R62 R: 45-23/24/25-48/22-62-68- >=5%Conc<10%: T; R45; R62; R68; R20/21/22
T; R23/24/25 50/53 >=3%Conc<5%: T; R45; R68; R20/21/22
Xn; R48/22 S: 53-45-60-61 >=1%Conc<3%: T; R45; R68
25321-14-6 Dinitrotoluene(Note: see also CAS No. 121-14-2) N; R50-53 Note: E >=0.1%Conc<1%: T; R45 Eu;A Dinitrotoluene (h) - 1.5 - - - Sk -
Xn; N
Thiazfluron (ISO) [1,3-Dimethyl-1-(5-trifluoromethyl- Xn; R22 R: 22 - 50/53
25366-23-8 1,3,4-thiadiazol-2-yl)urea] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
(R)-alpha-Phenylethylammonium (-)-(1R, 2S)-(1,2- Repr. Cat. 3; R62 Xn ; N ; R: 62 - 51/53
25383-07-7 epoxypropyl)phosphonate monohydrate N; R51-53 S: (2 - )22 - 36/37 - 61 Conc>=5%: Xn; R62 Eu - - - - - - - -
3-(But-2-enyl)-2-methyl-4-oxocyclopent-2-enyl-2,2- Xn; N
dimethyl-3-(2-methylprop-1- Xn; R22 R: 22 - 50/53
25402-06-6 enyl)cyclopropanecarboxylate [Cinerin-I] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

Hexahydromethylphthalic anhydride(Note: see also Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
25550-51-0 CAS No 19438-60-9; 48122-14-1 & 57110-29-9) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
T; N
T; R23/24/25 R: 23/24/25 - 33 - 50/53 Conc>=25%: T; R23/24/25; R33
R33 S: (1/2) - 28 - 37 - 45 - 60 - >=3%Conc<25%: Xn; R20/21/22; R33
25550-58-7 Dinitrophenol(Note: see also CAS No 71629-74-8) N; R50-53 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -

25551-13-7 Trimethyl benzene [Benzene, trimethyl] A Trimethyl benzene 25 123 - - - - -

T ; N ; R: 23/24/25 - 33 -
50/53 ,
T; R23/24/25 S: (1/2 ) - 28 - 36/37 - 45 - Conc>=25%: T; R23/24/25; R33
R33 60 - 61 ; >=3%Conc<25%: Xn; R20/21/22; R33
25567-67-3 Chlorodinitrobenzene N; R50-53 Note: C >=1%Conc<3%: Xn; R33 Eu - - - - - - - -

Conc>=10%: T; R23/24/25; R34; R43

2-Propenoic acid, monoester with 1,2-Propanediol [2- T; R23/24/25 T ; R: 23/24/25 - 34 - 43, >=5%Conc<10%: T; R23/24/25; R36/38; R43
Hydroxypropyl acrylate](Note: see also CAS No 999- C; R34 S: (1/2) - 26 - 36/37/39 - 45; >=2%Conc<5%: T; R23/24/25; R43
25584-83-2 61-1 & 2918-23-2) R43 Notes: C ; D >=0.2%Conc<2%: Xn; R20/21/22; R43 Eu - - - - - - - -
Xi ; R: 36/38,
25634-93-9 2-Methyl-5-phenylpentanol Xi; R 36/38 S: (2) - 26 - 37 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
Xn; N Tin, organic
Hexapentyldistannoxane (Note: see also CAS No. Xn; R20/21/22 R: 20/21/22-50/53 compounds (as
25637-27-8 20153-49-5) N; R50-53 S: (2-)26-28-60-61 Conc>=1%: Xn; R20/21/22 Eu; A Sn) - 0.1 - 0.2 - Sk -
Xn
Hexabromocyclododecane [HBCD; Cyclododecane, R: 63-64 Conc>=5%: Xn; R63; R64
25637-99-4 hexabromo](Note: see also CAS No 3194-55-6) Repr. Cat. 3; R63 R64 S: 22-53-60-61 >=1%Conc<5%: Xn; R64 Eu/N - - - - - - - -
Methylcyclohexano
25639-42-3 Methylcyclohexanol A l 50 234 - - - - -
4-(N-Ethyl-N-2-methanesulphonylaminoethyl)-2-
methylphenylenediamine sesquisulphate
monohydrate [N-(2-(4-Amino-N-ethyl-m- Xn; R22
toluidino)ethyl)methanesulphonamide R43 Xn ; N ; R: 22 - 43 - 50/53, Conc>=25%: Xn; R22; R43
25646-71-3 sesquisulphate] N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
T; R25 T ; N ; R: 25 - 43 - 48/22 - Conc>=25%: T; R25; R48/22; R43
(4-Ammonio-m-tolyl)ethyl(2-hydroxyethyl)ammonium Xn; R48/22 50/53, >=10%Conc<25%: Xn; R22; R48/22; R43
sulphate [4-(N-Ethyl-N-2-hydroxyethyl)-2- R43 S: (1/2) - 24 - 37 - 45 - 60 - >=3%Conc<10%: Xn; R22; R43
25646-77-9 methylphenylenediamine sulphate] N; R50-53 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R40; R23; R48/23; R36/37/38;

R42/43
>=20%Conc<25%: T; R40; R48/23; R20;
R36/37/38; R42/43
>=10%Conc<20%: T; R40; R48/23; R20;
Carc. Cat. 3; R40 R42/43
T; R23-R48/23 T >=3%Conc<10%: Xn; R40; R20; R48/20;
Benzene, 1,1'-methylenebis[4-isocyanato-, Xi; R36/37/38 R: 23-36/37/38-40-42/43- R42/43
25686-28-6 homopolymer R42/43 48/23 >=1%Conc<3%: Xn; R40; R48/20; R42/43 N - - - - - - - -
Repr. Cat. 1; R61 T; N
Repr. Cat. 3; R62 R: 61 - 62 - 20/22 - 33 - Conc>=25%: T; R61; R62; R20/22; R33
Xn; R20/22 50/53 >=5%Conc<25%: T; R61; R62; R33
R33 S: 53 - 45 - 60 - 61; >=1%Conc<5%: T; R61; R33
25808-74-6 Lead hexafluorosilicate N; R50-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 43 Conc>=25%: Xn; R22; R43
25965-81-5 1-(2-Propenyl)pyridinium chloride R43 S: (2)24 - 37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xn; N
Iprobenfos Xn; R22 R: 22-51/53
26087-47-8 [S-Benzyl diisopropyl phosphorothioate] N; R51-53 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi; R41 Xi ; N ; R: 41 - 50/53 Conc>=10%: Xi; R41
26116-56-3 (9S)-9-Amino-9-deoxyerythromycin N; R50-53 S: (2)26 - 39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
0.5 Peak 4.7 Peak
26140-60-3 Terphenyls A Terphenyls limitation limitation - - - - -

Page 196
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn
N,N',N"-Tris(2-methyl-2,3-epoxypropyl)-perhydro- Muta. Cat. 3; R68 R: 68-52/53
26157-73-3 2,4,6-oxo-1,3,5-triazine R52-53 S: (2-)36/37-61 Conc>=1%: Xn; R68 Eu - - - - - - - -

N R: 50/53
26218-04-2 2-Ethylhexyl 4-aminobenzoate N; R50-53 S: 60-61 Eu - - - - - - - -
Ethofumesate (ISO) [(+)-2-Ethoxy-2,3-dihydro-3,3- N ; R: 51/53
26225-79-6 dimethylbenzofuran-5-yl methanesulfonate N; R51-53 S: 61 Eu - - - - - - - -
Xn; R22
Secbumeton (ISO) [2-sec-Butylamino-4-ethylamino-6- Xi; R36 Xn ; N ; R: 22 - 36 - 50/53, Conc>=25%: Xn; R22; R36
26259-45-0 methoxy-1,3,5-triazine] N; R50-53 S: (2) - 60 - 61 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -

Xn ; R: 41 - 42/43 - 51/53 ,
Tetrahydrophthalic anhydride [1,3- Xi; R41 S: (2) - 22 - 24 - 26 - 37/39 - Conc>=10%: Xn; R42/43; R41
Isobenzofurandione, tetrahydro](Note: see also CAS Xn; R42/43 61; >=5%Conc<10%: Xn; R42/43; R36
26266-63-7 No 85-43-8, 935-79-5 & 2426-02-0) R51-53 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Xn
Xn; R22-48/22 R: 22-48/22-52/53 Conc>=25%: Xn; R22; R48/22
26364-65-8 2-Thiazolidinylidenecyanamide R52-53 S: (2-)22-36-61 >=10%Conc<25%: Xn; 48/22 Eu - - - - - - - -
Profluralin (ISO) [N-(Cyclopropylmethyl)-
alpha,alpha,alpha-trifluoro-2,6-dinitro-N-propyl-p- Xi; R36 Xi ; N ; R: 36 - 50/53,
26399-36-0 toluidine] N; R50-53 S: (2) - 60 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
Muta. Cat. 3; R68 Xn ; N ; R: 38 - 43 - 51/53 -
Xi; R38 68,
(Tolyloxy)methyl]oxirane [Cresyl glycidyl ether](Note: R43 S: (2) - 36/37 - 61; Conc>=20%:Xn; R68; R38; R43
26447-14-3 see also CAS No 2186-24-5; 2186-25-6 & 2210-79-9) N; R51-53 Note: C >=1%Conc<20%: Xn; R68; R43 Eu - - - - - - - -

Conc>=25%: T; R40; R23; R48/23; R36/37/38;

R42/43
>=20%Conc<25%: T; R40; R48/23; R20;
R36/37/38; R42/43
>=10%Conc<20%: T; R40; R48/23; R20;
Carc. Cat. 3; R40 R42/43
T; R23-R48/23 T >=3%Conc<10%: Xn; R40; R20; R48/20;
Benzene, 1,1'-methylenebis[isocyanato- Xi; R36/37/38 R: 23-36/37/38-40-42/43- R42/43 Isocyanates, all
26447-40-5 [Methylenediphenyl diisocyanate] R42/43 48/23 >=1%Conc<3%: Xn; R40; R48/20; R42/43 N/Eu; A (as-NCO) - 0.02 - 0.07 - Sen -
Carc. Cat. 3; R40
T+; R26 T+ Conc>=20%: T+; R40; R26; R36/37/38; R42/43
m-Toluene-diisocyanate [m-Tolylidene Xi; R36/37/38 R: 26-36/37/38-40-42/43- >=7%Conc<20%: T+; R40; R26; R42/43
diisocyanate](Note: see also CAS No. 91-08-7 and R42/43 52/53 >=1% Conc<7%: T; R40; R23; R42/43 Isocyanates, all
26471-62-5 584-84-9) R52-53 S: (1/2-)23-36/37-45-61 >=0.1%Conc<1%: Xn; R20; R42 Eu; A (as-NCO) - 0.02 - 0.07 - Sen -
Xi
26516-27-8 Pentanoic acid, 3-methyl-2-oxo-, ethyl ester R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Xi; N
Xi; R43 R: 43-50/53
26523-78-4 Tris(nonylphenyl) phosphite N; R50-53 S: 24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

T; R23/24 Conc>=25%: T; R23/24; R22; R34; R43

Xn; R22 T; N >=10%Conc<25%: C; R34; R20/21; R43
C; R34 R: 22-23/24-34-43-50/53 >=5%Conc<10%: Xn; R20/21; R36/38; R43
R43 S: (1/2-)26-36/37/39-45-60- >=3%Conc<5%: Xn; R20/21; R43
26530-20-1 2-Octyl-2H-isothiazol-3-one N; R50-53 61 >=0.05%Conc<3%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 52/53 ,
26576-84-1 1-Butyl-2-methylpyridinium bromide R52-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

1,2,3,6-Tetrahydromethylphthalic anhydride(Note: Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

see also CAS No 1694-82-2; 3425-89-6; 5333-84-6; Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
26590-20-5 11070-44-3; 34090-76-1 & 42498-58-80) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -

Carc. Cat. 3; R40 Conc>=20%: T+; R40; R26; R36/37/38; R42/43

T+; R26 >=7%Conc<20%: T+; R40; R26; R42/43
1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-tris(3- Xi; R36/37/38 T+ >=1%Conc<7%: T; R40; R23; R42/43
26603-40-7 isocyanatomethylphenyl)- R42/43 R: 26-36/37/38-40-42/23 >=0.1%Conc<1%: Xn; R20 N - - - - - - - -

Page 197
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

T+; R28 Conc>=7%: T+; R28; R32

R32 T+ ; N ; R: 28 - 32 - 50/53, >=1%Conc<7%: T; R25; R32 0.11 Peak 0.3 Peak
26628-22-8 Sodium azide N; R50-53 S: (1/2) - 28 - 45 - 60 - 61 >=0.1%Conc<1%: Xn; R22; R32 Eu; A Sodium azide (f) limitation limitation - - - - -
Isooctane(Note: see also CAS No. 111-65-9, 540-84- F; R11
1, 560-21-4, 563-16-6, 564-02-3, 565-75-3, 583-48-2, Xn; R65 F; Xn; N
584-94-1, 589-43-5, 589-53-7, 589-81-1, 590-73-8, Xi; R38 R: 11-38-65-67-50/53
592-13-2, 592-27-8, 594-82-1, 609-26-7, 619-99-8 & R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
26635-64-3 1067-08-9) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
Xn
R: 22
26739-54-8 Guanidinium benzoate Xn; R22 S: (2-)22-25 Conc>=25%: Xn; R22 Eu - - - - - - - -

Carc. Cat. 3; R40 Conc>=20%: T+; R40; R26; R36/37/38; R42/43

T+; R26 >=7%Conc<20%: T+; R40; R26; R42/43
1,3-Diazetidine-2,4-dione, 1,3-bis(3- Xi; R36/37/38 T+ >=1%Conc<7%: T; R40; R23; R42/43
26747-90-0 isocyanatomethylphenyl)- R42/43 R: 26-36/37/38-40-42/23 >=0.1%Conc<1%: Xn; R20 N - - - - - - - -
Triarimol [2,4-Dichloro-alpha-(pyrimidin-5-yl) Xn ; R: 22 ,
26766-27-8 benzhydryl alcohol] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, dodecyl-, compound with 2- Xn; R22 Xn >=10%Conc<20%: Xi; R41
26836-07-7 aminoethanol (1:1) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Xi; N
9-(2-Propenyloxy)tricyclo[5.2.1.0(2,6)]dec-3(or-4-)- Xi; R38 R: 38-51/53
26912-64-1 ene N; R51-53 S: (2-)23-37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
26952-21-6 Isooctyl alcohol [Isoactanol] A Isooctyl alcohol 50 266 - - - Sk -
R43 Xi ; R: 43 - 52/53
27080-42-8 2-[(4-Nitrophenyl)amino]ethyl]urea R52-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R45; R68; R23/24/25;

R48/23/24/25; R36/38; R43
>=20%Conc<25% : T; R45; R68;
R48/23/24/25; R20/21/22; R36/38; R43
>=10%Conc<20%: T; R45; R68; R48/23/24/25;
Carc. Cat. 2; R45 R20/21/22; R43
Muta. Cat. 3; R68 T; N >=3%Conc<10%: T; R45; R68; R20/21/22;
T; R23/24/25-48/23/24/25 R: 45-23/24/25-36/38-43- R48/20/21/22; R43
Xi; R36/38 48/23/24/25-68-50 >=1%Conc<3%: T; R45; R68; R48/20/21/22;
Phenylhydrazine hydrochloride (Note: see also R43 S: 53-45-61; R43
27140-08-5 Cas No. 100-63-0, 59-88-1 and 52033-74-6) N; R50 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Conc>=10%: Xi; R38; R41; R43
Xi; R38-41 >=1%Conc<10%: Xi; R41; R43
27176-87-0 Dodecylbenzene sulfonic acid R43 Xi; R: 38-41-43 >=0.5%Conc<1%: Xi; R41 V - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Xn; R22 Xn >=10%Conc<20%: Xi; R41
27177-77-1 Benzenesulfonic acid, dodecyl-, potassium salt Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
27253-28-7 Neodecanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
27253-41-4 Isononanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
T; N
Repr. Cat. 2; R61 R: 61-50/53
27366-72-9 N,N-(Dimethylamino)thioacetamide hydrochloride N; R50-53 S: 53-45-60-61 Conc>=0.5%: T; R61 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi
Xi; R38 R: 38-52/53
27460-02-2 Dodecyldiphenyl phosphate R52-53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Muta. Cat. 3; R68
Xn; R21
Xi; R38 Xn Conc>=25%: Xn; R68; R21; R38; R43
R43 R: 21-38-43-68-52/53 >=20%Conc<25%: Xn; R68; R38; R43
27610-48-6 6-Glycidyloxynapht-1-yl oxymethyloxirane R52-53 S: (2-)36/37/39-61 >=1%Conc<20%: Xn; R68; R43 Eu - - - - - - - -
E; R3 E; Xi
2,4-Diamino-5-[4-[(2-sulfoxyl Xi; R41 R: 3-41-52/53 Conc>=10%: Xi; R41
27624-67-5 ethyl)sulfonyl]phenylazo]benzenesulfonic acid R52-53 S: (2-)22-26-35-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
2-Propenoic acid, 2-methyl-, monoester with 1,2- Xi; R36 Xi Conc>=20%: Xi; R36; R43
27813-02-1 propanediol R43 R: 36-43 >=1%Conc<20%: Xi; R43 N - - - - - - - -
Xi ; R: 10 - 36/37
Methyl (S)-(-)-lactate(Note: see also CAS No 547-64- R10 S: (2) - 24;
27871-49-4 8; 2155-30-8 & 17392-83-5) Xi; R36/37 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -
N ; R: 51/53,
27955-94-8 4,4',4"-(Ethan-1,1,1-triyl)triphenoI N; R51-53 S: 61 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 50/53,
28249-77-6 s-4-Chlorobenzyl diethylthiocarbamate [Thiobencarb] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; N
Xn; R22-48/22 R: 22-48/22-51/53 Conc>=25%: Xn; R22; R48/22
28365-08-4 2,6-Diamino-3-((pyridine-3-yl)azo)pyridine N; R51-53 S: (2-)22-36-61 >=10%Conc<25%: Xn; 48/22 Eu - - - - - - - -

S-Bioallethrin [(S)-3-allyl-2-methyl-4-oxocyclopent-2-
enyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1- Xn ; N ; R: 20/22 - 50/53,
enyl)cyclopropanecarboxylate](Note: see also CAS Xn; R20/22 S: (2) - 36 - 60 - 61
28434-00-6 584-79-2 & 84030-86-4) N; R50-53 Note: C Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Bioresmethrin (ISO) [(5-Benzylfur-3-yl)methyl(1R)- N
trans-2,2-dimethyl-3-(2- R: 50/53
28434-01-7 methylpropenyl)cyclopropanecarboxylate] N; R50-53 S: 60-61 Eu - - - - - - - -
[(1-Methyl-1,2- Xi; N
ethanediyl)bis[nitrilobis(methylene)]]tetrakis(phospho Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
28698-31-9 nic acid) N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

E; R2. E ; Xn ; R: 2 - 4 - 20/21/22 ,
R4. S: (2) - 35 ;
28905-71-7 Trinitrocresol Xn; R20/21/22 Note: C Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -

Carc. Cat. 3; R40

Repr. Cat. 2; R61 T; N Conc>=25%: T; R40; R61; R64; R20/22;
T; R48/25 R: 61-20/22-40-48/25-64- R48/25
Ammonium perfluorooctane sulfonate [Ammonium Xn; R20/22 51/53 >=10%Conc<25%: T; R40; R61; R64; R48/25
heptadecafluorooctanesulfonate](Note: see also CAS R64 S: 53-45-61 >=1%Conc<10%: T; R40; R61; R64; R48/22
29081-56-9 No. 1763-23-1, 2795-39-3, 70225-14-8, 29457-72-5) N; R51-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Anisidine (o-, p-
29191-52-4 Anisidine, (o-, p- isomers) A isomers) 0.1 0.5 - - - Sk -
Xn; N
Pirimiphos-methyl (ISO) [O-(2-Diethylamino-6- Xn; R22 R: 22-50/53
29232-93-7 methylpyrimidin-4-yl) O,O-dimethyl phosphorothioate] N; R50-53 S: (2-)60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Phosphonic acid, (1-hydroxyethylidene)bis-, sodium Xn; R22 Xn Conc>=25%: Xn; R22; R36
29329-71-3 salt Xi; R36 R: 22-36 >=20%Conc<25%: Xi; R36 N - - - - - - - -
Xi; R: 36
29420-49-3 Potassium perfluorobutane sulfonate Xi; R36 S: 25-26 Conc>=20%: Xi; R36 N - - - - - - - -

Carc. Cat. 3; R40

Repr. Cat. 2; R61 T; N Conc>=25%: T; R40; R61; R64; R20/22;
T; R48/25 R: 61-20/22-40-48/25-64- R48/25
Lithium perfluorooctane sulfonate [Lithium Xn; R20/22 51/53 >=10%Conc<25%: T; R40; R61; R64; R48/25
heptadecafluorooctanesulfonate](Note: see also CAS R64 S: 53-45-61 >=1%Conc<10%: T; R40; R61; R64; R48/22
29457-72-5 No. 1763-23-1, 2795-39-3, 70225-14-8, 29081-56-9) N; R51-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Xi; N
Xi; R36/37/38 R: 36/37/38-50/53
29590-42-9 Isooctyl acrylate N; R50-53 S: (2-)26-28-60-61 Conc>=10%: Xi; R36/37/38 Eu - - - - - - - -

Page 199
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
29597-84-0 Docosanoic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Conc>=25%: C; R35; R21/22
C ; R: 21/22 - 35 >=10%Conc<25%: C; R35
Xn; R21/22 S: (1/2) - 23 - 26 - 28 - >=5%Conc<10%: C; R34
29617-66-1 (S)-2-Chloropropionic acid C; R35 36/37/39 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

Conc>=25%: T; R23/25; R21; R36/37/38; R43

T; R23/25 >=20%Conc<25%: Xn; R20/22; R36/37/38;
Xn; R21 R43
Xi; R36/37/38 T >=3%Conc<20%: Xn; R20/22; R43
29820-13-1 Acetic acid, mercapto-, calcium salt (1:1) R43 R: 21-23/25-36/37/38-43 >=1%Conc<3%: Xi; R43 N - - - - - - - -
Xn; R22 Xn ; R: 22 - 36/37/38 -
Xi; 36/37/38 52/53, Conc>=25%: Xn; R22; R36/37/38
29873-36-7 Morfamquat sulfate R52-53 S: (2) - 22 - 36 - 61 >=20%Conc<25%: Xi; R36/37/38 Eu - - - - - - - -
Ethiofencarb (ISO) [2-(Ethylthiomethyl)phenyl N- Xn; R22 Xn ; N ; R: 22 - 50/53,
29973-13-5 methylcarbamate] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
1-(5-Ethylsulphonyl-1-3,4-thiadiazol-2-yl)-1,3- Xi; R43 Xi ; N ; R: 43 - 50/53,
30043-49-3 dimethylurea [Ethidimuron] N; R50-53 S: (2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
30304-32-6 Isooctanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Acephate (ISO) [O,S-Dimethyl Xn ; R: 22 ,
30560-19-1 acetylphosphoramidothioate] Xn; R22 S: (2) - 36 Conc>=25%: Xn; R22 Eu - - - - - - - -

Xi; R43
This substance has only been
assessed against the single
endpoint of skin sensitisation.
This substance has not been
subject to a complete assessment
for hazard classification in
Acetic acid, mercapto-, monoester with 1,2,3- accordance with the approved
30618-84-9 propanetriol [Glycerol monothioglycolate; GMTG] criteria Xi; R:43 Conc>=1%: Xi; R43 N - - - - - - - -

Main component 6 (isomer): asym. 1:2 Cr(III)-

complex of: A: 3-hydroxy-4-(2-hydroxy-naphthalene-1-
ylazo)naphthalene-1-sulfonic acid, Na-salt and B: 1-[2-
hydroxy-5-(4-methoxy-
phenylazo)phenylazo]naphthalene-2-ol; Main
component 8 (isomer): asym. 1:2 Cr-complex of: A: 3-
hydroxy-4-(2-hydroxy-naphthalene-1-ylazo)-
naphthalene-1-sulfonic acid, Na-salt and B: 1-[2- Xi; N
hydroxy-5-(4-methoxy-phenylazo)-phenylazo]- Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
30785-74-1 naphthalene-2-ol N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22 Xn; N
Methyl 3-[(dimethoxyphosphinothioyl)oxyl- R43 R: 22 - 43 - 50/53 Conc>=25%: Xn; R22; R43
30864-28-9 methacryIate(Note: see also CAS No 62610-77-9) N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
R10 Xn
Xn; R20 R: 10-20-37-66
Pentanol isomers, with the exception of those Xi; R37 S: (2-)46; Conc>=25%: Xn; R20; R37
30899-19-5 specified elsewhere in HSIS [Amyl alcohol] R66 Note: C >=20%Conc<25%: Xi; R37 Eu - - - - - - - -

Page 200
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T; R40; R23; R48/23; R36/37/38;

R42/43
>=20%Conc<25%: T; R40; R48/23; R20;
R36/37/38; R42/43
>=10%Conc<20%: T; R40; R48/23; R20;
Carc. Cat. 3; R40 R42/43
1,3-Diazetidin-2-one, 1,3-bis[4-[(4- T; R23-R48/23 T >=3%Conc<10%: Xn; R40; R20; R48/20;
isocyanatophenyl)methyl]phenyl]-4-[[4-[(4- Xi; R36/37/38 R: 23-36/37/38-40-42/43- R42/43
31107-36-5 isocyanatophenyl)methyl]phenyl]imino]- R42/43 48/23 >=1%Conc<3%: Xn; R40; R48/20; R42/43 N - - - - - - - -
Propetamphos (ISO) [Trans-isopropyl-3-
[[(ethylamino)methoxyfosfinothioyl]oxy]crotonate;
Isopropyl 3- T; N
[[(ethylamino)methoxyphosphinothioyl]oxy]isocrotonat T; R25 R: 25-50/53 Conc>=25%: T; R25
31218-83-4 e] N; R50-53 S: (1/2-)37-45-60-61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Chlorinated
31242-93-0 Chlorinated diphenyl oxide A diphenyl oxide - 0.5 - - - - -
Sodium 2-anilino-5-(2-nitro-4-(N- Xi; R41 Xi ; R: 41 - 52/53 Conc>=10%: Xi; R41
31361-99-6 phenylsulfamoyl))anilinobenzenesulfonate R52-53 S: (2)26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi ; R: 41 , Conc>=10%: Xi; R41
31363-92-5 Titanium(4+)-oxalate Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
F; R11
Xn; R65 F; Xn; N
Isoheptane(Note: see also CAS No. 142-82-5, 108-08-Xi; R38 R: 11-38-65-67-50/53
7, 464-06-2, 562-49-2, 565-59-3,589-34-4, 590-35-2, R67 S: (2-)9-16-29-33-60-61-62 Conc>=20%: Xn; R65; R38
31394-54-4 591-76-4 & 617-78-7) N; R50-53 Note: C >=10%Conc<20%: Xn; R65 Eu - - - - - - - -
Xi ; R: 41 , Conc>=10%: Xi; R41
31506-43-1 3-(Dimethylamino)propylurea Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Bis(1,2,3-trithiacyclohexyldimethylammonium)oxalate Xn; R21/22 Xn ; N ; R: 21/22 - 50/53,

31895-22-4 [Thiocyclam oxalate] N; R50-53 S: (2) - 36/37 - 46 - 60 - 61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -
Xn; R22 C Conc>=25%: C; R34; R22; R43
C; R34 R: 22-34-43-52/53 >=10%Conc<25%: C; R34; R43
R43 S: (1/2-)22-26-36/37/39-45- >=5%Conc<10%: Xi; R36/38; R43
32047-53-3 1-Amino-2-methyl-2-propanethiol hydrochloride R52-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of 2,2'-bis(tert-pentylperoxy)-p- E; R2 E
diisopropylbenzene and 2,2'-bis(tert-pentylperoxy)-m- O; R7 R: 2-7-53
32144-25-5 diisopropylbenzene R53 S: (2-)3/7-14-36/37/39-61 Eu - - - - - - - -
Xi; N
Mixture of 3,7,11-trimethyl-cis-6,10-dodecadienal and Xi; R38 R: 38-50/53
32480-08-3 3,7,11-trimethyl-trans-6,10-dodecadienal N; R50-53 S: (2-)37-60-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xn ; N ; R: 48/21/22 - 64 -
Xn; R48/21/22 50/53 ,
Diphenyl ether, pentabromo R64 S: (1/2) - 36/37 - 45 - 60 - Conc>=10%: Xn; R64; R48/21/22
32534-81-9 derivativepentabromodiphenyl ether N; R50-53 61 >=1%Conc<10%: Xn; R64 Eu - - - - - - - -
T
Repr.Cat.2; R61 R: 61-62 Conc>=5%: T; R61; R62
32536-52-0 Diphenylether; octabromo derivate Repr.Cat.3; R62 S: 53-45 >=0.5%Conc<5%: T; R61 Eu - - - - - - - -
Poly(oxy-1,2-ethanediyl), .alpha.-sulfo-.omega.- Xn; R22 Xn Conc>=25%: Xn; R22; R36/38
32612-48-9 (dodecyloxy)-, ammonium salt Xi; R36/38 R: 22-36/38 >=20%Conc<25%: Xi; R36/38 N - - - - - - - -
N
R: 50/53
32750-89-3 Methyl 3-[[(dibutylamino)thioxomethyl]thio]propanoate N; R50-53 S: 60-61 Eu - - - - - - - -
(Cyclopentadienyl)(cumenyl)iron(1+)hexa- R: 52/53
32760-80-8 fluorophosphate(1-) R50-53 S: 61 Eu - - - - - - - -
R: 52/53
32998-95-1 N-tert-Butyl-3-methylpicolinamide R52-53 S: 61 Eu - - - - - - - -
Xn; R22-48/22 Xn; N Conc>=25%: Xn; R22; R48/22; R43
Amitraz (ISO) [N,N-Bis(2,4-xylyliminomethyl) R43 R: 22-43-48/22-50/53 >=10%Conc<25%: Xn; R48/22; R43
33089-61-1 methylamine] N; R50-53 S: (2-)22-24-60-36/37-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
tert-Butyl(5S,6R,7R)-3-bromomethyl-5,8-dioxo-7-(2-(2-
phenylacetamido)-5-thia-1-azabicyclo[4.2.0]oct-2-ene- Xn; R42/43 Xn ; R: 42/43 - 52/53,
33610-13-8 2-carboxylate R52-53 S: (2) - 22 - 24 - 37 - 61 Conc>=1%: Xn; R42/43 Eu - - - - - - - -

Page 201
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
33627-12-2 9,12-Octadecadienoic acid, (Z,Z)-, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Terbumeton (ISO) [2-tert-Butylamino-4-ethylamino-6- Xn; R22 Xn ; N ; R: 22 - 50/53,
33693-04-8 methoxy-1,3,5-triazine] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Etem [5,6-Dihydro-3H-imidazo[2,1-c]-1,2,4-dithiazole- Xn; R22 Xn ; N ; R: 22 - 50/53,
33813-20-6 3-thione] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn; N
Xi; R38 R: 22-38-51/53 Conc>=25%: Xn; R22; R38
33831-83-3 3,3,4,4-Tetrafluoro-4-iodo-1-butene N; R51-53 S: (2-)37-61 >=20%Conc<25%: Xi; R38 Eu - - - - - - - -
Xn; N
Tebuthiuron (ISO) [1-(5-tert-Butyl-1,3,4-thiadiazol-2- Xn; R22 R: 22 - 50/53
34014-18-1 yl)-1,3-dimethylurea] N; R50-53 S: (2) - 37 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R48/22 Xn
R43 R: 43-48/22-52/53 Conc>=10%: Xn; R48/22; R43
34036-80-1 2-Butanone-O,O',O''-(phenylsilylidyne)trioxime R52-53 S: (2-)36/37-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -

Tetrahydro-4-methylphthalic anhydride(Note: see Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

also CAS No 1694-82-2; 3425-89-6; 5333-84-6; Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
34090-76-1 11070-44-3; 26590-20-5 & 42498-58-80) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Isoproturon Xn; N
Carc. Cat. 3; R40 R: 40-50/53
34123-59-6 [3-(4-Isopropylphenyl)-1,1-dimethylurea] N; R50-53 S: (2-)36/37-60-61 Conc>=1%: Xn; R40 Eu - - - - - - - -
Xn; R20
Xi; R37/38 Xn ; N ; R: 20 - 37/38 - 43 - Conc>=25%: Xn; R20; R37/38; R43
2-Chloro-N-(ethoxymethyl)-N-(2-ethyl-6- R43 50/53, >=20%Conc<25%: Xi; R37/38; R43
34256-82-1 methyIphenyl)acetamide [Acetochlor] N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
34303-23-6 Docosanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

Conc>=25%: T; R23/25; R21; R36/37/38; R43

T; R23/25 >=20%Conc<25%: Xn; R20/22; R36/37/38;
Xn; R21 R43
Xi; R36/37/38 T >=3%Conc<20%: Xn; R20/22; R43
34452-51-2 Acetic acid, mercapto-, monopotassium salt R43 R: 21-23/25-36/37/38-43 >=1%Conc<3%: Xi; R43 N - - - - - - - -
(2-
2-(Methoxymethylethoxy) propanol [Dipropylene Methoxymethyleth
34590-94-8 glycol (mono) methyl ether] A oxy) propanol 50 308 - - - Sk -
Xi
R: 36
34640-92-1 2,2-Diethoxy-N,N-dimethylacetamide Xi; R36 S: (2-)26 Conc>=20%: Xi; R36 Eu - - - - - - - -
R10 T ; N ; R: 10 - 23/24/25 - 36 -
T; R23/24/25 50/53, Conc>=25%: T; R23/24/25; R36
Butocarboxim [3-(Methylthio)-2-butanone O- Xi; R36 S: (1/2) - 36/37 - 45 - 60 - >=20%Conc<25%: Xn; R20/21/22; R36
34681-10-2 [(methylamino)carbonyl]oxime] N; R50-53 61 >=3%Conc<20%: Xn; R20/21/22 Eu - - - - - - - -

T; R25 Conc>=25%: T; R25; R48/22; R36; R43

Xn; R48/22 T ; N ; R: 25 - 36 - 43 - >=20%Conc<25%: Xn; R22; R48/22; R36; R43
Xi; R36 48/22 - 51/53 >=10%Conc<20%: Xn; R22; R48/22; R43
R43 S: (1/2) - 26 - 36/37/39 - 45 - >=3%Conc<10%: Xn; R22; R43
35000-38-5 tert-Butyl (triphenylphosphoranylidene) acetate N; R51-53 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Xi; R: 10 - 36/37,
2-Methylbutyl formate(Note: see also CAS No 110-45- R10 S: (2) - 24;
35073-27-9 2 & 638-49-3]) Xi; R36/37 Note: C Conc>=20%: Xi; R36/37 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
35400-43-2 Sulprofos A Sulprofos - 1 - - - - -

Mixture of: cis-1,4-dimethylcyclohexyl dibenzoate and

35541-81-2 trans-1,4-dimethylcyclohexyl dibenzoate R 53 R: 53 S: 61 Eu - - - - - - - -
Xn; R20/22 Xn; N Conc>=25%: Xn; R20/22; R41
1-[2-(Allyloxy)-2-(2,4-dichlorophenyl)ethyl]-1H- Xi; R41 R: 20/22 - 41 - 50/53 >=10%Conc<25%: Xi; R41
35554-44-0 imidazole [Imazalil (ISO)] N; R50-53 S: (2) - 26 - 39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn
R: 22
35687-90-2 Tripropylammonium dihydrogenphosphate Xn; R22 S: (2-)22 Conc>=25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: Xn; R22; R41; R43
Xn; R22 >=10%Conc<25%: Xi; R41; R43
Xi; R41 Xn ; R: 22 - 41 – 43, S: 24 – >=5%Conc<10%: Xi; R36; R43
35691-65-7 Methyldibromo glutaronitrile [MDBGN] R43 25 – 26 – 37 - 39 >=1%Conc<5%: Xi; R43 N - - - - - - - -
C; N
Xn; R22-48/22 R: 22 - 34 - 43 - 48/22 - Conc>=25%: Xn; R22; R48/22; R43
C; R34 50/53 >=10%Conc<25%: Xn; R48/22; R34; R43
R43 S: (1/2) - 22 - 26 - 36/37/39 - >=5%Conc<10%: Xi; R36/38; R43
35950-52-8 2-Bromo-1-(2-furyl)-2-nitroethylene N; R50-53 45 - 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 1; R45 T ; N ; R: 45 - 22 - 50/53,
Benzidine, salt of Benzidine acetate(Note: see also Xn; R22 S: 53 - 45 - 60 - 61; Conc>=25%: T; R45; R22
36341-27-2 CAS No 531-85-1, 531-86-2 & 21136-70-9) N; R50-53 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
Xn; R48/22 Xn ; N ; R: 38 - 41 - 48/22 -
Xi; R38 50/53, Conc>=20%: Xn; R48/22; R38; R41
R41 S: (2) - 26 - 36/37/39 - 60 - >=10%Conc<20%: Xn; R48/22; R41
36362-09-1 2-(Decylthio)ethylammonium chloride N; R50-53 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Conc>=25%: C; R34; R22; R43
Xn; R22 C >=10%Conc<25%: C; R34; R43
(S)-(-)-2-Acetoxypropionylchloride [(1S)-2-Chloro-1- C; R34 R: 22-34-43 >=5%Conc<10%: Xi; R36/38; R43
36394-75-9 methyl-2-oxoethyl acetate] R43 S: (1/2-)23-26-36/37/39-45 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
S-2-Isopropylthioethyl O,O-dimethyl T ; R: 24/25 , Conc>=25%: T; R24/25
36614-38-7 phosphorodithioate [Isothioate (ISO)] T; R24/25 S: (1/2) - 28 - 36/37 - 45 >=3%Conc<25%: Xn; R21/22 Eu - - - - - - - -

Calcium-P,P'-(1- R: 52/53
36669-85-9 hydroxyethylene)bis(hydrogenphosphonate)dihydrate R52-53 S: 61 Eu - - - - - - - -
Iprodione (ISO) [3-(3,5-Dichlorophenyl)-2,4-dioxo-N- Carc. Cat. 3; R40 Xn ; N ; R: 40 - 50/53
36734-19-7 isopropylimidazolidine-1-carboxamide] N; R50-53 S: (2)36/37 - 60 - 61 Conc>=1%: Xn; R40 Eu - - - - - - - -
F; R11
C; R34 F; C Conc>=25%: C;R34; R22
Xn; R22 R: 11-22-34-52/53 >=10%Conc<25%: C; R34
37143-54-7 1-Methoxy-2-propylamine R52-53 S: (1/2-)9-26-36/37/39-45-61 >=5%Conc<10% : Xi; R36/38 Eu - - - - - - - -
R31
C; R34 C ; N ; R: 31 - 34 - 50, Conc>=10%: C; R34; R31
37199-66-9 Potassium polysulphides N; R50 S: (1/2) - 26 - 45 - 61 >=5%Conc<10%: Xi; R36/38; R31 Eu - - - - - - - -

Perboric acid, sodium salt, tetrahydrate [Sodium Conc>=36%: T; R61; R62; R37; R41
peroxoborate hexahydrate](Note: containing < 0.1 % >=22%Conc<36%: T; R61; R62; R36/37
(w/w) of particles with an aerodynamic diameter of Repr. Cat. 2; R61 T >=20%Conc<22%: T; R61; R62; R37
below 50 micrometres. See also CAS No. 13517-20- Repr. Cat. 3; R62 R: 61-37-41-62 >=14%Conc<20%: T; R61; R62
37244-98-7 9 & 10486-00-7) Xi; R37-41 S: 53-45-47 >=10%Conc<14%: T; R61 Eu - - - - - - - -

Conc>=36%: T; R61; R62; R20; R37; R41

Perboric acid, sodium salt, tetrahydrate [Sodium >=25%Conc<36%: T; R61; R62; R20; R36/37
peroxoborate hexahydrate](Note: containing >= 0.1 % Repr. Cat. 2; R61 T >=22%Conc<25%: T; R61; R62; R36/37
(w/w) of particles with an aerodynamic diameter of Repr. Cat. 3; R62 R: 61-20-37-41-62 >=20%Conc<22%: T; R61; R62; R37
below 50 micrometres. See also CAS No. 13517-20- Xn; R20 S: 53-45-47 >=14%Conc<20%: T; R61; R62
37244-98-7 9 & 10486-00-7) Xi; R37-41 Note: E >=10%Conc<14%: T; R61 Eu - - - - - - - -
37288-11-2 Phytase [Phytate phosphatate] Xn; R22 Xn ; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Carc. Cat. 1; R45 Conc>=25%: T; R45; R23; R22; R48/20; R43

T; R23 >=10%Conc<25%: T; R45; R20; R48/20; R43
Xn; R22-48/20 >=3%Conc<10%: T; R45; R20; R43
C.I. Pigment Yellow 36 [Zinc yellow; Zinc chromate R43 T >=1%Conc<3%: T; R45; R43 Zinc chromate (as
37300-23-5 pigment] N; R50-53 R: 45-22-23-43-48/20-50-53 >=0.1%Conc<1%: T; R45 N/Eu; A Cr) - 0.01 - - 1 - -

Carc. Cat. 1; R45 Conc>=25%: T; R45; R23; R22; R48/20; R43

T; R23 >=10%Conc<25%: T; R45; R20; R48/20; R43
Xn; R22-48/20 >=3%Conc<10%: T; R45; R20; R43
C.I. Pigment Yellow 36 [Zinc yellow; Zinc chromate R43 T >=1%Conc<3%: T; R45; R43 Zinc chromate (as
37300-23-5 pigment] N; R50-53 R: 45-22-23-43-48/20-50-53 >=0.1%Conc<1%: T; R45 N/Eu; A Cr) - 0.01 - - 1 - -

Carc. Cat. 1; R45 Conc>=25%: T; R45; R23; R22; R48/20; R43

T; R23 >=10%Conc<25%: T; R45; R20; R48/20; R43
Xn; R22-48/20 >=3%Conc<10%: T; R45; R20; R43
C.I. Pigment Yellow 36 [Zinc yellow; Zinc chromate R43 T >=1%Conc<3%: T; R45; R43 Zinc chromate (as
37300-23-5 pigment] N; R50-53 R: 45-22-23-43-48/20-50-53 >=0.1%Conc<1%: T; R45 N/Eu; A Cr) - 0.01 - - 1 - -
Xn ; R42,
37329-65-0 Cellobiohydrolase, exo Xn; R42 S: (2) - 22 - 24 - 36/37 Conc>=1%: Xn; R42 Eu - - - - - - - -
5-Amino-2,4,6-triiodo-1,3- R43 Xi ; N ; R: 43 - 51/53
37441-29-5 benzenedicarbonyldichloride N; R51-53 S: (2)22 - 36/37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
37443-42-8 Methyl tetrahydro-2-furancarboxylate Xi; R41 S: (2-)26-39 >=5%Conc<10% : Xi; R36 Eu - - - - - - - -
R43 Xi ; R: 43 - 52/53
37866-45-8 2-(O-aminooxy)ethylamine dihydrochloride R52-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Flubenzimine [N-(3-Phenyl-4,5- Xi; R36 Xi ; N ; R: 36 - 50/53,

37893-02-0 bis[(trifluoromethyl)imino]thiazolidin-2-ylidene)aniline] N; R50-53 S: (2) - 26 - 60 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
T ; R: 61 - 22 - 48/22, Conc>=25%: T; R61; R22; R48/22
6-(2-Chloroethyl)-6-2-methoxyethoxy)-2,5,7,10- Repr. Cat. 2; R61 S: 53 - 45; >=10%Conc<25%: T; R61; R48/22
37894-46-5 tetraoxa-6-silaundecane [Etacelasil] Xn; R22-48/22 Note: E >=0.5%Conc<10%: T; R61 Eu - - - - - - - -
1,1,1-Trifluoro-N-(4-phenylsulphonyl-o- Xn; R22. Xn ; R: 22 - 36 , Conc>=25%: Xn; R22; R36
37924-13-3 tolyl)methanesulphonamide [Perfluidone] Xi; R36 S: (2) >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
Xn; N
Etrimfos [O-6-Ethoxy-2-ethylpyrimidin-4-yl O,O- Xn; R22 R: 22-50/53
38260-54-7 dimethylphosphorothioate] N; R50-53 S: (2-)60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
R: 52/53
38313-48-3 3'5'-Anhydro thymidine R52-53 S: 61 Eu - - - - - - - -

Conc>=25%: T; R23/25; R21; R36/37/38; R43

T; R23/25 >=20%Conc<25%: Xn; R20/22; R36/37/38;
Xn; R21 R43
Xi; R36/37/38 T >=3%Conc<20%: Xn; R20/22; R43
38337-95-0 Acetic acid, mercapto-, strontium salt R43 R: 21-23/25-36/37/38-43 >=1%Conc<3%: Xi; R43 N - - - - - - - -
F; R11 F ; C ; R: 11 - 34 - 52/53,
C; R34 S: (1/2) - 7 - 26 - 36/37/39 - Conc>=10%: C; R34
38411-13-1 Sodium 2-ethylhexanolate R52-53 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xi
Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
38585-74-9 5-Thiazolylmethanol R 52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Muta. Cat. 3; R68 T Conc>=25%: T; R68; R48/25; R22
Thioimidodicarbonic acid ((HO)C(O)NHC(S)(OH)), T; R48/25 R: 22-48/25-68 >=10%Conc<25%: T; R68; R48/25
39142-36-4 dibutyl ester Xn; R22 S: 26-37-45-57 >=1%Conc<10%: Xn; R68; R48/22 N - - - - - - - -
Xi
Fosetyl-aluminium (ISO) [Aluminium triethyl R: 41 Conc>=10%: Xi; R41 Aluminium, soluble
39148-24-8 triphosphonate] Xi; R41 S: (2-)26-39-46 >=5%Conc<10%: Xi; R36 Eu;A salts (as Al) - 2 - - - - -

Page 204
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc.Cat.2; R45
Muta.Cat.3; R68 T; N Conc>=25%: T; R45; R68; R22
2,4-Diaminoanisole sulphate (Note: see also CAS Xn; R22 R: 45-22-68-51/53 >=1%Conc<25%: T; R45; R68
39156-41-7 No. 615-05-4) N; R51-53 S: 53-45-61 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
T+ ; N ; R: 27/28 - 50/53 , Conc>=7%: T+; R27/28
3,3-Dimethyl-1-(methylthio)butanone-o-(N- T+; R27/28 S: (1/2) - 27 - 36/37 - 45 - >=1%Conc<7%: T; R24/25
39196-18-4 methylcarbamoyl)oxime [Thiofanox] N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -

Xi; R43
This substance has only been
assessed against the single
endpoint of skin sensitisation.
This substance has not been
subject to a complete assessment
Urea, N,N"-methylenebis[N'-[3-(hydroxymethyl)-2,5- for hazard classification in
dioxo-4-imidazolidinyl]- [Imidazolidinyl urea; Germall accordance with the approved
39236-46-9 115] criteria Xi; R:43 Conc>=1%:Xi; R43 N - - - - - - - -

Conc>=25%: T; R61; R20/22; R48/22; R38;

Repr. Cat. 2; R61 T; N R43
Dinocap (ISO) [(RS)-2,6-Dinitro-4-octylphenyl Xn; R20/22-48/22 R: 61-20/22-38-43-48/22- >=20%Conc<25%: T; R61; R48/22; R38; R43
crotonates and (RS)-2,4-dinitro-6-octylphenyl Xi; R38 50/53 >=10%Conc<20%: T; R61; R48/22; R43
crotonates in which "octyl" is a mixture of 1- R43 S: 53-45-60-61 >=1%Conc<10%: T; R61; R43
39300-45-3 methylheptyl, 1-ethylhexyl and 1-propylpentyl groups] N; R50-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -

Conc>=25%: T; R40; R23; R48/23; R36/37/38;

R42/43
>=20%Conc<25%: T; R40; R48/23; R20;
R36/37/38; R42/43
>=10%Conc<20%: T; R40; R48/23; R20;
Carc. Cat. 3; R40 R42/43
T; R23-R48/23 T >=3%Conc<10%: Xn; R40; R20; R48/20;
Benzene, 1,1'-methylenebis[isocyanato-, Xi; R36/37/38 R: 23-36/37/38-40-42/43- R42/43
39310-05-9 homopolymer R42/43 48/23 >=1%Conc<3%: Xn; R40; R48/20; R42/43 N - - - - - - - -
Conc>=25%: T+; R26; R25; R21
T+; R26 T+; N ; R: 21 - 25 - 26 - >=7%Conc<25%: T+; R26; R22
T; R25 50/53 >=3%Conc<7%: T; R23; R22
alpha-Cyano-3-phenoxybenzyl 2,2,3,3- Xn; R21 S: (1/2) - 28 - 36/37 - 38 - >=1%Conc<3%: T; R23
39515-41-8 tetramethylcyclopropanecarboxylate [Fenpropathrin] N; R50-53 45 - 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
Xi; R41 Conc>=10%: Xi; R41; R43
R43 Xi ; R: 41 - 43 - 52/53, >=5%Conc<10%: Xi; R36; R43
39562-16-8 Ethyl 2-(3-nitrobenzylidene)acetoacetate R52-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; R43 Xi ; N ; R: 43 - 50/53 ,
39562-17-9 Methyl 2-(3-nitrobenzylidene)acetoacetate N; R50-53 S: (2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; R43. Xi ; N ; R: 43 - 51/53 ,
39562-27-1 Methyl 2-(2-nitrobenzylidene)acetoacetate N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Oxadiargyl (ISO) [3-[2,4-Dichloro-5-(2-

propynyloxy)phenyl]-5-(1,1-dimethylethyl)-1,3,4- Repr. Cat. 3; R63 Xn; N
oxadiazol-2(3H)-one; 5-tert-Butyl-3-[2,4-dichloro-5- Xn; R48/22 R: 48/22-63-50/53 Conc>=10%: Xn; R63; R48/22
39807-15-3 (prop-2-ynyloxy)phenyl]-1,3,4-oxadiazol-2(3H)-one] N; R50-53 S: (2-)36/37-46-60-61 >=5%Conc<10%: Xn; R63 Eu - - - - - - - -
Xi; R38
R43 Xi ; N ; R: 38 - 43 - 51/53, Conc>=20%: Xi; R38; R43
40188-41-8 3,7-Dimethyloctanenitrile N; R51-53 S: (2) - 36/37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
N ; R: 51/53,
40278-59-9 2,2'-Spirobi(6-hydroxy-4,4,7-trimethylchromane) N; R51-53 S: 61 Eu - - - - - - - -
Conc>=25%: T+; R22; R26; R34
>=10%Conc<25%: T+; R26; R34
>=7%Conc<10%: T+; R26; R36/37/38
T+; R26 T+ ; R: 22 - 26 - 34 >=5%Conc<7%: T; R23; R36/37/38
Xn; R22 S: (1/2) - 26 - 28 - 36/37/39 - >=1%Conc<5%: T; R23
40292-82-8 Neodecanoyl chloride C; R34 45 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -

Xi; N
N-(1-Ethylpropyl)-2,6-dinitro-3,4-xylidine R43 R: 43 - 50/53
40487-42-1 [Pendimethalin (ISO)] N; R50-53 S: (2) - 24 - 29 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 205
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi; R38 Xi ; R: 38 - 52/53
40649-36-3 4-Propylcyclohexanone R52-53 S: (2)25 - 37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Carc. Cat. 2; R45
Muta. Cat. 2; R46 T
Xn; R48/22 R: 45-46-43-48/22-52/53 Conc>=10%: T; R45; R46; R48/22; R43
R43 S: 53-45-61 >=1%Conc<10%: T; R45; R46; R43
40722-80-3 (2-Chloroethyl)(3-hydroxypropyl)ammonium chloride R52-53 Note: E >=0.1%Conc<1%: T; R45; R46 Eu - - - - - - - -

Conc>=25% T+; R26; R25; R37/38; R41

>=20%Conc<25%: T+; R26; R22; R37/38; R41
>=10%Conc<20%: T+; R26; R22; R41
>=7%Conc<10%: T+; R26; R22; R36
T+; R26 T+ ; N ; R: 25 - 26 - 37/38 - >=5%Conc<7%: T; R23; R22; R36
T; R25 41 - 50/53, >=3%Conc<5%: T; R23; R22 Tin, organic
1-(Tricyclohexylstannyl)-1H-1,2,4-triazole Xi; R37/38-41 S: (1/2) - 26 - 28 - 36/37/39 - >=1%Conc<3%: T; R23 compounds (as
41083-11-8 [Azocyclotin] N; R50-53 38 - 45 - 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu Sn) - 0.1 - 0.2 - Sk -
5-(2,4-Dioxo-1,2,3,4-tetrahydropyrimidine)-3- fluoro-2- Xn ; R: 68
41107-56-6 hydroxymethyltetrahydrofuran Muta. Cat. 3; R68 S: (2)22 - 36/37 Conc>=1%: Xn; R68 Eu - - - - - - - -
Xn; N
Profenofos (ISO) [O-(4-Bromo-2-chlorophenyl) O- Xn; R20/21/22 R: 20/21/22-50/53
41198-08-7 ethyl S-propyl phosphorothioate] N; R50-53 S: (2-)36/37-60-61 Conc>=25%: Xn; R20/21/22 Eu - - - - - - - -
Xn; N
Xn; 22-48/22 R: 22-48/22-51/53 Conc>=25%: Xn; R22; R48/22
41340-36-7 2-(7-Ethyl-1H-indol-3-yl)ethanol N; R51-53 S: (2-)36/37/39-61 >=10%Conc<25%: Xn; 48/22 Eu - - - - - - - -
Xn; N
Metamitron [4-Amino-3-methyl-6-phenyl-1,2,4-triazin- Xn; R22 R: 22-50
41394-05-2 5-one] N; R50 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -
R43 Xi ; N ; R: 43 - 51/53
41481-66-7 2,2'-Diallyl-4,4'-sulfonyldiphenol N; R51-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
2-[[2-(Acetyloxy)-3-(1,1-dimethyl-ethyl)-5-
methylphenyl]methyl]-6-(1,1-dimethylethyl)-4- N ; R: 50/53
41620-33-1 methylphenol N; R50-53 S: 60 - 61 Eu - - - - - - - -
5-Methyl-1,2,4-triazolo(3,4-b)benzo-1,3-thiazole Xn ; R: 22 ,
41814-78-2 [Tricyclazole] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi; N
Xi; R38 R: 38-50/53
41870-52-4 1-(Chlorophenylmethyl)-2-methylbenzene N; R50-53 S: (2-)36/37-60-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xn; N
Xn; R22 R: 22-51/53
41959-35-7 1,2,3,4-Tetrahydro-6-nitro-quinoxaline N; R51-53 S: (2-)22-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi
Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
42031-28-7 trans-2-Isopropyl-5-carboxy-1,3-dioxane R52-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
R10 N ; R: 10 - 50/53,
42152-47-6 7-Methylocta-1,6-diene N; R50-53 S: (2) - 60 - 61 Eu - - - - - - - -
Conc>=25%: C; R34; R22; R43
Xn; R22 >=10%Conc<25%: C; R34; R43
C; R34 C ; R: 22 - 34 - 43 >=5%Conc<10%: Xi; R36/38; R43
42221-52-3 2,3,4,5-Tetrachlorobenzoylchloride R43 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
F; R11 F ; Xn ; N ; R: 11 - 22 -
Xn; R22 50/53 ,
42405-40-3 Bis(3,5-di-tert-butylsalicylato-01,02)zinc N; R50-53 S: (2) - 7 - 22 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
C; R34 C ; R: 34 - 43 - 52/53 Conc>=10%: C; R34; R43
R43 S: (1/2) - 23 - 26 - 36/37/39 - >=5%Conc<10%: Xi; R36/38; R43
42413-03-6 2-Chloro-p-toluenesulfochloride R52-53 45 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

2,3,5,6-Tetrahydro-2-methylphthalic anhydride(Note: Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

see also CAS No 1694-82-2; 3425-89-6; 5333-84-6; Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
42498-58-8 11070-44-3; 26590-20-5 & 34090-76-1) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R26; R24/25; R48/20; R43

>=10%Conc<25%: T+; R26; R21/22; R48/20;
T+; R26 R43
T; R24/25 T+; N ; R: 24/25 - 26 - 43 - >=7%Conc<10%: T+; R26; R21/22; R43
Xn; R48/20 48/20 - 50/53, >=3%Conc<7%: T; R23; R21/22; R43
Isazofos [O-(5-Chloro-1-isopropyl-1,2,4-triazon-3-yl) R43 S: (1/2) - 28 - 36/37 - 38 - >=1%Conc<3%: T; R23; R43
42509-80-8 O,O-diethyl phosphorothioate] N; R50-53 45 - 59 - 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
1,3-Benzenedicarboxamide, N1,N3-bis(2,2,6,6- Xn
tetramethyl-4-piperidinyl)- [N,N'-Bis(2,2,6,6- Xn; R22 R: 22-36 Conc>=25%: Xn; R22; R36
42774-15-2 tetramethyl-4-piperidyl)isophthalamide] Xi; R36 S: (2)-22-25-26 >=20%Conc<25%: Xi; R36 N/Eu - - - - - - - -
(1-Methyl-1,2-ethanediyl)bis[oxy(methyl-2,1- Xi; R36/37/38 Xi; N
ethanediyl)] diacrylate [TPGDA; Tripropylene glycol R43 R: 36/37/38-43-51/53 Conc>=10%: Xi; R36/37/38; R43
42978-66-5 diacrylate] N; R51-53 S: (2-)24-37-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
Xn
2-(Formylamino)-3-thiophenecarboxylic acid [2- Xn; R22 R: 22-43 Conc>=25%: Xn; R22; R43
43028-69-9 Formamido-3-thiophenecarboxylic acid] R43 S: (2-)22-24-37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xn; N
Xn; R22-48/22 R: 22-48/22-50/53 Conc>=25%: Xn; R22; R48/22
43057-68-7 2-Ethyl-2,3-dihydro-2-methyl-1H-perimidine N; R50-53 S: (2-)36/37-60-61 >=10%Conc<25%: Xn; R48/22 Eu - - - - - - - -
Xn; R22 Xn; N
Triadimefon (ISO) [1-(4-Chlorophenoxy)-3,3-dimethyl- R43 R: 22-43-51/53 Conc>=25%: Xn; R22; R43
43121-43-3 1-(1,2,4-triazol-1-yl)butanone] N; R51-53 S: (2-)24-37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
3,3'-Dioctadecyl-1,1'-methylenebis(4,1- R: 53
43136-14-7 phenylene)diurea R 53 S: 61 Eu - - - - - - - -
T; R25 T; N Conc>=25%: T; R25; R48/22; R43
Xn; R48/22 R: 25 - 43 - 48/22 - 50/53 >=10%Conc<25%: Xn; 48/22; R22; R43
R43 S:(1/2) - 22 - 28 - 36/37 - 45 - >=3%Conc<10%: Xn; R22; R43
43151-99-1 4,4'-Diamino-2-methylazobenzene N; R50-53 60 - 61 >=1%Conc<3%: Xn; R43 Eu - - - - - - - -
1,2-Dimethyl-3,5-diphenylpyrazolium methylsulphate Xn; R22 Xn ; N ; R: 22 - 50/53,
43222-48-6 [Difenzoquat methylsulphate] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
C Conc>=10%: C; R35
R: 35 >=5%Conc<10%: C; R34
46492-07-3 Disodium 9,10-anthracenedioxide C; R35 S: (1/2-)26-36/37/39-45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

Xn; R20/22-48/22 Xn ; N ; R: 20/22 - 41 - Conc>=25%: Xn; R20/22; R48/22; R41

Xi; R41 48/22 - 50/53 >=10%Conc<25%: Xn; R48/22; R41
47073-92-7 4,4'-Ethylidenediphenyl dicyanate N; R50-53 S: (2)26 - 36/37/39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

Hexahydro-1-methylphthalicanhydride(Note: see also Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
48122-14-1 CAS No 19438-60-9; 25550-51-0 & 57110-29-9) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Xn
Xn; R22 R: 22-43 Conc>=25%: Xn; R22; R43
49805-30-3 (R,S)-2-Azabicyclo[2.2.1]hept-5-en-3-one R43 S: (2-)22-24-37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 3; R40
Repr. Cat. 2; R60-61 T ; N ; R: 60 - 61 - 40 - 43 -
Vinclozolin (ISO) [N-3,5-Dichlorophenyl-5-methyl-5- R43 51/53 Conc>=1%: T; R60; R61; R40; R43
50471-44-8 vinyl-1,3-oxazolidine-2,4-dione] N; R51-53 S: 53 - 45 - 61 >=0.5%Conc<1%: T; R60; R61 Eu - - - - - - - -
Xn; R22
Dimethachlor [2-Chloro-N-(2,6-dimethylphenyl)-N-(2- R43 Xn ; N ; R: 22 - 43 - 50/53, Conc>=25%: Xn; R22; R43
50563-36-5 methoxyethyl)acetamide] N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
Xn; R22 Xn ; N ; R: 22 - 38 - 41 - >=20%Conc<25%: Xi; R38; R41
5-[2-Chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoic Xi; R38-41 50/53, >=10%Conc<20%: Xi; R41
50594-66-6 acid [Acifluorfen](Note: see also CAS No 62476-59-9) N; R50-53 S: (2) - 24 - 39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

R10 Conc>=25%: T; R23; R22; R48/22; R41; R43

T; R23 >=10%Conc<25%: Xn; R20; R48/22; R41; R43
Xn; R22-48/22 T ; R: 10 - 22 - 23 - 41 - 43 - >=5%Conc<10%: Xn; R20; R36; R43
Xi; R41 48/22 >=3%Conc<5%: Xn; R20; R43
50715-28-1 Cyclopentyl chloroformate R43 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
R31 Xi; N
Xi; R36/37/38 R: 31 - 36/37/38 - 50
50864-67-0 Barium polysulphides N; R50 S: (2) - 28 - 61 Conc>=20%: Xi; R36/37/38; R31 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
50905-10-7 (R,S)-2-Butyloctanedioic acid Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Conc>=25%: T; R45; R23; R22; R48/20; R43

Carc. Cat. 1; R45 >=10%Conc<25%: T; R45; R20; R48/20; R43
T; R23 >=3%Conc<10%: T; R45; R20; R43
Xn; R22-48/20 T >=1%Conc<3%: T; R45; R43
50922-29-7 Chromium zinc oxide R43 R: 45-22-23-43-48/20 >=0.1%Conc<1%: T; R45 N - - - - - - - -
Carc.Cat.3; R40 T Conc>=25%: T; R40; R23/24/25
5-Nitro-o-toluidine hydrochloride (Note: see also T; R23/24/25 R: 23/24/25-40-52/53 >=3%Conc<25%: Xn; R40; R20/21/22
51085-52-0 CAS No. 99-55-8) R52-53 S: (1/2-)36/37-45-61 >=1%Conc<3%: Xn; R40 Eu - - - - - - - -
Xi
1,6-Hexanediammonium, sodium 5-sulfato-1,3- R: 43
51178-75-7 benzenedicarboxylate R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
F; R11
cis-1-(3-Chloroallyl)-3,5,7-triaza-1-azoniaadamantane Repr. Cat. 3; R63
chloride [3,5,7-Triaza-1- Xn; R22 Conc>=25%: Xn; R63; R22; R38; R43
azoniatricyclo[3.3.1.13,7]decane, 1-(3-chloro-2- Xi; R38 F; Xn; N >=20%Conc<25%: Xn; R63; R38; R43
propenyl)-, chloride, (Z)-; 1-(3-Chloroallyl)-3,5,7-triaza- R43 R: 11-22-38-43-63-51/53 >=5%Conc<20%: Xn; R63; R43
51229-78-8 1-azoiaadamantane chloride, cis-; Dowicil 200] N; R51-53 S: (2-)7-22-33-36/37-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R22
3-Cyclohexyl-6-dimethylamino-1-methyl-1,2,3,4- Xi; R36 Xn ; N ; R: 22 - 36 - 50/53, Conc>=25%: Xn; R22; R36
51235-04-2 tetrahydro-1,3,5-triazine-2,4-dione [Hexazinone] N; R50-53 S: (2) - 60 - 61 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
N
R: 51/53
51285-81-5 Gadolinium(III)sulfite trihydrate N; R51-53 S: 61 Eu - - - - - - - -

Isobutyl 2-(4-(4-chlorophenoxy)phenoxy)propionate Xn ; R: 22 ,
51337-71-4 [Clofop isobutyl (ISO)] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -

Methyl 2-(4-(2,4-dichlorophenoxy)phenoxy)propionate
[Methyl (RS)-2-[4-(2,4- Xn; R22
dichlorophenoxy)phenoxy]propionate; Diclofop methyl R43 Xn ; N ; R: 22 - 43 - 50/53, Conc>=25%: Xn; R22; R43
51338-27-3 (ISO)] N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

C; N
C; R34 R: 34-51/53 Conc>=10%: C; R34
51390-14-8 2-(1-Methylpropyl)-4-tert-butylphenol N; R51-53 S: (1/2-)26-36/37/39-45-61 >=5%Conc<10%; Xi; R36/38 Eu - - - - - - - -
Conc>=10%: C; R34, R43
C; R34 C ; R: 34 - 43 , >=5%Conc<10%: Xi; R36/38; R43
51395-42-7 2-(Diphosphonomethyl) succinic acid R43 S: (1/2) - 26 - 36/37/39 - 45 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
51404-69-4 Acetic acid, lead salt, basic R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xn; R22.
R31. Xn ; N ; R: 22 - 31 - 36/37 -
Xi; R36/37 50/53, Conc>=25%: Xn; R22; R36/37; R31
51580-86-0 Sodium dichloroisocyanurate, dihydrate N; R50-53 S: (2) - 8 - 26 - 41 - 60 - 61 >=20%Conc<25%: Xi; R36/37; R31 Eu - - - - - - - -

Conc>=25%: T; R45; R23/24/25; R34; R43

>=10%Conc<25%: T; R45; R20/21/22; R34;
R43
R10 >=5%Conc<10%: T; R45; R20/21/22; R36/38;
Carc. Cat. 2; R45 R43
T; R23/24/25 T ; R: 45 - 10 - 23/24/25 - 34 >=3%Conc<5%: T; R45; R20/21/22; R43
C; R34 - 43 >=1%Conc<3%: T; R45; R43
51594-55-9 (R)-1-Chloro-2,3-epoxypropane R43 S: 53 - 45 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R48/22 Xn ; R: 48/22 - 53,
51601-57-1 4-(4-Tolyloxy)biphenyl R53 S: (2) - 22 - 36 - 61 Conc>=10%:Xn; R48/22 Eu - - - - - - - -
Mixture of nitric acid, mixture with sulphuric acid
containing ... % HNO3 and sulphuric acid, mixture
with nitric acid containing ... % HNO3 [Mixture of O ; C ; R: 8 - 35 ,
nitric acid, mixture with sulfuric acid containing ... % S: (1/2) - 23 - 26 - 30 - 36 - Conc>=10%: C; R35
HNO3 and sulfuric acid, mixture with nitric acid O; R8 45 ; >=5%Conc<10%: C; R34
51602-38-1 containing ... % HNO3] C; R35 Note: B >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

Conc>=25%: T; R45; R68; R23/24/25;

R48/23/24/25; R36/38; R43
>=20%Conc<25% : T; R45; R68;
R48/23/24/25; R20/21/22; R36/38; R43
>=10%Conc<20%: T; R45; R68; R48/23/24/25;
Carc. Cat. 2; R45 R20/21/22; R43
Muta. Cat. 3; R68 T; N >=3%Conc<10%: T; R45; R68; R20/21/22;
T; R23/24/25-48/23/24/25 R: 45-23/24/25-36/38-43- R48/20/21/22; R43
Xi; R36/38 48/23/24/25-68-50 >=1%Conc<3%: T; R45; R68; R48/20/21/22;
Phenylhydrazinium sulphate (2:1) (Note: see also R43 S: 53-45-61; R43
52033-74-6 CAS No. 100-63-0, 59-88-1 and 27140-08-5) N; R50 Note: E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Xn
Muta. Cat. 3; R68 R: 41-43-68 Conc>=10%: Xn; R68; R41; R43
Xi; R41 S: 26-36/37/39-42 >=5%Conc<10%: Xn; R68; R36; R43
52234-82-9 Trimethylopropane tri(3-aziridinylpropanoate) [TAZ] R43 Note: H >=1%Conc<5%: Xn; R68; R43 Eu - - - - - - - -
N ; R: 50/53
52301-18-5 Tris(isopropenyloxy)phenyl silane N; R50-53 S: 60 - 61 Eu - - - - - - - -

Cypermethrin cis/trans +/- 40/60 (RS)-alpha-cyano-3- Xn; R20/22 Xn; N

phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2- Xi; R37 R: 20/22-37-50/53 Conc>=25%: Xn; R20/22; R37
52315-07-8 dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate N; R50-53 S: (2-)24-36/37/39-60-61 >=20%Conc<25%: Xi; R37 Eu - - - - - - - -

Cypermethrin cis/trans +/- 80/20 (RS)-alpha-cyano-3- Xn; R22 Xn; N Conc>=25%: Xn; R22; R37/38; R43
phenoxybenzyl (1RS; 3RS; 1RS, 3SR)-3-(2,2- Xi; R37/38 R: 22-37/38-43-50/53 >=20%Conc<25%: Xi; R37/38; R43
52315-07-8 dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate R43 N; R50-53 S: (2-)36/37/39-60-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
zeta-Cypermethrin [Cypermethrin cis/trans +/- 50/50
(RS)-alpha-cyano-3-phenoxybenzyl (1RS; 3RS; 1RS,
3SR)-3-(2,2-dichlorovinyl)-2,2- Conc>=25%: T; R25
52315-07-8 dimethylcyclopropanecarboxylate] T; R25 T ; R: 25 >=3%Conc<25%: Xn; R22 V - - - - - - - -
Xi; R38 Xi ; R: 38 - 52/53,
52460-86-3 Ethyl-2-chloro-2,2-diphenylacetate R52-53 S: (2) - 37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
N-(5-(Bis(2-methoxyethyl)amino)-2-((2-cyano-4,6- R: 53
52583-35-4 dinitrophenyl)-azo)phenyl)acetamide R53 S: 22-61 Eu - - - - - - - -
m-Phenoxybenzyl 3-(2,2-dichlorovinyl)-2,2-
dimethylcyclopropanecarboxylate (40:60 cis:trans
isometric ratio) [Permethrin (40:60 cis:trans isometric Xn; R22 Xn ; R: 22 - 43 , Conc>=25%: Xn; R22; R43
52645-53-1 ratio)] R43 S: (2) >=1%Conc<25%: Xi; R43 V - - - - - - - -

Xn; R20/22 Xn; N

Permethrin (ISO) [m-Phenoxybenzyl 3-(2,2- R43 R: 20/22-43-50/53 Conc>=25%: Xn; R20/22; R43
52645-53-1 dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate] N; R50-53 S: (2-)13-24-36/37/39-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

Mixture of 7,9,9-trimethyl-3,14-dioxa-4,13-dioxo-5,12-
diazahexadecane-1,16-diyl-prop-2-enoate and 7,7,9- Xi; R36
trimethyl-3,14-dioxa-4,13-dioxo-5,12-diazahexadecan- R43 Xi ; N ; R: 36 - 43 - 51/53 Conc>=20%: Xi; R36; R43
52658-19-2 1,16-diylprop-2-enoate N; R51-53 S: (2)26 - 36/37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xi; N
1,4,7,10-Tetrakis(p-toluensulfonyl)-1,4,7,10- R43 R: 43-50/53
52667-88-6 tetraazacyclododecane N; R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: T; R40; R61; R62; R68; R48/22;
Muta. Cat. 3; R68 R33
Repr. Cat. 1; R61 >=5%Conc>=10%: T; R40; R61; R62; R68;
Repr. Cat. 3; R62 R33
Xn; R48/22 T >=1%Conc>=5%: T; R40; R61; R68; R33
52732-72-6 Sulfuric acid, lead salt, tetrabasic R33 R: 61-33-40-48/22-62-68 >=0.5%Conc>=1%: T; R61 N - - - - - - - -

Page 209
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R45; R68; R28; R23;

R48/23/25; R34
>=10%Conc<25%: T+; R45; R68; R28;
R48/23/25; R34; R20
Carc. Cat. 1; R45 >=7%Conc<10%: T+; R45; R68; R28; R20;
Muta. Cat. 3; R68 R48/20/22; R36/38
T+; R28 >=5%Conc<7%: T; R45; R68; R25; R20;
T; R23-48/23/25 T+ R48/20/22; R36/38
52740-16-6 Arsonic acid, calcium salt (1:1) C; R34 R: 23-28-34-45-48/23/25-68 >=3%Conc<5%: T; R45; R68; R25; R20; R48/2 N - - - - - - - -

Mixture of 1-(4-isopropylphenyl)-1-phenylethane and Xi; N

1-(3-isopropylphenyl)-1-phenylethane and 1-(2- Xi; R38 R: 38-50/53
52783-21-8 isopropylphenyl)-1-phenylethane N; R50-53 S: (2-)37-60-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xi; N
N-(1,3-Dimethylbutyl)-N'-(phenyl)-1,4- Xi; R36 R: 36-50/53
52870-46-9 benzoquinonediimine N; R50-53 S: (2-)26-60-61 Conc>=20%: Xi; R36 Eu - - - - - - - -
Xn; R22 Xn; N
R43 R: 22-43-51/53 Conc>=25%: Xn; R22; R43
52888-80-9 Prosulfocarb [S-Benzyl N,N-dipropylthiocarbamate] N; R51-53 S: (2-)24-37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
N
R: 50/53
52894-02-7 Bis(2-ethylhexyl)octylphosphonate N; R50-53 S: 60-61 Eu - - - - - - - -
T; N
Deltamethrin (ISO) [(S)-alpha-Cyano-3- R: 23/25-50/53
phenoxybenzyl (1R, 3R)-3-(2,2-dibromovinyl)-2,2- T; R23/25 S: (1/2-)24-28-36/37/39-38- Conc>=25%: T; R23/25
52918-63-5 dimethylcyclopropanecarboxylate] N; R50-53 45-60-61 >=3%Conc<25%: Xn; R20/22 Eu - - - - - - - -
N
Pyrimethanil (ISO) [N-(4,6-Dimethylpyrimidin-2- R: 51/53
53112-28-0 yl)aniline] N; R51-53 S: 61 Eu - - - - - - - -
Xi; R: 41, Conc>=10%: Xi; R41
53250-83-2 2-Chloro-4-(methylsulfonyl)benzoic acid Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
3,6-Dichloro-o-anisic acid, compound with 2-
aminoethanol (1:1)(Note: see also CAS No 1982-69-0 R: 52/53,
53404-28-7 & 25059-78-3) R52-53 S: 61 Eu - - - - - - - -
C; R34 C; N Conc>=25%: C; R34; R22 R43
Xn; R22 R: 22-34-43-51/53 >=10%Conc<25%: C; R34; R43 Tin, organic
R43 S: (1/2-)22-26-36/37/39-45- >=5%Conc<10%: Xi; R36/38; R43 compounds (as
53408-94-9 Tin(II) methanesulphonate N; R51-53 61 >=1%Conc<5%: Xi; R43 Eu;A Sn) - 0.1 - 0.2 - Sk -
Chlorodiphenyl (42% Chlorine) [PCBs (42% PCBs (42%
53469-21-9 Chlorine); PCB-1242] A Chlorine) - 1 - 2 2 Sk -

Conc>=25%: T; R45; R61; R62; R68; R23;

R48/20; R43; R33
Carc. Cat. 2; R45 >=10%Conc<25%: T; R45; R61; R62; R68;
Muta. Cat. 3; R68 R20; R48/20; R43; R33
Repr. Cat. 1; R61 >=5%Conc<10%: T; R45; R61; R62; R68; R20;
Repr. Cat. 3; R62 R43; R33
T; R23 >=3%Conc<5%: T; R45; R61; R68; R20; R43;
Xn; R48/20 T R33
R33 R: 45-61-23-33-43-48/20-62- >=1%Conc<3%: T; R45; R61; R68; R43; R33
53529-09-2 Chromium lead oxide sulfate R43 68 >=0 N - - - - - - - -
R: 52/53
53641-10-4 N,N'-(2-Chloro-1,4-phenylene)bis(3-oxobutaneamide) R52-53 S: 61 Eu - - - - - - - -
Xn ; R: 20
53863-99-3 Bis(1,1-dimethyl-2-propynyloxy)dimethylsilane Xn; R20 S: (2) Conc>=25%: Xn; R20 Eu - - - - - - - -
E; R2 Conc>=25%: Xn; R40; R21/22; R48/22;
Carc. Cat. 3; R40 R36/38; R43
Xn; R21/22-48/22 E; Xn; N >=20%Conc<25%: Xn; R40; R48/22; R36/38;
Xi; R36/38 R: 2-21/22-36/38-40-43- R43
Hydroxylamine 4-methylbenzenesulfonate(Note: see R43 48/22-50 >=10%Conc<20%: Xn; R40; R48/22; R43
53933-48-5 also CAS No. 10046-00-1, 20845-01-6 & 19098-16-9) N; R50 S: (2-)36/37-61 >=1%Conc<10%: Xn; R40; R43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn Conc>=25%; Xn; R22; R48/22; R36
Xn; R22-48/22 R:22 - 36 - 48/22 >=20%Conc<25%: Xn; R48/22; R36
54236-98-5 2,4-Diamino-5-methoxymethylpyrimidine Xi; R36 S: (2)22 - 26 - 36 >=10%Conc<20%: Xn; R48/22 Eu - - - - - - - -

Xn; R22 Xn ; N ; R: 22 - 41 - 50/53 , Conc>=25%: Xn; R22, R41

Xi; R41 S: (2) - 26 - 36/37/39 - 60 - >=10%Conc<25%: Xi; R41
54253-62-2 Copper (II) methanesulfonate N; R50-53 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
(1S,3S,5R,6R)-(4-Nitrophenylmethyl)-1-dioxo-6- Xn ; R: 42
54275-93-3 phenylacetamido-penam-3-carboxylate R42 S: (2)22 Conc>=1%: Xn; R42 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R36; R43
Xi; R36 Xn ; R: 22 - 36 - 43, >=20%Conc<25%: Xi; R36; R43
54322-20-2 Sodium 4-chloro-1-hydroxybutane-1-sulfonate R43 S: (2) - 22 - 26 - 36/37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn
(R)-1,2,3,4-Tetrahydro-6,7-dimethoxy-1- Xn; R22 R: 22-52/53
54417-53-7 veratrylisoquinoline hydrochloride R52-53 S: (2-)22-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
2-(n-Benzyl-N-methylamino)ethyl-3-amino-2- Xi; R43 Xi ; N ; R: 43 - 51/53
54527-73-0 butenoate N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
4-(N,N-Dibutylamino)-2-hydroxy-2- R: 52/53
54574-82-2 carboxybenzophenone R52-53 S: 61 Eu - - - - - - - -
2-Ethoxy-1-methylethyl acetate R10 R: 10-67
54839-24-6 [2PG1EEA](Note: see also CAS No. 1569-02-4) R67 S: (2-)24 Eu - - - - - - - -
N ; R: 50/53
54914-85-1 1,2-Bis(3-methylphenoxy)ethane N; R50-53 S: 60 - 61 Eu - - - - - - - -
Conc >=25%: T; R61, Xn; R22
54965-21-8 Albendazole Repr. Cat. 2; R61 T ; R: 61 - 22 >=0.5%Conc<25%: T; R61 V - - - - - - - -
Xn; R22
Xi; R38 Xn; N Conc>=25%: Xn; R22; R38; R43
R43 R: 22-38-43-51/53 >=20%Conc<25%: Xi; R38; R43
55066-49-4 3-Methyl-5-phenylpentan-1-al N; R51-53 S: (2-)36/37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T+; R26; R25; R43
T+; R26 T+; N >=7%Conc<25%: T+; R26; R22; R43
T; R25 R: 25-26-43-50/53 >=3%Conc<7%: T; R23; R22; R43
Carbosulfan (ISO) [2,3-Dihydro-2,2-dimethyl-7- R43 S: (1/2-)28-36/37-38-45-63- >=1%Conc<3%: T; R23; R43
55285-14-8 benzofuryl [(dibutylamino)thio]methylcarbamate] N; R50-53 60-61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -

Mixture of: 2-[N-(2-hydroxyethyl)stearamido]ethyl

stearate and sodium [bis[2-
(stearoyloxy)ethyl]amino]methylsulfonate and sodium
[bis(2-hydroxyethyl)amino]methylsulfonate and N,N- R: 52/53
55349-70-7 bis(2-hydroxyethyl)stearamide R52-53 S: 61 Eu - - - - - - - -

Conc>=25%: T; R23; R22; R37/38; R41; R43

>=20%Conc<25%: Xn; R20; R37/38; R41; R43
T; R23 >=10%Conc<20%: Xn; R20; R41; R43
Xn; R22 >=5%Conc<10%: Xn; R20; R36; R43
Carbamic acid, butyl-, 3-iodo-2-propynyl ester Xi; R37/38-41 T >=3%Conc<5%: Xn; R20; R43
55406-53-6 [Iodocarb] R43 R: 22-23-37/38-41-43 >=1%Conc<3%: Xi; R43 N - - - - - - - -
F ; C ; R: 14/15 - 17 - 35 , Conc>=10%: C; R35
F; R14/15-17 S: (1/2) - 6 - 16 - 30 - 36/39 - >=5%Conc<10%: C; R34
55426-95-4 Diethyl(ethyldimethylsilanolato)aluminium C; R35 43 - 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Xi; R38
Pyridate (ISO) [O-(6-Chloro-3-phenylpyridazin-4-yl) S- R43 Xi ; N ; R: 38 - 43 - 50/53 Conc>=20%: Xi; R38; R43
55512-33-9 octyl thiocarbonate] N; R50-53 S: (2)24 - 37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
1-(2-Deoxy-5-O-trityl-beta-D- R: 53
55612-11-8 threopentofuranosyl)thymine R53 S: 61 Eu - - - - - - - -
Repr. Cat. 2; R60 Conc >=25%: T; R60; R63; R20
Repr. Cat. 3; R63 >=5%Conc<25%: T; R60; R63
55720-26-8 Aminoethoxyvinylglycine Xn; R20 T ; R: 60 - 20 - 63 >=0.5%Conc<5%: T; R60 V - - - - - - - -

E; R2 E ; Xn ; R: 2 - 20/21/22 - 33 ,
Xn; R20/21/22 S: (2) - 35 ; Conc>=25%: Xn; R20/21/22; R33
55810-18-9 Tetranitronaphthalene R33 Note: C >=1%Conc<25%: Xn; R33 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
(n-Benzyl-N-ethyl)amino-3'-hydroxyacetophenone Xi; R41 Xi ; N ; R: 41 - 51/53 , Conc>=10%: Xi; R41
55845-90-4 hydrochloride N; R51-53 S: (2) - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one
[CAS No. 26172-55-4] and 2-methyl-2Hisothiazol-3- Conc>=25%: T; R23/24/25; R34; R43
one [CAS No. 2682-20-4] (3:1) [Mixture of: 5- T; R23/24/25 T; N >=3%Conc<25%: C; R34; R20/21/22; R43
chloro-2-methyl-4-isothiazolin-3-one [CAS No. 26172- C; R34 R: 23/24/25-34-43-50/53 >=0.6%Conc<3%: C; R34; R43
55-4] and 2-methyl-4-isothiazolin-3-one [CAS No. R43 S: (2-)26-28-36/37/39-45-60- >=0.06%Conc<0.6%: Xi;R36/38; R43
55965-84-9 2682-20-4] (3:1)] N; R50-53 61 >=0.0015%Conc<0.06%: Xi; R43 Eu - - - - - - - -
T+ ; N ; R: 28 - 48/25 - Conc>=10%: T+; R28; R48/25
T+; R28 50/53, >=7%Conc<10%: T+: R28; R48/22
3-(3-Biphenyl-4-yl-1,2,3,4-tetrahydro-1-naphthyl)-4- T; R48/25 S: (1/2) - 36/37 - 45 - 60 - >=1%Conc<7%: T; R25; R48/22
56073-07-5 hydroxycoumarin [Difenacoum] N; R50-53 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -
T+ ; N ; R: 27/28 - 48/24/25 - Conc>=10%: T+; R27/28; R48/24/25
T+; R27/28 50/53, >=7%Conc<10%: T+: R27/28; R48/21/22
4-Hydroxy-3-(3-(4'-bromo-4-biphenylyl)-1,2,3,4- T; R48/24/25 S: (1/2) - 36/37 - 45 - 60 - >=1%Conc<7%: T; R24/25; R48/21/22
56073-10-0 tetrahydro-1-naphthyl)coumarin [Brodifacoum] N; R50-53 61 >=0.1%Conc<1%: Xn; R21/22 Eu - - - - - - - -
4-Methyl-N,N-bis(2-(((4-
methylphenyl)sulfonyl)amino)ethyl)benzenesulfonami R: 53
56187-04-3 de R53 S: 61 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
56189-09-4 Lead, bis(octadecanoato)dioxodi- R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xi
R43 R: 43-52/53
56309-94-5 4-(1,4-Dioxa-spiro[4.5]dec-8-yl)-cyclohexanone R52-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
C; N
Xn; R21/22-48/22 R: 21/22-34-48/22-50/53 Conc>=25%: C; R34; R21/22-R48/22
C; R34 S: (1/2-)26-36/37/39-45-60- >=10%Conc<25%: C; R34; R48/22
56533-00-7 1,1,3,3-Tetrabutyl-1,3-ditinoxydicaprylate N; R50-53 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
56552-15-9 4,4'-(Oxy-(bismethylene))-bis-1,3-dioxolane Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Repr.Cat. 3; R63
Xn; R20/22 Xn; N Conc>=25%: Xn; R63; R20/22; R43
Bromoxynil heptanoate (ISO) [2,6- Dibromo-4- R43 R: 20/22-43-63-50/53 >=5%Conc<25%: Xn; R63; R43
56634-95-8 cyanophenyl heptanoate] N; R50-53 S: (2-)36/37-46-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
N
R: 51/53
56973-87-6 1-(3,3-Dimethylcyclohexyl)pent-4-en-1-one N; R51-53 S: 61 Eu - - - - - - - -
Xi; N
Tolclofos-methyl (ISO) [O-(2,6-Dichloro-p-tolyl)-O,O- R43 R: 43-50/53
57018-04-9 dimethyl thiophosphate] N; R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
R10 Xi ; R: 10 - 41, Conc>=10%: Xi; R41
57018-52-7 1-tert-Butoxypropan-2-ol Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Conc>=25%: T; R45; R68; R60; R23; R21/22;

R34
>=10%Conc<25%: T; R45; R68; R60; R20;
E; R2 R34
Carc. Cat. 2; R45 >=5%Conc<10%: T; R45; R68; R60; R20;
Muta. Cat. 3; R68 E; T R36/38
Repr. Cat. 2; R60 R: 45 - 60 - 2 - 21/22 - 23 - >=3%Conc<5%: T; R45; R68; R60; R20
T; R23 34 - 68 >=1%Conc<3%: T; R45; R68; R60
Xn; R21/22 S: 53 - 45 >=0.5%Conc<1%: T; R45; R60
57044-25-4 R-2,3-Epoxy-1-propanol C; R34 Note: E >=0.1%Conc<0.5%: T; R45 Eu - - - - - - - -

Xn ; R: 41 - 42/43, Conc>=10%: Xn; R42/43; R41

Hexahydro-3-methylphthalicanhydride(Note: see also Xi; R41 S: (2) - 22 - 24 - 26 - 37/39; >=5%Conc<10%: Xn; R42/43; R36
57110-29-9 CAS No 19438-60-9; 25550-51-0 & 48122-14-1) Xn; R42/43 Note: C >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
57142-78-6 Lead, [1,2-benzenedicarboxylato(2-)]oxodi- R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xi
Xi; R36 R: 36-43 Conc>=20%: Xi; R36; R43
57280-22-5 4,4-Dimethyl-3,5,8-trioxabicyclo[5.1.0]octane R43 S: (2-)26-36/37 >=1%Conc<20%: Xi; R36 Eu - - - - - - - -
Pyroquilon [1,2,5,6-Tetrahydropyrrolo[3,2,1-ij]quinolin- Xn; R22 Xn ; R: 22 - 52/53,
57369-32-1 4-one] R52-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi; N
2-Cyclopentene-1-acetic acid, 3-hydroxy-2-pentyl-, R43 R: 43-51/53
57374-49-9 methyl ester acetate N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Furalaxyl [Methyl N-(2,6-dimethylphenyl)-N-(2- Xn; R22 Xn ; R: 22 - 52/53,
57646-30-7 furylcarbonyl)-DL-alaninate] R52-53 S: (2) - 36/37/39 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn
Metalaxyl (ISO) [Methyl-N-(2,6-dimethylphenyl)-N- R43 R: 22-43-52/53 Conc>=25%: Xn; R22; R43
57837-19-1 (methoxyacetyl)-DL-alaninate] R52-53 S: (2-)13-24-37-46-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
T; R39/23 T; N
Acequinocyl (ISO) [3-Dodecyl-1,4-dioxo-1,4- Xi; R43 R: 39/23-43-50/53 Conc>=10%: T; R39/23; R43;
57960-19-7 dihydronaphthalen-2-yl acetate] N; R50-53 S: (2-)24-37-38-60-61 >=1%Conc<10%: Xn; R68/20; R43 Eu - - - - - - - -
Xn; R22
2-Cyano-N-[(ethylamino)carbonyl]-2- R43 Xn ; N ; R: 22 - 43 - 50/53, Conc>=25%: Xn; R22; R43
57966-95-7 (methoxyimino)acetamide [Cymoxanil] N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
57987-55-0 2,4-Diethyl-1,5-pentanediol Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; N
R43 R: 43-51/53
57999-49-2 2-(3-Bromophenoxy)tetrahydro-2H-pyran N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, 4-dodecyl-, compound with 2- Xn; R22 Xn >=10%Conc<20%: Xi; R41
58089-99-9 aminoethanol (1:1) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
58405-97-3 Octadecanoic acid, 12-hydroxy-, lead(2+) salt (2:1) R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

1- [2-(Allyloxy)ethyl-2-(2,4-dichlorophenyl)]-1H- Xn; R22 Xn; N

imidazolium hydrogen sulphate [Imazalil sulphate R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
58594-72-2 (ISO) powder](Note: see also CAS No. 83918-57-4) N; R50-53 S: (2-)24/25-37-46-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

Conc>=50%: C; R34; R22; R43

>=30%Conc<50%: Xn; R22; R38; R41; R43
1- [2-(Allyoxy)ethyl-2-(2,4-dichlorophenyl)]-1H- Xn; R22 >=25%Conc<30%: Xn; R22; R41; R43
imidazolium hydrogen sulphate [Imazalil sulphate C; R34 C; N >=15%Conc<25%: Xi; R41; R43
aqueous solution (ISO)](Note: see also CAS No R43 R: 22-34-43-50/53 >=5%Conc<15%: Xi; R36; R43
58594-72-2 83918-57-4) N; R50-53 S: (2-)26-36/37/39-45-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; R36
R43 Xi ; R: 36 - 43 - 52/53, Conc>=20%: Xi; R36; R43
58834-75-6 Vanadyl pyrophosphate R52-53 S: (2) - 24 - 26 - 37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Conc>=20%: Xi; R38; R41; R43
Xi; R38-41 Xi; N >=10%Conc<20%: Xi; R41; R43
Reaction mass of: dodecanoic acid (35-40%) and R43 R: 38-41-43-50/53 >=5%Conc<10%: Xi; R36; R43
58856-63-6 poly(1-7)lactate esters of dodecanoic acid (60-65%) N; R50-53 S: (2-)24-26-37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi
3,3'-Dicyclohexyl-1,1'-methylenebis(4,1- R: 43-53
58890-25-8 phenylene)diurea R43 R 53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

C; R34 C; N Conc>=10%: C; R34; R43

R43 R: 34-43-51/53 >=5%Conc<10%: Xi; R36/38; R43
59227-88-2 1-Octylazepin-2-one N; R51-53 S: (1/2-)26-36/37/39-45-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53
59320-13-7 2-[(4-Chloro-2-nitrophenyl)amino]ethanol N; R51-53 S: (2)22 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi ; R: 43 ,
59337-93-8 Methyl 3-sulphamoyl-2-thenoate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Methyl acetylene-
propadiene mixture
59355-75-8 Methyl acetylene propadiene mixture (MAPP) A (MAPP) 1000 1640 1250 2050 - - -
Xi; N
1-[3-[4-((heptadecafluorononyl)oxy)- Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
59493-72-0 benzamido]propyl]-N,N,N-trimethylammonium iodide N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Conc>=25%: T; R46; R23; R22; R48/22; R41;

R43
>=10%Conc<25%: T; R46; R20; R48/22; R41;
Muta. Cat. 2; R46 R43
T; R23 T ; R: 46 - 22 - 23 - 41 - 43 - >=5%Conc<10%: T; R46; R20; R36; R43
Xn; R22-48/22 48/22 >=3%Conc<5%: T; R46; R20; R43
1,3,5-Tris-[(2S and 2R)-2,3-epoxypropyl]-1,3,5- Xi; R41 S: 53 - 45; >=1%Conc<3%: T; R46; R43
59653-74-6 triazine-2,4,6-(1H,3H,5H)-trione R43 Note: E >=0.1%Conc<1%: T; R46 Eu - - - - - - - -
Conc >=25%: T; R23/25; R36
T; R23/25 >=20%Conc<25%: Xn; R20/22; R36
59669-26-0 Thiodicarb Xi; R36 T ; R: 23/25 - 36 >=3% Conc<20%: Xn; R20/22 V - - - - - - - -
Repr. Cat. 3; R62-63 Xn ; N ; R: 51/53 - 62 - 63 -
Fenarimol (ISO) [2,4'-Dichloro-alpha-(pyrimidin-5- R64 64 Conc>=5%: Xn; R62; R63; R64
60168-88-9 yl)benzhydryl alcohol] N; R51-53 S: (2)36/37 - 61 >=1%Conc<5%: Xn; R64 Eu - - - - - - - -
Azaconazole (ISO)
Xn
[1-{2-(2,4-Dichlorophenyl)-1,3-dioxolan-2-yl]methyl}- R: 22
60207-31-0 1H-1,2.4-triazole] Xn; R22 S: (2-)46 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn; N
Propiconazole [(+)-1-[2-(2,4-Dichlorophenyl)-4-propyl- R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
60207-90-1 1,3-dioxolan-2-ylmethyl]-1H-1,2,4-triazole] N; R50-53 S: (2-)36/37-46-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
L-Arginine, N2-(1-oxododecyl)-, ethyl ester, Xi; N Conc>=20%: Xi; R38; R41
hydrochloride (1:1) [Ethyl N2-dodecanoyl-L-argininate Xi; R38-41 R: 38-41-50 >=10%Conc<20%: Xi; R41
60372-77-2 hydrochloride] N; R50 S: (2)-26-39-61 >=5%Conc<10%: Xi; R36 N/Eu - - - - - - - -
N-Cyclohexyl-N-methoxy-2,5-dimethyl-3-furamide Carc. Cat. 3; R40 Xn ; N ; R: 40 - 50/53,
60568-05-0 [Furmecyclox] N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=1%: Xn; R40 Eu - - - - - - - -
Conc>=25%: T; R25; R48/25; R43
T; R25-48/25 T; N >=10%Conc<25%: T; R48/25; R22; R43
R43 R: 25-43-48/25-51/53 >=3%Conc<10%: Xn; R22; R48/22; R43
60658-04-0 Ethyl 2-(3-benzoylphenyl)propanoate N; R51-53 S: (1/2-)36/37-45-61 >=1%Conc<3%: Xn; R48/22; R43 Eu - - - - - - - -
Xn; R22
Xi; R38 Xn ; N ; R: 22 - 38 - 50/53 Conc>=25%: Xn; R22; R38
60811-21-4 4-Bromo-2-chlorofluorobenzene N; R50-53 S: (2)26 - 36/37 - 60 - 61 >=20%Conc<25%: Xi; R38 Eu - - - - - - - -
N ; R:51/53
61203-83-6 4-Pentylcyclohexanone N; R51-53 S: R61 Eu - - - - - - - -
Conc>=25%: C; R35; R22; R48/20/21/22;
C R42/43
Xn; R22-48/20/21/22 R: 22-35-42/43-48/20/21/22- >=10%Conc<25%: C; R35; R48/20/21/22;
C; R35 52/53 R42/43
R42/43 S: (1/2-)23-24-26-28- >=5%Conc<10%: C; R34; R42/43
61420-92-6 Hydroxydisulfito platinum(II) acid R52-53 36/37/39-45-61 >=1%Conc<5%: Xn; R36/38; R42/43 Eu - - - - - - - -
S-(1-Methyl-1-phenylethyl) piperidine-1-carbothioate
[1-Piperidinecarbothioic acid, S-(1-methyl-1- Xn; R22 Xn ; N ; R: 22 - 51/53
61432-55-1 phenylethyl) ester] N; R51 - 53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi
2,2'-Azobis[N-(2-hydroxyethyl)-2- R43 R: 43-52/53
61551-69-7 methylpropionamide] R52-53 S: (2-)12-15-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Repr.Cat.2; R61 T Conc>=10%: T; R61; R41
Xi; R41 R: 61-41-52/53 >=5%Conc<10%: T; R61; R36
61571-06-0 Tetrahydrothiopyran-3-carboxaldehyde R 52-53 S: 53-45-61 >=0.5%Conc<5%: T; R61 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi ; R: 36,
61597-96-4 2-Methylpropyl (R)-2-hydroxypropanoate Xi; R36 S: (2) - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -
N
R: 51/53
61718-80-7 5-Methoxy-4'-(trifluoromethyl)valerophenone N; R51-53 S: 61 Eu - - - - - - - -
Xn; R20 C; N Conc>=25%: C; R35; R20; R43
C; R35 R: 20-35-43-51/53 >=10%Conc<25%: C; R35; R43
R43 S: (1/2-)26-28-36/37/39-45- >=5%Conc<10%: C; R34; R43
61721-07-1 4-Fluoro-3-trifluoromethylphenol N; R51-53 61 >=1%Conc<5%: Xi; R36/38; R43 Eu - - - - - - - -
Hydrogenated
61788-32-7 Hydrogenated terphenyls A terphenyls 0.5 4.9 - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
61788-54-3 Fatty acids, tall oil, lead salts R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Creosote oil [Wash Oil](Note: A complex combination

of hydrocarbons obtained by the distillation of coal
tar. It consists primarily of aromatic hydrocarbons T
and may contain appreciable quantities of tar acids R: 45
and tar bases. It distills at the approximate range of S: 53-45
61789-28-4 200 °C to 325 °C (392 °F to 617 °F).) Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
61789-60-4 Pitch [Pitch] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
Xi
61790-50-9 Resin acids and rosin acids, potassium salts R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Xi
61790-51-0 Resin acids and rosin acids, sodium salts R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Conc>=25%: C; R35; R22; R43
Xn; R22 C >=10%Conc<25%: C; R35; R43
C; R35 R:22-35-43 >=5%Conc<10%: C; R34; R43
61807-67-8 (2-(Aminomethyl)phenyl)acetylchloride hydrochloride R43 S: (1/2-)26-36/37/39-45 >=1%Conc<5%: Xi; R36/38; R43 Eu - - - - - - - -
Conc>=25%: T; R25; R41; R43
T; R25 T; N >=10%Conc<25%: Xn; R22; R41; R43
Xi; R41 R: 25-41-43-50/53 >=5%Conc<10%: Xn; R22; R36; R43
R43 S: (1/2-)9-26-36/37/39-45-60- >=3%Conc<5%: Xn; R22; R43
61826-76-4 (S)-alpha-Hydroxy-3-phenoxy-benzeneacetonitrile N; R50-53 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -

Poly(oxy-1,2-ethanediyl), .alpha.-isodecyl-.omega.-
hydroxy- (Note: Polymeric substances may be placed
on the market with a range of molecular weights
which will affect the toxicological properties of the
substance. The classifications need not apply if it can
be shown that the substance placed on the market
does not meet the criteria for classification; note 2: Conc>=25%: Xn; R22; R38; R41
The classification for skin irritation need not apply if it >=20%Conc<25%: Xi; R38; R41
can be shown that there are less than four or more Xn; R22 Xn >=10%Conc<20%: Xi; R41
61827-42-7 than 21 ethoxylate units) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
61951-96-0 Neodecanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Xn ; R: 22 ,
62096-63-3 2-Amino-6-ethoxy-4-methylamino-1,3,5-triazine Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -

Page 215
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=10%: T; R48/25
62229-50-9 Bioclip (urogastrone - uro-EGF) T; R48/25 T; R: 48/25 >=1%Conc<10%: Xn; R48/22 V - - - - - - - -
Xn; R22
R43 Xn ; N ; R: 22 - 43 - 51/53 , Conc>=25%: Xn; R22; R43
62268-47-7 Bis(2-ethylhexyl)dithiodiacetate N; R51-53 S: (2) - 24/25 - 37 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xi
Xi; R38 R: 38-52/53
62406-73-9 8,8-Dimethyl-7-isopropyl-6,10-dioxaspiro[4.5]decane R52-53 S: (2-)24-37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
Sodium 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2- Xn; R22 Xn ; N ; R: 22 - 38 - 41 - >=20%Conc<25%: Xi; R38; R41
nitrobenzoate [Acifluorfen-sodium](Note: see also Xi; R38-41 50/53, >=10%Conc<20%: Xi; R41
62476-59-9 CAS No 50594-66-6) N; R50-53 S: (2) - 24 - 39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
R10 C ; R: 10 - 20/22 - 35 - 48/20 Conc>=25%: C; R35; R20/22; R48/20
Xn; R20/22-48/20 - 52/53, >=10%Conc<25%: C; R35; R48/20
C; R35 S: (1/2) - 26 - 28 - 36/37/39 - >=5%Conc<10%: C; R34
62478-82-4 N,N-Diethyl-N',N'-dimethylpropan-1,3-diyl-diamine R52-53 45 - 61 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Methyl (E)-3-
[(dimethoxyphosphinothioyl)oxy]methacrylate Xn; R22 Xn; N
[Methacrifos (ISO)](Note: see also CAS No 30864-28- R43 R: 22 - 43 - 50/53 Conc>=25%: Xn; R22; R43
62610-77-9 9) N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xi; R36 Xi ; R: 36 - 52/53 ,
62782-03-0 Bis(2,2,6,6-tetramethyl-4-piperidyl) succinate R52-53 S: (2) - 26 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
Xi; R36/38
Flumetralin [N-(2-Chloro-6-fluorobenzyl)-N-ethyl- R43 Xi ; N ; R: 36/38 - 43 - 50/53, Conc>=20%: Xi; R36/38; R43
62924-70-3 alpha,alpha,alpha-trifluoro-2,6-dinitro-p-toluidine] N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Zinc, bis[(2S)-2-(hydroxy-kappaO)propanato-kappaO]- Xn; R22 Xn Conc>=25%: Xn; R22; R36
63179-81-7 , (T-4)- Xi; R36 R: 22-36 >=20%Conc<25%: Xi; R36 N - - - - - - - -
Conc>=20%: Xi; R38; R41
2-Hydroxymethyl-9-methyl-6-(1-methylethyl)-1,4- Xi; R38-41 Xi ; R: 38 - 41 - 52/53, >=10%Conc<20%: Xi; R41
63187-91-7 dioxaspiro[4,5]decane R52-53 S: (2) - 26 - 37/39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R21/22 Conc>=25%: C; R34; R21/22
Quaternary ammonium compounds, benzyl-C8-18- C; R34 C ; N ; R: 21/22 - 34 - 50, >=10%Conc<25%: C; R34
63449-41-2 alkyldimethyl,chlorides N; R50 S: (2) - 36/37/39 - 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xi
2-(10-Oxo-10H-9-oxa-10-phosphaphenanthren-10- R43 R: 43-52/53
63562-33-4 ylmethyl)succinic acid R52-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
T; R25 Conc>=25%: T; R25; R48/22; R43
Xn; R48/22 T; N >=10%Conc<25%: Xn; R22; R48/22; R43
cis-1-(3-Chloropropyl)-2,6-dimethyl-piperidin R43 N; R: 25-43-48/22-51/53 >=3%Conc<10%: Xn; R22; R43
63645-17-0 hydrochloride R51-53 S: (1/2-)22-36/37-45-61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Chrysoidine-p-dodecylbenzenesulfonate Conc>=25%: Xn; R68; R22; R38; R41
[Dodecylbenzenesulfonic acid, compound with 4- Muta. Cat. 3; R68 Xn; N >=20%Conc<25%: Xn; R68; R38; R41
(phenylazo)benzene-1,3-diamine (1:1)](Note: see Xn; R22 R: 22-38-41-68-50/53 >=10%Conc<20%: Xn; R68; R41
also CAS No. 532-82-1, 75660-25-2, 79234-33-6, Xi; R38-41 S: (2-)23-26-36/37/39-46-60- >=5%Conc<10%: Xn; R68; R36
63681-54-9 83968-67-6 & 84196-22-5) N; R50-53 61 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -
R43 Xi ; N ; R: 43 - 51/53 ,
63740-41-0 6-(2,3-Dimethylmaleimido)hexyl methacrylate N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture of diastereoisomers of 1-(1-hydroxyethyl)-4-(1-Xi; R36/38 Xi ; N ; R: 36/38 - 51/53
63767-86-2 methylethyl)cyclohexane N; R51-53 S: (2)26 - 37 - 61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
Dinocton [Mixture of isomers of methyl 2-octyl-4,6- Xn; N
dinitrophenyl carbonate and methyl 4-octyl-2,6- Xn; R22 R: 22 - 50/53
63919-26-6 dinitrophenyl carbonate] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
N ; R:51/53,
63967-06-6 2,5-Bis(1,1-dimethylbutyl)hydroquinone N; R51-53 S: 61 Eu - - - - - - - -
R: 53
64026-19-3 N-Decyl-4-nitrobenzamide R53 S: 61 Eu - - - - - - - -
Xi
Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
64137-52-6 2-[3-(Methylamino)propyl]-1H-benzimidazole R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 216
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Alcohols, C13-15, ethoxylated (Note: Polymeric

substances may be placed on the market with a
range of molecular weights which will affect the
toxicological properties of the substance. The
classifications need not apply if it can be shown that
the substance placed on the market does not meet
the criteria for classification; note 2: The classification Conc>=25%: Xn; R22; R38; R41
for skin irritation need not apply if it can be shown >=20%Conc<25%: Xi; R38; R41
that there are less than four or more than 21 Xn; R22 Xn >=10%Conc<20%: Xi; R41
64425-86-1 ethoxylate units) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
E; R2 E; Xn
(Z)-2-Methoxymino-2-[2-(tritylamino)thiazol-4-yl]acetic Carc. Cat. 3; R40 R: 2-40-52/53
64485-90-1 acid R52-53 S: (2-)23-25-35-36/37-61 Conc>=1%: Xn; R40 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
64504-12-7 Isooctanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
64700-56-7 Triclopyr Xn; R22 Xn ; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -

Naphtha (petroleum), heavy straight-run [Low boiling

point naphtha](Note: A complex combination of
hydrocarbons produced by distillation of crude oil. It
consists of hydrocarbons having carbon numbers T
predominantly in the range of C6 through C12 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately 65 °C to 230 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-41-9 (149 °F to 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), full-range straight-run [Low

boiling point naphtha](Note: A complex combination
of hydrocarbons produced by distillation of crude oil.
It consists of hydrocarbons having carbon numbers T
predominantly in the range of C4 through C11 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately -20 °C to 220 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-42-0 (-4 °F to 428 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
64741-45-3 Residues (petroleum), atm. tower [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Naphtha (petroleum), light straight-run [Low boiling

point naphtha](Note: A complex combination of
hydrocarbons produced by distillation of crude oil. It
consists predominantly of aliphatic hydrocarbons T
having carbon numbers predominantly in the range of Carc. Cat. 2; R45 R: 45-46-65
C4 through C10 and boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-46-4 approximately -20 °C to 180 °C (-4 °F to 356 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Natural gas condensates (petroleum) [Low boiling

point naphtha — unspecified](Note: A complex
combination of hydrocarbons separated as a liquid
from natural gas in a surface separator by retrograde
condensation. It consists mainly of hydrocarbons T
having carbon numbers predominantly in the range of Carc. Cat. 2; R45 R: 45-46-65
C2 to C20. It is a liquid at atmospheric temperature Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-47-5 and pressure.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 217
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Natural gas (petroleum), raw liq. mix [Low boiling

point naphtha — unspecified](Note: A complex
combination of hydrocarbons separated as a liquid
from natural gas in a gas recycling plant by
processes such as refrigeration or absorption. It T
consists mainly of saturated aliphatic hydrocarbons Carc. Cat. 2; R45 R: 45-46-65
having carbon numbers in the range of C2 through Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-48-6 C8.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Distillates, petroleum, light paraffinic [Unrefined or

mildly refined baseoil (A complex combination of
hydrocarbons produced by vacuum distillation of the Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
residuum from atmospheric distillation of crude oil. It Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
consists of hydrocarbons having carbon numbers Xn; R20 T >=5%Conc<20%: T; R45; R63
64741-50-0 predominantly in the range of C15 thro] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
Distillates, petroleum, heavy paraffinic [Unrefined or Xn; R20 T >=5%Conc<20%: T; R45; R63
64741-51-1 mildly refined baseoil] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
Distillates, petroleum, light naphthenic [Unrefined or Xn; R20 T >=5%Conc<20%: T; R45; R63
64741-52-2 mildly refined baseoil] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
Distillates, petroleum, heavy naphthenic [Unrefined or Xn; R20 T >=5%Conc<20%: T; R45; R63
64741-53-3 mildly refined baseoil] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -

Naphtha (petroleum), heavy catalytic cracked [Low

boiling point cat-cracked naphtha](Note: A complex
combination of hydrocarbons produced by a
distillation of products from a catalytic cracking
process. It consists of hydrocarbons having carbon
numbers predominantly in the range of C6 through T
C12 and boiling in the range of approximately 65 °C Carc. Cat. 2; R45 R: 45-46-65
to 230 °C (148 °F to 446 °F). It contains a relatively Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-54-4 large proportion of unsaturated hydrocarbons.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light catalytic cracked [Low

boiling point cat-cracked naphtha](Note: A complex
combination of hydrocarbons produced by the
distillation of products from a catalytic cracking
process. It consists of hydrocarbons having carbon
numbers predominantly in the range of C4 through T
C11 and boiling in the range of approximately -20 °C Carc. Cat. 2; R45 R: 45-46-65
to 190 °C (-4 °F to 374 °F). It contains a relatively Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-55-5 large proportion of unsaturated hydrocarbons.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
64741-57-7 Gas oils (petroleum), heavy vacuum [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), light catalytic cracked S: 53 - 45 ;
64741-59-9 [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), intermediate catalytic cracked S: 53 - 45 ;
64741-60-2 [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), heavy catalytic cracked S: 53 - 45 ;
64741-61-3 [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 218
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 45 ,
Clarified oils (petroleum), catalytic cracked [Heavy S: 53 - 45 ;
64741-62-4 fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Naphtha (petroleum), light catalytic reformed [Low

boiling point cat-reformed naphtha](Note: A complex
combination of hydrocarbons produced from the
distillation of products from a catalytic reforming
process. It consists of hydrocarbons having carbon
numbers predominantly in the range of C5 through
C11 and boiling in the range of approximately 35 °C
to 190 °C (95 °F to 374 °F). It contains a relatively T
large proportion of aromatic and branched chain Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons. This stream may contain 10 vol. % or Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-63-5 more benzene.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), full-range alkylate [Low boiling

point modified naphtha](Note: A complex combination
of hydrocarbons produced by distillation of the
reaction products of isobutane with monoolefinic
hydrocarbons usually ranging in carbon numbers
from C3 through C5. It consists of predominantly
branched chain saturated hydrocarbons having T
carbon numbers predominantly in the range of C7 Carc. Cat. 2; R45 R: 45-46-65
through C12 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-64-6 90 °C to 220 °C (194 °F to 428 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), heavy alkylate [Low boiling

point modified naphtha](Note: A complex combination
of hydrocarbons produced by distillation of the
reaction products of isobutane with monoolefinic
hydrocarbons usually ranging in carbon numbers
from C3 to C5. It consists of predominantly branched
chain saturated hydrocarbons having carbon T
numbers predominantly in the range of C9 through Carc. Cat. 2; R45 R: 45-46-65
C12 and boiling in the range of approximately 150 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-65-7 to 220 °C (302 °F to 428 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light alkylate [Low boiling point

modified naphtha](Note: A complex combination of
hydrocarbons produced by distillation of the reaction
products of isobutane with monoolefinic
hydrocarbons usually ranging in carbon numbers
from C3 through C5. It consists of predominantly
branched chain saturated hydrocarbons having T
carbon numbers predominantly in the range of C7 Carc. Cat. 2; R45 R: 45-46-65
through C10 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-66-8 90 °C to 160 °C (194 °F to 320 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), catalytic reformer fractionator S: 53 - 45 ;
64741-67-9 [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Naphtha (petroleum), heavy catalytic reformed [Low

boiling point cat-reformed naphtha](Note: A complex
combination of hydrocarbons produced from the
distillation of products from a catalytic reforming
process. It consists of predominantly aromatic
hydrocarbons having carbon numbers predominantly T
in the range of C7 through C12 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 90 °C to 230 °C (194 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-68-0 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), light hydrocracked [Low boiling

naphtha — unspecified](Note: A complex
combination of hydrocarbons from distillation of the
products from a hydrocracking process. It consists
predominantly of saturated hydrocarbons having T
carbon numbers predominantly in the range of C4 Carc. Cat. 2; R45 R: 45-46-65
through C10, and boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-69-1 approximately -20 °C to 180 °C (-4 °F to 356 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), isomerization [Low boiling point

modified naphtha](Note: A complex combination of
hydrocarbons obtained from catalytic isomerization of
straight chain paraffinic C4 through C6 hydrocarbons. T
It consists predominantly of saturated hydrocarbons Carc. Cat. 2; R45 R: 45-46-65
such as isobutane, isopentane, 2,2-dimethylbutane, 2- Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-70-4 methylpentane, and 3-methylpentane.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Xn ; R: 65 ,
Distillates (petroleum), alkylate [Kerosine - S: (2) - 23 - 24 - 62 ;
64741-73-7 unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

Naphtha (petroleum), light thermal cracked [Low

boiling point thermally cracked naphtha](Note: A
complex combination of hydrocarbons from
distillation of products from a thermal cracking
process. It consists predominantly of unsaturated
hydrocarbons having carbon numbers predominantly T
in the range of C4 through C8 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately -10 °C to 130 °C (14 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-74-8 266 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
64741-75-9 Residues (petroleum), hydrocracked [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Distillates (petroleum), heavy hydrocracked [Baseoil T ; R: 45 ,
64741-76-0 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 40 ,
Distillates (petroleum), light hydrocracked [Cracked S: (2) - 36/37 ;
64741-77-1 gasoil] Carc. Cat. 3; R40 Note: H Conc>=1%: Xn; R40 Eu - - - - - - - -

Naphtha (petroleum), heavy hydrocracked [Low

boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons from
distillation of the products from a hydrocracking
process. It consists predominantly of saturated
hydrocarbons having carbon numbers predominantly T
in the range of C6 through C12, and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 65 °C to 230 °C (148 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-78-2 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), thermal cracked [Heavy fuel S: 53 - 45 ;
64741-80-6 oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), heavy thermal cracked [Heavy S: 53 - 45 ;
64741-81-7 fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), light thermal cracked S: 53 - 45 ;
64741-82-8 [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 220
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), heavy thermal cracked [Low

boiling point thermally cracked naphtha](Note: A
complex combination of hydrocarbons from
distillation of the products from a thermal cracking
process. It consists predominantly of unsaturated
hydrocarbons having carbon numbers predominantly T
in the range of C6 through C12 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 65 °C to 220 °C (148 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-83-9 428 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), solvent-refined light [Low

boiling point modified naphtha](Note: A complex
combination of hydrocarbons obtained as the
raffinate from a solvent extraction process. It consists
predominantly of aliphatic hydrocarbons having T
carbon numbers predominantly in the range of C5 Carc. Cat. 2; R45 R: 45-46-65
through C11 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-84-0 35 °C to 190 °C (95 °F to 374 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), sweetened middle [Gasoil S: 53 - 45 ;
64741-86-2 unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -

Naphtha (petroleum), sweetened [Low boiling point

naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained by subjecting
a petroleum naphtha to a sweetening process to
convert mercaptans or to remove acidic impurities. It
consists of hydrocarbons having carbon numbers T
predominantly in the range of C4 through C12 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately -10 °C to 230 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-87-3 (14 °F to 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent refined heavy S: 53 - 45 ;
64741-88-4 paraffinic [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent refined light paraffinic S: 53 - 45 ;
64741-89-5 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Gas oils (petroleum), solvent refined [Gasoil S: 53 - 45 ;
64741-90-8 unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent refined middle [Gasoil S: 53 - 45 ;
64741-91-9 unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -

Naphtha (petroleum), solvent-refined heavy [Low

boiling point modified naphtha](Note: A complex
combination of hydrocarbons obtained as the
raffinate from a solvent extraction process. It consists
predominantly of aliphatic hydrocarbons having T
carbon numbers predominantly in the range of C7 Carc. Cat. 2; R45 R: 45-46-65
through C12 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64741-92-0 90 °C to 230 °C (194 °F to 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residual oils (petroleum), solvent deasphalted S: 53 - 45 ;
64741-95-3 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent refined heavy S: 53 - 45 ;
64741-96-4 naphthenic [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent refined light S: 53 - 45 ;
64741-97-5 naphthenic Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 221
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn ; R: 65 ,
Extracts (petroleum), heavy naphtha solvent S: (2) - 23 - 24 - 62 ;
64741-98-6 [Kerosine unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T ; R: 45 ,
Residual oils (petroleum), solvent refined [Baseoil S: 53 - 45 ;
64742-01-4 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

T
Extracts (petroleum), light naphthenic distillate R: 45
64742-03-6 solvent Carc. Cat. 2; R45 S: 53-45; Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T
Extracts (petroleum), heavy paraffinic distillate R: 45
64742-04-7 solvent Carc. Cat. 2; R45 S: 53-45 Conc>=0.1%: T; R45 Eu - - - - - - - -

T
R: 45
64742-05-8 Extracts (petroleum), light paraffinic distillate solvent Carc. Cat. 2; R45 S: 53-45; Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Extracts (petroleum), heavy naphtha solvent, clay T

treated R: 45
64742-11-6 [Low boiling point naptha unspecified] Carc. Cat. 2; R45 S: 53-45; Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Gas oils (petroleum), acid treated [Gasoil S: 53 - 45 ;
64742-12-7 unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), acid treated middle [Gasoil S: 53 - 45 ;
64742-13-8 unspecified] Carc. Cat. 2; R45 Note: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), acid treated light [Gasoil S: 53 - 45 ;
64742-14-9 unspecified] Carc. Cat. 2; R45 Note: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -

Naphtha (petroleum), acid-treated [Low boiling point

naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained as a raffinate
from a sulfuric acid treating process. It consists of
hydrocarbons having carbon numbers predominantly T
in the range of C7 through C12 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 90 °C to 230 °C (194 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-15-0 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
Distillates, petroleum, acid treated heavy naphthenic Xn; R20 T >=5%Conc<20%: T; R45; R63
64742-18-3 [Unrefined or mildly refined baseoil] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
Distillates, petroleum, acid treated light naphthenic Xn; R20 T >=5%Conc<20%: T; R45; R63
64742-19-4 [Unrefined or mildly refined baseoil] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
Distillates, petroleum, acid treated heavy paraffinic Xn; R20 T >=5%Conc<20%: T; R45; R63
64742-20-7 [Unrefined or mildly refined baseoil] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
Distillates, petroleum, acid treated light paraffinic Xn; R20 T >=5%Conc<20%: T; R45; R63
64742-21-8 [Unrefined or mildly refined baseoil] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -

Naphtha (petroleum), chemically neutralized heavy

[Low boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons produced by a
treating process to remove acidic materials. It
consists of hydrocarbons having carbon numbers T
predominantly in the range of C6 through C12 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately 65 °C to 230 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-22-9 (149 °F to 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 222
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), chemically neutralized light

[Low boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons produced by a
treating process to remove acidic materials. It
consists of hydrocarbons having carbon numbers T
predominantly in the range of C4 through C11 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately -20 °C to 190 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-23-0 (-4 °F to 374 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), chemically neutralized heavy S: 53 - 45 ; .
64742-27-4 paraffinic [Unrefined or mildly refined baseoil] Carc. Cat. 1; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), chemically neutralized light S: 53 - 45 ;
64742-28-5 paraffinic [Unrefined or mildly refined baseoil] Carc. Cat. 1 R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
Distillates, petroleum, chemically neutralized light Xn; R20 T >=5%Conc<20%: T; R45; R63
64742-28-5 paraffinic [Unrefined or mildly refined baseoil] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
T ; R: 45 ,
Gas oils (petroleum), chemically neutralized [Gasoil S: 53 - 45 ;
64742-29-6 unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), chemically neutralized middle S: 53 - 45 ;
64742-30-9 [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Distillates (petroleum), chemically neutralized light S: (2) - 23 - 24 - 62 ;
64742-31-0 [Kerosine unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
Distillates, petroleum, chemically neutralized heavy Xn; R20 T >=5%Conc<20%: T; R45; R63
64742-34-3 naphthenic [Unrefined or mildly refined baseoil] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Carc. Cat. 1; R45 Conc>=25%: T; R45; R63; R20; R38
Repr. Cat. 3; R63 >=20%Conc<25%: T; R45; R63; R38
Distillates, petroleum, chemically neutralized light Xn; R20 T >=5%Conc<20%: T; R45; R63
64742-35-4 naphthenic [Unrefined or mildly refined baseoil] Xi; R38 R: 45-20-38-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), clay treated paraffinic [Baseoil S: 53 - 45 ;
64742-36-5 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), clay treated light paraffinic S: 53 - 45 ;
64742-37-6 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), clay treated middle [Gasoil S: 53 - 45 ;
64742-38-7 unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residual oils (petroleum), clay treated [Baseoil S: 53 - 45 ;
64742-41-2 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), clay treated heavy naphthenic S: 53 - 45 ;
64742-44-5 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), clay treated light naphthenic S: 53 - 45 ;
64742-45-6 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrotreated middle [Gasoil S: 53 - 45 ;
64742-46-7 unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Distillates (petroleum), hydrotreated light [Kerosine S: (2) - 23 - 24 - 62 ;
64742-47-8 unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), hydrotreated heavy [Low boiling

point hydrogen treated naphtha](Note: A complex
combination of hydrocarbons obtained by treating a
petroleum fraction with hydrogen in the presence of a
catalyst. It consists of hydrocarbons having carbon T
numbers predominantly in the range of C6 through Carc. Cat. 2; R45 R: 45-46-65
C13 and boiling in the range of approximately 65 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-48-9 to 230 °C (149 °F to 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), hydrotreated light [Low boiling

point hydrogen treated naphtha](Note: A complex
combination of hydrocarbons obtained by treating a
petroleum fraction with hydrogen in the presence of a
catalyst. It consists of hydrocarbons having carbon T
numbers predominantly in the range of C4 through Carc. Cat. 2; R45 R: 45-46-65
C11 and boiling in the range of approximately minus Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-49-0 20 °C to 190 °C (-4 °F to 374 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrotreated heavy S: 53 - 45 ;
64742-52-5 naphthenic [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrotreated light naphthenic S: 53 - 45 ;
64742-53-6 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrotreated heavy paraffinic S: 53 - 45 ;
64742-54-7 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrotreated light paraffinic S: 53 - 45 ;
64742-55-8 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent dewaxed light S: 53 - 45 ;
64742-56-9 paraffinic [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residual oils (petroleum), hydrotreated [Baseoil S: 53 - 45 ;
64742-57-0 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Gas oils (petroleum), hydrotreated vacuum [Heavy S: 53 - 45 ;
64742-59-2 fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
64742-61-6 Slack wax (petroleum) [Slack wax] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residual oils (petroleum), solvent dewaxed [Baseoil S: 53 - 45 ;
64742-62-7 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent dewaxed heavy S: 53 - 45 ;
64742-63-8 naphthenic [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent dewaxed light S: 53 - 45 ;
64742-64-9 naphthenic [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent dewaxed heavy S: 53 - 45 ;
64742-65-0 paraffinic [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Naphtha (petroleum), catalytic dewaxed [Low boiling

point naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained from the
catalytic dewaxing of a petroleum fraction. It consists
predominantly of hydrocarbons having carbon T
numbers predominantly in the range of C5 through Carc. Cat. 2; R45 R: 45-46-65
C12 and boiling in the range of approximately 35 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-66-1 to 230 °C (95 °F to 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 224
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 45 ,
S: 53 - 45 ;
64742-67-2 Foots oil (petroleum) [Foots oil] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Naphthenic oils (petroleum), catalytic dewaxed heavy S: 53 - 45 ;
64742-68-3 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Naphthenic oils (petroleum), catalytic dewaxed light S: 53 - 45 ;
64742-69-4 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Paraffin oils (petroleum), catalytic dewaxed heavy S: 53 - 45 ;
64742-70-7 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Paraffin oils (petroleum), catalytic dewaxed light S: 53 - 45 ;
64742-71-8 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Naphtha (petroleum), hydrodesulfurized light [Low

boiling point hydrogen treated naphtha](Note: A
complex combination of hydrocarbons obtained from
a catalytic hydrodesulfurization process. It consists of
hydrocarbons having carbon numbers predominantly T
in the range of C4 through C11 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately -20 °C to 190 °C (-4 °F to 374 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-73-0 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Naphthenic oils (petroleum), complex dewaxed heavy S: 53 - 45 ;
64742-75-2 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Naphthenic oils (petroleum), complex dewaxed light S: 53 - 45 ;
64742-76-3 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), hydrodesulfurized atmospheric S: 53 - 45 ;
64742-78-5 tower [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Gas oils (petroleum), hydrodesulfurized [Gasoil S: 53 - 45 ;
64742-79-6 unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrodesulfurized middle S: 53 - 45 ;
64742-80-9 [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Kerosine (petroleum), hydrodesulfurized [Kerosine S: (2) - 23 - 24 - 62 ;
64742-81-0 unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

Naphtha (petroleum), hydrodesulfurized heavy [Low

boiling point hydrogen treated naphtha](Note: A
complex combination of hydrocarbons obtained from
a catalytic hydrodesulfurization process. It consists of
hydrocarbons having carbon numbers predominantly T
in the range of C7 through C12 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 90 °C to 230 °C (194 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-82-1 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light steam-cracked [Low

boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons obtained by
the distillation of the products from a steam cracking
process. It consists predominantly of unsaturated
hydrocarbons having carbon numbers predominantly
in the range of C4 through C11 and boiling in the T
range of approximately minus 20 °C to 190 °C (-4 °F Carc. Cat. 2; R45 R: 45-46-65
to 374 °F).This stream is likely to contain 10 vol. % or Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-83-2 more benzene.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 225
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 45 ,
Gas oils (petroleum), hydrodesulfurized heavy S: 53 - 45 ;
64742-86-5 vacuum [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Solvent naphtha (petroleum), medium aliph. [Straight S: (2) - 23 - 24 - 62 ;
64742-88-7 run kerosene] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

Solvent naphtha (petroleum), light aliph. [Low boiling

point naphtha](Note: A complex combination of
hydrocarbons obtained from the distillation of crude
oil or natural gasoline. It consists predominantly of
saturated hydrocarbons having carbon numbers T
predominantly in the range of C5 through C10 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately 35 °C to 160 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-89-8 (95 °F to 320 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
64742-90-1 Residues (petroleum), steam cracked [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Distillates (petroleum), steam cracked [Cracked S: (2) - 23 - 24 - 62 ;
64742-91-2 kerosine] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
Xn ; R: 65 ,
Solvent naphtha (petroleum), heavy arom. [Kerosene S: (2) - 23 - 24 - 62 ;
64742-94-5 unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

Solvent naphtha (petroleum), light arom. [Low boiling

point naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained from
distillation of aromatic streams. It consists
predominantly of aromatic hydrocarbons having T
carbon numbers predominantly in the range of C8 Carc. Cat. 2; R45 R: 45-46-65
through C10 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
64742-95-6 135 °C to 210 °C (275 °F to 410 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Xn ; R: 65 ,
Solvent naphtha (petroleum), heavy aliph. [Straight S: (2) - 23 - 24 - 62 ;
64742-96-7 run kerosene] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
64743-01-7 Petrolatum (petroleum), oxidized [Petrolatum] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
Poly(oxy-1,4-butanediyl), alpha-hydro-omega-hydroxy-
, polymer with alpha-hydro-omega-
hydroxypoly[oxy(methyl-1,2-ethanediyl)] and 1,1’- Xn Isocyanates, all
64784-81-2 methylenebis[4-isocyanatobenzene] Xn; R42 R: 42 Conc>=1%: Xn; R42 N; A (as-NCO) - 0.02 - 0.07 - Sen -
Chlorsulfuron [2-Chloro-N-[[(4-methoxy-6-methyl-
1,3,5-triazin-2-yl)amino] N ; R: 50/53
64902-72-3 carbonyl]benzenesulphonamide] N: R50-53 S: 60 - 61 Eu - - - - - - - -
3,3'-Dichlorobenzidine sulfate (1:2) salt of [[1,1'-
Biphenyl]-4,4'-diamine, 3,3'-dichloro-, sulfate (1:2); Carc. Cat. 2; R45 T ; N ; R: 45 - 21 - 43 -
3,3'-Dichlorobiphenyl-4,4'-ylenediamine sulfate (1:2) Xn; R21 50/53, Conc>=25%: T; R45; R21; R43
salt of](Note: see also CAS No 612-83-9 & 74332-73- R43 S: 53 - 45 - 60 - 61; >=1%Conc<25%: T; R45; R43
64969-34-2 3) N; R50-53 Notes: A; E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
4,4'-bi-o-Toluidine, salts of [3,3'-Dimethyl[1,1'-
biphenyl]-4,4'-diyl]diammonium bis(hydrogen Carc. Cat. 2; R45 T ; N ; R: 45 - 22 - 51/53,
sulphate); o-Tolidine, salts of](Note: see also CAS No Xn; R22 S: 53 - 45 - 61; Conc>=25%: T; R45; R22
64969-36-4 612-82-8 & 74753-18-7) N; R51-53 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
N,N'-Diphenyl-N,N'-bis(3-methylphenyl)-(1,1'- N ; R: 51/53
65181-78-4 diphenyl)-4,4'-diamine N; R51-53 S: 61 Eu - - - - - - - -

Page 226
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=10%: T+; R63; R26/28; R48/23/25

>=7%Conc<10%: T+; R63; R26/28; R48/23;
R48/22
>=5%Conc<7%: T; R63; R23/25; R48/23;
Repr. Cat. 3; R63 R48/22
T+; R26/28 T+; N >=1%Conc<5%: T; R23/25; R48/20/22
Avermectin B1a (purity =80%)(Note: see also CAS T; R48/23/25 R: 63-26/28-48/23/25-50/53 >=0.5%Conc<1%: Xn; R20/22; R48/20
65195-55-3 No 71751-41-2) N; R50-53 S: 28-36/37-45-60-61 >=0.1%Conc<0.5%: Xn; R20/22 Eu - - - - - - - -
Conc>=25%: Xn; R22; R41
Xn; R22 Xn ; R: 22 - 41 >=10%Conc<25%: Xi; R41
65197-96-8 D,L-(N,N-Diethyl-2-hydroxy-2-phenylacetamide) Xi; R41 S: (2)26 - 39 - (46 - ) >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
Xi; R41 Xn ; N ; R: 22 - 41 - 43 - >=10%Conc<25%: Xi; R41; R43
R43 51/53, >=5%Conc<10%: Xi; R36; R43
65232-89-5 Divanadyl pyrophosphate N; R51-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Repr. Cat. 2; R60 T; N Conc>=25%: T; R60; R25; R48/22
Ketoconazole [1-[4-[4-[[(2SR,4RS)-2-(2,4- T; R25 R: 60-25-48/22-50/53 >=10%Conc<25%: T; R60; R22; R48/22
Dichlorophenyl)-2-(imidazol-1-ylmethyl)-1,3-dioxolan- Xn; R48/22 S: 53-45-60-61 >=3%Conc<10%: T; R60; R22
65277-42-1 4-yl]methoxy]phenyl]piperazin-1-yl]ethanone] N; R50-53 Note: E >=0.5%Conc<3%: T; R60 Eu - - - - - - - -

Conc>=25%: T; R45; R62; R68; R25; R21;

Carc. Cat. 2; R45 R48/22; R36; R43
Muta. Cat. 3; R68 >=20%Conc<25%: T; R45; R62; R68; R22;
Repr. Cat. 3; R62 R48/22; R36; R43
T; R25 >=10%Conc<20%: T; R45; R62; R68; R22;
Xn; R21-48/22 R48/22; R43
1,3-Benzenediamine, 4-methyl-, sulfate (1:1) [4- Xi; R36 T; N >=5%Conc<10%: T; R45; R62; R68; R22; R43
Methyl-m-phenylenediamine sulfate; Toluene-2,4- R43 R: 45-21-25-36-43-48/22-62- >=3%Conc<5%: T; R45; R68; R22; R43
65321-67-7 diammonium sulphate] N; R51-53 68-51-53 >=1%Conc<3%: T; R4 N/Eu - - - - - - - -

Carc.Cat.3; R40
Muta.Cat.3; R68 Conc>=25%: Xn; R40; R68; R22; R41; R38
Xn; R22 >=20%Conc<25%: Xn; R40; R68; R41; R38
Xi; R38-41 Xn >=10%Conc<20%: Xn; R40; R68; R41
R 52-53 R: 22-38-40-41-52/53-68 >=5%Conc<10%: Xn; R40; R68; R36
65322-65-8 1-(1-Naphthylmethyl)quinolinium chloride S: (2-)22-26-36/37/39-61 >=1%Conc<5%: Xn; R40; R68 Eu - - - - - - - -

Conc>=25%: T; R24/25; R48/25; R34

T >=10%Conc<25%: T; R48/25; R34; R21/22
T; R24/25-48/25 R: 24/25-34-48/25-52/53 >=5%Conc<10%: Xn; R21/22; R48/22; R36/38
C; R34 S: (1/2-)23-26-36/37/39-45- >=3%Conc<5%: Xn; R21/22; R48/22
65753-47-1 2-Chloro-3-trifluoromethylpyridine R52-53 61 >=1%Conc<3%: Xn; R48/22 Eu - - - - - - - -
Xn ; R: 68
65756-41-4 1-Ethyl-1-methylmorpholinium bromide Muta. Cat. 3; R68 S: (2)36/37 Conc>=1%: Xn; R68 Eu - - - - - - - -
Xn
N-(2',6'-Dimethylphenyl)-2-piperidinecarboxamide Xn; R22 R: 22-52/53
65797-42-4 hydrochloride R52-53 S: (2-)22-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn
R: 22
65855-02-9 1-Benzyl-5-ethoxyimidazolidine-2,4-dione Xn; R22 S: (2-)22 Conc>=25%: Xn; R22 Eu - - - - - - - -

Conc>=25%: T+; R26; R25; R48/22; R36/38;

R43
>=20%Conc<25%: T+; R26; R22; R48/22;
T+; R26 R36/38; R43
T; R25 T+; N >=10%Conc<20%: T+; R26; R22; R48/22; R43
Xn; R48/22 R: 25-26-36/38-43-48/22- >=7%Conc<10%: T+; R26; R22; R43
Furathiocarb (ISO) [2,3-Dihydro-2,2-dimethyl-7- Xi; R36/38 50/53 >=3%Conc<7%: T; R23; R22; R43
benzofuryl 2,4-dimethyl-6-oxa-5-oxo-3-thia-2,4- R43 S: (1/2-)28-36/37-38-45-60- >=1%Conc<3%: T; R23; R43
65907-30-4 diazadecanoate] N; R50-53 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -

Page 227
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Light oil (coal), coke-oven [Crude benzole](Note: The

volatile organic liquid extracted from the gas evolved
in the high temperature (greater than 700 °C (1292 T
°F)) destructive distillation of coal. Composed R: 45-46
primarily of benzene, toluene, and xylenes. May Carc. Cat. 2; R45 S: 53-45
65996-78-3 contain other minor hydrocarbon constituents.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Solvent naphtha (coal) [Light Oil Extract Residues,

high boiling](Note: The distillate from either high
temperature coal tar, coke oven light oil, or coal tar
oil alkaline extract residue having an approximate
distillation range of 130 °C to 210 °C (266 °F to 410
°F). Composed primarily of indene and other T
polycyclic ring systems containing a single aromatic R: 45-46
ring. May contain phenolic compounds and aromatic Carc. Cat. 2; R45 S: 53-45
65996-79-4 nitrogen bases.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tar oils, coal [Carbolic Oil](Note: The distillate from
high temperature coal tar having an approximate
distillation range of 130 °C to 250 °C (266 °F to 410 T
°F). Composed primarily of naphthalene, R: 45-46
alkylnaphthalenes, phenolic compounds, and Carc. Cat. 2; R45 S: 53-45
65996-82-9 aromatic nitrogen bases.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Extracts, coal tar oil alk. [Alkaline Extract](Note: The
extract from coal tar oil produced by an alkaline wash T
such as aqueous sodium hydroxide. Composed R: 45-46
primarily of the alkali salts of various phenolic Carc. Cat. 2; R45 S: 53-45
65996-83-0 compounds.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tar bases, coal, crude [Crude Tar Bases](Note: The

reaction product obtained by neutralizing coal tar
base extract oil with an alkaline solution, such as
aqueous sodium hydroxide, to obtain the free bases. T
Composed primarily of such organic bases as R: 45-46
acridine, phenanthridine, pyridine, quinoline and their Carc. Cat. 2; R45 S: 53-45
65996-84-1 alkyl derivatives.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tar acids, coal, crude [Crude Phenols](Note: The

reaction product obtained by neutralizing coal tar oil
alkaline extract with an acidic solution, such as T
aqueous sulfuric acid, or gaseous carbon dioxide, to R: 45-46
obtain the free acids. Composed primarily of tar acids Carc. Cat. 2; R45 S: 53-45
65996-85-2 such as phenol, cresols, and xylenols.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract oils (coal), tar base [Acid Extract](Note: The

extract from coal tar oil alkaline extract residue
produced by an acidic wash such as aqueous sulfuric
acid after distillation to remove naphthalene. T
Composed primarily of the acid salts of various R: 45-46
aromatic nitrogen bases including pyridine, quinoline, Carc. Cat. 2; R45 S: 53-45
65996-86-3 and their alkyl derivatives.]) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Extract residues (coal), tar oil alk. [Carbolic Oil
Extract Residue](Note: The residue obtained from
coal tar oil by an alkaline wash such as aqueous T
sodium hydroxide after the removal of crude coal tar R: 45-46
acids. Composed primarily of naphthalenes and Carc. Cat. 2; R45 S: 53-45
65996-87-4 aromatic nitrogen bases.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Benzol forerunnings (coal) [Light Oil Redistillate, low

boiling](Note: The distillate from coke oven light oil T
having an approximate distillation range below 100 R: 45-46
°C (212 °F). Composed primarily of C4 to C6 Carc. Cat. 2; R45 S: 53-45
65996-88-5 aliphatic hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 45 ,
S: 53 - 45 ;
65996-89-6 Tar, coal, high temp. Carc. Cat. 1; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
65996-90-9 Tar, coal, low-temp. Carc. Cat. 1; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
65996-91-0 Distillates (coal tar), upper [Heavy anthracene oil] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
65996-92-1 Distillates (coal tar) [Heavy anthracene oil] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

T ; R: 45 , Coal tar pitch

Coal tar pitch volatiles (as benzene solubles) [Pitch, S: 53 - 45 ; volatiles (as
65996-93-2 coal tar, high temp.; Pitch] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu; A benzene solubles) - 0.2 - - 1 - -
Xi
65997-05-9 Rosin, polymerized R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Xi
65997-06-0 Rosin, hydrogenated R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Xi
66034-17-1 Diphosphoric acid, compd. With piperazine (1:1) Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
Conc>=7%: T+; R28
T+ >=1%Conc<7%: T; R25
66104-23-2 Pergolide mesylate T+; R28 R: 28 >=0.1%Conc<1%: Xn; R22 V - - - - - - - -
3,6,9,12,15,18,21,24,27,30,33,36-
Dodecaoxaoctatetracontan-1-ol, hydrogen sulfate, Xn; R22 Xn Conc>=25%: Xn; R22; R36/38
66161-57-7 sodium salt Xi; R36/38 R: 22-36/38 >=20%Conc<25%: Xi; R36/38 N - - - - - - - -
T; N
Esfenvalerate (ISO) [(S)-alpha-Cyano-3- T; R23/25 R: 23/25-43-50/53 Conc>=25%: T; R23/25; R43
phenoxybenzyl-(S)-2-(4-chlorophenyl)-3- R43 S: (1/2-)24-36/37/39-45-60- >=3%Conc<25%: Xn; R20/22; R43
66230-04-4 methylbutyrate] N; R50-53 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -

Fenoxaprop ethyl [Ethyl 2-[4-[(6-chlorobenzoxazol-2- Xi; R43 Xi ; N ; R: 43 - 50/53,

66441-23-4 yl)oxy]phenoxy]propionate] N; R50-53 S: (2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Alcohols, C12-13, ethoxylated (Note: Polymeric

substances may be placed on the market with a
range of molecular weights which will affect the
toxicological properties of the substance. The
classifications need not apply if it can be shown that
the substance placed on the market does not meet
the criteria for classification; note 2: The classification Conc>=25%: Xn; R22; R38; R41
for skin irritation need not apply if it can be shown >=20%Conc<25%: Xi; R38; R41
that there are less than four or more than 21 Xn; R22 Xn >=10%Conc<20%: Xi; R41
66455-14-9 ethoxylate units) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Xi ; R: 43
66531-87-1 Sodium benzoyloxybenzene-4-sulfonate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=10%: Xi; R41; R43
Xi; R41 Xi ; R: 41 - 43 , >=5%Conc<10%: Xi; R36; R43
66710-66-5 N,N'-Ethylenebis(vinylsulfonylacetamide) R43 S: (2) - 24 - 26 - 37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
(3-Chlorophenyl)-(4-methoxy-3- Muta. Cat. 3; R68 Xn ; N ; R: 68 - 50/53
66938-41-8 nitrophenyl)methanone N; R50-53 S: (2)22 - 36/37 - 60 - 61 Conc>=1%: Xn; R68 Eu - - - - - - - -
Xn; R22 Xn; N
R43 R: 22-43-51/53 Conc>=25%: Xn; R22; R43
67014-36-2 5-Amino-6-methyl-1,3-dihydrobenzoimidazol-2-one N; R51-53 S: (2-)24-37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
R43 Xn; N
Metazachlor (ISO) [2-Chloro-N-(2,6-dimethylphenyl)- Carc. Cat. 3; R40 R: 40-43-50/53
67129-08-2 N-(1H-pyrazol-1- ylmethyl)acetamide] N; R50-53 S: (2-)36-37-60-61 Conc>=1%: Xn; R40; R43 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R36
67233-85-6 Sodium 5-nitroguaiacolate Xi; R36 R: 22-36 >=20%Conc<25%: Xi; R36 V - - - - - - - -

Page 229
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

E; R2 E ; Xn ; R: 2 - 20/21/22 - 33 ,
Xn; R20/21/22 S: (2) - 35 ; Conc>=25%: Xn; R20/21/22; R33
67297-26-1 Trinitroxylene R33 Note: C >=1%Conc<25%: Xn; R33 Eu - - - - - - - -
Benzyl cis-4-ammonium-4'-toluenesulfonato-1- R: 52/53
67299-45-0 cyclohexanecarboxylate R52-53 S: 61 Eu - - - - - - - -

alpha-Cypermethrin (ISO) [Racemate comprising (R)-

alpha-cyano-3-phenoxybenzyl (1S,3S)-3-(2,2- T; R25 Conc>=25%: T; R25; R48/22; R37
dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate Xn; R48/22 T; N >=20%Conc<25%: Xn; R22; R48/22; R37
and (S)-alpha-cyano-3-phenoxybenzyl (1R,3R)-3-(2,2- Xi; R37 R: 25-37-48/22-50/53 >=10%Conc<20%: Xn; R22; R48/22
67375-30-8 dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate] N; R50-53 S: (1/2-)36/37/39-45-60-61 >=3%Conc<10%: Xn; R22 Eu - - - - - - - -
5,5-Dimethyl-perhydro-pyrimidin-2-one alpha-(4- T; R48/25 T; N Conc>=25%: T; R48/25; R22; R36
trifluoromethylstyryl)-alpha-(4- Xn; R22 R: 22-36-48/25-50/53 >=20%Conc<25%: T; R48/25; R36
trifluoromethyl)cinnamylidenehydrazone Xi; R36 S: (1/2-)22-26-36/37-45-60- >=10%Conc<20%: T; R48/25
67485-29-4 [Hydramethylnon] N; R50-53 61 >=1%Conc<10%: Xn; R48/22 Eu - - - - - - - -
Repr. Cat. 3; R63
Xn; R22 Xn; N Conc>=25%: Xn; R63; R22; R38
Fenpropimorph [cis-4-[3-(p-tert-Butylphenyl)-2- Xi; R38 R: 22-38-63-51/53 >=20%Conc<25%: Xn; R63; R38
67564-91-4 methylpropyl]-2,6-dimethylmorpholine] N; R51-53 S: (2-)36/37-46-61 >=5%Conc<20%: Xn; R63 Eu - - - - - - - -

Ethyl 3,3-bis(tert-pentylperoxy)butyrate [Butanoic E; R3 E; N

acid, 3,3-bis[(1,1-dimethylpropyl)dioxy; Ethyl 3,3- O; R7 R10 R: 3-7-10-51/53
67567-23-1 bis(1,1-dimethylpropyl)peroxy]butyrate] N; R51-53 S: (2-)3/7-14-33-36/37/39-61 Eu - - - - - - - -
R: 52/53
67669-19-6 2,4-Dichloro-5-hydroxyacetanilide R52-53 S: 61 Eu - - - - - - - -

Mixture of: 2-methyl-1-(6-methylbicyclo[2.2.1]hept-5-

en-2-yl)pent-1-en-3-ol and 2-methyl-1-(1-
methylbicyclo[2.2.1]hept-5-en-2-yl)-pent-1-en-3-ol Xi; N
and 2-methyl-1-(5-methylbicyclo[2.2.1]hept-5-en-2- R: 36-51/53
67739-11-1 yl)pent-1-en-3-ol Xi; R36 N; R51-53 S: (2-)26-61 Conc>=20%: Xi; R36 Eu - - - - - - - -

Prochloraz [N-Propyl-N-[2-(2,4,6- Xn; R22 Xn ; N ; R: 22 - 50/53,

67747-09-5 trichlorophenoxy)ethyl]-1H-imidazole-1-carboxamide] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
N ; R: 50 ,
67774-74-7 Benzene, C10-13-alkyl derivatives N; R50 S: 61 Eu - - - - - - - -
R: 53
67811-06-7 4-Methylphenyl)mesitylene sulfonate R53 S: 61 Eu - - - - - - - -
4,4',5,5',6,6',7,7'-Octachloro-(2,2')biisoindolyl-1,1',3,3'- R: 53
67887-47-2 tetraone R53 S: 61 Eu - - - - - - - -

Distillates (petroleum), heavy arom. [Low boiling point

thermally cracked naphtha](Note: The complex
combination of hydrocarbons from the distillation of
the products from the thermal cracking of ethane and
propane. This higher boiling fraction consists
predominantly of C5-7 aromatic hydrocarbons with T
some unsaturated aliphatic hydrocarbons having Carc. Cat. 2; R45 R: 45-46-65
carbon number predominantly of C5.This stream may Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
67891-79-6 contain benzene.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), light arom. [Low boiling point

thermally cracked naphtha](Note: The complex
combination of hydrocarbons from the distillation of
the products from the thermal cracking of ethane and
propane. This lower boiling fraction consists
predominantly of C5-7 aromatic hydrocarbons with T
some unsaturated aliphatic hydrocarbons having a Carc. Cat. 2; R45 R: 45-46-65
carbon number predominantly of C5.This stream may Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
67891-80-9 contain benzene.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 230
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Ethyl cis-4-[4-[[2-(2,4-dichlorophenyl)-2-(1H-imidazol- Xn; N
1-ylmethyl)-1,3-dioxolan-4- Xn; R22-48/22 R: 22-48/22-50/53 Conc>=25%: Xn; R22; R48/22
67914-69-6 yl]methoxy]phenyl]piperazine-1-carboxylate N; R50-53 S: (2-)36-60-61 >=10%Conc<25%: Xn; 48/22 Eu - - - - - - - -
T; R48/22
Repr. Cat. 2; R61 T; N Conc>=10%: T; R61; R62; R48/22
Repr. Cat. 3; R62 R: 61-48/22-62-50/53 >=5%Conc<10%: T; R61; R62
68049-83-2 Azafenidin N; R50-53 S: 53-45-60-61 >=0.5%Conc<5%: T; R61 Eu - - - - - - - -

Mixture of: 7-chloro-1-ethyl-6-fluoro-1,4-dihydro-4-oxo-

quinoline-3-carboxylic acid and 5-chloro-1-ethyl-6- R: 52/53
68077-26-9 fluoro-1,4-dihydro-4-oxo-quinoline-3-carboxylic acid R 52-53 S: 61 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, mono-C10-16-alkyl derivatives, Xn; R22 Xn >=10%Conc<20%: Xi; R41
68081-81-2 sodium salts Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Alcohols, C12-15, ethoxylated(Note: Polymeric

substances may be placed on the market with a
range of molecular weights which will affect the
toxicological properties of the substance. The
classifications need not apply if it can be shown that
the substance placed on the market does not meet
the criteria for classification; note 2: The classification Conc>=25%: Xn; R22; R38; R41
for skin irritation need not apply if it can be shown >=20%Conc<25%: Xi; R38; R41
that there are less than four or more than 21 Xn; R22 Xn >=10%Conc<20%: Xi; R41
68131-39-5 ethoxylate units) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
T
Carc. Cat. 2; R45 R: 45-46-65
Aromatic hydrocarbons, C6-10, acid-treated, Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68131-49-7 neutralized [Low boiling point naphtha — unspecified] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
68131-60-2 Fatty acids, C12-18, lead salts R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xn; R21/22 C; N Conc>=25%: C; R21/22; R34; R43
C; R34 R: 21/22-34-43-50/53 >=10%Conc<25%: C; R34; R43
R43 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: Xi; R36/38; R43
68131-73-7 Amines, polyethylenepoly [HEPA] N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Gases (petroleum), C3-4 [Petroleum gas](Note: A

complex combination of hydrocarbons produced by
distillation of products from the cracking of crude oil.
It consists of hydrocarbons having carbon numbers in F+; T
the range of C3 through C4, predominantly of F+; R12 R: 45-46-12
propane and propylene, and boiling in the range of Carc. Cat. 1; R45 S: 53-45
68131-75-9 approximately -51 °C to -1 °C (-60 °F to 30 °F.)) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Conc>=25%: T; R23; R34; R43
T; R23 T ; N ; R: 23 - 34 - 43 - >=10%Conc<25%: C; R34; R20; R43
C; R34 50/53, >=5%Conc<10%: Xn; R20; R36/38; R43
C8-18-Alkylbis(2-hydroxyethyl)ammonium bis(2- R43 S: (1/2) - 26 - 36/37/39 - 45 - >=3%Conc<5%: Xn; R20; R43
68132-19-4 ethylhexyl)phosphate N; R50-53 60 - 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Xn; N
Forchlorfenuron (ISO) [1-(2-Chloro-4-pyridyl)-3- Carc. Cat. 3; R40 R: 40-51/53
68157-60-8 phenylurea] N; R51-53 S: (2-)36/37-46-61 Conc>=1%: Xn; R40 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
68187-57-5 Pitch, coal tar petroleum [Pitch residues] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (coal petroleum), condensed ring arom. S: 53 - 45 ;
68188-48-7 [Distillates] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 231
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=20%: Xi; R38; R41
Xi >=10%Conc<20%: Xi; R41
68201-55-8 Betaines, coco alkyldimethyl(3-sulfopropyl) Xi; R38-41 R: 38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Alcohols, C12-18, ethoxylated(Note: Polymeric

substances may be placed on the market with a
range of molecular weights which will affect the
toxicological properties of the substance. The
classifications need not apply if it can be shown that
the substance placed on the market does not meet
the criteria for classification; note 2: The classification Conc>=25%: Xn; R22; R38; R41
for skin irritation need not apply if it can be shown >=20%Conc<25%: Xi; R38; R41
that there are less than four or more than 21 Xn; R22 Xn >=10%Conc<20%: Xi; R41
68213-23-0 ethoxylate units) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
T; R23 Conc>=25%: T; R23, R22
68213-26-3 Alkoxylated fatty alkylamine polymer Xn; R22 T ; R: 22 -23 >=3%Conc<25%: Xn; R20 V - - - - - - - -

Strychnidin-10-one, 2,3-dimethoxy, mono[(R)-1- Conc>=7%: T+; R26/28

methylheptyl 1,2-benzenedicarboxylate(Note: see T+; R26/28 T+ ; R: 26/28 - 52/53, >=1%Conc<7%: T; R23/25
68239-26-9 also CAS No 4845-99-2, 5786-97-0 & 68310-42-9) R52-53 S: (1/2) - 13 - 45 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -

Tail gas (petroleum), catalytic cracked distillate and

catalytic cracked naphtha fractionation absorber
[Petroleum gas](Note: The complex combination of
hydrocarbons from the distillation of the products
from catalytic cracked distillates and catalytic F+; T
cracked naphtha. It consists predominantly of F+; R12 R: 45-46-12
hydrocarbons having carbon numbers in the range of Carc. Cat. 1; R45 S: 53-45
68307-98-2 C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tail gas (petroleum), catalytic polymn. naphtha
fractionation stabilizer [Petroleum gas](Note: A
complex combination of hydrocarbons from the
fractionation stabilization products from F+; T
polymerization of naphtha. It consists predominantly F+; R12 R: 45-46-12
of hydrocarbons having carbon numbers in the range Carc. Cat. 1; R45 S: 53-45
68307-99-3 of C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), catalytic reformed naphtha

fractionation stabilizer, hydrogen sulfide-free
[Petroleum gas](Note: A complex combination of
hydrocarbons obtained from fractionation stabilization
of catalytic reformed naphtha and from which
hydrogen sulfide has been removed by amine F+; T
treatment. It consists predominantly of hydrocarbons F+; R12 R: 45-46-12
having carbon numbers predominantly in the range of Carc. Cat. 1; R45 S: 53-45
68308-00-9 C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), cracked distillate hydrotreater

stripper [Petroleum gas](Note: A complex
combination of hydrocarbons obtained by treating
thermal cracked distillates with hydrogen in the F+; T
presence of a catalyst. It consists predominantly of F+; R12 R: 45-46-12
saturated hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68308-01-0 predominantly in the range of C1 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tail gas (petroleum), gas oil catalytic cracking
absorber [Petroleum gas](Note: A complex
combination of hydrocarbons obtained from the
distillation of products from the catalytic cracking of F+; T
gas oil. It consists predominantly of hydrocarbons F+; R12 R: 45-46-12
having carbon numbers predominantly in the range of Carc. Cat. 1; R45 S: 53-45
68308-03-2 C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 232
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Tail gas (petroleum), gas recovery plant [Petroleum

gas](Note: A complex combination of hydrocarbons
from the distillation of products from miscellaneous F+; T
hydrocarbon streams. It consists predominantly of F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68308-04-3 in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), gas recovery plant deethanizer

[Petroleum gas](Note: A complex combination of
hydrocarbons from the distillation of products from F+; T
miscellaneous hydrocarbon streams. It consists of F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68308-05-4 in the range of C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), hydrodesulfurized distillate and

hydrodesulfurized naphtha fractionator, acid-free
[Petroleum gas](Note: A complex combination of
hydrocarbons obtained from fractionation of
hydrodesulfurized naphtha and distillate hydrocarbon
streams and treated to remove acidic impurities. It F+; T
consists predominantly of hydrocarbons having F+; R12 R: 45-46-12
carbon numbers predominantly in the range of C1 Carc. Cat. 1; R45 S: 53-45
68308-06-5 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), hydrodesulfurized vacuum gas

oil stripper, hydrogen sulfide-free [Petroleum
gas](Note: A complex combination of hydrocarbons
obtained from stripping stabilization of catalytic
hydrodesulfurized vacuum gas oil and from which
hydrogen sulfide has been removed by amine F+; T
treatment. It consists predominantly of hydrocarbons F+; R12 R: 45-46-12
having carbon numbers predominantly in the range of Carc. Cat. 1; R45 S: 53-45
68308-07-6 C1 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), isomerized naphtha

fractionation stabilizer [Petroleum gas](Note: A
complex combination of hydrocarbons obtained from
the fractionation stabilization products from F+; T
isomerized naphtha. It consists predominantly of F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68308-08-7 in the range of C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), light straight-run naphtha

stabilizer, hydrogen sulfide-free [Petroleum
gas](Note: A complex combination of hydrocarbons
obtained from fractionation stabilization of light
straight run naphtha and from which hydrogen sulfide
has been removed by amine treatment. It consists F+; T
predominantly of hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68308-09-8 C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), straight-run distillate

hydrodesulfurizer, hydrogen sulfide-free [Petroleum
gas](Note: A complex combination of hydrocarbons
obtained from catalytic hydrodesulfurization of
straight run distillates and from which hydrogen
sulfide has been removed by amine treatment. It F+; T
consists predominantly of hydrocarbons having F+; R12 R: 45-46-12
carbon numbers predominantly in the range of C1 Carc. Cat. 1; R45 S: 53-45
68308-10-1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 233
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Tail gas (petroleum), propane-propylene alkylation

feed prep deethanizer [Petroleum gas](Note: A
complex combination of hydrocarbons obtained from
the distillation of the reaction products of propane F+; T
with propylene. It consists of hydrocarbons having F+; R12 R: 45-46-12
carbon numbers predominantly in the range of C1 Carc. Cat. 1; R45 S: 53-45
68308-11-2 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), vacuum gas oil

hydrodesulfurizer, hydrogen sulfide-free [Petroleum
gas](Note: A complex combination of hydrocarbons
obtained from catalytic hydrodesulfurization of
vacuum gas oil and from which hydrogen sulfide has
been removed by amine treatment. It consists F+; T
predominantly of hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68308-12-3 C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Strychnidin-10-one, 2,3-dimethoxy, compd. with (S)-
mono(1-methylheptyl)- 1,2-benzenedicarboxylate Conc>=7%: T+; R26/28
(1:1)(Note: see also CAS No 4845-99-2, 5786-97-0 & T+; R26/28 T+ ; R: 26/28 - 52/53, >=1%Conc<7%: T; R23/25
68310-42-9 68239-26-9) R52-53 S: (1/2) - 13 - 45 - 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
68333-22-2 Residues (petroleum), atmospheric [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Naphtha (petroleum), heavy coker [Kerosene S: (2) - 23 - 24 - 62 ;
68333-23-3 unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrodesulfurized light S: 53 - 45 ;
68333-25-5 catalytic cracked [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Clarified oils (petroleum), hydrodesulfurised catalytic S: 53 - 45 ;
68333-26-6 cracked [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrodesulfurized S: 53 - 45 ;
68333-27-7 intermediate catalytic cracked [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrodesulfurized heavy S: 53 - 45 ;
68333-28-8 catalytic cracked [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Fuels, diesel [Automotive diesel fuel; Gasoil

unspecified](Note: A complex combination of
hydrocarbons produced by the distillation of crude oil.
It consists of hydrocarbons having carbon numbers Xn
predominantly in the range of C9 through C20 and R: 40
boiling in the range of approximately 163°C to 357°C S: (2-)36/37;
68334-30-5 (325°F to 675°F)) Carc. Cat. 3; R40 Notes: H; N Conc>=1%: Xn; R40 Eu; P - - - - - - - -
alpha-Cyano-4-fluoro-3-phenoxybenzyl-3-(2,2- T+ ; N ; R: 26/28 - 50/53, Conc>=7%: T+; R26/28
dichlorovinyl)-2,2-dimethylcyclopropane-carboxylate T+; R26/28 S: (1/2) - 36/37/39 - 45 - 60 - >=1%Conc<7%: T; R23/25
68359-37-5 [beta-Cyfluthrin] N; R50-53 61 >=0.1%Conc<1%: Xn; R20/22 Eu - - - - - - - -
Conc>=25%: T+; R28; R23
T+; N >=7%Conc<25%: T+; R28; R20
Cyfluthrin (ISO) [alpha-Cyano-4-fluoro-3- T+; R28 R: 23-28-50/53 >=3%Conc<7%: T; R25; R20
phenoxybenzyl-3-(2,2-dichlorovinyl)-2,2- T; R23 S: (1/2-)28-36/37/39-45-60- >=1%Conc<3%: T; R25
68359-37-5 dimethylcyclopropanecarboxylate] N; R50-53 61 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

Pyridine, alkyl derivs. [Crude Tar Bases](Note: The

complex combination of polyalkylated pyridines
derived from coal tar distillation or as high-boiling T
distillates approximately above 150 °C (302 °F) from R: 45-46
the reaction of ammonia with acetaldehyde, Carc. Cat. 2; R45 S: 53-45
68391-11-7 formaldehyde or paraformaldehyde.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 234
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Gases (petroleum), catalytic cracked overheads

[Petroleum gas](Note: A complex combination of
hydrocarbons produced by the distillation of products
from the catalytic cracking process. It consists of
hydrocarbons having carbon numbers predominantly F+; T
in the range of C3 through C5 and boiling in the F+; R12 R: 45-46-12
range of approximately -48 °C to 32 °C (-54 °F to 90 Carc. Cat. 1; R45 S: 53-45
68409-99-4 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), straight-run light [Low boiling

point naphtha](Note: A complex combination of
hydrocarbons produced by the distillation of crude oil
It consists of hydrocarbons having carbon numbers T
predominantly in the range of C2 through C7 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately -88 °C to 99 °C (- Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68410-05-9 127 °F to 210 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Raffinates (petroleum), catalytic reformer ethylene

glycol-water countercurrent exts. [Low boiling point
modified naphtha](Note: A complex combination of
hydrocarbons obtained as the raffinate from the
UDEX extraction process on the catalytic reformer T
stream. It consists of saturated hydrocarbons having Carc. Cat. 2; R45 R: 45-46-65
carbon numbers predominantly in the range of C6 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68410-71-9 through C9.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), hydrotreated middle,

intermediate boiling [Low boiling point hydrogen
treated naphtha](Note: A complex combination of
hydrocarbons obtained by the distillation of products
from a middle distillate hydrotreating process. It
consists of hydrocarbons having carbon numbers T
predominantly in the range of C5 through C10 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately 127 °C to 188 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68410-96-8 °C (262 °F to 370 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), light distillate hydrotreating

process, low-boiling [Low boiling point hydrogen
treated naphtha](Note: A complex combination of
hydrocarbons obtained by the distillation of products
from the light distillate hydrotreating process. It
consists of hydrocarbons having carbon numbers T
predominantly in the range of C6 through C9 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately 3 °C to 194 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68410-97-9 (37 °F to 382 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), hydrotreated heavy naphtha,

deisohexanizer overheads [Low boiling point
hydrogen treated naphtha](Note: A complex
combination of hydrocarbons obtained by distillation
of the products from a heavy naphtha hydrotreating
process. It consists of hydrocarbons having carbon T
numbers predominantly in the range of C3 through Carc. Cat. 2; R45 R: 45-46-65
C6 and boiling in the range of approximately -49 °C to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68410-98-0 68 °C (-57 °F to 155 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, C10-13-alkyl derivatives, Xn; R22 Xn >=10%Conc<20%: Xi; R41
68411-30-3 sodium salts Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Page 235
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
68424-76-0 Oils, menhaden, lead salts R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Distillates (petroleum), naphtha-raffinate pyrolyzate-

derived, gasoline-blending [Low boiling point
thermally cracked naphtha](Note: The complex
combination of hydrocarbons obtained by the
pyrolysis fractionation at 816 °C (1500 °F) of naphtha T
and raffinate. It consists predominantly of Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons having a carbon number of C9 and Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68425-29-6 boiling at approximately 204 °C (400 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Raffinates (petroleum), reformer, Lurgi unit-sepd.

[Low boiling point modified naphtha](Note: The
complex combination of hydrocarbons obtained as a
raffinate from a Lurgi separation unit. It consists
predominantly of non-aromatic hydrocarbons with T
various small amounts of aromatic hydrocarbons Carc. Cat. 2; R45 R: 45-46-65
having carbon numbers predominantly in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68425-35-4 C6 through C8.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Alcohols, C12-14, ethoxylated(Note: Polymeric

substances may be placed on the market with a
range of molecular weights which will affect the
toxicological properties of the substance. The
classifications need not apply if it can be shown that
the substance placed on the market does not meet
the criteria for classification; note 2: The classification Conc>=25%: Xn; R22; R38; R41
for skin irritation need not apply if it can be shown >=20%Conc<25%: Xi; R38; R41
that there are less than four or more than 21 Xn; R22 Xn >=10%Conc<20%: Xi; R41
68439-50-9 ethoxylate units) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, dodecyl-, reaction products Xn; R22 Xn >=10%Conc<20%: Xi; R41
68442-72-8 with ethanolamine Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
F+; R12 F+; T
Carc. Cat. 1; R45 R: 45-46-12
68475-57-0 Alkanes, C1-2 [Petroleum gas] Muta. Cat. 2; R46 S: 53-45 Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Carc. Cat. 1; R45 S: 53-45
68475-58-1 Alkanes, C2-3 [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Alkanes, C3-4 Carc. Cat. 1; R45 S: 53-45
68475-59-2 [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Carc. Cat. 1; R45 S: 53-45
68475-60-5 Alkanes, C4-5 [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Aromatic hydrocarbons, C6-8, naphtha-raffinate

pyrolyzate-derived [Low boiling point thermally
cracked naphtha](Note: A complex combination of
hydrocarbons obtained by the fractionation pyrolysis
at 816 °C (1500 °F) of naphtha and raffinate. It T
consists predominantly of aromatic hydrocarbons Carc. Cat. 2; R45 R: 45-46-65
having carbon numbers predominantly in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68475-70-7 C6 through C8, including benzene.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 236
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Distillates (petroleum), catalytic reformed

depentanizer [Low boiling point cat-reformed
naphtha](Note: A complex combination of
hydrocarbons from the distillation of products from a
catalytic reforming process. It consists predominantly
of aliphatic hydrocarbons having carbon numbers T
predominantly in the range of C3 through C6 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately -49 °C to 63 °C (- Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68475-79-6 57 °F to 145 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), light steam cracked naphtha S: 53 - 45 ;
68475-80-9 [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
F+; T
Fuel gases [Petroleum gas](Note: A combination of F+; R12 R: 45-46-12
light gases. It consists predominantly of hydrogen Carc. Cat. 1; R45 S: 53-45
68476-26-6 and/or low molecular weight hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Fuel gases, crude oil of distillates [Petroleum

gas](Note: A complex combination of light gases
produced by distillation of crude oil and by catalytic
reforming of naphtha. It consists of hydrogen and
hydrocarbons having carbon numbers predominantly F+; T
in the range of C1 through C4 and boiling in the F+; R12 R: 45-46-12
range of approximately -217 °C to -12 °C (-423 °F to Carc. Cat. 1; R45 S: 53-45
68476-29-9 10 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Xn ; R: 40 ,
S: (2) - 36/37 ;
68476-30-2 Fuel oil No. 2 [Gasoil unspecified] Carc. Cat. 3; R40 Note: H Conc>=1%: Xn; R40 Eu - - - - - - - -
Xn ; R: 40 ,
S: (2) - 36/37 ;
68476-31-3 Fuel oil No. 4 [Gasoil unspecified] Carc. Cat. 3; R40 Note: H Conc>=1%: Xn; R40 Eu - - - - - - - -
T ; R: 45 ,
Fuel oil, residues straight run gas oils, high sulfur S: 53 - 45 ;
68476-32-4 [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
68476-33-5 Fuel oil, residual [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 40 ,
S: (2) - 36/37 ;
68476-34-6 Fuel, diesel No.2 [Gasoil unspecified] Carc. Cat. 3; R40 Note: H Conc>=1%: Xn; R40 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Carc. Cat. 1; R45 S: 53-45
68476-40-4 Hydrocarbons, C3-4 [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Carc. Cat. 1; R45 S: 53-45
68476-42-6 Hydrocarbons, C4-5 [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C3-11, catalytic cracker distillates

[Low boiling point cat-cracked naphtha](Note: A
complex combination of hydrocarbons produced by
the distillations of products from a catalytic cracking
process. It consists of hydrocarbons having carbon T
numbers predominantly in the range of C3 through Carc. Cat. 2; R45 R: 45-46-65
C11 and boiling in a range approximately up to 204 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68476-46-0 °C (400 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T
Carc. Cat. 2; R45 R: 45-46-65
Hydrocarbons, C2-6, C6-8 catalytic reformer [Low Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68476-47-1 boiling point cat-reformed naphtha] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 237
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F+; T
F+; R12 R: 45-46-12
Carc. Cat. 1; R45 S: 53-45
68476-49-3 Hydrocarbons, C2-4, C3-rich [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T
Carc. Cat. 2; R45 R: 45-46-65
Hydrocarbons, C>=5, C5-6-rich [Low boiling point Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68476-50-6 naphtha — unspecified] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T
Carc. Cat. 2; R45 R: 45-46-65
Hydrocarbons, C5-rich [Low boiling point naphtha — Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68476-55-1 unspecified] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

LPG (liquified petroleum gas) [Petroleum gases,

liquefied
Petroleum gas](Note: A complex combination of
hydrocarbons produced by the distillation of crude oil.
It consists of hydrocarbons having carbon numbers F+; T
predominantly in the range of C3 through C7 and F+; R12 R: 45-46-12
boiling in the range of approximately -40 °C to 80 °C (- Carc. Cat. 1; R45 S: 53-45 LPG (liquified
68476-85-7 40 °F to 176 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu;A petroleum gas) 1000 1800 - - - - -

Petroleum gases, liquefied, sweetened [Petroleum

gas](Note: A complex combination of hydrocarbons
obtained by subjecting liquefied petroleum gas mix to
a sweetening process to convert mercaptans or to
remove acidic impurities. It consists of hydrocarbons F+; T
having carbon numbers predominantly in the range of F+; R12 R: 45-46-12
C3 through C7 and boiling in the range of Carc. Cat. 1; R45 S: 53-45
68476-86-8 approximately -40 °C to 80 °C (-40 °F to 176 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tar acids, residues, distillates, first-cut [Distillate T
Phenols](Note: The residue from the distillation in the R: 45-46
range of 235 °C to 355 °C (481 °F to 697 °F) of light Carc. Cat. 2; R45 S: 53-45
68477-23-6 carbolic oil.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), catalytic reformer fractionator S: 53 - 45 ;
68477-29-2 residue, high boiling [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), catalytic reformer fractionator S: 53 - 45 ;
68477-30-5 residue, intermediate boiling [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), catalytic reformer fractionator S: 53 - 45 ;
68477-31-6 residue, low boiling [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -

Gases (petroleum), C3-4, isobutane-rich [Petroleum

gas](Note: A complex combination of hydrocarbons
from the distillation of saturated and unsaturated
hydrocarbons usually ranging in carbon numbers
from C3 through C6, predominantly butane and F+; T
isobutane. It consists of saturated and unsaturated F+; R12 R: 45-46-12
hydrocarbons having carbon numbers in the range of Carc. Cat. 1; R45 S: 53-45
68477-33-8 C3 through C4, predominantly isobutane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), C3-5, 2-methyl-2-butene-rich

[Low boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons from the
distillation of hydrocarbons usually ranging in carbon
numbers from C3 through C5, predominantly
isopentane and 3-methyl-1-butene. It consists of T
saturated and unsaturated hydrocarbons having Carc. Cat. 2; R45 R: 45-46-65
carbon numbers in the range of C3 through C5, Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68477-34-9 predominantly 2-methyl-2-butene.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 238
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Distillates (petroleum), C3-6, piperylene-rich

[Petroleum gas](Note: A complex combination of
hydrocarbons from the distillation of saturated and
unsaturated aliphatic hydrocarbons usually ranging in
the carbon numbers C3 through C6. It consists of F+; T
saturated and unsaturated hydrocarbons having F+; R12 R: 45-46-12
carbon numbers in the range of C3 through C6, Carc. Cat. 1; R45 S: 53-45
68477-35-0 predominantly piperylenes.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), cracked steam cracked S: 53 - 45 ;
68477-38-3 petroleum distillate [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Distillates (petroleum), cracked stripped steam Xn ; R: 65 ,
cracked petroleum distillates C8-10 fraction [Cracked S: (2) - 23 - 24 - 62 ;
68477-39-4 kerosine] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
Distillates (petroleum), cracked stripped steam Xn ; R: 65 ,
cracked petroleum distillates C10-12 fraction S: (2) - 23 - 24 - 62 ;
68477-40-7 [Cracked kerosine] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

Distillates (petroleum), polymd. steam-cracked

petroleum distillates, C5-12 fraction [Low boiling point
naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained from the
distillation of polymerized steam-cracked petroleum T
distillate. It consists predominantly of hydrocarbons Carc. Cat. 2; R45 R: 45-46-65
having carbon numbers predominantly in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68477-50-9 C5 through C12.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), steam-cracked, C5-12 fraction

[Low boiling point naphtha — unspecified](Note: A
complex combination of organic compounds obtained
by the distillation of products from a steam cracking T
process. It consists of unsaturated hydrocarbons Carc. Cat. 2; R45 R: 45-46-65
having carbon numbers predominantly in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68477-53-2 C5 through C12.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Xn ; R: 65 ,
Distillates (petroleum), steam cracked, C8-12 fraction S: (2) - 23 - 24 - 62 ;
68477-54-3 [Cracked kerosine] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
Distillates (petroleum), steam-cracked, C5-10 T
fraction, mixed with light steam-cracked petroleum Carc. Cat. 2; R45 R: 45-46-65
naphtha C5 fraction [Low boiling point naphtha — Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68477-55-4 unspecified] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Extracts (petroleum), cold-acid, C4-6 [Low boiling

point naphtha — unspecified](Note: A complex
combination of organic compounds produced by cold
acid unit extraction of saturated and unsaturated
aliphatic hydrocarbons usually ranging in carbon
numbers from C3 through C6, predominantly
pentanes and amylenes. It consists predominantly of T
saturated and unsaturated hydrocarbons having Carc. Cat. 2; R45 R: 45-46-65
carbon numbers in the range of C4 through C6, Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68477-61-2 predominantly C5.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), amine system feed [Refinery

gas](Note: The feed gas to the amine system for
removal of hydrogen sulfide. It consists of hydrogen.
Carbon monoxide, carbon dioxide, hydrogen sulfide F+; T
and aliphatic hydrocarbons having carbon numbers F+; R12 R: 45-46-12
predominantly in the range of C1 through C5 may Carc. Cat. 1; R45 S: 53-45
68477-65-6 also be present.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 239
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Gases (petroleum), benzene unit hydrodesulfurizer

off [Refinery gas](Note: Off gases produced by the
benzene unit. It consists primarily of hydrogen. F+; T
Carbon monoxide and hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68477-66-7 C6, including benzene, may also be present.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), benzene unit recycle, hydrogen-

rich [Refinery gas](Note: A complex combination of
hydrocarbons obtained by recycling the gases of the
benzene unit. It consists primarily of hydrogen with F+; T
various small amounts of carbon monoxide and F+; R12 R: 45-46-12
hydrocarbons having carbon numbers in the range of Carc. Cat. 1; R45 S: 53-45
68477-67-8 C1 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), blend oil, hydrogen-nitrogen-rich

[Refinery gas](Note: A complex combination of
hydrocarbons obtained by distillation of a blend oil. It
consists primarily of hydrogen and nitrogen with
various small amounts of carbon monoxide, carbon F+; T
dioxide, and aliphatic hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68477-68-9 C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), butane splitter overheads
[Petroleum gas](Note: A complex combination of
hydrocarbons obtained from the distillation of the F+; T
butane stream. It consists of aliphatic hydrocarbons F+; R12 R: 45-46-12
having carbon numbers predominantly in the range of Carc. Cat. 1; R45 S: 53-45
68477-69-0 C3 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), C2-3 [Petroleum gas](Note: A

complex combination of hydrocarbons produced by F+; T
the distillation of products from a catalytic F+; R12 R: 45-46-12
fractionation process. It contains predominantly Carc. Cat. 1; R45 S: 53-45
68477-70-3 ethane, ethylene, propane, and propylene.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), catalytic-cracked gas oil

depropanizer bottoms, C4-rich acid-free [Petroleum
gas](Note: A complex combination of hydrocarbons
obtained from fractionation of catalytic cracked gas
oil hydrocarbon stream and treated to remove F+; T
hydrogen sulfide and other acidic components. It F+; R12 R: 45-46-12
consists of hydrocarbons having carbon numbers in Carc. Cat. 1; R45 S: 53-45
68477-71-4 the range of C3 through C5, predominantly C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), catalytic-cracked naphtha
debutanizer bottoms, C3-5-rich [Petroleum gas](Note:
A complex combination of hydrocarbons obtained
from the stabilization of catalytic cracked naphtha. It F+; T
consists of aliphatic hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C3 through Carc. Cat. 1; R45 S: 53-45
68477-72-5 C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), catalytic cracked naphtha

depropanizer overhead, C3-rich acid-free [Petroleum
gas](Note: A complex combination of hydrocarbons
obtained from fractionation of catalytic cracked
hydrocarbons and treated to remove acidic F+; T
impurities. It consists of hydrocarbons having carbon F+; R12 R: 45-46-12
numbers in the range of C2 through C4, Carc. Cat. 1; R45 S: 53-45
68477-73-6 predominantly C3.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 240
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Gases (petroleum), catalytic cracker [Petroleum

gas](Note: A complex combination of hydrocarbons
produced by the distillation of the products from a F+; T
catalytic cracking process. It consists predominantly F+; R12 R: 45-46-12
of aliphatic hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68477-74-7 predominantly in the range of C1 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), catalytic cracker, C1-5-rich
[Petroleum gas](Note: A complex combination of
hydrocarbons produced by the distillation of products
from a catalytic cracking process. It consists of F+; T
aliphatic hydrocarbons having carbon numbers in the F+; R12 R: 45-46-12
range of C1 through C6, predominantly C1 through Carc. Cat. 1; R45 S: 53-45
68477-75-8 C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), catalytic polymd. naphtha

stabilizer overhead, C2-4-rich [Petroleum gas](Note:
A complex combination of hydrocarbons obtained
from the fractionation stabilization of catalytic F+; T
polymerized naphtha. It consists of aliphatic F+; R12 R: 45-46-12
hydrocarbons having carbon numbers in the range of Carc. Cat. 1; R45 S: 53-45
68477-76-9 C2 through C6, predominantly C2 through C4.]) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), catalytic reformed naphtha

stripper overheads [Refinery gas](Note: A complex
combination of hydrocarbons obtained from
stabilization of catalytic reformed naphtha. Its F+; T
consists of hydrogen and saturated hydrocarbons F+; R12 R: 45-46-12
having carbon numbers predominantly in the range of Carc. Cat. 1; R45 S: 53-45
68477-77-0 C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), catalytic reformer, C1-4-rich

[Petroleum gas](Note: A complex combination of
hydrocarbons produced by distillation of products F+; T
from a catalytic reforming process. It consists of F+; R12 R: 45-46-12
hydrocarbons having carbon numbers in the range of Carc. Cat. 1; R45 S: 53-45
68477-79-2 C1 through C6, predominantly C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), C6-8 catalytic reformer recycle

[Refinery gas](Note: A complex combination of
hydrocarbons produced by distillation of products
from catalytic reforming of C6-C8 feed and recycled
to conserve hydrogen. It consists primarily of
hydrogen. It may also contain various small amounts F+; T
of carbon monoxide, carbon dioxide, nitrogen, and F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68477-80-5 in the range of C1 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), C6-8 catalytic reformer [Refinery

gas](Note: A complex combination of hydrocarbons
produced by distillation of products from catalytic F+; T
reforming of C6-C8feed. It consists of hydrocarbons F+; R12 R: 45-46-12
having carbon numbers in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68477-81-6 C5 and hydrogen.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Gases (petroleum), C6-8 catalytic reformer recycle, Carc. Cat. 1; R45 S: 53-45
68477-82-7 hydrogen-rich [Refinery gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 241
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Gases (petroleum), C3-5 olefinic-paraffinic alkylation

feed [Petroleum gas](Note: A complex combination of
olefinic and paraffinic hydrocarbons having carbon
numbers in the range of C3 through C5 which are F+; T
used as alkylation feed. Ambient temperatures F+; R12 R: 45-46-12
normally exceed the critical temperature of these Carc. Cat. 1; R45 S: 53-45
68477-83-8 combinations.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), C2-return stream [Refinery

gas](Note: A complex combination of hydrocarbons
obtained by the extraction of hydrogen from a gas
stream which consists primarily of hydrogen with
small amounts of nitrogen, carbon monoxide,
methane, ethane, and ethylene. It contains F+; T
predominantly hydrocarbons such as methane, F+; R12 R: 45-46-12
ethane, and ethylene with small amounts of Carc. Cat. 1; R45 S: 53-45
68477-84-9 hydrogen, nitrogen and carbon monoxide.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), C4-rich [Petroleum gas](Note: A

complex combination of hydrocarbons produced by
distillation of products from a catalytic fractionation F+; T
process. It consists of aliphatic hydrocarbons having F+; R12 R: 45-46-12
carbon numbers in the range of C3 through C5, Carc. Cat. 1; R45 S: 53-45
68477-85-0 predominantly C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), deethanizer overheads
[Petroleum gas](Note: A complex combination of
hydrocarbons produced from distillation of the gas F+; T
and gasoline fractions from the catalytic cracking F+; R12 R: 45-46-12
process. It contains predominantly ethane and Carc. Cat. 1; R45 S: 53-45
68477-86-1 ethylene.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), deisobutanizer tower overheads

[Petroleum gas](Note: A complex combination of
hydrocarbons produced by the atmospheric F+; T
distillation of a butane-butylene stream. It consists of F+; R12 R: 45-46-12
aliphatic hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68477-87-2 predominantly in the range of C3 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), depentanizer overheads [Low

boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons obtained from T
a catalytic cracked gas stream. It consists of aliphatic Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons having carbon numbers predominantly Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68477-89-4 in the range of C4 through C6.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), depropanizer dry, propene-rich

[Petroleum gas](Note: A complex combination of
hydrocarbons produced by the distillation of products F+; T
from the gas and gasoline fractions of a catalytic F+; R12 R: 45-46-12
cracking process. It consists predominantly of Carc. Cat. 1; R45 S: 53-45
68477-90-7 propylene with some ethane and propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), depropanizer overheads
[Petroleum gas](Note: A complex combination of
hydrocarbons produced by distillation of products
from the gas and gasoline fractions of a catalytic F+; T
cracking process. It consists of aliphatic F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68477-91-8 in the range of C2 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 242
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Gases (petroleum), dry sour, gas-concn.-unit-off

[Refinery gas](Note: The complex combination of dry
gases from a gas concentration unit. It consists of F+; T
hydrogen, hydrogen sulfide and hydrocarbons having F+; R12 R: 45-46-12
carbon numbers predominantly in the range of C1 Carc. Cat. 1; R45 S: 53-45
68477-92-9 through C3.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), gas concn. reabsorber distn.

[Refinery gas](Note: A complex combination of
hydrocarbons produced by distillation of products
from combined gas streams in a gas concentration
reabsorber. It consists predominantly of hydrogen, F+; T
carbon monoxide, carbon dioxide, nitrogen, hydrogen F+; R12 R: 45-46-12
sulfide and hydrocarbons having carbon numbers in Carc. Cat. 1; R45 S: 53-45
68477-93-0 the range of C1 through C3.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), gas recovery plant depropanizer

overheads [Petroleum gas](Note: A complex
combination of hydrocarbons obtained by
fractionation of miscellaneous hydrocarbon streams. F+; T
It consists predominantly of hydrocarbons having F+; R12 R: 45-46-12
carbon numbers in the range of C1 through C4, Carc. Cat. 1; R45 S: 53-45
68477-94-1 predominantly propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), Girbotol unit feed [Petroleum

gas](Note: A complex combination of hydrocarbons
that is used as the feed into the Girbatol unit to F+; T
remove hydrogen sulfide. It consists of aliphatic F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68477-95-2 in the range of C2 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), hydrogen absorber off [Refinery
gas](Note: A complex combination obtained by
absorbing hydrogen from a hydrogen rich stream. It F+; T
consists of hydrogen, carbon monoxide, nitrogen, F+; R12 R: 45-46-12
and methane with small amounts of C2 Carc. Cat. 1; R45 S: 53-45
68477-96-3 hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), hydrogen-rich [Refinery
gas](Note: A complex combination separated as a
gas from hydrocarbon gases by chilling. It consists F+; T
primarily of hydrogen with various small amounts of F+; R12 R: 45-46-12
carbon monoxide, nitrogen, methane, and C2 Carc. Cat. 1; R45 S: 53-45
68477-97-4 hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), hydrotreater blend oil recycle,

hydrogen-nitrogen-rich [Refinery gas](Note: A
complex combination obtained from recycled
hydrotreated blend oil. It consists primarily of
hydrogen and nitrogen with various small amounts of F+; T
carbon monoxide, carbon dioxide and hydrocarbons F+; R12 R: 45-46-12
having carbon numbers predominantly in the range of Carc. Cat. 1; R45 S: 53-45
68477-98-5 C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Gases (petroleum), isomerized naphtha fractionator, Carc. Cat. 1; R45 S: 53-45
68477-99-6 C4-rich, hydrogen sulfide-free [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 243
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Gases (petroleum), recycle, hydrogen-rich [Refinery

gas](Note: A complex combination obtained from
recycled reactor gases. It consists primarily of
hydrogen with various small amounts of carbon F+; T
monoxide, carbon dioxide, nitrogen, hydrogen sulfide, F+; R12 R: 45-46-12
and saturated aliphatic hydrocarbons having carbon Carc. Cat. 1; R45 S: 53-45
68478-00-2 numbers in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), reformer make-up, hydrogen-rich

[Refinery gas](Note: A complex combination obtained
from the reformers. It consists primarily of hydrogen F+; T
with various small amounts of carbon monoxide and F+; R12 R: 45-46-12
aliphatic hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68478-01-3 predominantly in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), reforming hydrotreater [Refinery

gas](Note: A complex combination obtained from the
reforming hydrotreating process. It consists primarily
of hydrogen, methane, and ethane with various small F+; T
amounts of hydrogen sulfide and aliphatic F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68478-02-4 in the range of C3 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), reforming hydrotreater, hydrogen-

methane-rich [Refinery gas](Note: A complex
combination obtained from the reforming
hydrotreating process. It consists primarily of
hydrogen and methane with various small amounts of
carbon monoxide, carbon dioxide, nitrogen and F+; T
saturated aliphatic hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C2 through Carc. Cat. 1; R45 S: 53-45
68478-03-5 C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), reforming hydrotreater make-up,

hydrogen-rich [Refinery gas](Note: A complex
combination obtained from the reforming
hydrotreating process. It consists primarily of
hydrogen with various small amounts of carbon F+; T
monoxide and aliphatic hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68478-04-6 C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), thermal cracking distn. [Refinery

gas](Note: A complex combination produced by
distillation of products from a thermal cracking
process. It consists of hydrogen, hydrogen sulfide, F+; T
carbon monoxide, carbon dioxide and hydrocarbons F+; R12 R: 45-46-12
having carbon numbers predominantly in the range of Carc. Cat. 1; R45 S: 53-45
68478-05-7 C1 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Residues (petroleum), butane splitter bottoms [Low
boiling point naphtha — unspecified](Note: A
complex residuum from the distillation of butane T
stream. It consists of aliphatic hydrocarbons having Carc. Cat. 2; R45 R: 45-46-65
carbon numbers predominantly in the range of C4 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68478-12-6 through C6.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), catalytic reformer fractionator S: 53 - 45 ;
68478-13-7 residue distn. [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Residues (petroleum), C6-8 catalytic reformer [Low

boiling point cat-reformed naphtha](Note: A complex T
residuum from the catalytic reforming of C6-8 feed. It Carc. Cat. 2; R45 R: 45-46-65
consists of hydrocarbons having carbon numbers Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68478-15-9 predominantly in the range of C2 through C6.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 244
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Residual oils (petroleum), deisobutanizer tower [Low

boiling point naphtha — unspecified](Note: A
complex residuum from the atmospheric distillation of T
the butane-butylene stream. It consists of aliphatic Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons having carbon numbers predominantly Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68478-16-0 in the range of C4 through C6.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), heavy coker gas oil and S: 53 - 45 ;
68478-17-1 vacuum gas oil [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Tail gas (petroleum), catalytic cracked clarified oil

and thermal cracked vacuum residue fractionation
reflux drum [Petroleum gas](Note: A complex
combination of hydrocarbons obtained from
fractionation of catalytic cracked clarified oil and
thermal cracked vacuum residue. It consists F+; T
predominantly of hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68478-21-7 C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tail gas (petroleum), catalytic cracked naphtha
stabilization absorber [Petroleum gas](Note: A
complex combination of hydrocarbons obtained from
the stabilization of catalytic cracked naphtha. It F+; T
consists predominantly of hydrocarbons having F+; R12 R: 45-46-12
carbon numbers predominantly in the range of C1 Carc. Cat. 1; R45 S: 53-45
68478-22-8 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), catalytic cracker, catalytic

reformer and hydrodesulfurizer combined fractionater
[Petroleum gas](Note: A complex combination of
hydrocarbons obtained from the fractionation of
products from catalytic cracking, catalytic reforming
and hydrodesulfurizing processes treated to remove F+; T
acidic impurities. It consists predominantly of F+; R12 R: 45-46-12
hydrocarbons having cabon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68478-24-0 in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), catalytic cracker refractionation

absorber [Refinery gas](Note: A complex combination
of hydrocarbons obtained from refractionation of
products from a catalytic cracking process. It consists F+; T
of hydrogen and hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68478-25-1 C3.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), catalytic reformed naphtha

fractionation stabilizer [Petroleum gas](Note: A
complex combination of hydrocarbons obtained from
the fractionation stabilization of catalytic reformed F+; T
naphtha. It consists predominantly of hydrocarbons F+; R12 R: 45-46-12
having carbon numbers predominantly in the range of Carc. Cat. 1; R45 S: 53-45
68478-26-2 C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tail gas (petroleum), catalytic reformed naphtha
separator [Refinery gas](Note: A complex
combination of hydrocarbons obtained from the
catalytic reforming of straight run naphtha. It consists F+; T
of hydrogen and hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68478-27-3 C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 245
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Tail gas (petroleum), catalytic reformed naphtha

stabilizer [Refinery gas](Note: A complex combination
of hydrocarbons obtained from the stabilization of F+; T
catalytic reformed naphtha. It consists of hydrogen F+; R12 R: 45-46-12
and hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68478-28-4 predominantly in the range of C1 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), cracked distillate hydrotreater

separator [Refinery gas](Note: A complex
combination of hydrocarbons obtained by treating
cracked distillates with hydrogen in the presence of a F+; T
catalyst. It consists of hydrogen and saturated F+; R12 R: 45-46-12
aliphatic hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68478-29-5 predominantly in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tail gas (petroleum), hydrodesulfurized straight-run
naphtha separator [Refinery gas](Note: A complex
combination of hydrocarbons obtained from
hydrodesulfurization of straight-run naphtha. It F+; T
consists of hydrogen and saturated aliphatic F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68478-30-8 in the range of C1 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), saturate gas plant mixed

stream, C4-rich [Petroleum gas](Note: A complex
combination of hydrocarbons obtained from the
fractionation stabilization of straight-run naphtha,
distillation tail gas and catalytic reformed naphtha F+; T
stabilizer tail gas. It consists of hydrocarbons having F+; R12 R: 45-46-12
carbon numbers in the range of C3 through C6, Carc. Cat. 1; R45 S: 53-45
68478-32-0 predominantly butane and isobutane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), saturate gas recovery plant, C1-

2-rich [Petroleum gas](Note: A complex combination
of hydrocarbons obtained from fractionation of
distillate tail gas, straight-run naphtha, catalytic
reformed naphtha stabilizer tail gas. It consists F+; T
predominantly of hydrocarbons having carbon F+; R12 R: 45-46-12
numbers in the range of C1through C5, Carc. Cat. 1; R45 S: 53-45
68478-33-1 predominantly methane and ethane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), vacuum residues thermal

cracker [Petroleum gas](Note: A complex
combination of hydrocarbons obtained from the F+; T
thermal cracking of vacuum residues. It consists of F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68478-34-2 in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Xn; N ; R: 21/22 - 36 - 48/22
Xn: R21/22 - 50/53,
Xn: R48/22 S: (2) - 26 - 28 - 36/37/39 - Conc>=25%: Xn; R21/22; R48/22; R36
Diethylmethylbenzenediamine(Note: see also CAS Xi; R36 60 - 61; >=20%Conc<25%: Xn; R48/22; R36
68479-98-1 No 2095-01-4 & 2095-02-5) N; R50-53 Note: C >=10%Conc<20%: Xn; R48/22 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), heavy coker and light vacuum S: 53 - 45 ;
68512-61-8 [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
68512-62-9 Residues (petroleum), light vacuum [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 246
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Solvent naphtha (petroleum), light arom.,

hydrotreated [Low boiling point hydrogen treated
naphtha](Note: A complex combination of
hydrocarbons obtained by treating a petroleum
fraction with hydrogen in the presence of a catalyst. It
consists predominantly of aromatic hydrocarbons T
having carbon numbers predominantly in the range of Carc. Cat. 2; R45 R: 45-46-65
C8 through C10 and boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68512-78-7 approximately 135 °C to 210 °C (275 °F to 410 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C3-4-rich, petroleum distillate

[Petroleum gas](Note: A complex combination of
hydrocarbons produced by distillation and F+; T
condensation of crude oil. It consists of hydrocarbons F+; R12 R: 45-46-12
having carbon numbers in the range of C3 through Carc. Cat. 1; R45 S: 53-45
68512-91-4 C5, predominantly C3 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), full-range coker [Low boiling

point naphtha — unspecified](Note: A complex
combination of hydrocarbons produced by the
distillation of products from a fluid coker. It consists
predominantly of unsaturated hydrocarbons having T
carbon numbers predominantly in the range of C4 Carc. Cat. 2; R45 R: 45-46-65
through C15 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68513-02-0 43 °C to 250 °C (110 °F-500 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light catalytic reformed, arom.-

free [Low boiling point cat-reformed naphtha](Note: A
complex combination of hydrocarbons obtained from
distillation of products from a catalytic reforming
process. It consists predominantly of hydrocarbons
having carbon numbers predominantly in the range of
C5 through C8 and boiling in the range of
approximately 35 °C to 120 °C (95 °F to 248 °F). It T
contains a relatively large proportion of branched Carc. Cat. 2; R45 R: 45-46-65
chain hydrocarbons with the aromatic components Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68513-03-1 removed.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), catalytic reformed straight-run

naphtha stabilizer overheads [Refinery gas](Note: A
complex combination of hydrocarbons obtained from F+; T
the catalytic reforming of straight-run naphtha F+; R12 R: 45-46-12
followed by fractionation of the total effluent. It Carc. Cat. 1; R45 S: 53-45
68513-14-4 consists of hydrogen, methane, ethane and propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), full-range straight-run naphtha

dehexanizer off [Petroleum gas](Note: A complex
combination of hydrocarbons obtained by the F+; T
fractionation of the full-range straight-run naphtha. It F+; R12 R: 45-46-12
consists of hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68513-15-5 predominantly in the range of C2 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), hydrocracking depropanizer off,

hydrocarbon-rich [Petroleum gas](Note: A complex
combination of hydrocarbon produced by the
distillation of products from a hydrocracking process.
It consists predominantly of hydrocarbons having F+; T
carbon numbers predominantly in the range of C1 F+; R12 R: 45-46-12
through C4. It may also contain small amounts of Carc. Cat. 1; R45 S: 53-45
68513-16-6 hydrogen and hydrogen sulfide.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 247
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Gases (petroleum), light straight-run naphtha
stabilizer off [Petroleum gas](Note: A complex
combination of hydrocarbons obtained by the
stabilization of light straight-run naphtha. It consists F+; T
of saturated aliphatic hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C2 through Carc. Cat. 1; R45 S: 53-45
68513-17-7 C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), reformer effluent high-pressure

flash drum off [Refinery gas](Note: A complex
combination produced by the high-pressure flashing F+; T
of the effluent from the reforming reactor. It consists F+; R12 R: 45-46-12
primarily of hydrogen with various small amounts of Carc. Cat. 1; R45 S: 53-45
68513-18-8 methane, ethane, and propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), reformer effluent low-pressure

flash drum off [Refinery gas](Note: A complex
combination produced by low-pressure flashing of the F+; T
effluent from the reforming reactor. It consists F+; R12 R: 45-46-12
primarily of hydrogen with various small amounts of Carc. Cat. 1; R45 S: 53-45
68513-19-9 methane, ethane, and propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), catalytic reformed straight-run

naphtha overheads [Low boiling point cat-reformed
naphtha](Note: A complex combination of
hydrocarbons obtained by the catalytic reforming of
straight-run naphtha followed by the fractionation of T
the total effluent. It consists of saturated aliphatic Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons having carbon numbers predominantly Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68513-63-3 in the range of C2 through C6.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Residues (petroleum), alkylation splitter, C4-rich

[Petroleum gas](Note: A complex residuum from the
distillation of streams various refinery operations. It
consists of hydrocarbons having carbon numbers in F+; T
the range of C4 through C5, predominantly butane F+; R12 R: 45-46-12
and boiling in the range of approximately -11.7 °C to Carc. Cat. 1; R45 S: 53-45
68513-66-6 27.8 °C (11 °F to 82 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), steam cracked light [Heavy S: 53 - 45 ;
68513-69-9 fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T
R: 45-46
Carc. Cat. 2; R45 S: 53-45
68513-87-1 Tar bases, quinoline derivs. [Distillate Bases] Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gasoline, vapor-recovery [Low boiling point

naphtha](Note: A complex combination of
hydrocarbons separated from the gases from vapor
recovery systems by cooling. It consists of
hydrocarbons having carbon numbers predominantly T
in the range of C4 through C11 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately -20 °C to 196 °C(-4 °F to 384 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68514-15-8 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C1-4 [Petroleum gas](Note: A

complex combination of hydrocarbons provided by
thermal cracking and absorber operations and by
distillation of crude oil. It consists of hydrocarbons
having carbon numbers predominantly in the range of F+; T
C1 through C4 and boiling in the range of F+; R12 R: 45-46-12
approximately minus 164 °C to minus 0.5 °C (-263 °F Carc. Cat 1; R45 S: 53-45
68514-31-8 to 31 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 248
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Hydrocarbons, C1-4, sweetened [Petroleum

gas](Note: A complex combination of hydrocarbons
obtained by subjecting hydrocarbon gases to a
sweetening process to convert mercaptans or to
remove acidic impurities. It consists of hydrocarbons F+; T
having carbon numbers predominantly in the range of F+; R12 R: 45-46-12
C1 through C4 and boiling in the range of Carc. Cat. 1; R45 S: 53-45
68514-36-3 approximately -164 °C to -0.5 °C (-263 °F to 31 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Petroleum products, hydrofiner-powerformer

reformates [Low boiling point cat-reformed
naphtha](Note: The complex combination of T
hydrocarbons obtained in a hydrofiner-powerformer Carc. Cat. 2; R45 R: 45-46-65
process and boiling in a range of approximately 27 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68514-79-4 to 210 °C (80 °F to 410 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T
1,2-Benzenedicarboxylic acid di-C7-11-branched and Repr. Cat. 2; R61 R: 61-62 Conc>=5%: T; R61; R62
68515-42-4 linear alkylesters Repr. Cat. 3; R62 S: 53-45 >=0.5%Conc<5%: T; R61 Eu - - - - - - - -

Naphtha (petroleum), steam-cracked middle arom.

[Low boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons produced by
the distillation of products from a steam-cracking
process. It consists predominantly of aromatic
hydrocarbons having carbon numbers predominantly T
in the range of C7 through C12 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 130 °C to 220 °C (266 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68516-20-1 428 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), oil refinery gas distn. off [Refinery

gas](Note: A complex combination separated by
distillation of a gas stream containing hydrogen,
carbon monoxide, carbon dioxide and hydrocarbons
having carbon numbers in the range of C1 through
C6 or obtained by cracking ethane and propane. It F+; T
consists of hydrocarbons having carbon numbers F+; R12 R: 45-46-12
predominantly in the range of C1 through C2, Carc. Cat. 1; R45 S: 53-45
68527-15-1 hydrogen, nitrogen, and carbon monoxide.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C1-3 [Petroleum gas](Note: A

complex combination of hydrocarbons having carbon F+; T
numbers predominantly in the range of C1 through F+; R12 R: 45-46-12
C3 and boiling in the range of approximately minus Carc. Cat. 1; R45 S: 53-45
68527-16-2 164 °C to minus 42 °C (-263 °F to -44 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Gas oils (petroleum), steam cracked [Cracked S: 53 - 45 ;
68527-18-4 gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Hydrocarbons, C1-4, debutanizer fraction [Petroleum Carc. Cat. 1; R45 S: 53-45
68527-19-5 gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 249
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), clay-treated full-range straight-

run [Low boiling point naphtha — unspecified](Note:
A complex combination of hydrocarbons resulting
from treatment of full-range straight-run naphtha with
natural or modified clay, usually in a percolation
process to remove the trace amounts of polar
compounds and impurities present. It consists of
hydrocarbons having carbon numbers predominantly T
in the range of C4 through C11 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately -20 °C to 220 °C (-4 °F to 429 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68527-21-9 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), clay-treated light straight-run

[Low boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons resulting from
treatment of light straight-run naphtha with a natural
or modified clay, usually in a percolation process to
remove the trace amounts of polar compounds and
impurities present. It consists of hydrocarbons having T
carbon numbers predominantly in the range of C7 Carc. Cat. 2; R45 R: 45-46-65
through C10 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68527-22-0 93 °C to 180 °C (200 °F to 356 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light steam-cracked arom. [Low

boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons produced by
distillation of products from a steam-cracking
process. It consists predominantly of aromatic
hydrocarbons having carbon numbers predominantly T
in the range of C7 through C9 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 110 °C to 165 °C (230 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68527-23-1 329 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light steam-cracked,

debenzenized [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons produced by distillation of products
from a steam-cracking process. It consists
predominantly of hydrocarbons having carbon T
numbers predominantly in the range of C4 through Carc. Cat. 2; R45 R: 45-46-65
C12 and boiling in the range of approximately 80 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68527-26-4 to 218 °C (176 °F to 424 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), full-range alkylate, butane-

contg. [Low boiling point modified naphtha](Note: A
complex combination of hydrocarbons produced by
the distillation of the reaction products of isobutane
with monoolefinic hydrocarbons usually ranging in
carbon numbers from C3 through C5. It consists of
predominantly branched chain saturated
hydrocarbons having carbon numbers predominantly T
in the range of C7 through C12 with some butanes Carc. Cat. 2; R45 R: 45-46-65
and boiling in the range of approximately 35 °C to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68527-27-5 200 °C (95 °F to 428 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Oxirane, 2-methyl-, polymer with oxirane, mono-C10- C Conc>=10%: C; R34
68551-05-3 12-alkyl ethers, phosphates C; R34 R: 34 >=5%Conc<10%: Xi; R36/38 N - - - - - - - -

Page 250
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Alcohols, C12-16, ethoxylated(Note: Polymeric

substances may be placed on the market with a
range of molecular weights which will affect the
toxicological properties of the substance. The
classifications need not apply if it can be shown that
the substance placed on the market does not meet
the criteria for classification; note 2: The classification Conc>=25%: Xn; R22; R38; R41
for skin irritation need not apply if it can be shown >=20%Conc<25%: Xi; R38; R41
that there are less than four or more than 21 Xn; R22 Xn >=10%Conc<20%: Xi; R41
68551-12-2 ethoxylate units) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
68553-00-4 Fuel oil No. 6 [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
68553-63-9 Oils, fish, lead salts R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Tar acids, cresylic, residues [Distillate Phenols](Note:

The residue from crude coal tar acids after removal
of phenol, cresols, xylenols and any higher boiling T
phenols. A black solid with a melting point R: 45-46
approximately 80 °C (176 °F). Composed primarily of Carc. Cat. 2; R45 S: 53-45
68555-24-8 polyalkylphenols, resin gums, and inorganic salts.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, C10-16-alkyl derivatives, Xn; R22 Xn >=10%Conc<20%: Xi; R41
68584-27-0 potassium salts Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Gases (petroleum), benzene unit hydrotreater

depentanizer overheads [Refinery gas](Note: A
complex combination produced by treating the feed
from the benzene unit with hydrogen in the presence
of a catalyst followed by depentanizing. It consists
primarily of hydrogen, ethane and propane with
various small amounts of nitrogen, carbon monoxide, F+; T
carbon dioxide and hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68602-82-4 C6. It may contain trace amounts of benzene.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), C1-5, wet [Petroleum gas](Note:

A complex combination of hydrocarbons produced by
the distillation of crude oil and/or the cracking of F+; T
tower gas oil. It consists of hydrocarbons having F+; R12 R: 45-46-12
carbon numbers predominantly in the range of C1 Carc. Cat. 1; R45 S: 53-45
68602-83-5 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), secondary absorber off, fluidized

catalytic cracker overheads fractionator [Refinery
gas](Note: A complex combination produced by the
fractionation of the overhead products from the
catalytic cracking process in the fluidized catalytic F+; T
cracker. It consists of hydrogen, nitrogen, and F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68602-84-6 in the range of C1 through C3.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 251
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Distillates (petroleum), thermal cracked naphtha and

gas oil [Low boiling point thermally cracked
naphtha](Note: A complex combination of
hydrocarbons produced by distillation of thermally
cracked naphtha and/or gas oil. It consists T
predominantly of olefinic hydrocarbons having a Carc. Cat. 2; R45 R: 45-46-65
carbon number of C5 and boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68603-00-9 approximately 33 °C to 60 °C (91 °F to 140 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), thermal cracked naphtha and

gas oil, C5-dimer-contg. [Low boiling point thermally
cracked naphtha](Note: A complex combination of
hydrocarbons produced by the extractive distillation
of thermal cracked naphtha and/or gas oil. It consists
predominantly of hydrocarbons having a carbon T
number of C5 with some dimerized C5 olefins and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately 33 °C to 184 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68603-01-0 (91 °F to 363 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), thermal cracked naphtha and

gas oil, extractive [Low boiling point thermally
cracked naphtha](Note: A complex combination of
hydrocarbons produced by the extractive distillation
of thermal cracked naphtha and/or gas oil.. It consists
of paraffinic and olefinic hydrocarbons, predominantly T
isoamylenes such as 2-methyl-1-butene and 2-methyl- Carc. Cat. 2; R45 R: 45-46-65
2-butene and boiling in the range of approximately 31 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68603-03-2 °C to 40 °C (88 °F to 104 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T
Carc. Cat. 2; R45 R: 45-46-65
Naphtha (petroleum), arom.-contg. [Low boiling point Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68603-08-7 naphtha — unspecified] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Alcohols, C8-10, ethoxylated propoxylated(Note:

Polymeric substances may be placed on the market
with a range of molecular weights which will affect the
toxicological properties of the substance. The
classifications need not apply if it can be shown that
the substance placed on the market does not meet
the criteria for classification; note 2: The classification Conc>=25%: Xn; R22; R38; R41
for skin irritation need not apply if it can be shown >=20%Conc<25%: Xi; R38; R41
that there are less than four or more than 21 Xn; R22 Xn >=10%Conc<20%: Xi; R41
68603-25-8 ethoxylate units) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
68605-98-1 Fatty acids, tallow, hydrogenated, lead salts R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Gasoline, pyrolysis, debutanizer bottoms [Low boiling
point naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained from the T
fractionation of depropanizer bottoms. It consists of Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons having carbon numbers predominantly Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68606-10-0 greater than C5.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Gasoline, straight-run, topping-plant [Low boiling

point naphtha](Note: A complex combination of T
hydrocarbons produced from the topping plant by the Carc. Cat. 2; R45 R: 45-46-65
distillation of crude oil. It boils in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68606-11-1 approximately 36.1 °C to 193.3 °C (97 °F to 380 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 252
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F+; T
F+; R12 R: 45-46-12
Carc. Cat. 1; R45 S: 53-45
68606-25-7 Hydrocarbons, C2-4 [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Carc. Cat. 1; R45 S: 53-45
68606-26-8 Hydrocarbons, C3 [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), alkylation feed [Petroleum

gas](Note: A complex combination of hydrocarbons F+; T
produced by the catalytic cracking of gas oil. It F+; R12 R: 45-46-12
consists of hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68606-27-9 predominantly in the range of C3 through C4.]) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), depropanizer bottoms

fractionation off [Petroleum gas](Note: A complex F+; T
combination of hydrocarbons obtained from the F+; R12 R: 45-46-12
fractionation of depropanizer bottoms. It consists Carc. Cat. 1; R45 S: 53-45
68606-34-8 predominantly of butane, isobutane and butadiene.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Petroleum products, refinery gases [Refinery F+; T

gas](Note: A complex combination which consists F+; R12 R: 45-46-12
primarily of hydrogen with various small amounts of Carc. Cat. 1; R45 S: 53-45
68607-11-4 methane, ethane, and propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), topping plant, low sulfur S: 53 - 45 ;
68607-30-7 [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Oxirane, mono[(C12-14-alkyloxy)methyl] derivatives Xi; R38 Xi ; R: 38 - 43, Conc>=20%: Xi; R38; R43
68609-97-2 [Alkyl (C12-14) glycidyl ether] R43 S: (2) - 24 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Conc>=10%: T+; R40; R61; R62; R26/27/28;

R48/23/25
>=7%Conc<10%: T+; R40; R61; R62;
R26/27/28; R48/20/22
>=5%Conc<7%: T; R40; R61; R62; R23/24/25;
Carc. Cat. 3; R40 R48/20/22
Repr. Cat. 1; R61 >=1%Conc<5%: T; R40; R61; R23/24/25;
Repr. Cat. 3; R62 T+ R48/20/22
T+; R26/27/28 R: 61-26/27/28-40-48/23/25- >=0.5%Conc<1%: T; R61; R20/21/22
68610-17-3 Plumbane, ethyl methyl derivatives T; R48/23/25 62 >=0.1%Conc<0.5%: X N - - - - - - - -

1,2-Dihydro-6-hydroxy-4-methyl-1-[3-(1- Xi ; R: 43
68612-94-2 methylethoxy)propyl]-2-oxo-3-pyridinecarbonitrile R43 S: (2)24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Extracts (petroleum), heavy naphthenic distillate T ; R: 45 ,
solvent, arom. conc [Distillate aromatic extract S: 53 - 45 ;
68783-00-6 (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Extracts (petroleum), solvent refined heavy paraffinic S: 53 - 45 ;
68783-04-0 distillate solvent [Distillate aromatic extract (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Gases (petroleum), hydrocracking low-pressure

separator [Refinery gas](Note: A complex
combination obtained by the liquid-vapor separation
of the hydrocracking process reactor effluent. It F+; T
consists predominantly of hydrogen and saturated F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68783-06-2 in the range of C1 through C3.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), refinery blend [Petroleum

gas](Note: A complex combination obtained from F+; T
various processes. It consists of hydrogen, hydrogen F+; R12 R: 45-46-12
sulfide and hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68783-07-3 predominantly in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 253
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 45 ,
Gas oils (petroleum), heavy atmospheric [Heavy fuel S: 53 - 45 ;
68783-08-4 oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Naphtha (petroleum), catalytic cracked light distd.

[Low boiling point cat-cracked naphtha](Note: A
complex combination of hydrocarbons produced by
the distillation of products from a catalytic cracking T
process. It consists of hydrocarbons having carbon Carc. Cat. 2; R45 R: 45-46-65
numbers predominantly in the range of C1 through Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68783-09-5 C5.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), unsweetened [Low boiling point

naphtha](Note: A complex combination of
hydrocarbons produced from the distillation of
naphtha streams from various refinery processes It
consists of hydrocarbons having carbon numbers T
predominantly in the range of C5 through C12 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately 0 °C to 230 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68783-12-0 (25 °F to 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), coker scrubber, condensed S: 53 - 45 ;
68783-13-1 ring arom. contg. [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Gases (petroleum), catalytic cracking [Petroleum

gas](Note: A complex combination of hydrocarbons
produced by the distillation of the products from a F+; T
catalytic cracking process. It consists predominantly F+; R12 R: 45-46-12
of hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68783-64-2 predominantly in the range of C3 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), C2-4, sweetened [Petroleum

gas](Note: A complex combination of hydrocarbons
obtained by subjecting a petroleum distillate to a
sweetening process to convert mercaptans or to
remove acidic impurities. It consists predominantly of
saturated and unsaturated hydrocarbons having F+; T
carbon numbers predominantly in the range of C2 F+; R12 R: 45-46-12
through C4 and boiling in the range of approximately - Carc. Cat. 1; R45 S: 53-45
68783-65-3 51 °C to -34 °C (-60 °F to -30 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light, sweetened [Low boiling

point naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained by subjecting
a petroleum distillate to a sweetening process to
convert mercaptans or to remove acidic impurities. It
consists predominantly of saturated and unsaturated
hydrocarbons having carbon numbers predominantly T
in the range of C3 through C6 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately -20 °C to 100 °C (-4 °F to 212 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68783-66-4 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Constitutional isomers of: penta-O-allyl-beta-D-
fructofuranosyl-alpha-D-glucopyranoside and hexa-O-
allyl-beta-D-fructofuranosyl-alpha-D-glucopyranoside Xn
and hepta-O-allyl-beta-D-fructofuransoyl-alpha-D- R: 22
68784-14-5 glucopyranoside Xn; R22 S: (2-) Conc>=25%: Xn; R22 Eu - - - - - - - -

Phenol, dodecyl-, sulfurized, carbonates, calcium

salts(Note: The classification for reproductive toxicity
need not apply if it can be shown that the substance
contains less than 0.5 % unreacted tetrapropenyl Xn
68784-25-8 phenol (TPP)/CaTPP.) Repr. Cat. 3; R62 R: 62 Conc>=5%: Xn; R62 N - - - - - - - -

Page 254
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Phenol, dodecyl-, sulfurized, carbonates, calcium

salts, overbased(Note: The classification for
reproductive toxicity need not apply if it can be shown
that the substance contains less than 0.5 % Xn
68784-26-9 unreacted tetrapropenyl phenol (TPP)/CaTPP.) Repr. Cat. 3; R62 R: 62 Conc>=5%: Xn; R62 N - - - - - - - -
Conc>=10%: T; R48/25
68786-66-3 Triclabendazole T; R48/25 T ; 48/25 >=1%Conc<10%: Xn; R48/22 V - - - - - - - -
68797-31-9 Econazole nitrate Xn; R22 Xn ; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -

Gases (petroleum), refinery [Refinery gas](Note: A

complex combination obtained from various F+; T
petroleum refining operations. It consists of hydrogen F+; R12 R: 45-46-12
and hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68814-67-5 predominantly in the range of C1 through C3.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Extracts (petroleum), heavy paraffinic distillates, T ; R: 45 ,
solvent deasphalted [Distillate aromatic extract S: 53 - 45 ;
68814-89-1 (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Gases (petroleum), platformer products separator off

[Refinery gas](Note: A complex combination obtained
from the chemical reforming of naphthenes to F+; T
aromatics. It consists of hydrogen and saturated F+; R12 R: 45-46-12
aliphatic hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68814-90-4 predominantly in the range of C2 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T
R: 45-46
Tar acids, cresylic, sodium salts, caustic solns. Carc. Cat. 2; R45 S: 53-45
68815-21-4 [Alkaline Extract] Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Phenol, dodecyl-, sulfurized, calcium salts(Note: The
classification for reproductive toxicity need not apply
if it can be shown that the substance contains less
than 0.5 % unreacted tetrapropenyl phenol Xn
68855-45-8 (TPP)/CaTPP.) Repr. Cat. 3; R62 R: 62 Conc>=5%: Xn; R62 N - - - - - - - -

O; R7 O; Xi; N
R43 R: 7-43-50/53
68860-54-8 1,1-Dimethylpropyl 3,5,5-trimethylperoxyhexanoate N; R50-53 S: (2-)3-14-36/37/39-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, mono-C10-16-alkyl derivatives, Xn; R22 Xn >=10%Conc<20%: Xi; R41
68910-31-6 ammonium salts Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, mono-C10-16-alkyl derivatives, Xn; R22 Xn >=10%Conc<20%: Xi; R41
68910-32-7 compounds with 2-aminoethanol Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Gases (petroleum), hydrotreated sour kerosine

depentanizer stabilizer off [Refinery gas](Note: The
complex combination obtained from the depentanizer
stabilization of hydrotreated kerosine. It consists
primarily of hydrogen, methane, ethane, and propane
with various small amounts of nitrogen, hydrogen F+; T
sulfide, carbon monoxide and hydrocarbons having F+; R12 R: 45-46-12
carbon numbers predominantly in the range of C4 Carc. Cat. 1; R45 S: 53-45
68911-58-0 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 255
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Gases (petroleum), hydrotreated sour kerosine flash

drum [Refinery gas](Note: A complex combination
obtained from the flash drum of the unit treating sour
kerosine with hydrogen in the presence of a catalyst.
It consists primarily of hydrogen and methane with F+; T
various small amounts of nitrogen, carbon monoxide, F+; R12 R: 45-46-12
and hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68911-59-1 predominantly in the range of C2 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), crude oil fractionation off
[Petroleum gas](Note: A complex combination of
hydrocarbons produced by the fractionation of crude F+; T
oil. It consists of saturated aliphatic hydrocarbons F+; R12 R: 45-46-12
having carbon numbers predominantly in the range of Carc. Cat. 1; R45 S: 53-45
68918-99-0 C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), dehexanizer off [Petroleum

gas](Note: A complex combination of hydrocarbons
obtained by the fractionation of combined naphtha F+; T
streams. It consists of saturated aliphatic F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68919-00-6 in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), distillate unifiner desulfurization

stripper off [Refinery gas](Note: A complex F+; T
combination stripped from the liquid product of the F+; R12 R: 45-46-12
unifiner desulfurization process. It consists of Carc. Cat. 1; R45 S: 53-45
68919-01-7 hydrogen sulfide, methane, ethane, and propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), fluidized catalytic cracker

fractionation off [Refinery gas](Note: A complex
combination produced by the fractionation of the
overhead product of the fluidized catalytic cracking F+; T
process. It consists of hydrogen, hydrogen sulfide, F+; R12 R: 45-46-12
nitrogen, and hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68919-02-8 predominantly in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), fluidized catalytic cracker
scrubbing secondary absorber off [Refinery
gas](Note: A complex combination produced by F+; T
scrubbing the overhead gas from the fluidized F+; R12 R: 45-46-12
catalytic cracker. It consists of hydrogen, nitrogen, Carc. Cat. 1; R45 S: 53-45
68919-03-9 methane, ethane and propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), heavy distillate hydrotreater

desulfurization stripper off [Refinery gas](Note: A
complex combination stripped from the liquid product
of the heavy distillate hydrotreater desulfurization
process. It consists of hydrogen, hydrogen sulfide, F+; T
and saturated aliphatic hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68919-04-0 C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), light straight run gasoline

fractionation stabilizer off [Petroleum gas](Note: A
complex combination of hydrocarbons obtained by
the fractionation of light straight-run gasoline. It F+; T
consists of saturated aliphatic hydrocarbons having F+; R12 R: 45-46-12
carbon numbers predominantly in the range of C1 Carc. Cat. 1; R45 S: 53-45
68919-05-1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 256
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Gases (petroleum), naphtha unifiner desulfurization

stripper off [Petroleum gas](Note: A complex
combination of hydrocarbons produced by a naphtha
unifiner desulfurization process and stripped from the F+; T
naphtha product. It consists of saturated aliphatic F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68919-06-2 in the range of C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), platformer stabilizer off, light

ends fractionation [Refinery gas](Note: A complex F+; T
combination obtained by the fractionation of the light F+; R12 R: 45-46-12
ends of the platinum reactors of the platformer unit. It Carc. Cat. 1; R45 S: 53-45
68919-07-3 consists of hydrogen, methane, ethane and propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), preflash tower off, crude distn.

[Refinery gas](Note: A complex combination
produced from the first tower used in the distillation of F+; T
crude oil. It consists of nitrogen and saturated F+; R12 R: 45-46-12
aliphatic hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68919-08-4 predominantly in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), straight-run naphtha catalytic
reforming off [Petroleum gas](Note: A complex
combination of hydrocarbons obtained by the F+; T
catalytic reforming of straight-run naphtha and F+; R12 R: 45-46-12
fractionation of the total effluent. It consists of Carc. Cat. 1; R45 S: 53-45
68919-09-5 methane, ethane, and propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), straight-run stabilizer off

[Petroleum gas](Note: A complex combination of
hydrocarbons obtained from the fractionation of the
liquid from the first tower used in the distillation of F+; T
crude oil. It consists of saturated aliphatic F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68919-10-8 in the range of C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), tar stripper off [Refinery

gas](Note: A complex combination obtained by the F+; T
fractionation of reduced crude oil. It consists of F+; R12 R: 45-46-12
hydrogen and hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68919-11-9 predominantly in the range of C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), unifiner stripper off [Refinery F+; T

gas](Note: A combination of hydrogen and methane F+; R12 R: 45-46-12
obtained by fractionation of the products from the Carc. Cat. 1; R45 S: 53-45
68919-12-0 unifiner unit.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), fluidized catalytic cracker splitter

overheads [Petroleum gas](Note: A complex F+; T
combination of hydrocarbons produced by the F+; R12 R: 45-46-12
fractionation of the charge to the C3 -C4 splitter. It Carc. Cat. 1; R45 S: 53-45
68919-20-0 consists predominantly of C3 hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), full-range reformed [Low boiling

point cat-reformed naphtha](Note: A complex
combination of hydrocarbons produced by the
distillation of the products from a catalytic reforming
process. It consists of hydrocarbons having carbon T
numbers predominantly in the range of C5 through Carc. Cat. 2; R45 R: 45-46-65
C12 and boiling in the range of approximately 35 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68919-37-9 to 230 °C (95 °F to 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Natural gas condensates [Low boiling point naphtha

— unspecified](Note: A complex combination of
hydrocarbons separated and/or condensed from
natural gas during transportation and collected at the
wellhead and/or from the production, gathering,
transmission, and distribution pipelines in deeps, T
scrubbers, etc. It consists predominantly of Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons having carbon numbers predominantly Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68919-39-1 in the range of C2 through C8.) Xn; R65 Notes: H ; J >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), light straight-run gasoline

fractionation stabilizer overheads [Low boiling point
naphtha](Note: A complex combination of
hydrocarbons obtained by the fractionation of light T
straight-run gasoline. It consists of saturated aliphatic Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons having carbon numbers predominantly Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68921-08-4 in the range of C3 through C6.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), naphtha unifiner stripper [Low

boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons produced by
stripping the products from the naphtha unifiner. It T
consists of saturated aliphatic hydrocarbons having Carc. Cat. 2; R45 R: 45-46-65
carbon numbers predominantly in the range of C2 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68921-09-5 through C6.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Extract oils (coal), tar base, collidine fraction

[Distillate Bases](Note: The extract produced by the
acidic extraction of bases from crude coal tar T
aromatic oils, neutralization, and distillation of the R: 45-46
bases. Composed primarily of collidines, aniline, Carc. Cat. 2; R45 S: 53-45
68937-63-3 toluidines, lutidines, xylidines.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), catalytic cracked naphtha

debutanizer [Petroleum gas](Note: A complex
combination of hydrocarbons obtained from F+; T
fractionation of catalytic cracked naphtha. It consists F+; R12 R: 45-46-12
of hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
68952-76-1 predominantly in the range of C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tail gas (petroleum), catalytic cracked distillate and
naphtha stabilizer [Petroleum gas](Note: A complex
combination of hydrocarbons obtained by the
fractionation of catalytic cracked naphtha and F+; T
distillate. It consists predominantly of hydrocarbons F+; R12 R: 45-46-12
having carbon numbers predominantly in the range of Carc. Cat. 1; R45 S: 53-45
68952-77-2 C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), catalytic hydrodesulfurized

naphtha separator [Refinery gas](Note: A complex F+; T
combination of hydrocarbons obtained from the F+; R12 R: 45-46-12
hydrodesulfurization of naphtha. It consists of Carc. Cat. 1; R45 S: 53-45
68952-79-4 hydrogen, methane, ethane, and propane.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), straight-run naphtha

hydrodesulfurizer [Refinery gas](Note: A complex
combination obtained from the hydrodesulfurization F+; T
of straight-run naphtha. It consists of hydrogen and F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68952-80-7 in the range of C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Tail gas (petroleum), thermal-cracked distillate, gas

oil and naphtha absorber [petroleum gas](Note: A
complex combination of hydrocarbons obtained from
the separation of thermal-cracked distillates, naphtha F+; T
and gas oil. It consists predominantly of F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68952-81-8 in the range of C1 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tail gas (petroleum), thermal cracked hydrocarbon

fractionation stabilizer, petroleum coking [Petroleum
gas](Note: A complex combination of hydrocarbons
obtained from the fractionation stabilization of
thermal cracked hydrocarbons from petroleum coking F+; T
process. It consists of hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
68952-82-9 C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
68953-39-9 Fatty acids, tallow, hydrogenated, cadmium salts Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), petroleum residues vacuum S: 53 - 45 ;
68955-27-1 [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Gases (petroleum, light steam-cracked, butadiene

conc. [Petroleum gas](Note: A complex combination
of hydrocarbons produced by the distillation of F+; T
products from a thermal cracking process. It consists F+; R12 R: 45-46-12
of hydrocarbons having a carbon number Carc. Cat. 1; R45 S: 53-45
68955-28-2 predominantly of C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Distillates (petroleum), light thermal cracked,
debutanized arom. [Low boiling point thermally
cracked naphtha](Note: A complex combination of
hydrocarbons produced by the distillation of products T
from a thermal cracking process. It consists Carc. Cat. 2; R45 R: 45-46-65
predominantly of aromatic hydrocarbons, primarily Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68955-29-3 benzene.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), sponge absorber off, fluidized

catalytic cracker and gas oil desulfurizer overhead
fractionation [Refinery gas](Note: A complex
combination obtained by the fractionation of products
from the fluidized catalytic cracker and gas oil F+; T
desulfurizer. It consists of hydrogen and F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68955-33-9 in the range of C1 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), straight-run naphtha catalytic

reformer stabilizer overhead [Petroleum gas](Note: A
complex combination of hydrocarbons obtained by
the catalytic reforming of straight-run naphtha and the
fractionation of the total effluent. It consists of F+; T
saturated aliphatic hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C2 through Carc. Cat. 1; R45 S: 53-45
68955-34-0 C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 259
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), catalytic reformed [Low boiling

point cat-reformed naphtha](Note: A complex
combination of hydrocarbons produced by the
distillation of products from a catalytic reforming
process. It consists of hydrocarbons having carbon
numbers predominantly in the range of C4 through
C12 and boiling in the range of approximately 30 °C
to 220 °C (90 °F to 430 °F). It contains a relatively T
large proportion of aromatic and branched chain Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons. This stream may contain 10 vol. % or Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
68955-35-1 more benzene.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), steam cracked, resinous S: 53 - 45 ;
68955-36-2 [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Vegetable oil mists

(except castor oil,
Vegetable oil mists (except castor oil, cashew nut or cashew nut or
68956-68-3 similar irritant oils) A similar irritant oils) - 10 - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
68956-81-0 Resin acids and rosin acids, cadmium salts Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

2,4,6-Tri-n-propyl-2,4,6-trioxo-1,3,5,2,4,6- C R: 34 Conc>=10%: C; R34

68957-94-8 trioxatriphosphorinane C; R34 S: (1/2-)26-36/37/39-45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -

Gases (petroleum), crude distn. and catalytic

cracking [Refinery gas](Note: A complex combination
produced by crude distillation and catalytic cracking
processes. It consists of hydrogen, hydrogen sulfide, F+; T
nitrogen, carbon monoxide and paraffinic and olefinic F+; R12 R: 45-46-12
hydrocarbons having carbon numbers predominantly Carc. Cat. 1; R45 S: 53-45
68989-88-8 in the range of C1 through C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Tar, coal, high temp., high solids [Coal tar solids S: 53 - 45 ;
68990-61-4 residue] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68
Repr. Cat. 1; R61 Conc>=25%: T; R40; R61; R62; R68; R20; R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20 T >=1%Conc<5%: T; R40; R61; R68; R33
69011-06-9 Lead, [1,2-benzenedicarboxylato(2-)]dioxotri- R33 R: 61-20-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
R10
Xi; R43 Xi ; R: 10 - 43 - 52/53 ,
69045-82-5 2-Fluoro-5-trifluoromethylpyridine R52-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R20/22
Xi; R41 Xn; N
R43 R: 20/22 - 41 - 43 - 51/53 Conc>=10%: Xn; R20/22; R41; R43
69045-84-7 2,3-Dichloro-5-trifluoromethyl-pyridine N; R51-53 S: (2)24 - 26 - 37/39 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
E; R2
Carc. Cat. 3; R40 E; C; N
Xn; R22-48/22 R: 2-22-35-40-43-48/22-
C; R35 50/53 Conc>=10%: C; R40; R35; R22; R48/22; R43
R43 S: (1/2-)23-26-35-36/37/39- >=5%Conc<10%: C; R40; R34; R43
69094-18-4 2,2-Dibromo-2-nitroethanol N; R50-53 45-60-61 >=1%Conc<5%: Xn; R40; R36/37/38; R43 Eu - - - - - - - -

Page 260
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
69121-20-6 Octadecanoic acid, 12-hydroxy-, cadmium salt (2:1) Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Methyl O-(4-amino-3,5-dichloro-6-fluoropyridin-2- N ; R: 51/53
69184-17-4 yloxy)acetate N; R51-53 S: 20/21 - 61 Eu - - - - - - - -
Benzenesulfonic acid, dodecyl-, branched, sodium Xn; R22 Xn Conc>=25%: Xn; R22; R36/38
69227-09-4 salt Xi; R36/38 R: 22-36/38 >=20%Conc<25%: Xi; R36/38 N - - - - - - - -
Xn ; R: 68
69227-51-6 1-Ethyl-1-methylpyrrolidinium bromide Muta. Cat. 3; R68 S: (2)36/37 Conc>=1%: Xn; R68 Eu - - - - - - - -
Poly(oxy-1,2-ethanediyl), alpha-isohexadecyl-omega- Xi
69364-63-2 hydroxy- Xi; R36/38 R: 36/38 Conc>=20%: Xi; R36/38 N - - - - - - - -
Fluroxypyr (ISO) [4-Amino-3,5-dichloro-6-fluoro-2- R: 52/53,
69377-81-7 pyridyloxyacetic acid] R52-53 S: 61 Eu - - - - - - - -

alpha-Trimethylsilanyl-omega-trimethylsiloxypoly[oxy-
(methyl-3-(2-(2-metho xypropoxy)propoxy)- R: 53
69430-40-6 propylsilanediyl]-co-oxy(dimethylsilane)) R53 S: 61 Eu - - - - - - - -
T; R25
N-(3-Chlorophenyl)-N-(tetrahydro-2-oxo-3- Xn; R21 T ; N ; R: 21 - 25 - 50/53, Conc>=25%: T; R25; R21
69581-33-5 furyI)cyclopropanecarboxamide [Cyprofuram] N; R50-53 S: (1/2) - 36/37 - 60 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, C10-14-alkyl derivatives, Xn; R22 Xn >=10%Conc<20%: Xi; R41
69669-44-9 sodium salts Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Conc>=25%: T; R25
69770-45-2 Flumethrin T; R25 T ; R: 25 >=3%Conc<25%: Xn; R22 V - - - - - - - -
R43 Xi ; N ; R: 43 - 51/53
69788-75-6 4-Chlorobutyl veratrate N; R51-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Fluazifop-butyl (ISO) [Butyl (RS)-2-[4-(5- Repr. Cat. 2; R61 T ; N ; R: 61 - 50/53

69806-50-4 trifluoromethyl-2-pyridyloxy)phenoxy]propionate] N; R50-53 S: 53 - 45 - 60 - 61 Conc>=0.5%: T; R61 Eu - - - - - - - -

Carc. Cat. 3; R40

Repr. Cat. 2; R61 T; N Conc>=25%: T; R40; R61; R64; R20/22;
T; R48/25 R: 61-20/22-40-48/25-64- R48/25
Diethanolamine perfluorooctane sulfonate(Note: see Xn; R20/22 51/53 >=10%Conc<25%: T; R40; R61; R64; R48/25
also CAS No. 1763-23-1, 2795-39-3, 29081-56-9, R64 S: 53-45-61 >=1%Conc<10%: T; R40; R61; R64; R48/22
70225-14-8 29457-72-5) N; R51-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Conc>=20%: Xi; R38; R41; R43
Xi; R38-41 Xi ; N ; R: 38 - 41 - 43 - >=10%Conc<20%: Xi; R41; R43
R43 50/53 >=5%Conc<10%: Xi; R36; R43
70264-94-7 Methyl 4-bromomethyl-3-methoxybenzoate N; R50-53 S: (2)26 - 36/37/39 - 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Conc >=25%: T+; R61; R64; R28, R24
>=7%Conc<25%: T+; R61; R64; R28, R21
Repr. Cat. 2; R61 >=3%Conc<7%: T; R61; R64; R25, R21
R64 >=1%Conc<3%: T; R61; R64; R25
T+; R28 >=0.5%Conc<1%: T; R61; R22
70288-86-7 Ivermectin T; R24 T+ ; R: 61 - 24 - 28 - 64 >=0.1%Conc<0.5%: Xn; R22 V - - - - - - - -
T
R: 45-46
Tar bases, coal, quinoline derivs. fraction [Distillate Carc. Cat. 2; R45 S: 53-45
70321-67-4 Bases] Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 261
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Creosote oil, high-boiling distillate [Wash Oil](Note:

The high-boiling distillation fraction obtained from the
high temperature carbonization of bituminous coal
which is further refined to remove excess crystalline
salts. It consists primarily of creosote oil with some of T
the normal polynuclear aromatic salts, which are R: 45
components of coal tar distillates, removed. It is S: 53-45
70321-79-8 crystal free at approximately 5 °C (41 °F).) Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Creosote oil, low-boiling distillate [Wash Oil](Note:

The low-boiling distillation fraction obtained from the
high temperature carbonization of bituminous coal,
which is further refined to remove excess crystalline
salts. It consists primarily of creosote oil with some of T
the normal polynuclear aromatic salts, which are R: 45
components of coal tar distillate, removed. It is S: 53-45
70321-80-1 crystal free at approximately 38 °C (100 °F).) Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
Xi
Xi; R41 R R: 41-52/53 Conc>=10%: Xi; R41
70445-33-9 3-(2-Ethylhexyloxy)propane-1,2-diol 52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T ; R: 45 ,
Distillate (petroleum), intermediate vacuum [Heavy S: 53 - 45 ;
70592-76-6 fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
70592-77-7 Distillates (petroleum), light vacuum [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
70592-78-8 Distillates (petroleum), vacuum [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Metalaxyl-M (ISO) [Mefenoxam; (R)-2-[(2,6- Conc>=25%: Xn; R22; R41
dimethylphenyl)-methoxyacetylamino]propionic acid Xn; R22 Xn ; R: 22 - 41 >=10%Conc<25%: Xi; R41
70630-17-0 methyl ester] Xi; R41 S: (2)26 - 39 - 46 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Conc>=25%: Xn; R22; R41; R43
Xn; R22 Xn >=10%Conc<25%: Xi; R41; R43
Xi; R41 R: 22-41-43 >=5%Conc<10%: Xi; R36; R43
70643-20-8 Ethanol, 2-(2,4-diaminophenoxy)-, sulfate (1:1) R43 S: 25-26-36 >=1%Conc<5%: Xi; R43 N - - - - - - - -
R10
Repr. Cat. 2; R61 T ; R: 61 - 10 - 37, Conc>=20%: T; R61; R37
70657-70-4 2-Methoxypropyl acetate Xi; R37 S: 53 - 45 >=0.5%Conc<20%: T; R61 Eu - - - - - - - -
C ; R: 34 - 52/53
N-[3-[(2-Acetyloxy)ethyl](phenyl-methyl)amino]-4- C; R34 S: (1/2) - 26 - 36/37/39 - 45 - Conc>=10%: C; R34
70693-57-1 methoxyphenylacetamide R52-53 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Conc>=10%: C; R34
70693-62-8 Potassium peroxomonosulfate triple salt C; R34 C ; R: 34 >=5%Conc<10%: Xi; R36/38 V - - - - - - - -
T; R23/24/25 T ; N ; R: 23/24/25 - 48/22 - Conc>=25%: T; R23/24/25; R48/22
1-(1,4-Benzodioxan-2-ylcarbonyl)piperazine Xn; R48/22 51/53 >=10%Conc<25%: Xn; R20/21/22; R48/22
70918-74-0 hydrochloride N; R51-53 S: 53 - 45 - 61 >=3%Conc<10%: Xn; R20/21/22 Eu - - - - - - - -
Dodecyl 3-(2-(3-benzyl-4-ethoxy-2,5- N
dioxoimidazolidin-1-yl)-3-(4-methoxybenzoyl)- R: 53
70950-45-7 acetamido)-4-chlorobenzoate N; R53 S: 61 Eu - - - - - - - -
Carc.Cat.2; R45
Muta.Cat.3; R68 Conc>=10%: T; R45; R68; R41; R43
Xi; R41 T; N >=5%Conc<10%: T; R45; R68; R36; R43
R43 R: 45-41-43-68-51/53 >=1%Conc<5%: T; R45; R68; R43
70987-78-9 Oxiranemethanol, 4-methylbenzene-sulfonate, (S)- N; R51-53 S: 53-45-61 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Vedaprofen [4-Cyclohexyl-alpha-methylnaphthalene-
71109-09-6 1-acetic acid] Xn; R22 Xn ; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -
T Conc>=10%: T; R48/25
71125-38-7 Meloxicam T; 48/25 R: 48/25 >=1%Conc<10%: Xn; R48/22 V - - - - - - - -
71283-80-2 Fenoxyprop-p-ethyl Xn: R20 Xn ; R: 20 Conc>=25%: Xn; R20 V - - - - - - - -

Page 262
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
4-(Bis(4-(diethylamino)phenyl)methyl)benzene-1,2- R: 52/53
71297-11-5 dimethanesulfonic acid R 52-53 S;61 Eu - - - - - - - -

Mixture of: 2-ethylhexyl linolenate and linoleate and Xi

oleate [2-Ethylhexyl epoxyoleate; 2-Ethylhexyl R: 43
71302-79-9 diepoxylinoleate and 2-Ethylhexyl triepoxylinolenate] R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn
R43 R: 22-43-53 Conc>=25%: Xn; R22; R43
71308-16-2 2-(4-Methyl-3-pentenyl)anthraquinone R53 S: (2-)22-24-37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Sodium (6R—trans)-7-amino-8-oxo-3-[[[1-
(sulfomethyl)-1H-tetrazol-5-yl]thio]methyl]-5-thia-1- Xi
azabicyclo[4.2.0]oct-2-ene-2-carboxylate R: 43
71420-85-4 monohydrate R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Diphenyl(4-phenylthiophenyl)sulfonium Xi; R43 Xi ; N ; R: 43 - 50/53 ,
71449-78-0 hexafluoroantimonate N; R50-53 S: (2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; N
R43 R: 43-51/53
71526-07-3 4-Dichloroacetyl-1-oxa-4-azaspiro[4.5]decane N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn
Xn; R22 R: 22-43 Conc>=25%: Xn; R22; R43
71550-12-4 Polymer of allylamine hydrochloride R43 S: (2-)36/37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

Mixture of: 1-methyl-1-(3-(1-methylethyl)phenyl)ethyl-

1-methyl-1-phenylethylperoxide 63% by weight and 1- O; N
methyl-1-(4-(1-methylethyl)phenyl)ethyl-1-methyl-1- O; R7 R: 7-51/53
71566-50-2 phenylethylperoxide 31% by weight N; R51-53 S: (2-)3/7-14-36/37/39-61 Eu - - - - - - - -
Benalaxyl methyl N-(2,6-dimethylphenyl)-N- N
(phenylacetyl)-DL-alaninate [Methyl N-(2,6- R: 50/53
71626-11-4 dimethylphenyl)-N-(phenylacetyl)-DL-alaninate] N; R50-53 S: 60-61 Eu - - - - - - - -
T; N
T; R23/24/25 R: 23/24/25 - 33 - 50/53 Conc>=25%: T; R23/24/25; R33
2,4(or 2,6)-Dinitrophenol(Note: see also CAS No R33 S: (1/2) - 28 - 37 - 45 - 60 - >=3%Conc<25%: Xn; R20/21/22; R33
71629-74-8 25550-58-7) N; R50-53 61 >=1%Conc<3%: Xn; R33 Eu - - - - - - - -

Conc>=10%: T+; R63; R26/28; R48/23/25

>=7%Conc<10%: T+; R63; R26/28; R48/23;
R48/22
>=5%Conc<7%: T; R63; R23/25; R48/23;
Repr. Cat. 3; R63 R48/22
Abamectin (combination of avermectin B1a and T+; R26/28 T+; N >=1%Conc<5%: T; R23/25; R48/20/22
avermectin B1b) (ISO)(Note: see also CAS No 65195- T; R48/23/25 R: 63-26/28-48/23/25-50/53 >=0.5%Conc<1%: Xn; R20/22; R48/20
71751-41-2 55-3) N; R50-53 S: 28-36/37-45-60-61 >=0.1%Conc<0.5%: Xn; R20/22 Eu - - - - - - - -
Bis(4-dodecylphenyl)iodonium Xi; R43 Xi ; R: 43 - 52/53 ,
71786-70-4 hexafluoroantimoonate R52-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Phenol, 4,4'-(1-methylethylidene)bis-, polymer with

N1,N2-bis(2-aminoethyl)-1,2-ethanediamine, 2-
(chloromethyl)oxirane, 2-[(dodecyloxy)methyl]oxirane, Conc>=25%: Xn; R22; R41
2-[(methylphenoxy)methyl]oxirane and 2- Xn; R22 Xn >=10%Conc<25%: Xi; R41
71832-62-7 [(tetradecyloxy)methyl]oxirane Xi; R41 R: 22-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
2-Methyl-1-(4-methylthiophenyl)-2-morpholinopropan- Xn; R22 Xn ; N ; R: 22 - 51/53 ,
71868-10-5 1-one N; R51-53 S: (2) - 22 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
T
1,2-Benzenedicarboxylic acid, di-C6-8-branched R: 61
71888-89-6 alkylesters, C7-rich Repr. Cat. 2; R61 S: 53-45 Conc>=0.5%: T; R61 Eu - - - - - - - -

T ; N ; R: 24/25 - 34 - 51/53, Conc>=25%: T; R24/25; R34

2,4(or 2,5)-Xylenol [2,4(or 2,5)-Dimethylphenol](Note: T; R24/25 S: (1/2) - 26 - 36/37/39 - 45 - >=10%Conc<25%: C; R34; R21/22
see also CAS No 95-65-8, 95-87-4, 105-67-9, 526-75- C; R34 61; >=5%Conc<10%: Xn; R21/22; R36/38
71975-58-1 0, 576-26-1 & 1300-71-6) N; R51-53 Note: C >=3%Conc<5%: Xn; R21/22 Eu - - - - - - - -

Fomesafen [5-[2-Chloro-4-(trifluoromethyl)phenoxy]-N- Xn ; R: 22
72178-02-0 (methylsulphonyl)-2-nitrobenzamide] Xn; R22 S: (2) Conc>=25%: Xn; R22 Eu - - - - - - - -

Page 263
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
6-Anilino-1-benzoyl-4-(4-tert-
pentylphenoxy)naphtho[1,2,3-de]quinoline-2,7-(3H)- N; R: 51/53,
72453-58-8 dione N; R51-53 S: 61 Eu - - - - - - - -
Fenoxycarb [Ethyl [2-(4- Xn; R48/22 Xn ; N ; R: 48/22 - 50/53,
72490-01-8 phenoxyphenoxy)ethyl]carbamate] N; R50 - 53 S: 60 - 61 Conc>=10%: Xn; R48/22 Eu/V - - - - - - - -
Xi ; R: 36/38
72531-53-4 2-Methylpropyl 2-hydroxy-2-methylbut-3-enoate Xi; R36/38 S: (2)26 - 37 Conc>=20%: Xi; R36/38 Eu - - - - - - - -
Methyl (R)-2-(4-(3-chloro-5-trifluoromethyl-2- Xn; R22 Xn ; N ; R: 22 - 50/53
72619-32-0 pyridyloxy)phenoxy)propionate N; R50-53 S: (2)60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
T ; R: 45 ,
Lubricating oils (petroleum), C20-50, hydrotreated S: 53 - 45 ;
72623-85-9 neutral oil based, high viscosity [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Lubricating oils (petroleum), C15-30, hydrotreated S: 53 - 45 ;
72623-86-0 neutral oil base [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Lubricating oils (petroleum), C20-50, hydrotreated S: 53 - 45 ;
72623-87-1 neutral oil based [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
L-Glutamic acid, N-(1-oxotetradecyl)-, potassium salt Xi
72716-26-8 (1:1) Xi; R38 R: 38 Conc>=20%: Xi; R38 N - - - - - - - -
N
R: 51/53
72752-52-4 2-Piperidin-1-yl-benzonitrile N; R51-53 S: 61 Eu - - - - - - - -

Conc>=25%: Xn; R21/22; R48/22; R38; R41;

R43
Xn; R21/22-48/22 Xn; N >=20%Conc<25%: Xn; R48/22; R38; R41; R43
Xi; R38-41 R: 21/22-38-41-43-48/22- >=10%Conc<20%: Xn; R48/22; R41; R43
R43 51/53 >=5%Conc<10%: Xi; R36; R43
72830-09-2 2-Chloromethyl-3,4-dimethoxypyridinium chloride N; R51-53 S: (2-)26-36/37/39-61 >=1%Conc<5%:Xi; R43 Eu - - - - - - - -
Flurazole [Benzyl 2-chloro-4-(trifluoromethyl)thiazole- N ; R: 51/53,
72850-64-7 5-carboxylate] N: R51-53 S: 61 Eu - - - - - - - -
N
R: 51/53
72903-27-6 Diethyl 1,4-cyclohexanedicarboxylate N; R51-53 S: 61 Eu - - - - - - - -
1-{Benzyl[2-(2-methoxyphenoxy)ethyl]amino}-3-(9H- R: 53
72955-94-3 carbazol-4-yloxy)propan-2-ol R53 S: 61 Eu - - - - - - - -

Mixture of [2,4-dioxo-(2-propyn-1-yl)imidazolidin-3-
yl]methyl(1R)-cis-chrysanthemate and [2,4-dioxo-(2- Xn; N
propyn-1-yl)imidazolidin-3-yl]methyl(1R)-trans- Xn; R22 R: 22-50/53
72963-72-5 chrysanthemate N; R50-53 S: (2-)60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R41
1-[3-[(Dimethylamino)methyl]-4- Xi; R41 R: 22-41-52/53 >=10%Conc<25%: Xi; R41
73096-98-7 hydroxyphenyl]ethanone R52-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Resin acids and rosin acids(Note: see also CAS No Xi ; R: 43 ,
73138-82-6 8052-10-6 & 8050-09-7) Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Repr. Cat. 3; R62-63 Conc>=10%: Xn; R62; R63; R48/22
73231-34-2 Florfenicol Xn; R48/22 Xn ; R: 48/22 - 62 - 63 >=5%Conc<10%: Xn; R62; R63 V - - - - - - - -
R10
Xn; R48/22 Xn ; R: 10 - 36 - 48/22 Conc>=20%: Xn; R48/22; R36
73246-45-4 (S)-Methyl-2-chloropropionate Xi; R36 S: (2)23 - 26 - 36 >=10%Conc<20%: Xn; R48/22 Eu - - - - - - - -
Mefenacet [2-(Benzothiazol-2-yloxy)-N-methyl-N- N; R51/53,
73250-68-7 phenylacetamide] N: R51-53 S: 61 Eu - - - - - - - -

Menadione nicotinamide bisulfite [1,2,3,4-Tetrahydro- Xi; N

2-methyl-1,4-dioxonaphthalene-2-sulfonic acid, Xi; R36/38 R: 36/38-50/53
73581-79-0 compound with nicotin-3-amide (1:1)] N; R50-53 S: (2-)24/25-60-61 Conc>=20%: Xi; R36/38 Eu - - - - - - - -

Page 264
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Extract residues (coal), tar oil alk., naphthalene distn.

residues [Naphthalene Oil Extract Residue](Note:
The residue obtained from chemical oil extracted
after the removal of naphthalene by distillation T
composed primarily of two to four membered R: 45-46
condensed ring aromatic hydrocarbons and aromatic Carc. Cat. 2; R45 S: 53-45
73665-18-6 nitrogen bases.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
4-[3-(3,5-Di-tert-butyl-4-hydroxyphenyl)propionyloxy]-
1-[2-[3-(3,5-di-tert-butyl-4-
hydrophenyl)propionyloxy]ethyl]-2,2,6,6- R: 53
73754-27-5 tetramethylpiperidine R 53 S: 61 Eu - - - - - - - -
2-Chloro-6-nitro-3-phenoxyaniline [Benzenamine, 2- N ; R: 50 - 53,
74070-46-5 chloro-6-nitro-3-phenoxy] N; R50-53 S: 60 - 61 Eu - - - - - - - -
N
Metsulfuron-methyl (ISO) [2-(4-Methoxy-6-methyl- R: 50/53
74223-64-6 1,3,5-triazin-2-ylcarbamoylsulfamoyl) benzoic acid] N; R50-53 S: 60-61 Eu - - - - - - - -
Mixture of: thiobis(4,1-phenylene)-S,S,S',S'-
tetraphenyldisulfonium bishexafluorophosphate and Xi; N
diphenyl(4-phenylthiophenyl)sulfonium Xi; R36 R43 R: 36-43-50/53 Conc>=20%: Xi; R36; R43
74227-35-3 hexafluorophosphate propylene carbonate N; R50-53 S: (2-)24-26-37-60-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 2; R45 T ; N ; R: 45 - 21 - 43 -
3,3'-Dichlorobenzidine sulphate salt of [3,3'- Xn; R21 50/53, Conc>=25%: T; R45; R21; R43
Dichlorobiphenyl-4,4'-ylenediamine sulphate salt R43 S: 53 - 45 - 60 - 61; >=1%Conc<25%: T; R45; R43
74332-73-3 of](Note: see also CAS No 612-83-9 & 64969-34-2) N; R50-53 Notes: A; E >=0.1%Conc<1%: T; R45 Eu - - - - - - - -
Xi; N
Xi; R38 R: 38-51/53
74338-72-0 2,4,4,7-Tetramethyl-6-octen-3-one N; R51-53 S: (2-)37-61 Conc>=20%: Xn; R38 Eu - - - - - - - -
Xi
R43 R: 43-52/53
74401-04-0 N-Methyl-4-(p-formylstyryl)pyridinium methylsulfate R52-53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

4,4'-bi-o-Toluidine sulphate [4,4'-bi-o-Toluidine, salts Carc. Cat. 2; R45 T ; N ; R: 45 - 22 - 51/53,

of; 3,3’-Dimethylbenzidine, salts of; o-Tolidine, salts Xn; R22 S: 53 - 45 - 61; Conc>=25%: T; R45; R22
74753-18-7 of](Note: see also CAS No 612-82-8 & 64969-36-4) N; R51-53 Notes: A ; E >=0.1%Conc<25%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
74869-21-9 Lubricating greases [Grease] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
74869-22-0 Lubricating oils [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Conc>=25%: T; R60; R61; R68; R48/25;

R21/22; R41; R 43
Muta. Cat. 3; R68 >=10%Conc<25%: T; R60; R61; R68; R48/25;
Repr. Cat. 2; R60-61 R41; R43
T; R48/25 T; N >=5%Conc<10%: T; R60; R61; R68; R48/22;
Xn; R21/22 R: 60-61-21/22-41-43-48/25- R36; R43
Xi; R41 68-50/53 >=1%Conc<5%: T; R60; R61; R68; R48/22; Tin, organic
R43 S: 53-45-60-61 R43 compounds (as
75113-37-0 Dibutyltin hydrogen borate N; R50-53 Note: E >=0.5%Conc<1%: T; R60; R61 Eu;A Sn) - 0.1 - 0.2 - Sk -
Xn; N
Xn; R22 R: 22-51/53
75490-39-0 2,2,4-Trimethyl-4-phenyl-butane-nitrile N; R51-53 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi
N-Butyl-3-(2-chloro-4-nitrophenylhydrazono)-1-cyano- R43 R: 43-52/53
75511-91-0 2-methylprop-1-ene-1,3-dicarboximide R 52-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
R,R-2-Hydroxy-5-(1-hydroxy-2-(4-phenylbut-2- F; R11
ylamino)ethyl)benzamide hydrogen 2,3- Xi; R43 F ; Xi ; R: 11 - 43 - 52/53 ,
75659-07-3 bis(benzoyloxy)succinate R52-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R68; R22; R38; R41
Chrysoidine monoacetate [4-(Phenylazo)benzene-1,3- Muta. Cat. 3; R68 Xn; N >=20%Conc<25%: Xn; R68; R38; R41
diamine monoacetate](Note: see also CAS No. 532- Xn; R22 R: 22-38-41-68-50/53 >=10%Conc<20%: Xn; R68; R41
82-1, 79234-33-6, 63681-54-9, 83968-67-6 & 84196- Xi; R38-41 S: (2-)23-26-36/37/39-46-60- >=5%Conc<10%: Xn; R68; R36
75660-25-2 22-5) N; R50-53 61 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -

Page 265
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Diclobutrazole [(2RS, 3RS)-1-(2,4-Dichlorophenyl)-

4,4-dimethyl-2-(1H-1,2,4-triazol-1yl)pentan-3-oI; (R*,
R*)-(±)-beta-[(2,4-Dichlorophenyl)methyl]-alpha-(1,1- Xi; R36 Xi ; N ; R: 36 - 51/53,
75736-33-3 dimethylethyl)-1H-1,2,4-triazole-1-ethanol] N; R51-53 S: (2) - 26 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
Xn
R: 62
75980-60-8 Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide Repr. Cat. 3; R62 S: (2)-22-36/37 Conc>=5%: Xn; R62 Eu - - - - - - - -

(1S,4R,6R,7R)-(4-Nitrophenylmethyl)3-methylene-1- Xn ; R: 42
76109-32-5 oxo-7-phenylacetamido-cepham-4-carboxylate R42 S: (2)22 Conc>=1%: Xn; R42 Eu - - - - - - - -
Xn; R48/22 Xn
R43 R: 43-48/22-52/53 Conc>=10%: Xn; R48/22; R43
76145-91-0 2,4-Diamino-6-hydroxymethylpteridinehydrobromide R52-53 S: (2-)22-36/37-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
Dichloro(dichlorophenyl)methyl methylbenzene,
mixed isomers
[(Dichlorophenyl)(dichlorotolyl)methane, mixed N ; R: 50/53,
76253-60-6 isomers (IUPAC)] N ; R50-53 S: 60 – 61 Eu - - - - - - - -
Hexasodium 2,2'-vinylenebis((3-sulfonato-4,1-
phenylene)imino(6-(N-cyanoethyl-N-(2-
hydroxypropyl)amino)-1,3,5-triazine-4,2- Xi ; R: 36 ,
76508-02-6 diyl)imino)dibenzene-1,4-disulfonate Xi; R36 S: (2) - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41; R43
>=20%Conc<25%: Xi; R38; R41; R43
(2S,5R)-6,6-Dibromo-3,3-dimethyl-7-oxo-4-thia-1- Xn; R22 Xn >=10%Conc<20%: Xi; R41; R43
azabicyclo[3.2.0]heptane-2-carboxylic acid 4,4- Xi; R38-41 R: 22-38-41-43 >=5%Conc<10%: Xi; R36; R43
76646-91-8 dioxide R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
76674-21-0 Flutriafol Xn; R20/22 Xn ; R: 20/22 Conc>=25%: Xn; R20/22 V - - - - - - - -

(E)-beta-[(2,4-Dichlorophenyl)methylene]-alpha-(1,1-
dimethylethyl)-1H-1,2,4-triazol-1-ethanol [(E)-(RS)-1-
(2,4-Dichlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol- Xn; R22 Xn; N ; R: 22 - 50/53
76714-88-0 1-yl)pent-1-en-3-ol; Diniconazole (ISO)] N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn
3-(2-Daminomethyleneamino)thiazol-4- Xn; R22 R: 22-43 Conc>=25%: Xn; R22; R43
76823-93-3 ylmethylthio)propionitrile R43 S: (2-)22-24-37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xi; R36 Xi; N
(2R,3R)-3-((R)-1-(tert-Butyldimethylsiloxy)ethyl)-4- R43 N; R: 36-43-51/53 Conc>=20%: Xi; R36; R43
76855-69-1 oxoazetidin-2-yl acetate R51-53 S: (2-)24-26-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R22; R41; R43
Xn; R22 Xn >=10%Conc<25%: Xi; R41; R43
Xi; R41 R: 22-41-43 >=5%Conc<10%: Xi R36; R43
76932-17-7 (S)-alpha-(Acetylthio)benzenepropanoic acid R43 S: (2-)22-26-36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T; R60; R63; R20/21/22;

T R48/20/22
Repr. Cat. 2; R60 R: 60-20/21/22-48/20/22-63 >=10%Conc<25%: T; R60; R63; R48/20/22
Glufosinate ammonium (ISO) [Ammonium 2-amino-4- Repr. Cat. 3; R63 S: 53-45 >=5%Conc<10%: T; R60; R63
77182-82-2 (hydroxymethylphosphinyl)butyrate] Xn; R20/21/22-48/20/22 Note: E >=0.5%Conc<5%: T; R60 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
77214-82-5 Iron (III) tris(4-methylbenzenesulfonate) Xi; R41 S: (2-)24-26-39 >=5%Conc<10% : Xi; R36 Eu - - - - - - - -
R10 Xn ; N ; R: 10 - 20/22 - 50 -
Xn; R20/22. 58 ,
77227-99-7 3-Chloro-4,5,alpha,alpha,alpha-pentafluorotoluene N; R50-58 S: (2) - 51 - 60 - 61 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Xi
[1R-(1-alpha,2beta,5alpha)]-Mono[5-methyl-2-(1- R: 41 Conc>=10%: Xi; R41
77341-67-4 methylethyl)cyclohexyl]butanedioate Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 266
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

R14 Xn Conc>=25%: Xn; R22; R48/22; R41; R42/43

Xn; R22-48/22 R: 14-22-41-42/43-48/22 >=10%Conc<25%: Xn; R48/22; R41; R42/43
Xi; R41 S: (2-)8-23-26-30-35- >=5%Conc<10%: Xn; R36; R42/43 Isocyanates, all
77375-79-2 Ethyl 2-(isocyanatosulfonyl)benzoate R42/43 36/37/39 >=1%Conc<5%: Xn; R42/43 Eu;A (as-NCO) - 0.02 - 0.07 - Sen -
Carc. Cat. 2; R45
Muta. Cat. 2; R46 T ; R: 45 - 46 - 22 - 36, Conc>=25%: T; R45; R46; R22; R36
Methyl acrylamidomethoxyacetate (containing >= Xn; R22 S: 53 - 45 ; >=20%Conc<25%: T; R45; R46; R36
77402-03-0 0.1% acrylamide ) Xi; R36 Note: E >=0.1%Conc<20%: T; R45; R46 Eu - - - - - - - -

Carc. Cat. 2; R45 Conc>=10%: T; R45; R46; R34; R43

Muta. Cat. 2; R46 >=5%Conc<10%: T; R45; R46; R36/38; R43
Methyl acrylamidoglycolate (containing >= 0.1% C; R34 T ; R: 45 - 46 - 34 - 43, >=1%Conc<5%: T; R45; R46; R43
77402-05-2 acrylamide ) R43 S: 53 - 45 >=0.1%Conc<1%: T; R45; R46 Eu - - - - - - - -
(S)-3-Benzyloxycarbonyl-1,2,3,4-tetrahydro- N ; R:51/53,
77497-97-3 isoquinolinium 4-methylbenzenesulfonate N; R51-53 S: 61 Eu - - - - - - - -
Asbestos, actinolite(Note: see also CAS No 132207- T ; R: 45 - 48/23 , Conc>=10%: T; R45; R48/23
32-0, 12172-73-5 , 77536-67-5, 77536-68-6, 12001- Carc. Cat. 1; R45 S: 53 - 45; >=1%Conc<10%: T; R45; R48/20
77536-66-4 28-4 & 12001-29-5) T; R48/23 Note: E >=0.1%Conc<1%: T; R45 Eu; A Other forms (b) 0.1 f/mL - - - 1 - -
Asbestos, anthophyllite(Note: see also CAS No T ; R: 45 - 48/23 , Conc>=10%: T; R45; R48/23
132207-32-0, 12172-73-5 , 77536-66-4, 77536-68-6, Carc. Cat. 1; R45 S: 53 - 45; >=1%Conc<10%: T; R45; R48/20
77536-67-5 12001-28-4 & 12001-29-5) T; R48/23 Note: E >=0.1%Conc<1%: T; R45 Eu; A Other forms (b) 0.1 f/mL - - - 1 - -
Asbestos, tremolite(Note: see also CAS No 132207- T ; R: 45 - 48/23 , Conc>=10%: T; R45; R48/23
32-0, 12172-73-5 , 77536-66-4 77536-67-5, 12001-28-Carc. Cat. 1; R45 S: 53 - 45; >=1%Conc<10%: T; R45; R48/20
77536-68-6 4 & 12001-29-5) T; R48/23 Note: E >=0.1%Conc<1%: T; R45 Eu; A Other forms (b) 0.1 f/mL - - - 1 - -

5-(4-Chloro-2-nitro-phenylazo)-1,2-dihydro-6-hydroxy- R: 53
77889-90-8 1,4-dimethyl-2-oxo-pyridine-3-carbonitrile R53 S: 61 Eu - - - - - - - -
Xi; R38 Xi Conc>=20%: Xi; R38; R43
78417-28-4 2,4,7-Decatrienoic acid, ethyl ester R43 R: 38-43 >=1%Conc<20%: Xi; R43 N - - - - - - - -

Xi; R43
This substance has only been
assessed against the single
endpoint of skin sensitisation.
This substance has not been
subject to a complete assessment
Urea, N-[1,3-bis(hydroxymethyl)-2,5-dioxo-4- for hazard classification in
imidazolidinyl]-N,N'-bis(hydroxymethyl)- [Diazolidinyl accordance with the approved
78491-02-8 urea; Germall II] criteria Xi; R:43 Conc>=1%: Xi; R43 N - - - - - - - -
Xi
R43 R: 43-53
78531-59-6 1-(4-(trans-4-Pentylcyclohexyl)phenyl)ethanone R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
R: 43-53
78531-60-9 1-(4-(trans-4-Heptylcyclohexyl)phenyl)ethane R43 R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; R43 Xi ; R: 43 - 53,
78531-61-0 4-(trans-4-Propylcyclohexyl)acetophenone R53 S: 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Hexythiazox [trans-5-(4-Chlorophenyl)-N-cyclohexyl-4- N ; R50/53

78587-05-0 methyl-2-oxo-3-thiazolidine-carboxamide] N; R50-53 S: 60 - 61 Eu - - - - - - - -
Methyl (3aR,4R,7aR)-2-methyl-4-(1S,2R,3- Xi
triacetoxypropyl)-3a,7a-dihydro-4H-pyrano[3,4- R: 41 Conc>=10%: Xi; R41
78850-37-0 d]oxazole-6-carboxylate Xi; R41 S: (2-)26-39 >=5%Conc<10% : Xi; R36 Eu - - - - - - - -
3-(2-{4-[2-(4- R: 53 S:
79026-02-1 Cyanophenyl)vinyl]phenyl}vinyl)benzonitrile R 53 61 Eu - - - - - - - -
Xi; N
7a-Ethyl-3,5-bis(1-methylethyl)-2,3,4,5- Xi; R38 R: 38-51/53
79185-77-6 tetrahydrooxazolo[3,4-c]-2,3,4,5-tetrahydrooxazole N; R51-53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Conc>=25%: Xn; R22; R41; R43
Xn; R22 Xn >=10%Conc<25%: Xi; R41; R43
Xi; R41 R: 22-41-43 >=5%Conc<10%: Xi; R36; R43
79200-56-9 (1R,4S)-2-Azabicyclo[2.2.1]hept-5-en-3-one R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Page 267
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: Xn; R68; R22; R38; R41
Muta. Cat. 3; R68 Xn; N >=20%Conc<25%: Xn; R68; R38; R41
Chrysoidine acetate [4-(Phenylazo)benzene-1,3- Xn; R22 R: 22-38-41-68-50/53 >=10%Conc<20%: Xn; R68; R41
diamine acetate](Note: see also CAS No. 532-82-1, Xi; R38-41 S: (2-)23-26-36/37/39-46-60- >=5%Conc<10%: Xn; R68; R36
79234-33-6 75660-25-2, 63681-54-9, 83968-67-6 & 84196-22-5) N; R50-53 61 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -
Xn ; N ; R: 50/53 - 63
Fluazifop-P-butyl (ISO) [Butyl (R)-2-[4-(5- Repr. Cat. 3; R63 S: (2)29 - 36/37 - 46 - 60 -
79241-46-6 trifluoromethyl-2-pyridyloxy)phenoxy]propionate] N; R50-53 61 Conc>=5%: Xn; R63 Eu - - - - - - - -
R14 Xn
Xn; R48/22 R: 14-42/43-48/22 Conc>=10%: Xn; R48/22; R42/43
79277-18-2 Methyl 3-isocyanatosulfonyl-2-thiophene-carboxylate R42/43 S: (2-)22-30-35-36/37-45 >=1%Conc<10%: Xn; R42/43 Eu - - - - - - - -
N R:
50/53
79277-27-3 Thifensulfuron-methyl N; R50-53 S; 60-61 Eu - - - - - - - -
Xn; R22 Xn ; R: 22 - 52/53 ,
79456-26-1 3-Chloro-5-trifluoromethyl-2-pyridylamine R52-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi
Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
79463-77-7 Diphenoxymethylenecyanamide R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; N
Xn; R48/22 R: 48/22-50/53
79568-06-2 (3-Aminophenyl)pyridin-3-ylmethanone N; R50-53 S: (2-)22-36-60-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
(1S-cis)-4-(3,4-Dichlorophenyl)-1,2,3,4-tetrahydro-N- Xi; N
methyl-1-naphthalenamine 2-hydroxy-2- Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
79617-97-3 phenylacetate N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Conc>=25%: T; R48/24; R23; R41; R43

>=10%Conc<25%: T; R48/24; R20; R41; R43
T; R23; R48/24 >=5%Conc<10%: Xn; R48/21; R20; R36; R43
Xi; R41 >=3%Conc<5%: Xn; R48/21; R20; R43
79622-59-6 Fluazinam R43 T ; R: 23 - 41 - 43 - 48/24 >=1%Conc<3%: Xn; R48/21; R43 V - - - - - - - -
T; R25 T; N Conc>=25%: T; R25; R48/22
Xn; R48/22 R: 25-48/22-50 >=10%Conc<25%: Xn; R22; R48/22
79723-02-7 Tetramethylammonium hydrogen phthalate N; R50 S: (1/2-)25-36-45-61 >=3%Conc<10%: Xn; R22 Eu - - - - - - - -
Repr. Cat. 3; R62 Conc>=10%: Xn; R62; R48/22; R43
Xn; R48/22 Xn ; R: 43 - 48/22 - 62 >=5%Conc<10%: Xn; R62; R43
79815-20-6 (S)-2,3-Dihydro-1H-indole-2-carboxylic acid R43 S: (2)22 - 25 - 26 - 36/37 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
N
R: 51/53
79876-59-8 4-(3-Triethoxysilylpropoxy)-2-hydroxybenzophenone N; R51-53 S: 61 Eu - - - - - - - -
Xn ; R: 22 - 48/22 Conc>=25%: Xn; R22; R48/22
79881-89-3 3'-(3-Acetyl-4-hydroxyphenyl)-1,1-diethylurea Xn; R22-48/22 S: (2) - 22 - 36 >=10%Conc<25%: Xn; R48/22 Eu - - - - - - - -
Xi
trans-(5RS,6SR)-6-Amino-2,2-dimethyl-1,3-dioxepan- R: 43
79944-37-9 5-ol R43 S: (2-)22-24/25-26-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22
(RS)-2-(2,4-Dichlorophenyl)-1-(1H-1,2,4-triazol-1- R43 Xn ; N ; R: 22 - 43 - 51/53 Conc>=25%: Xn; R22; R43
79983-71-4 yl)hexan-2-ol N; R51-53 S: (2)24 - 37 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T; R23; R22; R48/21/22
T; R23 >=10%Conc<25%: Xn; R20; R48/21/22
80060-09-9 Diafenthiuron Xn; R22-48/21/22 T R: 22-23-48/21/22 >=3%Conc<10%: Xn; R20 V - - - - - - - -
Ceftiofur crystalline free acid [CCFA](Note: See also
80370-57-6 CAS No. 104010-37-9 & 103980-44-5) Xi; R43 Xi ; R: 43 Conc>=1%: Xi; R43 V - - - - - - - -
Repr. Cat. 2; R61
2-Ethylhexyl [[[3,5-bis(1,1-dimethylethyl)-4- R43 T ; R: 61 - 43 - 52/53, Conc>=1%: T; R61; R43
80387-97-9 hydroxyphenyl]methyl]thio]acetate R52-53 S: 53 - 45 - 61 >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Xn
R: 42
80498-15-3 Laccase R42 S: (2-)23-45 Conc>=1%: Xn; R42 Eu - - - - - - - -
Mixture of ethyl exo-tricyclo[5.2.1.02,6]decane-endo-2-
carboxylate and ethyl endo-tricyclo[5.2.1.02,6]decane- Xi; R38 Xi ; N ; R: 38 - 51/53
80657-64-3 exo-2-carboxylate N; R51-53 S: (2)37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -

Page 268
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

3,9-Bis(2,6-di-tert-butyl-4-methylphenoxy)-2,4,8,10- R:53
80693-00-1 tetraoxa-3,9-diphosphaspiro[5,5]undecane R53 S: 61 Eu - - - - - - - -

2-[4,5-Dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H- Xi; R36 Xi ; R: 36 - 52/53,

81334-34-1 imidazol-2-yl]-3-pyridine carboxylate [Imazapyr] R52-53 S: (2) - 26 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
81335-77-5 Imazethapyr Xi; R36/38 Xi ; R: 36/38 Conc>=20%: Xi; R36/38 V - - - - - - - -
Fluoroxypyr -meptyl (ISO) [Methylhepyl, O-((4-amino-
3,5-dichloro-6-fluoro-2-pyridyloxy) acetate](Note: see N ; R: 50/53
81406-37-3 also CAS No:154486-27-8) N ; R50-53 S: 60 - 61 Eu - - - - - - - -
Glyphosate-trimesium [Glyphosate- Xn; R22 Xn ; N ; R: 22 - 51/53
81591-81-3 trimethylsulfonium] N; R51-53 S: (2)36/37 - 46 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi
Methyl 2,2-dimethyl-6- R: 38
81752-87-6 methylenecyclohexanecarboxylate Xi; R38 S: (2-)37 Conc>=20%: Xi; R38 Eu - - - - - - - -
81777-89-1 Clomazone Xn; R20/22 Xn; R: 20/22 Conc>=25%: Xn; R20/22 V - - - - - - - -

Muta. Cat. 3; R68 T ; N ; R: 25 - 43 - 48/25 - Conc>=25%: T; R68; R25; R48/25; R43

T; R25-48/25 68 - 50/53 >=10%Conc<25%: T; R68; R22; R48/25; R43
(4-Hydrazinophenyl)-N-methylmethanesulfonamide R43 S: (1/2) - 22 - 36/37/39 - 45 - >=3%Conc<10%: Xn; R68; R22; R48/22; R43
81880-96-8 hydrochloride N; R50-53 60 - 61 >=1%Conc<3%: Xn; R68; R48/22; R43 Eu - - - - - - - -

Tetrasodium 3,3'-(piperazine-1,4-diylbis((6-chloro-
1,3,5-triazine-4,2-diyl)imino(2-acetamido)-4,1- Xi ; R: 43 ,
81898-60-4 phenyleneazo))bis(naphthalene-1,5-disulphonate) Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; N
Sodium 2-[[4-[(4,6-dichloro-1,3,5-triazin-2- R43 R: 43-50/53
81992-66-7 yl)amino]phenyl]sulfonyl]ethyl sulfate N; R50-53 S: (2-)22-24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Hexasodium [4,4”-azoxybis(2,2’-disulfonatostilbene-
4,4’-diylazo)]-bis[5’-sulfonatobenzene-2,2’-diolato- N ; R: 51/53,
82027-60-9 O(2),O(2),N(1)]-copper(II) N; R51-53 S: 61 Eu - - - - - - - -

Triasulfuron [1-[2-(2-Chloroethoxy)phenylsulfonyl]-3- N; R: 50/53,

82097-50-5 (4-methoxy-6-methyl-1,3,5-triazin-2-yl)urea] N; R50-53 S: 60 - 61 Eu - - - - - - - -
Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
Xi; R41 R: 22-41-51/53 >=10%Conc<25%: Xi; R41
82380-18-5 2-Fluoro-4-hydroxybenzonitrile N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Carc. Cat. 3; R40
Repr. Cat. 2; R60 T; N
(E)-3-[1-[4-[2-(Dimethylamino)ethoxy]phenyl]-2- R43 R: 60-40-43-50/53
82413-20-5 phenylbut-1-enyl]phenol N; R50-53 S: 53-45-60-61 Eu - - - - - - - -
N-[3-(1-Ethyl-1 -methylpropyl)-1,2-oxazol-5-yl]-2,6- R:53,
82558-50-7 dimethoxybenzamide R53 S: 61 Eu - - - - - - - -
Conc>=25%: T; R23/25; R41
T; R23/25 T ; R: 23/25 - 41 - 52/53, >=10%Conc<25%: Xn; R20/22; R41
Xi; R41 S: (1/2) - 22 - 26 - 36/37/39 - >=5%Conc<10%: Xn; R20/22; R36
82560-06-3 3-(3-Methylpent-3-yl) isoxazol-5-ylamine R52-53 45 - 61 >=3%Conc<5%: Xn; R20/22 Eu - - - - - - - -
Benfuracarb (ISO) [Ethyl N-[2,3-dihydro-2,2- Repr. Cat. 3; R62
dimethylbenzofuran-7- T; R23 T; N Conc>=25%: T; R62; R23; R22
yloxycarbonyl(methyl)aminothio]-N-isopropyl-beta- Xn; R22 R: 22-23-62-50/53 >=5%Conc<25%: Xn; R62; R20
82560-54-1 alaninate] N; R50-53 S: (1/2-)36/37-45-60-61 >=3%Conc<5%: Xn; R20 Eu - - - - - - - -
Conc>=25%: T; R25; R41; R43
T; R25 T; N >=10%Conc<25%: Xn; R22; R41; R43
Xi; R41 R: 25-41-43-50/53 >=5%Conc<10%: Xn; R22; R36; R43
2,3,5,6-Tetrahydro-2-methyl-2H-cyclopenta[d]-1,2- R43 S: (1/2-)22-26-36/37/39-45- >=3%Conc<5%: Xn; R22; R43
82633-79-2 thiazol-3-one N; R50-53 60-61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T; R25
82657-04-3 Bifenthrin T; R25 T; R: 25 >=3%Conc<25%: Xn; R22 V - - - - - - - -

Page 269
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: T; R25; R41
T; R25 T ; N ; R: 25 - 41 - 51/53 >=10%Conc<25%: Xn; R22; R41
1-Chloro-N,N-diethyl-1,1-diphenyl-1- Xi; R41 S: (1/2) - 26 - 37/39 - 41 - 45 >=5%Conc<10%: Xn; R22; R36
82857-68-9 (phenylmethyl)phosphoramine N; R51-53 - 61 >=3%Conc<5%: Xn; R22 Eu - - - - - - - -
Xn; R22 Xn; N
(2,5-Dioxopyrrolidin-1-yl)-9H-fluoren-9-ylmethyl R43 R: 22-43-51/53 Conc>=25%: Xn; R22; R43
82911-69-1 carbonate N; R51-53 S: (2-)24-37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xi; R41 Xi ; N ; R: 41 - 51/53 , Conc>=10%: Xi; R41
82985-35-1 Bis(3-(trimethoxysilyl)propyl)amine N; R51-53 S: (2) - 24 - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22 C ; R: 22 - 34 - 52/53 Conc>=25%: C; R34; R22
2-[(2-[2- C; R34 S: (1/2) - 23 - 26 - 36/37/39 - >=10%Conc<25%:C; R34
83016-70-0 (Dimethylamino)ethoxy]ethyl)methylamino]ethanol R52-53 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Methyl alpha-((4,6-dimethoxypyrimidin-2- Xi; R43 Xi ; N ; R: 43 - 51/53 ,
83055-99-6 yl)ureidosulphonyl)-o-toluate N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

R10
R14
Muta. Cat. 3; R68 Xn Conc>=25%: Xn; R20; R48/22; R68; R41; R42
2-(Isocyanatosulfonylmethyl)benzoic acid methyl Xn; R20-48/22 R: 10 - 14 - 20 - 41 - 42 - >=10%Conc<25%:Xn; R48/22; R68; R41; R42
ester; (alt.): methyl 2- Xi; R41 48/22 - 68 >=5%Conc<10%:Xn; R48/22; R68; R42; R36
83056-32-0 (isocyanatosulfonylmethyl)benzoate R42 S:(2)23 - 26 - 36/37/39 >=1%Conc<10%:Xn; R68; R42 Eu - - - - - - - -

Diflufenican [N-(2,4-Difluorophenyl)-2-[3- R52/53,

83164-33-4 (trifluoromethyl)phenoxy]-3- pyridinecarboxamide] R52-53 S: 61 Eu - - - - - - - -
N,N'-1,4-Phenylenebis(2-((2-methoxy-4- R: 53
83372-55-8 nitrophenyl)azo)-3-oxobutanamide R 53 S: 61 Eu - - - - - - - -
Xn; R48/22 Conc>=10%: Xn; R48/22; R41; R43
Xi; R41 Xn ; R: 41 - 43 - 48/22 >=5%Conc<10%: Xi; R36; R43
83623-61-4 ((4-Phenylbutyl)hydroxyphosphoryl)acetic acid R43 S: (2)22 - 26 - 36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi
R43 R: 43-53
83626-30-6 1-(4-(trans-4-Butylcyclohexyl)phenyl)ethanone R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
83657-17-4 Uniconazole-p Xn; R22 Xn ; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -
R: 53
83708-14-9 3-Icosyl-4-henicosylidene-2-oxetanone R53 S: 61 Eu - - - - - - - -
Ketanserin tartate [3-[2-[4-(4-
Fluorobenzoyl)piperidino]ethyl]quinazoline-
83846-83-7 2,4(1H,3H)-dione [R (R*,R*)] tartrate] Xn; R48/22 Xn; R: 48/22 Conc>=10%: Xn; R48/22 V - - - - - - - -
Xi; N
R43 R: 43 - 51/53
83857-96-9 2-Butyl-4-chloro-5-formylimidazole N; R51-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Conc>=50%: C; R34; R22; R43

>=30%Conc<50%: Xn; R22; R38; R41; R43
(+/-)-1- [2-(Allyoxy)ethyl-2-(2,4-dichlorophenyl)]-1H- Xn; R22 >=25%Conc<30%: Xn; R22; R41; R43
imidazolium hydrogen sulphate [Imazalil sulphate C; R34 C; N >=15%Conc<25%: Xi; R41; R43
aqueous solution (ISO)](Note: see also CAS No. R43 R: 22-34-43-50/53 >=5%Conc<15%: Xi; R36; R43
83918-57-4 58594-72-2) N; R50-53 S: (2-)26-36/37/39-45-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
(±)-1- [2-(Allyloxy)ethyl-2-(2,4-dichlorophenyl)]-1H-
imidazolium hydrogen sulphate [Imazalil Xn; R22 Xn; N
sulphate (ISO) powder](Note: see also CAS No R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
83918-57-4 58594-72-2) N; R50-53 S: (2-)24/25-37-46-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xi; N
Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
83926-73-2 4-Cyclohexyl-2-methyl-2-butanol N; R51-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Conc>=25%: Xn; R68; R22; R38; R41
Chrysoidine dihydrochloride [4-(Phenylazo)benzene- Muta. Cat. 3; R68 Xn; N >=20%Conc<25%: Xn; R68; R38; R41
1,3-diamine dihydrochloride](Note: see also CAS No. Xn; R22 R: 22-38-41-68-50/53 >=10%Conc<20%: Xn; R68; R41
532-82-1, 75660-25-2, 79234-33-6, 63681-54-9 & Xi; R38-41 S: (2-)23-26-36/37/39-46-60- >=5%Conc<10%: Xn; R68; R36
83968-67-6 84196-22-5) N; R50-53 61 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Esbiothrin [(RS)-3-allyl-2-methyl-4-oxocyclopent-2-
enyl (1R, 3R)-2,2-dimethyl-3-(2-methylprop-1- Xn ; N ; R: 20/22 - 50/53,
enyl)cyclopropanecarboxylate](Note: see also CAS Xn; R20/22 S: (2) - 36 - 60 - 61
84030-86-4 584-79-2 & 28434-00-6) N; R50-53 Note: C Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Sodium 1-amino-4-[2-methyl-5-(4-
methylphenylsulfonylamino)phenylamino]- N ; R: 51/53,
84057-97-6 anthraquinone-2-sulfonate N; R51-53 S: 61 Eu - - - - - - - -
Xi ; R: 43 ,
84087-01-4 3,7-Dichloroquinoline-8-carboxylic acid Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
R: 10 - 66,
2(or 3)-Methylbutyl acetate(Note: see also CAS No R10 S: (2) - 23 - 25;
84145-37-9 123-92-2, 626-38-0, 624-41-99 & 628-63-7) R66 Note: C Eu; A - - - - - - - -
Conc>=25%: Xn; R68; R22; R38; R41
Muta. Cat. 3; R68 Xn; N >=20%Conc<25%: Xn; R68; R38; R41
Chrysoidine sulfate [Bis[4-(phenylazo)benzene-1,3- Xn; R22 R: 22-38-41-68-50/53 >=10%Conc<20%: Xn; R68; R41
diamine] sulfate](Note: see also CAS No. 532-82-1, Xi; R38-41 S: (2-)23-26-36/37/39-46-60- >=5%Conc<10%: Xn; R68; R36
84196-22-5 75660-25-2, 79234-33-6, 63681-54-9 & 83968-67-6) N; R50-53 61 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -
N-[6,9-Dihydro-9-[[2-hydroxy-1- Carc. Cat. 2; R45 T
(hydroxymethyl)ethoxy]methyl]-6-oxo-1H-purin-2- Muta. Cat. 2; R46 R: 45-46-60-61 Conc>=0.5%: T; R45; R46; R60; R61
84245-12-5 yl]acetamide Repr. Cat. 2; R60-61 S: 53-45 >=0.1%Conc<0.5%: T; R45; R46 Eu - - - - - - - -
Hexane-1,6-diyl bis(3-(3-benzotriazol-2-yl-5-tert-butyl- R53,
84268-08-6 4-hydroxyphenyl)propionate) R53 S: 61 Eu - - - - - - - -

Chlozolinate (ISO) [Ethyl (RS)-3-(3,5-dichlorophenyl)- Carc. Cat. 3; R40 Xn ; N ; R: 40 - 51/53

84332-86-5 5-methyl-2,4-dioxo-oxazolidine-5-carboxylate] N; R51-53 S: (2)36/37 - 61 Conc>=1%: Xn; R40 Eu - - - - - - - -
N ; R: 50/53,
84563-49-5 1,4-Bis[2-(vinyloxy)ethoxy] benzene N; R50-53 S: 60 - 61 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
84650-02-2 Distillates (coal tar), benzole fraction [Light oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Distillates (coal tar), light oils [Carbolic Oil](Note: A
complex combination of hydrocarbons obtained by
distillation of coal tar. It consists of aromatic and
other hydrocarbons, phenolic compounds and T
aromatic nitrogen compounds and distills at the R: 45-46
approximate range of 150 °C to 210 °C (302 °F to Carc. Cat. 2; R45 S: 53-45
84650-03-3 410 °F).) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (coal tar), naphthalene oils [Naphthalene

Oil](Note: A complex combination of hydrocarbons
obtained by the distillation of coal tar. It consists
primarily of aromatic and other hydrocarbons, T
phenolic compounds and aromatic nitrogen R: 45-46
compounds and distills in the approximate range of Carc. Cat. 2; R45 S: 53-45
84650-04-4 200 °C to 250 °C (392 °F to 482 °F).) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
84776-36-3 Fatty acids, C8-18 and C18-unsaturated, lead salts R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
1,2-Benzenedicarboxylic acid, dipentylester,
branched and linear (Note: see T; N
also CAS No. 131-18-0; 605-50-5 and n-Pentyl- Repr. Cat. 2; R60-61 R: 60-61-50
84777-06-0 isopentylphthalate) N; R50 S: 53-45-61 Conc>=0.5%: T; R60; R61 Eu - - - - - - - -
Xi Conc>=10%: Xi; R41; R43
N-[1-(S)-Ethoxycarbonyl-3-phenylpropyl]-L-alanyl-N- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
84793-24-8 carboxyanhydride R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Repr.Cat.3; R62
Repr.Cat.3; R63 C; N
Xn; R22 R: 22-34-62-63-50/53 Conc>=25%: C; R62; R63; R34; R22
4-Nonylphenol, branched (Note: see C; R34 S: (1/2-)26-36/37/39-45-46- >=10%Conc<25%: C; R62; 63; R34
84852-15-3 also CAS No. 25154-52-3 ) N; R50-53 60-61 >=5%Conc<10%: Xn; R62; R63; R36/38 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
84852-34-6 Isodecanoic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
84878-36-4 Isooctadecanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

Phenols, ammonia liquor ext. [Alkaline Extract](Note:

The combination of phenols extracted, using isobutyl
acetate, from the ammonia liquor condensed from
the gas evolved in low-temperature (less than 700 °C T
(1292 °F)) destructive distillation of coal. It consists R: 45-46
predominantly of a mixture of monohydric and Carc. Cat. 2; R45 S: 53-45
84988-93-2 dihydric phenols.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tar acids, ethylphenol fraction [Distillate T
Phenols](Note: The fraction of tar acids, rich in 3- and R: 45-46
4-ethylphenol, recovered by distillation of low- Carc. Cat. 2; R45 S: 53-45
84989-03-7 temperature coal tar crude tar acids.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tar acids, methylphenol fraction [Distillate T
Phenols](Note: The fraction of tar acid rich in 3- and 4- R: 45-46
methylphenol, recovered by distillation of low- Carc. Cat. 2; R45 S: 53-45
84989-04-8 temperature coal tar crude tar acids.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tar acids, polyalkylphenol fraction [Distillate
Phenols](Note: The fraction of tar acids, recovered by
distillation of low-temperature coal tar crude tar acids, T
having an approximate boiling range of 225 °C to 320 R: 45-46
°C (437 °F to 608 °F).Composed primarily of Carc. Cat. 2; R45 S: 53-45
84989-05-9 polyalkylphenols.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tar acids, xylenol fraction [Distillate Phenols](Note: T

The fraction of tar acids, rich in 2,4- and 2,5- R: 45-46
dimethylphenol, recovered by distillation of low- Carc. Cat. 2; R45 S: 53-45
84989-06-0 temperature coal tar crude tar acids.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Tar acids, 3,5-xylenol fraction [Distillate T
Phenols](Note: The fraction of tar acids, rich in 3,5- R: 45-46
dimethylphenol, recovered by distillation of low- Carc. Cat. 2; R45 S: 53-45
84989-07-1 temperature coal tar acids.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (coal tar), naphthalene oils, naphthalene-

low [Naphthalene Oil Redistillate](Note: A complex
combination of hydrocarbons obtained by T
crystallization of naphthalene oil.Composed primarily R: 45-46
of naphthalene, alkyl naphthalenes and phenolic Carc. Cat. 2; R45 S: 53-45
84989-09-3 compounds.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (coal tar), upper, fluorene free [Wash oil S: 53 - 45 ;
84989-10-6 redistillate] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (coal tar), upper, fluorene rich [Wash oil S: 53 - 45 ;
84989-11-7 redistillate] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 272
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Extract oils (coal), acidic, tar-base free

[Methylnaphthalene Oil Extract Residue](Note: The
extract oil boiling in the range of approximately 220
°C to 265 °C (428 °F to 509 °F) from coal tar alkaline T
extract residue produced by an acidic wash such as R: 45-46
aqueous sulfuric acid after distillation to remove tar Carc. Cat. 2; R45 S: 53-45
84989-12-8 bases. Composed primarily of alkylnaphthalenes.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (coal), coke-oven light oil, naphthalene cut

[Naphthalene Oil](Note: The complex combination of
hydrocarbons obtained from prefractionation T
(continuous distillation) of coke oven light oil. It R: 45-46
consists predominantly of naphthalene, coumarone Carc. Cat. 2; R45 S: 53-45
85029-51-2 and indene and boils above 148 °C (298 °F).) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
85029-74-9 Petrolatum (petroleum), alumina treated [Petrolatum] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrodesulfurized thermal S: 53 - 45 ;
85116-53-6 cracked middle Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Kerosine (petroleum), hydrodesulfurized thermal S: (2) - 23 - 24 - 62 ;
85116-55-8 cracked [Cracked kerosine] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
Naphtha (petroleum), catalytic reformed Xn ; R: 65 ,
hydrodesulfurized heavy, arom. fraction [Kerosene S: (2) - 23 - 24 - 62 ;
85116-57-0 unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

Distillates (petroleum), catalytic reformed

hydrotreated light, C8-12 arom. fraction [Low boiling
point cat-reformed naphtha](Note: A complex
combination of alkylbenzenes obtained by the
catalytic reforming of petroleum naphtha. It consists
predominantly of alkylbenzenes having carbon T
numbers predominantly in the range of C8 through Carc. Cat. 2; R45 R: 45-46-65
C10 and boiling in the range of approximately 160 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
85116-58-1 to 180 °C (320 °F to 356 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), catalytic reformed light, arom.-

free fraction [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons remaining after removal of aromatic
compounds from catalytic reformed light naphtha in a
selective absorption process. It consists
predominantly of paraffinic and cyclic compounds T
having carbon numbers predominantly in the range of Carc. Cat. 2; R45 R: 45-46-65
C5 to C8 and boiling in the range of approximately 66 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
85116-59-2 °C to 121 °C (151 °F to 250 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), hydrodesulfurized thermal

cracked light [Low boiling point hydrogen treated
naphtha](Note: A complex combination of
hydrocarbons obtained by fractionation of
hydrodesulfurized thermal cracker distillate. It
consists predominantly of hydrocarbons having T
carbon numbers predominantly in the range of C5 to Carc. Cat. 2; R45 R: 45-46-65
C11 and boiling in the range of approximately 23 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
85116-60-5 to 195 °C (73 °F to 383 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 273
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), hydrotreated light, cycloalkane-

contg. [Low boiling point hydrogen treated
naphtha](Note: A complex combination of
hydrocarbons obtained from the distillation of a T
petroleum fraction. It consists predominantly of Carc. Cat. 2; R45 R: 45-46-65
alkanes and cycloalkanes boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
85116-61-6 approximately -20 °C to 190 °C (-4 °F to 374 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Gas oils (petroleum), hydrodesulfurized coker heavy S: 53 - 45 ;
85117-03-9 vacuum [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
6-Hydroxy-1-(3-isopropoxypropyl)-4-methyl-2-oxo-5-[4
(phenylazo)phenylazo]-1,2-dihydro-3- Carc. Cat. 2; R45 T ; R: 45 - 53
85136-74-9 pyridinecarbonitrile R53 S: 53 - 45 - 61 Conc>=0.1%: T; R45 Eu - - - - - - - -
Hexasodium 6,13-dichloro-3,10-bis((4-(2,5-
disulfonatoanilino)-6-fluoro-1,3,5-triazin-2-
ylamino)prop-3-ylamino)-5,12-dioxa-7,14- Xn ; R: 42/43 ,
85153-92-0 diazapentacene-4,11-disulfonate Xn; R42/43 S: (2) - 22 - 24 - 37 Conc>=1%: Xn; R42/43 Eu - - - - - - - -
Disodium 1-amino-4-(4-benzenesulfonamido-3- Xi; R41 Xi ; R: 41 - 52/53 , Conc>=10%: Xi; R41
85153-93-1 sulfonatoanilino)anthraquinone-2-sulfonate R52-53 S: (2) - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Chrysoidine C10-14-alkyl derivatives Conc>=25%: Xn; R68; R22; R38; R41
[Benzenesulfonic acid, mono-C10-14-alkyl >=20%Conc<25%: Xn; R68; R38; R41
derivatives, compounds with 4-(phenylazo)-1,3- Muta. Cat. 3; R68 Xn >=10%Conc<20%: Xn; R68; R41
benzenediamine](Note: see also CAS No. 94247-67- Xn; R22 R: 22-38-41-68 >=5%Conc<10%: Xn; R68; R36
85407-90-5 3) Xi; R38-41 S: (2-)23-26-36/37/39-46 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, mono-C10-13-alkyl derivatives, Xn; R22 Xn >=10%Conc<20%: Xi; R41
85480-54-2 ammonium salts Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, mono-C10-13-alkyl derivatives, Xn; R22 Xn >=10%Conc<20%: Xi; R41
85480-55-3 compounds with ethanolamine Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, mono-C10-13-alkyl derivatives, Xn; R22 Xn >=10%Conc<20%: Xi; R41
85480-57-5 potassium salts Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
N ; R: 51/53 ,
85491-26-5 (Chloromethyl)bis(4-fluorophenyl)methylsilane N; R51-53 S: 61 Eu - - - - - - - -
Carc. Cat. 3; R40 T ; N ; R: 61 - 22 - 40 -
Repr. Cat. 2; R61 51/53 Conc>=25%: T; R61; R40; R22
Flusilazole (ISO) [Bis(4-fluorophenyl)(methyl)(1H- Xn; R22 S: 53 - 45 - 61; >=1%Conc<25%: T; R61; R40
85509-19-9 1,2,4-triazol-1-ylmethyl)silane] N; R51-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Carc. Cat. 3; R40 Xn; N
Alkanes, C10-13, chloro [Chlorinated paraffins, C10- R66 R: 40-66-50/53
85535-84-8 13] N; R50-53 S: (2-)24-36/37-46-60-61 Conc>=1%: Xn; R40 Eu - - - - - - - -
R64 N
Alkanes, C14-17, chloro [Chlorinated paraffins, C14- R66 R: 64-66-50/53
85535-85-9 17] N; R50-53 S: (2-)24-60-61 Conc>=1%: Xn; R64 Eu - - - - - - - -
T
R: 45-46
Solvent naphtha (coal), light [Light Oil Redistillate, Carc. Cat. 2; R45 S: 53-45
85536-17-0 low boiling] Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T
R: 45-46
Solvent naphtha (coal), coumarone-styrene contg. Carc. Cat. 2; R45 S: 53-45
85536-19-2 [Light Oil Redistillate, intermediate boiling] Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T
R: 45-46
Solvent naphtha (coal), xylene-styrene cut [Light Oil Carc. Cat. 2; R45 S: 53-45
85536-20-5 Redistillate, intermediate boiling] Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 274
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Hexasodium 7-(4-(4-(4-(2,5-disulphonatoanilino)-6-
fluoro-1,3,5-triazin-2-ylamino)-2-methylphenylazo)-7-
sulphonatonaphthylazo)naphthalene-1,3,5- Xi ; R: 43 ,
85665-96-9 trisulphonate Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Tetrasodium 5-benzamido-3-(5-(4-fluoro-6-(1-
sulphonato-2-naphthylamino)-1,3,5-triazin-2-ylamino)-
2-sulphonatophenylazo)-4-hydroxynaphthalene-2,7- Xi; R36/38 Xi ; R: 36/38 - 43 , Conc>=20%: Xi; R36/38; R43
85665-97-0 disulphonate [C.I. Reactive red 220] R43 S: (2) - 22 - 24/25 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Tetrasodium 4-amino-3,6-bis(5-[4-chloro-6-(2-
hydroxyethylamino)-1,3,5-triazin-2-ylamino]-2-
sulfonatophenylazo)-5-hydroxynaphthalene-2,7- N ; R: 51/53
85665-98-1 disulfonate N; R51-53 S: 61 Eu - - - - - - - -
S-(3-Trimethoxysilyl)propyl 19-isocyanato-11-(6-
isocyanatohexyl)-10,12-dioxo-2,9,11,13- R10 Xn ; R: 10 - 42/43 ,
85702-90-5 tetraazanonadecanethioate Xn; R42/43 S: (2) - 23 - 24 - 37 Conc>=1%: Xn; R42/43 Eu - - - - - - - -
Xn
2,2'-((3,3',5,5'-Tetramethyl-(1,1'-biphenyl)-4,4'-diyl)- Carc. Cat. 3; R40 R: 40-43
85954-11-6 bis(oxymethylene))-bis-oxirane R43 S: (2-)22-36/37 Conc>=1%: Xn; R40; R43 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R43
86273-46-3 2-Propenoic acid, 2-[2-(ethenyloxy)ethoxy]ethyl ester R43 R: 22-43 >=1%Conc<25%: Xi; R43 N - - - - - - - -
Gasoline [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons consisting primarily of paraffins,
cycloparaffins, aromatic and olefinic hydrocarbons T
having carbon numbers predominantly greater than Carc. Cat. 2; R45 R: 45-46-65
C3 and boiling in the range of 30 °C to 260 °C (86 °F Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
86290-81-5 to 500 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Conc>=25%: Xn; R22; R41; R43
Xn; R22 >=10%Conc<25%: Xi; R41; R43
2,4-Difluoro-alpha-(1H-1,2,4-triazol-1- Xi; R41 Xn ; R: 22 - 41 - 43 >=5%Conc<10%: Xi; R36; R43
86386-75-6 yl)acetophenone hydrochloride R43 S: (2 - )22 - 26 - 36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
7-Chloro-1-cyclopropyl-6-fluoro-1,4-dihydro-4- Xn; R22 Xn ; R: 22 - 52/53,
86393-33-1 oxoquinoline-3-carboxylic acid R52-53 S: (2) - 22 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Conc>=20%: Xi; R37/38; R41; R43
Xi; R37/38-41 Xi >=10%Conc<20%: Xi; R41; R43
R43 R: 37/38-41-43-52/53 >=5%Conc<10%: Xi; R36; R43
86393-34-2 2,4-Dichloro-5-fluorobenzoylchloride R52-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Disodium 6-((4-chloro-6-(n-methyl)-2-toluidino)-1,3,5-
triazin-2-ylamino)-1-hydroxy-2-(4-methoxy-2- Xi ; R: 43 ,
86393-35-3 sulphonatophenylazo)naphthalene-3-sulphonate Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture of: 2,2,6,6-tetramethylpiperidin-4-yl- Xi; R41 Xi; N Conc>=10%: Xi; R41; R43
hexadecanoate and 2,2,6,6-tetramethylpiperidin-4-yl- R43 R: 41-43-50/53 >=5%Conc<10%: Xi; R36; R43
86403-32-9 octadecanoate N; R50-53 S: (2-)24-26-37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn Conc>=10%: Xn; R40; R41
Carc.Cat.3; R40 R: 40-41 >=5%Conc<10%: Xn; R40; R36
86552-32-1 (4-Phenylbutyl)phosphinic acid Xi; R41 S: (2-)23-26-36/37/39 >=1%Conc<5%: Xn; R40 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R33
Xi; R41 >=10%Conc<25%: Xn; R41; R33
2-(1,3-Dioxolan-2-yl)ethyl)triphenylphosphonium R33 Xn ; R: 22 - 33 - 41 - 52/53 , >=5%Conc<10%: Xn; R36; R33
86608-70-0 bromide R52-53 S: (2) - 22 - 26 - 39 - 61 >=1%Conc<5%: Xn; R33 Eu - - - - - - - -
Xn
(Z)-2-(2-t-Butoxycarbonylamino-4-thiazolyl)pent-2- R: 22
86978-24-7 enoic acid Xn; R22 S: (2-)22 Conc>=25%: Xn; R22 Eu - - - - - - - -

Mixture of pentyl methylphosphinate and 2- C ; R: 34 , Conc>=10%: C; R34

87025-52-3 methylbutyl methylphosphinate C; R34 S: (1/2) - 26 - 36/37/39 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
3,5-Bis(3,5-di-tert-butyl-4-hydroxy)-benzyl)-2,4,6- R:52/53
87113-78-8 trimethylphenol R52-53 S: 61 Eu - - - - - - - -
Exo-4-isopropyl-1-methyl-1,4-epoxycyclohexan-2-ol Xn Conc>=25%: Xn; R22; R41
[Exo-1-methyl-4-(1-methylethyl)-7- Xn; R22 R: 22 - 41 >=10%Conc<25%: Xi; R41
87172-89-2 oxabicyclo[2.2.1]heptan-2-ol] Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi
R: 43
87199-17-5 4-Formylphenylboronic acid R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
2-Ethoxyethyl 2-(4-(3-chloro-5-trifluoromethyl-2-
pyridyloxy)phenoxy)propionate [Haloxyfop-(2- Xn; R22. Xn ; N ; R: 22 - 50/53 ,
87237-48-7 ethoxyethyl) (ISO)] N; R50-53 S: (2) - 22 - 36 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi; N
R43 R: 43-50/53
87333-22-0 Methyl 2-(acetylamino)-3-chloropropionate N; R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

S-Metachlor: A mixture of (S)-2-chloro-N-(2-ethyl-6-

methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-
acetamide (80-100%) and (R)-2-chloro-N-(2-ethyl-6- Xi; N
methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)- R43 N; R: 43-50/53
87392-12-9 acetamide (0-20%) (CAS No. 178961-20-1) R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
87460-09-1 Benzyl [hydroxy-(4-phenylbutyl)phosphinyl] acetate Xi; R41 S: (2-)26-36/39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Repr. Cat. 3; R62
Xn; R22 Conc>=25%: Xn; R62; R22; R36; R43
Xi; R36 Xn; N >=20%Conc<25%: Xn; R62; R36; R43
R43 R: 22-36-43-62-50/53 >=5%Conc<20%: Xn; R62; R43
87691-88-1 3-(Piperazin-1-yl)-benzo[d]isothiazole hydrochloride N; R50-53 S: (2-)22-26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi ; R: 43 ,
87731-18-8 Cyclooct-4-en-1-yl methyl carbonate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Carc. Cat. 1; R45 S: 53-45
87741-01-3 Hydrocarbons, C4 [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Conc>=25%: C; R35; R22
C ; R: 22 - 35 , >=10%Conc<25%: C; R35
C; R35 S: (1/2) - 26 - 28 - 36/37/39 - >=5%Conc<10%: C; R34
87787-67-5 7,7-Dimethyl-3-oxa-6-azaoctan-1-ol Xn; R22 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
Exo-(+/-)-1-methyl-2-(2-methylbenzyloxy)-4-isopropyl- Xn; R20 Xn ; N ; R: 20 - 51/53 ,
87818-31-3 7-oxabicyclo(2.2.1) heptane N; R51-53 S: (2) - 23 - 61 Conc>=25%: Xn; R20 Eu - - - - - - - -
tris(2-Ethylhexyl)-4,4',4''-(1,3,5-triazine-2,4,6- R: 53
88122-99-0 triyltriimino)tribenzoate R53 S: 61 Eu - - - - - - - -
Xn
Xn; R48/22 R: 48/22-52/53
88128-57-8 2-(3-Chloropropyl)-2,5,5-trimethyl-1,3-dioxane R52-53 S: (2-)23-25-36-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
T; R25 T; N Conc>=25%: T; R25; R48/22; R41
3-Ethyl 5-methyl 2-(2-aminoethoxymethyl)-4-(2- Xn; R48/22 R: 25-41-48/22-50/53 >=10%Conc<25%:Xn; R22; R48/22; R41
chlorophenyl)-1,4-dihydro-6-methyl-3,5- Xi; R41 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%:Xn; R22; R36
88150-42-9 pyridinedicarboxylate N; R50-53 61 >=3%Conc<5%:Xn; R22 Eu - - - - - - - -

3-Ethyl 5-methyl 4-(2-chlorophenyl)-1,4-dihydro-2-[2-

(1,3-dihydro-1,3-dioxo-(2H)isoindol-2-yl)- R: 53
88150-62-3 ethoxymethyl]-6-methyl-3,5-pyridinedicarboxylate R53 S: 61 Eu - - - - - - - -
Mixture of: 1-hexyl acetate; 2-methyl-1-pentyl
acetate; 3-methyl-1-pentyl acetate; 4-methyl-1-pentyl N
acetate and other mixed linear and branched C6-alkyl R: 51/53
88230-35-7 acetates N; R51-53 S: 61 Eu - - - - - - - -
Tetradecylammonium-bis(1-(5-chloro-1- Xn; R48/22 Xn ; R: 48/22 - 53 ,
88377-66-6 oxidophenylazo)-2-naphtholato)chromate(1-) R53 S: (2) - 22 - 36 - 61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Xn; R20 Conc>=25%: Xn; R20; R41
Xi; R41 Xn ; R: 20 - 41 - 52/53, >=10%Conc<25%: Xi; R41
88558-41-2 2-(3-Iodoprop-2-yn-1-yloxy)ethyl phenylcarbamate R52-53 S: (2) - 22 - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Repr. Cat. 3; R63
Xn; R22 Xn ; N ; R: 22 - 36 - 63 - Conc>=25%: Xn; R63; R22; R36
Myclobutanil [2-(4-Chlorophenyl)-2-(1H-1,2,4-triazol-1- Xi; R36 51/53, >=20%Conc<25%: Xn; R63; R36
88671-89-0 ylmethyl)hexanenitrile] N; R51-53 S: (2) - 36/37 - 46 - 61 >=5%Conc<20%: Xn; R63 Eu - - - - - - - -
Xi
(2S)-5-(Benzyloxy)-2-(1,3-dioxo-1,3-dihydro-2H- R: 36
88784-33-2 isoindol-2-yl)-5-oxopentanoic acid Xi; R36 S: (2-)26 Conc>=20%: Xi; R36 Eu - - - - - - - -

Page 276
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=20%: Xi; R38; R41; R43
Xi >=10%Conc<20%: Xi; R41; R43
Xi; R38-41 R: 38-41-43 >=5%Conc<10%: Xi; R36; R43
88805-65-6 Ethyl 3-hydroxy-5-oxo-3-cyclohexene-1-carboxylate R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; R41 Conc>=10%: Xi; R41; R43
(4-Aminophenyl)-N-methylmethylen-sulfonamide R43 Xi ; N ; R: 41 - 43 - 51/53, >=5%Conc<10%: Xi; R36; R43
88918-84-7 hydrochloride N; R51-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
N
R: 51/53
88938-23-2 2-Phenoxyethyl 4-aminobenzoate N; R51-53 S: 61 Eu - - - - - - - -

2-Phenoxyethyl 4-((5-cyano-1,6-dihydro-2-hydroxy- R: 53
88938-37-8 1,4-dimethyl-6-oxo-3-pyridinyl)azo)benzoate R 53 S: 61 Eu - - - - - - - -
R: 53
89114-90-9 4-(2,2-Diphenylethenyl)-N,N-di-phenylbenzenamine R 53 S: 61 Eu - - - - - - - -
6'-(Dibutylamino)-3'-methyl-2'-
(phenylamino)spiro[isobenzofuran-1(3H),9-(9H)- R: 52/53
89331-94-2 xanthen]-3-one R 52-53 S:61 Eu - - - - - - - -
Xi; N
R43 R:43 - 51/53
89392-03-0 Phenyl N-(4,6-dimethoxypyrimidin-2-yl)carbamate N; R51-53 S:(2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
R10 Xn
Xn; R22 R: 10 - 22 - 52/53
89402-43-7 5-Chloro-2,3-difluoropyridine R52-53 S: (2)23 - 36 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
O; R8 Conc>=25%: T; R23; R34; R22; R43
T; R23 >=10%Conc<25%: C; R34; R20; R43
C; R34 >=5%Conc<10%: Xn: R20; R36/38; R43
Xn; R22 O; T; N >=3%Conc<5%: Xn; R20; R43
R43 R: 8-22-23-34-43-50 >=1%Conc<3%: Xi; R43
89415-87-2 1,3-Dichloro-5-ethyl-5-methylimidazolidine-2,4-dione N; R50 S: (1/2-)8-26-36/37/39-45-61 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
2-(2,4-Dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)pent-4- Xi; R41 Xn ; N ; R: 22 - 41 - 51/53, >=10%Conc<25%: Xi; R41
89544-40-1 en-2-ol N; R51-53 S: (2) - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; R38
R43 Xi ; N ; R: 38 - 43 - 50/53 Conc>=20%: Xi; R38; R43
89544-48-9 2-(2,4-Dichlorophenyl)-2-(2-propenyl)oxirane N; R50-53 S: (2)24 - 37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

2-Mercaptobenzothiazolyl-(Z)-(2-aminothiazol-4-yl)-2- R: 53 S:
89604-92-2 (tert-butoxycarbonyl) isopropoxyiminoacetate R 53 61 Eu - - - - - - - -

(Trisodium (2-((3-(6-(2-chloro-5-sulfonato)anilino)-4-
(3-carboxypyridinio)-1,3,5-triazin-2-ylamino)-2-oxido-5-
sulfonatophenylazo)phenylmethylazo)-4- E; R2 E ; Xi ; R: 2 - 43 ,
89797-01-3 sulfonatobenzoato)copper(3-)) hydroxide Xi; R43 S: (2) - 22 - 24 - 35 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Hexasodium 1,1'-[(1-amino-8-hydroxy-3,6-disulfonate-
2,7-naphthalenediyl)bis(azo(4-sulfonate-1,3-
phenyl)imino[6-[(4-chloro-3-sulfonatophenyl)amino]-
1,3,5-triazin-2,4-diyl]]]bis[3-carboxypyridinium] N ; R: 51/53
89797-03-5 dihydroxide N; R51-53 S: 22 - 61 Eu - - - - - - - -

Mixture of cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4- T+ ; N ; R: 26/27/28 - Conc>=10%: T+; R26/27/28; R48/23/24/25

trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin T+; R26/27/28 48/23/24/25 - 50/53 >=7%Conc<10%: T+; R26/27/28; R48/20/21/22
and trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4- T; R48/23/24/25 S: (1/2) - 28 - 36/37/39 - 45 - >=1%Conc<7%: T; R23/24/25; R48/20/21/22
90035-08-8 trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R20/21/22 Eu - - - - - - - -

T; R24/25 T Conc>=25%: T; R24/25; R34; R48/22

Xn; R48/22 R: 24/25-34-48/22-52/53 >=10%Conc<25%: C; R34; R21/22; R48/22
C; R34 S: (1/2-)22-26-36/37/39-45- >=5%Conc<10%: Xn; R21/22; R36/38
90076-65-6 Lithium bis(trifluoromethylsulfonyl)imide R52-53 61 >=3%Conc<5%: Xn; R21/22 Eu - - - - - - - -

Page 277
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 1; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
90218-85-2 Benzoic acid, cadmium salt, basic Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

T; R48/23/25 Conc>=25%: T; R48/23/25; R22; R36; R43

Xn; R22 >=20%Conc<25%: T; R48/23/25; R36; R43
Xi; R36 >=10%Conc<20%: T; R48/23/25; R43
90274-24-1 Ractopamine hydrochloride R43 T ; R: 22 - 36 - 43 - 48/23/25 >=1%Conc<10%: Xn; R48/20/22; R43 V - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
90342-56-6 Dodecanoic acid, lead salt, basic R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xn; N
Xn; R48/22 R: 48/22-51/53
90357-53-2 N-[4-Cyano-3-trifluoromethylphenyl]methacrylamide N; R51-53 S: (2-)36-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
90388-09-3 Hexadecanoic acid, lead salt, basic R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
90388-15-1 9-Hexadecenoic acid, lead(2+) salt, (Z)-, basic R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
90411-62-4 Hexanoic acid, 2-ethyl-, cadmium salt, basic Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
90459-51-1 Octadecanoic acid, lead salt, basic R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
90459-88-4 9-Octadecenoic acid, lead salt, basic, (Z)- R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
3,9-Bis(2-(3-(3-tert-butyl-4-hydroxy-5-
methylphenyl)propionytoxy-1,1-dimethylethyl)- Xn ; R: 21,
90498-90-1 2,4,8,10-tetraoxaspiro[5.5]undecane Xn; R21 S: (2) - 36/37 Conc>=25%: Xn; R21 Eu - - - - - - - -

Page 278
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 1; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
90529-78-5 Propanoic acid, cadmium salt, basic Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
90583-65-6 Tetradecanoic acid, lead salt, basic R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
90622-53-0 Alkanes, C12-26 branched and linear Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Carc. Cat. 1; R45 S: 53-45
90622-55-2 Alkanes, C1-4, C3-rich [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Conc>=25%: T; R45; R46; R23; R38; R43
Carc. Cat. 2; R45 >=20%Conc<25%: T; R45; R46; R20; R38;
Anthracene oil(Note: R23 need not apply if it can be Muta. Cat. 2; R46 R43
shown that the anthracene oil contains less thaN 8 % T; R23 >=3%Conc<20%: T; R45; R46; R20; R43
pyrene; R20 applies for anthracene oils containing > Xi; R38 T >=1%Conc<3%: T; R45; R46; R43
90640-80-5 1 % pyrene) R43 R: 45-46-23-38-43 >=0.1%Conc<1%: T; R45; R46 N - - - - - - - -
Conc>=25%: T; R45; R46; R23; R38; R43
Carc. Cat. 2; R45 >=20%Conc<25%: T; R45; R46; R20; R38;
Anthracene oil, anthracene paste(Note: R23 need not Muta. Cat. 2; R46 R43
apply if it can be shown that the anthracene oil T; R23 >=3%Conc<20%: T; R45; R46; R20; R43
contains less thaN 8 % pyrene; R20 applies for Xi; R38 T >=1%Conc<3%: T; R45; R46; R43
90640-81-6 anthracene oils containing > 1 % pyrene) R43 R: 45-46-23-38-43 >=0.1%Conc<1%: T; R45; R46 N - - - - - - - -
Conc>=25%: T; R45; R46; R23; R38; R43
Carc. Cat. 2; R45 >=20%Conc<25%: T; R45; R46; R20; R38;
Anthracene oil, anthracene free(Note: R23 need not Muta. Cat. 2; R46 R43
apply if it can be shown that the anthracene oil T; R23 >=3%Conc<20%: T; R45; R46; R20; R43
contains less thaN 8 % pyrene; R20 applies for Xi; R38 T >=1%Conc<3%: T; R45; R46; R43
90640-82-7 anthracene oils containing > 1 % pyrene) R43 R: 45-46-23-38-43 >=0.1%Conc<1%: T; R45; R46 N - - - - - - - -

Creosote oil, acenaphthene fraction [Wash Oil](Note:

A complex combination of hydrocarbons produced by
the distillation of coal tar and boiling in the range of T
approximately 240 °C to 280 °C (464 °F to 536 °F). R: 45
Composed primarily of acenaphthene, naphthalene S: 53-45
90640-84-9 and alkyl naphthalene.) Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Creosote oil, acenaphthene fraction, acenaphthene-

free [Wash Oil Redistillate](Note: The oil remaining
after removal by a crystallization process of T
acenaphthene from acenaphthene oil from coal tar. R: 45
Composed primarily of naphthalene and S: 53-45
90640-85-0 alkylnaphthalenes.) Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
90640-86-1 Distillates (coal tar), heavy oils [Heavy anthracene oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Distillates (coal tar), light oils, acid exts. [Light Oil

Extract Residues, high boiling](Note: This oil is a
complex mixture of aromatic hydrocarbons, primarily T
indene, naphthalene, coumarone, phenol, and o-, m- R: 45-46
and p-cresol and boiling in the range of 140 °C to 215 Carc. Cat. 2; R45 S: 53-45
90640-87-2 °C (284 °F to 419 °F).) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Distillates (coal tar), light oils, alk. exts. [Alkaline

Extract](Note: The aqueous extract from carbolic oil T
produced by an alkaline wash such as aqueous R: 45-46
sodium hydroxide. Composed primarily of the alkali Carc. Cat. 2; R45 S: 53-45
90640-88-3 salts of various phenolic compounds.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (coal tar), naphthalene oils, alk. exts.

[Alkaline Extract](Note: The aqueous extract from T
naphthalene oil produced by an alkaline wash such R: 45-46
as aqueous sodium hydroxide. Composed primarily Carc. Cat. 2; R45 S: 53-45
90640-89-4 of the alkali salts of various phenolic compounds.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (coal tar), naphthalene oils, naphthalene-

free, alk. exts. [Naphthalene Oil Extract
Residue](Note: The oil remaining after the removal of T
phenolic compounds (tar acids) from drained R: 45-46
naphthalene oil by an alkali wash. Composed Carc. Cat. 2; R45 S: 53-45
90640-90-7 primarily of naphthalene and alkyl naphthalenes.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), complex dewaxed heavy S: 53 - 45 ;
90640-91-8 paraffinic [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), complex dewaxed light S: 53 - 45 ;
90640-92-9 paraffinic [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), highly refined middle [Gasoil S: 53 - 45 ;
90640-93-0 unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent dewaxed heavy S: 53 - 45 ;
90640-94-1 paraffinic, clay treated [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C20-50, solvent dewaxed heavy S: 53 - 45 ;
90640-95-2 paraffinic, hydrotreated [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent dewaxed light S: 53 - 45 ;
90640-96-3 paraffinic, clay treated [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent dewaxed light S: 53 - 45 ;
90640-97-4 paraffinic, hydrotreated [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Aromatic hydrocarbons C>=10, steam cracking, S: (2) - 23 - 24 - 62 ;
90640-98-5 hydrotreated [Cracked kerosine] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

Extract oils (coal), light oil [Acid Extract](Note: The

aqueous extract produced by an acidic wash of alkali- T
washed carbolic oil. Composed primarily of acid salts R: 45-46
of various aromatic nitrogen bases including pyridine, Carc. Cat. 2; R45 S: 53-45
90640-99-6 quinoline and their alkyl derivatives.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract oils (coal), naphthalene oils [Acid

Extract](Note: The aqueous extract produced by an
acidic wash of alkali-washed naphthalene oil. T
Composed primarily of acid salts of various aromatic R: 45-46
nitrogen bases including pyridine, quinoline and their Carc. Cat. 2; R45 S: 53-45
90641-00-2 alkyl derivatives.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract residues (coal), light oil alk., acid ext.

[Carbolic Oil Extract Residue](Note: The oil resulting
from the acid washing of alkali-washed carbolic oil to T
remove the minor amounts of basic compounds (tar R: 45-46
bases). Composed primarily of indene, indan and Carc. Cat. 2; R45 S: 53-45
90641-01-3 alkylbenzenes.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 280
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Extract residues (coal), light oil alk., distn. overheads

[Light Oil Extract Residues, low boiling](Note: The
first fraction from the distillation of aromatic
hydrocarbons, coumarone, naphthalene and indene
rich prefractionator bottoms or washed carbolic oil T
boiling substantially below 145 °C (293 R: 45-46
°F).Composed primarily of C7 and C8 aliphatic and Carc. Cat. 2; R45 S: 53-45
90641-02-4 aromatic hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract residues (coal), light oil alk., indene naphtha

fraction [Light Oil Extract Residues, high
boiling](Note: The distillate from aromatic
hydrocarbons, coumarone, naphthalene and indene
rich prefractionator bottoms or washed carbolic oils, T
having an approximate boiling range of 155 °C to 180 R: 45-46
°C (311 °F to 356 °F).Composed primarily of indene, Carc. Cat. 2; R45 S: 53-45
90641-03-5 indan and trimethylbenzenes.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract residues (coal), naphthalene oil alk., distn.

overheads [Naphthalene Oil Extract Residue](Note:
The distillate from alkali-washed naphthalene oil T
having an approximate distillation range of 180 °C to R: 45-46
220 °C (356 °F to 428 °F). Composed primarily of Carc. Cat. 2; R45 S: 53-45
90641-04-6 naphthalene, alkylbenzenes, indene and indan.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract residues (coal), naphthalene oil alk., distn.

residues [Methylnaphthalene Oil Extract
Residue](Note: The residue from the distillation of
alkali-washed naphthalene oil having an approximate T
distillation range of 220 °C to 300 °C (428 °F to 572 R: 45-46
°F). Composed primarily of naphthalene, Carc. Cat. 2; R45 S: 53-45
90641-05-7 alkylnaphthalenes and aromatic nitrogen bases.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract residues (coal), tar oil alk., carbonated, limed

[Crude Phenols](Note: The product obtained by T
treatment of coal tar oil alkaline extract with CO2 and R: 45-46
CaO. Composed primarily of CaCO3, Ca(OH)2, Carc. Cat. 2; R45 S: 53-45
90641-06-8 Na2CO3 and other organic and inorganic impurities.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Extracts (petroleum), heavy naphthenic distillate T ; R: 45 ,
solvent, hydrotreated [Distillate aromatic extract S: 53 - 45 ;
90641-07-9 (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
Extracts (petroleum), heavy paraffinic distillate T ; R: 45 ,
solvent, hydrotreated [Distillate aromatic extract S: 53 - 45 ;
90641-08-0 (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Extracts (petroleum), light paraffinic distillate solvent, S: 53 - 45 ;
90641-09-1 hydrotreated [Distillate aromatic extract (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Light oil (coal), semi-coking process [Fresh oil](Note:

The volatile organic liquid condensed from the gas T
evolved in the low-temperature (less than 700 °C R: 45-46
(1292 °F)) destructive distillation of coal. Composed Carc. Cat. 2; R45 S: 53-45
90641-11-5 primarily of C6-10 hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Naphtha (coal), distn. residues [Light Oil Redistillate,

high boiling](Note: The residue remaining from the T
distillation of recovered naphtha. Composed primarily R: 45-46
of naphthalene and condensation products of indene Carc. Cat. 2; R45 S: 53-45
90641-12-6 and styrene.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Xn ; R: 65 ,
Naphtha (petroleum), steam cracked, hydrotreated, S: (2) - 23 - 24 - 62 ;
90641-13-7 C9-10 arom. rich [Cracked kerosene] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

Page 281
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: Xn; R62; R22; R38; R41; R43

Repr. Cat. 3; R62 >=20%Conc<25%: Xn; R62; R38; R41; R43
Xn; R22 >=10%Conc<20%: Xn; R62; R41; R43
Xi; R38-41 Xn ; R: 22 - 38 - 41 - 43 - 62 >=5%Conc<10%: Xn; R62; R36; R43
90657-55-9 trans-4-Cyclohexyl-L-proline monohydrochloride R43 S: (2)22 - 26 - 36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
90669-57-1 Pitch, coal tar, low temperature [Pitch residue] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Pitch, coal tar, low temp., heat treated [Pitch residue, S: 53 - 45 ;
90669-58-2 heat treated; Pitch residue, oxidised] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Pitch, coal tar, low temp., oxidized [Pitch residue S: 53 - 45 ;
90669-59-3 oxidized; Pitch residue] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residual oils (petroleum), hydrotreated solvent S: 53 - 45 ;
90669-74-2 dewaxed [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), steam cracked, distillates S: 53 - 45 ;
90669-75-3 [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
90669-76-4 Residues (petroleum), vacuum, light [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
90669-77-5 Slack wax (petroleum), acid treated [Slack wax] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
90669-78-6 Slack wax (petroleum), clay treated [Slack wax] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
Xi; R43 Xi ; N ; R: 43 - 51/53 ,
90884-29-0 4,4'-Oxybis(ethylenethio)diphenol N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
C
C; R34 R: 22-34-52/53 Conc>=25%: C; R34; R22
Xn; R22 S: (1/2-)23-26-36/37/39-45- >=10%Conc<25%: C; R34
90886-53-6 Methyl 3-amino-2,2,3-trimethylbutyrate R52-53 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
T
R: 45-46
Aromatic hydrocarbons, C8 [Light Oil Redistillate, Carc. Cat. 2; R45 S: 53-45
90989-38-1 high boiling] Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T
Carc. Cat. 2; R45 R: 45-46-65
Aromatic hydrocarbons, C8-10 [Low boiling point Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
90989-39-2 naphtha — unspecified] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T
R: 45-46
Aromatic hydrocarbons, C6-10, C8-rich [Light Oil Carc. Cat. 2; R45 S: 53-45
90989-41-6 Redistillate, low boiling] Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T
Aromatic hydrocarbons, C7-8, dealkylation products, Carc. Cat. 2; R45 R: 45-46-65
distn. residues [Low boiling point naphtha — Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
90989-42-7 unspecified] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T
R: 45-46
Carc. Cat. 2; R45 S: 53-45
91079-47-9 Phenols, C9-11 [Distillate Phenols] Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
91082-50-7 Tar, coal, storage residues [Coal tar solids residue] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T
R: 45-46
Carc. Cat. 2; R45 S: 53-45
91082-52-9 Tar bases, coal, lutidine fraction [Distillate Bases] Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 282
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T
R: 45-46
Carc. Cat. 2; R45 S: 53-45
91082-53-0 Tar bases, coal, toluidine fraction [Distillate Bases] Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Xi Conc>=10%: Xi; R41; R43
Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
91125-43-8 Sodium 2-(nonanoyloxy)benzenesulfonate R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
C; R34 C ; N ; R: 34 - 43 - 51/53, Conc>=10%: C; R34; R43
N,N-Bis(2-ethylhexyl)-((1,2,4-triazol-1- R43 S: (1/2) - 26 - 28 - 36/37/39 - >=5%Conc<10%: Xi; R36/38; R43
91273-04-0 yl)methyl)amine N; R51-53 45 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
lambda-Cyhalothrin (ISO) [1:1Mixture of (S)-alpha-
cyano-3-phenoxybenzyl(Z)-(1R)-cis-3-(2-chloro-3,3,3-
trifluoropropenyl)-2,2- Conc>=25%: T+; R26; R25; R21
dimethylcyclopropanecarboxylate and (R)-alpha- T+; R26 T+; N >=7%Conc<25%: T+; R26; R22
cyano-3-phenoxybenzyl (Z)-(1S)-cis-3-(2-chloro-3,3,3- T; R25 R: 21-25-26-50/53 >=3%Conc<7%: T; R23; R22
trifluoropropenyl)-2,2- Xn; R21 S: (1/2-)28-36/37/39-38-45- >=1%Conc<3%: T; R23
91465-08-6 dimethylcyclopropanecarboxylate] N; R50-53 60-61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
91671-82-8 Isodecanoic acid, lead(2+) salt, basic R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
91671-83-9 Isooctanoic acid, lead(2+) salt, basic R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
91671-84-0 Isoundecanoic acid, lead(2+) salt, basic R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xi ; R43,
91673-30-2 Formaldehyde, reaction products with butylphenol Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41
>=20%Conc<25%: Xi; R38; R41
Benzenesulfonic acid, 4-C10-14-alkyl derivatives, Xn; R22 Xn >=10%Conc<20%: Xi; R41
91696-66-1 sodium salts Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
91697-23-3 Extracts residues (coal), brown [Coal tar extracts] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
91697-35-7 Fatty acids, castor oil, hydrogenated, cadmium salts Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
91697-36-8 Fatty acids, castor oil, hydrogenated, lead salts R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Xn ; R: 65 ,
Kerosine (petroleum), sweetened [Kerosine S: (2) - 23 - 24 - 62 ;
91770-15-9 unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 45 ,
Residual oils (petroleum), catalytic dewaxed [Baseoil S: 53 - 45 ;
91770-57-9 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

T; R48/25 T; N Conc>=25%: T; R48/25; R22

Tetrakis(1,2,2,6,6-pentamethyl-4-piperidyl)-1,2,3,4- Xn; R22 R: 22-48/25-50/53 >=10%Conc<25%: T; R48/25
91788-83-9 butanetetracarboxylate N; R50-53 S: (1/2-)22-36-45-57-60-61 >=1%Conc<10%: Xn; R48/22 Eu - - - - - - - -
4,8,12-Trimethyltrideca-3,7,11-trienoic acid, mixed Xi; R38 Xi ; N ; R: 38 - 50/53 ,
91853-67-7 isomers N; R50-53 S: (2) - 37/39 - 60 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
T ; R: 45 ,
Anthracene oil, acid ext. [Anthracene oil extract S: 53 - 45 ;
91995-14-1 residue] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Anthracene oil, anthracene paste, anthracene

fraction [Anthracene Oil Fraction](Note: A complex
combination of hydrocarbons from the distillation of
anthracene obtained by the crystallization of
anthracene oil from bituminous high temperature tar T
and boiling in the range of 330 °C to 350 °C (626 °F R: 45-46
to 662 °F). It contains chiefly anthracene, carbazole Carc. Cat. 2; R45 S: 53-45
91995-15-2 and phenanthrene.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Anthracene oil, anthracene paste, carbazole fraction

[Anthracene Oil Fraction](Note: A complex
combination of hydrocarbons from the distillation of
anthracene obtained by crystallization of anthracene
oil from bituminous coal high temperature tar and T
boiling in the approximate range of 350 °C to 360 °C R: 45-46
(662 °F to 680 °F). It contains chiefly anthracene, Carc. Cat. 2; R45 S: 53-45
91995-16-3 carbazole and phenanthrene.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Anthracene oil, anthracene paste, distn. lights

[Anthracene Oil Fraction](Note: A complex
combination of hydrocarbons from the distillation of
anthracene obtained by crystallization of anthracene
oil from bituminous high temperature tar and boiling T
in the range of approximately 290 °C to 340 °C (554 R: 45-46
°F to 644 °F). It contains chiefly trinuclear aromatics Carc. Cat. 2; R45 S: 53-45
91995-17-4 and their dihydro derivatives.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T
Carc. Cat. 2; R45 R: 45-46-65
Aromatic hydrocarbons, C8, catalytic reforming- Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
91995-18-5 derived [Low boiling point cat-reformed naphtha] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Aromatic hydrocarbons, C8-9, hydrocarbon resin

polymn. by-product [Light Oil Redistillate, high
boiling](Note: A complex combination of
hydrocarbons obtained from the evaporation of
solvent under vacuum from polymerized hydrocarbon
resin. It consists predominantly of aromatic
hydrocarbons having carbon numbers predominantly T
in the range of C8 through C9 and boiling in the R: 45-46
range of approximately 120 °C to 215 °C (248 °F to Carc. Cat. 2; R45 S: 53-45
91995-20-9 419 °F).) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

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Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Distillates (petroleum), alkene-alkyne manuf.

pyrolysis oil, mixed with high-temp. coal tar, indene
fraction [Redistillates](Note: A complex combination
of hydrocarbons obtained as a redistillate from the
fractional distillation of bituminous coal high
temperature tar and residual oils that are obtained by
the pyrolytic production of alkenes and alkynes from T
petroleum products or natural gas. It consists R: 45-46
predominantly of indene and boils in a range of Carc. Cat. 2; R45 S: 53-45
91995-31-2 approximately 160 °C to 190 °C (320 °F to 374 °F).) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), catalytic reformer, heavy S: 53 - 45 ;
91995-34-5 arom. conc. [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -

Distillates (coal), coal tar-residual pyrolysis oils,

naphthalene oils [Redistillates](Note: The redistillate
obtained from the fractional distillation of bituminous
coal high temperature tar and pyrolysis residual oils T
and boiling in the range of approximately 190 °C to R: 45-46
270 °C (374 °F to 518 °F). Composed primarily of Carc. Cat. 2; R45 S: 53-45
91995-35-6 substituted dinuclear aromatics.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C4-6, depentanizer lights, arom.

hydrotreater [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons obtained as first runnings from the
depentanizer column before hydrotreatment of the
aromatic charges. It consists predominantly of
hydrocarbons having carbon numbers predominantly T
in the range of C4 through C6, predominantly Carc. Cat. 2; R45 R: 45-46-65
pentanes and pentenes, and boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
91995-38-9 approximately 25 °C to 40 °C (77 °F to 104 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), dewaxed heavy paraffinic, S: 53 - 45 ;
91995-39-0 hydrotreated [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), dewaxed light paraffinic, S: 53 - 45 ;
91995-40-3 hydrotreated [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Distillates (petroleum), heat-soaked steam-cracked

naphtha, C5-rich [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons obtained by distillation of heat-soaked T
steam-cracked naphtha. It consists predominantly of Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons having carbon numbers in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
91995-41-4 C4 through C6, predominantly C5.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (coal tar), heavy oils, pyrene fraction S: 53 - 45 ;
91995-42-5 [Heavy anthracene oil redistillate] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrocracked solvent refined, S: 53 - 45 ;
91995-45-8 dewaxed [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Distillates (coal tar), naphthalene oils, acid exts.

[Methylnaphthalene Oil Extract Residue](Note: A
complex combination of hydrocarbons obtained by
debasing the methylnaphthalene fraction obtained by
the distillation of coal tar and boiling in the range of T
approximately 230 °C to 255 °C (446 °F to 491 °F). R: 45-46
Contains chiefly 1(2)-methylnaphthalene, Carc. Cat. 2; R45 S: 53-45
91995-48-1 naphthalene, dimethylnaphthalene and biphenyl.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (coal tar), naphthalene oil crystn. mother

liquor [Naphthalene Oil Redistillate](Note: A complex
combination of organic compounds obtained as a
filtrate from the crystallization of the naphthalene
fraction from coal tar and boiling in the range of T
approximately 200 °C to 230 °C (392 °F to 446 °F). R: 45-46
Contains chiefly naphthalene, thionaphthene and Carc. Cat. 2; R45 S: 53-45
91995-49-2 alkylnaphthalenes.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (petroleum), naphtha steam cracking-

derived, hydrotreated light arom. [Low boiling point
cat-cracked naphtha](Note: A complex combination T
of hydrocarbons obtained by treating a light distillate Carc. Cat. 2; R45 R: 45-46-65
from steam-cracked naphtha. It consists Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
91995-50-5 predominantly of aromatic hydrocarbons.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (coal tar), pitch, heavy oils [Heavy S: 53 - 45 ;
91995-51-6 anthracene oil] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (coal tar), pitch, pyrene fraction [Heavy S: 53 - 45 ;
91995-52-7 anthracene oil redistillate] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
Distillates (petroleum), naphtha steam cracking-
derived, solvent-refined light hydrotreated [Low
boiling point modified naphtha](Note: A complex
combination of hydrocarbons obtained as the T
raffinates from a solvent extraction process of Carc. Cat. 2; R45 R: 45-46-65
hydrotreated light distillate from steam-cracked Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
91995-53-8 naphtha.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent refined light S: 53 - 45 ;
91995-54-9 naphthenic, hydrotreated [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Extract residues (coal), benzole fraction alk., acid ext.

[Light Oil Extract Residues, low boiling](Note: The
redistillate from the distillate, freed of tar acids and
tar bases, from bituminous coal high temperature tar T
boiling in the approximate range of 90 °C to 160 °C R: 45-46
(194 °F to 320 °F). It consists predominantly of Carc. Cat. 2; R45 S: 53-45
91995-61-8 benzene, toluene and xylenes.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract oils (coal), coal tar-residual pyrolysis oils,

naphthalene oil, redistillate [Redistillates](Note: The
redistillate from the fractional distillation of
dephenolated and debased methylnaphthalene oil
obtained from bituminous coal high temperature tar
and pyrolysis residual oils boiling in the approximate T
range of 220 °C to 230 °C (428 °F to 446 °F). It R: 45-46
consists predominantly of unsubstituted and Carc. Cat. 2; R45 S: 53-45
91995-66-3 substituted dinuclear aromatic hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Extracts (petroleum), catalytic reformed light naphtha

solvent [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons obtained as the extract from the
solvent extraction of a catalytically reformed
petroleum cut. It consists predominantly of aromatic
hydrocarbons having carbon numbers predominantly T
in the range of C7 through C8 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 100 °C to 200 °C (212 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
91995-68-5 392 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Extracts (petroleum), hydrotreated light paraffinic S: 53 - 45 ;
91995-73-2 distillate solvent [Distillate aromatic extract (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
Extracts (petroleum), light naphthenic distillate T ; R: 45 ,
solvent, hydrodesulfurized [Distillate aromatic extract S: 53 - 45 ;
91995-75-4 (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Extracts (petroleum), light paraffinic distillate solvent, S: 53 - 45 ;
91995-76-5 acid treated [Distillate aromatic extract (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
Extracts (petroleum), light paraffinic distillate solvent, T ; R: 45 ,
hydrodesulfurized [Distillate aromatic extract S: 53 - 45 ;
91995-77-6 (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

T
R: 45
91995-78-7 Extracts (petroleum), light vacuum gas oil solvent Carc. Cat. 2; R45 S: 53-45; Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Extracts (petroleum), light vacuum gas oil solvent, S: 53 - 45 ;
91995-79-8 hydrotreated [Distillate aromatic extract (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
92045-12-0 Foots oil (petroleum), hydrotreated [Foots oil] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
92045-14-2 Fuel oil, heavy, high sulfur [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Gases (petroleum), gas oil diethanolamine scrubber
off [Refinery gas](Note: A complex combination
produced by desulfurization of gas oils with
diethanolamine. It consists predominantly of F+; T
hydrogen sulfide, hydrogen and aliphatic F+; R12 R: 45-46-12
hydrocarbons having carbon numbers in the range of Carc. Cat. 1; R45 S: 53-45
92045-15-3 C1 through C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), gas oil hydrodesulfurization

effluent [Refinery gas](Note: A complex combination
obtained by separation of the liquid phase from the
effluent from the hydrogenation reaction. It consists F+; T
predominantly of hydrogen, hydrogen sulfide and F+; R12 R: 45-46-12
aliphatic hydrocarbons having carbon numbers Carc. Cat. 1; R45 S: 53-45
92045-16-4 predominantly in the range of C1 through C3.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), gas oil hydrodesulfurization purge

[Refinery gas](Note: A complex combination of gases
obtained from the reformer and from the purges from
the hydrogenation reactor. It consists predominantly F+; T
of hydrogen and aliphatic hydrocarbons having F+; R12 R: 45-46-12
carbon numbers predominantly in the range of C1 Carc. Cat. 1; R45 S: 53-45
92045-17-5 through C4.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 287
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Gases (petroleum), hydrogenator effluent flash drum
off [Refinery gas](Note: A complex combination of
gases obtained from flash of the effluents after the
hydrogenation reaction. It consists predominantly of F+; T
hydrogen and aliphatic hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
92045-18-6 C6.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Gases (petroleum), naphtha steam cracking high-

pressure residual [Refinery gas](Note: A complex
combination obtained as a mixture of the non-
condensable portions from the product of a naphtha
steam cracking process as well as residual gases
obtained during the preparation of subsequent
products. It consists predominantly of hydrogen and F+; T
paraffinic and olefinic hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
92045-19-7 C5 with which natural gas may also be mixed.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), residue visbaking off [Refinery
gas](Note: A complex combination obtained from
viscosity reduction of residues in a furnace. It
consists predominantly of hydrogen sulfide and F+; T
paraffinic and olefinic hydrocarbons having carbon F+; R12 R: 45-46-12
numbers predominantly in the range of C1 through Carc. Cat. 1; R45 S: 53-45
92045-20-0 C5.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Gases (petroleum), steam-cracker C3-rich
[Petroleum gas](Note: A complex combination of
hydrocarbons produced by the distillation of products
from a steam cracking process. It consists F+; T
predominantly of propylene with some propane and F+; R12 R: 45-46-12
boils in the range of approximately -70 °C to 0 °C (-94 Carc. Cat. 1; R45 S: 53-45
92045-22-2 °F to 32 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C4, steam-cracker distillate

[Petroleum gas](Note: A complex combination of
hydrocarbons produced by the distillation of the
products of a steam cracking process. It consists
predominantly of hydrocarbons having a carbon
number of C4, predominantly 1-butene and 2-butene, F+; T
containing also butane and isobutene and boiling in F+; R12 R: 45-46-12
the range of approximately minus 12 °C to 5 °C (10.4 Carc. Cat. 1; R45 S: 53-45
92045-23-3 °F to 41 °F).) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Gas oils (petroleum), thermal cracked, S: 53 - 45 ;
92045-29-9 hydrodesulfurized [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Kerosine (petroleum), solvent refined sweetened S: (2) - 23 - 24 - 62 ;
92045-36-8 [Kerosine unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
Xn ; R: 65 ,
Kerosine (petroleum), straight run wide cut [Straight S: (2) - 23 - 24 - 62 ;
92045-37-9 run kerosine] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T ; R: 45 ,
Lubricating oils (petroleum), C17-35, solvent extd., S: 53 - 45 ;
92045-42-6 dewaxed, hydrotreated [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Lubricating oils (petroleum), hydrocracked nonarom. S: 53 - 45 ;
92045-43-7 solvent deparaffined [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 288
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), C4-12 butane-alkylate,

isooctane-rich [Low boiling point modified
naphtha](Note: A complex combination of
hydrocarbons obtained by alkylation of butanes. It
consists predominantly of hydrocarbons having
carbon numbers predominantly in the range of C4 T
through C12, rich in isooctane, and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 35 °C to 210 °C (95 °F to 410 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-49-3 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), heavy catalytic cracked,

sweetened [Low boiling point cat-cracked
naphtha](Note: A complex combination of
hydrocarbons obtained by subjecting a catalytic
cracked petroleum distillate to a sweetening process
to convert mercaptans or to remove acidic impurities.
It consists predominantly of hydrocarbons having T
carbon numbers predominantly in the range of C6 Carc. Cat. 2; R45 R: 45-46-65
through C12 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-50-6 60 °C to 200 °C (140 °F to 392 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T
Naphtha (petroleum), heavy steam-cracked, Carc. Cat. 2; R45 R: 45-46-65
hydrogenated [Low boiling point hydrogen treated Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-51-7 naphtha] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), hydrodesulfurized full-range

[Low boiling point hydrogen treated naphtha](Note: A
complex combination of hydrocarbons obtained from
a catalytic hydrodesulfurization process. It consists
predominantly of hydrocarbons having carbon T
numbers predominantly in the range of C4 through Carc. Cat. 2; R45 R: 45-46-65
C11 and boiling in the range of approximately 30 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-52-8 to 250 °C (86 °F to 482 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), hydrodesulfurized light,

dearomatized [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons obtained by distillation of
hydrodesulfurized and dearomatized light petroleum T
fractions. It consists predominantly of C7 paraffins Carc. Cat. 2; R45 R: 45-46-65
and cycloparaffins boiling in a range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-53-9 90 °C to 100 °C (194 °F to 212 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, hydrotreated light naphtha distillates,

solvent-refined [Low boiling point modified
naphtha](Note: A combination of hydrocarbons
obtained from the distillation of hydrotreated naphtha
followed by a solvent extraction and distillation T
process. It consists predominantly of saturated Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons boiling in the range of approximately 94 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-55-1 °C to 99 °C (201 °F to 210 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 289
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), hydrotreated light steam-

cracked [Low boiling point hydrogen treated
naphtha](Note: A complex combination of
hydrocarbons obtained by treating a petroleum
fraction, derived from a pyrolysis process, with
hydrogen in the presence of a catalyst. It consists
predominantly of unsaturated hydrocarbons having T
carbon numbers predominantly in the range of C5 Carc. Cat. 2; R45 R: 45-46-65
through C11 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-57-3 35 °C to 190 °C (95 °F to 374 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), isomerization, C6-fraction [Low

boiling point modified naphtha](Note: A complex
combination of hydrocarbons obtained by distillation
of a gasoline which has been catalytically isomerized. T
It consists predominantly of hexane isomers boiling in Carc. Cat. 2; R45 R: 45-46-65
the range of approximately 60 °C to 66 °C (140 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-58-4 151 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light catalytic cracked

sweetened [Low boiling point cat-cracked
naphtha](Note: A complex combination of
hydrocarbons obtained by subjecting naphtha from a
catalytic cracking process to a sweetening process to
convert mercaptans or to remove acidic impurities. It T
consists predominantly of hydrocarbons boiling in a Carc. Cat. 2; R45 R: 45-46-65
range of approximately 35 °C to 210 °C (95 °F to 410 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-59-5 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light, C5-rich, sweetened [Low

boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons obtained by
subjecting a petroleum naphtha to a sweetening
process to convert mercaptans or to remove acidic
impurities. It consists of hydrocarbons having carbon T
numbers predominantly in the range of C4 through Carc. Cat. 2; R45 R: 45-46-65
C5, predominantly C5, and boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-60-8 approximately minus 10 °C to 35 °C (14 °F to 95 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C4-12, naphtha-cracking,

hydrotreated [Low boiling point hydrogen treated
naphtha](Note: A complex combination of
hydrocarbons obtained by distillation from the product
of a naphtha steam cracking process and
subsequent catalytic selective hydrogenation of gum
formers. It consists of hydrocarbons having carbon T
numbers predominantly in the range of C4 through Carc. Cat. 2; R45 R: 45-46-65
C12 and boiling in the range of approximately 30 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-61-9 to 230 °C (86 °F to 446 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C8-11, naphtha-cracking, toluene cut

[Low boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons obtained by
distillation from prehydrogenated cracked naphtha. It
consists predominantly of hydrocarbons having T
carbon numbers predominantly in the range of C8 Carc. Cat. 2; R45 R: 45-46-65
through C11 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-62-0 130 °C to 205 °C (266 °F to 401 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Hydrocarbons, C4-11, naphtha-cracking, arom.-free

[Low boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons obtained from
prehydrogenated cracked naphtha after distillative
separation of benzene- and toluene-containing
hydrocarbon cuts and a higher boiling fraction. It
consists predominantly of hydrocarbons having T
carbon numbers predominantly in the range of C4 Carc. Cat. 2; R45 R: 45-46-65
through C11 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-63-1 30 °C to 205 °C (86 °F to 401 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C6-7, naphtha-cracking, solvent-

refined [Low boiling point modified naphtha](Note: A
complex combination of hydrocarbons obtained by
the sorption of benzene from a catalytically fully
hydrogenated benzene-rich hydrocarbon cut that was
distillatively obtained from prehydrogenated cracked
naphtha. It consists predominantly of paraffinic and
naphthenic hydrocarbons having carbon numbers T
predominantly in the range of C6 through C7 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately 70 °C to 100 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-64-2 (158 °F to 212 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light thermal cracked,

sweetened [Low boiling point thermally cracked
naphtha](Note: A complex combination of
hydrocarbons obtained by subjecting a petroleum
distillate from the high temperature thermal cracking
of heavy oil fractions to a sweetening process to
convert mercaptans. It consists predominantly of T
aromatics, olefins and saturated hydrocarbons boiling Carc. Cat. 2; R45 R: 45-46-65
in the range of approximately 20 °C to 100 °C (68 °F Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92045-65-3 to 212 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Paraffin waxes (coal), brown coal high temp. tar [Coal S: 53 - 45 ;
92045-71-1 tar extracts] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Paraffin waxes (coal), brown coal high temp. tar, S: 53 - 45 ;
92045-72-2 hydrotreated [Coal tar extracts] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
92045-77-7 Petrolatum (petroleum), hydrotreated [Petrolatum] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -

Petroleum gases, liquefied, sweetened, C4 fraction

[Petroleum gas](Note: A complex combination of
hydrocarbons obtained by subjecting a liquified
petroleum gas mix to a sweetening process to oxidize F+; T
mercaptans or to remove acidic impurities. It consists F+; R12 R: 45-46-12
predominantly of C4 saturated and unsaturated Carc. Cat. 1; R45 S: 53-45
92045-80-2 hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residual oils (petroleum), hydrocracked acid treated S: 53 - 45 ;
92061-86-4 solvent dewaxe [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Residues (coal tar), anthracene oil distn. [Anthracene

Oil Fraction](Note: The residue from the fraction
distillation of crude anthracene boiling in the T
approximate range of 340 °C to 400 °C (644 °F to R: 45-46
752 °F). It consists predominantly of tri- and Carc. Cat. 2; R45 S: 53-45
92061-92-2 polynuclear aromatic and heterocyclic hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Residues (coal tar), creosote oil distn. [Wash Oil

Redistillate](Note: The residue from the fractional
distillation of wash oil boiling in the approximate T
range of 270 °C to 330 °C (518 °F to 626 °F). It R: 45
consists predominantly of dinuclear aromatic and S: 53-45
92061-93-3 heterocyclic hydrocarbons.) Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
92061-94-4 Residues (coal tar), pitch distn. [Pitch redistillate] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), catalytic cracking [Heavy fuel S: 53 - 45 ;
92061-97-7 oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), hydrogenated steam cracked S: 53 - 45 ;
92062-00-5 naphtha [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), steam cracked naphtha distn. S: 53 - 45 ;
92062-04-9 [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
92062-09-4 Slack wax (petroleum), hydrotreated [Slack wax] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
92062-10-7 Slack wax (petroleum), low melting [Slack wax] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Slack wax (petroleum), low melting, hydrotreated S: 53 - 45 ;
92062-11-8 [Slack wax] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -

Solvent naphtha (petroleum), hydrotreated light

naphthenic [Low boiling point hydrogen treated
naphtha](Note: A complex combination of
hydrocarbons obtained by treating a petroleum
fraction with hydrogen in the presence of a catalyst. It
consists predominantly of cycloparaffinic
hydrocarbons having carbon numbers predominantly T
in the range of C6 through C7 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 73 °C to 85 °C (163 °F to 185 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92062-15-2 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Tar, coal, high temp., distn. and storage residues S: 53 - 45 ;
92062-20-9 [Coal tar solids residue] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
Tar acids, brown-coal gasification [Crude
Phenols](Note: A complex combination of organic T
compounds obtained from brown coal gasification. R: 45-46
Composed primarily of C6-10 hydroxy aromatic Carc. Cat. 2; R45 S: 53-45
92062-22-1 phenols and their homologs.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tar acids, cresylic [Distillate Phenols](Note: A

complex combination of organic compounds obtained T
from brown coal and boiling in the range of R: 45-46
approximately 200 °C to 230 °C (392 °F to 446 °F). It Carc. Cat. 2; R45 S: 53-45
92062-26-5 contains chiefly phenols and pyridine bases.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tar bases, coal, aniline fraction [Distillate

Bases](Note: The distillation fraction boiling in the
range of approximately 180 °C to 200 °C (356 °F to
392 °F) from the crude bases obtained by T
dephenolating and debasing the carbolated oil from R: 45-46
the distillation of coal tar. It contains chiefly aniline, Carc. Cat. 2; R45 S: 53-45
92062-27-6 collidines, lutidines and toluidines.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 292
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Tar bases, coal, collidine fraction [Distillate

Bases](Note: The distillation fraction boiling in the
range of approximately 181 °C to 186 °C (356 °F to
367 °F) from the crude bases obtained from the T
neutralized, acid-extracted base-containing tar R: 45-46
fractions obtained by the distillation of bituminous Carc. Cat. 2; R45 S: 53-45
92062-28-7 coal tar. It contains chiefly aniline and collidines.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tar bases, coal, distn. residues [Distillate

Bases](Note: The distillation residue remaining after
the distillation of the neutralized, acid-extracted base- T
containing tar fractions obtained by the distillation of R: 45-46
coal tars. It contains chiefly aniline, collidines, Carc. Cat. 2; R45 S: 53-45
92062-29-8 quinoline and quinoline derivatives and toluidines.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tar bases, coal, picoline fraction [Distillate

Bases](Note: Pyridine bases boiling in the range of
approximately 125 °C to 160 °C (257 °F 320 °F)
obtained by distillation of neutralized acid extract of T
the base-containing tar fraction obtained by the R: 45-46
distillation of bituminous coal tars. Composed chiefly Carc. Cat. 2; R45 S: 53-45
92062-33-4 of lutidines and picolines.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Waste solids, coal tar pitch coking [Coal tar solids S: 53 - 45 ;
92062-34-5 residue] Carc. Cat. 2; R45 Notes: H; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T
R: 45-46
Aromatic hydrocarbons, C9-12, benzene distn. [Light Carc. Cat. 2; R45 S: 53-45
92062-36-7 Oil Redistillate, high boiling] Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C8-12, catalytic-cracking, chem.

neutralized [Low boiling point cat-cracked
naphtha](Note: A complex combination of
hydrocarbons produced by the distillation of a cut
from the catalytic cracking process, having
undergone an alkaline washing. It consists
predominantly of hydrocarbons having carbon T
numbers in the range of C8 through C12 and boiling Carc. Cat. 2; R45 R: 45-46-65
in the range of approximately 130 °C to 210 °C (266 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92128-94-4 °F to 410 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Paraffin oils (petroleum), solvent refined dewaxed S: 53 - 45 ;
92129-09-4 heavy [Coal tar extracts] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), intermediate catalytic cracked, S: 53 - 45 ;
92201-59-7 thermally degraded [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), light catalytic cracked, S: 53 - 45 ;
92201-60-0 thermally degraded [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Imidazolium compounds, 2-(C9-19 and C9-19-
unsatd. alkyl)-1-[(C10-20 and C10-20-unsatd. Xi
92201-88-2 amido)ethyl]-4,5-dihydro-1-Me, Me sulfates Xi; R38 R: 38 Conc>=20%: Xi; R38 N - - - - - - - -

Naphtha (petroleum), light heat-soaked, steam-

cracked [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons obtained by the fractionation of steam
cracked naphtha after recovery from a heat soaking
process. It consists predominantly of hydrocarbons T
having a carbon number predominantly in the range Carc. Cat. 2; R45 R: 45-46-65
of C4 through C6 and boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
92201-97-3 approximately 0 °C to 80 °C (32 °F to 176 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Page 293
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Trisodium 5-benzamido-4-hydroxy-3-(4-methyl-2- R: 52/53

92408-46-3 sulfonatophenylazo)naphthalene-2,7-disulfonate R52-53 S: 61 Eu - - - - - - - -
Sodium 3-(2H-benzotriazol-2-yl)-5-sec-butyl-4- Xi ; R: 41 , Conc>=10%: Xi; R41
92484-48-5 hydroxybenzenesulfonate Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Disodium N-carboxymethyl-N-(2-(2- Xi ; R: 41 , Conc>=10%: Xi; R41
92511-22-3 hydroxyethoxy)ethyl)glycinate Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; R43 Xi ; N ; R: 43 - 51/53 ,
92585-24-5 2-Methyl-4-phenylpentanol N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Dodecyl 3-(2-(3-benzyl-4-ethoxy-2,5-
dioxoimidazolidin-1-yl)-4,4-dimethyl-3-oxovaleramido)- R: 53
92683-20-0 4-chlorobenzoate R53 S: 61 Eu - - - - - - - -
Extracts (petroleum), heavy paraffinic distillate T ; R: 45 ,
solvent, clay-treated [Distillate aromatic extract S: 53 - 45 ;
92704-08-0 (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
(E-E)-3,3'-(1,4-Phenylenedimethylidene)bis(2- Xi ; R41, Conc>=10%: Xi; R41
92761-26-7 oxobornane-10-sulfonic acid) Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

4-[4-(2,2-Dimethyl-propanamido)]phenylazo-3-(2- Xi
chloro-5-(2-(3-pentadecylphenoxy)butylamido)anilino)- R43 R: 43-53
92771-56-7 1-(2,4,6-trichlorophenyl)-2-pyrazoline-5-one R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn ; N ; R: 22 - 48/22 -
1-(2,3-Dihydro-1,3,3,6-tetramethyl-1-(1-methylethyl)- Xn; R22-48/22 51/53 Conc>=25%: Xn; R22; R48/22
92836-10-7 1H-inden-5-yl)ethanone N; R51-53 S: (2)24 - 36 - 61 >=10%Conc<25%: Xn; R48/22 Eu - - - - - - - -
Xi; R38 Xi ; N ; R: 38 - 51/53
92952-81-3 4-[(3-Hydroxypropyl)amino]-3-nitrophenol N; R51-53 S: (2)37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -

2'-Anilino-6'-((3-ethoxypropyl)ethylamino)-3'- R: 53,
93071-94-4 methylspiro(isobenzo-3-oxofuran)-1-(1 H)-9'-xanthene R53 S: 61 Eu - - - - - - - -
Conc>=25%: T; R25; R68/21; R48/22; R41;
R43
T; R25 T; N >=10%Conc<25%: Xn; R22; R68/21; R48/22;
Xn; R68/21-48/22 R: 25-41-43-48/22-68/21- R41; R43
Xi; R41 51/53 >=5%Conc<10%: Xn; R22; R36; R43
3-(2-Chloroethyl)-6,7,8,9-tetra-hydro-2-methyl-4H- R43 S: (1/2-)22-26-36/37/39-45- >=3%Conc<5%: Xn; R22; R43
93076-03-0 pyrido[1,2-a]pyrimidin-4-one monohydrochloride N; R51-53 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
1-Cyclopropyl-6,7-difluoro-1,4-dihydro-4-oxoquinoline- Repr. Cat. 3; R62 Xn ; R: 62 - 52/53
93107-30-3 3-carboxylic acid R52-53 S: (2) - 22 - 36/37 - 61 Conc>=5%: Xn; R62 Eu - - - - - - - -

Distillates (petroleum), C6-rich [Low boiling point

naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained from the
distillation of a petroleum feedstock. It consists
predominantly of hydrocarbons having carbon T
numbers of C5 through C7, rich in C6, and boiling in Carc. Cat. 2; R45 R: 45-46-65
the range of approximately 60 °C to 70 °C (140 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
93165-19-6 158 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
93165-26-5 Fatty acids, C14-26, lead salts R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), light steam-cracked,

hydrogenated [Low boiling point hydrogen treated
naphtha](Note: A complex combination of
hydrocarbons produced from the separation and
subsequent hydrogenation of the products of a steam-
cracking process to produce ethylene. It consists
predominantly of saturated and unsaturated paraffins,
cyclic paraffins and cyclic aromatic hydrocarbons
having carbon numbers predominantly in the range of
C4 through C10 and boiling in the range of
approximately 50 °C to 200 °C (122 °F to 392 °F).The T
proportion of benzene hydrocarbons may vary up to Carc. Cat. 2; R45 R: 45-46-65
30 wt. % and the stream may also contain small Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
93165-55-0 amounts of sulfur and oxygenated compounds.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Aromatic hydrocarbons, C7-12, C8-rich [Low boiling

point cat-reformed naphtha](Note: A complex
combination of hydrocarbons obtained by separation
from the platformate-containing fraction. It consists
predominantly of aromatic hydrocarbons having
carbon numbers predominantly in the range of C7
through C12 (primarily C8) and can contain T
nonaromatic hydrocarbons, both boiling in the range Carc. Cat. 2; R45 R: 45-46-65
of approximately 130 °C to 200 °C (266 °F to 392 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
93571-75-6 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Gasoline, C5-11, high-octane stabilized reformed

[Low boiling point cat-reformed naphtha](Note: A
complex high octane combination of hydrocarbons
obtained by the catalytic dehydrogenation of a
predominantly naphthenic naphtha. It consists
predominantly of aromatics and non-aromatics T
having carbon numbers predominantly in the range of Carc. Cat. 2; R45 R: 45-46-65
C5 through C11 and boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
93572-29-3 approximately 45 °C to 185 °C (113 °F to 365 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C7-12, C >9-arom.-rich, reforming

heavy fraction [Low boiling point cat-reformed
naphtha](Note: A complex combination of
hydrocarbons obtained by separation from the
platformate-containing fraction. It consists
predominantly of nonaromatic hydrocarbons having
carbon numbers predominantly in the range of C7 T
through C12 and boiling in the range of approximately Carc. Cat. 2; R45 R: 45-46-65
120 °C to 210 °C (248 °F to 380 °F) and C9 and Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
93572-35-1 higher aromatic hydrocarbons.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C5-11, nonaroms.-rich, reforming light

fraction [Low boiling point cat-reformed
naphtha](Note: A complex combination of
hydrocarbons obtained by separation from the
platformate-containing fraction. It consists
predominantly of nonaromatic hydrocarbons having
carbon numbers predominantly in the range of C5 T
through C11 and boiling in the range of approximately Carc. Cat. 2; R45 R: 45-46-65
35 °C to 125 °C (94 °F to 257 °F), benzene and Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
93572-36-2 toluene.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Lubricating oils (petroleum), base oils, paraffinic S: 53 - 45 ;
93572-43-1 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 295
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
N ; R: 51/53,
93589-69-6 4-4'-Methylenebis(oxyethylenethio)diphenol N; R51-53 S: 61 Eu - - - - - - - -
Muta.Cat.3; R68
Xi; R41 Xn Conc>=10%: Xn; R68; R41; R43
R43 R: 41-43-68-52/53 >=5%Conc<10%: Xn; R68; R36; R43
93629-90-4 1,3-Bis(Vinylsulfonylacetamido)propane R 52-53 S: (2-)22-26-36/37/39-61 >=1%Conc<5%: Xn; R68; R43 Eu - - - - - - - -

3-(N-Methyl-N-(4-methylamino-3- Xn; R22 Xn ; R: 22 - 52/53 ,

93633-79-5 nitrophenyl)amino)propane-1,2-diol hydrochloride R52-53 S: (2) - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
F; R11
Xn; R22 F ; Xn ; R: 11 - 22 - 41 - 43 - Conc>=25%: Xn; R22; R41; R43
Xi; R41 52/53 >=10%Conc<25%: Xi; R41; R43
2,5-Dibutoxy-4-(morpholin-4-yl)benzenediazonium 4- R43 S: (2)12 - 22 - 24 - 26 - >=5%Conc<10%: Xi; R36; R43
93672-52-7 methylbenzenesulfonate R52-53 37/39 - 47 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
93686-40-9 Nonanoic acid, branched, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
1,4-Diamino-2-(2-butyltetrazol-5-yl)-3- R: 53,
93686-63-6 cyanoanthraquinone R53 S: 61 Eu - - - - - - - -
Extracts (petroleum), heavy naphthenic distillate T ; R: 45 ,
solvent, hydrodesulfurized [Distillate aromatic extract S: 53 - 45 ;
93763-10-1 (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
Extracts (petroleum), solvent dewaxed heavy T ; R: 45 ,
paraffinic distillate solvent, hydrodesulfurized S: 53 - 45 ;
93763-11-2 [Distillate aromatic extract (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Hydrocarbons, C6-11, hydrotreated, dearomatized

[Low boiling point hydrogen treated naphtha](Note: A
complex combination of hydrocarbons obtained as T
solvents which have been subjected to Carc. Cat. 2; R45 R: 45-46-65
hydrotreatment in order to convert aromatics to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
93763-33-8 naphthenes by catalytic hydrogenation.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C9-12, hydrotreated, dearomatized

[Low boiling point hydrogen treated naphtha](Note: A
complex combination of hydrocarbons obtained as T
solvents which have been subjected to Carc. Cat. 2; R45 R: 45-46-65
hydrotreatment in order to convert aromatics to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
93763-34-9 naphthenes by catalytic hydrogenation.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Xn ; R: 65 ,
Hydrocarbons, , C9-16, hydrotreated, dearomatized S: (2) - 23 - 24 - 62 ;
93763-35-0 [Kerosine unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, , hydrocracked paraffinic distn. S: 53 - 45 ;
93763-38-3 residues, solvent dewaxed [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), steam cracked heat soaked S: 53 - 45 ;
93763-85-0 naphtha [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Extract residues (coal), benzole fraction acid [Light

Oil Extract Residues, low boiling](Note: An acid T
sludge by-product of the sulfuric acid refining of crude R: 45-46
high temperature coal. Composed primarily of sulfuric Carc. Cat. 2; R45 S: 53-45
93821-38-6 acid and organic compounds.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
93821-66-0 Residual oils (petroleum) [Heavy fuel oil] Carc. Cat. 2; R45 Notes: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 296
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
93858-24-3 9-Hexadecenoic acid, lead(2+) salt, (Z)- R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
93924-31-3 Foots oil (petroleum), acid treated Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
93924-32-4 Foots oil (petroleum), clay treated Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
93924-33-5 Gas oils, paraffinic [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C20-50, residual oil hydrogenation S: 53 - 45 ;
93924-61-9 vacuum distillate [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Trisodium-bis(2-(5-chloro-4-nitro-2-oxidophenylazo)-5- Xi; R41 Xi ; R: 41 - 52/53 , Conc>=10%: Xi; R41

93952-24-0 sulfonato-1-naphtholato)chromate(1-) R52-53 S: (2) - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
R: 53 S:
93957-49-4 N-Isopropyl-3-(4-fluorophenyl)-1H-indole R 53 61 Eu - - - - - - - -
Xi; N
3-[3-(4-Fluorophenyl)-1-(1-methylethyl)-1H-indol-2-yl]- R43 R: 43-50/53
93957-50-7 (E)-2-propenal N; R50-53 S: (2-)22-24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
93965-24-3 Isodecanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
93965-29-8 Isoundecanoic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
93965-30-1 Isoundecanoic acid, cadmium salt Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
93966-37-1 Tricosanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
93966-38-2 Tetracosanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Page 297
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Phthalocyanine-N-[3- R: 52/53
93971-95-0 (diethylamino)propyl]sulfonamide copper complex R52-53 S: 61 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
93981-67-0 Isooctanoic acid, lead(2+) salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Pentasodium 5-anilino-3-(4-(4-(6-chloro-4-(3-
sulphonatoanilino)-1,3,5-triazin-2-ylamino)-2,5-
dimethylphenylazo)-2,5-disulphonatophenylazo)-4- Xi ; R: 36 ,
93983-23-4 hydroxynaphthalene-2,7-disulphonate Xi; R36 S: (2) - 22 - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
94006-20-9 Hexacosanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -

Conc>=25%: T+; R26; R48/25; R22;

R36/37/38; R43
T+; R26 >=20%Conc<25%: T+; R26; R48/25;
T; R48/25 T+ ; N ; R: 22 - 26 - R36/37/38; R43
Xn; R22 36/37/38 - 43 - 48/25 - >=10%Conc<20%: T+; R26; R48/25; R43
6,7-Dihydrodipyrido[1,2-alpha:2’,1’-c]pyrazinediylium Xi; R36/37/38 50/53, >=7%Conc<10%: T+; R26; R48/22; R43
dihydroxide(Note: see also CAS No 85-00-7 & 4032- R43 S: (1/2) - 28 - 36/37/39 - 45 - >=1%Conc<7%: T; R23; R48/22; R43
94021-76-8 26-2) N; R50-53 60 - 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
Xn; R22
4-Chlorophenyl cyclopropyl ketone O-(4- R43 Xn ; N ; R: 22 - 43 - 50/53 Conc>=25%: Xn; R22; R43
94050-51-8 aminobenzyl)oxime N; R50-53 S: (2)24 - 37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xi ; R: 41, Conc>=10%: Xi; R41
94050-90-5 (R)-2-(4-Hydroxyphenoxy)propanoic acid Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
(E,Z)-4-Chlorophenyl(cyclopropyl)ketone O-(4- R43 Xi ; N ; R: 43 - 50/53
94097-88-8 nitrophenylmethyl)oxime N; R50-53 S: (2)24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Gasoline, pyrolysis, hydrogenated [Low boiling point
naphtha-unspecified](Note: A distillation fraction from T
the hydrogenation of pyrolysis gasoline boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 20 °C to 200 °C (68 °F to 392 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
94114-03-1 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Pitch, coal tar, high temp., secondary [Pitch S: 53 - 45 ;
94114-13-3 redistillate] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Tar acids, brown-coal, C2-alkylphenol fraction

[Distillate Phenols](Note: The distillate from the
acidification of alkaline washed lignite tar distillate T
boiling in the range of approximately 200 °C to 230 R: 45-46
°C (392 °F to 446 °F). Composed primarily of m- and Carc. Cat. 2; R45 S: 53-45
94114-29-1 p-ethylphenol as well as cresols and xylenols.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tar oils, brown-coal [Light Oil](Note: The distillate

from lignite tar boiling in the range of approximately T
80 °C to 250 °C (176 °F to 482 °F). Composed R: 45-46
primarily of aliphatic and aromatic hydrocarbons and Carc. Cat. 2; R45 S: 53-45
94114-40-6 monobasic phenols.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
94114-46-2 Residues (coal), liq. solvent extn. Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
94114-47-3 Coal liquids, liq. solvent extn. soln. Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 298
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 45 ,
S: 53 - 45 ;
94114-48-4 Coal liquids, liq. solvent extn. Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Distillates (coal), liq. solvent extn., primary(Note: The

liquid product of condensation of vapors emitted
during the digestion of coal in a liquid solvent and
boiling in the range of approximately 30 °C to 300 °C
(86 °F to 572 °F). Composed primarily of partly
hydrogenated condensed-ring aromatic
hydrocarbons, aromatic compounds containing T
nitrogen, oxygen and sulfur, and their alkyl R: 45-46
derivatives having carbon numbers predominantly in Carc. Cat. 2; R45 S: 53-45
94114-52-0 the range of C4 through C14.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (coal), solvent extn., hydrocracked(Note:

Distillate obtained by hydrocracking of coal extract or
solution produced by the liquid solvent extraction or
supercritical gas extraction processes and boiling in
the range of approximately 30 °C to 300 °C (86 °F to
572 °F). Composed primarily of aromatic,
hydrogenated aromatic and naphthenic compounds,
their alkyl derivatives and alkanes with carbon
numbers predominantly in the range of C4 through T
C14. Nitrogen, sulfur and oxygen-containing aromatic R: 45-46
and hydrogenated aromatic compounds are also Carc. Cat. 2; R45 S: 53-45
94114-53-1 present.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Naphtha (coal), solvent extn., hydrocracked(Note:

Fraction of the distillate obtained by hydrocracking of
coal extract or solution produced by the liquid solvent
extraction or supercritical gas extraction processes
and boiling in the range of approximately 30 °C to
180 °C (86 °F to 356 °F). Composed primarily of
aromatic, hydrogenated aromatic and naphthenic
compounds, their alkyl derivatives and alkanes with
carbon numbers predominantly in the range of C4 to T
C9. Nitrogen, sulfur and oxygen-containing aromatic R: 45-46
and hydrogenated aromatic compounds are also Carc. Cat. 2; R45 S: 53-45
94114-54-2 present.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
94114-55-3 Gasoline, coal solvent extn., hydrocracked naphtha Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -

Distillates (coal), solvent extn., hydrocracked

middle(Note: Distillate obtained from the
hydrocracking of coal extract or solution produced by
the liquid solvent extraction or supercritical gas
extraction processes and boiling in the range of
approximately 180 °C to 300 °C (356 °F to 572 °F.
Composed primarily of two-ring aromatic,
hydrogenated aromatic and naphthenic compounds,
their alkyl derivatives and alkanes having carbon T
numbers predominantly in the range of C9 through R: 45-46
C14. Nitrogen, sulfur and oxygen-containing Carc. Cat. 2; R45 S: 53-45
94114-56-4 compounds are also present.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 299
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Distillates (coal), solvent extn., hydrocracked

hydrogenated middle(Note: Distillate from the
hydrogenation of hydrocracked middle distillate from
coal extract or solution produced by the liquid solvent
extraction or supercritical gas extraction processes
and boiling in the range of approximately 180 °C to
280 °C (356 °F to 536 °F). Composed primarily of T
hydrogenated two- ring carbon compounds and their R: 45-46
alkyl derivatives having carbon numbers Carc. Cat. 2; R45 S: 53-45
94114-57-5 predominantly in the range of C9 through C14.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Xn ; R: 40 ,
Fuels, jet aircraft, coal solvent extn., hydrocracked S: (2) - 36/37 ;
94114-58-6 hydrogenated Carc. Cat. 3; R40 Note: H Conc>=1%: Xn; R40 Eu - - - - - - - -
Xn ; R: 40 ,
Fuels, diesel, coal solvent extn., hydrocracked S: (2) - 36/37 ;
94114-59-7 hydrogenated Carc. Cat. 3; R40 Note: H Conc>=1%: Xn; R40 Eu - - - - - - - -
Prosulfuron (ISO) [1-(4-Methoxy-6-methyl-1,3,5- Xn; N
triazin-2-yl)-3-[2-(3,3,3- Xn; R22 R: 22-50/53
94125-34-5 trifluoropropyl)phenylsulfonyl]urea] N; R50-53 S: (2-)60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi; R38 Xi Conc>=20%: Xi; R38; R43
94201-73-7 2H-Pyran, tetrahydro-4-methyl-2-phenyl- R43 R: 38-43 >=1%Conc<20%: Xi; R43 N - - - - - - - -
R10 Xn
Xn; R20/22 R: 10-20/22-52/53
94239-04-0 2-Fluoro-6-trifluoromethylpyridine R52-53 S: (2-)16-61 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
Conc>=25%: Xn; R68; R22; R38; R41
Chrysoidine compound with dibutylnaphthalene >=20%Conc<25%: Xn; R68; R38; R41
sulfonic acid [Dibutylnaphthalenesulfonic acid, Muta. Cat. 3; R68 Xn >=10%Conc<20%: Xn; R68; R41
compound with 4-(phenylazo)benzene-1,3-diamine Xn; R22 R: 22-38-41-68 >=5%Conc<10%: Xn; R68; R36
94247-67-3 (1:1)](Note: see also CAS No. 85407-90-5) Xi; R38-41 S: (2-)23-26-36/37/39-46 >=1%Conc<5%: Xn; R68 Eu - - - - - - - -
Butanamide, 2,2'-[[1,1'-biphenyl]-4,4'- Carc. Cat. 2; R45 T Conc>=5%: T; R45; R63
94249-03-3 diylbis(azo)]bis[N-(4-chlorophenyl)-3-oxo- Repr. Cat. 3; R63 R: 45-63 >=0.1%Conc<5%: T; R45 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
94266-31-6 Eicosanoic acid, lead(2+) salt (2:1) R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Carc. Cat. 3; R40
Muta. Cat. 3; R68 Conc>=25%: T; R40; R61; R62; R68; R20/22;
Repr. Cat. 1; R61 R33
Repr. Cat. 3; R62 >=5%Conc<25%: T; R40; R61; R62; R68; R33
Xn; R20/22 T >=1%Conc<5%: T; R40; R61; R68; R33
94266-32-7 Eicosanoic acid, lead salt R33 R: 61-20/22-33-40-62-68 >=0.5%Conc<1%: T; R61 N - - - - - - - -
Repr.Cat.3; R62 Xn; R: 41-62 Conc>=10%: Xn; R62; R41
94317-64-3 N-(n-Butyl) thiophosphoric triamide [NBPT] Xi; R41 S: 25-26-36/37/39 >=5%Conc<10%: Xn; R62; R36 N - - - - - - - -
Xi; N
Xi; R38 R: 38-51/53
94346-09-5 1,2-Dimethyl-3-(1-methylethenyl)cyclopentyl acetate N; R51-53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Cyproconazole (ISO)(2RS,3RS;2RS,3SR)-2-(4- Repr. Cat. 3; R63 Xn; N
chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1- Xn; R22 R: 22 - 50/53 - 63 Conc>=25%: Xn; R22; R63
94361-06-5 yl)butan-2-ol N; R50-53 S:(2)36/37 - 60 - 61 >=5%Conc<25%: Xn; R63 Eu - - - - - - - -

Conc>=25%: T; R23-48/23; R22; R36/37; R43

>=20%Conc<25%: T; R48/23; R20; R36/37;
T; R23-48/23 R43
Xn; R22 T ; R: 22 - 23 - 36/37 - 43 - >=10%Conc<20%: T; R48/23; R20; R43
Sodium 4-(2,4,4- Xi; R36/37 48/23, >=3%Conc<10%: Xn; R20-48/20; R43
94612-91-6 trimethylpentylcarbonyloxy)benzenesulphonate R43 S: (1/2) - - 22 - 24 - 36 - 45 >=1%Conc<3%: Xn; R48/20; R43 Eu - - - - - - - -
Repr.Cat.2; R60 T
Xn; R22 R: 60-22-43-52/53 Conc>=25%: T; R60; R22; R43
2-Butyryl-3-hydroxy-5-thiocyclohexan-3-yl-cyclohex-2- R43 S: 53-45-61 >=1%Conc<25%: T; R60; R43
94723-86-1 en-1-one R52-53 Note: E >=0.5%Conc<1%: T; R60 Eu - - - - - - - -

Page 300
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
T ; R: 45 ,
Distillates (petroleum), solvent refined hydrotreated S: 53 - 45 ;
94733-08-1 heavy, hydrogenated Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent refined hydrocracked S: 53 - 45 ;
94733-09-2 light [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
Lubricating oils (petroleum), C18-40, solvent T ; R: 45 ,
dewaxed hydrocracked distillate based [Baseoil S: 53 - 45 ;
94733-15-0 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
Lubricating oils (petroleum), C18-40, solvent T ; R: 45 ,
dewaxed hydrogenated raffinate based [Baseoil S: 53 - 45 ;
94733-16-1 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Distillates (petroleum), steam-cracked, C8-12

fraction, polymd., distn. lights [Low boiling point
naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained by distillation
of the polymerized C8 through C12 fraction from
steam-cracked petroleum distillates. It consists T
predominantly of aromatic hydrocarbons having Carc. Cat. 2; R45 R: 45-46-65
carbon numbers predominantly in the range of C8 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
95009-23-7 through C12.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Xi ; R: 43 ,
95154-01-1 (Benzothiazol-2-ylthio)succinic acid Xi; R43 S: (2) - 24 - 37 : Conc>=1%: Xi; R43 Eu - - - - - - - -

6’-(Isobutylethylamino)-3'-methyl-2'-phenylamino- R: 53,
95235-29-3 spiro[isobenzo-2-oxofuran-7,9'-[9H]-xanthene R53 S: 61 Eu - - - - - - - -
N ; R: 51/53,
95235-30-6 4-(4-Isopropoxyphenylsulfonyl)phenoI N; R51-53 S: 61 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C13-30, arom. rich, solvent extd. S: 53 - 45 ;
95371-04-3 naphthenic distillate [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C16-32, arom. rich, solvent extd. S: 53 - 45 ;
95371-05-4 naphthenic distillate [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C37-68, dewaxed deasphalted S: 53 - 45 ;
95371-07-6 hydrotreated vacuum distn [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C37-65, hydrotreated deasphalted S: 53 - 45 ;
95371-08-7 vacuum distn. residues [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
F+; T
F+; R12 R: 45-46-12
Hydrocarbons, C4, 1,3-butadiene- and isobutene-free Carc. Cat. 1; R45 S: 53-45
95465-89-7 [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Conc>=25%: T+; R26/27; R25
>=7%Conc<25%: T+; R26/27; R22
>=3%Conc<7%: T; R23/24; R22
T+; R26/27 >=1%Conc<3%: T; R23/24
95465-99-9 Cadusafos T; R25 T+ ; R: 25 - 26/27 >=0.1%Conc<1%: Xn; R20/21 V - - - - - - - -
Conc>=25%: C; R35; R21/22
C >=10%Conc<25%: C; R35
Xn; R21/22 R: 21/22-35 >=5%Conc<10%: C; R34
95500-19-9 Diethyldimethylammonium hydroxide C; R35 S: (1/2-)26-36/37/39-45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -
N
R: 50/53
95737-68-1 2-(1-Methyl-2-(4-phenoxyphenoxy)ethoxy)pyridine N; R50-53 S: 60-61 Eu - - - - - - - -
Xn
5-Ethyl-2,4-dihydro-4-(2-phenoxyethyl)-3H-1,2,4- Xn; R22 R: 22-52/53
95885-13-5 triazol-3-one R52-53 S: (2-)22-36-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
N
N-[3-[[4-(Diethylamino)-2-methylphenyl]imino]-6-oxo- R: 50/53
96141-86-5 1,4-cyclohexadienyl]acetamide N; R50-53 S: 60-61 Eu - - - - - - - -

Page 301
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn
Repr.Cat.3; R62 R: 43-62 Conc>=5%: Xn; R62; R43
96314-26-0 trans-4-Phenyl-L-proline R43 S: (2-)22-36/37 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
T; N
R: 23/25 - 50/53
2-tert-Butyl-5-(4-tert-butylbenzylthio)-4- T; R23/25 S: (1/2) - 36/37 - 45 - 60 - Conc>=25%: T; R23; R25
96489-71-3 chloropyridazin-3(2H)-one N; R50-53 61 >=3%Conc<25%:Xn; R20; R22 Eu - - - - - - - -

Flurtamone (ISO) [(RS)-5-Methylamino-2-phenyl-4- N ; R: 50/53

96525-23-4 (alpha,alpha,alpha-trifluoro-m-tolyl)furan-3(2H)-one] N; R50-53 S: 60 - 61 Eu - - - - - - - -
Xi; R41 Xi ; R: 41 - 52/53 Conc>=10%: Xi; R41
96562-58-2 Methyl (R)-2-(4-hydroxyphenoxy)propionate R52-53 S: (2)26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22
Xi; R36/37 Xn ; R: 22 - 36/37 - 52/53 , Conc>=25%: Xn; R22; R36/37
96566-70-0 Potassium 2-hydroxycarbazole-1-carboxylate R52-53 S: (2) - 22 - 26 - 61 >=20%Conc<25%; Xi; R36/37 Eu - - - - - - - -

Tar acids, distn. residues [Distillate Phenols](Note: A

residue from the distillation of crude phenol from
coal. It consists predominantly of phenols having T
carbon numbers in the range of C8 through C10 with R: 45-46
a softening point of 60 °C to 80 °C (140 °F to 176 Carc. Cat. 2; R45 S: 53-45
96690-55-0 °F).) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Mixture of: 1-(2,3,6,7,8,9-hexahydro-1,1-dimethyl-1H-
benz(g)inden-4-yl)ethanone and 1-(2,3,5,6,7,8-
hexahydro-1,1-dimethyl-1H-benz(f)inden-4-
yl)ethanone and 1-(2,3,6,7,8,9-hexahydro-1,1-
dimethyl-1H-benz(g)inden-5-yl)ethanone and 1- N
(2,3,6,7,8,9-hexahydro-3,3-dimethyl-1H-benz(g)inden- R: 50/53
96792-67-5 5-yl)ethanone N; R50-53 S: 60-61 Eu - - - - - - - -
Xn; R22
R43 Xn ; N ; R: 22 - 43 - 50/53, Conc>=25%: Xn; R22; R43
97101-46-7 Methyl 3-(acetylthio)-2-methyl-propanoate N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
F ; R: 11
97148-39-5 Ammonium (Z)-alpha-methoxyimino-2-furylacetate F; R11 S: (2 - )22 - 43 Eu - - - - - - - -
Xn
Xn; R22 R: 22-52/53
97384-48-0 2-Benzyl-2-methyl-3-butenitrile R 52-53 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -

2-(4-(N-Butyl-N-phenethylamino)phenyl)ethylene- R: 53
97460-76-9 1,1,2-tricarbonitrile R53 S: 61 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrocracked solvent refined S: 53 - 45 ;
97488-73-8 light [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), solvent refined hydrogenated S: 53 - 45 ;
97488-74-9 heavy [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Kerosine (petroleum), solvent refined S: (2) - 23 - 24 - 62 ;
97488-94-3 hydrodesulfurized [Kerosine unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T ; R: 45 ,
Lubricating oils (petroleum), C18-27, hydrocracked S: 53 - 45 ;
97488-95-4 solvent dewaxed [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 - 65 ,
Naphtha (petroleum), solvent refined S: 53 - 45;
97488-96-5 hydrodesulfurized heavy [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C16-20, hydrotreated middle distillate, S: 53 - 45 ;
97675-85-9 distn. lights [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons,C12-20, hydrotreated paraffinic, distn. S: 53 - 45 ;
97675-86-0 lights [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C17-30, hydrotreated solvent S: 53 - 45 ;
97675-87-1 deasphalted atm. distn. lights [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 302
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn ; R: 40 ,
Hydrocarbons, C16-20, solvent dewaxed S: (2) - 36/37 ;
97675-88-2 hydrocraccked paraffinic dist [Cracked gasoil] Carc. Cat. 3; R40 Note: H Conc>=1%: Xn; R40 Eu - - - - - - - -

T
R: 45
97722-04-8 Hydrocarbons, C26-55, arom-rich Carc. Cat. 2; R45 S: 53-45; Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Hydrocarbons, C17-40, hydrotreated solvent T ; R: 45 ,
deasphalted distn. residue, vacuum distn. lights S: 53 - 45 ;
97722-06-0 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C11-17, solvent extd. light naphthenic S: 53 - 45 ;
97722-08-2 [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C13-27, solvent extd. light naphthenic S: 53 - 45 ;
97722-09-3 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C14-29, solvent extd. light naphthenic S: 53 - 45 ;
97722-10-6 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
F+; T
Raffinates (petroleum), steam-cracked C4 fraction F+; R12 R: 45-46-12
cuprous ammonium acetate extn., C3-5 and C3-5 Carc. Cat. 1; R45 S: 53-45
97722-19-5 unsatd., butadiene-free [Petroleum gas] Muta. Cat. 2; R46 Notes: H ; K Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
97780-06-8 Ethametsulfuron methyl Xi; R36 Xi ; R: 36 Conc>=20%: Xi; R36 V - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
97862-76-5 Foots oil (petroleum), carbon treated Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
97862-77-6 Foots oil (petroleum), silicic acid treated Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
97862-78-7 Gas oils, hydrotreated [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C27-42, dearomatized [Baseoil S: 53 - 45 ;
97862-81-2 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C17-30, hydrotreated distillates, distn. S: 53 - 45 ;
97862-82-3 lights [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C27-45, naphthenic vacuum distn. S: 53 - 45 ;
97862-83-4 [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
97862-97-0 Petrolatum (petroleum), carbon treated [Petrolatum] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Petrolatum (petroleum), silicic acid treated S: 53 - 45 ;
97862-98-1 [Petrolatum] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Slack wax (petroleum), low melting, carbon treated S: 53 - 45 ;
97863-04-2 [Slack wax] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Slack wax (petroleum), low melting, clay treated S: 53 - 45 ;
97863-05-3 [Slack wax] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Slack wax (petroleum), low melting, silicic acid S: 53 - 45 ;
97863-06-4 treated [Slack wax] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
Potassium-N-(4-toluenesulfonyl)-4- Xi ; R: 41, Conc>=10%: Xi; R41
97888-41-0 toluenesulfonamide Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 303
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Extracts (petroleum) heavy naphtha solvent, clay-

treated [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons obtained by the treatment of heavy
naphthic solvent petroleum extract with bleaching
earth. It consists predominantly of hydrocarbons T
having carbon numbers predominantly in the range of Carc. Cat. 2; R45 R: 45-46-65
C6 through C10 and boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
97926-43-7 approximately 80 °C to 180 °C (175 °F to 356 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Gas oils (petroleum), light vacuum, thermal cracked S: 53 - 45 ;
97926-59-5 hydrodesulfuriz [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C27-45, dearomatized [Baseoil S: 53 - 45 ;
97926-68-6 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C20-58, hydrotreated [Baseoil S: 53 - 45 ;
97926-70-0 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Hydrocarbons, C27-42, naphthenic [Baseoil S: 53 - 45 ;
97926-71-1 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Paraffin waxes (coal), brown coal high temp. tar, S: 53 - 45 ;
97926-76-6 carbon treated [Coal tar extracts] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Paraffin waxes (coal), brown coal high temp. tar, clay S: 53 - 45 ;
97926-77-7 treated [Coal tar extracts] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Paraffin waxes (coal), brown coal high temp. tar, S: 53 - 45 ;
97926-78-8 silicic acid treated [Coal tar extracts] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
5(or 6)-tert-Butyl-2'-chloro-6'-ethylamino-3',7'-
dimethylspiro(isobenzofuran-1(1H),9'-xanthene)-3- Xn; R20 Xn ; N ; R: 20 - 50/53 ,
98181-47-6 one N; R50-53 S: (2) - 60 - 61 Conc>=25%: Xn; R20 Eu - - - - - - - -

Naphtha (petroleum), light steam-cracked,

debenzenized, thermally treated [Low boiling point
naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained by the
treatment and distillation of debenzenized light steam-
cracked petroleum naphtha. It consists predominantly
of hydrocarbons having carbon numbers T
predominantly in the range of C7 through C12 and Carc. Cat. 2; R45 R: 45-46-65
boiling in the range of approximately 95 °C to 200 °C Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
98219-46-6 (203 °F to 392 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Naphtha (petroleum), light steam-cracked, thermally

treated [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons obtained by the treatment and
distillation of light steam-cracked petroleum naphtha.
It consists predominantly of hydrocarbons having T
carbon numbers predominantly in the range of C5 Carc. Cat. 2; R45 R: 45-46-65
through C6 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
98219-47-7 35 °C to 80 °C (95 °F to 176 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Residues (petroleum), steam cracked light, arom. S: 53 - 45 ;
98219-64-8 [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xi
R43 R: 43-52/53
98377-35-6 1-(2-Chlorophenyl)-1,2-dihydro-5H-tetrazol-5-one R52-53 S: (2-)24/25-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
N
tert-Butyl (1S)-N-[1-((2S)-2-oxiranyl)-2- R: 50/53
98737-29-2 phenylethyl]carbamate N; R50-53 S: 60-61 Eu - - - - - - - -

Page 304
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of (2R,3R)-3-(2-ethoxyphenoxy)-2-hydroxy-3-
phenylpropylammonium methanesulfonate and Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
(2S,3S)-3-(2-ethoxyphenoxy)-2-hydroxy-3- Xi; R41 R: 22-41-51/53 >=10%Conc<25%: Xi; R41
98769-75-6 phenylpropylammonium methanesulfonate N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

2-[[4[[4,6-Bis[[3-(diethylamino)propyl]amino]-1,3,5- Xi; R41 Conc>=10%: Xi; R41; R43

triazine-2-yl]amino]phenyl]azo]-N-(2,3-dihydro-2-oxo- R43 Xi ; N ; R: 41 - 43 - 51/53, >=5%Conc<10%: Xi; R36; R43
98809-11-1 1H-benzimidazol-5-yl)-3-oxobutanamide N; R51-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
R: 53
98809-58-6 2-Benzotriazol-2-yl-4-methyl-6-(2-methylallyl)phenol R53 S: 61 Eu - - - - - - - -

Fatty acids, C16-C18 and C18 unsatd., esters with Xi

98859-60-0 acetaldehyde-formaldehyde reaction by-products R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -

T; R23/25-39 Conc>=25%: T; R23/25; R39; R21; R41; R43

Xn; R21 >=10%Conc<25%: T; R39; R20/22; R41; R43
Xi; R41 >=5%Conc<10%: Xn; R20/22; R68; R36; R43
R43 T ; N ; R: 21-23/25-39-41-43- >=3%Conc<5%: Xn; R20/22; R68; R43
98886-44-3 Fosthiazate (ISO) N; R50-53 50/53 >=1%Conc<3%: Xn; R68; R43 Eu - - - - - - - -
(+/-)-4-[2-[[3-(4-Hydroxyphenyl)-1- Xn
methylpropyl]amino]-1-hydroxyethyl]phenol Xn; R20/22 R: 20/22-43 Conc>=25%: Xn; R20/22; R43
99095-19-9 hydrochloride R43 S: (2-)24-26-37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
2-(2,4-Bis(1,1-dimethylethyl)phenoxy)-N-(3,5-dichloro- R: 53
99141-89-6 4-ethyl-2-hydroxyphenyl)-hexanamide R53 S: 61 Eu - - - - - - - -
Xn
Muta.Cat.3; R68 R: 43-68
99464-83-2 Chloro-1-ethylcyclohexyl carbonate R43 S: (2-)23-36/37 Conc>=1%: Xn; R68; R43 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
99469-99-5 Ethyl 2-ethoxy-4-carboxymethylbenzoate Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
99607-70-2 Cloquintocet mexyl Xi; R43 Xi ; R: 43 Conc>=1%: Xi; R43 V - - - - - - - -
F; R11
Repr. Cat. 3; R62 F ; Xn ; R: 11 - 22 - 62 Conc>=25%: R62; R22
99610-72-7 2-(2-Hydroxy-3,5-dinitroanilino)ethanol Xn; R22 S: (2)22 - 33 - 36/37 >=5%Conc<25%: Xn; R62 Eu - - - - - - - -

Xn; R48/22 Xn ; N ; R: 43 - 48/22 -

R43 50/53 , Conc>=10%: Xn; R48/22; R43
99688-47-8 Bromobenzylbromotoluene, mixed isomers N; R50-53 S: (2) - 24 - 37 - 41 - 60 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
N
R: 51/53
99788-75-7 1,4-Bis(2,3-dihydroxypropylamino)anthraquinone N; R51-53 S: 61 Eu - - - - - - - -
Conc>=25%: T; R25; R41; R43
T; R25 Xi; T; N >=10%Conc<25%: Xn; R22; R41; R43
R41 R: 25-41-43-50/53 >=5%Conc<10%: Xn; R22; R36; R43
R43 N; S: (1/2-)26-36/37/39-45-60- >=3%Conc<5%: Xn; R22; R43
99817-36-4 2,4-Dichloro-3-ethyl-6-nitrophenol R50-53 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41
Cumene-(cyclopentadienyl)iron(II) Xi; R41 Xn ; R: 22 - 41 - 52/53 >=10%Conc<25%: Xi; R41
100011-37-8 hexafluoroantimonate R52-53 S: (2)22 - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; R38 Xi ; N ; R: 38 - 43 - 50/53,
N; R50-53 S: (2) - 24 - 28 - 36/37 - 60 - Conc>=20%: Xi; R38; R43
100181-71-3 Isobutyl 3,4-epoxybutyrate R43 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn; R22
R43 Xn ; R: 22 - 43 - 52/53, Conc>=25%: Xn; R22; R43
100418-33-5 2-((4-Methyl-2-nitrophenyl)amino)ethanoI R52-53 S: (2) - 36/37 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xi; N
Ethyl 7-chloro-1-(2,4-difluorophenyl)-6-fluoro-1,4- R43 R: 43-51/53
100491-29-0 dihydro-4-oxo-1,8-naphthyridine-3-carboxylate N; R51-53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Ethyl 1-ethyl-6,7,8-trifluoro-1,4-dihydro-4- R43 Xi ; R: 43 - 52/53
100501-62-0 oxoquinoline-3-carboxylate R52-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 305
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
1,3-Cyclohexadiene-1-carboxylic acid, 4,6,6-trimethyl- Xi; R38 Xi Conc>=20%: Xi; R38; R43
100520-15-8 , ethyl ester R43 R: 38-43 >=1%Conc<20%: Xi; R43 N - - - - - - - -
100646-51-3 Quizalofop-p-ethyl Xn; R22 Xn ; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), carbon treated light paraffinic S: 53 - 45 ;
100683-97-4 [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), intermediate paraffinic, carbon S: 53 - 45 ;
100683-98-5 treated [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), intermediate paraffinic, clay S: 53 - 45 ;
100683-99-6 treated [Gasoil unspecified] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Extracts (petroleum), light paraffinic distillate solvent, S: 53 - 45 ;
100684-02-4 carbon treated [Distillate aromatic extract (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Extracts (petroleum), light paraffinic distillate solvent, S: 53 - 45 ;
100684-03-5 clay treated [Distillate aromatic extract (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Extracts (petroleum), light vacuum, gas oil solvent, S: 53 - 45 ;
100684-04-6 carbon treated [Distillate aromatic extract (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Extracts (petroleum), light vacuum gas oil solvent, S: 53 - 45 ;
100684-05-7 clay treated [Distillate aromatic extract (treated)] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
100684-33-1 Petrolatum (petroleum), clay treated [Petrolatum] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residual oils (petroleum), carbon treated solvent S: 53 - 45 ;
100684-37-5 dewaxed [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Residual oils (petroleum), clay treated solven S: 53 - 45 ;
100684-38-6 dewaxed [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
100684-49-9 Slack wax (petroleum), carbon treated [Slack wax] Carc. Cat. 2; R45 Notes: H ; N Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Tar, coal, high temp., residues [Coal tar solids S: 53 - 45 ;
100684-51-3 residue] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Hydrocarbon oils, arom., mixed with polyethylene and

polypropylene, pyrolyzed, light oil fraction [Heat
Treatment Products](Note: The oil obtained from the
heat treatment of a polyethylene/polypropylene
mixture with coal tar pitch or aromatic oils. It consists T
predominantly of benzene and its homologs boiling in R: 45-46
a range of approximately 70 °C to 120 °C (158 °F to Carc. Cat. 2; R45 S: 53-45
100801-63-6 248 °F).) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Hydrocarbon oils, arom., mixed with polyethylene,

pyrolyzed, light oil fraction [Heat Treatment
Products](Note: The oil obtained from the heat
treatment of polyethylene with coal tar pitch or T
aromatic oils. It consists predominantly of benzene R: 45-46
and its homologs boiling in a range of 70 °C to 120 Carc. Cat. 2; R45 S: 53-45
100801-65-8 °C (158 °F to 248 °F).) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Page 306
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Hydrocarbon oils, arom., mixed with polystyrene,

pyrolyzed, light oil fraction [Heat Treatment
Products](Note: The oil obtained from the heat
treatment of polystyrene with coal tar pitch or T
aromatic oils. It consists predominantly of benzene R: 45-46
and its homologs boiling in a range of approximately Carc. Cat. 2; R45 S: 53-45
100801-66-9 70 °C to 210 °C (158 °F to 410 °F).) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
(6R–trans)-1-((7-Ammonio-2-carboxylato-8-oxo-5-thia- Muta. Cat. 3; R68 Xn; N
1-azabicyclo-[4.2.0]oct-2-en-3-yl)methyl)pyridinium R43 R: 43-68-51/53
100988-63-4 iodide N; R51-53 S: (2-)36/37-61 Conc>=1%: Xn; R68; R43 Eu - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
101012-89-9 Dodecanoic acid, cadmium salt, basic Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
101012-93-5 Octadecanoic acid, cadmium salt, basic Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -

Conc>=25%: T+; R45; R46; R60; R61; R26;

R25; R48/23/25; R21
>=10%Conc<25%: T+; R45; R46; R60; R61;
Carc. Cat. 2; R45 R26; R25; R48/23/25
Muta. Cat. 2; R46 >=7%Conc<10%: T+; R45; R46; R60; R61;
Repr. Cat. 2; R60-61 R26; R48/23/25; R22
T+; R26 T+ >=1%Conc<7%: T; R45; R46; R60; R61; R23;
T; R25-48/23/25 R: 45-46-60-61-21-25-26- R22; R48/20/22
101012-94-6 Octadecanoic acid, 12-hydroxy-, cadmium salt, basic Xn; R21 48/23/25 >=0.5%Conc<1%: T; R45; N - - - - - - - -
Xn; R21/22
Xi; R38 Xn ; N ; R: 21/22 - 38 - 43 - Conc>=25%: Xn; R21/22; R38; R43
4-(1(or 4 or 5 or 6)-Methyl-8,9,10-trinorborn-5-en-2- R43 50/53 , >=20%Conc<25%: Xi; R38; R43
101051-62-1 yl)pyridine, mixture of isomers N; R50-53 S: (2) - 36/37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Tribenuron methyl (ISO) [2-[4-Methoxy-6-methyl-

1,3,5-triazin-2-yl(methyl)carbamoylsulfamoyl]benzoic Xi; N
acid; Methyl 2-(3-(4-methoxy-6-methyl-1,3,5-triazin-2- R43 R: 43-50/53
101200-48-0 yl)3-methylureidosulphonyl)benzoate] N; R50-53 S: (2-)24-37-46-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
R: 10
101226-85-1 trans-Methyl-2-ethyl-but-2-enoate R10 S: 23 Eu - - - - - - - -

Absorption oils, bicyclo arom. and heterocyclic

hydrocarbon fraction [Wash oil redistillate](Note: A
complex combination of hydrocarbons obtained as a
redistillate from the distillation of wash oil. It consists
predominantly of 2-ringed aromatic and heterocyclic T ; R: 45 ,
hydrocarbons boiling in the range of approximately S: 53 - 45 ;
101316-45-4 260°C to 290°C.) Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
101316-49-8 Distillates (coal tar), pitch [Heavy anthracene oil] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 307
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Distillates (petroleum), C7-9, C8-rich,

hydrodesulfurized dearomatized [Low boiling point
naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained by the
distillation of petroleum light fraction,
hydrodesulfurized and dearomatized. It consists
predominantly of hydrocarbons having carbon
numbers in the range of C7 through C9, T
predominantly C8 paraffins and cycloparaffins, boiling Carc. Cat. 2; R45 R: 45-46-65
in the range of approximately 120 °C to 130 °C (248 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
101316-56-7 °F to 266 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrodesulfurized full range S: 53 - 45 ;
101316-57-8 middle [Heavy fuel oil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Distillates (petroleum), hydrodesulfurized full range S: (2) - 23 - 24 - 62 ;
101316-58-9 middle coker [Kerosine unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), hydrodesulfurized middle S: 53 - 45 ;
101316-59-0 coker [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Distillates (petroleum), thermal cracked, alkylarom. S: (2) - 23 - 24 - 62 ;
101316-61-4 hydrocarbon rich [Cracked kerosine] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T
Extract residues (coal), light oil alk., acid ext., indene R: 45-46
fraction [Light Oil Extract Residues, intermediate Carc. Cat. 2; R45 S: 53-45
101316-62-5 boiling] Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract residues (coal tar), benzole fraction alk., acid

ext. [Light Oil Extract Residues, low boiling](Note: A
complex combination of hydrocarbons obtained by
the redistillation of the distillate of high temperature
coal tar (tar acid and tar base free). It consists T
predominantly of unsubstituted and substituted R: 45-46
mononuclear aromatic hydrocarbons boiling in the Carc. Cat. 2; R45 S: 53-45
101316-63-6 range of 85 °C to 195 °C (185 °F to 383 °F).) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C6-8, hydrogenated sorption-

dearomatized, toluene raffination [Low boiling point
naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained during the
sorptions of toluene from a hydrocarbon fraction from
cracked gasoline treated with hydrogen in the
presence of a catalyst. It consists predominantly of
hydrocarbons having carbon numbers predominantly T
in the range of C6 through C8 and boiling in the Carc. Cat. 2; R45 R: 45-46-65
range of approximately 80 °C to 135 °C (176 °F to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
101316-66-9 275 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C6-rich, hydrotreated light naphtha

distillates, solvent-refined [Low boiling point modified
naphtha](Note: A complex combination of
hydrocarbons obtained by distillation of hydrotreated
naphtha followed by solvent extraction. It consists T
predominantly of saturated hydrocarbons and boiling Carc. Cat. 2; R45 R: 45-46-65
in the range of approximately 65 °C to 70 °C (149 °F Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
101316-67-0 to 158 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Lubricating oils (petroleum), C>25, solvent extd., T ; R: 45 ,
deasphalted, dewaxed, hydrogenated [Baseoil S: 53 - 45 ;
101316-69-2 unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 308
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Lubricating oils (petroleum), C>17-32, solvent-extd.,

dewaxed, hydrogenated [Baseoil unspecified](Note: A
complex combination of hydrocarbons obtained by
solvent extraction and hydrogenation of atmospheric
distillation residues. It consists predominantly of
hydrocarbons having carbon numbers predominantly
in the range of C17 through C32 and produced a T ; R: 45 ,
finished oil with a viscosity in the order of 17cSt to S: 53 - 45 ;
101316-70-5 23cSt at 40 °C (104 °F).) Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Lubricating oils (petroleum), C20-35, solvent extd., S: 53 - 45 ;
101316-71-6 dewaxed, hydrogenated [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Lubricating oils (petroleum), C24-50, solvent extd., S: 53 - 45 ;
101316-72-7 dewaxed, hydrogenated [Baseoil unspecified] Carc. Cat. 2; R45 Notes: H ; L Conc>=0.1%: T; R45 Eu - - - - - - - -

Naphtha (petroleum), hydrodesulfurised full-range

coker [Low boiling point naphtha —
unspecified](Note: A complex combination of
hydrocarbons obtained by fractionation from
hydrodesulfurised coker distillate. It consists
predominantly of hydrocarbons having carbon T
numbers predominantly in the range of C5 to C11 Carc. Cat. 2; R45 R: 45-46-65
and boiling in the range of approximately 23 °C to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
101316-76-1 196 °C (73 °F to 385 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Xn ; R: 65 ,
Solvent naphtha (petroleum), hydrocracked heavy S: (2) - 23 - 24 - 62 ;
101316-80-7 arom. [Cracked kerosene] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
Xn ; R: 65 ,
Solvent naphtha (petroleum), hydrodesulfurized S: (2) - 23 - 24 - 62 ;
101316-81-8 heavy arom. [Kerosene unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
Xn ; R: 65 ,
Solvent naphtha (petroleum), hydrodesulfurized S: (2) - 23 - 24 - 62 ;
101316-82-9 medium [Kerosene unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
101316-83-0 Tar, brown coal Carc. Cat. 1. R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
101316-84-1 Tar, brown coal, low temp. . Carc. Cat. 1; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Tar, coal, low-temp., distn. residues [Tar oil, S: 53 - 45 ;
101316-85-2 intermediate boiling] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
Tar acids, brown-coal, crude [Crude Phenols](Note: T
An acidified alkaline extract of brown coal tar R: 45-46
distillate. Composed primarily of phenol and phenol Carc. Cat. 2; R45 S: 53-45
101316-86-3 homologs.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Tar oils, coal, low-temp. [Tar Oil, high boiling](Note: A

distillate from low-temperature coal tar. Composed T
primarily of hydrocarbons, phenolic compounds and R: 45-46
aromatic nitrogen bases boiling in the range of Carc. Cat. 2; R45 S: 53-45
101316-87-4 approximately 160 °C to 340 °C (320 °F to 644 °F).) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Mixture of compounds from (dodecakis(p-

tolylthio)phthalocyaninato)copper(II) to Xi ; R: 43
101408-30-4 (hexadecakis(p-tolylthio)phthalocyaninato)copper(II) R43 S: (2)24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
T; R23
C; R34 Conc>=25%: T; R23; R34; R22; R43; R29
Xn; R22 T ; C ; R: 22 - 23 - 29 - 34 - >=10%Conc<25%: C; R34; R20; R43; R29
R43 43 - 52/53 , >=5%Conc<10%: Xn; R20; R36/38; R43; R29
R29 S: (1/2) - 26 - 36/37/39 - 45 - >=3%Conc<5%: Xn; R20; R43; R29
101513-70-6 3,5-Dichloro-2,4-difluorobenzoyl fluoride R52-53 61 >=1%Conc<3%: Xi; R43; R29 Eu - - - - - - - -

Page 309
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn ; R: 65 ,
Distillates (petroleum), catalytic cracked heavy tar S: (2) - 23 - 24 - 62 ;
101631-13-4 light [Cracked kerosine] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
T ; R: 45 ,
Distillates (petroleum), heavy steam cracked S: 53 - 45 ;
101631-14-5 [Cracked gasoil] Carc. Cat. 2; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
Xn ; R: 65 ,
Distillates (petroleum), steam cracked heavy tar light S: (2) - 23 - 24 - 62 ;
101631-15-6 [Cracked kerosine] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -
Xn ; R: 65 ,
Kerosine (petroleum), hydrotreated [Kerosine S: (2) - 23 - 24 - 62 ;
101631-19-0 unspecified] Xn; R65 Note: H Conc>=10%: Xn; R65 Eu - - - - - - - -

Naphtha (petroleum), heavy straight run, arom.-

contg. [Low boiling point naphtha](Note: A complex
combination of hydrocarbons obtained from a
distillation process of crude petroleum. It consists
predominantly of hydrocarbons having carbon T
numbers in the range of C8 through C12 and boiling Carc. Cat. 2; R45 R: 45-46-65
in the range of approximately 130 °C to 210 °C (266 Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
101631-20-3 °F to 410 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
R43 Xi ; R: 43 - 52/53
101657-77-6 4,4'-Methylenebis(2,6-dimethylphenyl cyanate) R52-53 S: (2)22 - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
3',5'-Dichloro-2-(2,4-di-tert-pentylphenoxy)-4'-ethyl-2'- R: 53,
101664-25-9 hydroxyhexananilide R53 S: 61 Eu - - - - - - - -
Aromatic hydrocarbons, C20-28, polycyclic, mixed T ; R: 45 ,
coal tar pitch polyethylene polypropylene pyrolysis S: 53 - 45 ;
101794-74-5 derived [Pyrolysis products] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
Aromatic hydrocarbons, C20-28, polycyclic, mixed T ; R: 45 ,
coal tar pitch polyethylene pyrolysis derived S: 53 - 45 ;
101794-75-6 [Pyrolysis products] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
Aromatic hydrocarbons, C20-28, polycyclic, mixed T ; R: 45 ,
coal tar pitch polystyrene pyrolysis derived [Pyrolysis S: 53 - 45 ;
101794-76-7 products] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Distillates (coal tar), light oils, neutral fraction [Light

Oil Extract Residues, high boiling](Note: A distillate
from the fractional distillation of high temperature
coal tar. Composed primarily of alkyl-substituted one
ring aromatic hydrocarbons boiling in the range of T
approximately 135 °C to 210 °C (275 °F to 410 °F). R: 45-46
May also include unsaturated hydrocarbons such as Carc. Cat. 2; R45 S: 53-45
101794-90-5 indene and coumarone.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (coal tar), naphthalene oils, indole-

methylnaphthalene fraction [Methylnaphthalene
Oil](Note: A distillate from the fractional distillation of T
high temperature coal tar. Composed primarily of R: 45-46
indole and methylnaphthalene boiling in the range of Carc. Cat. 2; R45 S: 53-45
101794-91-6 approximately 235 °C to 255 °C (455 °F to 491 °F).) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C8-12, catalytic cracker distillates

[Low boiling point cat-cracked naphtha](Note: A
complex combination of hydrocarbons obtained by
distillation of products from a catalytic cracking
process. It consists predominantly of hydrocarbons T
having carbon numbers predominantly in the range of Carc. Cat. 2; R45 R: 45-46-65
C8 through C12 and boiling in the range of Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
101794-97-2 approximately 140 °C to 210 °C (284 °F to 410 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Naphtha (petroleum), sweetened light [Low boiling

point naphtha — unspecified](Note: A complex
combination of hydrocarbons obtained by subjecting
a petroleum naphtha to a sweetening process to
convert mercaptans or to remove acidic impurities. It
consists predominantly of hydrocarbons having T
carbon numbers predominantly in the range of C5 Carc. Cat. 2; R45 R: 45-46-65
through C8 and boiling in the range of approximately Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
101795-01-1 20 °C to 130 °C (68 °F to 266 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Bis(4-fluorophenyl)-methyl-(1,2,4-triazol-4- Xi; R36 Xi ; N ; R: 36 - 51/53 ,
101804-03-9 ylmethyl)silane hydrochloride N; R51-53 S: (2) - 26 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -

Distillates (coal tar), benzole fraction, BTX-rich [Light

Oil Redistillate, low boiling](Note: A residue from the
distillation of crude benzole to remove benzole fronts. T
Composed primarily of benzene, toluene and xylenes R: 45-46
boiling in the range of approximately 75 °C to 200 °C Carc. Cat. 2; R45 S: 53-45
101896-26-8 (167 °F to 392 °F).) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Distillates (coal tar), naphthalene oils,

methylnaphthalene fraction [Methylnaphthalene
Oil](Note: A distillate from the fractional distillation of
high temperature coal tar. Composed primarily of T
substituted two ring aromatic hydrocarbons and R: 45-46
aromatic nitrogen bases boiling in the range of Carc. Cat. 2; R45 S: 53-45
101896-27-9 approximately 225 °C to 255 °C (437 °F to 491 °F).) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
T
Hydrocarbons, C8-12, catalytic cracking, chem. Carc. Cat. 2; R45 R: 45-46-65
neutralized, sweetened [Low boiling point cat-cracked Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
101896-28-0 naphtha] Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Xi Conc>=10%: Xi; R41; R43
Sodium 1,1,2,2,3,3,4,4,4-nonafluoro-1- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
102061-82-5 butanesulfinate R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R48/21; R41
Xn; R22-48/21 Xn ; R: 22 - 38 - 41 - 48/21 - >=20%Conc<25%: Xn; R48/21; R38; R41
4-[3-(Diethoxymethylsilylpropoxy)-2,2,6,6- Xi; R38-41 52/53 >=10%Conc<20%: Xn; R48/21; R41
102089-33-8 tetramethyl]piperidine R52-53 S: (2)26 - 36/37/39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Hydrocarbons, C3-6, C5-rich, steam-cracked naphtha
[Low boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons obtained by
distillation of steam-cracked naphtha. It consists T
predominantly of hydrocarbons having carbon Carc. Cat. 2; R45 R: 45-46-65
numbers in the range of C3 through C6, Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
102110-14-5 predominantly C5.) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

Hydrocarbons, C5-rich, dicyclopentadiene-contg.

[Low boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons obtained by
distillation of the products from a steam-cracking
process. It consists predominantly of hydrocarbons T
having carbon numbers of C5 and dicyclopentadiene Carc. Cat. 2; R45 R: 45-46-65
and boiling in the range of approximately 30 °C to Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
102110-15-6 170 °C (86 °F to 338 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Residues (petroleum), steam-cracked light, arom.

[Low boiling point naphtha — unspecified](Note: A
complex combination of hydrocarbons obtained by
the distillation of the products of steam cracking or
similar processes after taking off the very light
products resulting in a residue starting with
hydrocarbons having carbon numbers greater than T
C5. It consists predominantly of aromatic Carc. Cat. 2; R45 R: 45-46-65
hydrocarbons having carbon numbers greater than Muta. Cat. 2; R46 S: 53-45 Conc>=10%: T; R45; R46; R65
102110-55-4 C5 and boiling above approximately 40 °C (104 °F).) Xn; R65 Notes: H ; P >=0.1%Conc<10%: T; R45; R46 Eu - - - - - - - -
Xi Conc>=10%: Xi; R41; R43
Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
102333-75-5 2-(para-Chlorophenyl)glycineamide R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
2-Acetylamino-6-chloro-4-[(4-diethylamino)2-
methylphenyl-imino]-5-methyl-1-oxo-2,5- R: 53
102387-48-4 cyclohexadiene R53 S: 61 Eu - - - - - - - -
Benzyltributylammonium 4-hydroxynaphthalene-1- Xn; R20 Xn ; N ; R: 20 - 51/53 ,
102561-46-6 sulphonate N; R51-53 S: (2) - 22 - 61 Conc>=25%: Xn; R20 Eu - - - - - - - -
Xn; R22
Tau-fluvalinate [Cyano-(3-phenoxyphenyl) methyl N- Xi; R38 Xn ; N ; R: 22 - 38 - 50/53, Conc>=25%: Xn; R22; R38
102851-06-9 [2-chloro-4-(trifluoromethyl)phenyl]-D-valinate] N; R50-53 S: (2) - 24 - 59 - 61 >=20%Conc<25%: Xi; R38 Eu - - - - - - - -
Xi; N
N-[2,5-dichloro-4-(1,1,2,3,3,3-hexafluoropropoxy)- R43 R: 43 - 50/53
103055-07-8 phenyl-aminocarbonyl]-2,6-difluorobenzamide N; R50-53 S: (2)24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
T; N
Ethyl 1-(2,4-dichlorophenyl)-5-(trichloromethyl)-1H- Carc.Cat.2; R45 R: 45-50/53
103112-35-2 1,2,4-triazole-3-carboxylate N; R50-53 S: 53-45-60-61 Conc>=0.1%: T; R45 Eu - - - - - - - -
R10
Carc. Cat. 2; R45 T; N
Muta. Cat. 2; R46 R: 45-46-10-22-43-48/22- Conc>=25%: T; R45; R46; R22; R48/22; R43
Xn; R22-48/22 51/53 >=10%Conc<25%: T; R45; R46; R48/22; R43
R43 S: 53-45-61 >=1%Conc<10%: T; R45; R46; R43
103122-66-3 O-Isobutyl-N-ethoxy carbonylthiocarbamate N; R51-53 Note: E >=0.1%Conc<1%: T; R45; R46 Eu - - - - - - - -
Xn; R22 Xn; N
(R,S)-4-(4-Dimethylamino-1-(4-fluorophenyl)-1- R43 R: 22-43-51/53 Conc>=25%: Xn; R22; R43
103146-25-4 hydroxybutyl)-3-(hydroxymethyl)benzonitrile N; R51-53 S: (2-)36/37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Flumioxazin (ISO) [N-(7-Fluoro-3,4-dihydro-3-oxo-4- T; N
prop-2-ynyl-2H-1,4-benzoxazin-6-yl)cyclohex-1-ene- Repr. Cat. 2; R61 R: 61-50/53
103361-09-7 1,2-dicarboxamide] N; R50-53 S: 53-45-60-61 Conc>=0.5%: T; R61 Eu - - - - - - - -
2-Hydroxymethyl-3-methyl-4-(2,2,2- R: 52/53
103577-66-8 trifluoroethoxy)pyridine R52-53 S: 61 Eu - - - - - - - -
2,2'-Methylenebis(6-(2H-benzotriazol-2-yl)4-(1,1,3,3- R: 53
103597-45-1 tetramethylbutyl)phenol) R53 S: 61 Eu - - - - - - - -
3-(2,2-Dimethyl-3-hydroxypropyl)toluene alt) [2,2- R: 52/53
103694-68-4 Dimethyl-3-(3-methylphenyl)propanol] R52-53 S: 61 Eu - - - - - - - -

Alcohols, C9-11, ethoxylated propoxylated(Note:

Polymeric substances may be placed on the market
with a range of molecular weights which will affect the
toxicological properties of the substance. The
classifications need not apply if it can be shown that
the substance placed on the market does not meet
the criteria for classification; note 2: The classification Conc>=25%: Xn; R22; R38; R41
for skin irritation need not apply if it can be shown >=20%Conc<25%: Xi; R38; R41
that there are less than four or more than 21 Xn; R22 Xn >=10%Conc<20%: Xi; R41
103818-93-5 ethoxylate units) Xi; R38-41 R: 22-38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Xn; N
Xn; R22 R: 22-51/53
103976-28-9 Diethyl[(p-ethoxyanilino)methylene]malonate N; R51-53 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Ceftiofur hydrochloride(Note: See also CAS No.
103980-44-5 80370-57-6 & 104010-37-9) Xi; R43 Xi ; R: 43 Conc>=1%: Xi; R43 V - - - - - - - -

Page 312
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Ceftiofur sodium(Note: See also CAS No. 80370-57-6
104010-37-9 & 103980-44-5) Xi; R43 Xi ; R: 43 Conc>=1%: Xi; R43 V - - - - - - - -
Flazasulfuron [1-(4,6-Dimethoxypyrimidin-2-yl)-3-(3- N ; R: 50/53
104040-78-0 trifluoromethyl-2-pyridylsulfonyl)urea] N; R50-53 S: 60 - 61 Eu - - - - - - - -
R: 53
104051-92-5 Dodecyl-omega-(C5/C6-cycloalkyl)alkyl carboxylate R53 S: 61 Eu - - - - - - - -

Trisodium (6-anilino-2-(5-nitro-2-oxidophenylazo)-3-
sulphonato-1-naphtholato)(4-sulphonato-1,1'-azodi- Xi; R41 Xi ; N ; R: 41 - 51/53 , Conc>=10%: Xi; R41
104105-46-6 2,2'naphtholato)chromate(1-) N; R51-53 S: (2) - 26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn ; N ; R: 22 - 50/53 ,
Xn; R22 S: (2) - 24/25 - 26 - 57 - 60 -
104147-32-2 3,5-Dichloro-4-(1,1,2,2-tetrafluoroethoxy)aniline N; R50-53 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
N
Mesotrione [2-[4-(Methylsulfonyl)-2-nitrobenzoyl]- R:50/53
104206-82-8 1,3-cyclohexanedione] N; R50-53 S: 60-61 Eu - - - - - - - -
1-(3-Mesyloxy-5-trityloxymethyl-2-D- R: 53
104218-44-2 threofuryl)thymine R53 S: 61 Eu - - - - - - - -
3-((4-(Bis(2-hydroxyethyl)amino)2-nitrophenyl)amino)- Xi; R43 Xi ; R: 43 - 52/53 ,
104226-19-9 1-propanol R52-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
3-((2-Nitro-4-(trifluoromethyl)phenyl)amino)propane- Xn; R22 Xn ; R: 22 - 52/53
104333-00-8 1,2-diol R52-53 S: (2)22 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi
2'-(4-Chloro-3-cyano-5-formyl-2-thienyl)azo-5'- R: 43
104366-25-8 diethylaminoacetanilide R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
Xi; R38 R: 38-52/53
104468-21-5 2,2-Dimethyl 3-methyl-3-butenyl propanoate R52-53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
2-[2,4-Bis(1,1-dimethyl-ethyl)phenoxy]-N-(2-hydroxy-5 R: 53
104541-33-5 methyl-phenyl)hexanamide R53 S: 61 Eu - - - - - - - -
N
R: 50/53
104560-40-9 N,N,N',N'-Tetracyclohexyl-1,3-benzenedicarboxamide N; R50-53 S: 60-61 Eu - - - - - - - -
Conc>=7%: T+; R28;
>=1%Conc<7%: T; R25;
104653-34-1 Difethialone T+; R28 T+ ; R: 28 >=0.1%Conc<1%: Xn; R22 V - - - - - - - -
O; R7 O ; Xi ; N ; R: 7 - 41 - 43 -
Xi; R41 50, Conc>=10%: Xi; R41; R43
R43 S: (2) - 3/7 - 14 - 26 - >=5%Conc<10%: Xi; R36; R43
104788-63-8 6-(Nonylamino)-6-oxo-peroxyhexanoic acid N; R50 36/37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R21/22-48/22 Xn; N Conc>=25%: Xn; R21/22; R48/22; R41
cis-1-(3-(4-Fluorophenoxy)propyl)-3-methoxy-4- Xi; R41 R: 21/22-41-48/22-50/53 >=10%Conc<25%: Xn; R48/22; R41
104860-26-6 piperidinamine N; R50-53 S: (2-)26-36/37/39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N
(3S,4S)-3-Hexyl-4-[(R)-2-hydroxytridecyl]-2- R: 50/53
104872-06-2 oxetanone N; R50-53 S: 60-61 Eu - - - - - - - -
Xi; R36
R43 Xi ; R: 36 - 43 - 52/53 Conc>=20%: Xi; R36; R43
104958-67-0 N-Butyl-2-(4-morpholinylcarbonyl)benzamide R52-53 S: (2)24 - 26 - 37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
T; N
(4-Ethoxyphenyl)(3-(4-fluoro-3- Repr.Cat.2; R60 R: 60-50/53
105024-66-6 phenoxyphenyl)propyl)dimethylsilane N; R50-53 S: 53-45-60-61 Conc>=0.5%: T; R60 Eu - - - - - - - -
3-Methyl-N-(5,8,13,14-tetrahydro-5,8,14- R: 53
105043-55-8 trioxonaphth[2,3-c]acridin-6-yl)benzamide R53 S: 61 Eu - - - - - - - -
N-(5-(Bis(2-methoxyethyl)amino)-2-((5-nitro-2,1- R: 53,
105076-77-5 benzisothiazol-3-yl)azo)phenylacetamide R53 S: 61 Eu - - - - - - - -
C; R34 C ; N ; R: 34 - 43 - 50/53, Conc>=10%: C; R34; R43
3-(Bis(2-ethylhexyl)aminomethyl)benzothiazole-2(3H)- R43 S: (1/2) - 26 - 28 - 36/37/39 - >=5%Conc<10%: Xi; R36/38; R43
105254-85-1 thione N; R50-53 45 - 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
3-(3-(4-(2,4-Bis(1,1-
dimethylpropyl)phenoxy)butylaminocarbonyl-4- R:53
105488-33-3 hydroxy-1-naphthalenyl)thio)propanoic acid R53 S: 61 Eu - - - - - - - -

Page 313
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R22-48/22 Xn; N Conc>=25%: Xn; R22; R48/22; R43
R43 R: 22-43-48/22-50/53 >=10%Conc<25%: Xn; R48/22; R43
105512-06-9 Clodinafop-propargyl (ISO) N; R50-53. S: (2-)24-36/37-46-60-61 >=0.001%Conc<10%: Xi; R43 Eu - - - - - - - -
Xi; R41 Conc>=10%: Xi; R41; R43
Methyl 2R,3S-(-)-3-(4- R43 Xi ; R: 41 - 43 - 52/53, >=5%Conc<10%: Xi; R36; R43
105560-93-8 methoxyphenyl)oxiranecarboxylate R52-53 S: (2) - 24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn
R: 22
105726-67-8 Methyl neodecanamide Xn; R22 S: (2-) Conc>=25%: Xn; R22 Eu/V - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 41 - 51/53 Conc>=25%: Xn; R22; R41
(-)-trans-4-(4'-Fluorophenyl)-3-hydroxymethyl-N- Xi; R41 S: (2)22 - 24 - 26 - 37/39 - >=10%Conc<25%: Xi; R41
105812-81-5 methylpiperidine N; R51-53 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22 Xn; N
(-)(3S,4R)-4-(4-Fluorophenyl)-3-(3,4-methylenedioxy- R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
105813-13-6 phenoxymethyl)-N-benzylpiperidine hydrochloride N; R50-53 S: (2-)22-24-37-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
T; R24 Conc>=25%: T; R24; R34; R22; R43
C; R34 >=10%Conc<25%: C; R34; R21; R43
Xn; R22 T; N >=5%Conc<10%: Xn; R21; R36/38; R43
R43 R: 22-24-34-43-51/53 >=3%Conc<5%: Xn; R21; R43
105827-91-6 2-Chloro-5-chloromethylthiazole N; R51-53 S: (1/2-)26-36/37/39-45-61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Xi Con>=10%: Xi; R41; R43
Xi; R41 R: 41-43 >=5%Conc<10%: Xi R36; R43
105996-54-1 N,N'-Bis(trifluoroacetyl)-S,S'-bis-L-homocysteine R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Dilithium 6-acetamido-4-hydroxy-3-(4-((2-
sulphonatooxy)ethylsulphonyl)phenylazo)naphthalene Xi ; R: 43 ,
106027-83-2 2-sulphonate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Tetralithium 6-amino-4-hydroxy-3-(7-sulfonato-4-(4-
sulfonatophenylazo)-1-naphthylazo(naphthalene-2,7- Xi ; R: 43 ,
106028-58-4 disulfonate Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22
R43 Xn ; N ; R: 22 - 43 - 50/53 , Conc>=25%: Xn; R22; R43
106264-79-3 6-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Trisodium 7-(4-(6-fluoro-4-(2-(2-
vinylsulphonylethoxy)ethylamino)-1,3,5-triazin-2-
ylamino)-2-ureidophenylazo)naphthalene-1,3,6- Xi ; R: 43 ,
106359-91-5 trisulphonate Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
2-(4-(3-(4-Chlorophenyl)-4,5-
dihydropyrazolyl)phenylsulphonyl)ethyldimethylammo Xi; R36 Xi ; N ; R: 36 - 50/53 ,
106359-93-7 nium hydrogen phosphonate N; R50-53 S: (2) - 26 - 60 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
2'-(2-Cyano-4,6-dinitrophenylazo)-5'-(N,N- Xi; R43 Xi ; R: 43 - 52/53 ,
106359-94-8 dipropylamino)propionanilide R52-53 S: (2) - 22 - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
3-(cis-1-Propenyl)-7-amino-8-oxo-5-thia-1- R: 43
106447-44-3 azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
2,4-Dihydro-4-(4-(4-(4-hydroxyphenyl)-1- Xn; N
piperazinyl)phenyl)-2-(1-methylpropyl)-3H-1,2,4- Xn; R48/22 R: 48/22-50/53
106461-41-0 triazol-3-one N; R50-53 S: (2-)22-36-60-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Xn; R22 Xn; N
Pethoxamide (ISO) [2-Chloro-N-(2-ethoxyethyl)-N-(2- R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
106700-29-2 methyl-1-phenylprop-1-enyl)acetamide] N; R50-53 S: (2-)24-37-46-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T; R23; R35; R22; R48/22
T; R23 T ; C ; N ; R: 22 - 23 - 35 - 10>=%Conc<25%: C; R35; R48/22; R20
Xn; R22-48/22 48/22 - 50/53 >=5%Conc<10%: C; R34; R20
3-Dodecyl-(1-(1,2,2,6,6-pentamethyl-4-piperidin)-yl)- C; R35 S: (1/2) - 26 - 28 - 36/37/39 - >=3%Conc<5%: Xn; R20; R36/38
106917-30-0 2,5-pyrrolidindione N; R50-53 45 - 60 - 61 >=1%Conc<3%: Xi; R36/38 Eu - - - - - - - -
Xi; R38 Xi; N
1-Acetyl-4-(3-dodecyl-2,5-dioxo-1-pyrrolidinyl)-2,2,6,6- R43 R: 38-43-50/53 Conc>=20%: Xi; R38; R43
106917-31-1 tetramethylpiperidine N; R50-53 S: (2-)24-37-60-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
N,N',N'',N'''-Tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-
tetramethylpiperidin-4-yl)amino)triazin-2-yl)-4,7- Xi; R43 Xi ; N ; R: 43 - 51/53 ,
106990-43-6 diazadecane-1,10-diamine N; R51-53 S: (2) - 22 - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53
107144-30-9 4-(4,4-Dimethyl-3-oxo-pyrazolidin-1-yl)-benzoic acid N; R51-53 S: (2)22 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Page 314
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Tetralithium 6-amino-4-hydroxy-3-[7-sulfonato-4-(5- N
sulfonato-2-naphthylazo)-1-naphthylazo]naphthalene- R: 51/53
107246-80-0 2,7-disulfonate N; R51-53 S: 61 Eu - - - - - - - -
Repr.Cat.3; R63 Xn; N
1-(4-Chlorophenyl)-4,4-dimethyl-3-(1,2,4-triazol-1- Xn; R22 R: 22-51/53-63 Conc>=25%: Xn; R22; R63
107534-96-3 ylmethyl)pentan-3-ol N; R51-53 S: (2-)22-36/37-61 >=5%Conc<25%: Xn; R63 Eu - - - - - - - -
Xn; R22. Xn ; R: 22 - 36 , Conc>=25%: Xn; R22; R36
107551-67-7 3-(3-tert-Butyl-4-hydroxyphenyl)propionic acid Xi; R36 S: (2) - 25 - 26 - 36 >=20%Conc<25%; Xi; R36 Eu - - - - - - - -
Poly(oxy-1,2-ethanediyl), alpha-[2-[(2-
hydroxyethyl)amino] -2-oxoethyl]- [omega-hydroxy,
107628-04-6 mono- C13-15 alkyl ethers] Xi; R38 Xi; R: 38 Conc>=20%: Xi; R38 N - - - - - - - -
R10
T; R23 Conc>=25%: T; R23; R34; R22
Xn; R22 T; N >=10%Conc<25%: C; R34; R20
C; R34 R: 10-22-23-34-51/53 >=5%Conc<10%: Xn; R20; R36/38
107667-02-7 Bis(2,4,4-trimethylpentyl)dithiophosphonic acid N; R51-53 S: (1/2-)9-26-36/37/39-45-61 >=3%Conc<5%: Xn; R20 Eu - - - - - - - -
R: 53
107786-36-7 3-(2-Methoxy-4-methoxycarboxybenzyl)-5-nitroindole R53 S: 61 Eu - - - - - - - -
(+/-) trans-3,3-Dimethyl-5-(2,2,3-trimethyl-cyclopent-3- Xi; R38 Xi ; N ; R: 38 - 50/53
107898-54-4 en-1-yl)-pent-4-en-2-ol N; R50-53 S: (2)24/25 - 37 - 60 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
N
R: 51/53
107934-68-9 4,4'-(9H-Fluoren-9-ylidene)bis(2-chloroaniline) N; R51-53 S: 61 Eu - - - - - - - -
Xn; R20 Conc>=25%: Xn; R20; R42/43; R36
Xi; R36 >=20%Conc<25%: Xn; R42/43; R36
108050-54-0 Tilmicosin R42/43 Xn ; R: 20 - 36 - 42/43 >=1%Conc<20%: Xn; R42/43 V - - - - - - - -

(6-(4-Hydroxy-3-(2-methoxyphenylazo)-2-sulfonato-7- Carc. Cat. 2; R45 Conc>=10%: T; R45; R41

naphthylamino)-1,3,5-triazin-2,4-diyl)bis[(amino-1- Xi; R41 T ; N ; R: 45 - 41 - 51/53 >=5%Conc<10%: T; R45; R36
108225-03-2 methylethyl)ammonium] formate N; R51-53 S: 53 - 45 - 61 >=0.1%Conc<5%: T; R45 Eu - - - - - - - -
Lithium sodium hydrogen 4-amino-6-(5-(5-chloro-2,6-
difluoropyrimidin-4-ylamino)-2-sulphonatophenylazo)-
5-hydroxy-3-(4-(2-
(sulphonatooxy)ethylsulphonyl)phenylazo)naphthalen Xi ; R: 43 ,
108624-00-6 e-2,7-disulphonate Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

N-(4-(3-(4-Cyanophenyl)ureido)-3-hydroxyphenyl)-2- Xi; R43 Xi ; R: 43 - 53 ,

108673-51-4 (2,4-di-tert-pentylphenoxy)octanamide R53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
108919-65-9 2,5-Furandione, polymer with 1-octene, sodium salt Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
Tetrasodium 10-amino-6,13-dichloro-3-(3-(4-(2,5-
disulfonatoanilino)-6-fluoro-1,3,5-triazin-2- Xi
ylamino)prop-3-ylamino)-5,12-dioxa-7,14- R: 41 Conc>=10%: Xi; R41
109125-56-6 diazapentacene-4,11-disulfonate Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Xi; R43 Xi ; N ; R: 43 - 51/53 ,

109678-33-3 2,2,6,6-Tetrakis(bromomethyl)-4-oxaheptane-1,7-diol N; R51-53 S: (2) - 22 - 24 - 37 - 41 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
(+/-)-trans-4-(4-Fluorophenyl)-3-hydroxymethyl-N- Xi; R41 R: 22-41-51/53 >=10%Conc<25%: Xi; R41
109887-53-8 methylpiperidine N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Potassium sodium 5'-(6-chloro-4-(2-(2-
vinylsulfonylethoxy)ethylamino)-1,3,5-triazin-2-
ylamino)-4'-hydroxy-2,3'-azodinaphthalene-1,2',5,7'- R: 52/53
110081-40-8 disulfonate R52-53 S: 22-61 Eu - - - - - - - -
Xn; N
Mepanipyrim [4-Methyl-N-phenyl-6-(1-propynyl)-2- Carc. Cat. 3; R40 R: 40-50/53
110235-47-7 pyrimidinamine] N; R50-53 S: (2-)36/37-46-60-61 Conc>=1%: Xn; R40 Eu - - - - - - - -
Xn; R22-48/22 Conc>=25%: Xn; R22; R48/22; R38
2-(4-(4-Cyano-3-methylisothiazol-5-ylazo)-N-ethyl-3- Xi; R38 Xn ; R: 22 - 38 - 48/22 - 53 , >=20%Conc<25%: Xn; R48/22; R38
110260-50-9 methylanilino)ethyl acetate R53 S: (2) - 22 - 36/37 - 61 >=10%Conc<20%: Xn; R48/22 Eu - - - - - - - -
N-(3-Hexadecyloxy-2-hydroxyprop-1-yl)-N-(2- R: 53
110483-07-3 hydroxyethyl)palmitamide R 53 S: 61 Eu - - - - - - - -

Page 315
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
4-(3-(4-Chlorophenyl)-3-(3,4- N ; R: 51/53 ,
110488-70-5 dimethoxyphenyl)acryloyl)morpholine N; R51-53 S: 61 Eu - - - - - - - -

1-Hydroxy-5-(2-methylpropyloxycarbonylamino)-N-(3- R: 53
110560-22-0 dodecyloxypropyl)-2-naphthoamide R53 S: 61 Eu - - - - - - - -
4,4'-(1-{4-[1-(4-Hydroxyphenyl)-1- R: 53
110726-28-8 methylethyl]phenyl}ethylidene)diphenol R53 S: 61 Eu - - - - - - - -
Xi; R43 Xi ; R: 43 - 52/53 ,
110799-28-5 N-tert-Pentyl-2-benzothiazolesulfenamide R52-53 S: (2) - 36/37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R21/22; R41; R43
Xn; R21/22 >=10%Conc<25%: Xi; R41; R43
Xi; R41 Xn ; R: 21/22 - 41 - 43, >=5%Conc<10%: Xi; R36; R43
110877-64-0 2-Chloro-4,5-difluorobenzoic acid R43 S: (2) - 26 - 36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
T ; N ; R: 23/25 - 50/53
1-(N,N-Dimethylcarbamoyl)-3-tert-butyl-5- T; R23/25 S: (1/2) - 37 - 38 - 45 - 60 - Conc>=25%: T; R23/25
110895-43-7 carbethoxymethylthio-1H-1,2,4-triazole N; R50-53 61 >=3%Conc<25%: Xn; R20/22 Eu - - - - - - - -
N-[3-(2,4-Di-(1,1-dimethyl-propyl)phenoxy)-propyl]-1-
hydroxy-5-(2-methylpropyl-oxycarbonylamino)- R: 53
111244-14-5 naphthamide R53 S: 61 Eu - - - - - - - -
7-Amino-3-((5-carboxymethyl-4-methyl-1,3-thiazol-2-
ylthio)methyl)-8-oxo-5-thia-1-azabicyclo(4,2,0)oct-2- Xn; R42/43 Xn ; R: 42/43 - 52/53 ,
111298-82-9 ene-2-carboxylic acid R52-53 S: (2) - 22 - 24 - 37 - 61 Conc>=1%: Xn; R42/43 Eu - - - - - - - -
Xn; R22 C ; N ; R: 22 - 34 - 43 - Conc>=25%: C; R34; R22; R43
C; R34 51/53 >=10%Conc<25%: C; R34; R43
R43 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%: Xi; R36/38; R43
111337-53-2 Lithium 3-oxo-1,2(2H)-benzisothiazol-2-ide N; R51-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
1:1 Mixture of: 2-[[4-[N-ethyl-N-(2-
acetoxyethyl)amino]phenyl]azo]-5,6-
dichlorobenzothiazole; 2-[[4-[N-ethyl-N-(2-
acetoxyethyl)amino]phenyl]azo]-6,7- R: 53
111381-11-4 dichlorobenzothiazole R53 S: 61 Eu - - - - - - - -
1:1 Mixture of 2-[[4-[bis(2-
acetoxyethyl)amino]phenyl]azo]-5,6-
dichlorobenzothiazole; 2-[[4-[bis(2-
acetoxyethyl)amino]phenyl]azo]-6,7- R: 53
111381-12-5 dichlorobenzothiazole R53 S: 61 Eu - - - - - - - -
R10
Xn; R20 Xn ; R: 10 - 20 - 38 , Conc>=25%: Xn; R20; R38
111439-76-0 Isobutylisopropyldimethoxysilane Xi; R38 S: (2) - 25 - 26 - 36/37 >=20%Conc<25%: Xi; R38 Eu - - - - - - - -
4-[2-(1-Methyl-2-(4-morpholinyl)ethoxy)ethyl] Xi ; R: 41, Conc>=10%: Xi; R41
111681-72-2 morpholine Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of 2,6,9-trimethyl-2,5,9-cyclododecatrien-1-ol
and 6,9-dimethyl-2-methylen-5,9-cyclododecadien-1- N ; R: 51/53
111850-00-1 ol N; R51-53 S: 61 Eu - - - - - - - -
Xn; R48/22 Xn ; N ; R: 36/38 - 43 -
Xi; R36/38 48/22 - 50/53 Conc>=20%: Xn; R48/22; R36/38; R43
R43 S: (2)23 - 26 - 36/37 - 60 - >=10%Conc<20%: Xn; R48/22; R43
111850-24-9 4-(4-Nitrophenylazo)-2,6-di-sec-butyl-phenol N; R50-53 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
N
4,4',4''-(1-Methylpropan-1-yl-3-ylidene)tris(2- R: 51/53
111850-25-0 cyclohexyl-5-methylphenol) N; R51-53 S: 61 Eu - - - - - - - -
Mixture of: (E)-oxacyclohexadec-12-en-2-one and (E)-
oxacyclohexadec-13-en-2-one and (Z)- N
oxacyclohexadec-(12)-en-2-one and (Z)- R: 50/53
111879-80-2 oxacyclohexadec-(13)-en-2-one N; R50-53 S: 60-61 Eu - - - - - - - -
Xn; R48/22 Xn; N
2S-Isopropyl-5R-methyl-1R-cyclohexyl 2,2- Xi; R41 R: 41-48/22-51/53 Conc>=10%; Xn; R48/22; R41
111969-64-3 dihydroxyacetate N; R51-53 S: (2-)22-26-36/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Conc>=25%: Xn; R40; R63; R20/22; R48/22

Carc. Cat. 3; R40 >=10%Conc<25%: Xn; R40; R63; R48/22
Repr. Cat. 3; R63 Xn ; R: 20/22 - 40 - 48/22 - >=5% Conc<10%: Xn R40; R63
111988-49-9 Thiacloprid Xn; R20/22-48/22 63 >=1% Conc<5%: Xn R40 V - - - - - - - -

Page 316
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
R43 Xi ; R: 43 - 52/53
112006-75-4 2-Aminosulfonyl-N,N-dimethylnicotinamide R52-53 S: (2)24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R22; R37; R41
Xn; R22 >=20%Conc<25%: Xi; R37; R41
Xi; R37-41 Xn ; R: 22 - 37 - 41 - 52/53 >=10%Conc<20%: Xi; R41
112193-77-8 1,4,7,10-Tetraazacyclododecane disulfate R52-53 S: (2)26 - 36/37/39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; R41 Conc>=10%: Xi; R41; R43
3-Amino-4-hydroxy-N-(2-methoxyethyl)- R43 Xi ; N ; R: 41 - 43 - 51/53 >=5%Conc<10%: Xi; R36; R43
112195-27-4 benzenesulfonamide N; R51-53 S: (2)24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; N
Benzoic acid, N–tert-butyl-N'-(4- R43 R: 43-51/53
112226-61-6 chlorobenzoyl)hydrazide N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Tetraconazole (ISO) [(+/-) 2-(2,4-Dichlorophenyl)-3- Xn; N
(1H-1,2,4-triazol-1-yl)propyl-1,1,2,2- Xn; R20/22 R: 20/22-51/53
112281-77-3 tetrafluoroethylether] N; R51-53 S: (2-)36-61 Conc>=25%: Xn; R20/22 Eu - - - - - - - -
N-tert-Butyl-N'-(4-ethylbenzoyl)-3,5- N ; R: 51/53
112410-23-8 dimethylbenzohydrazide N; R51-53 S: 61 Eu - - - - - - - -
112636-83-6 Dicyclanil Xn; R20/ R22 Xn ; R: 20/22 Conc>=25%: Xn; R20/22 V - - - - - - - -
Xi
Xi; R36 R: 36-43 Conc>=20%: Xi; R36; R43
112704-51-5 (E)-3-(2-Chlorophenyl)-2-(4-fluorophenyl)propenal R43 S: (2-)24-26-37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Silica, amorphous [Silica, amorphous, precipitated Precipitated silica (see Silica -

112926-00-8 and gel] A (a) - 10 - - - - Amorphous)
Diatomaceous
Silica, amorphous [Silica, amorphous, precipitated earth (uncalcined) (see Silica -
112926-00-8 and gel] A (a) - 10 - - - - Amorphous)

Fume (thermally
Silica, amorphous [Silica, amorphous, precipitated generated) (see Silica -
112926-00-8 and gel] A (respirable dust)(g) - 2 - - - - Amorphous)

Silica, amorphous [Silica, amorphous, precipitated Fumed silica (see Silica -

112926-00-8 and gel] A (respirable dust) - 2 - - - - Amorphous)

Silica, amorphous [Silica, amorphous, precipitated (see Silica -

112926-00-8 and gel] A Silica gel (a) - 10 - - - - Amorphous)
Xn; R20 Xn ; N ; R: 20 - 51/53 ,
113036-91-2 Hydroxo(2-(benzenesulfonamido)benzoato)zinc(II) N; R51-53 S: (2) - 22 - 57 - 61 Conc>=25%: Xn; R20 Eu - - - - - - - -
Xn; N
Cyclanilide [1-(2,4- Xn; R22 R: 22-51/53
113136-77-9 Dichloroanilinocarbonyl)cyclopropanecarboxylic acid] N; R51-53 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -
5-Amino-N-(2,6-dichloro-3-methylphenyl)-1H-1,2,4- R: 52/53
113171-13-4 triazole-3-sulfonamide R52-53 S: 61 Eu - - - - - - - -
Conc>=7%; T+: R26/28
>=1%Conc<7%: T; R23/25
113378-31-7 Semduramicin T+; R26/28 T+ ; R: 26/28 >=0.1%Conc<1%: Xn; R20/22 V - - - - - - - -
Conc>=25%: T; R25; R48/25; R36;
>=20%Conc<25%: T; R48/25; R22; R36
>=10%Conc<20%: T; R48/25; R22
T; R25-48/25 >=3%Conc<10%: Xn; R22; R48/22
113507-06-5 Moxidectin Xi; R36 T ; R: 25 - 36 - 48/25 >=1%Conc<3%: Xn; R48/22 V - - - - - - - -
Beflubutamid (ISO) [(RS)-N-Benzyl-2- N
(alpha,alpha,alpha,4-tetrafluoro-m- R: 50/53
113614-08-7 tolyoxy)butyramide] N; R50-53 S: 60-61 Eu - - - - - - - -
Conc>=25%: T; R48/25; R22; R48/20; R41;
T; R48/25 T; N R43
Xn; R22-48/20 R: 22-41-43-48/20-48/25- >=10%Conc<25%: T; R48/25; R48/20; R41;
Xi; R41 50/53 R43
4-(2-Chloro-4-trifluoromethyl)phenoxy-2-fluoroaniline R43 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: Xn; R48/22; R36; R43
113674-95-6 hydrochloride N; R50-53 61 >=1%Conc<5%: Xn; R48/22; R43 Eu - - - - - - - -

Page 317
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
C; R34 C ; N ; R: 22 - 34 - 50/53, Conc>=25%: C; R34; R22
Benzyl-2-hydroxydodecyldimethylammonium Xn; R22 S: (1/2) - 26 - 28 - 36/37/39 - >=10%Conc<25%: C; R34
113694-52-3 benzoate N; R50-53 45 - 60 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41; R43
>=20%Conc<25%: Xi; R38; R41; R43
Xn; R22 >=10%Conc<20%: Xi; R41; R43
Xi; R38-41 Xn ; R: 22 - 38 - 41 - 43 >=5%Conc<10%: Xi; R36; R43
113963-87-4 Potassium 2-(2,4-dichlorophenoxy)-(R)-propionate R43 S: (2)24 - 26 - 37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Benzene, diethenyl-, polymer with ethenylbenzene
and ethenylethylbenzene,
[bis(phosphonomethyl)amino]methyl Xi
[(phosphonomethyl)amino]methyl derivs., sodium R: 36
114060-55-8 salts Xi; R36 S: 25-26 Conc>=20%: Xi; R36 N - - - - - - - -
Xi; R38
R43 Xi ; N ; R: 38 - 43 - 51/53, Conc>=20%: Xi; R38; R43
114119-97-0 2,5,7,7-Tetramethyloctanal N; R51-53 S: (2) - 24 - 37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
N
R: 50/53
114311-32-9 Imazamox N; R50-53 S: 60-61 Eu - - - - - - - -

Conc>=25%: Xn; R22; R48/22; R38; R41; R43

Xn; R22-48/22 >=20%Conc<25%: Xn; R48/22; R38; R41; R43
Xi; R38-41 Xn; N >=10%Conc<20%: Xn; R48/22; R41; R43
3-(2-Bromopropionoyl)-4,4-dimethyl-1,3-oxazolan-2- R43 R: 22-38-41-43-48/22-50/53 >=5%Conc<10%: Xi; R36; R43
114341-88-7 one N; R50-53 S: (2-)26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
4-(4-Chlorophenyl)-2-phenyl-2-[(1H-1,2,4-triazl-1- N ; R: 50/53 ,
114369-43-6 yl)methyl]butanenitrile N; R50-53 S: 60 - 61 Eu - - - - - - - -

C.I. Direct Yellow 166 [Mixture of 2,2-iminodiethanol

6-methyl-2-(4-(2,4,6-triaminopyrimidin-5-
ylazo)phenyl)benzothiazole-7-sulfonate and N,N-
diethylpropane-1,3-diamine 6-methyl-2-(4-(2,4,6-
triaminopyrimidin-5-ylazo)phenylbenzothiazole-7-
sulfonate and 2-methylaminoethanol 6-methyl-2-(4-
(2,4,6-triaminopyrimidin-5-ylazo)phenyl)benzothiazole- Xi ; R: 43 ,
114565-65-0 7-sulfonate] Xi; R43 S: (2) - 22 - 24 - 26 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Carc. Cat. 3; R40
4-[4-(1,3-Dihydroxyprop-2-yl)phenylamino]-1,8- Xi; R43 Xn ; R: 40 - 43 - 53,
114565-66-1 dihydroxy-5-nitroanthraquinone R53 S: (2) - 36/37 - 61 Conc>=1%: Xn; R40; R43 Eu - - - - - - - -
Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
3-Amino-4-hydroxy-N-(3- Xi; R41 R: 22-41-50/53 >=10%Conc<25%: Xi; R41
114565-70-7 isopropoxypropyl)benzenesulfonamide hydrochloride N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn
2,5-Dihydroxy-5-methyl-3-(morpholin-4-yl)-2- Xn; R22 R: 22-52/53
114625-74-0 cyclopenten-1-one R52-53 S: (2-)46-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Mixture of cis-(5-ammonium-1,3,3-trimethyl)-
cyclohexanemethylammonium phosphate (1:1) and Xi; R41 Conc>=10%: Xi; R41; R43
trans-(5-ammonium-1,3,3-trimethyl)- R43 Xi ; R: 41 - 43 - 52/53 >=5%Conc<10%: Xi; R36; R43
114765-88-7 cyclohexanemethylammonium phosphate (1:1) R52-53 S: (2)24 - 26 - 37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi
1,1-Dimethylethyl 4'-(bromomethyl)biphenyl-2- R43 R: 43-53
114772-40-6 carboxylate R53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Sodium 3,5-dichloro-2-(5-cyano-2,6-bis(3-
hydroxypropylamino)-4-methylpyridin- Xi; R41. Xi ; R: 41 - 52/53 , Conc>=10%: Xi; R41
115035-41-1 3ylazo)benzenesulfonate R52-53 S: (2) - 26 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
(Tetrasodium 1-(4-(3-acetamido-4-(4'-nitro-2,2'-
disulfonatostilben-4-ylazo)anilino)-6-(2,5-
disulfonatoanilino)-1,3,5-triazin-2-yl)-3- Xi ; R: 43 ,
115099-55-3 carboxypyridinium)hydroxide Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

3-(5-Acetylamino-4-(4-[4,6-bis(3-
diethylaminopropylamino)-1,3,5-triazin-2-
ylamino]phenylazo)-2-(2-methoxyethoxy)phenylazo)-6 N; R: 50/53,
115099-58-6 amino-4-hydroxy-2-naphthalenesulfonic acid N; R50-53 S: 60 - 61 Eu - - - - - - - -
5,6,12,13-Tetrachloroanthra(2,1,9-def:6,5,10- Xn ; R: 62
115662-06-1 d'e'f')diisoquinoline-1,3,8,10(2H,9H)-tetrone Repr. Cat. 3; R62 S: (2)22 - 36/37 Conc>=5%: Xn; R62 Eu - - - - - - - -
P,P,P',P'-Tetrakis-(o-methoxyphenyl)propane-1,3- N ; R: 50/53
116163-96-3 diphosphine N; R50-53 S: 60 - 61 Eu - - - - - - - -

Conc>=25%: Xn; R21/22; R48/20; R38; R41

Xn ; R: 21/22 - 38 - 41 - >=20%Conc<25%: Xn; R48/20; R38; R41
2-(2-(2-Hydroxyethoxy)ethyl)-2-aza- Xn; R21/22-48/20 48/20 >=10%Conc<20%: Xn; R48/20; R41
116230-20-7 bicyclo[2.2.1]heptane Xi; R38-41 S: (2)26 - 36/37/39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
Xi; R41 Xn; N >=10%Conc<25%: Xi; R41; R43
1-(3-(4-Fluorophenoxy)propyl)-3-methoxy-4- R43 R: 22-41-43-51/53 >=5%Conc<10%: Xi; R36; R43
116256-11-2 piperidinone N; R51-53 S: (2-)22-24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R22; R41; R43
Xn; R22 Xn >=10%Conc<25%: Xi; R41; R43
Xi; R41 R: 22-41-43 >=5%Conc<10%: Xi; R36; R43
116313-85-0 3,4-Dihydroxy-5-nitrobenzaldehyde R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Tetrakis(tetramethylammonium) 6-amino-4-hydroxy-3- T; R25 T ; R: 25 - 43 - 52/53 , Conc>=25%: T; R25; R43

(7-sulfonato-4-(4-sulfonatophenylazo)-1- R43 S: (1/2) - 22 - 24 - 37 - 45 - >=3%Conc<25%: Xn; R22; R43
116340-05-7 naphthylazo)naphthalene-2,7-disulfonate R52-53 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
N ; R: 50/53
116412-83-0 4-Chloro-3',4'-dimethoxybenzophenone N; R50-53 S: 60 - 61 Eu - - - - - - - -
Bis(N,N',N''-trimethyl-1,4,7-triazacyclononane)-trioxo-
dimanganese (IV) di(hexafluorophosphate) N ; R: 51/53
116633-53-5 monohydrate N; R51-53 S: 61 Eu - - - - - - - -
O ; N; R7 - 50/53,
O; R7 S: (2) - 7 - 14 - 36/37/39 - 47
116753-76-5 O,O-tert-Butyl O-docosyl monoperoxyoxalate N; R50-53 - 60 - 61 Eu - - - - - - - -
Tetrakis(trimethylhexadecylammonium) hexa-mu- F; R11 F ; Xi ; N ; R: 11 - 41 - 50/53
oxotetra-mu3-oxodi-mu5- Xi; R41 , Conc>=10%: Xi; R41
116810-46-9 oxotetradecaoxooctamolybdate(4-) N; R50-53 S: (2) - 26 - 39 - 60 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Tetrasodium 4-amino-5-hydroxy-6-(4-(2-(2-
(sulfonatooxy)ethylsuifonyl)ethylcarbamoyl)phenylazo
)-3-(4-(2-
(sulfonatooxy)ethylsulfonyl)phenylazo)naphthalene- Xi ; R: 43 ,
116889-78-2 2,7-disulfonate [C.I. Reactive blue 238] Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Tetrasodium[5-((4-amino-6-chloro-1,3,5-triazin-2-
yl)amino)-2-((2-hydroxy-3,5-disulfonato-phenylazo)-2- R: 53
116912-62-0 sulfonatobenzylidene-hydrazino)benzoate]copper(II) R53 S: 61 Eu - - - - - - - -
Methyl [2-(1,1-dimethylethyl)-6-methoxypyrimidin-4- Xn; R22 Xn ; N ; R: 22 - 50/53
117291-73-3 yl]ethylphosphonothioate N; R50-53 S: (2)23 - 36 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Conc>=25%: T; R23; R41
Tetrakis(dimethylditetradecylammonium) hexa-mu- T >=10%Conc<25%: Xn; R20; R41
oxotetra-mu3-oxodi-mu5- T; R23 R: 23-41 >=5%Conc<10%: Xn; R20; R36
117342-25-3 oxotetradecaoxooctamolybdate(4-) Xi; R41 S: (1/2-)26-36/37/39-45 >=3%Conc<5%: Xn; R20 Eu - - - - - - - -
Trilithium-1-hydroxy-7-(3-sulfonatoanilino)-2-(3-
methyl-4-(2-methoxy-4-(3-
sulfonatophenylazo)phenylazo)phe- E; R2 E ; N ; R: 2 - 51/53,
117409-78-6 nylazo)naphthalene-3-sulfonate N; R51-53 S: (2) - 35 - 61 Eu - - - - - - - -

Page 319
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of; tert-alkyl(C12-C14)ammonium bis[1-[(2-

hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2)]-
chromate(1-); ter-alkyl (C12-C14)ammonium bis[1-[(2-
hydroxy-4-nitrophenyl)azo]-2-naphthalenolato(2)]-
chromate(1-); tert-alkyl(C12-C14)ammonium bis[1-[[5-
(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-
naphthalenolato(2)]-chromate(1-); tert-alkyl(C12-
C14)ammonium-[[1-[2-hydroxy-5-nitrophenyl)azo]-2-
naphthalenolato(2)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-
2-naphthalenolato(2)]]-chromate(1-); tert-alkyl(C12-
C14)ammonium-[[1-[[5-(1,1-dimethylpropyl)-2-
hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2)]-[1-
[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2)]]-
chromate(1-); tert-alkyl(C12-C14)ammonium((1-(4(or
5)-nitro-2-oxidophenylazo)-2-naphtholato)(1-(3-nitro-2- N
oxide-5-pentylphenylazo)-2-naphtholato))chromate(1- R: 51/53
117527-94-3 ) N; R51-53 S: 61 Eu - - - - - - - -
Cumene-(cyclopentadienyl)iron(II) trifluoromethane- Xn; R22 Xn ; R: 22 - 52/53
117549-13-0 sulfonate R52-53 S: (2)26 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
R: 53
117568-27-1 2-Nitro-4,5-bis(benzyloxy)phenylacetonitrile R53 S: 61 Eu - - - - - - - -
(4-(4-(4-Dimethylaminobenzyliden-1-yl)-3-methyl-5- R: 53
117573-89-4 oxo-2-pyrazolin-1-yl)benzoic acid R53 S: 61 Eu - - - - - - - -
3-(2,6-Dichloro-4-nitrophenylazo)-1-methyl-2- N ; R: 50/53
117584-16-4 phenylindole N; R50-53 S: 60 - 61 Eu - - - - - - - -

R10 O; N
1,3-Di(prop-2,2-diyl)benzene O; R7 R: 7-10-51/53
117663-11-3 bis(neodecanoylperoxide) N; R51-53 S: (2-)7-14-36/37/39-47-61 Eu - - - - - - - -
117704-25-3 Doramectin Xn; R22 Xn ; R: 22 Conc >=25%: Xn; R22 V - - - - - - - -
7-[((4,6-Dichloro-1,3,5-triazin-2-yl)amino)-4-hydroxy-3-
(4-((2-sulfoxy)ethyl)sulfonyl)-phenylazo]naphthalene- Xi; R: 43,
117715-57-8 2-sulfonic acid Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R20 Conc>=25%: Xn; R20; R36
117718-60-2 Thiazopyr Xi; R36 Xn ; R: 20 - 36 >=20%Conc<25%: Xi; R36 V - - - - - - - -
Xi; R: 43,
117827-06-2 3',5'-Dichloro-4'-ethyl-2'-hydroxypalmitanilide Xi; R43 S: (2) - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; R41 Xi Conc>=10%: Xi; R41; R43
R43 R: 41-43-52/53 >=5%Conc<10%: Xi; R36; R43
117907-43-4 2-((4-Amino-2-nitrophenyl)amino)benzoic acid R 52-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

2-(1-Butyl-3,5-dioxo-2-phenyl-(1,2,4)-triazolidin-4-yl)-
4,4-dimethyl-3-oxo-N-(2-methoxy-5-(2-(dodecyl-1- R: 53
118020-93-2 sulfonyl))propionylamino)-phenyl)-pentanamide R 53 S: 61 Eu - - - - - - - -
(2R,3S,4R,5R,7R,9R,10R,11S,12S,13R)-10-[(4-
Dimethylamino-3-hydroxy-6-methyltetrahydropyran-2-
yl)oxy]-2-ethyl-3,4,12-trihydroxy-9-methoxy- Xi
3,5,7,9,11,13-hexamethyl-6,14-dioxo-1- R: 36
118058-74-5 oxacyclotetradecane Xi; R36 S: (2-)26 Conc>=20%: Xi; R36 Eu - - - - - - - -
Xn; R20/21/22 Xn ; N ; R: 20/21/22 - 38 -
Xi; R38 43 - 50/53, Conc>=25%: Xn; R20/21/22; R38; R43
R43 S: (2) - 36/37/39 - 46 - 60 - >=20%Conc<25%: Xi; R38; R43
118134-30-8 Spiroxamine N; R50-53 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
2,4-Bis[2,2'-[2-(N,N- Xn; R22 Conc>=25%: Xn; R22; R41
dimethylamino)ethyloxycarbonyl]phenylazo]-1,3- Xi; R41 Xn ; N ;R: 22 - 41 - 51/53 >=10%Conc<25%: Xi; R41
118208-02-9 dihydroxybenzene, dihydrochloride N; R51-53 S: (2)26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Iso(C10-C14)alkyl(3,5-di-tert-butyl-4- N ; R: 50/53,
118232-72-7 hydroxyphenyl)methylthioacetate N; R50-53 S: 60 - 61 Eu - - - - - - - -

Page 320
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
N
R: 50/53
118289-55-7 6-Chloro-5-(2-chloroethyl)-1,3-dihydroindol-2-one N; R50-53 S: 60-61 Eu - - - - - - - -
N ; R: 50/53
118562-73-5 2-Cyclododecylpropan-1-ol N; R50-53 S: 60 - 61 Eu - - - - - - - -

Potassium sodium 5-(4-chloro-6-(N-(4-(4-chloro-6-(5-

hydroxy-2,7-disulphonato-6-(2-sulphonatophenylazo)-
4-naphthylamino)-1,3,5-triazin-2-ylamino)phenyl-N-
methyl)amino)-1,3,5-triazin-2-ylamino)-4-hydroxy-3-(2- Xi; R36 Xi ; R: 36 - 43 , Conc>=20%: Xi; R36; R43
118578-11-3 sulphonatophenylazo)naphthalene-2,7-disulphonat Xi; R43 S: (2) - 22 - 24 - 26 - 37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Dimethyl-(3-methyl-4-(5-nitro-3-ethoxycarbonyl-2- Xi; R43 Xi ; R: 43 - 52/53 ,
118578-14-6 thienyl)azo)phenylnitrilodipropionate R52-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R40; R22; R41; R38
>=20%Conc<25%: Xn; R40; R41; R38
Carc.Cat.3; R40 Xn >=10%Conc<20%: Xn; R40; R41
N,N-Dimethylanilinium Xn; R22 R: 22-38-40-41 >=5%Conc<10%: Xn; R40; R36
118612-00-3 tetrakis(pentafluorophenyl)borate Xi; R38-41 S: (2-)22-26-36/37/39 >=1%Conc<5%: Xn; R40 Eu - - - - - - - -

7-[4-(3-Diethylaminopropylamino)-6-(3-
diethylammoniopropylamino)-1,3,5-triazin-2-ylamino]- Xn; R48/22 Xn
4-hydroxy-3-(4-phenylazophenylazo)-naphthalene-2- R43 R: 43 - 48/22 - 52/53 Conc>=10%: Xn; R48/22; R43
118658-98-3 sulfonate, acetic acid, lactic acid (2:1:1) R52-53 S: (2)22 - 36/37 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
Xn; R22 C ; N ; R: 22 - 34 - 43 - Conc>=25%: C; R34; R22; R43
C; R34 51/53 , >=10%Conc<25%: C; R34; R43
R43 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%: Xi; R36/38; R43
118685-34-0 Sodium 5-n-butylbenzotriazole N; R51-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

2,3,5,6-Tetrafluorobenzyl trans-2-(2,2-dichlorovinyl)- Xi; R38 Xi ; N ; R: 38 - 50/53 ,

118712-89-3 3,3-dimethylcyclopropanecarboxylate N; R50-53 S: (2) - 36/37 - 60 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
(Tris(chloromethyl)phthalocyaninato)copper(II),
reaction products with N-methylpiperazine and Xi ; R: 36 ,
118800-27-4 methoxyacetic acid Xi; R36 S: (2) - 26 Conc>=20%: Xi; R36 Eu - - - - - - - -
4-(2-((3-Ethyl-4-methyl-2-oxo-pyrrolin-1- R: 52/53
119018-29-0 yl)carboxamido)ethyl)benzenesulfonamide) R52-53 S: 61 Eu - - - - - - - -
1-[4-Chloro-3-((2,2,3,3,3- N
pentafluoropropoxy)methyl)phenyl]-5-phenyl-1H-1,2,4- R: 51/53
119126-15-7 triazole-3-carboxamide N; R51-53 S: 61 Eu - - - - - - - -
Conc>=25%: C; R34; R22; R43
Xn; R22 C ; R: 22 - 34 - 43 >=10%Conc<25%: C; R34; R43
2-(2-Amino-1,3-thiazol-4-yl)-(Z)-2-methoxyiminoacetyl C; R34 S: (1/2) - 22 - 26 - 36/37/39 - >=5%Conc<10%: Xi; R36/38; R43
119154-86-8 chloride hydrochloride R43 45 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41; R43
>=20%Conc<25%: Xi; R38; R41; R43
Xn; R22 >=10%Conc<20%: Xi; R41; R43
Xi; R38-41 Xn ; R: 22 - 38 - 41 - 43 >=5%Conc<10%: Xi; R36; R43
119299-10-4 Sodium (R)-2-(2,4-dichlorophenoxy)propionate R43 S: (2)22 - 26 - 36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
2-Benzyl-2-dimethylamino-4- N ; R: 50/53;
119313-12-1 morpholinobutyrophenone N; R50-53 S: 60 - 61 Eu - - - - - - - -
Xn; R22 C ; N ; R: 22 - 34 - 51/53, Conc>=25%: C; R22; R34
C; R34 S: (1/2) - 26 - 28 - 36/37/39 - >=10%Conc<25%: C; R34
119415-07-5 C12-14-tert-Alkylamine, methylphosphonic acid salt N; R51-53 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R36;
119446-68-3 Difenoconazole Xi; R36 Xn ; R: 22 - 36 >=20%Con<25%: Xi, R36 V - - - - - - - -
Xn; R48/22
Xi; R41 Xn ; N ; R: 41 - 43 - 48/22 - Conc>=10%: Xn; R48/22; R41; R43
1,3-Bis(3-methyl-2,5-dioxo-1H- R43 50/53 >=5%Conc<10%: Xi; R36; R43
119462-56-5 pyrrolinylmethyl)benzene N; R50-53 S: (2)26 - 36/37/39 - 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
119515-38-7 Picaridin Xi; R36 Xi; R: 36 Conc>=10%: Xi; R36 V - - - - - - - -
Xn
Trisodium N,N-bis(carboxymethyl)-3-amino-2- R: 22
119710-96-2 hydroxypropionate Xn; R22 S: (2-)22 Conc>=25%: Xn; R22 Eu - - - - - - - -

Page 321
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Muta. Cat. 3; R68 Conc>=25%: T; R68; R61; R62; R22; R48/22

Repr. Cat. 2; R61 T ; N ; R: 61 - 22 - 48/22 - >=10%Conc<25%: T; R68; R61; R62; R48/22
Repr. Cat. 3; R62 62 - 68 - 50/53 >=5%Conc<10%: T; R68; R61; R62
(+/-)Tetrahydrofurfuryl (R)-2-[4-(6-chloroquinoxalin-2- Xn; R22-48/22 S: 53 - 45 - 60 - 61; >=1%Conc<5%: T; R68; R61
119738-06-6 yloxy)phenyloxy]propionate [Quizalafop-p-tefuryl] N; R50-53 Note: E >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Xn; N
Xn; R48/22 R: 48/22-51/53
119916-05-1 Methyl 3-amino-4,6-dibromo-2-methyl-benzoate N; R51-53 S: (2-)22-36-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -

Disodium 7-((4,6-bis(3-diethylaminopropylamino)-
1,3,5-triazine-2-yl)amino)-4-hydroxy-3-(4-(4-
sulfonatophenylazo)phenylazo)-2-naphthalene R: 52/53
120029-06-3 sulfonate R52-53 S: 61 Eu - - - - - - - -
Conc>=25%: T; R23/24/25; R48/25
Fipronil (ISO) [5-Amino-1-[2,6-dichloro-4- T; N >=10%Conc<25%: T; R48/25; R20/21/22
(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H- T; R23/24/25-48/25 R: 23/24/25-48/25-50/53 >=3%Conc<10%: Xn; R20/21/22; R48/22
120068-37-3 pyrazole-3-carbonitrile] N; R50-53 S: (1/2-)28-36/37-45-60-61 >=1%Conc<3%: Xn; R48/22 Eu - - - - - - - -
N
5-Amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-1H- R: 51/53
120068-79-3 pyrazole-3-carbonitrile N; R51-53 S: 22-61 Eu - - - - - - - -

C; N
(Z)-13-Docosenyl-N,N-bis(2-hydroxyethyl)-N-methyl- C; R34 R; 34-50/53 Conc>=10%: C; R34
120086-58-0 ammonium-chloride N; R50-53 S: (2-)26-36/37/39-45-60-61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
N
Cyazofamid (ISO) [4-Chloro-2-cyano-N,N-dimethyl-5- R: 50/53
120116-88-3 p-tolylimidazole-1-sulfonamide] N; R50-53 S: 60-61 Eu - - - - - - - -
Azimsulfuron (ISO) [1-(4,6-Dimethoxypyrimidin-2-yl)- N
3-[1-methyl-4-(2-methyl-2H-tetrazol-5-yl)pyrazol-5- R: 50/53
120162-55-2 ylsulfonyl]urea] N; R50-53 S: 60-61 Eu - - - - - - - -
Muta. Cat. 3; R68 Xn ; R: 68 - 53
120187-29-3 4'-Ethoxy-2-benzimidazoleanilide R53 S: (2)22 - 36/37 - 61 Conc>=1%: Xn; R68 Eu - - - - - - - -
Xi; N
(S,S)-trans-4-(Acetylamino)-5,6-dihydro-6-methyl-7,7- R43 R: 43-50/53
120298-38-6 dioxo-4H-thieno[2,3-b]thiopyran-2-sulfonamide N; R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; N
R 43 R: 43-50/53
120307-06-4 Tetrabutylammonium butyltriphenylborate N; R50-53 S: (2-)24-37-56-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25%: C; R35; R22
C ; R: 22 - 35 , >=10%Conc<25%: C; R35
Xn; R22 S: (1/2) - 26 - 28 - 36/37/39 - >=5%Conc<10%: C; R34
120447-91-8 Potassium 2-amino-2-methylpropionate octahydrate C; R35 45 >=1%Conc<5%: Xi; R36/38 Eu - - - - - - - -

trans-3-[2-(7-Chloro-2-quinolinyl)vinyl]benzaldehyde R: 53
120578-03-2 [3-[(E)-2-(7-Chloro-2-quinolinyl)vinyl]benzaldehyde] R53 S: 22-61 Eu - - - - - - - -
Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
Benzyl-N-(2-(2-methoxyphenoxy)ethyl)amine Xi; R41 R: 22-41-50/53 >=10%Conc<25%: Xi; R41
120606-08-8 hydrochloride N; R50-53 S: (2-)22-26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
R: 52/53
120807-02-5 cis-1-Benzoyl-4-[(4-methylsulfonyl)oxy]-L-proline R 52-53 S: 61 Eu - - - - - - - -
T; R25 T; N
Xn; R20 R: 20 - 25 - 50/53 Conc>=25%: T; R25; R20
120928-09-8 4-[2-[4-(1,1-Dimethylethyl)phenyl]-ethoxy]quinazoline N; R50-53 S:(1/2) - 37 - 45 - 60 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Repr.Cat.3; R63 Conc>=10%: Xn; R63; R48/22; R43
Xn; R48/22 >=5%Conc<10%: Xn; R63; R43
120983-64-4 Prothioconazole-desthio Xi; R43 Xn; R: 43-48/22-63 >=1%Conc<5%: Xi; R43 V - - - - - - - -
Xn
Xn; R22 R: 22-52/53
121219-07-6 1-Ethoxy-2,3-difluorobenzene R52-53 S: (2-)23-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi; N
N2,N4,N6-Tris{4-[(1,4-dimethylpentyl)amino]phenyl}- R43 R: 43-50/53
121246-28-4 1,3,5-triazine-2,4,6-triamine N; R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

trans-N-Methyl-2-styryl-[4'-aminomethine-(1-acetyl-1- Xi; R43 Xi ; N ; R: 43 - 51/53,

121315-16-0 (2-methoxyphenyl)acetamido)]pyridinium acetate N; R51-53 S: (2) - 22 - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn; N
3,5-Dichloro-2-fluoro-4-(1,1,2,3,3,3- R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
121451-05-6 hexafluoropropoxy)aniline N; R50-53 S: (2-)24-37-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

4-((4-(Diethylamino)-2-ethoxyphenyl)imino)-1,4- R: 53
121487-83-0 dihydro-1-oxo-N-propyl-2-naphthalenecarboxamide R53 S: 61 Eu - - - - - - - -
C ; N ; R: 34 - 50/53 ,
C; R34 S: (1/2) - 26 - 36/39 - 45 - Conc>=10%: C; R34
121518-45-4 2,4-Dichloro-3-ethylphenol N; R50-53 60 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xn; R48/22
Cyprodinil [4-Cyclopropyl-6-methyl-N-phenylpyrimidin- Xi; R43 Xn; N R: 43-48/22-50/53 Conc>=10%: Xn; R48/22; R43
121552-61-2 2-amine] N; R50-53 S: (2-)24-37-46-60-61 >=1%Conc<10%: Xi; R43 Eu/V - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
121575-60-8 Pitch, coal tar, high temp., heat treated [Pitch] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Distillates (coal tar), benzole fraction, distn. residues

[Wash Oil](Note: A complex combination of
hydrocarbons obtained from the distillation of crude
benzole (high temperature coal tar). It may be a liquid
with the approximate distillation range of 150 °C to T
300 °C (302 °F to 572 °F) or a semi-solid or solid with R: 45-46
a melting point up to 70 °C (158 °F). It is composed Carc. Cat. 2; R45 S: 53-45
121620-46-0 primarily of naphthalene and alkyl naphthalenes.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract residues (coal), naphthalene oil, alk.

[Naphthalene Oil Extract Residue](Note: A complex
combination of hydrocarbons obtained from the alkali T
washing of naphthalene oil to remove phenolic R: 45-46
compounds (tar acids). It is composed of Carc. Cat. 2; R45 S: 53-45
121620-47-1 naphthalene and alkyl naphthalenes.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract residues (coal), naphthalene oil, alk.,

naphthalene-low [Naphthalene Oil Extract
Residue](Note: A complex combination of
hydrocarbons remaining after the removal of T
naphthalene from alkali-washed naphthalene oil by a R: 45-46
crystallization process. It is composed primarily of Carc. Cat. 2; R45 S: 53-45
121620-48-2 naphthalene and alkyl naphthalenes.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Xi; R38 Xi ; N ; R: 38 - 51/53
121626-73-1 1-Allyl-3-chloro-4-fluorobenzene N; R51-53 S: (2)23 - 37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -

1-((3-(3-Chloro-4-fluorophenyl)propyl)dimethylsilanyl)- N ; R: 51/53
121626-74-2 4-ethoxybenzene N; R51-53 S: 61 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 41 - 42/43 - Conc>=25%: Xn; R22; R42/43; R41
Xi; R41 50 , >=10%Conc<25%: Xn; R42/43; R41
R42/43 S: (2) - 22 - 26 - 36/37/39 - >=5%Conc<10%: Xn; R42/43; R36
122012-52-6 Diamminediisocyanatozinc N; R50 41 - 61 >=1%Conc<5%: Xn; R42/43 Eu - - - - - - - -
Xi ; R: 41 - 43 Conc>=10%: Xi; R41; R43
Oxo-((2,2,6,6-tetramethylpiperidin-4- Xi; R41 S: (2)8 - 22 - 24 - 26 - 30 - >=5%Conc<10%: Xi; R36; R43
122035-71-6 yl)amino)carbonylacetohydrazide R43 37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
T ; R: 45 ,
Phenanthrene, distn. residues [Heavy anthracene oil S: 53 - 45 ;
122070-78-4 redistillate] Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -

Page 323
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Extract oils (coal), coal tar-residual pyrolysis oils,

naphthalene oils [Redistillates](Note: A neutral oil
obtained by debasing and dephenolating the oil
obtained from the distillation of high temperature tar
and pyrolysis residual oils which has a boiliing range T
of 225 °C to 255 °C (437 °F to 491 °F). Composed R: 45-46
primarily of substituted dinuclear aromatic Carc. Cat. 2; R45 S: 53-45
122070-79-5 hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -

Extract oils (coal), coal tar residual pyrolysis oils,

naphthalene oil, distn. residues [Redistillates](Note:
Residue from the distillation of dephenolated and
debased methylnaphthalene oil (from bituminous coal
tar and pyrolysis residual oils) with a boiling range of T
240 °C to 260 °C (464 °F to 500 °F). Composed R: 45-46
primarily of substituted dinuclear aromatic and Carc. Cat. 2; R45 S: 53-45
122070-80-8 heterocyclic hydrocarbons.) Muta. Cat. 2; R46 Notes: H ; J Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Xi
2'-(4-Chloro-3-cyano-5-formyl-2-thienylazo)-5'- R43 R: 43 - 53
122371-93-1 diethylamino-2-methoxyacetanilide R53 S: (2)22 - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Extract residues (coal), creosote oil acid [Wash Oil

Extract Residue](Note: A complex combination of
hydrocarbons from the base-freed fraction from the
distillation of coal tar, boiling in the range of T
approximately 250 °C to 280 °C (482 °F to 536 °F). It R: 45
consists predominantly of biphenyl and isomeric S: 53-45
122384-77-4 diphenylnaphthalenes.) Carc. Cat. 2; R45 Notes: H ; M Conc>=0.1%: T; R45 Eu - - - - - - - -
Extract residues (coal), low temp. coal tar alk.(Note:
The residue from low temperature coal tar oils after
an alkaline wash, such as aqueous sodium T
hydroxide, to remove crude coal tar acids. Composed R: 45-46
primarily of hydrocarbons and aromatic nitrogen Carc. Cat. 2; R45 S: 53-45
122384-78-5 bases.) Muta. Cat. 2; R46 Notes: H ; J ; M Conc>=0.1%: T; R45; R46 Eu - - - - - - - -
Phenol, tetrapropylene-, sulfurized, calcium
salts(Note: The classification for reproductive toxicity
need not apply if it can be shown that the substance
contains less than 0.5 % unreacted tetrapropenyl Xn
122384-85-4 phenol (TPP)/CaTPP) Repr. Cat. 3; R62 R: 62 Conc>=5%: Xn; R62 N - - - - - - - -

Phenol, tetrapropylene-, sulfurized, carbonates,

calcium salts(Note: The classification for reproductive
toxicity need not apply if it can be shown that the
substance contains less than 0.5 % unreacted Xn
122384-86-5 tetrapropenyl phenol (TPP)/CaTPP.) Repr. Cat. 3; R62 R: 62 Conc>=5%: Xn; R62 N - - - - - - - -

Phenol, tetrapropylene-, sulfurized, carbonates,

calcium salts, overbased(Note: The classification for
reproductive toxicity need not apply if it can be shown
that the substance contains less than 0.5 % Xn
122384-87-6 unreacted tetrapropenyl phenol (TPP)/CaTPP.) Repr. Cat. 3; R62 R: 62 Conc>=5%: Xn; R62 N - - - - - - - -

T; R23 T; N
Chlorfenapyr (ISO) [4-Bromo-2-(4-chlorophenyl)-1- Xn; R22 R: 22-23-50/53 Conc>=25%: T; R23; R22
122453-73-0 ethoxymethyl-5-trifluoromethylpyrrole-3-carbonitrile] N; R50-53 S: (1/2-)13-36/37-45-60-61 >=3%Conc<25%: Xn; R20 Eu - - - - - - - -

Dimethyl 3,3'-(N-(4-(4-bromo-2,6-dicyanophenylazo)- R: 53
122630-55-1 3-hydroxyphenyl)imino)dipropionate R53 S: 61 Eu - - - - - - - -
Xi
Ethyl (3-cyanomethyl-3,4-dihydro-4-oxophthalazin-1- R43 R: 43-52/53
122665-86-5 yl)acetate R52-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 324
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi; R38
R43 Xi ; N ; R: 38 - 43 - 51/53, Conc>=20%: Xi; R38; R43
122760-84-3 4-Methyl-8-methylenetricyclo[3.3.1.13,7]decan-2-ol N; R51-53 S: (2) - 24 - 37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xi; R38
4-Methyl-8-methylenetricyclo[3.3.1.13,7]decan-2-ol R43 Xi ; N ; R: 38 - 43 - 51/53 Conc>=20%: Xi; R38; R43
122760-85-4 acetate N; R51-53 S: (2)36/37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
R: 53
122886-55-9 N,N"-(Methylenedi-4,1-phenylene)bis[N'-octylurea] R53 S: 61 Eu - - - - - - - -
Xi; R36 Xi ; R: 36 - 53 ,
123312-54-9 Dimethyldioctadecylammonium hydrogen sulfate R53 S: (2) - 26 - 39 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
Xn
Pymetrozine (ISO) [(E)-4,5-Dihydro-6-methyl-4-(3- Carc.Cat3; R40 R: 40-52/53
123312-89-0 pyridylmethyleneamino)-1,2,4-triazin-3(2H)-one] R52-53 S: (2-)36/37-61 Conc>=1%: Xn; R40 Eu - - - - - - - -
E
1-Hydroxybenzotriazole, monohydrated(Note: see R: 2
123333-53-9 also CAS No. 2592-95-2) E; R2 S: 16-35 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22, R41
Xi; R41 R: 22-41-52/53 >=10%Conc<25%: Xi; R41
123439-82-7 Tetraammine platinum (II) hydrogen carbonate R52-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N-(2-(1-Allyl-4,5-dicyanoimidazol-2-ylazo)-5-
123590-00-1 (dipropylamino)phenyl)-acetamide R53 R: 53 S: 61 Eu - - - - - - - -
Xi
[[2-Methyl-1-(1-oxopropoxy)propoxy](4- R: 36
123599-82-6 phenylbutyl)phosphinyl] acetic acid Xi; R36 S: (2-)26 Conc>=20%: Xi; R36 Eu - - - - - - - -

Xn; R22 Xn ; R: 22 - 36/37/38 - 42 , Conc>=25%: Xn; R22; R36/37/38; R42.

Xi; R36/37/38 S: (2) - 39 ; >=10%Conc<25%: Xn; R36/37/38; R42
123748-85-6 8,9-Dinorborn-5-ene-2,3-dicarboxylic anhydride R42 Note: C >=1%Conc<10%: Xn; R42 Eu - - - - - - - -
2-(1-(2-Hydroxy-3,5-di-tert-pentyl-phenyl)ethyl)-4,6-di- R: 53
123968-25-2 tert-pentylphenyl acrylate R53 S: 61 Eu - - - - - - - -
N
Mixture of: (E)-2,12-tridecadiennitrile and (E)-3,12- R: 50/53
124071-40-5 tridecadiennitrile and (Z)-3,12-tridecadiennitrile N; R50-53 S: 60-61 Eu - - - - - - - -
N,N'-1,6-Hexanediylbis(N-(2,2,6,6-tetramethyl- Xi; R36 Xi ; R: 36 - 52/53
124172-53-8 piperidin-4-yl)formamide R52-53 S: (2)26 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
(S)-4-(3,4-Dichlorophenyl)-3,4-dihydro-2H-naphthalen- R: 53
124379-29-9 1-one R53 S: 61 Eu - - - - - - - -

Xi; R43 Xi ; N ; R: 43 - 50/53,

124495-18-7 Quinoxyfen N; R50-53 S: (2) - 24 - 37 - 46 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Hexakis(tetramethylammonium) 4,4'-vinylenebis((3-
sulfonato-4,1-phenylene)imino(6-morpholino-1,3,5- T; R25 Conc>=25%: T; R25; R43
triazine-4,2-diyl)imino)bis(5-hydroxy-6- R43 T ; R: 25 - 43 - 52/53 , >=3%Conc<25%: Xn; R22; R43
124537-30-0 phenylazonaphthalene-2,7-disulfonate R52-53 S: (1/2) - 24 - 37 - 45 - 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 41 - 43 - Conc>=25%: Xn; R22; R41; R43
3(or 5)-(4-(n-Benzyl-N-ethylamino)-2- Xi; R41 51/53, >=10%Conc<25%: Xi; R41; R43
methylphenyIazo)-1,4-dimethyl-1,2,4-triazolium R43 S: (2) - 22 - 24 - 26 - 37/39 - >=5%Conc<10%: Xi; R36; R43
124584-00-5 methylsulphate N; R51-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; N
Tetra-sodium/lithium 4,4'-bis-(8-amino-3,6-disulfonato- R43 R: 43-51/53
124605-82-9 1-naphthol-2-ylazo)-3-methylazobenzene N; R51-53 S: (2-)24-28-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
D-Erythro-hexanoic acid 2,4-dideoxy-3,5-O-(1-
methylethylidene)-1,1-dimethylethylester [tert-Butyl 2- Xn
[(4R,6S)-6-(hydroxymethyl)-2,2-dimethyl-1,3-dioxan-4- R: 22
124655-09-0 yl]acetate] Xn; R22 S: (2-)25 Conc>=25%: Xn; R22 Eu - - - - - - - -
Sodium ((N-(3- Xi
trimethylammoniopropyl)sulfamoyl)methylsulfonatoph R: 41 Conc>=10%: Xi; R41
124719-24-0 thalocyaninato)copper(II) Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn ; N ; R: 38 - 48/22 -
Xn; R48/22 50/53
Xi; R38 S: (2)23 - 25 - 36/37 - 60 - Conc>=20%: Xn; R48/22; R38
124719-26-2 4-(3,4-Dichlorophenylazo)-2,6-di-sec-butyl-phenol N; R50-53 61 >=10%Conc<20%: Xn; R48/22 Eu - - - - - - - -

Page 325
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

E; R2 Conc>=25%: T; R23/25; R21-48/22; R41; R43

T; R23/25 >=10%Conc<25%: Xn; R20/22; R48/22; R41;
Xn; R21-48/22 E ; T ; N ; R: 2 - 21 - 23/25 - R43
Xi; R41 41 - 43 - 48/22 - 50/53 , >=5%Conc<10%: Xn; R20/22; R36; R43
4-Dimethylaminobenzenediazonium 3-carboxy-4- R43 S: (1/2) - 3 - 12 - 26 - 35 - >=3%Conc<5%: Xn; R20/22; R43
124737-31-1 hydroxybenzenesulfonate N; R50-53 36/37/39 - 45 - 61 >=1%Conc<3%: Xi; R43 Eu - - - - - - - -
F; R11
Repr. Cat. 3; R62 F ; Xn ; N ; R: 11 - 48/22 -
Bis(eta5-cyclopentadienyl)-bis(2,6-difluoro-3-[pyrrol-1- Xn; R48/22 62 - 51/53 Conc>=10%: Xn; R62; R48/22
125051-32-3 yl]-phenyl)titanium N; R51-53 S: (2)7 - 22 - 33 - 36/37 - 61 >=5%Conc<10%: Xn; R62 Eu - - - - - - - -
R10 Conc>=25%: Xn; R22; R38; R41
Xn; R22 Xn ; N ; R: 10 - 22 - 38 - 41 - >=20%Conc<25%: Xi; R38; R41
Di-tert-(C12-14)-alkylammonium 2- Xi; R38-41 51/53 >=10%Conc<20%: Xi; R41
125078-60-6 benzothiazolylthiosuccinate N; R51-53 S: (2)26 - 37/39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N ; R: 51/53
125109-85-5 beta-Methyl-3-(1-methylethyl)-benzenepropanal N; R51-53 S: 61 Eu - - - - - - - -
Metconazole (ISO) [(1RS,5RS;1RS,5SR)-5-(4- Repr. Cat. 3; R63 Xn; N
Chlorobenzyl)-2,2-dimethyl-1-(1H-1,2,4-triazol-1- Xn; R22 R: 22-63-51/53 Conc>=25%: Xn; R63; R22
125116-23-6 ylmethyl)cyclopentanol] N; R51-53 S: (2-)36/37-46-61 >=5%Conc<25%: Xn; R63 Eu - - - - - - - -
Poly(vinyl acetate), partially hydrolyzed, with (E)-2-(4-
formylstyryl)-3,4-dimethylthiazolium methyl sulfate, R: 52/53,
125139-08-4 reaction products of R52-53 S: 61 Eu - - - - - - - -
Xi
1S)-2-Methyl-2,5-diazobicyclo[2.2.1]heptane R: 43
125224-62-6 dihydrobromide R43 S: (2)24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
125225-28-7 Ipconazole Xn; R20/22 Xn; R: 20/22 Conc>=25%: Xn; R20/22 V - - - - - - - -

Copolymer of vinyl-alcohol and vinyl acetate partially N

acetilized with 4-(2-(4-formylphenyl)ethenyl)-1- R: 51/53
125229-74-5 methylpyridinium methylsulfate N; R51-53 S: 61 Eu - - - - - - - -
Xi; R41 Conc>=10%: Xi; R41; R43
Lithium 1-amino-4-(4-tert-butylanilino)anthraquinone- R43 Xi ; N ; R: 41 - 43 - 51/53 >=5%Conc<10%: Xi; R36; R43
125328-86-1 2-sulfonate N; R51-53 S: (2)22 - 26 - 36/37/39 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Conc>=20%: Xi; R38; R41; R43
Xi; R38-41 Xi; N >=10%Conc<20%: Xi; R41; R43
R43 R: 38-41-43-50/53 >=5%Conc<10%: Xi; R36; R43
125474-34-2 (E,E)-3,7,11-Trimethyldodeca-1,4,6,10-tetraen-3-ol N; R50-53 S: (2-)23-24-26-37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; R38 Xi
R43 R: 38-43-53 Conc>=20%: Xi; R38; R43
125496-22-2 18-Methylnonadecyl 2,2 -dimethylpropanoate R53 S: (2-)24-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Methyl(5-hexenyl)dichlorosilane, hydrolysed [alpha,ú- N ; R: 51/53

125613-45-8 dihydroxypoly(hex-5-en-1-ylmethylsiloxane)] N; R51-53 S: 61 Eu - - - - - - - -
Ethyl N-(5-chloro-3-(4-(diethylamino)-2- N
methylphenylimino)-4-methyl-6-oxo-1,4- R: 50/53
125630-94-6 cyclohexadienyl)carbamate N; R50-53 S: 60-61 Eu - - - - - - - -
Reaction mass of isomers of: C7-9-alkyl 3-(3,5-di-tert- R: 53
125643-61-0 butyl-4-hydroxyphenyl)propionate R53 S: 61 Eu - - - - - - - -
N
Methyl (E)-2((3-(1,3-benzodioxol-5-yl)-2-methyl-1- R: 50/53
125778-19-0 propenyl)amino)benzoate N; R50-53 S: 60-61 Eu - - - - - - - -
Xn; R22-48/22 C ; N ; R: 22 - 34 - 43 - Conc>=25%: C; R22; R34; R48/22; R43
C; R34 48/22 - 50/53 >=10%Conc<25%: C; R34; R48/22; R43
R43 S: (1/2) - 26 - 28 - 36/37/39 - >=5%Conc<10%: Xi; R36/38; R43
125792-14-5 Tributyltetradecylphosphonium tetrafluoroborate N; R50-53 45 - 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

9,12-Octadecanoic acid (Z,Z)-, dimer, compound with

(Z,Z)-N-[3-(dimethylamino) propyl]-9, 12-
octadecadienamide (1:1) [Linoleamidopropyl
dimethylamine dimer dilinoleate; Bis Xi; R38 Conc>=20%: Xi; R38; R43
125804-10-6 (linoleamidopropyl dimethyl amine) dimer dilinoleate] Xi; R43 Xi; R: 38 - 43 >=1%Conc<20%: Xi; R43 N - - - - - - - -

Page 326
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
F; R11 F; Xi
2-Methyl-3-(trimethoxysilyl)propyl-2-propenoate Xi; R36 R: 11-36-67
125804-20-8 hydrolysis product with silica R67 S: (2-)16-26 Conc>=20%: Xi; R36 Eu - - - - - - - -
Xi; N
4-Methyl-3-oxo-N-phenyl-2- R43 R: 43-51/53
125971-57-5 (phenylmethylene)pentanamide N; R51-53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
4-(4-Fluorophenyl)-2-(2-methyl-1-oxopropyl)-4-oxo- R: 53
125971-96-2 3,N-diphenylbutanamide R53 S: 61 Eu - - - - - - - -
2,2'-Methylenebis(4,6-di-tert-butyl-phenyl)-2- R: 53
126050-54-2 ethylhexyl phosphite R53 S: 61 Eu - - - - - - - -

Dilithium disodium (5,5'-diamino-(-4,4'-dihydroxy-1:2-

k-2,O4,O4',-3,3'-[3,3'-dihydroxy-1:2-k-2-O3,O3'-
biphenyl-4,4'-ylenebisazo-1:2-(N3,N4-eta:N3',N4'-
eta)]-dinaphthalene-2,7-disulfonato(8)))dicuprate(2-) Xn; R22 Xn ; R: 22 - 43 Conc>=25%: Xn; R22; R43
126637-70-5 [(SYN- BLUE GS 1259 R5)] R43 S: (2 - )22 - 24 - 37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Ethoxysulfuron [1-(4,6-dimethoxypyrimidin-2-yl)-3-(2- N ; R: 50/53
126801-58-9 ethoxyphenoxysulfonyl)urea N; R50-53 S: 60 - 61 Eu - - - - - - - -
N
Fenhexamid [N-(2,3-Dichloro-4-hydroxyphenyl)-1- R: 51/53
126833-17-8 methylcyclohexancarboxamid] N; R51-53 S: 61 Eu - - - - - - - -
Xi; N Conc>=20%: Xi; R38; R41
Xi; R38-41 R: 38-41-50/53 >=10%Conc<20%: Xi; R41
126990-35-0 Dicyclopentyldimethoxysilane N; R50-53 S: (2-)26-37/39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; R22 Xn ; N ; R: 22 - 51/53
127047-77-2 2-(2-Iodoethyl)-1,3-propanediol diacetate N; R51-53 S: (2)36 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
R: 53
127474-91-3 Bis(2-ethylhexyl) naphthalene-2,6-dicarboxylate R53 S: 61 Eu - - - - - - - -
Mixture of branched and linear C7-C9 alkyl 3-[3-(2H-
benzotriazol-2-yl)-5-(1,1-dimethyl-ethyl)-4- N ; R: 51/53,
127519-17-9 hydroxyphenyl]propionates N; R51-53 S: 61 Eu - - - - - - - -
Xn; R22 Xn; N
(S)-4-(4-Dimethylamino-1-(4-fluorophenyl)-1- R43 R: 22-43-51/53 Conc>=25%: Xn; R22; R43
128173-52-4 hydroxybutyl)-3-(hydroxymethyl)benzonitrile N; R51-53 S: (2-)36/37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

O; R7 O; Xi; N
Xi; R41 R: 7-41-50 Conc>=10%: Xi; R41
128275-31-0 6-(Phthalimido)peroxyhexanoic acid N; R50 S: (2-)3/7-14-26-36/37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Carfentrazone-ethyl (ISO) [Ethyl (RS)-2-chloro-3-[2-

chloro-4-fluoro-5-[4-difluoromethyl-4,5-dihydro-3- N ; R: 50/53
128639-02-1 methyl-5-oxo-1H-1,2,4-triazol-1-yl]phenyl]propionate] N; R50-53 S: 60 - 61 Eu - - - - - - - -

C
C; R34 R: 34-52/53 Conc>=10%: C; R34
129050-62-0 Trisodium N,N-bis(carboxymethyl)-beta-alanine R52-53 S: (1/2-)26-36/37/39-45-61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xi; N
R43 R: 43-51/53
129205-19-2 2,4-Dihydroxy-N-(2-methoxyphenyl)benzamide N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; N
Reaction products of: aniline-terephthalaldehyde-o- R43 R: 43-51/53
129217-90-9 toluidine condensate with maleic anhydride N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; R38 Xi ; N ; R: 38 - 51/53
129228-11-1 2-Isopropyl-2-(1-methylbutyl)-1,3-dimethoxypropane N; R51-53 S: (2)36/37 - 61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xi; N
Xi; R38 R: 38-51/53
129228-21-3 2-Isobutyl-2-isopropyl-1,3-dimethoxypropane N; R51-53 S: (2-)23-37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -
Xn; R20 Conc>=25%: Xn; R20; R36
129496-10-2 Milbemycin oxime Xi; R36 Xn ; R: 20 - 36 >=20%Conc<25%: Xi; R36 V - - - - - - - -
N-(5-Chloro-3-((4-(diethylamino)-2-
methylphenyl)imino-4-methyl-6-oxo-1,4- Xi ; R: 43
129604-78-0 cyclohexadien-1-yl)benzamide R43 S: (2)24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 327
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Pyraflufen (ISO) [2-Chloro-5-(4-chloro-5-
difluoromethoxy-1-methylpyrazol-3-yl)-4- N
fluorophenoxyacetic acid](Note: see also CAS No. R: 50/53
129630-17-7 129630-19-9) N; R50-53 S: 60-61 Eu - - - - - - - -
Pyraflufen-ethyl (ISO) [2-Chloro-5-(4-chloro-5-
difluoromethoxy-1-methylpyrazol-3-yl)-4- N
fluorophenoxyacetic acid ethyl ester](Note: see also R: 50/53
129630-19-9 CAS No. 129630-17-7) N; R50-53 S: 60-61 Eu - - - - - - - -
2,3-Epoxypropyl-2-ethylcyclohexyl ether Xi; R36/38 Xi ; R: 36/38 - 43 , Conc>=20%: Xi; R36/38; R43
130014-35-6 [Ethylcyclohexylglycidyl ether] R43 S: (2) - 26 - 28 - 37/39 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
N
N-[4-(4-Cyano-2-furfurylidene-2,5-dihydro-5-oxo-3- R: 50/53
130016-98-7 furyl)phenyl]butane-1-sulfonamide N; R50-53 S: 60-61 Eu - - - - - - - -
R43 Xi ; N ; R: 43 - 50/53
130066-57-8 Bis[4-(ethenyloxy)butyl] 1,3-benzenedicarboxylate N; R50-53 S: (2)24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Trisodium(2-(alpha-(3-(4-chloro-6-(2-(2-
(vinylsulfonyl)ethoxy)ethylamino)-1,3,5-triazin-2-
ylamino)-2-oxido-5- Xi
sulfonatophenylazo)benzylidenehydrazino)-4- R: 41 Conc>=10%: Xi; R41
130201-51-3 sulfonatobenzoato)copper(II) Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Tetrasodium 5-[4-chloro-6-(N-ethyl-anilino)-1,3,5-
triazin-2-ylamino]-4-hydroxy-3-(1,5- Xi; R41 Xi ; N ; R: 41 - 43 - 51/53 Conc>=10%: Xi; R41; R43
disulfonatonaphthalen-2-ylazo)-naphthalene-2,7- R43 S: (2)22 - 24 - 26 - 37/39 - >=5%Conc<10%: Xi; R36; R43
130201-57-9 disulfonate N; R51-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
6-Docosyloxy-1-hydroxy-4-(1-(4-hydroxy-3-
methylphenanthren-1-yl)-3-oxo-2-oxaphenalen-1- Xi; R43 Xi ; R: 43 - 53 ,
130263-41-1 yl)naphthalene-2-carboxylic acid R53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of hydroxyaluminium bis[2-hydroxy-3,5-di-tert- Xn; R22 Xn ; N ; R: 22 - 50/53,

130296-87-6 butylbenzoate] and 3,5-di-tert-butyl-salicylic acid N; R50-53 S: (2) - 22 - 60 - 61 Conc>=25%: Xn; R22 Eu - - - - - - - -
3-(6-O-(6-Desoxy-alpha-L-mannopyranosyl-O-(alpha-
D-glucopyranosyl)-(beta-D-glucopyranosyl)oxy)-2-(3,4 Xi; N
dihydroxyphenyl)-5,7-dihydroxy-4H-1-benzopyran-4- R43 R: 43-51/53
130603-71-3 one N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Muta. Cat. 3; R68
N,N,N',N'-Tetraglycidyl-4,4'-diamino-3,3'- R43 Xn ; N ; R: 43 - 68 - 51/53
130728-76-6 diethyldiphenylmethane N; R51-53 S: (2)36/37 - 61 Conc>=1%: Xn; R68; R43 Eu - - - - - - - -
N
4,4'-Dithiobis(5-amino-1-(2,6-dichloro-4- R: 50/53
130755-46-3 (trifluoromethyl)phenyl)-1H-pyrazole-3-carbonitrile) N; R50-53 S: 60-61 Eu - - - - - - - -
Xn; R22 Xn; N
1,4-Dichloro-2-(1,1,2,3,3,3-hexafluoropropoxy)-5- R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
130841-23-5 nitrobenzene N; R50-53 S: (2-)36/37/39-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Tris(tetramethylammonium) 5-hydroxy-1-(4-
sulphonatophenyl)-4-(4- T; R25 T ; R: 25 - 52/53 Conc>=25%: T; R25
131013-81-5 sulphonatophenylazo)pyrazole-3-carboxylate R52-53 S: (1/2) - 37 - 45 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
Tetrakis(tetramethylammonium)3,3'-(6-(2-
hydroxyethylamino)1,3,5-triazine-2,4-diylbisimino(2-
methyl-4,1-phenyleneazo))bisnaphthalene-1,5- T; R25 T ; R: 25 - 52/53 Conc>=25%: T; R25
131013-83-7 disulfonate R52-53 S: (1/2) - 37 - 45 - 61 >=3%Conc<25%: Xn; R22 Eu - - - - - - - -
R: 52/53
131266-10-9 2-Acetoxymethyl-4-benzyloxybut-1-yl acetate R52-53 S: 61 Eu - - - - - - - -
Xn
R: 20
131298-44-7 Branched C10-alkyl benzoates Xn; R20 S: (2-)23 Conc>=25%: Xn; R20 Eu - - - - - - - -
(+/-)-2-(2,4-Dichlorophenyl)-3-(1H-1,2,4-triazol-1- R: 52/53
131320-44-0 yl)propan-1-ol R52-53 S: 61 Eu - - - - - - - -
Xn ; N ; R: 22 - 48/22 -
50/53
Xn; R22-48/22 S: (2)23 - 24/25 - 36 - 60 - Conc>=25%: Xn; R48/22; R22
131538-00-6 2,3-Bis((2-mercaptoethyl)thio)-1-propanethiol N; R50-53 61 >=10%Conc<25%: Xn; R48/22 Eu - - - - - - - -
Xn; R22
R43 Xn ; N ; R: 22 - 43 - 51/53 Conc>=25%: Xn; R22; R43
131657-78-8 2-Chloro-6-(ethylamino)-4-nitrophenol N; R51-53 S: (2)22 - 24 - 37/39 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -

Page 328
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Mixture of trans-4-acetoxy-4-methyl-2-propyl-
tetrahydro-2H-pyran and cis-4-acetoxy-4-methyl-2- Xi ; R: 43
131766-73-9 propyl-tetrahydro-2H-pyran R43 S: (2)24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; N
Famoxadone [3-Anilino-5-methyl-5-(4- Xn; R48/22 R: 48/22-50/53
131807-57-3 phenoxyphenyl)-1,3-oxazolidine-2,4-dione] N; R50-53 S: (2-)46-60-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -

T; R23 T ; N ; R: 23 - 50/53, Conc>=25%: T; R23

131860-33-8 Azoxystrobin N; R50-53 S: (1/2) - 22 - 45 - 60 - 61 >=3%Conc<25%: Xn; R20 Eu - - - - - - - -
N
Spinosyn A(Note: see also Spinosad (ISO) & CAS R: 50/53
131929-60-7 No. 131929-63-0) N; R50-53 S: 60-61 Eu - - - - - - - -
N
Spinosyn D(Note: see also Spinosad (ISO) & CAS R: 50/53
131929-63-0 No. 131929-60-7) N; R50-53 S: 60-61 Eu - - - - - - - -
Triticonazole (ISO) [(RS)-(E)-5-(4-Chlorobenzylidene)- N
2,2-dimethyl-1-(1H-1,2,4-triazol-1- R: 51/53
131983-72-7 methyl)cyclopentanol] N; R51-53 S: 61 Eu - - - - - - - -
N
(E)-5[(4-Chlorophenyl)methylene]-2,2- R: 51/53
131984-21-9 dimethylcyclopentanone N; R51-53 S: 61 Eu - - - - - - - -
Asbestos, any mixture of these, or where the Any mixture of
composition is unknown(Note: see also CAS No T ; R: 45 - 48/23 , Conc>=10%: T; R45; R48/23 these, or where the
12172-73-5, 77536-66-4, 77536-67-5, 77536-68-6, Carc. Cat. 1; R45 S: 53 - 45; >=1%Conc<10%: T; R45; R48/20 composition is
132207-32-0 12001-28-4 & 12001-29-5) T; R48/23 Note: E >=0.1%Conc<1%: T; R45 Eu; A unknown (b) 0.1 f/mL - - - 1 - -
Xi; N
R43 R: 43-50/53
132584-17-9 Ethyl 2-(4-phenoxyphenyl)lactate N; R50-53 S: (2-)36/37-57-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
4-[N-Ethyl-N-(2-hydroxyethyl)amino]-1-(2- Xn; R22
hydroxyethyl)amino-2-nitrobenzene, R43 Xn ; R: 22 - 43 - 52/53, Conc>=25%: Xn; R22; R43
132885-85-9 monohydrochloride R52-53 S: (2) - 22 - 24 - 37 - 61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Mixture of isomers of mono-(2-
tetradecyl)naphthalenes,di-(2-
tetradecyl)naphthalenes and tri-(2- Xi; R36 Xi ; R: 36 - 53
132983-41-6 tetradecyl)naphthalenes R53 S: (2)26 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
Sodium 3-acetoacetylamino-4-methoxytolyl-6- Xi ; R: 43
133167-77-8 sulfonate R43 S: (2)24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc >=25%: T, R25
133305-88-1 Eprinomectin (B1a) T; R25 T ; R: 25 >=3%Conc<25%: Xn, R22 V - - - - - - - -
Conc>=10%: T, R48/25
133305-89-2 Eprinomectin (B1b) T; R48/25 T ; R: 48/25 >=1%Conc<10%: Xn, R48/22 V - - - - - - - -
Xi
N,N''-(Methylenedi-4,1-phenylene)bis[N'-(4- R43 R: 43-53
133336-92-2 methylphenyl)urea] R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

(3S,6R,9S,12R,15S,18R,21S,24R)-6,18-Dibenzyl-
3,9,15,21-tetraisobutyl-4,10,12,16,22,24-hexamethyl- Xi
1,7,13,19-tetraoxa-4,10,16,22-tetraazacyclo- Xi; R36 R: 36-53
133413-70-4 tetracosane-2,5,8,11,14,17,20,23-octaone R53 S: (2-)26-61 Conc>=20%: Xi; R36 Eu - - - - - - - -
Xn; N
4-[4-(2-Ethylhexyloxy)phenyl](1,4-thiazinane-1,1- Xn; R22 R: 22-50/53
133467-41-1 dioxide) N; R50-53 S: (2-)22-60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xn
Xn; R22-48/22 R: 22-48/22-52/53 Conc>=25%: Xn; R22; R48/22
133481-10-4 Ethyl 2-(1-cyanocyclohexyl)acetate R 52-53 S: (2-)36/37-61 >=10%Conc<25%: Xn; 48/22 Eu - - - - - - - -
C; R34 C ; N ; R: 34 - 43 - 48/22 -
Xn; R48/22 50/53 , Conc>=10%: C; R34; R48/22; R43
2-(4-(3-(4-Chlorophenyl)-2-pyrazolin-1- R43 S: (1/2) - 24 - 26 - 28 - >=5%Conc<10%: Xi; R36/38; R43
133514-97-3 yl)phenylsulfonyl)ethyldimethylammonium formate N; R50-53 37/39 - 45 - 60 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
C; N
(+)-(1S,2S,3S,5R)-2,6,6- C; R34 R: 34-43-50/53 Conc>=10%: C; R34; R43
Trimethylbicyclo[3.1.1]heptane-3-spiro-1'-(cyclohex-2'- R43 S: (1/2-)26-36/37/39-45-57- >=5%Conc<10%: Xi; R36/38; R43
133636-82-5 en-4'-one) N; R50-53 60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Page 329
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Epoxiconazole Carc. Cat. 3; R40

Repr. Cat. 3; R62 Xn; N
[(2RS,3SR)-3-(2-Chlorophenyl)-2-(4-fluorophenyl)- Repr. Cat. 3; R63 R: 40-62-63-51/53 Conc>=5%; Xn; R40; R62; R63
133855-98-8 [(1H-1,2,4-triazol-1-yl)methyl]oxirane] N; R51-53 S: (2-)36/37-46-61 >=1%Conc<5%: Xn; R40 Eu - - - - - - - -
2-Butyl-4-chloro-4,5-dihydro-5-hydroxymethyl-1-[2'-(2-
triphenylmethyl-1,2,3,4-2H-tetrazol-5-yl)-1,1'-biphenyl- R: 53
133909-99-6 4-methyl]-1H-imidazole R53 S: 61 Eu - - - - - - - -
6-tert-Butyl-3-(3-dodecylsulfonyl)propyl-7H-1,2,4- R: 53
133949-92-5 triazolo[3.4b][1,3,4]thiadiazine R53 S: 61 Eu - - - - - - - -
T; R23 Conc>=25%: T; R23; R22; R36; R43
Fenpyroximate [Benzoic acid, 4-(((((1,3-dimethyl-5- Xn; R22 >=20%Conc<25%: Xn; R20; R36; R43
phenoxy-1H-pyrazol-4- Xi; R36 >=3%Conc<20%: Xn; R20; R43
134098-61-6 l)methylene)amino)oxy)methy,1,1-dimethylethyl ester] Xi; R43 T ; R: 23 - 22 - 36 - 43 >=1%Conc<3%: Xi; R43 V - - - - - - - -
T; R48/25
Xn; R22 T; N Conc>=25%: T; R48/25; R22; R41; R43
Xi; R41 R: 22-41-43-48/25-51/53 >=10%Conc<25%: T; R48/25;R41; R43
R43 S: (1/2-)22-26-36/37/39-45- >=5%Conc<10%: Xn; R48/22; R36; R43
134164-24-2 Dibenzylphenylsulfonium hexafluoroantimonate N; R51-53 61 >=1%Conc<5%: Xn; R48/22; R43 Eu - - - - - - - -

Conc>=25%: Xn; R22; R48/22; R41; R43

Xn; R22-48/22 Xn >=10%Conc<25%: Xn; R48/22; R41; R43
tert-Butyl (1R,5S)-3-azabicyclo[3.1.0]hex-6- Xi; R41 R: 22-41-43-48/22 >=5%Conc<10%: Xi; R36; R43
134575-17-0 ylcarbamate R43 S: (2-)22-26-36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Sodium (1.0-1.95)/lithium (0.05-1) 5-((5-((5-chloro-6-
fluoro-pyrimidin-4-yl)amino)-2-sulfonatophenyl)azo)-
1,2-dihydro-6-hydroxy-1,4-dimethyl-2-oxo-3- Xi ; R: 43
134595-59-8 pyridinemethylsulfonate R43 S: (2)22 - 24/25 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22-48/22 Conc>=25%: Xn; R22; R48/22; R41; R43
Xi; R41 Xn; N >=10%Conc<25%: Xn; R48/22; R41; R43
R43 R: 22-41-43-48/22-50/53 >=5%Conc<10%: Xi; R36; R43
134620-00-1 Tetraammine palladium (II) hydrogen carbonate N; R50-53 S: (2-)22-26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
3-Phenyl-7-[4-(tetrahydrofurfuryloxy)phenyl]-1,5-dioxa- R: 53
134724-55-3 s-indacen-2,6-dione R53 S: 61 Eu - - - - - - - -
Xi
R: 43
134841-35-3 Potassium N-(1-methoxy-1-oxobut-2-en-3-yl)valinate R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn; N
R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
135043-64-0 4-Amino-2-(aminomethyl)phenol dihydrochloride N; R50-53 S: (2-)22-24-37-60-61 >=1%Conc<25%: Xi R43 Eu - - - - - - - -
Xi ; N ; R: 36/37/38 - 43 -
Xi; R36/37/38 50/53
Acibenzolar-S-methyl [Benzo[1,2,3]thiadiazole-7- R43 S: (2)24/25 - 37 - 46 - 59 - Conc>=20%: Xi; R36/37/38; R43
135158-54-2 carbothioic acid S-methyl ester] N; R50-53 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn
Acetamiprid (ISO) [(E)-N1-[(6-Chloro-3- Xn; R22 R: 22-52/53
135410-20-7 pyridyl)methyl]-N2-cyano-N1-methylacetamidine] R52-53 S: (2-)46-61 Conc>=25%: Xn; R22 Eu/V - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R41
Xi; R41 R: 22-41-52/53 >=10%Conc<25%: Xi; R41
135756-61-5 1,3-Bis(dimethylcarbamoyl)-imidazolium chloride R52-53 S: (2-)22-26-37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

2-[4-[(4-Hydroxyphenyl)sulfonyl]phenoxy]-4,4-
dimethyl-N-[5-[(methylsulfonyl)amino]-2-[4-(1,1,3,3- R: 53
135937-20-1 tetramethylbutyl)phenoxy]phenyl]-3-oxopentanamide R 53 S: 61 Eu - - - - - - - -
Xn; R22 C; N Conc>=25%: C; R34; R22; R43
C; R34 R: 22-34-43-50/53 >=10%Conc<25%: C; R34; R43
R43 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: Xi; R36/38; R43
136122-15-1 2,5-Dimercaptomethyl-1,4-dithiane N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi
Tetraethyl N,N'-(methylenedicyclohexane-4,1-diyl)bis- R43 R: 43-52/53
136210-30-5 Dl-aspartate R52-53 S: (2-)36/37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Bis(4-(1,2-bis(ethoxycarbonyl)ethylamino)-3- R43 Xi ; R: 43 - 52/53
136210-32-7 methylcyclohexyl)methane R52-53 S: (2)36/37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 330
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Trisodium 5-amino-3-[5-(2-bromoacryloyl-amino)-2-
sulfonatophenylazo]-4-hydroxy-6-(4- R: 52/53,
136213-71-3 vinylsulfonylphenylazo)naphthalene-2,7-disulfonate R52-53 S: 61 Eu - - - - - - - -
2-((4-(Ethyl-(2-hydroxyethyl)amino)-2- Xn; R48/22 Xn ; N ; R: 43 - 48/22 -
methylphenyl)azo)-6-methoxy-3-methyl- R43 50/53 Conc>=10%: Xn; R48/22; R43
136213-73-5 benzothiazolium methylsulfate N; R50-53 S: (2)22 - 36/37 - 60 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
2-(4-(N-Ethyl-N-(2-hydroxyl)ethyl)amino-2- N
methylphenyl)azo-6-methoxy-3-methylbenzo- R: 50/53
136213-74-6 thiazolium chloride N; R50-53 S: 60 - 61 Eu - - - - - - - -

Sodium 4-(4-chloro-6-(N-ethylanilino)-1,3,5-triazin-2- Xi; N

ylamino)-2-(1-(2-chlorophenyl)-5-hydroxy-3-methyl- R43 R: 43-51/53
136213-75-7 1H-pyrazol-4-ylazo)benzenesulfonate N; R51-53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture (9:1) of sodium 3,3'-(1,4-
phenylenebis(carbonylimino-3,1-propanediyl-
imino))bis(10-amino-6,13-dichloro)-4,11-
triphenodioxazinedisulfonate) and lithium 3,3'-(1,4-
phenylenebis(carbonylimino-3,1-propanediyl-
imino))bis(10-amino-6,13-dichloro)-4,11- N ; R: 51/53,
136213-76-8 triphenodioxazinedisulfonate N; R51-53 S: 61 Eu - - - - - - - -
Trisodium 3-amino-6,13-dichloro-10-((3-((4-chloro-6-
(2-sulfophenylamino)-1,3,5-triazin-2-
yl)amino)propyl)amino)-4,11- Xi ; R: 43 ,
136248-03-8 triphenoxydioxazinedisulfonate Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Mixture of: strontium (4-chloro-2-((4,5-dihydro-3-
methyl-5-oxo-1-(3-sulfonatophenyl)-1H-pyrazol-4-
yl)azo)-5-methyl)benzenesulfonate and disodium (4-
chloro-2-((4,5-dihydro-3-methyl-5-oxo-1-(3- N
sulfonatophenyl)-1H-pyrazol-4-yl)azo)-5- R: 51/53
136248-04-9 methyl)benzenesulfonate N; R51-53 S: 22-61 Eu - - - - - - - -

Conc>=25%: T; R23/25; R48/25; R21; R38

T; R23/25-48/25 T ; N ; R: 21 - 23/25 - 38 - >=20%Conc<25%: T; R48/25; R20/22; R38
Xn; R21 48/25 - 50/53 >=10%Conc<20%: T; R48/25; R20/22
3-(2,4-Dichlorophenyl)-6-fluoro-2-(1H-1,2,4-triazol-1- Xi; R38 S: (1/2) - 36/37/39 - 38 - 45 - >=3%Conc<10%: Xn; R20/22; R48/22
136426-54-5 yl)quinazolin-4-(3H)-one N; R50-53 60 - 61 >=1%Conc<3%: Xn; R48/22 Eu - - - - - - - -
N-(3-Acetyl-2-hydroxyphenyl)-4-(4-
136450-06-1 phenylbutoxy)benzamide R53 R: 53 S: 61 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R41
(3S,4aS,8aS)-N–trans-Butyldecahydro-3- Xi; R41 R: 22-41-52/53 >=10%Conc<25%: Xi; R41
136465-81-1 isoquinolinecarboxamide R52-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi Conc>=10%: Xi; R41; R43
Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
136465-99-1 1-((2-Quinolinyl-carbonyl)oxy)-2,5-pyrrolidinedione R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
(3S,4aS,8aS)-2-[(2R,3S)-3-Amino-2-hydroxy-4- Xn
phenylbutyl]-N-tert-butyldecahydroisoquinoline-3- Xn; R22 R: 22-52/53
136522-17-3 carboxamide R52-53 S: (2-)22-61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Dodecanamide, N,N'-(9,9',10,10'-tetrahydro- R: 53
136897-58-0 9,9',10,10'-tetraoxo(1,1'-bianthracene)-4,4'-diyl)bis- R53 S: 22-61 Eu - - - - - - - -
Xi; R41 Xi; N Conc>=10%: Xi; R41; R43
Behenamidopropyl-dimethyl-(dihydroxypropyl) R43 R: 41-43-50/53 >=5%Conc<10%: Xi; R36; R43
136920-10-0 ammonium chloride N; R50-53 S: (2-)26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi
R: 43
136997-71-2 1-Dimethylcarbamoyl-4-(2-sulfonatoethyl)pyridinium R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; N
Xn; R22 R: 22-50/53
137234-87-8 6-Ethyl-5-fluoro-4(3H)-pyrimidone N; R50-53 S: (2-)60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -

T+ Conc>=7%: T+; R28

[(Dimethylsilylene)bis((1,2,3,3a,7a-eta)-1H-inden-1- R: 28 >=1%Conc<7%: T; R25
137390-08-0 ylidene)dimethyl]hafnium T+; R28 S: (1/2-)6-22-28-36/37-45 >=0.1%Conc<1%: Xn; R22 Eu - - - - - - - -

Page 331
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Conc>=25%: T; R25; R48/25; R20; R41
>=10%Conc<25%: T; R48/25; R22 R41
T; R25-48/25: >=5%Conc<10%: Xn; R22; R48/22; R36
Xn; R20 >=3%Conc<5%: Xn; R22; R48/22
137512-74-4 Emamectin benzoate Xi; R41 T ; R: 20 - 25 - 41 - 48/25 >=1%Conc<3%: Xn; R48/22 V - - - - - - - -

[R-(R*,S*)]-[[2-Methyl-1-(1-oxopropoxy)propoxy]-(4- Xi Conc>=10%: Xi; R41; R43

phenylbutyl)phosphinyl] acetic acid, (-)-cinchonidine Xi; R41 R43 R: 41-43-52/53 >=5%Conc<10%: Xi; R36; R43
137590-32-0 (1:1) salt R 52-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R21/22-48/22 C ; R: 21/22 - 34 - 43 - 48/22 Conc>=25%: C; R34; R21/22; R48/22; R43
C; R34 - 52/53 >=10%Conc<25%: C; R34; R48/22; R43
R43 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%: Xi; R36/38; R43
137605-95-9 2-Butyl-2-ethyl-1,5-diaminopentane R52-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

2,(4,6-Bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl)-5-(3- R: 53
137658-79-8 ((2-ethylhexyl)oxy)-2-hydroxypropoxy)phenol R53 S: 61 Eu - - - - - - - -
C ; R: 34 - 43 Conc>=10%: C; R34; R43
C; R34 S: (1/2) - 7/8 - 26 - 36/37/39 - >=5%Conc<10%: Xi; R36/37/38; R43
137796-06-6 4-Ethyl-2-methyl-2-isopentyl-1,3-oxazolidine R43 45 >=1%Conc<5%: R43 Eu - - - - - - - -
Xn
Benzyl(S)-2-[(2'-cyanobiphenyl-4- Xn; R22 R: 22-43 Conc>=25%: Xn; R22; R43
137864-22-3 ylmethyl)pentanoylamino]-3-methylbutyrate R43 S: (2-)36/37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Repr.Cat.3; R62-63
Xn; R22 Xn; N Conc>=25%: Xn; R62; R63; R22; R38
5-(3-Butyryl-2,4,6-trimethylphenyl)-2-[1- Xi; R38 R: 22-38-62-63-50/53 >=20%Conc<25%: Xn; R62; R63; R38
138164-12-2 (ethoxyimino)propyl]-3-hydroxycyclohex-2-en-1-one N; R50-53 S: (2-)22-36/37-60-61 >=5%Conc<20%: Xn; R62; R63 Eu - - - - - - - -
Xn; N
Imidacloprid (ISO) [1-(6-Chloropyridin-3-ylmethyl)-N- Xn; R22 R: 22-50/53
138261-41-3 nitroimidazolidin-2-ylidenamine] N; R50-53 S: (2-)22-57-60-61 Conc>=25%: Xn; R22 Eu/V - - - - - - - -
138265-88-0 Zinc borate Repr. Cat. 2; R60-61 T ; R: 60 - 61 Conc>=5.5%: T; R60; R61 V - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R41
(Z)-(2,4-Difluorophenyl)piperidin-4-ylmethanone Xi; R41 R: 22-41-52/53 >=10%Conc<25%: Xi; R41
138271-16-6 oxime monohydrochloride R52-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Poly(oxo(2-butoxyethyl-3-oxobutanoato- Xi ; R: 41 , Conc>=10%: Xi; R41
138360-92-6 O'1,O'3)aluminium) Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N
4'-((2-Butyl-4-oxo-1,3-diazaspiro[4.4]non-1-ene-3- R: 50/53
138401-24-8 yl)methyl)(1,1'-biphenyl)-2-carbonitrile N; R50-53 S: 60-61 Eu - - - - - - - -

Hexanedioic acid, polymer with 1,6-hexanediol, alpha-

hydro-omega-hydroxypoly[oxy(methyl-1,2-ethanediyl)] Xn Isocyanates, all
138427-39-1 and 1,1'-methylenebis[4-isocyanatobenzene] Xn; R42 R: 42 Conc>=1%: Xn; R42 N; A (as-NCO) - 0.02 - 0.07 - Sen -
Xn; R22-48/22 Xn ; N ; R: 22 - 41 - 43 - Conc>=25%: Xn; R22; R48/22; R41; R43
Xi; R41 48/22 - 51/53 >=10%Conc<25%: Xn; R48/22; R41; R43
5-Acetyl-3-amino-10,11-dihydro-5H- R43 S: (2) - 22 - 26 - 36/37/39 - >=5%Conc<10%: Xi; R36; R43
138451-65-7 dibenz[b,f]azepine-hydrochloride N; R51-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
R10 Conc>=20%: Xn; R40; R38; R41
Carc. Cat. 3; R40 Xn ; N ; R: 10 - 38 - 40 - 41 - >=10%Conc<20%: Xn; R40; R41
Xi; R38-41 51/53 >=5%Conc<10%: Xn; R40; R36
138526-69-9 1-Bromo-3,4,5-trifluorobenzene N; R51-53 S: (2)23 - 26 - 36/37/39 - 61 >=1%Conc<5%: Xn; R40 Eu - - - - - - - -
N
5-Methyl-2-[(2-nitrophenyl)amino]-3- R: 50/53
138564-59-7 thiophenecarbonitrile N; R50-53 S: 22-60-61 Eu - - - - - - - -
Conc>=25%: Xn; R22; R48/22; R41; R43
Xn; R22-48/22 Xn >=10%Conc<25%:Xn; R48/22; R41; R43
Xi; R41 R: 22-41-43-48/22 >=5%Conc<10%:Xi; R36; R43
138666-92-9 Potassium 2-chloro-3-(benzyloxy)propionate R43 S: (2-)26-36/37/39 >=1%Conc<5%:Xi; R43 Eu - - - - - - - -
Xn Conc>=25%: Xn; R22; R41
Xn; R22 R: 22-41 >=10%Conc<25%: Xi; R41
138937-28-7 5,6-Dihydroxy-2,3-dihydro-1H-indolium bromide Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Profoxydim (ISO) [2-{(EZ)-1-[(2RS)-2-(4- Carc. Cat. 3; R40 Xn
Chlorophenoxy)propoxyimino]butyl}-3-hydroxy-5- Repr. Cat. 3; R63 R: 40-43-63 Conc>=5%: Xn; R40; R63; R43
139001-49-3 (thian-3-yl)cyclohex-2-en-1-one] R43 S: (2-)36/37-46 >=1%Conc<5%: Xn; R40; R43 Eu - - - - - - - -

Page 332
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi
Tetrakis(2,6-dimethylphenyl)-m-phenylene R43 R: 43-53
139189-30-3 biphosphate R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn
1-Methyl-4-(2-methyl-2H-tetrazol-5-yl)-1H-pyrazole-5- Xn; R22 R: 22-52/53
139481-22-4 sulfonamide R52-53 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -
N ; R: 51/53
139504-68-0 1-[(2-tert-Butyl)cyclohexyloxy]-2-butanol N; R51-53 S: 61 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: Xn; R40; R48/22
139528-85-1 Metosulam Xn; R48/22 Xn ; R: 40 - 48/22 >=1%Conc<10%: Xn; R40 V - - - - - - - -
Conc>=25%: C; R34; R22
Amines, N-C10-16-alkyltrimethylenedi-, reaction Xn; R22 C >=10%Conc<25%: C; R34
139734-65-9 products with chloroacetic acid C; R34 R: 22-34 >=5%Conc<10%: Xi; R36/38 N - - - - - - - -
Xn
Xn; R22-48/22 R: 22-48/22-52/53 Conc>=25%: Xn; R22; R48/22
139756-01-7 1-Methyl-4-nitro-3-propyl-1H-pyrazole-5-carboxamide R52-53 S: (2-)22-36/37-61 >=10%Conc<25%: Xn; R48/22 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
140203-12-9 Coke (coal tar), high temperature pitch Carc. Cat. 1; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
S: 53 - 45 ;
140203-13-0 Coke (coal tar), mixed coal high temperature pitch Carc. Cat. 1; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
T ; R: 45 ,
Coke (coal tar) low temperature, high temperature S: 53 - 45 ;
140413-61-2 pitch Carc. Cat. 1; R45 Note: H Conc>=0.1%: T; R45 Eu - - - - - - - -
C; R34 C; N Conc>=25%: C; R34; R22; R43
Xn; R22 R: 22-34-43-50/53 >=10%Conc<25%: C; R34; R43
R43 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: Xi; R36/38; R43
140623-89-8 2,6-Dichloro-1-fluoropyridiniumtetrafluoroborate N; R50-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
Xi; R41 Xn >=10%Conc<25%: Xi; R41; R43
1-Chloromethyl-4-fluoro-1,4- R43 R: 22-41-43-52/53 >=5%Conc<10%: Xi; R36; R43
140681-55-6 diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) R52-53 S: (2-)21-26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

A 2:1 mixture of: 4-(7-hydroxy-2,4,4-trimethyl-2-

chromanyl)resorcinol-4-yl-tris(6-diazo-5,6-dihydro-5-
oxonaphthalen-1-sulfonate) and 4-(7-hydroxy-2,4,4- F; Xn
trimethyl-2-chromanyl)resorcinolbis(6-diazo-5,6- F; R11 R: 11-40
140698-96-0 dihydro-5-oxonaphthalen-1-sulfonate) Carc.Cat.3; R40 S: (2-)7-36/37 Conc>=1%: Xn; R40 Eu - - - - - - - -
Potassium sodium 3,3'-(3(or4)-methyl-1,2-
phenylenebis(imino(6-chloro)-1,3,5-triazine-4,2- Xi
diylimino(2-acetamido-5-methoxy)-4,1- R: 41 Conc>=10%: Xi; R41
140876-13-7 phenylenazo)dinaphthalene-1,5-disulfonate Xi; R41 S: (2-)26-39 >=5%Conc<10% : Xi; R36 Eu - - - - - - - -
1,6-Hexanediyl-bis(2-(2-(1-ethylpentyl)-3- Xi ; R: 43
140921-24-0 oxazolidinyl)ethyl)carbamate R43 S: (2)24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Tetrasodium [7-(2,5-dihydroxy-KO2-7-sulfonato-6-[4-
(2,5,6-trichloro-pyrimidin-4-ylamino)phenylazo]-
(N1,N7-N)-1-naphthylazo)-8-hydroxy-KO8- R43 Xi ; R: 43 - 52/53
141048-13-7 naphthalene-1,3,5-trisulfonato(6-)]cuprate(II) R52-53 S: (2)22 - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Isoxaflutole (ISO) [5-Cyclopropyl-1,2-oxazol-4-yl Repr. Cat. 3; R63 Xn ; N ; R: 50/53 - 63

141112-29-0 alpha,alpha,alpha-trifluoro-2-mesyl-p-tolyl ketone] N; R50-53 S: (2 - )36/37 - 60 - 61 Conc>=5%: Xn; R63 Eu - - - - - - - -
Sodium salt of 4-amino-3,6-bis[[5-[[4-chloro-6-[(2-
methyl-4-sulfophenyl)amino]-1,3,5-triazin-2-yl]amino]- Xi
2-sulfophenyl]azo]-5-hydroxy-2,7- Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
141250-43-3 naphthalenedisulfonic acid R52-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Trifloxystrobin (ISO) [(E,E)-alpha-Methoxyimino-{2-
[[[[1-[3- Xi; N
(trifluoromethyl)phenyl]ethylidene]amino]oxy]methyl]b R43 R: 43-50/53
141517-21-7 enzeneacetic acid methyl ester] N; R50-53 S: (2-)24-37-46-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
N
R: 50/53
141631-22-3 3,6,9-Trithiaundecamethylene-1,11-dimethacrylate N; R50-53 S: 60-61 Eu - - - - - - - -

Page 333
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

R10 Conc>=25%: Xn; R22; R48/22; R38; R41; R43

Xn; R22-48/22 Xn; N >=20%Conc<25%: Xn; R48/22; R38; R41; R43
Xi; R38-41 R: 10-22-38-41-43-48/22- >=10%Conc<20%: Xn; R48/22; R41; R43
(2-Butyl-5-nitrobenzofuran-3-yl)[4-(3- R43 50/53 >=5%Conc<10%: Xi; R36; R43
141645-23-0 dibutylaminopropoxy)phenyl]methanone N; R50-53 S: (2-)23-26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Diethyl{4-[1,5,5-tris(4-diethylaminophenyl)penta-2,4- Xi; N
dienylidene]cyclohexa-2,5-dienylidene}ammonium R 43 N; R50- R: 43-50/53
141714-54-7 butyltriphenylborate 53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R48/22 Xn; N
R43 R: 43-48/22-50/53 Conc>=10%: Xn; R48/22; R43
141772-37-4 2-Chloro-4-fluoro-5-nitrophenyl (isobutyl)carbonate N; R50-53 S: (2-)36/37-60-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
N
2-(1-(3',3'-Dimethyl-1'-cyclohexyl)ethoxy)-2-methyl R: 51/53
141773-73-1 propyl propanoate N; R51-53 S: 61 Eu - - - - - - - -
N
Sulfosulfuron [1-(4,6-Dimethoxypyrimidin-2-yl)-3-(2- R: 50/53
141776-32-1 ethylsulfonylimidazo[1,2-a]pyridin-3-yl)sulfonylurea] N; R50-53 S: 60-61 Eu - - - - - - - -

Mixture of isobutyl hydrogen 2-(alpha-2,4,6-

trimethylnon-2-enyl)succinate and isobutyl hydrogen Xi; R41 Xi ; N ; R: 41 - 51/53 Conc>=10%: Xi; R41
141847-13-4 2-(beta-2,4,6-trimethylnon-2-enyl)succinate N; R51-53 S: (2 - )26 - 39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of sodium / potassium 7-[[[3-[[4-((2-hydroxy-

naphthyl)azo)phenyl]azo]phenyl]sulfonyl]amino]- R43 Xi ; R: 43 - 52/53
141880-36-6 naphthalene-1,3-disulfonate R52-53 S: (2) - 22 - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
2-Hydroxy-3-[(2-hydroxyethyl)-[2-(1- Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
oxotetradecyl)amino]ethyl]amino]-N,N,N-trimethyl-1- Xi; R41 R: 22-41-50/53 >=10%Conc<25%: Xi; R41
141890-30-4 propanammonium chloride N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; R43 Xi ; N ; R: 43 - 51/53,
141915-64-2 3,5-Bis-(tetradecyloxycarbonyl)benzenesulfinic acid N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
R: 36
141942-85-0 Ethyl (3R)-4-cyano-3-hydroxybutanoate Xi; R36 S: (2-)26 Conc>=20%: Xi; R36 Eu - - - - - - - -
Xi
142104-11-8 2-Butenedioic acid (2E)-, di-C12-15-alkyl esters R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Xn; R22-48/22 Xn; N Conc>=25%: Xn; R22; R48/22; R43
Flufenacet (ISO) [N-(4-Fluorophenyl)-N-isopropyl-2-(5- R43 R: 22-43-48/22-50/53 >=10%Conc<25%: Xn; R48/22; R43
142459-58-3 trifluoromethyl-[1,3,4]thiadiazol-2-yloxy)acetamide] N; R50-53 S: (2-)13-24-37-60-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -

Tritosulfuron (ISO) (containing <= 0.02 % AMTT) [1-

[4-Methoxy-6-(trifluoromethyl)-1,3,5-triazin-2-yl]-3-[2- Xi; N
(trifluoromethyl)benzenesulfonyl]urea (containing R43 R: 43-50/53
142469-14-5 &lt;= 0.02 % AMTT)] N; R50-53 S: (2-)24-37-46-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
N
3-(4-Chloro-2-fluoro-5-methylphenyl)-1-methyl-5- R: 50/53
142623-48-1 (trifluoromethyl)-1H-pyrazole N; R50-53 S: 60-61 Eu - - - - - - - -

T; R23 T; N
Xn; R22 R: 22-23-50/53 Conc>=25%: T; R22; R23
142653-61-0 3-(cis-3-Hexenyloxy)propanenitril N; R50-53 S: (1/2-)13-36/37-45-60-61 >=3%Conc<25%: Xn; R20 Eu - - - - - - - -
N-(2-Methoxy-5-octadecanoylaminophenyl)-2-(3-
benzyl-2,5-dioxoimidazolidin-1-yl)-4,4-dimethyl-3- R: 53
142776-95-2 oxopentanoic acidamide R53 S: 22-61 Eu - - - - - - - -

N-(2-(6-Ethyl-7-(4-methylphenoxy)-1H-pyrazolo[1,5- Xi; R: 43,

142859-67-4 b][1,2,4]triazol-2-yl)propyl)-2-octadecyloxybenzamide Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi Conc>=20%: Xi; R38; R41
Xi; R38-41 R: 38-41-52/53 >=10%Conc<20%: Xi; R41
142877-45-0 (2,3-Dimethylbut-2-yl)-trimethoxysilane R52-53 S: (2-)26-37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Carc. Cat. 3; R40 Xn; N
Cinidon ethyl (ISO) [Ethyl (Z)-2-chloro-3-[2-chloro-5- R43 R: 40-43-50/53
142891-20-1 (cyclohex-1-ene-1,2-dicarboximido)phenyl]acrylate] N; R50-53 S: (2-)24-37-46-60-61 Conc>=1%: Xn; R40; R43 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture (50:50) of 2-[2-acetylamino-4-[N,N-bis[2-

ethoxycarbonyloxy)ethyl]amino]phenylazo]-5,6-
dichloro-1,3-benzothiazole and 2-[2-acetylamino-4-
[N,N-bis[2-ethoxycarbonyloxy)ethyl]amino]phenylazo]- R: 53
143145-93-1 6,7-dichloro-1,3-benzotriazole R53 S: 61 Eu - - - - - - - -
2-Butenedioic acid (Z), disodium salt, reaction
143239-08-1 products with disodium phosphonate Xi; R43 Xi ; R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
N R:
51/53
143269-74-3 3-Amino-4-chlorobenzoic acid, hexadecyl ester N; R51-53 S: 61 Eu - - - - - - - -
Conc>=25%: T; R39/25; R48/25; R20/22; R62;
R41; R43
Repr.Cat.3; R62 >=10%Conc<25%: T; R39/25; R62; R48/25;
T; R39-48/25 T; N R41; R43
Xn; R20/22 R: 20/22-39-41-43-48/25-62- >=5%Conc<10%: Xn; R68/22; R62; R48/22;
(R)-5-Bromo-3-(1-methyl-2-pyrrolidinyl methyl)-1H- Xi; R41 50/53 R36; R43
143322-57-0 indole R43 S: (1/2-)53-45-60-61 >=1%Conc<5%: Xn; R68/22; R48/22; R43 Eu - - - - - - - -

Kresoxim-methyl (ISO) [Methyl (E)-2-methoxyimino-[2- Carc. Cat. 3; R40 Xn ; N ; R: 40 - 50/53

143390-89-0 (o-tolyloxymethyl)phenyl]acetate] N; R50-53 S: (2)36/37 - 60 - 61 Conc>=1%: Xn; R40 Eu - - - - - - - -
Xn; R22 Xn; N
R43 R: 22-43-50 Conc>=25%: Xn; R22; R43
143446-73-5 5-Acetoxy-2-(R,S)butyryloxymethyl-1,3-oxathiolane N; R50 S: (2-)24-37-57-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Conc>=20%: Xn; R38; R41; R43
Xi >=10%Conc<20%: Xi; R41; R43
Xi; R38-41 R: 38-41-43 >=5%Conc<10%: Xi; R36; R43
143468-96-6 Ethyl 2-carboxy-3-(2-thienyl)propionate R43 S: (2-)24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Tetrasodium 1,2-bis(4-fluoro-6-[5-(1-amino-2-
sulfonatoanthrachinon-4-ylamino)-2,4,6-trimethyl-3- Xi; R43 Xi ; R: 43 - 52/53,
143683-23-2 sulfonatophenylamino]-1,3,5-triazin-2-ylamino)ethane R52-53 S: (2) - 22 - 24/25 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
6,9-Bis(hexadecyloxymethyl)-4,7-dioxanonane-1,2,9- R: 53
143747-72-2 triol R53 S: 61 Eu - - - - - - - -
Polymer of 1,3-dibromopropane and N,N-diethyl-N',N'- N ; R: 50/53
143747-73-3 dimethyl-1,3-propanediamine N; R50-53 S: 60 - 61 Eu - - - - - - - -
Repr.Cat.2; R60 T; N Conc>=10%: T; R60; R34
C; R34 R: 60-34-50/53 >=5%Conc<10%: T; R60; R36/38
143860-04-2 3-Ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine N; R50-53 S: 53-45-60-61 >=0.5%Conc<5%: T; R60 Eu - - - - - - - -

143925-92-2 Amines, bis(hydrogenated tallow alkyl), oxidised Xi; R43 Xi ; R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
2-Propenoic acid, polymer with 2,2-
bis(hydroxymethyl)-1,3-propanediol, methyloxirane Xi; R36/38 Xi Conc>=20%: Xi; R36/38; R43
144086-02-2 and oxirane R43 R:36/38-43 >=1%Conc<20%: Xi; R43 N - - - - - - - -

Repr. Cat. 3; R62 Conc>=20%: Xn; R62; R48/22; R36/38; R43

Xn; R48/22 Xn >=10%Conc<20%: Xn; R62; R48/22; R43
Xi; R36/38 R: 36/38-43-48/22-62 >=5%Conc<10%: Xn; R62; R43
144177-62-8 (R,S)-2-Amino-3,3-dimethylbutane amide R43 S: (2-)22-26-36/37 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Complex mixture of Chinese gum rosin post reacted R: 53
144413-22-9 with acrylic acid R53 S: 61 Eu - - - - - - - -
N
Methyl 4-iodo-2-(3-(4-methoxy-6-methyl-1,3,5-triazine- R: 50/53
144550-06-1 2-yl)ureidosulfonyl)benzoate N; R50-53 S: 60-61 Eu - - - - - - - -
N
R: 50/53
144550-36-7 Iodosulfuron-methyl-sodium N; R50-53 S: 60-61 Eu - - - - - - - -
Xn; N
Oxasulfuron [Oxetan-3-yl 2-[(4,6-dimethylpyrimidin-2- Xn; R48/22 R: 48/22-50/53
144651-06-9 yl)-carbamoylsulfamoyl]benzoate] N; R50-53 S: (2-)46-60-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -

Page 335
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
alpha[2-[[[(2-
Hydroxyethyl)methylamino]acetyl]amino]propyl]- C; R34 C ; N ; R: 34 - 43 - 51/53 Conc>=10%: C; R34; R43
gamma-(nonylphenoxy)poly[oxo(methyl-1,2- R43 S: (1/2 - )26 - 28 - 36/37/39 - >=5%Conc<10%: Xi; R36/38; R43
144736-29-8 ethanediyl) N; R51-53 45 - 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Conc>=20%: Xi; R38; R41
Poly[oxy(methyl-1,2-ethanediyl)], alpha-(2- Xi >=10%Conc<20%: Xi; R41
144736-30-1 aminomethylethyl)-omega-(nonylphenoxy)-, branched Xi; R38-41 R:38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Flupyrsulfuron-methyl-sodium (ISO) [Methyl 2-[[(4,6- N

dimethoxypyrimidin-2-ylcarbamoyl)sulfamoyl]-6- R: 50/53
144740-54-5 trifluoromethyl]nicotinate, monosodium salt] N; R50-53 S: 60-61 Eu - - - - - - - -
Xi; N
Methyl 2-aminosulfonyl-6-(trifluoromethyl)pyridine-3- R43 R: 43-51/53
144740-59-0 carboxylate N; R51-53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Bis(2,6-dimethoxybenzoyl)-2,4,4- Xi; R43 Xi ; N ; R: 43 - 50/53,
145052-34-2 trimethylpentylphosphinoxide N; R50-53 S: (2) - 24 - 37 - 60 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
2-Methyl-1,5-pentanediamine-1,3- R: 43
145153-52-2 benzenedicarboxylate R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
N
Florasulam (ISO) [2',6',8-Trifluoro-5-methoxy-5- R: 50/53
145701-23-1 triazolo[1,5-c] pyrimidine-2-sulfonanilide] N; R50-53 S: 60-61 Eu - - - - - - - -
Xn
2-Amino-4-dimethylamino-6-trifluoroethoxy-1,3,5- Xn; R22-48/22 R: 22-48/22-52/53 Conc>=25%: Xn; R22; R48/22
145963-84-4 triazine R52-53 S: (2-)22-36-61 >=10%Conc<25%: Xn; 48/22 Eu - - - - - - - -
Sodium 2-(4-(4-fluoro-6-(2-sulfoethylamino)-
[1,3,5]triazin-2-ylamino)-2-ureidophenylazo)-5-(4- Xi ; R: 43
146177-84-6 sulfophenylazo)benzene-1-sulfonate R43 S: (2)22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Alcohols C12-C14 secondary, beta-(2- Xn
146340-15-0 hydroxyethoxy), ethoxylated Xn; R22 R: 22 Conc>=25%: Xn; R22 N - - - - - - - -
N
2-(Hydroxymethyl)-2-[[2-hydroxy-3- R: 50/53
146925-83-9 (isooctadecyloxy)propoxy]methyl]-1,3-propanediol N; R50-53 S: 60-61 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41; R43
>=20%Conc<25%: Xi; R38; R41; R43
Mixture of trans-(2R)-5-acetoxy-1,3-oxathiolane-2- Xn; R22 >=10%Conc<20%: Xi; R41; R43
carboxylic acid and cis-(2R)-5-acetoxy-1,3- Xi; R38-41 Xn ; R: 22 - 38 - 41 - 43 >=5%Conc<10%: Xi; R36; R43
147027-04-1 oxathiolane-2-carboxylic acid R43 S: (2)22 - 24 - 26 - 37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
2S-Isopropyl-5R-methyl-1R-cyclohexyl (2R,5S)-5-(4- N
amino-2-oxo-2H-pyrimidin-1-yl)-[1.3]-oxathiolane-2- R: 51/53
147027-10-9 carboxylate N; R51-53 S: 61 Eu - - - - - - - -
Xn
trans-(4S,6S)-5,6-Dihydro-6-methyl-4H-thieno[2,3- R: 22
147086-81-5 b]thiopyran-4-ol, 7,7-dioxide Xn; R22 S: (2-)36 Conc>=25%: Xn; R22 Eu - - - - - - - -
1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-
dimethyl-, N-(C8-18 and C18-unsatd. acyl) derivs.,
inner salts (INCI name: Babassuamidopropyl Xi
147170-44-3 Betaine) Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
2-(4,6-Diphenyl-1,3,5-triazin-2-yl)-5-((hexyl)oxy)- R: 53
147315-50-2 phenol R53 S: 61 Eu - - - - - - - -
Xn; R48/20/21 Xn ; N ; R: 43 - 48/20/21 -
4-(2-Cyano-3-phenylamino)-acryloyloxy-methyl- R43 51/53 Conc>=10%: Xn; R48/20/21; R43
147374-67-2 cyclohexyl-methyl 2-cyano-3-phenylamino)-acrylate N; R51-53 S: (2)36/37 - 61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
N
Ethyl (2-acetylamino-5-fluoro-4- R: 50/53
147379-38-2 isothiocyanatophenoxy)acetate N; R50-53 S: 60-61 Eu - - - - - - - -

N,N-Di-n-butyl-2-(1,2-dihydro-3-hydroxy-6-isopropyl-2- R: 53
147613-95-4 quinolylidene)-1,3-dioxoindan-5-carboxamide R 53 S: 61 Eu - - - - - - - -
Sodium 3-(2-acetamido-4-(4-(2-
hydroxybutoxy)phenylazo)phenylazo)benzenesulfonat Xi ; R: 43
147703-65-9 e R43 S: (2)22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 336
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi; N
Mixture of: disodium hexyldiphenyl ether disulphonate Xi; R36 R: 36-51/53
147732-60-3 and disodium dihexyldiphenyl ether disulphonate N; R51-53 S: (2-)26-61 Conc>=20%: Xi; R36 Eu - - - - - - - -
N-Acetyl-N-[5-cyano-3-(2-dibutylamino-4-
phenylthyazol-5-yl-methylene)-4-methyl-2,6-dioxo- N ; R: 50/53
147741-93-3 1,2,3,6-tetrahydropyridin-1-yl]benzamide N; R50-53 S: 60 - 61 Eu - - - - - - - -
N
Bis(1,2,2,6,6-pentamethyl-4-piperidinyl) 2-(4- R: 50/53
147783-69-5 methoxybenzylidene)malonate N; R50-53 S: 22-60-61 Eu - - - - - - - -
Xn
Xn; R22 R: 22-52/53
148043-73-6 4,4,5,5,5-Pentafluoropentan-1-ol R52-53 S: (2-)23-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Calcium 2,5-dichloro-4-(4-((5-chloro-4-methyl-2-
sulphonatophenyl)azo)-5-hydroxy-3-methylpyrazol-1- Xn ; R: 20 ,
148240-74-8 yl)benzenesulphonate Xn; R20 S: (2) Conc>=25%: Xn; R20 Eu - - - - - - - -
Trisodium-bis(7-acetamido-2-(4-nitro-2-
oxidophenylazo)-3-sulphonato-1- Xn ; R: 68 ,
148262-86-6 naphtholato)chromate(1-) Muta. Cat. 3; R68 S: (2) - 22 - 36/37 Conc>=1%: Xn; R68 Eu - - - - - - - -
Sodium-(1-(5-(4-(4-anilino-3-sulphophenylazo)-2-
methyl-5-methylsulphonamidophenylazo)-4-hydroxy-2-
oxido-3-(phenylazo)phenylazo)-5-nitro-4-sulfonato-2- Xn; R20 Xn ; R: 20 - 52/53 ,
148262-87-7 naphtholato)iron(II) R52-53 S: (2) - 61 Conc>=25%: Xn; R20 Eu - - - - - - - -
C ; N ; R: 34 - 51/53 ,
C; R34 S: (1/2) - 26 - 28 - 36/37/39 - Conc>=10%: C; R34
148262-93-5 Calcium octadecylxylenesulfonate N; R51-53 45 - 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xn; R21/22 Xn ; R: 21/22 - 52/53 ,
148292-41-5 2-Methyl-1-pentylpyridinium bromide R52-53 S: (2) - 36/37 - 61 Conc>=25%: Xn; R21/22 Eu - - - - - - - -

Diethyl 2,4-dihydroxycyclodisiloxane-2,4- Conc>=25%: C; R34; R22

diylbis(trimethylene)diphosphonate, tetrasodium salt, C; R34 C ; R: 22 - 34 , >=10%Conc<25%: C; R34
148324-78-1 reaction products with disodium metasilicate Xn; R22 S: (1/2) - 26 - 36/37/39 - 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
N
R: 51/53
148348-12-3 2-Hexyldecyl p-hydroxybenzoate N; R51-53 S: 61 Eu - - - - - - - -
C
R: 34-52/53
Isobutylidene-(2-(2-isopropyl-4,4-dimethyloxazolidine- C; R34 S: (1/2-)23-26-36/37/39-45- Conc>=10%: C; R34
148348-13-4 3-yl)-1,1-dimethylethyl)amine R52-53 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Carc. Cat. 2; R45 Conc>=25%: T; R45; R34; R22; R43
Xn; R22 >=10%Conc<25%: T; R45; R34; R43
C; R34 T ; R: 45 - 22 - 34 - 43 - >=5%Conc<10%: T; R45; R36/38; R43
R43 52/53 , >=1%Conc<5%: T; R45; R43
148434-03-1 Hydrazine-bis(3-carboxy-4-hydroxybenzensulfonate) R52-53 S: 53 - 45 - 61 >=0.1%Conc<1%: T; R45 Eu - - - - - - - -

Tetrasodium (c-(3-(1-(3--(e-6-dichloro-5-
cyanopyrimidin-f-yl(methyl)amino)propyl)-1,6-dihydro-
2-hydroxy-4-methyl-6-oxo-3-pyridylazo)4-
sulfonatophenylsulfamoyl)phtalocyanine-a,b,d-
trisulfonato(6))nickelato (II), where a is 1 or 2 or 3 or
4, b is 8 or 9 or 10 or 11, c is 15 or 16 or 17 or 18, d Xi; R36 Xi
is 22 or 23 or 24 or 25 and where e and f together are R43 R: 36 - 43 - 52/53 Conc>=20%: Xi; R36; R43
148732-74-5 2 and 4 or 4 and 2 respectively. R52-53 S: (2) - 22 - 26 - 36/37 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xi; N
R43 N; R: 43-50/53
148757-89-5 1-Bromo-9-(4,4,5,5,5-pentafluoropentylthio)nonane R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture (50/50) of: tetrasodium 7-(4-[4-chloro-6-

[methyl-(3-sulfonatophenyl)amino]-1,3,5-triazin-2-
ylamino]-2-ureidophenylazo)naphthalene-1,3,6-
trisulfonate and tetrasodium 7-(4-[4-chloro-6-[methyl- Xi
(4-sulfonatophenyl)amino]-1,3,5-triazin-2-ylamino]-2- R: 43
148878-18-6 ureidophenylazo)naphthalene-1,3,6-trisulfonate R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 337
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Octasodium 2-(6-(4-chloro-6-(3-(N-methyl-N-(4-chloro-
6-(3,5-disulfonato-2-naphthylazo)-1-hydroxy-6-
naphthylamino)-1,3,5-triazin-2-
yl)aminomethyl)phenylamino)-1,3,5-triazin-2-ylamino)- Xi; R41 Xi ; R: 41 - 43 - 52/53 Conc>=10%: Xi; R41; R43
3,5-disulfonato-1-hydroxy-2-naphthylazo)naphthalene- R43 S: (2)22 - 24 - 26 - 37/39 - >=5%Conc<10%: Xi; R36; R43
148878-21-1 1,5-disulfonate R52-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Tetrasodium 4-[4-chloro-6-(4-methyl-2-
sulfophenylamino)-1,3,5-triazin-2-ylamino]-6-(4,5- Xi Conc>=10%: Xi; R41; R43
dimethyl-2-sulfophenylazo)-5-hydroxynaphthalene-2,7 Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
148878-22-2 disulfonate R43 S: (2-)22-24-26-37/39 >=1%Conc< 5%: Xi; R43 Eu - - - - - - - -
2,2'-(1,3-Phenylene)bis[5-chloro-1H-isoindole]- R: 53
148935-94-8 1,3(2H)-dione R53 S: 61 Eu - - - - - - - -
Xn; R48/22
Xi; R41 Xn; N Conc>=10%: Xn; R48/22; R41; R43
Bis(N-(7-hydroxy-8-methyl-5-phenylphenazin-3- R43 N; R: 41-43-48/22-50/53 >=5%Conc<10%: Xi; R36; R43
149057-64-7 ylidene)dimethylammonium) sulfate R50-53 S: (2-)22-26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
(Ethyl-3-oxobutanoato-O'1,O'3)(2-
dimethylaminoethanolato)(1-methoxypropan-2- R10 Xi ; R: 10 - 41 , Conc>=10%: Xi; R41
149057-70-5 olato)aluminium(III), dimerised Xi; R41 S: (2) - 26 - 39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Tetrasodium 5'-(4,6-dichloro-5-cyanopyrimidin-2-
ylamino)-4'-hydroxy-2,3'-azodinaphthalene-1,2',5,7'- Xn; R42 Xn ; N ; R: 42 - 51/53 ,
149057-72-7 disulfonate N; R51-53 S: (2) - 22 - 61 Conc>=1%: Xn; R42 Eu - - - - - - - -

Tetrasodium 2-(6-chloro-4-(4-(2,5-dimethyl-4-(2,5-
disulphonatophenylazo)phenylazo)-3-ureidoanilino)- Xi ; R: 43 ,
149057-74-9 1,3,5-triazin-2-ylamino)benzene-1,4-disulphonate Xi; R43 S: (2) - 22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
N-Cyclohexyl-S,S-dioxobenzo[b]tiophene-2- Xi; R41 R: 22-41-50/53 >=10%Conc<25%; Xi; R41
149118-66-1 carboxamide N; R50-53 S: (2-)22-26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn
(S)-N-tert-Butyl-1,2,3,4-tetrahydro-3- Xn; R22 R: 22-52/53
149182-72-9 isoquinolinecarboxamide R 52-53 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Disodium 1-amino-4-(2-(5-chloro-6-fluoro-pyrimidin-4- Xn
ylamino-methyl)-4-methyl-6-sulfo-phenylamino)-9,10- Xn; R22 R: 22-43 Conc>=25%: Xn; R22; R43
149530-93-8 dioxo-9,10-dihydro-anthracene-2-sulfonate R43 S: (2-)22-24-37 >=1%Conc<25%: Xi R43 Eu - - - - - - - -
Trilithium bis(4-((4-(diethylamino)-2- Xn
hydroxyphenyl)azo)-3-hydroxy-1- Xn; R22 R: 22-52/53
149564-65-8 naphthalenesulfonato(3-))chromate(3-) R 52-53 S: (2-)22-61 Conc>=25%: Xn; R22 Eu - - - - - - - -

Lithium sodium (4-((5-chloro-2-hydroxyphenyl)azo)-

2,4-dihydro-5-methyl-3H-pyrazol-3-onato(2-))(3-((4,5-
dihydro-3-methyl-1-(4-methylphenyl)-5-oxo-1H- Xn; R22 Xn Conc>=25%: Xn; R22; R41
pyrazol-4-yl)azo)-4-hydroxy-5- Xi; R41 R 52- R: 22-41-52/53 >=10%Conc<25%: Xi; R41
149564-66-9 nitrobenzenesulfonato(3-)) chromate(2-) 53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xn; Repr. Cat. 3; R62 Xn
N,N'-Dihexadecyl-N,N'-bis(2- Xi; R36 R: 62-36-53 Conc>=20%: Xn; R62; R36
149591-38-8 hydroxyethyl)propanediamide R53 S: (2-)26-36/37-61 >=5%Conc<20%: Xn; R62 Eu - - - - - - - -

Lithium sodium (2-(((5-((2,5-dichlorophenyl)azo)-2-

hydroxyphenyl)methylene)amino)benzoato(2-))(2- N
((4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4- R: 51/53
149626-00-6 yl)azo)-5-sulfobenzoato(3-)) chromate(2-) N; R51-53 S: 24/25-61 Eu - - - - - - - -
1,3-Bis{6-fluoro-4-[1,5-disulfo-4-(3-aminocarbonyl-1-
ethyl-6-hydroxy-4-methyl-pyrid-2-on-5-ylazo)-phenyl-2 Xi
ylamino]-1,3,5-triazin-2-ylamino}propane lithium-, R: 43
149850-29-3 sodium salt R43 S : (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Methyl N-[3-acetylamino)-4-(2-cyano-4-
nitrophenylazo)phenyl]-N-[(1- Xi ; R: 43
149850-30-6 methoxy)acetyl]glycinate R43 S: (2)22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 338
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Sodium 1,2-bis[4-[4-{4-(4-sulfophenylazo)-2- Xi
sulfophenylazo}-2-ureido-phenyl-amino]-6-fluoro- R: 43
149850-31-7 1,3,5-triazin-2-ylamino]-propane, sodium salt R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25%: C; R35; R22; R43
Xn; R22 C >10%Conc<25%: C; R35; R43
C; R35 R: 22-35-43 >=5%Conc<10%: C; R34; R43
149861-22-3 Phenol, 2-amino-5-ethyl-, hydrochloride R43 S: 24/25-26-37-39 >=1%Conc<5%: Xi; R36/38; R43 N - - - - - - - -
149877-41-8 Bifenazate Xn; R20 Xn ; R: 20 Conc>25%: Xn; R20 V - - - - - - - -
Xi
1-Propanaminium, N-(carboxymethyl)-N,N-dimethyl-3- Xi; R38 R: 38-43 Conc>=20%: Xi; R38; R43
149879-98-1 [[(13Z)-1-oxo-13-docosen-1-yl]amino]-, inner salt R43 S: 24-27-28-36-37 >=1%Conc<20%: Xi; R43 N - - - - - - - -
Carc. Cat. 3; R40
Repr. Cat. 3; R63 Xn; N Conc>=25%: Xn; R40; R63; R20
Dimoxystrobin (ISO) [(E)-2-(Methoxyimino)-N-methyl- Xn; R20 R: 20-40-63-50/53 >=5%Conc<25%: Xn; R40; R63
149961-52-4 2-[alpha-(2,5-xylyloxy)-o-tolyl]acetamide] N; R50-53 S: (2-)36/37-46-60-61 >=1%Conc<5%: Xn; R40 Eu - - - - - - - -
Tepraloxydim (ISO) [(RS)-(EZ)-2-{1-[(2E)-3- Xn
Chloroallyloxyimino]propyl}-3-hydroxy-5- Carc. Cat. 3; R40 R: 40-62-63 Conc>=5%: Xn; R40; R62; R63
149979-41-9 perhydropyran-4-ylcyclohex-2-en-1-one] Repr. Cat. 3; R62-63 S: (2-)36/37-46 >=1%Conc<5%: Xn; R40 Eu - - - - - - - -
Sodium [29H,31H-phthalocyaninato-(2)-
N29,N30,N31,N32]-((3-(N-methyl-N-(2- C ; R: 34
hydroxyethyl)amino)propyl)amino)sulfonyl-sulfonato, S: (1/2) - 22 - 26 - 36/37/39 - Conc>=10%: C; R34
150522-10-4 copper complex C; R34 45 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
N-(3-(2-(4,4-Dimethyl-2,5-dioxo-imidazolin-1-yl)-4,4-
dimethyl-3-oxo-pentanoylamino)-4-methoxy-phenyl)-
150919-56-5 octadecanamide R53 R: 53 S: 61 Eu - - - - - - - -
Xn
Mixture of branched icosane and branched docosane Xn; R20 R: 20-53
151006-58-5 and branched tetracosane R53 S: (2-)61 Conc>=25%: Xn; R20 Eu - - - - - - - -
Mixture of: branched triacontane and branched
dotriacontane and branched tetratriacontane and
151006-59-6 branched hexatriacontane R 53 R: 53 S: 61 Eu - - - - - - - -
Xn
R: 20-53
151006-61-0 Mixture of isomers of branched tetracosane Xn; R20 R53 S: (2-)61 Conc>=25%: Xn; R20 Eu - - - - - - - -
R: 53
151006-62-1 Branched hexatriacontane R53 S: 61 Eu - - - - - - - -

C; R34 C; N Conc>=25%: C; R34; R20/22; R48/22

Xn; R20/22-48/22 R: 20/22-34-48/22-51/53 >=10%Conc<25%: C; R34; R48/22
151213-39-7 (4aS–cis-)-6-Benzyl-octahydropyrrolo[3.4-b]pyridine N; R51-53 S: (1/2-)26-36/37/39-45-61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Xn
2-Butyl-1,3-diazaspiro[4.4]non-1-en-4-one Xn; R22 R: 22-36 Conc>=25%: Xn; R22; R36
151257-01-1 hydrochloride Xi; R36 S: (2-)22-26 >=20%Conc<25%: Xi; R36 Eu - - - - - - - -
N
3-Cyano-N-(1,1-dimethylethyl)androsta-3,5-diene-17- R: 50/53
151338-11-3 beta-carboxamide N; R50-53 S: 60-61 Eu - - - - - - - -
Hexasodium (di[N-(3-(4-[5-(5-amino-3-methyl-1-
phenylpyrazol-4-yl-azo)-2,4-disulfo-anilino]-6-chloro- Xi Conc>=10%: Xi; R41; R43
1,3,5-triazin-2-ylamino)phenyl)-sulfamoyl](di-sulfo)- Xi; R41 R: 41-43 >=5%Conc<10%: Xi R36; R43
151436-99-6 phthalocyaninato)nickel R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Hydroxy aluminium bis(2,4,8,10-tetra-trans-butyl-6- N
hydroxy-12H-dibenzo[d, g][1.3.2]dioxaphosphocin-6- R: 51/53
151841-65-5 oxide) N; R51-53 S: 61 Eu - - - - - - - -
Xi
3-Benzyl-exo-6-nitro-2,4-dioxo-3-aza-cis- R43 R: 43-52/53
151860-15-0 bicyclo[3.1.0]hexane R52-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn
4,4'-Bis(N-carbamoyl-4- R: 40
151882-81-4 methylbenzenesulfonamide)diphenylmethane Carc. Cat. 3; R40 S: (2-)22-36/37 Conc>=1%: Xn; R40 Eu - - - - - - - -
R: 53
151900-44-6 1,6-Bis((dibenzylthiocarbamoyl)disulfanyl)hexane R53 S: 61 Eu - - - - - - - -

Page 339
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xn; R22
Xi; R36 Xn Conc>=25%: Xn; R22; R36; R43
R43 R: 22-36-43-52/53 >=20%Conc<25%: Xi; R36; R43
152460-07-6 Methyl-5-nitrophenyl-guanidine R52-53 S: (2-)22-24-26-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn; R22-48/22 Xn; N Conc>=25%: Xn; R22; R48/22; R43
1-(3-Cyclopentyloxy-4-methoxyphenyl)-4-oxo- R43 R: 22-43-48/22-51/53 >=10%Conc<25%: Xn; R48/22; R43
152630-47-2 cyclohexanecarbonitrile N; R51-53 S: (2-)36/37-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
T; R48/25 T Conc>=25%: T; R48/25; R22
N-[3-(1,1-Dimethylethyl)-1H-pyrazol-5-yl]-N'-hydroxy- Xn; R22 R: 22-48/25-52/53 >=10%Conc<25%: T; R48/25
152828-23-4 4-nitrobenzenecarboximidamide R52-53 S: (1/2-)22-36-45-61 >=1%Conc<10%: Xn; R48/22 Eu - - - - - - - -
Xi; N
2-(4-Aminophenyl)-6-tert-butyl-1H-pyrazolo[1,5- R43 R: 43-51/53
152828-25-6 b][1,2,4]triazole N; R51-53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
N
R: 50/53
153233-91-1 Etoxazol N; R50-53 S: 60-61 Eu - - - - - - - -

Potassium bis(N-carboxymethyl)-N-methyl-glycinato- Xn ; R: 22
153352-59-1 (2)N,O,O,N)-ferrate-(1-) monohydrate Xn; R22 S: (2)37 Conc>=25%: Xn; R22 Eu - - - - - - - -
R: 52/53
153441-77-1 Methyl N-(phenoxycarbonyl)-L-valinate R 52-53 S: 61 Eu - - - - - - - -
Xn; N
Thiamethoxam (ISO) [3-(2-Chloro-thiazol-5-ylmethyl)- Xn; R22 R: 22-50/53
153719-23-4 5-methyl[1,3,5]oxadiazinan-4-ylidene-N-nitroamine] N; R50-53 S: (2-)60-61 Conc>=25%: Xn; R22 Eu/V - - - - - - - -
Xn; R22 Xn
N-Nitro-N-(3-methyl-3,6-dihydro-2H-1,3,5-oxadiazin-4- R43 R: 22-43-52/53 Conc>=25%: Xn; R22; R43
153719-38-1 yl)amine R52-53 S: (2-)22-24-37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
N
Spiro[1,3-dioxolane-2,5'-(4',4',8',8'-tetramethyl- R: 51/53
154171-77-4 hexahydro-3',9'-methanonaphthalene)] N; R51-53 S: 24-61 Eu - - - - - - - -

Lithium sodium 3-amino-10-{4-(10-amino-6,13-

dichloro-4,11-disulfonatobenzo[5,6][1,4]oxazino[2,3-
b]phenoxazine-3-ylamino)-6-[methyl(2-sulfonato-
ethyl)amino]-1,3,5-triazin-2-ylamino}-6,13- Xn
dichlorobenzo[5,6][1,4]oxazino[2,3-b]phenoxazine- R: 20/21/22-68/20/21/22 Conc>=25%: Xn; R20/21/22 - 68/20/21/22
154212-58-5 4,11-disulfonate Xn; R20/21/22-68/20/21/22 S: (2-)36/37 >=10%Conc<25%: Xn; R68/20/21/22 Eu - - - - - - - -
Conc>=25%: Xn; R21/22; R38; R41
Xn; R21/22 Xn; N >=20%Conc<25%: Xi; R38; R41
Xi; R38-41 N; R: 21/22-38-41-51/53 >=10%Conc<20%: Xi; R41
154212-60-9 2-Isopropyl-4-(N-methyl)aminomethylthiazole R51-53 S: (2-)26-36/37/39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi
154248-98-3 Glycols, 1,2-, C12-16, ethoxylated propoxylated Xi; R36/38 R: 36/38 Conc>=20%: Xi; R36/38 N - - - - - - - -
Xn; R22 Xn; N Conc>=25%: Xn; R22; R41
1-(2,4-Dichlorophenyl)-2-(1H-imidazol-1-yl)ethanone Xi; R41 R: 22-41-51/53 >=10%Conc<25%: Xi; R41
154486-26-7 methanesulfonate N; R51-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Fluoroxypyr-butometyl (ISO) [2-Butoxy-1-
methylethyl,O-(4-amino-3,5-dichloro-6-fluoro-2-
pyridyloxy) acetate](Note: see also CAS No: 81406- N ; R: 50/53
154486-27-8 37-3) N ; R50-53 S: 60 - 61 Eu - - - - - - - -
2-[4-(4-Methoxyphenyl)-6-phenyl-1,3,5-triazin-2-yl]- R: 52/53
154825-62-4 phenol R52-53 S: 61 Eu - - - - - - - -

Bis(2,4-dicumylphenyl) neopentyl diphosphite [3,9-

Bis[2,4-bis(1-methyl-1-phenylethyl)phenoxy]-2,4,8,10- R: 53
154862-43-8 tetraoxa-3,9-diphosphaspiro[5.5]undecane] R53 S: 61 Eu - - - - - - - -
Sodium 3,5-bis(tetradecyloxy- Xi; R43 Xi ; N ; R: 43 - 51/53 ,
155160-86-4 carbonyl)benzenesulfinate N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

1,2-Bis[4-fluoro-6-{4-sulfo-5-(2-(4-sulfonaphtalene-3-
ylazo)-1-hydroxy-3,6-disulfo-8-aminonaphthalene-7- Xi
ylazo)phenylamino}-1,3,5-triazin-2ylamino]ethane;x- R: 43
155522-09-1 sodium, y-potassium salts x = 7,755 y = 0,245 R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Page 340
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi
Methyl 2-[4-(2-chloro-4-nitrophenylazo)-3-(1- R43 R: 43-53
155522-12-6 oxopropyl)amino]phenylaminopropionate R 53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; R41 Xi; N Conc>=10%: Xi; R41; R43
1-(2-Hydroxyethyl)-1H-pyrazol-4,5- R43 R: 41-43-51/53 >=5%Conc<10%: Xi; R36; R43
155601-30-2 diyldiammoniumsulfate N; R51-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; N
Zoxamide (ISO) [(RS)-3,5-Dichloro-N-(3-chloro-1- R43 R: 43-50/53
156052-68-5 ethyl-1-methyl-2-oxopropyl)-p-toluamide] N; R50-53 S: (2-)24-37-46-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Conc>=25%: Xn; R21/22; R48/22; R38; R41;

R43
Xn; R21/22-48/22 Xn; N >=20%Conc<25%: Xn; R48/22; R38; R41; R43
Xi; R38-41 R: 21/22-38-41-43-48/22- >=10%Conc<20%: Xn; R48/22; R41; R43
R43 51/53 >=5%Conc<10%: Xi; R36; R43
156126-48-6 Tetrabutylammonium 2-amino-6-iodopurinate N; R51-53 S: (2-)26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of: 2-methylsulfanyl-4,6-bis-(2-hydroxy-4- Xi

methoxy-phenyl)-1,3,5-triazine and 2-(4,6-bis- R: 43
156137-33-6 methylsulfanyl-1,3,5-triazin-2-yl)-5-methoxy-phenol R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

2-Isopropyl-5-methylcyclohexyloxycarbonyloxy-2- Xi; R36 Xi ; N ; R: 36 - 51/53,

156324-82-2 hydroxypropane N; R51-53 S: (2) - 26 - 61 Conc>=20%: Xi; R36 Eu - - - - - - - -
Xi; N Conc>=10%: Xi; R41; R43
N-Dodecyl-[3-(4-dimethylamino)benzamido)- Xi; R41 R43 R: 41-43-50/53 >=5%Conc<10%: Xi; R36; R43
156679-41-3 propyl]dimethylammonium tosylate N; R50-53 S: (2-)24-26-37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
5-Amino-[2S-di(methylphenyl)amino]-1,6-diphenyl-4Z-
hexen-3-one [(2S,4Z)-5-Amino-2-(dibenzylamino)-1,6- R: 53
156732-13-7 diphenylhex-4-en-3-one] R53 S: 61 Eu - - - - - - - -
Xi R:
Sodium 4-[4-(4-hydroxyphenylazo)phenylamino]-3- R43 43-52/53
156738-27-1 nitrobenzenesulfonate R52-53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Sodium and potassium 4-(3-aminopropylamino)-2,6- Xi

bis[3-(4-methoxy-2-sulfophenylazo)-4-hydroxy-2-sulfo- R: 43
156769-97-0 7-naphthylamino]-1,3,5-triazine R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; N
2-(4-(4-(Butyl-(1-methylhexyl)amino)phenyl)-3-cyano- R43 R: 43-50/53
157362-53-3 5-oxo-1,5-dihydropyrrol-2-ylidene)propandinitrile N; R50-53 S: (2-)24-37-60-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi; R38
2-Methyl 4-[(1,1-dimethylethyl)-6-(1-methyl- R43 Xi ; N ; R: 38 - 43 - 50/53, Conc>=20%: Xi; R38; R43
157661-93-3 pentadecyl)-phenol N; R50-53 S: (2) - 24 - 37 - 60 - 61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Poly(oxy-1,2-ethanediyl), alpha-(carboxymethyl)- Xi Conc>=10%: Xi; R41

157707-83-0 omega-hydroxy-, C10-C16-alkyl ethers Xi; R41 R: 41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

5-{4-[5-Amino-2-[4-(2-sulfoxyethylsulfonyl)phenylazo]-
4-sulfo-phenylamino]-6-chloro-1,3,5-triazin-2-ylamino}- Xi
4-hydroxy-3-(1-sulfo-naphthalen-2-ylazo)- Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
157707-94-3 naphthalene-2,7-disulfonicacid sodium salt R 52-53 S: (2-)22-26-39-61 >=5% Conc<10%: Xi; R36 Eu - - - - - - - -

Ethanaminium, 2-hydroxy-N,N-bis(2-hydroxyethyl)-N- Xi Conc>=20%: Xi; R38; R41

methyl-, esters with C16-18 and C18-unsatd. fatty R: 38-41 >=10%Conc<20%: Xi; R41
157905-74-3 acids, Me sulfates (salts) Xi; R38-41 S: 25-26-28-37-39 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Repr. Cat. 3; R63 Conc>=25%: Xn; R63; R22
158062-67-0 Flonicamid Xn; R22 Xn ; R: 22 - 63 >=5%Conc<25%: Xn; R63 V - - - - - - - -
Xi; R38 Xi; N
Mixed linear and branched C14-15 alcohols R43 R: 38-43-50/53 Conc>=20%: Xi; R38; R43
158570-99-1 ethoxylated, reaction product with epichlorohydrin N; R50-53 S: (2-)24-37-60-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
R: 53
158574-65-3 1-Benzyl-5-(hexadecyloxy)-2,4-imidazolidinedione R53 S: 61 Eu - - - - - - - -
Ethyl 6,8-difluoro-1-(formylmethylamino)-1,4-dihydro-
7-(4-methyl)piperazin-1-yl)-4-oxo-quinoline-3- R: 52/53
158585-86-5 carboxylate R52-53 S: 61 Eu - - - - - - - -

Page 341
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
R10 C
Carc.Cat.3; R40 R: 10-34-40-43 Conc>=10%: C; R34; R40; R43
C; R34 S: (1/2-)7/9-8-23-26- >=5%Conc<10%: Xn; R40; R36/38; R43
158894-67-8 1-Bromo-2-methylpropyl propionate R43 36/37/39-45 >=1%Conc<5%: Xn; R40; R43 Eu - - - - - - - -
6-tert-Butyl-7-chloro-3-tridecyl-7,7a-dihydro-1H- R: 53 S:
159038-16-1 pyrazolo[5,1-c]-1,2,4-triazole R 53 61 Eu - - - - - - - -
Xi
R43 R: 43-52/53
159235-16-2 4-(2-Methylacryloyloxy)phenyl 4-allyloxybenzoate R52-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
(2,2'-(3,3'-Dioxidobiphenyl-4,4'-diyldiazo)bis(6-(4-(3-
(diethylamino)propylamino)-6-(3-
(diethylammonio)propylamino)-1,3,5-triazin-2-
ylamino)-3-sulfonato-1-naphtholato))dicopper(II) R43 Xi ; N ; R: 43 - 51/53
159604-94-1 acetate lactate N; R51-53 S: (2)22 - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Repr. Cat. 3; R62
Xn; R22 C; N Conc>=25%: C; R62; R34; R22; R43
C; R34 R: 22-34-43-62-51/53 >=10%Conc<25%: C; R62; R34; R43
4-[(3-Chlorophenyl)(1H-imidazol-1-yl)methyl]-1,2- R43 S: (1/2-)22-26-36/37/39-45- >=5%Conc<10%: Xn; R62; R36/38; R43
159939-85-2 benzenediamine dihydrochloride N; R51-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn; N
R43 R: 22-43-51/53 Conc>=25%: Xn; R22; R43
160194-26-3 1-(3-Iodo-4-aminobenzyl)-1H-1,2,4-triazole N; R51-53 S: (2-)24-37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Mixture of ethyl 2-((4-(5,6-dichlorobenzothiazol-2-
ylazo)phenyl)ethylamino)benzoate and ethyl 2-((4-
(6,7-dichlorobenzothiazol-2- R: 53
160987-57-5 ylazo)phenyl)ethylamino)benzoate R53 S: 61 Eu - - - - - - - -
N
Fenamidone (ISO) [(S)-5-Methyl-2-methylthio-5- R: 50/53
161326-34-7 phenyl-3-phenylamino-3,5-dihydroimidazol-4-one] N; R50-53 S: 60-61 Eu - - - - - - - -
Xn; N
1-Cyclopropyl-3-(2-methylthio-4- Xn; R48/22 R: 48/22-50/53
161462-35-7 trifluoromethylphenyl)-1,3-propanedione N; R50-53 S: (2-)36-60-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Xi
2,4,6-Tri-tert-butylphenyl 2-butyl-2-ethyl-1,3- R43 R: 43-53
161717-32-4 propanediolphosphite R53 S: (2-)24-37/39-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

4-[4-Amino-5-hydroxy-3-(4-(2-
sulfoxyethylsulfonyl)phenylazo)-2,7-disulfonapht-6-
ylazo]-6-[3-(4-amino-5-hydroxy-3-(4-(2-
sulfoxyethylsulfonyl)phenylazo)-2,7-disulfonapht-6- Xi Conc>=10%: Xi; R41; R43
ylazo]phenylcarbonylamino]benzenesulfonic acid, R: 41-43 >=5%Conc<10%: Xi; R36; R43
161935-19-9 sodium salt Xi; R41 R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Conc>=25%: T+; R26; R34; R22; R42/43

T+; R26 >=10%Conc<25%: T+; R26; R34; R42/43
Xn; R22 T+ ; R: 22 - 26 - 34 - 42/43 - >=7%Conc<10%: T+; R26; R36/38; R42/43
C; R34 52/53 >=5%Conc<7%: T; R23; R36/38; R42/43
R42/43 S: (1/2) - 23 - 26 - 28 - >=1%Conc<5%: T; R23; R42/43
161973-12-2 2,5-Bis-isocyanatomethyl-bicyclo[2.2.1]heptane R52-53 36/37/39 - 45 - 61 >=0.1%Conc<1%: Xn; R20 Eu - - - - - - - -
Xn; R21/22-48/22 Xn; N Conc>=25%: Xn; R21/22; R48/22; R43
Diethyl thiophosphoryl (Z)-(2-aminothiazol-4- R43 R: 21/22-43-48/22-50/53 >=10%Conc<25%: Xn; R48/22; R43
162208-27-7 yl)methoxyimino acetate N; R50-53 S: (2-)36/37-60-61 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
Xi
[(4S,5S)-4-Benzyl-2-oxo-5-oxazolidinyl]methyl 4- R: 43
162221-28-5 nitrobenzenesulfonate R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
E; R2
Xn; R22-48/22 Conc>=25%: Xn; R22; R48/22; R41; R43
Xi; R41 E; Xn; N >=10%Conc<25%: Xn; R48/22; R41; R43
1-Hydroxy-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane R43 R: 2-22-41-43-48/22-50/53 >=5%Conc<10%: Xi; R36; R43
162241-33-0 bis(tetrafluoroborate) N; R50-53 S: (2-)22-26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
C; R34 C; N Conc>=25%: C; R34; R21/22; R43
Xn; R21/22 R: 21/22-34-43-51/53 >=10%Conc<25%: C; R34; R43
R43 S: (1/2-)22-26-36/37/39-45- >=5%Conc<10%: Xi; R36/38; R43
162515-68-6 1-(Mercaptomethyl)cyclopropylacetic acid N; R51-53 61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Page 342
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi
R43 R:43-53
162881-26-7 Phosphine oxide, phenyl bis(2,4,6-trimethylbenzoyl)- R53 S:(2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
6,13-Dichloro-3,10-bis{2-[4-fluoro-6-(2-
sulfophenylamino)-1,3,5-triazin-2-
ylamino]propylamino}benzo[5,6][1,4]oxazino[2,3- Xi
.b.]phenoxazine-4,11-disulphonic acid, lithium-, R: 41 Conc>=10%: Xi; R41
163062-28-0 sodium salt. Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
T; R23 T; N Conc>=25%: T; R23; R48/22; R41
Xn; R48/22 R: 23-41-48/22-50/53 >=10%Conc<25%:Xn; R20; R48/22; R41
3-(Benzo[b]thien-2-yl)-5,6-dihydro-1,4,2-oxathiazine-4-Xi; R41 S: (1/2-)26-36/39-45-57-60- >=5%Conc<10%:Xn; R20; R36
163269-30-5 oxide N; R50-53 61 >=3%Conc<5%:Xn; R20 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R43
163515-14-8 Dimethenamid-P R43 Xn; R: 22-43 >=1%Conc<25%: Xi; R43 V - - - - - - - -
Xn; R22 Xn; N
R43 R: 22-43-50/53 Conc>=25%: Xn; R22; R43
163520-33-0 Ethyl 5,5-diphenyl-2-isoxazoline-3-carboxylate N; R50-53 S: (2-)22-36/37-60-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
2,((4,6-Bis(4-(2-(1-methylpyridinium-4- N
yl)vinyl)phenylamino)-1,3,5-triazin-2-yl)(2- R: 50/53
163661-77-6 hydroxyethyl)amino)ethanol dichloride N; R50-53 S: 60-61 Eu - - - - - - - -

1-(2-(Ethyl(4-(4-(4-(4-(ethyl(2-pyridinoethyl)amino)-2- Xi; N
methylphenylazo)benzoylamino)-phenylazo)-3- Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
163831-67-2 methylphenyl)amino)ethyl-pyridinium dichloride N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of: 5-[(4-[(7-amino-1-hydroxy-3-sulfo-2-
naphthyl)azo]-2,5-diethoxyphenyl)azo]-2-[(3-
phosphonophenyl)azo]benzoic acid and 5-[(4-[(7- E; R2
amino-1-hydroxy-3-sulfo-2-naphthyl)azo]-2,5- Repr.Cat.3; R62 E; Xn; N Conc>=10%: Xn; R62; R48/22; R43
diethoxyphenyl)azo]-3-[(3- Xn; R48/22 R: 2-43-48/22-62-51/53 >=5%Conc<10%: Xn; R62; R43
163879-69-4 phosphonophenyl)azo]benzoic acid R43 N; R51-53 S: (2-)26-35-36/37-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Trisodium [4'-(8-acetylamino-3,6-disulfonato-2-
naphthylazo)-4''-(6-benzoylamino-3-sulfonato-2- T
naphthylazo)-biphenyl-1,3',3'',1'''-tetraolato- R: 45
164058-22-4 O,O',O'',O''']copper(II) Carc. Cat. 2; R45 S: 53-45 Conc>=0.1%: T; R45 Eu - - - - - - - -
Xi; N
3-((C12-18)-Acylamino)-N-(2-((2-hydroxyethyl)amino)- Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
164288-56-6 2-oxoethyl)-N,N-dimethyl-1-propanaminium chloride N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

2,9-Bis(3-(diethylamino)propylsulfamoyl)quino(2,3- Xi; R43 Xi ; R: 43 - 53 ,

164578-11-4 b)acridine-7,14-dione R53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22-48/22 Xn ; R: 22 - 41 - 48/22 - Conc>=25%: Xn; R22-48/22; R41
Xi; R41 52/53 , >=10%Conc<25%: Xn; 48/22; R41
164578-13-6 5-tert-Butyl-3-isoxazolylamine hydrochloride R52-53 S: (2) - 26 - 36/39 - 61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

2-(4-(Diethylaminopropylcarbamoyl)phenylazo)-3-oxo- Xi; R43 Xi ; N ; R: 43 - 51/53 ,

164578-14-7 N-(2,3-dihydro-2-oxobenzimidazol-5-yl)butyramide N; R51-53 S: (2) - 24 - 37 - 61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of 1,5-bis[(2-ethylhexyl)amino]-9,10-
anthracenedione and 1-[(2-ethylhexyl)amino]-5-[3-[(2-
ethylhexyl)oxy]propyl]amino-9,10-anthracenedione
and 1,5-bis[3-[(2-ethylhexyl)oxy]propyl]amino-9,10-
anthracenedione and 1-[(2-ethylhexyl)amino]-5-[(3-
methoxypropyl)amino]-9,10-anthracenedione and 1-[3-
[(2-ethylhexyl)oxy]propyl]amino-5-[(3- N
methoxypropyl)amino]-9,10-anthracenedione and 1,5- R: 50/53
165038-51-7 bis[(3-methyloxypropyl)amino]-9,10-anthracenedione N; R50-53 S: 60-61 Eu - - - - - - - -

Carc. Cat. 3; R40

Xn; R22-48/22 C; N Conc>=25%: C; R34; R40; R22-R48/22; R43
UVCB condensation product of: tetrakis- C; R34 R: 22-34-40-43-48/22-50/53 >=10%Conc<25%: C; R34; R40; R48/22; R43
hydroxymethylphosphonium chloride, urea and R43 S: (1/2-)26-36/37/39-45-60- >=5%Conc<10%: Xn; R40; R36/38; R43
166242-53-1 distilled hydrogenated C16-18 tallow alkylamine N; R50-53 61 >=1%Conc<5%: Xn; R40; R43 Eu - - - - - - - -

Page 343
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi
Mixture of cis-2-isobutyl-5-methyl 1,3-dioxane and Xi; R38 R: 38-52/53
166301-21-9 trans-2-isobutyl-5-methyl 1,3-dioxane R52-53 S: (2-)23-37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -

(3'-Carboxymethyl-5-(2-(3-ethyl-3H-benzothiazol-2- Xi Conc>=10%: Xi; R41; R43

ylidene)-1-methyl-ethylidene)-4,4'-dioxo-2'-thioxo- R: 41-43 >=5%Conc<10%: Xi; R36; R43
166596-68-5 (2,5')bithiazolidinyliden-3-yl)-acetic acid Xi; R41 R: 43 S: (2)26-36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

C Conc>=10%: C; R35; R43

C; R35 R: 35-43 >=5%Conc<10%: C; R34; R43
167678-46-8 [3-(Chlorocarbonyl)-2-methylphenyl]acetate R43 S: (1/2-)7/8-26-36/37/39-45 >=1%Conc<5%: Xi; R36/38; R43 Eu - - - - - - - -
3-[3-(2-Dodecyloxy-5-methylphenylcarbamoyl)-4- R: 53
167684-63-1 hydroxy-1-naphthylthio]propionic acid R53 S: 57-61 Eu - - - - - - - -

(S)-1-[2-tert-Butoxycarbonyl-3-(2-
methoxyethoxy)propyl]-1-cyclopentanecarboxylic R: 52/53
167944-94-7 acid, cyclohexylamine salt R52-53 S: 61 Eu - - - - - - - -
5-[[4-Chloro-6-[[2-[[4-fluoro-6-[[5-hydroxy-6-[(4-
methoxy-2-sulfophenyl)azo]-7-sulfo-2-
naphthalenyl]amino]-1,3,5-triazin-2-yl]amino]-1-
methylethyl]amino]-1,3,5-triazin-2-yl]amino]-3-[[4- Xi
(ethenylsulfonyl)phenyl]azo]-4-hydroxy-naphtalene- R: 41 Conc>=10%: Xi; R41
168113-78-8 2,7-disulfonic acid, sodium salt Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi
Sodium 4-sulfophenyl-6-((1- R: 43
168151-92-6 oxononyl)amino)hexanoate R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
N,N-Dibutyl-(2,5-dihydro-5-thioxo-1H-tetrazol-1- Xi; R36 R: 36-43 Conc>=20%: Xi; R36; R43
168612-06-4 yl)acetamide R43 S: (2-)24-26-37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Hexadecyl 4-chloro-3-[2-(5,5-dimethyl-2,4-dioxo-1,3-
oxazolidin-3-yl)-4,4-dimethyl-3- R: 53
168689-49-4 oxopentamido]benzoate R53 S: 61 Eu - - - - - - - -
3-(2,4-Dichlorophenyl)-6-fluoroquinazoline-2,4(1H,3H) N ; R: 50/53
168900-02-5 dione N; R50-53 S: 60 - 61 Eu - - - - - - - -
[N-(1,1-Dimethylethyl)-1,1-dimethyl-1-[(1,2,3,4,5-eta)- F; R11 F; C
2,3,4,5-tetramethyl-2,4-cyclopentadien-1- C; R34 R: 11-34-43-53 Conc>=10%: C; R34; R43
yl]silanaminato(2-)-kappaN][(1,2,3,4-eta)-1,3- R43 S: (1/2-)6-9-16-26-36/37/39- >=5%Conc<10%: Xi; R36/38; R43
169104-71-6 pentadiene]-titanium R53 45-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
R: 52/53
169314-88-9 Aluminium-magnesium-zinc-carbonate-hydroxide R52-53 S: 61 Eu - - - - - - - -
Xi
Salt of (1S–cis)-1-amino-2,3-dihydro-1H-inden-2-ol R: 43
169939-84-8 and [R-[R*R*]]-2,3-dihydroxybutanedioic acid R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
2-Phthalimidoethyl N-[4-(2-cyano-4- R43 R: 43-53
170222-39-6 nitrophenylazo)phenyl]-N-methyl-beta-alaninate R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Conc>=25%: T; R61; 48/25; R22
Repr. Cat. 2; R61 >=10%Conc<25%: T; R61; R48/25
T; R48/25 >=1%Conc<10%: T; R61; R48/22
170569-88-7 Mavacoxib Xn; R22 T ; R: 61 - 22 - 48/25 >=0.5%Conc<1%: T; R61 V - - - - - - - -
Xi
4-Oxo-4-(p-tolyl)butyric acid adduct with 4- R: 41 Conc>=10%: Xi; R41
171054-89-0 ethylmorpholine Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Mixture of: esters of C14-C15 branched alcohols with

3,5-di-t-butyl-4-hydroxyphenyl propionic acid; C15
branched and linear alkyl 3,5-bis(1,1-dimethylethyl)-4-
hydroxybenzenepropanoate; C13 branched and linear
alkyl 3,5-bis(1,1-dimethylethyl)-4- R: 53
171090-93-0 hydroxybenzenepropanoate R 53 S: 61 Eu - - - - - - - -
Xn;
171228-49-2 Posaconazole Repr. Cat. 3; R63 R: 63 Conc>=5%: Xn; R63 V - - - - - - - -

Page 344
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Pentasodium 7-(4-(4-(5-amino-4-sulfonato-2-(4-((2-
(sulfonato-ethoxy)sulfonyl)phenylazo)phenylamino)-6-
chloro-1,3,5-triazin-2-yl)amino-2- R: 52/53 S: 22-
171599-84-1 ureidophenylazo)naphtalene-1,3,6-trisulfonate R52-53 61 Eu - - - - - - - -

N,N'-Bis{6-chloro-4-[6-(4-vinylsulfonylphenylazo)-2,7-
disulfonicacid-5-hydroxynapht-4-ylamino]-1,3,5-triazin- Xi Conc>=10%: Xi; R41; R43
2-yl}-N-(2-hydroxyethyl)ethane-1,2-diamine, sodium Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
171599-85-2 salt R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
N
R: 51/53
171850-30-9 5,7-Dichloro-4-hydroxyquinoline-3-carboxylic acid N; R51-53 S: 61 Eu - - - - - - - -

Mixture of 2,2'-[[cis-1,2-
cyclohexanediylbis(nitrilomethylidene)]bis[phenolate]]
(2-)N,N',O,O'-copper complex and 2,2'-[[trans-1,2- Xn; N
cyclohexanediylbis(nitrilomethylidyne)]bis[phenolate]] Xn; R48/22 R: 48/22-51/53
171866-24-3 (2-)N,N',O,O'-copper complex N; R51-53 S: (2-)22-36-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
Xi; R41 Xn >=10%Conc<25%: Xi; R41; R43
R43 R: 22-41-43-52/53 >=5%Conc<10%: Xi; R36; R43
171887-03-9 N-(2-Amino-4,6-dichloropyrimidin-5-yl)formamide R52-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
T; R48/25
Xn; R22 T Conc>=25%: T; R48/25; R22; R41; R43
Xi; R41 R: 22-41-43-48/25-52/53 >=10%Conc<25%: T; R48/25;R41; R43
(1S–cis)-4-(2-Amino-6-chloro-9H-purin-9-yl)-2- R43 S: (1/2-)22-26-36/37/39-45- >=5%Conc<10%: Xn; R48/22; R36; R43
172015-79-1 cyclopentene-1-methanol hydrochloride R52-53 61 >=1%Conc<5%: Xn; R48/22; R43 Eu - - - - - - - -
Tetrasodium dihydrogen 1,1''-dihydroxy-8,8''-[p-
phenylbis(imino-{6-[4-(2-aminoethyl)piperazin-1-yl]}- Xi; N
1,3,5-triazine-4,2-diyl-imino)]bis(2,2'-azonaphthalene- Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
172277-97-3 1',3,6-trisulfonate) N; R51-53 S: (2-)26-39-61 >=5%Conc<10% : Xi; R36 Eu - - - - - - - -

Pentasodium 7-(4-(4-(3-(2-
sulfatoethanesulfonyl)phenylamino)-6-(4-(2-
sulfatoethanesulfonyl)phenylamino)-1,3,5-triazin-2- Xi
ylamino)-2-ureidophenylazo)naphthalene-1,3,6- R: 41 Conc>=10%: Xi; R41
172399-10-9 trisulfonate Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
172737-80-3 Trisodium N-(3-propionato)-L-aspartate Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

1-Amino-4-(3-[4-chloro-6-(2,5-di-sulfophenylamino)- Xi
1,3,5-triazin-2-ylamino]-2,2-dimethyl-propylamino)- R: 43
172890-93-6 anthraquinone-2-sulfonic acid, na/li salt R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xi
4-Benzyl-2,6-dihydroxy-4-aza-heptylene bis(2,2- R43 R: 43-53
172964-15-7 dimethyloctanoate) R 53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R43
173584-44-6 Indoxacarb R43 Xn ; R: 22 - 43 >=1%Conc<25%: Xi; R43 V - - - - - - - -
2-(4-(4-(3-Pyridinyl)-1H-imidazol-1-yl)butyl)-1H- R: 52/53
173838-67-0 isoindole-1,3(2H)-dione R52-53 S: 61 Eu - - - - - - - -

Potassium 4-(11- Xi ; R: 43
174393-75-0 methacrylamidoundecanamido)benzenesulfonate R43 S: (2)22 - 24 - 37 Conc>=1%: Xi; R43 Eu - - - - - - - -
2,6-Bis-(2-(4-(4-amino-phenylamino)-phenylazo)-1,3- Xi; N
dimethyl-3H-imidazolium)-4-dimethylamino-1,3,5- Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
174514-06-8 triazine, dichloride N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10% : Xi; R36 Eu - - - - - - - -
Conc>=20%: Xi; R38; R41; R43
Mixture of: tetradecanoic acid (42.5-47.5%) and Xi; R38-41 Xi; N >=10%Conc<20%: Xi; R41; R43
poly(1-7)lactate esters of tetradecanoic acid (52.5- R43 R: 38-41-43-50/53 >=5%Conc<10%: Xi; R36; R43
174591-51-6 57.5%) N; R50-53 S: (2-)24-26-37/39-60-61 >=1%Conc<5%:Xi; R43 Eu - - - - - - - -

Page 345
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Poly-[((4-((4-(ethyl-ethylene)amino)phenyl)-(4-(ethyl-
(2-oxyethylene)amino)phenyl)methinyl)-3- Xi; N Conc>=20%: Xi; R37/38; R41
methylcyclohexa-2,5-dienylidene)-N-ethyl-N-(2- Xi; R37/38-41 R: 37/38-41-50/53 >=10%Conc<20%: Xi; R41
176429-22-4 hydroxyethyl)ammonium acetate] N; R50-53 S: (2-)26-37/39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Poly-[((4-((4-ethyl-ethylene)amino)phenyl)-((4-(ethyl-
(2-oxyethylene)amino)phenyl)methinyl)cyclohexa-2,5- Xi; N Conc>=20%: Xi; R37/38; R41
dienylidene)-N-ethyl-N-(2-hydroxyethyl)ammonium Xi; R37/38-41 R: 37/38-41-50/53 >=10%Conc<20%: Xi; R41
176429-27-9 acetate] N; R50-53 S: (2-)26-37/39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; R36 Xi
(E)-3-(4-(4-Fluorophenyl)-5-methoxymethyl-2,6-bis(1- R43 R: 36-43-53 Conc>=20%: Xi; R36; R43
177964-68-0 methoxymethyl)pyridin-3-yl)prop-2-enal R53 S: (2-)24-26-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
Xn; N
(4-(1-Methylethyl)phenyl)-(4-methylphenyl)iodonium Xn; R21/22-48/22 R: 21/22-48/22-50/53 Conc>=25%: Xn; R21/22; R48/22
178233-72-2 tetrakis(pentafluorophenyl)borate (1-) N; R50-53 S: (2-)22-36/37-60-61 >=10%Conc<25%: Xn; R48/22 Eu - - - - - - - -

3-(2,4-Bis(4-((5-(4,6-bis(2-aminopropylamino)-1,3,5-
triazin-2-ylamino)-4-hydroxy-2,7-disulfonaphthalen-3- Xi
yl)azo)phenylamino)-1,3,5-triazin-6- R: 41 Conc>=10%: Xi; R41
178452-66-9 ylamino)propyldiethylammonium lactate Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
178928-70-6 Prothioconazole Xn; R48/22 Xn ; R: 48/22 Conc>=10%: Xn; R48/22 V - - - - - - - -
Xi; N
Xi; R38 R: 38-51/53
179104-32-6 3-Chloro-2-(isopropylthio)aniline N; R51-53 S: (2-)37-61 Conc>=20%: Xi; R38 Eu - - - - - - - -

Xn; R21/22 C Conc>=25%: C; R34; R21/22

C; R34 R: 21/22-34-52/53 >=10%Conc<25%: C; R34
179474-79-4 1-(3-Methoxypropyl)-4-piperidinamine R52-53 S: (1/2-)26-36/37/39-45-61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Coconut oil, reaction products with glycerol esters of
3,5-bis(1,1-dimethylethyl)-4- R: 53
179986-09-5 hydroxybenzenepropanoic acid R53 S: 61 Eu - - - - - - - -
Conc>=25%: Xn; R22; R48/22; R41; R43
Xn; R22-48/22 Xn >=10%Conc<25%: Xn; R48/22; R41; R43
(R)-3-[(1-Methylpyrrolidin-2-yl)methyl]-5-[2- Xi; R41 R: 22-41-43-48/22 >=5%Conc<10%: Xi; R36; R43
180637-89-2 (phenylsulfonyl)ethenyl]-1H-indole R43 S: (2-)26-36/37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of: pentasodium 5-amino-3-(5-{4-chloro-6-[4-

(2-sulfoxyethoxysulfonato)phenylamino]-1,3,5-triazin-
2-ylamino}-2-sulfonatophenylazo)-6-[5-(2,3-
dibromopropionylamino)-2-sulfonatophenylazo]-4-
hydroxynaphthalene-2,7-disulfonate and
pentasodium 5-amino-6-[5-(2-bromoacryloylamino)-2-
sulfonatophenylazo]-3-(5-{4-chloro-6-[4-(2-
sulfoxyethoxysulfonato)phenylamino]-1,3,5-triazin-2-
ylamino}-2-sulfonatophenylazo)-4-
hydroxynaphthalene-2,7-disulfonate and
tetrasodium 5-amino-3-[5-{4-chloro-6-[4-
(vinylsulfonyl)phenylamino]-1,3,5-triazin-2-ylamino}-2-
sulfonatophenylazo]-6-[5-(2,3- Xi; N
dibromopropionylamino)-2-sulfonatophenylazo]-4- Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
180778-23-8 hydroxynaphthalene-2,7-disulfonate N; R51-53 S: (2-)26-39-61 >=5%Conc<10% : Xi; R36 Eu - - - - - - - -
Disodium (E)-1,2-bis-(4-(4-methylamino-6-(4- Xi
methylcarbamoylphenylamino)-1,3,5-triazin-2- R: 41 Conc>=10%: Xi; R41
180850-95-7 ylamino)phenyl-2-sulfonato)ethene Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Mixture of 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-
octanesulfonic acid and ammonium Xn Conc>=25%: Xn; R22; R48/22; R41
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1- Xn; R22-48/22 R: 22-41-48/22 >=10%Conc<25%: Xn; R48/22; R41
182176-52-9 octanesulfonate Xi; R41 S: (2-)26-36/37/39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N
4,4'-(1,6-Hexamethylenebis(formylimino))bis(2,2,6,6- R: 51/53
182235-14-9 tetramethyl-1-oxylpiperidine) N; R51-53 S: 61 Eu - - - - - - - -

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 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Trisodium 2,4-diamino-3,5-bis-[4-(2- R: 52/53 S:

182926-43-8 sulfonatoethoxy)sulfonyl)phenylazo]benzenesulfonate R52-53 22-61 Eu - - - - - - - -

Tetra-ammonium 2-[6-[7-(2-carboxylato-phenylazo)-8- Xi
hydroxy-3,6-disulfonato-1-naphthylamino]-4-hydroxy- Xi; R36 R: 36-52/53
183130-96-3 1,3,5-triazin-2-ylamino]benzoate R52-53 S: (2-)26-39-61 Conc>=20%: Xi; R36 Eu - - - - - - - -

Potassium 1-methyl-3-morpholinocarbonyl-4-[3-(1-
methyl-3-morpholinocarbonyl-5-oxo-2-pyrazolin-4- Xi
ylidene)-1-propenyl]pyrazole-5-olate(Note: containing R: 43
183196-57-8 < 0.5 % N,N-dimethylformamide (CAS No 68-12-2)]) R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Potassium 1-methyl-3-morpholinocarbonyl-4-[3-(1-
methyl-3-morpholinocarbonyl-5-oxo-2-pyrazolin-4- T
ylidene)-1-propenyl]pyrazole-5-olate(Note: containing Repr. Cat. 2; R61 R: 61-43 Conc>=1%: T; R61; R43
183196-57-8 >= 0.5 % N,N-dimethylformamide (CAS No 68-12-2)]) R43 S: 53-45 >=0.5%Conc<1%: T; R61 Eu - - - - - - - -
Sodium salt of the polymer of sodium 2-methyl-buta-
1,3-diene-1-sulfonate with acrylic acid and 2- R: 52/53
184246-86-4 hydroxyethyl-2-methylacrylate R52-53 S: 61 Eu - - - - - - - -
Mixture of triisopropanolamine salt of 1-amino-4-(3-
propionamidoanilino)anthraquinone-2-sulfonic acid
and triisopropanolamine salt of 1-amino-4-[3,4-
dimethyl-5-(2-
hydroxyethylaminosulfonyl)anilino]anthraquinone-2- R: 52/53
186148-38-9 sulfonic acid R52-53 S: 61 Eu - - - - - - - -
Xi
N-Benzyl-N-ethyl-(4-(5-nitro-benzo[c]isothiazol-3- R43 R: 43-53
186450-73-7 ylazo)phenyl)amine R53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Potassium,sodium 2,4-diamino-3-[4-(2-
sulfonatoethoxysulfonyl)phenylazo]-5-[4-(2- Xi
sulfonatoethoxysulfonyl)-2-sulfonatophenylazo]- R: 41 Conc>=10%: Xi; R41
187026-95-5 benzenesulfonate Xi; R41 S: (2-)22-26-39 >=5%Conc<10% : Xi; R36 Eu - - - - - - - -
Pentaerythritol, dipentaerythritol, fatty acids, C6-10, Xi
mixed esters with adipic acid, heptanoic acid and R: 43
187412-41-5 isostearic acid R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -

Mixture of: 2,4,6-tri(butylcarbamoyl)-1,3,5-triazine and

2,4,6-tri(methylcarbamoyl)-1,3,5-triazine and [(2-butyl- Xi; N
4,6-dimethyl)tricarbamoyl]-1,3,5-triazine and [(2,4- R43 R: 43-51/53
187547-46-2 dibutyl-6-methyl)tricarbamoyl]-1,3,5-triazine N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
187865-22-1 Derquantel Xn ; R48/22 Xn ; R: 48/22 Conc>=10%: Xn; R48/22 V - - - - - - - -

Mixture of methyl {[5-acetylamino-4-(2-chloro-4-

nitrophenylazo)phenyl]methoxycarbonylmethylamino}
acetate and methyl {[5-acetylamino-4-(2-chloro-4- Xi
nitrophenylazo)phenyl]ethoxycarbonylmethylamino}ac R: 43
188070-47-5 etate R43 S: (2-)22-24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
Xn
188116-07-6 Imepitoin Repr. Cat. 3; R62 R: 62 Conc>=5%: Xn; R62 V - - - - - - - -
Xi; R41 Xi Conc>=10%: Xi; R41; R43
4-Amino-3-[[4-[[2-(sulfooxy)ethyl]sulfonyl]phenyl]azo]- R43 R: 41-43-52/53 >=5%Conc<10%: Xi; R36; R43
188907-52-0 1-naphthalene sulfonic acid R52-53 S: (2-)22-24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi; R41 Xi; N Conc>=10%: Xi; R41; R43
4-Hydroxy-7-(2-aminoethyl)-1,3-benzothiazol-2(3H)- R43 R: 41-43-50/53 >=5%Conc<10%: Xi; R36; R43
189012-93-9 one hydrochloride N; R50-53 S: (2-)24-26-37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
189278-12-4 Proquinazid Carc. Cat. 3; R40 Xn ; R: 40 Conc>=1%: Xn; R40 V - - - - - - - -
R: 53
190085-41-7 2-Hydroxybenzoic acid 2-butyloctyl ester R53 S: 61 Eu - - - - - - - -
Bis(2-hydroxyethyl)-(2-hydroxypropyl)ammonium R: 52/53
191617-13-7 acetate R52-53 S: 61 Eu - - - - - - - -

Page 347
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Reaction products of 3,10-bis((2-aminopropyl)amino)-

6,13-dichloro-4,11-triphenodioxazinedisulfonic acid
with 2-amino-1,4-benzenedisulfonic acid, 2-((4- Xi
aminophenyl)sulfonyl)ethyl hydrogen sulfate and R: 41 Conc>=10%: Xi; R41
191877-09-5 2,4,6-trifluoro-1,3,5-triazine, sodium salts Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Tetrahydro-3-methyl-5-((2-phenylthio)thiazol-5- N
ylmethyl)-[4H]-1,3,5-oxadiazinan-4-ylidene-N- R: 51/53
192439-46-6 nitroamine N; R51-53 S: 61 Eu - - - - - - - -
4,4'-Methylenebis[N-(4-chlorophenyl)-3- R: 53
192463-88-0 hydroxynaphthalene-2-carboxamide] R53 S: 61 Eu - - - - - - - -
Xi
(S)-3-Methyl-2-(2-oxotetrahydropyrimidine-1-yl)butyric R: 41 Conc>=10%: Xi; R41
192725-50-1 acid Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
2-(2-Chloroacetoxy)ethyl 3-((4-(2,5-dichloro-4- N
fluorosulfonylphenylazo)-3- R: 51/53
193486-83-8 methylphenyl)ethylamino)propionate N; R51-53 S: 61 Eu - - - - - - - -

Lithium sodium 4,4',4''-(nitrilotris(ethane-2,1-

diylimino(6-chloro-1,3,5-triazine-4,2-diyl)imino))tris(5- Xi Conc>=10%: Xi; R41; R43
hydroxy-6-(1-sulfonaphthalene-2-ylazo)-2,7- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
193562-37-7 naphthalene)disulfonate R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R41; R43
Xi; R41 Xn; N >=10%Conc<25%: Xi; R41; R43
(S)-2,2-Diphenyl-2-(3-pyrrolidinyl)acetonitrile R43 R: 22-41-43-51/53 >=5%Conc<10%: Xi; R36; R43
194602-27-2 hydrobromide N; R51-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Mixture of 1-heptyl-4-ethyl-2,6,7- N
trioxabicyclo[2.2.2]octane and 1-nonyl-4-ethyl-2,6,7- R: 50/53
196965-91-0 trioxabicyclo[2.2.2]octane N; R50-53 S: 60-61 Eu - - - - - - - -
Xi; N
[Phosphinyldynetris(oxy)] tris[3-aminopropyl-2- Xi; R41 R: 41-50/53 Conc>=10%: Xi; R41
197179-61-6 hydroxy-N,N-dimethyl-N-(C6-18)-alkyl] trichlorides N; R50-53 S: (2-)26-39-60-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Propyl((4-(5-oxo-3-propylisoxazolidin-4-
ylidenmethin)phenyl)propoxycarbonylmethyleneamin R: 53
198705-81-6 o)acetate R53 S: 61 Eu - - - - - - - -
199119-58-9 Trifloxysulfuron Xi; R36 Xi ; R: 36 Conc >=20%: Xi; R36 V - - - - - - - -
7-Methoxy-6-(3-morpholin-4-yl-propoxy)-3H-
quinazolin-4-one(Note: containing < 0.5 % formamide R52/53
199327-61-2 (CAS No 75-12-7)) R52-53 S: 61 Eu - - - - - - - -
7-Methoxy-6-(3-morpholin-4-yl-propoxy)-3H- T
quinazolin-4-one(Note: containing >= 0.5 % Repr. Cat. 2; R61 R: 61-52/53
199327-61-2 formamide (CAS No 75-12-7)) R52-53 S: 53-45-61 Conc>=0.5%: T; R61 Eu - - - - - - - -
Xn; N
Barium calcium cesium lead samarium strontium Xn; R22-48/22 R: 22-48/22-51/53 Conc>=25%: Xn; R22; R48/22
199876-46-5 bromide chloride fluoride iodide europium doped N; R51-53 S: (2-)22-36-61 >=10%Conc<25%: Xn; 48/22 Eu - - - - - - - -
Xn
N,N- Xn; R22 R: 22-43 Conc>=25%: Xn; R22; R43
201290-01-9 Bis(trimethylsilyl)aminopropylmethyldiethoxysilane R43 S: (2-)24-37 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Muta. Cat. 3; R68 Xn; N Conc>=25%: Xn; R68; R22; R48/22
Xn; R22-48/22 R: 22-48/22-68-50/53 >=10%Conc<25%: Xn; R68; R48/22
202197-26-0 3-Chloro-4-(3-fluorobenzyloxy)aniline N; R50-53 S: (2-)22-36/37-60-61 >=1%Conc<10%: Xn; R68 Eu - - - - - - - -
C
Mixture of 4-chloro-7-methylbenzotriazole sodium salt R: 34-52/53
and 4-chloro-5-methylbenzotriazole sodium salt and 5-C; R34 S: (1/2-)26-28-36/37/39-45- Conc>=10%: C; R34
202420-04-0 chloro-4-methylbenzotriazole sodium salt R52-53 61 >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
R: 53
202483-62-3 2-(2-Hexyldecyloxy)benzamide R53 S: 61 Eu - - - - - - - -
Repr. Cat. 3; R62-63 Conc>=20%: Xn; R62; R63; R36; R43
Xi; R36 >=5%Conc<20%: Xn; R62; R63; R43
203313-25-1 Spirotetramat R43 Xn ; R: 36-43-62-63 >=1%Conc<5%: Xi; R43 V - - - - - - - -

Page 348
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

alpha-Hydro-omega-[[[(1,1-
dimethylethyl)dioxy]carbonyl]oxy]-poly[oxy(methyl-1,2-
ethanediyl)] ether with 2,2-bis(hydroxymethyl)-1,3-
propanediol (4:1) [Reaction product of alpha-hydro-
omega-((chlorocarbonyl)oxy)-poly(oxy(methyl-1,2-
ethanediyl)) ether with 2,2-bis(hydroxymethyl)-1,3- O; N
propanediol with potassium 1,1- O; R7 R: 7-50/53
203574-04-3 dimethylethylperoxalate] N; R50-53 S: (2-)3/7-14-36/37/39-60-61 Eu - - - - - - - -
Xn
Ethyl (1S,5R,6S)-5-(1-ethylpropoxy)-7- Xn; R48/22 R: 43-48/22 Conc>=10%: Xn; R48/22; R43
204254-96-6 oxabicyclo[4.1.0]hept-3-ene-3-carboxylate R43 S: (2-)22-36/37 >=1%Conc<10%: Xi; R43 Eu - - - - - - - -
6-(2-Chloro-6-cyano-4-nitrophenylazo)-4-methoxy-3-
[N-(methoxycarbonylmethyl)-N-(1- R: 53
204277-61-2 methoxycarbonylethyl)amino]acetanilide R53 S: 61 Eu - - - - - - - -
Sodium, potassium, lithium 5-amino-3,6-bis(5-(4-
chloro-6-(methyl-(2-methylaminoacetyl)amino)-1,3,5- Xi Conc>=10%: Xi; R41; R43
triazin-2-ylamino)-2-sulfonatophenylazo)-4- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
205764-96-1 hydroxynaphthalene-2,7-disulfonate R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Conc>=20%: Xi; R38; R41; R43
Xi; R38-41 Xi; N >=10%Conc<20%: Xi; R41; R43
Fatty acids, C18-unsatd., dimers, reaction products R43 R: 38-41-43-50/53 >=5%Conc<10%: Xi; R36; R43
206565-89-1 with 1-piperazineethanamine and tall oil N; R50-53 S: (2-)23-26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xi
207228-93-1 2H-1,5-Benzodioxepin-3(4H)-one, 7-propyl- Xi; R38 R: 38 Conc>=20%: Xi; R38 N - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R38
208041-98-9 Heptanenitrile, 2-propyl- Xi; R38 R: 22-38 >=20%Conc<25%: Xi; R38 N - - - - - - - -
Hexane, 1,6-diisocyanato-, homopolymer, di-Et
malonate and N-(1-methylethyl)-2-propanamine- Xi
208408-04-2 blocked R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
208535-04-0 N-Amidino-N-methylglycine-2-oxopropionate Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Conc>=25%: Xn; R22; R41; R43
Xn; R22 Xn >=10%Conc<25%: Xi; R41; R43
4-Cyanomethyl-4-methylmorpholin-4-iumhydrogene Xi; R41 R: 22-41-43 >=5%Conc<10%: Xi; R36; R43
208538-34-5 sulfate R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Hexadecyl 3-[2-(5,5-dimethyl-2,4-dioxo-1,3-oxazolidin-
3-yl)-4,4-dimethyl-3-oxovaleramido]-4- R: 53
210706-50-6 isopropoxybenzoate R53 S: 61 Eu - - - - - - - -
Xn; N
Clothianidin (ISO) [3-[(2-Chloro-1,3-thiazol-5- Xn; R22 R: 22-50/53
210880-92-5 yl)methyl]-2-methyl-1-nitroguanidine] N; R50-53 S: (2-)46-60-61 Conc>=25%: Xn; R22 Eu - - - - - - - -
trans-7,7'-Dimethyl-(4H,4H')- R: 53
211387-26-7 (2,2')bi[benzo[1,4]thiazinylidene]-3,3'-dione R53 S: 22-61 Eu - - - - - - - -
Trisodium 3-amino-4-[4-[4-(2-(2-
ethenylsulfonylethoxy)ethylamino)-6-fluoro-1,3,5- Xi
triazine-2-ylamino]-2-sulfophenylazo]-5- R: 41 Conc>=10%: Xi; R41
212652-59-0 hydroxynaphthalene-2,7-disulfonate Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

C; N
1-(2-Amino-5-chlorophenyl)-2,2,2-trifluoro-1,1- Xn; R22 R: 22-34-51/53 Conc>=25%: C; R34; R22
ethanediol, hydrochloride(Note: containing < 0.1 % 4- C; R34 S: (1/2-)26-36/37/39-45-61 >=10%Conc<25%: C; R34
214353-17-0 chloroaniline (CAS No. 106-47-8)) N; R51-53 Note: E >=5%Conc<10%: Xi; R36/38 Eu - - - - - - - -
Carc. Cat. 2; R45 Conc>=25%: T; R45; R34; R22
1-(2-Amino-5-chlorophenyl)-2,2,2-trifluoro-1,1- Xn; R22 T; N >=10%Conc<25%: T; R45; R34
ethanediol, hydrochloride(Note: containing >= 0.1 % C; R34 R: 45-22-34-51/53 >=5%Conc<10%: T; R45; R36/38
214353-17-0 4-chloroaniline (CAS No. 106-47-8)) N; R51-53 S: 53-45-61 >=0.1%Conc<5%: T; R45 Eu - - - - - - - -

Page 349
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of 7-amino-3,8-bis-[4-(2-
sulfoxyethylsulfonyl)phenylazo]-4-
hydroxynaphthalene-2-sulfonic acid, Na/K salt and 7-
amino-3-[4-(2-sulfoxyethylsulfonyl)phenylazo]-4-
hydroxy-8-[4-(2-sulfoxyethylsulfonyl)-2-
sulfophenylazo]naphthalene-2-sulfonic acid, Na/K
salt and 7-amino-8-[4-(2-sulfoxyethylsulfonyl)-
phenylazo]-4-hydroxy-3-[4-(2-sulfoxyethylsulfonyl)-2-
sulfophenylazo]naphthalene-2-sulfonic acid, Na/K
salt and 7-amino-3,8-bis-[4-(2-sulfoxyethylsulfonyl)-2- Xi
sulfophenylazo]-4-hydroxynaphthalene-2-sulfonic R: 41 Conc>=10%: Xi; R41
214362-06-8 acid, Na/K salt Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi; N
N'-(1,3-Dimethylbutylidene)-3-hydroxy-2- R43 R: 43-51/53
214417-91-1 naphthohydrazide N; R51-53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -

Trisodium 3-[2-acetylamino-4-[4-chloro-6-[4-(2- Xi; R41 Xi Conc>=10%: Xi; R41; R43

sulfonatoxyethylsulfonyl)phenylamino]-1,3,5-triazine-2-R43 R: 41-43-52/53 >=5%Conc<10%: Xi; R36; R43
215612-56-9 ylamino]phenylazo]naphthalene-1,5-disulfonate R52-53 S: (2-)24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
2-(2-Oxo-5-(1,1,3,3-tetramethylbutyl)-2,3-dihydro-1-
benzofuran-3-yl)-4-(1,1,3,3-tetramethylbutyl)phenyl R: 53
216698-07-6 acetate R53 S: 61 Eu - - - - - - - -

(3-(4-(2-(Butyl-(4-
methylphenylsulfonyl)amino)phenylthio)-5-oxo-1-
(2,4,6-trichlorophenyl)-4,5-dihydro-1H-pyrazole-3-
ylamino)-4-chlorophenyl)tetradecanamide [N-[3-({4-
[(2-{Butyl[(4-methylphenyl)sulfonyl]amino}phenyl)thio]-
5-oxo-1-(2,4,6-trichlorophenyl)-4,5-dihydro-1H- R: 53
217324-98-6 pyrazol-3-yl}amino)-4-chlorophenyl]tetradecanamide] R53 S: 61 Eu - - - - - - - -
Xn; R22 Xn; N
(R)-4-(4-Dimethylamino-1-(4-fluorophenyl)-1- R43 R: 22-43-51/53 Conc>=25%: Xn; R22; R43
219861-18-4 hydroxybutyl)-3-(hydroxymethyl)benzonitrile N; R51-53 S: (2-)36/37-61 >=1%Conc<25%: Xi; R43 Eu - - - - - - - -
Xn
1,4-Dihydroxy-2,2,6,6-tetramethylpiperidinium 2- R: 22
220410-74-2 hydroxy-1,2,3-propanetricarboxylate Xn; R22 S: (2-) Conc>=25%: Xn; R22 Eu - - - - - - - -
Carc. Cat. 3; R40
Xn; R22 C; N Conc>=25%: C; R40; R34; R22; R43
C; R34 R: 22-34-40-43-51/53 >=10%Conc<25%: C; R40; R34; R43
Reaction products of diisopropanolamine with R43 S: (1/2-)13-25-26-36/37/39- >=5%Conc<10%: Xn; R40; R36/38; R43
220444-73-5 formaldehyde (1:4) N; R51-53 45-61 >=1%Conc<5%: Xn; R40; R43 Eu - - - - - - - -
Xn
Tetrabutyl-phosphonium nonafluoro-butane-1- Xn; R22 R: 22-52/53
220689-12-3 sulfonate R52-53 S: (2-)61 Conc>=25%: Xn; R22 Eu - - - - - - - -
Xi
R: 43
220727-26-4 S-(3-(Triethoxysilyl)propyl)octanethioate R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
220899-03-6 Metrafenone Carc. Cat. 3; R40 Xn ; R: 40 Conc>=1%: Xn; R40 V - - - - - - - -
12-Hydroxyoctadecanoic acid, reaction products with Xn
1,3-benzenedimethanamine and Xn; R20 R: 20-53
220926-97-6 hexamethylenediamine R53 S: (2-)22-61 Conc>=25%: Xn; R20 Eu - - - - - - - -
220991-32-2 Robenacoxib Xn; R22 Xn; R: 22 Conc>=25%: Xn; R22 V - - - - - - - -

2-(5,5-Dimethyl-2,4-dioxooxazolidin-3-yl)-4,4-dimethyl- Xi
3-oxo-N-(2-methoxy-5- R43 R: 43-53
221215-20-9 octadecanoylaminophenyl)pentanoic acid amide R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Triammonium 4-[4-[7-(4-carboxylatoanilino)-1- Repr. Cat. 3; R62 Xn; N
hydroxy-3-sulfonato-2-naphthylazo]-2,5- Xn; R48/22 R: 48/22-62-51/53 Conc>=10%: Xn; R62; R48/22
221354-37-6 dimethoxyphenylazo]benzoate N; R51-53 S: (2-)36/37-61 >=5%Conc<10%: Xn; R62 Eu - - - - - - - -

Page 350
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Ethyl 2-{[3-acetylamino-4-(6-bromo-2-methyl-1,3-
dioxo-2,3-dihydro-1H-isoindol-5- R: 53
221452-67-1 ylazo)phenyl]ethylamino}propionate R53 S: 61 Eu - - - - - - - -
Benzenesulfonic acid, 2-[[1-benzoyl-2,7-dihydro-2,7-
dioxo-6-[(4-sulfophenyl)amino]-3H-naphtho[1,2,3-
de]quinolin-4-yl]oxy]-5-(1,1,3,3-tetramethylbutyl)-, Xi Conc>=10%: Xi; R41
224628-70-0 sodium salt (1:2) Xi; R41 R: 41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
R10
Carc. Cat. 3; R40
C; R34 C ; N ; R: 10 - 20 - 34 - 40 - Conc>=25%: C; R40; R34; R20; R43
Xn; R20 43 - 50/53, >=10%Conc<25%: C; R40; R34; R43
Acetophenone, Formaldehyde, Cyclohexylamine, R43 S: (1/2) - 26 - 36/37/39 - 45 - >=5%Conc<10%: Xn; R40; R36/38; R43
224635-63-6 Methanol and Acetic acid, reaction product of N; R50-53 60 - 61 >=1%Conc<5%: Xn; R40; R43 Eu - - - - - - - -

Tetrakis(bis(2-hydroxyethyl)methylammonium) 3-(4-
(7-acetylamino-1-hydroxy-3-sulfonatonaphthalen-2-
ylazo)-5-methoxy-2-sulfonatophenylazo)-7-(4-amino-3 N
sulfonatophenylamino)-4-hydroxynaphthalene-2- R: 51/53
225786-91-4 sulfonate N; R51-53 S: 61 Eu - - - - - - - -
Xi
R43 R: 43-53
226065-73-2 3,4,3',4'-Tetraphenyl-1,1'-ethandiylbispyrol-2,5-dione R53 S: (2-)22-24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
Reaction product of 3,5-di-tert-butylsalicylic acid and N
zirconium oxychloride, dehydrated, basic Zr: DTBS = R: 50/53
226996-19-6 1.0: 1.0 to 1.0: 1.5 N; R50-53 S: 60-61 Eu - - - - - - - -
Xi
R: 41 Conc>=10%: Xi; R41
227085-51-0 N-Ethyl-3-trimethoxysilyl-2-methyl-propanamine Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
N-(p-Toluenesulfonyl)-N'-(3-(p-
toluenesulfonyloxy)phenyl)urea [3-({[(4- N
Methylphenyl)sulfonyl]carbamoyl}amino)phenyl 4- R: 51/53
232938-43-1 methylbenzenesulfonate] N; R51-53 S: 22-61 Eu - - - - - - - -
Alkenes, C12-14, hydroformylation products, distn. Xi
residues, C-(hydrogen sulfobutanedioates), disodium Xi; R38 R: 38-43 Conc>=20%: Xi; R38; R43
243662-67-1 salts R43 S: (2-)24-37 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -

Tetrasodium 2-(4-fluoro-6-(methyl-(2-
(sulfatoethylsulfonyl)ethyl)amino)-1,3,5-triazin-2- Xi
ylamino)-5-hydroxy-6-(4-methyl-2- R: 41 Conc>=10%: Xi; R41
243858-01-7 sulfonatophenylazo)naphthalene-1,7-disulfonate Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Disodium 2-(5-carbamoyl-1-ethyl-2-hydroxy-4-methyl-
6-oxo-1,6-dihydro-pyridine-3-ylazo)-4-(4-fluoro-6-(4-(2- Xi
sulfonyloxy-ethylsulfonyl)-phenylamino)-1,3,5-triazine- R: 41 Conc>=10%: Xi; R41
243858-60-8 2-ylamino)benzene sulfonate Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Benzenesulfonic acid, 3,3'-
(methylenebis((dihydroxyphenylene)azo))bis-,
potassium sodium salt [Potassium sodium 3-[(E)-(6-
{3,4-dihydroxy-2-[(Z)-(3- Xi
sulfonatophenyl)diazenyl]benzyl}-2,3- Xi; R36 R: 36-52/53
243869-48-9 dihydroxyphenyl)diazenyl]benzenesulfonate] R52-53 S: (2-)26-61 Conc>=20%: Xi; R36 Eu - - - - - - - -
Disodium 8-amino-5-{4-[2- Xi
(sulfonatoethoxy)sulfonyl]phenylazo}naphthalene-2- R: 41 Conc>=10%: Xi; R41
250688-43-8 sulfonate Xi; R41 S: (2-)26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Dimethyl[2S,2S']-6,6,6'6'-tetramethoxy-2,2'-[N,N'- Xi
bis(trifluoracetyl)-S,S'-bi(L-homocysteinyl) R: 43
255387-46-3 diimino]dihexanoate R43 S: (2-)24-37 Conc>=1%: Xi; R43 Eu - - - - - - - -
4,4'-Sulfonylbisphenol, polymer with ammonium
chloride(NH4Cl), pentachlorophosphorane and R: 53
260408-02-4 phenol R53 S: 61 Eu - - - - - - - -
Xi
1-[4-(4-Benzoylphenylsulfanyl)phenyl]-2-methyl-2-(4- Xi; R41 R: 41-53 Conc>=10%: Xi; R41
272460-97-6 methylphenylsulfonyl)propan-1-one R53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 351
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
Xi
285977-85-7 1H-Indene-2-methanol, 2,3-dihydro-2,5-dimethyl- Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
3-Ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2- R: 53
297730-93-9 (trifluoromethyl)-hexane R53 S: 61 Eu - - - - - - - -
Xi
298695-60-0 Oxetane, 3-ethyl-3-[[(2-ethylhexyl)oxy]methyl]- Xi; R38 R: 38 Conc>=20%: Xi; R38 N - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R43
300371-33-9 1H-Indene-ar-propanal, 2,3-dihydro-1,1-dimethyl- R43 R: 22-43 >=1%Conc<25%: Xi; R43 N - - - - - - - -
Conc>=20%: Xi; R38; R41
Xi >=10%Conc<20%: Xi; R41
301341-58-2 Glycine, N-coco acyl derivs., potassium salts Xi; R38-41 R: 38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -

Hexyl 2-(1- R: 53
302776-68-7 (diethylaminohydroxyphenyl)methanoyl)benzoate R53 S: 61 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: Xn; R40; R48/20
308068-56-6 Carbon nanotubes (CNTs) Xn; R48/20 Xn ; R: 40 – 48/20 >=1%Conc<10%: Xn; R40 N - - - - - - - -
Carc. Cat. 3; R40
Xn; R22 Xn Conc>=25%: Xn; R40; R22; R43
318290-98-1 Fluensulfone R43 R: 22 - 40 - 43 >=1%Conc<25%: Xn; R40; R43 V - - - - - - - -
2-{4-[4-[4-Fluoro-6-(2-(2-
vinylsulfonylethoxy)ethylamino)-1,3,5-triazin-2- Xi
ylamino]phenylazo]phenylazo}naphthalene-4,6,8- R: 41 Conc>=10%: Xi; R41
321679-52-1 trisulfonate, trisodium salt Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Pentasodium N-[5-[[4-[[3-[(aminocarbonyl)amino]-4-
[(3,6,8-trisulfonatonaphthalen-2-yl)azo]phenyl]amino]-
6-chloro-1,3,5-triazin-2-yl]amino]-2-sulfonato-4-[[4-[[-2- Xi
(oxysulfonato)ethyl] sulfonyl]phenyl]azo]phenyl]-3- R: 41 Conc>=10%: Xi; R41
321912-47-4 aminopropanoic acid Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
328898-40-4 Tildipirosin R43 Xi R: 43 Conc>=1%: Xi; R43 V - - - - - - - -
Conc>=25%: T; R25; R41
Triphenyl(phenylmethyl)phosphonium T; R25 T; N >=10%Conc<25%: Xn; R22; R41
1,1,2,2,3,3,4,4,4-nonafluoro-N-methyl-1- Xi; R41 R: 25-41-50/53 >=5%Conc<10%: Xn; R22; R36
332350-93-3 butanesulfonamide (1:1) N; R50-53 S: (1/2-)26-39-45-60-61 >=3%Conc<5%: Xn; R22 Eu - - - - - - - -

Trisodium 5-{[4-chloro-6-(1-naphthylamino)-1,3,5- Xi Conc>=10%: Xi; R41; R43

triazin-2-yl]amino}-4-hydroxy-3-[(E)-(4-methoxy-2- Xi; R41 R: 41-43 >=5%Conc<10%: Xi; R36; R43
341026-59-3 sulfonatophenyl)diazenyl]-2,7-naphthalenedisulfonate R43 S: (2-)22-24-26-37/39 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -
Xn; R22 Xn Conc>=25%: Xn; R22; R41
11-Amino-3-chloro-6,11-dihydro-5,5-dioxo-6-methyl- Xi; R41 R: 22-41-52/53 >=10%Conc<25%: Xi; R41
363138-44-7 dibenzo[c,f][1,2]thiazepine hydrochloride R52-53 S: (2-)22-26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Repr.Cat.3; R63 Conc>=20%: Xn; R63; R48/22; R36
Xn; R48/22 >=10%Conc<20%: Xn; R63; R48/22
365400-11-9 Pyrasulfotole Xi; R36 Xn; R: 36-48/22-63 >=5%Conc<10%: Xn; R63 V - - - - - - - -

N-[2-(2-Butyl-4,6-dicyano-1,3-dioxo-2,3-dihydro-1H- R: 53
368450-39-9 isoindol-5-ylazo)-5-diethylamino-phenyl]acetamide R53 S: 61 Eu - - - - - - - -
3,10-Diamino-6,13-dichloro-2-((6-(((4-(1,1-
dimethylethyl)phenyl)sulfonyl)amino)-2-
naphthalenyl)sulfonyl)-4,11- Xi
triphenodioxazinedisulfonic acid, lithium potassium Xi; R41 R: 41-52/53 Conc>=10%: Xi; R41
371921-63-0 sodium salt R52-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
372137-35-4 Saflufenacil Repr. Cat. 3; R63 Xn ; R: 63 Conc>=5%: Xn; R63 V - - - - - - - -
Xi
Methyl (9-acetoxy-3,8,10-triethyl-7,8,10-trimethyl-1,5- R43 R: 43-53
376588-17-9 dioxa-9-aza-spiro[5.5]undec-3-yl)octadecanoate R53 S: (2-)24-37-61 Conc>=1%: Xi; R43 Eu - - - - - - - -
2-Hexyldecanoic acid [4-(6-tert-butyl-7-chloro-1H-
pyrazolo[1,5-b][1,2,4]triazol-2- R: 53
379268-96-9 yl)phenylcarbamoyl]methylester R53 S: 61 Eu - - - - - - - -
Xi; N
Methyl 2-chlorosulfonyl-4- Xi; R41 R: 41-51/53 Conc>=10%: Xi; R41
393509-79-0 (methanesulfonylaminomethyl) benzoate N; R51-53 S: (2-)26-39-61 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -

Page 352
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Conc>=25%: C; R35; R22; R48/21/22; R43

Xn; R22-48/21/22 >=10%Conc<25%: C; R35; R48/21/22; R43
1,3-Benzenedimethanamine, N-(2-phenylethyl) C; R35 C >=5%Conc<10%: C; R34; R43
404362-22-7 derivs. R43 R:22-35-43-48/21/22 >=1%Conc<5%: Xi; R36/38; R43 N - - - - - - - -
Xn; R22
Xi; R36/38 Xn; N Conc>=25%: Xn; R22; R36/38; R43
R43 R: 22-36/38-43-51/53 >=20%Conc<25%: Xi; R36/38; R43
406488-30-0 2-Ethyl-N-methyl-N-(3-methylphenyl)butanamide N; R51-53 S: (2-)24-26-37-61 >=1%Conc<20%: Xi; R43 Eu - - - - - - - -
2-(4-tert-Butylphenyl)-6-cyano-5-
[bis(ethoxycarbonylmethyl)carbamoyloxy]-1H-
pyrrolo[1,2-b][1,2,4] triazole-7-carboxylic acid 2,6-di- R: 53
444065-11-6 tert-butyl-4-methylcyclohexylester R53 S: 61 Eu - - - - - - - -
Carc. Cat. 3; R40 Conc>=10%: Xn; R40; R48/22
447399-55-5 Pyroxasulfone Xn; R48/22 Xn; R: 40-48/22 >=1%Conc<10%: Xn; R40 V - - - - - - - -
N-[5-(Bis-(2-methoxy-ethyl)-amino]-2-(6-bromo-2-
methyl-1,3-dioxo-2,3-dihydro-1H-isoindol-5-ylazo)- R: 53
452962-97-9 phenyl]acetamide R53 S: 61 Eu - - - - - - - -

Mixture of 3-[5-(4-ethenesulfonylbutyrylamino)-2-
sulfophenylazo]-5-{4-chloro-[6-(4-(3-amino-5-hydroxy-
2,7-disulfonaphthalene-4-ylazo)-3-sulfophenylamino]-
1,3,5-triazin-2-ylamino}-4-hydroxynaphthalene-2,7-
disulfonic acid, sodium salt and 3-[5-(4-(2-
chloroethanesulfonyl)butyrylamino)-2-sulfophenylazo]-
5-{4-chloro-[6-(4-(3-amino-5-hydroxy-2,7-
disulfonaphthalene-4-ylazo)-3-sulfophenylamino]- Xi
1,3,5-triazin-2-ylamino}-4-hydroxynaphthalene-2,7- R: 41 Conc>=10%: Xi; R41
457624-86-1 disulfonic acid, sodium salt Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
2-Hydroxy-1-(4-(4-(2-hydroxy-2- Xn; N
methylpropionyl)benzyl)phenyl)-2-methylpropan-1- Xn; R48/22 R: 48/22-50/53
474510-57-1 one N; R50-53 S: (2-)22-36-60-61 Conc>=10%: Xn; R48/22 Eu - - - - - - - -

Cyclopropanecarboxylic acid, 2-[1-(3,3- Xi

477218-42-1 dimethylcyclohexyl)ethoxy]-2-methylpropyl ester R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Conc>=25%: C; R35; R22; R48/22
Nitriles, tallow, hydrogenated, reaction products with >=10%Conc<25%: C; R35; R48/22
acrylonitrile, hydrogenated, reaction products with Xn; R22-48/22 C >=5%Conc<10%: C; R34
490021-69-7 propylene oxide C; R35 R: 22-35-48/22 >=1%Conc<5%: Xi; R36/38 N - - - - - - - -
1-Amino-4-[(4-amino-2-sulfofenyl)amino]-9,10-
dihydro-9,10-dioxo-2-anthracenesulfonic acid,
disodium salt, reaction products with 2-[[3-[(4,6-
dichloro-1,3,5-triazin-2- Xi; R41 Xi Conc>=10%: Xi; R41; R43
yl)ethylamino]phenyl]sulfonyl]ethyl hydrogen sulfate, R43 R: 41-43-52/53 >=5%Conc<10%: Xi; R36; R43
500717-36-2 sodium salts R52-53 S: (2-)22-24-26-36/37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Dibutyl-3-(4-(5-ammonio-2-butyl)benzofuran-3- Xn; R48/22

yl)carbonyl)phenoxy)propyl ammonium oxalate [(5- Xi; R41 Xn; N Conc>=10%: Xn; R41; R48/22; R43
Amino-2-butylbenzofuran-3-yl) [4-(3- R43 R: 41-43-48/22-50/53 >=5%Conc<10%: Xi; R36; R43
500791-70-8 dibutylaminopropoxy)phenyl]methanone, dioxalate] N; R50-53 S: (2-)22-26-36/37/39-60-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Mixture of pentasodium bis[6-anilino-3,5'-

disulfonatonaphthalene-2-azobenzene-1,2'-
diolato]cobaltate(III) and tetrasodium [6-anilino-3,5'-
disulfonatonaphthalene-2-azobenzene-1,2'-diolato][6-
anilino-5'-sulfamoyl-3-sulfonatonaphthalene-2-
azobenzene-1,2'-diolato]cobaltate(III) and trisodium Xi; R41 Xi Conc>=10%: Xi; R41; R43
bis[6-anilino-5'-sulfamoyl-3-sulfonatonaphthalene-2- R43 R: 41-43-52/53 >=5%Conc<10%: Xi; R36; R43
508202-43-5 azobenzene-1,2'-diolato]cobaltate(III) R52-53 S: (2-)22-24-26-37/39-61 >=1%Conc<5%: Xi; R43 Eu - - - - - - - -

Page 353
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes

Mixture of 4-amino-3-(4-ethenesulfonyl-2-
sulfonatophenylazo)-5-hydroxy-6-(5-{4-chloro-6-[4-(2-
sulfonatooxyethanesulfonyl)phenylamino]-1,3,5-
triazin-2-ylamino}-2-sulfonatophenylazo)naphthalene-
2,7-disulfonate potassium/sodium and 4-amino-5-
hydroxy-6-(5-{4-chloro-6-[4-(2-
sulfonatooxyethanesulfonyl)phenylamino]-1,3,5-
triazin-2-ylamino}-2-sulfonatophenylazo)-3-(2-
sulfonato-4-(2- Xi
sulfonatooxyethanesulfonyl)phenylazo)naphthalene- R: 41 Conc>=10%: Xi; R41
586372-44-3 2,7-disulfonate potassium/sodium Xi; R41 S: (2-)22-26-39 >=5%Conc<10%: Xi; R36 Eu - - - - - - - -
Xi
688046-61-9 Pyriofenone R43 R: 43 Conc>=1%: Xi; R43 V - - - - - - - -

2-[2-(3-Butoxypropyl)-1,1-dioxo-1,2,4-benzothiadiazin-
3-yl]-5'-tert-butyl-2-(5,5-dimethyl-2,4-dioxo-1,3- R: 53
727678-39-9 oxazolidin-3-yl)-2'-[(2-ethylhexyl)thio]acetanilide R53 S: 61 Eu - - - - - - - -
Conc>=25%: Xn; R22; R38; R41; R43
>=20%Conc<25%: Xi; R38; R41: R43
Xn; R22 >=10%Conc<20%: Xi; R41; R43
Xi; R38-41 Xn >=5%Conc<10%: Xi; R36; R43
850997-10-3 1-Cyclohexene-1-propanal, 4,4-dimethyl- R43 R: 22-38-41-43 >=1%Conc<5%: Xi; R43 N - - - - - - - -

Conc>=25%: T; R23; R38; R41; R43

>=20%Conc<25%: Xn; R20; R38; R41; R43
>=10%Conc<20%: Xn; R20; R41; R43
T; R23 >=5%Conc<10%: Xn; R20; R36; R43
Carbonimidodithioic acid, cyano-, chloromethyl hexyl Xi; R38-41 T; >=3%Conc<5%: Xn; R20; R43
852023-54-2 ester R43 R: 23-38-41-43 >=1%Conc<3%: Xi; R43 N - - - - - - - -
Poly(oxy-1,2-ethanediyl), alpha-phosphono-omega- C Conc>=10%: C; R34
873662-29-4 [(2-propylheptyl)oxy]- C; R34 R: 34 >=5%Conc<10%: Xi; R36/38 N - - - - - - - -
Benzoic acid, 2-hydroxy-, (3Z)-1-methyl-3-hexen-1-yl Xi
873888-84-7 ester R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -

Conc>=25%: T; R61; R62; R48/25; R22; R36

Repr. Cat. 2; R61 >=20%Conc<25%: T; R61; R62; R48/25; R36
Repr. Cat. 3; R62 >=10%Conc<20%: T; R61; R62; R48/25
T; R48/25 >=5%Conc<10%: T; R61; R62; R48/22
Xn; R22 T ; R: 61 - 62 - 22 - 36 - >=1%Conc<5%: T; R61; R48/22
874819-74-6 Toceranib Xi; R36 48/25 >=0.5%Conc<1%: T; R61 V - - - - - - - -
Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, di-C12-16- Xi Conc>=10%: Xi; R41
886848-66-4 alkyl esters Xi; R41 R: 41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
C Conc>=10%: C; R35
R: 35 >=5%Conc<10%: C; R34
900169-60-0 Amines, bis(C11-14-branched and linear alkyl) C; R35 S: 26-36/37/39 >=1%Conc<5%: Xi; R36/38 N - - - - - - - -

Copper, phthalic anhydride-2,3-pyridinedicarboxylic

acid-urea reaction products complexes, [[2-[[4-amino-
6-[(2,5-disulfophenyl)amino]-1,3,5-triazin-2- Xi
yl]amino]ethyl]amino]sulfonyl aminosulfonyl sulfo R: 41 Conc>=10%: Xi; R41
908355-26-0 derivs., sodium salts Xi; R41 S: 25-26-39 >=5%Conc<10%: Xi; R36 N - - - - - - - -
1,3-Benzenedicarboxylic acid, 5-[[4-[[3-[2-[8-
(benzoylamino)-1-hydroxy-3,6-disulfo-2-
naphthalenyl]diazenyl]-4-sulfophenyl]amino]-6-[(2-
sulfoethyl)amino]-1,3,5-triazin-2-yl]amino]-, sodium Xi
909094-45-7 salt (1:?) R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -
Dodecanoic acid, methyl-2-sulfoethyl ester, sodium Xi
928663-45-0 salt (1:1) Xi; R36/38 R: 36/38 Conc>=20%: Xi; R36/38 N - - - - - - - -
Xn; R65 Xn
928771-01-1 Alkanes, C10-20-branched and linear R66 R: 65-66 Conc>=10%: Xn; R65 N - - - - - - - -
935545-74-7 Spinetoram R43 Xi R: 43 Conc>=1%: Xi; R43 V - - - - - - - -

Page 354
 Carcinogen
Cas No Substance Name Classification Labelling Cut Offs Source Standard Name TWA ppm TWA mgm3 STEL ppm STEL mgm3 Category Notices Notes
950782-86-2 Indaziflam Xn; R48/22 Xn; R: 48/22 Conc>=10%: Xn; R48/22 V - - - - - - - -
Xn; R22 Conc>=25%: Xn; R22; R38; R43
Xi; R38 Xn >=20%Conc<25%: Xi; R38; R43
950919-28-5 2H-1,5-Benzodiazepin-3(4H)-one, 7-(1-methylethyl)- R43 R: 22-38-43 >=1%Conc<20%: Xi; R43 N - - - - - - - -

2,7-Naphthalenedisulfonic acid, 5-[[4-[(3-amino-4-

sulfophenyl)amino]-6-chloro-1,3,5-triazin-2-yl]amino]-
4-hydroxy-3-[2-(1-sulfo-2-naphthalenyl)diazenyl]-,
sodium salt (1:?), diazotized, reaction products with 2-
[(3-aminophenyl)sulfonyl]ethyl hydrogen hydroxy,
sodium 4-amino-5-hydroxy-2,7-
naphthalenedisulfonate (1:1) and 2,4,6-trichloro-1,3,5- Xi Conc>=10%: Xi; R41
958872-41-8 triazine, sodium salts Xi; R41 R: 41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
Pentadecane, 7-methylene-, mixed with 1- Xn
1000172-11-1 tetradecene, dimers and trimers, hydrogenated Xn; R65 R: 65 Conc>=10%: Xn; R65 N - - - - - - - -
Conc>=10%: C; R35
C >=5%Conc<10%: C; R34
1005516-89-1 Amines, di-C11-14-isoalkyl, C13-rich C; R35 R: 35 >=1%Conc<5%: Xi; R36/38 N - - - - - - - -
Xi
1019768-09-2 Ethanamine, 2-(4-polyisobutylenephenoxy) derivs. R43 R: 43 Conc>=1%: Xi; R43 N - - - - - - - -

1,1'-Biphenyl]-4,4'-bis(diazonium), 3,3'-dichloro-,
chloride (1:2), reaction products with aluminum
hydroxide, 4-[(1,3-dioxobutyl)amino]benzamide, 2-
[(1,3-dioxobutyl)amino]benzoic acid, 5-[(1,3-
dioxobutyl)amino]-2-hydroxybenzoic acid and 3-oxo-N Xn
1026108-50-8 phenylbutanamide Xn; R20 R: 20 Conc>=25%: Xn; R20 N - - - - - - - -
[1,1’-Biphenyl]-4,4’-bis(diazonium), 3,3’-dichloro-,
chloride (1:2), reaction products with aluminium
chloride, calcium carbonate, N-(2,4-dimethylphenyl)-3-
oxobutanamide, potassium 4-[(1,3-
dioxobutyl)amino]benzenesulfonate (1:1) and sodium Xn
1032192-78-1 hydroxide Xn; R20 R: 20 Conc>=25%: Xn; R20 N - - - - - - - -
Butanamide, N-[4-[[[3-
(dimethylamino)propyl]amino]sulfonyl]phenyl]-2-[2-(2- Xi
1065519-44-9 methoxy-4-nitrophenyl)diazenyl]-3-oxo- Xi; R36 R: 36 Conc>=20%: Xi; R36 N - - - - - - - -
Conc>=20%: Xi; R38; R41
Fatty acids, coco, reaction products with glycine, Xi >=10%Conc<20%: Xi; R41
1170699-53-2 potassium salts Xi; R38-41 R: 38-41 >=5%Conc<10%: Xi; R36 N - - - - - - - -
[5,5'-Biisobenzofuran]-1,1',3,3'-tetrone, polymer with
2,2-bis(hydroxymethyl)-1,3-propanediol, 2-hydroxy-3-
[(2-methyl-1-oxo-2-propen-1-yl)oxy]propyl ester, 2- Xi; R36/38 Xi Conc>=20%: Xi; R36/38; R43
1265979-58-5 propenoate R43 R: 36/38-43 >=1%Conc<20%: Xi; R43 N - - - - - - - -

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