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MENGKUDU 1 - Quercetin

The report provides an analysis of two samples, BLANK WATER and MENGKUDU 1, using a specific method and instrument settings. It includes detailed experimental records, gradient tables, and data from the PDA detector, highlighting the conditions and parameters used during the analysis. Additionally, it presents chromatograms and identified compounds related to the MENGKUDU 1 sample.

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Izzat
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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19 views244 pages

MENGKUDU 1 - Quercetin

The report provides an analysis of two samples, BLANK WATER and MENGKUDU 1, using a specific method and instrument settings. It includes detailed experimental records, gradient tables, and data from the PDA detector, highlighting the conditions and parameters used during the analysis. Additionally, it presents chromatograms and identified compounds related to the MENGKUDU 1 sample.

Uploaded by

Izzat
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SUMMARY REPORT

Analysis Information
Item name: POS_SCREENING POLAR_FRI TANJUNG Analysis Method Item name: POS_SCREENING POLAR_PDA
DEMONG_DR.SHAHARAH_report
Version: 4 Analysis Method Version: 4
Modified date: Sep 08, 2023 12:39:35 Malay Peninsula Standard Sample Set Created date:
Time
Modified by: Fashiha, Siti Sample Set Instrument system
name:
Folder: Company/Central Lab/External

Sample Information
Item name: BLANK WATER Sample type: Blank
Item description: Sample position: 1:A,1
Item name: MENGKUDU 1 Sample type: Unknown
Item description: Sample position: 1:A,3

Experimental Record : BLANK WATER


I-Class Binary Solvent Manager
General
Solvent Name A: Water +0.1%Formic Acid Solvent Name B: Acetonitrile + 0.1%Formic Acid
Solvent Selection A: A1 Solvent Selection B: B1
Comment: Seal Wash Period: 5.000 min
Gradient start: At injection Pre-Injector Volume: 0 µL
2D Repeat Enabled: No High Pressure Limit: 18000 psi
2D Repeat Enabled: No High Pressure Limit: 18000 psi
Low Pressure Limit: 0 psi

Gradient Table
Flow Rate Compositio Compositio
Time (min) Curve
(mL/min) n A (%) n B (%)
0.00 0.600 99.0 1.0 Initial
0.50 0.600 99.0 1.0 6
16.00 0.600 65.0 35.0 6
18.00 0.600 0.0 100.0 1
20.00 0.600 99.0 1.0 1

Data
System Pressure (psi) Channel Enabled: Yes Flow Rate (mL/min) Channel Enabled: No
A Composition (%) Channel Enabled: No B Composition (%) Channel Enabled: No
Primary A Pressure (psi) Channel Enabled: No Accumulator A Pressure (psi) Channel Enabled: No
Primary B Pressure (psi) Channel Enabled: No Accumulator B Pressure (psi) Channel Enabled: No
Degasser Pressure (psi) Channel Enabled: No

Analog Out
Chart Out 1: Flow Rate Chart Out 2: Flow Rate

Events
Initial Switch 1: No Change Initial Switch 2: No Change
Initial Switch 3: No Change Pre-Analysis mode: No
Run Events: No

PDA Detector

General
Lamp state: On Sampling rate: 10 points/sec
Filter Time Constant Mode: No filter Filter Time Constant: N/A
Exposure Time: Auto Interpolate 2nd Order Filter (340 nm) Region: No
Use UV Blocking Filter: No Negative absorbance margin: -0.07 AU

3D Channel
Start Wavelength: 190 nm
End Wavelength: 500 nm
Resolution: 1.2 nm
Comment:

2D Channel Table
Spectral
Wavelengt Wavelengt Minimum
Channel Data mode channel
h 1 (nm) h 2 (nm) channel ratio
resolution
Channel 1 Absorbance 1.2 254

Analog Out
Output 1
Channel: 1: Absorbance : 254 nm Full Scale Range: 4.000 units
Ratio Full Scale: 100 Full Scale Voltage: 2000 mV
Voltage Offset: 0 mV

Events
Switch 1
Initial Switch 1: No Change Threshold event: Channel: 1: Absorbance : 254 nm
Threshold State: On Threshold Level: 1.000 AU
Pulse width: 1 sec Rect wave period: 0.2 sec
Run Events: No

Sample Manager FTN


General
Wash Solvent: H2O:MEOH:ACN:IPA 1:1:1:1 Wash Solvent Pre Inject: 0 s
Wash Solvent Post Inject: 5 s Purge Solvent: 90:10 Water/MeOH
Load Ahead: Disabled Loop Offline: Disabled
Column Temperature Enable: Yes Column Temperature: 40.0 °C
Column Temperature Alarm: No Sample Temperature Enable: Yes
Sample Temperature: 20.0 °C Sample Temperature Alarm Enable: No
Comment:

Data
Sample Temperature (°C) Channel Enabled: Yes Column Temperature (°C) Channel Enabled: No
Ambient Temperature (°C) Channel Enabled: Yes Sample Pressure (psi) Channel Enabled: No
Seal Force (%) Channel Enabled: No Pre Heater Temperature (°C) Channel Enabled: No
Dilution
Dilution Enable: Disabled Needle Placement (from bottom): Disabled
Dilution Dispense Purge Solvent: Disabled Post Dilution Delay: Disabled

Events
Run Events: No

Advanced
Syringe Draw Rate: Automatic Needle Placement (from bottom): 2.0 mm
Pre Aspirate Air: Automatic Post Aspirate Air: Automatic
Mix Stroke Cycles: Automatic Mix Stroke Volume: Automatic

Vion IMS QTof


Instrument software build: 2.0.0

Method
Polarity: Positive Analyzer mode: Sensitivity

Function 1 : MSᴱ
Mode: High Definition MSᴱ Start time: 0.00 min
End time: 20.00 min Low mass: 50 m/z
High mass: 1000 m/z Scan time: 0.200 s
Low collision energy: 4.00 eV High collision energy ramp start: 10.00 eV
High collision energy ramp end: 40.00 eV Enable Tof data reduction on acquired data: Yes
Intensity threshold: 10000 counts

Source parameters
Source type: ESI Source temperature: 120 °C
Desolvation temperature: 550 °C Cone gas: 50 L/h
Desolvation gas: 800 L/h Capillary voltage: 2.50 kV

Lock correction
Mode: Automatic Automatic sampling interval: No
Interval: 0.50 min

Options
Acquisition check failure: Stop acquisition Automatic detector check: Disabled
Events
Time (min) Event Parameters
Initial Flow state LC, Sample
Initial Infusion Start, Reference
Initial Refill Refill always, Reference
Initial Reservoir B, Reference

Method trigger
Trigger type: Network Event input 1: Enabled
Event input 2: Disabled

Experimental Record : MENGKUDU 1


I-Class Binary Solvent Manager
General
Solvent Name A: Water +0.1%Formic Acid Solvent Name B: Acetonitrile + 0.1%Formic Acid
Solvent Selection A: A1 Solvent Selection B: B1
Comment: Seal Wash Period: 5.000 min
Gradient start: At injection Pre-Injector Volume: 0 µL
2D Repeat Enabled: No High Pressure Limit: 18000 psi
Low Pressure Limit: 0 psi

Gradient Table
Flow Rate Compositio Compositio
Time (min) Curve
(mL/min) n A (%) n B (%)
0.00 0.600 99.0 1.0 Initial
0.50 0.600 99.0 1.0 6
16.00 0.600 65.0 35.0 6
18.00 0.600 0.0 100.0 1
20.00 0.600 99.0 1.0 1

Data
System Pressure (psi) Channel Enabled: Yes Flow Rate (mL/min) Channel Enabled: No
A Composition (%) Channel Enabled: No B Composition (%) Channel Enabled: No
Primary A Pressure (psi) Channel Enabled: No Accumulator A Pressure (psi) Channel Enabled: No
Primary A Pressure (psi) Channel Enabled: No Accumulator A Pressure (psi) Channel Enabled: No
Primary B Pressure (psi) Channel Enabled: No Accumulator B Pressure (psi) Channel Enabled: No
Degasser Pressure (psi) Channel Enabled: No

Analog Out
Chart Out 1: Flow Rate Chart Out 2: Flow Rate

Events
Initial Switch 1: No Change Initial Switch 2: No Change
Initial Switch 3: No Change Pre-Analysis mode: No
Run Events: No

PDA Detector

General
Lamp state: On Sampling rate: 10 points/sec
Filter Time Constant Mode: No filter Filter Time Constant: N/A
Exposure Time: Auto Interpolate 2nd Order Filter (340 nm) Region: No
Use UV Blocking Filter: No Negative absorbance margin: -0.07 AU

3D Channel
Start Wavelength: 190 nm
End Wavelength: 500 nm
Resolution: 1.2 nm
Comment:

2D Channel Table
Spectral
Wavelengt Wavelengt Minimum
Channel Data mode channel
h 1 (nm) h 2 (nm) channel ratio
resolution
Channel 1 Absorbance 1.2 254

Analog Out
Output 1
Channel: 1: Absorbance : 254 nm Full Scale Range: 4.000 units
Ratio Full Scale: 100 Full Scale Voltage: 2000 mV
Voltage Offset: 0 mV

Events
Switch 1
Initial Switch 1: No Change Threshold event: Channel: 1: Absorbance : 254 nm
Threshold State: On Threshold Level: 1.000 AU
Pulse width: 1 sec Rect wave period: 0.2 sec
Run Events: No

Sample Manager FTN


General
Wash Solvent: H2O:MEOH:ACN:IPA 1:1:1:1 Wash Solvent Pre Inject: 0 s
Wash Solvent Post Inject: 5 s Purge Solvent: 90:10 Water/MeOH
Load Ahead: Disabled Loop Offline: Disabled
Column Temperature Enable: Yes Column Temperature: 40.0 °C
Column Temperature Alarm: No Sample Temperature Enable: Yes
Sample Temperature: 20.0 °C Sample Temperature Alarm Enable: No
Comment:

Data
Sample Temperature (°C) Channel Enabled: Yes Column Temperature (°C) Channel Enabled: No
Ambient Temperature (°C) Channel Enabled: Yes Sample Pressure (psi) Channel Enabled: No
Seal Force (%) Channel Enabled: No Pre Heater Temperature (°C) Channel Enabled: No

Dilution
Dilution Enable: Disabled Needle Placement (from bottom): Disabled
Dilution Dispense Purge Solvent: Disabled Post Dilution Delay: Disabled

Events
Run Events: No

Advanced
Syringe Draw Rate: Automatic Needle Placement (from bottom): 2.0 mm
Pre Aspirate Air: Automatic Post Aspirate Air: Automatic
Mix Stroke Cycles: Automatic Mix Stroke Volume: Automatic

Vion IMS QTof


Instrument software build: 2.0.0

Method
Polarity: Positive Analyzer mode: Sensitivity

Function 1 : MSᴱ
Mode: High Definition MSᴱ Start time: 0.00 min
End time: 20.00 min Low mass: 50 m/z
High mass: 1000 m/z Scan time: 0.200 s
Low collision energy: 4.00 eV High collision energy ramp start: 10.00 eV
High collision energy ramp end: 40.00 eV Enable Tof data reduction on acquired data: Yes
Intensity threshold: 10000 counts

Source parameters
Source type: ESI Source temperature: 120 °C
Desolvation temperature: 550 °C Cone gas: 50 L/h
Desolvation gas: 800 L/h Capillary voltage: 2.50 kV

Lock correction
Mode: Automatic Automatic sampling interval: No
Interval: 0.50 min

Options
Acquisition check failure: Stop acquisition Automatic detector check: Disabled

Events
Time (min) Event Parameters
Initial Flow state LC, Sample
Initial Infusion Start, Reference
Initial Refill Refill always, Reference
Initial Reservoir B, Reference

Method trigger
Trigger type: Network Event input 1: Enabled
Event input 2: Disabled
TIC (Total Ion Chromatogram) Plot

BPI (Base Peak Intensity) Plot


PDA (Photo Diode Array) Plot

Item name: BLANK WATER


Channel name: PDA MaxPlot (190-500)
18.50
Absorbance [AU]

16.43

0.5

0.56
0
0 2 4 6 8 10 12 14 16 18 20
Retention time [min]

Item name: MENGKUDU 1


Channel name: PDA MaxPlot (190-500)
1.07
0.48

2
Absorbance [AU]

1.12

6.25 18.49
2.65
7.48 8.15
1 1.62
3.92 6.05 6.38 16.43
2.43 4.13
3.74 6.80 7.82 8.36 9.10
4.71 5.90
0
0 2 4 6 8 10 12 14 16 18 20
Retention time [min]
Idened Compounds
Item name: MENGKUDU 1
O
O
O
O

O
O O

O
O
O
O
O
O

60000
O
O
O
O O

O
O

Quercetin-3-O-rhamnosi… O
Intensity [Counts]

7.50 O

40000 Quercetin_2 Quercetin-3-O-rhamnosi…


C hir al

O O O

7.28
O

8.18
O
O O O
O O

O O
O O O O
O O
O O

O O
O

O
O
O O
Quercetin-3-O-rhamnoside
O
20000 O O
O
7.20
O
Isorhamnetin
Quercetin 3-O-2-O-a-rha… Quercetin_2 8.48 Quercetin-3-O-a…
Quercetin-3-O-glucuroni… 5.27 6.81 10.04
2.58
0
2 3 4 5 6 7 8 9 10
Retention time [min]

Item name: MENGKUDU 1, Sample position: 1:A,3, Replicate number: 1


Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
1 Quercetin 3-O-2-O-a- C30H32O19 Identified 696.1553 697.1626 1.5 2.2 1.38 613 +H 241.71 2
rhamnosyl-6-O-malonyl
2 3-O-β-D- C21H22O12 Identified 466.1093 467.1166 -1.8 -3.9 1.83 525 +H 201.15 6
Galacopyanosyl
quercetin
3 Quercetin-3-O- C22H20O13 Identified 492.0907 493.0980 0.3 0.6 2.56 646 +H 226.10 7
glucuronide 6″-
methylester
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
4 Quercetin-3-O- C22H20O13 Identified 492.0907 493.0980 0.3 0.7 2.58 967 +H 214.73 4
glucuronide 6″-
methylester
5 Quercetin-3-O- C20H18O11 Identified 434.0835 435.0907 -1.4 -3.3 2.85 554 +H 258.20 4
arabinofuranoside
6 Quercetin-3- C33H40O21 Identified 772.2069 773.2142 0.7 0.9 4.57 501 +H 271.36 4
rhamnogentiobioside
7 Quercetin-3-O- C20H18O11 Identified 434.0851 435.0924 0.2 0.4 4.86 511 +H 185.50 0
arabinofuranoside
8 Quercetin-3- C33H40O21 Identified 772.2050 773.2123 -1.2 -1.5 4.93 1458 +H 267.49 5
rhamnogentiobioside
9 Quercetin-3-O- C22H20O13 Identified 492.0918 493.0991 1.4 2.9 5.01 727 +H 211.09 5
glucuronide 6″-
methylester
10 Quercetin-3-O-(2G-α-L- C33H40O20 Identified 756.2128 757.2201 1.5 2.0 5.06 859 +H 300.85 4
rhamnosyl)-rutinoside
11 Quercetin-3-O-(2G-α-L- C33H40O20 Identified 756.2110 757.2183 -0.3 -0.4 5.07 757 +H 269.22 6
rhamnosyl)-rutinoside
12 Quercetin 3-O-2-O-a- C30H32O19 Identified 696.1506 697.1579 -3.2 -4.5 5.27 2082 +H 256.34 6
rhamnosyl-6-O-malonyl
13 quercetin 3-O-a-L- C20H20O11 Identified 436.1003 437.1076 -0.3 -0.6 5.52 1207 +H 191.83 3
arabinoside
14 quercetin 3-O-a-L- C20H20O11 Identified 436.1004 437.1077 -0.2 -0.4 5.54 1197 +H 202.78 2
arabinoside
15 Quercetin-7-O- C27H30O16 Identified 610.1534 611.1606 0.0 0.0 5.61 1312 +H 270.33 6
rutinoside
16 Quercetin-3-O- C21H20O11 Identified 448.1014 449.1087 0.8 1.8 5.61 1985 +H 270.82 3
rhamnoside
17 quercetin 3-O-a-L- C20H20O11 Identified 436.1010 437.1083 0.4 1.0 6.00 1230 +H 195.63 3
arabinoside
18 Quercetin-3-O- C20H18O11 Identified 434.0834 435.0907 -1.5 -3.4 6.13 492 +H 194.79 2
arabinofuranoside
19 Quercetin-6-O- C21H20O13 Identified 480.0899 481.0972 -0.5 -1.0 6.69 527 +H 205.13 4
glucoside
20 Quercetin-3′-O- C21H20O12 Identified 464.0964 465.1037 0.9 2.0 6.79 581 +H 211.09 5
glucoside
21 Quercetin-7-O- C27H30O16 Identified 610.1542 611.1614 0.8 1.3 6.81 700 +H 210.95 11
rutinoside
22 Isorhamnetin C16H12O7 Identified 316.0594 317.0667 1.1 3.5 6.81 497 +H 194.01 2
23 Quercetin-3′-O- C21H20O12 Identified 464.0966 465.1038 1.1 2.3 6.81 5694 +H 268.70 3
glucoside
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
24 Quercetin-3-O-β-D- C27H30O16 Identified 610.1541 611.1614 0.7 1.2 6.81 1623 +H 238.67 13
gluco-pyranosyl(14)-
α-L-rhamnopyranoside
25 Quercetin_2 C15H10O7 Identified 302.0435 303.0508 0.9 2.9 6.81 1641 +H 210.09 1
26 Quercetin hydrate C15H10O7 Identified 302.0435 303.0508 0.9 2.9 6.81 15156 +H 272.26 1
27 Quercetin_2 C15H10O7 Identified 302.0435 303.0508 0.9 2.9 6.81 15156 +H 272.26 1
28 Quercetin-3-O-β-D- C26H28O16 Identified 596.1373 597.1445 -0.5 -0.8 6.81 1673 +H 267.96 6
xylopyranosyl (12)-β-
D-glucopyranoside
29 Quercetin-7-O- C27H30O16 Identified 610.1540 611.1613 0.6 1.0 6.81 8274 +H 267.79 6
rutinoside
30 quercetin 3-glucoside C21H20O12 Identified 464.0966 465.1038 1.1 2.4 6.81 1469 +H 237.14 8
31 Quercetin_2 C15H10O7 Identified 302.0435 303.0508 0.9 2.8 6.81 3970 +H 241.50 2
32 Quercetin-3-O- C21H20O11 Identified 448.1004 449.1077 -0.1 -0.3 7.19 4915 +H 234.93 3
rhamnoside
33 Quercetin-3-O- C21H20O11 Identified 448.1004 449.1077 -0.1 -0.3 7.20 15464 +H 268.20 3
rhamnoside
34 Quercetin-3′-O- C21H20O12 Identified 464.0969 465.1041 1.4 3.0 7.27 1299 +H 274.70 3
glucoside
35 Quercetin-7-O- C27H30O16 Identified 610.1542 611.1615 0.8 1.3 7.28 2234 +H 332.06 4
rutinoside
36 Quercetin hydrate C15H10O7 Identified 302.0436 303.0509 1.0 3.3 7.28 42420 +H 242.05 2
37 Quercetin_2 C15H10O7 Identified 302.0436 303.0509 1.0 3.3 7.28 42420 +H 242.05 2
38 Quercetin_2 C15H10O7 Identified 302.0436 303.0509 1.0 3.3 7.28 9538 +H 166.54 2
39 Quercetin-3-O- C27H30O16 Identified 610.1542 611.1615 0.8 1.4 7.28 10062 +H 239.14 11
rutinoside_2
40 Quercetin_2 C15H10O7 Identified 302.0436 303.0509 1.0 3.3 7.28 6025 +H 208.40 1
41 Quercetin-7-O- C27H30O16 Identified 610.1542 611.1615 0.8 1.3 7.28 1039 +H 369.50 1
rutinoside
42 quercetin 3-glucoside C21H20O12 Identified 464.0969 465.1041 1.4 3.0 7.29 1974 +H 206.88 4
43 Quercetin_2 C15H10O7 Identified 302.0443 303.0516 1.6 5.4 7.40 655 +H 206.63 0
44 Quercetin-3-O- C21H20O11 Identified 448.1008 449.1081 0.2 0.5 7.50 64149 +H 265.19 11
rhamnoside
45 Quercetin-3-O- C21H20O11 Identified 448.1008 449.1081 0.2 0.5 7.50 14627 +H 233.74 5
rhamnoside
46 Isorhamnetin C16H12O7 Identified 316.0578 317.0650 -0.5 -1.7 7.72 673 +H 273.14 2
47 Quercetin-3-O- C21H20O11 Identified 448.1023 449.1096 1.8 3.9 7.73 3249 +H 236.12 3
rhamnoside
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
48 Quercetin-3-O-(2G-α-L- C33H40O20 Identified 756.2118 757.2191 0.6 0.7 7.74 1195 +H 269.26 6
rhamnosyl)-rutinoside
49 Quercetin-3-O- C21H20O11 Identified 448.1012 449.1085 0.7 1.5 8.16 2207 +H 199.46 2
rhamnoside
50 Quercetin-3-O- C21H20O11 Identified 448.1012 449.1085 0.7 1.5 8.18 71464 +H 235.60 6
rhamnoside
51 Quercetin-3-O- C21H20O11 Identified 448.1012 449.1085 0.7 1.5 8.18 2812 +H 318.89 2
rhamnoside
52 3-O-Methylquercetin C16H12O7 Identified 316.0591 317.0664 0.8 2.5 8.48 1330 +H 240.38 1
53 Isorhamnetin C16H12O7 Identified 316.0591 317.0664 0.8 2.5 8.48 1330 +H 240.38 1
54 Isorhamnetin C16H12O7 Identified 316.0591 317.0664 0.8 2.5 8.48 878 +H 172.67 1
55 Quercetin-3-O- C20H18O11 Identified 434.0835 435.0907 -1.4 -3.3 10.04 1005 +H 198.54 2
arabinofuranoside
56 Quercetin 3-O-2-O-a- C30H32O19 Identified 696.1524 697.1597 -1.4 -1.9 10.60 665 +H 255.17 3
rhamnosyl-6-O-malonyl
57 Quercetin 3-O-2-O-a- C30H32O19 Identified 696.1533 697.1606 -0.5 -0.7 10.66 709 +H 269.89 1
rhamnosyl-6-O-malonyl
Detils of Idened Components
Item name: MENGKUDU 1
Channel name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl [+H] : (39.7 PPM)
697.1626 : DT=6.94 to 7.42 ms

600
Intensity [Counts]

400

1.27
Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl
1.37
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000

Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl
0 1.47
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 1.3801 +/-
Channel name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl [+H] : (39.7 PPM) Component name: Quercetin 3-O-2-O-a- 0.0288 minutes : Drift Times: 7.18 +/- 0.24 ms
697.1626 rhamnosyl-6-O-malonyl
7.87
337.10538
10000
2500

Intensity [Counts]
355.11367
768.16526
2000 4.56
Intensity [Counts]

5000 785.17375
593.17079
1500 5.29 814.16950
268.10400 368.21921

9.53 256.08457 460.11543


1.81 3.58 7.72
1000 9.59 0
1.27 7.14 13.12
10.62 200 400 600 800 1000
13.15
500 Item name: MENGKUDU 1 Channel name: High energy : Time 1.3801 +/-
14.34 Component name: Quercetin 3-O-2-O-a- 0.0288 minutes : Drift Times: 7.02 +/- 0.24 ms
13.44
15.36 rhamnosyl-6-O-malonyl
0
239.05579 802.20397
0 5 10 15 20
Retention time [min]
347.02816

Intensity [Counts]
2000
355.13594 702.19529
698.16087
421.05937
531.13486
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: 3-O-β-D-Galacopyanosyl quercetin [+H] : (39.7 PPM) 467.1166 :
DT=5.47 to 5.96 ms
1250

1000
Intensity [Counts]

750

500

3-O-β-D-Galacopyanosyl quercetin
250 1.82

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000

3-O-β-D-Galacopyanosyl quercetin
0 1.81
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 1.8307 +/-
Channel name: 3-O-β-D-Galacopyanosyl quercetin [+H] : (39.7 PPM) 467.1166 Component name: 3-O-β-D-Galacopyanosyl 0.0288 minutes : Drift Times: 5.82 +/- 0.24 ms
3.53 quercetin
2500
431.08252

441.10201
2000 20000

Intensity [Counts]
385.15187
2.97
Intensity [Counts]

1500
10.14 353.09746 473.10903
10000
5.78 10.11
10.20 591.11830
1.81 6.91 351.07237
1000 831.12833
9.99 10.27 266.09609
0.98
5.00 7.28 0
10.97 200 400 600 800 1000
500 13.90 14.99 Item name: MENGKUDU 1 Channel name: High energy : Time 1.8307 +/-
Component name: 3-O-β-D-Galacopyanosyl 0.0288 minutes : Drift Times: 5.67 +/- 0.24 ms
15.16
18.52 quercetin
0
459.11291
0 5 10 15 20
Retention time [min]
441.10030

Intensity [Counts]
20000

183.02869
385.15058
109.02821 251.00163 543.04378 633.10454

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-glucuronide 6″-methylester [+H] : (39.7 PPM)
493.0980 : DT=6.50 to 6.99 ms

400

300
Quercetin-3-O-glucuronide 6″-methylester
Intensity [Counts]

2.56
2.50

200 2.45
2.41
2.36

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 2.5623 +/-
Channel name: Quercetin-3-O-glucuronide 6″-methylester [+H] : (39.7 PPM) Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 6.68 +/- 0.24 ms
493.0980 glucuronide 6″-methylester
5.03
619.14638
3.03 601.13664
1250
2.91 50000

Intensity [Counts]
3.06
1000 2.57
3.12
Intensity [Counts]

3.19 566.13591
2.45 25000
750 3.26
2.39 8.38 360.11628 539.17207 903.11125
4.61 633.14471
8.77 657.16252 899.10287
500 2.36 6.25 7.09 281.08043
1.73 0
8.94 11.81 14.99
0.72 200 400 600 800 1000
250 15.03
Item name: MENGKUDU 1 Channel name: High energy : Time 2.5623 +/-
16.50 18.52 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 6.53 +/- 0.24 ms
glucuronide 6″-methylester
0
566.13550 633.07694
0 5 10 15 20
Retention time [min] 10000 222.07610 291.09808

Intensity [Counts]
539.17522

473.03918
5000 135.04363 897.06664
637.12555
647.05305
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-glucuronide 6″-methylester [+H] : (39.7 PPM)
493.0980 : DT=6.05 to 6.53 ms

300

2.45
Quercetin-3-O-glucuronide 6″-methylester
Intensity [Counts]

200 2.60
2.32

2.22

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61
Quercetin-3-O-glucuronide 6″-methylester
0 2.59
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 2.5826 +/-
Channel name: Quercetin-3-O-glucuronide 6″-methylester [+H] : (39.7 PPM) Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 6.29 +/- 0.24 ms
493.0980 glucuronide 6″-methylester
5.03
485.00088
3.03 75000 431.08133
1250
2.91

Intensity [Counts]
3.06
1000 2.57 50000
3.12
Intensity [Counts]

3.19
511.10505
750 2.45 3.26 25000
2.39 8.38 529.11981 915.07553
4.61 277.08219
2.36 8.77
500 6.25 7.09 686.11680
1.73 0
8.94 11.81 14.99
0.72 200 400 600 800 1000
15.03
250 Item name: MENGKUDU 1 Channel name: High energy : Time 2.5826 +/-
16.50 18.52 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 6.14 +/- 0.24 ms
glucuronide 6″-methylester
0
337.10295
0 5 10 15 20
Retention time [min]
20000

Intensity [Counts]
161.02360

319.09281
10000
529.12304 632.06938 897.06664
887.12971
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-arabinofuranoside [+H] : (39.7 PPM) 435.0907 :
DT=7.49 to 7.97 ms

500

400
Intensity [Counts]

300

Quercetin-3-O-arabinofuranoside
2.85
200

2.78
100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 2.8539 +/-
Channel name: Quercetin-3-O-arabinofuranoside [+H] : (39.7 PPM) 435.0907 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 7.73 +/- 0.24 ms
4.61 arabinofuranoside
5000
20000 304.09374
0.97

4000

Intensity [Counts]
4.69
705.05971 794.15621
Intensity [Counts]

3000 10000 318.10918


471.07355 810.15366

2.85 868.18584
2000 286.08338 603.14895 910.13349
241.07043
0
4.85
3.71 10.04 200 400 600 800 1000
1000 6.83
Item name: MENGKUDU 1 Channel name: High energy : Time 2.8539 +/-
2.08 5.59 9.98
10.37 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 7.58 +/- 0.24 ms
13.87 14.82
14.93 arabinofuranoside
0
336.11885
0 5 10 15 20
Retention time [min]
20000

Intensity [Counts]
436.08993

10000 286.08222
453.10772
274.03696
693.13174
617.11049
794.14102
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-rhamnogentiobioside [+H] : (39.7 PPM) 773.2142 :
DT=7.88 to 8.36 ms

600
Intensity [Counts]

400

Quercetin-3-rhamnogentiobioside
200 4.57

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000

Quercetin-3-rhamnogentiobioside
0 4.55
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 4.5708 +/-
Channel name: Quercetin-3-rhamnogentiobioside [+H] : (39.7 PPM) 773.2142 Component name: Quercetin-3- 0.0288 minutes : Drift Times: 8.12 +/- 0.24 ms
4.93 rhamnogentiobioside

5.22 871.13309
1250
725.17936
5000
884.11605

Intensity [Counts]
1000 4.30 5.32
8.23 443.07518
7.04 897.23211
1.44
Intensity [Counts]

8.54 673.23413
1.64 2.89 7.81 324.10908
750 1.30 9.34 2500
5.60 11.69 275.10188 471.15116
9.49
11.96
500 1.24 15.48 16.59
12.48 0
200 400 600 800 1000
250 Item name: MENGKUDU 1 Channel name: High energy : Time 4.5708 +/-
18.53
17.45 Component name: Quercetin-3- 0.0288 minutes : Drift Times: 7.97 +/- 0.24 ms
rhamnogentiobioside
0
175.04039
0 5 10 15 20
Retention time [min] 10000 216.98052

Intensity [Counts]
257.06568 469.00597

503.08739
5000
308.11482 545.09767

765.23367

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-arabinofuranoside [+H] : (39.7 PPM) 435.0924 :
DT=4.98 to 5.46 ms

1000

750
Intensity [Counts]

500
Quercetin-3-O-arabinofuranoside
4.87

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 4.8631 +/-
Channel name: Quercetin-3-O-arabinofuranoside [+H] : (39.7 PPM) 435.0924 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 5.27 +/- 0.24 ms
4.61 arabinofuranoside
5000
425.13649
75000
4000 0.97

Intensity [Counts]
4.67
50000
Intensity [Counts]

3000 354.11817

2.85 25000
332.11372
2000 306.09588 435.09237

0
3.71 4.85 10.04 200 400 600 800 1000
1000 6.82 9.98
5.59 Item name: MENGKUDU 1 Channel name: High energy : Time 4.8631 +/-
2.08 8.94 10.28 13.87 14.82 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 5.11 +/- 0.24 ms
14.93 arabinofuranoside
0
248.09331 425.13718
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
354.11829
207.09013

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-rhamnogentiobioside [+H] : (39.7 PPM) 773.2123 :
DT=7.82 to 8.30 ms
Quercetin-3-rhamnogentiobioside
4.93

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61
Quercetin-3-rhamnogentiobioside
0 4.94
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 4.9339 +/-
Channel name: Quercetin-3-rhamnogentiobioside [+H] : (39.7 PPM) 773.2123 Component name: Quercetin-3- 0.0288 minutes : Drift Times: 8.00 +/- 0.24 ms
4.93 rhamnogentiobioside
5.22
834.24297
1250
773.21232 843.28041
7500
5.33

Intensity [Counts]
1000 8.23 755.21648
4.30
5000 876.23378
Intensity [Counts]

1.44 7.04 8.54 704.18632


750 1.30 2.88 6.91 675.17561
9.34 11.69 447.11357
9.49 2500 276.08839 587.19001
11.96 15.49
500 1.24 16.59
12.48 0
200 400 600 800 1000
250 Item name: MENGKUDU 1 Channel name: High energy : Time 4.9339 +/-
18.53
17.45 Component name: Quercetin-3- 0.0288 minutes : Drift Times: 7.85 +/- 0.24 ms
rhamnogentiobioside
0
303.05286
0 5 10 15 20
Retention time [min]

Intensity [Counts]
5000 409.17070

526.15269
2500 834.23290
283.10673
675.17975
843.29935
227.03446
221.09656
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-glucuronide 6″-methylester [+H] : (39.7 PPM)
493.0991 : DT=5.93 to 6.41 ms

Quercetin-3-O-glucuronide 6″-methylester
5.02
400

300
Intensity [Counts]

4.90
200
5.11

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 5.0131 +/-
Channel name: Quercetin-3-O-glucuronide 6″-methylester [+H] : (39.7 PPM) Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 6.17 +/- 0.24 ms
493.0991 glucuronide 6″-methylester
5.03
439.12216
3.03
1250 1.5e5
2.91

Intensity [Counts]
3.06
1000 2.57
3.12 100000
2.55
Intensity [Counts]

3.19
750 2.45 3.26 461.16291
50000
2.39 3.79 8.38
317.08367 530.18604
2.36 6.25 7.09 8.77 859.23423
500 115.03774 658.20366
1.83 0
8.94 14.99
0.72 10.17 200 400 600 800 1000
15.03
250 Item name: MENGKUDU 1 Channel name: High energy : Time 5.0131 +/-
15.31 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 6.02 +/- 0.24 ms
18.52
glucuronide 6″-methylester
0
439.12327
0 5 10 15 20 50000
Retention time [min]

Intensity [Counts]
25000 461.16404

216.98112
198.97022 347.09374 531.17804
629.23076
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside [+H] : (39.7 PPM)
757.2201 : DT=8.82 to 9.30 ms

Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside
5.06

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 5.0557 +/-
Channel name: Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside [+H] : (39.7 PPM) Component name: Quercetin-3-O-(2G-α-L- 0.0288 minutes : Drift Times: 9.04 +/- 0.24 ms
757.2201 rhamnosyl)-rutinoside
5.61
889.25988
4000
7500

Intensity [Counts]
890.26691
3000 5000 757.22010
449.10387
Intensity [Counts]

821.22757
499.10851
2500
2000 324.10928
5.05
5.93 0
4.75 7.74 10.04
7.90 200 400 600 800 1000
1000
1.41 10.22
4.65 Item name: MENGKUDU 1 Channel name: High energy : Time 5.0557 +/-
11.47 16.53
Component name: Quercetin-3-O-(2G-α-L- 0.0288 minutes : Drift Times: 8.89 +/- 0.24 ms
13.51
17.67 rhamnosyl)-rutinoside
0
287.05639
0 5 10 15 20
Retention time [min]
10000

Intensity [Counts]
330.11590
449.10947
5000 161.02460

461.16331 611.19155
911.22979

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside [+H] : (39.7 PPM)
757.2183 : DT=7.82 to 8.30 ms

2000

1500
Intensity [Counts]

1000

500

Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside
0 5.05

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000

Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside
0 5.04
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 5.0659 +/-
Channel name: Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside [+H] : (39.7 PPM) Component name: Quercetin-3-O-(2G-α-L- 0.0288 minutes : Drift Times: 8.06 +/- 0.24 ms
757.2183 rhamnosyl)-rutinoside
5.61
346.09140
4000

30000

Intensity [Counts]
3000
20000
Intensity [Counts]

330.11599
10000 856.27941
2000 365.13496 637.19756 794.31637
5.05 324.10933 899.26630

5.93 0
4.76 7.74
10.04 200 400 600 800 1000
1000
1.41 10.22
4.65 Item name: MENGKUDU 1 Channel name: High energy : Time 5.0659 +/-
11.48 16.53
Component name: Quercetin-3-O-(2G-α-L- 0.0288 minutes : Drift Times: 7.90 +/- 0.24 ms
13.51
17.67 rhamnosyl)-rutinoside
0
346.09129
0 5 10 15 20
40000
Retention time [min]

Intensity [Counts]
378.02852
20000 330.11590

379.03114
295.09916 595.18307
478.13739 794.32029 875.22241
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl [+H] : (39.7 PPM)
697.1579 : DT=7.40 to 7.88 ms

1500

1000
Intensity [Counts]

Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl
5.28
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61
Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl
0 5.27
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 5.2720 +/-
Channel name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl [+H] : (39.7 PPM) Component name: Quercetin 3-O-2-O-a- 0.0288 minutes : Drift Times: 7.65 +/- 0.24 ms
697.1579 rhamnosyl-6-O-malonyl
7.87
633.11649
2500
4.56 40000

Intensity [Counts]
2000 290.10339
Intensity [Counts]

308.11504
20000
1500
5.29 326.12479 723.43169
9.53 746.20558
1.81 3.58 342.11080
1000 7.72 935.17017
9.59 0
1.38 7.14 13.12 200 400 600 800 1000
10.62
500 10.91 13.15
Item name: MENGKUDU 1 Channel name: High energy : Time 5.2720 +/-
14.34 Component name: Quercetin 3-O-2-O-a- 0.0288 minutes : Drift Times: 7.50 +/- 0.24 ms
14.71 16.9618.52
rhamnosyl-6-O-malonyl
0
308.11451
0 5 10 15 20
Retention time [min] 345.02697
20000

Intensity [Counts]
346.06006
291.10595 363.03559
10000 286.03967 723.43073
634.11831
205.04978 578.11615 799.17818
831.20608
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: quercetin 3-O-a-L-arabinoside [+H] : (39.7 PPM) 437.1076 : DT=5.26
to 5.74 ms

1250

1000
Intensity [Counts]

750

500

quercetin 3-O-a-L-arabinoside
250
5.53

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 5.5223 +/-
Channel name: quercetin 3-O-a-L-arabinoside [+H] : (39.7 PPM) 437.1076 Component name: quercetin 3-O-a-L- 0.0288 minutes : Drift Times: 5.49 +/- 0.24 ms
4.55 arabinoside
5000
4e5 377.14557

4000

Intensity [Counts]
Intensity [Counts]

2e5
3000

2000 243.08843 399.12788


0.95 577.18535
456.10728 837.22167
3.91 6.01 0
2.18 7.89 200 400 600 800 1000
1000 7.28 Item name: MENGKUDU 1 Channel name: High energy : Time 5.5223 +/-
7.95 10.84 12.40 13.41
Component name: quercetin 3-O-a-L- 0.0288 minutes : Drift Times: 5.34 +/- 0.24 ms
13.45 arabinoside
0
377.14627
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000
243.08911

50000
198.06656
399.12787
493.15896
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: quercetin 3-O-a-L-arabinoside [+H] : (39.7 PPM) 437.1077 : DT=5.64
to 6.12 ms

2500

2000
Intensity [Counts]

1500

1000

500

quercetin 3-O-a-L-arabinoside
5.52
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 5.5354 +/-
Channel name: quercetin 3-O-a-L-arabinoside [+H] : (39.7 PPM) 437.1077 Component name: quercetin 3-O-a-L- 0.0288 minutes : Drift Times: 5.88 +/- 0.24 ms
4.55 arabinoside
5000
418.16210

4000 40000

Intensity [Counts]
Intensity [Counts]

425.17796
3000
20000
447.18027
413.13898
2000 237.09602 483.13712
0.95 797.21956 962.28867
3.91 6.01 0
2.18 7.89 200 400 600 800 1000
1000 7.28
12.40 Item name: MENGKUDU 1 Channel name: High energy : Time 5.5354 +/-
7.95 10.84
Component name: quercetin 3-O-a-L- 0.0288 minutes : Drift Times: 5.73 +/- 0.24 ms
10.90
13.41 arabinoside
0
418.16005
0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
401.13328
10000
176.06951 473.23495
315.10211
553.20599

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-7-O-rutinoside [+H] : (39.7 PPM) 611.1606 : DT=7.87 to
8.35 ms

6000
Intensity [Counts]

4000

2000

Quercetin-7-O-rutinoside
5.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 5.6097 +/-
Channel name: Quercetin-7-O-rutinoside [+H] : (39.7 PPM) 611.1606 Component name: Quercetin-7-O-rutinoside 0.0288 minutes : Drift Times: 8.11 +/- 0.24 ms
7.28
757.21718
20000
15000 449.10866
739.21792

Intensity [Counts]
15000 10000 837.23166
611.16065
Intensity [Counts]

6.81
607.16393
5000 289.17629
10000 871.16816
287.05419 313.13111 595.16452
885.27111

0
5000 200 400 600 800 1000

5.61 Item name: MENGKUDU 1 Channel name: High energy : Time 5.6097 +/-
7.87 9.52 11.81 Component name: Quercetin-7-O-rutinoside 0.0288 minutes : Drift Times: 7.96 +/- 0.24 ms
1.88
5.05 18.16
0 287.05697

0 5 10 15 20 30000
Retention time [min]

Intensity [Counts]
299.05626
20000

449.10867

10000 239.05425
438.99438 513.12491 657.16925
871.30383
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1087 : DT=7.91 to
8.39 ms

30000
Intensity [Counts]

20000

10000

Quercetin-3-O-rhamnoside
0 5.61
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 5.6122 +/-
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1087 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 8.13 +/- 0.24 ms
7.50
8.17 757.21718
15000 449.10866

Intensity [Counts]
60000
10000 837.23166
611.16065
Intensity [Counts]

607.16393 740.21663
40000 5000
871.16816
317.16997 595.16452
7.20 885.27111
303.04641
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 5.6122 +/-
5.61 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 7.98 +/- 0.24 ms
6.41
2.32
0 287.05697

0 5 10 15 20 30000
Retention time [min]

Intensity [Counts]
20000

299.10569 449.10867
10000 239.05425
513.12491 657.16925
808.21795
871.30383
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: quercetin 3-O-a-L-arabinoside [+H] : (39.7 PPM) 437.1083 : DT=5.39
to 5.87 ms

2000

1500
Intensity [Counts]

1000

quercetin 3-O-a-L-arabinoside
6.01
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 5.9983 +/-
Channel name: quercetin 3-O-a-L-arabinoside [+H] : (39.7 PPM) 437.1083 Component name: quercetin 3-O-a-L- 0.0288 minutes : Drift Times: 5.63 +/- 0.24 ms
4.55 arabinoside
5000
30000 397.13985

4000

Intensity [Counts]
20000
Intensity [Counts]

3000 405.17546
10000
437.10826
274.01611
489.19891 689.19841
2000
0.94
6.01 727.22978
3.91 0
2.18 7.89 200 400 600 800 1000
1000 7.28
12.40 Item name: MENGKUDU 1 Channel name: High energy : Time 5.9983 +/-
7.95 10.84 14.07
10.90 Component name: quercetin 3-O-a-L- 0.0288 minutes : Drift Times: 5.48 +/- 0.24 ms
13.41 arabinoside
0
397.14035
0 5 10 15 20
15000
Retention time [min]

Intensity [Counts]
10000
204.06616
321.02638 405.17263
5000
128.06290 633.07746

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-arabinofuranoside [+H] : (39.7 PPM) 435.0907 :
DT=5.36 to 5.84 ms
0.98

1000
4.61
Intensity [Counts]

750
2.84 4.65
10.03

500 3.72

9.98
4.79
250 2.53 6.13
7.768.94 12.43
13.32
14.93
18.43
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61
Quercetin-3-O-arabinofuranoside
0 6.17
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.1312 +/-
Channel name: Quercetin-3-O-arabinofuranoside [+H] : (39.7 PPM) 435.0907 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 5.60 +/- 0.24 ms
4.61 arabinofuranoside
5000
427.15135
0.97

4000 75000

Intensity [Counts]
4.69 439.15839
50000
Intensity [Counts]

3000
359.16159
2.85 471.09701
25000 342.13386
2000 314.14113
481.12771 633.08087 841.15039
188.07133
0
4.85
3.71 10.04 200 400 600 800 1000
1000 6.83
9.98 Item name: MENGKUDU 1 Channel name: High energy : Time 6.1312 +/-
2.08 5.59
10.37 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 5.45 +/- 0.24 ms
13.87 14.82
14.93 arabinofuranoside
0
439.15967
0 5 10 15 20
Retention time [min]
342.13695

Intensity [Counts]
20000

314.14010
10000
228.10087 455.12432
216.98023 471.09541
841.14899
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-6-O-glucoside [+H] : (39.7 PPM) 481.0972 : DT=5.72 to
6.20 ms

2000

1500
Intensity [Counts]

1000

5.91
500
6.40
6.59
Quercetin-6-O-glucoside
6.69
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61
Quercetin-6-O-glucoside
0 6.68
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.6940 +/-
Channel name: Quercetin-6-O-glucoside [+H] : (39.7 PPM) 481.0972 Component name: Quercetin-6-O-glucoside 0.0288 minutes : Drift Times: 5.96 +/- 0.24 ms
4.19
483.11366

20000
3000
455.14542

Intensity [Counts]
420.22275 501.12020
Intensity [Counts]

417.17246
10000 411.19875
2000
535.14602
326.19727
617.14907 815.20809
750.19932
276.08699
5.92 0
1000
1.83 200 400 600 800 1000
6.40
2.02 5.45 7.10 8.40
12.7113.47 Item name: MENGKUDU 1 Channel name: High energy : Time 6.6940 +/-
Component name: Quercetin-6-O-glucoside 0.0288 minutes : Drift Times: 5.81 +/- 0.24 ms
14.79
0 455.14300
10000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
351.08643 497.20015
5000
263.07175
151.04002 521.21940
555.17959
637.11771
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3′-O-glucoside [+H] : (39.7 PPM) 465.1037 : DT=5.95 to
6.43 ms

1000

750
Intensity [Counts]

500 7.00

250 Quercetin-3′-O-glucoside
6.79

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.7891 +/-
Channel name: Quercetin-3′-O-glucoside [+H] : (39.7 PPM) 465.1037 Component name: Quercetin-3′-O-glucoside 0.0288 minutes : Drift Times: 6.17 +/- 0.24 ms
20000 7.27
475.25149
40000 507.18634

Intensity [Counts]
15000
Intensity [Counts]

20000
6.81 303.05080
10000 451.13451 508.18695
292.08439 466.18032
565.15632 756.20327 917.23960
266.10371 833.19867
0
5000 200 400 600 800 1000
7.57
3.38 Item name: MENGKUDU 1 Channel name: High energy : Time 6.7891 +/-
6.41
0.98 8.02 9.89 Component name: Quercetin-3′-O-glucoside 0.0288 minutes : Drift Times: 6.02 +/- 0.24 ms
4.94
12.73
30000 475.25321
0
0 5 10 15 20 303.05136
Retention time [min]

Intensity [Counts]
20000
503.21277
175.03941 571.14748

10000
305.08626
161.09647 781.15117 917.24040
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-7-O-rutinoside [+H] : (39.7 PPM) 611.1614 : DT=5.91 to
6.39 ms

300 Quercetin-7-O-rutinoside
6.81
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8077 +/-
Channel name: Quercetin-7-O-rutinoside [+H] : (39.7 PPM) 611.1614 Component name: Quercetin-7-O-rutinoside 0.0288 minutes : Drift Times: 6.15 +/- 0.24 ms
7.28
475.25149
20000 507.18634
40000

Intensity [Counts]
15000
Intensity [Counts]

6.81 20000
303.05080
10000 508.18695

266.10371 565.15632 756.20327 917.23960

0
5000 200 400 600 800 1000

5.61 Item name: MENGKUDU 1 Channel name: High energy : Time 6.8077 +/-
1.88 7.87 9.52 11.81 Component name: Quercetin-7-O-rutinoside 0.0288 minutes : Drift Times: 6.00 +/- 0.24 ms
5.05 18.16
30000 475.25321
0
0 5 10 15 20 303.05136
Retention time [min]

Intensity [Counts]
20000
503.21277
175.03941 571.14748

10000
459.27448
781.15117 917.24040
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Isorhamnetin [+H] : (39.7 PPM) 317.0667 : DT=5.32 to 5.80 ms

800

600

6.37 6.57
Intensity [Counts]

6.66
400
Isorhamnetin
6.81

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8099 +/- 0.0288
Channel name: Isorhamnetin [+H] : (39.7 PPM) 317.0667 Component name: Isorhamnetin minutes : Drift Times: 5.56 +/- 0.24 ms
8.48
361.13961
3000 75000

Intensity [Counts]
50000
7.72 417.16652
Intensity [Counts]

2000
6.42
25000 421.14712
341.13843 449.11058
451.13328 762.17717
1000 1.98 0
5.04 200 400 600 800 1000
3.68 6.26 8.59
1.93
11.76 Item name: MENGKUDU 1 Channel name: High energy : Time 6.8099 +/- 0.0288
8.64 14.72 Component name: Isorhamnetin minutes : Drift Times: 5.41 +/- 0.24 ms
11.88
15.06
0 361.14098

0 5 10 15 20
Retention time [min] 40000

Intensity [Counts] 20000

293.08517 362.14218
133.10235
604.12749 781.15117
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3′-O-glucoside [+H] : (39.7 PPM) 465.1038 : DT=7.81 to
8.29 ms
Quercetin-3′-O-glucoside
5000 6.81

4000
Intensity [Counts]

3000

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8118 +/-
Channel name: Quercetin-3′-O-glucoside [+H] : (39.7 PPM) 465.1038 Component name: Quercetin-3′-O-glucoside 0.0288 minutes : Drift Times: 8.07 +/- 0.24 ms
20000 7.27
303.05080

100000

Intensity [Counts]
15000
Intensity [Counts]

6.81 611.16128 743.20354


50000 465.10384
10000
901.17523
304.05402
279.10488
0
5000 200 400 600 800 1000
7.57
3.38 Item name: MENGKUDU 1 Channel name: High energy : Time 6.8118 +/-
6.41
0.98 8.02 9.89 Component name: Quercetin-3′-O-glucoside 0.0288 minutes : Drift Times: 7.91 +/- 0.24 ms
4.94
12.73
0
0 5 10 15 20
O

Retention time [min]

Intensity [Counts]
2e5
O
O O
O O

O
O
O
O

O
O

100000
303.05135
Mass error: 1.4 mDa 869.23298
162.05602 293.08470 765.18857
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-β-D-gluco-pyranosyl(14)-α-L-rhamnopyranoside
[+H] : (39.7 PPM) 611.1614 : DT=6.84 to 7.33 ms

6000
Intensity [Counts]

4000

2000

Quercetin-3-O-β-D-gluco-pyranosyl(14)-α-L-rhamnopyranoside
0 6.81
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8120 +/-
Channel name: Quercetin-3-O-β-D-gluco-pyranosyl(14)-α-L-rhamnopyranoside Component name: Quercetin-3-O-β-D-gluco- 0.0288 minutes : Drift Times: 7.09 +/- 0.24 ms
[+H] : (39.7 PPM) 611.1614 pyranosyl(14)-α-L-rhamnopyranoside
7.28
303.05079
20000
30000

Intensity [Counts]
601.16235
15000
20000
Intensity [Counts]

6.81
611.16141
465.10385
10000 622.19473
10000
297.04382 671.24844 829.23487
0
200 400 600 800 1000
5000
5.61 Item name: MENGKUDU 1 Channel name: High energy : Time 6.8120 +/-
1.88 7.87 9.52 11.81 Component name: Quercetin-3-O-β-D-gluco- 0.0288 minutes : Drift Times: 6.94 +/- 0.24 ms
5.05 18.16 pyranosyl(14)-α-L-rhamnopyranoside
0
303.05134
0 5 10 15 20
Retention time [min]
50000

Intensity [Counts] 25000


292.08282
342.04041 671.22275
250.03037 569.19335 901.17598
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin_2 [+H] : (39.7 PPM) 303.0508 : DT=5.88 to 6.36 ms

5000

4000
Intensity [Counts]

3000

2000 Quercetin_2
6.81

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8128 +/- 0.0288 minutes :
Channel name: Quercetin_2 [+H] : (39.7 PPM) 303.0508 Component name: Quercetin_2 Drift Times: 6.11 +/- 0.24 ms
7.27
475.25149
80000
40000 507.18634

Intensity [Counts]
60000
Intensity [Counts]

20000
303.05080
40000 6.81 508.18695

266.10371 611.16143 756.20327 917.23960

0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 6.8128 +/- 0.0288 minutes :
Component name: Quercetin_2 Drift Times: 5.96 +/- 0.24 ms
30000 475.25321
0
0 5 10 15 20
Retention time [min] 303.05136

Intensity [Counts]
20000
503.21277

10000 251.03822
381.09683
204.06689
509.19299
135.11942 781.15117 917.24040
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin hydrate [+H] : Quercetin_2 [+H] : (39.7 PPM) 303.0508 :
DT=7.90 to 8.38 ms
Quercetin_2
15000 6.81

10000
Intensity [Counts]

5000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8130 +/- 0.0288
Channel name: Quercetin hydrate [+H] : Quercetin_2 [+H] : (39.7 PPM) 303.0508 Component name: Quercetin hydrate minutes : Drift Times: 8.14 +/- 0.24 ms
7.27
303.05080
80000

100000

Intensity [Counts]
60000
Intensity [Counts]

611.16128 743.20354
50000 465.10384
40000 6.81
901.17523
304.05402
279.10488
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 6.8130 +/- 0.0288
Component name: Quercetin hydrate minutes : Drift Times: 7.98 +/- 0.24 ms

0 303.05135

0 5 10 15 20
Retention time [min]

Intensity [Counts]
2e5

100000
304.05450

162.05602 293.08470 507.18883 571.14757 765.18857 869.23298


0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8130 +/- 0.0288 minutes :
Component name: Quercetin_2 Drift Times: 8.14 +/- 0.24 ms

303.05080

100000

Intensity [Counts]
611.16128 743.20354
50000 465.10384
901.17523
304.05402
279.10488
0
200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 6.8130 +/- 0.0288 minutes :
Component name: Quercetin_2 Drift Times: 7.98 +/- 0.24 ms

303.05135

Intensity [Counts]
2e5

100000
304.05450

162.05602 293.08470 507.18883 571.14757 765.18857 869.23298


0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-β-D-xylopyranosyl (12)-β-D-glucopyranoside
[+H] : (39.7 PPM) 597.1445 : DT=7.80 to 8.28 ms

1250 Quercetin-3-O-β-D-xylopyranosyl (12)-β-D-glucopyranoside


6.82

1000
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8130 +/-
Channel name: Quercetin-3-O-β-D-xylopyranosyl (12)-β-D-glucopyranoside Component name: Quercetin-3-O-β-D- 0.0288 minutes : Drift Times: 8.04 +/- 0.24 ms
[+H] : (39.7 PPM) 597.1445 xylopyranosyl (12)-β-D-glucopyranoside
7.49
303.05080
2500

6.81 8.16

Intensity [Counts]
100000
2000 8.56
Intensity [Counts]

16.67
1500 611.16128 743.20354
50000 465.10384
901.17523
304.05402
1000 279.10488
1.88 5.77 8.95
0
5.19 10.49
200 400 600 800 1000
500 11.58
12.14 Item name: MENGKUDU 1 Channel name: High energy : Time 6.8130 +/-
13.28 Component name: Quercetin-3-O-β-D- 0.0288 minutes : Drift Times: 7.89 +/- 0.24 ms
18.51 xylopyranosyl (12)-β-D-glucopyranoside
0
303.05135
0 5 10 15 20
Retention time [min]

Intensity [Counts]
2e5

100000
304.05450
162.05602 293.08470 507.18883 571.14757 765.18857 869.23298
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-7-O-rutinoside [+H] : (39.7 PPM) 611.1613 : DT=7.79 to
8.27 ms
Quercetin-7-O-rutinoside
6.81
6000
Intensity [Counts]

4000

2000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8133 +/-
Channel name: Quercetin-7-O-rutinoside [+H] : (39.7 PPM) 611.1613 Component name: Quercetin-7-O-rutinoside 0.0288 minutes : Drift Times: 8.03 +/- 0.24 ms
7.28
303.05080
20000

100000

Intensity [Counts]
15000
Intensity [Counts]

6.81
611.16128 743.20354
50000 465.10384
10000 901.17523
304.05402
279.10488
0
5000 200 400 600 800 1000

5.61 Item name: MENGKUDU 1 Channel name: High energy : Time 6.8133 +/-
1.88 7.87 9.52 11.81 Component name: Quercetin-7-O-rutinoside 0.0288 minutes : Drift Times: 7.88 +/- 0.24 ms
5.05 18.16
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
2e5
O O
O
O O O

O O O

O O
O O O
O
O

100000
303.05135
Mass error: 1.4 mDa 869.23298
162.05602 293.08470 765.18857
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: quercetin 3-glucoside [+H] : (39.7 PPM) 465.1038 : DT=6.86 to 7.34
ms

12500

10000
Intensity [Counts]

7500

5000

2500 quercetin 3-glucoside


6.80

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8137 +/- 0.0288
Channel name: quercetin 3-glucoside [+H] : (39.7 PPM) 465.1038 Component name: quercetin 3-glucoside minutes : Drift Times: 7.05 +/- 0.24 ms
20000 7.27
303.05079

30000

Intensity [Counts]
15000
601.16235
20000
Intensity [Counts]

6.81
611.16141
10000 465.10385
10000
671.24844
297.04382
829.23487 959.27618
0
5000 200 400 600 800 1000
7.57
3.38 Item name: MENGKUDU 1 Channel name: High energy : Time 6.8137 +/- 0.0288
6.41
0.98 8.02 9.89 Component name: quercetin 3-glucoside minutes : Drift Times: 6.90 +/- 0.24 ms
4.94
12.73
0
0 5 10 15 20 C hir al

Retention time [min] 50000 O


O

Intensity [Counts]
O

O
O
O O
O

O O
O

25000
O

292.08282
303.05134
Mass error: 1.4 mDa 671.22275
250.03037
901.17598
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin_2 [+H] : (39.7 PPM) 303.0508 : DT=6.92 to 7.40 ms

40000

30000
Intensity [Counts]

20000

10000
Quercetin_2
6.81

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 6.8139 +/- 0.0288 minutes :
Channel name: Quercetin_2 [+H] : (39.7 PPM) 303.0508 Component name: Quercetin_2 Drift Times: 7.16 +/- 0.24 ms
7.27
303.05079
80000

30000

Intensity [Counts]
60000
20000
Intensity [Counts]

465.10385 611.16141
40000 6.81 10000
622.19473
287.05223
829.23487 959.27618
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 6.8139 +/- 0.0288 minutes :
Component name: Quercetin_2 Drift Times: 7.01 +/- 0.24 ms

0 303.05134

0 5 10 15 20
Retention time [min] 50000

Intensity [Counts] 25000


292.08282
381.09710
250.03037 569.19335 671.22275
901.17598
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1077 : DT=6.74 to
7.22 ms

40000
Intensity [Counts]

30000

20000

10000

Quercetin-3-O-rhamnoside
0 7.19
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.1926 +/-
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1077 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 6.98 +/- 0.24 ms
7.50
8.17 287.05607

100000

Intensity [Counts]
60000
Intensity [Counts]

50000
40000 449.10769
595.16578

7.20 288.05895 587.14039 741.22403 829.22976


206.05348
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 7.1926 +/-
5.61 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 6.82 +/- 0.24 ms
6.41
2.33
0 2e5 287.05670

0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

255.06546 643.25947
288.05994
575.17122 885.14762
779.17307
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1077 : DT=7.82 to
8.30 ms

40000

30000
Intensity [Counts]

20000

Quercetin-3-O-rhamnoside
10000 7.20

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

Quercetin-3-O-rhamnoside
50000 7.20
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.1972 +/-
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1077 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 8.05 +/- 0.24 ms
7.50
8.17 3e5 287.05607

Intensity [Counts]
60000
2e5
595.16578
Intensity [Counts]

741.22403
449.10769
40000 100000

7.20 288.05896 742.22761


257.09786 596.16933
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 7.1972 +/-
5.61 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 7.90 +/- 0.24 ms
6.41
2.33
0
0 5 10 15 20
O

Retention time [min]


O
O

Intensity [Counts]
O

5e5 O
O
O

O
O
O

2.5e5
287.05670
Mass error: 1.7 mDa
206.05430 763.20862 851.15280
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3′-O-glucoside [+H] : (39.7 PPM) 465.1041 : DT=8.02 to
8.50 ms

4000

3000
Intensity [Counts]

2000

1000 Quercetin-3′-O-glucoside
7.27

7.40
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.2710 +/-
Channel name: Quercetin-3′-O-glucoside [+H] : (39.7 PPM) 465.1041 Component name: Quercetin-3′-O-glucoside 0.0288 minutes : Drift Times: 8.26 +/- 0.24 ms
20000 7.27
814.20458

Intensity [Counts]
15000 100000
Intensity [Counts]

6.81 815.20644
50000
10000

465.10415 612.16521 765.25672 845.16700


340.14030 531.13256
0
5000 200 400 600 800 1000
7.57
3.38 6.40 Item name: MENGKUDU 1 Channel name: High energy : Time 7.2710 +/-
0.98 8.02 9.89 Component name: Quercetin-3′-O-glucoside 0.0288 minutes : Drift Times: 8.10 +/- 0.24 ms
4.94
12.73
0 303.05148

0 5 10 15 20
Retention time [min] 40000

Intensity [Counts] 20000 170.06118


814.20769

428.09972 842.16836
652.14896
895.07133
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-7-O-rutinoside [+H] : (39.7 PPM) 611.1615 : DT=9.73 to
10.21 ms
Quercetin-7-O-rutinoside
7.28

1000
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.2758 +/-
Channel name: Quercetin-7-O-rutinoside [+H] : (39.7 PPM) 611.1615 Component name: Quercetin-7-O-rutinoside 0.0288 minutes : Drift Times: 9.99 +/- 0.24 ms
7.28
611.16149
20000

Intensity [Counts]
10000
15000
Intensity [Counts]

6.81
5000 612.16527
10000 303.05093 633.14324 842.16469
561.16022
729.15270
868.12740
0
5000 200 400 600 800 1000

5.61 Item name: MENGKUDU 1 Channel name: High energy : Time 7.2758 +/-
1.88 7.87 9.52 11.81 Component name: Quercetin-7-O-rutinoside 0.0288 minutes : Drift Times: 9.84 +/- 0.24 ms
5.05 18.16
0 303.05133

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
519.02460 633.14208
10000
665.08244 814.20875
205.05051 489.06142 868.12613
749.20011
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin hydrate [+H] : Quercetin_2 [+H] : (39.7 PPM) 303.0509 :
DT=6.94 to 7.42 ms
Quercetin_2
7.28
40000

30000
Intensity [Counts]

20000

10000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.2768 +/- 0.0288
Channel name: Quercetin hydrate [+H] : Quercetin_2 [+H] : (39.7 PPM) 303.0509 Component name: Quercetin hydrate minutes : Drift Times: 7.18 +/- 0.24 ms
7.27
4e5 303.05093
80000

3e5

Intensity [Counts]
60000
2e5
Intensity [Counts]

465.10414
40000 6.81 100000
611.16149
304.05427
297.07829 607.24774 925.24383
679.20115 814.20458
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 7.2768 +/- 0.0288
Component name: Quercetin hydrate minutes : Drift Times: 7.02 +/- 0.24 ms

0 303.05148

0 5 10 15 20
Retention time [min]

Intensity [Counts]
4e5

2e5
304.05511

519.02455 611.16324
229.05164
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1 Channel name: Low energy : Time 7.2768 +/- 0.0288 minutes :
Component name: Quercetin_2 Drift Times: 7.18 +/- 0.24 ms
4e5 303.05093

3e5

Intensity [Counts]
2e5

465.10414
100000
611.16149
304.05427
297.07829 607.24774 925.24383
679.20115 814.20458
0
200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 7.2768 +/- 0.0288 minutes :
Component name: Quercetin_2 Drift Times: 7.02 +/- 0.24 ms

303.05148

Intensity [Counts]
4e5

2e5
304.05511

611.16324
229.05164 519.02455
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin_2 [+H] : (39.7 PPM) 303.0509 : DT=4.31 to 4.79 ms
Quercetin_2
7.28
10000

7500
Intensity [Counts]

5000

2500

7.40

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.2773 +/- 0.0288 minutes :
Channel name: Quercetin_2 [+H] : (39.7 PPM) 303.0509 Component name: Quercetin_2 Drift Times: 4.56 +/- 0.24 ms
7.27
303.05092
80000
75000

Intensity [Counts]
60000
50000
Intensity [Counts]

25000 311.18396
40000 6.81
283.15201
315.08953
585.24412
503.02762
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 7.2773 +/- 0.0288 minutes :
Component name: Quercetin_2 Drift Times: 4.41 +/- 0.24 ms

0 303.05148

0 5 10 15 20 100000
Retention time [min]

Intensity [Counts]
50000

304.05512
170.06118
519.02461 631.12808
161.02206
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-rutinoside_2 [+H] : (39.7 PPM) 611.1615 : DT=6.86 to
7.34 ms
Quercetin-3-O-rutinoside_2
7.28

6000
Intensity [Counts]

4000

2000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.2782 +/-
Channel name: Quercetin-3-O-rutinoside_2 [+H] : (39.7 PPM) 611.1615 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 7.10 +/- 0.24 ms
7.28 rutinoside_2

20000 4e5 303.05093

Intensity [Counts]
15000
Intensity [Counts]

6.81 2e5

465.10414
10000
611.16149
304.05427
297.07829
679.20115 814.20458 963.24217
0
5000 200 400 600 800 1000

5.61 Item name: MENGKUDU 1 Channel name: High energy : Time 7.2782 +/-
1.88 7.87 9.52 11.81 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 6.95 +/- 0.24 ms
5.05 18.16 rutinoside_2
0
303.05148
0 5 10 15 20
5e5
Retention time [min]

Intensity [Counts]
2.5e5

304.05511 465.10502
227.03672 611.16324 739.21519
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin_2 [+H] : (39.7 PPM) 303.0509 : DT=5.81 to 6.29 ms
Quercetin_2
5000 7.28

4000
Intensity [Counts]

3000

2000

1000 7.39

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.2800 +/- 0.0288 minutes :
Channel name: Quercetin_2 [+H] : (39.7 PPM) 303.0509 Component name: Quercetin_2 Drift Times: 6.05 +/- 0.24 ms
7.27
457.24191
80000 75000

Intensity [Counts]
303.05092
60000 50000
Intensity [Counts]

25000
40000 6.81 465.10415
297.07835
507.18596 814.20469 909.27812
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 7.2800 +/- 0.0288 minutes :
Component name: Quercetin_2 Drift Times: 5.90 +/- 0.24 ms

0 303.05134

0 5 10 15 20
Retention time [min]

Intensity [Counts]
40000

20000
163.03907 458.24279
649.11365
483.11058
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-7-O-rutinoside [+H] : (39.7 PPM) 611.1615 : DT=10.83 to
11.32 ms
Quercetin-7-O-rutinoside
7.28

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.2839 +/-
Channel name: Quercetin-7-O-rutinoside [+H] : (39.7 PPM) 611.1615 Component name: Quercetin-7-O-rutinoside 0.0288 minutes : Drift Times: 11.07 +/- 0.24 ms
7.28
611.16148
20000

5000

Intensity [Counts]
15000
Intensity [Counts]

6.81
2500
10000 561.15957

0
5000 200 400 600 800 1000

5.61 Item name: MENGKUDU 1 Channel name: High energy : Time 7.2839 +/-
1.88 7.87 9.52 11.81 Component name: Quercetin-7-O-rutinoside 0.0288 minutes : Drift Times: 10.92 +/- 0.24 ms
5.05 18.16
0 303.05136

0 5 10 15 20 15000
Retention time [min]

Intensity [Counts]
10000

5000
465.10491 814.20890
633.14221
901.17183
665.08249
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: quercetin 3-glucoside [+H] : (39.7 PPM) 465.1041 : DT=5.77 to 6.25
ms

quercetin 3-glucoside
7.28

750
Intensity [Counts]

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.2869 +/- 0.0288
Channel name: quercetin 3-glucoside [+H] : (39.7 PPM) 465.1041 Component name: quercetin 3-glucoside minutes : Drift Times: 6.02 +/- 0.24 ms
20000 7.27
457.24191
75000

Intensity [Counts]
15000 303.05092
50000
Intensity [Counts]

6.81
10000 25000
465.10415
297.07835 561.16012
631.12663 842.16507
0
5000 200 400 600 800 1000
7.57
3.38 6.40 Item name: MENGKUDU 1 Channel name: High energy : Time 7.2869 +/- 0.0288
0.98 8.02 9.89 Component name: quercetin 3-glucoside minutes : Drift Times: 5.87 +/- 0.24 ms
4.94
12.73
0 303.05134

0 5 10 15 20
Retention time [min]

Intensity [Counts]
40000

20000
163.03907
483.11058
649.11365
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin_2 [+H] : (39.7 PPM) 303.0516 : DT=5.75 to 6.23 ms
7.28
5000

4000
Intensity [Counts]

3000

2000

Quercetin_2
1000 7.39

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61
Quercetin_2
0 7.38
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.4040 +/- 0.0288 minutes :
Channel name: Quercetin_2 [+H] : (39.7 PPM) 303.0516 Component name: Quercetin_2 Drift Times: 5.99 +/- 0.24 ms
7.27
391.15013
80000

50000

Intensity [Counts]
60000
455.22428
Intensity [Counts]

25000

40000 6.81
489.24456
353.09342
814.20378
526.19026
303.05157 682.22398 841.19653
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 7.4040 +/- 0.0288 minutes :
Component name: Quercetin_2 Drift Times: 5.84 +/- 0.24 ms

0 391.15091

0 5 10 15 20
40000
Retention time [min]

Intensity [Counts]
20000
392.15490
205.04984
455.22411
188.07175 501.18935
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1081 : DT=7.71 to
8.20 ms

Quercetin-3-O-rhamnoside
7.50

30000
Intensity [Counts]

20000

10000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Quercetin-3-O-rhamnoside
7.50
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.4966 +/-
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1081 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 7.96 +/- 0.24 ms
7.50
8.17 287.05590

Intensity [Counts]
60000 1e6
Intensity [Counts]

5e5 449.10806 595.16564


40000 727.20859
288.05933
7.20 433.11265 581.15021 597.17147 749.18966
279.10738
781.12797
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 7.4966 +/-
5.61 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 7.80 +/- 0.24 ms
6.41
2.32
0
3e6
0 5 10 15 20
O

Retention time [min]


O
O

Intensity [Counts]
O

O
O O

2e6 O
O

1e6
287.05621
Mass error: 1.2 mDa
241.05145 749.19346
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1081 : DT=6.69 to
7.17 ms

40000

30000
Intensity [Counts]

20000

10000
Quercetin-3-O-rhamnoside
7.50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.4996 +/-
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1081 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 6.94 +/- 0.24 ms
7.50
4e5 287.05590
8.17

3e5

Intensity [Counts]
60000

2e5
Intensity [Counts]

40000 449.10805
100000
288.05933 595.16562
7.20 643.25808
874.29356
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 7.4996 +/-
5.61 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 6.78 +/- 0.24 ms
6.41
2.32
0
0 5 10 15 20
O

Retention time [min]


O
O

Intensity [Counts]
5e5
O

O
O O

O
O
O

2.5e5

258.05093 287.05621
Mass error: 1.2 mDa
765.16070 863.12684
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Isorhamnetin [+H] : (39.7 PPM) 317.0650 : DT=7.93 to 8.41 ms

Isorhamnetin
7.72

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.7169 +/- 0.0288
Channel name: Isorhamnetin [+H] : (39.7 PPM) 317.0650 Component name: Isorhamnetin minutes : Drift Times: 8.17 +/- 0.24 ms
8.48
15000 287.05666 826.16857
3000

798.18313

Intensity [Counts]
10000 595.16726
715.20446
7.72
Intensity [Counts]

2000 317.06503 845.29245


6.42
5000 945.39939
441.13084

1000 0
1.98 200 400 600 800 1000
3.66 5.04 8.56
1.81
8.59 11.76 Item name: MENGKUDU 1 Channel name: High energy : Time 7.7169 +/- 0.0288
14.72 Component name: Isorhamnetin minutes : Drift Times: 8.02 +/- 0.24 ms
15.06
0 317.06181 447.16446
10000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
319.09424
139.04018
5000 808.15469
507.26611
216.97922 634.13117
811.32897
885.16607

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1096 : DT=6.78 to
7.26 ms

40000
Intensity [Counts]

30000

20000

10000

Quercetin-3-O-rhamnoside
0 7.73
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61
Quercetin-3-O-rhamnoside
0 7.73
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.7342 +/-
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1096 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 7.01 +/- 0.24 ms
7.50
8.17 287.05665
100000

Intensity [Counts]
60000
Intensity [Counts]

50000

40000 599.25190
449.10960
288.06005
7.20 656.18280
251.07211
945.40009
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 7.7342 +/-
5.61 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 6.86 +/- 0.24 ms
6.41
2.33
0 287.05718

0 5 10 15 20
1.5e5
Retention time [min]

Intensity [Counts]
100000

50000
288.06035 647.24630
211.00607 560.14541 861.14962
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside [+H] : (39.7 PPM)
757.2191 : DT=7.82 to 8.30 ms

2000

1500
Intensity [Counts]

1000

7.25 7.90
500
7.13 Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinos…
7.75

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 7.7422 +/-
Channel name: Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside [+H] : (39.7 PPM) Component name: Quercetin-3-O-(2G-α-L- 0.0288 minutes : Drift Times: 8.06 +/- 0.24 ms
757.2191 rhamnosyl)-rutinoside
5.61
15000 287.05666
4000

Intensity [Counts]
10000 595.16726 729.20634
3000
818.23903
Intensity [Counts]

317.06503

5000 581.15247 825.29688


2000 441.13084 921.24809
5.05
5.93 0
4.76 7.74 10.04
200 400 600 800 1000
1000 7.90
1.41 10.22
4.65 Item name: MENGKUDU 1 Channel name: High energy : Time 7.7422 +/-
11.48 16.53
Component name: Quercetin-3-O-(2G-α-L- 0.0288 minutes : Drift Times: 7.90 +/- 0.24 ms
13.51
17.67 rhamnosyl)-rutinoside
0
287.05710
0 5 10 15 20 40000
Retention time [min]

Intensity [Counts]
20000
317.06181

211.00627 319.09424 507.26611


840.21758
161.02314 567.15153 755.24369
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1085 : DT=5.51 to
5.99 ms

600
Quercetin-3-O-rhamnoside
8.15

8.20

400
Intensity [Counts]

8.37

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 8.1631 +/-
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1085 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 5.76 +/- 0.24 ms
7.50
8.17 287.05644

3e5

Intensity [Counts]
60000

2e5
Intensity [Counts]

40000
100000

7.20 288.05992 449.10851


821.22018
749.38234
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 8.1631 +/-
5.61 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 5.61 +/- 0.24 ms
6.41
2.32
0 287.05669

0 5 10 15 20 3e5
Retention time [min]

Intensity [Counts]
2e5

100000
487.21844
288.06024
241.04929 505.03147
382.02420 748.88084
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1085 : DT=6.75 to
7.23 ms
Quercetin-3-O-rhamnoside
8.17

40000
Intensity [Counts]

30000

20000

10000

8.32
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Quercetin-3-O-rhamnoside
Channel name: Identified Components
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 8.1761 +/-
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1085 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 7.00 +/- 0.24 ms
7.50
8.17 287.05644

1.5e6

Intensity [Counts]
60000

1e6
Intensity [Counts]

40000 449.10849
5e5

7.20 288.05992 595.16682


769.22848
129.05348 586.24701 675.28349
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 8.1761 +/-
5.61 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 6.84 +/- 0.24 ms
6.41
2.32
0
0 5 10 15 20
O

Retention time [min]


O
O

Intensity [Counts]
O

2e6 O
O
O

O
O
O

1e6
287.05669
Mass error: 1.7 mDa
675.27599
213.05605
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1085 : DT=9.34 to
9.82 ms

1500 Quercetin-3-O-rhamnoside
8.17

1000
Intensity [Counts]

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 8.1770 +/-
Channel name: Quercetin-3-O-rhamnoside [+H] : (39.7 PPM) 449.1085 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 9.60 +/- 0.24 ms
7.50
8.17 595.16682
100000

Intensity [Counts]
60000
Intensity [Counts]

50000
40000 287.05643 596.17096
449.10849
7.20 649.08654
467.31495 934.12902
288.05993 683.39909
0
20000 200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 8.1770 +/-
5.61 Component name: Quercetin-3-O-rhamnoside 0.0288 minutes : Drift Times: 9.45 +/- 0.24 ms
6.41
2.32
0
0 5 10 15 20
O

Retention time [min]


O
O

2e5

Intensity [Counts]
O

O
O O

O
O
O

100000
287.05670
Mass error: 1.7 mDa
205.04992 867.43147
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: 3-O-Methylquercetin [+H] : Isorhamnetin [+H] : (39.7 PPM)
317.0664 : DT=6.88 to 7.36 ms
Isorhamnetin
8.48
1250

1000
Intensity [Counts]

750

500

250
8.55

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 8.4794 +/- 0.0288
Channel name: 3-O-Methylquercetin [+H] : Isorhamnetin [+H] : (39.7 PPM) Component name: 3-O-Methylquercetin minutes : Drift Times: 7.13 +/- 0.24 ms
317.0664
8.48 503.24929

3000
20000

Intensity [Counts]
584.24232
7.72 317.06637
Intensity [Counts]

2000 608.38663
6.42 10000
479.11573 856.20298
655.14533
302.09904 883.16312
225.07719
1000 0
1.98 200 400 600 800 1000
5.04
3.68 8.59
1.83 11.76 Item name: MENGKUDU 1 Channel name: High energy : Time 8.4794 +/- 0.0288
9.32 8.64 Component name: 3-O-Methylquercetin minutes : Drift Times: 6.98 +/- 0.24 ms
14.72
11.88
15.06
0 20000 147.04439 317.06713

0 5 10 15 20
Retention time [min]

Intensity [Counts]
557.17049
10000
721.10858
292.07019 584.23755
415.15151
848.21593

867.19245
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1 Channel name: Low energy : Time 8.4794 +/- 0.0288
Component name: Isorhamnetin minutes : Drift Times: 7.13 +/- 0.24 ms

503.24929

20000

Intensity [Counts]
584.24232
317.06637
608.38663
10000
479.11573 856.20298
655.14533
302.09904 883.16312
225.07719
0
200 400 600 800 1000
Item name: MENGKUDU 1 Channel name: High energy : Time 8.4794 +/- 0.0288
Component name: Isorhamnetin minutes : Drift Times: 6.98 +/- 0.24 ms

20000 147.04439 317.06713

Intensity [Counts]
557.17049
10000
721.10858
292.07019 584.23755
415.15151
848.21593

867.19245
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Isorhamnetin [+H] : (39.7 PPM) 317.0664 : DT=4.51 to 4.99 ms

Isorhamnetin
8.48

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 8.4819 +/- 0.0288
Channel name: Isorhamnetin [+H] : (39.7 PPM) 317.0664 Component name: Isorhamnetin minutes : Drift Times: 4.79 +/- 0.24 ms
8.48
327.17696
15000
3000

Intensity [Counts]
10000 248.12750
339.17581
7.72
Intensity [Counts]

2000
6.42
5000
522.72173
558.17196
686.23086
1000 0
1.98
5.04 200 400 600 800 1000
3.68 8.59
1.83 Item name: MENGKUDU 1 Channel name: High energy : Time 8.4819 +/- 0.0288
11.76
8.64 14.72 Component name: Isorhamnetin minutes : Drift Times: 4.64 +/- 0.24 ms
11.88
15.06
0 317.06679
292.17838
0 5 10 15 20
5000
Retention time [min]

Intensity [Counts]
265.08046
327.17931
194.07996 345.12753 571.14729
2500 541.21479
391.14069

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin-3-O-arabinofuranoside [+H] : (39.7 PPM) 435.0907 :
DT=5.49 to 5.97 ms

1250

1000
Quercetin-3-O-arabinofuranoside
Intensity [Counts]

10.04
750

500 9.98

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 10.0385 +/-
Channel name: Quercetin-3-O-arabinofuranoside [+H] : (39.7 PPM) 435.0907 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 5.73 +/- 0.24 ms
4.61 arabinofuranoside
5000
418.16132
0.97
30000
4000

Intensity [Counts]
4.69 450.18808
20000
Intensity [Counts]

3000 361.17583

2.85 10000 453.20846


2000 239.07193 663.16941 814.24255
455.22268

0
4.85
3.71 10.04 200 400 600 800 1000
1000 6.83
Item name: MENGKUDU 1 Channel name: High energy : Time 10.0385 +/-
2.08 5.59 9.98
10.37 Component name: Quercetin-3-O- 0.0288 minutes : Drift Times: 5.58 +/- 0.24 ms
13.87 14.82
14.93 arabinofuranoside
0
188.07183
0 5 10 15 20 20000
Retention time [min]

Intensity [Counts]
288.12627

10000 418.16233

435.16407
605.17027 734.13684
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl [+H] : (39.7 PPM)
697.1597 : DT=7.38 to 7.86 ms

1500
Intensity [Counts]

1000

500
10.65

Quercetin 3-O-2-O-a-rhamnosyl-6-…
10.58
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61
Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl
0 10.61
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 10.6016 +/-
Channel name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl [+H] : (39.7 PPM) Component name: Quercetin 3-O-2-O-a- 0.0288 minutes : Drift Times: 7.62 +/- 0.24 ms
697.1597 rhamnosyl-6-O-malonyl
7.87
603.28195
2500
30000

Intensity [Counts]
4.56
2000
399.14753
20000
Intensity [Counts]

675.19145
1500 5.29
10000 686.31712
248.09071 570.25755
9.53 728.30858
1.81 3.58 7.72
1000 220.09602
9.59 0
1.27 7.14 13.12 200 400 600 800 1000
10.62
13.15
500 Item name: MENGKUDU 1 Channel name: High energy : Time 10.6016 +/-
14.34 Component name: Quercetin 3-O-2-O-a- 0.0288 minutes : Drift Times: 7.46 +/- 0.24 ms
14.7114.84 18.52
rhamnosyl-6-O-malonyl
0
176.07069
0 5 10 15 20
Retention time [min] 7500

Intensity [Counts]
248.09198
5000
399.14679 625.25273
586.26589 830.29199
2500 569.18397
852.15554

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 1
Channel name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl [+H] : (39.7 PPM)
697.1606 : DT=7.85 to 8.33 ms

300
Intensity [Counts]

200

Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl
10.66

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1
Channel name: Identified Components Quercetin-3-O-rhamnoside
8.17

2.5e5 Quercetin hydrate


7.28

2e5
Intensity [Counts]

1.5e5
Quercetin hydrate
6.81
100000

50000
Quercimeritrin
8.61
Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl
0 10.64
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 1 Item name: MENGKUDU 1 Channel name: Low energy : Time 10.6607 +/-
Channel name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl [+H] : (39.7 PPM) Component name: Quercetin 3-O-2-O-a- 0.0288 minutes : Drift Times: 8.09 +/- 0.24 ms
697.1606 rhamnosyl-6-O-malonyl
7.87
747.32390
30000
2500

Intensity [Counts]
4.56
2000 20000
Intensity [Counts]

765.33138
1500 5.29 10000 727.38647
383.17520 821.32011
707.05124
9.53 318.13468
1.81 3.58 481.22058 826.23835
1000 7.72
9.59 0
1.27 7.14 13.12
10.62 200 400 600 800 1000
13.15
500 Item name: MENGKUDU 1 Channel name: High energy : Time 10.6607 +/-
14.34 Component name: Quercetin 3-O-2-O-a- 0.0288 minutes : Drift Times: 7.93 +/- 0.24 ms
14.71 15.03
rhamnosyl-6-O-malonyl
0
747.32696
0 5 10 15 20
Retention time [min] 10000

Intensity [Counts]
370.13016
829.29362
5000
336.13998
586.26436
167.06991 832.31700
567.25595 657.27426
843.23130
0
200 400 600 800 1000
Observed mass [m/z]
Frgmenton (high energy)

Item name: MENGKUDU 1, Component name: 3-O-Methylquercetin


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 147.04406 Theoretical 147.04439 0.3 2.271 1434 8.49276 6.74968 C9H7O2

O O
O
O
O
O
O

Item name: MENGKUDU 1, Component name: 3-O-β-D-Galacopyanosyl quercetin


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 109.02841 Theoretical 109.02821 -0.2 -1.757 291 1.82061 5.78161 C6H5O2

O
O
H
O O
O
O O O
O O O

2 123.04406 Theoretical 123.04465 0.6 4.811 259 1.85917 5.87773 C7H7O2

O
O
H
O O
O
O O O
O O O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 155.03389 Theoretical 155.03458 0.7 4.454 201 1.84023 5.62597 C7H7O4

O
O
H
O O
O
O O O
O O O

4 165.01824 Theoretical 165.01947 1.2 7.478 164 1.80905 5.67291 C8H5O4

O
O
H
O O
O
O O O
O O O

5 183.02880 Theoretical 183.02869 -0.1 -0.593 714 1.82346 5.47903 C8H7O5

O
O
H
O O
O
O O O
O O O

6 197.08084 Theoretical 197.08133 0.5 2.529 155 1.81078 5.71228 C10H13O4

O
O
H
O O
O
O O O
O O O

O
Item name: MENGKUDU 1, Component name: Isorhamnetin
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 182.05736 Theoretical 182.05792 0.6 3.073 111 8.49718 4.70308 C9H10O4

O
O

O O

O
O O

Item name: MENGKUDU 1, Component name: Isorhamnetin


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 147.04406 Theoretical 147.04395 -0.1 -0.705 230 6.81869 5.51910 C9H7O2

O
O

O O

O
O O

2 265.04954 Theoretical 265.05039 0.9 3.209 158 6.80916 5.19029 C16H9O4

O
O

O O

O
O O
Item name: MENGKUDU 1, Component name: Isorhamnetin
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 139.03897 Theoretical 139.04018 1.2 8.674 303 7.70205 8.20785 C7H7O3

O
O

O O

O
O O

2 181.04954 Theoretical 181.04894 -0.6 -3.303 91 7.70312 7.92822 C9H9O4

O
O

O O

O
O O

Item name: MENGKUDU 1, Component name: Isorhamnetin


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 147.04406 Theoretical 147.04439 0.3 2.271 1434 8.49276 6.74968 C9H7O2

O
O

O O

O
O O
Item name: MENGKUDU 1, Component name: quercetin 3-glucoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 139.03897 Theoretical 139.03825 -0.7 -5.219 92 6.79525 6.93411 C7H7O3
C hiral

O
O

O O

O
O O O
O

O
O O

2 161.02332 Theoretical 161.02155 -1.8 -11.000 142 6.82218 6.97559 C9H5O3


C hiral

O
O

O O

O
O O O
O

O
O O

3 222.07340 Theoretical 222.07436 1.0 4.285 156 6.78836 7.11616 C8H14O7


C hiral

O
O

O O

O
O O O
O

O
O O

4 223.06010 Theoretical 223.05893 -1.2 -5.231 124 6.81908 6.97332 C11H11O5


C hiral

O
O

O O

O
O O O
O

O
O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 303.04993 Theoretical 303.05134 1.4 4.667 8311 6.80902 6.83511 C15H11O7
C hiral

O
O

O O

O
O O O
O

O
O O

6 315.04993 Theoretical 315.05106 1.1 3.576 202 6.81663 6.65584 C16H11O7


C hiral

O
O

O O

O
O O O
O

O
O O

7 345.06049 Theoretical 345.06211 1.6 4.695 215 6.80713 6.93942 C17H13O8


C hiral

O
O

O O

O
O O O
O

O
O O

8 403.10236 Theoretical 403.10131 -1.0 -2.601 128 6.83081 6.93438 C20H19O9


C hiral

O
O

O O

O
O O O
O

O
O O
Item name: MENGKUDU 1, Component name: quercetin 3-glucoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 163.03897 Theoretical 163.03907 0.1 0.586 417 7.30740 5.79869 C9H7O3
C hiral

O
O

O O

O
O O O
O

O
O O

2 249.06049 Theoretical 249.05973 -0.8 -3.058 134 7.30229 5.73767 C9H13O8


C hiral

O
O

O O

O
O O O
O

O
O O

3 303.04993 Theoretical 303.05134 1.4 4.664 7788 7.27743 5.76641 C15H11O7


C hiral

O
O

O O

O
O O O
O

O
O O

4 399.10744 Theoretical 399.10678 -0.7 -1.668 870 7.29332 5.77110 C21H19O8


C hiral

O
O

O O

O
O O O
O

O
O O
Item name: MENGKUDU 1, Component name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 161.02332 Theoretical 161.02502 1.7 10.578 134 5.27302 7.42584 C9H5O3
Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O

2 207.02880 Theoretical 207.03043 1.6 7.863 249 5.27662 7.52947 C10H7O5


Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O

3 224.08905 Theoretical 224.09072 1.7 7.428 166 5.24743 7.50243 C8H16O7


Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O

4 239.05501 Theoretical 239.05515 0.1 0.552 114 5.26242 7.67839 C11H11O6


Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 274.06832 Theoretical 274.06894 0.6 2.261 163 5.28725 7.37090 C11H14O8
Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O

6 363.03467 Theoretical 363.03559 0.9 2.515 865 5.25936 7.26383 C16H11O10


Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O

Item name: MENGKUDU 1, Component name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 336.14148 Theoretical 336.13998 -1.5 -4.470 439 10.68624 7.88274 C14H24O9
Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O
Item name: MENGKUDU 1, Component name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 239.05501 Theoretical 239.05579 0.8 3.233 255 1.40618 6.92163 C11H11O6
Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O

2 531.13445 Theoretical 531.13486 0.4 0.774 153 1.36495 7.12210 C22H27O15


Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O

Item name: MENGKUDU 1, Component name: Quercetin 3-O-2-O-a-rhamnosyl-6-O-malonyl


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 207.02880 Theoretical 207.02708 -1.7 -8.310 195 10.62029 7.30618 C10H7O5
Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 236.08905 Theoretical 236.08887 -0.2 -0.780 131 10.60583 7.69258 C9H16O7
Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O

3 354.15205 Theoretical 354.15324 1.2 3.377 304 10.60486 7.62109 C14H26O10


Ch iral

O
O

O O

O O
O O O O
O
O O O
O O
O O O

Item name: MENGKUDU 1, Component name: quercetin 3-O-a-L-arabinoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 222.07340 Theoretical 222.07265 -0.8 -3.408 124 6.01474 5.37976 C8H14O7
C hiral

O O
O

O OO
O O O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 253.07066 Theoretical 253.07012 -0.5 -2.136 165 6.02278 5.52422 C12H13O6
C hiral

O O
O

O OO
O O O

3 343.08123 Theoretical 343.08196 0.7 2.125 162 6.00813 5.30014 C18H15O7


C hiral

O O
O

O OO
O O O

Item name: MENGKUDU 1, Component name: quercetin 3-O-a-L-arabinoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 194.07849 Theoretical 194.07945 1.0 4.955 134 5.51040 5.22544 C7H14O6
C hiral

O O
O

O OO
O O O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 409.11292 Theoretical 409.11356 0.6 1.553 990 5.53279 5.41629 C19H21O10
C hiral

O O
O

O OO
O O O

3 424.10001 Theoretical 424.10010 0.1 0.203 462 5.54776 5.48234 C19H20O11


C hiral

O O
O

O OO
O O O

Item name: MENGKUDU 1, Component name: quercetin 3-O-a-L-arabinoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 176.06792 Theoretical 176.06951 1.6 9.027 208 5.54103 5.90998 C7H12O5
C hiral

O O
O

O OO
O O O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 191.03389 Theoretical 191.03207 -1.8 -9.506 123 5.52440 5.83639 C10H7O4
C hiral

O O
O

O OO
O O O

Item name: MENGKUDU 1, Component name: Quercetin hydrate


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 285.03936 Theoretical 285.03840 -1.0 -3.369 135 6.79899 7.85554 C15H9O6

O O
O

O
O
O
O

Item name: MENGKUDU 1, Component name: Quercetin hydrate


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 165.01824 Theoretical 165.01995 1.7 10.411 170 7.28674 7.13863 C8H5O4

O O
O

O
O
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 285.03936 Theoretical 285.04021 0.8 2.967 314 7.28312 6.95325 C15H9O6

O O
O

O
O
O
O

Item name: MENGKUDU 1, Component name: Quercetin_2


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 139.03897 Theoretical 139.03825 -0.7 -5.219 92 6.79525 6.93411 C7H7O3

O O
O

O
O O

2 161.02332 Theoretical 161.02155 -1.8 -11.000 142 6.82218 6.97559 C9H5O3

O O
O

O
O O
Item name: MENGKUDU 1, Component name: Quercetin_2
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 149.05971 Theoretical 149.06007 0.4 2.433 79 6.80924 5.79584 C9H9O2

O O
O

O
O O

Item name: MENGKUDU 1, Component name: Quercetin_2


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 163.03897 Theoretical 163.03907 0.1 0.586 417 7.30740 5.79869 C9H7O3

O O
O

O
O O

Item name: MENGKUDU 1, Component name: Quercetin_2


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 161.02332 Theoretical 161.02206 -1.3 -7.847 119 7.25702 4.17373 C9H5O3

O O
O

O
O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 285.03936 Theoretical 285.04079 1.4 4.991 230 7.27555 4.41905 C15H9O6

O O
O

O
O O

Item name: MENGKUDU 1, Component name: Quercetin_2


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 285.03936 Theoretical 285.03840 -1.0 -3.369 135 6.79899 7.85554 C15H9O6

O O
O

O
O O

Item name: MENGKUDU 1, Component name: Quercetin_2


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 165.01824 Theoretical 165.01995 1.7 10.411 170 7.28674 7.13863 C8H5O4

O O
O

O
O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 285.03936 Theoretical 285.04021 0.8 2.967 314 7.28312 6.95325 C15H9O6

O O
O

O
O O

Item name: MENGKUDU 1, Component name: Quercetin-3′-O-glucoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 285.03936 Theoretical 285.03840 -1.0 -3.369 135 6.79899 7.85554 C15H9O6
O O
O

O O
O
O
O O
O
O
O

2 303.04993 Theoretical 303.05135 1.4 4.682 36265 6.81185 7.84707 C15H11O7


O O
O

O O
O
O
O O
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 315.04993 Theoretical 315.05092 1.0 3.139 261 6.79282 7.99195 C16H11O7
O O
O

O O
O
O
O O
O
O
O

Item name: MENGKUDU 1, Component name: Quercetin-3′-O-glucoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 145.02841 Theoretical 145.02935 0.9 6.518 140 7.28534 8.22113 C9H5O2
O O
O

O O
O
O
O O
O
O
O

2 223.06010 Theoretical 223.05848 -1.6 -7.278 384 7.28573 8.32226 C11H11O5


O O
O

O O
O
O
O O
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 303.04993 Theoretical 303.05148 1.5 5.106 7103 7.27745 8.16693 C15H11O7
O O
O

O O
O
O
O O
O
O
O

Item name: MENGKUDU 1, Component name: Quercetin-3′-O-glucoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 149.05971 Theoretical 149.06007 0.4 2.433 79 6.80924 5.79584 C9H9O2
O O
O

O O
O
O
O O
O
O
O

2 191.03389 Theoretical 191.03222 -1.7 -8.717 93 6.78821 6.17763 C10H7O4


O O
O

O O
O
O
O O
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 303.04993 Theoretical 303.05136 1.4 4.721 2326 6.81461 5.87599 C15H11O7
O O
O

O O
O
O
O O
O
O
O

4 315.10744 Theoretical 315.10843 1.0 3.125 116 6.80396 6.18158 C14H19O8


O O
O

O O
O
O
O O
O
O
O

5 329.06558 Theoretical 329.06454 -1.0 -3.155 116 6.81218 5.95034 C17H13O7


O O
O

O O
O
O
O O
O
O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 161.02332 Theoretical 161.02460 1.3 7.952 193 5.07367 8.83960 C9H5O3

O O
O O O O
O O
O O O O
O
O
O O O

O O

2 278.00572 Theoretical 278.00445 -1.3 -4.569 109 5.03916 8.82321 C12H6O8

O O
O O O O
O O
O O O O
O
O
O O O

O O

3 287.05501 Theoretical 287.05639 1.4 4.797 1391 5.05451 8.89299 C15H11O6

O O
O O O O
O O
O O O O
O
O
O O O

O O

4 449.10784 Theoretical 449.10947 1.6 3.633 667 5.05777 8.96779 C21H21O11

O O
O O O O
O O
O O O O
O
O
O O O

O O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 239.05501 Theoretical 239.05550 0.5 2.038 126 5.03836 7.72595 C11H11O6

O O
O O O O
O O
O O O O
O
O
O O O

O O

2 287.05501 Theoretical 287.05630 1.3 4.472 312 5.05258 7.83069 C15H11O6

O O
O O O O
O O
O O O O
O
O
O O O

O O

3 340.11527 Theoretical 340.11330 -2.0 -5.787 368 5.08198 7.76546 C16H20O8

O O
O O O O
O O
O O O O
O
O
O O O

O O

4 346.08945 Theoretical 346.09129 1.8 5.307 7113 5.04990 7.89902 C14H18O10

O O
O O O O
O O
O O O O
O
O
O O O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 366.11566 Theoretical 366.11614 0.5 1.307 202 5.05142 7.89974 C14H22O11

O O
O O O O
O O
O O O O
O
O
O O O

O O

6 499.10823 Theoretical 499.10779 -0.4 -0.877 420 5.04290 7.81369 C21H23O14

O O
O O O O
O O
O O O O
O
O
O O O

O O

Item name: MENGKUDU 1, Component name: Quercetin-3-O-(2G-α-L-rhamnosyl)-rutinoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 161.02332 Theoretical 161.02314 -0.2 -1.143 83 7.76406 8.06182 C9H5O3

O O
O O O O
O O
O O O O
O
O
O O O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 274.10470 Theoretical 274.10396 -0.7 -2.716 190 7.73758 7.75887 C12H18O7

O O
O O O O
O O
O O O O
O
O
O O O

O O

3 423.11332 Theoretical 423.11378 0.5 1.085 580 7.74223 8.04303 C16H23O13

O O
O O O O
O O
O O O O
O
O
O O O

O O

4 521.18648 Theoretical 521.18845 2.0 3.782 225 7.73968 8.13950 C22H33O14

O O
O O O O
O O
O O O O
O
O
O O O

O O

5 535.14462 Theoretical 535.14609 1.5 2.747 201 7.71481 7.97148 C25H27O13

O O
O O O O
O O
O O O O
O
O
O O O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
6 581.15010 Theoretical 581.15072 0.6 1.081 176 7.75067 8.12950 C26H29O15

O O
O O O O
O O
O O O O
O
O
O O O

O O

Item name: MENGKUDU 1, Component name: Quercetin-3-O-arabinofuranoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 163.03897 Theoretical 163.03893 0.0 -0.244 99 2.83232 7.81227 C9H7O3
O
O

O
O O O
O

O O

O
O

2 211.06010 Theoretical 211.06014 0.0 0.175 134 2.85123 7.41019 C10H11O5


O
O

O
O O O
O

O O

O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 329.02919 Theoretical 329.02977 0.6 1.740 173 2.84922 7.44311 C16H9O8
O
O

O
O O O
O

O O

O
O

4 344.05267 Theoretical 344.05445 1.8 5.181 125 2.85722 7.45405 C17H12O8


O
O

O
O O O
O

O O

O
O

Item name: MENGKUDU 1, Component name: Quercetin-3-O-arabinofuranoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 145.02841 Theoretical 145.02944 1.0 7.148 508 10.01450 5.58663 C9H5O2
O
O

O
O O O
O

O O

O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 193.04954 Theoretical 193.04880 -0.7 -3.818 108 10.01227 5.36600 C10H9O4
O
O

O
O O O
O

O O

O
O

Item name: MENGKUDU 1, Component name: Quercetin-3-O-arabinofuranoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 147.04406 Theoretical 147.04514 1.1 7.396 331 6.15702 5.37290 C9H7O2
O
O

O
O O O
O

O O

O
O

2 271.08123 Theoretical 271.08162 0.4 1.447 116 6.12281 5.32728 C12H15O7


O
O

O
O O O
O

O O

O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-glucuronide 6″-methylester
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 145.02841 Theoretical 145.02876 0.4 2.430 259 2.56337 6.66326 C9H5O2

O O

O
O O

O O
O
O
O
O O
O

2 151.03897 Theoretical 151.03952 0.6 3.670 286 2.58699 6.56861 C8H7O3

O O

O
O O

O O
O
O
O
O O
O

3 175.02371 Theoretical 175.02338 -0.3 -1.928 210 2.53474 6.41594 C6H7O6

O O

O
O O

O O
O
O
O
O O
O

4 221.04445 Theoretical 221.04322 -1.2 -5.569 739 2.58398 6.60612 C11H9O5

O O

O
O O

O O
O
O
O
O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 239.05501 Theoretical 239.05510 0.1 0.375 341 2.58235 6.50889 C11H11O6

O O

O
O O

O O
O
O
O
O O
O

6 262.06832 Theoretical 262.06687 -1.4 -5.512 104 2.56825 6.50469 C10H14O8

O O

O
O O

O O
O
O
O
O O
O

7 339.10744 Theoretical 339.10740 0.0 -0.129 297 2.54700 6.42128 C16H19O8

O O

O
O O

O O
O
O
O
O O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-glucuronide 6″-methylester
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 161.02332 Theoretical 161.02360 0.3 1.711 1194 2.58945 6.14874 C9H5O3

O O

O
O O

O O
O
O
O
O O
O

2 189.01824 Theoretical 189.01874 0.5 2.684 385 2.57079 6.12408 C10H5O4

O O

O
O O

O O
O
O
O
O O
O

3 221.04445 Theoretical 221.04356 -0.9 -4.025 763 2.55433 6.23289 C11H9O5

O O

O
O O

O O
O
O
O
O O
O

4 459.09219 Theoretical 459.09188 -0.3 -0.681 156 2.60537 5.93650 C22H19O11

O O

O
O O

O O
O
O
O
O O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-glucuronide 6″-methylester
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 97.02841 Theoretical 97.02960 1.2 12.263 153 5.03777 5.81251 C5H5O2

O O

O
O O

O O
O
O
O
O O
O

2 130.06245 Theoretical 130.06403 1.6 12.164 205 5.02137 6.05780 C6H10O3

O O

O
O O

O O
O
O
O
O O
O

3 292.02137 Theoretical 292.02109 -0.3 -0.951 210 4.99654 5.92110 C13H8O8

O O

O
O O

O O
O
O
O
O O
O

4 403.06597 Theoretical 403.06532 -0.7 -1.622 152 5.01289 6.18692 C19H15O10

O O

O
O O

O O
O
O
O
O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 426.05815 Theoretical 426.05997 1.8 4.270 180 5.02407 6.21079 C21H14O10

O O

O
O O

O O
O
O
O
O O
O

Item name: MENGKUDU 1, Component name: Quercetin-3-O-rhamnoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 287.05501 Theoretical 287.05670 1.7 5.858 33681 8.17460 9.54250 C15H11O6
O

O O
O
O
O O
O

O O
O

2 434.12075 Theoretical 434.12153 0.8 1.797 161 8.16324 9.60823 C21H22O10


O

O O
O
O
O O
O

O O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-rhamnoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 162.03115 Theoretical 162.02931 -1.8 -11.355 92 7.74748 6.72415 C9H6O3
O

O O
O
O
O O
O

O O
O

2 193.04954 Theoretical 193.04989 0.4 1.853 228 7.73568 6.68217 C10H9O4


O

O O
O
O
O O
O

O O
O

3 234.07340 Theoretical 234.07346 0.1 0.249 147 7.75916 7.03868 C9H14O7


O

O O
O
O
O O
O

O O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-rhamnoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 153.01824 Theoretical 153.01778 -0.5 -2.989 172 7.20746 7.91353 C7H5O4
O

O O
O
O
O O
O

O O
O

2 165.01824 Theoretical 165.01818 -0.1 -0.358 186 7.19158 7.82763 C8H5O4


O

O O
O
O
O O
O

O O
O

3 287.05501 Theoretical 287.05671 1.7 5.889 91216 7.19925 7.85186 C15H11O6


O

O O
O
O
O O
O

O O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-rhamnoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 165.01824 Theoretical 165.01782 -0.4 -2.543 290 7.48894 6.65294 C8H5O4
O

O O
O
O
O O
O

O O
O

2 258.05227 Theoretical 258.05093 -1.3 -5.229 432 7.49336 6.96994 C14H10O5


O

O O
O
O
O O
O

O O
O

3 287.05501 Theoretical 287.05621 1.2 4.165 87719 7.49704 6.76846 C15H11O6


O

O O
O
O
O O
O

O O
O

4 329.06558 Theoretical 329.06498 -0.6 -1.807 616 7.49433 6.91916 C17H13O7


O

O O
O
O
O O
O

O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 431.09727 Theoretical 431.09592 -1.4 -3.142 329 7.50645 6.93354 C21H19O10
O

O O
O
O
O O
O

O O
O

Item name: MENGKUDU 1, Component name: Quercetin-3-O-rhamnoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 153.01824 Theoretical 153.01895 0.7 4.655 736 8.16798 6.70456 C7H5O4
O

O O
O
O
O O
O

O O
O

2 165.01824 Theoretical 165.01827 0.0 0.200 969 8.17838 6.81963 C8H5O4


O

O O
O
O
O O
O

O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 258.05227 Theoretical 258.05226 0.0 -0.055 1695 8.17784 6.86522 C14H10O5
O

O O
O
O
O O
O

O O
O

4 269.04445 Theoretical 269.04417 -0.3 -1.058 269 8.16709 6.82213 C15H9O5


O

O O
O
O
O O
O

O O
O

5 287.05501 Theoretical 287.05669 1.7 5.840 364143 8.17673 6.84388 C15H11O6


O

O O
O
O
O O
O

O O
O

6 317.06558 Theoretical 317.06385 -1.7 -5.455 436 8.16223 7.00260 C16H13O7


O

O O
O
O
O O
O

O O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-rhamnoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 153.01824 Theoretical 153.01827 0.0 0.248 456 7.50009 7.76440 C7H5O4
O

O O
O
O
O O
O

O O
O

2 165.01824 Theoretical 165.01794 -0.3 -1.800 558 7.48756 7.82999 C8H5O4


O

O O
O
O
O O
O

O O
O

3 225.07575 Theoretical 225.07394 -1.8 -8.034 254 7.50829 7.88401 C11H13O5


O

O O
O
O
O O
O

O O
O

4 258.05227 Theoretical 258.05079 -1.5 -5.763 1135 7.49923 7.73580 C14H10O5


O

O O
O
O
O O
O

O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 269.04445 Theoretical 269.04370 -0.7 -2.773 294 7.48720 7.79892 C15H9O5
O

O O
O
O
O O
O

O O
O

6 287.05501 Theoretical 287.05621 1.2 4.163 405559 7.49744 7.78406 C15H11O6


O

O O
O
O
O O
O

O O
O

7 329.06558 Theoretical 329.06480 -0.8 -2.380 2803 7.49712 7.70184 C17H13O7


O

O O
O
O
O O
O

O O
O

8 383.07614 Theoretical 383.07733 1.2 3.090 1204 7.50919 7.75809 C20H15O8


O

O O
O
O
O O
O

O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
9 397.05541 Theoretical 397.05364 -1.8 -4.449 254 7.51681 7.65594 C20H13O9
O

O O
O
O
O O
O

O O
O

10 419.09727 Theoretical 419.09783 0.6 1.333 2332 7.50176 7.64428 C20H19O10


O

O O
O
O
O O
O

O O
O

11 431.09727 Theoretical 431.09686 -0.4 -0.952 715 7.49293 7.70180 C21H19O10


O

O O
O
O
O O
O

O O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-rhamnoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 183.02880 Theoretical 183.02766 -1.1 -6.219 93 5.63356 8.03742 C8H7O5
O

O O
O
O
O O
O

O O
O

2 239.05501 Theoretical 239.05425 -0.8 -3.184 222 5.59304 8.04100 C11H11O6


O

O O
O
O
O O
O

O O
O

3 287.05501 Theoretical 287.05697 2.0 6.813 4261 5.61103 7.90070 C15H11O6


O

O O
O
O
O O
O

O O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-rhamnoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 255.06519 Theoretical 255.06546 0.3 1.078 323 7.18060 6.69095 C15H11O4
O

O O
O
O
O O
O

O O
O

2 271.06010 Theoretical 271.05866 -1.4 -5.329 122 7.18105 6.80819 C15H11O5


O

O O
O
O
O O
O

O O
O

3 287.05501 Theoretical 287.05671 1.7 5.889 26106 7.19925 6.83885 C15H11O6


O

O O
O
O
O O
O

O O
O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-rhamnoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 258.05227 Theoretical 258.05262 0.3 1.321 439 8.18250 5.53293 C14H10O5
O

O O
O
O
O O
O

O O
O

2 287.05501 Theoretical 287.05669 1.7 5.849 43566 8.17713 5.70058 C15H11O6


O

O O
O
O
O O
O

O O
O

Item name: MENGKUDU 1, Component name: Quercetin-3-O-rutinoside_2


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 153.01824 Theoretical 153.01770 -0.5 -3.502 171 7.27601 6.77782 C7H5O4
O

O O
O
O O
O O O
O
O
O
O O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 165.01824 Theoretical 165.01995 1.7 10.411 170 7.28674 7.13863 C8H5O4
O

O O
O
O O
O O O
O
O
O
O O

O O

3 249.06049 Theoretical 249.06192 1.4 5.720 123 7.27071 6.90032 C9H13O8


O

O O
O
O O
O O O
O
O
O
O O

O O

4 258.07340 Theoretical 258.07446 1.1 4.078 211 7.27967 6.92356 C11H14O7


O

O O
O
O
O
O O O
O
O
O
O O

O O

5 285.03936 Theoretical 285.04021 0.8 2.967 314 7.28312 6.95325 C15H9O6


O

O O
O
O
O
O O O
O
O
O
O O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
6 295.10236 Theoretical 295.10218 -0.2 -0.609 523 7.26587 7.02574 C11H19O9
O

O O
O
O O
O O O
O
O
O
O O

O O

7 303.04993 Theoretical 303.05148 1.5 5.107 72226 7.27770 6.93652 C15H11O7


O

O O
O
O O
O O O
O
O
O
O O

O O

8 331.10236 Theoretical 331.10294 0.6 1.760 477 7.26285 7.13821 C14H19O9


O

O O
O
O
O
O O O
O
O
O
O O

O O

9 386.12075 Theoretical 386.12210 1.4 3.505 192 7.30471 7.11140 C17H22O10


O

O O
O
O
O
O O O
O
O
O
O O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
10 471.05580 Theoretical 471.05438 -1.4 -3.019 138 7.27748 7.09398 C22H15O12
O

O O
O
O O
O O O
O
O
O
O O

O O

11 483.11332 Theoretical 483.11136 -2.0 -4.054 246 7.29798 6.94723 C21H23O13


O

O O
O
O O
O O O
O
O
O
O O

O O

Item name: MENGKUDU 1, Component name: Quercetin-3-O-β-D-gluco-pyranosyl(14)-α-L-rhamnopyranoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 139.03897 Theoretical 139.03825 -0.7 -5.218 92 6.79525 6.93411 C7H7O3

O O
O O

O O
O O O
O O O
O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 161.02332 Theoretical 161.02155 -1.8 -11.000 142 6.82218 6.97559 C9H5O3

O O
O O

O O
O O O
O O O
O

O O

3 222.07340 Theoretical 222.07436 1.0 4.285 156 6.78836 7.11616 C8H14O7

O O
O O

O O
O O O
O O O
O

O O

4 223.06010 Theoretical 223.05893 -1.2 -5.231 124 6.81908 6.97332 C11H11O5

O O
O O

O O
O O O
O O O
O

O O

5 246.07340 Theoretical 246.07455 1.1 4.663 191 6.79525 7.08032 C10H14O7

O O
O O

O O
O O O
O O O
O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
6 293.08671 Theoretical 293.08479 -1.9 -6.546 930 6.82568 6.95446 C11H17O9

O O
O O

O O
O O O
O O O
O

O O

7 303.04993 Theoretical 303.05134 1.4 4.667 8311 6.80902 6.83511 C15H11O7

O O
O O

O O
O O O
O O O
O

O O

8 332.07380 Theoretical 332.07500 1.2 3.608 131 6.79570 7.01097 C13H16O10

O O
O O

O O
O O O
O O O
O

O O

9 345.06049 Theoretical 345.06211 1.6 4.695 215 6.80713 6.93942 C17H13O8

O O
O O

O O
O O O
O O O
O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
10 403.10236 Theoretical 403.10131 -1.0 -2.601 128 6.83081 6.93438 C20H19O9

O O
O O

O O
O O O
O O O
O

O O

11 413.07145 Theoretical 413.07218 0.7 1.759 316 6.83084 7.16513 C17H17O12

O O
O O

O O
O O O
O O O
O

O O

12 432.12623 Theoretical 432.12659 0.4 0.847 202 6.79846 7.01536 C18H24O12

O O
O O

O O
O O O
O O O
O

O O

13 535.14462 Theoretical 535.14569 1.1 1.997 317 6.83866 6.89557 C25H27O13

O O
O O

O O
O O O
O O O
O

O O
Item name: MENGKUDU 1, Component name: Quercetin-3-O-β-D-xylopyranosyl (12)-β-D-glucopyranoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 265.09179 Theoretical 265.09033 -1.5 -5.521 224 6.79470 7.92330 C10H17O8

O O
O
O
O
O O O
O O
O
O O
O
O
O

2 285.03936 Theoretical 285.03840 -1.0 -3.369 135 6.79899 7.85554 C15H9O6

O O
O
O
O
O O O
O O
O
O O
O
O
O

3 295.10236 Theoretical 295.10151 -0.9 -2.881 196 6.82581 7.87777 C11H19O9

O O
O
O
O
O O O
O O
O
O O
O
O
O

4 303.04993 Theoretical 303.05135 1.4 4.682 36265 6.81185 7.84707 C15H11O7

O O
O
O
O
O O O
O O
O
O O
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 315.04993 Theoretical 315.05092 1.0 3.139 261 6.79282 7.99195 C16H11O7

O O
O
O
O
O O O
O O
O
O O
O
O
O

6 465.10275 Theoretical 465.10243 -0.3 -0.700 1304 6.81040 7.95549 C21H21O12

O O
O
O
O
O O O
O O
O
O O
O
O
O

Item name: MENGKUDU 1, Component name: Quercetin-3-rhamnogentiobioside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 147.04406 Theoretical 147.04472 0.7 4.510 227 4.54602 7.82607 C9H7O2

O
O
O O O
O O
O O
O O O
O O
O O O
O
OO
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 193.04954 Theoretical 193.05019 0.7 3.384 305 4.55877 7.80387 C10H9O4

O
O
O O O
O O
O O
O O O
O O
O O O
O
OO
O

3 257.06558 Theoretical 257.06568 0.1 0.409 671 4.58874 8.03661 C11H13O7

O
O
O O O
O O
O O
O O O
O O
O O O
O
OO
O

4 471.14970 Theoretical 471.14949 -0.2 -0.444 384 4.59203 7.76000 C21H27O12

O
O
O O O
O O
O O
O O O
O OO
O O O
OO
O
Item name: MENGKUDU 1, Component name: Quercetin-3-rhamnogentiobioside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 299.09727 Theoretical 299.09654 -0.7 -2.467 154 4.93748 7.86302 C10H19O10

O
O
O O O
O O
O O
O O O
O O
O O O
O
OO
O

2 395.06089 Theoretical 395.06165 0.8 1.929 126 4.91580 8.05873 C17H15O11

O
O
O O O
O O
O O
O O O
O O
O O O
O
OO
O

3 409.17044 Theoretical 409.17070 0.3 0.639 519 4.95256 7.75797 C17H29O11

O
O
O O O
O O
O O
O O O
O O
O O O
O
OO
O

4 471.14970 Theoretical 471.14817 -1.5 -3.249 243 4.90726 7.97155 C21H27O12

O
O
O O O
O O
O O
O O O
O O
O O O
O
OO
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 526.15284 Theoretical 526.15269 -0.2 -0.287 322 4.95481 7.73669 C20H30O16

O
O
O O O
O O
O O
O O O
O O
O O O
O
OO
O

Item name: MENGKUDU 1, Component name: Quercetin-6-O-glucoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 149.02332 Theoretical 149.02343 0.1 0.744 92 6.70405 6.00553 C8H5O3

O O
O O
O O O
O O O
O
O

2 151.03897 Theoretical 151.04002 1.0 6.923 237 6.67773 5.67012 C8H7O3

O O
O O

O O O
O O O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 183.02880 Theoretical 183.02960 0.8 4.386 140 6.70144 5.64130 C8H7O5

O O
O O

O O O
O O O
O
O

4 258.07340 Theoretical 258.07266 -0.7 -2.879 183 6.68964 5.88531 C11H14O7

O O
O O

O O O
O O O
O
O

Item name: MENGKUDU 1, Component name: Quercetin-7-O-rutinoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 303.04993 Theoretical 303.05133 1.4 4.635 3468 7.27662 9.73267 C15H11O7

O O
O
O O O
O O O
O O
O OO
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 309.11801 Theoretical 309.11739 -0.6 -1.994 170 7.29362 9.77231 C12H21O9

O O
O
O O O
O O O
O O
O OO
O
O

3 460.12114 Theoretical 460.12223 1.1 2.355 154 7.26045 9.77392 C19H24O13

O O
O
O O O
O O O
O O
O OO
O
O

4 545.16535 Theoretical 545.16497 -0.4 -0.708 257 7.27798 9.67368 C27H29O12

O O
O
O O O
O O O
O O
O OO
O
O
Item name: MENGKUDU 1, Component name: Quercetin-7-O-rutinoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 303.04993 Theoretical 303.05136 1.4 4.712 1939 7.27716 10.83653 C15H11O7

O O
O
O O O
O O O
O O
O OO
O
O

Item name: MENGKUDU 1, Component name: Quercetin-7-O-rutinoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 149.05971 Theoretical 149.06007 0.4 2.433 79 6.80924 5.79584 C9H9O2

O O
O
O O O
O O O
O O
O OO
O
O

2 186.05227 Theoretical 186.05159 -0.7 -3.674 109 6.83618 6.05370 C8H10O5

O O
O
O O O
O O O
O O
O OO
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 257.06558 Theoretical 257.06663 1.1 4.094 281 6.82680 6.03597 C11H13O7

O O
O
O O O
O O O
O O
O OO
O
O

4 264.08397 Theoretical 264.08285 -1.1 -4.242 160 6.79025 5.89547 C10H16O8

O O
O
O O O
O O O
O O
O OO
O
O

5 265.09179 Theoretical 265.09128 -0.5 -1.956 303 6.81973 6.01966 C10H17O8

O O
O
O O O
O O O
O O
O OO
O
O

6 293.08671 Theoretical 293.08503 -1.7 -5.743 572 6.82575 6.03707 C11H17O9

O O
O
O O O
O O O
O O
O OO
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
7 303.04993 Theoretical 303.05136 1.4 4.721 2326 6.81461 5.87599 C15H11O7

O O
O
O O O
O O O
O O
O OO
O
O

8 311.05501 Theoretical 311.05573 0.7 2.302 237 6.83237 6.13512 C17H11O6

O O
O
O O O
O O O
O O
O OO
O
O

9 329.06558 Theoretical 329.06454 -1.0 -3.155 116 6.81218 5.95034 C17H13O7

O O
O
O O O
O O O
O O
O OO
O
O

10 378.11566 Theoretical 378.11372 -1.9 -5.144 148 6.78418 5.82464 C15H22O11

O O
O
O O O
O O O
O O
O OO
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
11 390.11566 Theoretical 390.11601 0.3 0.896 229 6.82347 6.03946 C16H22O11

O O
O
O O O
O O O
O O
O OO
O
O

Item name: MENGKUDU 1, Component name: Quercetin-7-O-rutinoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 183.02880 Theoretical 183.02766 -1.1 -6.219 93 5.63356 8.03742 C8H7O5

O O
O
O O O
O O O
O O
O OO
O
O

2 239.05501 Theoretical 239.05425 -0.8 -3.184 222 5.59304 8.04100 C11H11O6

O O
O
O O O
O O O
O O
O OO
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 287.05501 Theoretical 287.05697 2.0 6.813 4261 5.61103 7.90070 C15H11O6

O O
O
O O O
O O O
O O
O OO
O
O

4 329.08671 Theoretical 329.08570 -1.0 -3.061 152 5.58968 7.86468 C14H17O9

O O
O
O O O
O O O
O O
O OO
O
O

5 421.17044 Theoretical 421.16899 -1.4 -3.433 179 5.58704 8.05427 C18H29O11

O O
O
O O O
O O O
O O
O OO
O
O

6 449.10784 Theoretical 449.10867 0.8 1.854 1765 5.60820 7.98007 C21H21O11

O O
O
O O O
O O O
O O
O OO
O
O
Item name: MENGKUDU 1, Component name: Quercetin-7-O-rutinoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 265.09179 Theoretical 265.09033 -1.5 -5.521 224 6.79470 7.92330 C10H17O8

O O
O
O O O
O O O
O O
O OO
O
O

2 285.03936 Theoretical 285.03840 -1.0 -3.369 135 6.79899 7.85554 C15H9O6

O O
O
O O O
O O O
O O
O OO
O
O

3 295.10236 Theoretical 295.10151 -0.9 -2.881 196 6.82581 7.87777 C11H19O9

O O
O
O O O
O O O
O O
O OO
O
O

4 303.04993 Theoretical 303.05135 1.4 4.682 36265 6.81185 7.84707 C15H11O7

O O
O
O O O
O O O
O O
O OO
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 315.04993 Theoretical 315.05092 1.0 3.139 261 6.79282 7.99195 C16H11O7

O O
O
O O O
O O O
O O
O OO
O
O

6 465.10275 Theoretical 465.10243 -0.3 -0.700 1304 6.81040 7.95549 C21H21O12

O O
O
O O O
O O O
O O
O OO
O
O
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Chapter: tic plot
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