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MENGKUDU 2 - Terpenoid

The report provides an analysis of two samples, BLANK WATER and MENGKUDU 2, using a specific experimental setup involving a binary solvent manager and a PDA detector. It details the gradient tables, data collection parameters, and the identified compounds from the MENGKUDU 2 sample, including their respective retention times and mass errors. The document also includes various settings and configurations for the analytical instruments used in the analysis.

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13 views3,282 pages

MENGKUDU 2 - Terpenoid

The report provides an analysis of two samples, BLANK WATER and MENGKUDU 2, using a specific experimental setup involving a binary solvent manager and a PDA detector. It details the gradient tables, data collection parameters, and the identified compounds from the MENGKUDU 2 sample, including their respective retention times and mass errors. The document also includes various settings and configurations for the analytical instruments used in the analysis.

Uploaded by

Izzat
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SUMMARY REPORT

Analysis Information
Item name: POS_SCREENING POLAR_FRI TANJUNG Analysis Method Item name: POS_SCREENING POLAR_PDA
DEMONG_DR.SHAHARAH_report
Version: 5 Analysis Method Version: 5
Modified date: Sep 11, 2023 10:41:39 Malay Peninsula Standard Sample Set Created date:
Time
Modified by: Fashiha, Siti Sample Set Instrument system
name:
Folder: Company/Central Lab/External

Sample Information
Item name: BLANK WATER Sample type: Blank
Item description: Sample position: 1:A,1
Item name: MENGKUDU 2 Sample type: Unknown
Item description: Sample position: 1:A,4

Experimental Record : BLANK WATER


I-Class Binary Solvent Manager
General
Solvent Name A: Water +0.1%Formic Acid Solvent Name B: Acetonitrile + 0.1%Formic Acid
Solvent Selection A: A1 Solvent Selection B: B1
Comment: Seal Wash Period: 5.000 min
Gradient start: At injection Pre-Injector Volume: 0 µL
2D Repeat Enabled: No High Pressure Limit: 18000 psi
2D Repeat Enabled: No High Pressure Limit: 18000 psi
Low Pressure Limit: 0 psi

Gradient Table
Flow Rate Compositio Compositio
Time (min) Curve
(mL/min) n A (%) n B (%)
0.00 0.600 99.0 1.0 Initial
0.50 0.600 99.0 1.0 6
16.00 0.600 65.0 35.0 6
18.00 0.600 0.0 100.0 1
20.00 0.600 99.0 1.0 1

Data
System Pressure (psi) Channel Enabled: Yes Flow Rate (mL/min) Channel Enabled: No
A Composition (%) Channel Enabled: No B Composition (%) Channel Enabled: No
Primary A Pressure (psi) Channel Enabled: No Accumulator A Pressure (psi) Channel Enabled: No
Primary B Pressure (psi) Channel Enabled: No Accumulator B Pressure (psi) Channel Enabled: No
Degasser Pressure (psi) Channel Enabled: No

Analog Out
Chart Out 1: Flow Rate Chart Out 2: Flow Rate

Events
Initial Switch 1: No Change Initial Switch 2: No Change
Initial Switch 3: No Change Pre-Analysis mode: No
Run Events: No

PDA Detector

General
Lamp state: On Sampling rate: 10 points/sec
Filter Time Constant Mode: No filter Filter Time Constant: N/A
Exposure Time: Auto Interpolate 2nd Order Filter (340 nm) Region: No
Use UV Blocking Filter: No Negative absorbance margin: -0.07 AU

3D Channel
Start Wavelength: 190 nm
End Wavelength: 500 nm
Resolution: 1.2 nm
Comment:

2D Channel Table
Spectral
Wavelengt Wavelengt Minimum
Channel Data mode channel
h 1 (nm) h 2 (nm) channel ratio
resolution
Channel 1 Absorbance 1.2 254

Analog Out
Output 1
Channel: 1: Absorbance : 254 nm Full Scale Range: 4.000 units
Ratio Full Scale: 100 Full Scale Voltage: 2000 mV
Voltage Offset: 0 mV

Events
Switch 1
Initial Switch 1: No Change Threshold event: Channel: 1: Absorbance : 254 nm
Threshold State: On Threshold Level: 1.000 AU
Pulse width: 1 sec Rect wave period: 0.2 sec
Run Events: No

Sample Manager FTN


General
Wash Solvent: H2O:MEOH:ACN:IPA 1:1:1:1 Wash Solvent Pre Inject: 0 s
Wash Solvent Post Inject: 5 s Purge Solvent: 90:10 Water/MeOH
Load Ahead: Disabled Loop Offline: Disabled
Column Temperature Enable: Yes Column Temperature: 40.0 °C
Column Temperature Alarm: No Sample Temperature Enable: Yes
Sample Temperature: 20.0 °C Sample Temperature Alarm Enable: No
Comment:

Data
Sample Temperature (°C) Channel Enabled: Yes Column Temperature (°C) Channel Enabled: No
Ambient Temperature (°C) Channel Enabled: Yes Sample Pressure (psi) Channel Enabled: No
Seal Force (%) Channel Enabled: No Pre Heater Temperature (°C) Channel Enabled: No
Dilution
Dilution Enable: Disabled Needle Placement (from bottom): Disabled
Dilution Dispense Purge Solvent: Disabled Post Dilution Delay: Disabled

Events
Run Events: No

Advanced
Syringe Draw Rate: Automatic Needle Placement (from bottom): 2.0 mm
Pre Aspirate Air: Automatic Post Aspirate Air: Automatic
Mix Stroke Cycles: Automatic Mix Stroke Volume: Automatic

Vion IMS QTof


Instrument software build: 2.0.0

Method
Polarity: Positive Analyzer mode: Sensitivity

Function 1 : MSᴱ
Mode: High Definition MSᴱ Start time: 0.00 min
End time: 20.00 min Low mass: 50 m/z
High mass: 1000 m/z Scan time: 0.200 s
Low collision energy: 4.00 eV High collision energy ramp start: 10.00 eV
High collision energy ramp end: 40.00 eV Enable Tof data reduction on acquired data: Yes
Intensity threshold: 10000 counts

Source parameters
Source type: ESI Source temperature: 120 °C
Desolvation temperature: 550 °C Cone gas: 50 L/h
Desolvation gas: 800 L/h Capillary voltage: 2.50 kV

Lock correction
Mode: Automatic Automatic sampling interval: No
Interval: 0.50 min

Options
Acquisition check failure: Stop acquisition Automatic detector check: Disabled
Events
Time (min) Event Parameters
Initial Flow state LC, Sample
Initial Infusion Start, Reference
Initial Refill Refill always, Reference
Initial Reservoir B, Reference

Method trigger
Trigger type: Network Event input 1: Enabled
Event input 2: Disabled

Experimental Record : MENGKUDU 2


I-Class Binary Solvent Manager
General
Solvent Name A: Water +0.1%Formic Acid Solvent Name B: Acetonitrile + 0.1%Formic Acid
Solvent Selection A: A1 Solvent Selection B: B1
Comment: Seal Wash Period: 5.000 min
Gradient start: At injection Pre-Injector Volume: 0 µL
2D Repeat Enabled: No High Pressure Limit: 18000 psi
Low Pressure Limit: 0 psi

Gradient Table
Flow Rate Compositio Compositio
Time (min) Curve
(mL/min) n A (%) n B (%)
0.00 0.600 99.0 1.0 Initial
0.50 0.600 99.0 1.0 6
16.00 0.600 65.0 35.0 6
18.00 0.600 0.0 100.0 1
20.00 0.600 99.0 1.0 1

Data
System Pressure (psi) Channel Enabled: Yes Flow Rate (mL/min) Channel Enabled: No
A Composition (%) Channel Enabled: No B Composition (%) Channel Enabled: No
Primary A Pressure (psi) Channel Enabled: No Accumulator A Pressure (psi) Channel Enabled: No
Primary A Pressure (psi) Channel Enabled: No Accumulator A Pressure (psi) Channel Enabled: No
Primary B Pressure (psi) Channel Enabled: No Accumulator B Pressure (psi) Channel Enabled: No
Degasser Pressure (psi) Channel Enabled: No

Analog Out
Chart Out 1: Flow Rate Chart Out 2: Flow Rate

Events
Initial Switch 1: No Change Initial Switch 2: No Change
Initial Switch 3: No Change Pre-Analysis mode: No
Run Events: No

PDA Detector

General
Lamp state: On Sampling rate: 10 points/sec
Filter Time Constant Mode: No filter Filter Time Constant: N/A
Exposure Time: Auto Interpolate 2nd Order Filter (340 nm) Region: No
Use UV Blocking Filter: No Negative absorbance margin: -0.07 AU

3D Channel
Start Wavelength: 190 nm
End Wavelength: 500 nm
Resolution: 1.2 nm
Comment:

2D Channel Table
Spectral
Wavelengt Wavelengt Minimum
Channel Data mode channel
h 1 (nm) h 2 (nm) channel ratio
resolution
Channel 1 Absorbance 1.2 254

Analog Out
Output 1
Channel: 1: Absorbance : 254 nm Full Scale Range: 4.000 units
Ratio Full Scale: 100 Full Scale Voltage: 2000 mV
Voltage Offset: 0 mV

Events
Switch 1
Initial Switch 1: No Change Threshold event: Channel: 1: Absorbance : 254 nm
Threshold State: On Threshold Level: 1.000 AU
Pulse width: 1 sec Rect wave period: 0.2 sec
Run Events: No

Sample Manager FTN


General
Wash Solvent: H2O:MEOH:ACN:IPA 1:1:1:1 Wash Solvent Pre Inject: 0 s
Wash Solvent Post Inject: 5 s Purge Solvent: 90:10 Water/MeOH
Load Ahead: Disabled Loop Offline: Disabled
Column Temperature Enable: Yes Column Temperature: 40.0 °C
Column Temperature Alarm: No Sample Temperature Enable: Yes
Sample Temperature: 20.0 °C Sample Temperature Alarm Enable: No
Comment:

Data
Sample Temperature (°C) Channel Enabled: Yes Column Temperature (°C) Channel Enabled: No
Ambient Temperature (°C) Channel Enabled: Yes Sample Pressure (psi) Channel Enabled: No
Seal Force (%) Channel Enabled: No Pre Heater Temperature (°C) Channel Enabled: No

Dilution
Dilution Enable: Disabled Needle Placement (from bottom): Disabled
Dilution Dispense Purge Solvent: Disabled Post Dilution Delay: Disabled

Events
Run Events: No

Advanced
Syringe Draw Rate: Automatic Needle Placement (from bottom): 2.0 mm
Pre Aspirate Air: Automatic Post Aspirate Air: Automatic
Mix Stroke Cycles: Automatic Mix Stroke Volume: Automatic

Vion IMS QTof


Instrument software build: 2.0.0

Method
Polarity: Positive Analyzer mode: Sensitivity

Function 1 : MSᴱ
Mode: High Definition MSᴱ Start time: 0.00 min
End time: 20.00 min Low mass: 50 m/z
High mass: 1000 m/z Scan time: 0.200 s
Low collision energy: 4.00 eV High collision energy ramp start: 10.00 eV
High collision energy ramp end: 40.00 eV Enable Tof data reduction on acquired data: Yes
Intensity threshold: 10000 counts

Source parameters
Source type: ESI Source temperature: 120 °C
Desolvation temperature: 550 °C Cone gas: 50 L/h
Desolvation gas: 800 L/h Capillary voltage: 2.50 kV

Lock correction
Mode: Automatic Automatic sampling interval: No
Interval: 0.50 min

Options
Acquisition check failure: Stop acquisition Automatic detector check: Disabled

Events
Time (min) Event Parameters
Initial Flow state LC, Sample
Initial Infusion Start, Reference
Initial Refill Refill always, Reference
Initial Reservoir B, Reference

Method trigger
Trigger type: Network Event input 1: Enabled
Event input 2: Disabled
TIC (Total Ion Chromatogram) Plot

BPI (Base Peak Intensity) Plot


PDA (Photo Diode Array) Plot

Item name: BLANK WATER


Channel name: PDA MaxPlot (190-500)
18.50
Absorbance [AU]

16.43

0.5

0.56
0
0 2 4 6 8 10 12 14 16 18 20
Retention time [min]

Item name: MENGKUDU 2


Channel name: PDA MaxPlot (190-500)
1.07
0.48

2
Absorbance [AU]

1.11
6.24 18.49
2.65
7.47 8.16
1 1.62
3.91 6.38
6.04 16.43
2.43 4.12
3.73 6.79 7.82
5.88 9.11
0
0 2 4 6 8 10 12 14 16 18 20
Retention time [min]
Idened Compounds
Item name: MENGKUDU 2

2e5
O

O O
O O
Chiral

O O
O
1.5e5 O O
O
H
O
Intensity [Counts]

O O
O O O
5,7,2',5'-Tetrahydroxy-fla…
7.49
5,7,2',5'-Tetrahydroxy-fla…
100000
8.18 14-Deoxy-11-hydro-xyan…
8-Debenzoylpae… 13.68
5.49 14-Deoxy-12R-h…
13.53 14-Deoxy-12R-h…
50000 Blumenol C gluc… 13.94 11-O-p-Coumary…
Ginkgolide M 8.72 16.92
Fibraurin Azedarachin C
4.97
1.89 12.53

0
2 4 6 8 10 12 14 16 18
Retention time [min]

Item name: MENGKUDU 2, Sample position: 1:A,4, Replicate number: 1


Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
1 Orientanone C15H24O5S Identified 348.1046 349.1119 -1.9 -5.4 0.53 960 +H 211.99 0
2
2 10-O-Acetylgeniposidic C18H24O11 Identified 416.1308 417.1381 -1.1 -2.6 0.59 584 +H 247.93 2
acid
3 10-O-Acetylgeniposidic C18H24O11 Identified 416.1310 417.1382 -0.9 -2.2 0.59 508 +H 230.30 3
acid
4 8-Acetyl harpagide C16H24O12 Identified 408.1241 409.1314 -2.7 -6.6 0.60 2682 +H 189.51 3
5 Paeonisuffral C10H14O5 Identified 214.0855 215.0928 1.4 6.3 0.86 2699 +H 224.69 1
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
6 1,4α,5,7α-Tetrahydro-7- C10H12O4 Identified 196.0753 197.0826 1.7 8.7 0.86 2142 +H 225.40 2
hydroxyl-cyclopenta [c]
pyran-4-carboxylic
methyl ester
7 trans-2-Methoxy C10H10O2 Identified 162.0676 163.0749 -0.5 -3.0 0.93 1118 +H 159.53 2
cinnamaldehyde
8 1,4α,5,7α-Tetrahydro-7- C10H12O4 Identified 196.0748 197.0821 1.2 6.3 0.94 738 +H 164.31 5
hydroxyl-cyclopenta [c]
pyran-4-carboxylic
methyl ester
9 Sesamoside C17H24O12 Identified 420.1272 421.1344 0.4 0.9 0.95 1179 +H 180.59 3
10 Sesamoside C17H24O12 Identified 420.1269 421.1342 0.2 0.4 0.98 1250 +H 150.15 8
11 Sesamoside C17H24O12 Identified 420.1270 421.1343 0.2 0.6 0.98 1323 +H 196.85 5
12 Secologanoside C16H22O11 Identified 390.1172 391.1245 1.0 2.6 1.00 573 +H 199.06 7
13 Adoxosidic acid C16H24O10 Identified 376.1371 377.1444 0.1 0.4 1.01 1009 +H 215.36 4
14 Paeonisuffral C10H14O5 Identified 214.0844 215.0917 0.3 1.2 1.03 623 +H 219.94 0
15 Sesamoside C17H24O12 Identified 420.1264 421.1337 -0.4 -0.9 1.05 840 +H 245.99 1
16 Physalin E C28H32O11 Identified 544.1955 545.2028 1.1 2.0 1.25 1130 +H 224.82 0
17 Anemonin C10H8O4 Identified 192.0441 193.0514 1.9 9.7 1.33 527 +H 140.55 0
18 Paeonisuffral C10H14O5 Identified 214.0853 215.0926 1.2 5.6 1.44 769 +H 179.47 3
19 Paeonisuffral C10H14O5 Identified 214.0853 215.0925 1.1 5.3 1.44 1253 +H 206.82 3
20 8-Epi-loganic acid C16H24O10 Identified 376.1374 377.1447 0.4 1.2 1.44 1551 +H 230.31 5
21 8-Epi-loganic acid C16H24O10 Identified 376.1375 377.1447 0.5 1.3 1.44 1219 +H 207.73 10
22 8- C16H24O10 Identified 376.1374 377.1447 0.5 1.2 1.44 1698 +H 255.78 6
Debenzoylpaeoniflorin
23 8-Epi-loganic acid C16H24O10 Identified 376.1374 377.1447 0.5 1.2 1.44 1698 +H 255.78 10
24 1,4α,5,7α-Tetrahydro-7- C10H12O4 Identified 196.0755 197.0828 1.9 9.8 1.45 645 +H 195.17 3
hydroxyl-cyclopenta [c]
pyran-4-carboxylic
methyl ester
25 1,4α,5,7α-Tetrahydro-7- C10H12O4 Identified 196.0755 197.0828 1.9 9.8 1.45 1166 +H 181.95 6
hydroxyl-cyclopenta [c]
pyran-4-carboxylic
methyl ester
26 Paeonisuffral C10H14O5 Identified 214.0853 215.0925 1.1 5.3 1.45 568 +H 244.36 2
27 Secologanic acid C16H22O10 Identified 374.1218 375.1291 0.5 1.4 1.52 497 +H 210.91 4
28 Sweroside C16H22O9 Identified 358.1251 359.1323 -1.3 -3.7 1.53 582 +H 178.56 3
29 Secologanic acid C16H22O10 Identified 374.1226 375.1299 1.3 3.5 1.59 736 +H 183.84 5
30 Geniposidic acid C16H22O10 Identified 374.1229 375.1302 1.6 4.3 1.62 1013 +H 222.08 3
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
31 8-Epi-loganic acid C16H24O10 Identified 376.1374 377.1447 0.5 1.3 1.64 1401 +H 253.33 5
32 1,4α,5,7α-Tetrahydro-7- C10H12O4 Identified 196.0755 197.0828 2.0 9.9 1.64 629 +H 225.20 3
hydroxyl-cyclopenta [c]
pyran-4-carboxylic
methyl ester
33 Paeonisuffral C10H14O5 Identified 214.0859 215.0932 1.8 8.4 1.65 784 +H 260.15 2
34 Paeonisuffral C10H14O5 Identified 214.0857 215.0930 1.6 7.6 1.70 1692 +H 219.55 1
35 1,4α,5,7α-Tetrahydro-7- C10H12O4 Identified 196.0752 197.0824 1.6 8.1 1.70 808 +H 219.46 1
hydroxyl-cyclopenta [c]
pyran-4-carboxylic
methyl ester
36 Sweroside C16H22O9 Identified 358.1292 359.1365 2.9 8.0 1.72 1482 +H 254.19 3
37 Sweroside C16H22O9 Identified 358.1294 359.1367 3.0 8.3 1.72 1196 +H 286.36 3
38 Fibraurin C20H20O7 Identified 372.1187 373.1259 -2.2 -6.0 1.89 3310 +H 181.69 1
39 Anemonin C10H8O4 Identified 192.0431 193.0504 0.9 4.5 2.04 489 +H 151.51 1
40 Sesamoside C17H24O12 Identified 420.1268 421.1341 0.0 0.1 2.08 778 +H 241.10 9
41 Sesamoside C17H24O12 Identified 420.1271 421.1344 0.3 0.8 2.10 656 +H 216.67 8
42 Reptoside C16H24O11 Identified 392.1310 393.1383 -0.8 -2.1 2.11 508 +H 184.36 4
43 Asperulosidic acid C18H24O12 Identified 432.1281 433.1354 1.3 3.1 2.29 1286 +H 199.01 7
44 Sweroside C16H22O9 Identified 358.1245 359.1318 -1.9 -5.2 2.35 801 +H 178.54 6
45 Acetylharpagide C17H26O11 Identified 406.1445 407.1518 -3.0 -7.4 2.37 2296 +H 192.33 9
46 Lamiophlomiol B C11H14O6 Identified 242.0788 243.0861 -0.2 -0.9 2.45 1229 +H 203.48 3
47 7-epi-Vogeloside C17H24O10 Identified 388.1359 389.1432 -1.0 -2.6 2.59 795 +H 195.48 12
48 8-Epi-loganic acid C16H24O10 Identified 376.1356 377.1429 -1.4 -3.6 2.70 1898 +H 184.38 2
49 Pueroside B C29H34O15 Identified 622.1891 623.1964 -0.7 -1.1 2.78 652 +H 234.25 10
50 Phloyoside Ⅱ C17H25ClO1 Identified 456.1043 457.1116 0.8 1.9 2.79 1127 +H 200.01 7
2
51 Phloyoside Ⅱ C17H25ClO1 Identified 456.1048 457.1120 1.3 2.9 2.83 675 +H 212.27 4
2
52 Centaurepensin C19H24Cl2O Identified 434.0881 435.0954 -1.8 -4.2 2.85 685 +H 276.21 13
7
53 Centaurepensin C19H24Cl2O Identified 434.0888 435.0961 -1.1 -2.6 2.89 1112 +H 190.04 4
7
54 8-Acetyl harpagide C16H24O12 Identified 408.1266 409.1339 -0.2 -0.4 2.92 817 +H 194.76 6
55 Nigakilactone J C23H34O7 Identified 422.2285 423.2358 -2.0 -4.6 2.94 705 +H 205.49 5
56 Shanzhiside methyl C17H26O11 Identified 406.1457 407.1529 -1.8 -4.5 2.95 553 +H 200.39 11
ester
57 6′-O-β-D-Glucosyl C22H30O14 Identified 518.1624 519.1697 -1.1 -2.2 2.97 1952 +H 206.98 18
gentiopicroside
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
58 8-O-Acetyl shanzhiside C19H28O12 Identified 448.1562 449.1635 -1.9 -4.2 3.04 2399 +H 197.96 12
methyl ester
59 Anemonin C10H8O4 Identified 192.0438 193.0511 1.6 8.2 3.06 488 +H 132.54 0
60 Asperuloside C18H22O11 Identified 414.1147 415.1220 -1.5 -3.7 3.17 1702 +H 190.06 10
61 Anemonin C10H8O4 Identified 192.0435 193.0507 1.2 6.3 3.27 5350 +H 144.94 1
62 8-Epi-loganic acid C16H24O10 Identified 376.1356 377.1429 -1.3 -3.5 3.31 2517 +H 186.62 10
63 Bruceaketolic acid C22H28O12 Identified 484.1573 485.1646 -0.8 -1.6 3.54 811 +H 204.99 5
64 Picroside Ⅲ C25H30O13 Identified 538.1676 539.1749 -1.1 -2.0 3.56 2332 +H 236.82 9
65 Erythrocentaurin C10H8O3 Identified 176.0489 177.0562 1.6 8.8 3.62 500 +H 137.90 1
66 Geniposide C17H24O11 Identified 404.1305 405.1378 -1.3 -3.3 3.65 525 +H 183.27 6
67 Picroside Ⅲ C25H30O13 Identified 538.1675 539.1748 -1.1 -2.0 3.72 915 +H 233.37 10
68 Asperuloside C18H22O11 Identified 414.1166 415.1239 0.4 1.0 3.83 1181 +H 193.24 19
69 Ginkgolide C C20H24O11 Identified 440.1329 441.1401 1.0 2.2 3.84 525 +H 194.92 7
70 Asperuloside C18H22O11 Identified 414.1150 415.1223 -1.2 -2.9 3.85 1082 +H 218.00 13
71 Asperuloside C18H22O11 Identified 414.1174 415.1247 1.2 2.9 3.90 1690 +H 233.07 4
72 Asperuloside C18H22O11 Identified 414.1171 415.1244 0.9 2.2 3.92 1713 +H 190.58 4
73 Asperuloside C18H22O11 Identified 414.1173 415.1246 1.1 2.7 3.93 2033 +H 245.63 7
74 3-Hydroxy-12,14- C29H42O4 Identified 454.3086 455.3159 0.3 0.6 3.93 661 +H 196.22 1
diene-27-nordeane-28-
nic acid
75 Anemonin C10H8O4 Identified 192.0430 193.0503 0.8 4.1 3.93 2496 +H 206.20 3
76 Asperuloside C18H22O11 Identified 414.1170 415.1243 0.8 2.0 3.93 2085 +H 276.38 11
77 Asperuloside C18H22O11 Identified 414.1171 415.1244 0.9 2.2 3.93 746 +H 212.79 7
78 Anemonin C10H8O4 Identified 192.0432 193.0504 0.9 4.6 3.93 565 +H 256.53 0
79 Anemonin C10H8O4 Identified 192.0431 193.0504 0.8 4.3 3.94 944 +H 149.40 2
80 Isohistiopterosin A C14H16O4 Identified 248.1037 249.1110 -1.2 -4.6 3.97 941 +H 152.03 0
81 Bruceine H C20H26O10 Identified 426.1512 427.1585 -1.4 -3.3 4.00 1463 +H 205.83 5
82 Lactiflorin C23H26O10 Identified 462.1514 463.1587 -1.2 -2.5 4.15 792 +H 203.91 7
83 Lactiflorin C23H26O10 Identified 462.1520 463.1593 -0.6 -1.3 4.18 1340 +H 216.90 8
84 Ginkgolide C C20H24O11 Identified 440.1309 441.1382 -1.0 -2.2 4.24 553 +H 192.32 6
85 Picroside Ⅱ C23H28O13 Identified 512.1535 513.1608 0.5 1.0 4.26 573 +H 215.67 4
86 Physalin C C28H30O9 Identified 510.1893 511.1966 0.3 0.6 4.34 576 +H 218.96 4
87 6'-O-Benzoyl-4''- C31H34O14 Identified 630.1954 631.2027 0.5 0.9 4.34 659 +H 229.47 10
hydroxy-3''-
methoxypaeoniflorin
88 Isophysalin B C28H30O9 Identified 510.1897 511.1969 0.7 1.3 4.34 881 +H 246.67 3
89 Rehmannioside A C21H32O15 Identified 524.1748 525.1821 0.7 1.3 4.35 896 +H 220.50 12
90 Lactiflorin C23H26O10 Identified 462.1535 463.1608 0.9 2.0 4.35 1352 +H 277.24 4
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
91 Lactiflorin C23H26O10 Identified 462.1537 463.1609 1.1 2.3 4.36 5706 +H 220.18 5
92 Harpagoside C24H30O11 Identified 494.1785 495.1858 -0.3 -0.7 4.40 698 +H 207.95 16
93 6-O-α-D-Galactopyra- C30H40O16 Identified 656.2279 657.2352 -3.7 -5.7 4.41 5885 +H 239.73 3
nosylharpagoside
94 Harpagoside C24H30O11 Identified 494.1785 495.1858 -0.3 -0.7 4.42 736 +H 215.17 10
95 Anemonin C10H8O4 Identified 192.0423 193.0496 0.0 0.1 4.49 537 +H 212.12 1
96 Deacetylmatricarin-8-O- C21H28O9 Identified 424.1735 425.1807 0.1 0.3 4.51 1131 +H 201.38 9
β-D-glucopyranoside
97 Oleuropein C25H32O13 Identified 540.1862 541.1935 1.9 3.5 4.54 707 +H 232.60 6
98 Sesamoside C17H24O12 Identified 420.1257 421.1330 -1.0 -2.4 4.55 897 +H 185.48 6
99 Ginkgolide A C20H24O9 Identified 408.1434 409.1507 1.4 3.5 4.62 500 +H 184.21 4
100 Cichorioside B C21H28O10 Identified 440.1702 441.1775 1.9 4.4 4.67 1293 +H 200.76 8
101 Centaurepensin C19H24Cl2O Identified 434.0889 435.0962 -1.0 -2.2 4.67 1042 +H 239.29 5
7
102 Centaurepensin C19H24Cl2O Identified 434.0886 435.0959 -1.3 -3.0 4.71 673 +H 185.39 12
7
103 Fibleucin C20H20O6 Identified 356.1258 357.1331 -0.2 -0.5 4.77 518 +H 177.85 7
104 Cichorioside B C21H28O10 Identified 440.1674 441.1747 -0.8 -1.8 4.88 1137 +H 198.97 5
105 Sonchuside A C21H32O8 Identified 412.2084 413.2157 -1.3 -3.2 4.92 1847 +H 199.39 4
106 6-O-α-D-Galactopyra- C30H40O16 Identified 656.2317 657.2390 0.1 0.1 4.97 640 +H 241.76 10
nosylharpagoside
107 4,7- C28H28O9 Identified 508.1726 509.1798 -0.8 -1.5 4.97 648 +H 217.65 6
Didehydroneophysalin B
108 Lactiflorin C23H26O10 Identified 462.1546 463.1618 2.0 4.2 4.97 566 +H 212.60 4
109 Ginkgolide B C20H24O10 Identified 424.1345 425.1418 -2.4 -5.7 4.97 28392 +H 192.46 2
110 Ginkgolide M C20H24O10 Identified 424.1345 425.1418 -2.4 -5.7 4.97 28392 +H 192.46 3
111 Schizonepetoside E C16H28O8 Identified 348.1769 349.1842 -1.5 -4.3 5.01 7381 +H 172.25 3
112 Melia-ionoside A C19H36O8 Identified 392.2399 393.2472 -1.1 -2.9 5.04 6764 +H 196.27 4
113 Lactucopicrin C23H22O7 Identified 410.1338 411.1411 -2.7 -6.6 5.09 7948 +H 186.86 4
114 Pterodontoside B C21H32O8 Identified 412.2077 413.2150 -2.0 -4.8 5.09 537 +H 197.55 8
115 Lactucopicrin C23H22O7 Identified 410.1337 411.1409 -2.9 -7.0 5.09 1759 +H 277.29 6
116 Yadanzigan C26H38O14 Identified 574.2261 575.2334 -0.1 -0.1 5.10 527 +H 225.84 8
117 Lactiflorin C23H26O10 Identified 462.1535 463.1608 0.9 2.0 5.15 895 +H 209.58 7
118 Ginkgolide M C20H24O10 Identified 424.1337 425.1409 -3.3 -7.7 5.15 7219 +H 195.14 0
119 Actinidioionoside C19H34O9 Identified 406.2193 407.2266 -1.0 -2.4 5.23 655 +H 202.62 4
120 Physalin C C28H30O9 Identified 510.1875 511.1948 -1.5 -2.9 5.24 1001 +H 212.88 1
121 Cichorioside C C21H32O9 Identified 428.2057 429.2130 1.1 2.6 5.25 804 +H 198.38 4
122 Picroside Ⅰ C24H28O11 Identified 492.1630 493.1703 -0.1 -0.2 5.25 1483 +H 218.12 5
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
123 Nigakilactone E C24H34O8 Identified 450.2238 451.2310 -1.6 -3.5 5.29 1018 +H 206.20 2
124 Kansuinin B C38H42O14 Identified 722.2583 723.2655 0.8 1.1 5.30 1397 +H 262.84 6
125 Brucealin A C32H42O16 Identified 682.2459 683.2532 -1.4 -2.0 5.33 790 +H 244.36 4
126 Dehydrobruceine B C23H26O11 Identified 478.1480 479.1553 0.5 1.0 5.36 494 +H 206.32 11
127 Ulmoside C21H32O14 Identified 508.1792 509.1865 0.0 0.0 5.37 647 +H 212.38 12
128 ApocynosideⅠ C19H30O8 Identified 386.1937 387.2010 -0.4 -0.9 5.38 1061 +H 261.18 2
129 ArteamisinineⅠ C13H18O2 Identified 206.1313 207.1386 0.6 2.9 5.40 694 +H 227.63 3
130 ApocynosideⅠ C19H30O8 Identified 386.1939 387.2011 -0.2 -0.6 5.41 1223 +H 224.16 4
131 7-O-Methylmorroniside C18H28O11 Identified 420.1622 421.1694 -1.0 -2.4 5.42 531 +H 198.47 3
132 ApocynosideⅠ C19H30O8 Identified 386.1942 387.2014 0.1 0.3 5.42 851 +H 240.07 7
133 Yadanzigan C26H38O14 Identified 574.2239 575.2311 -2.3 -4.0 5.44 1156 +H 235.12 6
134 Fibleucin C20H20O6 Identified 356.1257 357.1329 -0.3 -0.9 5.45 641 +H 181.25 4
135 Cichorioside B C21H28O10 Identified 440.1681 441.1754 -0.2 -0.4 5.46 2312 +H 210.18 4
136 Bruceaketolic acid C22H28O12 Identified 484.1591 485.1663 1.0 2.0 5.47 766 +H 209.85 4
137 8-Epi-loganic acid C16H24O10 Identified 376.1389 377.1462 1.9 5.1 5.48 2515 +H 295.80 0
138 8- C16H24O10 Identified 376.1389 377.1462 1.9 5.1 5.49 51220 +H 189.87 6
Debenzoylpaeoniflorin
139 8-Epi-loganic acid C16H24O10 Identified 376.1389 377.1462 1.9 5.1 5.49 51220 +H 189.87 8
140 Sweroside C16H22O9 Identified 358.1272 359.1345 0.9 2.4 5.49 1365 +H 190.23 9
141 Lamiophlomiol B C11H14O6 Identified 242.0807 243.0880 1.7 7.0 5.49 3170 +H 192.83 3
142 Cichorioside C C21H32O9 Identified 428.2055 429.2128 0.9 2.0 5.52 614 +H 200.40 0
143 Benzoylpaeoniflorin C30H32O12 Identified 584.1893 585.1966 -0.1 -0.1 5.55 504 +H 226.92 4
144 Brucealin A C32H42O16 Identified 682.2493 683.2566 2.0 2.9 5.56 614 +H 238.01 9
145 Picroside Ⅰ C24H28O11 Identified 492.1647 493.1720 1.5 3.1 5.59 801 +H 210.56 8
146 Cimicifugic acid B C21H20O11 Identified 448.1013 449.1085 0.7 1.5 5.60 2299 +H 272.54 4
147 Deacetylmatricarin-8-O- C21H28O9 Identified 424.1702 425.1774 -3.2 -7.5 5.60 2457 +H 196.60 7
β-D-glucopyranoside
148 ApocynosideⅠ C19H30O8 Identified 386.1946 387.2018 0.5 1.3 5.61 1268 +H 242.01 5
149 ArteamisinineⅠ C13H18O2 Identified 206.1322 207.1394 1.5 7.1 5.63 1729 +H 197.03 2
150 Aduncin C15H18O6 Identified 294.1085 295.1158 -1.8 -6.2 5.64 525 +H 168.58 1
151 ApocynosideⅠ C19H30O8 Identified 386.1924 387.1997 -1.7 -4.4 5.65 502 +H 190.85 6
152 Cichorioside B C21H28O10 Identified 440.1702 441.1775 2.0 4.5 5.67 6103 +H 207.05 4
153 ArteamisinineⅠ C13H18O2 Identified 206.1326 207.1399 1.9 9.3 5.70 1148 +H 149.74 3
154 ArteamisinineⅠ C13H18O2 Identified 206.1322 207.1395 1.5 7.3 5.70 964 +H 282.72 5
155 ArteamisinineⅠ C13H18O2 Identified 206.1322 207.1394 1.5 7.1 5.70 5025 +H 225.25 17
156 ApocynosideⅠ C19H30O8 Identified 386.1933 387.2006 -0.8 -2.0 5.71 788 +H 259.92 6
157 cis-Anethole C10H12O Identified 148.0886 149.0959 -0.2 -1.4 5.71 512 +H 153.95 0
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
158 Vomifoliol C13H20O3 Identified 224.1428 225.1501 1.6 7.1 5.71 801 +H 225.34 16
159 Deacetylmatricarin-8-O- C21H28O9 Identified 424.1731 425.1803 -0.3 -0.6 5.75 1762 +H 195.24 12
β-D-glucopyranoside
160 Lactiflorin C23H26O10 Identified 462.1546 463.1619 2.0 4.3 5.80 601 +H 205.39 9
161 6-Feruloyl catalpol C25H30O12 Identified 522.1743 523.1816 0.6 1.1 5.88 1945 +H 218.91 16
162 Onitin-2′-O-β-D- C21H30O8 Identified 410.1924 411.1996 -1.7 -4.1 5.92 916 +H 199.19 7
glucopyranoside
163 GrayanotoxinⅠ C21H34O8 Identified 414.2257 415.2330 0.3 0.8 5.94 528 +H 204.95 3
164 Inuchinenolide C C19H26O7 Identified 366.1664 367.1737 -1.4 -3.9 6.00 695 +H 185.54 2
165 cis-Anethole C10H12O Identified 148.0902 149.0975 1.4 9.2 6.05 562 +H 129.48 0
166 ArteamisinineⅠ C13H18O2 Identified 206.1321 207.1394 1.4 6.7 6.06 882 +H 223.84 6
167 ArteamisinineⅠ C13H18O2 Identified 206.1322 207.1395 1.5 7.4 6.08 792 +H 187.83 4
168 Sesamoside C17H24O12 Identified 420.1260 421.1333 -0.8 -1.8 6.12 1047 +H 211.74 9
169 Mudanpioside D C24H30O12 Identified 510.1717 511.1790 -2.0 -3.9 6.12 1004 +H 219.12 7
170 Deacetylmatricarin-8-O- C21H28O9 Identified 424.1739 425.1812 0.6 1.4 6.13 1147 +H 198.97 8
β-D-glucopyranoside
171 Brazilide A C16H14O7 Identified 318.0767 319.0840 2.8 8.7 6.14 1612 +H 171.33 1
172 Brazilide A C16H14O7 Identified 318.0762 319.0835 2.3 7.1 6.14 1193 +H 186.64 2
173 Bruceaketolic acid C22H28O12 Identified 484.1559 485.1632 -2.1 -4.4 6.24 8399 +H 202.93 2
174 Erythrocentaurin C10H8O3 Identified 176.0482 177.0555 0.9 5.0 6.25 1648 +H 135.21 3
175 Ginkgolide M C20H24O10 Identified 424.1379 425.1452 0.9 2.2 6.26 656 +H 195.86 5
176 Scropolioside A C35H44O18 Identified 752.2487 753.2560 -4.1 -5.4 6.27 12975 +H 252.46 19
177 Cichorioside C C21H32O9 Identified 428.2050 429.2123 0.4 0.9 6.27 593 +H 209.22 5
178 Gedunin C28H34O7 Identified 482.2320 483.2393 1.5 3.2 6.29 708 +H 213.60 8
179 Picroside Ⅲ C25H30O13 Identified 538.1691 539.1763 0.4 0.8 6.37 1100 +H 220.29 15
180 Acetylpaeoniflorin C25H30O12 Identified 522.1756 523.1828 1.8 3.5 6.39 1096 +H 269.39 3
181 6-Feruloyl catalpol C25H30O12 Identified 522.1756 523.1828 1.8 3.5 6.39 15913 +H 224.21 24
182 5-O-Benzoyl-20- C27H32O5 Identified 436.2288 437.2361 3.9 8.8 6.39 10893 +H 192.05 4
deoxyingenol
183 1,1,6-Trimethyl-1,2- C13H16 Identified 172.1261 173.1334 0.9 5.1 6.44 887 +H 140.57 3
dihydronaphthalene
184 Deacetylmatricarin-8-O- C21H28O9 Identified 424.1719 425.1792 -1.4 -3.3 6.55 640 +H 198.54 5
β-D-glucopyranoside
185 Secoxyloganin C17H24O11 Identified 404.1304 405.1377 -1.5 -3.6 6.58 589 +H 192.85 4
186 Loganic acid-6'-O-β-D- C22H34O15 Identified 538.1888 539.1960 -1.0 -1.9 6.68 924 +H 219.03 4
glucoside
187 Taraxacolide-1-O-β-D- C21H34O9 Identified 430.2200 431.2273 -0.3 -0.6 6.69 504 +H 198.85 1
glucopyranoside
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
188 Digiprolactone C11H16O3 Identified 196.1107 197.1180 0.8 4.0 6.77 535 +H 168.18 0
189 Ulmoside C21H32O14 Identified 508.1788 509.1861 -0.4 -0.8 6.78 558 +H 232.81 6
190 Digiprolactone C11H16O3 Identified 196.1109 197.1182 1.0 5.0 6.80 2176 +H 144.98 3
191 Digiprolactone C11H16O3 Identified 196.1109 197.1182 1.0 5.0 6.82 1059 +H 175.51 4
192 Ulmoside C21H32O14 Identified 508.1798 509.1871 0.6 1.2 6.82 913 +H 215.06 3
193 m-Isopropyltoluene C10H14 Identified 134.1105 135.1178 0.9 6.9 6.83 731 +H 147.76 1
194 Digiprolactone C11H16O3 Identified 196.1110 197.1183 1.1 5.3 6.84 637 +H 200.75 1
195 Jangomolide C26H28O8 Identified 468.1767 469.1839 -1.7 -3.7 6.86 1116 +H 209.77 9
196 Scropolioside A C35H44O18 Identified 752.2508 753.2580 -2.0 -2.7 6.88 26579 +H 256.99 17
197 6-Feruloyl catalpol C25H30O12 Identified 522.1750 523.1823 1.3 2.5 6.89 1026 +H 241.30 16
198 Chloranthalactone F C30H32O4 Identified 456.2335 457.2408 3.5 7.6 6.92 6181 +H 208.02 6
199 Cichorioside B C21H28O10 Identified 440.1666 441.1739 -1.6 -3.7 6.93 619 +H 195.73 10
200 Ginkgolide A C20H24O9 Identified 408.1402 409.1475 -1.9 -4.5 6.99 706 +H 195.55 4
201 Cichorioside C C21H32O9 Identified 428.2054 429.2126 0.7 1.7 7.15 1090 +H 199.43 11
202 5,7,2',5'-Tetrahydroxy- C15H10O6 Identified 286.0487 287.0560 0.9 3.3 7.19 11953 +H 239.08 0
flavone
203 5,7,2',5'-Tetrahydroxy- C15H10O6 Identified 286.0487 287.0560 0.9 3.3 7.19 31747 +H 271.86 1
flavone
204 Cimicifugic acid B C21H20O11 Identified 448.1014 449.1087 0.8 1.9 7.19 14872 +H 267.25 3
205 Cimicifugic acid B C21H20O11 Identified 448.1015 449.1088 0.9 2.1 7.20 4776 +H 235.65 3
206 Onitin-2′-O-β-D- C21H30O8 Identified 410.1952 411.2025 1.2 2.9 7.20 647 +H 197.84 2
glucopyranoside
207 Rehmannioside A C21H32O15 Identified 524.1738 525.1810 -0.4 -0.7 7.22 532 +H 224.09 8
208 1β,3α,9β- C15H22O5 Identified 282.1461 283.1534 -0.6 -2.2 7.25 1335 +H 165.30 2
Trihydroxyeudesma-5,1
1(13)-dien-12-oic acid
209 Chloranthalactone F C30H32O4 Identified 456.2342 457.2415 4.1 9.0 7.25 10096 +H 205.42 1
210 Genkwadaphnin C34H34O10 Identified 602.2152 603.2224 0.0 0.0 7.27 515 +H 241.32 8
211 Picroside Ⅰ C24H28O11 Identified 492.1641 493.1714 0.9 1.9 7.29 640 +H 202.95 5
212 Galloyloxypaeoniflorin C30H32O16 Identified 648.1685 649.1757 -0.6 -0.9 7.34 1264 +H 249.13 12
213 Fibraurin C20H20O7 Identified 372.1223 373.1296 1.4 3.8 7.38 495 +H 184.33 1
214 Onitin-2′-O-β-D- C21H30O8 Identified 410.1913 411.1986 -2.8 -6.7 7.40 3510 +H 196.18 3
glucopyranoside
215 Qinghaosu Ⅳ C15H22O5 Identified 282.1461 283.1534 -0.6 -2.2 7.42 510 +H 166.46 4
216 Fibraurin C20H20O7 Identified 372.1219 373.1291 1.0 2.6 7.43 496 +H 184.39 4
217 Nigakilactone E C24H34O8 Identified 450.2238 451.2310 -1.6 -3.6 7.46 637 +H 205.39 6
218 Cimicifugic acid B C21H20O11 Identified 448.1014 449.1087 0.8 1.9 7.49 15205 +H 234.22 5
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
219 5,7,2',5'-Tetrahydroxy- C15H10O6 Identified 286.0491 287.0563 1.3 4.6 7.49 49998 +H 161.96 2
flavone
220 Cimicifugic acid B C21H20O11 Identified 448.1014 449.1087 0.8 1.9 7.49 64628 +H 265.13 8
221 5,7,2',5'-Tetrahydroxy- C15H10O6 Identified 286.0491 287.0563 1.3 4.6 7.49 158603 +H 269.27 2
flavone
222 5,7,2',5'-Tetrahydroxy- C15H10O6 Identified 286.0491 287.0563 1.3 4.6 7.49 16904 +H 205.59 1
flavone
223 5,7,2',5'-Tetrahydroxy- C15H10O6 Identified 286.0491 287.0563 1.3 4.6 7.49 44775 +H 237.87 1
flavone
224 Lamiophlomiol B C11H14O6 Identified 242.0792 243.0864 0.1 0.5 7.50 697 +H 271.10 2
225 Cichorioside B C21H28O10 Identified 440.1693 441.1766 1.1 2.4 7.57 813 +H 198.90 18
226 12-α-Hydroxyevodol C26H28O10 Identified 500.1693 501.1765 1.0 2.0 7.57 912 +H 219.67 6
227 Evodol C26H28O9 Identified 484.1721 485.1794 -1.2 -2.5 7.62 566 +H 211.80 5
228 Pueroside B C29H34O15 Identified 622.1913 623.1985 1.5 2.4 7.63 1081 +H 238.76 14
229 Tinoside C26H32O11 Identified 520.1942 521.2014 -0.3 -0.6 7.64 1185 +H 218.83 6
230 8-O-Acetyl shanzhiside C19H28O12 Identified 448.1599 449.1672 1.8 4.1 7.65 899 +H 210.06 9
methyl ester
231 Onitin-2′-O-β-D- C21H30O8 Identified 410.1923 411.1996 -1.8 -4.3 7.70 1494 +H 196.48 7
glucopyranoside
232 Cimicifugic acid B C21H20O11 Identified 448.1023 449.1096 1.8 3.9 7.72 3023 +H 233.86 5
233 5,7,2',5'-Tetrahydroxy- C15H10O6 Identified 286.0492 287.0565 1.5 5.2 7.74 13473 +H 238.86 1
flavone
234 Jasminoside E C16H26O7 Identified 330.1660 331.1733 -1.8 -5.5 7.81 490 +H 183.26 5
235 ArteamisinineⅠ C13H18O2 Identified 206.1308 207.1381 0.1 0.5 7.81 614 +H 147.21 2
236 Ligustroside C25H32O12 Identified 524.1878 525.1951 -1.6 -3.0 7.84 655 +H 226.50 9
237 Dihydrobrusatol C26H34O11 Identified 522.2082 523.2154 -1.9 -3.7 7.84 1929 +H 219.86 14
238 Oleanolic acid-28-O-β- C36H58O8 Identified 618.4094 619.4166 -3.8 -6.1 7.95 1261 +H 251.55 4
D-glucopyranoside (PJS
1)
239 Qinghaosu Ⅳ C15H22O5 Identified 282.1451 283.1524 -1.6 -5.8 7.95 775 +H 163.38 3
240 Poricoic acid B C30H44O5 Identified 484.3198 485.3271 0.9 1.9 7.96 707 +H 261.09 3
241 Esculentoside B C36H56O11 Identified 664.3812 665.3885 -1.0 -1.6 7.97 626 +H 254.46 8
242 Ganolucidic acid B C30H46O6 Identified 502.3294 503.3366 -0.1 -0.2 7.97 823 +H 227.90 3
243 Poricoic acid B C30H44O5 Identified 484.3189 485.3262 0.1 0.1 7.97 1142 +H 224.86 7
244 11α,12α-Epoxy-23β,23- C30H46O6 Identified 502.3294 503.3366 -0.1 -0.2 7.97 852 +H 255.07 5
dihydroxyolean-28,13β-
olide
245 Platycodigenin C30H48O7 Identified 520.3411 521.3484 1.1 2.2 7.99 820 +H 293.60 1
246 Esculentoside B C36H56O11 Identified 664.3821 665.3894 -0.1 -0.2 7.99 623 +H 286.30 2
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
247 Trachelosperoside E-1 C36H58O12 Identified 682.3924 683.3996 -0.5 -0.7 7.99 1264 +H 254.54 9
248 Trachelosperoside E-1 C36H58O12 Identified 682.3925 683.3997 -0.4 -0.5 7.99 1104 +H 290.06 2
249 Bruceine A C26H34O11 Identified 522.2098 523.2171 -0.3 -0.6 8.01 1359 +H 219.43 7
250 Bruceine E_1 C20H28O9 Identified 412.1739 413.1812 0.6 1.5 8.03 537 +H 196.66 8
251 Esculentoside B C36H56O11 Identified 664.3819 665.3892 -0.4 -0.6 8.07 519 +H 252.36 11
252 11α,12α-Epoxy-23β,23- C30H46O6 Identified 502.3290 503.3363 -0.4 -0.9 8.07 815 +H 262.52 4
dihydroxyolean-28,13β-
olide
253 11α,12α-Epoxy-23β,23- C30H46O6 Identified 502.3290 503.3363 -0.4 -0.9 8.07 950 +H 241.19 4
dihydroxyolean-28,13β-
olide
254 Ganolucidic acid B C30H46O6 Identified 502.3290 503.3363 -0.4 -0.9 8.07 836 +H 227.92 8
255 Lactiflorin C23H26O10 Identified 462.1520 463.1593 -0.6 -1.2 8.11 490 +H 204.89 14
256 Galloylpaeoniflorin C30H32O15 Identified 632.1732 633.1805 -0.9 -1.5 8.12 587 +H 234.60 10
257 6′-O-β-D-Glucosyl C22H30O14 Identified 518.1633 519.1706 -0.3 -0.5 8.17 555 +H 232.95 8
gentiopicroside
258 Cimicifugic acid B C21H20O11 Identified 448.1020 449.1093 1.5 3.3 8.18 3199 +H 288.21 0
259 5,7,2',5'-Tetrahydroxy- C15H10O6 Identified 286.0494 287.0566 1.6 5.7 8.18 38883 +H 205.11 0
flavone
260 Cimicifugic acid B C21H20O11 Identified 448.1020 449.1093 1.5 3.3 8.18 70676 +H 235.32 11
261 5,7,2',5'-Tetrahydroxy- C15H10O6 Identified 286.0494 287.0566 1.6 5.7 8.18 199129 +H 238.79 2
flavone
262 5,7,2',5'-Tetrahydroxy- C15H10O6 Identified 286.0494 287.0566 1.6 5.7 8.18 78939 +H 161.94 1
flavone
263 Cimicifugic acid B C21H20O11 Identified 448.1020 449.1093 1.4 3.2 8.18 2063 +H 326.29 1
264 Bilindestenolide C30H34O4 Identified 458.2463 459.2536 0.6 1.3 8.19 682 +H 208.13 4
265 Trachelosperoside E-1 C36H58O12 Identified 682.3932 683.4005 0.4 0.6 8.21 1235 +H 318.06 3
266 Galloyloxypaeoniflorin C30H32O16 Identified 648.1707 649.1779 1.6 2.5 8.24 1235 +H 249.47 7
267 Picrasin G C21H28O7 Identified 392.1843 393.1916 0.8 2.1 8.32 978 +H 191.49 4
268 6′-O-β-D-Glucosyl C22H30O14 Identified 518.1652 519.1725 1.7 3.3 8.33 1200 +H 215.49 5
gentiopicroside
269 Roseoside_1 C19H30O8 Identified 386.1952 387.2025 1.1 2.9 8.33 782 +H 220.38 4
270 Ganosporeric acid A C30H38O8 Identified 526.2568 527.2641 0.2 0.3 8.35 831 +H 223.52 9
271 Galloyloxypaeoniflorin C30H32O16 Identified 648.1697 649.1769 0.6 1.0 8.37 999 +H 239.09 16
272 5-O-Benzoyl-20- C27H32O5 Identified 436.2237 437.2310 -1.2 -2.8 8.38 719 +H 208.96 14
deoxyingenol
273 Galloyloxypaeoniflorin C30H32O16 Identified 648.1693 649.1766 0.2 0.4 8.39 1333 +H 294.93 6
274 Genkwadaphnin C34H34O10 Identified 602.2135 603.2207 -1.7 -2.9 8.40 945 +H 233.95 14
275 Picrasin G C21H28O7 Identified 392.1827 393.1899 -0.8 -2.2 8.40 906 +H 193.99 8
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
276 ApocynosideⅠ C19H30O8 Identified 386.1944 387.2017 0.3 0.9 8.41 996 +H 216.71 6
277 Roseoside_1 C19H30O8 Identified 386.1936 387.2009 -0.5 -1.2 8.45 1027 +H 226.69 8
278 Melianol C35H48O9 Identified 612.3346 613.3419 4.8 7.8 8.52 8191 +H 234.31 6
279 Picroside Ⅲ C25H30O13 Identified 538.1667 539.1740 -2.0 -3.6 8.56 549 +H 257.09 14
280 Cichorioside C C21H32O9 Identified 428.2051 429.2124 0.4 1.0 8.57 822 +H 199.76 8
281 Catalpol C15H22O10 Identified 362.1209 363.1282 -0.4 -1.1 8.57 1158 +H 196.12 7
282 6-Feruloyl catalpol C25H30O12 Identified 522.1750 523.1822 1.2 2.4 8.58 931 +H 293.75 3
283 Bruceine E_1 C20H28O9 Identified 412.1749 413.1822 1.5 3.7 8.62 1094 +H 192.23 4
284 Blumenol C glucoside C19H32O7 Identified 372.2122 373.2195 -2.6 -6.9 8.63 11887 +H 190.92 2
285 Ulmoside C21H32O14 Identified 508.1798 509.1871 0.6 1.2 8.64 597 +H 235.71 11
286 Chloranthalactone F C30H32O4 Identified 456.2336 457.2409 3.6 7.8 8.66 3876 +H 204.27 1
287 Sonchuside A C21H32O8 Identified 412.2105 413.2177 0.7 1.8 8.66 635 +H 204.68 5
288 m-Isopropyltoluene C10H14 Identified 134.1092 135.1165 -0.3 -2.3 8.70 492 +H 226.61 3
289 Bruceine E_1 C20H28O9 Identified 412.1734 413.1806 0.0 0.1 8.71 1589 +H 196.98 2
290 Picrasin G C21H28O7 Identified 392.1818 393.1891 -1.7 -4.3 8.71 837 +H 194.81 1
291 Ganoderenic acid F C30H38O7 Identified 510.2611 511.2684 -0.7 -1.3 8.71 979 +H 225.04 16
292 Ganoderenic acid F C30H38O7 Identified 510.2666 511.2739 4.8 9.4 8.71 1080 +H 292.02 6
293 Ganoderenic acid F C30H38O7 Identified 510.2659 511.2732 4.2 8.1 8.72 11499 +H 223.01 17
294 Physalin K (Physalin Q) C28H30O12 Identified 558.1780 559.1853 4.3 7.7 8.72 7802 +H 273.82 3
295 Blumenol C glucoside C19H32O7 Identified 372.2143 373.2215 -0.5 -1.5 8.72 15342 +H 218.11 10
296 Yadanzioside P C34H46O16 Identified 710.2789 711.2862 0.4 0.5 8.74 513 +H 273.29 2
297 Blumenol C glucoside C19H32O7 Identified 372.2157 373.2230 0.9 2.4 8.75 1991 +H 276.85 1
298 Picrasin G C21H28O7 Identified 392.1818 393.1890 -1.7 -4.4 8.75 539 +H 193.90 3
299 Catalpol C15H22O10 Identified 362.1214 363.1287 0.1 0.3 8.75 962 +H 189.82 1
300 Nigakilactone O C30H36O11 Identified 572.2276 573.2348 1.8 3.1 8.76 633 +H 242.81 12
301 GrayanotoxinⅠ C21H34O8 Identified 414.2235 415.2308 -1.9 -4.5 8.83 489 +H 198.92 6
302 Paeonidanin C24H30O11 Identified 494.1798 495.1870 1.0 1.9 8.83 619 +H 313.21 3
303 Blumenol C glucoside C19H32O7 Identified 372.2159 373.2232 1.1 2.9 8.84 651 +H 177.17 4
304 Harpagoside C24H30O11 Identified 494.1787 495.1860 -0.1 -0.2 8.84 4049 +H 215.23 10
305 Crocin A C44H64O24 Identified 976.3798 977.3871 1.1 1.1 8.84 787 +H 302.24 14
306 Physalin K (Physalin Q) C28H30O12 Identified 558.1779 559.1851 4.1 7.4 8.84 4240 +H 266.93 0
307 Blumenol C glucoside C19H32O7 Identified 372.2159 373.2232 1.1 2.9 8.84 1541 +H 319.45 4
308 Pseudoionone C13H20O Identified 192.1530 193.1603 1.6 8.3 8.84 797 +H 148.55 1
309 Blumenol C glucoside C19H32O7 Identified 372.2159 373.2232 1.1 2.9 8.84 5106 +H 219.38 6
310 Blumenol C glucoside C19H32O7 Identified 372.2158 373.2231 1.0 2.8 8.84 3711 +H 291.79 4
311 Blumenol C glucoside C19H32O7 Identified 372.2159 373.2232 1.1 2.9 8.85 6009 +H 242.17 3
312 Trachelosperoside E-1 C36H58O12 Identified 682.3934 683.4007 0.6 0.8 8.86 672 +H 317.66 6
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
313 Picrasinoside A C27H38O11 Identified 538.2423 539.2496 0.9 1.7 8.88 516 +H 232.95 14
314 Bruceine I C22H28O9 Identified 436.1717 437.1790 -1.6 -3.7 8.90 600 +H 204.10 7
315 Asperulosidic acid C18H24O12 Identified 432.1286 433.1358 1.8 4.1 8.90 895 +H 211.09 15
316 Semiaquilegoside A C26H38O9 Identified 494.2538 495.2611 2.2 4.5 8.91 1048 +H 226.40 7
317 Esculentoside O C35H54O10 Identified 634.3712 635.3785 -0.5 -0.8 8.96 632 +H 242.79 3
318 Nigakilactone N C21H30O7 Identified 394.1975 395.2048 -1.7 -4.2 8.98 1058 +H 283.61 1
319 Borneol 2-O-β-D- C21H36O10 Identified 448.2302 449.2375 -0.6 -1.4 8.98 535 +H 208.59 4
apiosyl-(16)-β-D-
glucoside
320 Loganic acid-6'-O-β-D- C22H34O15 Identified 538.1882 539.1955 -1.5 -2.8 8.99 894 +H 223.11 11
glucoside
321 Nigakilactone M C21H30O7 Identified 394.1998 395.2070 0.6 1.5 9.10 646 +H 205.54 3
322 Ulmoside C21H32O14 Identified 508.1788 509.1861 -0.4 -0.8 9.16 554 +H 219.23 16
323 Rehmannioside D C27H42O20 Identified 686.2264 687.2336 -0.6 -0.9 9.22 1465 +H 268.45 6
324 Rehmannioside D C27H42O20 Identified 686.2249 687.2322 -2.0 -2.9 9.25 842 +H 256.52 8
325 Oxyphyllenodiol B C14H22O3 Identified 238.1573 239.1646 0.4 1.9 9.26 817 +H 219.11 6
326 Nigakilactone F C22H32O7 Identified 408.2144 409.2217 -0.4 -1.0 9.27 836 +H 196.98 6
327 Onitin-2′-O-β-D- C21H30O8 Identified 410.1930 411.2003 -1.1 -2.7 9.31 937 +H 195.56 4
glucopyranoside
328 Pterodontoside A C21H32O8 Identified 412.2086 413.2158 -1.1 -2.8 9.31 1154 +H 200.02 4
329 trans-Chrysanthenyl C12H18O2 Identified 194.1302 195.1375 -0.5 -2.4 9.34 750 +H 151.98 1
acetate
330 Poricoic acid B C30H44O5 Identified 484.3197 485.3270 0.8 1.7 9.37 4646 +H 220.96 40
331 Poricoic acid E C30H44O6 Identified 500.3124 501.3197 -1.4 -2.8 9.39 922 +H 225.53 29
332 Eclalbasaponin Ⅴ C36H58O12 Identified 714.3634 715.3707 -1.5 -2.1 9.43 655 +H 257.95 7
S
333 Picroside Ⅱ C23H28O13 Identified 512.1530 513.1603 0.0 0.0 9.44 1285 +H 305.40 0
334 2α-Acetoxycostic acid C17H24O4 Identified 292.1674 293.1747 0.0 -0.2 9.46 764 +H 169.84 1
335 Picroside Ⅱ C23H28O13 Identified 512.1529 513.1602 -0.1 -0.2 9.47 661 +H 291.74 4
336 Picroside Ⅱ C23H28O13 Identified 512.1528 513.1600 -0.2 -0.5 9.50 901 +H 318.38 1
337 Poricoic acid B C30H44O5 Identified 484.3207 485.3280 1.8 3.8 9.54 2419 +H 221.63 17
338 3-Hydroxy-12,14- C29H42O4 Identified 454.3090 455.3163 0.7 1.5 9.55 550 +H 219.65 15
diene-27-nordeane-28-
nic acid
339 Ganolucidic acid B C30H46O6 Identified 502.3320 503.3392 2.5 5.0 9.55 1144 +H 225.83 10
340 Papyriogenin G C30H44O4 Identified 468.3259 469.3332 1.9 4.1 9.61 800 +H 227.34 3
341 3β-Hydroxyurs-12- C30H46O5 Identified 486.3336 487.3409 -0.9 -1.9 9.62 519 +H 219.96 5
en-27,28-dioic acid
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
342 Arnicolide D C19H24O5 Identified 332.1606 333.1679 -1.8 -5.3 9.64 514 +H 186.34 3
343 Nigakilactone H C22H32O8 Identified 424.2083 425.2156 -1.4 -3.3 9.67 569 +H 202.24 6
344 Picrasin G C21H28O7 Identified 392.1823 393.1896 -1.2 -3.1 9.67 1907 +H 194.11 4
345 Picroside Ⅱ C23H28O13 Identified 512.1517 513.1589 -1.3 -2.6 9.78 831 +H 312.71 2
346 Picroside Ⅱ C23H28O13 Identified 512.1521 513.1594 -0.8 -1.7 9.79 7259 +H 219.65 8
347 Kansuinin D C41H47NO1 Identified 793.2955 794.3028 0.9 1.2 9.86 937 +H 279.93 10
5
348 Curcolone C15H18O3 Identified 246.1260 247.1333 0.4 1.7 9.90 644 +H 156.98 0
349 Nigakilactone F C22H32O7 Identified 408.2166 409.2239 1.8 4.5 9.98 625 +H 195.69 4
350 Mudanpioside H C30H32O14 Identified 616.1784 617.1856 -0.9 -1.4 10.03 815 +H 251.46 9
351 2β-Acetoxypterodontic C17H24O4 Identified 292.1658 293.1730 -1.7 -5.8 10.05 503 +H 171.86 1
acid
352 3-O-(2′E,4′Z- C30H42O6 Identified 498.2992 499.3065 1.1 2.2 10.11 823 +H 229.14 13
Decadienoyl) ingenol
353 Bruceine I C22H28O9 Identified 436.1739 437.1812 0.6 1.4 10.11 770 +H 197.88 5
354 Rehmannioside D C27H42O20 Identified 686.2269 687.2341 -0.1 -0.1 10.15 668 +H 253.68 8
355 6'-O-Benzoyl-4''- C31H34O14 Identified 630.1972 631.2045 2.4 3.8 10.18 1157 +H 229.30 5
hydroxy-3''-
methoxypaeoniflorin
356 Catalpol C15H22O10 Identified 362.1197 363.1269 -1.6 -4.5 10.18 679 +H 184.09 8
357 Gentiopicroside C16H20O9 Identified 356.1118 357.1191 1.1 3.1 10.21 585 +H 226.84 1
358 Rel-2R-methyl-5S- C18H24O5 Identified 320.1609 321.1682 -1.5 -4.6 10.24 554 +H 179.61 2
acetoxy-4R-furano-
germacr-1(10)Z-en-6-
one
359 12-α-Hydroxyevodol C26H28O10 Identified 500.1689 501.1761 0.6 1.2 10.25 692 +H 205.16 7
360 Physalin W C28H30O10 Identified 526.1855 527.1928 1.6 3.1 10.28 593 +H 222.39 7
361 12-α-Hydroxyevodol C26H28O10 Identified 500.1689 501.1762 0.6 1.3 10.28 599 +H 271.69 3
362 Rehmannioside A C21H32O15 Identified 524.1729 525.1802 -1.2 -2.3 10.30 651 +H 222.02 8
363 12S- C20H32O6 Identified 368.2185 369.2258 -1.4 -3.7 10.34 3303 +H 191.81 2
Hydroxyandrographolid
e
364 Picrasinoside G C28H44O12 Identified 572.2807 573.2879 -2.6 -4.6 10.34 6582 +H 226.35 7
365 1β,3α,9β- C15H22O5 Identified 282.1486 283.1558 1.8 6.5 10.37 607 +H 167.41 3
Trihydroxyeudesma-5,1
1(13)-dien-12-oic acid
366 6-Feruloyl catalpol C25H30O12 Identified 522.1727 523.1800 -1.0 -1.9 10.39 1429 +H 223.46 10
367 Chloranthalactone F C30H32O4 Identified 456.2306 457.2379 0.6 1.3 10.40 880 +H 210.79 4
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
368 1,1,6-Trimethyl-1,2- C13H16 Identified 172.1267 173.1340 1.5 8.7 10.44 848 +H 144.40 0
dihydronaphthalene
369 Nigakilactone F C22H32O7 Identified 408.2132 409.2205 -1.6 -3.8 10.60 643 +H 204.42 2
370 Pseudoionone C13H20O Identified 192.1524 193.1597 1.0 5.2 10.61 1397 +H 147.46 3
371 Artemisitene C15H20O5 Identified 280.1330 281.1402 1.9 6.7 10.72 5772 +H 164.06 2
372 12S- C20H32O6 Identified 368.2187 369.2260 -1.2 -3.3 10.76 2576 +H 188.97 4
Hydroxyandrographolid
e
373 Picrasinoside B C28H40O11 Identified 552.2588 553.2661 1.7 3.2 10.77 773 +H 229.43 6
374 Methyl lucidenate P C30H44O8 Identified 532.3050 533.3123 1.4 2.6 10.81 993 +H 228.69 9
375 Artemisitene C15H20O5 Identified 280.1315 281.1388 0.4 1.5 10.83 2563 +H 164.67 0
376 Picrasin G C21H28O7 Identified 392.1822 393.1895 -1.3 -3.3 10.83 706 +H 196.11 8
377 Loganic acid-6'-O-β-D- C22H34O15 Identified 538.1900 539.1973 0.2 0.4 10.85 709 +H 219.81 2
glucoside
378 Ganosporelactone B C30H42O7 Identified 514.2940 515.3013 0.9 1.8 10.91 881 +H 228.29 8
379 Yadanzioside P C34H46O16 Identified 710.2791 711.2863 0.5 0.7 10.92 623 +H 255.56 11
380 Yadanzigan C26H38O14 Identified 574.2265 575.2337 0.3 0.5 10.93 512 +H 222.57 10
381 Yadanzioside P C34H46O16 Identified 710.2797 711.2870 1.1 1.6 10.96 541 +H 253.78 6
382 Notonipetranone C22H34O5 Identified 378.2390 379.2463 -1.6 -4.2 10.99 898 +H 190.00 5
383 (E)-Aldosecologanin C34H46O18 Identified 742.2694 743.2766 1.0 1.3 10.99 570 +H 275.86 11
384 Physalin H C28H31ClO1 Identified 562.1599 563.1672 -0.7 -1.2 11.03 756 +H 223.30 4
0
385 Nigakihemiacetal F C22H32O6 Identified 392.2199 393.2272 0.0 0.0 11.05 490 +H 193.09 6
386 Nigakilactone E C24H34O8 Identified 450.2267 451.2340 1.4 3.1 11.07 513 +H 201.69 5
387 12-α-Hydroxyevodol C26H28O10 Identified 500.1664 501.1737 -1.9 -3.7 11.08 777 +H 237.46 9
388 6'- C28H42O9 Identified 522.2825 523.2897 -0.4 -0.8 11.15 496 +H 226.61 7
Acetylneoandrographoli
de
389 Oxypaeoniflorin C23H28O12 Identified 496.1549 497.1622 -3.2 -6.4 11.20 1298 +H 211.40 9
390 Platycogenic acid B C30H46O8 Identified 534.3204 535.3277 1.1 2.1 11.23 545 +H 223.18 11
391 Neoquassin C22H30O6 Identified 390.2025 391.2097 -1.8 -4.5 11.24 750 +H 197.05 7
392 Nigakilactone F C22H32O7 Identified 408.2128 409.2201 -2.0 -4.9 11.25 522 +H 198.23 9
393 Neoquassin C22H30O6 Identified 390.2023 391.2096 -2.0 -5.0 11.28 787 +H 186.83 3
394 Ganoderenic acid C C30H44O7 Identified 516.3092 517.3165 0.5 1.0 11.32 1805 +H 226.93 3
395 Loganic acid-6'-O-β-D- C22H34O15 Identified 538.1909 539.1982 1.1 2.1 11.33 569 +H 231.84 2
glucoside
396 Nimbolin B C39H46O10 Identified 674.3108 675.3181 1.7 2.6 11.33 550 +H 248.68 4
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
397 3-O-(2′E,4′Z- C30H42O6 Identified 498.2989 499.3061 0.7 1.4 11.33 786 +H 225.28 2
Decadienoyl) ingenol
398 Ganosporelactone B C30H42O7 Identified 514.2917 515.2990 -1.3 -2.5 11.40 566 +H 225.09 5
399 Acetylharpagide C17H26O11 Identified 406.1489 407.1562 1.4 3.5 11.42 1077 +H 199.64 8
400 2β-(Isobutryloxy) C19H26O5 Identified 334.1764 335.1837 -1.6 -4.7 11.42 986 +H 181.48 6
florenalin
401 12S- C20H32O6 Identified 368.2169 369.2242 -3.0 -8.1 11.42 5723 +H 196.60 3
Hydroxyandrographolid
e
402 Kansuinin B C38H42O14 Identified 722.2591 723.2663 1.6 2.2 11.44 702 +H 260.35 12
403 3-O-(2′E,4′Z- C30H42O6 Identified 498.2981 499.3053 -0.1 -0.1 11.65 689 +H 223.70 6
Decadienoyl) ingenol
404 2α,3β- C15H22O4 Identified 266.1533 267.1606 1.5 5.6 11.66 507 +H 165.79 0
Dihydroxypterondontic
acid
405 Physalin E C28H32O11 Identified 544.1960 545.2033 1.5 2.8 11.67 1158 +H 217.37 7
406 Notonipetranone C22H34O5 Identified 378.2394 379.2467 -1.2 -3.3 11.73 538 +H 195.81 5
407 Yadanzioside I C29H38O16 Identified 642.2177 643.2250 1.7 2.7 11.78 770 +H 254.19 2
408 Ganoderic acid S C30H44O3 Identified 452.3281 453.3354 -1.0 -2.1 11.78 671 +H 219.84 3
409 Azedarachin C C32H42O10 Identified 586.2757 587.2830 -2.1 -3.6 11.80 3079 +H 275.57 2
410 Sericoside C36H58O11 Identified 666.3951 667.4023 -2.8 -4.3 11.90 1125 +H 316.12 2
411 Nimbolin B C39H46O10 Identified 674.3099 675.3172 0.8 1.2 11.91 639 +H 242.99 9
412 Picrasinol A C24H36O7 Identified 436.2462 437.2535 0.1 0.3 11.92 763 +H 200.99 5
413 Neoquassin C22H30O6 Identified 390.2049 391.2122 0.7 1.7 11.93 772 +H 192.37 4
414 Nigakilactone F C22H32O7 Identified 408.2151 409.2224 0.3 0.7 11.98 634 +H 217.67 3
415 Physalin E C28H32O11 Identified 544.1960 545.2033 1.6 2.9 12.11 1439 +H 224.96 6
416 Azedarachin C C32H42O10 Identified 586.2789 587.2862 1.1 1.9 12.12 10131 +H 237.44 14
417 Picrasinoside G C28H44O12 Identified 572.2849 573.2922 1.6 2.8 12.16 498 +H 235.25 3
418 Ganoderic acid S C30H44O3 Identified 452.3282 453.3355 -0.8 -1.8 12.19 826 +H 216.60 6
419 6α-Acetoxy-5- C30H38O9 Identified 542.2528 543.2601 1.3 2.3 12.27 774 +H 229.85 5
epilimonin
420 (rel 5S,6R,8R,9R,10S)-6- C22H34O5 Identified 378.2425 379.2497 1.8 4.8 12.28 852 +H 195.73 0
Acetoxy-9-hydroxy-13
(14)-labden-16,15-olide
421 Nigakihemiacetal F C22H32O6 Identified 392.2182 393.2255 -1.7 -4.2 12.34 684 +H 196.17 1
422 26,27-Dihydroxy- C30H44O4 Identified 468.3250 469.3322 1.0 2.1 12.37 666 +H 216.40 6
lanosta-7,9(11),24-
triene-3,16-dion
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
423 Pseudolaric acid A O-β- C28H38O11 Identified 550.2410 551.2482 -0.5 -0.8 12.38 494 +H 224.74 7
D-glucopyranoside
424 Picrasinoside C C28H42O11 Identified 554.2722 555.2795 -0.5 -0.9 12.39 6595 +H 226.19 4
425 Picrasinoside B C28H40O11 Identified 552.2576 553.2648 0.5 0.9 12.41 907 +H 226.31 4
426 Nigakilactone I C21H28O6 Identified 376.1885 377.1957 -0.1 -0.3 12.41 491 +H 197.56 2
427 m-Isopropyltoluene C10H14 Identified 134.1103 135.1175 0.7 5.2 12.41 618 +H 148.02 1
428 7-O-Methylmorroniside C18H28O11 Identified 420.1648 421.1720 1.6 3.8 12.44 655 +H 206.30 2
429 19β- C26H40O10 Identified 512.2595 513.2667 -2.7 -5.2 12.45 4886 +H 226.94 2
Glucosylandrographosid
e
430 Physalin E C28H32O11 Identified 544.1977 545.2049 3.2 5.9 12.45 5167 +H 221.84 0
431 2α-Acetoxycostic acid C17H24O4 Identified 292.1659 293.1732 -1.6 -5.3 12.47 627 +H 169.00 2
432 12S- C20H32O6 Identified 368.2183 369.2256 -1.6 -4.3 12.49 1393 +H 196.72 5
Hydroxyandrographolid
e
433 Mudanpioside D C24H30O12 Identified 510.1728 511.1801 -0.9 -1.8 12.49 11967 +H 216.80 3
434 3-Hydroxy-12,14- C29H42O4 Identified 454.3094 455.3167 1.1 2.4 12.49 519 +H 216.46 6
diene-27-nordeane-28-
nic acid
435 Picrasinol A C24H36O7 Identified 436.2447 437.2520 -1.4 -3.2 12.51 512 +H 221.61 1
436 Azedarachin C C32H42O10 Identified 586.2809 587.2881 3.1 5.2 12.53 15868 +H 239.60 4
437 Kansuinin E C41H47NO1 Identified 777.3010 778.3082 1.3 1.7 12.54 843 +H 284.43 2
4
438 Notonipetranone C22H34O5 Identified 378.2389 379.2462 -1.7 -4.6 12.56 579 +H 191.43 5
439 2-Hydroxyesculentic C30H46O7 Identified 518.3259 519.3332 1.6 3.0 12.57 552 +H 225.27 2
acid
440 Picrasinoside C C28H42O11 Identified 554.2726 555.2799 -0.1 -0.1 12.58 1013 +H 244.43 5
441 Chloranthalactone E C15H18O4 Identified 262.1207 263.1280 0.2 0.7 12.58 7737 +H 165.26 0
442 Ganoderic acid H C32H44O9 Identified 572.2974 573.3047 -1.2 -2.0 12.59 628 +H 239.36 3
443 Clinopodiside F C49H82O20 Identified 990.5386 991.5459 -1.4 -1.4 12.65 500 +H 314.84 1
444 19β- C26H40O10 Identified 512.2608 513.2680 -1.4 -2.7 12.68 1629 +H 227.77 5
Glucosylandrographosid
e
445 Picroside Ⅱ C23H28O13 Identified 512.1532 513.1604 0.2 0.3 12.70 757 +H 212.86 8
446 Cichorioside C C21H32O9 Identified 428.2028 429.2100 -1.9 -4.4 12.72 612 +H 202.63 7
447 (rel 5S,6R,8R,9R,10S)-6- C22H34O5 Identified 378.2395 379.2468 -1.1 -2.9 12.76 623 +H 194.00 2
Acetoxy-9-hydroxy-13
(14)-labden-16,15-olide
448 RhodomolleinⅠ C20H32O6 Identified 368.2197 369.2270 -0.2 -0.5 12.76 809 +H 194.95 2
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
449 19β- C26H40O10 Identified 512.2622 513.2695 0.1 0.1 12.77 1271 +H 224.14 5
Glucosylandrographosid
e
450 Mudanpioside D C24H30O12 Identified 510.1735 511.1808 -0.2 -0.4 12.78 13541 +H 216.15 8
451 Picrasinoside B C28H40O11 Identified 552.2582 553.2655 1.2 2.1 12.83 967 +H 227.48 6
452 14-Deoxy-17β- C20H32O6 Identified 368.2191 369.2264 -0.7 -2.0 12.86 1602 +H 195.57 1
hydroxyandrographolid
e
453 Mudanpioside H C30H32O14 Identified 616.1789 617.1862 -0.3 -0.5 12.90 816 +H 250.07 3
454 Prosapogenin 1 C38H58O12 Identified 706.3944 707.4017 1.6 2.3 12.90 680 +H 267.81 2
455 Nigakilactone J C23H34O7 Identified 422.2309 423.2382 0.5 1.1 12.92 1158 +H 203.86 0
456 14-Deoxy-11- C20H28O5 Identified 348.1932 349.2005 -0.5 -1.3 12.93 7935 +H 184.02 1
oxoandrographolide
457 Florilenalin isovalerate C20H28O5 Identified 348.1932 349.2005 -0.5 -1.3 12.93 7935 +H 184.02 1
458 Nigakilactone G C26H34O8 Identified 474.2251 475.2324 -0.2 -0.5 13.02 664 +H 221.48 8
459 Rhodojaponin Ⅱ C22H34O7 Identified 410.2298 411.2371 -0.6 -1.5 13.03 773 +H 200.84 5
460 Ganoderic acid S C30H44O3 Identified 452.3286 453.3358 -0.5 -1.0 13.04 627 +H 222.20 6
461 7β-(3-Ethyl-cis- C21H32O4 Identified 348.2307 349.2380 0.6 1.8 13.04 683 +H 196.52 2
crotonoyloxy)-14-
hydroxynotonipetranon
e
462 Fibraurin C20H20O7 Identified 372.1191 373.1264 -1.8 -4.9 13.12 628 +H 181.74 2
463 Nigakilactone J C23H34O7 Identified 422.2287 423.2360 -1.7 -4.1 13.14 1330 +H 204.51 1
464 RhodojaponinⅠ C24H36O8 Identified 452.2423 453.2496 1.3 2.8 13.14 770 +H 217.85 4
465 Picrasinoside B C28H40O11 Identified 552.2568 553.2641 -0.2 -0.4 13.15 2779 +H 224.01 7
466 Ligustroside C25H32O12 Identified 524.1847 525.1920 -4.6 -8.8 13.16 2129 +H 218.14 6
467 Tenuifolin C36H56O12 Identified 680.3778 681.3851 0.6 0.9 13.21 593 +H 258.57 5
468 Nigakihemiacetal F C22H32O6 Identified 392.2199 393.2272 0.0 0.1 13.22 548 +H 194.74 3
469 14-epi-Andrographolide C20H30O5 Identified 350.2100 351.2173 0.7 1.9 13.24 5259 +H 186.64 2
470 Ganoderic acid S C30H44O3 Identified 452.3300 453.3372 0.9 2.0 13.24 802 +H 233.79 2
471 RhodojaponinⅠ C24H36O8 Identified 452.2408 453.2481 -0.2 -0.5 13.30 652 +H 211.50 2
472 Pseudolaric acid A O-β- C28H38O11 Identified 550.2406 551.2478 -0.8 -1.5 13.30 821 +H 228.77 8
D-glucopyranoside
473 Ganoderic acid S C30H44O3 Identified 452.3299 453.3372 0.9 1.9 13.31 1347 +H 217.39 3
474 Nigakilactone J C23H34O7 Identified 422.2286 423.2359 -1.9 -4.4 13.31 752 +H 202.16 2
475 3-O-(2′E,4′Z- C30H42O6 Identified 498.2968 499.3040 -1.4 -2.8 13.32 579 +H 220.50 2
Decadienoyl) ingenol
476 Neoquassin C22H30O6 Identified 390.2045 391.2118 0.3 0.7 13.32 731 +H 192.18 4
477 Catalpol C15H22O10 Identified 362.1225 363.1298 1.2 3.3 13.42 878 +H 206.60 2
Observed Total
Identification Mass error Mass error Observed RT Observed CCS
. Component name Formula neutral Observed m/z Response Adducts Fragments
status (mDa) (ppm) (min) (Ų)
mass (Da) Found
478 Florilenalin isovalerate C20H28O5 Identified 348.1921 349.1994 -1.5 -4.4 13.42 7712 +H 187.17 3
479 Ligustroside C25H32O12 Identified 524.1881 525.1954 -1.2 -2.4 13.43 1279 +H 217.79 2
480 Catalpol C15H22O10 Identified 362.1218 363.1291 0.5 1.3 13.43 1734 +H 182.51 1
481 Sericoside C36H58O11 Identified 666.3960 667.4033 -1.9 -2.8 13.47 506 +H 263.87 3
482 Epianhydrobelachinal C30H44O4 Identified 468.3242 469.3315 0.3 0.6 13.47 960 +H 218.56 9
483 Picrasinoside B C28H40O11 Identified 552.2558 553.2630 -1.3 -2.4 13.52 2598 +H 227.66 8
484 Cimidahuside C C37H58O12 Identified 694.3974 695.4047 4.6 6.6 13.53 2249 +H 336.08 1
485 Cimidahuside C C37H58O12 Identified 694.3973 695.4046 4.5 6.5 13.53 21559 +H 265.92 13
486 24-O-Acetyl- C37H60O11 Identified 680.4099 681.4172 -3.6 -5.3 13.53 19622 +H 269.96 6
cimigenol-3-O-β-D-
xylopyranoside
487 Inuchinenolide C C19H26O7 Identified 366.1682 367.1755 0.4 1.0 13.53 658 +H 177.26 2
488 28- C30H46O5 Identified 486.3353 487.3425 0.7 1.5 13.53 1406 +H 231.12 5
Deacetylbelamcandal
489 14-Deoxy-11-hydro- C20H30O5 Identified 350.2082 351.2155 -1.1 -3.2 13.53 59647 +H 189.72 3
xyandrographolide
490 14-Deoxy-12R- C20H30O5 Identified 350.2082 351.2155 -1.1 -3.2 13.53 59647 +H 189.72 3
hydroxyandrographolid
e
491 24-O-Acetyl- C37H60O11 Identified 680.4099 681.4172 -3.6 -5.3 13.53 1170 +H 338.47 1
cimigenol-3-O-β-D-
xylopyranoside
492 Cimidahuside J C37H56O11 Identified 676.3837 677.3910 1.5 2.2 13.53 1218 +H 268.07 14
493 Aucubin C15H22O9 Identified 346.1248 347.1321 -1.6 -4.6 13.54 866 +H 267.96 9
494 Cimidahuside J C37H56O11 Identified 676.3839 677.3911 1.6 2.4 13.54 572 +H 186.72 7
495 Florilenalin angelate C20H26O5 Identified 346.1763 347.1836 -1.7 -4.9 13.56 1495 +H 183.03 1
496 Hypoglaucin H C39H60O15 Identified 768.3917 769.3990 -1.5 -2.0 13.59 857 +H 272.95 2
497 Rotundifuran C22H34O4 Identified 362.2451 363.2523 -0.7 -1.8 13.60 2748 +H 188.95 1
498 Florilenalin isovalerate C20H28O5 Identified 348.1916 349.1989 -2.1 -6.0 13.60 5282 +H 187.35 0
499 Nigakilactone J C23H34O7 Identified 422.2290 423.2363 -1.5 -3.4 13.60 1246 +H 204.73 3
500 ent-16α,17-Hydroxy-19- C20H32O3 Identified 320.2360 321.2433 0.9 2.7 13.62 622 +H 182.33 4
kauranoic acid
Detils of Idened Components
Item name: MENGKUDU 2
Channel name: Orientanone [+H] : (39.7 PPM) 349.1119 : DT=5.95 to 6.43 ms
Orientanone
0.53
400

300
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.5274 +/- 0.0285 minutes :
Channel name: Orientanone [+H] : (39.7 PPM) 349.1119 Component name: Orientanone Drift Times: 6.19 +/- 0.24 ms
11.28
527.15886
5000
40000

Intensity [Counts]
4000
0.53
Intensity [Counts]

266.07636
20000
3000 4.14 543.13418
282.04971
351.12635
0.62 247.08041 587.13787
2000
4.34 0
0.93 2.84 6.65 200 400 600 800 1000
1000 9.08
1.57 4.74 7.85 Item name: MENGKUDU 2 Channel name: High energy : Time 0.5274 +/- 0.0285
9.78 13.72 Component name: Orientanone minutes : Drift Times: 6.04 +/- 0.24 ms
12.32
16.51
18.52
0 20000 527.16083

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000 282.05089

233.04819
348.13072 529.16955

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 10-O-Acetylgeniposidic acid [+H] : (39.7 PPM) 417.1381 : DT=7.20
to 7.68 ms

1000
Intensity [Counts]

750
10-O-Acetylgeniposidic acid
0.58
500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

10-O-Acetylgeniposidic acid
0 0.60
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.5872 +/-
Channel name: 10-O-Acetylgeniposidic acid [+H] : (39.7 PPM) 417.1381 Component name: 10-O-Acetylgeniposidic 0.0285 minutes : Drift Times: 7.40 +/- 0.24 ms
5.92 acid

321.11695
5000 662.20543

Intensity [Counts]
0.57 10000
4000 8.81 9.42
Intensity [Counts]

9.58
3000 497.14184
8.37 5000 417.13807
302.12290 663.20433
569.16889
8.24 701.20832
12.67
2000
2.54 3.84 6.82 10.45 0
2.59 6.96 13.76 200 400 600 800 1000
1000 2.07 14.18 16.47 Item name: MENGKUDU 2 Channel name: High energy : Time 0.5872 +/-
Component name: 10-O-Acetylgeniposidic 0.0285 minutes : Drift Times: 7.24 +/- 0.24 ms
acid
0
321.11729
0 5 10 15 20
Retention time [min]
20000

Intensity [Counts] 10000


180.10095
417.13893
530.16120

662.20264
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 10-O-Acetylgeniposidic acid [+H] : (39.7 PPM) 417.1382 : DT=6.58
to 7.06 ms

10-O-Acetylgeniposidic acid
0.59

300
Intensity [Counts]

200

0.68

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.5913 +/-
Channel name: 10-O-Acetylgeniposidic acid [+H] : (39.7 PPM) 417.1382 Component name: 10-O-Acetylgeniposidic 0.0285 minutes : Drift Times: 6.82 +/- 0.24 ms
5.92 acid

575.15892
5000

20000

Intensity [Counts]
4000 0.57 8.81 9.42
Intensity [Counts]

9.58
3000 8.37 10000
561.18452
324.10559 585.13966
8.24 417.13823
12.68 683.20335
2000 318.09457
2.54 3.84 6.82 10.45 0
2.59 6.96 11.66 13.76 200 400 600 800 1000
1000 2.07 14.18 16.47 Item name: MENGKUDU 2 Channel name: High energy : Time 0.5913 +/-
Component name: 10-O-Acetylgeniposidic 0.0285 minutes : Drift Times: 6.67 +/- 0.24 ms
acid
0
591.14068
0 5 10 15 20
Retention time [min] 5000 409.13219

Intensity [Counts]
361.11160 577.17104

2500
263.06049 433.11633 643.20622
206.04463 689.21016
179.07490
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-Acetyl harpagide [+H] : (39.7 PPM) 409.1314 : DT=5.18 to 5.66 ms

6000

4000
Intensity [Counts]

2000

8-Acetyl harpagide
0.60

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.5997 +/- 0.0285
Channel name: 8-Acetyl harpagide [+H] : (39.7 PPM) 409.1314 Component name: 8-Acetyl harpagide minutes : Drift Times: 5.41 +/- 0.24 ms
12.04
75000 429.10160

12500 445.09269

Intensity [Counts]
50000
10000
Intensity [Counts]

409.13136 461.07235
7500 25000
407.11638
392.11960 463.07021
5000 176.07465
3.54 0
0.61 3.25 9.12 200 400 600 800 1000
9.86
2500 3.65
9.24 Item name: MENGKUDU 2 Channel name: High energy : Time 0.5997 +/- 0.0285
2.73 4.40 3.84 7.22 Component name: 8-Acetyl harpagide minutes : Drift Times: 5.26 +/- 0.24 ms
12.99
13.50
14.92 30000 429.10269
0
0 5 10 15 20
Retention time [min] 445.09596

Intensity [Counts]
20000
409.13223

10000 392.12086

515.13819
233.04374

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0928 : DT=6.30 to 6.78 ms
Paeonisuffral
0.85
2000

1500
Intensity [Counts]

1000

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.8565 +/- 0.0285
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0928 Component name: Paeonisuffral minutes : Drift Times: 6.53 +/- 0.24 ms
1.45
508.24003
3000

75000

Intensity [Counts]
1.71
50000
Intensity [Counts]

2000
575.15923
215.09276
25000 197.08255 651.11696
179.07141 377.14381
775.26362
1000 1.81 0
4.71 6.52 7.60 200 400 600 800 1000
2.23 11.13
9.90 Item name: MENGKUDU 2 Channel name: High energy : Time 0.8565 +/- 0.0285
5.43 9.17
13.26 14.90 16.55 Component name: Paeonisuffral minutes : Drift Times: 6.38 +/- 0.24 ms

0 40000 635.14571

0 5 10 15 20
Retention time [min]

Intensity [Counts]
575.16151
20000

651.12050
133.06495 379.08003 561.17750
652.12016
195.94583 491.09150
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic
methyl ester [+H] : (39.7 PPM) 197.0826 : DT=6.29 to 6.77 ms

1500
1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic m…
0.85

1000
Intensity [Counts]

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.8590 +/-
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 6.53 +/- 0.24 ms
methyl ester [+H] : (39.7 PPM) 197.0826 hydroxyl-cyclopenta [c]pyran-4-carboxylic
0.93 methyl ester
1.45
508.24003
2000

Intensity [Counts]
1500 50000
Intensity [Counts]

1.70 575.15923
215.09276
197.08255 651.11696
1000
1.81 377.14381
775.26362
2.07 0
200 400 600 800 1000
500 2.94 3.60 6.55 7.62
8.96 Item name: MENGKUDU 2 Channel name: High energy : Time 0.8590 +/-
5.30 11.65 Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 6.38 +/- 0.24 ms
12.32 16.56 17.98
hydroxyl-cyclopenta [c]pyran-4-carboxylic
0 methyl ester
0 5 10 15 20 635.14571
40000
Retention time [min]

Intensity [Counts]
575.16151
20000
133.06495 651.12050
379.08003 561.17750
652.12016
195.94583 491.09150
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: trans-2-Methoxy cinnamaldehyde [+H] : (39.7 PPM) 163.0749 :
DT=3.94 to 4.42 ms
trans-2-Methoxy cinnamaldehyde
0.92

0.97
750
Intensity [Counts]

500

250
1.06

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.9294 +/-
Channel name: trans-2-Methoxy cinnamaldehyde [+H] : (39.7 PPM) 163.0749 Component name: trans-2-Methoxy 0.0285 minutes : Drift Times: 4.18 +/- 0.24 ms
0.93 cinnamaldehyde
1250
237.07554
0.97
40000

1000

Intensity [Counts]
Intensity [Counts]

750 20000 105.07043


413.09927
483.09603
311.02328
500
5.80
0
3.17 5.73 6.07 7.95 16.51 200 400 600 800 1000
8.51 10.38 12.14
250 5.38 7.10
Item name: MENGKUDU 2 Channel name: High energy : Time 0.9294 +/-
12.89 17.01 Component name: trans-2-Methoxy 0.0285 minutes : Drift Times: 4.03 +/- 0.24 ms
cinnamaldehyde
0
10000 417.06401
0 5 10 15 20 77.03868
Retention time [min]

Intensity [Counts]
219.05179
5000 311.02353

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic
methyl ester [+H] : (39.7 PPM) 197.0821 : DT=4.17 to 4.65 ms

1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic me…


0.94

300
1.02
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.9353 +/-
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 4.41 +/- 0.24 ms
methyl ester [+H] : (39.7 PPM) 197.0821 hydroxyl-cyclopenta [c]pyran-4-carboxylic
0.93 methyl ester
1.45
341.10692
2000

Intensity [Counts]
1500
Intensity [Counts]

20000
1.70 163.07487 413.09927
311.02328 437.11460
1000 482.08973
1.81 665.15401
484.09683
2.07 0
200 400 600 800 1000
500 2.94 3.60 6.55 7.62
8.96 Item name: MENGKUDU 2 Channel name: High energy : Time 0.9353 +/-
4.04 11.65
Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 4.25 +/- 0.24 ms
12.38 16.56 17.98
hydroxyl-cyclopenta [c]pyran-4-carboxylic
0 methyl ester
0 5 10 15 20 205.01832
Retention time [min] 10000 417.06401
77.03868

Intensity [Counts] 5000


437.10995
453.08377

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1344 : DT=4.85 to 5.33 ms

Sesamoside
0.95
250

200
Intensity [Counts]

150

100

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.9498 +/- 0.0285 minutes :
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1344 Component name: Sesamoside Drift Times: 5.09 +/- 0.24 ms
8.06
413.09948
4000
20000

Intensity [Counts]
3000
Intensity [Counts]

9.15 355.10215 421.13445


10000
311.02330
0.96
2000 6.81 827.20774
302.11901
2.09 430.13772 645.14795
4.54 6.55
215.09264 807.20234
0
3.17 9.23 200 400 600 800 1000
1000
11.83 Item name: MENGKUDU 2 Channel name: High energy : Time 0.9498 +/- 0.0285 minutes :
9.39
12.36 Component name: Sesamoside Drift Times: 4.94 +/- 0.24 ms
13.3315.07 18.50
0 251.00166

0 5 10 15 20 30000
Retention time [min]

Intensity [Counts]
20000 237.07519
286.16618

10000 179.07162 311.02358

381.10360 447.07682

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1342 : DT=3.72 to 4.20 ms
Sesamoside
500
0.97

400
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.9758 +/- 0.0285 minutes :
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1342 Component name: Sesamoside Drift Times: 3.94 +/- 0.24 ms
8.06
431.06564
4000
40000
387.05445
435.07495

Intensity [Counts]
3000
Intensity [Counts]

453.08630
9.15 20000 105.07043 179.07117
0.96 256.08391 465.08597
2000 6.81 483.09603
2.09 4.54 6.55

6.04 0
3.17 9.23 200 400 600 800 1000
1000
11.83 Item name: MENGKUDU 2 Channel name: High energy : Time 0.9758 +/- 0.0285 minutes :
9.39
12.36 Component name: Sesamoside Drift Times: 3.79 +/- 0.24 ms
13.3315.07 18.50
0 30000 251.00163

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000 387.05529

220.99061
10000
405.06358
435.07394
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1343 : DT=5.43 to 5.91 ms
8.06

3000
Intensity [Counts]

2000

6.81

1000
4.54 6.55
8.76
5.04
2.07 4.34
10.92 12.07
14.10 13.20
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 0.9762 +/- 0.0285 minutes :
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1343 Component name: Sesamoside Drift Times: 5.67 +/- 0.24 ms
8.06
387.05446
4000
435.07494
515.13717
40000

Intensity [Counts]
3000
Intensity [Counts]

9.15 357.04278
20000
0.96
2000 6.81
239.00070 529.04001 827.20774
2.09 4.54 6.55

6.04 0
3.17 9.23 200 400 600 800 1000
1000
11.83 Item name: MENGKUDU 2 Channel name: High energy : Time 0.9762 +/- 0.0285 minutes :
9.39
12.36 Component name: Sesamoside Drift Times: 5.52 +/- 0.24 ms
13.3315.07 18.50
0 387.05531
251.00162
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000 220.99066
417.06401

177.00039
91.05351 433.15162
447.07696 827.20885
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Secologanoside [+H] : (39.7 PPM) 391.1245 : DT=5.51 to 5.99 ms

7500
Intensity [Counts]

5000

2500

Secologanoside
0 1.00
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.0011 +/- 0.0285
Channel name: Secologanoside [+H] : (39.7 PPM) 391.1245 Component name: Secologanoside minutes : Drift Times: 5.75 +/- 0.24 ms
7.60
453.08631
12500 40000 515.13717
405.06416

Intensity [Counts]
10000
Intensity [Counts]

20000 387.10290
7500
592.17245
4.85 12.04
239.00070 618.62675 827.20774
5000
13.62 207.06281
0
5.73 200 400 600 800 1000
2500 4.57
3.24 Item name: MENGKUDU 2 Channel name: High energy : Time 1.0011 +/- 0.0285
8.60 16.50
3.66 6.38 Component name: Secologanoside minutes : Drift Times: 5.60 +/- 0.24 ms
0.93 9.39 14.92
0 251.00162

0 5 10 15 20 30000
Retention time [min] 515.13955
357.04409

Intensity [Counts]
20000 220.99066

179.07194 485.12970
10000

827.20885
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Adoxosidic acid [+H] : (39.7 PPM) 377.1444 : DT=6.06 to 6.54 ms
2500

2000
Intensity [Counts]

1500

1000

500 Adoxosidic acid


1.01

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.0108 +/- 0.0285
Channel name: Adoxosidic acid [+H] : (39.7 PPM) 377.1444 Component name: Adoxosidic acid minutes : Drift Times: 6.31 +/- 0.24 ms
5.50
60000 482.08919

405.11024

20000

Intensity [Counts]
40000
Intensity [Counts]

545.14567
10000 377.14437
215.09166
297.05712 619.13066
136.06305 701.17152
20000 748.08864
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 1.0108 +/- 0.0285
1.44 5.25 Component name: Adoxosidic acid minutes : Drift Times: 6.16 +/- 0.24 ms
2.69 6.19
0 431.06620

0 5 10 15 20 20000
Retention time [min]

Intensity [Counts]
387.10141

10000 360.09500
257.06764
545.14939
584.17780
807.20791
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0917 : DT=6.14 to 6.62 ms

0.85

1500
Intensity [Counts]

1000

500
Paeonisuffral
1.03

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.0296 +/- 0.0285
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0917 Component name: Paeonisuffral minutes : Drift Times: 6.38 +/- 0.24 ms
1.45
545.14567
3000 10000

377.14437

Intensity [Counts]
215.09166 404.10503
1.71 591.14430
Intensity [Counts]

2000 5000
297.05712 613.13690
136.06305 807.20129
680.69118
823.18587

1000 1.81 7.60 0


4.71
6.52 11.13 200 400 600 800 1000
2.23
9.18 10.99 Item name: MENGKUDU 2 Channel name: High energy : Time 1.0296 +/- 0.0285
5.43
13.26 14.90 16.55 Component name: Paeonisuffral minutes : Drift Times: 6.22 +/- 0.24 ms

0 431.06620

0 5 10 15 20 20000
Retention time [min]

Intensity [Counts]
10000
136.06300
405.06469 545.14939

645.14111 807.20791
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1337 : DT=7.10 to 7.58 ms

200

150
Intensity [Counts]

100
0.95

50
Sesamoside
1.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.0505 +/- 0.0285 minutes :
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1337 Component name: Sesamoside Drift Times: 7.34 +/- 0.24 ms
8.06
268.10500
4000

30000

Intensity [Counts]
3000
20000
Intensity [Counts]

9.15
0.96
2000 10000
6.81 430.06237
644.24256 727.16388
2.09 4.54 136.06306
6.55 798.26400 995.27004
6.04 0
3.18 9.23 200 400 600 800 1000
1000
11.83 Item name: MENGKUDU 2 Channel name: High energy : Time 1.0505 +/- 0.0285 minutes :
9.39
10.65 Component name: Sesamoside Drift Times: 7.18 +/- 0.24 ms
13.3315.07 18.50
0 177.00011

0 5 10 15 20 4000
Retention time [min]

Intensity [Counts]
267.04339 335.07264
2000 435.12643 799.14684

437.06591 637.09126 831.17093

837.16695

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Physalin E [+H] : (39.7 PPM) 545.2028 : DT=6.41 to 6.89 ms
12.45

2000

1500
Intensity [Counts]

11.92
1000
8.83 11.85
8.72
8.47 8.92 12.57
7.40 9.33
500 1.26 12.76
6.15 9.41 16.53
1.66 6.90
12.89 16.88 18.53
17.67
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.2521 +/- 0.0285 minutes :
Channel name: Physalin E [+H] : (39.7 PPM) 545.2028 Component name: Physalin E Drift Times: 6.63 +/- 0.24 ms
12.44
635.14393

4000
30000

Intensity [Counts]
617.13393

3000 11.92
20000
Intensity [Counts]

11.85
10000 545.20282 641.13011
2000
400.04848 649.07098
8.71 258.07140
8.83 831.16270
12.61 0
8.66 11.66
8.47 9.13 16.53 200 400 600 800 1000
1000 12.72
1.66 3.58 6.90
13.02 16.61 Item name: MENGKUDU 2 Channel name: High energy : Time 1.2521 +/- 0.0285 minutes :
2.45 16.88 18.53 Component name: Physalin E Drift Times: 6.48 +/- 0.24 ms

0 15000 383.04453
353.03419
0 5 10 15 20 431.06692
Retention time [min]

Intensity [Counts]
10000

636.14857
5000 131.05014 651.11350 821.18658
433.06545
239.05329 654.09357
529.03929

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Anemonin [+H] : (39.7 PPM) 193.0514 : DT=3.26 to 3.74 ms

3000
Intensity [Counts]

2000

1000

Anemonin
0 1.33

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.3261 +/- 0.0285 minutes :
Channel name: Anemonin [+H] : (39.7 PPM) 193.0514 Component name: Anemonin Drift Times: 3.50 +/- 0.24 ms
3.27
6000 193.05140

6000

Intensity [Counts]
3.93 4000
Intensity [Counts]

119.04983 211.06101
4000 2000 397.11325
414.10329
6.04
1.89 0
2000 1.83
200 400 600 800 1000
4.54
6.16 Item name: MENGKUDU 2 Channel name: High energy : Time 1.3261 +/- 0.0285 minutes :
8.51 9.81 Component name: Anemonin Drift Times: 3.35 +/- 0.24 ms
7.09 12.67 14.89
1
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
0.5

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0926 : DT=4.74 to 5.22 ms

Paeonisuffral
1.45
400 1.41

300
Intensity [Counts]

1.35

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.4371 +/- 0.0285
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0926 Component name: Paeonisuffral minutes : Drift Times: 4.98 +/- 0.24 ms
1.45
369.11792
3000 75000

Intensity [Counts]
383.15209
1.71 50000
Intensity [Counts]

2000
396.11759
25000 332.19902
433.06847
197.08277
577.67178 789.20013 860.12024
1000 1.81 0
4.71 6.52 7.60 200 400 600 800 1000
2.23 11.13
Item name: MENGKUDU 2 Channel name: High energy : Time 1.4371 +/- 0.0285
5.43 9.18 9.90 Component name: Paeonisuffral minutes : Drift Times: 4.83 +/- 0.24 ms
13.26 14.90 16.55

0 399.12886
2e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

369.11732 413.05605

216.98147 415.09438
807.20292
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0925 : DT=5.67 to 6.15 ms
Paeonisuffral
1.45

600
Intensity [Counts]

400

1.36 1.72
200 1.28 1.81
1.24

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.4422 +/- 0.0285
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0925 Component name: Paeonisuffral minutes : Drift Times: 5.94 +/- 0.24 ms
1.45
20000 404.10422
3000

15000

Intensity [Counts]
215.09253
1.71
396.11748
10000
Intensity [Counts]

2000 377.14473
368.22004 469.10576
657.16076
5000 179.07080 701.17055
789.19791

1000 1.81 0
4.71 6.52 7.60 200 400 600 800 1000
2.23 11.13
Item name: MENGKUDU 2 Channel name: High energy : Time 1.4422 +/- 0.0285
5.43 9.18 9.90 Component name: Paeonisuffral minutes : Drift Times: 5.78 +/- 0.24 ms
13.26 14.90 16.55

0 431.06674

0 5 10 15 20 40000
Retention time [min]

Intensity [Counts]
20000
197.08255
432.06999
353.08756
443.02907
649.07345 860.11734
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1447 : DT=6.54 to 7.02 ms

1500
Intensity [Counts]

1000

8-Epi-loganic acid
500 1.44

1.59
1.68

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.4424 +/- 0.0285
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1447 Component name: 8-Epi-loganic acid minutes : Drift Times: 6.81 +/- 0.24 ms
5.50
60000 566.13882

2e5

Intensity [Counts]
40000
Intensity [Counts]

100000

582.13174

20000 197.08286 377.14467 806.19580 889.72355


0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 1.4424 +/- 0.0285
1.44 5.25 Component name: 8-Epi-loganic acid minutes : Drift Times: 6.66 +/- 0.24 ms
2.69 6.19
0 431.06672

0 5 10 15 20 40000 413.05599
Retention time [min]

Intensity [Counts]
383.04450
20000
251.00178
197.08254
582.13600
557.11431
584.19165 801.16153
983.23820
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1447 : DT=5.82 to 6.30 ms

4000

3000
Intensity [Counts]

2000

1000

8-Epi-loganic acid
1.44
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.4443 +/- 0.0285
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1447 Component name: 8-Epi-loganic acid minutes : Drift Times: 6.05 +/- 0.24 ms
5.50
60000 215.09253 396.11748

529.11449
377.14473
10000

Intensity [Counts]
40000 368.22004
Intensity [Counts]

657.16076
5000
179.07080 680.18883
983.23691

20000
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 1.4443 +/- 0.0285
1.44 5.25 Component name: 8-Epi-loganic acid minutes : Drift Times: 5.90 +/- 0.24 ms
2.69 6.19
0 431.06674

0 5 10 15 20 40000
Retention time [min]

Intensity [Counts]
20000
432.06999
353.08756
216.98117 443.02907
529.11664 860.11844
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-Debenzoylpaeoniflorin [+H] : 8-Epi-loganic acid [+H] : (39.7 PPM)
377.1447 : DT=7.40 to 7.89 ms

1500
Intensity [Counts]

1000
1.65

500 1.36

1.26
1.74

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.4450 +/-
Channel name: 8-Debenzoylpaeoniflorin [+H] : 8-Epi-loganic acid [+H] : (39.7 PPM) Component name: 8-Debenzoylpaeoniflorin 0.0285 minutes : Drift Times: 7.65 +/- 0.24 ms
377.1447
5.50 399.12809
60000

Intensity [Counts]
100000

40000
Intensity [Counts]

806.19588
50000
819.16904
777.24715
383.15188 415.10730 843.18013
215.09278 377.14467 615.18793 775.26123
949.24403
20000 0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 1.4450 +/-
1.44 Component name: 8-Debenzoylpaeoniflorin 0.0285 minutes : Drift Times: 7.49 +/- 0.24 ms
2.69 5.25
6.19
0 399.12886

0 5 10 15 20 1.5e5
Retention time [min]

Intensity [Counts]
100000 431.06655

50000 179.07164 382.03754


369.11737 467.04366 806.19635
907.15709
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2 Channel name: Low energy : Time 1.4450 +/- 0.0285
Component name: 8-Epi-loganic acid minutes : Drift Times: 7.65 +/- 0.24 ms

399.12809

Intensity [Counts]
100000

806.19588
50000
819.16904
777.24715
383.15188 415.10730 843.18013
215.09278 377.14467 615.18793 775.26123
949.24403
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 1.4450 +/- 0.0285
Component name: 8-Epi-loganic acid minutes : Drift Times: 7.49 +/- 0.24 ms

399.12886

1.5e5

Intensity [Counts]
100000 431.06655

50000 179.07164 382.03754


369.11737 467.04366 806.19635
907.15709
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic
methyl ester [+H] : (39.7 PPM) 197.0828 : DT=5.27 to 5.75 ms

1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic me…


400 1.43

1.33 1.47

300
Intensity [Counts]

200 1.54

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.4463 +/-
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 5.51 +/- 0.24 ms
methyl ester [+H] : (39.7 PPM) 197.0828 hydroxyl-cyclopenta [c]pyran-4-carboxylic
0.93 methyl ester
1.45
1.5e5 431.06552
2000

Intensity [Counts]
100000
1500 415.10751
Intensity [Counts]

1.70
50000
592.17295
1000 404.10422
1.81 197.08277 598.15281 807.20224
353.09080 584.18468
953.21768
2.07 0
200 400 600 800 1000
500 2.94 3.60 6.55 7.62
8.96 Item name: MENGKUDU 2 Channel name: High energy : Time 1.4463 +/-
5.30 11.65 Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 5.36 +/- 0.24 ms
12.32 16.56 17.98
hydroxyl-cyclopenta [c]pyran-4-carboxylic
0 methyl ester
0 5 10 15 20 431.06665
Retention time [min]
40000 413.05615

Intensity [Counts]
251.00206
20000 216.98115
133.06537
447.13060 807.20287
649.07345
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic
methyl ester [+H] : (39.7 PPM) 197.0828 : DT=4.81 to 5.29 ms

1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic me…


1.45
400
Intensity [Counts]

300

200
1.57

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.4470 +/-
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 5.05 +/- 0.24 ms
methyl ester [+H] : (39.7 PPM) 197.0828 hydroxyl-cyclopenta [c]pyran-4-carboxylic
0.93 methyl ester
1.45
4e5 399.12816
2000

Intensity [Counts]
1500
Intensity [Counts]

2e5
1.70
369.11792
1000 413.05566
1.81 197.08277 332.19902 607.09845
505.11910 860.12024
2.07 0
200 400 600 800 1000
500 2.94 3.60 6.55 7.62
8.96 Item name: MENGKUDU 2 Channel name: High energy : Time 1.4470 +/-
5.30 11.65 Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 4.89 +/- 0.24 ms
12.32 16.56 17.98
hydroxyl-cyclopenta [c]pyran-4-carboxylic
0 methyl ester
0 5 10 15 20 399.12886
2e5
Retention time [min]

Intensity [Counts]
100000

369.11732
415.09438
216.98147
807.20292
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0925 : DT=6.93 to 7.41 ms
1.35
Paeonisuffral
250 1.45

1.65

200 1.30
Intensity [Counts]

1.25
150

100

1.74

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.4546 +/- 0.0285
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0925 Component name: Paeonisuffral minutes : Drift Times: 7.17 +/- 0.24 ms
1.45
674.13961
3000

10000

Intensity [Counts]
659.12651
1.71
215.09254 592.17293
Intensity [Counts]

2000 382.03752 741.18238


5000
402.10018 780.23998
378.14724 797.18701

1000 1.81 0
4.71 6.52 7.60 200 400 600 800 1000
2.23 11.13
Item name: MENGKUDU 2 Channel name: High energy : Time 1.4546 +/- 0.0285
5.43 9.18 9.90 Component name: Paeonisuffral minutes : Drift Times: 7.02 +/- 0.24 ms
13.26 14.90 16.55

0 20000 383.04450

0 5 10 15 20
Retention time [min]

Intensity [Counts]
215.09295
10000
216.98125
412.04820

371.04420 592.17593 776.18605


107.04930
657.18278 789.19027
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Secologanic acid [+H] : (39.7 PPM) 375.1291 : DT=5.92 to 6.40 ms

300
Intensity [Counts]

Secologanic acid
1.53
200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.5222 +/- 0.0285
Channel name: Secologanic acid [+H] : (39.7 PPM) 375.1291 Component name: Secologanic acid minutes : Drift Times: 6.16 +/- 0.24 ms
3.75
5000 527.10122

20000
4000

Intensity [Counts]
547.15708
Intensity [Counts]

3000 10000
3.61
438.19882
562.09014
2000 7.60 375.12911 831.17157
8.26 746.17077
1.58 355.10866
0
2.60 5.45 6.09 13.43 200 400 600 800 1000
1000 11.38
5.09 9.30 Item name: MENGKUDU 2 Channel name: High energy : Time 1.5222 +/- 0.0285
13.59
Component name: Secologanic acid minutes : Drift Times: 6.00 +/- 0.24 ms
14.71
0 545.11419
10000
0 5 10 15 20
193.05019
Retention time [min]

Intensity [Counts]
535.18557
216.98126
5000
379.03486

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sweroside [+H] : (39.7 PPM) 359.1323 : DT=4.77 to 5.25 ms

800

600
Intensity [Counts]

400

Sweroside
1.53
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.5255 +/- 0.0285 minutes :
Channel name: Sweroside [+H] : (39.7 PPM) 359.1323 Component name: Sweroside Drift Times: 5.01 +/- 0.24 ms
1.73
257.06722
4000
75000

Intensity [Counts]
3000 50000
Intensity [Counts]

25000
2000
355.10899
6.47 252.08689 687.12563
2.35 3.39 393.13176 595.14984
7.36 8.94 0
4.64 5.49
1000 200 400 600 800 1000
0.92 9.76 10.42
14.12 Item name: MENGKUDU 2 Channel name: High energy : Time 1.5255 +/- 0.0285 minutes :
10.31 16.52 Component name: Sweroside Drift Times: 4.86 +/- 0.24 ms
16.59
0 257.06749

0 5 10 15 20
Retention time [min]

Intensity [Counts]
179.03521

10000

649.07430
429.05175

481.94202
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Secologanic acid [+H] : (39.7 PPM) 375.1299 : DT=4.97 to 5.45 ms

1500
Intensity [Counts]

1000

500

Secologanic acid
1.58

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.5908 +/- 0.0285
Channel name: Secologanic acid [+H] : (39.7 PPM) 375.1299 Component name: Secologanic acid minutes : Drift Times: 5.21 +/- 0.24 ms
3.75
1.5e5 397.11293
5000

Intensity [Counts]
4000 100000
369.11784
Intensity [Counts]

3000
3.61 50000

360.16800 413.14604
2000 7.60 430.05441
8.26 263.10490 649.07290
1.58
0
2.60 5.45 6.09 13.43 200 400 600 800 1000
1000 11.38
4.06 9.30 Item name: MENGKUDU 2 Channel name: High energy : Time 1.5908 +/- 0.0285
13.59
Component name: Secologanic acid minutes : Drift Times: 5.05 +/- 0.24 ms
14.71
0 30000 369.11847
397.11435
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

10000 251.00207 415.12540


431.06402
203.08270

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Geniposidic acid [+H] : (39.7 PPM) 375.1302 : DT=6.30 to 6.78 ms
Geniposidic acid
1.62

600
Intensity [Counts]

400

1.54
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.6178 +/- 0.0285
Channel name: Geniposidic acid [+H] : (39.7 PPM) 375.1302 Component name: Geniposidic acid minutes : Drift Times: 6.54 +/- 0.24 ms
3.75
5000 120.08251

30000

Intensity [Counts]
4000
593.12128
20000
Intensity [Counts]

540.21007 636.14765
3000
3.61 10000 375.13020
215.09394
522.20692
2000 7.60
1.58 8.26
0
5.45 6.09 13.43
2.60 200 400 600 800 1000
1000 11.38
4.06 9.30
Item name: MENGKUDU 2 Channel name: High energy : Time 1.6178 +/- 0.0285
13.59
Component name: Geniposidic acid minutes : Drift Times: 6.38 +/- 0.24 ms
14.71
0 40000 561.18335

0 5 10 15 20
Retention time [min]

Intensity [Counts]
166.08764
20000

636.14976
649.07446
305.01305 413.07625
661.14164
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1447 : DT=7.34 to 7.82 ms

1500

1.44
Intensity [Counts]

1000

8-Epi-loganic acid
1.65

500 1.36

1.74

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.6436 +/- 0.0285
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1447 Component name: 8-Epi-loganic acid minutes : Drift Times: 7.57 +/- 0.24 ms
5.50
60000 760.23373
778.24402
100000

Intensity [Counts]
40000
Intensity [Counts]

50000 704.27907
397.11308
215.09320 377.14472
520.20333 780.25146
20000
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 1.6436 +/- 0.0285
1.44 5.25 Component name: 8-Epi-loganic acid minutes : Drift Times: 7.41 +/- 0.24 ms
2.69 6.19
0 120.08233

0 5 10 15 20 1.5e5
Retention time [min]

Intensity [Counts]
100000

166.08763
50000
179.07216
397.11435 670.19966 760.23617
778.24658
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic
methyl ester [+H] : (39.7 PPM) 197.0828 : DT=6.28 to 6.77 ms

1500

1000
Intensity [Counts]

1.69
500 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic m…
1.62

1.84

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.6442 +/-
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 6.53 +/- 0.24 ms
methyl ester [+H] : (39.7 PPM) 197.0828 hydroxyl-cyclopenta [c]pyran-4-carboxylic
0.93 methyl ester
1.45
166.08865
2000 100000

617.13624

Intensity [Counts]
561.18098
1500
Intensity [Counts]

50000
1.70

1000 385.09035 633.11418


1.81
2.07 0
200 400 600 800 1000
500 2.94 3.60 6.55 7.62
8.96 Item name: MENGKUDU 2 Channel name: High energy : Time 1.6442 +/-
5.30 11.65 Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 6.37 +/- 0.24 ms
12.32 16.56 17.98
hydroxyl-cyclopenta [c]pyran-4-carboxylic
0 methyl ester
0 5 10 15 20 120.08233
Retention time [min]

Intensity [Counts]
100000
617.13864
166.08764 635.14757
561.18335
190.04921 385.08933 636.14976
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0932 : DT=7.43 to 7.92 ms
Paeonisuffral
1.65
500

400
Intensity [Counts]

300

200
1.70

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.6470 +/- 0.0285
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0932 Component name: Paeonisuffral minutes : Drift Times: 7.67 +/- 0.24 ms
1.45
760.23373
3000
778.24402
100000

Intensity [Counts]
1.71
Intensity [Counts]

2000
50000 704.27907
397.11308
215.09320 377.14472
584.19882 780.25146
1000 1.81 0
4.71 6.52 7.60 200 400 600 800 1000
2.23 11.13
9.90 Item name: MENGKUDU 2 Channel name: High energy : Time 1.6470 +/- 0.0285
5.43 9.17
13.26 14.90 16.55 Component name: Paeonisuffral minutes : Drift Times: 7.52 +/- 0.24 ms

0 120.08233

0 5 10 15 20 1.5e5
Retention time [min]

Intensity [Counts]
100000

166.08763
50000
397.11435 760.23617
175.00921
604.08308 778.24658
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0930 : DT=6.13 to 6.61 ms

1500
Paeonisuffral
1.71
Intensity [Counts]

1000

500

1.82

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.7031 +/- 0.0285
Channel name: Paeonisuffral [+H] : (39.7 PPM) 215.0930 Component name: Paeonisuffral minutes : Drift Times: 6.36 +/- 0.24 ms
1.45
512.21578
3000
100000

Intensity [Counts]
1.71
Intensity [Counts]

2000
50000

215.09303
514.22264
197.08244 337.10446
1000 1.81 0
4.71 6.52 7.60 200 400 600 800 1000
2.23 11.13
Item name: MENGKUDU 2 Channel name: High energy : Time 1.7031 +/- 0.0285
5.43 9.17 9.90 Component name: Paeonisuffral minutes : Drift Times: 6.21 +/- 0.24 ms
13.26 14.90 16.55

0 166.08767
20000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
567.14091
10000
570.17101
175.04155
390.10652
615.12105

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic
methyl ester [+H] : (39.7 PPM) 197.0824 : DT=6.09 to 6.58 ms

1000

750
Intensity [Counts]

1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic m…
1.70
500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.7048 +/-
Channel name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 6.34 +/- 0.24 ms
methyl ester [+H] : (39.7 PPM) 197.0824 hydroxyl-cyclopenta [c]pyran-4-carboxylic
0.93 methyl ester
1.45
512.21578
2000
100000

Intensity [Counts]
1500
Intensity [Counts]

1.70 50000

1000 215.09303 514.22264


1.81 337.10446
197.08244
2.07 0
200 400 600 800 1000
500 2.94 3.60 6.55 7.62
8.96 Item name: MENGKUDU 2 Channel name: High energy : Time 1.7048 +/-
4.04 11.65 Component name: 1,4α,5,7α-Tetrahydro-7- 0.0285 minutes : Drift Times: 6.18 +/- 0.24 ms
12.32 16.56 17.98
hydroxyl-cyclopenta [c]pyran-4-carboxylic
0 methyl ester
0 5 10 15 20 166.08767
Retention time [min] 20000

Intensity [Counts] 10000 570.17101


175.04155
390.10652
615.12105

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sweroside [+H] : (39.7 PPM) 359.1365 : DT=7.34 to 7.82 ms

Sweroside
1.72

1000
Intensity [Counts]

750

500

1.65

250
1.60

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.7172 +/- 0.0285 minutes :
Channel name: Sweroside [+H] : (39.7 PPM) 359.1365 Component name: Sweroside Drift Times: 7.59 +/- 0.24 ms
1.73
369.11841
4000
75000

Intensity [Counts]
3000 50000
Intensity [Counts]

762.24402
25000
2000 359.13652 803.13440
370.12215
341.12810 755.16702 809.12338
2.35 5.49 6.47 513.21909
8.95 0
3.39 200 400 600 800 1000
1000
0.92 10.32 Item name: MENGKUDU 2 Channel name: High energy : Time 1.7172 +/- 0.0285 minutes :
10.42 14.12 16.51 Component name: Sweroside Drift Times: 7.44 +/- 0.24 ms
18.50
0 100000 369.11903

0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

166.08370 257.06853
401.05780
593.17503 803.13922
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sweroside [+H] : (39.7 PPM) 359.1367 : DT=8.34 to 8.82 ms
Sweroside
1.72

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.7240 +/- 0.0285 minutes :
Channel name: Sweroside [+H] : (39.7 PPM) 359.1367 Component name: Sweroside Drift Times: 8.60 +/- 0.24 ms
1.73
981.27525
10000 359.13665
4000

Intensity [Counts]
3000 965.25658
Intensity [Counts]

5000
619.15234 846.13996
355.11345 715.24146
2000 360.13309
341.12805
2.35 5.49 6.47
8.95 0
3.39 200 400 600 800 1000
1000
0.92 10.32 Item name: MENGKUDU 2 Channel name: High energy : Time 1.7240 +/- 0.0285 minutes :
10.42 14.12 16.51 Component name: Sweroside Drift Times: 8.44 +/- 0.24 ms
18.50
0 341.12703
10000
0 5 10 15 20
Retention time [min] 103.05545

Intensity [Counts]
166.08467
359.13690

5000
337.10468

512.21504
567.14087
858.13498
650.08200
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Fibraurin [+H] : (39.7 PPM) 373.1259 : DT=4.90 to 5.38 ms
Fibraurin
1.89

2000
Intensity [Counts]

1500

1000

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 1.8908 +/- 0.0285 minutes :
Channel name: Fibraurin [+H] : (39.7 PPM) 373.1259 Component name: Fibraurin Drift Times: 5.13 +/- 0.24 ms
7.71
40000 395.09784
4000 7.65

1.89
30000 373.12595

Intensity [Counts]
3000 0.62
20000
Intensity [Counts]

7.05 12.10 411.06704


2000 10000
426.02846
5.73 225.04201 547.07326 799.14220
857.11533
9.43 0
3.03 4.96 6.78 200 400 600 800 1000
1000 9.58
13.09
Item name: MENGKUDU 2 Channel name: High energy : Time 1.8908 +/- 0.0285 minutes :
13.39 14.60 Component name: Fibraurin Drift Times: 4.97 +/- 0.24 ms
18.54

0 373.12686

0 5 10 15 20
395.09764
Retention time [min]
10000

Intensity [Counts]
216.98135

5000 131.05047

487.05449

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Anemonin [+H] : (39.7 PPM) 193.0504 : DT=3.68 to 4.17 ms

2500

2000
Intensity [Counts]

1500

1000

500

Anemonin
2.03
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.0437 +/- 0.0285 minutes :
Channel name: Anemonin [+H] : (39.7 PPM) 193.0504 Component name: Anemonin Drift Times: 3.93 +/- 0.24 ms
3.27
257.06772
30000

6000

Intensity [Counts]
3.93
20000
Intensity [Counts]

179.03614
4000
10000

6.04 431.08349
0
2000 1.831.89
4.54 200 400 600 800 1000

6.16 Item name: MENGKUDU 2 Channel name: High energy : Time 2.0437 +/- 0.0285 minutes :
8.51 9.81 Component name: Anemonin Drift Times: 3.77 +/- 0.24 ms
7.09 12.67 14.89
0 179.03609

0 5 10 15 20 4000
Retention time [min]

Intensity [Counts]
183.03007
2000
235.02872

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1341 : DT=6.94 to 7.42 ms

300
Sesamoside
2.05 2.10
250

200
Intensity [Counts]

150

100

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.0838 +/- 0.0285 minutes :
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1341 Component name: Sesamoside Drift Times: 7.18 +/- 0.24 ms
8.06
431.08308
4000
10000
651.12677

Intensity [Counts]
687.12749 891.12533
3000 421.13408 461.04018
699.08762
Intensity [Counts]

9.15 621.15700
5000 709.21988 904.12157
535.13840
0.96
2000 6.81 259.07645
2.09 4.54 6.55 227.05589

6.04 0
3.17 9.23 200 400 600 800 1000
1000
11.83 Item name: MENGKUDU 2 Channel name: High energy : Time 2.0838 +/- 0.0285 minutes :
9.39
12.36 Component name: Sesamoside Drift Times: 7.02 +/- 0.24 ms
13.3315.07 18.50
0 431.08187

0 5 10 15 20 258.07148
Retention time [min] 399.04599

Intensity [Counts]
10000
127.03939

443.02991
903.12177
5000
563.10718 635.12437 891.13466
873.10491
693.10847
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1344 : DT=6.12 to 6.60 ms

1250

1000
Intensity [Counts]

750

500 Sesamoside
2.11
1.85 2.27
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.1022 +/- 0.0285 minutes :
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1344 Component name: Sesamoside Drift Times: 6.36 +/- 0.24 ms
8.06
501.15927
432.08727
4000
7500
371.10055 522.13771

Intensity [Counts]
879.15465
528.10735
3000 5000 579.14510
893.14899
Intensity [Counts]

9.15 360.07777
665.14184
0.96 310.13086
2500 752.14713
2000 6.81 209.04602
2.09 4.54 6.55 197.08261
0
3.17 9.23 200 400 600 800 1000
1000
11.83 Item name: MENGKUDU 2 Channel name: High energy : Time 2.1022 +/- 0.0285 minutes :
9.39
12.36 Component name: Sesamoside Drift Times: 6.21 +/- 0.24 ms
13.3315.07 18.50
0 531.17056

0 5 10 15 20
399.04402
Retention time [min] 10000 151.04019

Intensity [Counts]
241.07297

5000 575.12466
260.95146 465.20621
587.12583

867.14997

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Reptoside [+H] : (39.7 PPM) 393.1383 : DT=4.99 to 5.47 ms

1000

750
Intensity [Counts]

500 Reptoside
2.11

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.1087 +/- 0.0285 minutes :
Channel name: Reptoside [+H] : (39.7 PPM) 393.1383 Component name: Reptoside Drift Times: 5.23 +/- 0.24 ms
13.44
342.11580

5000 7500

298.12577

Intensity [Counts]
4000 5000 252.08739 351.06696
Intensity [Counts]

241.07211 393.13830
3000 193.05035 400.12960
2500 863.16914
520.09701 667.07941
5.30 12.13 879.15438
2000 0.60 6.64
0
8.41 9.16 200 400 600 800 1000
4.25
1000 5.41 13.61 Item name: MENGKUDU 2 Channel name: High energy : Time 2.1087 +/- 0.0285 minutes :
1.67 4.19 9.22
16.60 Component name: Reptoside Drift Times: 5.07 +/- 0.24 ms

0 257.06792

0 5 10 15 20 40000
Retention time [min]

Intensity [Counts]
20000

225.04023
320.07913
399.04599
196.09921
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Asperulosidic acid [+H] : (39.7 PPM) 433.1354 : DT=5.54 to 6.03 ms

4000

3000
Intensity [Counts]

Asperulosidic acid
2.27
2000

2.13
1000 2.10

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.2861 +/- 0.0285
Channel name: Asperulosidic acid [+H] : (39.7 PPM) 433.1354 Component name: Asperulosidic acid minutes : Drift Times: 5.75 +/- 0.24 ms
3.06
433.13628
10000
40000

427.12183

Intensity [Counts]
7500 513.13478
Intensity [Counts]

20000
2.27
5000 420.12424 905.12658
319.09246 703.11211 883.11837
7.50 8.23 193.05120
2.13 0
3.31 6.35
2500 200 400 600 800 1000

0.95 Item name: MENGKUDU 2 Channel name: High energy : Time 2.2861 +/- 0.0285
5.05 8.92 11.38 Component name: Asperulosidic acid minutes : Drift Times: 5.59 +/- 0.24 ms
11.45 13.96
0 427.12233

0 5 10 15 20 20000
Retention time [min]

Intensity [Counts]
256.02724 419.12188
10000
401.10685
202.10888
433.13681
174.98503 473.04243 665.06741
917.09836
492.12553
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sweroside [+H] : (39.7 PPM) 359.1318 : DT=4.77 to 5.25 ms

800 Sweroside
2.35

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.3503 +/- 0.0285 minutes :
Channel name: Sweroside [+H] : (39.7 PPM) 359.1318 Component name: Sweroside Drift Times: 5.01 +/- 0.24 ms
1.73
4000 270.12480

50000

Intensity [Counts]
298.11968
3000
Intensity [Counts]

341.12195
25000 360.12037
2000
381.04663
6.47 244.09342 899.09837
2.35 3.39 503.01401 675.11859
7.36 8.94 0
4.64 5.49
1000 200 400 600 800 1000
0.92 9.76 10.42
14.12 Item name: MENGKUDU 2 Channel name: High energy : Time 2.3503 +/- 0.0285 minutes :
10.31 16.52 Component name: Sweroside Drift Times: 4.86 +/- 0.24 ms
16.59
0 270.12442
30000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

298.11866
10000
316.12873
144.04523
359.13056
631.08305
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Acetylharpagide [+H] : (39.7 PPM) 407.1518 : DT=5.28 to 5.76 ms

2000

1500
Acetylharpagide
Intensity [Counts]

2.37

1000

2.07

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.3710 +/- 0.0285
Channel name: Acetylharpagide [+H] : (39.7 PPM) 407.1518 Component name: Acetylharpagide minutes : Drift Times: 5.51 +/- 0.24 ms
5.90
2500 5.92 257.06683

5.85 2e5
11.29

Intensity [Counts]
2000
2.37
5.74 11.18 11.56
Intensity [Counts]

5.46 10.48
1500 100000
9.57 431.08329
5.40
2.05 9.17
3.71
8.66 407.15178
1000 5.15 204.06646 445.13494 633.07746
6.36 918.09995
7.27 12.74 0
0.57 13.45 200 400 600 800 1000
500
Item name: MENGKUDU 2 Channel name: High energy : Time 2.3710 +/- 0.0285
13.62 14.96
18.50 Component name: Acetylharpagide minutes : Drift Times: 5.36 +/- 0.24 ms

0 257.06699

0 5 10 15 20
Retention time [min] 50000

Intensity [Counts] 25000 151.03998

407.15202
337.02129 899.09785
445.13571
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lamiophlomiol B [+H] : (39.7 PPM) 243.0861 : DT=5.61 to 6.09 ms

1000

750
Intensity [Counts]

Lamiophlomiol B
2.45

500
2.41

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.4470 +/- 0.0285
Channel name: Lamiophlomiol B [+H] : (39.7 PPM) 243.0861 Component name: Lamiophlomiol B minutes : Drift Times: 5.85 +/- 0.24 ms
5.50
75000 459.11112

4000

Intensity [Counts]
50000

3000
Intensity [Counts]

2.45 472.07808 915.07590


25000
211.06114
2000 261.09582 481.15601733.12691 899.10296
206.08035 501.04119
0
2.83 7.51 200 400 600 800 1000
1000
1.94 3.40 9.20 Item name: MENGKUDU 2 Channel name: High energy : Time 2.4470 +/- 0.0285
6.52 9.83 11.10 13.50 Component name: Lamiophlomiol B minutes : Drift Times: 5.69 +/- 0.24 ms
4.70
1.24 13.95 14.86
0 211.06070 471.07498

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
277.08237

97.02919 453.06573
10000 285.00638

503.01134
713.14770 915.07934
555.07886
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 7-epi-Vogeloside [+H] : (39.7 PPM) 389.1432 : DT=5.38 to 5.86 ms
6.21
6.19
3000
Intensity [Counts]

2000

3.74

1000
8.07 10.71
2.82 5.85 10.77
7.62 8.12
5.20
2.62 13.36 14.97 16.53
16.74
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.5934 +/- 0.0285
Channel name: 7-epi-Vogeloside [+H] : (39.7 PPM) 389.1432 Component name: 7-epi-Vogeloside minutes : Drift Times: 5.62 +/- 0.24 ms
6000 6.20
257.06609
2e5
5000

Intensity [Counts]
431.08148

4000
Intensity [Counts]

100000 471.07426

3000
10.81 399.05515
3.74
224.09110 501.04728 633.07513
2000 899.10262
8.11 0
3.44 4.24 200 400 600 800 1000
0.61 7.74
5.44 6.45 9.26
1000 2.83 Item name: MENGKUDU 2 Channel name: High energy : Time 2.5934 +/- 0.0285
11.76 13.69 Component name: 7-epi-Vogeloside minutes : Drift Times: 5.47 +/- 0.24 ms
13.99
14.83 16.74
0 257.06594

0 5 10 15 20
40000
Retention time [min]

Intensity [Counts]
471.07520

20000
179.03395 453.06515
429.13272
123.04460 633.07555
897.07194
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1429 : DT=4.98 to 5.47 ms

25000

20000
Intensity [Counts]

15000

10000

5000 8-Epi-loganic acid


2.70

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.6997 +/- 0.0285
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1429 Component name: 8-Epi-loganic acid minutes : Drift Times: 5.23 +/- 0.24 ms
5.50
60000 377.14286
15000

Intensity [Counts]
10000 206.04593
40000
Intensity [Counts]

369.13724
5000
350.08257 405.16527
434.16355
20000
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 2.6997 +/- 0.0285
1.44 5.24 Component name: 8-Epi-loganic acid minutes : Drift Times: 5.07 +/- 0.24 ms
2.69 6.19
0 377.14135

0 5 10 15 20 7500

Retention time [min] 160.03947

Intensity [Counts]
5000
346.12809
297.13760
2500
398.10291

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Pueroside B [+H] : (39.7 PPM) 623.1964 : DT=6.70 to 7.18 ms
4.55 5.40

2000

1500
Intensity [Counts]

5.50
1000
5.59 9.05
5.66
7.13 8.99
500 1.67 3.99 10.70
7.91
2.68 9.87
0.99 10.82 11.82
14.60
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.7800 +/- 0.0285 minutes :
Channel name: Pueroside B [+H] : (39.7 PPM) 623.1964 Component name: Pueroside B Drift Times: 6.94 +/- 0.24 ms
5.41
5.07 619.14919
4000 4.55
9.04
40000

Intensity [Counts]
3000 7.13
2.66 6.41
Intensity [Counts]

7.89
20000

2000 596.18236
387.12954 677.12535
241.07225 903.11681
9.16
0
11.17 15.38
1000 1.67 200 400 600 800 1000
4.34 11.21
14.30 Item name: MENGKUDU 2 Channel name: High energy : Time 2.7800 +/- 0.0285 minutes :
15.96
0.99 Component name: Pueroside B Drift Times: 6.79 +/- 0.24 ms
18.52
16.32
0 257.06641

0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
10000
191.03437

411.02526 574.17677

631.07832 903.12024
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Phloyoside Ⅱ [+H] : (39.7 PPM) 457.1116 : DT=5.54 to 6.02 ms

1500
Intensity [Counts]

1000

500 Phloyoside Ⅱ
2.79

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.7934 +/- 0.0285
Channel name: Phloyoside Ⅱ [+H] : (39.7 PPM) 457.1116 Component name: Phloyoside Ⅱ minutes : Drift Times: 5.78 +/- 0.24 ms
3.93
4.97 397.17343
3000
75000

Intensity [Counts]
471.07587
50000
2000 388.15212
Intensity [Counts]

25000
2.78 487.05040 633.07583
2.62 265.08069 903.11674
5.13 114.10229 509.12852 697.11573
1000 2.39 7.03 0
8.60
2.31 9.84 200 400 600 800 1000
0.51 8.93 Item name: MENGKUDU 2 Channel name: High energy : Time 2.7934 +/- 0.0285
10.99 16.56 Component name: Phloyoside Ⅱ minutes : Drift Times: 5.63 +/- 0.24 ms
15.36

0 30000 511.10914

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

388.15125
179.03503
10000
310.98681
116.05061 633.07888
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Phloyoside Ⅱ [+H] : (39.7 PPM) 457.1120 : DT=5.97 to 6.45 ms

500

400
Phloyoside Ⅱ
Intensity [Counts]

2.82
300 3.94
2.56
2.39
200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.8349 +/- 0.0285
Channel name: Phloyoside Ⅱ [+H] : (39.7 PPM) 457.1120 Component name: Phloyoside Ⅱ minutes : Drift Times: 6.21 +/- 0.24 ms
3.93 4.97
513.12356
3000
20000

Intensity [Counts]
559.12748

2000 512.11394
Intensity [Counts]

10000
502.17377
387.13039
2.78 575.08126
337.12419
2.39 735.16595 873.15422
1000 5.13
7.03 0
2.29 8.60 200 400 600 800 1000
9.84
1.83 8.93 Item name: MENGKUDU 2 Channel name: High energy : Time 2.8349 +/- 0.0285
10.99 16.56 Component name: Phloyoside Ⅱ minutes : Drift Times: 6.06 +/- 0.24 ms
15.36

0 30000 511.10914

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

513.12115
10000
543.13368
221.04056 448.14931
579.19414
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Centaurepensin [+H] : (39.7 PPM) 435.0954 : DT=8.06 to 8.54 ms

500

400
Intensity [Counts]

300 Centaurepensin
2.84

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.8452 +/- 0.0285
Channel name: Centaurepensin [+H] : (39.7 PPM) 435.0954 Component name: Centaurepensin minutes : Drift Times: 8.30 +/- 0.24 ms
4.59
905.13074
30000

5000

Intensity [Counts]
20000
4000
4.68 337.12447
Intensity [Counts]

882.15034
0.95
436.09242 751.25804
3000 10000

305.09696 455.11978
2.84
2000 241.07199
0
3.18 4.74 6.81 200 400 600 800 1000
4.83 10.04
1000 2.30 Item name: MENGKUDU 2 Channel name: High energy : Time 2.8452 +/- 0.0285
5.74 9.98 10.25
7.56 13.74 Component name: Centaurepensin minutes : Drift Times: 8.15 +/- 0.24 ms
12.79 15.68

0 304.09464

0 5 10 15 20 40000
Retention time [min] 336.12084

Intensity [Counts]
20000

337.12341
204.06683
475.05336
751.26643 907.15167
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Centaurepensin [+H] : (39.7 PPM) 435.0961 : DT=5.19 to 5.67 ms

1250

1000
2.82
Intensity [Counts]

750
2.85

500
Centaurepensin
2.91
2.77
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.8930 +/- 0.0285
Channel name: Centaurepensin [+H] : (39.7 PPM) 435.0961 Component name: Centaurepensin minutes : Drift Times: 5.43 +/- 0.24 ms
4.59
339.12098
2e5
5000

Intensity [Counts]
443.11828
4000
4.68
Intensity [Counts]

100000
0.96
3000
295.13089 459.10054
2.84 224.09135 515.14852 795.15941 887.12449
2000
0
3.18 4.74 6.81 200 400 600 800 1000
4.83 10.04
1000 2.30 Item name: MENGKUDU 2 Channel name: High energy : Time 2.8930 +/- 0.0285
5.73 10.25
7.56 9.98 13.74 Component name: Centaurepensin minutes : Drift Times: 5.28 +/- 0.24 ms
12.79 15.68

0 443.11808
40000
0 5 10 15 20
Retention time [min] 419.13544

Intensity [Counts]
20000
340.12586

322.20391
175.09423 453.10447

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-Acetyl harpagide [+H] : (39.7 PPM) 409.1339 : DT=5.36 to 5.84 ms

10000

7500
Intensity [Counts]

5000

2500

2.87
8-Acetyl harpagide
0 2.93
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.9239 +/- 0.0285
Channel name: 8-Acetyl harpagide [+H] : (39.7 PPM) 409.1339 Component name: 8-Acetyl harpagide minutes : Drift Times: 5.60 +/- 0.24 ms
15000 12.04
257.06735
40000
12500

Intensity [Counts]
10000 388.15122 453.11045
Intensity [Counts]

20000
471.07538
7500
633.07694
250.13028 887.12449
5000 796.15707
890.14315
0
3.54
0.61 9.12 9.86 200 400 600 800 1000
3.25 3.65
2500 Item name: MENGKUDU 2 Channel name: High energy : Time 2.9239 +/- 0.0285
3.84 7.60 10.74
2.73 Component name: 8-Acetyl harpagide minutes : Drift Times: 5.44 +/- 0.24 ms
13.50 14.92

0 421.17052

0 5 10 15 20 20000 257.06715
Retention time [min] 425.10841

Intensity [Counts]
205.05155

388.15296
10000 428.12729
183.02759
431.08503
633.08007
469.13790

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2358 : DT=5.73 to 6.22 ms

1500
Intensity [Counts]

1000

Nigakilactone J
2.94

500
2.89

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.9365 +/- 0.0285
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2358 Component name: Nigakilactone J minutes : Drift Times: 5.98 +/- 0.24 ms
15.12
511.11391
75000

2000

Intensity [Counts]
50000
Intensity [Counts]

1500 13.60 16.54

25000 485.00294
16.58
11.20 513.12200
1000 467.12999 859.16323
10.89 16.67 225.07686 525.12910
2.94 769.15103 973.12914
10.60 0
6.56 10.40 200 400 600 800 1000
500 16.75
5.56 9.77 Item name: MENGKUDU 2 Channel name: High energy : Time 2.9365 +/- 0.0285
2.44 4.06 16.94 Component name: Nigakilactone J minutes : Drift Times: 5.82 +/- 0.24 ms
0.82
0 205.05155
15000
0 5 10 15 20
Retention time [min] 512.11756

Intensity [Counts]
10000
191.03707
467.13472 519.16722

175.03961 431.08498
5000
520.17708

543.05259
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Shanzhiside methyl ester [+H] : (39.7 PPM) 407.1529 : DT=5.56 to
6.04 ms

1250

1000
Intensity [Counts]

750

500

250
Shanzhiside methyl ester
2.96

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.9481 +/-
Channel name: Shanzhiside methyl ester [+H] : (39.7 PPM) 407.1529 Component name: Shanzhiside methyl ester 0.0285 minutes : Drift Times: 5.80 +/- 0.24 ms
5.90
511.11391
75000 427.12559
2500 5.85

Intensity [Counts]
11.29
50000
2000 2.37 11.18
5.75 11.56 421.16874
Intensity [Counts]

10.49
5.46
1500 9.57 25000
5.40 519.16970
2.05 9.17 412.20911
3.71 223.06143 859.16323
8.66 525.12910
1000 5.15 873.15188
6.43 12.74 0
13.45 200 400 600 800 1000
0.57
500 Item name: MENGKUDU 2 Channel name: High energy : Time 2.9481 +/-
14.97 16.56
Component name: Shanzhiside methyl ester 0.0285 minutes : Drift Times: 5.64 +/- 0.24 ms
16.61
0 427.12299
30000
0 5 10 15 20
421.17052
Retention time [min]

Intensity [Counts]
20000
205.05155
189.05607 216.98041 512.11756
10000
91.05435 321.10638
635.07953
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6′-O-β-D-Glucosyl gentiopicroside [+H] : (39.7 PPM) 519.1697 :
DT=5.78 to 6.26 ms

6′-O-β-D-Glucosyl gentiopicroside
600 2.93 2.97

2.88
Intensity [Counts]

400
2.79

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 2.9670 +/-
Channel name: 6′-O-β-D-Glucosyl gentiopicroside [+H] : (39.7 PPM) 519.1697 Component name: 6′-O-β-D-Glucosyl 0.0285 minutes : Drift Times: 6.02 +/- 0.24 ms
7.54 gentiopicroside
9.01
511.11391
2500 75000

Intensity [Counts]
2000
7.46 50000
Intensity [Counts]

1500 6.90
25000 467.12999
2.93 4.54 11.71 13.45 14.33 519.16970
5.46 10.95
543.04614 859.16323
1000 2.63 441.09776
205.05281 653.11115
2.48 0
16.49 200 400 600 800 1000
2.06
500 14.79 16.56 Item name: MENGKUDU 2 Channel name: High energy : Time 2.9670 +/-
0.61
Component name: 6′-O-β-D-Glucosyl 0.0285 minutes : Drift Times: 5.87 +/- 0.24 ms
16.61 gentiopicroside
0
511.11028
0 5 10 15 20
30000
Retention time [min]
257.06713

Intensity [Counts]
20000
205.05155

10000 191.03707
441.05623
91.05447 294.98934 539.17971
871.12882
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-O-Acetyl shanzhiside methyl ester [+H] : (39.7 PPM) 449.1635 :
DT=5.46 to 5.95 ms
5000

4000
Intensity [Counts]

3000

2000

1000
8-O-Acetyl shanzhiside methyl ester
3.03

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.0396 +/-
Channel name: 8-O-Acetyl shanzhiside methyl ester [+H] : (39.7 PPM) 449.1635 Component name: 8-O-Acetyl shanzhiside 0.0285 minutes : Drift Times: 5.71 +/- 0.24 ms
12.06 methyl ester

443.11763

40000
20000 449.16348

Intensity [Counts]
Intensity [Counts]

30000
459.11394
419.15231
10000
633.07672
229.07189
20000 875.15164
191.03663 745.09252

0
200 400 600 800 1000
10000
Item name: MENGKUDU 2 Channel name: High energy : Time 3.0396 +/-
8.16 11.33 Component name: 8-O-Acetyl shanzhiside 0.0285 minutes : Drift Times: 5.56 +/- 0.24 ms
3.04 7.51 methyl ester
0
425.10754
0 5 10 15 20 10000
Retention time [min] 266.99632

Intensity [Counts]
234.97103 419.15321 437.12635
449.16185
5000 147.04343
461.10693

463.18100 641.11898
493.18966
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Anemonin [+H] : (39.7 PPM) 193.0511 : DT=2.95 to 3.43 ms

3.27

1500
Intensity [Counts]

1000

Anemonin
500 3.06

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.0562 +/- 0.0285 minutes :
Channel name: Anemonin [+H] : (39.7 PPM) 193.0511 Component name: Anemonin Drift Times: 3.19 +/- 0.24 ms
3.27
178.05223
10000

91.05417
6000

Intensity [Counts]
3.93
193.05113
Intensity [Counts]

5000
4000 297.00761

6.04
0
2000 1.831.89
200 400 600 800 1000
4.54
6.16 Item name: MENGKUDU 2 Channel name: High energy : Time 3.0562 +/- 0.0285 minutes :
8.51 9.81 Component name: Anemonin Drift Times: 3.03 +/- 0.24 ms
7.09 12.67 14.89
0 178.04911

0 5 10 15 20 3000 234.97106
Retention time [min]

Intensity [Counts]
266.99632
2000

1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1220 : DT=5.21 to 5.69 ms

3000
Intensity [Counts]

2000

Asperuloside
3.18
1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.1737 +/- 0.0285
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1220 Component name: Asperuloside minutes : Drift Times: 5.43 +/- 0.24 ms
1.30
322.20222
6000
1.44
3.92
30000

Intensity [Counts]
359.18296
20000 411.14440
Intensity [Counts]

4000
457.12695
861.17173
10000 633.07742
304.19443
3.18 637.10704 873.14841
276.10303
807.15360
2000 8.51
0
9.86 200 400 600 800 1000
2.40 4.34 8.25 9.15 11.07
6.09 7.58 Item name: MENGKUDU 2 Channel name: High energy : Time 3.1737 +/- 0.0285
10.42
12.09 Component name: Asperuloside minutes : Drift Times: 5.28 +/- 0.24 ms
14.58
0 322.20242

0 5 10 15 20 15000 360.22883
Retention time [min]

Intensity [Counts]
10000 216.97894

411.14726

5000 415.12091
426.10581 633.07995

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Anemonin [+H] : (39.7 PPM) 193.0507 : DT=3.43 to 3.91 ms
Anemonin
4000 3.27

3000
Intensity [Counts]

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.2675 +/- 0.0285 minutes :
Channel name: Anemonin [+H] : (39.7 PPM) 193.0507 Component name: Anemonin Drift Times: 3.67 +/- 0.24 ms
3.27
193.05075

50000
6000

Intensity [Counts]
3.93
Intensity [Counts]

192.13949
25000 225.07648
4000

91.05518
6.04 231.05375

0
2000 1.831.89
4.54 200 400 600 800 1000

6.16 Item name: MENGKUDU 2 Channel name: High energy : Time 3.2675 +/- 0.0285 minutes :
8.51 9.81 Component name: Anemonin Drift Times: 3.52 +/- 0.24 ms
7.09 12.67 14.89
0 192.13979
20000 193.04980
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000

200.98385 356.04242

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1429 : DT=5.06 to 5.54 ms

30000
Intensity [Counts]

20000

10000

3.27 8-Epi-loganic acid


0 3.31
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.3064 +/- 0.0285
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1429 Component name: 8-Epi-loganic acid minutes : Drift Times: 5.31 +/- 0.24 ms
5.50
60000 351.11801

30000

Intensity [Counts]
222.07642 377.14292
20000
40000 431.09357
Intensity [Counts]

10000 130.04958
440.13230 699.12092 871.12458
473.08206
20000 890.13777
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 3.3064 +/- 0.0285
1.44 5.24 Component name: 8-Epi-loganic acid minutes : Drift Times: 5.15 +/- 0.24 ms
2.69 6.19
0 290.06515

0 5 10 15 20
261.00543
Retention time [min]

Intensity [Counts]
5000 260.05291
147.04466 314.11064
392.11302
2500 415.12132

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bruceaketolic acid [+H] : (39.7 PPM) 485.1646 : DT=5.72 to 6.20 ms

4000

3000
Intensity [Counts]

2000

1000

3.40
Bruceaketolic acid
0 3.52
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.5418 +/- 0.0285
Channel name: Bruceaketolic acid [+H] : (39.7 PPM) 485.1646 Component name: Bruceaketolic acid minutes : Drift Times: 5.96 +/- 0.24 ms
6.25
457.13676
8.95
5000
15000 441.10151

Intensity [Counts]
6.04
4000
10000 471.05465
Intensity [Counts]

309.18119
9.69 655.18904
3000 6.88 633.15460
5000 281.09448
7.01 853.11498
226.08154
841.16155
2000 192.03856
0
200 400 600 800 1000
3.99 8.83
3.18 10.00 11.83
1000 1.40 Item name: MENGKUDU 2 Channel name: High energy : Time 3.5418 +/- 0.0285
3.52 11.96 Component name: Bruceaketolic acid minutes : Drift Times: 5.80 +/- 0.24 ms
12.89
14.84 18.54
0 395.15412

0 5 10 15 20 427.08071

Retention time [min]

Intensity [Counts]
10000

266.10343
261.00950
5000 91.05476 541.11479

649.08831

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅲ [+H] : (39.7 PPM) 539.1749 : DT=6.77 to 7.25 ms
Picroside Ⅲ
3.56
1250

1000
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.5558 +/- 0.0285 minutes :
Channel name: Picroside Ⅲ [+H] : (39.7 PPM) 539.1749 Component name: Picroside Ⅲ Drift Times: 7.03 +/- 0.24 ms
3.56
40000 594.16622
2.52 633.15438
2500
30000

Intensity [Counts]
2000
20000
Intensity [Counts]

539.17486
522.15027 859.16034
1500
5.69 642.17174
8.61 10000
4.34
6.03 319.08537 849.69478 873.13690
8.73 14.37
1000 5.61
7.91
8.76 9.06 0
1.76 13.32 200 400 600 800 1000
500 1.72 14.42 16.53
Item name: MENGKUDU 2 Channel name: High energy : Time 3.5558 +/- 0.0285 minutes :
14.85 18.52 Component name: Picroside Ⅲ Drift Times: 6.88 +/- 0.24 ms
17.71
0 20000 617.16949

0 5 10 15 20
Retention time [min]

Intensity [Counts]
189.05567
10000
319.08574 633.15302
458.04690
91.05435 871.13012
649.08878 875.14628
861.17508
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Erythrocentaurin [+H] : (39.7 PPM) 177.0562 : DT=3.14 to 3.62 ms

1500

1250

1000
Intensity [Counts]

750

3.40
500
Erythrocentaurin
3.33 3.63
250 3.12

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.6191 +/- 0.0285
Channel name: Erythrocentaurin [+H] : (39.7 PPM) 177.0562 Component name: Erythrocentaurin minutes : Drift Times: 3.38 +/- 0.24 ms
6.25
3000
6000 177.05619

2500

Intensity [Counts]
4000
2000
163.03983
Intensity [Counts]

197.13925
1500 2000
7.85

3.49
1000 3.40 5.18 9.43 10.99
12.84 0
3.33
12.98 200 400 600 800 1000
3.22
500 13.15 Item name: MENGKUDU 2 Channel name: High energy : Time 3.6191 +/- 0.0285
2.38
15.15 Component name: Erythrocentaurin minutes : Drift Times: 3.23 +/- 0.24 ms

0 145.02885

0 5 10 15 20 3000
Retention time [min]

Intensity [Counts]
2000
167.06840

1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Geniposide [+H] : (39.7 PPM) 405.1378 : DT=4.95 to 5.43 ms

600
Intensity [Counts]

400

200
Geniposide
3.70

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.6533 +/- 0.0285 minutes :
Channel name: Geniposide [+H] : (39.7 PPM) 405.1378 Component name: Geniposide Drift Times: 5.19 +/- 0.24 ms
5.09
5000 337.09899
871.12349
4.71 30000

Intensity [Counts]
4000
20000 317.14937
391.12009
Intensity [Counts]

3000
10000 883.08890
291.09617 649.08286
163.03912 429.08595 860.15768
2000 599.66176 889.13535
4.31

5.41 0
9.77 200 400 600 800 1000
1.75 2.84 8.43 10.49
1000 5.73
11.24 Item name: MENGKUDU 2 Channel name: High energy : Time 3.6533 +/- 0.0285 minutes :
12.35 Component name: Geniposide Drift Times: 5.03 +/- 0.24 ms
15.35
0 206.05131
10000
0 5 10 15 20
Retention time [min] 457.04484

Intensity [Counts]
325.12466
188.07154

5000 117.03378

470.01133

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅲ [+H] : (39.7 PPM) 539.1748 : DT=6.69 to 7.18 ms

1250

1000
Intensity [Counts]

750

500
Picroside Ⅲ
3.72
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.7165 +/- 0.0285 minutes :
Channel name: Picroside Ⅲ [+H] : (39.7 PPM) 539.1748 Component name: Picroside Ⅲ Drift Times: 6.92 +/- 0.24 ms
3.56
595.22851
75000
2.52
2500

Intensity [Counts]
50000
2000 613.23939
Intensity [Counts]

1500 25000
5.69 361.12744
8.61 589.20445
4.34 304.08096
6.03 8.73 667.15298
5.61 14.37 539.17482
1000 7.91 207.06519 866.09350
8.76 9.06 0
1.76 13.32 200 400 600 800 1000
500 1.72 14.42 16.53
Item name: MENGKUDU 2 Channel name: High energy : Time 3.7165 +/- 0.0285 minutes :
14.85 18.52 Component name: Picroside Ⅲ Drift Times: 6.77 +/- 0.24 ms
17.71
0 15000 304.08121

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000

127.05471 595.22468
5000
371.05868 453.02320 667.15705
797.22417 885.11587

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1239 : DT=5.30 to 5.79 ms

2500

2000
Intensity [Counts]

1500

Asperuloside
3.92
1000

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.8336 +/- 0.0285
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1239 Component name: Asperuloside minutes : Drift Times: 5.55 +/- 0.24 ms
1.30
6000 425.10591
1.26 3.92 100000
1.45 455.11559
5000

Intensity [Counts]
4000
Intensity [Counts]

1.52 50000
457.04326
871.12320
223.06103
3000
3.18 205.05178 383.06117
477.13714 884.09280
8.51 191.03553 770.16607
2000
9.86 0
2.40 8.25 10.42 200 400 600 800 1000
4.34
1000 4.54 7.13 11.07 Item name: MENGKUDU 2 Channel name: High energy : Time 3.8336 +/- 0.0285
14.58
11.43 16.46 Component name: Asperuloside minutes : Drift Times: 5.39 +/- 0.24 ms
13.59
14.69
0 205.05079

0 5 10 15 20 40000
191.03438 425.10478
Retention time [min]

Intensity [Counts]
437.07039
223.06080
20000 443.11797

409.13198
456.03631

493.13258
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ginkgolide C [+H] : (39.7 PPM) 441.1401 : DT=5.36 to 5.85 ms

8000

6000
Intensity [Counts]

4000

2000

Ginkgolide C
0 3.84
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.8413 +/- 0.0285 minutes :
Channel name: Ginkgolide C [+H] : (39.7 PPM) 441.1401 Component name: Ginkgolide C Drift Times: 5.60 +/- 0.24 ms
8.34
425.10591
20000 100000
455.11559

Intensity [Counts]
15000
Intensity [Counts]

50000
457.04326
871.12320
223.06103
10000
383.06117
209.04624 475.21724 884.09280
770.16607
0
5000 5.57 7.71 200 400 600 800 1000
5.12 7.49 Item name: MENGKUDU 2 Channel name: High energy : Time 3.8413 +/- 0.0285
5.70 9.99 11.21 Component name: Ginkgolide C minutes : Drift Times: 5.45 +/- 0.24 ms
4.54
3.54
0 205.05079

0 5 10 15 20 40000
425.10478
Retention time [min]

Intensity [Counts]
191.03438
437.07039

20000 223.06080
409.13198
456.03631

493.13258
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1223 : DT=6.12 to 6.60 ms
3.95

3.45
300

3.19
Intensity [Counts]

200

Asperuloside
3.85
3.09

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.8470 +/- 0.0285
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1223 Component name: Asperuloside minutes : Drift Times: 6.41 +/- 0.24 ms
1.30
883.09159
6000
1.44 3.92

Intensity [Counts]
20000
872.12674

223.06143
Intensity [Counts]

4000
257.06622
10000 205.05199
415.12227 601.11079 859.15535 904.22088
397.11168 515.11438
3.18 649.07018
847.13686
8.51
2000 0
9.86 200 400 600 800 1000
2.40 4.34 8.25 9.15 11.07
6.09 7.58 Item name: MENGKUDU 2 Channel name: High energy : Time 3.8470 +/- 0.0285
10.42
12.09 Component name: Asperuloside minutes : Drift Times: 6.25 +/- 0.24 ms
14.58
15.21
0 191.03438

0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
223.06081

177.05518
10000 257.06628

337.09568 453.04134 872.12876


649.08582
855.14817 884.09602
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1247 : DT=6.67 to 7.15 ms

Asperuloside
3.88
400 3.91

300
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.8982 +/- 0.0285
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1247 Component name: Asperuloside minutes : Drift Times: 6.91 +/- 0.24 ms
6000 1.30
3.92 30000 919.17842
1.26
901.13347
5000 1.45

Intensity [Counts]
20000
4000 668.15993
1.53
Intensity [Counts]

415.12468
633.15473
10000 337.09608 884.22329
3000 618.17145
3.18 567.15716 705.16588
8.51 193.05012 799.16782
2000 9.86
0
2.40 8.25 10.42 200 400 600 800 1000
4.35
1000 11.07
4.54 7.13 14.58
Item name: MENGKUDU 2 Channel name: High energy : Time 3.8982 +/- 0.0285
11.43 16.46 Component name: Asperuloside minutes : Drift Times: 6.76 +/- 0.24 ms
13.59
14.69
0 147.04475
20000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
91.05455
223.06076
10000 469.00722
531.10255
580.22940
887.23131
633.15393

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1244 : DT=5.20 to 5.69 ms

3000

2500

2000
Intensity [Counts]

1500

Asperuloside
3.92
1000

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.9150 +/- 0.0285
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1244 Component name: Asperuloside minutes : Drift Times: 5.45 +/- 0.24 ms
6000 1.30
3.92 455.11628
1.26

5000 1.45

Intensity [Counts]
4e5

4000
Intensity [Counts]

1.53

2e5
3000
3.18 439.14273
457.12298
8.51 203.08158 348.11913
2000 9.86 531.10377 741.15499 883.08970
0
2.40 8.25 10.42 200 400 600 800 1000
4.35
1000 4.54 7.13 11.07 Item name: MENGKUDU 2 Channel name: High energy : Time 3.9150 +/- 0.0285
14.58
11.43 16.46 Component name: Asperuloside minutes : Drift Times: 5.30 +/- 0.24 ms
13.59
14.69
0 455.11704
2e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

275.05264 457.12450
197.01984 903.20548
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1246 : DT=7.08 to 7.56 ms

Asperuloside
3.92
500

400
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.9251 +/- 0.0285
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1246 Component name: Asperuloside minutes : Drift Times: 7.32 +/- 0.24 ms
6000 1.30
3.92 726.29871
1.26

5000 1.45
20000 748.27796

Intensity [Counts]
415.12462
4000 724.11612
1.53 487.05352
Intensity [Counts]

235.06079 780.18106
10000 253.07074
3000 193.05043 531.10353 783.11629
3.18 650.23228 917.19184
8.51
2000 9.86
0
2.40 8.25 10.42 200 400 600 800 1000
4.35
1000 11.07
4.54 7.13 14.58
Item name: MENGKUDU 2 Channel name: High energy : Time 3.9251 +/- 0.0285
11.43 16.46 Component name: Asperuloside minutes : Drift Times: 7.17 +/- 0.24 ms
13.59
14.69
0 175.04006

0 5 10 15 20
75000
Retention time [min]

Intensity [Counts]
50000
193.05060
487.05506
25000
281.01128
726.29844
349.06890 901.13730
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3-Hydroxy-12,14-diene-27-nordeane-28-nic acid [+H] : (39.7 PPM)
455.3159 : DT=5.41 to 5.89 ms

800 3-Hydroxy-12,14-diene-27-nordeane-28-nic acid


3.93

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.9265 +/-
Channel name: 3-Hydroxy-12,14-diene-27-nordeane-28-nic acid [+H] : (39.7 PPM) Component name: 3-Hydroxy-12,14- 0.0285 minutes : Drift Times: 5.65 +/- 0.24 ms
455.3159 diene-27-nordeane-28-nic acid
16.52
455.11628
1500 5e5

Intensity [Counts]
12.61
12.56
Intensity [Counts]

1000 12.34 2.5e5


3.93 12.68 16.62
9.55 12.26
439.14273
7.98 471.08747
193.05032 388.15224
13.52 499.15491 709.15349 902.13810
500 9.72 0
14.08 16.91
200 400 600 800 1000
15.67
7.80 16.98 Item name: MENGKUDU 2 Channel name: High energy : Time 3.9265 +/-
2.42 Component name: 3-Hydroxy-12,14- 0.0285 minutes : Drift Times: 5.50 +/- 0.24 ms
1.55 5.09 7.71 17.36
diene-27-nordeane-28-nic acid
0
455.11704
0 5 10 15 20 2e5
Retention time [min]

Intensity [Counts]
100000

275.05264 457.12450
197.01984 371.12316
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Anemonin [+H] : (39.7 PPM) 193.0503 : DT=5.64 to 6.12 ms

Anemonin
3.93

2000

1500
Intensity [Counts]

3.89
1000

500

4.05

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.9281 +/- 0.0285 minutes :
Channel name: Anemonin [+H] : (39.7 PPM) 193.0503 Component name: Anemonin Drift Times: 5.88 +/- 0.24 ms
3.27
455.11628

6000

Intensity [Counts]
3.93 4e5
Intensity [Counts]

4000 2e5

439.14273 459.16022
6.04 193.05032 427.03092 659.14297
471.08747 885.15169
0
2000 1.831.89
4.54 200 400 600 800 1000

6.16 Item name: MENGKUDU 2 Channel name: High energy : Time 3.9281 +/- 0.0285 minutes :
8.51 9.81 Component name: Anemonin Drift Times: 5.73 +/- 0.24 ms
7.09 12.67 14.89
0 455.11704
2e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000 175.04006

439.14403
91.05453 459.16237
277.00074 903.20499
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1243 : DT=8.07 to 8.55 ms
Asperuloside
1250
3.93

1000
Intensity [Counts]

750

500

250
3.84

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.9291 +/- 0.0285
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1243 Component name: Asperuloside minutes : Drift Times: 8.30 +/- 0.24 ms
1.30
6000
3.92 919.17849
1.26 2e5
1.45 901.13333
5000

Intensity [Counts]
4000
Intensity [Counts]

1.53 100000 455.11626

3000
3.18 487.05355 889.15922
439.14249
8.51 175.04046 589.15169 738.07568
2000 415.12430
9.86
0
2.40 8.25 10.42 200 400 600 800 1000
4.35
1000 4.54 7.13 11.07 Item name: MENGKUDU 2 Channel name: High energy : Time 3.9291 +/- 0.0285
14.58
11.43 16.46 Component name: Asperuloside minutes : Drift Times: 8.15 +/- 0.24 ms
13.59
14.69
0 75000 455.11695

0 5 10 15 20
Retention time [min] 281.01127 487.05501

Intensity [Counts]
50000
193.05059 919.18271

25000 427.03368
901.13731
409.02143
488.05935
810.31293
652.22891
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1244 : DT=6.05 to 6.53 ms

500

Asperuloside
400
3.94
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.9322 +/- 0.0285
Channel name: Asperuloside [+H] : (39.7 PPM) 415.1244 Component name: Asperuloside minutes : Drift Times: 6.23 +/- 0.24 ms
6000 1.30
3.92 459.16022
1.26 319.09182

5000 1.45
40000

Intensity [Counts]
4000
Intensity [Counts]

1.53 452.10166
20000 460.16386 901.13380
3000
3.18 659.14297 885.15169
8.51 266.10220
2000 9.86
0
2.40 8.25 10.42 200 400 600 800 1000
4.35
1000 4.54 7.13 11.07 Item name: MENGKUDU 2 Channel name: High energy : Time 3.9322 +/- 0.0285
14.58
11.43 16.46 Component name: Asperuloside minutes : Drift Times: 6.07 +/- 0.24 ms
13.59
14.69
0 175.04006

0 5 10 15 20
Retention time [min] 50000

Intensity [Counts] 25000 319.08953

459.16237
427.03361 471.08683
919.18259
587.15321
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Anemonin [+H] : (39.7 PPM) 193.0504 : DT=7.28 to 7.76 ms

250

Anemonin
3.95
200
3.89
Intensity [Counts]

150

100

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.9332 +/- 0.0285 minutes :
Channel name: Anemonin [+H] : (39.7 PPM) 193.0504 Component name: Anemonin Drift Times: 7.52 +/- 0.24 ms
3.27
781.18438

6000 30000
726.29871

Intensity [Counts]
3.93

20000
Intensity [Counts]

415.12462
4000 724.11612
235.06079
10000 253.07074 884.22139
531.10353
193.05043
6.04
0
2000 1.831.89
4.54 200 400 600 800 1000

6.16 Item name: MENGKUDU 2 Channel name: High energy : Time 3.9332 +/- 0.0285 minutes :
8.51 9.81 Component name: Anemonin Drift Times: 7.37 +/- 0.24 ms
7.09 12.67 14.89
30000 487.05506
0
0 5 10 15 20
Retention time [min] 919.18265

Intensity [Counts]
20000

176.04263
726.29844
10000 216.97959
427.03362 903.20540
601.10157

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Anemonin [+H] : (39.7 PPM) 193.0504 : DT=3.60 to 4.09 ms

3000
Intensity [Counts]

2000

1000 Anemonin
3.93

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.9382 +/- 0.0285 minutes :
Channel name: Anemonin [+H] : (39.7 PPM) 193.0504 Component name: Anemonin Drift Times: 3.85 +/- 0.24 ms
3.27
175.04046
40000

6000

Intensity [Counts]
3.93
Intensity [Counts]

20000
4000
193.05037
249.11098
6.04 325.05722
0
2000 1.831.89
4.54 200 400 600 800 1000

6.16 Item name: MENGKUDU 2 Channel name: High energy : Time 3.9382 +/- 0.0285 minutes :
8.51 9.81 Component name: Anemonin Drift Times: 3.69 +/- 0.24 ms
7.09 12.67 14.89
0
0 5 10 15 20 20000 Chiral

Retention time [min]

Intensity [Counts]
O O

O O
10000

175.04006
Mass error: 1.1 mDa

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Isohistiopterosin A [+H] : (39.7 PPM) 249.1110 : DT=3.75 to 4.23 ms

2000

Isohistiopterosin A
3.97
1500
Intensity [Counts]

1000

3.91
500

4.09

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.9667 +/- 0.0285
Channel name: Isohistiopterosin A [+H] : (39.7 PPM) 249.1110 Component name: Isohistiopterosin A minutes : Drift Times: 3.99 +/- 0.24 ms
10.91
193.05037
4000
10000
249.11098

Intensity [Counts]
3000
Intensity [Counts]

5000

2000 3.97 325.05722

7.96 0
1000 3.91 200 400 600 800 1000
10.33
3.02 7.07
5.53 Item name: MENGKUDU 2 Channel name: High energy : Time 3.9667 +/- 0.0285
8.40 11.76 12.67 Component name: Isohistiopterosin A minutes : Drift Times: 3.84 +/- 0.24 ms
2.76 13.50 16.56
18.53
0 249.11001

0 5 10 15 20 4000
Retention time [min]

Intensity [Counts]
216.97921

2000
283.11732

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bruceine H [+H] : (39.7 PPM) 427.1585 : DT=5.71 to 6.20 ms

5000

4000
Intensity [Counts]

3000

2000

1000
Bruceine H
4.02
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 3.9990 +/- 0.0285 minutes :
Channel name: Bruceine H [+H] : (39.7 PPM) 427.1585 Component name: Bruceine H Drift Times: 5.99 +/- 0.24 ms
6.13
75000 469.00636

7.06 487.14308

Intensity [Counts]
7500 50000
Intensity [Counts]

9.64 883.08820
420.14028
5000 25000 257.06524
8.85 503.11037
3.70 4.54
513.10367 865.07839 889.13029
241.06721
684.64419
8.12 0
2500 3.22 200 400 600 800 1000
2.98 9.85 Item name: MENGKUDU 2 Channel name: High energy : Time 3.9990 +/- 0.0285 minutes :
2.89 12.18 14.25
11.12 Component name: Bruceine H Drift Times: 5.83 +/- 0.24 ms
2.25 16.58
0 487.14273

0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
257.06536
469.13139

10000 218.97421 420.14188 572.13137


200.98401

695.12071 849.10687
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1587 : DT=5.68 to 6.16 ms

600

4.32

4.04
Intensity [Counts]

400

Lactiflorin
4.17

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.1469 +/- 0.0285 minutes :
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1587 Component name: Lactiflorin Drift Times: 5.92 +/- 0.24 ms
4.35
472.18146
6000 75000

Intensity [Counts]
50000

4000
Intensity [Counts]

25000 473.18248
292.08190 495.13238 795.10765
238.07159 638.17192 843.17121
2000 4.17
0
7.62 200 400 600 800 1000
8.86
5.79 10.85
9.95 13.46 Item name: MENGKUDU 2 Channel name: High energy : Time 4.1469 +/- 0.0285 minutes :
2.29 11.99 16.96 Component name: Lactiflorin Drift Times: 5.77 +/- 0.24 ms
2.04 15.18
18.53
0 472.18393

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

292.07916
10000
260.98424 511.10437

161.02341 525.19173 649.07178 865.07642


0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1593 : DT=6.13 to 6.61 ms

3000 4.35

2500

2000
Intensity [Counts]

1500

Lactiflorin
1000
4.17

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.1812 +/- 0.0285 minutes :
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1593 Component name: Lactiflorin Drift Times: 6.37 +/- 0.24 ms
4.35
656.18208
6000
30000
494.12976

Intensity [Counts]
20000
Intensity [Counts]

4000

333.11229
10000 506.14174

315.06162 872.15146
820.24012
2000 4.17
0
7.62 200 400 600 800 1000
8.86
5.79 10.85
2.29 9.95 13.46 Item name: MENGKUDU 2 Channel name: High energy : Time 4.1812 +/- 0.0285 minutes :
11.99 16.96 Component name: Lactiflorin Drift Times: 6.21 +/- 0.24 ms
2.04 15.18
18.53
0 15000 494.13112

0 5 10 15 20
476.12127
Retention time [min]

Intensity [Counts]
10000
371.05881
204.06629
5000 587.15488 818.23867
193.05007 638.17411
649.07178
872.15625
658.18947
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ginkgolide C [+H] : (39.7 PPM) 441.1382 : DT=5.27 to 5.75 ms

6000

4000
Intensity [Counts]

2000

Ginkgolide C
0 4.26
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.2438 +/- 0.0285 minutes :
Channel name: Ginkgolide C [+H] : (39.7 PPM) 441.1382 Component name: Ginkgolide C Drift Times: 5.51 +/- 0.24 ms
8.34
437.07014
20000

455.08075

Intensity [Counts]
40000 428.15394

15000
Intensity [Counts]

361.13928

20000

10000
359.12225 459.05225 771.24828 883.08808
163.04094
0
5.57 7.71 200 400 600 800 1000
5000
5.12 5.71 Item name: MENGKUDU 2 Channel name: High energy : Time 4.2438 +/- 0.0285
7.49 9.99 11.21 Component name: Ginkgolide C minutes : Drift Times: 5.36 +/- 0.24 ms
4.47
3.54
0 30000 437.07064

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
205.05059 428.15447

191.03468 376.15030
10000
177.05578 441.18569
359.12117
134.05936
485.15598 825.16871
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1608 : DT=6.08 to 6.57 ms

3000
Intensity [Counts]

2000

1000

Picroside Ⅱ
0 4.27
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.2644 +/- 0.0285 minutes :
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1608 Component name: Picroside Ⅱ Drift Times: 6.32 +/- 0.24 ms
9.79
413.08605
6000
15000
9.51 439.24412

Intensity [Counts]
10000
405.16832
4000
Intensity [Counts]

337.10217 441.18703

5000 629.12312 885.13802


680.18192
10.02
191.03432 262.10522 895.20345
11.71
2000 0
2.31 4.54 5.32 200 400 600 800 1000
7.60
4.09 6.26 12.70 Item name: MENGKUDU 2 Channel name: High energy : Time 4.2644 +/- 0.0285 minutes :
0.58
13.19 16.55 Component name: Picroside Ⅱ Drift Times: 6.17 +/- 0.24 ms

0 405.10024
15000
0 5 10 15 20
413.08770
Retention time [min]

Intensity [Counts]
10000

5000 319.09329
266.10334 555.16921
825.16913
571.19485
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Physalin C [+H] : (39.7 PPM) 511.1966 : DT=6.20 to 6.68 ms
12.79

11.84

3000
Intensity [Counts]

2000

10.00 10.86
1000
9.67
5.25 7.38
2.89 9.37 12.93
4.12 7.27 16.47
2.05 14.90 16.56
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.3357 +/- 0.0285 minutes :
Channel name: Physalin C [+H] : (39.7 PPM) 511.1966 Component name: Physalin C Drift Times: 6.44 +/- 0.24 ms
12.79
6000 463.16093
40000
11.84

Intensity [Counts]
4000
Intensity [Counts]

20000 587.15562
451.15904
10.87
337.10305 589.15685
794.22586
267.08766 597.15298
2000 892.15193
9.95 0
4.34
7.55 200 400 600 800 1000
5.43 7.27 9.67
4.12 12.93 Item name: MENGKUDU 2 Channel name: High energy : Time 4.3357 +/- 0.0285 minutes :
3.01 13.45 16.48 Component name: Physalin C Drift Times: 6.28 +/- 0.24 ms
0.61 17.82
7500 464.16166
0 276.08791 363.09848
0 5 10 15 20 248.09154
Retention time [min] 472.11282

Intensity [Counts]
5000
163.04090

483.18193
2500
600.22989
753.23733
759.16052

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6'-O-Benzoyl-4''-hydroxy-3''-methoxypaeoniflorin [+H] : (39.7 PPM)
631.2027 : DT=6.54 to 7.02 ms

800

600
Intensity [Counts]

400

4.48
200
6'-O-Benzoyl-4''-hydroxy-3''-methoxypaeoniflorin
4.33

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.3370 +/-
Channel name: 6'-O-Benzoyl-4''-hydroxy-3''-methoxypaeoniflorin [+H] : (39.7 PPM) Component name: 6'-O-Benzoyl-4''- 0.0285 minutes : Drift Times: 6.78 +/- 0.24 ms
631.2027 hydroxy-3''-methoxypaeoniflorin
8.61
587.15562
2000

Intensity [Counts]
1500 539.17979 599.15909
10000
Intensity [Counts]

680.17725
3.75 4.97 512.16618
9.16 282.09871
7.13
1000 10.17 11.32 383.06060
812.22357 946.23457
6.01
3.62 12.61
13.34 0
3.58 200 400 600 800 1000
500 3.53 14.92 18.53
Item name: MENGKUDU 2 Channel name: High energy : Time 4.3370 +/-
15.67
Component name: 6'-O-Benzoyl-4''- 0.0285 minutes : Drift Times: 6.62 +/- 0.24 ms
17.47 hydroxy-3''-methoxypaeoniflorin
0 175.03930 333.06514
0 5 10 15 20
Retention time [min] 10000

Intensity [Counts]
488.08553
163.04090 355.08144
5000
577.26428
158.97451 636.15644

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Isophysalin B [+H] : (39.7 PPM) 511.1969 : DT=7.12 to 7.60 ms
Isophysalin B
4.34

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.3428 +/- 0.0285
Channel name: Isophysalin B [+H] : (39.7 PPM) 511.1969 Component name: Isophysalin B minutes : Drift Times: 7.36 +/- 0.24 ms
6000 12.79
75000 703.21139

11.84
5000

Intensity [Counts]
50000

4000
Intensity [Counts]

10.87 25000
3000 541.15629
705.21213
669.24393
294.00626 379.06891
743.17802
2000 276.08687 964.22809
9.95 0
4.34
7.55 200 400 600 800 1000
5.43 7.27 9.67
1000 4.12 12.93 Item name: MENGKUDU 2 Channel name: High energy : Time 4.3428 +/- 0.0285
3.01 13.45 16.48 Component name: Isophysalin B minutes : Drift Times: 7.21 +/- 0.24 ms
0.61 17.82
0 216.98008
40000
0 5 10 15 20 289.03787
Retention time [min]

Intensity [Counts]
379.06900
20000

703.21257
201.06835
687.24028 767.19569
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Rehmannioside A [+H] : (39.7 PPM) 525.1821 : DT=6.25 to 6.73 ms

1000
Intensity [Counts]

750

500
Rehmannioside A
4.35

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.3468 +/- 0.0285
Channel name: Rehmannioside A [+H] : (39.7 PPM) 525.1821 Component name: Rehmannioside A minutes : Drift Times: 6.49 +/- 0.24 ms
2000 13.16
8.37
463.16093
40000

4.65
6.38 8.92 14.10

Intensity [Counts]
1500 4.59

4.34
Intensity [Counts]

13.09 20000 587.15562

1000 7.90 379.06889 599.15909


5.35 10.33
613.13706 794.22586
355.07889
3.44 631.14284 892.15193
14.2016.49 0
267.08766
500 3.10 200 400 600 800 1000
1.88 16.56
Item name: MENGKUDU 2 Channel name: High energy : Time 4.3468 +/- 0.0285
16.60 Component name: Rehmannioside A minutes : Drift Times: 6.33 +/- 0.24 ms
20000 463.16026
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
276.08791 363.09848 488.08553

248.09154 541.15333
601.13346
801.26445
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1608 : DT=8.09 to 8.58 ms
Lactiflorin
4.35

600
Intensity [Counts]

400

200
4.18

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.3509 +/- 0.0285 minutes :
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1608 Component name: Lactiflorin Drift Times: 8.34 +/- 0.24 ms
4.35
819.23567
6000

10000 463.16079

Intensity [Counts]
779.16598
855.29640
Intensity [Counts]

4000 728.16941
5000 439.12000
337.10321 703.21151

487.07706

2000 4.17 0
7.62 200 400 600 800 1000
5.62 8.86
2.29 10.85 Item name: MENGKUDU 2 Channel name: High energy : Time 4.3509 +/- 0.0285 minutes :
11.99
16.96 Component name: Lactiflorin Drift Times: 8.18 +/- 0.24 ms
2.04 13.46 18.53
0 10000 356.04504 463.15993
0 5 10 15 20
Retention time [min]

Intensity [Counts]
854.29783
303.10123
5000
282.09746 819.24109
489.08951 855.30202
198.96987
726.20186 955.23788

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1609 : DT=6.23 to 6.71 ms

Lactiflorin
4.35

3000
Intensity [Counts]

2000

1000
4.17

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.3610 +/- 0.0285 minutes :
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1609 Component name: Lactiflorin Drift Times: 6.48 +/- 0.24 ms
4.35
463.16093
40000
6000

Intensity [Counts]
Intensity [Counts]

4000 20000

379.06889
464.16237
599.15909
355.07889 813.22561
702.20509
2000 4.17 0
7.62 200 400 600 800 1000
5.62 8.86
2.29 10.85 Item name: MENGKUDU 2 Channel name: High energy : Time 4.3610 +/- 0.0285 minutes :
11.99
16.96 Component name: Lactiflorin Drift Times: 6.33 +/- 0.24 ms
2.04 13.46 18.53
20000 463.16026
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
488.08553
248.09154 363.09848
541.15333
189.05669
649.10813 801.26445

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Harpagoside [+H] : (39.7 PPM) 495.1858 : DT=5.82 to 6.30 ms

2000

1500
Intensity [Counts]

1000

4.31
500

Harpagoside
4.40
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.3984 +/- 0.0285 minutes :
Channel name: Harpagoside [+H] : (39.7 PPM) 495.1858 Component name: Harpagoside Drift Times: 6.06 +/- 0.24 ms
9.20
5000 469.00753

12.94 425.20448
8.84
50000

Intensity [Counts]
4000
Intensity [Counts]

3000
25000

517.12392
2000 10.59 282.09862 357.14655
680.18085 869.10826
11.72 0
4.69 6.30 200 400 600 800 1000
8.60
1000 3.25 5.65
4.30 13.52 Item name: MENGKUDU 2 Channel name: High energy : Time 4.3984 +/- 0.0285
16.50
Component name: Harpagoside minutes : Drift Times: 5.90 +/- 0.24 ms
2.34 18.54
0 425.20678
7500 216.06637
457.15656
0 5 10 15 20
Retention time [min] 189.05699
469.00923

Intensity [Counts]
5000

177.05583 407.12033 489.19392


278.99225
2500 520.21577

573.14236

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6-O-α-D-Galactopyra-nosylharpagoside [+H] : (39.7 PPM)
657.2352 : DT=6.89 to 7.37 ms
6-O-α-D-Galactopyra-nosylharpagoside
3000 4.41

2000
Intensity [Counts]

1000 4.34

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.4076 +/-
Channel name: 6-O-α-D-Galactopyra-nosylharpagoside [+H] : (39.7 PPM) 657.2352 Component name: 6-O-α-D-Galactopyra- 0.0285 minutes : Drift Times: 7.12 +/- 0.24 ms
4.40 nosylharpagoside
4000 657.23518

30000

Intensity [Counts]
3000
20000
Intensity [Counts]

4.18
2000 10000 665.16726
229.11839 344.07496 583.20330
12.18 703.13796 835.18519
10.42 12.11 12.92 0
6.58 200 400 600 800 1000
1000 8.80 13.66 16.55
3.55 5.61
15.03 Item name: MENGKUDU 2 Channel name: High energy : Time 4.4076 +/-
2.98 16.86 Component name: 6-O-α-D-Galactopyra- 0.0285 minutes : Drift Times: 6.96 +/- 0.24 ms
0.61 18.52
nosylharpagoside
0
30000 657.23889
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

344.07609
10000
328.10121 667.15671
189.05692 577.26358
437.06366
689.16033
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Harpagoside [+H] : (39.7 PPM) 495.1858 : DT=6.07 to 6.55 ms

3000
Intensity [Counts]

2000

1000

Harpagoside
0 4.42
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.4198 +/- 0.0285 minutes :
Channel name: Harpagoside [+H] : (39.7 PPM) 495.1858 Component name: Harpagoside Drift Times: 6.31 +/- 0.24 ms
9.20
5000 469.12946

517.12392
8.84 12.94 7500

Intensity [Counts]
4000
547.17777
5000 571.17968
Intensity [Counts]

3000 351.06842 573.14270


324.10964 616.12455
2500
308.05560 741.18332 884.09605
2000 10.59

11.72 0
4.69 6.30 200 400 600 800 1000
8.60
1000 3.25 5.65
4.30 13.52 Item name: MENGKUDU 2 Channel name: High energy : Time 4.4198 +/- 0.0285
16.50
Component name: Harpagoside minutes : Drift Times: 6.15 +/- 0.24 ms
2.34 18.54
0 239.04941

0 5 10 15 20 5000 191.03499
Retention time [min]

Intensity [Counts]
464.15258
533.18640
179.06865 344.07560
2500 575.21041
591.22869
656.20187

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Anemonin [+H] : (39.7 PPM) 193.0496 : DT=5.84 to 6.33 ms

1500

1000
Intensity [Counts]

500
Anemonin
4.48

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.4864 +/- 0.0285 minutes :
Channel name: Anemonin [+H] : (39.7 PPM) 193.0496 Component name: Anemonin Drift Times: 6.08 +/- 0.24 ms
3.27
30000 501.15672

6000

Intensity [Counts]
3.93
20000 337.10398
Intensity [Counts]

4000 464.19032
10000
509.16043
193.04956
6.04 321.02715 533.09083 901.15755

2000 1.89 0
4.54 200 400 600 800 1000

6.16 Item name: MENGKUDU 2 Channel name: High energy : Time 4.4864 +/- 0.0285 minutes :
Component name: Anemonin Drift Times: 5.93 +/- 0.24 ms
7.09 8.52 9.81 12.67 14.89
0 501.15749

0 5 10 15 20
Retention time [min] 10000

Intensity [Counts]
91.05490 177.05469

5000 423.15297 555.20445


259.07447

655.18413 883.12765
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Deacetylmatricarin-8-O-β-D-glucopyranoside [+H] : (39.7 PPM)
425.1807 : DT=5.59 to 6.07 ms
5.05

2500

2000
Intensity [Counts]

5.75

1500
4.92

1000 6.13
4.37
Deacetylmatricarin-8-O-β-D-glucopyranoside
4.53
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.5096 +/-
Channel name: Deacetylmatricarin-8-O-β-D-glucopyranoside [+H] : (39.7 PPM) Component name: Deacetylmatricarin-8-O-β- 0.0285 minutes : Drift Times: 5.83 +/- 0.24 ms
425.1807 D-glucopyranoside
5.04
437.06803
4000 30000 469.00660

Intensity [Counts]
3000 20000
381.15205
4.93
Intensity [Counts]

5.75
10000 365.13381
2000 4.37
5.94 193.04982 539.12801
673.14496 847.19076
6.13 8.46 10.97 0
3.53 200 400 600 800 1000
1000 9.20 11.16
3.03 11.22 Item name: MENGKUDU 2 Channel name: High energy : Time 4.5096 +/-
16.32
12.23 16.62 Component name: Deacetylmatricarin-8-O-β- 0.0285 minutes : Drift Times: 5.68 +/- 0.24 ms
2.88
D-glucopyranoside
0
465.19356
0 5 10 15 20 306.09817
Retention time [min]

Intensity [Counts]
5000 222.07876
218.97457 555.20445
144.04486

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Oleuropein [+H] : (39.7 PPM) 541.1935 : DT=6.65 to 7.14 ms

1000

750
Intensity [Counts]

500

Oleuropein
250 4.54

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.5370 +/- 0.0285 minutes :
Channel name: Oleuropein [+H] : (39.7 PPM) 541.1935 Component name: Oleuropein Drift Times: 6.89 +/- 0.24 ms
8.51
75000 641.21898

8.21 623.20790
3000

Intensity [Counts]
9.27 50000
5.70
Intensity [Counts]

8.15
2000 642.22002
25000 605.19837
9.51 425.13511 587.19170
407.12467 673.14344
7.98 235.06080 883.10100
5.20 338.10634 675.16258
4.34 7.76 9.80 11.62 0
1000
1.61 4.08 12.51 13.85 200 400 600 800 1000
13.17 16.53 Item name: MENGKUDU 2 Channel name: High energy : Time 4.5370 +/- 0.0285 minutes :
1.48 3.70
Component name: Oleuropein Drift Times: 6.74 +/- 0.24 ms
18.52
0 641.21169
375.09291 469.00714
0 5 10 15 20
Retention time [min]

Intensity [Counts]
277.00206
639.18552
5000 146.06104 571.23355

642.22236

871.11806

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1330 : DT=5.03 to 5.51 ms

800

600
Intensity [Counts]

400

200
Sesamoside
4.53

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.5520 +/- 0.0285 minutes :
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1330 Component name: Sesamoside Drift Times: 5.27 +/- 0.24 ms
8.06
396.12619
4000
10000

Intensity [Counts]
421.13302
349.14166
3000
453.13421
Intensity [Counts]

9.15 5000 475.17140


0.96 235.06070
883.11061
2000 641.16864
6.81
2.09 4.54 175.04055 555.20445
6.55 657.16440
6.04 0
3.18 9.23 200 400 600 800 1000
1000
11.83 Item name: MENGKUDU 2 Channel name: High energy : Time 4.5520 +/- 0.0285 minutes :
10.65
12.36 18.50 Component name: Sesamoside Drift Times: 5.11 +/- 0.24 ms
15.07
0 175.03990
15000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
395.12441
10000
349.11673
419.11960
198.96899
5000 425.13822

468.04089
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ginkgolide A [+H] : (39.7 PPM) 409.1507 : DT=4.98 to 5.46 ms
7.60
12.05
800
12.01
4.97

600
0.60
Intensity [Counts]

4.34

400 3.55
3.11 7.82
0.65 7.46
6.30 9.13
2.71 9.51 13.43
200
0.76 9.58 14.98
16.4917.24
17.89
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.6203 +/- 0.0285
Channel name: Ginkgolide A [+H] : (39.7 PPM) 409.1507 Component name: Ginkgolide A minutes : Drift Times: 5.22 +/- 0.24 ms
12.04
435.09440
7.60

10000 20000

Intensity [Counts]
7500
Intensity [Counts]

10000
205.05049

373.18441
5000 472.14665 786.25726
859.15732
505.13568
0
9.12 9.86 200 400 600 800 1000
2500
4.96 7.22 10.74
0.61 2.73 3.45 Item name: MENGKUDU 2 Channel name: High energy : Time 4.6203 +/- 0.0285
2.22 6.36 8.34 13.43 Component name: Ginkgolide A minutes : Drift Times: 5.07 +/- 0.24 ms
14.9816.57
0 40000 403.15800

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

216.97983
207.02858 405.16891
441.01159
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1775 : DT=5.57 to 6.05 ms

3000
Intensity [Counts]

2000

Cichorioside B
1000
4.62

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.6665 +/- 0.0285
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1775 Component name: Cichorioside B minutes : Drift Times: 5.81 +/- 0.24 ms
7.91
6000 455.08036

5.66 20000

Intensity [Counts]
4000 422.14585
Intensity [Counts]

405.12705
10000 469.14757

526.18574
293.11375
5.46 225.04051 849.18001
541.12371
2000 8.35 209.04696
0
4.90 7.57 200 400 600 800 1000
9.66
4.80 6.35 Item name: MENGKUDU 2 Channel name: High energy : Time 4.6665 +/- 0.0285
4.19 9.71 13.94 Component name: Cichorioside B minutes : Drift Times: 5.66 +/- 0.24 ms
3.14 16.53
18.34
0 191.03407

0 5 10 15 20
455.08161
Retention time [min] 5000 246.99083

Intensity [Counts]
187.08374

2500 488.16525

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Centaurepensin [+H] : (39.7 PPM) 435.0962 : DT=6.88 to 7.36 ms
4.57

800

Centaurepensin
600 4.68
Intensity [Counts]

400

4.74

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.6745 +/- 0.0285
Channel name: Centaurepensin [+H] : (39.7 PPM) 435.0962 Component name: Centaurepensin minutes : Drift Times: 7.12 +/- 0.24 ms
4.59
20000 594.16724

5000
15000

Intensity [Counts]
4000
4.68 10000
Intensity [Counts]

435.09621
0.96 637.20812
3000
5000 346.09117 528.23226
670.16774 867.18343
2.84 307.01164
2000
0
3.18 4.74 6.81 200 400 600 800 1000
4.83 10.04
1000 2.30 Item name: MENGKUDU 2 Channel name: High energy : Time 4.6745 +/- 0.0285
5.73 10.25
7.56 9.98 13.74 Component name: Centaurepensin minutes : Drift Times: 6.96 +/- 0.24 ms
12.79 15.68

0 306.09806
15000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
147.04431 320.07617

347.03367
5000
674.22618
455.07967 843.18512

858.16973
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Centaurepensin [+H] : (39.7 PPM) 435.0959 : DT=5.02 to 5.50 ms
4.60
1250

1000

4.56
Intensity [Counts]

750

Centaurepensin
4.68
500

250 4.77

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.7108 +/- 0.0285
Channel name: Centaurepensin [+H] : (39.7 PPM) 435.0959 Component name: Centaurepensin minutes : Drift Times: 5.26 +/- 0.24 ms
4.59
337.10322

1.5e5
5000

Intensity [Counts]
4000 100000
4.68
Intensity [Counts]

0.96
3000 50000
320.07508 399.08656
2.84
2000 222.07713
0
3.18 4.74 6.81 200 400 600 800 1000
4.83 10.04
1000 2.30 Item name: MENGKUDU 2 Channel name: High energy : Time 4.7108 +/- 0.0285
5.73 9.98 10.25
7.56 13.74 Component name: Centaurepensin minutes : Drift Times: 5.11 +/- 0.24 ms
12.79 15.68

0 337.10397
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
293.11493

20000 222.07712

215.08248
351.08408
405.12229
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Fibleucin [+H] : (39.7 PPM) 357.1331 : DT=4.75 to 5.23 ms

Fibleucin
4.78
300

4.69
4.63
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.7697 +/- 0.0285 minutes :
Channel name: Fibleucin [+H] : (39.7 PPM) 357.1331 Component name: Fibleucin Drift Times: 4.99 +/- 0.24 ms
6.98
1000 305.07835
4.79 6.93 7.39

11.33
5.45 7.56
10.23 40000

Intensity [Counts]
750 6.88
4.28 12.61
2.14 4.26 6.76
12.74
Intensity [Counts]

3.08 287.06690
13.83 20000 338.10696
500 2.10 14.12 349.10071
14.24 364.10831
14.38 16.47 216.06630 563.11843
14.86 0
250 16.55 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 4.7697 +/- 0.0285 minutes :
Component name: Fibleucin Drift Times: 4.83 +/- 0.24 ms

0 190.05001

0 5 10 15 20 259.07315
Retention time [min] 10000

Intensity [Counts]
175.04001

379.11911
5000 163.03946

389.14338

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1747 : DT=5.51 to 5.99 ms
7.91
3000

2000
Intensity [Counts]

5.66

8.35

1000
5.59
7.58
4.90 8.95
6.35
4.37 9.71 10.77
4.24 13.04 13.84 16.53 18.53

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.8798 +/- 0.0285
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1747 Component name: Cichorioside B minutes : Drift Times: 5.75 +/- 0.24 ms
7.91
391.13323

6000
40000
422.15537

Intensity [Counts]
5.66
Intensity [Counts]

363.12031
4000
20000 423.15854

435.26049
328.13280 471.14588
5.46 8.35 235.07346
2000 0
4.90 7.58 200 400 600 800 1000
9.37
4.80 6.35 9.66 Item name: MENGKUDU 2 Channel name: High energy : Time 4.8798 +/- 0.0285
4.26 10.20 13.94 16.53
Component name: Cichorioside B minutes : Drift Times: 5.59 +/- 0.24 ms
2.94
0 30000 425.13636

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

391.13445

177.05559 363.11936
10000
249.09330 427.19951

495.10882
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sonchuside A [+H] : (39.7 PPM) 413.2157 : DT=5.54 to 6.02 ms
Sonchuside A
800 4.92

4.88
600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.9168 +/- 0.0285
Channel name: Sonchuside A [+H] : (39.7 PPM) 413.2157 Component name: Sonchuside A minutes : Drift Times: 5.76 +/- 0.24 ms
4.93
425.14195
1250

363.12031
9.34 20000

Intensity [Counts]
1000

427.19280
Intensity [Counts]

8.24 9.40
13.61
750 16.59 10000 441.01135
5.09 9.52 13.67
7.29 16.66 475.17756
10.04 16.51 276.08520
4.81 13.02 581.14423
500 6.54 16.36 273.08821 741.21842 875.21620
16.96
2.98 13.88 0
17.27 200 400 600 800 1000
250 2.78 Item name: MENGKUDU 2 Channel name: High energy : Time 4.9168 +/- 0.0285
17.71 Component name: Sonchuside A minutes : Drift Times: 5.61 +/- 0.24 ms
2.52

0 363.11936

0 5 10 15 20 10000 413.21604
Retention time [min]

Intensity [Counts]
427.19951
177.05559
276.08807 495.10882
5000

507.19899

529.13203
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6-O-α-D-Galactopyra-nosylharpagoside [+H] : (39.7 PPM)
657.2390 : DT=6.94 to 7.42 ms

3000

2000
Intensity [Counts]

1000

6-O-α-D-Galactopyra-nosylharpagoside
5.01
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.9653 +/-
Channel name: 6-O-α-D-Galactopyra-nosylharpagoside [+H] : (39.7 PPM) 657.2390 Component name: 6-O-α-D-Galactopyra- 0.0285 minutes : Drift Times: 7.18 +/- 0.24 ms
4.40 nosylharpagoside

4000 457.07995
30000

Intensity [Counts]
591.21845
3000
20000
Intensity [Counts]

606.19670
10000 425.14192 668.21921
2000 4.18
583.19698 722.21028 859.22948
295.10310
12.18
294.09940
10.42 12.09 0
1000 6.58 12.91 200 400 600 800 1000
8.79 16.55
3.55 5.61
13.66 Item name: MENGKUDU 2 Channel name: High energy : Time 4.9653 +/-
16.86 Component name: 6-O-α-D-Galactopyra- 0.0285 minutes : Drift Times: 7.03 +/- 0.24 ms
2.68
18.52 nosylharpagoside
0
30000 457.08076
0 5 10 15 20
Retention time [min] 325.03811

Intensity [Counts]
20000 307.02574

10000 476.12316
235.05833
591.21329 675.16623 817.25620

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 4,7-Didehydroneophysalin B [+H] : (39.7 PPM) 509.1798 : DT=6.15
to 6.63 ms

600
Intensity [Counts]

400
4.63

4,7-Didehydroneophysalin B
4.96
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.9656 +/-
Channel name: 4,7-Didehydroneophysalin B [+H] : (39.7 PPM) 509.1798 Component name: 4,7-Didehydroneophysalin 0.0285 minutes : Drift Times: 6.39 +/- 0.24 ms
B
0.49
531.17650

1500 15000
483.13484

Intensity [Counts]
6.11 7.69 295.10216
10000 462.16743
Intensity [Counts]

8.57 623.18035
1000 2.22 6.79 10.90 859.23101
8.61
4.56 8.82 11.82 5000 630.19615 887.16304
294.09902
4.34 12.37 277.12294

500 1.91 3.59 13.39 16.51 0


1.80 14.01 16.61 200 400 600 800 1000

16.75 18.53 Item name: MENGKUDU 2 Channel name: High energy : Time 4.9656 +/-
Component name: 4,7-Didehydroneophysalin 0.0285 minutes : Drift Times: 6.24 +/- 0.24 ms
B
0
325.03813
0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
441.11284

10000 567.20690
198.96967

193.04987 568.20070
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1618 : DT=5.98 to 6.46 ms

2500

2000
Intensity [Counts]

1500

1000

500 Lactiflorin
4.96

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.9693 +/- 0.0285 minutes :
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1618 Component name: Lactiflorin Drift Times: 6.22 +/- 0.24 ms
4.35
530.18696
6000
20000

Intensity [Counts]
531.17650

295.10216
Intensity [Counts]

4000 461.16193
10000 623.18035
859.23101
631.19431 933.20037
294.09902
786.21514
4.17 115.05192
2000 0
7.62 8.60 200 400 600 800 1000
5.62 10.85
2.29 8.86 Item name: MENGKUDU 2 Channel name: High energy : Time 4.9693 +/- 0.0285 minutes :
11.10 13.46
16.96 Component name: Lactiflorin Drift Times: 6.07 +/- 0.24 ms
2.04 11.99
18.53
0 457.08117

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts] 10000 505.22819


198.96967
327.04132 531.17842
186.96914 568.20070
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ginkgolide B [+H] : Ginkgolide M [+H] : (39.7 PPM) 425.1418 :
DT=5.28 to 5.76 ms
Ginkgolide M
4.97
12500

10000
Intensity [Counts]

4.85
7500

5000
5.15

2500
5.37

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 4.9745 +/- 0.0285 minutes :
Channel name: Ginkgolide B [+H] : Ginkgolide M [+H] : (39.7 PPM) 425.1418 Component name: Ginkgolide B Drift Times: 5.52 +/- 0.24 ms
4.97
20000 425.14179
2e5

Intensity [Counts]
15000 3.53
Intensity [Counts]

4.85 8.46 100000 457.07992

10000 10.98
325.03817
280.13189 631.19445
5.15 537.16128 859.23283
0
5000 3.08 200 400 600 800 1000
9.16
5.41 8.31 Item name: MENGKUDU 2 Channel name: High energy : Time 4.9745 +/- 0.0285
13.16 Component name: Ginkgolide B minutes : Drift Times: 5.36 +/- 0.24 ms
16.50
0 425.14250

0 5 10 15 20
100000
Retention time [min]

Intensity [Counts]
50000
441.11154
325.03813
459.08320
307.02552
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2 Channel name: Low energy : Time 4.9745 +/- 0.0285
Component name: Ginkgolide M minutes : Drift Times: 5.52 +/- 0.24 ms

425.14179
2e5

Intensity [Counts]
100000 457.07992

325.03817
280.13189 631.19445
537.16128 859.23283
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 4.9745 +/- 0.0285
Component name: Ginkgolide M minutes : Drift Times: 5.36 +/- 0.24 ms

425.14250

100000

Intensity [Counts]
50000
441.11154
325.03813
459.08320
307.02552
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Schizonepetoside E [+H] : (39.7 PPM) 349.1842 : DT=4.54 to 5.02 ms

Schizonepetoside E
5.02

4000
Intensity [Counts]

3000

4.96

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.0131 +/- 0.0285
Channel name: Schizonepetoside E [+H] : (39.7 PPM) 349.1842 Component name: Schizonepetoside E minutes : Drift Times: 4.78 +/- 0.24 ms
5.02
349.18421
6000

50000

Intensity [Counts]
13.74
Intensity [Counts]

4000
13.41 25000
378.02787
4.96
15.46
12.94 278.10433 379.03045
16.54 207.08221
422.13368 657.15091
2000 16.60 0
12.76 200 400 600 800 1000
12.27 16.77 Item name: MENGKUDU 2 Channel name: High energy : Time 5.0131 +/- 0.0285
5.27 7.87
11.75 Component name: Schizonepetoside E minutes : Drift Times: 4.63 +/- 0.24 ms
2.78 6.72
2.22 16.98
0 349.18483

0 5 10 15 20 40000
Retention time [min]

Intensity [Counts]
20000 347.09397

292.17754

201.00745 365.13156

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Melia-ionoside A [+H] : (39.7 PPM) 393.2472 : DT=5.40 to 5.88 ms
Melia-ionoside A
6000 5.04

4000
Intensity [Counts]

2000

5.12

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.0414 +/- 0.0285
Channel name: Melia-ionoside A [+H] : (39.7 PPM) 393.2472 Component name: Melia-ionoside A minutes : Drift Times: 5.65 +/- 0.24 ms
5.04
393.24717

6000 40000 425.14145

Intensity [Counts]
475.12361
Intensity [Counts]

4000 20000
377.27372
361.13295 802.24140
193.05202 593.09600
16.61 0
2000 200 400 600 800 1000
16.51 16.66

16.25 Item name: MENGKUDU 2 Channel name: High energy : Time 5.0414 +/- 0.0285
5.74 9.11 12.79 Component name: Melia-ionoside A minutes : Drift Times: 5.50 +/- 0.24 ms
9.87 11.82 16.97

0 393.24849

0 5 10 15 20 40000 425.14271
Retention time [min]

Intensity [Counts]
20000
377.27532

163.04054 301.11502 459.14696

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lactucopicrin [+H] : (39.7 PPM) 411.1411 : DT=5.07 to 5.55 ms

Lactucopicrin
5.09
5000

4000
Intensity [Counts]

3000

2000

1000
5.29

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.0917 +/- 0.0285
Channel name: Lactucopicrin [+H] : (39.7 PPM) 411.1411 Component name: Lactucopicrin minutes : Drift Times: 5.32 +/- 0.24 ms
5.09
10000 411.14111

50000

Intensity [Counts]
7500
Intensity [Counts]

347.12394
25000
315.09681
5000
293.11529 413.14507
176.07189 622.17827
0
2500 3.20 7.03 200 400 600 800 1000
6.60 13.43
Item name: MENGKUDU 2 Channel name: High energy : Time 5.0917 +/- 0.0285
2.97 9.14 12.03
5.84 14.17 Component name: Lactucopicrin minutes : Drift Times: 5.16 +/- 0.24 ms
2.05
0 315.09777
15000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000 441.12226
287.10401
204.06575
5000 133.02894

453.16856

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Pterodontoside B [+H] : (39.7 PPM) 413.2150 : DT=5.46 to 5.94 ms
4.93
800

4.89

600
Intensity [Counts]

Pterodontoside B
400 5.10

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.0942 +/- 0.0285
Channel name: Pterodontoside B [+H] : (39.7 PPM) 413.2150 Component name: Pterodontoside B minutes : Drift Times: 5.70 +/- 0.24 ms
4.93
404.14659
1250
2e5
9.34

Intensity [Counts]
1000

8.24 9.40
Intensity [Counts]

13.61 409.18368
750 100000
5.09 9.52
13.67 16.51
7.29 16.59 441.12389
13.02
4.81 16.36 443.14258
500 10.04 16.66 387.11327
6.54 207.13833 802.24140 908.26993
13.88 16.96 622.17827
2.98 0
17.27 200 400 600 800 1000
250 2.78 Item name: MENGKUDU 2 Channel name: High energy : Time 5.0942 +/- 0.0285
17.71 Component name: Pterodontoside B minutes : Drift Times: 5.54 +/- 0.24 ms
2.52

0 404.14806

0 5 10 15 20 100000
Retention time [min]

Intensity [Counts]
409.18426
50000 387.11985

289.11967
441.12226
215.08369
604.17031
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lactucopicrin [+H] : (39.7 PPM) 411.1409 : DT=8.10 to 8.58 ms
Lactucopicrin
5.10

600
Intensity [Counts]

5.04
400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.0947 +/- 0.0285
Channel name: Lactucopicrin [+H] : (39.7 PPM) 411.1409 Component name: Lactucopicrin minutes : Drift Times: 8.33 +/- 0.24 ms
5.09
10000 2e5 802.24138

Intensity [Counts]
7500
Intensity [Counts]

100000
803.24409
5000
623.18123 824.22450
319.09272 411.14094 871.26199
0
2500 3.20 7.03 200 400 600 800 1000
6.60 13.43
Item name: MENGKUDU 2 Channel name: High energy : Time 5.0947 +/- 0.0285
2.97 9.14 12.03
5.84 14.17 Component name: Lactucopicrin minutes : Drift Times: 8.18 +/- 0.24 ms
2.05
0 460.12610

0 5 10 15 20 75000
Retention time [min]

Intensity [Counts]
50000
442.11636

25000 400.10463
622.18070
204.06575 382.09388 824.22212
604.17031 640.18962
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yadanzigan [+H] : (39.7 PPM) 575.2334 : DT=6.42 to 6.90 ms

1500
Intensity [Counts]

1000

Yadanzigan
500 5.10

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.1049 +/- 0.0285 minutes :
Channel name: Yadanzigan [+H] : (39.7 PPM) 575.2334 Component name: Yadanzigan Drift Times: 6.66 +/- 0.24 ms
3000 7.25
3.45 561.20572

2500 7.58 10000 527.21922


591.20949

Intensity [Counts]
411.14130
2000
Intensity [Counts]

595.18401
5000 308.11515
661.15944
1500 5.45 6.45
804.24256 887.23962
7.67
1000 11.20
5.10 8.44 16.50 0
12.69
200 400 600 800 1000
12.79
500 2.87 16.58 Item name: MENGKUDU 2 Channel name: High energy : Time 5.1049 +/- 0.0285 minutes :
18.52 Component name: Yadanzigan Drift Times: 6.51 +/- 0.24 ms
0.74

0 308.11413

0 5 10 15 20 5000
411.14292 543.20697
Retention time [min]

Intensity [Counts]
275.07232
561.20939
248.09279 537.25050
2500 591.15512
245.08533
595.17783

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1608 : DT=5.88 to 6.36 ms

1250

1000
Intensity [Counts]

750
5.62

500 Lactiflorin
5.15

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.1455 +/- 0.0285 minutes :
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1608 Component name: Lactiflorin Drift Times: 6.12 +/- 0.24 ms
4.35
453.27223
6000 40000

Intensity [Counts]
Intensity [Counts]

4000 20000 505.22598


323.20617
513.12498
290.10305
280.11974 545.14117
917.24441
2000 4.17 0
7.62 200 400 600 800 1000
5.62 8.86
2.29 10.85 Item name: MENGKUDU 2 Channel name: High energy : Time 5.1455 +/- 0.0285 minutes :
11.99
16.96 Component name: Lactiflorin Drift Times: 5.96 +/- 0.24 ms
2.04 13.46 18.53
0 323.20897

0 5 10 15 20 10000
Retention time [min] 475.25509

Intensity [Counts]
222.07775 575.10861
5000
177.05494

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ginkgolide M [+H] : (39.7 PPM) 425.1409 : DT=5.38 to 5.86 ms

4.97
12500

10000
Intensity [Counts]

7500 4.85

5000

Ginkgolide M
2500 5.15

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.1478 +/- 0.0285
Channel name: Ginkgolide M [+H] : (39.7 PPM) 425.1409 Component name: Ginkgolide M minutes : Drift Times: 5.61 +/- 0.24 ms
4.97
20000 376.19915

3e5

Intensity [Counts]
15000 3.53
2e5
Intensity [Counts]

4.85 8.46

10000 10.98 100000


377.20163
425.14094
235.06119 369.09738
5.15 539.09155 770.25053
0
5000 3.08 200 400 600 800 1000
9.16
5.41 8.31 Item name: MENGKUDU 2 Channel name: High energy : Time 5.1478 +/- 0.0285
13.16 Component name: Ginkgolide M minutes : Drift Times: 5.46 +/- 0.24 ms
16.50
0 3e5 376.20034

0 5 10 15 20
Retention time [min]

Intensity [Counts]
2e5

100000
377.20269

145.02942 290.10472 425.14287


0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Actinidioionoside [+H] : (39.7 PPM) 407.2266 : DT=5.66 to 6.14 ms
16.51

2500

2000
16.60
Intensity [Counts]

1500

1000
16.42

500 16.31
14.23
4.93 7.15 8.82 15.26 17.08
2.51 13.32
0.74
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.2327 +/- 0.0285
Channel name: Actinidioionoside [+H] : (39.7 PPM) 407.2266 Component name: Actinidioionoside minutes : Drift Times: 5.88 +/- 0.24 ms
16.51
16.61 450.13747
4000
495.11483
15000
290.10326

Intensity [Counts]
3000
10000
Intensity [Counts]

2000 5000 262.10909 529.17890


610.12406 771.20952 838.30513

16.43 0
1000 200 400 600 800 1000
16.30 Item name: MENGKUDU 2 Channel name: High energy : Time 5.2327 +/- 0.0285
4.56 10.30 12.07 17.08
2.56 5.25 7.15 8.60 Component name: Actinidioionoside minutes : Drift Times: 5.72 +/- 0.24 ms
18.47
0.73
0 290.10387

0 5 10 15 20
Retention time [min] 10000

Intensity [Counts]
450.13744

499.10661
5000

161.07229 224.09076

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Physalin C [+H] : (39.7 PPM) 511.1948 : DT=5.94 to 6.42 ms
12.79
4000
11.84

3000
Intensity [Counts]

2000

10.14
1000
7.42 10.03
2.05 3.01 5.38 9.32 13.03
2.92 16.47 17.83
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.2372 +/- 0.0285 minutes :
Channel name: Physalin C [+H] : (39.7 PPM) 511.1948 Component name: Physalin C Drift Times: 6.23 +/- 0.24 ms
12.79
20000 450.13747 517.12017
11.84 308.11509
6000
15000

Intensity [Counts]
10000
Intensity [Counts]

4000
520.19018
5000 529.17890
10.87
553.20328 872.26860
205.05010 798.17227

2000 9.95 0
4.34 7.55 200 400 600 800 1000
5.43 7.27 9.79 12.93
4.12 Item name: MENGKUDU 2 Channel name: High energy : Time 5.2372 +/- 0.0285 minutes :
13.45 16.48 Component name: Physalin C Drift Times: 6.07 +/- 0.24 ms
3.01
0.61
0 308.11422

0 5 10 15 20 30000
Retention time [min]

Intensity [Counts]
20000
290.10387
345.02582
10000 257.98588 521.20945
537.15925
147.04446
838.30874
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2130 : DT=5.49 to 5.97 ms

1000

750

Cichorioside C
Intensity [Counts]

5.25
500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.2468 +/- 0.0285
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2130 Component name: Cichorioside C minutes : Drift Times: 5.73 +/- 0.24 ms
8.24
13.51 290.10326
1250 13.64 377.13948
8.95 428.15073
9.02 10000 443.14734

Intensity [Counts]
1000 9.06
7.14 495.11459
5.80 13.01
Intensity [Counts]

13.69 16.53
750 5.25 5000
262.10909
5.09 16.60
9.60 11.63 610.12406
4.81
500
14.51 16.63
3.99 0
3.17 16.69 200 400 600 800 1000
250 2.51 17.08
0.96 18.55 Item name: MENGKUDU 2 Channel name: High energy : Time 5.2468 +/- 0.0285
Component name: Cichorioside C minutes : Drift Times: 5.57 +/- 0.24 ms

0 450.23528
377.13472
0 5 10 15 20
7500
Retention time [min]

Intensity [Counts]
5000 499.10661
373.18374

2500
317.11159

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅰ [+H] : (39.7 PPM) 493.1703 : DT=6.17 to 6.65 ms
5.43

1000

750
Picroside Ⅰ
Intensity [Counts]

5.24

500
7.23

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.2490 +/- 0.0285 minutes :
Channel name: Picroside Ⅰ [+H] : (39.7 PPM) 493.1703 Component name: Picroside Ⅰ Drift Times: 6.41 +/- 0.24 ms
5.43
2500 290.10343
30000

Intensity [Counts]
2000 518.14237
20000 308.11509
Intensity [Counts]

1500 488.17973
3.85
10.47 555.20899
2.29 6.82 10000
4.52 7.91 480.16064
561.25527
1000 8.68
205.05010 839.30587
3.64 0
11.82
12.84 200 400 600 800 1000
500 1.88
13.02 16.47 Item name: MENGKUDU 2 Channel name: High energy : Time 5.2490 +/- 0.0285 minutes :
Component name: Picroside Ⅰ Drift Times: 6.25 +/- 0.24 ms
18.54
0 344.02353

0 5 10 15 20
Retention time [min] 290.10361
50000

Intensity [Counts] 25000

274.01763 521.20945
227.97609 545.25471 838.30874
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone E [+H] : (39.7 PPM) 451.2310 : DT=5.76 to 6.24 ms

Nigakilactone E
5.37
5.30

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.2909 +/- 0.0285
Channel name: Nigakilactone E [+H] : (39.7 PPM) 451.2310 Component name: Nigakilactone E minutes : Drift Times: 6.00 +/- 0.24 ms
13.30
2000 469.17883
13.45 451.23105 513.12447
7500
441.12856

Intensity [Counts]
257.06533
1500
415.14423
5000 830.19896
Intensity [Counts]

534.18023
239.05431
5.37 6.48
1000 16.57 2500 773.19066
5.30 872.26860
16.50 609.12131
5.14 11.81
8.20 10.72
5.06 9.16 14.03 0
500 4.83 15.13 200 400 600 800 1000
16.71
4.59 Item name: MENGKUDU 2 Channel name: High energy : Time 5.2909 +/- 0.0285
3.84 16.78 Component name: Nigakilactone E minutes : Drift Times: 5.85 +/- 0.24 ms

0 489.23059

0 5 10 15 20
222.07729
Retention time [min]
411.20435

Intensity [Counts]
4000 176.07178
501.19947
513.12268
2000 515.12217
525.09286

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Kansuinin B [+H] : (39.7 PPM) 723.2655 : DT=7.61 to 8.09 ms

1000

750
Intensity [Counts]

Kansuinin B
500 5.31

5.20
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.3008 +/- 0.0285 minutes :
Channel name: Kansuinin B [+H] : (39.7 PPM) 723.2655 Component name: Kansuinin B Drift Times: 7.86 +/- 0.24 ms
6.33
30000 739.24112

1500

Intensity [Counts]
20000
771.18012
Intensity [Counts]

792.24133
1000 10.52 10000 723.26553
11.86
2.73 7.65 8.62 12.30
342.11013 793.24266
5.30 608.17324
8.66 357.07207 837.24062
2.68 297.11372
4.77 12.58 16.48 514.12489 869.14902
0
500 13.09
4.47 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 5.3008 +/- 0.0285 minutes :
1.44 18.53 Component name: Kansuinin B Drift Times: 7.70 +/- 0.24 ms

0 15000 739.24467

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
342.11008
270.12512 740.23891

5000 262.10642 609.12776


771.18329
417.15119
144.04483
805.21123
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Brucealin A [+H] : (39.7 PPM) 683.2532 : DT=7.08 to 7.56 ms

1000

750
Intensity [Counts]

500

5.27
250
Brucealin A
5.31

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.3314 +/- 0.0285 minutes :
Channel name: Brucealin A [+H] : (39.7 PPM) 683.2532 Component name: Brucealin A Drift Times: 7.27 +/- 0.24 ms
9.81
697.23442
649.20113
635.17060
1500 11.03 5000

Intensity [Counts]
555.20514
11.32 742.24942
295.06348
Intensity [Counts]

548.18895
2500 337.10302
1000 758.23513
6.76 8.87 11.37 13.14 963.28442
8.43 11.63 16.53
5.11 7.75 795.10364
6.00 13.85
2.89 0
500
2.72 4.63 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 5.3314 +/- 0.0285 minutes :
2.28 16.76 18.53
Component name: Brucealin A Drift Times: 7.11 +/- 0.24 ms

0 417.14894

0 5 10 15 20 4000 216.97980
673.26886
Retention time [min]

Intensity [Counts]
242.04679
595.23166

2000 700.23409
770.18883

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Dehydrobruceine B [+H] : (39.7 PPM) 479.1553 : DT=5.76 to 6.24 ms

800

600
Intensity [Counts]

6.04

5.90
400

Dehydrobruceine B
5.37
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.3646 +/- 0.0285
Channel name: Dehydrobruceine B [+H] : (39.7 PPM) 479.1553 Component name: Dehydrobruceine B minutes : Drift Times: 6.00 +/- 0.24 ms
2500 6.06
418.16240

6.41
2000
40000

Intensity [Counts]
7.13
5.90
5.40
Intensity [Counts]

1500
9.21 20000
9.41 452.16629
8.83 11.02
1000 405.17296
513.12149
4.74 11.27 903.22509
295.06322 827.21740
0
3.84 4.30 11.39 200 400 600 800 1000
500 11.89
1.04
Item name: MENGKUDU 2 Channel name: High energy : Time 5.3646 +/- 0.0285
14.76 Component name: Dehydrobruceine B minutes : Drift Times: 5.85 +/- 0.24 ms
18.54
0 418.16252

0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
289.11793

505.22753
10000

276.08726
257.06658 530.15973

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ulmoside [+H] : (39.7 PPM) 509.1865 : DT=5.97 to 6.45 ms

500

400
Intensity [Counts]

300
Ulmoside
5.37
200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.3653 +/- 0.0285 minutes :
Channel name: Ulmoside [+H] : (39.7 PPM) 509.1865 Component name: Ulmoside Drift Times: 6.21 +/- 0.24 ms
6.11
1250 7.41 496.15304
7.70
454.15067
10000
2.22 6.80 10.90 513.12149

Intensity [Counts]
1000
10.84
451.22772
1.91 551.20288
13.39
Intensity [Counts]

11.85 405.17296
750 4.56 12.37 5000
4.33 295.06322
553.21308
3.78 240.08684
13.79
579.18905 849.21413
500 14.01
1.84
1.81 14.91 0
16.46
200 400 600 800 1000
250 17.29 Item name: MENGKUDU 2 Channel name: High energy : Time 5.3653 +/- 0.0285 minutes :
Component name: Ulmoside Drift Times: 6.06 +/- 0.24 ms

0 15000 337.10449

0 5 10 15 20
Retention time [min]
505.22753

Intensity [Counts]
10000

276.08726
5000
248.09088 542.20320

589.20597
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2010 : DT=7.58 to 8.06 ms
5.71

600
Intensity [Counts]

400 5.65
5.62

ApocynosideⅠ
5.37
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.3820 +/- 0.0285
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2010 Component name: ApocynosideⅠ minutes : Drift Times: 7.82 +/- 0.24 ms
8.63
10000 383.14626

30000

Intensity [Counts]
7500
20000
Intensity [Counts]

621.21408
5000 5.70 387.20098
10000 749.25208
401.16162
338.10855 774.22904
5.62
0
2500 5.42 200 400 600 800 1000
8.41 16.58
5.15 Item name: MENGKUDU 2 Channel name: High energy : Time 5.3820 +/- 0.0285
7.65 10.04
Component name: ApocynosideⅠ minutes : Drift Times: 7.67 +/- 0.24 ms
4.69 10.12 14.92 16.95

0 383.14652

0 5 10 15 20 337.10458
Retention time [min] 20000

Intensity [Counts] 10000


333.07680
259.07192 622.22217 705.16507

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1386 : DT=6.38 to 6.86 ms

3000

2000
Intensity [Counts]

1000

ArteamisinineⅠ
5.39

5.34

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.3974 +/- 0.0285
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1386 Component name: ArteamisinineⅠ minutes : Drift Times: 6.62 +/- 0.24 ms
5.70
337.10404
10000

20000
510.18524

Intensity [Counts]
7500 493.16304
Intensity [Counts]

6.08 10000 593.15773


207.13856
5000
606.17666
901.27331
825.68901
5.42
0
2500 200 400 600 800 1000

5.13 Item name: MENGKUDU 2 Channel name: High energy : Time 5.3974 +/- 0.0285
7.81 15.71 16.53 Component name: ArteamisinineⅠ minutes : Drift Times: 6.47 +/- 0.24 ms
4.42 6.99 9.03 10.67 13.44
10000 493.15992
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
91.05389 333.07722
5000 559.23794
302.10256 339.15550
587.18912

621.21461
667.14216
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2011 : DT=6.38 to 6.86 ms
5.70

1250

1000
Intensity [Counts]

750
ApocynosideⅠ
5.42
500
5.37

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4095 +/- 0.0285
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2011 Component name: ApocynosideⅠ minutes : Drift Times: 6.61 +/- 0.24 ms
8.63
10000 337.10404

20000
510.18524

Intensity [Counts]
7500
493.16304
Intensity [Counts]

10000 593.15773
207.13856
5000 5.70
606.17666
901.27331
825.68901
5.62
0
2500 5.42 200 400 600 800 1000
8.41 16.58
5.15 Item name: MENGKUDU 2 Channel name: High energy : Time 5.4095 +/- 0.0285
7.65 10.04
16.95 Component name: ApocynosideⅠ minutes : Drift Times: 6.46 +/- 0.24 ms
4.69 10.12 14.92
10000 493.15992
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
361.04979
91.05389
5000 333.07722
510.18906
233.09301
575.23366
621.21461
905.26616
667.14216
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 7-O-Methylmorroniside [+H] : (39.7 PPM) 421.1694 : DT=5.49 to
5.97 ms

2500

2000
Intensity [Counts]

1500

1000

5.28 5.56
500
7-O-Methylmorroniside
5.43
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4208 +/-
Channel name: 7-O-Methylmorroniside [+H] : (39.7 PPM) 421.1694 Component name: 7-O-Methylmorroniside 0.0285 minutes : Drift Times: 5.73 +/- 0.24 ms
2.95
409.18391
4000
1.5e5

Intensity [Counts]
3000 2.84
100000
3.36
Intensity [Counts]

2.78

10.16 50000 366.17696 441.12295


2000
8.05 9.99 466.16144
189.12964 321.07886 623.20078 765.24882
3.56 6.82 478.17693
2.34 0
3.60 9.16 10.91 200 400 600 800 1000
1000
12.33
2.25 Item name: MENGKUDU 2 Channel name: High energy : Time 5.4208 +/-
0.98 12.89 Component name: 7-O-Methylmorroniside 0.0285 minutes : Drift Times: 5.58 +/- 0.24 ms
14.49
16.64
0 409.18510

0 5 10 15 20
75000
Retention time [min]

Intensity [Counts]
50000

175.04024
25000
393.20930 410.18783

466.16309
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2014 : DT=6.90 to 7.38 ms

800

ApocynosideⅠ
600 5.43
Intensity [Counts]

400

5.36

200 5.33

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4238 +/- 0.0285
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2014 Component name: ApocynosideⅠ minutes : Drift Times: 7.14 +/- 0.24 ms
8.63
10000 641.21973

100000

Intensity [Counts]
7500
Intensity [Counts]

623.20798
50000
383.14627
5000 5.70
337.10403 591.20565 643.22619
679.23142
5.62 225.14629 554.16496 943.27718
0
2500 5.42 200 400 600 800 1000
8.41 16.58
5.15 Item name: MENGKUDU 2 Channel name: High energy : Time 5.4238 +/- 0.0285
7.65 10.04
16.95 Component name: ApocynosideⅠ minutes : Drift Times: 6.98 +/- 0.24 ms
2.47 4.69 10.12 14.92
0 175.04021
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
623.21092
641.22259
20000
337.10460
188.07087 383.14654
305.07681
461.15283
657.18013 843.19282
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yadanzigan [+H] : (39.7 PPM) 575.2311 : DT=6.75 to 7.23 ms

1500
Intensity [Counts]

1000
Yadanzigan
5.44

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4410 +/- 0.0285 minutes :
Channel name: Yadanzigan [+H] : (39.7 PPM) 575.2311 Component name: Yadanzigan Drift Times: 6.97 +/- 0.24 ms
3.45
3000 40000 591.20565
7.25
7.58
30000

Intensity [Counts]
2000 20000
Intensity [Counts]

605.18672

586.25037
5.45 6.45
10000 623.20063
299.12798 371.15154 511.18634
640.20754
8.44 9.39 225.14629 911.29739
1000 11.21
3.86 16.50 0
11.55 200 400 600 800 1000
12.88 16.59 Item name: MENGKUDU 2 Channel name: High energy : Time 5.4410 +/- 0.0285 minutes :
3.25
Component name: Yadanzigan Drift Times: 6.82 +/- 0.24 ms
2.87 18.52
0 175.04021
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
591.20604

275.05434 437.10562
107.08631 605.18226
635.16289
843.19282
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Fibleucin [+H] : (39.7 PPM) 357.1329 : DT=4.87 to 5.35 ms
Fibleucin
400
5.45

300
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4456 +/- 0.0285 minutes :
Channel name: Fibleucin [+H] : (39.7 PPM) 357.1329 Component name: Fibleucin Drift Times: 5.11 +/- 0.24 ms
6.98
1000 319.13023
7.39
4.79 6.93

11.33 347.12397
5.45 7.56 20000
10.23

Intensity [Counts]
307.12812
750 6.88
4.28 12.61 293.11488
2.14 6.76
4.26 12.74
Intensity [Counts]

3.08 385.14995
13.83 10000
500 2.10 405.16682
14.12
1.74 191.08429
14.24
577.19083
14.38 16.47
16.55 0
250 16.66 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 5.4456 +/- 0.0285 minutes :
Component name: Fibleucin Drift Times: 4.96 +/- 0.24 ms

0 191.08244
319.12648
0 5 10 15 20 15000
175.04029
Retention time [min]

Intensity [Counts]
347.12202
10000

5000 353.09636
174.05481
421.17551
607.16927
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1754 : DT=5.92 to 6.41 ms

5.67

3000
Intensity [Counts]

2000

5.62

1000 Cichorioside B
5.46
5.80

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4568 +/- 0.0285
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1754 Component name: Cichorioside B minutes : Drift Times: 6.14 +/- 0.24 ms
7.91
441.17536
6000
15000
408.13730

Intensity [Counts]
5.66
529.13362
10000 299.12833
533.21789
Intensity [Counts]

4000

5000
551.08176
211.17019 889.30243
5.46
8.35
2000 0
4.90 7.57 200 400 600 800 1000
9.66
4.80 6.35 Item name: MENGKUDU 2 Channel name: High energy : Time 5.4568 +/- 0.0285
4.26 9.71 12.37 13.94 Component name: Cichorioside B minutes : Drift Times: 5.98 +/- 0.24 ms
2.94 16.53
30000 175.04024
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

10000 307.12911 397.18989


507.23942
601.12693

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bruceaketolic acid [+H] : (39.7 PPM) 485.1663 : DT=5.88 to 6.37 ms
6.25
3000

8.95
2000 6.20
Intensity [Counts]

6.88
6.03 9.69
7.02
5.97

1000 7.07

8.65
3.18 4.29
8.23 10.45 11.99
1.40
12.75 14.85 16.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4659 +/- 0.0285
Channel name: Bruceaketolic acid [+H] : (39.7 PPM) 485.1663 Component name: Bruceaketolic acid minutes : Drift Times: 6.13 +/- 0.24 ms
6.25
8.95 441.17536

5000 15000
408.13730

Intensity [Counts]
507.24333
6.04
4000 10000 299.12833 529.13362
9.69
Intensity [Counts]

533.21789
3000 6.88
5000
7.01 551.08176
211.17019 889.30243
759.22498
2000
0
8.59 200 400 600 800 1000
3.99 10.00 11.83
1000 3.18
Item name: MENGKUDU 2 Channel name: High energy : Time 5.4659 +/- 0.0285
1.40 11.96 Component name: Bruceaketolic acid minutes : Drift Times: 5.97 +/- 0.24 ms
12.89 14.84 18.54
30000 175.04024
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

10000 307.12911 397.18989


507.23942
601.12693

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1462 : DT=8.66 to 9.14 ms
8-Epi-loganic acid
5.50
5.45

750
Intensity [Counts]

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4763 +/- 0.0285
Channel name: 8-Epi-loganic acid [+H] : (39.7 PPM) 377.1462 Component name: 8-Epi-loganic acid minutes : Drift Times: 8.89 +/- 0.24 ms
5.50
60000 377.14616
20000

Intensity [Counts]
868.28852
40000
Intensity [Counts]

10000

869.28894
577.19060 818.24118
379.14845

20000 753.18556
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 5.4763 +/- 0.0285
1.44 Component name: 8-Epi-loganic acid minutes : Drift Times: 8.74 +/- 0.24 ms
2.69 6.19
0 377.14717

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

10000
577.19232
351.12187
205.09968 605.18153 859.16235
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-Debenzoylpaeoniflorin [+H] : 8-Epi-loganic acid [+H] : (39.7 PPM)
377.1462 : DT=5.18 to 5.66 ms
8-Epi-loganic acid
5.50

30000
Intensity [Counts]

20000

10000

5.24
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4893 +/-
Channel name: 8-Debenzoylpaeoniflorin [+H] : 8-Epi-loganic acid [+H] : (39.7 PPM) Component name: 8-Debenzoylpaeoniflorin 0.0285 minutes : Drift Times: 5.42 +/- 0.24 ms
377.1462
5.50 377.14616
4e5
60000

Intensity [Counts]
40000 2e5
Intensity [Counts]

243.08801 399.12732
443.13896 723.17042
20000 0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 5.4893 +/-
1.44 Component name: 8-Debenzoylpaeoniflorin 0.0285 minutes : Drift Times: 5.27 +/- 0.24 ms
2.69 6.19
0 377.14724
1.5e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
243.08944
100000

50000
198.06889
399.12968
431.13792
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4893 +/- 0.0285
Component name: 8-Epi-loganic acid minutes : Drift Times: 5.42 +/- 0.24 ms

377.14616
4e5

Intensity [Counts]
2e5

243.08801 399.12732
443.13896 723.17042
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 5.4893 +/- 0.0285
Component name: 8-Epi-loganic acid minutes : Drift Times: 5.27 +/- 0.24 ms

377.14724
1.5e5

Intensity [Counts]
243.08944
100000

50000
198.06889
399.12968
431.13792
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sweroside [+H] : (39.7 PPM) 359.1345 : DT=5.19 to 5.67 ms

750 Sweroside
5.49
Intensity [Counts]

500

5.42

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4893 +/- 0.0285 minutes :
Channel name: Sweroside [+H] : (39.7 PPM) 359.1345 Component name: Sweroside Drift Times: 5.43 +/- 0.24 ms
1.73
377.14616
4e5
4000

Intensity [Counts]
3000
Intensity [Counts]

2e5

2000
243.08801 399.12732
2.35 3.39 6.47 443.13896 723.17042
5.49 7.36 8.94 0
1000 200 400 600 800 1000
0.92
10.31 11.59 Item name: MENGKUDU 2 Channel name: High energy : Time 5.4893 +/- 0.0285 minutes :
14.12
16.52 Component name: Sweroside Drift Times: 5.28 +/- 0.24 ms
18.50
0 377.14724
1.5e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
243.08944
100000

50000
198.06889
399.12968
431.13792
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lamiophlomiol B [+H] : (39.7 PPM) 243.0880 : DT=5.24 to 5.72 ms

Lamiophlomiol B
5.49
3000
Intensity [Counts]

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.4899 +/- 0.0285
Channel name: Lamiophlomiol B [+H] : (39.7 PPM) 243.0880 Component name: Lamiophlomiol B minutes : Drift Times: 5.48 +/- 0.24 ms
5.50
377.14616
4e5

4000

Intensity [Counts]
Intensity [Counts]

3000 2e5

2.45

2000 399.12732
243.08801
443.13896 723.17042
0
7.51 200 400 600 800 1000
1000 2.84
1.95 9.20 Item name: MENGKUDU 2 Channel name: High energy : Time 5.4899 +/- 0.0285
3.40 6.54 9.83 14.83 16.57 Component name: Lamiophlomiol B minutes : Drift Times: 5.32 +/- 0.24 ms
13.50
1.24 9.57 13.95
0 377.14724
1.5e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
243.08944
100000

50000
198.06889
163.03942 399.12968
431.13792
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2128 : DT=5.56 to 6.04 ms

1000

750
Intensity [Counts]

500

250 Cichorioside C
5.50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.5201 +/- 0.0285
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2128 Component name: Cichorioside C minutes : Drift Times: 5.80 +/- 0.24 ms
8.24
13.51 418.16167
1250 13.64
8.95

9.02
40000

Intensity [Counts]
1000 9.06
7.14
9.15 13.01
5.80
Intensity [Counts]

13.69
16.53
750 405.17243 424.15299
5.25 20000
5.09 16.60
9.60 11.63 400.13411 461.19851
4.81 262.10879 663.14781 825.25234
500 384.14087 551.23366
14.51 16.63
3.99 0
3.17 16.69 200 400 600 800 1000
250 2.51 17.08
0.96 Item name: MENGKUDU 2 Channel name: High energy : Time 5.5201 +/- 0.0285
Component name: Cichorioside C minutes : Drift Times: 5.64 +/- 0.24 ms

0 418.16225

0 5 10 15 20 20000
Retention time [min]

Intensity [Counts]
401.13193
10000
317.11432 447.18094

176.07197 489.18971

501.19135
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Benzoylpaeoniflorin [+H] : (39.7 PPM) 585.1966 : DT=6.46 to 6.94
ms
6.88

4.53 5.18
500

3.85 7.14
7.26
400
5.59 9.11
Intensity [Counts]

300 2.92 10.67

0.93 2.39 12.89


12.98
200
13.19
13.51
16.52
100
18.34

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.5547 +/- 0.0285
Channel name: Benzoylpaeoniflorin [+H] : (39.7 PPM) 585.1966 Component name: Benzoylpaeoniflorin minutes : Drift Times: 6.70 +/- 0.24 ms
4.52
11.88 513.03483
8.55 15000
1000 6.87
1.43
1.67 8.92

Intensity [Counts]
3.85 5.18 539.21381
10.12
10000
750 5.21 595.16851
11.99
Intensity [Counts]

3.82
12.88 299.10467
3.71 289.17466 473.23416
13.34 5000 611.16251
500 14.98 313.13240 627.13326
16.49 840.66812
223.05990
0
250 200 400 600 800 1000
18.53
Item name: MENGKUDU 2 Channel name: High energy : Time 5.5547 +/- 0.0285
18.34
Component name: Benzoylpaeoniflorin minutes : Drift Times: 6.54 +/- 0.24 ms

0 299.10553

0 5 10 15 20 10000
Retention time [min]

Intensity [Counts]
297.08737
301.11189 635.16765
5000
263.07149 567.20301
501.19114
210.07890
701.24275

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Brucealin A [+H] : (39.7 PPM) 683.2566 : DT=6.81 to 7.30 ms
9.80
500

400
10.12
Intensity [Counts]

13.54
300
7.15
5.11
6.94 7.76 8.40 14.02
200 2.72
4.34 6.77 11.32
5.98 11.78
4.26 14.50
100
1.89 15.26
15.35

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.5551 +/- 0.0285 minutes :
Channel name: Brucealin A [+H] : (39.7 PPM) 683.2566 Component name: Brucealin A Drift Times: 7.06 +/- 0.24 ms
9.81
2000
15000 635.17344

667.15802

Intensity [Counts]
1500 10000 595.16851
11.03
583.18520
Intensity [Counts]

11.32 299.10467
372.11685 670.15915
5000
1000
9.45 13.14 289.17365 683.25655
6.76 12.34 16.53
14.02 223.05990 971.29310
5.11
6.00
2.89 0
500 4.63 200 400 600 800 1000
2.72
Item name: MENGKUDU 2 Channel name: High energy : Time 5.5551 +/- 0.0285 minutes :
2.28
18.53 Component name: Brucealin A Drift Times: 6.90 +/- 0.24 ms

0 299.10553

0 5 10 15 20 10000 269.14581
Retention time [min] 372.11552

Intensity [Counts]
652.18603

5000 639.18213

239.05831 602.26785 675.17490


701.24275
743.17887
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅰ [+H] : (39.7 PPM) 493.1720 : DT=5.91 to 6.39 ms
5.43

600
Intensity [Counts]

400

5.53

Picroside Ⅰ
200 5.59

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.5870 +/- 0.0285 minutes :
Channel name: Picroside Ⅰ [+H] : (39.7 PPM) 493.1720 Component name: Picroside Ⅰ Drift Times: 6.15 +/- 0.24 ms
5.43
2500 469.13210
40000

2000

Intensity [Counts]
499.10659
Intensity [Counts]

20000
1500 371.11330
10.47 503.20875
3.85 5.60 6.83
2.29 4.52 524.13399
7.91 327.08902
1000
8.68 223.05562 543.23496 863.22660
3.64 11.80 0
12.84 200 400 600 800 1000
500 1.88 13.90 16.47
13.02 16.56 Item name: MENGKUDU 2 Channel name: High energy : Time 5.5870 +/- 0.0285 minutes :
Component name: Picroside Ⅰ Drift Times: 6.00 +/- 0.24 ms
18.54
0 469.13208

0 5 10 15 20 371.11294
20000
Retention time [min]

Intensity [Counts]
10000
165.05413 503.21035
287.05601 529.22106 683.12953

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1085 : DT=7.94 to 8.42 ms

25000

20000
Intensity [Counts]

15000

10000

Cimicifugic acid B
5000
5.60

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.6000 +/- 0.0285
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1085 Component name: Cimicifugic acid B minutes : Drift Times: 8.19 +/- 0.24 ms
7.49
80000 20000 757.21991
8.18 449.10853

15000

Intensity [Counts]
60000 611.16216
819.21986
10000
Intensity [Counts]

837.22611
595.16216
40000 289.17478
5000 887.24607
287.05755 461.14297
7.19
0
20000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 5.6000 +/- 0.0285
Component name: Cimicifugic acid B minutes : Drift Times: 8.03 +/- 0.24 ms
2.22 5.60
0 287.05597

0 5 10 15 20 30000
Retention time [min]

Intensity [Counts]
20000

10000 269.14556 449.10818 657.16647


257.06538 495.11606
288.05717 675.17849 843.25387
175.04000
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Deacetylmatricarin-8-O-β-D-glucopyranoside [+H] : (39.7 PPM)
425.1774 : DT=5.43 to 5.91 ms

5.04
5.01

2000

4.92
Intensity [Counts]

1500
5.25
Deacetylmatricarin-8-O-β-D-glucopyranoside
5.59
1000
5.68

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.6037 +/-
Channel name: Deacetylmatricarin-8-O-β-D-glucopyranoside [+H] : (39.7 PPM) Component name: Deacetylmatricarin-8-O-β- 0.0285 minutes : Drift Times: 5.66 +/- 0.24 ms
425.1774 D-glucopyranoside
5.04
439.11789
4000
20000 425.17743
207.13943

Intensity [Counts]
4.97
364.22202 495.11495
3000 4.93
Intensity [Counts]

675.17789
5.75 10000

2000 683.12583
4.86 506.22480
5.94 857.20011
4.54 10.97
6.138.46 9.20 0
4.37 11.17 200 400 600 800 1000
1000 9.84
3.53
11.22 16.32 Item name: MENGKUDU 2 Channel name: High energy : Time 5.6037 +/-
2.88 13.54 16.56 Component name: Deacetylmatricarin-8-O-β- 0.0285 minutes : Drift Times: 5.51 +/- 0.24 ms
D-glucopyranoside
0
317.11462 425.18012
0 5 10 15 20
Retention time [min] 10000

Intensity [Counts]
299.10519

5000 145.02915 439.11753


456.18653

467.19255

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2018 : DT=6.96 to 7.44 ms
ApocynosideⅠ
5.61

600

5.68
5.72
Intensity [Counts]

400

200

5.55

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.6139 +/- 0.0285
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2018 Component name: ApocynosideⅠ minutes : Drift Times: 7.20 +/- 0.24 ms
8.63
10000 675.17769

651.18843
40000

Intensity [Counts]
7500
Intensity [Counts]

20000 371.11333
5000 5.70 387.20185
495.11521
757.21967 937.32963
5.62 279.17196
0
2500 5.42 200 400 600 800 1000
8.41 16.58
5.15 Item name: MENGKUDU 2 Channel name: High energy : Time 5.6139 +/- 0.0285
7.65 10.04
16.95 Component name: ApocynosideⅠ minutes : Drift Times: 7.05 +/- 0.24 ms
2.47 4.69 10.12 14.92
0 371.11301
30000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

257.06632 495.11686 657.16613


10000
239.05588 675.17906
133.03004 891.15542
719.28990
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1394 : DT=5.35 to 5.83 ms
5.70
ArteamisinineⅠ
5.63
500

6.07
400
Intensity [Counts]

300

200 5.53

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.6319 +/- 0.0285
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1394 Component name: ArteamisinineⅠ minutes : Drift Times: 5.59 +/- 0.24 ms
5.70
407.05964
10000
439.11789

Intensity [Counts]
20000 207.13943 405.17255
7500
Intensity [Counts]

459.11396
6.08 377.10842
10000
5000
657.16842
845.19791
5.42 0
2500 200 400 600 800 1000

5.27 Item name: MENGKUDU 2 Channel name: High energy : Time 5.6319 +/- 0.0285
7.81 15.71 16.53 Component name: ArteamisinineⅠ minutes : Drift Times: 5.44 +/- 0.24 ms
5.13 9.03 10.67 13.44
0 317.11462 425.18012
0 5 10 15 20 10000
Retention time [min]

Intensity [Counts]
5000
216.97924 438.99761

467.19255

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Aduncin [+H] : (39.7 PPM) 295.1158 : DT=4.39 to 4.87 ms

500

Aduncin
400 5.65
4.86
Intensity [Counts]

300

4.73
200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.6419 +/- 0.0285 minutes :
Channel name: Aduncin [+H] : (39.7 PPM) 295.1158 Component name: Aduncin Drift Times: 4.63 +/- 0.24 ms
2.89 8.90 10000
4.97 246.24484
1500

5.13 7500 308.11328

Intensity [Counts]
320.08749
6.46
5000
Intensity [Counts]

1000
7.07
495.11534
3.70
10.60 2500 499.18336
8.82 228.23229
1.80 8.07 11.09
500 11.14 14.01 0
1.48 12.38 16.65 200 400 600 800 1000
13.19
0.61 14.82 16.97 Item name: MENGKUDU 2 Channel name: High energy : Time 5.6419 +/- 0.0285 minutes :
Component name: Aduncin Drift Times: 4.48 +/- 0.24 ms
17.85
0 275.10469
15000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000

5000 228.23382 327.17351


178.07920 328.09749
561.12651
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.1997 : DT=5.15 to 5.64 ms
8.64
5000

4000
Intensity [Counts]

3000

2000

1000
7.69
4.68
2.21 3.35 7.64 7.10 10.57 11.86 15.05 16.67

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.6471 +/- 0.0285
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.1997 Component name: ApocynosideⅠ minutes : Drift Times: 5.46 +/- 0.24 ms
10000 8.63
207.13943

15000

Intensity [Counts]
7500 425.17437
383.14533
10000
Intensity [Counts]

377.10842
5000 5.70 367.08047 433.14734
5000
657.16842 757.16224
193.05167 506.22480
5.62 845.19791
0
2500 5.42 200 400 600 800 1000
7.69 16.58 Item name: MENGKUDU 2 Channel name: High energy : Time 5.6471 +/- 0.0285
10.04
4.69 6.44 Component name: ApocynosideⅠ minutes : Drift Times: 5.30 +/- 0.24 ms
10.12 14.92 16.95
3.35
0 425.18012

0 5 10 15 20 10000
Retention time [min]

Intensity [Counts]
5000 163.03904
331.12782

558.20190

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1775 : DT=5.80 to 6.28 ms

Cichorioside B
5.67
3000
Intensity [Counts]

2000

5.62

1000 5.46

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.6688 +/- 0.0285
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1775 Component name: Cichorioside B minutes : Drift Times: 6.03 +/- 0.24 ms
7.91
6000 441.17752

40000
5.66

Intensity [Counts]
459.18504

4000
Intensity [Counts]

20000

397.18986 483.11881
539.21669
5.46 280.10990 757.16269
8.35 913.23267
2000
0
4.90 7.57 8.66 200 400 600 800 1000
4.80 6.35 9.66 Item name: MENGKUDU 2 Channel name: High energy : Time 5.6688 +/- 0.0285
4.19 9.71 13.94 Component name: Cichorioside B minutes : Drift Times: 5.88 +/- 0.24 ms
3.14 16.53
18.34
0 441.17804

0 5 10 15 20 280.10950
Retention time [min] 463.18028

Intensity [Counts]
10000
505.22854
577.10270
179.03501
5000
578.10535
585.22314
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1399 : DT=3.64 to 4.12 ms

2500

2000
Intensity [Counts]

1500 ArteamisinineⅠ
5.71

1000

5.64

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.7015 +/- 0.0285
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1399 Component name: ArteamisinineⅠ minutes : Drift Times: 3.87 +/- 0.24 ms
5.70
207.13989
10000

10000

Intensity [Counts]
7500
Intensity [Counts]

223.08028
6.08 5000

5000 231.02118 573.16324


279.60159

5.42 0
2500 200 400 600 800 1000

5.27 Item name: MENGKUDU 2 Channel name: High energy : Time 5.7015 +/- 0.0285
7.81 15.71 16.53 Component name: ArteamisinineⅠ minutes : Drift Times: 3.72 +/- 0.24 ms
5.13 9.64
10.66 13.44
0 149.09716

0 5 10 15 20 4000
189.12788
Retention time [min]

Intensity [Counts]
207.13928
2000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1395 : DT=8.12 to 8.60 ms
ArteamisinineⅠ
5.71
500

400 5.68
Intensity [Counts]

300

200

5.59

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.7017 +/- 0.0285
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1395 Component name: ArteamisinineⅠ minutes : Drift Times: 8.36 +/- 0.24 ms
5.70
40000 809.21516
10000 541.22639

Intensity [Counts]
7500 572.15247
Intensity [Counts]

20000 830.20030
6.08 573.16325
207.13947
5000 804.25464 884.11632
422.15686
319.08938 891.32519
5.42 0
2500 200 400 600 800 1000

5.27 Item name: MENGKUDU 2 Channel name: High energy : Time 5.7017 +/- 0.0285
7.81 15.71 16.53 Component name: ArteamisinineⅠ minutes : Drift Times: 8.20 +/- 0.24 ms
5.13 9.03 10.67 13.44
0 571.14822

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
809.21453
175.04043
10000 189.12860 519.24567
668.14814
319.08428 825.18002
793.21752
937.26367
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1394 : DT=6.29 to 6.78 ms
ArteamisinineⅠ
5.70

3000
Intensity [Counts]

2000

5.65

1000
6.06

5.42
5.39

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.7029 +/- 0.0285
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1394 Component name: ArteamisinineⅠ minutes : Drift Times: 6.54 +/- 0.24 ms
5.70
541.22643
4e5
10000

Intensity [Counts]
7500
Intensity [Counts]

2e5
571.14734
6.08
573.16329
5000 519.24390
207.13943
440.11521 575.16687
149.09641 337.09848 805.31997 939.81924
5.42 0
2500 200 400 600 800 1000

5.27 Item name: MENGKUDU 2 Channel name: High energy : Time 5.7029 +/- 0.0285
7.81 15.71 16.53 Component name: ArteamisinineⅠ minutes : Drift Times: 6.39 +/- 0.24 ms
5.13 9.03 10.67 13.44
0 541.22777

0 5 10 15 20 3e5
Retention time [min]

Intensity [Counts]
2e5

100000 542.23135
525.25379
207.13921
441.12200 571.14835
841.14729
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2006 : DT=7.54 to 8.02 ms

ApocynosideⅠ
5.71
600
Intensity [Counts]

5.65
400
5.62
5.37

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.7058 +/- 0.0285
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2006 Component name: ApocynosideⅠ minutes : Drift Times: 7.78 +/- 0.24 ms
8.63
10000 573.16329 783.17531

40000

Intensity [Counts]
7500

520.24825
Intensity [Counts]

784.17675
20000
5000 5.70 738.22281
440.11500
208.14196 705.27403 939.31646
387.20057
5.62
0
2500 5.42 200 400 600 800 1000
7.65 16.58 Item name: MENGKUDU 2 Channel name: High energy : Time 5.7058 +/- 0.0285
5.15 10.04
6.44 Component name: ApocynosideⅠ minutes : Drift Times: 7.63 +/- 0.24 ms
4.69 10.12 14.92 16.95

0 149.09717 441.12244 783.17472


0 5 10 15 20
15000 574.16816
Retention time [min]

Intensity [Counts]
189.12857
10000
784.18086
198.97003 739.19587
5000
320.07032 825.18152
931.32834
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: cis-Anethole [+H] : (39.7 PPM) 149.0959 : DT=3.71 to 4.19 ms

800 cis-Anethole
5.70

6.08
600
Intensity [Counts]

400

5.54

200 5.44

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.7059 +/- 0.0285 minutes :
Channel name: cis-Anethole [+H] : (39.7 PPM) 149.0959 Component name: cis-Anethole Drift Times: 3.95 +/- 0.24 ms
6.08
207.13989
2500

10000

Intensity [Counts]
2000
279.09948
Intensity [Counts]

1500 5.70 5000

573.16324
13.67
1000
0
5.40 7.81 16.56 200 400 600 800 1000
500 4.69 7.89 10.43 16.63 Item name: MENGKUDU 2 Channel name: High energy : Time 5.7059 +/- 0.0285
10.55 13.87 Component name: cis-Anethole minutes : Drift Times: 3.79 +/- 0.24 ms
2.49 4.26 14.80 16.88
2.09
0 149.09716

0 5 10 15 20 4000
Retention time [min]

Intensity [Counts]
207.13928
2000

573.16644

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Vomifoliol [+H] : (39.7 PPM) 225.1501 : DT=6.33 to 6.81 ms

Vomifoliol
400 5.69

300
Intensity [Counts]

5.65

200

5.78
5.58
100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.7104 +/- 0.0285 minutes :
Channel name: Vomifoliol [+H] : (39.7 PPM) 225.1501 Component name: Vomifoliol Drift Times: 6.57 +/- 0.24 ms
5.70
541.22643
4e5
1000

Intensity [Counts]
5.42

750
Intensity [Counts]

2e5
571.14734

573.16329
500 5.12 7.78 519.24390
207.13943
440.11521 575.16687
7.15 805.31997 939.81924
149.09641 337.09848
4.80 0
9.38 10.36 16.65 200 400 600 800 1000
250 3.53
8.71 11.80 16.55
2.66 Item name: MENGKUDU 2 Channel name: High energy : Time 5.7104 +/- 0.0285 minutes :
15.38 Component name: Vomifoliol Drift Times: 6.41 +/- 0.24 ms
1.13 18.01

0 541.22777

0 5 10 15 20 3e5
Retention time [min]

Intensity [Counts]
O O

2e5
O

100000 542.23135
207.13921
525.25379
Mass error: 1.3 mDa
571.14835
841.14729
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Deacetylmatricarin-8-O-β-D-glucopyranoside [+H] : (39.7 PPM)
425.1803 : DT=5.38 to 5.86 ms
5.04
2000 5.01

4.92
Deacetylmatricarin-8-O-β-D-glucopyranoside
1500
5.76
Intensity [Counts]

1000 5.85

6.13
6.17
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.7525 +/-
Channel name: Deacetylmatricarin-8-O-β-D-glucopyranoside [+H] : (39.7 PPM) Component name: Deacetylmatricarin-8-O-β- 0.0285 minutes : Drift Times: 5.62 +/- 0.24 ms
425.1803 D-glucopyranoside
5.04
409.18389
4000

40000

Intensity [Counts]
404.14497
3000
4.93
Intensity [Counts]

360.15605
5.75 425.18258
20000
222.07822 441.12069
2000 4.37
5.94 220.05960 572.15239
701.07960 852.25403
6.13 7.07 10.97 0
3.53 200 400 600 800 1000
1000 11.16
3.03 11.22 Item name: MENGKUDU 2 Channel name: High energy : Time 5.7525 +/-
16.32
2.88 12.23 16.62 Component name: Deacetylmatricarin-8-O-β- 0.0285 minutes : Drift Times: 5.46 +/- 0.24 ms
D-glucopyranoside
0
409.18413
0 5 10 15 20
30000
Retention time [min]

Intensity [Counts]
20000

222.07723
10000
423.16079

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1619 : DT=5.73 to 6.21 ms

600

Lactiflorin
5.79
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.7989 +/- 0.0285 minutes :
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1619 Component name: Lactiflorin Drift Times: 5.97 +/- 0.24 ms
4.35
222.07822
6000
10000

Intensity [Counts]
447.18429
500.11057
443.13996
Intensity [Counts]

4000 517.23230
5000 423.16238
210.07705 387.16069 669.13226
225.05779 734.09577
799.18956 873.16304

2000 4.17 0
7.62 8.60 200 400 600 800 1000
5.62 10.85
2.29 8.86 Item name: MENGKUDU 2 Channel name: High energy : Time 5.7989 +/- 0.0285 minutes :
11.10 13.46
16.96 Component name: Lactiflorin Drift Times: 5.82 +/- 0.24 ms
2.04 11.99
18.53
0 425.18040

0 5 10 15 20
Retention time [min] 10000 403.10302 447.18475

Intensity [Counts]
204.06654

164.07151 307.06113 499.10806


5000 523.24238

701.07643
529.18361
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6-Feruloyl catalpol [+H] : (39.7 PPM) 523.1816 : DT=6.22 to 6.70 ms

7500
Intensity [Counts]

5000

2500
6-Feruloyl catalpol
5.89
5.78
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.8840 +/- 0.0285
Channel name: 6-Feruloyl catalpol [+H] : (39.7 PPM) 523.1816 Component name: 6-Feruloyl catalpol minutes : Drift Times: 6.43 +/- 0.24 ms
6.39
324.10865

15000 515.16870

15000 523.18156

Intensity [Counts]
491.21480 822.23895
10000
780.14362
Intensity [Counts]

223.06133 471.18394 589.14690


10000 823.23970
5000 205.05237
713.10029
876.15945
193.05058
8.58

8.92 0
5000
200 400 600 800 1000
6.91 10.41 Item name: MENGKUDU 2 Channel name: High energy : Time 5.8840 +/- 0.0285
5.89
11.43 12.32 14.47 Component name: 6-Feruloyl catalpol minutes : Drift Times: 6.28 +/- 0.24 ms
3.21 4.63
175.04070 641.17419
0
0 5 10 15 20 10000
Retention time [min] 223.06108

Intensity [Counts]
327.99149 515.17278
659.18463
501.19200
5000

764.17463 875.15673

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Onitin-2′-O-β-D-glucopyranoside [+H] : (39.7 PPM) 411.1996 :
DT=5.51 to 6.00 ms

2000

1500
Intensity [Counts]

1000

5.79

500
Onitin-2′-O-β-D-glucopyranoside
5.91

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.9195 +/-
Channel name: Onitin-2′-O-β-D-glucopyranoside [+H] : (39.7 PPM) 411.1996 Component name: Onitin-2′-O-β-D- 0.0285 minutes : Drift Times: 5.76 +/- 0.24 ms
3000 7.41 glucopyranoside

469.13329
2500 7.37
407.16850
40000

Intensity [Counts]
2000 8.97
Intensity [Counts]

6.65
473.19700
20000
1500
7.76 391.14788 497.13098 840.20601
2.74 205.05234
9.85 501.07857
4.11 5.33 381.14582 759.17547 844.21967
1000
0
11.06 16.62
2.60 11.78 200 400 600 800 1000
13.48
500 16.98 Item name: MENGKUDU 2 Channel name: High energy : Time 5.9195 +/-
2.47 14.06
18.30 Component name: Onitin-2′-O-β-D- 0.0285 minutes : Drift Times: 5.60 +/- 0.24 ms
1.43 glucopyranoside
0
469.13453
0 5 10 15 20
Retention time [min]
20000

Intensity [Counts]
407.16878

391.15388
485.16145
10000
151.03956
317.07330
571.14706 679.11535

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: GrayanotoxinⅠ [+H] : (39.7 PPM) 415.2330 : DT=5.68 to 6.16 ms

600

500

GrayanotoxinⅠ
400 5.94
Intensity [Counts]

300

5.87
200
5.84

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 5.9352 +/- 0.0285
Channel name: GrayanotoxinⅠ [+H] : (39.7 PPM) 415.2330 Component name: GrayanotoxinⅠ minutes : Drift Times: 5.96 +/- 0.24 ms
16.59
16.56 416.14642
1250
4e5

Intensity [Counts]
1000 16.50 16.85
12.39
Intensity [Counts]

9.05
2e5
750 9.12
8.77
11.96
5.94 469.13329
11.53 17.01
500 205.05234 391.14788 485.11161 633.07512
5.59
6.40 9.22 12.52 15.80 841.14989
13.59 17.21 0
200 400 600 800 1000
4.02 5.22 17.56
250
4.34 Item name: MENGKUDU 2 Channel name: High energy : Time 5.9352 +/- 0.0285
1.88 Component name: GrayanotoxinⅠ minutes : Drift Times: 5.80 +/- 0.24 ms

0 469.13453

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
398.13753
485.16145
10000 372.15214
145.02919
571.14706 679.11535

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Inuchinenolide C [+H] : (39.7 PPM) 367.1737 : DT=5.03 to 5.51 ms
13.54
13.69

3000

13.95
Intensity [Counts]

2000

14.91
1000
13.41 14.96
6.44 8.28 10.49
2.81 5.43 10.43 10.98 15.23
4.17
15.63
2.45 16.66
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.0038 +/- 0.0285
Channel name: Inuchinenolide C [+H] : (39.7 PPM) 367.1737 Component name: Inuchinenolide C minutes : Drift Times: 5.27 +/- 0.24 ms
13.69
13.64 360.10712
13.54
10000 75000

Intensity [Counts]
13.94
7500 50000
Intensity [Counts]

25000 344.13323
5000 364.04818
274.01703 688.20635
14.91 0
15.03 200 400 600 800 1000
2500
15.15 Item name: MENGKUDU 2 Channel name: High energy : Time 6.0038 +/- 0.0285
5.42 6.44 8.26 10.49 13.04 Component name: Inuchinenolide C minutes : Drift Times: 5.11 +/- 0.24 ms
2.76
15.62
0 360.10682

0 5 10 15 20
Retention time [min] 40000

Intensity [Counts] 20000


344.13434
204.10529 479.12071
274.01838
133.02862
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: cis-Anethole [+H] : (39.7 PPM) 149.0975 : DT=2.76 to 3.24 ms
cis-Anethole
300 6.05

200
Intensity [Counts]

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.0460 +/- 0.0285 minutes :
Channel name: cis-Anethole [+H] : (39.7 PPM) 149.0975 Component name: cis-Anethole Drift Times: 3.00 +/- 0.24 ms
6.08
2500 170.06118

10000

Intensity [Counts]
2000
Intensity [Counts]

1500 5.70 5000

1000 13.67

0
5.40 7.71 16.56 200 400 600 800 1000
500 4.69 7.81 10.00
16.53 16.63 Item name: MENGKUDU 2 Channel name: High energy : Time 6.0460 +/- 0.0285
7.89 10.55
2.49 4.44 13.87 16.88 Component name: cis-Anethole minutes : Drift Times: 2.85 +/- 0.24 ms
2.09
0 142.06385

0 5 10 15 20
Retention time [min] 2000

Intensity [Counts]
149.09665

316.11856
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1394 : DT=6.25 to 6.74 ms

5.70

3000
Intensity [Counts]

2000

5.65

ArteamisinineⅠ
1000
6.06

5.42
5.39

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.0568 +/- 0.0285
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1394 Component name: ArteamisinineⅠ minutes : Drift Times: 6.50 +/- 0.24 ms
5.70
539.20842
10000
40000

Intensity [Counts]
7500 876.15925
Intensity [Counts]

20000 480.12081
6.08

5000 207.13935 574.17521


465.19147 803.22507 879.15771
579.18374
5.42 0
2500 200 400 600 800 1000

5.27 Item name: MENGKUDU 2 Channel name: High energy : Time 6.0568 +/- 0.0285
7.81 15.71 16.53 Component name: ArteamisinineⅠ minutes : Drift Times: 6.34 +/- 0.24 ms
5.13 9.03 10.67 13.44
0 479.12126

0 5 10 15 20 30000 539.21156
Retention time [min]

Intensity [Counts]
239.05678
20000
179.03478
457.04425
713.10473
245.02716
10000
258.07108 695.09373 876.16446

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1395 : DT=5.03 to 5.51 ms

600
ArteamisinineⅠ
6.08
500

400
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.0797 +/- 0.0285
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1395 Component name: ArteamisinineⅠ minutes : Drift Times: 5.27 +/- 0.24 ms
5.70
395.12502
10000 1.5e5

Intensity [Counts]
100000
7500
Intensity [Counts]

6.08
50000 383.15992
5000 356.19113 396.12728

207.13949 485.15839 642.17697


5.42 0
2500 200 400 600 800 1000

5.27 Item name: MENGKUDU 2 Channel name: High energy : Time 6.0797 +/- 0.0285
7.81 15.71 16.53 Component name: ArteamisinineⅠ minutes : Drift Times: 5.11 +/- 0.24 ms
5.13 9.03 10.67 13.44
0 395.12607
75000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

25000
91.05563 363.09730 396.12600
261.05819
485.16017 553.19214
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1333 : DT=5.95 to 6.43 ms

1250

1000
Intensity [Counts]

750

Sesamoside
500 6.13

6.05

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.1232 +/- 0.0285 minutes :
Channel name: Sesamoside [+H] : (39.7 PPM) 421.1333 Component name: Sesamoside Drift Times: 6.19 +/- 0.24 ms
8.06
529.13510
4000

Intensity [Counts]
40000
3000
Intensity [Counts]

9.15
20000 499.10550
0.96
2000 431.16466
6.81 531.13910
319.08393 841.15056
2.09 4.54
6.55 227.16369 577.19184 978.27308
6.04 0
3.18 9.23 200 400 600 800 1000
1000
11.83 Item name: MENGKUDU 2 Channel name: High energy : Time 6.1232 +/- 0.0285 minutes :
10.65
12.36 18.50 Component name: Sesamoside Drift Times: 6.04 +/- 0.24 ms
15.07
0 529.13605

0 5 10 15 20 319.08273
15000
Retention time [min] 188.07162

Intensity [Counts]
431.16491
10000 193.05039
91.05563

5000 575.18387
843.20629
730.12640
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Mudanpioside D [+H] : (39.7 PPM) 511.1790 : DT=6.20 to 6.68 ms

5000

4000
Intensity [Counts]

3000

2000

1000 Mudanpioside D
6.13

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.1244 +/- 0.0285
Channel name: Mudanpioside D [+H] : (39.7 PPM) 511.1790 Component name: Mudanpioside D minutes : Drift Times: 6.44 +/- 0.24 ms
12.79
8000 529.13510
11.84

Intensity [Counts]
40000
6000 543.24087
Intensity [Counts]

11.71 575.17974
20000
4000 501.19163
9.95
397.11294 841.15056
343.12002 591.13131
9.84 209.15254
0
9.62
2000 200 400 600 800 1000
4.35 5.43 9.55
3.38 9.17 13.45 15.89 Item name: MENGKUDU 2 Channel name: High energy : Time 6.1244 +/- 0.0285
3.32 16.04 Component name: Mudanpioside D minutes : Drift Times: 6.29 +/- 0.24 ms
0.61
16.71
0 175.03995

0 5 10 15 20 30000

Retention time [min]

Intensity [Counts]
543.24102
20000 319.08273 529.13605

193.05039
10000 339.05174
575.18139
842.14929
633.07379
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Deacetylmatricarin-8-O-β-D-glucopyranoside [+H] : (39.7 PPM)
425.1812 : DT=5.51 to 5.99 ms

2500

2000
Intensity [Counts]

1500

Deacetylmatricarin-8-O-β-D-glucopyranoside
1000 6.13

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.1290 +/-
Channel name: Deacetylmatricarin-8-O-β-D-glucopyranoside [+H] : (39.7 PPM) Component name: Deacetylmatricarin-8-O-β- 0.0285 minutes : Drift Times: 5.75 +/- 0.24 ms
425.1812 D-glucopyranoside
5.04
427.15089
4000
75000

Intensity [Counts]
439.15872
3000 50000
4.93
Intensity [Counts]

5.75 359.16144
4.37 25000
2000 443.14542
5.94 314.13977
841.14934
193.05151 575.17984
6.13 8.46 10.97 0
3.53 200 400 600 800 1000
1000 9.20 11.22
Item name: MENGKUDU 2 Channel name: High energy : Time 6.1290 +/-
3.03 11.92 16.32
16.62 Component name: Deacetylmatricarin-8-O-β- 0.0285 minutes : Drift Times: 5.59 +/- 0.24 ms
0.61 D-glucopyranoside
0
30000 439.15859
0 5 10 15 20
365.15037
Retention time [min]

Intensity [Counts]
20000

188.07162
359.16147
10000 91.05563
343.12433 471.09472
531.14400

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Brazilide A [+H] : (39.7 PPM) 319.0840 : DT=4.47 to 4.95 ms

60000
Intensity [Counts]

40000

20000

Brazilide A
6.14
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.1361 +/- 0.0285 minutes :
Channel name: Brazilide A [+H] : (39.7 PPM) 319.0840 Component name: Brazilide A Drift Times: 4.74 +/- 0.24 ms
1.5e5 6.52
337.12697

1.25e5 20000

Intensity [Counts]
319.08401
100000
307.13077
Intensity [Counts]

343.11965
10000
75000
293.11396 351.08430
575.17939
266.10294 369.09620
841.14763
50000
0
200 400 600 800 1000
25000 Item name: MENGKUDU 2 Channel name: High energy : Time 6.1361 +/- 0.0285 minutes :
4.71 Component name: Brazilide A Drift Times: 4.59 +/- 0.24 ms
2.53 3.94 8.39
0 175.03996

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
337.12593

319.08308
5000
351.08661

371.16760
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Brazilide A [+H] : (39.7 PPM) 319.0835 : DT=5.08 to 5.56 ms

20000

15000
Intensity [Counts]

10000

5000

Brazilide A
6.14

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.1367 +/- 0.0285 minutes :
Channel name: Brazilide A [+H] : (39.7 PPM) 319.0835 Component name: Brazilide A Drift Times: 5.30 +/- 0.24 ms
6.52
359.16144
30000
1.25e5
342.13440

Intensity [Counts]
100000 20000 471.09542
338.08641
Intensity [Counts]

319.08350
75000
10000
256.09010 575.17984
175.04087 657.17009 825.21284
50000
0
200 400 600 800 1000
25000 Item name: MENGKUDU 2 Channel name: High energy : Time 6.1367 +/- 0.0285 minutes :
4.71 Component name: Brazilide A Drift Times: 5.14 +/- 0.24 ms
2.53 3.94 8.39
0 342.13527

0 5 10 15 20
15000
Retention time [min]

Intensity [Counts]
314.14381
10000 359.16147

228.10212
5000 366.12078
471.09377

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bruceaketolic acid [+H] : (39.7 PPM) 485.1632 : DT=5.65 to 6.13 ms

Bruceaketolic acid
6.25
4000

3000
Intensity [Counts]

6.03

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.2441 +/- 0.0285
Channel name: Bruceaketolic acid [+H] : (39.7 PPM) 485.1632 Component name: Bruceaketolic acid minutes : Drift Times: 5.88 +/- 0.24 ms
6.25
60000 485.16322

8.95
5000 394.12861

Intensity [Counts]
6.04 40000
4000
Intensity [Counts]

9.69
3000 6.88 20000
390.13730
7.01 824.21262
491.21889
319.01054 697.10381
2000 826.21048
0
3.99 8.83 200 400 600 800 1000
1000 10.00 11.83
1.41 Item name: MENGKUDU 2 Channel name: High energy : Time 6.2441 +/- 0.0285
3.52 10.45
14.84 15.87 18.54
Component name: Bruceaketolic acid minutes : Drift Times: 5.73 +/- 0.24 ms
14.91
0 485.16467

0 5 10 15 20 394.13056
Retention time [min] 20000

Intensity [Counts]
350.14298

824.21260

10000

117.03429 216.97691
507.24268 825.71902

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Erythrocentaurin [+H] : (39.7 PPM) 177.0555 : DT=3.04 to 3.52 ms
Erythrocentaurin
6.26
1500
Intensity [Counts]

1000

6.22

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.2547 +/- 0.0285
Channel name: Erythrocentaurin [+H] : (39.7 PPM) 177.0555 Component name: Erythrocentaurin minutes : Drift Times: 3.27 +/- 0.24 ms
6.25
3000
205.05172

2500
2e5

Intensity [Counts]
2000
Intensity [Counts]

100000
1500 7.85
206.05444
3.47
1000 3.40 5.18 9.43 10.99
3.33 12.84 0
8.00 200 400 600 800 1000
3.22 12.98
500 13.15 Item name: MENGKUDU 2 Channel name: High energy : Time 6.2547 +/- 0.0285
2.38
15.15 Component name: Erythrocentaurin minutes : Drift Times: 3.12 +/- 0.24 ms
16.45 117.03414
0
0 5 10 15 20
10000
Retention time [min]

Intensity [Counts]
146.03249
5000

163.04027

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ginkgolide M [+H] : (39.7 PPM) 425.1452 : DT=5.40 to 5.88 ms

10000

7500
Intensity [Counts]

5000

2500

Ginkgolide M
0 6.28
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.2557 +/- 0.0285
Channel name: Ginkgolide M [+H] : (39.7 PPM) 425.1452 Component name: Ginkgolide M minutes : Drift Times: 5.64 +/- 0.24 ms
4.97
20000 439.15973

40000

Intensity [Counts]
15000
3.53
Intensity [Counts]

447.16785
4.85 8.46 20000
486.16902
10000 427.09676
10.98 360.22881
163.03959 660.20892 795.21777
5.14
0
5000 3.07 200 400 600 800 1000
5.41 9.16 Item name: MENGKUDU 2 Channel name: High energy : Time 6.2557 +/- 0.0285
7.22 13.16 Component name: Ginkgolide M minutes : Drift Times: 5.48 +/- 0.24 ms
16.49
0 485.16467

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
145.02926

10000 163.04032

206.05340
623.15144
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Scropolioside A [+H] : (39.7 PPM) 753.2560 : DT=7.27 to 7.75 ms

12500

10000

Scropolioside A
Intensity [Counts]

7500 6.27

5000

2500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.2705 +/- 0.0285
Channel name: Scropolioside A [+H] : (39.7 PPM) 753.2560 Component name: Scropolioside A minutes : Drift Times: 7.52 +/- 0.24 ms
6.88
75000 753.25598

20000
445.11381
607.16728

Intensity [Counts]
50000
205.05169
15000 832.20138
Intensity [Counts]

859.16053

6.27 25000 737.28610


385.11248
10000 446.11722
349.09120
163.03949
299.12750 979.24613
0
200 400 600 800 1000
5000
7.53 Item name: MENGKUDU 2 Channel name: High energy : Time 6.2705 +/- 0.0285
4.74 8.81 11.69 Component name: Scropolioside A minutes : Drift Times: 7.36 +/- 0.24 ms
1.43 2.72 10.53 16.55
0 205.05103

0 5 10 15 20
Retention time [min]

Intensity [Counts]
2e5

100000 177.05570 457.04519


339.14187 753.25996
859.16369
577.08344
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2123 : DT=5.86 to 6.35 ms

500

400
Intensity [Counts]

300
Cichorioside C
6.28
200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.2731 +/- 0.0285
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2123 Component name: Cichorioside C minutes : Drift Times: 6.11 +/- 0.24 ms
8.24
13.64
60000 485.16322
1250 8.21 8.94 13.51
394.12861
9.02

Intensity [Counts]
631.14000
1000 9.06 40000 860.16392
7.14
9.15 13.01 13.69
5.80
Intensity [Counts]

16.53
750
5.25 20000
345.19122 501.19226 637.10488
5.09 9.60 11.63 824.21262
16.60 319.01056
4.81 177.05573
500 873.20767
3.99 14.51 16.63 0
3.17 16.69 200 400 600 800 1000
250 2.51 17.08
0.96 Item name: MENGKUDU 2 Channel name: High energy : Time 6.2731 +/- 0.0285
Component name: Cichorioside C minutes : Drift Times: 5.95 +/- 0.24 ms

0 499.21752
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
394.13056
20000 350.14298
223.06121 824.21260

697.10714
501.09255
825.21816
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Gedunin [+H] : (39.7 PPM) 483.2393 : DT=6.05 to 6.53 ms

750

Gedunin
6.29
Intensity [Counts]

500

6.22
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.2919 +/- 0.0285 minutes :
Channel name: Gedunin [+H] : (39.7 PPM) 483.2393 Component name: Gedunin Drift Times: 6.26 +/- 0.24 ms
10.72
499.21530

50000
10.57 445.11383

Intensity [Counts]
1500
Intensity [Counts]

25000
1000 11.88
10.05 637.10488
6.30 345.19122
16.54
9.49 13.04 824.21262
6.75 16.61 241.07040
5.01 915.14908
8.60 13.14
0
500 16.75 200 400 600 800 1000
3.44 13.69
2.84 Item name: MENGKUDU 2 Channel name: High energy : Time 6.2919 +/- 0.0285 minutes :
2.77 16.81
Component name: Gedunin Drift Times: 6.10 +/- 0.24 ms

0 499.21752
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
145.02927
20000
223.06121 441.07210

501.09255 825.21816
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅲ [+H] : (39.7 PPM) 539.1763 : DT=6.24 to 6.72 ms

1000

750
Intensity [Counts]

Picroside Ⅲ
6.37
500
6.02
5.60

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.3716 +/- 0.0285 minutes :
Channel name: Picroside Ⅲ [+H] : (39.7 PPM) 539.1763 Component name: Picroside Ⅲ Drift Times: 6.48 +/- 0.24 ms
3.56
523.18284

2.52 100000 505.17274


2500

Intensity [Counts]
2000
465.12989
Intensity [Counts]

50000
1500
5.69
6.03 8.61 461.19122
4.35 14.37 533.21858
6.37 8.73 315.11331 391.12802 830.20218
5.61
1000 7.91 623.17845
9.06 9.49 0
1.76 13.32 200 400 600 800 1000
14.42 16.53
500 1.72 Item name: MENGKUDU 2 Channel name: High energy : Time 6.3716 +/- 0.0285 minutes :
16.58 Component name: Picroside Ⅲ Drift Times: 6.33 +/- 0.24 ms

0 505.17372

0 5 10 15 20 30000
Retention time [min] 289.12127 465.12886

Intensity [Counts]
20000

429.15917 523.18548

10000 265.08671 802.24401


164.07091 543.23957
669.15011 866.11522
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Acetylpaeoniflorin [+H] : (39.7 PPM) 523.1828 : DT=7.89 to 8.38 ms

500
Acetylpaeoniflorin
6.38

400
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.3856 +/- 0.0285
Channel name: Acetylpaeoniflorin [+H] : (39.7 PPM) 523.1828 Component name: Acetylpaeoniflorin minutes : Drift Times: 8.09 +/- 0.24 ms
6.39
417.17331

7500 523.18285

15000
807.25302

Intensity [Counts]
670.15011
5000 605.18572
Intensity [Counts]

10000 842.14653
2500 415.14584 844.13661
318.13093
8.58 863.22620

8.92 0
5000
200 400 600 800 1000
6.91 10.41 Item name: MENGKUDU 2 Channel name: High energy : Time 6.3856 +/- 0.0285
5.89
11.43 12.32 14.47 Component name: Acetylpaeoniflorin minutes : Drift Times: 7.93 +/- 0.24 ms
3.21 4.63
0 447.11214

0 5 10 15 20 417.17485
Retention time [min] 462.12687

Intensity [Counts]
805.25083
355.11423

5000 797.26293

308.10869 785.24133
244.05810 573.06036 857.17743
873.25262

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6-Feruloyl catalpol [+H] : (39.7 PPM) 523.1828 : DT=6.36 to 6.85 ms

6-Feruloyl catalpol
6.39

10000
Intensity [Counts]

7500

5000

2500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

6-Feruloyl catalpol
6.39
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.3881 +/- 0.0285
Channel name: 6-Feruloyl catalpol [+H] : (39.7 PPM) 523.1828 Component name: 6-Feruloyl catalpol minutes : Drift Times: 6.61 +/- 0.24 ms
6.39
523.18284
100000 505.17274
15000

Intensity [Counts]
465.12989
Intensity [Counts]

50000
10000

449.10975 543.23711
8.58 655.13716
307.11103 821.73115
8.92 0
5000
200 400 600 800 1000
6.91 10.41 Item name: MENGKUDU 2 Channel name: High energy : Time 6.3881 +/- 0.0285
5.89
11.43 12.32 14.47 Component name: 6-Feruloyl catalpol minutes : Drift Times: 6.46 +/- 0.24 ms
3.21 4.63
0 505.17372

0 5 10 15 20 30000
Retention time [min]

Intensity [Counts]
289.12127

20000 473.14579

265.08671 523.18548

10000 541.22537
164.07091 546.25237
856.16444
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5-O-Benzoyl-20-deoxyingenol [+H] : (39.7 PPM) 437.2361 : DT=5.26
to 5.74 ms
5-O-Benzoyl-20-deoxyingenol
6.39

6000
Intensity [Counts]

4000

2000

6.47

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.3891 +/-
Channel name: 5-O-Benzoyl-20-deoxyingenol [+H] : (39.7 PPM) 437.2361 Component name: 5-O-Benzoyl-20- 0.0285 minutes : Drift Times: 5.50 +/- 0.24 ms
6.40 deoxyingenol
8000 437.23610
75000
417.17323

Intensity [Counts]
6000
50000
Intensity [Counts]

4000 11.19 25000 352.17717 449.11040


11.12 317.15658 453.20939 622.17671 803.24392
11.07 11.53
0
8.00 16.58 200 400 600 800 1000
2000 10.76 16.52
8.38 16.66 Item name: MENGKUDU 2 Channel name: High energy : Time 6.3891 +/-
11.83 13.42
5.95 17.59 Component name: 5-O-Benzoyl-20- 0.0285 minutes : Drift Times: 5.35 +/- 0.24 ms
3.07 deoxyingenol
0
75000 437.23707
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000
417.17498

25000

453.21110
204.06614 352.17818 641.19193 803.24755
484.15397
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1,1,6-Trimethyl-1,2-dihydronaphthalene [+H] : (39.7 PPM)
173.1334 : DT=3.25 to 3.73 ms

600 6.42
1,1,6-Trimethyl-1,2-dihydronaphthalene
6.45
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.4375 +/-
Channel name: 1,1,6-Trimethyl-1,2-dihydronaphthalene [+H] : (39.7 PPM) 173.1334 Component name: 1,1,6-Trimethyl-1,2- 0.0285 minutes : Drift Times: 3.48 +/- 0.24 ms
6.45 dihydronaphthalene

173.13335
1000 13.69 10000
10.45

Intensity [Counts]
16.51
750
Intensity [Counts]

16.58
10.52 5000
0.98
7.76
13.54
500 10.19 192.14737
9.47 12.53
5.84
0
5.69 13.96
16.69 200 400 600 800 1000
250
1.84 4.42 16.81 Item name: MENGKUDU 2 Channel name: High energy : Time 6.4375 +/-
16.91 Component name: 1,1,6-Trimethyl-1,2- 0.0285 minutes : Drift Times: 3.33 +/- 0.24 ms
dihydronaphthalene
0
173.13202
0 5 10 15 20
Retention time [min]
2000

Intensity [Counts]
181.06421

1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Deacetylmatricarin-8-O-β-D-glucopyranoside [+H] : (39.7 PPM)
425.1792 : DT=5.49 to 5.97 ms

2500

2000
Intensity [Counts]

1500

1000

6.70
500
Deacetylmatricarin-8-O-β-D-glucopyranoside
6.56
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.5515 +/-
Channel name: Deacetylmatricarin-8-O-β-D-glucopyranoside [+H] : (39.7 PPM) Component name: Deacetylmatricarin-8-O-β- 0.0285 minutes : Drift Times: 5.73 +/- 0.24 ms
425.1792 D-glucopyranoside
5.04
447.16389
4000

Intensity [Counts]
50000

3000 4.93 403.15047


Intensity [Counts]

5.75
25000 377.12236
482.70671
2000 342.10732
4.54 5.94 509.16410 659.18004 836.23869
317.07060
4.37 10.97
6.13 0
7.07 200 400 600 800 1000
1000 3.53 11.16
3.03 11.22 Item name: MENGKUDU 2 Channel name: High energy : Time 6.5515 +/-
16.32
2.88 12.63 16.56 Component name: Deacetylmatricarin-8-O-β- 0.0285 minutes : Drift Times: 5.58 +/- 0.24 ms
D-glucopyranoside
0
447.16443
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000 417.17335

10000 189.06445
475.22275

291.09886 482.70890
709.07341
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Secoxyloganin [+H] : (39.7 PPM) 405.1377 : DT=5.29 to 5.77 ms

2000
Intensity [Counts]

1500

1000

500
Secoxyloganin
6.61
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.5823 +/- 0.0285
Channel name: Secoxyloganin [+H] : (39.7 PPM) 405.1377 Component name: Secoxyloganin minutes : Drift Times: 5.53 +/- 0.24 ms
5.09
5000 30000 417.17302
4.71 205.05042

4000

Intensity [Counts]
20000 377.12236

482.70671
Intensity [Counts]

361.12090
3000
10000

2000 177.05776 872.12703


4.31 653.13412

5.41 0
9.77 200 400 600 800 1000
1.75 2.84 8.43 10.49
1000 5.73
11.20 Item name: MENGKUDU 2 Channel name: High energy : Time 6.5823 +/- 0.0285
12.35 Component name: Secoxyloganin minutes : Drift Times: 5.38 +/- 0.24 ms
15.35
0 417.17335

0 5 10 15 20 15000
Retention time [min] 347.12327

Intensity [Counts]
10000

177.05439
421.14784
5000
459.15546
91.05405
469.00629 871.12377
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Loganic acid-6'-O-β-D-glucoside [+H] : (39.7 PPM) 539.1960 :
DT=6.20 to 6.68 ms
6.05
5.95
1500
5.89
Intensity [Counts]

1000

8.61
2.48 5.49 14.36
2.53 6.15 9.00 16.58
500
2.59 9.49
16.43
12.61
1.67
16.78

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.6812 +/-
Channel name: Loganic acid-6'-O-β-D-glucoside [+H] : (39.7 PPM) 539.1960 Component name: Loganic acid-6'-O-β-D- 0.0285 minutes : Drift Times: 6.44 +/- 0.24 ms
5000 5.96 glucoside
6.05
503.20914

4000
20000

Intensity [Counts]
5.90
455.14485
Intensity [Counts]

3000 547.18832
10000
5.70 446.19049 551.14898
14.37 257.06427
2000 3.56 425.17076 577.17581 881.69759
5.40 7.98 8.60 243.04990
2.53 0
5.35 6.67 9.00 200 400 600 800 1000
1000 14.18 16.58
9.50 Item name: MENGKUDU 2 Channel name: High energy : Time 6.6812 +/-
1.66
15.01 Component name: Loganic acid-6'-O-β-D- 0.0285 minutes : Drift Times: 6.28 +/- 0.24 ms
18.52 glucoside
0
491.32338
0 5 10 15 20
Retention time [min]

Intensity [Counts]
368.11390 523.23247
5000
573.25076
309.11458
279.10272 605.18721

767.17966

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Taraxacolide-1-O-β-D-glucopyranoside [+H] : (39.7 PPM) 431.2273 :
DT=5.50 to 5.98 ms
600

400
Intensity [Counts]

6.64 Taraxacolide-1-O-β-D-glucopyranoside
6.70

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.6865 +/-
Channel name: Taraxacolide-1-O-β-D-glucopyranoside [+H] : (39.7 PPM) 431.2273 Component name: Taraxacolide-1-O-β-D- 0.0285 minutes : Drift Times: 5.74 +/- 0.24 ms
16.52 glucopyranoside
15000 380.13115

7500 420.22498

Intensity [Counts]
10000 459.11574
Intensity [Counts]

360.24048
5000 257.06445
5000 465.18701
15.18 222.07637 505.17625
687.14871 842.16278
14.96
14.81 0
2500 14.55 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 6.6865 +/-
7.00 10.71 12.09 16.83 Component name: Taraxacolide-1-O-β-D- 0.0285 minutes : Drift Times: 5.59 +/- 0.24 ms
2.784.54 9.34
6.48 glucopyranoside
0
473.23616
0 5 10 15 20 15000
Retention time [min]

Intensity [Counts]
10000 417.17388

362.18582
5000 216.06664 295.10152
524.23371
207.10396
606.28185
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Digiprolactone [+H] : (39.7 PPM) 197.1180 : DT=4.31 to 4.79 ms
Digiprolactone
6.76

400

300
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.7724 +/- 0.0285
Channel name: Digiprolactone [+H] : (39.7 PPM) 197.1180 Component name: Digiprolactone minutes : Drift Times: 4.55 +/- 0.24 ms
6.83
292.08360
3000

1.5e5

Intensity [Counts]
100000
Intensity [Counts]

2000

50000
271.15181 293.08639
6.29 303.08933
131.08460
1000 6.92 0
6.20 200 400 600 800 1000

5.74 Item name: MENGKUDU 2 Channel name: High energy : Time 6.7724 +/- 0.0285
15.70
7.86 10.28 11.07 16.50 17.42 Component name: Digiprolactone minutes : Drift Times: 4.40 +/- 0.24 ms
2.18 5.19 13.57
0 292.08281
1.5e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

262.07170
50000
230.08234
293.08490
175.04008
303.09006
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ulmoside [+H] : (39.7 PPM) 509.1861 : DT=6.66 to 7.14 ms

6.10
600

Ulmoside
400 6.77
Intensity [Counts]

7.41

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.7814 +/- 0.0285 minutes :
Channel name: Ulmoside [+H] : (39.7 PPM) 509.1861 Component name: Ulmoside Drift Times: 6.90 +/- 0.24 ms
6.11
1250 7.41 601.16222

7.70
2.22 6.80 10.90 20000

Intensity [Counts]
1000
10.84
533.21411
0.49
Intensity [Counts]

11.85 465.10408
750 4.56 12.37 608.16321 743.20390
10000
4.33
304.05439
3.78
13.79 762.17611
292.08361
500 14.01 16.52 744.20707 995.27299
1.84
16.61 0
16.46 200 400 600 800 1000
250 17.29 Item name: MENGKUDU 2 Channel name: High energy : Time 6.7814 +/- 0.0285 minutes :
Component name: Ulmoside Drift Times: 6.75 +/- 0.24 ms

0 303.05147

0 5 10 15 20
Retention time [min] 50000

Intensity [Counts] 25000


292.08281
391.12210
601.15964
251.03693 883.16164
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Digiprolactone [+H] : (39.7 PPM) 197.1182 : DT=3.44 to 3.92 ms
1250 Digiprolactone
6.79

1000
Intensity [Counts]

750

6.91
500

250 6.95

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.7960 +/- 0.0285
Channel name: Digiprolactone [+H] : (39.7 PPM) 197.1182 Component name: Digiprolactone minutes : Drift Times: 3.68 +/- 0.24 ms
6.83
133.10237
3000 40000

Intensity [Counts]
197.11821
Intensity [Counts]

2000 20000

234.07545
6.29
1000 6.92 0
6.20 200 400 600 800 1000

5.74 Item name: MENGKUDU 2 Channel name: High energy : Time 6.7960 +/- 0.0285
16.49
7.86 10.28 11.07 15.70 Component name: Digiprolactone minutes : Drift Times: 3.53 +/- 0.24 ms
2.18 5.19 13.56 16.61
0 179.10764

0 5 10 15 20
Retention time [min] 10000

Intensity [Counts] 5000

197.11739

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Digiprolactone [+H] : (39.7 PPM) 197.1182 : DT=4.58 to 5.06 ms

Digiprolactone
500 6.83

6.79
400
6.76
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.8169 +/- 0.0285
Channel name: Digiprolactone [+H] : (39.7 PPM) 197.1182 Component name: Digiprolactone minutes : Drift Times: 4.82 +/- 0.24 ms
6.83
294.13508
3000
266.10321
312.14533
40000

Intensity [Counts]
Intensity [Counts]

2000
20000 251.03748

197.11820
489.13067
161.09745 665.08028
6.29 507.18773 861.17057
1000 6.92 0
6.20 200 400 600 800 1000

5.74 Item name: MENGKUDU 2 Channel name: High energy : Time 6.8169 +/- 0.0285
16.50
7.86 10.28 11.07 15.70 Component name: Digiprolactone minutes : Drift Times: 4.66 +/- 0.24 ms
2.18 5.19 13.56 16.61
0 266.10251
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
294.13433

251.03669
20000
206.08140

133.10193 340.99954
553.13943
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ulmoside [+H] : (39.7 PPM) 509.1871 : DT=6.06 to 6.54 ms

500

400
Intensity [Counts]

300
Ulmoside
6.81

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.8177 +/- 0.0285 minutes :
Channel name: Ulmoside [+H] : (39.7 PPM) 509.1871 Component name: Ulmoside Drift Times: 6.30 +/- 0.24 ms
6.11
1250 7.41 503.20788

7.70
20000
2.22 6.80
10.90

Intensity [Counts]
1000
1.90 10.84

11.85 13.39 518.25909


Intensity [Counts]

0.49 466.17991
750 4.56 12.37 10000
4.33 575.22582
463.10728
3.78 312.14557 743.20386
13.79 445.20402
197.11829
500 1.84 14.01 829.23745 935.23396
14.91 0
200 400 600 800 1000
250 18.32
17.44 Item name: MENGKUDU 2 Channel name: High energy : Time 6.8177 +/- 0.0285 minutes :
Component name: Ulmoside Drift Times: 6.15 +/- 0.24 ms

0 15000 503.20927

0 5 10 15 20
Retention time [min] 479.32345

Intensity [Counts]
10000
293.08494 476.25717
345.13817
517.18599
5000
176.07174 559.24399
159.07784
737.18454 917.23821

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: m-Isopropyltoluene [+H] : (39.7 PPM) 135.1178 : DT=3.44 to 3.92
ms
6.81

m-Isopropyltoluene
6.84
600
Intensity [Counts]

400
6.74

200

6.91

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.8259 +/- 0.0285
Channel name: m-Isopropyltoluene [+H] : (39.7 PPM) 135.1178 Component name: m-Isopropyltoluene minutes : Drift Times: 3.68 +/- 0.24 ms
8.73
179.10791
1250
75000
10.62
6.83 8.68

Intensity [Counts]
1000 12.43
50000
Intensity [Counts]

6.29 9.22
12.39
750
25000
13.72 16.61 204.06719
500 16.52 251.03752
6.21 8.55
14.91 0
5.93
7.10 16.68 200 400 600 800 1000
250
5.04 Item name: MENGKUDU 2 Channel name: High energy : Time 6.8259 +/- 0.0285
1.80 16.76 Component name: m-Isopropyltoluene minutes : Drift Times: 3.53 +/- 0.24 ms

0 179.10764

0 5 10 15 20
Retention time [min] 10000

Intensity [Counts] 5000

197.11739
235.06598
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Digiprolactone [+H] : (39.7 PPM) 197.1183 : DT=5.46 to 5.95 ms

Digiprolactone
6.83
300
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.8356 +/- 0.0285
Channel name: Digiprolactone [+H] : (39.7 PPM) 197.1183 Component name: Digiprolactone minutes : Drift Times: 5.70 +/- 0.24 ms
6.83
361.14019
3000
75000

Intensity [Counts]
50000
417.16492
Intensity [Counts]

2000
421.14637
25000
449.10857
197.11828
6.29 479.12346 797.12097
1000 6.92 0
6.20 200 400 600 800 1000

5.74 Item name: MENGKUDU 2 Channel name: High energy : Time 6.8356 +/- 0.0285
16.49
7.86 10.28 11.07 15.70 Component name: Digiprolactone minutes : Drift Times: 5.55 +/- 0.24 ms
2.18 5.19 13.56 16.61
0 361.13929

0 5 10 15 20
Retention time [min] 40000

Intensity [Counts]
417.16767
20000
421.14860
175.03990
459.27877 785.19979
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Jangomolide [+H] : (39.7 PPM) 469.1839 : DT=5.88 to 6.36 ms

800

600
Intensity [Counts]

6.87
400
Jangomolide
6.86

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.8610 +/- 0.0285 minutes :
Channel name: Jangomolide [+H] : (39.7 PPM) 469.1839 Component name: Jangomolide Drift Times: 6.12 +/- 0.24 ms
5.30
418.16212
7.76
1250 5.53
2e5

Intensity [Counts]
8.64
1000 8.76 10.22
6.89
Intensity [Counts]

3.01 14.82
10.71 100000
750 5.09
2.88 14.79
2.57 4.28 12.69
16.53 401.13073 785.19641
500 515.19450
2.27 14.91 205.05090 845.24428
0
2.13 200 400 600 800 1000
250 2.05 16.76 Item name: MENGKUDU 2 Channel name: High energy : Time 6.8610 +/- 0.0285
18.14 Component name: Jangomolide minutes : Drift Times: 5.97 +/- 0.24 ms

0 418.16381

0 5 10 15 20
Retention time [min] 100000

Intensity [Counts]
401.13510
50000 175.03996

204.06723 473.19648
785.19971
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Scropolioside A [+H] : (39.7 PPM) 753.2580 : DT=7.42 to 7.91 ms
Scropolioside A
15000
6.88

10000
Intensity [Counts]

5000

7.53

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Scropolioside A
6.88
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.8775 +/- 0.0285
Channel name: Scropolioside A [+H] : (39.7 PPM) 753.2580 Component name: Scropolioside A minutes : Drift Times: 7.67 +/- 0.24 ms
6.88
753.25803
1.5e5
20000

Intensity [Counts]
100000
15000
Intensity [Counts]

754.26109
6.27 50000
748.30031 785.19643
10000 497.12952
386.08740 737.28079 839.21980
0
200 400 600 800 1000
5000
7.53 Item name: MENGKUDU 2 Channel name: High energy : Time 6.8775 +/- 0.0285
4.74 8.81 11.69 Component name: Scropolioside A minutes : Drift Times: 7.51 +/- 0.24 ms
1.43 2.72 10.53 16.55
0 753.26090
100000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000 339.14255

605.13172 754.26496

333.10997 497.12969 623.14160


785.19985
147.04522
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6-Feruloyl catalpol [+H] : (39.7 PPM) 523.1823 : DT=6.89 to 7.37 ms

1500
Intensity [Counts]

1000

500

6-Feruloyl catalpol
6.89

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.8889 +/- 0.0285
Channel name: 6-Feruloyl catalpol [+H] : (39.7 PPM) 523.1823 Component name: 6-Feruloyl catalpol minutes : Drift Times: 7.18 +/- 0.24 ms
6.39
703.27808

15000 20000

Intensity [Counts]
589.20500

571.18776
Intensity [Counts]

10000 10000
371.14833 523.18232

782.18847
8.58 257.06489 988.32207
8.92 0
5000
200 400 600 800 1000
6.91 10.41 Item name: MENGKUDU 2 Channel name: High energy : Time 6.8889 +/- 0.0285
5.89
11.43 12.32 14.47 Component name: 6-Feruloyl catalpol minutes : Drift Times: 7.03 +/- 0.24 ms
3.21 4.63
0 175.03996

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000 369.09564 703.27958

737.28831

10000 204.06714
605.13206
786.20043

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Chloranthalactone F [+H] : (39.7 PPM) 457.2408 : DT=5.81 to 6.30
ms

5000 7.26

7.56
4000 Chloranthalactone F
6.93 7.64
Intensity [Counts]

3000

8.45
2000
8.99

1000 9.10
6.69
6.53

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.9246 +/- 0.0285
Channel name: Chloranthalactone F [+H] : (39.7 PPM) 457.2408 Component name: Chloranthalactone F minutes : Drift Times: 6.06 +/- 0.24 ms
7.25
497.12995
457.24082
40000
7.56

Intensity [Counts]
6000
6.93 7.65
Intensity [Counts]

20000
4000 8.66 441.26537
8.98 519.19879
223.05969 606.13383 735.21418
402.16016
795.20092
0
2000 200 400 600 800 1000
6.69 10.61 Item name: MENGKUDU 2 Channel name: High energy : Time 6.9246 +/- 0.0285
11.10 16.51
Component name: Chloranthalactone F minutes : Drift Times: 5.91 +/- 0.24 ms
6.60 14.51
2.894.08
0 205.05001 457.24209
20000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
497.12965

10000

163.03947 441.26770
345.13698
577.10261
787.19841
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1739 : DT=5.39 to 5.87 ms
7.91

2000

1500
Intensity [Counts]

5.66 8.35
1000

4.88 7.58
4.63
6.35 8.95
500 4.37

4.24 3.54 9.56


1.05 9.71 13.04 13.93
16.53 18.34

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.9290 +/- 0.0285
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1739 Component name: Cichorioside B minutes : Drift Times: 5.63 +/- 0.24 ms
7.91
383.14813

6000 20000
417.17518

Intensity [Counts]
5.66 375.15597
Intensity [Counts]

4000 10000
483.17051
546.16425
223.05969
676.20566 815.20784 931.24045
5.46 8.35
2000 0
4.90 7.58 200 400 600 800 1000
9.37
4.80 6.35 9.66 Item name: MENGKUDU 2 Channel name: High energy : Time 6.9290 +/- 0.0285
13.94
4.26 10.20 Component name: Cichorioside B minutes : Drift Times: 5.48 +/- 0.24 ms
2.94 16.53
0 315.08617

0 5 10 15 20
Retention time [min]

Intensity [Counts]
5000 147.04548
330.10600
411.20168
391.15773 607.14838
2500

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ginkgolide A [+H] : (39.7 PPM) 409.1475 : DT=5.39 to 5.87 ms

10000

7500
Intensity [Counts]

5000

2500

Ginkgolide A
0 7.00
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 6.9891 +/- 0.0285
Channel name: Ginkgolide A [+H] : (39.7 PPM) 409.1475 Component name: Ginkgolide A minutes : Drift Times: 5.63 +/- 0.24 ms
12.04
481.26260
75000
12500

Intensity [Counts]
10000 50000
7.60
Intensity [Counts]

382.12986

7500 25000

357.14363 532.15287 717.16879


5000
0
9.12 9.86 200 400 600 800 1000
2500 10.74 Item name: MENGKUDU 2 Channel name: High energy : Time 6.9891 +/- 0.0285
0.61 3.54
3.45 3.87 8.35 13.43 Component name: Ginkgolide A minutes : Drift Times: 5.47 +/- 0.24 ms
3.24 14.98 16.57
0 481.26245

0 5 10 15 20
Retention time [min] 50000

Intensity [Counts] 25000

434.17605
497.24085
193.06853 370.10151
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2126 : DT=5.52 to 6.00 ms

750 Cichorioside C
7.14
Intensity [Counts]

7.10
500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.1458 +/- 0.0285
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2126 Component name: Cichorioside C minutes : Drift Times: 5.76 +/- 0.24 ms
8.24
13.51 20000 420.22480
1250 13.64
8.95 403.10361 459.12686
9.02 15000

Intensity [Counts]
1000 9.06
7.14
9.15 13.01
5.80 10000
Intensity [Counts]

13.69 205.05126
16.53
750 5.25 883.08761
362.14062 496.14752
5.09 5000 695.09257
9.60 11.63 16.60 191.03943
4.81
500
3.99 14.51 16.63
0
3.17 16.69 200 400 600 800 1000
250 2.51 17.08
0.96 Item name: MENGKUDU 2 Channel name: High energy : Time 7.1458 +/- 0.0285
Component name: Cichorioside C minutes : Drift Times: 5.61 +/- 0.24 ms

0 30000 418.16311

0 5 10 15 20
Retention time [min]

Intensity [Counts]
205.05078
20000
177.05434 257.06659

163.03980
10000 401.12773
459.12688

481.12812
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0560 : DT=6.83
to 7.31 ms

8.18

1.5e5
Intensity [Counts]

100000

50000
7.49

5,7,2',5'-Tetrahydroxy-flavone
0 7.19
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.1924 +/-
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0560 Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 7.07 +/- 0.24 ms
8.18 flavone

287.05596
7.49
100000
3e5

Intensity [Counts]
Intensity [Counts]

50000 643.25637
2e5 449.10876

288.05915 595.16664 645.26558


205.05098 687.14009 984.30418
7.20 0
100000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.1924 +/-
Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 6.92 +/- 0.24 ms
flavone
0
2e5 287.05676
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

643.25803
288.05979
175.03949 510.26340 804.17177
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0560 : DT=7.87
to 8.35 ms
7.49

100000
Intensity [Counts]

75000

50000

5,7,2',5'-Tetrahydroxy-flavone
25000
7.19

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.1932 +/-
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0560 Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 8.11 +/- 0.24 ms
8.18 flavone

3e5 287.05596
7.49

3e5

Intensity [Counts]
2e5
595.16664
Intensity [Counts]

741.22496
449.10868
2e5 100000

288.05915 579.17378 742.22725


275.11009
893.11462
7.20 0
100000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.1932 +/-
Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 7.96 +/- 0.24 ms
flavone
0
7.5e5 287.05676
0 5 10 15 20
Retention time [min]

Intensity [Counts]
5e5

2.5e5

288.05980 449.10833 851.15345


213.05610 763.20842
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1087 : DT=7.78 to 8.26 ms

30000
Intensity [Counts]

20000

Cimicifugic acid B
7.19
10000

7.08
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.1941 +/- 0.0285
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1087 Component name: Cimicifugic acid B minutes : Drift Times: 8.02 +/- 0.24 ms
7.49
80000 3e5 287.05596
8.18

Intensity [Counts]
60000 2e5
595.16664
Intensity [Counts]

741.22496
449.10868
100000
40000

288.05915 742.22725
7.19 275.11009 579.17378
596.16978
0
20000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.1941 +/- 0.0285
Component name: Cimicifugic acid B minutes : Drift Times: 7.87 +/- 0.24 ms
2.22 5.60
0 7.5e5

0 5 10 15 20
Retention time [min]
Chi ral

Intensity [Counts]
O
O O

5e5
O

O
O O
O

2.5e5
287.05676
Mass error: 1.7 mDa
763.20842 869.23696
213.05610
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1088 : DT=6.77 to 7.25 ms

40000

30000
Intensity [Counts]

20000

10000
Cimicifugic acid B
7.20

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.1956 +/- 0.0285
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1088 Component name: Cimicifugic acid B minutes : Drift Times: 7.00 +/- 0.24 ms
7.49
80000 287.05596
8.18 100000

Intensity [Counts]
60000
Intensity [Counts]

50000 643.25637
449.10876
40000

288.05915 595.16664 645.26558


7.19 205.05098 829.23351
687.14009
0
20000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.1956 +/- 0.0285
Component name: Cimicifugic acid B minutes : Drift Times: 6.84 +/- 0.24 ms
2.22 5.60
0 2e5 287.05676

0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

175.03949 288.05979 643.25803


703.27492
510.26340
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Onitin-2′-O-β-D-glucopyranoside [+H] : (39.7 PPM) 411.2025 :
DT=5.47 to 5.95 ms
7.41

1500 7.37
Intensity [Counts]

1000

7.31

500 Onitin-2′-O-β-D-glucopyranoside
7.20

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.1959 +/-
Channel name: Onitin-2′-O-β-D-glucopyranoside [+H] : (39.7 PPM) 411.2025 Component name: Onitin-2′-O-β-D- 0.0285 minutes : Drift Times: 5.71 +/- 0.24 ms
3000 7.41 glucopyranoside

375.15599
2500 7.37

Intensity [Counts]
2e5
2000
Intensity [Counts]

8.97
6.65

1500 100000
8.92
2.74
4.11 5.80 9.85 287.05596 425.13413
760.20060 883.08761
1000 271.06563 469.00843
0
2.60 11.06 16.62 200 400 600 800 1000
11.78
500 13.83 16.98 Item name: MENGKUDU 2 Channel name: High energy : Time 7.1959 +/-
2.47 Component name: Onitin-2′-O-β-D- 0.0285 minutes : Drift Times: 5.55 +/- 0.24 ms
1.59 glucopyranoside
0
2e5 375.15674
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

287.05676
175.03949
377.15784 883.09225
633.10657 779.17379
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Rehmannioside A [+H] : (39.7 PPM) 525.1810 : DT=6.37 to 6.85 ms

1000
Intensity [Counts]

750

500

250 Rehmannioside A
7.25

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.2207 +/- 0.0285
Channel name: Rehmannioside A [+H] : (39.7 PPM) 525.1810 Component name: Rehmannioside A minutes : Drift Times: 6.61 +/- 0.24 ms
8.37 13.16
575.24938
510.25699
4.65 315.08956
6.38 8.92 20000
14.10

Intensity [Counts]
1500 4.59
4.34
Intensity [Counts]

13.09
10000 487.20985
1000 7.90
205.05098 476.15658
5.35 9.86 11.76 594.21569 814.20361
467.25491
3.44 639.20250
881.19669
3.10 16.49
0
500 1.88 200 400 600 800 1000
16.56
1.01 Item name: MENGKUDU 2 Channel name: High energy : Time 7.2207 +/- 0.0285
Component name: Rehmannioside A minutes : Drift Times: 6.46 +/- 0.24 ms
16.74
0 279.06821
15000 227.03674
0 5 10 15 20
Retention time [min] 315.08939

Intensity [Counts]
10000

473.23704
5000
225.02138 645.26388
157.10064
804.17113
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1β,3α,9β-Trihydroxyeudesma-5,11(13)-dien-12-oic acid [+H] : (39.7
PPM) 283.1534 : DT=4.27 to 4.75 ms

1β,3α,9β-Trihydroxyeudesma-5,11(13)-dien-12-oic acid
1250
7.24

1000
Intensity [Counts]

750

500
7.18

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.2459 +/-
Channel name: 1β,3α,9β-Trihydroxyeudesma-5,11(13)-dien-12-oic acid [+H] : (39.7 Component name: 1β,3α,9β- 0.0285 minutes : Drift Times: 4.51 +/- 0.24 ms
PPM) 283.1534 Trihydroxyeudesma-5,11(13)-dien-12-oic acid
7.25
303.05088

75000

Intensity [Counts]
1500

50000
Intensity [Counts]

1000 10.38 304.05457


25000
7.95
170.06145 315.08966
2.45 519.02127
0.44 5.37 0
500 9.22 10.77 200 400 600 800 1000
5.09 6.46 13.97 16.50
2.23 3.12 10.84
Item name: MENGKUDU 2 Channel name: High energy : Time 7.2459 +/-
1.78 5.02 16.31
16.86 Component name: 1β,3α,9β- 0.0285 minutes : Drift Times: 4.35 +/- 0.24 ms
Trihydroxyeudesma-5,11(13)-dien-12-oic acid
0
303.05142
0 5 10 15 20
Retention time [min] 100000

Intensity [Counts] 50000

304.05470
169.07624 299.11678
519.02241
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Chloranthalactone F [+H] : (39.7 PPM) 457.2415 : DT=5.72 to 6.21
ms

Chloranthalactone F
7.26

4000
7.56
6.93
7.64
Intensity [Counts]

3000

2000
8.45
8.98

1000
6.69 9.10

6.23
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.2542 +/- 0.0285
Channel name: Chloranthalactone F [+H] : (39.7 PPM) 457.2415 Component name: Chloranthalactone F minutes : Drift Times: 5.97 +/- 0.24 ms
7.25
75000 457.24147

7.56

Intensity [Counts]
6000 303.05088
6.93 7.65 50000
Intensity [Counts]

473.23664

4000 25000
8.66
8.98
520.15406
635.13738 842.16349
205.05077
0
2000 200 400 600 800 1000
6.69 10.61 Item name: MENGKUDU 2 Channel name: High energy : Time 7.2542 +/- 0.0285
11.10 16.51
Component name: Chloranthalactone F minutes : Drift Times: 5.82 +/- 0.24 ms
14.51
2.894.08 6.60
0 303.05142

0 5 10 15 20 50000
Retention time [min] 457.24266

Intensity [Counts]
25000
473.23529

279.06789 507.18992
441.26421
219.09362 665.08247
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Genkwadaphnin [+H] : (39.7 PPM) 603.2224 : DT=6.94 to 7.42 ms

800

600
Intensity [Counts]

400

Genkwadaphnin
200
7.27

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.2655 +/- 0.0285
Channel name: Genkwadaphnin [+H] : (39.7 PPM) 603.2224 Component name: Genkwadaphnin minutes : Drift Times: 7.18 +/- 0.24 ms
8.92
4e5 303.05088
2500

3e5

Intensity [Counts]
8.76
2000
8.71 2e5
Intensity [Counts]

8.66
1500
9.21 465.10491
10.47 12.23 100000
9.87 611.16122
7.69 304.05446
1000 5.73 290.10257 842.16254
7.37 6.55 371.10841 665.08135
1.66 0
5.64 13.18 200 400 600 800 1000
1.70 13.44
500 4.24 Item name: MENGKUDU 2 Channel name: High energy : Time 7.2655 +/- 0.0285
13.96
18.53 Component name: Genkwadaphnin minutes : Drift Times: 7.02 +/- 0.24 ms
15.76

0 303.05142

0 5 10 15 20 5e5
Retention time [min]

Intensity [Counts]
2.5e5

304.05470
229.05010
571.23796 704.20125
465.10470
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅰ [+H] : (39.7 PPM) 493.1714 : DT=5.64 to 6.13 ms

600

Picroside Ⅰ
7.29
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.2920 +/- 0.0285 minutes :
Channel name: Picroside Ⅰ [+H] : (39.7 PPM) 493.1714 Component name: Picroside Ⅰ Drift Times: 5.89 +/- 0.24 ms
5.43
2500 303.05088

40000
2000

Intensity [Counts]
Intensity [Counts]

1500 20000 399.10802


3.85 10.47
5.59 6.83
4.52 465.10471 561.15991
2.29
7.91 257.06714
1000 611.16118
8.68 177.05639 871.12490
3.64 11.82 0
12.84 200 400 600 800 1000
500 1.88 13.02 16.47 Item name: MENGKUDU 2 Channel name: High energy : Time 7.2920 +/- 0.0285 minutes :
Component name: Picroside Ⅰ Drift Times: 5.73 +/- 0.24 ms
16.56
0 303.05142 403.14944
0 5 10 15 20 50000
Retention time [min]

Intensity [Counts]
25000

297.07693
165.06934 438.14282
649.11052
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Galloyloxypaeoniflorin [+H] : (39.7 PPM) 649.1757 : DT=7.19 to 7.67
ms

600

Galloyloxypaeoniflorin
7.31
Intensity [Counts]

400
7.27

7.21

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.3408 +/- 0.0285
Channel name: Galloyloxypaeoniflorin [+H] : (39.7 PPM) 649.1757 Component name: Galloyloxypaeoniflorin minutes : Drift Times: 7.43 +/- 0.24 ms
8.24
722.23420
2500 8.11 8.39
10000 673.25229

Intensity [Counts]
2000 3.76 619.12702

402.11870 603.27675
Intensity [Counts]

3.94 5000 729.15013


1500 586.25099
351.08777
8.49 767.26344
4.36 6.78 987.16932
8.63 223.06138
1000 3.53 4.41 8.66
2.81
4.59 10.84 11.63 13.64 0
3.37
10.87 200 400 600 800 1000
500 1.27 14.35
Item name: MENGKUDU 2 Channel name: High energy : Time 7.3408 +/-
14.82 18.52 Component name: Galloyloxypaeoniflorin 0.0285 minutes : Drift Times: 7.27 +/- 0.24 ms

0 673.24798
257.06601
0 5 10 15 20
7500
Retention time [min]

Intensity [Counts]
145.02897
703.25515
5000
382.09835
723.22611
386.12458
2500
767.17898

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Fibraurin [+H] : (39.7 PPM) 373.1296 : DT=4.98 to 5.46 ms
1.89
12.10

2000
Intensity [Counts]

1500

1000
7.71
4.96 7.60
500 3.02 4.91 5.75
1.44 7.89
10.65 16.52
13.30

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.3815 +/- 0.0285 minutes :
Channel name: Fibraurin [+H] : (39.7 PPM) 373.1296 Component name: Fibraurin Drift Times: 5.22 +/- 0.24 ms
7.70
351.10581
5000
12.10 15000

Intensity [Counts]
370.22275
4000 384.10842
1.89 10000
348.10658 392.15355
Intensity [Counts]

3000 424.10390
267.06897
0.62 5000 445.11371
7.05 257.06745
504.14262 693.11857
2000 530.13692
5.74 0
200 400 600 800 1000
4.96 8.87 9.58
1000 3.03 9.43 13.09 14.60 16.53 Item name: MENGKUDU 2 Channel name: High energy : Time 7.3815 +/- 0.0285 minutes :
13.39 Component name: Fibraurin Drift Times: 5.07 +/- 0.24 ms

0 145.02905

0 5 10 15 20 364.19920
Retention time [min] 5000 250.09404 385.22243

Intensity [Counts]
413.15292
2500
440.09086

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Onitin-2′-O-β-D-glucopyranoside [+H] : (39.7 PPM) 411.1986 :
DT=5.41 to 5.90 ms

2000 Onitin-2′-O-β-D-glucopyranoside
7.41

7.37
1500
Intensity [Counts]

1000
7.20

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.4011 +/-
Channel name: Onitin-2′-O-β-D-glucopyranoside [+H] : (39.7 PPM) 411.1986 Component name: Onitin-2′-O-β-D- 0.0285 minutes : Drift Times: 5.65 +/- 0.24 ms
7.41 glucopyranoside

391.14991
2500 7.37

Intensity [Counts]
50000
2000 8.97
Intensity [Counts]

6.65 411.19858

1500 25000
7.76 356.11310
438.23528
9.85 338.09994
2.73 5.41
5.33 246.08836 443.13795 814.20491
1000 659.22890
2.64 16.62 0
11.06
2.59 11.78 200 400 600 800 1000
13.48
500 16.98 Item name: MENGKUDU 2 Channel name: High energy : Time 7.4011 +/-
2.47 14.06
Component name: Onitin-2′-O-β-D- 0.0285 minutes : Drift Times: 5.49 +/- 0.24 ms
1.88 17.32
glucopyranoside
0
391.15060
0 5 10 15 20 50000
Retention time [min]

Intensity [Counts]
25000

145.02905 392.16351
306.10633
471.23065 628.18806
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Qinghaosu Ⅳ [+H] : (39.7 PPM) 283.1534 : DT=4.31 to 4.79 ms
7.24
1250

1000
Intensity [Counts]

750

500

7.18 Qinghaosu Ⅳ
7.43
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.4247 +/- 0.0285
Channel name: Qinghaosu Ⅳ [+H] : (39.7 PPM) 283.1534 Component name: Qinghaosu Ⅳ minutes : Drift Times: 4.55 +/- 0.24 ms
7.25
311.14548

7500
227.03681

Intensity [Counts]
1500

5000
Intensity [Counts]

324.10154
1000 10.38 365.11415
2500 607.10929
7.95 177.05501
426.57630

2.45
0.44 5.37 0
500 9.22 10.77
5.09 6.46 13.97 16.50
200 400 600 800 1000
2.23 3.12 10.84
5.02 Item name: MENGKUDU 2 Channel name: High energy : Time 7.4247 +/- 0.0285
16.31
1.78 16.86 Component name: Qinghaosu Ⅳ minutes : Drift Times: 4.40 +/- 0.24 ms
205.05083
0 293.17288
4000
0 5 10 15 20
313.10906
Retention time [min] 191.03384

Intensity [Counts]
2000
353.09958

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Fibraurin [+H] : (39.7 PPM) 373.1291 : DT=4.98 to 5.47 ms
1.89

12.10
2000
Intensity [Counts]

1500

1000
7.71
4.96 7.60
500 3.02 5.75
1.44 7.89
3.70 8.21 10.65 16.52
0.78 13.30

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.4325 +/- 0.0285 minutes :
Channel name: Fibraurin [+H] : (39.7 PPM) 373.1291 Component name: Fibraurin Drift Times: 5.23 +/- 0.24 ms
7.70
4e5
350.10400
5000

12.10 3e5

Intensity [Counts]
4000
1.89
2e5
Intensity [Counts]

3000
0.62
351.10528
7.05 100000
306.11130
364.19861
2000 267.06897 675.20841
375.15910567.17341 901.18920
5.74 0
8.87 200 400 600 800 1000
3.03 4.96
1000 9.43 13.09 14.60 16.52 Item name: MENGKUDU 2 Channel name: High energy : Time 7.4325 +/- 0.0285 minutes :
13.39 Component name: Fibraurin Drift Times: 5.07 +/- 0.24 ms

0 350.10411

0 5 10 15 20
Retention time [min] 100000

Intensity [Counts]
304.09837

246.08979
50000
367.13032
212.06844
150.09751 607.11438
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone E [+H] : (39.7 PPM) 451.2310 : DT=5.73 to 6.21 ms

600

400 Nigakilactone E
Intensity [Counts]

7.45

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.4578 +/- 0.0285
Channel name: Nigakilactone E [+H] : (39.7 PPM) 451.2310 Component name: Nigakilactone E minutes : Drift Times: 5.97 +/- 0.24 ms
13.30
2000 499.14405
13.45
30000

Intensity [Counts]
1500
20000
485.19632
Intensity [Counts]

5.37 6.48 454.23259 595.16681


1000 16.57 10000
5.30
16.50 393.15149 727.20984 843.16960
5.14 11.81 377.17212
8.20 10.72 136.06304
5.06 9.16 14.03 0
500 4.83 15.13 200 400 600 800 1000
16.71
4.59 Item name: MENGKUDU 2 Channel name: High energy : Time 7.4578 +/- 0.0285
4.06 16.78 Component name: Nigakilactone E minutes : Drift Times: 5.82 +/- 0.24 ms

0 499.14161

0 5 10 15 20 473.23482
10000 503.03013
Retention time [min] 218.09664

Intensity [Counts]
447.20824
5000

91.05438 504.03308 649.08887

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1087 : DT=6.71 to 7.19 ms

40000

30000
Intensity [Counts]

20000

Cimicifugic acid B
7.49
10000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.4889 +/- 0.0285
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1087 Component name: Cimicifugic acid B minutes : Drift Times: 6.95 +/- 0.24 ms
7.49
80000 287.05634
4e5
8.18

Intensity [Counts]
60000
Intensity [Counts]

2e5

40000 449.10867
595.16684
288.05958
7.19 643.25858
369.09434
0
20000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.4889 +/- 0.0285
Component name: Cimicifugic acid B minutes : Drift Times: 6.80 +/- 0.24 ms
2.22 5.60
0
0 5 10 15 20
Retention time [min]
Chi ral

5e5

Intensity [Counts]
O
O O
O

O
O O
O

2.5e5

287.05677
Mass error: 1.8 mDa
213.05592 765.16250
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0563 : DT=4.14
to 4.63 ms

60000
Intensity [Counts]

5,7,2',5'-Tetrahydroxy-flavone
40000 7.49

20000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.4905 +/-
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0563 Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 4.38 +/- 0.24 ms
8.18 flavone

287.05634
7.49
4e5
3e5

Intensity [Counts]
Intensity [Counts]

2e5
2e5

288.05962
220.17021 503.02671 635.06986
7.20 0
100000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.4905 +/-
Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 4.23 +/- 0.24 ms
flavone
0
287.05677
0 5 10 15 20
Retention time [min] 5e5

Intensity [Counts] 2.5e5

288.06036
241.04891
436.99725
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1087 : DT=7.71 to 8.20 ms
Cimicifugic acid B
40000 7.49

30000
Intensity [Counts]

20000

10000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.4908 +/- 0.0285
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1087 Component name: Cimicifugic acid B minutes : Drift Times: 7.95 +/- 0.24 ms
7.49
80000 1.5e6 287.05634
8.18

Intensity [Counts]
60000 1e6
Intensity [Counts]

5e5 449.10868 595.16683


40000 727.20977

288.05959 581.15122 749.19121


7.19 279.10776
781.12803
0
20000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.4908 +/- 0.0285
Component name: Cimicifugic acid B minutes : Drift Times: 7.80 +/- 0.24 ms
2.22 5.60
0
3e6
0 5 10 15 20
Retention time [min]
Chi ral

Intensity [Counts]
O
O O
O

2e6 O
O

O
O O
O

1e6
287.05677
Mass error: 1.8 mDa
749.19374
213.05596 874.79592
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0563 : DT=7.79
to 8.28 ms
5,7,2',5'-Tetrahydroxy-flavone
7.49

100000
Intensity [Counts]

75000

50000

25000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6
5,7,2',5'-Tetrahydroxy-flavone
7.49
Cimicifugic acid B
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.4909 +/-
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0563 Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 8.03 +/- 0.24 ms
8.18 flavone

1.5e6 287.05634
7.49

3e5

Intensity [Counts]
1e6
Intensity [Counts]

2e5 5e5 449.10868 595.16683


727.20977

279.10776 288.05959 581.15122 749.19121


781.12803
7.20 0
100000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.4909 +/-
Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 7.88 +/- 0.24 ms
flavone
0
287.05677
0 5 10 15 20 3e6
Retention time [min]

Intensity [Counts]
2e6

1e6

288.06036 449.11017
749.19374 864.14952
213.05596
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0563 : DT=5.71
to 6.19 ms

30000
Intensity [Counts]

20000

5,7,2',5'-Tetrahydroxy-flavone
7.49
10000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.4911 +/-
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0563 Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 5.95 +/- 0.24 ms
8.18 flavone

287.05633
7.49 1.5e5

3e5

Intensity [Counts]
100000
Intensity [Counts]

2e5
50000

438.23538 781.12801
261.09682 595.16681
782.13117
7.20 0
100000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.4911 +/-
Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 5.80 +/- 0.24 ms
flavone
0
287.05677
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

288.06036
218.09664 503.03013
649.08887 781.13081
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0563 : DT=6.79
to 7.28 ms

1.5e5 8.18

100000
Intensity [Counts]

50000

5,7,2',5'-Tetrahydroxy-flavone
7.19 7.49
8.51
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.4927 +/-
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0563 Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 7.03 +/- 0.24 ms
8.18 flavone

287.05634
7.49 4e5

3e5

Intensity [Counts]
Intensity [Counts]

2e5
2e5
449.10867
595.16684
288.05958
643.25858
369.09434 874.29274
7.20 0
100000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.4927 +/-
Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 6.88 +/- 0.24 ms
flavone
0
287.05677
0 5 10 15 20
Retention time [min]
5e5

Intensity [Counts] 2.5e5

288.06038 765.16250
643.25780
165.01822 502.02234
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lamiophlomiol B [+H] : (39.7 PPM) 243.0864 : DT=7.79 to 8.28 ms
Lamiophlomiol B
7.51
500

400
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.5047 +/- 0.0285
Channel name: Lamiophlomiol B [+H] : (39.7 PPM) 243.0864 Component name: Lamiophlomiol B minutes : Drift Times: 8.05 +/- 0.24 ms
5.50
1.5e6 287.05634

4000

Intensity [Counts]
1e6

3000
Intensity [Counts]

2.45 5e5 449.10868 595.16683


727.20977
2000
288.05959 581.15122 749.19121
279.10776
781.12803
0
2.84 7.51 200 400 600 800 1000
1000
1.94 9.20 Item name: MENGKUDU 2 Channel name: High energy : Time 7.5047 +/- 0.0285
3.40 6.50 9.83 11.10 14.83 16.57 Component name: Lamiophlomiol B minutes : Drift Times: 7.90 +/- 0.24 ms
13.50
1.24 13.95
0 287.05677
3e6
0 5 10 15 20
Retention time [min]

Intensity [Counts]
2e6

1e6

288.06036
449.11017 595.16826 749.19374
213.05596 874.28758
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1766 : DT=5.50 to 5.99 ms

2500

2000
Intensity [Counts]

1500

1000

500 Cichorioside B
7.58

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.5688 +/- 0.0285
Channel name: Cichorioside B [+H] : (39.7 PPM) 441.1766 Component name: Cichorioside B minutes : Drift Times: 5.75 +/- 0.24 ms
7.91
75000 409.16012
6000

Intensity [Counts]
5.66
50000
Intensity [Counts]

4000
392.13714
25000 376.13133

345.11946 459.22263
5.46 645.09000
8.35 496.18881 853.29769
2000 0
4.90 7.57 200 400 600 800 1000
9.66
4.80 6.35 Item name: MENGKUDU 2 Channel name: High energy : Time 7.5688 +/- 0.0285
4.26 9.71 12.37 13.94 Component name: Cichorioside B minutes : Drift Times: 5.59 +/- 0.24 ms
2.94 16.53
0 391.13224

0 5 10 15 20
40000 408.15632
Retention time [min]

Intensity [Counts]
20000 455.22793
204.06635
475.20381
621.11755
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 12-α-Hydroxyevodol [+H] : (39.7 PPM) 501.1765 : DT=6.22 to 6.70
ms

1000

12-α-Hydroxyevodol
7.53
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.5706 +/- 0.0285
Channel name: 12-α-Hydroxyevodol [+H] : (39.7 PPM) 501.1765 Component name: 12-α-Hydroxyevodol minutes : Drift Times: 6.46 +/- 0.24 ms
10.27
525.28859

4000
50000

Intensity [Counts]
6.97 513.12324
Intensity [Counts]

3000
7.52 25000 465.11508
6.57
4.50
575.22945
2000 8.23 341.13849
14.86
257.06463 659.18515 854.25861
8.89
5.97 11.07 0
1.89
200 400 600 800 1000
1000 11.42
2.24
11.71 Item name: MENGKUDU 2 Channel name: High energy : Time 7.5706 +/- 0.0285
0.70 16.49 Component name: 12-α-Hydroxyevodol minutes : Drift Times: 6.31 +/- 0.24 ms
17.61
0 575.22931

0 5 10 15 20
10000
Retention time [min] 473.23756

Intensity [Counts]
437.14175
275.07573
5000 235.06031

627.17165
645.08738

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Evodol [+H] : (39.7 PPM) 485.1794 : DT=5.95 to 6.43 ms

2000

1500
Intensity [Counts]

1000

500

Evodol
7.64

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.6246 +/- 0.0285 minutes : Drift
Channel name: Evodol [+H] : (39.7 PPM) 485.1794 Component name: Evodol Times: 6.19 +/- 0.24 ms
8.95
457.24115

5000
40000

Intensity [Counts]
6.25
4000 422.12371
6.04 9.69 503.15229
Intensity [Counts]

20000
3000
8.63 305.14991 504.15180
799.17557
287.13594 535.09069 845.15880
2000 8.59
12.18 0
11.96 200 400 600 800 1000
5.49
1000 10.24 12.75 Item name: MENGKUDU 2 Channel name: High energy : Time 7.6246 +/- 0.0285 minutes : Drift
1.40 3.17 4.44 15.89
14.84 Component name: Evodol Times: 6.04 +/- 0.24 ms
16.49
0 457.24221

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
422.12628
503.15315
619.11305
10000
176.04229 287.13965

637.12189 819.25564

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Pueroside B [+H] : (39.7 PPM) 623.1985 : DT=6.85 to 7.33 ms

2500

2000
Intensity [Counts]

1500

1000

500
Pueroside B
7.62

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.6342 +/- 0.0285 minutes :
Channel name: Pueroside B [+H] : (39.7 PPM) 623.1985 Component name: Pueroside B Drift Times: 7.09 +/- 0.24 ms
5.41
351.08661 603.28043
5.07
4000
4.55
20000

Intensity [Counts]
9.04

3000 2.66
Intensity [Counts]

6.41 7.13 524.20424


7.89 10000 659.18402
663.18559
2000 308.11411
267.06588 766.33720
9.16
0
11.21 15.38
1.67 200 400 600 800 1000
1000 4.34
15.12 14.30
15.96 Item name: MENGKUDU 2 Channel name: High energy : Time 7.6342 +/- 0.0285 minutes :
0.99 Component name: Pueroside B Drift Times: 6.94 +/- 0.24 ms
18.52
16.32
0 619.11292

0 5 10 15 20 15000
Retention time [min] 235.05973

Intensity [Counts]
10000
665.16826
177.05536 568.24539
352.08791
5000
679.19684
800.17579
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Tinoside [+H] : (39.7 PPM) 521.2014 : DT=6.28 to 6.76 ms
7.81

1250

1000
Intensity [Counts]

750 8.05
7.74
5.29
9.11
5.09 7.70 9.99
500
4.64 9.52
1.64
4.44 10.04
250 4.19 12.18 16.49
16.60

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.6351 +/- 0.0285 minutes :
Channel name: Tinoside [+H] : (39.7 PPM) 521.2014 Component name: Tinoside Drift Times: 6.43 +/- 0.24 ms
4.64
541.22681
20000
2500 7.81
473.20264

Intensity [Counts]
2000 305.14991
9.11 619.11236
Intensity [Counts]

10000

1500 799.17593
5.29 287.13594 452.13801
7.59
9.51 637.11990 913.29879
6.64 235.05974
1000 10.47
1.64 0
4.30 10.72 13.83 16.48 200 400 600 800 1000
3.63
500 16.56 Item name: MENGKUDU 2 Channel name: High energy : Time 7.6351 +/- 0.0285 minutes :
18.53 Component name: Tinoside Drift Times: 6.28 +/- 0.24 ms

0 175.04000

0 5 10 15 20 50000
Retention time [min]

Intensity [Counts]
25000

543.24227
619.11305
291.06654 799.18189

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 8-O-Acetyl shanzhiside methyl ester [+H] : (39.7 PPM) 449.1672 :
DT=5.89 to 6.38 ms

30000
Intensity [Counts]

20000

10000

8-O-Acetyl shanzhiside methyl ester


0 7.66
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.6546 +/-
Channel name: 8-O-Acetyl shanzhiside methyl ester [+H] : (39.7 PPM) 449.1672 Component name: 8-O-Acetyl shanzhiside 0.0285 minutes : Drift Times: 6.13 +/- 0.24 ms
50000 12.06 methyl ester

457.24115

40000
40000

Intensity [Counts]
503.15229
Intensity [Counts]

30000 455.22697
20000
305.14991 433.15327
504.15180
799.17557
20000 235.05889
539.26726 820.25881
0
200 400 600 800 1000
10000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.6546 +/-
11.34 Component name: 8-O-Acetyl shanzhiside 0.0285 minutes : Drift Times: 5.98 +/- 0.24 ms
3.04 7.52 methyl ester
0
175.04000
0 5 10 15 20
Retention time [min] 50000

Intensity [Counts]
457.24221
25000
503.15315

369.09669 619.11305
819.25564
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Onitin-2′-O-β-D-glucopyranoside [+H] : (39.7 PPM) 411.1996 :
DT=5.42 to 5.90 ms

2000

1500
Intensity [Counts]

1000 Onitin-2′-O-β-D-glucopyranoside
7.70

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.6990 +/-
Channel name: Onitin-2′-O-β-D-glucopyranoside [+H] : (39.7 PPM) 411.1996 Component name: Onitin-2′-O-β-D- 0.0285 minutes : Drift Times: 5.66 +/- 0.24 ms
3000 7.41 glucopyranoside

387.15593
7.5e5
2500 7.37

Intensity [Counts]
2000 5e5
8.97
Intensity [Counts]

6.65

1500 2.5e5
7.76
2.74 9.85 447.16277
4.11 5.33 239.06749 369.09645 449.17202
1000 729.20764 875.24241
0
11.06 16.62
2.60 11.78 200 400 600 800 1000
13.48
500 16.98 Item name: MENGKUDU 2 Channel name: High energy : Time 7.6990 +/-
2.47 14.06
18.30 Component name: Onitin-2′-O-β-D- 0.0285 minutes : Drift Times: 5.51 +/- 0.24 ms
1.43 glucopyranoside
0
387.15677
0 5 10 15 20
5e5
Retention time [min]

Intensity [Counts]
2.5e5

447.16452
188.07204 260.09188
603.28446
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1096 : DT=6.72 to 7.20 ms

40000

30000
Intensity [Counts]

20000

10000

Cimicifugic acid B
0 7.72
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.7245 +/- 0.0285
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1096 Component name: Cimicifugic acid B minutes : Drift Times: 6.94 +/- 0.24 ms
7.49
80000 287.05652
8.18
100000

Intensity [Counts]
60000
Intensity [Counts]

50000
40000
449.10961 599.25144
276.08676 656.18216
7.19
826.17148 945.39888
0
20000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.7245 +/- 0.0285
Component name: Cimicifugic acid B minutes : Drift Times: 6.79 +/- 0.24 ms
2.22 5.60
0
0 5 10 15 20 1.5e5
Retention time [min]
Chi ral

Intensity [Counts]
O
O O
O

100000 O

O
O O
O

50000
287.05644
211.00623 Mass error: 1.4 mDa
658.18236
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0565 : DT=6.82
to 7.30 ms

8.18

1.5e5
Intensity [Counts]

100000

50000
7.49

7.19
5,7,2',5'-Tetrahydroxy-flavone
8.42
0 7.72
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.7385 +/-
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0565 Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 7.06 +/- 0.24 ms
8.18 flavone

287.05652
7.49

3e5 100000

Intensity [Counts]
Intensity [Counts]

2e5 50000

449.10961 599.25144
656.18216
222.07365 985.30168
7.20 0
100000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 7.7385 +/-
Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 6.91 +/- 0.24 ms
flavone
0
287.05644
0 5 10 15 20
1.5e5
Retention time [min]

Intensity [Counts]
100000

50000
288.05977
211.00623 617.15020 687.19311
449.10754
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Jasminoside E [+H] : (39.7 PPM) 331.1733 : DT=4.94 to 5.42 ms

600
Intensity [Counts]

400

Jasminoside E
7.80

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.8050 +/- 0.0285
Channel name: Jasminoside E [+H] : (39.7 PPM) 331.1733 Component name: Jasminoside E minutes : Drift Times: 5.18 +/- 0.24 ms
1250 13.64
30000 370.15012

16.57
1000 338.12550

Intensity [Counts]
4.35 16.43 20000
324.10875
9.54 13.71
13.51 422.09628
Intensity [Counts]

750 205.05113
7.83 13.08 13.95
3.74 7.41 10000
9.42 11.99 16.63
2.55 441.06977
6.65 14.74
500 5.02 163.03857 517.06277
661.20337
0
2.40 16.71 200 400 600 800 1000
250
2.18 Item name: MENGKUDU 2 Channel name: High energy : Time 7.8050 +/- 0.0285
16.84
Component name: Jasminoside E minutes : Drift Times: 5.02 +/- 0.24 ms

0 338.12321
20000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
216.98010
371.16534
206.05361
375.15561
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1381 : DT=3.55 to 4.03 ms

2000

1500
Intensity [Counts]

1000

7.84
ArteamisinineⅠ
500 7.72 7.81
7.55 7.90
7.94
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.8142 +/- 0.0285
Channel name: ArteamisinineⅠ [+H] : (39.7 PPM) 207.1381 Component name: ArteamisinineⅠ minutes : Drift Times: 3.78 +/- 0.24 ms
5.70
207.13805
10000

5000

Intensity [Counts]
7500
119.08658
Intensity [Counts]

6.08 2500
223.06041
5000

5.42
0
2500 200 400 600 800 1000

5.13 Item name: MENGKUDU 2 Channel name: High energy : Time 7.8142 +/- 0.0285
7.81 15.71 16.53 Component name: ArteamisinineⅠ minutes : Drift Times: 3.62 +/- 0.24 ms
4.42 6.99 9.03 10.67 13.44
40000 205.05100
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

123.08108

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ligustroside [+H] : (39.7 PPM) 525.1951 : DT=6.45 to 6.93 ms

1000

750
Intensity [Counts]

500 Ligustroside
7.77 7.84

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.8380 +/- 0.0285 minutes :
Channel name: Ligustroside [+H] : (39.7 PPM) 525.1951 Component name: Ligustroside Drift Times: 6.69 +/- 0.24 ms
2500 8.91
832.19924

8.37 13.16
30000 457.04298 541.22801
2000

Intensity [Counts]
13.85 223.06063
4.65 14.10
6.38 20000 577.17165
Intensity [Counts]

1500 9.29
8.29
9.44 13.09
385.11326 578.17379
4.34 10000
858.15372
1000 7.60 9.49 378.02530 601.17763
5.35 191.03329 973.26234

4.12 0
0.80 3.44 14.2116.49 200 400 600 800 1000
500 3.22 16.56 Item name: MENGKUDU 2 Channel name: High energy : Time 7.8380 +/- 0.0285
16.61 Component name: Ligustroside minutes : Drift Times: 6.54 +/- 0.24 ms

0 457.04453

0 5 10 15 20
Retention time [min] 40000 541.22706

Intensity [Counts]
135.04452

163.03967
20000 177.05505
379.01423 824.21639
543.25136
860.16134
623.16127
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Dihydrobrusatol [+H] : (39.7 PPM) 523.2154 : DT=6.23 to 6.71 ms

2500 8.58 8.68

8.92
9.02
2000
Intensity [Counts]

1500
8.37
9.35
8.34
1000
Dihydrobrusatol
7.83
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04
Dihydrobrusatol
7.76

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.8420 +/- 0.0285
Channel name: Dihydrobrusatol [+H] : (39.7 PPM) 523.2154 Component name: Dihydrobrusatol minutes : Drift Times: 6.47 +/- 0.24 ms
8.67
5000 8.58 824.21369
8.92
859.16041
8.98
631.13997
50000

Intensity [Counts]
4000

457.04298 607.16677
Intensity [Counts]

6.40
3000 8.49 541.22801
25000 223.06063
8.37 860.16360
9.98 205.05110
241.07115 816.72328
2000 8.26 191.03329
10.41 973.26234
7.83
0
7.65
5.88 16.49 200 400 600 800 1000
1000 11.46
0.73 Item name: MENGKUDU 2 Channel name: High energy : Time 7.8420 +/- 0.0285
5.25 11.78
0.92 17.14 Component name: Dihydrobrusatol minutes : Drift Times: 6.31 +/- 0.24 ms

0 40000 541.22706

0 5 10 15 20
135.04452
Retention time [min]

Intensity [Counts]
145.02942
20000 223.06160 441.07118

294.99135 859.16456
543.25136
623.16127 697.15493

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Oleanolic acid-28-O-β-D-glucopyranoside (PJS 1) [+H] : (39.7 PPM)
619.4166 : DT=7.27 to 7.75 ms

10000

7500
Intensity [Counts]

5000

2500
Oleanolic acid-28-O-β-D-glucopyranoside (PJS 1)
7.95

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9481 +/-
Channel name: Oleanolic acid-28-O-β-D-glucopyranoside (PJS 1) [+H] : (39.7 PPM) Component name: Oleanolic acid-28-O-β-D- 0.0285 minutes : Drift Times: 7.51 +/- 0.24 ms
619.4166 glucopyranoside (PJS 1)
16.85
665.16623

7500 619.41664

Intensity [Counts]
15000 503.33664 741.24550

5000
Intensity [Counts]

10000 994.82875
2500 257.06581 418.15148
983.23970

0
5000 200 400 600 800 1000
16.73 Item name: MENGKUDU 2 Channel name: High energy : Time 7.9481 +/-
7.95 Component name: Oleanolic acid-28-O-β-D- 0.0285 minutes : Drift Times: 7.36 +/- 0.24 ms
16.59
glucopyranoside (PJS 1)
0
257.06573
0 5 10 15 20 15000
Retention time [min]

Intensity [Counts]
10000
619.41795

175.03928 351.08563
5000 693.12685
415.14894
751.33845

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Qinghaosu Ⅳ [+H] : (39.7 PPM) 283.1524 : DT=4.19 to 4.68 ms

1250

1000
Intensity [Counts]

Qinghaosu Ⅳ
750 7.95

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9488 +/- 0.0285
Channel name: Qinghaosu Ⅳ [+H] : (39.7 PPM) 283.1524 Component name: Qinghaosu Ⅳ minutes : Drift Times: 4.44 +/- 0.24 ms
7.25
248.09446
15000

1500

Intensity [Counts]
10000
283.15236
Intensity [Counts]

1000 10.38 5000


7.95 236.08599
327.12741
383.07283
0.44 2.46 5.37 0
500 9.22 10.77 200 400 600 800 1000
5.31 6.46 16.50
2.23 3.12 10.84 13.97
12.15 16.31 16.61 Item name: MENGKUDU 2 Channel name: High energy : Time 7.9488 +/- 0.0285
1.78 5.09
Component name: Qinghaosu Ⅳ minutes : Drift Times: 4.28 +/- 0.24 ms
16.86
0 248.09341
2e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

220.09771
250.10023
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3271 : DT=7.56 to 8.04 ms

600

400 Poricoic acid B


Intensity [Counts]

7.96

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9638 +/- 0.0285
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3271 Component name: Poricoic acid B minutes : Drift Times: 7.83 +/- 0.24 ms
9.37
721.24670

6000
20000

Intensity [Counts]
8.07
Intensity [Counts]

4000 9.54 10000


503.33664 618.16939
737.33429
485.32706 741.24695 994.82875
7.98
9.69 376.10301 963.26366
2000 0
16.49 200 400 600 800 1000
11.03 Item name: MENGKUDU 2 Channel name: High energy : Time 7.9638 +/- 0.0285
12.63 13.66 16.66
7.24 Component name: Poricoic acid B minutes : Drift Times: 7.67 +/- 0.24 ms

0 351.08563 467.31804 618.17044


0 5 10 15 20 5000
Retention time [min] 540.24758

Intensity [Counts]
763.32139
163.04099 239.07281
2500 778.30236
91.05465 811.21257

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Esculentoside B [+H] : (39.7 PPM) 665.3885 : DT=7.33 to 7.82 ms

750
Intensity [Counts]

500

8.06

Esculentoside B
250 7.97

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9670 +/- 0.0285
Channel name: Esculentoside B [+H] : (39.7 PPM) 665.3885 Component name: Esculentoside B minutes : Drift Times: 7.60 +/- 0.24 ms
16.51
4000 619.41664 683.39963
7500

503.33664

Intensity [Counts]
3000 737.33429
5000 485.32706
467.31589
Intensity [Counts]

415.08987 994.82875
2000 2500 749.23646
8.06 387.10713 755.20994
16.64
7.99 376.10301 762.21644
16.79
8.85 0
13.70 16.96
1000 7.23 200 400 600 800 1000
9.37 13.57 13.91
14.65 Item name: MENGKUDU 2 Channel name: High energy : Time 7.9670 +/- 0.0285
7.12 17.11
Component name: Esculentoside B minutes : Drift Times: 7.44 +/- 0.24 ms
4.64
5.59
0 257.06573
15000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
619.41795

467.31804 721.24686
5000 206.05162 595.23970
748.17321
199.14847 871.12007
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganolucidic acid B [+H] : (39.7 PPM) 503.3366 : DT=6.50 to 6.98 ms

4000

3000
Intensity [Counts]

2000

1000 Ganolucidic acid B 8.07


7.97

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9700 +/- 0.0285
Channel name: Ganolucidic acid B [+H] : (39.7 PPM) 503.3366 Component name: Ganolucidic acid B minutes : Drift Times: 6.74 +/- 0.24 ms
16.86
543.24018
6000

20000

Intensity [Counts]
545.14913
510.25601 559.10413
16.61
Intensity [Counts]

4000
507.24042
10000 561.23195
8.07 367.08019
9.54 581.20124
353.06566 591.16419
947.27478
211.16804
2000 7.98
0
9.70 16.49 200 400 600 800 1000
13.69
Item name: MENGKUDU 2 Channel name: High energy : Time 7.9700 +/- 0.0285
7.24 15.61 17.00
12.26 Component name: Ganolucidic acid B minutes : Drift Times: 6.59 +/- 0.24 ms
6.67 17.72
0 543.24165

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
519.11313

10000 367.08240 558.25995


199.07494 559.23457
737.32056 925.57381
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3262 : DT=6.34 to 6.82 ms
2500

2000
Intensity [Counts]

1500

8.07
1000
Poricoic acid B
7.98

500 7.67

7.61
7.53
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9736 +/- 0.0285
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3262 Component name: Poricoic acid B minutes : Drift Times: 6.64 +/- 0.24 ms
9.37
543.24018

6000 20000

Intensity [Counts]
545.14913

8.07 510.25601
557.25444
Intensity [Counts]

507.24042
4000 9.54 10000 559.22825
500.15154 581.20124
211.16804 397.07981 591.16419
814.20445 998.26418
7.98
9.69 0
2000
16.49 200 400 600 800 1000
11.03 Item name: MENGKUDU 2 Channel name: High energy : Time 7.9736 +/- 0.0285
12.63 13.66 16.66
7.24 14.20 Component name: Poricoic acid B minutes : Drift Times: 6.48 +/- 0.24 ms

0 543.24165

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
519.11313

10000 199.07494 558.25995


468.16036
279.06193 559.23457
737.32056 925.57381
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide [+H] : (39.7
PPM) 503.3366 : DT=7.41 to 7.90 ms

8.07
400

11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide
Intensity [Counts]

300 7.98

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9742 +/-
Channel name: 11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide [+H] : (39.7 Component name: 11α,12α-Epoxy-23β,23- 0.0285 minutes : Drift Times: 7.63 +/- 0.24 ms
PPM) 503.3366 dihydroxyolean-28,13β-olide
16.86
680.17799
6000 7500 619.41664
683.39963
713.26002
503.33664

Intensity [Counts]
737.33429
5000 485.32706
16.61 760.21429
Intensity [Counts]

4000 467.31589
415.08987 773.25058
8.07 2500
9.54 376.10301
374.12089 917.70512

7.98 0
2000
9.70 16.49 200 400 600 800 1000
13.69 Item name: MENGKUDU 2 Channel name: High energy : Time 7.9742 +/-
7.24 15.61 17.00 Component name: 11α,12α-Epoxy-23β,23- 0.0285 minutes : Drift Times: 7.48 +/- 0.24 ms
12.26
6.67 17.72 dihydroxyolean-28,13β-olide
0
619.41795
0 5 10 15 20
7500
Retention time [min]

Intensity [Counts]
351.08563 467.31804 721.24686
5000

263.07130 595.23970
199.14847 748.17321
2500
843.21231

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Platycodigenin [+H] : (39.7 PPM) 521.3484 : DT=8.59 to 9.07 ms

Platycodigenin
7.99
500

400
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9885 +/- 0.0285
Channel name: Platycodigenin [+H] : (39.7 PPM) 521.3484 Component name: Platycodigenin minutes : Drift Times: 8.84 +/- 0.24 ms
7.99
2000 15000 883.15923

Intensity [Counts]
1500 10000

16.66
Intensity [Counts]

683.39975
16.56 16.71 521.34841 885.16283
5000 460.12534 845.45468
1000 16.91
8.21 16.48 841.19518
9.37
16.97 0
7.39
500 10.38 12.13 13.64 200 400 600 800 1000
17.05
6.89 15.09 Item name: MENGKUDU 2 Channel name: High energy : Time 7.9885 +/- 0.0285
17.51 Component name: Platycodigenin minutes : Drift Times: 8.69 +/- 0.24 ms
4.675.89
0 4000 319.00867

0 5 10 15 20
Retention time [min] 469.00962 545.15040

Intensity [Counts]
557.25935
769.31863
2000
317.07107 817.20156
643.04151
304.97325
199.14895
181.04682

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Esculentoside B [+H] : (39.7 PPM) 665.3894 : DT=8.37 to 8.85 ms

600

Esculentoside B
400 7.99
Intensity [Counts]

8.07
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9889 +/- 0.0285
Channel name: Esculentoside B [+H] : (39.7 PPM) 665.3894 Component name: Esculentoside B minutes : Drift Times: 8.61 +/- 0.24 ms
16.51
4000 15000 883.15923

Intensity [Counts]
3000 10000
Intensity [Counts]

683.39975
521.34841 812.17913
927.22222
5000 460.12534
2000
8.06 16.64 427.10261
7.99
8.85 16.79 0
13.70
1000 7.23 16.95 200 400 600 800 1000
9.37 13.57
13.91 Item name: MENGKUDU 2 Channel name: High energy : Time 7.9889 +/- 0.0285
17.11
7.12 Component name: Esculentoside B minutes : Drift Times: 8.45 +/- 0.24 ms
5.59
0 369.09776

0 5 10 15 20 5000
Retention time [min] 319.00867

Intensity [Counts]
455.22791 545.15040 763.32442

2500
304.97364
867.43801
206.05152

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Trachelosperoside E-1 [+H] : (39.7 PPM) 683.3996 : DT=7.36 to 7.84
ms

1000 Trachelosperoside E-1


7.99

750
Intensity [Counts]

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9893 +/- 0.0285
Channel name: Trachelosperoside E-1 [+H] : (39.7 PPM) 683.3996 Component name: Trachelosperoside E-1 minutes : Drift Times: 7.60 +/- 0.24 ms
13.65
677.13459

16.49 10000
3000 7.99 680.17799

Intensity [Counts]
661.24851 683.39963
8.21
503.33664
Intensity [Counts]

5000 747.17751
485.32706
2000 758.29855
467.31589
13.53 16.74
415.08987
8.43 981.26589

9.03 13.94 319.09443


0
1000 200 400 600 800 1000
9.37 15.03
7.40 9.71 13.07 16.81 Item name: MENGKUDU 2 Channel name: High energy : Time 7.9893 +/-
Component name: Trachelosperoside E-1 0.0285 minutes : Drift Times: 7.44 +/- 0.24 ms
6.52 16.97
5.00
0 677.13165

0 5 10 15 20
7500
Retention time [min]

Intensity [Counts]
721.24686
351.08563 467.31804
5000
747.17450
206.05162 621.29147
750.19065
2500 188.07168
843.21231

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Trachelosperoside E-1 [+H] : (39.7 PPM) 683.3997 : DT=8.48 to 8.96
ms
Trachelosperoside E-1
600 7.99
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 7.9909 +/- 0.0285
Channel name: Trachelosperoside E-1 [+H] : (39.7 PPM) 683.3997 Component name: Trachelosperoside E-1 minutes : Drift Times: 8.72 +/- 0.24 ms
13.65
15000 883.15923

16.49
3000 7.99

Intensity [Counts]
10000
8.21
Intensity [Counts]

683.39975
521.34841 885.16283
2000 5000 460.12534
13.53 16.74
8.43
9.03 13.94
0
1000 200 400 600 800 1000
9.37 15.03
7.40 9.71 13.07 16.81 Item name: MENGKUDU 2 Channel name: High energy : Time 7.9909 +/-
Component name: Trachelosperoside E-1 0.0285 minutes : Drift Times: 8.57 +/- 0.24 ms
6.52 16.97
5.00
0 369.09776

0 5 10 15 20 5000
Retention time [min] 319.00867

Intensity [Counts]
513.12219
652.14454
2500
304.97364 817.20156
206.05152 867.43801

181.04682
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bruceine A [+H] : (39.7 PPM) 523.2171 : DT=6.21 to 6.69 ms

8.68
2500 8.62

8.58 8.92
9.02
2000
9.07
Intensity [Counts]

1500
8.37
9.35
8.32
1000

Bruceine A
500 8.02

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.0085 +/- 0.0285 minutes :
Channel name: Bruceine A [+H] : (39.7 PPM) 523.2171 Component name: Bruceine A Drift Times: 6.45 +/- 0.24 ms
8.67
5000 20000 465.10415
8.58 8.92 545.14913
8.98

Intensity [Counts]
4000
557.25444
Intensity [Counts]

10000 579.21218
3000 8.49
6.40
8.37 423.12005
655.14065
9.98
191.03745 366.22806 884.16168
2000 8.26 814.20447
7.83 10.41
7.76 0
5.89 16.49 200 400 600 800 1000
1000
0.73 11.46 Item name: MENGKUDU 2 Channel name: High energy : Time 8.0085 +/- 0.0285 minutes :
5.64
0.92 3.24 11.78 17.14 Component name: Bruceine A Drift Times: 6.30 +/- 0.24 ms

0 205.05126

0 5 10 15 20 15000
Retention time [min]

Intensity [Counts]
225.03898
557.25826
10000
542.22884
573.23689
191.03448 263.07059
5000 467.31863
188.07161
649.18955
123.08021 907.29307
801.20902
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bruceine E_1 [+H] : (39.7 PPM) 413.1812 : DT=5.43 to 5.91 ms
8.71
1250

1000

8.65
Intensity [Counts]

750

8.85
500
5.51 7.77 12.75 14.40
10.39
2.23 2.87 5.01 16.51
250 16.66
2.06
16.74
18.22
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.0279 +/- 0.0285 minutes :
Channel name: Bruceine E_1 [+H] : (39.7 PPM) 413.1812 Component name: Bruceine E_1 Drift Times: 5.67 +/- 0.24 ms
8.71
2000 423.11954

366.22797 453.09572
8.66 20000

Intensity [Counts]
1500
Intensity [Counts]

10000
205.05118
1000 459.13873
8.87
191.03745 675.23203 811.22934
9.25 12.75 13.56 517.18366
8.00
4.09 5.38 6.20 16.52 849.26866
0
500 3.34 14.40 16.60 200 400 600 800 1000
2.87 16.75 Item name: MENGKUDU 2 Channel name: High energy : Time 8.0279 +/- 0.0285
2.06 16.98 Component name: Bruceine E_1 minutes : Drift Times: 5.51 +/- 0.24 ms

0 421.14163
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
366.22776
20000 423.11604

163.03960 437.23054
457.15392
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Esculentoside B [+H] : (39.7 PPM) 665.3892 : DT=7.21 to 7.69 ms

800

600
Intensity [Counts]

Esculentoside B
400
8.06
7.97

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.0693 +/- 0.0285
Channel name: Esculentoside B [+H] : (39.7 PPM) 665.3892 Component name: Esculentoside B minutes : Drift Times: 7.53 +/- 0.24 ms
16.51
4000 663.25355

15000

Intensity [Counts]
3000
10000
Intensity [Counts]

521.16829 687.28854
689.28694
485.32907
2000 5000 765.30895
8.06 16.64 319.08712
476.11731 860.24086
7.99 308.11377
8.85 16.79 0
13.70
1000 7.23 16.95 200 400 600 800 1000
9.37 13.57
13.91 Item name: MENGKUDU 2 Channel name: High energy : Time 8.0693 +/- 0.0285
17.11
7.12 Component name: Esculentoside B minutes : Drift Times: 7.38 +/- 0.24 ms
5.59
20000 175.04052
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000 663.25586
521.17046
216.97962
266.11722 719.31365
585.25085 737.32478
817.27070
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide [+H] : (39.7
PPM) 503.3363 : DT=7.63 to 8.11 ms

500
11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide
8.07
400
Intensity [Counts]

300 7.97

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide
0 8.07

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.0708 +/-
Channel name: 11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide [+H] : (39.7 Component name: 11α,12α-Epoxy-23β,23- 0.0285 minutes : Drift Times: 7.87 +/- 0.24 ms
PPM) 503.3363 dihydroxyolean-28,13β-olide
16.86
15000 744.23593
6000

Intensity [Counts]
10000
521.16829
16.61 689.28694
Intensity [Counts]

4000 503.33627
669.27975 778.29365
8.07 5000
485.32907 787.22196
9.54
467.31747 821.32401
340.13791
7.98 0
2000
9.70 16.49 200 400 600 800 1000
13.69 Item name: MENGKUDU 2 Channel name: High energy : Time 8.0708 +/-
7.55 17.00
12.26 15.61 Component name: 11α,12α-Epoxy-23β,23- 0.0285 minutes : Drift Times: 7.72 +/- 0.24 ms
7.24
17.72 dihydroxyolean-28,13β-olide
0
521.17016
0 5 10 15 20 7500
145.02982
Retention time [min]

Intensity [Counts]
177.05428
5000 835.24820
273.08022 489.23263 600.21451 668.16871

868.19720
2500

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide [+H] : (39.7
PPM) 503.3363 : DT=6.94 to 7.42 ms

1500
Intensity [Counts]

1000

11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide
8.07
500
7.97

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.0718 +/-
Channel name: 11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide [+H] : (39.7 Component name: 11α,12α-Epoxy-23β,23- 0.0285 minutes : Drift Times: 7.18 +/- 0.24 ms
PPM) 503.3363 dihydroxyolean-28,13β-olide
16.86
10000 587.27572
6000
613.25039

Intensity [Counts]
503.33627 633.25250

829.24014
16.61 5000
Intensity [Counts]

4000
8.07 317.19762
9.54 959.33682

267.11509
7.98 0
2000
9.70 16.49 200 400 600 800 1000
13.69 Item name: MENGKUDU 2 Channel name: High energy : Time 8.0718 +/-
7.55 17.00
12.26 15.61 Component name: 11α,12α-Epoxy-23β,23- 0.0285 minutes : Drift Times: 7.03 +/- 0.24 ms
7.24
17.72 dihydroxyolean-28,13β-olide
0
20000 175.04052
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000 663.25586
521.17046
505.20491
371.11377 587.26655 698.20462
91.05478
737.32478
852.22114
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganolucidic acid B [+H] : (39.7 PPM) 503.3363 : DT=6.45 to 6.93 ms

4000

3000
Intensity [Counts]

2000

Ganolucidic acid B
1000 8.06
7.97

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.0719 +/- 0.0285
Channel name: Ganolucidic acid B [+H] : (39.7 PPM) 503.3363 Component name: Ganolucidic acid B minutes : Drift Times: 6.74 +/- 0.24 ms
16.86
569.31566
6000

40000

Intensity [Counts]
16.61
Intensity [Counts]

4000 564.35979
20000 521.25631
8.07
9.54
503.20138 635.13058
317.19762 403.30186 856.32878
667.18622
2000 7.98
0
9.70 16.49 200 400 600 800 1000
13.69
7.55 Item name: MENGKUDU 2 Channel name: High energy : Time 8.0719 +/- 0.0285
13.95 17.00
12.26 Component name: Ganolucidic acid B minutes : Drift Times: 6.59 +/- 0.24 ms
7.24
17.72
0 569.31686

0 5 10 15 20 O
Chiral

Retention time [min] 40000 O

Intensity [Counts]
O O

O
H

20000
449.30539
Mass error: 0.4 mDa 587.26655
721.10074 885.16645
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1593 : DT=5.71 to 6.20 ms

500

400
Intensity [Counts]

Lactiflorin
300 8.11

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.1104 +/- 0.0285 minutes :
Channel name: Lactiflorin [+H] : (39.7 PPM) 463.1593 Component name: Lactiflorin Drift Times: 5.95 +/- 0.24 ms
4.35
453.16690
6000
100000

Intensity [Counts]
483.11872
Intensity [Counts]

4000
50000

304.11908

519.15894 884.16538
257.06645 685.24651
4.17 616.13466
2000 0
7.62 200 400 600 800 1000
8.86
5.79 10.85
2.29 9.95 13.46 Item name: MENGKUDU 2 Channel name: High energy : Time 8.1104 +/- 0.0285 minutes :
11.99 16.96 Component name: Lactiflorin Drift Times: 5.80 +/- 0.24 ms
2.04 15.18
18.53
0 453.16836
75000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

304.11937
25000 205.05015 483.11978

522.17023 884.16523
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Galloylpaeoniflorin [+H] : (39.7 PPM) 633.1805 : DT=6.71 to 7.19 ms
3.57

1000

750
Intensity [Counts]

3.91

6.09
10.12
500
6.03 6.15 16.92
2.97 4.95
8.61
2.20 10.97
8.47
250 1.58 11.17
13.69 14.59
16.55 18.52

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.1155 +/- 0.0285
Channel name: Galloylpaeoniflorin [+H] : (39.7 PPM) 633.1805 Component name: Galloylpaeoniflorin minutes : Drift Times: 6.95 +/- 0.24 ms
3.57
2500 621.29291
7.27
20000

Intensity [Counts]
2000

3.71
10.12
Intensity [Counts]

582.23815 634.13599
1500 3.17 10000 573.15126 641.18677
5.23 561.25463
6.03 653.13837 829.24014
257.06625 440.21213
1000 2.98
8.92 848.21701
8.11 10.60 0
1.582.19 11.30
15.01 16.91 200 400 600 800 1000
500 0.98 11.63 15.11
18.52 Item name: MENGKUDU 2 Channel name: High energy : Time 8.1155 +/- 0.0285
Component name: Galloylpaeoniflorin minutes : Drift Times: 6.80 +/- 0.24 ms

0 177.05571 619.29919
7500
0 5 10 15 20
Retention time [min] 191.03481

Intensity [Counts]
5000 587.26655
321.08247
885.16744
399.10896
646.19472
2500 469.04301 867.19062

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6′-O-β-D-Glucosyl gentiopicroside [+H] : (39.7 PPM) 519.1706 :
DT=6.67 to 7.15 ms
9.01

750
Intensity [Counts]

7.46

500
8.64
13.08

5.79 7.31 9.39 11.47


250
2.81 5.17 6.48 13.73
2.63 4.90 14.88 14.60
2.32 16.74
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.1720 +/-
Channel name: 6′-O-β-D-Glucosyl gentiopicroside [+H] : (39.7 PPM) 519.1706 Component name: 6′-O-β-D-Glucosyl 0.0285 minutes : Drift Times: 6.91 +/- 0.24 ms
7.54 9.00 gentiopicroside

287.05664
2500
1.5e6

Intensity [Counts]
2000 7.46
1e6
Intensity [Counts]

1500 6.90 449.10931


2.93 4.54 11.71 13.45 14.33
5e5
5.46 10.95 288.06049 595.16769
1000 2.63 9.39
129.05390 640.18928
2.48 0
16.49 200 400 600 800 1000
2.06
500 15.00 Item name: MENGKUDU 2 Channel name: High energy : Time 8.1720 +/-
0.61 16.56
Component name: 6′-O-β-D-Glucosyl 0.0285 minutes : Drift Times: 6.75 +/- 0.24 ms
16.61 gentiopicroside
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
O

2e6
O
O

O O
O
O O
O
O
O
O
O

1e6
O

165.01902 287.05699
Mass error: 2 mDa 649.08914
920.16597
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1093 : DT=8.41 to 8.89 ms

4000

3000
Intensity [Counts]

2000
Cimicifugic acid B
8.17

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.1772 +/- 0.0285
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1093 Component name: Cimicifugic acid B minutes : Drift Times: 8.67 +/- 0.24 ms
7.49
80000 595.16768
8.18 100000

Intensity [Counts]
60000
Intensity [Counts]

50000 649.08724

40000 449.10931
528.07366
805.23888
7.19 288.06050 922.26267
0
20000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 8.1772 +/- 0.0285
Component name: Cimicifugic acid B minutes : Drift Times: 8.52 +/- 0.24 ms
2.22 5.60
0 288.06070
30000 649.08919
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

504.03309
10000 650.09112
502.02316
837.18682 934.13094

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0566 : DT=5.69
to 6.18 ms
5,7,2',5'-Tetrahydroxy-flavone
8.18

30000
Intensity [Counts]

20000

10000

8.32

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.1812 +/-
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0566 Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 5.93 +/- 0.24 ms
8.18 flavone

287.05664
7.49

3e5 3e5

Intensity [Counts]
2e5
Intensity [Counts]

2e5
100000
288.06049 457.24382
266.12031
411.19723 482.26482 748.88858
7.20 0
100000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 8.1812 +/-
Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 5.78 +/- 0.24 ms
flavone
0
287.05699
0 5 10 15 20
Retention time [min]

Intensity [Counts]
2e5

288.06070 471.22446
241.05063
749.38499
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1093 : DT=6.75 to 7.23 ms
Cimicifugic acid B
8.18

40000

30000
Intensity [Counts]

20000

10000

8.31
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.1812 +/- 0.0285
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1093 Component name: Cimicifugic acid B minutes : Drift Times: 6.99 +/- 0.24 ms
7.49
80000 287.05664
8.18
1.5e6

Intensity [Counts]
60000

1e6
Intensity [Counts]

40000 449.10931
5e5
288.06049 595.16769
7.19 675.27716
129.05390
0
20000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 8.1812 +/- 0.0285
Component name: Cimicifugic acid B minutes : Drift Times: 6.83 +/- 0.24 ms
2.22 5.60
0
0 5 10 15 20
Retention time [min]
Chi ral

Intensity [Counts]
O

2e6
O O
O

O
O O
O

1e6
287.05699
Mass error: 2 mDa
649.08914
165.01902 920.16597
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0566 : DT=6.82
to 7.30 ms
5,7,2',5'-Tetrahydroxy-flavone
8.18
1.5e5
Intensity [Counts]

100000

50000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
8.18
1.5e6
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.1814 +/-
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0566 Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 7.06 +/- 0.24 ms
8.18 flavone

287.05664
7.49

3e5 1.5e6

Intensity [Counts]
1e6
Intensity [Counts]

2e5
449.10931
5e5
288.06049 595.16769
675.27716
129.05390 575.30200
7.20 0
100000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 8.1814 +/-
Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 6.91 +/- 0.24 ms
flavone
0
287.05699
0 5 10 15 20
Retention time [min]

Intensity [Counts]
2e6

1e6

288.06070
675.27972
165.01902 449.11076 601.17751 920.16597
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0566 : DT=4.14
to 4.62 ms
5,7,2',5'-Tetrahydroxy-flavone
8.18

60000
Intensity [Counts]

40000

20000

8.29
8.46
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.1824 +/-
Channel name: 5,7,2',5'-Tetrahydroxy-flavone [+H] : (39.7 PPM) 287.0566 Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 4.38 +/- 0.24 ms
8.18 flavone

7.5e5 287.05664
7.49

3e5

Intensity [Counts]
5e5
Intensity [Counts]

2e5 2.5e5

288.06049
249.11465
7.20 0
100000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 8.1824 +/-
Component name: 5,7,2',5'-Tetrahydroxy- 0.0285 minutes : Drift Times: 4.23 +/- 0.24 ms
flavone
0
287.05699
0 5 10 15 20
Retention time [min]

Intensity [Counts]
5e5

288.06069
258.05264
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1093 : DT=9.59 to 10.07 ms

Cimicifugic acid B
1250 8.17

1000
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.1828 +/- 0.0285
Channel name: Cimicifugic acid B [+H] : (39.7 PPM) 449.1093 Component name: Cimicifugic acid B minutes : Drift Times: 9.82 +/- 0.24 ms
7.49
80000 595.16764
8.18 100000

Intensity [Counts]
60000
Intensity [Counts]

50000

40000 287.05663 596.17127


449.10929
7.19 683.40052
868.44344
0
20000 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 8.1828 +/- 0.0285
Component name: Cimicifugic acid B minutes : Drift Times: 9.66 +/- 0.24 ms
2.22 5.60
0 287.05699

0 5 10 15 20
Retention time [min] 2e5

Intensity [Counts] 100000 503.02938


649.08927
288.06070
862.24811 957.19551
191.14286
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bilindestenolide [+H] : (39.7 PPM) 459.2536 : DT=5.83 to 6.31 ms
7.81
10000

7500
Intensity [Counts]

5000

2500

16.59
7.94
7.03 9.16
6.92 12.72
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.1876 +/- 0.0285
Channel name: Bilindestenolide [+H] : (39.7 PPM) 459.2536 Component name: Bilindestenolide minutes : Drift Times: 6.07 +/- 0.24 ms
15000 7.81
287.05664

12500 3e5

Intensity [Counts]
10000 2e5
Intensity [Counts]

7500
100000
288.06049 457.24382
266.12031
5000 558.17040 748.88858 895.24704
0
200 400 600 800 1000
2500 16.59 Item name: MENGKUDU 2 Channel name: High energy : Time 8.1876 +/- 0.0285
13.74 Component name: Bilindestenolide minutes : Drift Times: 5.91 +/- 0.24 ms
7.03 10.32 14.82
6.92
0 287.05699

0 5 10 15 20 3e5
Retention time [min]

Intensity [Counts]
2e5

100000
288.06070
457.24098 597.06499
165.01909
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Trachelosperoside E-1 [+H] : (39.7 PPM) 683.4005 : DT=9.40 to 9.88
ms

Trachelosperoside E-1
8.21

750
Intensity [Counts]

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.2104 +/- 0.0285
Channel name: Trachelosperoside E-1 [+H] : (39.7 PPM) 683.4005 Component name: Trachelosperoside E-1 minutes : Drift Times: 9.57 +/- 0.24 ms
13.65
596.17127

30000
16.49 287.05663

Intensity [Counts]
3000 7.99

8.21 20000
Intensity [Counts]

503.24959
2000 16.74
13.53 10000
683.40052
450.11268 993.30779
8.43
684.40335
13.94
9.03 0
1000 15.03 200 400 600 800 1000
9.37
7.40 9.71 16.81 Item name: MENGKUDU 2 Channel name: High energy : Time 8.2104 +/-
Component name: Trachelosperoside E-1 0.0285 minutes : Drift Times: 9.42 +/- 0.24 ms
6.52 16.97
5.34
0 525.23440

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

10000 450.11509
133.10268

633.11948 867.43511
175.04021
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Galloyloxypaeoniflorin [+H] : (39.7 PPM) 649.1779 : DT=7.20 to 7.68
ms

600
Galloyloxypaeoniflorin
8.24
8.68
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.2400 +/- 0.0285
Channel name: Galloyloxypaeoniflorin [+H] : (39.7 PPM) 649.1779 Component name: Galloyloxypaeoniflorin minutes : Drift Times: 7.44 +/- 0.24 ms
8.24
501.14098
2500 8.11 8.39
20000

Intensity [Counts]
3.76 685.17334
2000
687.26118
371.20702 503.24991
Intensity [Counts]

3.94 10000 709.28160


1500
8.49 729.29709
4.36 6.78
8.63 352.13955 751.26635
1000 3.53 4.41 9.08
4.58 337.09639
2.81 10.11 0
3.37 9.24 13.64 200 400 600 800 1000
500 1.27 14.35
Item name: MENGKUDU 2 Channel name: High energy : Time 8.2400 +/-
14.82 18.52 Component name: Galloyloxypaeoniflorin 0.0285 minutes : Drift Times: 7.28 +/- 0.24 ms

0 369.09905

0 5 10 15 20 423.11000
7500
Retention time [min] 469.04227

Intensity [Counts]
617.27771
5000 352.13589
193.05062 333.07689 659.28764
686.25554
2500
763.18904

851.22965
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1916 : DT=5.24 to 5.72 ms

1500

1000
Intensity [Counts]

8.25
Picrasin G
8.33
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.3177 +/- 0.0285 minutes :
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1916 Component name: Picrasin G Drift Times: 5.48 +/- 0.24 ms
5.75
11.66 393.19162
7500 425.12575
2500
9.67 351.17406
9.49

Intensity [Counts]
9.72 306.10023
5000
2000
237.10123 557.16805
Intensity [Counts]

573.15571
1500 218.09504
8.71 2500 785.30426
209.15420 695.69251
5.41
8.66 883.15870
1000 8.26
7.76 0
5.12 16.58 200 400 600 800 1000
13.44
500 3.55 16.67
13.54 Item name: MENGKUDU 2 Channel name: High energy : Time 8.3177 +/- 0.0285 minutes :
1.54 3.36 18.48 Component name: Picrasin G Drift Times: 5.33 +/- 0.24 ms

0 278.11749

0 5 10 15 20 217.09157
Retention time [min] 10000

Intensity [Counts]
350.10489
370.13327

5000 215.03490 442.12474 541.21443


204.06708
557.16871

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6′-O-β-D-Glucosyl gentiopicroside [+H] : (39.7 PPM) 519.1725 :
DT=6.08 to 6.56 ms

800

600
Intensity [Counts]

6′-O-β-D-Glucosyl gentiopicroside
8.34
400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.3277 +/-
Channel name: 6′-O-β-D-Glucosyl gentiopicroside [+H] : (39.7 PPM) 519.1725 Component name: 6′-O-β-D-Glucosyl 0.0285 minutes : Drift Times: 6.32 +/- 0.24 ms
9.00 gentiopicroside
3000 7.54
432.17766
100000

Intensity [Counts]
7.46
2000
Intensity [Counts]

50000

8.34
7.40 503.20726
2.93 4.54 14.33 387.20247
6.90 10.9511.71 13.45 209.15441 556.16767 798.21192
1000 2.63 975.26236
9.39 0
200 400 600 800 1000
2.48 16.49
2.06 Item name: MENGKUDU 2 Channel name: High energy : Time 8.3277 +/-
16.56 Component name: 6′-O-β-D-Glucosyl 0.0285 minutes : Drift Times: 6.16 +/- 0.24 ms
16.61 gentiopicroside
0
525.23489
0 5 10 15 20
Retention time [min] 432.17986
50000

Intensity [Counts]
545.15088
25000
415.15093

133.10270 292.07153 720.10841849.22149


634.14194
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Roseoside_1 [+H] : (39.7 PPM) 387.2025 : DT=6.24 to 6.72 ms

1250

1000
8.64
Intensity [Counts]

750

Roseoside_1
500
8.33

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.3335 +/- 0.0285 minutes :
Channel name: Roseoside_1 [+H] : (39.7 PPM) 387.2025 Component name: Roseoside_1 Drift Times: 6.48 +/- 0.24 ms
8.63
525.23236
10000

75000

Intensity [Counts]
7500 559.23227
50000
Intensity [Counts]

433.17932

5000 5.70 25000 371.20765

339.11284 687.14276
798.21192 871.20959
5.62
0
2500 5.42 200 400 600 800 1000
8.41 16.58
5.15 Item name: MENGKUDU 2 Channel name: High energy : Time 8.3335 +/- 0.0285
8.34 10.04 Component name: Roseoside_1 minutes : Drift Times: 6.33 +/- 0.24 ms
2.47 4.69 10.12 14.92 16.95

0 525.23489

0 5 10 15 20
Retention time [min] 50000

Intensity [Counts]
545.15088
25000
503.21070
133.10270
547.27419
292.07153
585.26692 725.06810
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganosporeric acid A [+H] : (39.7 PPM) 527.2641 : DT=6.35 to 6.83
ms

30000
Intensity [Counts]

20000

10000

8.22 Ganosporeric acid A


0 8.36
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.3517 +/- 0.0285
Channel name: Ganosporeric acid A [+H] : (39.7 PPM) 527.2641 Component name: Ganosporeric acid A minutes : Drift Times: 6.59 +/- 0.24 ms
8.73
559.23227

50000 40000

Intensity [Counts]
40000 523.21224
8.84
Intensity [Counts]

20000
30000
513.18856
575.19261
387.20247 842.20880
20000 215.03699 687.14276
0
200 400 600 800 1000
10000 Item name: MENGKUDU 2 Channel name: High energy : Time 8.3517 +/- 0.0285
Component name: Ganosporeric acid A minutes : Drift Times: 6.44 +/- 0.24 ms

0 545.15088

0 5 10 15 20 527.13932 559.23826
Retention time [min]

Intensity [Counts]
20000

369.10034
10000 265.08719 525.22925
442.12493 615.27218
264.08160
634.14170

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Galloyloxypaeoniflorin [+H] : (39.7 PPM) 649.1769 : DT=6.86 to 7.34
ms

600

400
Intensity [Counts]

Galloyloxypaeoniflorin
8.37

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.3716 +/- 0.0285
Channel name: Galloyloxypaeoniflorin [+H] : (39.7 PPM) 649.1769 Component name: Galloyloxypaeoniflorin minutes : Drift Times: 7.10 +/- 0.24 ms
8.24
571.14636
2500 8.11 8.39
75000
369.09893

Intensity [Counts]
3.76 543.11565
2000 351.08774
50000
Intensity [Counts]

3.94 267.06651
1500
8.49 583.10889
25000
4.36 6.78
8.63 239.07002 619.28398 811.23093
387.10855
1000 3.53 4.41 8.66 990.75016
4.58 10.11 13.64 0
3.37 9.24 200 400 600 800 1000
11.63
500 1.27 11.86
14.35 Item name: MENGKUDU 2 Channel name: High energy : Time 8.3716 +/-
14.82 18.52 Component name: Galloyloxypaeoniflorin 0.0285 minutes : Drift Times: 6.94 +/- 0.24 ms

0 75000 351.08820

0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

319.08599
263.07234
25000
215.03493 572.15096 689.30071
561.20902 883.16203
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5-O-Benzoyl-20-deoxyingenol [+H] : (39.7 PPM) 437.2310 : DT=5.86
to 6.34 ms

3000
Intensity [Counts]

2000

1000

5-O-Benzoyl-20-deoxyingenol
8.37
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.3800 +/-
Channel name: 5-O-Benzoyl-20-deoxyingenol [+H] : (39.7 PPM) 437.2310 Component name: 5-O-Benzoyl-20- 0.0285 minutes : Drift Times: 6.10 +/- 0.24 ms
6.40 deoxyingenol
8000
417.15639

20000 515.13720
11.24

Intensity [Counts]
6000
11.17 319.06062
Intensity [Counts]

11.52 10000
521.16545
4000
295.09752 603.08156
849.21128
10.76 205.06914
863.21059
0
2000 8.00 200 400 600 800 1000
16.58
10.60 11.83 Item name: MENGKUDU 2 Channel name: High energy : Time 8.3800 +/-
16.67
Component name: 5-O-Benzoyl-20- 0.0285 minutes : Drift Times: 5.94 +/- 0.24 ms
5.50 11.99 18.49
3.48 deoxyingenol
0
175.04026
0 5 10 15 20 20000
Retention time [min]
497.12965

Intensity [Counts]
417.15949
10000
323.09328
528.13725
572.15074
675.09517 867.18942

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Galloyloxypaeoniflorin [+H] : (39.7 PPM) 649.1766 : DT=8.65 to 9.13
ms

500 8.23 Galloyloxypaeoniflorin


8.39

400
Intensity [Counts]

300

200

8.53

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Galloyloxypaeoniflorin
8.34
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.3885 +/- 0.0285
Channel name: Galloyloxypaeoniflorin [+H] : (39.7 PPM) 649.1766 Component name: Galloyloxypaeoniflorin minutes : Drift Times: 8.87 +/- 0.24 ms
8.24
571.14630 846.26878
2500 8.11 8.39 20000

811.23104

Intensity [Counts]
3.76
2000
Intensity [Counts]

10000
3.94 531.14956 649.17656
1500 319.05997 888.20120
8.49 797.21647
4.36 6.78 977.39845
8.63 527.13980 669.13221
3.53 4.41 309.07784
1000 8.66
10.84 0
4.58
3.37 9.24
11.63 200 400 600 800 1000
500 1.27 10.87
14.35 Item name: MENGKUDU 2 Channel name: High energy : Time 8.3885 +/-
14.82 18.52 Component name: Galloyloxypaeoniflorin 0.0285 minutes : Drift Times: 8.72 +/- 0.24 ms

0 205.05106
571.14658
0 5 10 15 20 369.09967
15000
Retention time [min] 417.15954

Intensity [Counts]
10000

204.06744
5000
681.16659 884.16587 985.31973

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Genkwadaphnin [+H] : (39.7 PPM) 603.2207 : DT=6.69 to 7.17 ms

1500
Intensity [Counts]

1000

7.69
500
6.39
Genkwadaphnin
8.42

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.3984 +/- 0.0285
Channel name: Genkwadaphnin [+H] : (39.7 PPM) 603.2207 Component name: Genkwadaphnin minutes : Drift Times: 6.93 +/- 0.24 ms
8.92
369.09893

2500 351.08774 559.23340


50000 543.11565

Intensity [Counts]
8.76
319.06062
2000
8.69
Intensity [Counts]

267.06651 511.08933
25000 583.10889
1500 8.66 9.21 619.28398
239.07002 621.29197
7.69 10.47 12.23
811.23093
1000 219.10530 982.25454
5.73
0
1.66 5.64
13.18 200 400 600 800 1000
5.22
500 13.44
4.54 Item name: MENGKUDU 2 Channel name: High energy : Time 8.3984 +/- 0.0285
14.51
Component name: Genkwadaphnin minutes : Drift Times: 6.78 +/- 0.24 ms
18.53

0 75000 351.08820

0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000
291.06734
263.07234
183.08188
25000
165.06994
546.25941
687.29441 883.16203
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1899 : DT=5.33 to 5.81 ms

1500
Intensity [Counts]

1000

8.33
8.30
Picrasin G
500 8.40

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.4044 +/- 0.0285 minutes :
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1899 Component name: Picrasin G Drift Times: 5.57 +/- 0.24 ms
11.66
369.09895
2500 9.67
9.49
5.75
9.72 40000

Intensity [Counts]
2000
Intensity [Counts]

436.17140
1500 20000
8.71 263.07226
8.66
239.07006
5.41 8.26 543.11538
1000 235.07386 708.16662 777.24961
7.76 0
5.14 16.58 200 400 600 800 1000
7.00 13.44
500 3.55 16.67
13.54 Item name: MENGKUDU 2 Channel name: High energy : Time 8.4044 +/- 0.0285 minutes :
3.36 18.48 Component name: Picrasin G Drift Times: 5.42 +/- 0.24 ms
2.73
351.08816
0 263.07235
30000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
235.07432
20000

404.14677
10000 195.08022

189.07166 451.16664
721.33094
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2017 : DT=6.12 to 6.60 ms

1250

1000
8.63
Intensity [Counts]

750
8.33

500

ApocynosideⅠ
8.40
250 7.67 8.79

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.4056 +/- 0.0285
Channel name: ApocynosideⅠ [+H] : (39.7 PPM) 387.2017 Component name: ApocynosideⅠ minutes : Drift Times: 6.36 +/- 0.24 ms
8.63
10000 545.14988

40000

Intensity [Counts]
7500
Intensity [Counts]

20000
5000 5.70 319.06062

211.17097 687.14277 849.21128


5.62
0
2500 5.42 200 400 600 800 1000
8.41 16.58
5.15 Item name: MENGKUDU 2 Channel name: High energy : Time 8.4056 +/- 0.0285
7.65 10.04
16.95 Component name: ApocynosideⅠ minutes : Drift Times: 6.20 +/- 0.24 ms
2.47 4.69 10.12 14.92
0 319.08584

0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
544.25063
541.22290
275.07255
10000
247.07593
587.10519
223.07736 821.34382
721.32997
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Roseoside_1 [+H] : (39.7 PPM) 387.2009 : DT=6.46 to 6.94 ms

1250

1000 8.64
Intensity [Counts]

8.61
750

8.34
500

Roseoside_1
8.30 8.45
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.4454 +/- 0.0285 minutes :
Channel name: Roseoside_1 [+H] : (39.7 PPM) 387.2009 Component name: Roseoside_1 Drift Times: 6.70 +/- 0.24 ms
8.63
10000 559.23340

Intensity [Counts]
40000
7500 545.25702
544.24526
Intensity [Counts]

527.23426
20000
5000 5.70 565.14794
387.20089 582.24546
329.07054 854.21445
5.62
0
2500 5.42 200 400 600 800 1000
8.41 16.58
5.15 10.04 Item name: MENGKUDU 2 Channel name: High energy : Time 8.4454 +/- 0.0285
7.65
Component name: Roseoside_1 minutes : Drift Times: 6.54 +/- 0.24 ms
4.69 10.12 14.92 16.95

0 209.15410
546.15021
0 5 10 15 20
4000 105.07041 508.24909
Retention time [min]

Intensity [Counts]
493.16584 565.14781
839.35305
323.13767
2000
855.22996

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Melianol [+H] : (39.7 PPM) 613.3419 : DT=6.69 to 7.17 ms

Melianol
8.52

3000
Intensity [Counts]

2000

1000
8.36

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.5217 +/- 0.0285 minutes :
Channel name: Melianol [+H] : (39.7 PPM) 613.3419 Component name: Melianol Drift Times: 6.94 +/- 0.24 ms
8.52
571.14638

4000 4e5

Intensity [Counts]
Intensity [Counts]

3000
2e5

2000 613.34188
655.14185
16.58 370.10151 883.16020
0
200 400 600 800 1000
1000 16.67
8.36 14.54 Item name: MENGKUDU 2 Channel name: High energy : Time 8.5217 +/- 0.0285 minutes :
8.13 16.97
9.93 14.33 Component name: Melianol Drift Times: 6.79 +/- 0.24 ms
5.85
0 613.34418
30000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000 147.04492 559.23725
557.16985

10000 614.34465
257.06536 397.14007 721.10985
848.72096
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅲ [+H] : (39.7 PPM) 539.1740 : DT=7.46 to 7.94 ms

Picroside Ⅲ
8.56

300
Intensity [Counts]

200

8.66
100 8.70

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.5631 +/- 0.0285 minutes :
Channel name: Picroside Ⅲ [+H] : (39.7 PPM) 539.1740 Component name: Picroside Ⅲ Drift Times: 7.70 +/- 0.24 ms
3.56
15000 615.15217
2.52 649.22600
2500
721.24484

Intensity [Counts]
10000 587.18890
2000 758.22338
Intensity [Counts]

769.28654
432.17807
1500 5000
5.69 802.22680
3.72 8.61 205.05142 417.15863
8.73 370.10094 956.30664
5.61 8.57
1000 14.37 351.08709
7.81 8.76 0
9.06
1.76 13.32 200 400 600 800 1000
500 1.72 14.42 16.53
Item name: MENGKUDU 2 Channel name: High energy : Time 8.5631 +/- 0.0285 minutes :
14.85 18.52 Component name: Picroside Ⅲ Drift Times: 7.54 +/- 0.24 ms
17.71
0 417.15303

0 5 10 15 20
177.05568 257.06511 443.09792
Retention time [min]

Intensity [Counts]
5000
523.21474

783.34450
649.23198
2500
865.20199

868.17863
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2124 : DT=5.53 to 6.02 ms
8.24

8.20

750 9.02
13.51
7.14
Intensity [Counts]

5.25 7.10
500
5.80
9.15 12.99 13.63 16.53

3.38 4.81 13.69


10.21
250
3.16 14.03 16.69

1.69 2.51 16.82


0.72 17.03
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.5652 +/- 0.0285
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2124 Component name: Cichorioside C minutes : Drift Times: 5.78 +/- 0.24 ms
8.24
13.64
423.15740
1250 8.21 8.94 13.51 75000

9.02

Intensity [Counts]
1000 9.06
7.14 50000
9.15 13.01
5.80 13.69
Intensity [Counts]

16.53
750
5.25
25000 444.13028
5.09 9.60 11.63 16.60 363.12817 461.16017
4.81
500 240.07404 823.27961
474.14463 705.19521
3.99 14.51 16.63 0
3.17 16.69 200 400 600 800 1000
250 2.51 17.08
0.96 Item name: MENGKUDU 2 Channel name: High energy : Time 8.5652 +/- 0.0285
Component name: Cichorioside C minutes : Drift Times: 5.62 +/- 0.24 ms

0 423.15545
30000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
455.22960

177.05418 402.17642
10000

162.05706 459.12143 605.28432

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Catalpol [+H] : (39.7 PPM) 363.1282 : DT=5.40 to 5.88 ms

1250

1000
Intensity [Counts]

750

500

250 Catalpol
8.55

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.5712 +/- 0.0285 minutes :
Channel name: Catalpol [+H] : (39.7 PPM) 363.1282 Component name: Catalpol Drift Times: 5.64 +/- 0.24 ms
9.06
5000 423.15740
75000
369.09828
4000

Intensity [Counts]
50000 267.06645
Intensity [Counts]

3000 239.07202

4.90 12.04 25000


3.13
2000 9.82 13.44 429.21235
205.05082 621.29287
555.15749
3.78 9.89 13.74 0
8.77 200 400 600 800 1000
6.74 14.04
1000 1.83 7.62
Item name: MENGKUDU 2 Channel name: High energy : Time 8.5712 +/- 0.0285 minutes :
14.42
14.86 Component name: Catalpol Drift Times: 5.49 +/- 0.24 ms

0 423.15545
30000 183.08151
0 5 10 15 20
Retention time [min] 319.08878

Intensity [Counts]
20000

177.05383
10000
427.19652
443.19205
434.18076
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6-Feruloyl catalpol [+H] : (39.7 PPM) 523.1822 : DT=8.61 to 9.10 ms
6-Feruloyl catalpol
8.59

300
Intensity [Counts]

8.78
200
9.08

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.5819 +/- 0.0285
Channel name: 6-Feruloyl catalpol [+H] : (39.7 PPM) 523.1822 Component name: 6-Feruloyl catalpol minutes : Drift Times: 8.85 +/- 0.24 ms
6.39
621.29267

15000
15000

Intensity [Counts]
10000 849.23981
Intensity [Counts]

319.06076 523.18225 872.19797


10000 823.27907
5000 810.26527 880.08521
485.20055
8.58 763.22462
205.05143
8.92 0
5000
200 400 600 800 1000
6.91 10.41 Item name: MENGKUDU 2 Channel name: High energy : Time 8.5819 +/- 0.0285
5.89
11.43 12.32 14.47 Component name: 6-Feruloyl catalpol minutes : Drift Times: 8.69 +/- 0.24 ms
3.21 4.63
0 319.09595
10000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
432.17908
5000
603.28429
835.24754
247.07529 786.20715 918.33938

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bruceine E_1 [+H] : (39.7 PPM) 413.1822 : DT=5.27 to 5.75 ms

8.71

1000

Bruceine E_1
750 8.64
Intensity [Counts]

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.6230 +/- 0.0285 minutes :
Channel name: Bruceine E_1 [+H] : (39.7 PPM) 413.1822 Component name: Bruceine E_1 Drift Times: 5.51 +/- 0.24 ms
8.71
2000 403.17717

1.5e5
8.66

Intensity [Counts]
402.17115
1500
100000
373.21952
Intensity [Counts]

1000 50000 337.19685


8.87
229.05270 407.17507
4.09 5.38 6.20
8.00 9.25 12.75 13.56 16.50 211.04333 557.16907 688.23425
0
4.84 14.40 16.60
500 200 400 600 800 1000
3.34
16.75 Item name: MENGKUDU 2 Channel name: High energy : Time 8.6230 +/- 0.0285
2.22
16.98 Component name: Bruceine E_1 minutes : Drift Times: 5.35 +/- 0.24 ms

0 337.19637

0 5 10 15 20
50000
Retention time [min]

Intensity [Counts]
319.18751 403.17653

25000 213.08132
195.07079

428.14631
675.21100
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2195 : DT=5.21 to 5.69
ms
Blumenol C glucoside
8.63

7500
Intensity [Counts]

5000

2500

8.84

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.6294 +/- 0.0285
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2195 Component name: Blumenol C glucoside minutes : Drift Times: 5.46 +/- 0.24 ms
8.85
8.73 403.17717

8.64 1.5e5
15000

Intensity [Counts]
402.17115

100000
373.21952
Intensity [Counts]

10000
50000 337.19685

229.05270 407.17507
211.04333 557.16907 707.73411
0
5000
200 400 600 800 1000
8.93 Item name: MENGKUDU 2 Channel name: High energy : Time 8.6294 +/- 0.0285
8.01 Component name: Blumenol C glucoside minutes : Drift Times: 5.31 +/- 0.24 ms
9.27
11.62 13.69 16.62
0 337.19637

0 5 10 15 20
50000
Retention time [min]

Intensity [Counts]
319.18751 403.17653

25000 213.08132
195.07079

428.14631
593.19018
469.14586
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ulmoside [+H] : (39.7 PPM) 509.1871 : DT=6.76 to 7.24 ms

600

500

400
Intensity [Counts]

300 Ulmoside
8.65
9.28
200
9.37

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.6397 +/- 0.0285 minutes :
Channel name: Ulmoside [+H] : (39.7 PPM) 509.1871 Component name: Ulmoside Drift Times: 7.00 +/- 0.24 ms
6.11
1250 7.41 517.14127

7.70 630.21795

2.22 6.80 20000


10.90

Intensity [Counts]
1000 631.16596
1.90 10.84
387.20582 669.13166
11.85 13.39
Intensity [Counts]

0.49 290.10247
750 4.56 12.37
4.33 10000

3.78 287.05708
13.79 670.13848
848.27656
500 1.84 14.01 691.19175
14.91 0
200 400 600 800 1000
250 18.32
17.44 Item name: MENGKUDU 2 Channel name: High energy : Time 8.6397 +/- 0.0285 minutes :
Component name: Ulmoside Drift Times: 6.85 +/- 0.24 ms

0 290.10320
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
205.05020 308.11384
513.18602 630.21765
185.05932
631.21022 859.20821
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Chloranthalactone F [+H] : (39.7 PPM) 457.2409 : DT=5.70 to 6.18
ms
7.26

5000

4000
7.56
6.93
Intensity [Counts]

7.64
3000

Chloranthalactone F
8.65
2000
8.98

1000 9.10
6.68

6.23
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.6578 +/- 0.0285
Channel name: Chloranthalactone F [+H] : (39.7 PPM) 457.2409 Component name: Chloranthalactone F minutes : Drift Times: 5.93 +/- 0.24 ms
7.25
75000 405.16841

7.56

Intensity [Counts]
6000 50000
6.93 7.65
Intensity [Counts]

457.24092

4000 25000 462.14146


8.66
393.18552
8.98 471.17064
195.06883 266.10575 537.16053
775.85411 846.25801
0
2000 200 400 600 800 1000
6.69 10.61 Item name: MENGKUDU 2 Channel name: High energy : Time 8.6578 +/- 0.0285
11.10 16.51
Component name: Chloranthalactone F minutes : Drift Times: 5.78 +/- 0.24 ms
6.60 14.51
2.894.08
0 405.16790
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
361.14008
20000 457.24220
267.06854

227.03566
471.22030
489.17998
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sonchuside A [+H] : (39.7 PPM) 413.2177 : DT=5.71 to 6.19 ms

600

400 8.70
Intensity [Counts]

Sonchuside A
8.66

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.6640 +/- 0.0285
Channel name: Sonchuside A [+H] : (39.7 PPM) 413.2177 Component name: Sonchuside A minutes : Drift Times: 5.95 +/- 0.24 ms
4.93
75000 405.16841
1250
4.90

9.34

Intensity [Counts]
1000 50000

8.24 9.40 16.59


Intensity [Counts]

13.61 457.24092
750 5.09 9.52 13.67 25000
7.29 9.74 13.02 16.66 393.18552
16.51
4.81 10.04 353.19489 473.18465
500 6.54 13.88 846.25801
16.36 16.96 211.04343 623.16413 775.85411
2.98 0
2.78 200 400 600 800 1000
17.27
250 2.74
17.88 Item name: MENGKUDU 2 Channel name: High energy : Time 8.6640 +/- 0.0285
2.15 Component name: Sonchuside A minutes : Drift Times: 5.79 +/- 0.24 ms

0 405.16790
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
361.14008
20000 457.24220
267.06854

471.22030
227.03566
489.17998
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: m-Isopropyltoluene [+H] : (39.7 PPM) 135.1165 : DT=6.18 to 6.66
ms
8.71
m-Isopropyltoluene
8.69
400

300
Intensity [Counts]

200
8.64

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7002 +/- 0.0285
Channel name: m-Isopropyltoluene [+H] : (39.7 PPM) 135.1165 Component name: m-Isopropyltoluene minutes : Drift Times: 6.42 +/- 0.24 ms
1250 8.73
373.22153
10.62
8.68
559.18509
6.83 100000
1000

Intensity [Counts]
511.27318
12.43 211.17052
9.22
12.39
Intensity [Counts]

750 6.29
50000
16.52 561.18548
13.72 193.16118
16.61 573.16708
500 8.63
5.93 834.25097
7.09 727.70679
14.91 0
5.52
8.21 16.68 200 400 600 800 1000
250 5.41
1.80 16.76 Item name: MENGKUDU 2 Channel name: High energy : Time 8.7002 +/- 0.0285
5.06 Component name: m-Isopropyltoluene minutes : Drift Times: 6.26 +/- 0.24 ms

0 527.24861

0 5 10 15 20 5e5
Retention time [min]

Intensity [Counts]
2.5e5

528.25235
211.17020 427.14269
135.11800 559.18590 722.22934
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bruceine E_1 [+H] : (39.7 PPM) 413.1806 : DT=5.44 to 5.92 ms
Bruceine E_1
1250 8.71

1000

8.64
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7100 +/- 0.0285 minutes :
Channel name: Bruceine E_1 [+H] : (39.7 PPM) 413.1806 Component name: Bruceine E_1 Drift Times: 5.68 +/- 0.24 ms
8.71
2000
20000 312.08501

8.66 427.14329
15000

Intensity [Counts]
1500

10000
Intensity [Counts]

445.18325
1000 268.07185
9.25 5000 582.13261
109.03677 702.21748 871.11746
4.09 6.20 8.00 9.77 12.75 13.56
16.52
5.89 0
500 3.34 14.40 16.60
200 400 600 800 1000
2.87 16.75 Item name: MENGKUDU 2 Channel name: High energy : Time 8.7100 +/- 0.0285
2.06 Component name: Bruceine E_1 minutes : Drift Times: 5.52 +/- 0.24 ms
17.13

0 411.16970
7500
0 5 10 15 20
Retention time [min]
265.08736 428.14668

Intensity [Counts]
5000 219.08416
203.08279
117.03332 460.12599
2500
541.22057 667.23371

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1891 : DT=5.32 to 5.80 ms

1500

Picrasin G
8.70
Intensity [Counts]

1000
8.63

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7109 +/- 0.0285 minutes :
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1891 Component name: Picrasin G Drift Times: 5.60 +/- 0.24 ms
11.66
376.13863
2500 9.67
9.49
30000
9.72

Intensity [Counts]
2000
5.75 312.08501
20000
Intensity [Counts]

427.14329
1500 267.06735
8.62
8.30 10000 445.18325
204.06886
8.26 582.13261
1000 109.03677 871.11746
5.41 7.76
0
5.30 7.00 13.44 16.58 200 400 600 800 1000
500 5.14 4.39 16.67
13.54 Item name: MENGKUDU 2 Channel name: High energy : Time 8.7109 +/- 0.0285 minutes :
17.04 18.48 Component name: Picrasin G Drift Times: 5.45 +/- 0.24 ms
3.36
3.24
0 411.16970
7500
116.04979
0 5 10 15 20
Retention time [min]
265.08736 428.14668

Intensity [Counts]
5000

2500 437.13731
541.22057 667.23371

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderenic acid F [+H] : (39.7 PPM) 511.2684 : DT=6.40 to 6.88 ms

Ganoderenic acid F
8.73
5000

4000
8.84
Intensity [Counts]

3000

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7111 +/- 0.0285
Channel name: Ganoderenic acid F [+H] : (39.7 PPM) 511.2684 Component name: Ganoderenic acid F minutes : Drift Times: 6.64 +/- 0.24 ms
8.73
527.24707

7500 8.84 5e5

Intensity [Counts]
Intensity [Counts]

5000 2.5e5

373.22153 543.22983
211.17052 559.18509
590.23900 841.20956
0
2500
12.94 200 400 600 800 1000
12.87 13.17 Item name: MENGKUDU 2 Channel name: High energy : Time 8.7111 +/- 0.0285
5.54 7.22 7.96 16.60 Component name: Ganoderenic acid F minutes : Drift Times: 6.49 +/- 0.24 ms
12.59
4.37 16.65
0 527.24861

0 5 10 15 20 5e5
Retention time [min]

Intensity [Counts]
2.5e5

211.17020
427.14269 559.18590
135.11800 722.22934
603.27163
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderenic acid F [+H] : (39.7 PPM) 511.2739 : DT=8.55 to 9.03 ms

600 Ganoderenic acid F


8.72

400
Intensity [Counts]

8.85

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7120 +/- 0.0285
Channel name: Ganoderenic acid F [+H] : (39.7 PPM) 511.2739 Component name: Ganoderenic acid F minutes : Drift Times: 8.79 +/- 0.24 ms
8.73
527.24704

8.84 40000
7500

Intensity [Counts]
Intensity [Counts]

20000 910.32011
5000
543.11468 896.35719
511.27385
290.10321 557.17260 832.35825
501.23118
0
2500 200 400 600 800 1000
12.87
Item name: MENGKUDU 2 Channel name: High energy : Time 8.7120 +/- 0.0285
5.54 7.22 7.96 12.99 16.51
Component name: Ganoderenic acid F minutes : Drift Times: 8.64 +/- 0.24 ms
12.57 14.18
0 559.18589
427.14268
0 5 10 15 20
Retention time [min] 40000

Intensity [Counts] 20000


193.15968 373.22365
308.11392
848.27063 912.32781
655.15260
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderenic acid F [+H] : (39.7 PPM) 511.2732 : DT=6.34 to 6.82 ms

6000 Ganoderenic acid F


8.73

5000
8.84

4000
Intensity [Counts]

3000

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7211 +/- 0.0285
Channel name: Ganoderenic acid F [+H] : (39.7 PPM) 511.2732 Component name: Ganoderenic acid F minutes : Drift Times: 6.57 +/- 0.24 ms
8.73
527.24707

8.84 5e5
7500

Intensity [Counts]
Intensity [Counts]

5000 2.5e5

267.06725 373.22153 543.22983


559.18509
211.17052
834.76354
0
2500 200 400 600 800 1000
12.87
Item name: MENGKUDU 2 Channel name: High energy : Time 8.7211 +/- 0.0285
5.54 7.22 7.96 12.94 16.51 Component name: Ganoderenic acid F minutes : Drift Times: 6.42 +/- 0.24 ms
12.57
4.37
0 527.24861

0 5 10 15 20 5e5
Retention time [min]

Intensity [Counts]
2.5e5

211.17020
427.14269 559.18590
135.11800
631.09798
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Physalin K (Physalin Q) [+H] : (39.7 PPM) 559.1853 : DT=8.00 to 8.48
ms
Physalin K (Physalin Q)
8.73

3000
Intensity [Counts]

2000

8.85

1000
8.62
8.94

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7246 +/- 0.0285
Channel name: Physalin K (Physalin Q) [+H] : (39.7 PPM) 559.1853 Component name: Physalin K (Physalin Q) minutes : Drift Times: 8.23 +/- 0.24 ms
8.73
20000 505.26531
8.84

75000

Intensity [Counts]
15000 559.18529
50000 789.33581
Intensity [Counts]

10000 25000 761.22236


376.13878 790.33869
759.37164 845.19446
308.11467
0
5000 200 400 600 800 1000

8.51 9.50 Item name: MENGKUDU 2 Channel name: High energy : Time 8.7246 +/-
Component name: Physalin K (Physalin Q) 0.0285 minutes : Drift Times: 8.07 +/- 0.24 ms
3.12 5.26 6.15 10.89
16.49
1.83
0 75000 559.18590

0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000
427.14278

25000 267.06813
561.18592
344.02230 603.28339
263.07259
827.22655
983.72624
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2215 : DT=6.17 to 6.65
ms
Blumenol C glucoside
8000 8.73

6000
Intensity [Counts]

4000

8.84

2000

8.93
8.52
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04
Blumenol C glucoside
8.72
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7247 +/- 0.0285
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2215 Component name: Blumenol C glucoside minutes : Drift Times: 6.40 +/- 0.24 ms
8.85
8.73 373.22153

8.64 559.18509
15000 100000

Intensity [Counts]
511.27318
211.17052
Intensity [Counts]

50000
10000
561.18548
193.16118
573.16708
804.79535 870.15604
0
5000
200 400 600 800 1000
8.93 Item name: MENGKUDU 2 Channel name: High energy : Time 8.7247 +/- 0.0285
8.01 Component name: Blumenol C glucoside minutes : Drift Times: 6.25 +/- 0.24 ms
9.27
11.6213.19 16.61
0 527.24861

0 5 10 15 20 5e5
Retention time [min]

Intensity [Counts]
2.5e5

211.17020 528.25235
135.11800
427.14269
559.18590 722.22934
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yadanzioside P [+H] : (39.7 PPM) 711.2862 : DT=7.95 to 8.43 ms

200
8.87

150
Intensity [Counts]

Yadanzioside P
8.73
100

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7423 +/- 0.0285
Channel name: Yadanzioside P [+H] : (39.7 PPM) 711.2862 Component name: Yadanzioside P minutes : Drift Times: 8.19 +/- 0.24 ms
4.75
505.26531
2000
75000

Intensity [Counts]
559.18529
1500 50000 789.33581
Intensity [Counts]

8.85
11.13
3.42
12.14 25000 790.33869
1000 10.97 373.22297 759.37164
16.53 757.37951 793.34653
8.62 9.55 12.27 308.11467
6.03 7.73 13.19 16.61 0
6.69 15.24 200 400 600 800 1000
500 2.68
Item name: MENGKUDU 2 Channel name: High energy : Time 8.7423 +/- 0.0285
16.73
1.81 18.47 Component name: Yadanzioside P minutes : Drift Times: 8.04 +/- 0.24 ms

0 75000 559.18590

0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000
427.14278

25000 267.06813
561.18592
603.28339
239.07096 881.38555
719.22309 809.17348
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2230 : DT=8.07 to 8.55
ms

8.85

1500

8.80
Blumenol C glucoside
8.74
Intensity [Counts]

1000

8.68

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7455 +/- 0.0285
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2230 Component name: Blumenol C glucoside minutes : Drift Times: 8.31 +/- 0.24 ms
8.85
8.73 505.26531

75000
8.64
15000

Intensity [Counts]
559.18529
50000 789.33581
Intensity [Counts]

10000
25000 790.33869
373.22297 759.37164
757.37951 845.19446
308.11467
0
5000
200 400 600 800 1000
8.93 Item name: MENGKUDU 2 Channel name: High energy : Time 8.7455 +/- 0.0285
8.01 Component name: Blumenol C glucoside minutes : Drift Times: 8.15 +/- 0.24 ms
9.27
16.61
11.6213.19
0 75000 559.18590

0 5 10 15 20 527.24864
Retention time [min]

Intensity [Counts]
50000
427.14278

25000 267.06813
351.08811
239.07096 568.24703
827.22655 914.33315
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1890 : DT=5.33 to 5.81 ms

1500

Picrasin G
8.70
Intensity [Counts]

1000
8.63

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7546 +/- 0.0285 minutes :
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1890 Component name: Picrasin G Drift Times: 5.57 +/- 0.24 ms
11.66
427.14329
2500 15000
9.67 383.20686
9.49
9.72 369.09751

Intensity [Counts]
2000 10000
5.75 267.06735 432.12615
445.18325
Intensity [Counts]

1500 525.10678 597.03417


8.62 5000
8.30
760.22746
1000 8.26
5.41 7.76
0
5.30 7.00 13.44 16.58 200 400 600 800 1000
500 5.14 4.39 16.67
13.54 Item name: MENGKUDU 2 Channel name: High energy : Time 8.7546 +/- 0.0285 minutes :
17.04 18.48 Component name: Picrasin G Drift Times: 5.41 +/- 0.24 ms
3.36
3.24
0 15000 351.08807

0 5 10 15 20 408.23650
Retention time [min]

Intensity [Counts]
10000

263.07265
239.07067
5000 183.08227
513.28070

553.05812
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Catalpol [+H] : (39.7 PPM) 363.1287 : DT=5.18 to 5.66 ms

2500

2000
Intensity [Counts]

1500

1000

500
Catalpol
8.77
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7550 +/- 0.0285 minutes :
Channel name: Catalpol [+H] : (39.7 PPM) 363.1287 Component name: Catalpol Drift Times: 5.42 +/- 0.24 ms
9.06
5000 351.08683
20000

427.14329

Intensity [Counts]
4000
543.11411
267.06735
Intensity [Counts]

10000
3000 211.17058
12.04 597.03417
4.90
3.13 9.82
2000 13.44 686.22313
10.32
3.78 13.74 0
8.77 10.53 200 400 600 800 1000
6.74 14.04
1000 1.83 Item name: MENGKUDU 2 Channel name: High energy : Time 8.7550 +/- 0.0285 minutes :
14.42
14.86 Component name: Catalpol Drift Times: 5.27 +/- 0.24 ms

0 15000 351.08807

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000

263.07265
239.07067
385.22053
5000 183.08227
437.13731
543.11283

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone O [+H] : (39.7 PPM) 573.2348 : DT=6.99 to 7.47 ms

600
Intensity [Counts]

Nigakilactone O
400 8.76

8.42

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.7649 +/- 0.0285
Channel name: Nigakilactone O [+H] : (39.7 PPM) 573.2348 Component name: Nigakilactone O minutes : Drift Times: 7.23 +/- 0.24 ms
6.45
603.28204

2000 100000

Intensity [Counts]
583.10808
Intensity [Counts]

1500
50000

11.97 13.48
5.40 8.02 8.76 568.24163
1000 5.30 641.17957
13.79 205.05110 308.11465 535.27551 840.71479
4.54 14.02 16.52 0
200 400 600 800 1000
500 4.35 16.63
4.19 Item name: MENGKUDU 2 Channel name: High energy : Time 8.7649 +/- 0.0285
3.67 Component name: Nigakilactone O minutes : Drift Times: 7.07 +/- 0.24 ms
18.54

0 603.28312

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
568.24712
167.07016 242.11677 689.30376
545.21507
10000
352.09341

690.30539 862.69609
871.12790
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: GrayanotoxinⅠ [+H] : (39.7 PPM) 415.2308 : DT=5.51 to 5.99 ms

600

9.05
500
GrayanotoxinⅠ
8.84
400 9.12
Intensity [Counts]

8.78
8.76
300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8268 +/- 0.0285
Channel name: GrayanotoxinⅠ [+H] : (39.7 PPM) 415.2308 Component name: GrayanotoxinⅠ minutes : Drift Times: 5.75 +/- 0.24 ms
16.58
444.13046

1250
40000
427.14388

Intensity [Counts]
1000
12.39 16.50
417.15524 455.22736
Intensity [Counts]

9.05 11.96 20000


750 16.85 411.16445
8.77 9.12 524.23384
409.18418
11.46
5.95
8.61 9.22 15.81 17.01 215.08485 375.19406 694.33378 768.73451
500 12.52
5.59 10.57 0
8.31
12.66 17.21 200 400 600 800 1000
4.02 5.22 17.56
250 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8268 +/- 0.0285
2.99
Component name: GrayanotoxinⅠ minutes : Drift Times: 5.59 +/- 0.24 ms

0 427.14426

0 5 10 15 20
Retention time [min] 20000 205.05057

Intensity [Counts]
419.17741
411.16794

10000
135.11765 375.19854 524.23640

633.13119
694.33562
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Paeonidanin [+H] : (39.7 PPM) 495.1870 : DT=9.19 to 9.68 ms

Paeonidanin
8.83

400

300
Intensity [Counts]

8.75
200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8344 +/- 0.0285 minutes :
Channel name: Paeonidanin [+H] : (39.7 PPM) 495.1870 Component name: Paeonidanin Drift Times: 9.43 +/- 0.24 ms
9.20
527.24802
5000

8.84 12.94
40000

Intensity [Counts]
4000
Intensity [Counts]

3000 20000 505.26443


373.22315 867.43219
683.40066
2000 10.60 529.15610 773.34770
9.95
0
11.72
4.70 6.30 200 400 600 800 1000
8.60
1000 3.25 5.65
4.30 13.52 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8344 +/- 0.0285
16.50
Component name: Paeonidanin minutes : Drift Times: 9.28 +/- 0.24 ms
2.34 18.54
0 527.24935

0 5 10 15 20
75000
Retention time [min]

Intensity [Counts]
50000

25000 545.15113
211.17033 511.27660
373.22435 673.17635 867.43779
119.08662
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2232 : DT=4.71 to 5.19
ms

8.63
500
Blumenol C glucoside
8.84
400
Intensity [Counts]

300

200

8.95
100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8351 +/- 0.0285
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2232 Component name: Blumenol C glucoside minutes : Drift Times: 4.96 +/- 0.24 ms
8.85
8.73 559.18518
20000
524.23354

8.64
15000

Intensity [Counts]
Intensity [Counts]

10000
427.14325
10000 272.10870 561.18794
264.08748 571.21766
235.08279 652.13889
0
5000
200 400 600 800 1000
8.93 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8351 +/- 0.0285
8.01 Component name: Blumenol C glucoside minutes : Drift Times: 4.81 +/- 0.24 ms
9.27
16.61
11.6213.19
0 7500 427.14484

0 5 10 15 20
Retention time [min] 543.22957

Intensity [Counts]
5000 411.16865

266.13808
190.05251 559.18607
2500 119.04983
561.18765
837.86349

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Harpagoside [+H] : (39.7 PPM) 495.1860 : DT=6.07 to 6.55 ms

3000
Harpagoside
8.84
Intensity [Counts]

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8400 +/- 0.0285 minutes :
Channel name: Harpagoside [+H] : (39.7 PPM) 495.1860 Component name: Harpagoside Drift Times: 6.31 +/- 0.24 ms
9.20
100000 465.16761
5000
559.18514
8.84 12.94
75000

Intensity [Counts]
4000

50000
Intensity [Counts]

373.22316
3000

25000
211.16964
2000 10.59 205.05285 369.19045 570.20766 776.86898 883.35688
9.95
11.72 0
4.70 6.30 200 400 600 800 1000
8.60
1000 3.25 5.65
4.30 6.80 13.52 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8400 +/- 0.0285
16.50
Component name: Harpagoside minutes : Drift Times: 6.16 +/- 0.24 ms
2.34 18.54
0 427.14426 527.13884
0 5 10 15 20
40000
Retention time [min]

Intensity [Counts]
559.18688

20000
211.17038
570.21106
737.32167 899.37463
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Crocin A [+H] : (39.7 PPM) 977.3871 : DT=8.80 to 9.28 ms

4000

3000
Intensity [Counts]

2000

1000

Crocin A
0 8.84
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8404 +/- 0.0285 minutes :
Channel name: Crocin A [+H] : (39.7 PPM) 977.3871 Component name: Crocin A Drift Times: 9.04 +/- 0.24 ms
9.20
962.28284
6000 20000

Intensity [Counts]
844.24681
Intensity [Counts]

4000 10000

843.33469
506.27201
8.06 326.24417 819.23250

2000 0
200 400 600 800 1000
7.59 9.45 11.26
13.73 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8404 +/- 0.0285 minutes :
10.34 Component name: Crocin A Drift Times: 8.89 +/- 0.24 ms
0.44 5.43 6.91 16.52
4.04 18.53
0 427.14424

0 5 10 15 20
15000
Retention time [min]

Intensity [Counts]
205.05079 373.22435
495.18617
10000

175.14909 543.22859
5000
698.19443 984.25480

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Physalin K (Physalin Q) [+H] : (39.7 PPM) 559.1851 : DT=7.76 to 8.24
ms
2500
8.73

2000 Physalin K (Physalin Q)


8.67 8.85
Intensity [Counts]

1500

1000

500
8.54

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8405 +/- 0.0285
Channel name: Physalin K (Physalin Q) [+H] : (39.7 PPM) 559.1851 Component name: Physalin K (Physalin Q) minutes : Drift Times: 8.01 +/- 0.24 ms
8.73
20000
8.84 373.22315

40000

Intensity [Counts]
15000
559.18514
Intensity [Counts]

20000

10000 374.22637
340.14038 731.29740
823.24584
211.16964
887.12594
0
5000 200 400 600 800 1000

8.51 9.50 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8405 +/-
3.12 5.26 6.15 10.90 Component name: Physalin K (Physalin Q) 0.0285 minutes : Drift Times: 7.86 +/- 0.24 ms
1.83 16.49
0 427.14424

0 5 10 15 20
559.18684
Retention time [min] 20000

Intensity [Counts] 10000 561.18751


119.08657
257.06644 689.29022 764.33786 855.17391

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2232 : DT=9.37 to 9.85
ms

Blumenol C glucoside
8.84

600
Intensity [Counts]

8.75
400

8.72

8.68
8.97
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8411 +/- 0.0285
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2232 Component name: Blumenol C glucoside minutes : Drift Times: 9.60 +/- 0.24 ms
8.85
8.73 527.24802

8.64
15000 40000

Intensity [Counts]
Intensity [Counts]

10000 20000 505.26443


373.22315 867.43219
683.40066
529.15610
765.32888
0
5000
200 400 600 800 1000
8.93 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8411 +/- 0.0285
8.01 Component name: Blumenol C glucoside minutes : Drift Times: 9.44 +/- 0.24 ms
9.27
16.61
11.6213.19
0 527.24935

0 5 10 15 20
75000 O
Retention time [min]

Intensity [Counts]
O O

O O
O

50000 O

211.17033
25000
Mass error: 1.1 mDa 543.22975
135.11765 673.17635 867.43779
417.15691
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Pseudoionone [+H] : (39.7 PPM) 193.1603 : DT=3.57 to 4.05 ms

Pseudoionone
8.83
8.73
600
Intensity [Counts]

8.94
400

200
8.67

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8417 +/- 0.0285
Channel name: Pseudoionone [+H] : (39.7 PPM) 193.1603 Component name: Pseudoionone minutes : Drift Times: 3.81 +/- 0.24 ms
8.73
193.16029

2500 8.84 7500 175.14915

Intensity [Counts]
2000 5000
Intensity [Counts]

9.28
10.61 218.08175
1500
2500 109.10108 243.08127 559.18530
349.15653
1000
8.53 0
5.54 200 400 600 800 1000
11.20
500 5.47 8.37 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8417 +/- 0.0285
16.57
13.36 Component name: Pseudoionone minutes : Drift Times: 3.66 +/- 0.24 ms
4.90 8.01 15.52
3.24
16.76
0
2000 291.13120
0 5 10 15 20 175.14921
Retention time [min]

Intensity [Counts]
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2232 : DT=6.24 to 6.72
ms
8000 8.73

6000
Intensity [Counts]

4000
Blumenol C glucoside
8.84

2000

8.94
8.52
9.21
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8439 +/- 0.0285
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2232 Component name: Blumenol C glucoside minutes : Drift Times: 6.45 +/- 0.24 ms
8.85
8.73 527.24802
3e5

8.64
15000

Intensity [Counts]
2e5
Intensity [Counts]

10000 559.18514
100000
373.22316 511.27485
211.16964 563.18293 717.22210
940.81993
0
5000
200 400 600 800 1000
8.93 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8439 +/- 0.0285
8.01 Component name: Blumenol C glucoside minutes : Drift Times: 6.29 +/- 0.24 ms
9.27
16.61
11.6213.19
0 527.24932

0 5 10 15 20
Retention time [min] 2e5

Intensity [Counts] 100000


528.25284
211.17038 427.14426
559.18688 737.32167
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2231 : DT=8.53 to 9.01
ms

Blumenol C glucoside
8.85

1500
Intensity [Counts]

8.73
1000

500
8.93
8.64
9.02

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8445 +/- 0.0285
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2231 Component name: Blumenol C glucoside minutes : Drift Times: 8.77 +/- 0.24 ms
8.85
8.73 30000 373.22311

8.64 527.13780
15000

Intensity [Counts]
20000 559.18521

802.30988
Intensity [Counts]

898.31261
10000 10000
374.22621 774.35888
755.32992
294.09923
0
5000
200 400 600 800 1000
8.93 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8445 +/- 0.0285
8.01 Component name: Blumenol C glucoside minutes : Drift Times: 8.62 +/- 0.24 ms
9.27
16.61
11.6213.19
0 559.18684

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

193.16052
373.22435
10000
205.05079 543.22859
855.18144
175.14909
737.32012 984.25480

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2232 : DT=7.00 to 7.48
ms
Blumenol C glucoside
8.85
2500

2000
Intensity [Counts]

8.73

1500

1000

500 8.63
8.95

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8460 +/- 0.0285
Channel name: Blumenol C glucoside [+H] : (39.7 PPM) 373.2232 Component name: Blumenol C glucoside minutes : Drift Times: 7.20 +/- 0.24 ms
8.85
8.73 373.22315

8.64 40000
15000

Intensity [Counts]
Intensity [Counts]

20000 505.26463
10000
374.22632 619.18688
211.16970
826.17150
653.13686
928.25381
0
5000
200 400 600 800 1000
8.93 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8460 +/- 0.0285
8.01 Component name: Blumenol C glucoside minutes : Drift Times: 7.05 +/- 0.24 ms
9.27
16.61
11.6213.19
0 135.11774

0 5 10 15 20 10000
524.23662
Retention time [min]

Intensity [Counts]
560.18951
499.16442
181.05612
5000 435.17093
647.20070
689.21782
857.32727

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Trachelosperoside E-1 [+H] : (39.7 PPM) 683.4007 : DT=9.31 to 9.79
ms

1000

750

9.03
Intensity [Counts]

500
Trachelosperoside E-1
8.86

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8603 +/- 0.0285
Channel name: Trachelosperoside E-1 [+H] : (39.7 PPM) 683.4007 Component name: Trachelosperoside E-1 minutes : Drift Times: 9.56 +/- 0.24 ms
13.65
527.24802

16.49
40000

Intensity [Counts]
3000 7.99

8.21
Intensity [Counts]

20000 505.26443
2000 16.74
13.53 373.22315 867.43219
8.43 845.45329
529.15610
13.94 683.40066
9.03 0
1000 15.03 200 400 600 800 1000
9.37
7.40 9.71 16.81 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8603 +/-
Component name: Trachelosperoside E-1 0.0285 minutes : Drift Times: 9.40 +/- 0.24 ms
6.52 16.97
5.34
0 527.24935

0 5 10 15 20 O

75000
Retention time [min]
H

Intensity [Counts]
O
O
O
O O H

O O

50000 O

O
O
O

211.17033
25000
Mass error: 1.1 mDa 511.27660
135.11765 529.15785 867.43779
417.15691
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside A [+H] : (39.7 PPM) 539.2496 : DT=6.67 to 7.15 ms

400

9.11
300
Intensity [Counts]

Picrasinoside A
8.87
200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.8777 +/- 0.0285
Channel name: Picrasinoside A [+H] : (39.7 PPM) 539.2496 Component name: Picrasinoside A minutes : Drift Times: 6.91 +/- 0.24 ms
7.65 16.51
14.90 617.19921
1000 16.56
5.71
30000
8.87
6.04 13.07

Intensity [Counts]
9.41 16.61
750 524.22964
14.78 20000
11.44
Intensity [Counts]

6.85

10000 374.22632
500 5.54
340.14026 512.27166 633.28632
5.24 294.09890
776.86904 955.43930
16.71
5.15 0
250 3.67 16.86 200 400 600 800 1000
2.69 Item name: MENGKUDU 2 Channel name: High energy : Time 8.8777 +/- 0.0285
2.65 Component name: Picrasinoside A minutes : Drift Times: 6.75 +/- 0.24 ms

15000 205.05109
0
0 5 10 15 20
Retention time [min] 294.09964

Intensity [Counts]
10000
529.15677
175.14905
541.21687
5000 546.15033
109.10202 647.20070
775.27897

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bruceine I [+H] : (39.7 PPM) 437.1790 : DT=5.69 to 6.17 ms

30000
Intensity [Counts]

20000

10000

Bruceine I
8.89
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.9019 +/- 0.0285 minutes :
Channel name: Bruceine I [+H] : (39.7 PPM) 437.1790 Component name: Bruceine I Drift Times: 5.93 +/- 0.24 ms
10.98
497.12846
523.21927
60000
20000 453.20318

Intensity [Counts]
425.13267
411.16064
Intensity [Counts]

40000 390.13526
10000
353.11709
11.37 907.31426
222.07712 592.18766 791.71584

20000 0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 8.9019 +/- 0.0285 minutes :
Component name: Bruceine I Drift Times: 5.77 +/- 0.24 ms
7.07 16.58
0 176.07051

0 5 10 15 20
10000 391.14140
Retention time [min]

Intensity [Counts]
406.13795
354.14058

5000 216.06607 433.17407


470.17043

474.17714

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Asperulosidic acid [+H] : (39.7 PPM) 433.1358 : DT=5.93 to 6.41 ms

6000
Intensity [Counts]

4000

2000

Asperulosidic acid
8.90
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.9037 +/- 0.0285
Channel name: Asperulosidic acid [+H] : (39.7 PPM) 433.1358 Component name: Asperulosidic acid minutes : Drift Times: 6.17 +/- 0.24 ms
3.06
491.24738
10000
40000

Intensity [Counts]
497.12846
7500 432.17754
523.21927
Intensity [Counts]

20000
425.13267
2.27
5000 390.13526
531.16333
294.09896 907.31426
7.50 662.19035 820.32372
8.23 281.04841
2.13 0
3.31 6.35
2500 200 400 600 800 1000

0.95 Item name: MENGKUDU 2 Channel name: High energy : Time 8.9037 +/- 0.0285
5.05 11.38 Component name: Asperulosidic acid minutes : Drift Times: 6.02 +/- 0.24 ms
8.92
11.45 13.96
16.59
0 491.24752
351.13407
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

175.03969
305.12750
492.25124
705.22081
547.14529
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2611 : DT=6.46 to 6.94
ms

600
Semiaquilegoside A
8.91
Intensity [Counts]

400

8.78

200 9.01

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.9139 +/- 0.0285
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2611 Component name: Semiaquilegoside A minutes : Drift Times: 6.69 +/- 0.24 ms
18.39
480.17882
2000 527.13913
100000

Intensity [Counts]
16.50
1500 16.61
Intensity [Counts]

16.44 50000 545.15046


18.32
16.17 557.25726
1000 8.91
10.87 16.11 434.12627 603.20795
12.91 340.14026 605.20191 875.25741
13.29 0
7.10 9.37
200 400 600 800 1000
500
7.05 Item name: MENGKUDU 2 Channel name: High energy : Time 8.9139 +/- 0.0285
3.28 4.65
Component name: Semiaquilegoside A minutes : Drift Times: 6.54 +/- 0.24 ms
1.48
0 525.23200

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000 205.05109 481.18011

603.20720
281.04812
160.04125 391.14402
616.13365

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Esculentoside O [+H] : (39.7 PPM) 635.3785 : DT=6.98 to 7.46 ms

750
Intensity [Counts]

500 Esculentoside O
8.96

8.83
250 9.06

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.9575 +/- 0.0285
Channel name: Esculentoside O [+H] : (39.7 PPM) 635.3785 Component name: Esculentoside O minutes : Drift Times: 7.22 +/- 0.24 ms
16.85
677.13404
2000 16.58

40000
657.36760

Intensity [Counts]
1500
Intensity [Counts]

20000 484.17337
709.07218
1000
223.06143 452.14647 743.25094
876.27924
8.96 16.99 0
500 200 400 600 800 1000
12.56 14.01
8.90
14.88 18.48 Item name: MENGKUDU 2 Channel name: High energy : Time 8.9575 +/- 0.0285
11.48
4.51 7.97 Component name: Esculentoside O minutes : Drift Times: 7.07 +/- 0.24 ms
5.65
3.58 4.30
0 677.13558

0 5 10 15 20 657.37018
30000
Retention time [min]

Intensity [Counts]
20000

145.02929
10000 452.14720
175.03989 687.29086 826.17395
613.26036
695.21417 915.23728
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone N [+H] : (39.7 PPM) 395.2048 : DT=8.28 to 8.76 ms
8.97
Nigakilactone N
8.99
400

300
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.9828 +/- 0.0285
Channel name: Nigakilactone N [+H] : (39.7 PPM) 395.2048 Component name: Nigakilactone N minutes : Drift Times: 8.52 +/- 0.24 ms
8.97
872.24590

6000
20000

Intensity [Counts]
854.23747
Intensity [Counts]

4000 674.17262 831.27771


10000 395.20478 894.22727

619.13301

2000 0
200 400 600 800 1000
9.91 10.76 Item name: MENGKUDU 2 Channel name: High energy : Time 8.9828 +/- 0.0285
7.18 13.54 16.76 Component name: Nigakilactone N minutes : Drift Times: 8.37 +/- 0.24 ms
2.33 3.02 5.40
16.98
0 7500 470.12998

0 5 10 15 20
Retention time [min]

Intensity [Counts]
424.10302
5000 674.16896 848.15043

368.11590
652.14781
216.98006
2500 777.27460

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Borneol 2-O-β-D-apiosyl-(16)-β-D-glucoside [+H] : (39.7 PPM)
449.2375 : DT=5.84 to 6.32 ms

1000

750
Intensity [Counts]

500 8.87

Borneol 2-O-β-D-apiosyl-(16)-β-D-…
250 8.99

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.9849 +/-
Channel name: Borneol 2-O-β-D-apiosyl-(16)-β-D-glucoside [+H] : (39.7 PPM) Component name: Borneol 2-O-β-D-apiosyl- 0.0285 minutes : Drift Times: 6.08 +/- 0.24 ms
449.2375 (16)-β-D-glucoside
13.68
457.24252
3000

Intensity [Counts]
20000

8.73
Intensity [Counts]

2000 448.15834 501.23463


10000
16.61 413.20969 517.16057
16.53 369.18828 562.23785 844.25305
10.73 781.20129
191.03533
11.30 0
1000 8.89
8.06 200 400 600 800 1000
9.99
6.55
7.42 14.92 Item name: MENGKUDU 2 Channel name: High energy : Time 8.9849 +/-
0.81 4.81
2.48 5.96 17.56 18.41 Component name: Borneol 2-O-β-D-apiosyl- 0.0285 minutes : Drift Times: 5.93 +/- 0.24 ms
(16)-β-D-glucoside
0
457.24370
0 5 10 15 20
Retention time [min] 191.03498
10000

Intensity [Counts]
439.24933
351.08859
5000 517.24020
165.05549

587.25100 709.07281 855.22314

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Loganic acid-6'-O-β-D-glucoside [+H] : (39.7 PPM) 539.1955 :
DT=6.37 to 6.85 ms

2500

2000
Intensity [Counts]

1500

1000

500 Loganic acid-6'-O-β-D-glucoside


9.00

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 8.9933 +/-
Channel name: Loganic acid-6'-O-β-D-glucoside [+H] : (39.7 PPM) 539.1955 Component name: Loganic acid-6'-O-β-D- 0.0285 minutes : Drift Times: 6.58 +/- 0.24 ms
5.96 glucoside
6.05
527.13840

4000 100000

Intensity [Counts]
5.90
Intensity [Counts]

3000
50000
519.19021
5.70 503.24985
14.37 529.15882
2000 3.56
257.06809
355.10255 872.24653
5.40 577.19750
2.53 7.98 8.60 0
5.35 6.67 9.00 200 400 600 800 1000
1000 14.18 16.58
9.50 Item name: MENGKUDU 2 Channel name: High energy : Time 8.9933 +/-
1.66
15.01 Component name: Loganic acid-6'-O-β-D- 0.0285 minutes : Drift Times: 6.42 +/- 0.24 ms
18.52 glucoside
0
545.15095
0 5 10 15 20 20000
519.19180
Retention time [min]

Intensity [Counts]
10000
289.09101
502.17498
133.10128

624.25330
819.26363
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone M [+H] : (39.7 PPM) 395.2070 : DT=5.74 to 6.22 ms

8.97

1000

8.91
750
Intensity [Counts]

500

250 Nigakilactone M
9.10

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.1018 +/- 0.0285
Channel name: Nigakilactone M [+H] : (39.7 PPM) 395.2070 Component name: Nigakilactone M minutes : Drift Times: 5.98 +/- 0.24 ms
8.97
455.22522

6000
40000

Intensity [Counts]
497.12812

426.12012
Intensity [Counts]

4000
20000

408.10848 589.18259 805.22068


376.08029 606.18263
293.08308 824.20210
2000 0
200 400 600 800 1000

9.92 10.76 13.54 Item name: MENGKUDU 2 Channel name: High energy : Time 9.1018 +/- 0.0285
7.18 16.57
3.02 5.40 Component name: Nigakilactone M minutes : Drift Times: 5.82 +/- 0.24 ms
2.58 16.79
0 455.22751
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
497.12988

20000
426.12161
204.06733
588.17446
363.13388
786.25020
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ulmoside [+H] : (39.7 PPM) 509.1861 : DT=6.21 to 6.69 ms

500

400
Intensity [Counts]

9.32

300 Ulmoside
9.17

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.1650 +/- 0.0285 minutes :
Channel name: Ulmoside [+H] : (39.7 PPM) 509.1861 Component name: Ulmoside Drift Times: 6.45 +/- 0.24 ms
6.11
1250 7.41 527.13860

7.70
2.22 6.80 10.90 100000

Intensity [Counts]
1000
10.84
0.49
Intensity [Counts]

11.85 495.19491
750 4.56 12.37
4.33 50000
476.18463
3.78
13.79 338.12452
543.11231
500 14.01 16.52 871.28955
1.84 238.10835 751.22921
16.61 0
16.46 200 400 600 800 1000
250 17.29 Item name: MENGKUDU 2 Channel name: High energy : Time 9.1650 +/- 0.0285 minutes :
Component name: Ulmoside Drift Times: 6.29 +/- 0.24 ms

0 527.13996

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
421.14275
135.11738
269.08236
528.14248
840.17022
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Rehmannioside D [+H] : (39.7 PPM) 687.2336 : DT=7.80 to 8.28 ms

2000
Intensity [Counts]

1500

1000 Rehmannioside D
9.22

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Rehmannioside D
9.17
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.2168 +/- 0.0285
Channel name: Rehmannioside D [+H] : (39.7 PPM) 687.2336 Component name: Rehmannioside D minutes : Drift Times: 8.04 +/- 0.24 ms
1.48
4000 4.34 503.24977

Intensity [Counts]
40000
3000
Intensity [Counts]

20000 338.12453
2000 8.61 687.23363 765.33528
287.05649 372.21125 526.23568
8.28 797.24603
3.78 9.22
11.12 0
1000 6.65 200 400 600 800 1000
2.94 5.11 11.62
13.45 Item name: MENGKUDU 2 Channel name: High energy : Time 9.2168 +/- 0.0285
14.36
Component name: Rehmannioside D minutes : Drift Times: 7.89 +/- 0.24 ms
16.15 18.52
0 287.05623

0 5 10 15 20 15000
Retention time [min]

Intensity [Counts]
10000
360.10665
175.04034

5000 371.20912 568.24544 737.31477


899.24998

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Rehmannioside D [+H] : (39.7 PPM) 687.2322 : DT=7.36 to 7.84 ms
1.48

1500

8.61
Intensity [Counts]

1000
4.34
8.27
3.78
3.74 7.87
500
6.92 8.82
2.94 5.11
10.02 12.30 13.41
13.45 16.49
18.52
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.2489 +/- 0.0285
Channel name: Rehmannioside D [+H] : (39.7 PPM) 687.2322 Component name: Rehmannioside D minutes : Drift Times: 7.66 +/- 0.24 ms
1.48
4000 4.34 503.24991

Intensity [Counts]
40000
3000
Intensity [Counts]

20000
2000 8.61
386.12555 643.21528 736.34202
799.21468
8.28 9.21 223.06175
3.78 372.21125
0
11.12
1000 6.64 200 400 600 800 1000
2.94 5.11 11.62
13.45 Item name: MENGKUDU 2 Channel name: High energy : Time 9.2489 +/- 0.0285
16.06 Component name: Rehmannioside D minutes : Drift Times: 7.51 +/- 0.24 ms
18.52
0 351.08823

0 5 10 15 20 15000
Retention time [min]

Intensity [Counts]
10000 211.17028

455.18449
5000 166.08629 514.17468 767.27923
798.21525

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Oxyphyllenodiol B [+H] : (39.7 PPM) 239.1646 : DT=6.13 to 6.62 ms
Oxyphyllenodiol B
600
9.28
9.25

500

9.17
400
Intensity [Counts]

300
9.02

200
8.97

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.2630 +/- 0.0285
Channel name: Oxyphyllenodiol B [+H] : (39.7 PPM) 239.1646 Component name: Oxyphyllenodiol B minutes : Drift Times: 6.38 +/- 0.24 ms
9.28
1250 455.18300

2e5

Intensity [Counts]
1000
9.20 371.20708
16.86
Intensity [Counts]

750 100000
9.49
9.12 557.16991
9.05 16.80 16.93 211.17105
500 13.70 618.14631 767.28016
16.51
13.54 0
200 400 600 800 1000
8.30 10.93
250
6.21 6.85 15.22 17.18 Item name: MENGKUDU 2 Channel name: High energy : Time 9.2630 +/- 0.0285
2.72
2.34 6.40 Component name: Oxyphyllenodiol B minutes : Drift Times: 6.22 +/- 0.24 ms
17.40

0 525.23380
3e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
2e5

100000
455.18429
193.16019
437.17314 545.15105 674.16737
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2217 : DT=5.44 to 5.92 ms

1000

750
Intensity [Counts]

500 Nigakilactone F
9.26

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.2664 +/- 0.0285
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2217 Component name: Nigakilactone F minutes : Drift Times: 5.68 +/- 0.24 ms
13.71
16.21 408.10677

2000 40000

Intensity [Counts]
5.42
Intensity [Counts]

1500
13.54 14.78 20000
8.73 16.53 401.20849
5.13
16.60 392.13222 453.20929
1000 11.98 283.06334 517.15598 713.18790 798.21161
9.95
5.76 16.66
8.34 0
7.91 16.88 200 400 600 800 1000
500
4.16 Item name: MENGKUDU 2 Channel name: High energy : Time 9.2664 +/- 0.0285
2.18 4.07 17.18
Component name: Nigakilactone F minutes : Drift Times: 5.52 +/- 0.24 ms
3.67
0 30000 408.10864

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
391.17992

351.08813
10000 409.14283
243.08608 417.14512
180.07945
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Onitin-2′-O-β-D-glucopyranoside [+H] : (39.7 PPM) 411.2003 :
DT=5.39 to 5.87 ms

2000

1500
Intensity [Counts]

8.97

1000 8.91

9.16
9.44
500
Onitin-2′-O-β-D-glucopyranoside
9.29

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.3059 +/-
Channel name: Onitin-2′-O-β-D-glucopyranoside [+H] : (39.7 PPM) 411.2003 Component name: Onitin-2′-O-β-D- 0.0285 minutes : Drift Times: 5.63 +/- 0.24 ms
3000 7.41 glucopyranoside

375.15607
100000
2500 7.37

Intensity [Counts]
2000 8.97
Intensity [Counts]

6.65
50000

1500
7.76 443.09831
2.74
5.80 9.85 371.20268 461.10717
5.33 827.22018
1000 725.06641
0
2.60 11.06 16.62
11.78 200 400 600 800 1000
13.48
500 16.98 Item name: MENGKUDU 2 Channel name: High energy : Time 9.3059 +/-
2.47 14.06
18.30 Component name: Onitin-2′-O-β-D- 0.0285 minutes : Drift Times: 5.47 +/- 0.24 ms
1.43 glucopyranoside
0
75000 375.15677
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

25000
329.15225 377.14929
91.05488
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Pterodontoside A [+H] : (39.7 PPM) 413.2158 : DT=5.54 to 6.03 ms

800

600

Pterodontoside A
Intensity [Counts]

9.31

400 9.34

9.41

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.3141 +/- 0.0285
Channel name: Pterodontoside A [+H] : (39.7 PPM) 413.2158 Component name: Pterodontoside A minutes : Drift Times: 5.78 +/- 0.24 ms
4.93
375.15607
1250 100000

9.34

Intensity [Counts]
1000
Intensity [Counts]

8.24 9.40 50000


13.61
750 16.59
5.09 9.52 13.67
7.29 16.66 443.09831
10.04 16.51
4.81 13.02 16.36 495.11334
500 6.54 175.14972 685.70602 827.22018
16.96 271.06074 571.14806
13.88
2.98 0
17.27 200 400 600 800 1000
250 2.78 Item name: MENGKUDU 2 Channel name: High energy : Time 9.3141 +/- 0.0285
2.52 17.71 Component name: Pterodontoside A minutes : Drift Times: 5.63 +/- 0.24 ms

0 75000 375.15677

0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

25000 437.17305

176.07090 245.10747 469.00915


641.19603
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: trans-Chrysanthenyl acetate [+H] : (39.7 PPM) 195.1375 : DT=3.70
to 4.18 ms
trans-Chrysanthenyl acetate
9.35
500

400 9.31
Intensity [Counts]

300

200 9.25

9.20
100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.3400 +/-
Channel name: trans-Chrysanthenyl acetate [+H] : (39.7 PPM) 195.1375 Component name: trans-Chrysanthenyl 0.0285 minutes : Drift Times: 3.95 +/- 0.24 ms
9.34 acetate
800
213.15137

13.68 20000

Intensity [Counts]
600
Intensity [Counts]

237.16903
97.06527
10000
400
13.71 16.63
6.60 248.09293
6.28 10.87 14.78 257.11817
0
200 5.82 7.79 16.86 200 400 600 800 1000

3.31 4.22 17.32 Item name: MENGKUDU 2 Channel name: High energy : Time 9.3400 +/-
0.61 3.18 Component name: trans-Chrysanthenyl 0.0285 minutes : Drift Times: 3.79 +/- 0.24 ms
18.24
acetate
0
237.16543
0 5 10 15 20
Retention time [min] 219.15591
4000

Intensity [Counts]
213.14752
119.08620
2000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3270 : DT=6.31 to 6.79 ms
Poricoic acid B
9.37

2500

2000 9.54
Intensity [Counts]

1500

1000
9.69

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Poricoic acid B
9.37
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.3743 +/- 0.0285
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3270 Component name: Poricoic acid B minutes : Drift Times: 6.51 +/- 0.24 ms
9.37
527.13833

6000 50000
480.17866

Intensity [Counts]
449.30674
8.07 467.31753
Intensity [Counts]

545.14750
4000 9.54 25000
421.31346
223.06275 318.13344 575.27699
860.28494
7.98 763.79144
9.69 0
2000
16.49 200 400 600 800 1000
11.03 Item name: MENGKUDU 2 Channel name: High energy : Time 9.3743 +/- 0.0285
12.63 13.66 16.66
7.24 Component name: Poricoic acid B minutes : Drift Times: 6.35 +/- 0.24 ms

0 480.17747
20000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
251.09628 501.20630
318.13659
10000 157.10157 527.24562
545.14828

556.24709
763.32273
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Poricoic acid E [+H] : (39.7 PPM) 501.3197 : DT=6.51 to 6.99 ms

1000

750 Poricoic acid E


9.40
Intensity [Counts]

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.3877 +/- 0.0285
Channel name: Poricoic acid E [+H] : (39.7 PPM) 501.3197 Component name: Poricoic acid E minutes : Drift Times: 6.66 +/- 0.24 ms
16.63
467.31753
485.32699
30000
15.09 501.19961
1500

Intensity [Counts]
545.14750
6.89
20000
9.39
Intensity [Counts]

16.88

1000
10000
575.27699
422.31683 860.28671
217.15836 763.79144
12.68
10.76 0
500 9.31 200 400 600 800 1000
16.99
6.70 Item name: MENGKUDU 2 Channel name: High energy : Time 9.3877 +/- 0.0285
2.76 Component name: Poricoic acid E minutes : Drift Times: 6.51 +/- 0.24 ms
3.89 6.37 17.17
2.68
0 501.20630
10000 482.14301 545.14828
0 5 10 15 20
Retention time [min] 157.10157
599.27062

Intensity [Counts]
467.31544

177.05618
5000
206.05249
616.28538
819.28712
733.33116

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Eclalbasaponin Ⅴ [+H] : (39.7 PPM) 715.3707 : DT=7.46 to 7.94 ms

2000

1500
Intensity [Counts]

1000

500 Eclalbasaponin Ⅴ
9.43

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.4331 +/- 0.0285
Channel name: Eclalbasaponin Ⅴ [+H] : (39.7 PPM) 715.3707 Component name: Eclalbasaponin Ⅴ minutes : Drift Times: 7.70 +/- 0.24 ms
13.69
633.29374

10000 10000

Intensity [Counts]
223.06177 757.27261
7500 626.17074
Intensity [Counts]

5000 767.21451
16.48 427.10368 617.27735
14.80
5000 13.53 369.10248 959.28317
14.91

0
200 400 600 800 1000
2500
Item name: MENGKUDU 2 Channel name: High energy : Time 9.4331 +/- 0.0285
Component name: Eclalbasaponin Ⅴ minutes : Drift Times: 7.55 +/- 0.24 ms
8.21 9.82 11.78
0 163.03979 417.15668

0 5 10 15 20
5000 206.05192 427.10150
Retention time [min]

Intensity [Counts]
351.08805 749.31046
559.16220 643.24545

2500 760.28263
873.28444

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1603 : DT=8.96 to 9.44 ms
9.78

9.71
300
Intensity [Counts]

Picroside Ⅱ
200 9.44 10.09

10.21

10.58
100 10.78

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.4377 +/- 0.0285 minutes :
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1603 Component name: Picroside Ⅱ Drift Times: 9.20 +/- 0.24 ms
9.79
10000 975.39042
6000
513.16026 926.25052
9.51
7500

Intensity [Counts]
919.26807
4000 5000 883.35854
Intensity [Counts]

859.25606
368.11462
10.02 2500
742.22562
223.06188
11.70
2000 0
2.31 4.54 5.32 200 400 600 800 1000
7.55
4.09 6.26 Item name: MENGKUDU 2 Channel name: High energy : Time 9.4377 +/- 0.0285 minutes :
0.58 12.70
13.19 16.55 Component name: Picroside Ⅱ Drift Times: 9.05 +/- 0.24 ms
15.22
0 545.14767

0 5 10 15 20 528.14341
7500
Retention time [min]

Intensity [Counts]
5000 828.23131
368.11545

509.25923 827.22550
2500 625.15872 856.32244
193.15981

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 2α-Acetoxycostic acid [+H] : (39.7 PPM) 293.1747 : DT=4.44 to 4.92
ms

3000

2000
Intensity [Counts]

1000 2α-Acetoxycostic acid


9.45

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.4565 +/- 0.0285
Channel name: 2α-Acetoxycostic acid [+H] : (39.7 PPM) 293.1747 Component name: 2α-Acetoxycostic acid minutes : Drift Times: 4.68 +/- 0.24 ms
10.04
4000 244.22904
10000

293.17469

Intensity [Counts]
3000
Intensity [Counts]

5000
351.17316
223.06188
2000 177.05652 522.71534 635.23790

0
1000 7.45 9.54 16.60
200 400 600 800 1000

6.86 9.38 12.49 Item name: MENGKUDU 2 Channel name: High energy : Time 9.4565 +/-
16.72
5.01 11.44 13.93 Component name: 2α-Acetoxycostic acid 0.0285 minutes : Drift Times: 4.52 +/- 0.24 ms
2.09 4.64 15.70
17.19
0 279.15914
10000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
244.22813
5000
319.09248
191.03461
350.12355
363.12358
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1602 : DT=8.54 to 9.03 ms
9.79
250 Picroside Ⅱ
9.47

10.21
200
10.26
10.47
Intensity [Counts]

150
10.69

100

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.4679 +/- 0.0285 minutes :
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1602 Component name: Picroside Ⅱ Drift Times: 8.79 +/- 0.24 ms
9.79
858.23763
6000
844.25397
9.51 696.17813
10000
926.25052

Intensity [Counts]
397.08170 832.36719
4000
Intensity [Counts]

5000 513.16016

10.02 205.05078
682.20663
11.70
2000 0
2.31
4.54 5.32 200 400 600 800 1000
7.55
4.09 6.26 Item name: MENGKUDU 2 Channel name: High energy : Time 9.4679 +/- 0.0285 minutes :
0.58 12.70
13.19 16.55 Component name: Picroside Ⅱ Drift Times: 8.63 +/- 0.24 ms
15.22
0 525.23376

0 5 10 15 20
Retention time [min] 10000

Intensity [Counts]
163.03978
5000 371.20733
559.15638
294.99013 838.31195

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1600 : DT=9.35 to 9.83 ms
Picroside Ⅱ
9.50

400

300
Intensity [Counts]

200

9.44

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.5015 +/- 0.0285 minutes :
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1600 Component name: Picroside Ⅱ Drift Times: 9.59 +/- 0.24 ms
9.79
525.23162
6000 20000

9.51

Intensity [Counts]
527.13885

4000
Intensity [Counts]

10000
513.16003

10.05 545.14655 945.42197


799.21479
11.70
2000 0
2.31
4.54 5.32 200 400 600 800 1000
7.55
4.09 6.26 Item name: MENGKUDU 2 Channel name: High energy : Time 9.5015 +/- 0.0285 minutes :
0.58 12.70
13.19 16.55 Component name: Picroside Ⅱ Drift Times: 9.44 +/- 0.24 ms
15.22 30000
0 525.23337

0 5 10 15 20
Retention time [min]

Intensity [Counts]
511.14550
20000

10000 588.17556
618.14981
211.17005 426.12108
371.20656 838.31335
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3280 : DT=6.28 to 6.76 ms
9.37

2500

Poricoic acid B
2000 9.54
Intensity [Counts]

1500

1000
9.69

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.5441 +/- 0.0285
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3280 Component name: Poricoic acid B minutes : Drift Times: 6.53 +/- 0.24 ms
9.37
60000 529.15399

6000

Intensity [Counts]
40000
8.07 352.11916
Intensity [Counts]

567.24197
4000 9.54
20000
569.25898
780.20066
7.98 335.18452 606.18040
982.32623
9.69
2000 0
16.49 200 400 600 800 1000
11.03 Item name: MENGKUDU 2 Channel name: High energy : Time 9.5441 +/- 0.0285
12.63 13.66 16.66
7.24 Component name: Poricoic acid B minutes : Drift Times: 6.37 +/- 0.24 ms
16.97
0 527.13954
40000 352.11968
0 5 10 15 20
Retention time [min]

Intensity [Counts]
513.15806
20000
567.24419

205.05119
568.24652
854.88541
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3-Hydroxy-12,14-diene-27-nordeane-28-nic acid [+H] : (39.7 PPM)
455.3163 : DT=6.22 to 6.70 ms

750
Intensity [Counts]

500

250 3-Hydroxy-12,14-diene-27-nordeane-28-nic acid


9.55

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.5488 +/-
Channel name: 3-Hydroxy-12,14-diene-27-nordeane-28-nic acid [+H] : (39.7 PPM) Component name: 3-Hydroxy-12,14- 0.0285 minutes : Drift Times: 6.46 +/- 0.24 ms
455.3163 diene-27-nordeane-28-nic acid
16.52
529.15399
1500
50000

Intensity [Counts]
12.61
12.56 352.11916
Intensity [Counts]

1000 567.24197
12.34 25000
3.93 12.68 16.62
9.55 12.26 569.25898
7.98
335.18452 606.18040
982.32623
13.52
500 9.72 0
14.08 16.91
200 400 600 800 1000
15.67
7.80 16.98 Item name: MENGKUDU 2 Channel name: High energy : Time 9.5488 +/-
2.42 Component name: 3-Hydroxy-12,14- 0.0285 minutes : Drift Times: 6.31 +/- 0.24 ms
1.55 5.09 7.71 17.36
diene-27-nordeane-28-nic acid
0
352.11968 527.13954
0 5 10 15 20 40000
Retention time [min]

Intensity [Counts]
513.15806
20000 567.24419
167.07142

568.24652
854.88541
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganolucidic acid B [+H] : (39.7 PPM) 503.3392 : DT=6.36 to 6.85 ms

4000

3000
Intensity [Counts]

2000

Ganolucidic acid B
1000 9.54
9.37

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.5504 +/- 0.0285
Channel name: Ganolucidic acid B [+H] : (39.7 PPM) 503.3392 Component name: Ganolucidic acid B minutes : Drift Times: 6.67 +/- 0.24 ms
16.86
60000 529.15399
6000

Intensity [Counts]
40000
16.61
352.11916
Intensity [Counts]

4000 567.24197
485.32798
8.07 20000
9.54 569.25898
339.10805
598.16872
224.06716 982.32623
2000 7.98
0
9.70 16.49 200 400 600 800 1000
13.69 Item name: MENGKUDU 2 Channel name: High energy : Time 9.5504 +/- 0.0285
7.24 15.61 17.00 Component name: Ganolucidic acid B minutes : Drift Times: 6.52 +/- 0.24 ms
12.26
17.72
0 527.13954
40000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
567.24419
353.12243 417.15596
205.05119
568.24652
854.88541
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Papyriogenin G [+H] : (39.7 PPM) 469.3332 : DT=6.49 to 6.97 ms

3000
Intensity [Counts]

2000

1000
Papyriogenin G
9.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.6110 +/- 0.0285
Channel name: Papyriogenin G [+H] : (39.7 PPM) 469.3332 Component name: Papyriogenin G minutes : Drift Times: 6.72 +/- 0.24 ms
13.68
601.28488
6000

2e5

Intensity [Counts]
Intensity [Counts]

4000
100000

585.31079 633.22156
16.50 239.07191 901.20358
351.08744 826.17126
2000 13.56 0
8.429.61 16.62 200 400 600 800 1000
12.37 14.10
7.90 9.74 16.91 Item name: MENGKUDU 2 Channel name: High energy : Time 9.6110 +/- 0.0285
14.83 Component name: Papyriogenin G minutes : Drift Times: 6.57 +/- 0.24 ms
6.07
7.11 17.51
0 601.28578

0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

50000 423.23703

421.22377 585.31474 617.26302


239.07392 653.13925
309.11463
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3β-Hydroxyurs-12-en-27,28-dioic acid [+H] : (39.7 PPM) 487.3409 :
DT=6.23 to 6.71 ms

12500

10000
Intensity [Counts]

7500

5000

2500

3β-Hydroxyurs-12-en-27,28-dioic acid
0 9.62
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.6162 +/-
Channel name: 3β-Hydroxyurs-12-en-27,28-dioic acid [+H] : (39.7 PPM) 487.3409 Component name: 3β-Hydroxyurs-12- 0.0285 minutes : Drift Times: 6.47 +/- 0.24 ms
16.86 en-27,28-dioic acid

512.14856
543.11242
20000
571.26758

Intensity [Counts]
Intensity [Counts]

15000 10000 506.18668


489.23658
13.68 233.08256 351.08744
576.21619
10000 901.20358
769.21341

0
200 400 600 800 1000
5000
Item name: MENGKUDU 2 Channel name: High energy : Time 9.6162 +/-
13.54 16.59
Component name: 3β-Hydroxyurs-12- 0.0285 minutes : Drift Times: 6.32 +/- 0.24 ms
8.429.62 12.37 en-27,28-dioic acid
0
529.15638
0 5 10 15 20
Retention time [min]

Intensity [Counts]
191.03516
10000 545.15123

309.11463
633.22013
653.13925

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Arnicolide D [+H] : (39.7 PPM) 333.1679 : DT=5.05 to 5.53 ms

1000

750
Intensity [Counts]

500

250 Arnicolide D
9.63

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.6391 +/- 0.0285 minutes :
Channel name: Arnicolide D [+H] : (39.7 PPM) 333.1679 Component name: Arnicolide D Drift Times: 5.29 +/- 0.24 ms
5.83
2000 20000 334.09363

367.21126
5.87
15000

Intensity [Counts]
1500
3.15 386.12456
14.80 10000
Intensity [Counts]

3.11 14.76 399.14723


299.11731 633.22192
1000 5.75 10.32 5000
265.09063 590.14603 635.22591
10.07
257.06708
9.63 10.53 13.43 16.59 682.21218
0
2.33 6.98 8.76 11.06 16.65 200 400 600 800 1000
500 3.76
2.23 16.69 Item name: MENGKUDU 2 Channel name: High energy : Time 9.6391 +/- 0.0285
18.54 Component name: Arnicolide D minutes : Drift Times: 5.14 +/- 0.24 ms
1.13

0 334.08925

0 5 10 15 20 367.21144
312.12630
Retention time [min]

Intensity [Counts]
288.08845
5000
167.06712 409.14105

413.18218
464.12877
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone H [+H] : (39.7 PPM) 425.2156 : DT=5.62 to 6.10 ms

4000

3000
Intensity [Counts]

2000

1000
Nigakilactone H
9.67

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.6706 +/- 0.0285
Channel name: Nigakilactone H [+H] : (39.7 PPM) 425.2156 Component name: Nigakilactone H minutes : Drift Times: 5.86 +/- 0.24 ms
16.71
452.14731
75000
10000
484.17318

Intensity [Counts]
50000
7500
Intensity [Counts]

422.17352
4.38
25000
5000 409.13612 485.17582
324.12716 633.22193 717.23443 871.28937
0
200 400 600 800 1000
2500
4.04 Item name: MENGKUDU 2 Channel name: High energy : Time 9.6706 +/- 0.0285
16.53
5.89 18.47 Component name: Nigakilactone H minutes : Drift Times: 5.71 +/- 0.24 ms
5.04 8.60 10.39 12.13 15.13 17.65
3.70
0 452.14816

0 5 10 15 20
20000 422.17280
Retention time [min]

Intensity [Counts]
324.12349
484.17390
10000
271.08862
191.03552 495.17677 650.14539
575.15765
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1896 : DT=5.31 to 5.79 ms
Picrasin G
9.49
9.67
1500
9.72
Intensity [Counts]

1000

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.6715 +/- 0.0285 minutes :
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1896 Component name: Picrasin G Drift Times: 5.57 +/- 0.24 ms
11.66
40000 360.13623
2500 9.67
9.49
9.72 30000

Intensity [Counts]
5.75
2000

20000
Intensity [Counts]

342.12365 393.18957
1500
8.71 409.13612
8.66 10000 323.23221
424.15481
8.30 717.23443 831.27690
1000 5.41 284.11787 515.11485
7.76 0
5.30 7.00 13.44 16.58 200 400 600 800 1000
500 5.14 4.39 16.67
13.54 Item name: MENGKUDU 2 Channel name: High energy : Time 9.6715 +/- 0.0285 minutes :
3.36 18.48 Component name: Picrasin G Drift Times: 5.42 +/- 0.24 ms
2.73
0 328.10939

0 5 10 15 20 10000 360.13603
Retention time [min]

Intensity [Counts]
385.22046

323.23427
389.13847
5000 310.10473
393.19041

423.17926

495.17677
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1589 : DT=9.18 to 9.66 ms

9.50

400 Picroside Ⅱ
9.78

300
Intensity [Counts]

200 9.44

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.7768 +/- 0.0285 minutes :
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1589 Component name: Picroside Ⅱ Drift Times: 9.42 +/- 0.24 ms
9.79
10000 529.15422
6000

9.51
7500

Intensity [Counts]
513.15895

4000 5000
Intensity [Counts]

991.33704

947.30658
10.05 2500 601.28257
821.32450
11.71
2000 0
2.31
4.54 5.32 200 400 600 800 1000
7.55
4.09
7.43 12.70 Item name: MENGKUDU 2 Channel name: High energy : Time 9.7768 +/- 0.0285 minutes :
0.58
13.19 15.91 Component name: Picroside Ⅱ Drift Times: 9.27 +/- 0.24 ms
16.47
0 10000 287.05679
513.15972
0 5 10 15 20
Retention time [min] 529.15636

Intensity [Counts]
5000

817.20212
383.17213 602.28397 865.41869
734.36096

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1594 : DT=6.21 to 6.69 ms
Picroside Ⅱ
4000
9.79

3000
Intensity [Counts]

2000
10.01
10.05

1000
9.66

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Picroside Ⅱ
0 9.79

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.7862 +/- 0.0285 minutes :
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1594 Component name: Picroside Ⅱ Drift Times: 6.46 +/- 0.24 ms
9.79
450.15668
6000

9.51 513.15942
50000

Intensity [Counts]
529.15354

4000
Intensity [Counts]

25000 541.15361

10.05
589.15840
11.70 285.07674 351.08856 810.17466
942.26647
2000 0
2.31
4.54 5.32 200 400 600 800 1000
7.55
4.09
12.70 Item name: MENGKUDU 2 Channel name: High energy : Time 9.7862 +/- 0.0285 minutes :
0.58
13.19 15.91 Component name: Picroside Ⅱ Drift Times: 6.31 +/- 0.24 ms
15.22
0 450.15812 513.15834
30000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
527.13900
20000 529.15651

406.16671

10000
289.08853
542.22218
190.05100 687.20329
586.27065
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Kansuinin D [+H] : (39.7 PPM) 794.3028 : DT=8.15 to 8.63 ms

400
Kansuinin D
9.87

300
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.8617 +/- 0.0285 minutes :
Channel name: Kansuinin D [+H] : (39.7 PPM) 794.3028 Component name: Kansuinin D Drift Times: 8.39 +/- 0.24 ms
3.79
2500 810.17512

40000

Intensity [Counts]
2000
Intensity [Counts]

1500 12.75 20000


811.17844
13.09 775.28235
833.29436
1000 9.87 529.15601 759.27665
7.65 8.65 398.07802 873.18640
5.04 13.54
7.43 11.17 0
7.39 13.77 200 400 600 800 1000
500 15.05
3.59 Item name: MENGKUDU 2 Channel name: High energy : Time 9.8617 +/- 0.0285 minutes :
16.59 Component name: Kansuinin D Drift Times: 8.23 +/- 0.24 ms
3.05
0 15000 600.13720

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000

397.07762
731.30881
5000 527.13564 823.19801 897.18937
139.04035
363.12387

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Curcolone [+H] : (39.7 PPM) 247.1333 : DT=3.94 to 4.42 ms
Curcolone
9.90

600
Intensity [Counts]

400

10.05
10.19
9.83
200
9.78

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.8993 +/- 0.0285 minutes :
Channel name: Curcolone [+H] : (39.7 PPM) 247.1333 Component name: Curcolone Drift Times: 4.18 +/- 0.24 ms
6.53
247.13329

1250
5000

Intensity [Counts]
1000
9.91
Intensity [Counts]

2500 231.13448
750
321.09546
808.77378
4.29 177.05476
7.81 336.14198
500 4.78
9.82 0
1.72 2.89 10.08
8.63 200 400 600 800 1000
10.19 13.04
250 1.33 16.58
13.27 Item name: MENGKUDU 2 Channel name: High energy : Time 9.8993 +/- 0.0285 minutes :
16.74 Component name: Curcolone Drift Times: 4.02 +/- 0.24 ms

0 247.13336

0 5 10 15 20 4000
Retention time [min]

Intensity [Counts]
2000 279.07755
220.09783
142.07991 502.16761

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2239 : DT=5.39 to 5.87 ms

800

600 Nigakilactone F
9.98
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 9.9810 +/- 0.0285
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2239 Component name: Nigakilactone F minutes : Drift Times: 5.63 +/- 0.24 ms
13.71
16.21 441.12637
15000
2000

Intensity [Counts]
407.16105
10000
5.42 389.17700
1500
Intensity [Counts]

13.54 14.78 205.05195


16.53 369.22411

16.60 5000 483.15656 747.32227 964.29530


5.13 8.73 361.17255
1000 5.09 8.71 639.18922
11.96 16.66
9.95
5.77 8.34 0
7.91 16.88 200 400 600 800 1000
500
4.16 Item name: MENGKUDU 2 Channel name: High energy : Time 9.9810 +/- 0.0285
4.07 17.18 Component name: Nigakilactone F minutes : Drift Times: 5.48 +/- 0.24 ms
3.66

0 383.16762

0 5 10 15 20
7500 407.16015
Retention time [min]

Intensity [Counts]
5000
409.18015
222.07753 747.32718 909.38202
456.22111
2500
622.17812

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Mudanpioside H [+H] : (39.7 PPM) 617.1856 : DT=7.27 to 7.75 ms

3000
Intensity [Counts]

2000

1000

Mudanpioside H
10.03
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.0311 +/- 0.0285
Channel name: Mudanpioside H [+H] : (39.7 PPM) 617.1856 Component name: Mudanpioside H minutes : Drift Times: 7.51 +/- 0.24 ms
8.17
20000 618.14760
6000

15000

Intensity [Counts]
3.44 658.13632
3.56 10000 669.22053
Intensity [Counts]

4000 8.87

615.25730 725.21514
5000
3.20 3.84 461.10944 813.21573
397.14065
12.18 204.06616 941.36193

2000 7.26 0
4.33 6.73 200 400 600 800 1000
10.04 12.92
1.241.84 6.04 Item name: MENGKUDU 2 Channel name: High energy : Time 10.0311 +/- 0.0285
16.49 Component name: Mudanpioside H minutes : Drift Times: 7.35 +/- 0.24 ms
13.40
18.53
0 177.05539
10000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
216.06667
5000 176.07127 589.17613 659.12750
767.25912
381.13748 460.12158
793.25164

797.32210
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 2β-Acetoxypterodontic acid [+H] : (39.7 PPM) 293.1730 : DT=4.51 to
4.99 ms
2β-Acetoxypterodontic acid
2500 10.04

2000
Intensity [Counts]

9.96
1500

1000

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.0501 +/-
Channel name: 2β-Acetoxypterodontic acid [+H] : (39.7 PPM) 293.1730 Component name: 2β-Acetoxypterodontic 0.0285 minutes : Drift Times: 4.75 +/- 0.24 ms
10.04 acid
4000
75000 293.17380

Intensity [Counts]
3000 50000
Intensity [Counts]

2000 25000

218.12054 309.07512 478.13352


0
1000 7.45 9.54 16.60
200 400 600 800 1000
9.38 12.49 Item name: MENGKUDU 2 Channel name: High energy : Time 10.0501 +/-
4.34 6.86 16.72
5.01 11.44 14.47 Component name: 2β-Acetoxypterodontic 0.0285 minutes : Drift Times: 4.60 +/- 0.24 ms
1.37 2.10 3.58
17.19 acid
0
293.17386
0 5 10 15 20
Retention time [min]
50000

Intensity [Counts] 25000

277.20031
145.02900 299.05192 432.17659
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3065 :
DT=6.49 to 6.97 ms

2000

1500
Intensity [Counts]

1000
3-O-(2′E,4′Z-Decadienoyl) ingenol
10.10

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.1051 +/-
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3065 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.78 +/- 0.24 ms
14.22 ingenol
4000
571.26929

20000 600.27229
482.14553

Intensity [Counts]
3000
Intensity [Counts]

10000
2000 613.23281
14.60 16.54 826.17130
340.11638 621.29206
16.49 173.15138
16.58
10.10 16.78 0
12.12
1000 200 400 600 800 1000
14.75
7.81 13.32 Item name: MENGKUDU 2 Channel name: High energy : Time 10.1051 +/-
16.24
16.90 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.63 +/- 0.24 ms
3.17 9.42
4.29 7.26 18.46 ingenol
0
191.03578
0 5 10 15 20 615.25090
Retention time [min]
587.25629

Intensity [Counts]
5000
503.21932 617.27581
345.10094
421.17629

2500 665.27097
676.24735
744.24560
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bruceine I [+H] : (39.7 PPM) 437.1812 : DT=5.47 to 5.95 ms
10.98

10000

11.37
Intensity [Counts]

7500

5000

2500

15.04 16.57
2.18 3.03 7.06 8.45 9.32
5.16
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.1088 +/- 0.0285 minutes :
Channel name: Bruceine I [+H] : (39.7 PPM) 437.1812 Component name: Bruceine I Drift Times: 5.71 +/- 0.24 ms
10.98
351.23381

60000 10000

409.13784

Intensity [Counts]
437.18121
Intensity [Counts]

5000 469.14111
40000
291.19604 483.14121
493.17116 654.15487
289.08809 783.31471
11.37
253.07413 799.67054
20000 0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 10.1088 +/- 0.0285 minutes :
Component name: Bruceine I Drift Times: 5.56 +/- 0.24 ms
7.07 16.58
0 403.17532

0 5 10 15 20 288.12220
10000
Retention time [min]

Intensity [Counts]
435.08274

5000 439.23176
216.97912
215.07963 447.16209
198.96898 505.22588
634.18943
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Rehmannioside D [+H] : (39.7 PPM) 687.2341 : DT=7.33 to 7.81 ms

1000
Intensity [Counts]

750

500

10.25
250
Rehmannioside D
10.14

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.1508 +/- 0.0285
Channel name: Rehmannioside D [+H] : (39.7 PPM) 687.2341 Component name: Rehmannioside D minutes : Drift Times: 7.57 +/- 0.24 ms
1.48
4000 4.34
589.17871

15000

Intensity [Counts]
3000
669.13274
10000
Intensity [Counts]

2000 687.22249
8.61 5000 290.10153 555.15358
740.20069
495.16212
8.28 992.78888
3.78 9.22
11.12 0
1000 6.65 200 400 600 800 1000
5.11 11.62
2.94
13.45 Item name: MENGKUDU 2 Channel name: High energy : Time 10.1508 +/- 0.0285
14.36
Component name: Rehmannioside D minutes : Drift Times: 7.41 +/- 0.24 ms
16.15 18.52
0 589.18384
15000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
145.02964

5000 578.21476
352.08912 691.10987
304.11759 731.31555
826.33998
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6'-O-Benzoyl-4''-hydroxy-3''-methoxypaeoniflorin [+H] : (39.7 PPM)
631.2045 : DT=6.55 to 7.03 ms

750
Intensity [Counts]

500

6'-O-Benzoyl-4''-hydroxy-3''-methoxypaeoniflorin
250 10.18

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.1773 +/-
Channel name: 6'-O-Benzoyl-4''-hydroxy-3''-methoxypaeoniflorin [+H] : (39.7 PPM) Component name: 6'-O-Benzoyl-4''- 0.0285 minutes : Drift Times: 6.77 +/- 0.24 ms
631.2045 hydroxy-3''-methoxypaeoniflorin
8.61
516.16342
2000

10000

Intensity [Counts]
351.08659 659.12242
1500
481.15571
Intensity [Counts]

5000 670.13705
4.97 9.16
3.75 7.13
679.51183 917.25101
1000 10.17 11.32 306.12997
729.30971
6.01 13.34 248.09060
3.62 12.53
0
14.80
500 3.58 200 400 600 800 1000
3.33 14.92
18.53 Item name: MENGKUDU 2 Channel name: High energy : Time 10.1773 +/-
16.85 Component name: 6'-O-Benzoyl-4''- 0.0285 minutes : Drift Times: 6.62 +/- 0.24 ms
hydroxy-3''-methoxypaeoniflorin
0
599.26706
0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
175.03895
10000 290.10331

359.23289 516.16809

680.51945 971.22347
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Catalpol [+H] : (39.7 PPM) 363.1269 : DT=4.97 to 5.46 ms

4000

3000
Intensity [Counts]

2000

9.83

1000 10.06
10.36

Catalpol
0 10.17

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.1773 +/- 0.0285 minutes :
Channel name: Catalpol [+H] : (39.7 PPM) 363.1269 Component name: Catalpol Drift Times: 5.21 +/- 0.24 ms
9.06
5000
399.14733
15000
365.19135
423.16001
4000

Intensity [Counts]
351.08679
10000
Intensity [Counts]

3000 321.11645

3.13 4.90 12.04 5000


276.72777

2000 9.82 13.44 267.15535 634.19160

3.78 9.89 13.74 0


8.77 14.04 200 400 600 800 1000
1000 6.74
1.83 Item name: MENGKUDU 2 Channel name: High energy : Time 10.1773 +/- 0.0285 minutes :
14.42
14.86 Component name: Catalpol Drift Times: 5.06 +/- 0.24 ms

0 365.19613
5000 363.12382
0 5 10 15 20 145.02946
Retention time [min]

Intensity [Counts]
305.08340 394.12870

2500
427.22032
432.16100

447.15899
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Gentiopicroside [+H] : (39.7 PPM) 357.1191 : DT=6.45 to 6.94 ms

Gentiopicroside
300 10.22

10.19
9.98
200
Intensity [Counts]

9.94

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.2115 +/- 0.0285
Channel name: Gentiopicroside [+H] : (39.7 PPM) 357.1191 Component name: Gentiopicroside minutes : Drift Times: 6.70 +/- 0.24 ms
7.35
5.90 516.16342
1000

10000
10.23

Intensity [Counts]
0.62 2.14 4.70
750 10.29
9.98
3.64
Intensity [Counts]

557.28897
3.60 11.80 5000 357.11913
9.93
669.13363
917.25108
500 12.14
352.08951 818.20374
13.38
16.47 248.09060
13.65
14.25 16.54 0
250 200 400 600 800 1000
16.65
Item name: MENGKUDU 2 Channel name: High energy : Time 10.2115 +/- 0.0285
16.70 Component name: Gentiopicroside minutes : Drift Times: 6.54 +/- 0.24 ms

0 10000 191.03604

0 5 10 15 20
Retention time [min]

Intensity [Counts]
163.03900
573.28906
359.23289
5000
531.15067
659.11592
529.26251
680.51945
840.23310

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Rel-2R-methyl-5S-acetoxy-4R-furano-germacr-1(10)Z-en-6-one
[+H] : (39.7 PPM) 321.1682 : DT=4.80 to 5.29 ms
13.74
600

13.79
Intensity [Counts]

400
14.46
7.43 11.76
9.66
11.13 15.03
7.23 16.60
6.02 9.23
200 2.13 3.84 5.62
8.58
2.46 18.55
1.38

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.2427 +/-
Channel name: Rel-2R-methyl-5S-acetoxy-4R-furano-germacr-1(10)Z-en-6-one Component name: Rel-2R-methyl-5S- 0.0285 minutes : Drift Times: 5.04 +/- 0.24 ms
[+H] : (39.7 PPM) 321.1682 acetoxy-4R-furano-germacr-1(10)Z-en-6-one
7.85
1000 399.14765

13.74 20000 320.11348

Intensity [Counts]
750 291.19668
16.59 582.13053
12.03
Intensity [Counts]

10.47
10000
10.25 14.51
12.92 283.06261 871.11568
500 5.94
5.64 9.66 262.14473 544.18076 590.11476
4.66 239.07032 743.36822
2.13
4.13 18.55 0
250 200 400 600 800 1000
2.06 18.32
Item name: MENGKUDU 2 Channel name: High energy : Time 10.2427 +/-
Component name: Rel-2R-methyl-5S- 0.0285 minutes : Drift Times: 4.89 +/- 0.24 ms
acetoxy-4R-furano-germacr-1(10)Z-en-6-one
0
369.09762
0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
271.14569
144.04562
10000
383.17288

582.13167 871.11933
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 12-α-Hydroxyevodol [+H] : (39.7 PPM) 501.1761 : DT=5.72 to 6.20
ms

600
Intensity [Counts]

400
12-α-Hydroxyevodol
10.27

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.2505 +/- 0.0285
Channel name: 12-α-Hydroxyevodol [+H] : (39.7 PPM) 501.1761 Component name: 12-α-Hydroxyevodol minutes : Drift Times: 5.96 +/- 0.24 ms
10.27
434.27474

4000 20000

Intensity [Counts]
6.97 467.11795
Intensity [Counts]

3000
7.52 10000 400.14996 475.15483
6.57
4.50 582.13039 754.22291
393.22603
2000 8.23 204.06712 800.77363
663.30058
14.86 382.13267
8.89 864.30199
5.97 11.07 0
1.89
200 400 600 800 1000
1000 11.42
2.24
11.71 Item name: MENGKUDU 2 Channel name: High energy : Time 10.2505 +/-
0.70 16.49 Component name: 12-α-Hydroxyevodol 0.0285 minutes : Drift Times: 5.81 +/- 0.24 ms
16.60
0 434.27708
15000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000

437.21600
337.10761
5000
133.10153 488.20227
655.14638 871.11999

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Physalin W [+H] : (39.7 PPM) 527.1928 : DT=6.31 to 6.79 ms

750
Intensity [Counts]

500

10.54

250
Physalin W
10.30

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.2776 +/- 0.0285 minutes :
Channel name: Physalin W [+H] : (39.7 PPM) 527.1928 Component name: Physalin W Drift Times: 6.55 +/- 0.24 ms
9.47
2000
8.91 511.14365

8.71 3e5

Intensity [Counts]
1500 8.61
9.58
2e5
Intensity [Counts]

8.53
9.62
5.16 8.31
1000 0.52 9.67
5.71 12.88 100000 529.15467
4.97 10.50
4.78 11.87 13.17 339.11309 743.36796 914.29231
206.05381 530.15968
13.55 0
3.42
500 14.21 200 400 600 800 1000
2.92 14.70
Item name: MENGKUDU 2 Channel name: High energy : Time 10.2776 +/- 0.0285
1.73 18.53 Component name: Physalin W minutes : Drift Times: 6.40 +/- 0.24 ms

0 511.14599

0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

105.06951
321.11484 559.17321
399.14854
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 12-α-Hydroxyevodol [+H] : (39.7 PPM) 501.1762 : DT=7.93 to 8.41
ms

12-α-Hydroxyevodol
10.28

300
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.2780 +/- 0.0285
Channel name: 12-α-Hydroxyevodol [+H] : (39.7 PPM) 501.1762 Component name: 12-α-Hydroxyevodol minutes : Drift Times: 8.16 +/- 0.24 ms
10.27
75000 743.36792

4000

Intensity [Counts]
50000

6.97
Intensity [Counts]

3000
7.52 744.36936
6.57 25000 713.40578
4.50
399.14730
2000 768.34023
8.23
14.86 339.11258 626.27830 809.29875
8.89
5.97 11.07 0
1.89
200 400 600 800 1000
1000 11.42
2.24
11.71 Item name: MENGKUDU 2 Channel name: High energy : Time 10.2780 +/-
0.70 16.49 Component name: 12-α-Hydroxyevodol 0.0285 minutes : Drift Times: 8.01 +/- 0.24 ms
16.60
0 399.14866

0 5 10 15 20
20000
Retention time [min] 223.04214

Intensity [Counts]
321.11468 743.37173
10000
727.39048
501.17976 716.25631 801.23463
209.02353

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Rehmannioside A [+H] : (39.7 PPM) 525.1802 : DT=6.30 to 6.78 ms
8.37 13.16

1000

14.10
750
6.39
Intensity [Counts]

4.65 13.09
4.34 7.84 8.92
500
5.91
7.11 10.02 10.87
3.44
11.74
1.89 14.23
250
1.78 14.81
16.49

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.3014 +/- 0.0285
Channel name: Rehmannioside A [+H] : (39.7 PPM) 525.1802 Component name: Rehmannioside A minutes : Drift Times: 6.54 +/- 0.24 ms
8.37 13.16
530.15968
20000
4.65
6.38 8.92 14.10 339.11309
1500

Intensity [Counts]
4.58
4.34
Intensity [Counts]

13.09 10000 475.16518


7.90 569.25662
1000
5.35 7.84 9.86 279.08680
11.76
571.16804
3.44 914.29231
16.49 206.05381
3.10
0
500 1.88 200 400 600 800 1000
16.56
1.01 Item name: MENGKUDU 2 Channel name: High energy : Time 10.3014 +/- 0.0285
Component name: Rehmannioside A minutes : Drift Times: 6.39 +/- 0.24 ms
16.74

0 574.29160

0 5 10 15 20
527.11812
Retention time [min] 10000

Intensity [Counts]
204.06656

585.27183
5000 339.12520

629.29669

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 12S-Hydroxyandrographolide [+H] : (39.7 PPM) 369.2258 : DT=5.25
to 5.73 ms

3000

12S-Hydroxyandrographolide
10.34 11.42
Intensity [Counts]

2000
9.78

1000 9.70

9.46

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.3431 +/-
Channel name: 12S-Hydroxyandrographolide [+H] : (39.7 PPM) 369.2258 Component name: 12S- 0.0285 minutes : Drift Times: 5.49 +/- 0.24 ms
13.08 Hydroxyandrographolide

347.12431
5000 30000 369.22579
433.16996

Intensity [Counts]
4000 11.42
20000
Intensity [Counts]

10.34
3000
10000 345.11344
9.78
222.07738 440.03904 619.13082
2000 708.72877
0
14.80
200 400 600 800 1000
13.22 14.91
1000 9.63 Item name: MENGKUDU 2 Channel name: High energy : Time 10.3431 +/-
1.44 16.57
9.47 Component name: 12S- 0.0285 minutes : Drift Times: 5.34 +/- 0.24 ms
2.97 3.71 5.70
0.65 16.72 Hydroxyandrographolide
0
347.12740
0 5 10 15 20
390.14580
Retention time [min]

Intensity [Counts]
10000
301.11916
145.02910 405.18769

444.14234
688.28341
458.20733
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside G [+H] : (39.7 PPM) 573.2879 : DT=6.43 to 6.91 ms
9.91
4000

Picrasinoside G
10.35
3000
Intensity [Counts]

2000

9.84

10.45
1000
10.75
9.77

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.3445 +/- 0.0285
Channel name: Picrasinoside G [+H] : (39.7 PPM) 573.2879 Component name: Picrasinoside G minutes : Drift Times: 6.68 +/- 0.24 ms
9.92
6000 573.28794
40000

5000 10.35 529.15490

Intensity [Counts]
489.23169
4000
Intensity [Counts]

20000 587.27009

3000 604.27411
339.11051
325.11526 605.22118
249.11033 733.22108 894.29115
2000
0
200 400 600 800 1000
11.0712.59
6.44 16.60
1000 8.53 9.21 Item name: MENGKUDU 2 Channel name: High energy : Time 10.3445 +/- 0.0285
16.54
Component name: Picrasinoside G minutes : Drift Times: 6.53 +/- 0.24 ms
3.70
4.32 5.61 18.53
0 30000 573.28958

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000 489.23033

10000
191.03412 290.10205 589.26498
414.15669 616.26708
966.30989
726.24815
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1β,3α,9β-Trihydroxyeudesma-5,11(13)-dien-12-oic acid [+H] : (39.7
PPM) 283.1558 : DT=4.34 to 4.83 ms

1250

1000
Intensity [Counts]

750

500

1β,3α,9β-Trihydroxyeudesma-5,11(13)-dien-12-oic acid
250 10.37

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.3697 +/-
Channel name: 1β,3α,9β-Trihydroxyeudesma-5,11(13)-dien-12-oic acid [+H] : (39.7 Component name: 1β,3α,9β- 0.0285 minutes : Drift Times: 4.59 +/- 0.24 ms
PPM) 283.1558 Trihydroxyeudesma-5,11(13)-dien-12-oic acid
7.25
209.11861

7500 281.04549

Intensity [Counts]
1500 283.15585

5000 297.16887
Intensity [Counts]

307.16711
10.37 191.14576 355.08162
1000
2.45 7.95 2500
576.23633
0.44
5.37 0
500 9.22 16.86
5.02 6.46 10.77 13.97 200 400 600 800 1000
2.23 3.12 4.95 16.50 16.91
11.60 Item name: MENGKUDU 2 Channel name: High energy : Time 10.3697 +/-
15.52 18.23 Component name: 1β,3α,9β- 0.0285 minutes : Drift Times: 4.43 +/- 0.24 ms
Trihydroxyeudesma-5,11(13)-dien-12-oic acid
0
296.16588
0 5 10 15 20
Retention time [min] 324.15108

Intensity [Counts]
5000
277.11453
383.17287
244.22724
507.21011

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6-Feruloyl catalpol [+H] : (39.7 PPM) 523.1800 : DT=6.35 to 6.83 ms

10000
Intensity [Counts]

7500

5000

2500
6-Feruloyl catalpol
10.41

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.3872 +/- 0.0285
Channel name: 6-Feruloyl catalpol [+H] : (39.7 PPM) 523.1800 Component name: 6-Feruloyl catalpol minutes : Drift Times: 6.59 +/- 0.24 ms
6.39
491.24582

30000
15000

Intensity [Counts]
635.23312
20000
Intensity [Counts]

10000
10000 339.11051

8.58 285.16759 839.25032


939.30081
248.09148
8.92 0
5000
200 400 600 800 1000
6.91 10.41 Item name: MENGKUDU 2 Channel name: High energy : Time 10.3872 +/- 0.0285
5.89
Component name: 6-Feruloyl catalpol minutes : Drift Times: 6.43 +/- 0.24 ms
3.21 4.63 11.43 12.32 14.47
0.61
0 30000 571.27616

0 5 10 15 20
Retention time [min] 491.24932

Intensity [Counts]
20000
205.05113

10000 135.04534
597.24823
452.31703 635.23755
304.11409 899.26005
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Chloranthalactone F [+H] : (39.7 PPM) 457.2379 : DT=5.92 to 6.40
ms

4000

3000
Intensity [Counts]

2000

Chloranthalactone F
1000 10.39

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.3958 +/- 0.0285
Channel name: Chloranthalactone F [+H] : (39.7 PPM) 457.2379 Component name: Chloranthalactone F minutes : Drift Times: 6.16 +/- 0.24 ms
7.25
40000 419.18191

7.56 30000
6000

Intensity [Counts]
440.23503
6.93 7.65

20000 523.18020
Intensity [Counts]

4000 8.66
10000
8.98 415.13994 524.18619
249.09672 884.29225
608.19120 811.79229
0
2000 200 400 600 800 1000
6.69 10.61 Item name: MENGKUDU 2 Channel name: High energy : Time 10.3958 +/- 0.0285
11.10 16.51
14.51 Component name: Chloranthalactone F minutes : Drift Times: 6.00 +/- 0.24 ms
6.60 17.35
2.894.08
0 419.18245

0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
423.15389
375.15413
10000
446.16775
357.14330 530.15958
220.05923
289.08681
633.25264 770.22755 899.27602
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1,1,6-Trimethyl-1,2-dihydronaphthalene [+H] : (39.7 PPM)
173.1340 : DT=3.39 to 3.87 ms

1,1,6-Trimethyl-1,2-dihydronaphthalene
600
10.45

10.52
Intensity [Counts]

400 10.40

10.31 10.56

10.61
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.4388 +/-
Channel name: 1,1,6-Trimethyl-1,2-dihydronaphthalene [+H] : (39.7 PPM) 173.1340 Component name: 1,1,6-Trimethyl-1,2- 0.0285 minutes : Drift Times: 3.63 +/- 0.24 ms
6.45 dihydronaphthalene

173.13398
1000 10000
13.69
10.45

Intensity [Counts]
16.51
750
16.58
Intensity [Counts]

10.52
5000
0.98
7.76 13.54

500 9.47
12.53
5.84
0
13.96
250 3.21 5.69 16.69 200 400 600 800 1000
2.98 16.81 Item name: MENGKUDU 2 Channel name: High energy : Time 10.4388 +/-
16.91 Component name: 1,1,6-Trimethyl-1,2- 0.0285 minutes : Drift Times: 3.47 +/- 0.24 ms
dihydronaphthalene
0
158.10600
0 5 10 15 20 1000
Retention time [min]

Intensity [Counts]
500

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2205 : DT=5.66 to 6.15 ms
16.21
1500

1000 8.71
Intensity [Counts]

8.75 13.71
16.56
13.65 15.79
5.42
5.10 14.78 16.60
9.26
500 11.63
5.04
7.32 10.28 16.68

3.51 4.16 6.36 16.88


2.18
1.56 18.33

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.5953 +/- 0.0285
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2205 Component name: Nigakilactone F minutes : Drift Times: 5.94 +/- 0.24 ms
13.71
16.21 439.23183

2000 75000

Intensity [Counts]
5.42
50000
Intensity [Counts]

1500
13.54 14.78
8.73 16.53
5.12 16.60 25000
483.23075
1000 11.98 401.15945
16.66 494.14005 681.19135
5.76 9.95 395.24183 883.08700
8.34 0
16.88 200 400 600 800 1000
500 6.25
4.16 Item name: MENGKUDU 2 Channel name: High energy : Time 10.5953 +/- 0.0285
2.18 4.07 17.18
Component name: Nigakilactone F minutes : Drift Times: 5.78 +/- 0.24 ms
3.49
0 439.23238
75000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

25000
454.16987
176.99957 248.08947
501.15033
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Pseudoionone [+H] : (39.7 PPM) 193.1597 : DT=3.53 to 4.01 ms

Pseudoionone
800 10.58 10.61

600
Intensity [Counts]

400 10.51

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.6097 +/- 0.0285
Channel name: Pseudoionone [+H] : (39.7 PPM) 193.1597 Component name: Pseudoionone minutes : Drift Times: 3.77 +/- 0.24 ms
8.73
175.14890
15000 193.15970
2500 8.84

Intensity [Counts]
2000 10000
Intensity [Counts]

9.28

1500 10.61
5000

207.00982
1000
8.53 0
5.54 200 400 600 800 1000
11.20
500 5.47 8.37
16.57 Item name: MENGKUDU 2 Channel name: High energy : Time 10.6097 +/- 0.0285
13.36
4.90 8.01 Component name: Pseudoionone minutes : Drift Times: 3.62 +/- 0.24 ms
3.24 15.52
16.76
0 133.10189

0 5 10 15 20 4000
Retention time [min] 205.04996

Intensity [Counts]
2000
207.02692
244.05379

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Artemisitene [+H] : (39.7 PPM) 281.1402 : DT=4.22 to 4.70 ms
Artemisitene
4000
10.74

3000
10.82
Intensity [Counts]

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Artemisitene
0 10.73
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.7236 +/- 0.0285
Channel name: Artemisitene [+H] : (39.7 PPM) 281.1402 Component name: Artemisitene minutes : Drift Times: 4.46 +/- 0.24 ms
10.72
281.14023
10.67
4000
40000

Intensity [Counts]
10.82
Intensity [Counts]

3000
20000

265.16166
2000
290.10260 451.14650
133.10140
10.91 0
200 400 600 800 1000
1000 3.99
2.34 Item name: MENGKUDU 2 Channel name: High energy : Time 10.7236 +/- 0.0285
8.03 13.69
2.24 5.22 7.27 Component name: Artemisitene minutes : Drift Times: 4.31 +/- 0.24 ms
12.29 14.91 16.5317.30

0 223.09681

0 5 10 15 20 7500
Retention time [min]

Intensity [Counts]
337.11977
5000

219.07988
2500 107.05083

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 12S-Hydroxyandrographolide [+H] : (39.7 PPM) 369.2260 : DT=5.14
to 5.62 ms

12S-Hydroxyandrographolide
1500
10.76
Intensity [Counts]

1000

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.7582 +/-
Channel name: 12S-Hydroxyandrographolide [+H] : (39.7 PPM) 369.2260 Component name: 12S- 0.0285 minutes : Drift Times: 5.39 +/- 0.24 ms
13.08 Hydroxyandrographolide

342.13485
5000 2e5
388.14039

Intensity [Counts]
4000 11.42
Intensity [Counts]

100000
10.34
3000
9.78 338.10416
297.13167 389.17350
2000 267.06623 399.14853 636.22217 898.27734
0
14.80 200 400 600 800 1000
13.22 14.91
1000 9.63 Item name: MENGKUDU 2 Channel name: High energy : Time 10.7582 +/-
1.44 16.57
9.47 Component name: 12S- 0.0285 minutes : Drift Times: 5.24 +/- 0.24 ms
2.97 3.71 5.70
0.65 16.72 Hydroxyandrographolide
0
371.13386
0 5 10 15 20
40000
Retention time [min]

Intensity [Counts]
324.19734

20000

222.07750
383.17517
131.08562
681.23843
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside B [+H] : (39.7 PPM) 553.2661 : DT=6.55 to 7.03 ms

1250

1000
Intensity [Counts]

750

500
10.30

Picrasinoside B
250
10.80

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.7745 +/- 0.0285
Channel name: Picrasinoside B [+H] : (39.7 PPM) 553.2661 Component name: Picrasinoside B minutes : Drift Times: 6.79 +/- 0.24 ms
2000 13.16
13.53 506.18983
10000

529.14644
13.69 7500 464.32714 567.25820

Intensity [Counts]
1500
16.53
571.19498
16.66
13.05 5000 649.21000
Intensity [Counts]

13.01
367.11745
1000 13.91 838.72979
12.42 2500 953.33057
7.76 10.49 14.23 342.13518
10.44
15.37 0
6.59 9.63 16.71
500 200 400 600 800 1000
4.19 6.20
17.00
Item name: MENGKUDU 2 Channel name: High energy : Time 10.7745 +/- 0.0285
3.62 18.19 Component name: Picrasinoside B minutes : Drift Times: 6.63 +/- 0.24 ms
2.85
0 617.26933

0 5 10 15 20 603.28122
Retention time [min] 5000

Intensity [Counts]
573.28610
341.11909
505.24344
303.10144
649.21384
2500 288.08384

746.30160
804.30220

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Methyl lucidenate P [+H] : (39.7 PPM) 533.3123 : DT=6.52 to 7.00
ms

750
Methyl lucidenate P
10.82
Intensity [Counts]

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.8128 +/- 0.0285
Channel name: Methyl lucidenate P [+H] : (39.7 PPM) 533.3123 Component name: Methyl lucidenate P minutes : Drift Times: 6.76 +/- 0.24 ms
16.62
16.58 515.29920

1500 370.13003
16.55 20000

Intensity [Counts]
14.31
Intensity [Counts]

1000 10000
10.82 570.25876
571.19498
16.80 367.11745 620.21507
10.35 320.11078 727.23267 953.33057
10.92 14.63
500 9.95 0
11.38
200 400 600 800 1000
6.54 9.46
16.94
9.20 Item name: MENGKUDU 2 Channel name: High energy : Time 10.8128 +/- 0.0285
4.94 5.65 17.01 Component name: Methyl lucidenate P minutes : Drift Times: 6.61 +/- 0.24 ms
1.60
2.23
0 515.30223

0 5 10 15 20 15000 352.12001
Retention time [min]

Intensity [Counts]
281.04783
10000

5000 105.07060 555.27710


505.24344
615.25724
746.30160
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Artemisitene [+H] : (39.7 PPM) 281.1388 : DT=4.22 to 4.70 ms
10.73
4000

3000 Artemisitene
10.82
Intensity [Counts]

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.8319 +/- 0.0285
Channel name: Artemisitene [+H] : (39.7 PPM) 281.1388 Component name: Artemisitene minutes : Drift Times: 4.48 +/- 0.24 ms
10.72
281.13876
10.67
4000 20000

Intensity [Counts]
10.82
Intensity [Counts]

3000
10000 251.12689

324.12791
2000
505.17162
556.17328
0
200 400 600 800 1000
1000
2.34 3.99 Item name: MENGKUDU 2 Channel name: High energy : Time 10.8319 +/- 0.0285
5.22 10.12 13.69
2.20 7.19 Component name: Artemisitene minutes : Drift Times: 4.33 +/- 0.24 ms
12.29 14.91 16.5317.30
0 251.11817
4000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
340.12447

235.07470
2000
216.97983 403.12055

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1895 : DT=5.40 to 5.89 ms

1500

1000
Intensity [Counts]

Picrasin G
10.84

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.8348 +/- 0.0285 minutes :
Channel name: Picrasin G [+H] : (39.7 PPM) 393.1895 Component name: Picrasin G Drift Times: 5.65 +/- 0.24 ms
11.66
424.04955
2500 9.67 393.18722
9.49 15000
9.72

Intensity [Counts]
2000 5.75 390.17109
10000
Intensity [Counts]

348.10956
1500 441.24489
8.71
5000 292.09575
8.66 471.17758 669.69832
281.14011 566.20084 828.23782
8.30 757.23775
1000
5.41
7.76
0
5.30 7.00 13.44 16.58 200 400 600 800 1000
500 5.14 4.39 16.67
13.54 Item name: MENGKUDU 2 Channel name: High energy : Time 10.8348 +/- 0.0285 minutes :
3.36 18.48 Component name: Picrasin G Drift Times: 5.49 +/- 0.24 ms
3.24
0 442.24936

0 5 10 15 20
7500
Retention time [min]

Intensity [Counts]
389.17119
5000 383.17606
240.10277

2500 528.17154
677.13540

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Loganic acid-6'-O-β-D-glucoside [+H] : (39.7 PPM) 539.1973 :
DT=6.21 to 6.69 ms

1500
Intensity [Counts]

1000

500
Loganic acid-6'-O-β-D-glucoside
10.85

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.8538 +/-
Channel name: Loganic acid-6'-O-β-D-glucoside [+H] : (39.7 PPM) 539.1973 Component name: Loganic acid-6'-O-β-D- 0.0285 minutes : Drift Times: 6.46 +/- 0.24 ms
5.96 glucoside
5000 6.05
479.27187

20000 421.27121
4000 511.20979
5.90

Intensity [Counts]
571.26989
Intensity [Counts]

3000 404.24597
10000
5.70 403.25890
14.37 574.31183 757.25706
2000 351.13264 923.82547
3.56 257.19172
5.40
7.98 8.60 0
2.48 6.67 200 400 600 800 1000
8.99
1000 4.34 14.18 16.58
9.50 Item name: MENGKUDU 2 Channel name: High energy : Time 10.8538 +/-
1.66
15.01 Component name: Loganic acid-6'-O-β-D- 0.0285 minutes : Drift Times: 6.31 +/- 0.24 ms
18.52 glucoside
0
479.27392
0 5 10 15 20
569.26111
Retention time [min]

Intensity [Counts]
281.04783
10000

275.20069
119.08596 605.22726
757.27580
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganosporelactone B [+H] : (39.7 PPM) 515.3013 : DT=6.49 to 6.97
ms
10.80
2500

2000
Intensity [Counts]

1500

1000

500 Ganosporelactone B
10.91

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.9143 +/- 0.0285
Channel name: Ganosporelactone B [+H] : (39.7 PPM) 515.3013 Component name: Ganosporelactone B minutes : Drift Times: 6.75 +/- 0.24 ms
10.81
10000 491.19705
4000

16.78 7500

Intensity [Counts]
585.25573
3000
5000 604.29171
Intensity [Counts]

883.08803
471.16372 631.07115
902.27018
2000 2500 405.19396
639.20244
16.60 401.15081
16.56
10.91 16.51 0
13.69
1000 200 400 600 800 1000
13.95 Item name: MENGKUDU 2 Channel name: High energy : Time 10.9143 +/- 0.0285
8.83 9.76 14.86 Component name: Ganosporelactone B minutes : Drift Times: 6.60 +/- 0.24 ms
3.96 4.68 6.99 17.56
1.89
0 145.02931
571.27746
0 5 10 15 20 163.03987
Retention time [min] 5000

Intensity [Counts]
469.00943
311.10754 575.27976
625.26542

2500
635.64088 865.08080
713.20189
883.09100

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yadanzioside P [+H] : (39.7 PPM) 711.2863 : DT=7.39 to 7.87 ms

1000

750
Intensity [Counts]

500

250

Yadanzioside P
10.93
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.9158 +/- 0.0285
Channel name: Yadanzioside P [+H] : (39.7 PPM) 711.2863 Component name: Yadanzioside P minutes : Drift Times: 7.63 +/- 0.24 ms
4.75
10000 697.29347
2000 399.14579

7500

Intensity [Counts]
370.13023
1500 623.22834
698.28391
5000
Intensity [Counts]

8.85 620.25921
11.13 746.30602
3.42 596.30498
12.14 205.05114 784.23147
1000 10.97 2500
462.16267
16.53 832.23188
8.62 9.55 12.27
6.03 7.73 13.19 16.61 0
6.69 15.24 200 400 600 800 1000
500 2.68

16.73 Item name: MENGKUDU 2 Channel name: High energy : Time 10.9158 +/- 0.0285
1.81 18.47 Component name: Yadanzioside P minutes : Drift Times: 7.47 +/- 0.24 ms

0 4000 381.13537 471.16773


311.10715
0 5 10 15 20 625.26542
303.10592
Retention time [min]

Intensity [Counts]
135.04410 655.20760
657.27341
883.09180
2000
717.32753
891.22350

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yadanzigan [+H] : (39.7 PPM) 575.2337 : DT=6.31 to 6.79 ms

1000
Intensity [Counts]

750

500

250
Yadanzigan
10.91
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.9311 +/- 0.0285 minutes :
Channel name: Yadanzigan [+H] : (39.7 PPM) 575.2337 Component name: Yadanzigan Drift Times: 6.55 +/- 0.24 ms
7.25
3000
515.30127 883.08852
3.45
507.27344 523.18006
2500 7.58 5000 474.22246

Intensity [Counts]
460.21678
631.07115
2000
Intensity [Counts]

452.26246
2500 825.26183
398.07984 937.30564
1500 5.45 6.45 747.20369
379.11661
7.67
1000 11.20
5.10 7.85 16.50 0
12.69
200 400 600 800 1000
12.79
500 2.87 16.58 Item name: MENGKUDU 2 Channel name: High energy : Time 10.9311 +/- 0.0285
18.52 Component name: Yadanzigan minutes : Drift Times: 6.40 +/- 0.24 ms
0.74

0 205.05058

0 5 10 15 20
Retention time [min] 10000

Intensity [Counts]
289.08721
135.04458 571.27746
5000 569.26877

626.29768 848.13064
865.08080
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yadanzioside P [+H] : (39.7 PPM) 711.2870 : DT=7.33 to 7.81 ms

1250

1000
Intensity [Counts]

750

500

250
Yadanzioside P
10.96
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.9572 +/- 0.0285
Channel name: Yadanzioside P [+H] : (39.7 PPM) 711.2870 Component name: Yadanzioside P minutes : Drift Times: 7.57 +/- 0.24 ms
4.75
2000 685.25887
650.20751
5000 397.07680 617.27708

Intensity [Counts]
688.36098
1500 438.17566 699.32730
810.17464
Intensity [Counts]

8.85
11.13 2500
3.42 975.38173
1000 12.14
10.97 874.26876
8.64 9.55 12.19 16.53

6.03 7.73 12.27 16.61


0
6.69 15.24
500 2.68 200 400 600 800 1000

16.73 Item name: MENGKUDU 2 Channel name: High energy : Time 10.9572 +/- 0.0285
1.81 17.82 Component name: Yadanzioside P minutes : Drift Times: 7.41 +/- 0.24 ms

0 176.07214

0 5 10 15 20
Retention time [min] 4000 471.16773

Intensity [Counts]
367.07864 607.22410 717.27503
361.11861
773.29045
2000 347.12706
803.32411
170.05992
881.34749

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Notonipetranone [+H] : (39.7 PPM) 379.2463 : DT=5.19 to 5.67 ms

2000

1500
Intensity [Counts]

1000
Notonipetranone
10.98

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.9895 +/- 0.0285
Channel name: Notonipetranone [+H] : (39.7 PPM) 379.2463 Component name: Notonipetranone minutes : Drift Times: 5.43 +/- 0.24 ms
16.53
306.13465
8000 75000

Intensity [Counts]
50000 425.13504
6000
288.12332
Intensity [Counts]

25000
4000
284.09256 429.12111
764.31308
667.25634
0
200 400 600 800 1000
2000
11.48 12.27 Item name: MENGKUDU 2 Channel name: High energy : Time 10.9895 +/- 0.0285
8.97 14.68 16.87 Component name: Notonipetranone minutes : Drift Times: 5.27 +/- 0.24 ms
7.18
0 288.12410

0 5 10 15 20 306.13437
Retention time [min] 20000 256.09714

Intensity [Counts]
232.06245

329.09312
10000
374.12147

115.05352 447.11294 623.19560

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (E)-Aldosecologanin [+H] : (39.7 PPM) 743.2766 : DT=8.03 to 8.51
ms

4000
Intensity [Counts]

3000

2000

1000
(E)-Aldosecologanin
10.99 11.06

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 10.9919 +/- 0.0285
Channel name: (E)-Aldosecologanin [+H] : (39.7 PPM) 743.2766 Component name: (E)-Aldosecologanin minutes : Drift Times: 8.27 +/- 0.24 ms
3.75
748.31033

75000

7500

Intensity [Counts]
50000
749.31174
Intensity [Counts]

5000
25000 586.25768
738.19021
802.22820
352.14069 425.13455
889.28593
0
2500 200 400 600 800 1000

7.18 Item name: MENGKUDU 2 Channel name: High energy : Time 10.9919 +/- 0.0285
9.61 11.89
3.36 6.80 12.18 16.54 Component name: (E)-Aldosecologanin minutes : Drift Times: 8.11 +/- 0.24 ms
2.89
0 367.20960
587.26269
0 5 10 15 20
4000 729.23253 803.32515
Retention time [min]

Intensity [Counts]
334.12706
181.05037 821.34314
831.31764
2000 840.35548
665.23476

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Physalin H [+H] : (39.7 PPM) 563.1672 : DT=6.34 to 6.82 ms

800

600
Intensity [Counts]

400

Physalin H
11.03
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.0281 +/- 0.0285 minutes :
Channel name: Physalin H [+H] : (39.7 PPM) 563.1672 Component name: Physalin H Drift Times: 6.58 +/- 0.24 ms
7.02
573.18061
2000
40000

Intensity [Counts]
1.79
1500
1.43
Intensity [Counts]

6.15
7.14 20000
8.82 488.21805
1000 1.28 6.10 352.14070 589.15340
8.73 10.98
4.30 5.38
9.55 334.12828 612.22766 802.22854
4.99 11.17 941.82915
3.73 11.61 0
500 200 400 600 800 1000
12.64
13.54 Item name: MENGKUDU 2 Channel name: High energy : Time 11.0281 +/- 0.0285 minutes :
15.31 Component name: Physalin H Drift Times: 6.42 +/- 0.24 ms

0 573.18277

0 5 10 15 20 15000
Retention time [min]

Intensity [Counts]
10000 527.13857
306.13418

5000
91.05405 216.06659
504.22264 593.21362 802.22838
374.12144 724.15794
940.37083
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakihemiacetal F [+H] : (39.7 PPM) 393.2272 : DT=5.31 to 5.79 ms

1250

1000
Intensity [Counts]

750

500 10.40

Nigakihemiacetal F
11.05
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.0523 +/- 0.0285
Channel name: Nigakihemiacetal F [+H] : (39.7 PPM) 393.2272 Component name: Nigakihemiacetal F minutes : Drift Times: 5.54 +/- 0.24 ms
5.74
367.21099

4000 30000

Intensity [Counts]
20000
Intensity [Counts]

3000

351.23796 473.18404
16.50 10000
2000 5.04 16.54 349.19486 519.15080
755.72228 855.12661
290.10301
0
11.87
8.65 14.03 200 400 600 800 1000
1000 11.81 11.96 16.69
7.94 Item name: MENGKUDU 2 Channel name: High energy : Time 11.0523 +/- 0.0285
2.83 17.43 Component name: Nigakihemiacetal F minutes : Drift Times: 5.38 +/- 0.24 ms
3.55 6.53
1.79
0 336.14771

0 5 10 15 20 365.19634
Retention time [min]

Intensity [Counts]
4000

438.17674
172.04099

2000 442.11245
803.31315
537.11530

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone E [+H] : (39.7 PPM) 451.2340 : DT=5.60 to 6.08 ms

600

400
Intensity [Counts]

200
Nigakilactone E
11.06

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.0710 +/- 0.0285
Channel name: Nigakilactone E [+H] : (39.7 PPM) 451.2340 Component name: Nigakilactone E minutes : Drift Times: 5.84 +/- 0.24 ms
13.30
40000 389.17298
13.45
1500
30000

Intensity [Counts]
Intensity [Counts]

20000
5.36 16.59 378.13467 435.16789
1000
5.30 16.50 473.18404
6.48 11.81 10000
5.14 8.20 11.05 205.05072 367.07764 792.26607
686.31900
5.06 835.26972
14.03 0
500 4.83 200 400 600 800 1000
16.78
4.59 Item name: MENGKUDU 2 Channel name: High energy : Time 11.0710 +/- 0.0285
3.99 17.37
Component name: Nigakilactone E minutes : Drift Times: 5.69 +/- 0.24 ms

0 389.17298

0 5 10 15 20 30000
Retention time [min]

Intensity [Counts]
20000

378.13385
10000
390.17549
215.08866 343.17288
451.19171 591.23807
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 12-α-Hydroxyevodol [+H] : (39.7 PPM) 501.1737 : DT=6.84 to 7.32
ms

1500
Intensity [Counts]

1000

12-α-Hydroxyevodol
11.08
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.0783 +/- 0.0285
Channel name: 12-α-Hydroxyevodol [+H] : (39.7 PPM) 501.1737 Component name: 12-α-Hydroxyevodol minutes : Drift Times: 7.06 +/- 0.24 ms
10.27
10000
595.23269
573.28468
4000
7500 550.22410

Intensity [Counts]
501.17366 636.15000
3000 6.98 5000
Intensity [Counts]

4.50 681.17955
7.52
262.10889
6.57 417.15509 858.29058
2500 205.05063
8.24 790.21980
2000

1.89 8.89 14.86


5.97 11.07 0
200 400 600 800 1000
1000 2.24 11.42
11.48 Item name: MENGKUDU 2 Channel name: High energy : Time 11.0783 +/-
1.60
16.49 Component name: 12-α-Hydroxyevodol 0.0285 minutes : Drift Times: 6.90 +/- 0.24 ms
17.61
0 637.25612

0 5 10 15 20 5000 205.05093 386.12666


Retention time [min]

Intensity [Counts]
415.13437
276.08733
584.25000
485.16550 664.20008
2500 202.08517 840.35724
685.14842 954.18114

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6'-Acetylneoandrographolide [+H] : (39.7 PPM) 523.2897 : DT=6.45
to 6.94 ms

600
Intensity [Counts]

400 6'-Acetylneoandrographolide
11.17

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.1526 +/-
Channel name: 6'-Acetylneoandrographolide [+H] : (39.7 PPM) 523.2897 Component name: 6'- 0.0285 minutes : Drift Times: 6.69 +/- 0.24 ms
16.59 Acetylneoandrographolide
2000
386.12524
40000

Intensity [Counts]
1500
Intensity [Counts]

20000

1000 571.27037
368.11407 452.26175 619.24136
16.75 793.76180
12.81 14.91 336.08871 617.22435
12.18
5.45 0
11.07
500 10.70 200 400 600 800 1000
16.82
8.65
Item name: MENGKUDU 2 Channel name: High energy : Time 11.1526 +/-
5.19 16.98
1.49 2.99 5.07 Component name: 6'- 0.0285 minutes : Drift Times: 6.54 +/- 0.24 ms
Acetylneoandrographolide
0
336.08914
0 5 10 15 20
Retention time [min]

Intensity [Counts]
291.09374

5000 368.11687
274.10925 452.26795 601.20176
188.07067 632.08187 839.35289
994.35209
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Oxypaeoniflorin [+H] : (39.7 PPM) 497.1622 : DT=5.94 to 6.42 ms

1250
10.29

1000 10.14 10.93


Intensity [Counts]

Oxypaeoniflorin
750 11.18

11.24

500
11.28

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.2022 +/- 0.0285
Channel name: Oxypaeoniflorin [+H] : (39.7 PPM) 497.1622 Component name: Oxypaeoniflorin minutes : Drift Times: 6.18 +/- 0.24 ms
0.57 6.89
10.29 480.17499
483.14822
6.98 15000 418.16150
2000

Intensity [Counts]
10.13
10.92 497.16216
10000
1500 6.21 11.17
Intensity [Counts]

8.84
5.90 399.14497

4.88 5000 396.13162 531.15571


1000 772.71739
4.38 11.28 226.08493 617.18166

3.39 11.55
0
2.78 11.99 200 400 600 800 1000
500 12.69 16.51
2.41 Item name: MENGKUDU 2 Channel name: High energy : Time 11.2022 +/- 0.0285
16.60
Component name: Oxypaeoniflorin minutes : Drift Times: 6.02 +/- 0.24 ms
18.52
10000 483.15010
0
0 5 10 15 20
Retention time [min] 497.16228

Intensity [Counts]
191.03502
383.17763
5000

188.07077 511.27655
642.20712

708.17667
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Platycogenic acid B [+H] : (39.7 PPM) 535.3277 : DT=6.34 to 6.82 ms

1000

750
Intensity [Counts]

500

250
Platycogenic acid B
11.25

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.2321 +/- 0.0285
Channel name: Platycogenic acid B [+H] : (39.7 PPM) 535.3277 Component name: Platycogenic acid B minutes : Drift Times: 6.58 +/- 0.24 ms
16.56
30000 481.19376
2000 16.76

Intensity [Counts]
20000
1500
Intensity [Counts]

10000
1000 494.19048
441.15239
8.54 617.18166
339.10878 858.23708
690.27987
6.92 9.30 0
6.78 16.88 200 400 600 800 1000
500 11.21
12.78 14.64
6.67 17.00 Item name: MENGKUDU 2 Channel name: High energy : Time 11.2321 +/- 0.0285
1.29 17.16 Component name: Platycogenic acid B minutes : Drift Times: 6.42 +/- 0.24 ms
2.04 3.59 6.36
0 481.19802

0 5 10 15 20 15000
Retention time [min]

Intensity [Counts]
10000

517.31627
191.03502 436.19262
5000
105.07017 539.25779
708.17667

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Neoquassin [+H] : (39.7 PPM) 391.2097 : DT=5.44 to 5.92 ms

600

11.14
Intensity [Counts]

400

Neoquassin
11.27
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.2389 +/- 0.0285
Channel name: Neoquassin [+H] : (39.7 PPM) 391.2097 Component name: Neoquassin minutes : Drift Times: 5.68 +/- 0.24 ms
16.55
437.21519
1250 16.61 2e5

Intensity [Counts]
1000
13.06

11.28
Intensity [Counts]

100000
750 9.17 11.15 11.37 15.22

3.87 5.93 13.11 16.75


401.15831 438.21628
500 3.56 5.86 6.56 8.00 267.15522
3.28 581.21929 737.18777 885.33767
7.41 0
5.81 200 400 600 800 1000
2.69 16.81
250
Item name: MENGKUDU 2 Channel name: High energy : Time 11.2389 +/- 0.0285
17.21
2.28 Component name: Neoquassin minutes : Drift Times: 5.52 +/- 0.24 ms

0 15000 383.17687

0 5 10 15 20
438.22052
Retention time [min]

Intensity [Counts]
10000

315.08776
5000 441.24903
167.07072
473.17463
689.15952
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2201 : DT=5.49 to 5.98 ms

1250

1000
Intensity [Counts]

750

500 11.63

Nigakilactone F
11.25
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.2516 +/- 0.0285
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2201 Component name: Nigakilactone F minutes : Drift Times: 5.72 +/- 0.24 ms
13.71
437.21519
16.21 2e5

2000

Intensity [Counts]
5.42
Intensity [Counts]

1500 100000
13.54 14.78
8.73 16.53
5.12
16.60
1000 11.98
16.66 267.15522 369.22054 471.19764
5.76 9.95 737.18777 885.33767
8.48 0
16.88 200 400 600 800 1000
500 8.34
4.16 Item name: MENGKUDU 2 Channel name: High energy : Time 11.2516 +/- 0.0285
4.07 17.18
Component name: Nigakilactone F minutes : Drift Times: 5.57 +/- 0.24 ms
1.03
0 15000 383.17687

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000

167.07072
5000 261.18431 441.24903
165.05349 504.22152
689.15952
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Neoquassin [+H] : (39.7 PPM) 391.2096 : DT=5.07 to 5.56 ms

500

400
Neoquassin
11.28
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.2816 +/- 0.0285
Channel name: Neoquassin [+H] : (39.7 PPM) 391.2096 Component name: Neoquassin minutes : Drift Times: 5.31 +/- 0.24 ms
16.55
1250 367.20965
16.61
348.10905
2e5

Intensity [Counts]
1000
13.06

11.28
Intensity [Counts]

750 9.17 11.15 11.37 15.22 100000

3.87 5.93 13.11 16.75


320.07725 368.21286
500 3.56 5.85 6.56 8.00
407.16706 601.24807
3.28 7.41 267.06858
0
5.81
200 400 600 800 1000
2.69 16.81
250
Item name: MENGKUDU 2 Channel name: High energy : Time 11.2816 +/- 0.0285
17.21
2.28 Component name: Neoquassin minutes : Drift Times: 5.16 +/- 0.24 ms

0 367.21069

0 5 10 15 20 1.5e5
Retention time [min]

Intensity [Counts]
348.10944

100000

320.07763
50000
276.08627 368.21416
137.05918 521.20419
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderenic acid C [+H] : (39.7 PPM) 517.3165 : DT=6.45 to 6.93 ms

1250 Ganoderenic acid C


11.32

1000
Intensity [Counts]

750

11.25
500
11.45

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.3238 +/- 0.0285
Channel name: Ganoderenic acid C [+H] : (39.7 PPM) 517.3165 Component name: Ganoderenic acid C minutes : Drift Times: 6.71 +/- 0.24 ms
16.61
2000 515.18076

11.33 50000

Intensity [Counts]
16.56
1500
16.49
Intensity [Counts]

25000

1000 499.20690 517.31652


11.25
486.21831 572.27210
13.74 765.33416 923.76515
16.78 320.11481
13.96 0
16.89
500 200 400 600 800 1000
8.55 9.58 14.78
6.02 Item name: MENGKUDU 2 Channel name: High energy : Time 11.3238 +/- 0.0285
4.09 7.61 7.91 18.52 Component name: Ganoderenic acid C minutes : Drift Times: 6.55 +/- 0.24 ms
3.53
0 40000 515.18347

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

499.30535
571.27646
290.10224 587.28233
190.04877 765.33418
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Loganic acid-6'-O-β-D-glucoside [+H] : (39.7 PPM) 539.1982 :
DT=6.63 to 7.11 ms
6.05

5.96
2500

2000 5.90
Intensity [Counts]

1500
14.37

1000
3.56
5.54
500 7.84 8.59 10.73 14.18
2.59 8.89 13.04 16.42
2.49 16.58
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.3273 +/-
Channel name: Loganic acid-6'-O-β-D-glucoside [+H] : (39.7 PPM) 539.1982 Component name: Loganic acid-6'-O-β-D- 0.0285 minutes : Drift Times: 6.87 +/- 0.24 ms
5.96 glucoside
5000 6.05
515.18076

4000 50000
5.90

Intensity [Counts]
Intensity [Counts]

3000
25000
5.70
499.20690 517.31652
14.37
2000 603.28082 765.33416
399.14738 923.76515
3.56 5.40
7.98 8.60 0
2.48 9.07 200 400 600 800 1000
1000 4.34 14.18 16.58
9.50 Item name: MENGKUDU 2 Channel name: High energy : Time 11.3273 +/-
1.66
15.06 Component name: Loganic acid-6'-O-β-D- 0.0285 minutes : Drift Times: 6.71 +/- 0.24 ms
18.52 glucoside
0
40000 515.18347
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

571.27646
290.10224 499.20618
586.27104
214.08961 801.23996
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nimbolin B [+H] : (39.7 PPM) 675.3181 : DT=7.17 to 7.65 ms

400
Intensity [Counts]

300

Nimbolin B
200 11.33

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.3276 +/- 0.0285 minutes :
Channel name: Nimbolin B [+H] : (39.7 PPM) 675.3181 Component name: Nimbolin B Drift Times: 7.41 +/- 0.24 ms
13.66
1500 625.24770
7500

416.14378 621.27404
1250
16.54

Intensity [Counts]
5000 437.17157 681.18001
13.54 705.10475
1000
Intensity [Counts]

8.06 714.22936
750 13.18 2500 724.18128
367.08038
9.96 11.95 938.31892
8.00 9.27 14.07
500 7.41
0
16.66
5.12 6.96 200 400 600 800 1000
4.51 16.76
250 Item name: MENGKUDU 2 Channel name: High energy : Time 11.3276 +/- 0.0285
1.90 2.62 16.90 18.53 Component name: Nimbolin B minutes : Drift Times: 7.25 +/- 0.24 ms
1.81 7500
0 417.15345
625.27315
0 5 10 15 20
Retention time [min]

Intensity [Counts]
5000 614.23302

221.04389 345.11335 587.29048


705.15803
2500 568.25453
725.25807
117.03292
839.19404

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3061 :
DT=6.36 to 6.85 ms

2500

2000
Intensity [Counts]

1500

1000

500
3-O-(2′E,4′Z-Decadienoyl) ingenol
11.32
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.3306 +/-
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3061 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.65 +/- 0.24 ms
14.22 ingenol
4000
515.18076

50000

Intensity [Counts]
3000
Intensity [Counts]

25000 447.17454
2000 517.31652
14.60 16.54
16.49 435.27928 572.27210 738.18812
16.58 865.27002

10.10 16.78 0
12.12 200 400 600 800 1000
1000
14.75
7.81 13.32 Item name: MENGKUDU 2 Channel name: High energy : Time 11.3306 +/-
16.90
3.17 9.42 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.50 +/- 0.24 ms
4.29 7.26 18.46 ingenol
0
40000 515.18347
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

571.27646
499.30535
290.10224
190.04877 671.22070 795.33986
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganosporelactone B [+H] : (39.7 PPM) 515.2990 : DT=6.40 to 6.89
ms

2500

2000
Intensity [Counts]

1500

1000

11.64
500
Ganosporelactone B
11.41
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.4029 +/- 0.0285
Channel name: Ganosporelactone B [+H] : (39.7 PPM) 515.2990 Component name: Ganosporelactone B minutes : Drift Times: 6.64 +/- 0.24 ms
10.81
511.14291
4000
100000

Intensity [Counts]
3000 16.78
Intensity [Counts]

50000 481.19769

2000
16.60 571.26869
16.56 339.11784 765.33469
290.10193 948.76439
10.91 13.69 0
16.51 200 400 600 800 1000
1000
13.95
Item name: MENGKUDU 2 Channel name: High energy : Time 11.4029 +/- 0.0285
7.73 9.76 14.36 Component name: Ganosporelactone B minutes : Drift Times: 6.49 +/- 0.24 ms
3.96 4.68 6.99 17.56
1.89
0 40000 511.14406

0 5 10 15 20
481.19820
Retention time [min]

Intensity [Counts]
20000

191.03559 571.27663
475.14472
614.23004 802.23821
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Acetylharpagide [+H] : (39.7 PPM) 407.1562 : DT=5.53 to 6.01 ms

2000

1500
11.55
Intensity [Counts]

1000

Acetylharpagide
11.49
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.4161 +/- 0.0285
Channel name: Acetylharpagide [+H] : (39.7 PPM) 407.1562 Component name: Acetylharpagide minutes : Drift Times: 5.77 +/- 0.24 ms
5.90
5.92 369.22419

5.85 40000
3000

Intensity [Counts]
11.29 439.22869
Intensity [Counts]

5.81 11.18
2.37 20000
2000 11.56
5.75
5.48 9.17 353.25177
472.16933
3.71 6.36 323.13004 812.35306
2.05 5.40 706.16908
1000 5.29 8.66 0
7.28 13.45 200 400 600 800 1000
1.94 13.62 Item name: MENGKUDU 2 Channel name: High energy : Time 11.4161 +/- 0.0285
16.61 Component name: Acetylharpagide minutes : Drift Times: 5.62 +/- 0.24 ms
17.69

0 15000 369.22432

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
205.05023 439.23203

176.07137
5000

639.18652 875.33987
774.29518
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 2β-(Isobutryloxy) florenalin [+H] : (39.7 PPM) 335.1837 : DT=4.87 to
5.36 ms

600

2β-(Isobutryloxy) florenalin
11.42
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.4237 +/-
Channel name: 2β-(Isobutryloxy) florenalin [+H] : (39.7 PPM) 335.1837 Component name: 2β-(Isobutryloxy) florenalin 0.0285 minutes : Drift Times: 5.12 +/- 0.24 ms
16.60
342.26473
1250 13.67
11.43 13.70
13.59 20000

Intensity [Counts]
1000 13.94

13.42 16.55
Intensity [Counts]

750 11.85 10000 335.18373


14.44
10.35
364.11982
15.70 601.20069
9.76 16.66 839.34081
205.04996 587.29559
500 9.01 748.32360
8.61 0
2.82 7.13 16.75
200 400 600 800 1000
250 1.55 4.88 17.76 Item name: MENGKUDU 2 Channel name: High energy : Time 11.4237 +/-
1.33
Component name: 2β-(Isobutryloxy) florenalin 0.0285 minutes : Drift Times: 4.96 +/- 0.24 ms

0 342.26282

0 5 10 15 20
Retention time [min] 175.04017
5000

Intensity [Counts] 2500 422.21024


158.06272 640.19280
803.31757
661.23614
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 12S-Hydroxyandrographolide [+H] : (39.7 PPM) 369.2242 : DT=5.42
to 5.90 ms

4000

3000 12S-Hydroxyandrographolide
11.42
Intensity [Counts]

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

12S-Hydroxyandrographolide
0 11.38

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.4245 +/-
Channel name: 12S-Hydroxyandrographolide [+H] : (39.7 PPM) 369.2242 Component name: 12S- 0.0285 minutes : Drift Times: 5.66 +/- 0.24 ms
13.08 Hydroxyandrographolide

369.22419
5000
40000

Intensity [Counts]
4000 11.42
Intensity [Counts]

10.34 20000
3000
9.78 353.25177 407.15621

323.13004 423.23439 747.32091


2000 677.25208
14.80 0
14.91 200 400 600 800 1000
13.22
1000 9.63 16.57 Item name: MENGKUDU 2 Channel name: High energy : Time 11.4245 +/-
1.44
1.81 3.71 5.70 9.47 16.63 Component name: 12S- 0.0285 minutes : Drift Times: 5.51 +/- 0.24 ms
0.65 Hydroxyandrographolide
0
15000 369.22432
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
205.05023 439.23203
177.05553
5000 163.04055

639.18652
774.29518
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Kansuinin B [+H] : (39.7 PPM) 723.2663 : DT=7.54 to 8.02 ms

1000

750
Intensity [Counts]

500

250

Kansuinin B
11.45

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.4399 +/- 0.0285 minutes :
Channel name: Kansuinin B [+H] : (39.7 PPM) 723.2663 Component name: Kansuinin B Drift Times: 7.78 +/- 0.24 ms
6.33
607.21683 733.15866

1500
10000

Intensity [Counts]
748.32558

600.24926
Intensity [Counts]

1000 10.52 483.12979


11.86 5000 427.10354
8.62 805.32755
2.73 7.65 12.30 369.13132
5.30 8.66 205.05004 827.23553
2.68 12.81
4.77 12.58 16.48 888.36137
352.14085
500 4.47 13.98 0
3.23 16.59 200 400 600 800 1000

1.44 Item name: MENGKUDU 2 Channel name: High energy : Time 11.4399 +/- 0.0285
18.53
Component name: Kansuinin B minutes : Drift Times: 7.62 +/- 0.24 ms

0 567.26043
205.05019
0 5 10 15 20 10000
Retention time [min] 733.15913

Intensity [Counts]
541.27928
302.10239
5000 191.03543 359.15736 749.33672
360.16933
771.34527

839.35000
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3053 :
DT=6.36 to 6.84 ms

2500

2000
Intensity [Counts]

1500

1000

500

3-O-(2′E,4′Z-Decadienoyl) ingenol
0 11.63

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.6473 +/-
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3053 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.60 +/- 0.24 ms
14.22 ingenol
4000
515.28191
10000
484.17336 527.11636

Intensity [Counts]
3000 545.20329
547.22066
Intensity [Counts]

223.06133 331.08899
5000 558.18442
480.25673
2000 613.23073
923.26579
14.60 16.59 869.27458
16.78
10.10 0
1000 12.12 200 400 600 800 1000
14.75
7.81 13.32 Item name: MENGKUDU 2 Channel name: High energy : Time 11.6473 +/-
16.90
3.17 9.12 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.44 +/- 0.24 ms
4.29 7.26 18.46 ingenol
0
10000 205.05019
0 5 10 15 20
Retention time [min]

Intensity [Counts]
191.03462 331.12009 494.18816
5000 515.28681
525.22466
117.03400
653.21097
861.26912

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 2α,3β-Dihydroxypterondontic acid [+H] : (39.7 PPM) 267.1606 :
DT=4.28 to 4.76 ms
11.63

300 11.58

2α,3β-Dihydroxypterondontic acid
Intensity [Counts]

200 11.67

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.6632 +/-
Channel name: 2α,3β-Dihydroxypterondontic acid [+H] : (39.7 PPM) 267.1606 Component name: 2α,3β- 0.0285 minutes : Drift Times: 4.52 +/- 0.24 ms
11.63 Dihydroxypterondontic acid

267.16057
800

4000
16.52 251.12468

Intensity [Counts]
600 290.10226
Intensity [Counts]

6.88
7.56 10.24 2000 322.08180
227.03884
9.55
400 0.43 11.72 392.12720
4.50 7.72
5.39
14.38 0
2.85
3.48 14.81 16.63 200 400 600 800 1000
200 2.41
2.22 17.05 Item name: MENGKUDU 2 Channel name: High energy : Time 11.6632 +/-
Component name: 2α,3β- 0.0285 minutes : Drift Times: 4.36 +/- 0.24 ms
17.14
Dihydroxypterondontic acid
0
273.18453
0 5 10 15 20
2000 261.02531
Retention time [min]

Intensity [Counts]
237.10612
379.02205

1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Physalin E [+H] : (39.7 PPM) 545.2033 : DT=6.14 to 6.62 ms

1500
Intensity [Counts]

1000

Physalin E
11.67

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Physalin E
0 11.63
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.6658 +/- 0.0285 minutes :
Channel name: Physalin E [+H] : (39.7 PPM) 545.2033 Component name: Physalin E Drift Times: 6.38 +/- 0.24 ms
12.44
545.20329
7500
503.24553
4000
414.32076

Intensity [Counts]
5000 275.20129
11.92
3000
Intensity [Counts]

563.20863 798.21331
11.85 2500 697.75610
207.06824 933.30685
2000
8.71
8.83
12.61 0
8.66
8.47 11.66 200 400 600 800 1000
1000 12.72 16.53
1.66 3.58 6.90
13.24 16.61 Item name: MENGKUDU 2 Channel name: High energy : Time 11.6658 +/- 0.0285 minutes :
2.45 16.88 18.53 Component name: Physalin E Drift Times: 6.23 +/- 0.24 ms

0 513.26723

0 5 10 15 20
145.02914
Retention time [min] 10000 512.14732

Intensity [Counts]
331.12009 414.32372 557.17682

5000 267.06732

802.26197
861.26912
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Notonipetranone [+H] : (39.7 PPM) 379.2467 : DT=5.39 to 5.87 ms

5000

4000
Intensity [Counts]

3000

2000

1000

Notonipetranone
0 11.72
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.7253 +/- 0.0285
Channel name: Notonipetranone [+H] : (39.7 PPM) 379.2467 Component name: Notonipetranone minutes : Drift Times: 5.63 +/- 0.24 ms
16.53
367.21019
8000
75000

Intensity [Counts]
6000 50000
Intensity [Counts]

420.17687
25000
4000 501.20297 592.19777
351.08662 690.21561 839.34473
145.05033
0
200 400 600 800 1000
2000
11.48 12.27 Item name: MENGKUDU 2 Channel name: High energy : Time 11.7253 +/- 0.0285
8.97 14.68 16.87 Component name: Notonipetranone minutes : Drift Times: 5.48 +/- 0.24 ms
7.18
0 367.21027

0 5 10 15 20
30000
Retention time [min]

Intensity [Counts]
20000

131.05064 349.19934
10000 383.17696 623.19191 839.35102
205.05072 422.20559
640.19207
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yadanzioside I [+H] : (39.7 PPM) 643.2250 : DT=7.35 to 7.83 ms

600
Intensity [Counts]

400

Yadanzioside I
200 11.75

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.7788 +/- 0.0285
Channel name: Yadanzioside I [+H] : (39.7 PPM) 643.2250 Component name: Yadanzioside I minutes : Drift Times: 7.59 +/- 0.24 ms
5.40
7.22
704.18159
2000 10000
11.26

Intensity [Counts]
7.49 11.21 11.32
1500 697.21927
685.36035
Intensity [Counts]

5000 721.24548
9.28 598.07933 736.30406
13.64 398.13278
1000 5.91 749.35122
13.72 16.50 294.09647
4.57 481.19833
13.83 806.33366
4.53
14.07
0
4.35
500 14.36 200 400 600 800 1000
2.34
Item name: MENGKUDU 2 Channel name: High energy : Time 11.7788 +/- 0.0285
18.52
Component name: Yadanzioside I minutes : Drift Times: 7.44 +/- 0.24 ms

0 691.22354
4000
294.09644
0 5 10 15 20
Retention time [min] 249.09193 403.18732

Intensity [Counts]
675.31793
481.19766
733.33938
2000
216.98321 999.39262

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3354 : DT=6.17 to 6.65 ms

20000

15000
Intensity [Counts]

10000

5000
Ganoderic acid S
11.78

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.7798 +/- 0.0285
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3354 Component name: Ganoderic acid S minutes : Drift Times: 6.47 +/- 0.24 ms
7.76
60000 515.18153

30000
501.10059

Intensity [Counts]
40000

481.19813
Intensity [Counts]

20000
20000
467.27133
451.31984 539.12153
294.09831 627.21421 836.30626
10000 0
16.65 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 11.7798 +/- 0.0285
13.30 Component name: Ganoderic acid S minutes : Drift Times: 6.31 +/- 0.24 ms
10.20 11.78
0 515.18471

0 5 10 15 20 40000
Retention time [min]

Intensity [Counts]
481.19855
20000

175.03977 517.18695
302.10216
165.06954 589.29295 785.22749
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2830 : DT=8.04 to 8.52 ms

3000
Intensity [Counts]

2000

Azedarachin C
11.81

1000

11.71
11.90

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Azedarachin C
0 11.78

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.8008 +/- 0.0285
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2830 Component name: Azedarachin C minutes : Drift Times: 8.28 +/- 0.24 ms
12.53
780.33173

20000 587.28296

Intensity [Counts]
7500
15.14
12.13 767.34690 808.22977
Intensity [Counts]

605.28832 821.32285
15.38
10000 700.33238
5000
825.29274
11.81
291.10305 855.28914
15.96 403.18679
885.27963
11.73 0
2500 13.03 16.41 200 400 600 800 1000
11.02
8.58 9.94 Item name: MENGKUDU 2 Channel name: High energy : Time 11.8008 +/- 0.0285
16.49
8.07 Component name: Azedarachin C minutes : Drift Times: 8.13 +/- 0.24 ms
2.44 3.51
0 587.28544

0 5 10 15 20
433.18018
Retention time [min] 5000

Intensity [Counts]
291.11021 781.33145

242.11829 701.33720
2500 848.27032
188.07150 925.37834

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sericoside [+H] : (39.7 PPM) 667.4023 : DT=9.27 to 9.75 ms

600
Intensity [Counts]

400

11.77
200
Sericoside
11.90

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.8999 +/- 0.0285 minutes :
Channel name: Sericoside [+H] : (39.7 PPM) 667.4023 Component name: Sericoside Drift Times: 9.51 +/- 0.24 ms
16.76
11.90 16.50 667.40235
851.44013
1500 882.37225
5000 883.37797

Intensity [Counts]
829.45515
Intensity [Counts]

1000 469.32916
2500
451.32174 487.34247
668.40437
11.78 12.53 505.35042
12.94 17.01
500 11.56 0
8.41 14.83
17.06 200 400 600 800 1000

17.66 Item name: MENGKUDU 2 Channel name: High energy : Time 11.8999 +/- 0.0285 minutes :
8.06
3.59 18.41 Component name: Sericoside Drift Times: 9.36 +/- 0.24 ms
3.23 7.96
0 4000 851.44141

0 5 10 15 20
Retention time [min] 883.37348

Intensity [Counts]
911.25181
2000 451.31943 779.29243

405.31251 747.30625

344.02135 549.23975

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nimbolin B [+H] : (39.7 PPM) 675.3172 : DT=6.98 to 7.46 ms

250

200
Intensity [Counts]

Nimbolin B
150 11.92

100

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.9099 +/- 0.0285 minutes :
Channel name: Nimbolin B [+H] : (39.7 PPM) 675.3172 Component name: Nimbolin B Drift Times: 7.22 +/- 0.24 ms
13.66
653.13474
75000
1250
16.54

Intensity [Counts]
50000
1000 13.54
Intensity [Counts]

8.06 619.12904
750 13.18
25000 654.13820
11.95
8.00 9.27 517.16003
9.70 14.07
205.05083 724.16743
500 7.41 14.98 461.10545 861.83653
7.05 16.66 0
5.12 200 400 600 800 1000
16.76
250 4.51 Item name: MENGKUDU 2 Channel name: High energy : Time 11.9099 +/- 0.0285
16.90 18.53
1.90 2.62 Component name: Nimbolin B minutes : Drift Times: 7.07 +/- 0.24 ms
1.81
0 205.05042

0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
177.05514 479.12146
653.13889
10000

240.10174
675.31265
291.11217 727.26430 925.31063
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinol A [+H] : (39.7 PPM) 437.2535 : DT=5.58 to 6.06 ms

1500
Intensity [Counts]

1000

500 Picrasinol A
11.90

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.9191 +/- 0.0285 minutes :
Channel name: Picrasinol A [+H] : (39.7 PPM) 437.2535 Component name: Picrasinol A Drift Times: 5.82 +/- 0.24 ms
6.40
425.25235
479.11948
4000
10000

Intensity [Counts]
408.22545

3000
Intensity [Counts]

401.16697
5000
16.59 379.24170
640.18899
16.52
2000 797.30645 961.29700
309.20358

0
11.13 200 400 600 800 1000
1000
10.76 11.24 13.94 16.71
8.01 Item name: MENGKUDU 2 Channel name: High energy : Time 11.9191 +/- 0.0285
10.03 12.56 16.9418.49 Component name: Picrasinol A minutes : Drift Times: 5.66 +/- 0.24 ms
2.22 3.07 4.85

0 7500 145.02884 379.24600

0 5 10 15 20 177.05514
Retention time [min]

Intensity [Counts]
5000
205.05017

309.11799 479.12261
2500
621.17692 725.24670

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Neoquassin [+H] : (39.7 PPM) 391.2122 : DT=5.27 to 5.75 ms

600

Neoquassin
11.94
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.9319 +/- 0.0285
Channel name: Neoquassin [+H] : (39.7 PPM) 391.2122 Component name: Neoquassin minutes : Drift Times: 5.51 +/- 0.24 ms
16.55
393.22329

1250 16.61 369.22305


10000

Intensity [Counts]
1000 368.21235
13.07
Intensity [Counts]

5000 352.24274
11.27 417.15019
750 573.73557
15.22 205.05102
10.71 16.75 444.12689 647.15583 724.30938
13.15
5.93 9.17 348.21577 800.20143
3.87
500 5.86 6.56 8.00
3.28 0
4.96 200 400 600 800 1000
2.69 16.98
250 Item name: MENGKUDU 2 Channel name: High energy : Time 11.9319 +/- 0.0285
17.20 Component name: Neoquassin minutes : Drift Times: 5.36 +/- 0.24 ms
2.28

0 7500 379.24600

0 5 10 15 20
Retention time [min] 205.05017

Intensity [Counts]
5000 399.14794

369.22195
117.03337
358.12723
2500
455.17417 622.15346

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2224 : DT=6.15 to 6.63 ms

300

Nigakilactone F
11.98
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 11.9812 +/- 0.0285
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2224 Component name: Nigakilactone F minutes : Drift Times: 6.39 +/- 0.24 ms
13.71
16.21 416.18970

2000

Intensity [Counts]
40000

5.42
1500
Intensity [Counts]

13.54 14.78
16.53 470.31034
8.73 20000
5.13
16.60
1000 409.22239 503.24194 715.87618
11.98 16.66
9.95 331.09111 603.25925 895.29959
5.77 0
8.34
7.91 16.88 200 400 600 800 1000
500
4.16 Item name: MENGKUDU 2 Channel name: High energy : Time 11.9812 +/- 0.0285
4.07 17.18 Component name: Nigakilactone F minutes : Drift Times: 6.24 +/- 0.24 ms
3.67

0 415.18667

0 5 10 15 20 1.5e5
Retention time [min]

Intensity [Counts]
100000

50000

204.06545 495.21910 804.30511


731.29365
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Physalin E [+H] : (39.7 PPM) 545.2033 : DT=6.40 to 6.88 ms

2000

1500
Intensity [Counts]

11.92
1000
11.85 Physalin E
12.11

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.1130 +/- 0.0285 minutes :
Channel name: Physalin E [+H] : (39.7 PPM) 545.2033 Component name: Physalin E Drift Times: 6.64 +/- 0.24 ms
12.44
10000 545.20331

4000
7500

Intensity [Counts]
499.30234

11.92 373.14731
3000 5000 549.24655
Intensity [Counts]

577.21672
11.85 370.12796
2500 661.19673 887.27108
2000 336.13122
8.71 325.19819
8.83
12.61 0
8.66
8.47 11.66 200 400 600 800 1000
1000 12.72 16.53
1.66 3.58 6.90
13.24 16.61 Item name: MENGKUDU 2 Channel name: High energy : Time 12.1130 +/- 0.0285 minutes :
2.45 16.88 18.53 Component name: Physalin E Drift Times: 6.48 +/- 0.24 ms

0 499.30699

0 5 10 15 20 347.12932
Retention time [min]

Intensity [Counts]
4000 340.11771 514.26278
312.12346 553.25341
117.03454 560.27416
2000 805.32460
623.19576

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2862 : DT=6.80 to 7.28 ms
12.53

6000
Azedarachin C
12.12
Intensity [Counts]

4000

12.07
2000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Azedarachin C
12.11
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.1218 +/- 0.0285
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2862 Component name: Azedarachin C minutes : Drift Times: 7.05 +/- 0.24 ms
12.53
10000
603.27924
75000
587.28617

605.29203

Intensity [Counts]
7500 15.14 50000
12.13 585.26885
Intensity [Counts]

15.38
5000 25000 372.14397
11.81 570.25655
677.12945
15.96 311.12830 882.33747
984.32465
11.73 0
2500 13.04 16.41 200 400 600 800 1000
11.43
8.58 11.02 16.49 Item name: MENGKUDU 2 Channel name: High energy : Time 12.1218 +/- 0.0285
8.07 Component name: Azedarachin C minutes : Drift Times: 6.90 +/- 0.24 ms
2.44 3.51
0 585.26916
30000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
587.28167
567.25462
603.27964
433.17487
10000 242.11589
605.28858

147.04382 627.26023
968.32996
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside G [+H] : (39.7 PPM) 573.2922 : DT=6.74 to 7.22 ms

3000
Intensity [Counts]

2000

1000

12.31
Picrasinoside G
0 12.16
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.1636 +/- 0.0285
Channel name: Picrasinoside G [+H] : (39.7 PPM) 573.2922 Component name: Picrasinoside G minutes : Drift Times: 6.98 +/- 0.24 ms
9.92
6000 20000 485.19799

5000 10.35 15000

Intensity [Counts]
4000 10000
Intensity [Counts]

585.17128
3000
5000 603.19331
483.31006
947.31170
744.28455
383.14456
2000
0
200 400 600 800 1000
11.0712.59 16.59
1000 6.44 7.43 Item name: MENGKUDU 2 Channel name: High energy : Time 12.1636 +/- 0.0285
9.21 16.54
2.86 4.32 16.91 18.53 Component name: Picrasinoside G minutes : Drift Times: 6.83 +/- 0.24 ms
5.30
0 603.27964
10000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
485.19879
5000
287.05505 657.25805
351.08497
145.02923 838.26730
671.23248

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3355 : DT=6.12 to 6.60 ms

25000

20000
Intensity [Counts]

15000

10000

5000

11.78 Ganoderic acid S


0 12.19
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.1861 +/- 0.0285
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3355 Component name: Ganoderic acid S minutes : Drift Times: 6.36 +/- 0.24 ms
7.76
511.17754

30000

50000

Intensity [Counts]
Intensity [Counts]

20000
25000
471.22054
527.14797
432.17721 545.20571 796.33024 928.82744
10000 0
16.65 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 12.1861 +/- 0.0285
13.30 Component name: Ganoderic acid S minutes : Drift Times: 6.20 +/- 0.24 ms
10.20 11.78
0 511.17800

0 5 10 15 20
30000
Retention time [min]

Intensity [Counts]
20000

10000 471.21276
216.98069 528.23897
410.26441 691.28786
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6α-Acetoxy-5-epilimonin [+H] : (39.7 PPM) 543.2601 : DT=6.56 to
7.04 ms

3000
Intensity [Counts]

2000

1000

6α-Acetoxy-5-epilimonin
12.32

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.2704 +/-
Channel name: 6α-Acetoxy-5-epilimonin [+H] : (39.7 PPM) 543.2601 Component name: 6α-Acetoxy-5-epilimonin 0.0285 minutes : Drift Times: 6.80 +/- 0.24 ms
8.59
513.26535
5000 8.39 10000

9.08

Intensity [Counts]
571.27396
4000
9.14 584.23566
Intensity [Counts]

5000 615.22429
9.19 290.10297
3000
6.12 490.16673
941.38156
5.70 889.28461
2000
9.42 16.51
0
12.36 200 400 600 800 1000
9.51
1000 12.90
11.35 Item name: MENGKUDU 2 Channel name: High energy : Time 12.2704 +/-
4.92 14.40
16.96 Component name: 6α-Acetoxy-5-epilimonin 0.0285 minutes : Drift Times: 6.65 +/- 0.24 ms
0.93 4.36
0 513.26922
15000
0 5 10 15 20
265.05196
Retention time [min]

Intensity [Counts]
10000 549.24806
402.17939
204.06637 559.30725
5000 176.07128 391.17460
583.26792
159.11695 619.21178
849.29069
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (rel 5S,6R,8R,9R,10S)-6-Acetoxy-9-hydroxy-13(14)-labden-16,15-
olide [+H] : (39.7 PPM) 379.2497 : DT=5.39 to 5.87 ms

4000
Intensity [Counts]

3000

2000

1000
12.32
(rel 5S,6R,8R,9R,10S)-6-Acetoxy-9-hydroxy-13(14)-labden-16,15-olide
12.27
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.2808 +/-
Channel name: (rel 5S,6R,8R,9R,10S)-6-Acetoxy-9-hydroxy-13(14)-labden-16,15- Component name: (rel 5S,6R,8R,9R,10S)-6- 0.0285 minutes : Drift Times: 5.63 +/- 0.24 ms
olide [+H] : (39.7 PPM) 379.2497 Acetoxy-9-hydroxy-13(14)-labden-16,15-olide
16.53
362.12412
375.21611
7500 10000

Intensity [Counts]
379.24973

407.18197
Intensity [Counts]

5000 5000

314.20967 536.18804 747.30859


257.06459
800.20869
0
2500
200 400 600 800 1000

11.48 12.27 Item name: MENGKUDU 2 Channel name: High energy : Time 12.2808 +/-
8.97 14.15
7.20 10.98 16.87 Component name: (rel 5S,6R,8R,9R,10S)-6- 0.0285 minutes : Drift Times: 5.48 +/- 0.24 ms
Acetoxy-9-hydroxy-13(14)-labden-16,15-olide
0
176.07115 379.24273
0 5 10 15 20
Retention time [min] 5000

Intensity [Counts]
362.12036
265.05314
393.22368
2500 621.17469
567.25928
723.33315

748.30886
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakihemiacetal F [+H] : (39.7 PPM) 393.2255 : DT=5.39 to 5.87 ms

1000

750
Intensity [Counts]

500
Nigakihemiacetal F
12.34

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.3446 +/- 0.0285
Channel name: Nigakihemiacetal F [+H] : (39.7 PPM) 393.2255 Component name: Nigakihemiacetal F minutes : Drift Times: 5.65 +/- 0.24 ms
5.74
442.11422
5000 7500 397.13123

393.22551

Intensity [Counts]
4000 5000
205.05002
Intensity [Counts]

487.20582 622.23527
351.12182
3000 671.22704
2500
682.74492
16.60
2000 776.29289
5.41 16.50
0
11.87 200 400 600 800 1000
5.05 8.65
1000 11.60 12.76 11.96 16.69 Item name: MENGKUDU 2 Channel name: High energy : Time 12.3446 +/- 0.0285
2.83 7.94 17.43 Component name: Nigakihemiacetal F minutes : Drift Times: 5.49 +/- 0.24 ms
3.55 6.53
1.79
0 145.02919

0 5 10 15 20 5000
Retention time [min]

Intensity [Counts]
159.11781
2500 421.23507
370.13401
456.16448 613.26877
704.17732

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 26,27-Dihydroxy-lanosta-7,9(11),24-triene-3,16-dion [+H] : (39.7
PPM) 469.3322 : DT=6.11 to 6.59 ms

1500
Intensity [Counts]

1000

500

26,27-Dihydroxy-lanosta-7,9(11),24-triene-3,16-dion
12.38
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.3730 +/-
Channel name: 26,27-Dihydroxy-lanosta-7,9(11),24-triene-3,16-dion [+H] : (39.7 Component name: 26,27-Dihydroxy- 0.0285 minutes : Drift Times: 6.35 +/- 0.24 ms
PPM) 469.3322 lanosta-7,9(11),24-triene-3,16-dion
13.68
496.10099
6000 7500 451.32106
565.21347

Intensity [Counts]
435.19670
5000 587.27144
426.28410
Intensity [Counts]

4000 387.14481

2500 789.26274 890.86343


223.06394

16.50
2000 13.56 0
200 400 600 800 1000
8.429.61 12.37 14.10
16.62
7.90 9.74 Item name: MENGKUDU 2 Channel name: High energy : Time 12.3730 +/-
14.24 16.91
Component name: 26,27-Dihydroxy- 0.0285 minutes : Drift Times: 6.20 +/- 0.24 ms
6.07
7.11 17.51 lanosta-7,9(11),24-triene-3,16-dion
0
556.28236
0 5 10 15 20 7500
Retention time [min]

Intensity [Counts]
5000 333.07775
449.16549
204.06793
163.03982 561.22639
2500
602.24900 820.31003

842.27599
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Pseudolaric acid A O-β-D-glucopyranoside [+H] : (39.7 PPM)
551.2482 : DT=6.39 to 6.87 ms

1500
Intensity [Counts]

1000

500

Pseudolaric acid A O-β-D-glucopyranoside


12.39
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.3786 +/-
Channel name: Pseudolaric acid A O-β-D-glucopyranoside [+H] : (39.7 PPM) Component name: Pseudolaric acid A O-β-D- 0.0285 minutes : Drift Times: 6.63 +/- 0.24 ms
551.2482 glucopyranoside
6.59
2500 555.27949
40000

2000

Intensity [Counts]
Intensity [Counts]

1500 6.76 20000

7.73 572.25983
16.52 451.32106
12.89
1000 10.67 16.85 722.19305 983.36234
16.31 405.31653
5.96 10.57 12.81 0
16.90 200 400 600 800 1000
500 5.44
16.99 Item name: MENGKUDU 2 Channel name: High energy : Time 12.3786 +/-
4.70 Component name: Pseudolaric acid A O-β-D- 0.0285 minutes : Drift Times: 6.48 +/- 0.24 ms
3.65 17.69
glucopyranoside
0
555.27908
0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
567.25412
10000

333.07775 417.15153
204.06793 613.25486 777.31800

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside C [+H] : (39.7 PPM) 555.2795 : DT=6.43 to 6.91 ms

3000 Picrasinoside C
12.39

2500

12.90
2000
Intensity [Counts]

1500

1000

13.10
500 12.24 13.24

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Picrasinoside C
0 12.40

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.3886 +/- 0.0285
Channel name: Picrasinoside C [+H] : (39.7 PPM) 555.2795 Component name: Picrasinoside C minutes : Drift Times: 6.68 +/- 0.24 ms
13.54
555.27949
5000 12.39 13.68
40000

Intensity [Counts]
4000
Intensity [Counts]

20000
3000
572.25983
553.26484
587.27144
2000 539.29638 888.86336 983.36234
290.10380
13.95 16.53 0
200 400 600 800 1000
1000 9.87 10.82
14.89 16.71 Item name: MENGKUDU 2 Channel name: High energy : Time 12.3886 +/- 0.0285
7.46 9.57
1.99 Component name: Picrasinoside C minutes : Drift Times: 6.52 +/- 0.24 ms
2.98 6.337.97 18.50
0 555.27908

0 5 10 15 20 20000
Retention time [min]

Intensity [Counts]
10000

333.07775 417.15153
572.22881
290.10368
615.20078 849.29644
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside B [+H] : (39.7 PPM) 553.2648 : DT=6.44 to 6.92 ms
13.24

13.16
1000
13.11
Intensity [Counts]

750
Picrasinoside B
12.42
500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.4110 +/- 0.0285
Channel name: Picrasinoside B [+H] : (39.7 PPM) 553.2648 Component name: Picrasinoside B minutes : Drift Times: 6.68 +/- 0.24 ms
13.16
13.53 555.27949
40000

13.69

Intensity [Counts]
1500
16.53
13.05
Intensity [Counts]

16.66 20000
13.01
1000 13.91
12.42 572.25983
527.24063
7.76 11.51 14.23 871.29872
10.49 576.23457 983.36234
452.32530 802.29221
290.10380
6.59 9.63 15.37 0
500 16.71
4.19 6.42 200 400 600 800 1000
16.80
17.00 Item name: MENGKUDU 2 Channel name: High energy : Time 12.4110 +/- 0.0285
3.62
Component name: Picrasinoside B minutes : Drift Times: 6.53 +/- 0.24 ms
18.40
2.85
0 545.20706

0 5 10 15 20 556.28236
7500
Retention time [min]

Intensity [Counts]
5000 333.07775
503.24671
290.10368 567.24951
495.21219
2500 198.96960 483.31347 572.22881
613.25486 849.29644

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone I [+H] : (39.7 PPM) 377.1957 : DT=5.45 to 5.94 ms

2000

1500
Intensity [Counts]

1000

500

Nigakilactone I
0 12.41
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.4128 +/- 0.0285
Channel name: Nigakilactone I [+H] : (39.7 PPM) 377.1957 Component name: Nigakilactone I minutes : Drift Times: 5.70 +/- 0.24 ms
5.13
421.17559

5000 403.20551 592.18340


377.19575

Intensity [Counts]
4000
375.21187 454.15045
4000
335.24505 599.67015
Intensity [Counts]

329.10378
739.23173
3000 2000
800.73947
808.31037
2000
0
200 400 600 800 1000
5.47
1000 8.26 9.13 Item name: MENGKUDU 2 Channel name: High energy : Time 12.4128 +/- 0.0285
11.94 16.57
1.44 7.32 13.58 Component name: Nigakilactone I minutes : Drift Times: 5.54 +/- 0.24 ms
2.28 3.83 17.88
0 177.05607

0 5 10 15 20
4000
Retention time [min]

Intensity [Counts]
396.27685 545.20695

216.06596 591.68439
377.22968 405.19276
2000 416.19330
856.25203

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: m-Isopropyltoluene [+H] : (39.7 PPM) 135.1175 : DT=3.45 to 3.93
ms
m-Isopropyltoluene
12.42

12.39
600
12.34
Intensity [Counts]

400 12.30

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.4138 +/- 0.0285
Channel name: m-Isopropyltoluene [+H] : (39.7 PPM) 135.1175 Component name: m-Isopropyltoluene minutes : Drift Times: 3.69 +/- 0.24 ms
8.73
181.12380
1250

10.62 30000
8.68
6.83

Intensity [Counts]
1000
12.43
20000
9.22
Intensity [Counts]

6.29 12.39
750 12.34
10000
13.72 16.61
500 205.05036
16.52
6.21 8.55
14.91 0
5.93
7.10 16.68 200 400 600 800 1000
5.04
250
Item name: MENGKUDU 2 Channel name: High energy : Time 12.4138 +/- 0.0285
1.80 4.14 16.76
Component name: m-Isopropyltoluene minutes : Drift Times: 3.54 +/- 0.24 ms

0 204.06769

0 5 10 15 20
Retention time [min]

Intensity [Counts]
4000

135.11756
2000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 7-O-Methylmorroniside [+H] : (39.7 PPM) 421.1720 : DT=5.76 to
6.24 ms

1250

1000
Intensity [Counts]

750

500 7-O-Methylmorroniside
12.44

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.4434 +/-
Channel name: 7-O-Methylmorroniside [+H] : (39.7 PPM) 421.1720 Component name: 7-O-Methylmorroniside 0.0285 minutes : Drift Times: 6.00 +/- 0.24 ms
2.95
20000
4000 451.19444

15000

Intensity [Counts]
3000 2.84

3.36 10000
Intensity [Counts]

2.78
449.17399 513.19506
10.16
2000 5000 350.23651 591.68399
9.99 204.06782 845.34624

3.56 6.82 8.05


0
2.34 3.60 5.88 9.19
1000 12.34 200 400 600 800 1000
5.49
2.25 12.38 Item name: MENGKUDU 2 Channel name: High energy : Time 12.4434 +/-
0.98 13.44 Component name: 7-O-Methylmorroniside 0.0285 minutes : Drift Times: 5.85 +/- 0.24 ms
14.49
16.64
0 451.19636

0 5 10 15 20
Retention time [min]

Intensity [Counts]
290.10387

5000

545.20695
216.06596
560.25312
133.10089
592.18598

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosylandrographoside [+H] : (39.7 PPM) 513.2667 : DT=6.46
to 6.94 ms
2000 19β-Glucosylandrographoside
12.46
11.92

1500
11.84
Intensity [Counts]

1000 11.71
12.59
11.46 12.68
11.42 12.75
500
11.28

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.4529 +/-
Channel name: 19β-Glucosylandrographoside [+H] : (39.7 PPM) 513.2667 Component name: 19β- 0.0285 minutes : Drift Times: 6.71 +/- 0.24 ms
12.44 Glucosylandrographoside

11.92 545.20494

30000 513.26674
3000

Intensity [Counts]
11.84
20000
Intensity [Counts]

2000 11.65
12.59 10000 565.21513
11.43 347.12889
12.69 629.22043 871.29872
16.61
13.94
16.55 0
1000 200 400 600 800 1000
8.72 10.14 14.00 16.74
14.08 Item name: MENGKUDU 2 Channel name: High energy : Time 12.4529 +/-
7.81 18.16
1.68 3.63 4.60 7.22 Component name: 19β- 0.0285 minutes : Drift Times: 6.55 +/- 0.24 ms
Glucosylandrographoside
0
20000 513.26904
0 5 10 15 20
Retention time [min]

Intensity [Counts]
347.13257
545.20706
10000

497.29685
297.07656 564.34885
803.30316 967.38669
197.02579
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Physalin E [+H] : (39.7 PPM) 545.2049 : DT=6.28 to 6.76 ms
Physalin E
12.45

2000
Intensity [Counts]

1500

1000

12.54

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.4532 +/- 0.0285 minutes :
Channel name: Physalin E [+H] : (39.7 PPM) 545.2049 Component name: Physalin E Drift Times: 6.53 +/- 0.24 ms
12.44
545.20494

4000 30000 513.26674

Intensity [Counts]
11.92 20000
3000
Intensity [Counts]

11.85 503.24470
10000
2000 347.12889
452.19240
8.71 629.22043 959.39422
767.25365
8.83 12.61
8.66 0
11.67 200 400 600 800 1000
1000 8.47 12.72 16.53
1.66 3.58 6.90 9.13
16.61 Item name: MENGKUDU 2 Channel name: High energy : Time 12.4532 +/- 0.0285 minutes :
4.68 13.58
16.88 18.53 Component name: Physalin E Drift Times: 6.38 +/- 0.24 ms

0 20000 513.26904

0 5 10 15 20
Retention time [min]

Intensity [Counts]
347.13257

10000 545.20706
304.11956

497.29685
207.06668
626.25105
803.30316 967.38669
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 2α-Acetoxycostic acid [+H] : (39.7 PPM) 293.1732 : DT=4.41 to 4.89
ms

3000
Intensity [Counts]

2000

1000
2α-Acetoxycostic acid
12.48

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.4663 +/-
Channel name: 2α-Acetoxycostic acid [+H] : (39.7 PPM) 293.1732 Component name: 2α-Acetoxycostic acid 0.0285 minutes : Drift Times: 4.65 +/- 0.24 ms
10.04
4000 6e5
304.12098

Intensity [Counts]
4e5
3000
Intensity [Counts]

2e5
2000
277.18079
261.20762 351.13167 492.17629
0
1000 7.45 9.54 16.60
200 400 600 800 1000
9.38 12.49 Item name: MENGKUDU 2 Channel name: High energy : Time 12.4663 +/-
4.34 5.01 6.86 16.72
11.44 13.93 Component name: 2α-Acetoxycostic acid 0.0285 minutes : Drift Times: 4.49 +/- 0.24 ms
1.37 2.10 3.58 15.70
17.19
0 304.11957

0 5 10 15 20
5e5
Retention time [min]

Intensity [Counts]
2.5e5

204.06761
309.11487
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 12S-Hydroxyandrographolide [+H] : (39.7 PPM) 369.2256 : DT=5.42
to 5.91 ms

4000

3000
Intensity [Counts]

2000

1000

12S-Hydroxyandrographolide
12.49

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.4871 +/-
Channel name: 12S-Hydroxyandrographolide [+H] : (39.7 PPM) 369.2256 Component name: 12S- 0.0285 minutes : Drift Times: 5.66 +/- 0.24 ms
13.08 Hydroxyandrographolide

369.22556
5000
10000

Intensity [Counts]
11.42 351.13120
4000
439.22947
Intensity [Counts]

10.34 5000 454.19222 613.23485


3000
683.20547
9.78 295.10339
750.27090
2000
177.05259
0
14.80
200 400 600 800 1000
13.22 14.91
1000 9.63 Item name: MENGKUDU 2 Channel name: High energy : Time 12.4871 +/-
1.44 16.57
5.70 9.47 Component name: 12S- 0.0285 minutes : Drift Times: 5.51 +/- 0.24 ms
1.81
0.65 3.71 16.72 Hydroxyandrographolide
0
451.19636
0 5 10 15 20
Retention time [min]
369.22596

Intensity [Counts]
5000 205.04993

91.05518 469.24355
574.22503 721.32931
765.24454
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Mudanpioside D [+H] : (39.7 PPM) 511.1801 : DT=6.12 to 6.61 ms

11.84

5000
Mudanpioside D
12.50

4000
Intensity [Counts]

3000

11.71
2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.4900 +/- 0.0285
Channel name: Mudanpioside D [+H] : (39.7 PPM) 511.1801 Component name: Mudanpioside D minutes : Drift Times: 6.36 +/- 0.24 ms
12.79
8000 511.18009
11.84
75000

Intensity [Counts]
6000
50000
Intensity [Counts]

11.72
4000 25000
9.95
470.25559 531.15172
337.10625
9.85 759.74802 892.37018
0
2000 9.62 200 400 600 800 1000
4.34 9.55
9.16 Item name: MENGKUDU 2 Channel name: High energy : Time 12.4900 +/- 0.0285
3.38 13.45 15.89
3.31 16.04 Component name: Mudanpioside D minutes : Drift Times: 6.21 +/- 0.24 ms
0.61
16.71
0 40000 511.18142

0 5 10 15 20
Retention time [min]

Intensity [Counts]
289.09015
20000

248.09324 497.29685 552.25132


639.21350 781.79044
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3-Hydroxy-12,14-diene-27-nordeane-28-nic acid [+H] : (39.7 PPM)
455.3167 : DT=6.11 to 6.59 ms
12.61
800

12.27
600
Intensity [Counts]

12.67

400

3-Hydroxy-12,14-diene-27-nordeane-28-nic acid
12.43
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.4949 +/-
Channel name: 3-Hydroxy-12,14-diene-27-nordeane-28-nic acid [+H] : (39.7 PPM) Component name: 3-Hydroxy-12,14- 0.0285 minutes : Drift Times: 6.35 +/- 0.24 ms
455.3167 diene-27-nordeane-28-nic acid
16.52
511.18009
1500
75000

Intensity [Counts]
12.61
12.56 50000
Intensity [Counts]

1000 12.34 16.56


3.93 12.68
9.55 12.26 16.62 25000
7.98 470.25559 531.15172
337.10625
13.52 759.74802 892.37018
500 9.72 0
14.08 16.91
200 400 600 800 1000
16.98 Item name: MENGKUDU 2 Channel name: High energy : Time 12.4949 +/-
7.80
2.42 Component name: 3-Hydroxy-12,14- 0.0285 minutes : Drift Times: 6.20 +/- 0.24 ms
1.55 5.09 7.71 17.36
diene-27-nordeane-28-nic acid
0
40000 511.18142
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
289.09015
481.20013

248.09324 552.25132
453.20373
639.21350 781.79044
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinol A [+H] : (39.7 PPM) 437.2520 : DT=6.29 to 6.77 ms

600
Intensity [Counts]

400

200

Picrasinol A
12.55

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.5079 +/- 0.0285 minutes :
Channel name: Picrasinol A [+H] : (39.7 PPM) 437.2520 Component name: Picrasinol A Drift Times: 6.53 +/- 0.24 ms
6.40
511.18009
5000 75000

Intensity [Counts]
4000
50000
Intensity [Counts]

3000
25000
481.19880
16.59
447.21410 543.18561
2000 16.52
275.20218 759.74802 892.37018
0
11.13 200 400 600 800 1000
1000 11.24 13.94 Item name: MENGKUDU 2 Channel name: High energy : Time 12.5079 +/- 0.0285
8.01
5.84 10.76 14.64 Component name: Picrasinol A minutes : Drift Times: 6.37 +/- 0.24 ms
2.22 3.07 17.58 18.49
0 40000 511.18142

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

481.20013

552.25132
144.10231 290.10377 850.38292
639.21350 781.79044
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2881 : DT=6.87 to 7.36 ms
Azedarachin C
12.53

6000

12.12
Intensity [Counts]

4000

12.07

2000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Azedarachin C
12.51
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.5315 +/- 0.0285
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2881 Component name: Azedarachin C minutes : Drift Times: 7.12 +/- 0.24 ms
12.53
10000 587.28814
100000

Intensity [Counts]
7500 15.14
12.13
609.26962
Intensity [Counts]

50000
15.38
5000 570.26293
11.81 610.27157
15.96 433.17158 655.23874 878.29240
11.73 0
2500 16.41 200 400 600 800 1000
11.43 13.04
8.57 11.02 16.49 Item name: MENGKUDU 2 Channel name: High energy : Time 12.5315 +/- 0.0285
8.07 Component name: Azedarachin C minutes : Drift Times: 6.97 +/- 0.24 ms
2.44 3.51
30000 609.27055
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000 587.28767

433.17685

10000 242.11766
415.17199 611.28713
240.10466 649.32251 791.27577

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Kansuinin E [+H] : (39.7 PPM) 778.3082 : DT=8.39 to 8.87 ms

800

600
Intensity [Counts]

Kansuinin E
12.54
400
12.48

12.36

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.5423 +/- 0.0285 minutes :
Channel name: Kansuinin E [+H] : (39.7 PPM) 778.3082 Component name: Kansuinin E Drift Times: 8.53 +/- 0.24 ms
14.50
2000 803.30963

7500

Intensity [Counts]
1500 12.74 735.31690 833.30131
5000
Intensity [Counts]

860.31642
12.53 588.29097 721.32701
1000 2500
1.66 11.96 505.35041
9.99
425.13512
8.41 0
500 3.79 7.34 16.49 200 400 600 800 1000
1.45 5.61 16.58 18.52 Item name: MENGKUDU 2 Channel name: High energy : Time 12.5423 +/- 0.0285
3.39
Component name: Kansuinin E minutes : Drift Times: 8.38 +/- 0.24 ms

0 803.31370

0 5 10 15 20
Retention time [min] 4000 747.31556

Intensity [Counts]
805.32928
865.46627
2000 609.27088
426.15448
162.05729

333.11130
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Notonipetranone [+H] : (39.7 PPM) 379.2462 : DT=5.24 to 5.72 ms

3000
Intensity [Counts]

2000

1000

Notonipetranone
0 12.55
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.5642 +/- 0.0285
Channel name: Notonipetranone [+H] : (39.7 PPM) 379.2462 Component name: Notonipetranone minutes : Drift Times: 5.48 +/- 0.24 ms
16.53
365.19365
8000 7500 360.25420 375.21745

Intensity [Counts]
379.24617
6000 5000
391.17494
Intensity [Counts]

424.15671
335.17632
467.18606 667.23011
2500
4000 205.05043 688.74305 988.30605

820.20054
0
200 400 600 800 1000
2000
11.48 12.27 Item name: MENGKUDU 2 Channel name: High energy : Time 12.5642 +/- 0.0285
8.97 14.68 16.87 Component name: Notonipetranone minutes : Drift Times: 5.32 +/- 0.24 ms
7.18
0 288.12300 383.15639

0 5 10 15 20 4000 385.29525
Retention time [min]

Intensity [Counts]
91.05537

216.06825
2000 424.16304
636.15424
532.12366

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 2-Hydroxyesculentic acid [+H] : (39.7 PPM) 519.3332 : DT=6.41 to
6.89 ms

1500
Intensity [Counts]

1000

500 2-Hydroxyesculentic acid


12.57

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.5690 +/-
Channel name: 2-Hydroxyesculentic acid [+H] : (39.7 PPM) 519.3332 Component name: 2-Hydroxyesculentic acid 0.0285 minutes : Drift Times: 6.65 +/- 0.24 ms
16.66
454.31933
3000
20000

Intensity [Counts]
16.60
513.26360
Intensity [Counts]

2000
10000
547.22279

433.31110 563.28611
263.12792 351.13079 612.24923 864.34797

1000 14.36
0
200 400 600 800 1000
9.73 12.48 13.52
6.88 7.64
16.91 Item name: MENGKUDU 2 Channel name: High energy : Time 12.5690 +/-
6.37 16.96 Component name: 2-Hydroxyesculentic acid 0.0285 minutes : Drift Times: 6.50 +/- 0.24 ms
4.17
0 7500 511.25537

0 5 10 15 20
Retention time [min]

Intensity [Counts]
5000
529.23316
181.05114 493.23338
573.26923
351.08716 641.26299
2500 263.07096
815.27619

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside C [+H] : (39.7 PPM) 555.2799 : DT=7.04 to 7.53 ms

12.84
12.91
500 12.39

400
Intensity [Counts]

300 Picrasinoside C
12.58

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.5769 +/- 0.0285
Channel name: Picrasinoside C [+H] : (39.7 PPM) 555.2799 Component name: Picrasinoside C minutes : Drift Times: 7.28 +/- 0.24 ms
13.54
10000 619.13527
5000 12.39 13.68

605.29229
7500

Intensity [Counts]
4000 555.27992
522.18725 635.21601
5000
Intensity [Counts]

3000 659.12326
693.30811
2500 425.16553
743.26932 979.33265
2000
918.29209
13.95 16.53 0
200 400 600 800 1000
1000 9.87 10.82
14.89 16.71 Item name: MENGKUDU 2 Channel name: High energy : Time 12.5769 +/- 0.0285
9.57
1.99 8.95 Component name: Picrasinoside C minutes : Drift Times: 7.13 +/- 0.24 ms
2.98 6.33 18.50
0 391.17065
4000
0 5 10 15 20
Retention time [min] 167.07040 387.14221 604.29187

Intensity [Counts]
559.28422 659.12516
367.16075
676.36007
2000
207.06699
699.26510

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Chloranthalactone E [+H] : (39.7 PPM) 263.1280 : DT=4.25 to 4.73
ms
Chloranthalactone E
4000
12.60

12.55

3000
Intensity [Counts]

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.5812 +/- 0.0285
Channel name: Chloranthalactone E [+H] : (39.7 PPM) 263.1280 Component name: Chloranthalactone E minutes : Drift Times: 4.50 +/- 0.24 ms
12.59
5000 263.12797
75000

4000

Intensity [Counts]
50000
Intensity [Counts]

3000
25000

2000 247.15439 271.06433


319.08139 539.19281
0
200 400 600 800 1000
1000
0.58 Item name: MENGKUDU 2 Channel name: High energy : Time 12.5812 +/- 0.0285
5.27 5.94 8.30 Component name: Chloranthalactone E minutes : Drift Times: 4.34 +/- 0.24 ms
5.22 11.09 13.64 16.49
1.47 18.49
0 263.12771

0 5 10 15 20
Retention time [min]

Intensity [Counts]
40000

20000

241.10384

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid H [+H] : (39.7 PPM) 573.3047 : DT=6.87 to 7.36 ms

1500
Intensity [Counts]

1000

500
Ganoderic acid H
12.58

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.5871 +/- 0.0285
Channel name: Ganoderic acid H [+H] : (39.7 PPM) 573.3047 Component name: Ganoderic acid H minutes : Drift Times: 7.12 +/- 0.24 ms
9.92
7500
555.27992 619.25386
5000

Intensity [Counts]
4000 5000 625.24582
10.35

631.21781
Intensity [Counts]

549.21560 645.29916
3000 917.82088
2500 474.21682 743.26932

388.14221
2000
0
16.50 200 400 600 800 1000
1000 10.68 12.59 16.60
Item name: MENGKUDU 2 Channel name: High energy : Time 12.5871 +/- 0.0285
6.43 7.439.19 13.43
Component name: Ganoderic acid H minutes : Drift Times: 6.96 +/- 0.24 ms
2.85 16.90
3.70 5.10
0 543.32382

0 5 10 15 20 569.28009
4000
Retention time [min]

Intensity [Counts]
604.29187
488.23712
207.06699
359.12305 632.29285
2000
357.19852 652.27324
144.09807
699.26510

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Clinopodiside F [+H] : (39.7 PPM) 991.5459 : DT=9.18 to 9.66 ms

250

200
Intensity [Counts]

150

100

50 Clinopodiside F
12.70

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.6528 +/- 0.0285
Channel name: Clinopodiside F [+H] : (39.7 PPM) 991.5459 Component name: Clinopodiside F minutes : Drift Times: 9.42 +/- 0.24 ms
16.54
600 15000 961.40043
16.48
16.59

500 16.69
16.73

Intensity [Counts]
10000
16.82
400
Intensity [Counts]

16.86
10.26 797.33838
5000
300 950.33338
13.19 14.30 417.15582
200
8.48 9.63 12.91 14.75 0
4.91 18.51
2.14 6.93 200 400 600 800 1000
3.74 5.09
100 Item name: MENGKUDU 2 Channel name: High energy : Time 12.6528 +/- 0.0285
Component name: Clinopodiside F minutes : Drift Times: 9.27 +/- 0.24 ms

0 417.15900
4000
0 5 10 15 20
Retention time [min] 961.40474

Intensity [Counts]
781.33993

2000 175.04008 929.24210


387.14617 418.16431 633.22874

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosylandrographoside [+H] : (39.7 PPM) 513.2680 : DT=6.52
to 7.00 ms
12.45

2000

1500
Intensity [Counts]

12.59
1000

19β-Glucosylandrographoside
12.68
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

19β-Glucosylandrographoside
0 12.66
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.6783 +/-
Channel name: 19β-Glucosylandrographoside [+H] : (39.7 PPM) 513.2680 Component name: 19β- 0.0285 minutes : Drift Times: 6.73 +/- 0.24 ms
12.44 Glucosylandrographoside

11.92 513.26804

10000 481.19887
3000
417.15540

Intensity [Counts]
11.84
571.26872
Intensity [Counts]

613.22516
5000
2000 11.65
12.59 626.18854 918.30901

312.12425 637.22744
11.43 12.69
16.61
16.54 0
1000 8.72 200 400 600 800 1000
10.14 16.74
14.08
7.81 14.35 Item name: MENGKUDU 2 Channel name: High energy : Time 12.6783 +/-
1.68 4.60 7.22 18.16
Component name: 19β- 0.0285 minutes : Drift Times: 6.58 +/- 0.24 ms
3.22 Glucosylandrographoside
0
10000 205.05092
0 5 10 15 20
Retention time [min]

Intensity [Counts]
347.13161
517.29882
5000
536.32293
599.24828
664.24686 817.33179 960.39889

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1604 : DT=5.99 to 6.47 ms

2500

2000
Intensity [Counts]

1500

1000
Picroside Ⅱ
12.70
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.6975 +/- 0.0285
Channel name: Picroside Ⅱ [+H] : (39.7 PPM) 513.1604 Component name: Picroside Ⅱ minutes : Drift Times: 6.23 +/- 0.24 ms
9.79
445.18456
6000

9.51
50000

Intensity [Counts]
4000
Intensity [Counts]

25000 490.19942

10.02
513.16044
209.11668 820.31759
11.70 334.12975 745.75341
2000 0
2.31 4.54 5.32 200 400 600 800 1000
7.55
4.09 6.26 Item name: MENGKUDU 2 Channel name: High energy : Time 12.6975 +/- 0.0285
0.58 12.70
13.19 16.55 Component name: Picroside Ⅱ minutes : Drift Times: 6.07 +/- 0.24 ms

0 445.18430

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
490.19937
177.05564
10000 249.11011

157.10204 417.15838 497.19416


632.19805 779.32719 959.39864
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2100 : DT=5.64 to 6.12 ms

800

600
Intensity [Counts]

400

Cichorioside C
12.72

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.7175 +/- 0.0285
Channel name: Cichorioside C [+H] : (39.7 PPM) 429.2100 Component name: Cichorioside C minutes : Drift Times: 5.88 +/- 0.24 ms
13.64
1500 445.18456
8.24 13.50

8.21 8.94 50000

Intensity [Counts]
9.02
9.06
1000
Intensity [Counts]

7.14 9.15 13.01


5.80 222.07748
25000
446.18769
5.25
16.53 397.17787 449.17825
5.09 9.43
4.44 11.63 16.59 388.14675 451.19420 861.26833
745.75341
500
14.51 16.64 0
3.38 200 400 600 800 1000
3.17 16.69
0.96 Item name: MENGKUDU 2 Channel name: High energy : Time 12.7175 +/- 0.0285
18.55 Component name: Cichorioside C minutes : Drift Times: 5.72 +/- 0.24 ms

0 445.18430

0 5 10 15 20
162.05566
Retention time [min] 20000

Intensity [Counts]
177.05564

10000 249.11011 449.18273

290.10262
454.18780
713.28497 880.30935
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (rel 5S,6R,8R,9R,10S)-6-Acetoxy-9-hydroxy-13(14)-labden-16,15-
olide [+H] : (39.7 PPM) 379.2468 : DT=5.33 to 5.81 ms

4000

3000
Intensity [Counts]

2000

1000

(rel 5S,6R,8R,9R,10S)-6-Acetoxy-9-hydroxy-13(14)-labden-16,15-olide
0 12.75
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.7569 +/-
Channel name: (rel 5S,6R,8R,9R,10S)-6-Acetoxy-9-hydroxy-13(14)-labden-16,15- Component name: (rel 5S,6R,8R,9R,10S)-6- 0.0285 minutes : Drift Times: 5.57 +/- 0.24 ms
olide [+H] : (39.7 PPM) 379.2468 Acetoxy-9-hydroxy-13(14)-labden-16,15-olide
16.53
367.20882

15000
7500

Intensity [Counts]
10000 393.22395
Intensity [Counts]

336.14412
5000 397.25575
5000
205.05121 455.20175
725.16618 861.26755
0
2500 200 400 600 800 1000

11.48 12.27 Item name: MENGKUDU 2 Channel name: High energy : Time 12.7569 +/-
8.97 14.68 16.87 Component name: (rel 5S,6R,8R,9R,10S)-6- 0.0285 minutes : Drift Times: 5.42 +/- 0.24 ms
7.18 Acetoxy-9-hydroxy-13(14)-labden-16,15-olide
0
321.11978
0 5 10 15 20
Retention time [min] 367.21029
10000

Intensity [Counts]
167.07128 393.22679
5000
421.21861
130.06572
454.18780 753.20456

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: RhodomolleinⅠ [+H] : (39.7 PPM) 369.2270 : DT=5.36 to 5.84 ms
13.08

3000
Intensity [Counts]

2000

1000

RhodomolleinⅠ
0 12.75
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.7589 +/- 0.0285
Channel name: RhodomolleinⅠ [+H] : (39.7 PPM) 369.2270 Component name: RhodomolleinⅠ minutes : Drift Times: 5.60 +/- 0.24 ms
13.08
367.20882

5000 15000

Intensity [Counts]
4000 11.42
10000
393.22395
Intensity [Counts]

336.14412
10.34 397.25575
3000
5000
9.78 205.05121 455.20175
685.15523 861.26755
2000
0
14.80 200 400 600 800 1000
1000 13.59 14.91 16.57 Item name: MENGKUDU 2 Channel name: High energy : Time 12.7589 +/- 0.0285
1.44 8.33
7.51 Component name: RhodomolleinⅠ minutes : Drift Times: 5.45 +/- 0.24 ms
2.97 5.71
3.71 16.72
0 10000 367.21029

0 5 10 15 20
Retention time [min]

Intensity [Counts]
5000 167.07128 393.22679

421.21861

454.18780 753.20456
608.21782
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosylandrographoside [+H] : (39.7 PPM) 513.2695 : DT=6.37
to 6.85 ms
12.46
2000

1500
Intensity [Counts]

12.59
1000
12.69

19β-Glucosylandrographoside
500 12.78

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.7705 +/-
Channel name: 19β-Glucosylandrographoside [+H] : (39.7 PPM) 513.2695 Component name: 19β- 0.0285 minutes : Drift Times: 6.61 +/- 0.24 ms
12.44 Glucosylandrographoside
481.27366 567.25307
11.92

3000 10000

Intensity [Counts]
11.84 461.19732 571.26212
603.28465
Intensity [Counts]

2000 5000
11.65 861.26765
12.59 437.29555 807.34596
877.24396
11.44 12.69 387.14514 709.20281
16.60
16.54 0
1000 8.72
16.74 200 400 600 800 1000
10.14 14.08
7.81 14.35 16.87 Item name: MENGKUDU 2 Channel name: High energy : Time 12.7705 +/-
1.69 4.60 7.22 18.16 Component name: 19β- 0.0285 minutes : Drift Times: 6.46 +/- 0.24 ms
3.22 Glucosylandrographoside
0
461.18941
0 5 10 15 20
Retention time [min]

Intensity [Counts]
597.24720

5000
319.09877

301.11580
661.27713
981.35262

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Mudanpioside D [+H] : (39.7 PPM) 511.1808 : DT=6.10 to 6.58 ms
Mudanpioside D
12.79
5000

4000
Intensity [Counts]

3000

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Mudanpioside D
12.78
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.7833 +/- 0.0285
Channel name: Mudanpioside D [+H] : (39.7 PPM) 511.1808 Component name: Mudanpioside D minutes : Drift Times: 6.34 +/- 0.24 ms
12.79
8000 511.18079
11.84

75000

Intensity [Counts]
6000
50000
Intensity [Counts]

11.72
4000 25000
481.27366 527.14578
9.95
709.20281
9.85 240.08531 461.19732 833.77998
0
2000 9.62 200 400 600 800 1000
4.34
9.36
9.16 Item name: MENGKUDU 2 Channel name: High energy : Time 12.7833 +/- 0.0285
3.38 13.45 15.89
3.31 Component name: Mudanpioside D minutes : Drift Times: 6.19 +/- 0.24 ms
0.61 16.04
16.71
0 511.18218

0 5 10 15 20
Retention time [min] 40000

Intensity [Counts] 20000


289.09056
77.03938
513.26181

616.26664 743.28089 877.38254


0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside B [+H] : (39.7 PPM) 553.2655 : DT=6.48 to 6.96 ms
13.24

13.16
1000
13.11
Intensity [Counts]

750

12.41
500
Picrasinoside B
12.81

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.8300 +/- 0.0285
Channel name: Picrasinoside B [+H] : (39.7 PPM) 553.2655 Component name: Picrasinoside B minutes : Drift Times: 6.72 +/- 0.24 ms
13.16
13.53 511.25246

20000
13.69

Intensity [Counts]
1500 569.25872
16.53
13.05 16.66
Intensity [Counts]

13.01 10000
483.31298 595.21958
1000 13.91
12.42 473.32728 601.26964
7.76 10.49 14.23 925.30152
10.44 223.06367 350.16146 760.26519
6.59 15.37 0
500 16.71
4.19 6.42 200 400 600 800 1000
17.00
Item name: MENGKUDU 2 Channel name: High energy : Time 12.8300 +/- 0.0285
3.62 18.19 Component name: Picrasinoside B minutes : Drift Times: 6.57 +/- 0.24 ms
2.85
0 569.26134
10000
0 5 10 15 20 481.27632
Retention time [min]

Intensity [Counts]
304.12000
5000 322.13023
367.20585
119.05168 618.29466
737.27361 884.31384

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-17β-hydroxyandrographolide [+H] : (39.7 PPM)
369.2264 : DT=5.38 to 5.86 ms
13.08
4000

3000
Intensity [Counts]

2000

1000
14-Deoxy-17β-hydroxyandrographolide
12.86

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.8633 +/-
Channel name: 14-Deoxy-17β-hydroxyandrographolide [+H] : (39.7 PPM) 369.2264 Component name: 14-Deoxy-17β- 0.0285 minutes : Drift Times: 5.62 +/- 0.24 ms
13.08 hydroxyandrographolide

369.22642
5000

10000

Intensity [Counts]
4000 11.42
Intensity [Counts]

205.05137
10.34
3000 5000 445.11453
345.11118
9.78 645.27889
543.19091 776.30602
2000
0
14.80 200 400 600 800 1000
13.22 14.91
1000 Item name: MENGKUDU 2 Channel name: High energy : Time 12.8633 +/-
1.44 8.34 9.63 16.57
9.47 Component name: 14-Deoxy-17β- 0.0285 minutes : Drift Times: 5.47 +/- 0.24 ms
2.97 5.71
3.71 16.72 hydroxyandrographolide
0
4000 345.11218
0 5 10 15 20
377.23769
Retention time [min]
409.25257

Intensity [Counts]
223.06163 451.19921
2000
215.97523
578.25740 747.33125

175.07606 757.30972

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Mudanpioside H [+H] : (39.7 PPM) 617.1862 : DT=7.21 to 7.69 ms

3000
Intensity [Counts]

2000

1000
Mudanpioside H
12.91

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.8996 +/- 0.0285
Channel name: Mudanpioside H [+H] : (39.7 PPM) 617.1862 Component name: Mudanpioside H minutes : Drift Times: 7.46 +/- 0.24 ms
8.17
657.18158
6000 75000

Intensity [Counts]
3.44 50000
3.56 8.87
4000
Intensity [Counts]

25000
3.20 3.84 586.26060
666.26689
12.18 289.09328 369.09752 540.25872
764.32561
2000 7.26
0
4.33 6.73 200 400 600 800 1000
1.84 3.10 10.04 12.92
6.04 Item name: MENGKUDU 2 Channel name: High energy : Time 12.8996 +/- 0.0285
16.49 Component name: Mudanpioside H minutes : Drift Times: 7.31 +/- 0.24 ms
13.40
18.53
0 15000 657.18295
289.09086
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
608.23793
539.26678
319.06151
5000 680.18481
495.17770
176.07071 843.25741

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Prosapogenin 1 [+H] : (39.7 PPM) 707.4017 : DT=7.78 to 8.26 ms

3000

2000
Intensity [Counts]

1000

Prosapogenin 1
0 12.90
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.9033 +/- 0.0285
Channel name: Prosapogenin 1 [+H] : (39.7 PPM) 707.4017 Component name: Prosapogenin 1 minutes : Drift Times: 8.02 +/- 0.24 ms
13.68
789.33613

5000 50000

Intensity [Counts]
811.31888
4000
Intensity [Counts]

25000
3000 751.21123
821.31753
13.54 587.28662 666.26731 843.25984
2000 381.13701
16.49 0
200 400 600 800 1000
16.70
13.94
1000 9.38 16.90 Item name: MENGKUDU 2 Channel name: High energy : Time 12.9033 +/- 0.0285
12.90 14.81
9.61 Component name: Prosapogenin 1 minutes : Drift Times: 7.87 +/- 0.24 ms
6.12 16.98
15000 666.27075 789.33515
0
0 5 10 15 20 811.32266
Retention time [min]

Intensity [Counts]
10000

634.24452
555.28033
5000 827.29941

235.07729 861.28905
318.13639 531.25030
191.07190 890.25394
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2382 : DT=5.68 to 6.16 ms

1500

1000
Intensity [Counts]

500 Nigakilactone J
12.92

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.9198 +/- 0.0285
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2382 Component name: Nigakilactone J minutes : Drift Times: 5.92 +/- 0.24 ms
15.12
425.25334
40000

2000
375.15762

Intensity [Counts]
Intensity [Counts]

1500 16.54 20000


13.60

13.55 16.67 369.09805


11.20
1000
13.14 13.45 349.24074 427.23118 705.23080
809.75283
2.94 10.89
0
6.56 10.40 200 400 600 800 1000
500 16.75
5.56 8.43
Item name: MENGKUDU 2 Channel name: High energy : Time 12.9198 +/- 0.0285
2.44 4.06 16.94 Component name: Nigakilactone J minutes : Drift Times: 5.76 +/- 0.24 ms
0.98
0 425.25434
375.15593
0 5 10 15 20
15000
Retention time [min]

Intensity [Counts]
10000

5000 347.13192 476.13751


263.07199
622.15759 757.30972
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-11-oxoandrographolide [+H] : Florilenalin isovalerate
[+H] : (39.7 PPM) 349.2005 : DT=4.98 to 5.46 ms

Florilenalin isovalerate
12.93
4000

3000
Intensity [Counts]

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 12.9324 +/-
Channel name: 14-Deoxy-11-oxoandrographolide [+H] : Florilenalin isovalerate Component name: 14-Deoxy-11- 0.0285 minutes : Drift Times: 5.21 +/- 0.24 ms
[+H] : (39.7 PPM) 349.2005 oxoandrographolide
13.74
13.42 349.20050

6000 12.94 15.47

50000

Intensity [Counts]
16.54
Intensity [Counts]

4000 16.60
25000
365.19387

5.02 244.15680 383.14969


12.75 789.33624
561.18195
2000 0
12.28
200 400 600 800 1000
11.62
16.75 Item name: MENGKUDU 2 Channel name: High energy : Time 12.9324 +/-
7.67 8.34 11.12
4.66 Component name: 14-Deoxy-11- 0.0285 minutes : Drift Times: 5.06 +/- 0.24 ms
2.78 6.08 16.98 oxoandrographolide
0
349.20141
0 5 10 15 20
Retention time [min] 20000

Intensity [Counts] 10000


347.16196
351.08927
279.15502 583.25654
473.13317
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2 Channel name: Low energy : Time 12.9324 +/-
Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.21 +/- 0.24 ms

349.20050

50000

Intensity [Counts]
25000
365.19387
244.15680 383.14969
561.18195 789.33624
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 12.9324 +/-
Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.06 +/- 0.24 ms

349.20141

20000

Intensity [Counts]
10000

347.16196
351.08927
583.25654
303.10243 473.13317
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone G [+H] : (39.7 PPM) 475.2324 : DT=6.28 to 6.77 ms

1250

1000
Intensity [Counts]

750

500 Nigakilactone G
13.02

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.0223 +/- 0.0285
Channel name: Nigakilactone G [+H] : (39.7 PPM) 475.2324 Component name: Nigakilactone G minutes : Drift Times: 6.52 +/- 0.24 ms
7.02
583.15853
515.28486
6.65 10000 477.23333
10.61

Intensity [Counts]
3000 427.10473
7.15
Intensity [Counts]

6.56 5000
402.15620 601.26308
2000
373.12651 915.33757
603.26834
352.11997
6.09
7.45 0
1000 5.14 16.53 200 400 600 800 1000
7.64 10.68 13.02
4.98 16.59 Item name: MENGKUDU 2 Channel name: High energy : Time 13.0223 +/- 0.0285
14.20 16.76 18.32 Component name: Nigakilactone G minutes : Drift Times: 6.37 +/- 0.24 ms
4.24
3.59
0 160.09708

0 5 10 15 20 191.03467
Retention time [min] 4000 287.05656

Intensity [Counts]
475.24067
583.15289
622.18347
2000
777.27315
841.25852

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Rhodojaponin Ⅱ [+H] : (39.7 PPM) 411.2371 : DT=5.57 to 6.05 ms

1000

750
Intensity [Counts]

12.62
500
12.87

12.39
Rhodojaponin Ⅱ
250 13.00

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.0305 +/- 0.0285
Channel name: Rhodojaponin Ⅱ [+H] : (39.7 PPM) 411.2371 Component name: Rhodojaponin Ⅱ minutes : Drift Times: 5.81 +/- 0.24 ms
7.88
425.25254
100000

1500

Intensity [Counts]
Intensity [Counts]

50000
1000
16.56 397.25759
8.65 12.62 16.62
12.56 12.87 367.25436 619.13158 698.30075 852.33372
7.61 9.85 16.71 191.03662
4.81 7.36 9.22 13.85 0
500 2.77
200 400 600 800 1000
2.61 7.31
16.96 Item name: MENGKUDU 2 Channel name: High energy : Time 13.0305 +/- 0.0285
2.51 Component name: Rhodojaponin Ⅱ minutes : Drift Times: 5.66 +/- 0.24 ms
0.73
0 425.25360

0 5 10 15 20
50000
Retention time [min]

Intensity [Counts]
25000 397.25708
177.05612

204.06655 427.25869
691.23714
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3358 : DT=6.31 to 6.79 ms
7.76

12500

10000
Intensity [Counts]

7500

5000

2500

10.19 11.78 13.30 16.60 17.61

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.0374 +/- 0.0285
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3358 Component name: Ganoderic acid S minutes : Drift Times: 6.55 +/- 0.24 ms
7.76
517.20583

30000 515.28486

Intensity [Counts]
10000 477.23333
527.22018
Intensity [Counts]

567.25462
20000 475.23241
5000
453.33585 570.32545
402.15620 915.33757
603.26834
331.17889

10000 0
16.65 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 13.0374 +/- 0.0285
13.30 Component name: Ganoderic acid S minutes : Drift Times: 6.39 +/- 0.24 ms
10.20 11.78
0 555.27866

0 5 10 15 20 7500 517.20736
Retention time [min]

Intensity [Counts]
5000 191.03467 483.25965
287.05656
583.15289
2500
622.18347 793.28481

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 7β-(3-Ethyl-cis-crotonoyloxy)-14-hydroxynotonipetranone [+H] :
(39.7 PPM) 349.2380 : DT=5.41 to 5.90 ms

1000
Intensity [Counts]

500
12.91
7β-(3-Ethyl-cis-crotonoyloxy)-14-hydroxynotonipetranone
13.05

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.0432 +/-
Channel name: 7β-(3-Ethyl-cis-crotonoyloxy)-14-hydroxynotonipetranone [+H] : Component name: 7β-(3-Ethyl-cis- 0.0285 minutes : Drift Times: 5.65 +/- 0.24 ms
(39.7 PPM) 349.2380 crotonoyloxy)-14-hydroxynotonipetranone
16.63
402.15630

3000
40000

Intensity [Counts]
375.15741
Intensity [Counts]

16.52
2000 20000

367.25436 411.23710
640.17942
275.20218 457.18806 775.30331
0
1000
13.04 200 400 600 800 1000
12.91 15.47 Item name: MENGKUDU 2 Channel name: High energy : Time 13.0432 +/-
12.10 16.85 Component name: 7β-(3-Ethyl-cis- 0.0285 minutes : Drift Times: 5.50 +/- 0.24 ms
4.29 10.07
3.99 16.93 crotonoyloxy)-14-hydroxynotonipetranone
0
384.14774
0 5 10 15 20
15000
Retention time [min] 375.15573 397.25708

Intensity [Counts]
10000 204.06655

370.22933
5000 181.05153
342.13105 433.17810
691.23714
483.09183
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Fibraurin [+H] : (39.7 PPM) 373.1264 : DT=4.89 to 5.37 ms
1.89

2000
Intensity [Counts]

1500

12.10
1000

7.72 12.07
4.96
500 1.44 3.02
5.75 8.41 9.21
1.21 3.99 16.52
13.30
15.40
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.1184 +/- 0.0285 minutes :
Channel name: Fibraurin [+H] : (39.7 PPM) 373.1264 Component name: Fibraurin Drift Times: 5.13 +/- 0.24 ms
7.71
349.20078
20000
4000
1.89

Intensity [Counts]
3000 0.62
Intensity [Counts]

10000
12.10 339.21562
365.19592
7.05 325.20085
2000 373.12637 573.25008
291.19741 746.27617
5.73 553.25814 671.25500

9.43 0
6.78
3.03 4.96 200 400 600 800 1000
1000 9.58
13.09
Item name: MENGKUDU 2 Channel name: High energy : Time 13.1184 +/- 0.0285 minutes :
13.39 14.60 Component name: Fibraurin Drift Times: 4.98 +/- 0.24 ms
18.54
3000 273.18734
0 347.18666

0 5 10 15 20
91.05444
Retention time [min] 363.12396

Intensity [Counts]
2000

421.12105
683.14299
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2360 : DT=5.70 to 6.18 ms

1500
Intensity [Counts]

1000

12.92
Nigakilactone J
13.14
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.1356 +/- 0.0285
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2360 Component name: Nigakilactone J minutes : Drift Times: 5.94 +/- 0.24 ms
15.12
397.25778
15000

2000

Intensity [Counts]
423.23601
10000
Intensity [Counts]

1500 13.60 16.54

360.25560 469.20458
16.58 5000
347.13005 483.26679
11.20 721.25160 816.23080
1000 286.10773 583.67095
10.89 13.45 16.67
2.94
10.60 0
6.56 10.40 200 400 600 800 1000
500 5.56 16.75
9.77 Item name: MENGKUDU 2 Channel name: High energy : Time 13.1356 +/- 0.0285
2.44 4.06 16.94 Component name: Nigakilactone J minutes : Drift Times: 5.79 +/- 0.24 ms
0.82
0 360.25579 423.23415

0 5 10 15 20 5000
Retention time [min] 191.03404 289.08920

Intensity [Counts]
117.03436
439.23353
2500
523.18795
644.24635 855.35480

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: RhodojaponinⅠ [+H] : (39.7 PPM) 453.2496 : DT=6.16 to 6.64 ms

500

400 RhodojaponinⅠ
13.13
Intensity [Counts]

300 13.48

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.1433 +/- 0.0285
Channel name: RhodojaponinⅠ [+H] : (39.7 PPM) 453.2496 Component name: RhodojaponinⅠ minutes : Drift Times: 6.40 +/- 0.24 ms
5.14
3000 553.26412

525.19202
2500 15000

Intensity [Counts]
2000 10000
Intensity [Counts]

445.12685
1500 5000
554.27287
205.05160 420.25459 854.30866

1000 379.12704
16.55
0
10.19 12.85
8.61 9.45 16.49 16.60 200 400 600 800 1000
6.78 13.14
500 16.73 Item name: MENGKUDU 2 Channel name: High energy : Time 13.1433 +/- 0.0285
3.133.74 17.74 Component name: RhodojaponinⅠ minutes : Drift Times: 6.25 +/- 0.24 ms
0.99
0 525.19559

0 5 10 15 20 7500
511.25370
Retention time [min]

Intensity [Counts]
5000
541.28909
191.03417 412.14857

2500 181.05109 333.07533 593.23455


783.20055
835.31805
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside B [+H] : (39.7 PPM) 553.2641 : DT=6.37 to 6.85 ms
Picrasinoside B 13.64
13.15

1000 13.13

13.01
750
Intensity [Counts]

12.42

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Picrasinoside B
0 13.15

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.1450 +/- 0.0285
Channel name: Picrasinoside B [+H] : (39.7 PPM) 553.2641 Component name: Picrasinoside B minutes : Drift Times: 6.60 +/- 0.24 ms
13.16
13.53 20000 511.25080
553.26412

13.69 15000

Intensity [Counts]
1500

13.05 16.53
10000 571.27303
Intensity [Counts]

13.01 16.66
445.12685
1000 12.42 13.91
5000 578.24651
7.76 11.51 14.23 205.05160 365.14011 854.30866
10.49 690.21112
6.59 9.63 15.37 0
500 16.71 200 400 600 800 1000
4.19 6.42
17.00
16.90 Item name: MENGKUDU 2 Channel name: High energy : Time 13.1450 +/- 0.0285
3.62
Component name: Picrasinoside B minutes : Drift Times: 6.45 +/- 0.24 ms
2.85 18.40

0 525.19559

0 5 10 15 20 7500 511.25370
Retention time [min]

Intensity [Counts]
5000
541.28909
333.07533 483.21668
547.22010
472.33371
2500 306.13148
567.35274 783.23508
93.07130
583.28542

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ligustroside [+H] : (39.7 PPM) 525.1920 : DT=6.18 to 6.66 ms
Ligustroside
13.17
1250

1000
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.1612 +/- 0.0285
Channel name: Ligustroside [+H] : (39.7 PPM) 525.1920 Component name: Ligustroside minutes : Drift Times: 6.41 +/- 0.24 ms
13.16
8.91 30000 490.17388
8.37
2000 444.13051

14.10

Intensity [Counts]
4.65 20000 553.26412
6.38
1500
Intensity [Counts]

13.09
4.34 9.27
7.84 10000
9.44
1000
5.35 7.62 437.21158
205.05160 554.27287 854.30866
4.11 16.49
14.20 0
500 0.80 3.44 200 400 600 800 1000
3.22 16.56 Item name: MENGKUDU 2 Channel name: High energy : Time 13.1612 +/- 0.0285
16.61 Component name: Ligustroside minutes : Drift Times: 6.25 +/- 0.24 ms
16.74
0 444.13083 525.19559
0 5 10 15 20 7500
Retention time [min]

Intensity [Counts]
5000 191.03417
541.28909
290.10210
181.05109 547.22010
2500 593.23455
657.25273
752.31709
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Tenuifolin [+H] : (39.7 PPM) 681.3851 : DT=7.49 to 7.97 ms

6000
Intensity [Counts]

4000

2000

Tenuifolin
13.21

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.2126 +/- 0.0285 minutes :
Channel name: Tenuifolin [+H] : (39.7 PPM) 681.3851 Component name: Tenuifolin Drift Times: 7.73 +/- 0.24 ms
13.66
15000 637.22198

10000
683.33223

Intensity [Counts]
10000 685.24309
Intensity [Counts]

5000 205.05170 691.06450


13.54 290.10398 417.20068 621.25414 700.30746 957.37898
751.36781
5000
13.94 0
200 400 600 800 1000
16.52
Item name: MENGKUDU 2 Channel name: High energy : Time 13.2126 +/- 0.0285 minutes :
10.42 11.64 14.73 16.94 Component name: Tenuifolin Drift Times: 7.57 +/- 0.24 ms
7.64
0 779.29237

0 5 10 15 20 10000
Retention time [min]

Intensity [Counts]
620.22830
637.23214

5000
589.32424 783.19737
344.12505 467.18104 821.30431
175.04025
867.39278
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakihemiacetal F [+H] : (39.7 PPM) 393.2272 : DT=5.36 to 5.84 ms

1500

1000
Intensity [Counts]

500

Nigakihemiacetal F
13.21

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.2170 +/- 0.0285
Channel name: Nigakihemiacetal F [+H] : (39.7 PPM) 393.2272 Component name: Nigakihemiacetal F minutes : Drift Times: 5.60 +/- 0.24 ms
5.74
400.14130
432.16756
4000 40000

Intensity [Counts]
386.12384
3000
Intensity [Counts]

20000

16.50 358.16475
2000 5.04 450.11580 790.33954
16.54
288.12269 867.78473
453.19350
0
11.87
8.65 14.03 200 400 600 800 1000
1000 11.81 11.96 16.69
7.94 Item name: MENGKUDU 2 Channel name: High energy : Time 13.2170 +/- 0.0285
2.83 17.43 Component name: Nigakihemiacetal F minutes : Drift Times: 5.44 +/- 0.24 ms
3.55 6.53
1.79
0 400.14111

0 5 10 15 20
30000
Retention time [min]

Intensity [Counts]
351.21698
20000

10000 432.16126
117.03422
286.10864
593.23948 811.30592
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-epi-Andrographolide [+H] : (39.7 PPM) 351.2173 : DT=5.07 to
5.55 ms
13.68
80000

60000
Intensity [Counts]

40000 13.54

13.94
20000
14-epi-Andrographolide
14.06
13.25

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.2443 +/-
Channel name: 14-epi-Andrographolide [+H] : (39.7 PPM) 351.2173 Component name: 14-epi-Andrographolide 0.0285 minutes : Drift Times: 5.30 +/- 0.24 ms
13.68
60000 367.21017

1.25e5
351.21726

Intensity [Counts]
40000
100000
Intensity [Counts]

75000 20000
13.54 418.20540
277.08950
50000 599.26720 843.25573
13.94
0
200 400 600 800 1000
25000 Item name: MENGKUDU 2 Channel name: High energy : Time 13.2443 +/-
15.01 Component name: 14-epi-Andrographolide 0.0285 minutes : Drift Times: 5.15 +/- 0.24 ms
15.25
0 15000 351.21698

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000

365.19298
5000 205.05033
175.04031 399.14490
720.19007 843.25915
408.13916
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3372 : DT=6.70 to 7.18 ms

2000

1500
Intensity [Counts]

1000

500 Ganoderic acid S


13.24

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.2444 +/- 0.0285
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3372 Component name: Ganoderic acid S minutes : Drift Times: 6.94 +/- 0.24 ms
7.76
599.26681

30000 553.26419
15000

Intensity [Counts]
10000
Intensity [Counts]

20000
453.33724
5000 661.26845
427.10279 757.31039 903.35404
349.19930
10000 0
16.65 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 13.2444 +/- 0.0285
13.30 Component name: Ganoderic acid S minutes : Drift Times: 6.78 +/- 0.24 ms
10.20 11.78
0 7500 553.26170

0 5 10 15 20
Retention time [min]

Intensity [Counts]
600.27766
5000
608.24603
175.03951 843.25983
549.37335
2500 277.08918 675.29408 844.26214
415.17552
924.31405

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: RhodojaponinⅠ [+H] : (39.7 PPM) 453.2481 : DT=5.94 to 6.42 ms

800

600
Intensity [Counts]

400 RhodojaponinⅠ
13.28
13.31

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

RhodojaponinⅠ
0 13.32
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.2978 +/- 0.0285
Channel name: RhodojaponinⅠ [+H] : (39.7 PPM) 453.2481 Component name: RhodojaponinⅠ minutes : Drift Times: 6.18 +/- 0.24 ms
5.14
451.18839

2000
2e5

Intensity [Counts]
Intensity [Counts]

1500
100000
425.25285
1000 16.55 453.19460
5.19 275.20151 421.21985 878.29684
9.45 10.18 12.85 16.59 558.18663 781.74162
0
6.78 8.08 13.14 16.67 200 400 600 800 1000
500
Item name: MENGKUDU 2 Channel name: High energy : Time 13.2978 +/- 0.0285
16.73
3.133.74 Component name: RhodojaponinⅠ minutes : Drift Times: 6.03 +/- 0.24 ms
1.02
0 2e5 451.18952

0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

425.25211

453.19781
213.06618 827.29649
514.26144 718.18613
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Pseudolaric acid A O-β-D-glucopyranoside [+H] : (39.7 PPM)
551.2478 : DT=6.48 to 6.96 ms

1500

1000
Intensity [Counts]

12.87

13.11
500
12.56

Pseudolaric acid A O-β-D-glucopyranoside


13.32

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.3044 +/-
Channel name: Pseudolaric acid A O-β-D-glucopyranoside [+H] : (39.7 PPM) Component name: Pseudolaric acid A O-β-D- 0.0285 minutes : Drift Times: 6.76 +/- 0.24 ms
551.2478 glucopyranoside
6.59
2500 456.33343
20000

2000

Intensity [Counts]
511.25287

573.25043
Intensity [Counts]

10000
1500 6.76

7.73
275.20257 440.28360 578.31530 872.26404
12.89 16.52
1000 10.67 16.85 765.30576
16.31
5.96 10.57 12.81 0
16.90 200 400 600 800 1000
500 5.44
16.99 Item name: MENGKUDU 2 Channel name: High energy : Time 13.3044 +/-
4.70 Component name: Pseudolaric acid A O-β-D- 0.0285 minutes : Drift Times: 6.61 +/- 0.24 ms
3.65 17.69
glucopyranoside
0
456.33001
0 5 10 15 20 347.13253 491.20287
Retention time [min] 4000

Intensity [Counts]
589.23036
144.09992
315.15179
275.20166 602.17866
2000
689.22084

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3372 : DT=6.11 to 6.60 ms

25000

20000
Intensity [Counts]

15000

10000

5000
Ganoderic acid S
13.30
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.3058 +/- 0.0285
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3372 Component name: Ganoderic acid S minutes : Drift Times: 6.39 +/- 0.24 ms
7.76
451.18839

30000
2e5

Intensity [Counts]
Intensity [Counts]

20000 100000

456.33343
435.32831 878.29684
543.19445 781.74162
10000 0
16.65 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 13.3058 +/- 0.0285
13.30 Component name: Ganoderic acid S minutes : Drift Times: 6.23 +/- 0.24 ms
10.20 11.78
0 2e5 451.18952

0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

213.06618 453.19781
314.12667
643.28891 827.29649
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2359 : DT=5.62 to 6.10 ms
15.11

1500

15.07

1000 14.62
Intensity [Counts]

13.60
13.02

500 12.89
Nigakilactone J
13.31

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.3074 +/- 0.0285
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2359 Component name: Nigakilactone J minutes : Drift Times: 5.86 +/- 0.24 ms
15.12
425.25285

40000
2000

Intensity [Counts]
Intensity [Counts]

1500 13.60 16.54


20000 435.23067

16.58 397.21110
11.20 439.22512
1000
10.89 16.67 387.14188 697.27673 776.30261
2.94
10.60 0
6.56 10.40 200 400 600 800 1000
500 16.75
5.56 9.77 Item name: MENGKUDU 2 Channel name: High energy : Time 13.3074 +/- 0.0285
2.44 4.06 16.94 Component name: Nigakilactone J minutes : Drift Times: 5.71 +/- 0.24 ms
0.82
0 425.25211
20000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
435.22772
397.21026
214.06918 459.27141
718.18613 814.31685

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3040 :
DT=6.25 to 6.73 ms

2000

1500
Intensity [Counts]

1000

500

3-O-(2′E,4′Z-Decadienoyl) ingenol
13.32
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.3174 +/-
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3040 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.49 +/- 0.24 ms
14.22 ingenol
4000
451.18839

2e5

Intensity [Counts]
3000
Intensity [Counts]

100000
2000
16.59 456.33343
435.32831
16.78 551.24784 872.26404
10.10 0
1000 12.12 200 400 600 800 1000
7.81 14.75
13.32 Item name: MENGKUDU 2 Channel name: High energy : Time 13.3174 +/-
7.26 16.90
3.17 9.12 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.34 +/- 0.24 ms
4.29 5.81 18.46 ingenol
0
453.19781
0 5 10 15 20
Retention time [min]
10000

Intensity [Counts]
491.20287
5000 435.22761
144.09992 541.27769
311.13889 547.21068
827.29649
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Neoquassin [+H] : (39.7 PPM) 391.2118 : DT=5.27 to 5.75 ms

600
Intensity [Counts]

400

Neoquassin
13.32
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.3238 +/- 0.0285
Channel name: Neoquassin [+H] : (39.7 PPM) 391.2118 Component name: Neoquassin minutes : Drift Times: 5.51 +/- 0.24 ms
16.55
368.17118
1250 16.61 15000

350.16098

Intensity [Counts]
1000 336.14592
10000
13.07
Intensity [Counts]

333.22778 387.14188
11.27
750 391.21178
15.22 5000
10.71 16.75
13.15 290.10234 465.16848
5.93 9.17 714.25873
3.87
500 5.86 6.56 8.00
3.28
0
4.96 200 400 600 800 1000
2.69 16.98
250 Item name: MENGKUDU 2 Channel name: High energy : Time 13.3238 +/- 0.0285
17.20 Component name: Neoquassin minutes : Drift Times: 5.35 +/- 0.24 ms
2.28

0 336.14713
349.20230
0 5 10 15 20
Retention time [min] 10000

Intensity [Counts] 5000 177.05485 365.19297

393.22434

485.19801 727.23775

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Catalpol [+H] : (39.7 PPM) 363.1298 : DT=5.77 to 6.25 ms
Catalpol
400
13.42

300

13.28
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.4226 +/- 0.0285 minutes :
Channel name: Catalpol [+H] : (39.7 PPM) 363.1298 Component name: Catalpol Drift Times: 6.01 +/- 0.24 ms
9.06
5000 411.15551
15000
397.20987

Intensity [Counts]
4000
10000 424.30945
363.12978
Intensity [Counts]

3000
466.16115
12.04 5000 477.21798
4.90 663.18948 791.74032
9.82 13.44 348.21986 511.17340
2000 3.13
10.32 292.11419
3.79 10.39 13.74 0
200 400 600 800 1000
6.74 8.77 14.04
1000 1.83 Item name: MENGKUDU 2 Channel name: High energy : Time 13.4226 +/- 0.0285 minutes :
14.41
14.86 Component name: Catalpol Drift Times: 5.85 +/- 0.24 ms
30000 405.17881
0
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

424.30740
10000 397.21489
204.06629
453.24372
839.35239
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Florilenalin isovalerate [+H] : (39.7 PPM) 349.1994 : DT=5.09 to 5.57
ms

13.74

12.94
4000
Florilenalin isovalerate
13.42
Intensity [Counts]

3000

2000
12.75

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.4226 +/-
Channel name: Florilenalin isovalerate [+H] : (39.7 PPM) 349.1994 Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.32 +/- 0.24 ms
13.74
13.42 349.19940

6000 12.94 15.47

50000

Intensity [Counts]
16.54
Intensity [Counts]

4000 16.60
25000
323.18495 363.12906
5.02
388.10509
12.75 277.08888 601.25962
520.18407 839.34169
2000 12.28 0
12.11 200 400 600 800 1000

16.75 Item name: MENGKUDU 2 Channel name: High energy : Time 13.4226 +/-
7.67 8.34 11.12
4.66 Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.17 +/- 0.24 ms
2.73 6.08 16.99
0 349.19948

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts] 10000 363.12818

118.06350
277.08809 623.20232
428.10949
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ligustroside [+H] : (39.7 PPM) 525.1954 : DT=6.15 to 6.64 ms

1250

1000
Ligustroside
13.44
Intensity [Counts]

750

13.38

500
13.28

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.4328 +/- 0.0285
Channel name: Ligustroside [+H] : (39.7 PPM) 525.1954 Component name: Ligustroside minutes : Drift Times: 6.40 +/- 0.24 ms
8.91
2500
451.18808
3e5
8.37 13.16

2000

Intensity [Counts]
13.85
2e5
4.65 14.10
6.38
Intensity [Counts]

1500 9.29
9.44 13.09
7.84 100000
4.34
7.60 9.50
1000 406.16742 453.19125
5.35
364.12880 569.24809 867.76580
4.12 0
0.80 3.44 14.2116.49 200 400 600 800 1000
500 3.22 16.56 Item name: MENGKUDU 2 Channel name: High energy : Time 13.4328 +/- 0.0285
Component name: Ligustroside minutes : Drift Times: 6.24 +/- 0.24 ms
16.61

0 451.18888

0 5 10 15 20
2e5
Retention time [min]

Intensity [Counts]
100000

406.16842 453.19274
214.07175
301.11797 651.20844 839.35239
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Catalpol [+H] : (39.7 PPM) 363.1291 : DT=4.91 to 5.39 ms

4000

3000
Intensity [Counts]

2000

Catalpol
1000
13.44
13.73

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.4332 +/- 0.0285 minutes :
Channel name: Catalpol [+H] : (39.7 PPM) 363.1291 Component name: Catalpol Drift Times: 5.16 +/- 0.24 ms
9.06
5000 349.19940

50000

Intensity [Counts]
4000
Intensity [Counts]

3000
25000
4.90 12.04 363.12906
291.19624
3.13 9.82 13.44 388.10509 519.15674
2000 253.05036
601.25962 839.34169
10.32
3.78 13.74 0
8.77 10.53 200 400 600 800 1000
6.74 14.04
1000 1.83 Item name: MENGKUDU 2 Channel name: High energy : Time 13.4332 +/- 0.0285 minutes :
14.42
16.50 Component name: Catalpol Drift Times: 5.00 +/- 0.24 ms

0 349.19948

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts] 10000


291.19854
216.97903 358.15414 623.20232
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sericoside [+H] : (39.7 PPM) 667.4033 : DT=7.66 to 8.14 ms
16.76

1000
Intensity [Counts]

750 16.61

16.53
500

13.73 16.87
11.90
250 13.48 14.77 17.00
10.89
17.48
8.63 10.47
3.06 4.31
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.4736 +/- 0.0285 minutes :
Channel name: Sericoside [+H] : (39.7 PPM) 667.4033 Component name: Sericoside Drift Times: 7.90 +/- 0.24 ms
16.76
11.90 16.50 767.20181
40000
1500

Intensity [Counts]
351.21549
Intensity [Counts]

20000
1000
689.38363
11.78 12.53 661.28579 824.33791
12.94 17.01 650.32797 904.29499
500 0
11.56
8.41 17.06 200 400 600 800 1000

17.66 Item name: MENGKUDU 2 Channel name: High energy : Time 13.4736 +/- 0.0285 minutes :
8.06
3.59 Component name: Sericoside Drift Times: 7.75 +/- 0.24 ms
3.23 6.54
0 768.20848
10000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
689.38803
204.06755 285.12414
5000

159.11779 467.16647 623.25024 783.22595


785.39345

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Epianhydrobelachinal [+H] : (39.7 PPM) 469.3315 : DT=6.18 to 6.67
ms

13.68

2000
Intensity [Counts]

1500

1000
13.56

500
Epianhydrobelachinal
13.48

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.4743 +/-
Channel name: Epianhydrobelachinal [+H] : (39.7 PPM) 469.3315 Component name: Epianhydrobelachinal 0.0285 minutes : Drift Times: 6.43 +/- 0.24 ms
13.68
451.18808
6000 3e5

Intensity [Counts]
2e5
Intensity [Counts]

4000
417.20293
100000

16.50 267.06911 405.31607 454.31755 801.26942


868.26934
2000 13.56 0
8.429.61 16.62 200 400 600 800 1000
12.37 14.10
7.90 9.74 Item name: MENGKUDU 2 Channel name: High energy : Time 13.4743 +/-
14.24 16.91
10.10 Component name: Epianhydrobelachinal 0.0285 minutes : Drift Times: 6.27 +/- 0.24 ms
6.07
7.11 17.51
0 451.18888

0 5 10 15 20
2e5
Retention time [min]

Intensity [Counts]
417.20378
100000

159.11760 453.19274
276.12294 640.17973 809.30887
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside B [+H] : (39.7 PPM) 553.2630 : DT=6.47 to 6.95 ms

13.65

1000

13.60
Intensity [Counts]

750 Picrasinoside B
13.49

13.35
500
13.81

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5212 +/- 0.0285
Channel name: Picrasinoside B [+H] : (39.7 PPM) 553.2630 Component name: Picrasinoside B minutes : Drift Times: 6.73 +/- 0.24 ms
13.16
13.64 383.15214

20000
553.26303
13.69

Intensity [Counts]
1500

13.05 609.18112
16.52
Intensity [Counts]

12.92 10000
16.66 365.14206
1000 12.42 13.91 712.38014
293.21335
10.49 11.51 765.29568
7.76 14.23
9.63
6.59 15.37 0
500 6.42 16.71 200 400 600 800 1000
4.19
16.90 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5212 +/- 0.0285
3.62
18.19 Component name: Picrasinoside B minutes : Drift Times: 6.57 +/- 0.24 ms
2.85
0 547.29073

0 5 10 15 20 40000

Retention time [min]

Intensity [Counts]
20000
367.18016
227.03800
599.27867
159.11760 609.37610 741.27095 924.41817

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimidahuside C [+H] : (39.7 PPM) 695.4047 : DT=9.87 to 10.35 ms
13.68
5000

4000
Intensity [Counts]

3000

Cimidahuside C
2000 13.53

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5291 +/- 0.0285
Channel name: Cimidahuside C [+H] : (39.7 PPM) 695.4047 Component name: Cimidahuside C minutes : Drift Times: 10.10 +/- 0.24 ms
13.68
695.40467
80000 711.37722

10000 765.29606

Intensity [Counts]
681.41720
60000
Intensity [Counts]

5000

40000 60.67478 768.20598


351.21544 547.28841 869.28239
13.54
0
200 400 600 800 1000
20000
13.94
Item name: MENGKUDU 2 Channel name: High energy : Time 13.5291 +/- 0.0285
Component name: Cimidahuside C minutes : Drift Times: 9.95 +/- 0.24 ms
16.61
0 609.18375 695.40645
10000
0 5 10 15 20
367.18046
Retention time [min]

Intensity [Counts]
765.30022

5000 227.03799 547.29077

961.38169
768.20330

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimidahuside C [+H] : (39.7 PPM) 695.4046 : DT=7.72 to 8.20 ms
13.68

40000

30000
Intensity [Counts]

20000
Cimidahuside C
13.53

10000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5293 +/- 0.0285
Channel name: Cimidahuside C [+H] : (39.7 PPM) 695.4046 Component name: Cimidahuside C minutes : Drift Times: 7.96 +/- 0.24 ms
13.68
711.37722
80000
4e5

Intensity [Counts]
60000
Intensity [Counts]

2e5
710.37225
383.15213 695.40462
40000
681.41720 714.38220
365.14206
13.54 227.03794 555.26423 772.27101
0
200 400 600 800 1000
20000
13.94
Item name: MENGKUDU 2 Channel name: High energy : Time 13.5293 +/- 0.0285
Component name: Cimidahuside C minutes : Drift Times: 7.81 +/- 0.24 ms
16.61
1.5e5 227.03800
0
0 5 10 15 20
Retention time [min] 347.13204

Intensity [Counts]
100000 383.15333

50000 711.38014
695.40647 767.20465
211.06548
209.02618
768.20848
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside [+H] : (39.7 PPM)
681.4172 : DT=7.85 to 8.34 ms
13.68
30000
Intensity [Counts]

20000

10000 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranosi…
13.53

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5299 +/-
Channel name: 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) Component name: 24-O-Acetyl-cimigenol-3- 0.0285 minutes : Drift Times: 8.09 +/- 0.24 ms
681.4172 O-β-D-xylopyranoside
13.68
711.37722
50000
4e5

Intensity [Counts]
40000
Intensity [Counts]

30000 2e5
710.37225
383.15213 695.40462
13.54 681.41720 714.38220
20000 227.03794 365.14206 555.26423 794.34184
0
200 400 600 800 1000
13.94
10000 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5299 +/-
Component name: 24-O-Acetyl-cimigenol-3- 0.0285 minutes : Drift Times: 7.94 +/- 0.24 ms
16.52
O-β-D-xylopyranoside
0
1.5e5 227.03800
0 5 10 15 20
Retention time [min] 347.13204

Intensity [Counts]
100000 383.15333

50000 711.38014
695.40647
209.02618
765.29901
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Inuchinenolide C [+H] : (39.7 PPM) 367.1755 : DT=4.73 to 5.21 ms
Inuchinenolide C
13.53

1000

13.69

750
Intensity [Counts]

500

13.42

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5302 +/- 0.0285
Channel name: Inuchinenolide C [+H] : (39.7 PPM) 367.1755 Component name: Inuchinenolide C minutes : Drift Times: 4.97 +/- 0.24 ms
12500 13.69
13.64 275.20254
100000
13.54
10000
347.13204

Intensity [Counts]
13.94 365.14208
Intensity [Counts]

7500 50000

5000 241.05147 382.15408


593.21109
499.17263
0
14.91
200 400 600 800 1000
2500 15.04
15.15 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5302 +/- 0.0285
5.42 6.44 8.26 10.49 13.04 Component name: Inuchinenolide C minutes : Drift Times: 4.81 +/- 0.24 ms
2.76
15.62
0 275.20266

0 5 10 15 20
Retention time [min] 40000

Intensity [Counts]
347.13210
227.03800

20000

138.98504 352.11841
695.40644
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 28-Deacetylbelamcandal [+H] : (39.7 PPM) 487.3425 : DT=6.61 to
7.09 ms

20000

15000
Intensity [Counts]

10000
13.68

5000
28-Deacetylbelamcandal
13.54
13.79
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5307 +/-
Channel name: 28-Deacetylbelamcandal [+H] : (39.7 PPM) 487.3425 Component name: 28-Deacetylbelamcandal 0.0285 minutes : Drift Times: 6.85 +/- 0.24 ms
16.86
30000 547.28877

50000

Intensity [Counts]
20000
Intensity [Counts]

25000 383.15214
553.26303
609.18112
13.68 365.14206 599.26520 765.29568
293.21335 984.40065
10000
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 13.5307 +/-
13.54 16.59 Component name: 28-Deacetylbelamcandal 0.0285 minutes : Drift Times: 6.69 +/- 0.24 ms
8.42 12.37
0 547.29073

0 5 10 15 20 40000

Retention time [min]

Intensity [Counts]
20000
367.18016
227.03800 555.27246
211.06544 599.27867
913.25611
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-11-hydro-xyandrographolide [+H] : 14-Deoxy-12R-
hydroxyandrographolide [+H] : (39.7 PPM) 351.2155 : DT=5.17 to 5.66 ms
13.68

75000
Intensity [Counts]

50000 14-Deoxy-12R-hydroxyandrographolide
13.54

13.94
25000

15.01
13.25
15.22
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5314 +/-
Channel name: 14-Deoxy-11-hydro-xyandrographolide [+H] : 14-Deoxy-12R- Component name: 14-Deoxy-11-hydro- 0.0285 minutes : Drift Times: 5.41 +/- 0.24 ms
hydroxyandrographolide [+H] : (39.7 PPM) 351.2155 xyandrographolide
13.68
351.21549
1.25e5
4e5

Intensity [Counts]
100000
Intensity [Counts]

2e5
75000
335.24163 367.18011
13.54
227.03780
50000 383.15222 695.40461
13.94 0
200 400 600 800 1000
25000 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5314 +/-
15.01 Component name: 14-Deoxy-11-hydro- 0.0285 minutes : Drift Times: 5.26 +/- 0.24 ms
15.25 xyandrographolide
0
351.21586
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

335.24259 367.18046

378.20603
211.06571
416.19476 696.41098
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5314 +/-
Component name: 14-Deoxy-12R- 0.0285 minutes : Drift Times: 5.41 +/- 0.24 ms
hydroxyandrographolide

351.21549

4e5

Intensity [Counts]
2e5

335.24163 367.18011
227.03780
383.15222 695.40461
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 13.5314 +/-
Component name: 14-Deoxy-12R- 0.0285 minutes : Drift Times: 5.26 +/- 0.24 ms
hydroxyandrographolide

351.21586

Intensity [Counts]
100000

335.24259 367.18046

378.20603
211.06571
416.19476 696.41098
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside [+H] : (39.7 PPM)
681.4172 : DT=9.99 to 10.47 ms
13.67
13.68

1000

750 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranosi…
Intensity [Counts]

13.54

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5320 +/-
Channel name: 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) Component name: 24-O-Acetyl-cimigenol-3- 0.0285 minutes : Drift Times: 10.17 +/- 0.24 ms
681.4172 O-β-D-xylopyranoside
13.68
695.40467
50000
711.37722

10000 765.29606

Intensity [Counts]
40000
681.41720
Intensity [Counts]

30000 5000
60.67478 768.20598
351.21544 547.28841
13.54 886.47831
20000
0
200 400 600 800 1000
13.94
10000 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5320 +/-
Component name: 24-O-Acetyl-cimigenol-3- 0.0285 minutes : Drift Times: 10.02 +/- 0.24 ms
16.52
O-β-D-xylopyranoside
0
609.18375 695.40645
0 5 10 15 20 10000
Retention time [min]

Intensity [Counts]
765.30022

5000 227.03799 347.13218

365.14300 983.39961
961.38169
768.20330
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimidahuside J [+H] : (39.7 PPM) 677.3910 : DT=7.79 to 8.27 ms

3000
Intensity [Counts]

2000

1000
13.70
Cimidahuside J
13.55

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5348 +/- 0.0285
Channel name: Cimidahuside J [+H] : (39.7 PPM) 677.3910 Component name: Cimidahuside J minutes : Drift Times: 8.03 +/- 0.24 ms
16.76
711.37722

5000 4e5

Intensity [Counts]
4000
Intensity [Counts]

2e5
710.37225
3000
383.15213 695.40462
16.55
681.41720 714.38220
13.66 365.14206
2000 227.03794 555.26423
794.34184
13.54 16.94 0
200 400 600 800 1000
1000 14.41 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5348 +/- 0.0285
13.39 Component name: Cimidahuside J minutes : Drift Times: 7.88 +/- 0.24 ms
8.96 10.23 18.53
4.55 6.98
1.5e5 227.03800
0
0 5 10 15 20
Retention time [min] 347.13204

Intensity [Counts]
100000 383.15333

50000 711.38014
695.40647
211.06548
751.21348
209.02618 911.37115
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Aucubin [+H] : (39.7 PPM) 347.1321 : DT=7.80 to 8.28 ms
13.69

1000

750 Aucubin
Intensity [Counts]

13.54

500

250

13.45

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5364 +/- 0.0285 minutes :
Channel name: Aucubin [+H] : (39.7 PPM) 347.1321 Component name: Aucubin Drift Times: 8.02 +/- 0.24 ms
4.34
711.37722
15000
4e5

Intensity [Counts]
13.68
Intensity [Counts]

10000 2e5
13.54 710.37225
383.15213 695.40462
13.94 681.41720 714.38220
365.14206
227.03794 555.26423 772.27101
5000 0
5.43 10.33 200 400 600 800 1000
6.71 10.66 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5364 +/- 0.0285 minutes :
5.62 14.43
3.98 Component name: Aucubin Drift Times: 7.87 +/- 0.24 ms
1.80 8.01 12.46
15.04
1.5e5 227.03800
0
0 5 10 15 20
Retention time [min] 347.13204

Intensity [Counts]
100000 383.15333

50000 711.38014
695.40647
211.06548
209.02618 765.29901
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimidahuside J [+H] : (39.7 PPM) 677.3911 : DT=5.04 to 5.52 ms
13.70

400

Cimidahuside J
300 13.54
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5410 +/- 0.0285
Channel name: Cimidahuside J [+H] : (39.7 PPM) 677.3911 Component name: Cimidahuside J minutes : Drift Times: 5.28 +/- 0.24 ms
16.76
351.21549

5000
4e5

Intensity [Counts]
4000
Intensity [Counts]

2e5
3000

16.55 335.24163 367.18011


227.03780 383.15222
2000 13.66
539.28609 695.40461
13.54 16.94 0
200 400 600 800 1000
1000 14.41 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5410 +/- 0.0285
13.39 Component name: Cimidahuside J minutes : Drift Times: 5.13 +/- 0.24 ms
8.96 10.23 18.53
4.55 6.98
0
0 5 10 15 20
1.5e5
Retention time [min] O

Intensity [Counts]
O

O
O

100000 O O
H
O

O
O

335.24259
50000
351.21586
211.06571 Mass error: -0.7 mDa

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Florilenalin angelate [+H] : (39.7 PPM) 347.1836 : DT=4.93 to 5.41
ms

1500

Florilenalin angelate
13.56
Intensity [Counts]

1000

13.53

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5590 +/- 0.0285
Channel name: Florilenalin angelate [+H] : (39.7 PPM) 347.1836 Component name: Florilenalin angelate minutes : Drift Times: 5.17 +/- 0.24 ms
15.34
20000 293.21332

6000

Intensity [Counts]
379.13329
14.44
Intensity [Counts]

10000
4000 385.15477
14.17
228.04120 677.39115
514.68827 711.37695
7.95 15.81
2000 0
7.88 13.56 200 400 600 800 1000
8.24 16.53
12.76 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5590 +/- 0.0285
6.99 9.19 12.38 16.61
0.92 Component name: Florilenalin angelate minutes : Drift Times: 5.02 +/- 0.24 ms
2.78 6.92 18.50
0 30000 347.13210

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

10000 363.25033
241.05314
138.98504 383.15437 695.40644
416.19476
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Hypoglaucin H [+H] : (39.7 PPM) 769.3990 : DT=7.93 to 8.41 ms

1250

1000
Intensity [Counts]

750 Hypoglaucin H
13.59

500
13.49

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5851 +/- 0.0285
Channel name: Hypoglaucin H [+H] : (39.7 PPM) 769.3990 Component name: Hypoglaucin H minutes : Drift Times: 8.17 +/- 0.24 ms
16.57
769.39899

16.51 730.38805
771.39936
4000 351.21543
1500 703.35118 819.35412

Intensity [Counts]
673.41887 983.39464
Intensity [Counts]

670.24746
2000
1000 13.59 493.24179

13.49
14.79
14.92 0
500 11.57
6.38 16.71 200 400 600 800 1000
8.90
7.84 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5851 +/- 0.0285
5.63 8.84 16.78 Component name: Hypoglaucin H minutes : Drift Times: 8.02 +/- 0.24 ms
0.37
5.40 4.44
0 769.40780
4000
349.16686 749.32130
0 5 10 15 20
Retention time [min] 532.11968 663.39625

Intensity [Counts]
122.98786

309.10213
2000
779.35935
885.37035

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Rotundifuran [+H] : (39.7 PPM) 363.2523 : DT=5.13 to 5.61 ms

Rotundifuran
13.59
1500
Intensity [Counts]

1000

14.29
500 13.50

13.34 14.34

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5972 +/- 0.0285
Channel name: Rotundifuran [+H] : (39.7 PPM) 363.2523 Component name: Rotundifuran minutes : Drift Times: 5.39 +/- 0.24 ms
16.63
349.19887
2500
40000 391.13362
13.59

Intensity [Counts]
2000
Intensity [Counts]

20000
1500

392.13386
204.06690
1000 16.49 597.26501
514.68827 889.64844
14.30 0
13.50 14.59 200 400 600 800 1000
16.78
500 12.82 14.70
Item name: MENGKUDU 2 Channel name: High energy : Time 13.5972 +/- 0.0285
8.95 16.96
2.80 3.91 9.77 Component name: Rotundifuran minutes : Drift Times: 5.23 +/- 0.24 ms
6.09 7.66
0 204.06718
15000
0 5 10 15 20 349.16650
Retention time [min]

Intensity [Counts]
10000 391.12784

5000 193.03072

120.08170 395.20562
696.41012 892.88872
437.14130
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Florilenalin isovalerate [+H] : (39.7 PPM) 349.1989 : DT=5.09 to 5.57
ms

13.74

12.94
4000
Intensity [Counts]

3000
Florilenalin isovalerate
13.60
2000
12.75

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5974 +/-
Channel name: Florilenalin isovalerate [+H] : (39.7 PPM) 349.1989 Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.33 +/- 0.24 ms
13.74
13.42 349.19887
6000 12.94 15.47 40000 391.13362

Intensity [Counts]
16.54
Intensity [Counts]

4000 16.60 20000

5.02
392.13386
204.06690
12.75 399.14960 597.26501 892.88858

2000 12.28 0
12.11 200 400 600 800 1000

16.75 Item name: MENGKUDU 2 Channel name: High energy : Time 13.5974 +/-
7.67 8.34 11.12
4.66 Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.17 +/- 0.24 ms
2.73 6.08 16.99
0 204.06718
15000
0 5 10 15 20 349.16650
Retention time [min]

Intensity [Counts]
10000 391.12784

5000 193.03072

395.13942
696.41012 892.88872
437.14130
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2363 : DT=5.71 to 6.19 ms

1500
Intensity [Counts]

1000 Nigakilactone J
13.59

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.5983 +/- 0.0285
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2363 Component name: Nigakilactone J minutes : Drift Times: 5.95 +/- 0.24 ms
15.12
397.25645

75000
2000

Intensity [Counts]
50000
Intensity [Counts]

1500 13.60 16.54

25000 383.15222
11.20 16.67 423.23627
1000 262.06653
13.45 642.27408 764.29031 846.28324
2.94 10.89 0
6.56 200 400 600 800 1000
10.40 16.75
500 10.33
5.56
Item name: MENGKUDU 2 Channel name: High energy : Time 13.5983 +/- 0.0285
2.44 4.06 16.94 Component name: Nigakilactone J minutes : Drift Times: 5.79 +/- 0.24 ms
0.82
0 371.19878

0 5 10 15 20
Retention time [min] 4000 439.17807

Intensity [Counts]
292.11348

889.15790
2000 118.07242
447.23363
640.19760 821.34302

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: ent-16α,17-Hydroxy-19-kauranoic acid [+H] : (39.7 PPM) 321.2433 :
DT=4.90 to 5.38 ms

1000

750 ent-16α,17-Hydroxy-19-kauranoic acid


Intensity [Counts]

13.61
13.66

500

250 13.71

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6212 +/-
Channel name: ent-16α,17-Hydroxy-19-kauranoic acid [+H] : (39.7 PPM) 321.2433 Component name: ent-16α,17-Hydroxy-19- 0.0285 minutes : Drift Times: 5.14 +/- 0.24 ms
16.65 kauranoic acid

2500 267.06910

100000 365.14170

Intensity [Counts]
2000

383.15251
Intensity [Counts]

1500 50000

16.52 265.07235 399.14960


1000 893.13888
13.61 631.23302
0
13.66 200 400 600 800 1000
13.01
500 12.44
7.37 10.90 13.88 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6212 +/-
0.56 8.41 17.20 Component name: ent-16α,17-Hydroxy-19- 0.0285 minutes : Drift Times: 4.99 +/- 0.24 ms
9.68 15.13
1.53 2.86 4.08 6.40 kauranoic acid
0
267.06975
0 5 10 15 20
Retention time [min]
40000

Intensity [Counts] 20000


249.05870 365.14277
211.04291 385.15404
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Platycogenic acid C [+H] : (39.7 PPM) 505.3539 : DT=7.67 to 8.15 ms
Platycogenic acid C
13.65
200

150
Intensity [Counts]

13.55
100
13.71

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6323 +/- 0.0285
Channel name: Platycogenic acid C [+H] : (39.7 PPM) 505.3539 Component name: Platycogenic acid C minutes : Drift Times: 7.91 +/- 0.24 ms
13.68
351.21546
6000 20000
723.41312
721.35245
764.29066

Intensity [Counts]
Intensity [Counts]

4000 10000 648.20697


381.15642
268.07107 629.32622 769.28340

16.61 776.29170
89.36149 838.34188
2000 16.71 0
200 400 600 800 1000
16.51 16.86
Item name: MENGKUDU 2 Channel name: High energy : Time 13.6323 +/- 0.0285
8.42 9.62 11.91 16.98 Component name: Platycogenic acid C minutes : Drift Times: 7.76 +/- 0.24 ms
7.79 14.98 18.53
0 20000 349.16668

0 5 10 15 20
Retention time [min] 693.37441

Intensity [Counts]
479.21003
154.97959
10000

573.34734
701.33268
751.21303
853.37017
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1,1,6-Trimethyl-1,2-dihydronaphthalene [+H] : (39.7 PPM)
173.1336 : DT=4.33 to 4.81 ms
13.67

1,1,6-Trimethyl-1,2-dihydronaphthalene 13.73
300 13.64
Intensity [Counts]

200
13.53

100 13.83

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6529 +/-
Channel name: 1,1,6-Trimethyl-1,2-dihydronaphthalene [+H] : (39.7 PPM) 173.1336 Component name: 1,1,6-Trimethyl-1,2- 0.0285 minutes : Drift Times: 4.57 +/- 0.24 ms
6.45 dihydronaphthalene

4e5 275.20326
1000 13.69
10.45

Intensity [Counts]
16.51
750
Intensity [Counts]

16.58 2e5
10.52
0.98 13.54
7.76
500 9.47 239.18131
12.53 277.21174
5.84
0
5.69 13.96 16.69 200 400 600 800 1000
250
4.42 16.81 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6529 +/-
16.91 Component name: 1,1,6-Trimethyl-1,2- 0.0285 minutes : Drift Times: 4.42 +/- 0.24 ms
dihydronaphthalene
0
257.19144
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
145.10243

10000

258.19439
333.19439
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Esculentagenin [+H] : (39.7 PPM) 547.3219 : DT=7.82 to 8.30 ms
Esculentagenin
13.67

1500
Intensity [Counts]

1000

500 13.55

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6704 +/- 0.0285
Channel name: Esculentagenin [+H] : (39.7 PPM) 547.3219 Component name: Esculentagenin minutes : Drift Times: 8.04 +/- 0.24 ms
13.67
2e6 711.37683
4000

1.5e6

Intensity [Counts]
3000
1e6
Intensity [Counts]

16.57 695.40517
13.54 14.60 712.38047
383.15246 681.41742
2000 16.64
5e5
714.38282
8.05 381.15553 385.15375 594.28653
733.35431
16.73 0
1000 200 400 600 800 1000
16.84
10.09 12.84 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6704 +/- 0.0285
4.60 6.26 6.90 16.97 Component name: Esculentagenin minutes : Drift Times: 7.89 +/- 0.24 ms
8.99 12.38
0 267.06970
1e6
0 5 10 15 20
Retention time [min]

Intensity [Counts]
5e5 383.15399

695.40830
227.03824
529.31379 711.38059
211.04254 885.29638
712.38464
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside [+H] : (39.7 PPM)
681.4174 : DT=9.78 to 10.26 ms

1500
24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside
13.66

1000
Intensity [Counts]

13.54
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6747 +/-
Channel name: 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) Component name: 24-O-Acetyl-cimigenol-3- 0.0285 minutes : Drift Times: 10.04 +/- 0.24 ms
681.4174 O-β-D-xylopyranoside
13.68
695.40518
50000
75000 711.37683

Intensity [Counts]
40000
50000
Intensity [Counts]

30000 681.41742 712.38046


25000 764.29073
13.54 383.15246 765.29597
20000 885.24591
565.33269
0
200 400 600 800 1000
13.94
10000 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6747 +/-
Component name: 24-O-Acetyl-cimigenol-3- 0.0285 minutes : Drift Times: 9.89 +/- 0.24 ms
16.52
O-β-D-xylopyranoside
0
695.40831
0 5 10 15 20
Retention time [min] 40000

Intensity [Counts]
267.06971 367.18112 765.29909
20000 383.15400 550.13115

532.11953 767.29566
227.03824
868.36409
211.04257
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside [+H] : (39.7 PPM)
681.4174 : DT=7.78 to 8.27 ms

24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside
30000 13.68
Intensity [Counts]

20000

13.53
10000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6772 +/-
Channel name: 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) Component name: 24-O-Acetyl-cimigenol-3- 0.0285 minutes : Drift Times: 8.02 +/- 0.24 ms
681.4174 O-β-D-xylopyranoside
13.68
2e6 711.37683
50000

Intensity [Counts]
40000

1e6
Intensity [Counts]

695.40517
30000 712.38047
383.15246
681.41742
13.54 594.28653 714.38282
20000 381.15553
765.29597 839.35574
0
200 400 600 800 1000
13.94
10000 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6772 +/-
Component name: 24-O-Acetyl-cimigenol-3- 0.0285 minutes : Drift Times: 7.86 +/- 0.24 ms
16.52
O-β-D-xylopyranoside
0
267.06970
0 5 10 15 20 1e6
Retention time [min]

Intensity [Counts]
5e5 383.15399

695.40830
227.03824
529.31379 711.38059
211.04254 885.29638
712.38464
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Epianhydrobelachinal [+H] : (39.7 PPM) 469.3327 : DT=6.48 to 6.97
ms
Epianhydrobelachinal
13.68
4000

3000
Intensity [Counts]

2000

1000 13.56

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6781 +/-
Channel name: Epianhydrobelachinal [+H] : (39.7 PPM) 469.3327 Component name: Epianhydrobelachinal 0.0285 minutes : Drift Times: 6.74 +/- 0.24 ms
13.68
487.34289
6000

75000

Intensity [Counts]
469.33267
505.35380
50000
Intensity [Counts]

4000

25000 275.20326
506.35607
451.31889 713.38095
16.50 257.19216 817.77033
365.14227
2000 13.56 0
8.429.61 16.62 200 400 600 800 1000
12.37 14.10
7.90 9.74 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6781 +/-
14.83 16.91 Component name: Epianhydrobelachinal 0.0285 minutes : Drift Times: 6.59 +/- 0.24 ms
6.07
7.11 17.51
0 30000 267.06971 487.34258

0 5 10 15 20 469.33206 529.31416
Retention time [min]

Intensity [Counts]
20000
275.20294
451.32227
10000 347.13269
251.09666 555.27324
712.38469
919.31321
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-
one-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) 645.3967 : DT=7.73 to 8.21 ms

(3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-o…
13.68

3000
Intensity [Counts]

2000
13.54

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6803 +/-
Channel name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24- Component name: (3β,12β,16β)-12- 0.0285 minutes : Drift Times: 7.96 +/- 0.24 ms
one-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) 645.3967 Acetoxy-16,23-epoxy-9,19-cyclolanost-22-
13.69 ene-24-one-3-O-β-D-xylopyranoside

2e6 711.37683

Intensity [Counts]
4000
Intensity [Counts]

1e6
695.40517
712.38047
13.54 383.15246
681.41742
381.15553 594.28653 714.38282
2000 16.55 794.35758
0
16.49 16.60 200 400 600 800 1000
16.71 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6803 +/-
13.94
13.16 Component name: (3β,12β,16β)-12- 0.0285 minutes : Drift Times: 7.80 +/- 0.24 ms
7.76 10.33 16.82
6.96 Acetoxy-16,23-epoxy-9,19-cyclolanost-22-
0 ene-24-one-3-O-β-D-xylopyranoside
0 5 10 15 20 267.06970
Retention time [min] 1e6

Intensity [Counts] 5e5 383.15399

695.40830
227.03824
529.31379 711.38059 885.29638
211.04254
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 28-Deacetylbelamcandal [+H] : (39.7 PPM) 487.3429 : DT=6.61 to
7.09 ms

15000
Intensity [Counts]

10000 28-Deacetylbelamcandal
13.68

5000

13.54
13.93
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6803 +/-
Channel name: 28-Deacetylbelamcandal [+H] : (39.7 PPM) 487.3429 Component name: 28-Deacetylbelamcandal 0.0285 minutes : Drift Times: 6.85 +/- 0.24 ms
16.86
487.34289
30000

75000

Intensity [Counts]
469.33267
505.35380
50000
Intensity [Counts]

20000

25000 275.20326
506.35607
13.68 451.31889 713.38095
364.13472 817.77033
195.13738
10000 0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 13.6803 +/-
13.54 16.59 Component name: 28-Deacetylbelamcandal 0.0285 minutes : Drift Times: 6.69 +/- 0.24 ms
8.42
0 30000 267.06971 487.34258

0 5 10 15 20 529.31416
Retention time [min] 469.33206

Intensity [Counts]
20000
275.20294
451.32227
10000 347.13269
251.09666 555.27324
712.38469
919.31321
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-11-hydro-xyandrographolide [+H] : 14-Deoxy-12R-
hydroxyandrographolide [+H] : (39.7 PPM) 351.2154 : DT=5.26 to 5.74 ms
14-Deoxy-12R-hydroxyandrographolide
13.68
100000

75000
Intensity [Counts]

50000
13.54

13.94
25000

15.01
13.25
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6813 +/-
Channel name: 14-Deoxy-11-hydro-xyandrographolide [+H] : 14-Deoxy-12R- Component name: 14-Deoxy-11-hydro- 0.0285 minutes : Drift Times: 5.50 +/- 0.24 ms
hydroxyandrographolide [+H] : (39.7 PPM) 351.2154 xyandrographolide
13.68
351.21544
1.5e6
1.25e5

Intensity [Counts]
100000 1e6
Intensity [Counts]

75000 5e5
335.24190
13.54 352.21905
299.21980
50000 565.80106 697.41096 888.64706
13.94 0
200 400 600 800 1000
25000 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6813 +/-
15.01 Component name: 14-Deoxy-11-hydro- 0.0285 minutes : Drift Times: 5.34 +/- 0.24 ms
15.25 xyandrographolide
0
351.21548
0 5 10 15 20
Retention time [min]
4e5

Intensity [Counts] 2e5 335.24254

352.21844
299.22158
367.18113
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6813 +/-
Component name: 14-Deoxy-12R- 0.0285 minutes : Drift Times: 5.50 +/- 0.24 ms
hydroxyandrographolide

351.21544
1.5e6

Intensity [Counts]
1e6

5e5
335.24190
352.21905
299.21980
565.80106 697.41096 888.64706
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 13.6813 +/-
Component name: 14-Deoxy-12R- 0.0285 minutes : Drift Times: 5.34 +/- 0.24 ms
hydroxyandrographolide

351.21548

4e5

Intensity [Counts] 2e5 335.24254

352.21844
299.22158
367.18113
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (+)-Bakuchiol [+H] : (39.7 PPM) 257.1921 : DT=4.40 to 4.88 ms

(+)-Bakuchiol
13.68
3000
Intensity [Counts]

2000

1000 13.54

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6823 +/- 0.0285
Channel name: (+)-Bakuchiol [+H] : (39.7 PPM) 257.1921 Component name: (+)-Bakuchiol minutes : Drift Times: 4.64 +/- 0.24 ms
13.69
4e5 275.20326
5000

3e5

Intensity [Counts]
4000

2e5
Intensity [Counts]

3000

100000 257.19209
276.20659
2000 145.10243 295.22231
13.54 0
16.52
13.95 200 400 600 800 1000
1000
Item name: MENGKUDU 2 Channel name: High energy : Time 13.6823 +/- 0.0285
9.57 10.73 14.98
16.67 Component name: (+)-Bakuchiol minutes : Drift Times: 4.49 +/- 0.24 ms
7.20
4.69 5.89
0 275.20292

0 5 10 15 20 1.5e5
Retention time [min]

Intensity [Counts]
100000

50000 257.19144
276.20538
147.11788
330.13081
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 2α,3α,19α,23-Tetrahy-droursa-12-en-28-acid [+H] : (39.7 PPM)
505.3538 : DT=6.60 to 7.08 ms
2α,3α,19α,23-Tetrahy-droursa-12-en-28-acid
4000 13.68

3000
Intensity [Counts]

2000

1000

13.55

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6836 +/-
Channel name: 2α,3α,19α,23-Tetrahy-droursa-12-en-28-acid [+H] : (39.7 PPM) Component name: 2α,3α,19α,23-Tetrahy- 0.0285 minutes : Drift Times: 6.85 +/- 0.24 ms
505.3538 droursa-12-en-28-acid
13.68
487.34289
6000
75000

Intensity [Counts]
469.33267
505.35380
50000
Intensity [Counts]

4000

25000 275.20326
506.35607
451.31889 713.38095
16.61 817.77033
195.13738 364.13472
2000 16.71 0
200 400 600 800 1000
16.51 16.86
Item name: MENGKUDU 2 Channel name: High energy : Time 13.6836 +/-
8.42 9.62 11.91 16.98 Component name: 2α,3α,19α,23-Tetrahy- 0.0285 minutes : Drift Times: 6.70 +/- 0.24 ms
7.79 14.98 17.99 droursa-12-en-28-acid
0
30000 487.34258
0 5 10 15 20 267.06971
Retention time [min]
469.33206 529.31416

Intensity [Counts]
20000
451.32227

10000
251.09666 555.27324
712.38469
589.27159
919.31321
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2187 : DT=7.69 to 8.17 ms
Nigakilactone F
13.68
600
Intensity [Counts]

400

13.62
13.53

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6838 +/- 0.0285
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2187 Component name: Nigakilactone F minutes : Drift Times: 7.95 +/- 0.24 ms
13.71
2e6 711.37683
16.21

2000
5.42 1.5e6

Intensity [Counts]
1e6
Intensity [Counts]

1500
695.40517
8.73 13.54 14.78 712.38047
5.12 16.53 383.15246 681.41742

16.60 5e5
1000 11.98 714.38282
5.76 10.57
16.66 381.15553 385.15375 594.28653
794.35758
8.48 0
16.83 200 400 600 800 1000
500 8.34
4.16 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6838 +/- 0.0285
4.07 16.88
Component name: Nigakilactone F minutes : Drift Times: 7.79 +/- 0.24 ms
1.03
0 267.06970
1e6
0 5 10 15 20
Retention time [min]

Intensity [Counts]
5e5 383.15399

695.40830
227.03824
529.31379 711.38059
211.04254 885.29638
712.38464
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-12R-hydroxyandrographolide [+H] : (39.7 PPM)
351.2155 : DT=5.24 to 5.72 ms
14-Deoxy-12R-hydroxyandrographolide
100000 13.68

75000
Intensity [Counts]

50000
13.54

13.94
25000

14.43
13.25
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6858 +/-
Channel name: 14-Deoxy-12R-hydroxyandrographolide [+H] : (39.7 PPM) 351.2155 Component name: 14-Deoxy-12R- 0.0285 minutes : Drift Times: 5.48 +/- 0.24 ms
13.68 hydroxyandrographolide

351.21544
1.25e5 1.5e6

Intensity [Counts]
100000
1e6
Intensity [Counts]

75000
5e5
13.54 335.24190
352.21905
50000 299.21980
13.94 565.80106 696.40905 888.64706
0
200 400 600 800 1000
25000 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6858 +/-
15.01 Component name: 14-Deoxy-12R- 0.0285 minutes : Drift Times: 5.32 +/- 0.24 ms
15.25 hydroxyandrographolide
0
351.21548
0 5 10 15 20
Retention time [min]
4e5

Intensity [Counts] 2e5 335.24254

352.21844
299.22158
367.18113
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cuminic aldehyde [+H] : (39.7 PPM) 149.0974 : DT=4.50 to 4.98 ms
13.67
Cuminic aldehyde
13.69

400
Intensity [Counts]

300

200 13.62
13.86

13.54
100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6873 +/- 0.0285
Channel name: Cuminic aldehyde [+H] : (39.7 PPM) 149.0974 Component name: Cuminic aldehyde minutes : Drift Times: 4.74 +/- 0.24 ms
6.08
2500 4e5 275.20326

3e5

Intensity [Counts]
2000

2e5
Intensity [Counts]

1500 5.70

100000 257.19209
13.67 276.20659
1000
145.10243 295.22231
579.32179
0
5.40 7.71 16.56 200 400 600 800 1000
500 4.69 7.81 10.00
16.53 16.63 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6873 +/- 0.0285
7.89 10.55
2.49 4.44 13.87 16.88 Component name: Cuminic aldehyde minutes : Drift Times: 4.58 +/- 0.24 ms
2.09
0 275.20292

0 5 10 15 20 1.5e5
Retention time [min]

Intensity [Counts]
100000

50000 257.19144
276.20538
147.11788
377.18606
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nimbolidin E [+H] : (39.7 PPM) 739.3707 : DT=7.68 to 8.16 ms

600

Nimbolidin E
Intensity [Counts]

13.70
13.53
400

13.87

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6916 +/- 0.0285
Channel name: Nimbolidin E [+H] : (39.7 PPM) 739.3707 Component name: Nimbolidin E minutes : Drift Times: 7.92 +/- 0.24 ms
16.51
2e6 711.37683

14.80

1500 1.5e6

Intensity [Counts]
1e6
Intensity [Counts]

14.91 695.40517
13.65 712.38047
1000 383.15246 681.41742
5e5
13.61
11.19 594.28653 714.38282
10.33 381.15553
839.35574
10.27 0
500 200 400 600 800 1000
9.39 16.72
6.73 9.35 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6916 +/- 0.0285
4.33 16.84 Component name: Nimbolidin E minutes : Drift Times: 7.77 +/- 0.24 ms
2.53 6.44
3.49
0 267.06970
1e6
0 5 10 15 20
Retention time [min]

Intensity [Counts]
5e5 383.15399

695.40830
227.03824
529.31379 711.38059
211.04254 885.29638
712.38464
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1,1,6-Trimethyl-1,2-dihydronaphthalene [+H] : (39.7 PPM)
173.1336 : DT=4.55 to 5.04 ms
1,1,6-Trimethyl-1,2-dihydronaphthalene
13.69

13.67
300
Intensity [Counts]

200 13.54

100
13.83

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6927 +/-
Channel name: 1,1,6-Trimethyl-1,2-dihydronaphthalene [+H] : (39.7 PPM) 173.1336 Component name: 1,1,6-Trimethyl-1,2- 0.0285 minutes : Drift Times: 4.80 +/- 0.24 ms
6.45 dihydronaphthalene

4e5 275.20326
1000 13.69
10.45

Intensity [Counts]
16.51
750
Intensity [Counts]

16.58 2e5
10.52
0.98 13.54
7.76
500 257.19209
9.47 276.20659
12.53 145.10243
5.84 293.21341 579.32179
0
5.69 13.96 16.69 200 400 600 800 1000
250
4.42 16.81 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6927 +/-
16.91 Component name: 1,1,6-Trimethyl-1,2- 0.0285 minutes : Drift Times: 4.64 +/- 0.24 ms
dihydronaphthalene
0
275.20292
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

257.19144
276.20538
147.11788
346.12693
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Belachinal [+H] : (39.7 PPM) 487.3429 : DT=7.66 to 8.15 ms
Belachinal
500 13.69

400
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6928 +/- 0.0285 minutes :
Channel name: Belachinal [+H] : (39.7 PPM) 487.3429 Component name: Belachinal Drift Times: 7.90 +/- 0.24 ms
16.86
2e6 711.37683
30000

1.5e6

Intensity [Counts]
1e6
Intensity [Counts]

20000
695.40517
712.38047
383.15246 681.41742
5e5
13.68 714.38282
381.15553 594.28653
10000 839.35574
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 13.6928 +/- 0.0285 minutes :
13.54 16.59 Component name: Belachinal Drift Times: 7.75 +/- 0.24 ms
8.42
0 267.06970
1e6
0 5 10 15 20
Retention time [min]

Intensity [Counts]
5e5 383.15399

695.40830
227.03824
529.31379 711.38059
211.04254 885.29638
712.38464
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganolucidic acid B [+H] : (39.7 PPM) 503.3364 : DT=6.56 to 7.04 ms

4000

3000
Intensity [Counts]

2000

1000
Ganolucidic acid B
13.69

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.6933 +/- 0.0285
Channel name: Ganolucidic acid B [+H] : (39.7 PPM) 503.3364 Component name: Ganolucidic acid B minutes : Drift Times: 6.80 +/- 0.24 ms
16.86
487.34289
6000

75000

Intensity [Counts]
469.33267
505.35380
16.61 50000
Intensity [Counts]

4000

8.07
9.54 25000 275.20326
506.35607
451.31889 713.38095
257.19216 817.77033
2000 7.98
0
9.70 16.49 200 400 600 800 1000
13.69
7.55 Item name: MENGKUDU 2 Channel name: High energy : Time 13.6933 +/- 0.0285
15.61 17.00
12.26 Component name: Ganolucidic acid B minutes : Drift Times: 6.64 +/- 0.24 ms
7.24
17.72
0 30000 487.34258
267.06971
0 5 10 15 20
Retention time [min] 469.33206

Intensity [Counts]
20000
275.20294
451.32227
511.30209
10000 347.13269
251.09666
530.31748 712.38469
834.30604
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimidahuside J [+H] : (39.7 PPM) 677.3922 : DT=4.93 to 5.42 ms
500 Cimidahuside J
13.70

400
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.7024 +/- 0.0285
Channel name: Cimidahuside J [+H] : (39.7 PPM) 677.3922 Component name: Cimidahuside J minutes : Drift Times: 5.25 +/- 0.24 ms
16.76
335.24190
5000

2e5

Intensity [Counts]
4000
347.13171
Intensity [Counts]

3000 100000
367.18108
16.55 695.40517

2000 13.66 677.39223 697.41096


16.50 334.23945 368.18392
13.54 16.94 0
200 400 600 800 1000
1000 14.41 Item name: MENGKUDU 2 Channel name: High energy : Time 13.7024 +/- 0.0285
13.39 Component name: Cimidahuside J minutes : Drift Times: 5.09 +/- 0.24 ms
8.96 10.23 18.53
4.55 6.98
0 335.24254

0 5 10 15 20
Retention time [min] 100000

Intensity [Counts]
367.18113

50000
267.06978
219.15746
695.40830
368.18486
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Florilenalin isovalerate [+H] : (39.7 PPM) 349.1988 : DT=5.08 to 5.57
ms
Florilenalin isovalerate
13.74

12.94 15.48
4000

16.54
Intensity [Counts]

3000
16.59

2000
12.27

12.11
1000
11.96
11.51 16.75

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.7465 +/-
Channel name: Florilenalin isovalerate [+H] : (39.7 PPM) 349.1988 Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.33 +/- 0.24 ms
13.74
13.42 349.19879
6000 12.94 15.47
50000

Intensity [Counts]
16.54
Intensity [Counts]

4000 16.60
25000
5.02
345.13510 363.17556

12.75 227.03760 385.15371 615.70696 699.31826 869.39043


2000 12.28 0
12.11 200 400 600 800 1000

16.75 Item name: MENGKUDU 2 Channel name: High energy : Time 13.7465 +/-
7.67 8.34 11.12
4.66 Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.17 +/- 0.24 ms
2.73 6.08 16.99
0 349.20185

0 5 10 15 20 20000
Retention time [min]

Intensity [Counts]
10000
383.15410
179.12608 317.17198
419.18233
624.18174
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Rel-2R-methyl-5S-acetoxy-4R-furano-germacr-1(10)Z-en-6-one
[+H] : (39.7 PPM) 321.1684 : DT=4.75 to 5.24 ms

600 Rel-2R-methyl-5S-acetoxy-4R-furano-germacr-1(10)Z-en-6-one
13.74

400
Intensity [Counts]

13.67

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.7531 +/-
Channel name: Rel-2R-methyl-5S-acetoxy-4R-furano-germacr-1(10)Z-en-6-one Component name: Rel-2R-methyl-5S- 0.0285 minutes : Drift Times: 4.99 +/- 0.24 ms
[+H] : (39.7 PPM) 321.1684 acetoxy-4R-furano-germacr-1(10)Z-en-6-one
1000 7.85
10000 345.13510
321.16842
13.74
363.12596

Intensity [Counts]
750
16.59
12.03 291.19588
5000 615.70696
Intensity [Counts]

10.47 381.15775
10.25 14.51 253.05293
12.92
500 5.94 15.03
5.64 9.66 542.27307
868.36920
4.66
2.13
4.13 18.55 0
250 200 400 600 800 1000
2.06 18.32
Item name: MENGKUDU 2 Channel name: High energy : Time 13.7531 +/-
Component name: Rel-2R-methyl-5S- 0.0285 minutes : Drift Times: 4.84 +/- 0.24 ms
acetoxy-4R-furano-germacr-1(10)Z-en-6-one
0
291.19569
0 5 10 15 20
Retention time [min] 321.16703
4000 219.04345

Intensity [Counts]
201.03582 352.12151
2000
120.97435 370.13187

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Acetoxy-7β-senecioyloxy-notonipetranone [+H] : (39.7 PPM)
377.2310 : DT=5.38 to 5.86 ms

1250

1000
Intensity [Counts]

750
14-Acetoxy-7β-senecioyloxy-notonipetranone
13.78
500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.7850 +/-
Channel name: 14-Acetoxy-7β-senecioyloxy-notonipetranone [+H] : (39.7 PPM) Component name: 14-Acetoxy-7β- 0.0285 minutes : Drift Times: 5.61 +/- 0.24 ms
377.2310 senecioyloxy-notonipetranone
16.56
377.23103
2500
16.59
10000

Intensity [Counts]
2000
401.16499
Intensity [Counts]

14.76 5000 350.20158 415.16778


1500
335.10843 542.67174 623.69763
5.14 699.31826 809.30062
333.10672
1000 839.35047
13.78 0
13.17 200 400 600 800 1000
10.29 14.86
500 16.75
4.75 7.15 8.62 Item name: MENGKUDU 2 Channel name: High energy : Time 13.7850 +/-
16.84 Component name: 14-Acetoxy-7β- 0.0285 minutes : Drift Times: 5.46 +/- 0.24 ms
3.96
1.84 17.38 senecioyloxy-notonipetranone
0
175.03964
0 5 10 15 20 7500
Retention time [min]

Intensity [Counts]
167.07046
5000
345.11221
377.22535
2500
413.21712 624.18174 839.35433

435.15721
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ligustroside [+H] : (39.7 PPM) 525.1943 : DT=6.23 to 6.71 ms

1250
Ligustroside
13.85
1000
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.8487 +/- 0.0285
Channel name: Ligustroside [+H] : (39.7 PPM) 525.1943 Component name: Ligustroside minutes : Drift Times: 6.48 +/- 0.24 ms
8.91
525.19432
13.16
8.37
2000 10000 513.26694

Intensity [Counts]
14.10
4.65
6.38
1500
Intensity [Counts]

9.29 471.24590
13.09 5000 574.21823
8.29
9.44 427.26838
4.34 784.27050 880.81932
1000 7.60 9.49 297.07740 691.27783
5.35

4.12 0
0.80 3.44 14.2016.49 200 400 600 800 1000
500
3.22 16.56 Item name: MENGKUDU 2 Channel name: High energy : Time 13.8487 +/- 0.0285
16.61 Component name: Ligustroside minutes : Drift Times: 6.32 +/- 0.24 ms

0 525.19561
7500
0 5 10 15 20
Retention time [min]

Intensity [Counts]
5000
543.31302

216.06653 383.15399 555.27676


2500
569.28568 839.35399
641.27474
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Notonipetranone [+H] : (39.7 PPM) 379.2470 : DT=5.33 to 5.81 ms

4000

3000
Intensity [Counts]

2000

1000
13.82

Notonipetranone
0 13.92

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.9233 +/- 0.0285
Channel name: Notonipetranone [+H] : (39.7 PPM) 379.2470 Component name: Notonipetranone minutes : Drift Times: 5.57 +/- 0.24 ms
16.53
351.21542
4e5
8000

Intensity [Counts]
6000
Intensity [Counts]

2e5

4000 335.24163 367.18029

315.18204 375.21377 560.19319


848.27968
0
2000 200 400 600 800 1000
11.48 12.27 Item name: MENGKUDU 2 Channel name: High energy : Time 13.9233 +/- 0.0285
8.97 14.68 16.87 Component name: Notonipetranone minutes : Drift Times: 5.42 +/- 0.24 ms
7.18
0 1.5e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
H
O

100000 O
O
O
H
H

50000
335.24182
351.21606
331.15872 Mass error: -0.5 mDa
211.06501 414.19003
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Kadsurenin E [+H] : (39.7 PPM) 345.1693 : DT=5.20 to 5.68 ms

1250

1000
Intensity [Counts]

750

500
Kadsurenin E
13.94

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.9335 +/- 0.0285
Channel name: Kadsurenin E [+H] : (39.7 PPM) 345.1693 Component name: Kadsurenin E minutes : Drift Times: 5.44 +/- 0.24 ms
6.49
351.21542
4e5
1500
6.43

Intensity [Counts]
6.54
Intensity [Counts]

1000 2e5

6.58
3.75 6.34 335.24163
11.18 367.18029
6.61 16.56
9.85 267.06942
13.51 383.15295
3.25 5.37 227.03867 695.40532 848.27968
500 13.55 0
12.28
1.38 200 400 600 800 1000
2.88 14.91
16.73 Item name: MENGKUDU 2 Channel name: High energy : Time 13.9335 +/- 0.0285
Component name: Kadsurenin E minutes : Drift Times: 5.29 +/- 0.24 ms
16.80
0 351.21606
1.5e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

50000
335.24182 367.18011
267.06920
385.15362
211.06501 695.40666
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Harpagide [+H] : (39.7 PPM) 365.1418 : DT=4.93 to 5.42 ms

4000

3000
Harpagide
Intensity [Counts]

13.94

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.9342 +/- 0.0285 minutes :
Channel name: Harpagide [+H] : (39.7 PPM) 365.1418 Component name: Harpagide Drift Times: 5.18 +/- 0.24 ms
13.66
60000 347.13125
13.53

7500

Intensity [Counts]
267.06942 365.14175
40000
383.15295
Intensity [Counts]

227.03867
5000 20000
13.94
385.15324
5.55 695.40532
225.02107
0.58 5.09 16.66 0
2500
4.49 6.11 7.30 200 400 600 800 1000
14.40
1.62 3.69 Item name: MENGKUDU 2 Channel name: High energy : Time 13.9342 +/- 0.0285 minutes :
9.78 12.45
8.53 Component name: Harpagide Drift Times: 5.02 +/- 0.24 ms
2.78

0 347.13198

0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
267.06920

227.03811
365.14316
10000
211.06339
385.15362
179.01516

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Aucubin [+H] : (39.7 PPM) 347.1313 : DT=4.88 to 5.37 ms

8000

6000
13.67
Intensity [Counts]

13.64 13.71
4000 13.53 Aucubin
13.94

2000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.9349 +/- 0.0285 minutes :
Channel name: Aucubin [+H] : (39.7 PPM) 347.1313 Component name: Aucubin Drift Times: 5.12 +/- 0.24 ms
4.34
60000 347.13125
15000

Intensity [Counts]
267.06942 365.14175
40000
383.15295
13.68
Intensity [Counts]

10000
13.54 227.03867
20000

385.15324
13.94 695.40532
225.02107
5000 0
5.43 10.33 200 400 600 800 1000
5.62 10.66
8.01 14.43 Item name: MENGKUDU 2 Channel name: High energy : Time 13.9349 +/- 0.0285 minutes :
3.98 6.71 Component name: Aucubin Drift Times: 4.97 +/- 0.24 ms
1.80 10.94
15.04
0 347.13198

0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
267.06920

227.03811
365.14316
10000
211.06339
385.15362
179.01516

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-11-hydro-xyandrographolide [+H] : 14-Deoxy-12R-
hydroxyandrographolide [+H] : (39.7 PPM) 351.2154 : DT=5.28 to 5.76 ms
13.68

100000

75000
Intensity [Counts]

50000
13.54

25000

15.01
13.25
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.9371 +/-
Channel name: 14-Deoxy-11-hydro-xyandrographolide [+H] : 14-Deoxy-12R- Component name: 14-Deoxy-11-hydro- 0.0285 minutes : Drift Times: 5.51 +/- 0.24 ms
hydroxyandrographolide [+H] : (39.7 PPM) 351.2154 xyandrographolide
13.68
351.21542
4e5
1.25e5

Intensity [Counts]
100000
Intensity [Counts]

2e5

75000
335.24163 367.18029
13.54
315.18204 375.21377
50000 695.40532 848.27968
13.94 0
200 400 600 800 1000
25000 Item name: MENGKUDU 2 Channel name: High energy : Time 13.9371 +/-
15.01 Component name: 14-Deoxy-11-hydro- 0.0285 minutes : Drift Times: 5.36 +/- 0.24 ms
15.25 xyandrographolide
0
351.21606
0 5 10 15 20 1.5e5
Retention time [min]

Intensity [Counts]
100000

50000 335.24182 367.18011


331.15872
385.15362
211.06501 695.40666
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2 Channel name: Low energy : Time 13.9371 +/-
Component name: 14-Deoxy-12R- 0.0285 minutes : Drift Times: 5.51 +/- 0.24 ms
hydroxyandrographolide

351.21542
4e5

Intensity [Counts]
2e5

335.24163 367.18029
315.18204 375.21377
695.40532 848.27968
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 13.9371 +/-
Component name: 14-Deoxy-12R- 0.0285 minutes : Drift Times: 5.36 +/- 0.24 ms
hydroxyandrographolide

351.21606
1.5e5

Intensity [Counts]
100000

50000
335.24182 367.18011
331.15872
385.15362
211.06501 695.40666
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Harpagide [+H] : (39.7 PPM) 365.1423 : DT=7.80 to 8.28 ms

2000

1500
Intensity [Counts]

1000

Harpagide
500 13.94

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.9418 +/- 0.0285 minutes :
Channel name: Harpagide [+H] : (39.7 PPM) 365.1423 Component name: Harpagide Drift Times: 8.04 +/- 0.24 ms
13.66
711.37694
2e5
13.53

7500

Intensity [Counts]
Intensity [Counts]

100000 710.37067

5000 695.40532
13.94 383.15295
681.41549
5.55 765.29872
335.24186 555.26190
0.58 794.30172
5.09 16.66 0
2500
4.49 6.11 7.30 200 400 600 800 1000
14.40
1.62 3.69 Item name: MENGKUDU 2 Channel name: High energy : Time 13.9418 +/- 0.0285 minutes :
9.78 12.45
8.53 Component name: Harpagide Drift Times: 7.88 +/- 0.24 ms
2.78

0 267.06954

0 5 10 15 20 383.15336
Retention time [min] 50000

Intensity [Counts]
227.03805

25000 695.40668

211.06508 711.37872
201.03677 384.15623 609.37025 766.30138
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nimbolidin D [+H] : (39.7 PPM) 727.3696 : DT=7.75 to 8.23 ms

1000

750
Intensity [Counts]

500

Nimbolidin D
250 13.95

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 13.9434 +/- 0.0285
Channel name: Nimbolidin D [+H] : (39.7 PPM) 727.3696 Component name: Nimbolidin D minutes : Drift Times: 7.99 +/- 0.24 ms
11.56
711.37694
2e5
10.27

2000

Intensity [Counts]
Intensity [Counts]

1500 100000 710.37067


16.52
695.40532
16.56 383.15295
681.41549
1000 765.29872
365.14227 555.26190
13.61 794.30172
10.07
0
13.95 16.69 200 400 600 800 1000
500 9.21 16.75 Item name: MENGKUDU 2 Channel name: High energy : Time 13.9434 +/- 0.0285
3.94 5.57 7.55
16.90 Component name: Nimbolidin D minutes : Drift Times: 7.83 +/- 0.24 ms
2.58
0 267.06954

0 5 10 15 20 383.15336
Retention time [min] 50000

Intensity [Counts]
227.03805

25000 695.40668

211.06508 711.37872
201.03677 384.15623 609.37025 766.30138
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Florilenalin isovalerate [+H] : (39.7 PPM) 349.1992 : DT=5.11 to 5.59
ms
13.74

13.42
4000
12.94

3000 Florilenalin isovalerate


Intensity [Counts]

14.01

2000
12.85
12.75
1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.0159 +/-
Channel name: Florilenalin isovalerate [+H] : (39.7 PPM) 349.1992 Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.35 +/- 0.24 ms
13.74
13.42 370.13037

6000 15.47 75000


12.94

Intensity [Counts]
16.54 50000 336.14640
Intensity [Counts]

4000 16.60
296.12922
5.02 25000

12.75 262.14373 404.16774


623.31312 808.35939 998.37458
2000 12.28 0
12.11 200 400 600 800 1000

16.75 Item name: MENGKUDU 2 Channel name: High energy : Time 14.0159 +/-
7.67 8.34 11.12
4.66 Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.19 +/- 0.24 ms
2.73 6.08 16.99
0 370.12975

0 5 10 15 20 30000
Retention time [min] 336.14512

Intensity [Counts]
20000
381.26281

10000 222.07733
417.15343
103.05602
426.14725 808.34935
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Inuchinenolide C [+H] : (39.7 PPM) 367.1764 : DT=5.27 to 5.76 ms
13.64
13.54 13.70
4000

3000 13.93
Intensity [Counts]

2000

14.91
14.97
1000 15.04
5.42 10.50
8.26 10.13 13.18 15.15
2.76 4.28 6.44
15.84
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.0721 +/- 0.0285
Channel name: Inuchinenolide C [+H] : (39.7 PPM) 367.1764 Component name: Inuchinenolide C minutes : Drift Times: 5.52 +/- 0.24 ms
13.69
12500 386.12497
13.64
20000
13.54
367.17640
10000

Intensity [Counts]
13.94 299.11422
Intensity [Counts]

7500 10000

432.16813
5000 630.18683 727.72540 984.38311
0
15.04
200 400 600 800 1000
2500
15.15 Item name: MENGKUDU 2 Channel name: High energy : Time 14.0721 +/- 0.0285
5.42 6.44 8.26 10.50 13.04 Component name: Inuchinenolide C minutes : Drift Times: 5.36 +/- 0.24 ms
2.76
15.63
0 312.12338
7500
0 5 10 15 20
Retention time [min] 379.24462

Intensity [Counts]
5000 287.05548
386.12330

2500 280.10638
419.18753
192.06383

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lucidenic acid A [+H] : (39.7 PPM) 459.2732 : DT=5.91 to 6.39 ms

7500
Intensity [Counts]

5000

2500

Lucidenic acid A
14.09
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.0844 +/- 0.0285
Channel name: Lucidenic acid A [+H] : (39.7 PPM) 459.2732 Component name: Lucidenic acid A minutes : Drift Times: 6.15 +/- 0.24 ms
7.81
427.26829
12500 30000

Intensity [Counts]
10000
20000
Intensity [Counts]

7500
10000 490.17258

421.21830 525.19373 714.24857 857.29288


5000 387.13420 643.24679
0
16.56 200 400 600 800 1000
2500 16.84 Item name: MENGKUDU 2 Channel name: High energy : Time 14.0844 +/- 0.0285
7.00
13.76 Component name: Lucidenic acid A minutes : Drift Times: 6.00 +/- 0.24 ms
6.64 9.77 14.81
0 15000 427.26748

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000

5000 289.08613
526.17998
119.08582
659.27217 875.24406
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Epianhydrobelachinal [+H] : (39.7 PPM) 469.3312 : DT=6.37 to 6.85
ms

4000

3000
Intensity [Counts]

2000

1000

Epianhydrobelachinal
14.11
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.1092 +/-
Channel name: Epianhydrobelachinal [+H] : (39.7 PPM) 469.3312 Component name: Epianhydrobelachinal 0.0285 minutes : Drift Times: 6.61 +/- 0.24 ms
13.68
504.21256
6000 20000

Intensity [Counts]
Intensity [Counts]

4000 10000
469.33124 526.19458

465.28846 589.20193
599.28031
866.24310 983.37967
451.19402
16.50
2000 13.56 0
8.429.61 16.62 200 400 600 800 1000
12.37 14.10
7.90 9.74 Item name: MENGKUDU 2 Channel name: High energy : Time 14.1092 +/-
14.24 16.91
10.10 Component name: Epianhydrobelachinal 0.0285 minutes : Drift Times: 6.46 +/- 0.24 ms
6.07
7.11 17.51
0 504.21180

0 5 10 15 20 10000 525.19255
Retention time [min]

Intensity [Counts]
470.21925 588.19747
5000
171.11631 433.16043
339.12783 589.19814
659.27244
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Inuchinenolide C [+H] : (39.7 PPM) 367.1764 : DT=5.26 to 5.74 ms
13.64
13.54 13.70
4000

3000 13.93
Intensity [Counts]

2000

14.91
14.97
1000 15.04
5.42 10.50
8.26 10.13 13.18 15.15
2.76 4.28 6.44
15.84
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.1338 +/- 0.0285
Channel name: Inuchinenolide C [+H] : (39.7 PPM) 367.1764 Component name: Inuchinenolide C minutes : Drift Times: 5.50 +/- 0.24 ms
13.69
12500 351.21528
13.64

13.54 75000

10000

Intensity [Counts]
13.94 50000
Intensity [Counts]

7500

25000 323.18309
379.25102
5000
720.31406
177.05596 423.23274 656.24417
0
15.04
200 400 600 800 1000
2500
15.15 Item name: MENGKUDU 2 Channel name: High energy : Time 14.1338 +/- 0.0285
5.42 6.44 8.26 10.50 13.04 Component name: Inuchinenolide C minutes : Drift Times: 5.35 +/- 0.24 ms
2.76
15.63
0 351.21621

0 5 10 15 20 40000
Retention time [min]

Intensity [Counts]
20000

323.18341
379.24483

307.09929 396.21432
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3249 : DT=6.36 to 6.84 ms

2500

2000
Intensity [Counts]

1500

1000

Poricoic acid B
14.20
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.1904 +/- 0.0285
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3249 Component name: Poricoic acid B minutes : Drift Times: 6.60 +/- 0.24 ms
9.37
538.19741

6000

Intensity [Counts]
10000

8.07 511.25043
Intensity [Counts]

463.27881
4000 9.54 5000
437.20613
275.20175 542.17757 828.27149 910.37880
7.98
9.69 0
2000
16.49 200 400 600 800 1000
11.03
12.63 13.66 16.56
Item name: MENGKUDU 2 Channel name: High energy : Time 14.1904 +/- 0.0285
7.24 14.20 Component name: Poricoic acid B minutes : Drift Times: 6.45 +/- 0.24 ms
16.66
0 20000 352.11996

0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
538.19822
563.26605
511.25123
204.06712
463.27226
639.24162 803.29732
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2221 : DT=5.46 to 5.94 ms

1000

750
Intensity [Counts]

500

Nigakilactone F
14.25
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.2455 +/- 0.0285
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2221 Component name: Nigakilactone F minutes : Drift Times: 5.70 +/- 0.24 ms
13.71
16.21 382.25961

2000

Intensity [Counts]
10000 395.24050
5.42
375.21406
Intensity [Counts]

1500
13.54 14.78
16.53 409.22211
8.73 5000 358.12679
5.13 355.24572
16.60 427.10078
1000 11.98 689.74187
16.66 349.19431 828.26510
9.95
5.77
8.34 0
7.91 16.88 200 400 600 800 1000
500
4.16 Item name: MENGKUDU 2 Channel name: High energy : Time 14.2455 +/- 0.0285
4.07 17.18 Component name: Nigakilactone F minutes : Drift Times: 5.55 +/- 0.24 ms
3.67
2000 192.06568
0
381.25380
0 5 10 15 20
Retention time [min] 425.12839

Intensity [Counts]
358.13564 508.22991
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yadanzioside G [+H] : (39.7 PPM) 769.2923 : DT=7.89 to 8.37 ms

2000

1500
Intensity [Counts]

1000

500

Yadanzioside G
14.27
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.2795 +/- 0.0285
Channel name: Yadanzioside G [+H] : (39.7 PPM) 769.2923 Component name: Yadanzioside G minutes : Drift Times: 8.13 +/- 0.24 ms
9.12
541.28260 805.29543
5000
4000
769.29230
763.31077 839.35128

Intensity [Counts]
4000
748.24843
Intensity [Counts]

2000
3000

2000
10.48
14.80 0
13.24 200 400 600 800 1000
1000 7.09 8.70 11.95 14.91
4.28 Item name: MENGKUDU 2 Channel name: High energy : Time 14.2795 +/- 0.0285
4.22 16.49
6.29 Component name: Yadanzioside G minutes : Drift Times: 7.98 +/- 0.24 ms
1.63 3.73
16.58
0 623.21328
3000 617.20589
0 5 10 15 20
Retention time [min]

Intensity [Counts]
721.33535
2000 276.12045 597.26659

583.26558 895.38566
1000 248.09410 446.20489

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside H [+H] : (39.7 PPM) 613.2834 : DT=6.91 to 7.39 ms
Picrasinoside H
14.33
14.55

3000
14.28
Intensity [Counts]

14.83

2000

1000 15.00

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.3226 +/- 0.0285
Channel name: Picrasinoside H [+H] : (39.7 PPM) 613.2834 Component name: Picrasinoside H minutes : Drift Times: 7.15 +/- 0.24 ms
14.33
5000 14.55 60000 613.28343

Intensity [Counts]
4000
40000
14.84
Intensity [Counts]

3000
20000 564.35200
629.25432
533.32479
2000 637.31559 999.39020
14.99 16.55 0
3.74 7.58
200 400 600 800 1000
1000
5.73 6.43 9.53 11.39 13.74 16.61 Item name: MENGKUDU 2 Channel name: High energy : Time 14.3226 +/- 0.0285
4.85 16.77 Component name: Picrasinoside H minutes : Drift Times: 6.99 +/- 0.24 ms
2.68
0 613.28441

0 5 10 15 20 30000
Retention time [min]

Intensity [Counts]
20000
564.35488

10000
533.32103 629.25447
242.11940
175.03934
639.18859
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosylandrographoside [+H] : (39.7 PPM) 513.2688 : DT=6.51
to 6.99 ms

2000

1500
Intensity [Counts]

1000

500
19β-Glucosylandrographoside
14.35

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.3415 +/-
Channel name: 19β-Glucosylandrographoside [+H] : (39.7 PPM) 513.2688 Component name: 19β- 0.0285 minutes : Drift Times: 6.75 +/- 0.24 ms
12.44 Glucosylandrographoside

11.92 40000 538.19694

3000

Intensity [Counts]
11.84 519.30567
Intensity [Counts]

20000
2000 11.65
12.59
513.26878 591.24153
11.44 12.69
16.60 815.78212 956.39600
490.20775
16.54 0
1000 8.72 200 400 600 800 1000
10.14 16.74
14.08
7.81 14.35 Item name: MENGKUDU 2 Channel name: High energy : Time 14.3415 +/-
1.69 4.60 7.22 18.16 Component name: 19β- 0.0285 minutes : Drift Times: 6.59 +/- 0.24 ms
3.22 Glucosylandrographoside
0
15000 564.35488
0 5 10 15 20 519.30722
Retention time [min]

Intensity [Counts]
10000

501.29962
5000 289.08898 589.23659
287.05381 612.27561

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Crocetin [+H] : (39.7 PPM) 329.1733 : DT=5.02 to 5.51 ms
Crocetin
14.47
300 14.36
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.4689 +/- 0.0285 minutes :
Channel name: Crocetin [+H] : (39.7 PPM) 329.1733 Component name: Crocetin Drift Times: 5.27 +/- 0.24 ms
3.14 8.13
347.18368
16.57
600 14.35
40000

Intensity [Counts]
16.54
3.36
13.88
5.47 7.92 11.81
13.84
Intensity [Counts]

5.33 9.56
400 6.26 20000
5.13 324.19706
4.33 16.69
361.11082
1.77 16.76 267.07057
505.21401 602.18559 847.36951
200 0
0.88 200 400 600 800 1000
18.18
Item name: MENGKUDU 2 Channel name: High energy : Time 14.4689 +/- 0.0285 minutes :
18.48 Component name: Crocetin Drift Times: 5.11 +/- 0.24 ms

0 324.19786

0 5 10 15 20 7500
347.18534
Retention time [min] 349.19863

Intensity [Counts]
5000
322.12880
304.11826 361.23021
2500 211.06709 383.15335
528.13570
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside H [+H] : (39.7 PPM) 613.2852 : DT=6.87 to 7.35 ms
14.33
Picrasinoside H
14.55

3000

14.28
14.84
Intensity [Counts]

2000

1000 15.00

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.5251 +/- 0.0285
Channel name: Picrasinoside H [+H] : (39.7 PPM) 613.2852 Component name: Picrasinoside H minutes : Drift Times: 7.11 +/- 0.24 ms
14.33
5000 14.55 613.28385

75000

Intensity [Counts]
4000
14.84
50000
Intensity [Counts]

3000

25000 549.30146
629.26153
2000 533.34088
318.13534 661.29172
946.36154
14.99 16.55 0
3.74 7.58 200 400 600 800 1000
1000 13.74 16.61
5.73 6.43 8.929.53 11.41 Item name: MENGKUDU 2 Channel name: High energy : Time 14.5251 +/- 0.0285
4.85 16.77 Component name: Picrasinoside H minutes : Drift Times: 6.96 +/- 0.24 ms
2.68
0 613.28529
Chir al

0 5 10 15 20 O
O

O
O H H
O

Retention time [min]


O

40000

Intensity [Counts]
O O
O O
H
O
O

20000 549.30698
Mass error: 1.2 mDa
352.12115 615.29667
145.03043
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinoside H [+H] : (39.7 PPM) 613.2839 : DT=6.90 to 7.38 ms
14.33

Picrasinoside H
14.55

3000
14.28
Intensity [Counts]

14.83

2000

1000 15.00

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.5478 +/- 0.0285
Channel name: Picrasinoside H [+H] : (39.7 PPM) 613.2839 Component name: Picrasinoside H minutes : Drift Times: 7.15 +/- 0.24 ms
14.33
5000 14.55 613.28385

75000

Intensity [Counts]
4000
14.84
50000
Intensity [Counts]

3000

25000
629.26153
589.27342
2000 318.13534 398.16159 661.29172
970.39156
14.99 16.55 0
3.74 7.58 200 400 600 800 1000
1000 13.74 16.61
5.73 6.43 9.53 11.39 Item name: MENGKUDU 2 Channel name: High energy : Time 14.5478 +/- 0.0285
4.85 16.77 Component name: Picrasinoside H minutes : Drift Times: 6.99 +/- 0.24 ms
2.68
0 613.28529

0 5 10 15 20
Retention time [min] 40000

Intensity [Counts] 20000

550.30715 629.26274
318.13564
290.13774
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Pseudolaric acid A O-β-D-glucopyranoside [+H] : (39.7 PPM)
551.2499 : DT=6.61 to 7.09 ms

1000

750
Intensity [Counts]

500

14.53
250
Pseudolaric acid A O-β-D-glucopyranoside
14.55
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.5518 +/-
Channel name: Pseudolaric acid A O-β-D-glucopyranoside [+H] : (39.7 PPM) Component name: Pseudolaric acid A O-β-D- 0.0285 minutes : Drift Times: 6.85 +/- 0.24 ms
551.2499 glucopyranoside
6.59
2500 561.28900

Intensity [Counts]
2000 10000
521.27351
589.27342
Intensity [Counts]

1500 6.76 489.28684


7.73 5000
16.85 486.28592 595.22032
12.89 16.52 858.34023 980.24983
1000 418.17499
9.53 10.57
16.31
0
5.96 8.66
16.90 200 400 600 800 1000
500 5.44
16.99 Item name: MENGKUDU 2 Channel name: High energy : Time 14.5518 +/-
2.49 4.70 Component name: Pseudolaric acid A O-β-D- 0.0285 minutes : Drift Times: 6.69 +/- 0.24 ms
17.80
glucopyranoside
0
613.28529
0 5 10 15 20 50000
Retention time [min]

Intensity [Counts]
25000

191.03476 561.28735
352.12115 629.26274

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3363 : DT=6.39 to 6.88 ms

7500
Intensity [Counts]

5000

2500

Ganoderic acid S
14.60
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.5973 +/- 0.0285
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3363 Component name: Ganoderic acid S minutes : Drift Times: 6.63 +/- 0.24 ms
7.76
465.20414

30000 75000

Intensity [Counts]
50000
Intensity [Counts]

20000

25000 466.20637

275.20158 463.30863 499.30547


838.32965
10000 0
16.65 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 14.5973 +/- 0.0285
13.30 Component name: Ganoderic acid S minutes : Drift Times: 6.48 +/- 0.24 ms
10.20 11.78
0 465.20421

0 5 10 15 20
Retention time [min] 50000

Intensity [Counts] 25000


352.12027 466.20667

204.06728 561.28735

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3055 :
DT=6.44 to 6.92 ms

2500

2000
Intensity [Counts]

1500

3-O-(2′E,4′Z-Decadienoyl) ingenol
1000 14.59

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.6012 +/-
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3055 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.69 +/- 0.24 ms
14.22 ingenol
4000
499.30547

Intensity [Counts]
3000 10000 352.11870
Intensity [Counts]

275.20158 529.33653
5000
2000
14.60 16.59 579.22253
838.32965
16.78 607.23176
10.10 0
1000 12.12 200 400 600 800 1000
14.75
7.81 13.32 Item name: MENGKUDU 2 Channel name: High energy : Time 14.6012 +/-
16.90
3.17 9.42 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.54 +/- 0.24 ms
4.29 7.26 18.46 ingenol
0
20000 352.12027
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
204.06728
353.12272
548.29468
176.07208
561.25190
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2372 : DT=5.64 to 6.12 ms
15.11

1500

15.07
Nigakilactone J
14.62
Intensity [Counts]

1000

13.60

13.02

500 12.89

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.6176 +/- 0.0285
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2372 Component name: Nigakilactone J minutes : Drift Times: 5.88 +/- 0.24 ms
15.12
398.16163
3e5

2000

Intensity [Counts]
2e5
Intensity [Counts]

1500 13.60 16.54

100000
11.20 13.45 16.67 424.04907
1000 369.12195
220.06213 338.10377 438.15425 680.21799
2.94 10.89
0
6.56 10.40 200 400 600 800 1000
500 16.75
5.56 10.33
Item name: MENGKUDU 2 Channel name: High energy : Time 14.6176 +/- 0.0285
2.44 4.06 16.94 Component name: Nigakilactone J minutes : Drift Times: 5.73 +/- 0.24 ms
0.82
0 398.16193
1.5e5
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

416.17297

50000 371.13312

204.06730 417.17120
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6'-Acetylneoandrographolide [+H] : (39.7 PPM) 523.2885 : DT=6.44
to 6.92 ms
16.59
1250

1000
16.62
Intensity [Counts]

750
16.50
16.67

500 16.74
12.11 13.97
8.66 14.75
11.17
16.82
250 5.50 7.75 17.17
2.38 5.06 16.98
0.93
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.6208 +/-
Channel name: 6'-Acetylneoandrographolide [+H] : (39.7 PPM) 523.2885 Component name: 6'- 0.0285 minutes : Drift Times: 6.68 +/- 0.24 ms
16.59 Acetylneoandrographolide
2000
30000 465.20368

Intensity [Counts]
1500 20000
499.30547
Intensity [Counts]

10000 352.11870
1000
529.33653
14.91 16.75 340.11918 559.31054
12.18 838.32965
5.45 11.07 12.81 0
8.65
500 200 400 600 800 1000
8.35 16.82
5.25 7.44 Item name: MENGKUDU 2 Channel name: High energy : Time 14.6208 +/-
16.98
1.49 2.99 5.19 18.44
Component name: 6'- 0.0285 minutes : Drift Times: 6.52 +/- 0.24 ms
Acetylneoandrographolide
0
20000 352.12027
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
204.06728
465.20337 548.29468
131.04952
561.25190
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside [+H] : (39.7 PPM)
681.4206 : DT=7.81 to 8.29 ms
13.68

30000
Intensity [Counts]

20000

13.54
10000

13.94

16.62
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.7053 +/-
Channel name: 24-O-Acetyl-cimigenol-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) Component name: 24-O-Acetyl-cimigenol-3- 0.0285 minutes : Drift Times: 8.05 +/- 0.24 ms
681.4206 O-β-D-xylopyranoside
13.68
681.42064
50000
10000
673.23953

Intensity [Counts]
40000 713.40162
663.37737 765.18086
Intensity [Counts]

5000
30000 770.32418
655.23803
409.21936 789.30585
13.54 594.29706
20000 592.27711
0
200 400 600 800 1000
13.94
10000 Item name: MENGKUDU 2 Channel name: High energy : Time 14.7053 +/-
Component name: 24-O-Acetyl-cimigenol-3- 0.0285 minutes : Drift Times: 7.90 +/- 0.24 ms
16.51
O-β-D-xylopyranoside
0
335.20873
0 5 10 15 20
Retention time [min]
5000

Intensity [Counts]
197.02742
761.38789
375.21476 673.23754 765.18617
2500 159.11751
664.37940 804.31703
644.27082 823.33180
636.27566
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Tracheloionoside [+H] : (39.7 PPM) 517.2643 : DT=6.40 to 6.88 ms

800

600
Intensity [Counts]

400

14.75
Tracheloionoside
200
14.70

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.7286 +/- 0.0285
Channel name: Tracheloionoside [+H] : (39.7 PPM) 517.2643 Component name: Tracheloionoside minutes : Drift Times: 6.64 +/- 0.24 ms
16.59
15000 571.17140
16.54
1250
16.62
16.49 466.20619

Intensity [Counts]
1000 10000
Intensity [Counts]

750
5000
6.03 607.24394
5.97 10.46 12.2013.73 262.11074
6.07 817.33262
13.94 612.24016
500 5.79 9.92
0
16.71
5.69 200 400 600 800 1000
250 5.52 16.82 Item name: MENGKUDU 2 Channel name: High energy : Time 14.7286 +/- 0.0285
4.43 18.49 Component name: Tracheloionoside minutes : Drift Times: 6.49 +/- 0.24 ms
2.84
0 503.20719

0 5 10 15 20 4000 167.06992
Retention time [min] 517.25886

Intensity [Counts]
162.01660 385.16939

572.17383
370.20041
2000 587.26111

589.31816

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Methyl lucidenate F [+H] : (39.7 PPM) 471.2746 : DT=6.44 to 6.92
ms

600
Intensity [Counts]

400

Methyl lucidenate F
200 14.80

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.7935 +/- 0.0285
Channel name: Methyl lucidenate F [+H] : (39.7 PPM) 471.2746 Component name: Methyl lucidenate F minutes : Drift Times: 6.68 +/- 0.24 ms
16.55
15.20
431.22001
1500 30000

Intensity [Counts]
16.63
20000
Intensity [Counts]

1000 13.54 503.21065


699.43816
10000
715.40973
11.72
277.21841 420.17810
11.17 864.30730
8.43
500 9.32 16.76 0
200 400 600 800 1000
7.34
3.81 7.07 17.17 Item name: MENGKUDU 2 Channel name: High energy : Time 14.7935 +/- 0.0285
1.73 5.53 18.17 Component name: Methyl lucidenate F minutes : Drift Times: 6.53 +/- 0.24 ms

0 503.21253
491.29844
0 5 10 15 20 5000 227.03820 575.30214
Retention time [min]
289.08734

Intensity [Counts]
337.19781
699.43953
350.15230
2500
159.11866 715.41237

769.32750

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3379 : DT=6.31 to 6.79 ms

12500

10000
Intensity [Counts]

7500

5000

2500
Ganoderic acid S
14.81
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.7944 +/- 0.0285
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3379 Component name: Ganoderic acid S minutes : Drift Times: 6.61 +/- 0.24 ms
7.76
431.22001
30000
30000

Intensity [Counts]
20000
Intensity [Counts]

503.21065
20000
699.43816
10000
715.40973
521.27640
295.22906
631.27901 768.32412

10000 0
16.65 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 14.7944 +/- 0.0285
13.30 Component name: Ganoderic acid S minutes : Drift Times: 6.45 +/- 0.24 ms
10.20 11.78
0 431.22187

0 5 10 15 20 20000
Retention time [min]

Intensity [Counts]
10000
432.22271
227.03820 351.21753
503.21253 699.43953
211.04144
769.32750
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Bayogenin [+H] : (39.7 PPM) 489.3590 : DT=6.86 to 7.34 ms

Bayogenin
14.80
600
Intensity [Counts]

400
14.92

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.7999 +/- 0.0285 minutes :
Channel name: Bayogenin [+H] : (39.7 PPM) 489.3590 Component name: Bayogenin Drift Times: 7.06 +/- 0.24 ms
16.71
547.29001

15000

Intensity [Counts]
3000 531.32463
16.86
10000 385.16907 597.30596
Intensity [Counts]

353.23151

2000 16.58 659.35394


5000
277.21841 822.27140
667.22771
14.80
0
1000 13.67
200 400 600 800 1000
14.92
13.32 Item name: MENGKUDU 2 Channel name: High energy : Time 14.7999 +/- 0.0285 minutes :
17.18 Component name: Bayogenin Drift Times: 6.91 +/- 0.24 ms
12.65
7.37 11.76
0 369.19695
547.28947
0 5 10 15 20 267.06978
Retention time [min] 10000

Intensity [Counts]
575.30214
5000 541.30473 585.28612
223.09358
615.28626
131.08653
729.30154
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Hyptadienic acid [+H] : (39.7 PPM) 471.3469 : DT=6.67 to 7.15 ms
Hyptadienic acid
14.80
400

300
Intensity [Counts]

200

100 14.91

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.8023 +/- 0.0285
Channel name: Hyptadienic acid [+H] : (39.7 PPM) 471.3469 Component name: Hyptadienic acid minutes : Drift Times: 6.91 +/- 0.24 ms
16.66
547.29001

15000
1000

Intensity [Counts]
14.80 489.35904
10000 385.16907
715.40973
Intensity [Counts]

750 12.21 353.23151

16.74 717.41265
5000
13.29 277.21841
500 11.78 16.84 822.27140 978.84722

16.98 0
9.42 10.52 14.91 200 400 600 800 1000
250 9.34 17.16
6.87 Item name: MENGKUDU 2 Channel name: High energy : Time 14.8023 +/- 0.0285
5.57 6.27
18.17 Component name: Hyptadienic acid minutes : Drift Times: 6.75 +/- 0.24 ms
1.89 3.40 6.19
0 369.19695
547.28947
0 5 10 15 20 267.06978
Retention time [min] 10000

Intensity [Counts]
575.30214
5000 541.30473 585.28612
131.08653
699.43953
715.41237
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Methyl ganoderenate D [+H] : (39.7 PPM) 527.2994 : DT=6.54 to
7.02 ms
8.73
1500
Intensity [Counts]

1000 8.82
16.55
8.86
16.60

500 14.97

8.61 9.40
12.86
5.97 6.65 8.47 16.74
11.78
5.74 16.86
1.43 5.64
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.8099 +/-
Channel name: Methyl ganoderenate D [+H] : (39.7 PPM) 527.2994 Component name: Methyl ganoderenate D 0.0285 minutes : Drift Times: 6.78 +/- 0.24 ms
8.73
3000 715.40973

7500

Intensity [Counts]
8.85 507.36817 577.28444
5000
2000 16.55 717.41265
Intensity [Counts]

453.33792
277.21841
822.27140
14.77 2500 865.29782

14.91
1000
0
200 400 600 800 1000
7.54
12.86 16.86
7.25 12.53 Item name: MENGKUDU 2 Channel name: High energy : Time 14.8099 +/-
2.98 17.12 Component name: Methyl ganoderenate D 0.0285 minutes : Drift Times: 6.63 +/- 0.24 ms
3.99 6.65
18.42
0 369.19695
547.28947
0 5 10 15 20 267.06978
Retention time [min] 10000

Intensity [Counts]
503.21253
227.03820 575.30214
5000
615.28626

131.08653 715.41237
769.32750
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Arnicolide D [+H] : (39.7 PPM) 333.1695 : DT=5.50 to 5.98 ms
14.81

400
14.76

Arnicolide D
300 14.94
Intensity [Counts]

14.72

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.9310 +/- 0.0285
Channel name: Arnicolide D [+H] : (39.7 PPM) 333.1695 Component name: Arnicolide D minutes : Drift Times: 5.74 +/- 0.24 ms
5.83
353.23144

1500 5.87

Intensity [Counts]
2e5
14.80

3.15 14.76
364.17700
Intensity [Counts]

3.11 382.18800
1000 5.75 100000
10.32
337.25786
10.07 404.16947
13.43 16.59 227.03845
9.63 10.53 681.16780
6.98 11.32 0
500 16.65
2.33 3.76 200 400 600 800 1000
16.69
2.23 Item name: MENGKUDU 2 Channel name: High energy : Time 14.9310 +/- 0.0285
18.54 Component name: Arnicolide D minutes : Drift Times: 5.59 +/- 0.24 ms

0 353.23178
100000
0 5 10 15 20 336.14671
Retention time [min]

Intensity [Counts]
364.17720

50000

365.18382
227.03856 382.18780
437.25120
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM)
497.2751 : DT=6.21 to 6.69 ms

1250

1000
Intensity [Counts]

750

500

250 19β-Glucosyl-14-deoxyandrographoside
14.95

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.9517 +/-
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM) 497.2751 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 6.45 +/- 0.24 ms
16.73 deoxyandrographoside
3000
465.20388

2500
2e5

Intensity [Counts]
2000 17.96
16.53
Intensity [Counts]

18.11
16.49 100000
1500
12.24 431.21843
467.20967
421.21529
1000 11.90 556.26621 828.28404
16.08 0
14.09 200 400 600 800 1000
11.70
500 11.13 Item name: MENGKUDU 2 Channel name: High energy : Time 14.9517 +/-
5.78 7.29
2.44 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 6.30 +/- 0.24 ms
3.39 4.59 deoxyandrographoside
0
2e5 465.20522
0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

431.21986
467.21120
227.03795 328.14202 613.28520
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ajugaside A [+H] : (39.7 PPM) 659.3273 : DT=7.17 to 7.65 ms

600
Intensity [Counts]

400
Ajugaside A
14.96

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.9634 +/- 0.0285
Channel name: Ajugaside A [+H] : (39.7 PPM) 659.3273 Component name: Ajugaside A minutes : Drift Times: 7.41 +/- 0.24 ms
16.53
632.30033
1250

20000

Intensity [Counts]
1000
Intensity [Counts]

633.30245
750 603.29789
16.67 10000

14.96 659.32732
9.52 10.39 14.80
8.09 387.16908 552.26637
500 8.64 703.29478 999.36684
16.76 0
7.83
16.99 200 400 600 800 1000
3.86 6.70
250
5.92 Item name: MENGKUDU 2 Channel name: High energy : Time 14.9634 +/- 0.0285
2.10 18.54 Component name: Ajugaside A minutes : Drift Times: 7.25 +/- 0.24 ms

0 433.17557
4000
0 5 10 15 20 382.18752
Retention time [min]

Intensity [Counts]
565.33508

2000 654.28398
719.39452
819.36593 969.42327

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Inuchinenolide C [+H] : (39.7 PPM) 367.1765 : DT=5.16 to 5.64 ms

4000

3000
Intensity [Counts]

2000

14.78
1000 14.90

Inuchinenolide C
14.97

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.9759 +/- 0.0285
Channel name: Inuchinenolide C [+H] : (39.7 PPM) 367.1765 Component name: Inuchinenolide C minutes : Drift Times: 5.40 +/- 0.24 ms
13.69
12500 13.64 364.17700
382.18800
13.54 336.14590
100000
10000

Intensity [Counts]
13.94
Intensity [Counts]

7500 50000

318.13460
5000 304.11964 399.14612
624.20732
0
15.04
200 400 600 800 1000
2500
15.15 Item name: MENGKUDU 2 Channel name: High energy : Time 14.9759 +/- 0.0285
5.42 6.44 8.26 10.50 13.04 Component name: Inuchinenolide C minutes : Drift Times: 5.25 +/- 0.24 ms
2.76
15.63
0 336.14671

0 5 10 15 20 75000
Retention time [min]

Intensity [Counts]
50000

25000 318.13518
308.14914
351.19820
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM)
497.2736 : DT=6.48 to 6.97 ms
16.72

1000

16.49
750
Intensity [Counts]

500 16.07
12.23
11.76
14.79
13.14 17.92
250 11.70
6.45 7.86
5.25
1.93 3.25 4.63
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 14.9761 +/-
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM) 497.2736 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 6.73 +/- 0.24 ms
16.73 deoxyandrographoside

465.20388
2500

2e5

Intensity [Counts]
2000
16.53 17.96
Intensity [Counts]

16.49 18.10

1500 100000

12.24
490.31675
1000 625.24265
11.90 318.13506 828.28404
16.08 0
14.09 14.96 200 400 600 800 1000
11.70
500 5.78 7.29 8.90 Item name: MENGKUDU 2 Channel name: High energy : Time 14.9761 +/-
4.17 6.98 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 6.57 +/- 0.24 ms
3.39 deoxyandrographoside
0
490.31799
0 5 10 15 20 318.13566
Retention time [min]

Intensity [Counts]
5000 551.35472
329.11678
227.03783

215.08406 488.18710 571.27496


822.32274
205.12382
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-11-hydro-xyandrographolide [+H] : 14-Deoxy-12R-
hydroxyandrographolide [+H] : (39.7 PPM) 351.2152 : DT=5.25 to 5.73 ms
13.68

100000

75000
Intensity [Counts]

50000
13.54

13.94
25000

13.25 15.23

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.0205 +/-
Channel name: 14-Deoxy-11-hydro-xyandrographolide [+H] : 14-Deoxy-12R- Component name: 14-Deoxy-11-hydro- 0.0285 minutes : Drift Times: 5.50 +/- 0.24 ms
hydroxyandrographolide [+H] : (39.7 PPM) 351.2152 xyandrographolide
13.68
351.21522
1.25e5 1.5e5

Intensity [Counts]
100000 100000
Intensity [Counts]

75000
50000
335.24166
13.54
267.06822 354.23474
741.29398
50000 465.20083 654.28429
13.94 0
200 400 600 800 1000
25000 Item name: MENGKUDU 2 Channel name: High energy : Time 15.0205 +/-
15.01 Component name: 14-Deoxy-11-hydro- 0.0285 minutes : Drift Times: 5.34 +/- 0.24 ms
15.25 xyandrographolide
0
351.21616
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

335.24128
25000

193.05039 267.06829 511.14244


423.16201
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2 Channel name: Low energy : Time 15.0205 +/-
Component name: 14-Deoxy-12R- 0.0285 minutes : Drift Times: 5.50 +/- 0.24 ms
hydroxyandrographolide

351.21522
1.5e5

Intensity [Counts]
100000

50000
335.24166
267.06822 354.23474
741.29398
465.20083 654.28429
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 15.0205 +/-
Component name: 14-Deoxy-12R- 0.0285 minutes : Drift Times: 5.34 +/- 0.24 ms
hydroxyandrographolide

351.21616

Intensity [Counts]
50000

335.24128
25000

193.05039 267.06829 511.14244


423.16201
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cimidahuside C [+H] : (39.7 PPM) 695.4001 : DT=7.91 to 8.39 ms

30000
Intensity [Counts]

20000

10000

Cimidahuside C
15.02

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.0224 +/- 0.0285
Channel name: Cimidahuside C [+H] : (39.7 PPM) 695.4001 Component name: Cimidahuside C minutes : Drift Times: 8.21 +/- 0.24 ms
13.68
713.39057
80000

20000

Intensity [Counts]
711.38066
60000 697.41644 715.40094
Intensity [Counts]

683.42784
10000
681.41992
383.15163 731.33823
40000
596.29673 767.30630
13.54 351.21525
852.30991
0
20000 200 400 600 800 1000
13.94
Item name: MENGKUDU 2 Channel name: High energy : Time 15.0224 +/- 0.0285
Component name: Cimidahuside C minutes : Drift Times: 8.05 +/- 0.24 ms
16.61
0 267.06830 367.18020

0 5 10 15 20 383.15187
10000
Retention time [min]

Intensity [Counts]
5000 695.39742
385.16618
713.40682
248.09248 431.21932 691.40000
585.28190 830.40568
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Aucubin [+H] : (39.7 PPM) 347.1327 : DT=4.90 to 5.38 ms

8000

6000
Intensity [Counts]

4000

2000
Aucubin
15.01

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.0228 +/- 0.0285 minutes :
Channel name: Aucubin [+H] : (39.7 PPM) 347.1327 Component name: Aucubin Drift Times: 5.17 +/- 0.24 ms
4.34
383.15117
15000
15000

Intensity [Counts]
347.13265

13.68 10000
Intensity [Counts]

10000
13.54 399.14612
293.21224
5000
227.03808
13.94
592.19442
5000 0
5.43 10.33 200 400 600 800 1000
6.71 10.66 Item name: MENGKUDU 2 Channel name: High energy : Time 15.0228 +/- 0.0285 minutes :
5.62 14.43
1.80 3.98 8.01 12.46 Component name: Aucubin Drift Times: 5.02 +/- 0.24 ms
15.04
0 335.24128

0 5 10 15 20 20000
Retention time [min]

Intensity [Counts]
10000 347.13132

365.17643
201.03572 331.18636 423.16201

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2593 : DT=6.28 to 6.76
ms

600
Intensity [Counts]

400

Semiaquilegoside A
200 15.05

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.0648 +/- 0.0285
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2593 Component name: Semiaquilegoside A minutes : Drift Times: 6.52 +/- 0.24 ms
18.40
495.25925
2000

502.32502
5000

Intensity [Counts]
16.56
1500 16.50 16.61 471.27530 505.25056
Intensity [Counts]

16.44 523.28389
18.32 2500 275.20237 437.25996
749.34073 876.32385
533.23255
1000 16.17 957.38728
8.91 10.87 365.13814
16.11
13.28
15.88
7.10 9.21 0
7.98 9.86 200 400 600 800 1000
500
7.05
3.28 4.65 Item name: MENGKUDU 2 Channel name: High energy : Time 15.0648 +/- 0.0285
Component name: Semiaquilegoside A minutes : Drift Times: 6.37 +/- 0.24 ms
1.48

0 383.15268

0 5 10 15 20 352.11721
3000
Retention time [min] 435.19989

Intensity [Counts]
563.26121
2000
248.09255
191.07160
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid β [+H] : (39.7 PPM) 501.3215 : DT=6.35 to 6.83 ms

Ganoderic acid β
15.09
1000
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.0935 +/- 0.0285
Channel name: Ganoderic acid β [+H] : (39.7 PPM) 501.3215 Component name: Ganoderic acid β minutes : Drift Times: 6.61 +/- 0.24 ms
16.63
40000 547.28796
2000

30000

Intensity [Counts]
15.09
1500
6.89
20000
Intensity [Counts]

9.39 16.88 501.32151

1000 10000
471.27530
463.27653 879.31830
12.59 0
10.76
500 9.31 200 400 600 800 1000
8.84 16.99
6.70 Item name: MENGKUDU 2 Channel name: High energy : Time 15.0935 +/- 0.0285
2.76 Component name: Ganoderic acid β minutes : Drift Times: 6.45 +/- 0.24 ms
3.89 6.37 17.17
2.68
0 547.28994

0 5 10 15 20
15000
Retention time [min]

Intensity [Counts]
10000
501.31902

5000 405.22675

352.11722 622.18906 785.24269


0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 2-Hydroxyesculentic acid [+H] : (39.7 PPM) 519.3300 : DT=6.48 to
6.96 ms

1500

1000
Intensity [Counts]

500

2-Hydroxyesculentic acid
15.09

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.0979 +/-
Channel name: 2-Hydroxyesculentic acid [+H] : (39.7 PPM) 519.3300 Component name: 2-Hydroxyesculentic acid 0.0285 minutes : Drift Times: 6.72 +/- 0.24 ms
16.66
501.32151
2500 548.29121

16.60
10000

Intensity [Counts]
2000
Intensity [Counts]

1500 5000
619.22675
14.36 497.23476
879.31830
1000
0
9.73 12.48 13.52 200 400 600 800 1000
6.88 7.64
500 16.96 Item name: MENGKUDU 2 Channel name: High energy : Time 15.0979 +/-
6.37 Component name: 2-Hydroxyesculentic acid 0.0285 minutes : Drift Times: 6.56 +/- 0.24 ms
17.34
4.17
0 547.28994

0 5 10 15 20
15000
Retention time [min]

Intensity [Counts]
10000
501.31902

5000 405.22675
149.02354
562.31321 785.24269
622.18906
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2352 : DT=5.68 to 6.16 ms
Nigakilactone J
1500 15.11

1250
15.07

1000
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.1153 +/- 0.0285
Channel name: Nigakilactone J [+H] : (39.7 PPM) 423.2352 Component name: Nigakilactone J minutes : Drift Times: 5.92 +/- 0.24 ms
15.12
423.23520

2000 415.18541

Intensity [Counts]
20000
Intensity [Counts]

1500 13.60 16.54


10000
16.58 407.23938
11.20 391.21134 455.17442
1000
16.67 587.28661 749.34021
10.89 273.18290
2.94 803.24518
10.60 0
6.56 200 400 600 800 1000
500 10.40 16.75
5.56 8.43
Item name: MENGKUDU 2 Channel name: High energy : Time 15.1153 +/- 0.0285
2.44 4.06
16.94 Component name: Nigakilactone J minutes : Drift Times: 5.77 +/- 0.24 ms
1.78
0 423.23872
10000 415.18785
0 5 10 15 20
Retention time [min]

Intensity [Counts]
227.03752
5000

167.07074 405.22654 479.22256

391.20944 623.19832

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2866 : DT=6.99 to 7.47 ms

5000

4000
Intensity [Counts]

3000

2000

1000
Azedarachin C
15.13
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.1307 +/- 0.0285
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2866 Component name: Azedarachin C minutes : Drift Times: 7.22 +/- 0.24 ms
12.53
10000
587.28660
10000 585.29034

Intensity [Counts]
7500 15.14 569.27487
12.13
Intensity [Counts]

5000 632.29517
15.38 564.26770
5000 552.36409 655.28941
11.81 993.85787
546.35251 900.30287
15.96
11.73 0
2500 16.41 200 400 600 800 1000
13.04
11.43
8.57 11.02 16.49 Item name: MENGKUDU 2 Channel name: High energy : Time 15.1307 +/- 0.0285
8.07 Component name: Azedarachin C minutes : Drift Times: 7.07 +/- 0.24 ms
2.44 3.51
0 585.28656

0 5 10 15 20
7500
Retention time [min]

Intensity [Counts]
5000 569.27863

551.26489 587.28874
227.03727 598.26495
2500 479.22257
393.15104 657.28361

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2869 : DT=8.08 to 8.56 ms
Azedarachin C
15.13

3000
Intensity [Counts]

2000

1000

14.98

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.1317 +/- 0.0285
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2869 Component name: Azedarachin C minutes : Drift Times: 8.34 +/- 0.24 ms
12.53
10000
100000 749.34015

Intensity [Counts]
7500 15.14
12.13
Intensity [Counts]

50000
587.28688
15.38
5000
11.81 751.34580
731.33086
569.27467
15.96 352.11926 771.31958
11.73 0
2500 16.41 200 400 600 800 1000
13.04
11.43
8.57 11.02 16.49 Item name: MENGKUDU 2 Channel name: High energy : Time 15.1317 +/- 0.0285
8.07 Component name: Azedarachin C minutes : Drift Times: 8.18 +/- 0.24 ms
2.44 3.51
0 20000 587.28781

0 5 10 15 20
569.27802
Retention time [min]

Intensity [Counts]
551.26406

10000
749.34321
360.16953 450.20123
731.33250
771.31944
237.10332 589.29166
827.38807
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Leonuridine [+H] : (39.7 PPM) 349.1471 : DT=5.23 to 5.71 ms
14.78

14.90

3000
Intensity [Counts]

2000
14.94

Leonuridine
15.17
1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.1674 +/- 0.0285
Channel name: Leonuridine [+H] : (39.7 PPM) 349.1471 Component name: Leonuridine minutes : Drift Times: 5.46 +/- 0.24 ms
2.80
14.78 349.14715
14.91
6000 354.23388
10000

Intensity [Counts]
337.25435
385.16728
Intensity [Counts]

227.03891
4000 5000
425.21775
579.22444
15.17
0
2000
5.70 200 400 600 800 1000
5.20 13.50 Item name: MENGKUDU 2 Channel name: High energy : Time 15.1674 +/- 0.0285
2.60 6.10 8.82 9.89 15.91
11.29 Component name: Leonuridine minutes : Drift Times: 5.31 +/- 0.24 ms
2.41
0 349.14466
7500
0 5 10 15 20
Retention time [min] 227.03748

Intensity [Counts]
5000
354.23329
375.21370
2500 225.01953 377.22951

467.08706

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Acetoxy-7β-senecioyloxy-notonipetranone [+H] : (39.7 PPM)
377.2308 : DT=5.28 to 5.76 ms
1500

1000
Intensity [Counts]

500

14-Acetoxy-7β-senecioyloxy-notonipetranone
15.19

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.1885 +/-
Channel name: 14-Acetoxy-7β-senecioyloxy-notonipetranone [+H] : (39.7 PPM) Component name: 14-Acetoxy-7β- 0.0285 minutes : Drift Times: 5.52 +/- 0.24 ms
377.2308 senecioyloxy-notonipetranone
16.56
15000 369.19588
2500
16.59 349.14715

Intensity [Counts]
2000 10000 337.25435
Intensity [Counts]

14.76 377.23075
1500 5000 333.20343
329.17109 383.24371
5.14 579.22444
228.04085 425.21775
1000 643.23481
13.78 0
13.17
10.29 14.86 200 400 600 800 1000
500 16.75
4.75 7.15 8.62 Item name: MENGKUDU 2 Channel name: High energy : Time 15.1885 +/-
16.84 Component name: 14-Acetoxy-7β- 0.0285 minutes : Drift Times: 5.37 +/- 0.24 ms
3.96
1.84 17.38 senecioyloxy-notonipetranone
0
349.14466
0 5 10 15 20 7500 369.19486
Retention time [min]

Intensity [Counts]
227.03748
5000

2500 375.21446
225.01953
179.01622 467.08706

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Methyl lucidenate F [+H] : (39.7 PPM) 471.2750 : DT=6.16 to 6.64
ms
Methyl lucidenate F
800 15.21

600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.2051 +/- 0.0285
Channel name: Methyl lucidenate F [+H] : (39.7 PPM) 471.2750 Component name: Methyl lucidenate F minutes : Drift Times: 6.42 +/- 0.24 ms
16.55
15.20
431.21767
1500 40000

Intensity [Counts]
16.63
Intensity [Counts]

1000 13.54 20000


471.27501

11.72 489.28416
275.20143
11.17
521.31194 823.33199
8.43 16.76
500 9.32 0
200 400 600 800 1000
7.34
3.81 6.63 16.86 Item name: MENGKUDU 2 Channel name: High energy : Time 15.2051 +/- 0.0285
1.73 7.07
5.53 17.17 Component name: Methyl lucidenate F minutes : Drift Times: 6.26 +/- 0.24 ms
2.92
0 431.21963

0 5 10 15 20 30000
Retention time [min]

Intensity [Counts]
20000

432.22041
10000
474.28634
275.20171
501.32479
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosyl-14-deoxy-11,12-didehydroand-rographoside [+H] :
(39.7 PPM) 333.2047 : DT=4.91 to 5.39 ms

3000
Intensity [Counts]

2000

1000

19β-Glucosyl-14-deoxy-11,12-didehydroand-rographoside
0 15.30

0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.2918 +/-
Channel name: 19β-Glucosyl-14-deoxy-11,12-didehydroand-rographoside [+H] : Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 5.15 +/- 0.24 ms
(39.7 PPM) 333.2047 deoxy-11,12-didehydroand-rographoside
16.55
333.20469
5000

Intensity [Counts]
7500

379.12157
Intensity [Counts]

2500 311.21854
5000 271.16932

0
2500 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 15.2918 +/-
12.27 13.66 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 4.99 +/- 0.24 ms
5.96 8.90 9.60 15.30
1.39 3.23 5.00 deoxy-11,12-didehydroand-rographoside
0
228.23294
0 5 10 15 20
Retention time [min] 2000

Intensity [Counts]
409.10879
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Brevilin [+H] : Florilenalin angelate [+H] : (39.7 PPM) 347.1840 :
DT=5.55 to 6.03 ms
Florilenalin angelate
15.34
4000

3000
Intensity [Counts]

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.3347 +/- 0.0285 minutes :
Channel name: Brevilin [+H] : Florilenalin angelate [+H] : (39.7 PPM) 347.1840 Component name: Brevilin Drift Times: 5.79 +/- 0.24 ms
15.34
347.18402

6000 75000

Intensity [Counts]
14.44 50000
Intensity [Counts]

4000
14.17 25000
331.20935 348.18722
7.95 15.81 622.18734 762.23027
2000 0
7.88 13.56 200 400 600 800 1000
8.24 16.53
12.76 Item name: MENGKUDU 2 Channel name: High energy : Time 15.3347 +/- 0.0285 minutes :
6.99 9.19 12.38 16.61
0.92 Component name: Brevilin Drift Times: 5.63 +/- 0.24 ms
2.78 6.93 18.50
0 347.18329

0 5 10 15 20 30000
Retention time [min]

Intensity [Counts]
20000

10000

343.09594 348.18854

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2 Channel name: Low energy : Time 15.3347 +/- 0.0285
Component name: Florilenalin angelate minutes : Drift Times: 5.79 +/- 0.24 ms

347.18402
75000

Intensity [Counts]
50000

25000
331.20935 348.18722
622.18734 762.23027
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 15.3347 +/- 0.0285
Component name: Florilenalin angelate minutes : Drift Times: 5.63 +/- 0.24 ms

347.18329

30000

Intensity [Counts]
20000

10000

343.09594 348.18854
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2605 : DT=6.36 to 6.84
ms

600
Intensity [Counts]

400

Semiaquilegoside A
15.33
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.3416 +/- 0.0285
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2605 Component name: Semiaquilegoside A minutes : Drift Times: 6.60 +/- 0.24 ms
18.39
7500 543.19261
2000
495.26046

Intensity [Counts]
16.50 5000

1500 16.61
Intensity [Counts]

465.25174
16.44
18.32 2500 562.19011
447.30807
16.17 750.34269
1000 8.91 434.29034 875.34739
10.87 16.11
12.91
13.28
7.10 9.21 0
500 200 400 600 800 1000
7.05
Item name: MENGKUDU 2 Channel name: High energy : Time 15.3416 +/- 0.0285
3.28 4.65
Component name: Semiaquilegoside A minutes : Drift Times: 6.45 +/- 0.24 ms
1.48

0 505.33137

0 5 10 15 20 495.25403 517.28419
Retention time [min] 2000 623.19443

Intensity [Counts]
304.11797
351.10490 784.25209
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2855 : DT=7.04 to 7.52 ms

4000
Intensity [Counts]

3000

2000

1000 Azedarachin C
15.38

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.3774 +/- 0.0285
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2855 Component name: Azedarachin C minutes : Drift Times: 7.24 +/- 0.24 ms
10000 12.53
587.28554
15000 569.27596

Intensity [Counts]
7500 15.14
10000
12.13
Intensity [Counts]

15.38
5000 5000 623.19157
11.81 552.24578
624.19536
15.96
11.73 0
2500 13.03 16.41 200 400 600 800 1000
11.43
8.58 11.02 16.49 Item name: MENGKUDU 2 Channel name: High energy : Time 15.3774 +/- 0.0285
8.07 Component name: Azedarachin C minutes : Drift Times: 7.08 +/- 0.24 ms
2.44 3.51
0 7500 569.27876

0 5 10 15 20
Retention time [min]

Intensity [Counts]
5000
587.28616

625.34230
2500
237.10341 360.16919
659.35196
731.32719

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2857 : DT=8.05 to 8.53 ms

3000

Azedarachin C
Intensity [Counts]

15.38
2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.3778 +/- 0.0285
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2857 Component name: Azedarachin C minutes : Drift Times: 8.31 +/- 0.24 ms
10000 12.53
749.33965

1.5e5

Intensity [Counts]
7500 15.14
12.13
100000
Intensity [Counts]

15.38
5000
50000
11.81 751.34398
587.28574 771.31527
15.96
11.73 0
2500 13.03 16.41 200 400 600 800 1000
11.43
8.58 11.02 16.49 Item name: MENGKUDU 2 Channel name: High energy : Time 15.3778 +/- 0.0285
8.07 Component name: Azedarachin C minutes : Drift Times: 8.15 +/- 0.24 ms
2.44 3.51
0 569.27883

0 5 10 15 20 749.34045
Retention time [min]
20000

Intensity [Counts]
587.28619
551.26637

731.32427
10000 360.16899
299.13652 751.34880
237.10192 771.32059
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid β [+H] : (39.7 PPM) 501.3229 : DT=6.40 to 6.88 ms

1000
15.09
Intensity [Counts]

750

500

250
Ganoderic acid β
15.44

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.4402 +/- 0.0285
Channel name: Ganoderic acid β [+H] : (39.7 PPM) 501.3229 Component name: Ganoderic acid β minutes : Drift Times: 6.64 +/- 0.24 ms
16.63
4000 493.34722
2000 501.32285
483.31046
3000

Intensity [Counts]
15.09 506.27020
1500 469.32884 521.26747
6.89 2000
Intensity [Counts]

16.88 539.27574
9.39 811.26888
353.12280 878.27925

1000 1000

12.51 0
10.76 200 400 600 800 1000
500 9.31
8.84 17.00
6.70 Item name: MENGKUDU 2 Channel name: High energy : Time 15.4402 +/- 0.0285
2.76 Component name: Ganoderic acid β minutes : Drift Times: 6.49 +/- 0.24 ms
3.89 6.37 17.17
2.68
0 2000 483.30996

0 5 10 15 20
603.25774
Retention time [min]

Intensity [Counts]
477.29208
176.07049
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lucidenic acid O [+H] : (39.7 PPM) 477.2830 : DT=6.04 to 6.52 ms

8000

6000
Intensity [Counts]

4000

2000

Lucidenic acid O
15.47

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.4699 +/- 0.0285
Channel name: Lucidenic acid O [+H] : (39.7 PPM) 477.2830 Component name: Lucidenic acid O minutes : Drift Times: 6.28 +/- 0.24 ms
7.81
417.15248

15000 4000 477.28300

Intensity [Counts]
489.23830
Intensity [Counts]

10000 2000

5000 0
200 400 600 800 1000
16.59
Item name: MENGKUDU 2 Channel name: High energy : Time 15.4699 +/- 0.0285
16.51 Component name: Lucidenic acid O minutes : Drift Times: 6.13 +/- 0.24 ms
5.94 14.32
0 352.11903
4000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
2000 345.11620

282.10910 489.23896

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-11-oxoandrographolide [+H] : Florilenalin isovalerate
[+H] : (39.7 PPM) 349.1995 : DT=5.05 to 5.54 ms

4000
Intensity [Counts]

3000

2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.4765 +/-
Channel name: 14-Deoxy-11-oxoandrographolide [+H] : Florilenalin isovalerate Component name: 14-Deoxy-11- 0.0285 minutes : Drift Times: 5.31 +/- 0.24 ms
[+H] : (39.7 PPM) 349.1995 oxoandrographolide
13.74
13.42 349.19948

6000 12.94 15.47


50000

Intensity [Counts]
16.54
Intensity [Counts]

4000 16.60
25000

5.02 333.21203 352.11786


12.75 370.12844
268.22681
2000 0
12.28
200 400 600 800 1000
12.11
16.75 Item name: MENGKUDU 2 Channel name: High energy : Time 15.4765 +/-
7.67 8.34 11.12
4.66 Component name: 14-Deoxy-11- 0.0285 minutes : Drift Times: 5.15 +/- 0.24 ms
2.73 6.08 16.99 oxoandrographolide
0
349.19923
0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
10000

370.12946
325.12718 377.23122
205.04924
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2 Channel name: Low energy : Time 15.4765 +/-
Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.31 +/- 0.24 ms

349.19948

50000

Intensity [Counts]
25000

333.21203 352.11786
370.12844
268.22681
0
200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 15.4765 +/-
Component name: Florilenalin isovalerate 0.0285 minutes : Drift Times: 5.15 +/- 0.24 ms

349.19923
20000

Intensity [Counts]
10000

370.12946
325.12718 377.23122
205.04924
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2573 : DT=6.30 to 6.78
ms

600
Intensity [Counts]

400

Semiaquilegoside A
15.64

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.6487 +/- 0.0285
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2573 Component name: Semiaquilegoside A minutes : Drift Times: 6.54 +/- 0.24 ms
18.40
483.30536
2000
495.25728
4000 479.22213
452.29743 539.27428

Intensity [Counts]
16.56
1500 291.19623
16.50 16.61
Intensity [Counts]

16.44
2000
18.32
839.33559
8.91 10.87 16.11 770.81780
1000 821.30861
13.28 15.92
7.10 14.33
9.21 0
7.05 8.05 200 400 600 800 1000
500
3.28 4.65 5.82 Item name: MENGKUDU 2 Channel name: High energy : Time 15.6487 +/- 0.0285
Component name: Semiaquilegoside A minutes : Drift Times: 6.39 +/- 0.24 ms
1.48

0 436.26632

0 5 10 15 20
Retention time [min] 1500 352.11466

Intensity [Counts]
199.14871
559.26508
1000

500

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM)
497.2740 : DT=6.35 to 6.83 ms

1250

1000
Intensity [Counts]

750

500

15.83

250 19β-Glucosyl-14-deoxyandrographoside
15.80

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.8119 +/-
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM) 497.2740 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 6.59 +/- 0.24 ms
3000 16.73 deoxyandrographoside

497.27396
2500
5000

Intensity [Counts]
2000 17.96 527.27972
16.53
Intensity [Counts]

16.49 18.10 551.28041


2500 450.29376
1500
566.27959
12.24

1000 11.90 16.08 0


14.09 14.96 200 400 600 800 1000
11.70
500 5.78 7.29 11.13 Item name: MENGKUDU 2 Channel name: High energy : Time 15.8119 +/-
4.17 6.98 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 6.44 +/- 0.24 ms
3.39 deoxyandrographoside
0
497.27040
0 5 10 15 20 3000
Retention time [min]

Intensity [Counts]
2000
509.29197

517.28207
383.27631
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM)
497.2752 : DT=6.09 to 6.57 ms

1000

750
Intensity [Counts]

500

250
19β-Glucosyl-14-deoxyandrographoside
15.84

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.8735 +/-
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM) 497.2752 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 6.33 +/- 0.24 ms
16.73 deoxyandrographoside
3000
20000 511.15959

2500

Intensity [Counts]
2000 17.96
16.53
Intensity [Counts]

10000
18.11
465.30127 525.30741
1500
12.24
419.28813
809.34463
1000 11.90 304.11926
16.08 0
14.09 200 400 600 800 1000
11.70
500 11.13 Item name: MENGKUDU 2 Channel name: High energy : Time 15.8735 +/-
5.78 7.29
2.44 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 6.17 +/- 0.24 ms
3.39 4.59 deoxyandrographoside
0
149.02426 525.29716
0 5 10 15 20
Retention time [min] 485.32713

Intensity [Counts]
465.30303
2000

318.13410

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid β [+H] : (39.7 PPM) 501.3203 : DT=6.37 to 6.85 ms

1000

750
Intensity [Counts]

Ganoderic acid β
15.90
500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.8880 +/- 0.0285
Channel name: Ganoderic acid β [+H] : (39.7 PPM) 501.3203 Component name: Ganoderic acid β minutes : Drift Times: 6.60 +/- 0.24 ms
16.63
20000 511.15959

15.09 15000

Intensity [Counts]
1500
6.89
10000 501.32031
Intensity [Counts]

9.39 16.88
483.31162 546.34433
1000 465.30127
5000 552.28299
419.28813
304.11926
12.59
12.25 0
500 12.68
9.31 200 400 600 800 1000
16.99
6.70 Item name: MENGKUDU 2 Channel name: High energy : Time 15.8880 +/- 0.0285
2.76 Component name: Ganoderic acid β minutes : Drift Times: 6.44 +/- 0.24 ms
3.89 6.37 17.17
2.68
0 511.15892

0 5 10 15 20
7500
Retention time [min]

Intensity [Counts]
5000 485.32713
525.29716
149.02426
465.30303 547.34478
2500
318.13410

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2570 : DT=6.27 to 6.75
ms
16.62

600 16.44

16.37
16.10
Intensity [Counts]

400
Semiaquilegoside A
15.92

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.9190 +/- 0.0285
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2570 Component name: Semiaquilegoside A minutes : Drift Times: 6.51 +/- 0.24 ms
18.40
10000 495.25697
2000
483.31162 501.32031
7500

Intensity [Counts]
16.56
1500
16.50 16.61
5000
Intensity [Counts]

16.44
18.32 519.29940

1000 8.91 10.87 16.11 2500 419.28813 555.28100


304.11928 827.30428
13.28 15.92
7.10 14.33
9.21 0
7.05 8.05 200 400 600 800 1000
500
3.28 4.65 5.82 Item name: MENGKUDU 2 Channel name: High energy : Time 15.9190 +/- 0.0285
1.48 Component name: Semiaquilegoside A minutes : Drift Times: 6.35 +/- 0.24 ms

0 511.15892

0 5 10 15 20
7500
Retention time [min]

Intensity [Counts]
5000 149.02426

177.05485 465.30303
2500

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Leonuridine [+H] : (39.7 PPM) 349.1478 : DT=5.34 to 5.82 ms

3000

2000
Intensity [Counts]

1000

Leonuridine
15.92

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.9206 +/- 0.0285
Channel name: Leonuridine [+H] : (39.7 PPM) 349.1478 Component name: Leonuridine minutes : Drift Times: 5.58 +/- 0.24 ms
2.79
14.78
353.22963
14.91 15000
6000

Intensity [Counts]
10000
Intensity [Counts]

4000 349.14784
5000
377.22526
337.25691
425.25870
15.17
2000 0
5.70 200 400 600 800 1000
5.20 13.64 Item name: MENGKUDU 2 Channel name: High energy : Time 15.9206 +/- 0.0285
2.60 6.10 8.82 9.89 15.91
13.50 Component name: Leonuridine minutes : Drift Times: 5.42 +/- 0.24 ms
2.41
0 4000 353.23158

0 5 10 15 20
Retention time [min]

Intensity [Counts]
205.05041
2000
393.22212

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Pueroside B [+H] : (39.7 PPM) 623.1962 : DT=7.11 to 7.59 ms

1500
Intensity [Counts]

1000

500

15.97

Pueroside B
0 15.94
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.9471 +/- 0.0285
Channel name: Pueroside B [+H] : (39.7 PPM) 623.1962 Component name: Pueroside B minutes : Drift Times: 7.39 +/- 0.24 ms
5.41
5.07 587.28799
4000 4.55
9.04
20000

Intensity [Counts]
3000 7.13 647.16291
2.66 6.41
Intensity [Counts]

7.89 569.28122
10000
551.27549
2000
673.37309
450.20441
9.16
0
11.17 15.38
1000 1.67 200 400 600 800 1000
4.34 11.21
14.30 Item name: MENGKUDU 2 Channel name: High energy : Time 15.9471 +/- 0.0285
15.96
0.99 Component name: Pueroside B minutes : Drift Times: 7.23 +/- 0.24 ms
18.52
16.32
0 177.05517 569.28593

0 5 10 15 20
Retention time [min] 4000 587.28875

Intensity [Counts]
551.27263
688.16005

360.17129
2000
432.19223
267.06846

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2880 : DT=7.00 to 7.49 ms

5000

4000
Intensity [Counts]

3000
Azedarachin C
15.96
2000

1000

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 15.9555 +/- 0.0285
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2880 Component name: Azedarachin C minutes : Drift Times: 7.24 +/- 0.24 ms
12.53
10000 587.28799

20000

Intensity [Counts]
7500 15.14
12.13
Intensity [Counts]

569.28122
15.38 10000
5000 551.27549
11.81 623.19622
549.34742
15.96 450.20441 673.37309
11.73 0
2500 16.41 200 400 600 800 1000
13.04
11.43
8.57 11.02 16.49 Item name: MENGKUDU 2 Channel name: High energy : Time 15.9555 +/- 0.0285
8.07 Component name: Azedarachin C minutes : Drift Times: 7.08 +/- 0.24 ms
2.44 3.51
0 569.28593

0 5 10 15 20
Retention time [min] 4000 587.28875

Intensity [Counts]
551.27263

360.17129
2000
539.24955 651.37098
267.06846

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM)
497.2757 : DT=6.43 to 6.91 ms

1000

750
Intensity [Counts]

500
19β-Glucosyl-14-deoxyandrographoside
16.08
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.0751 +/-
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM) 497.2757 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 6.67 +/- 0.24 ms
16.73 deoxyandrographoside
3000
497.27566

507.29015
4000

Intensity [Counts]
543.25483

2000 17.96
Intensity [Counts]

16.53
18.11 480.29064
2000
12.24

1000 11.90 16.08 0


14.09 200 400 600 800 1000
11.70
11.13 Item name: MENGKUDU 2 Channel name: High energy : Time 16.0751 +/-
5.78 7.29
2.44 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 6.51 +/- 0.24 ms
3.39 4.59 deoxyandrographoside
0
549.30831
0 5 10 15 20
Retention time [min] 497.27346

Intensity [Counts]
5000 495.25279

2500
385.16739

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Florilenalin angelate [+H] : (39.7 PPM) 347.1833 : DT=5.05 to 5.54
ms
14.48
14.44

15.81
1500
7.96 14.20

7.88
Intensity [Counts]

15.86
14.14
1000
8.24 13.56
16.61
12.77
9.18 12.39
500
6.98 12.25
16.73
4.91 6.93
1.58 2.31
4.17 18.49

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.1397 +/- 0.0285
Channel name: Florilenalin angelate [+H] : (39.7 PPM) 347.1833 Component name: Florilenalin angelate minutes : Drift Times: 5.30 +/- 0.24 ms
15.34
347.18331

6000
10000

Intensity [Counts]
14.44
Intensity [Counts]

4000 5000
14.17 363.17954

7.95
15.81
2000 0
7.88 13.56 200 400 600 800 1000
8.24 16.52
12.76 Item name: MENGKUDU 2 Channel name: High energy : Time 16.1397 +/- 0.0285
6.99 9.19 12.38 16.61
0.92 Component name: Florilenalin angelate minutes : Drift Times: 5.14 +/- 0.24 ms
2.78 6.92 18.50
0 351.21601

0 5 10 15 20 3000
Retention time [min]

Intensity [Counts]
2000
293.21179

1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2205 : DT=5.64 to 6.13 ms
Nigakilactone F
1500 16.21

1000
Intensity [Counts]

500

16.33

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.2100 +/- 0.0285
Channel name: Nigakilactone F [+H] : (39.7 PPM) 409.2205 Component name: Nigakilactone F minutes : Drift Times: 5.88 +/- 0.24 ms
13.71
16.21 409.22055
20000
2000

Intensity [Counts]
5.42
Intensity [Counts]

1500 10000
13.54 14.78
8.73 16.53
5.12 16.60 404.24207
425.19183
1000 11.98 401.16014
16.66
5.76 9.95 481.23523
8.34 0
16.88 200 400 600 800 1000
500 6.25
4.16 Item name: MENGKUDU 2 Channel name: High energy : Time 16.2100 +/- 0.0285
2.18 4.07 17.18
Component name: Nigakilactone F minutes : Drift Times: 5.73 +/- 0.24 ms
3.49
0 409.22101

0 5 10 15 20
Retention time [min] 10000

Intensity [Counts] 5000


393.21896

357.31290 481.27743

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-12S-methoxyandrographolide [+H] : (39.7 PPM)
365.2314 : DT=5.36 to 5.84 ms
16.56
16.60

750

16.49
Intensity [Counts]

500
16.64
16.16
16.76
14-Deoxy-12S-methoxyandrographolide
250 16.23
16.84

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.2257 +/-
Channel name: 14-Deoxy-12S-methoxyandrographolide [+H] : (39.7 PPM) 365.2314 Component name: 14-Deoxy-12S- 0.0285 minutes : Drift Times: 5.60 +/- 0.24 ms
16.56 methoxyandrographolide

393.22283
7500 369.29917
1500

Intensity [Counts]
5000 365.23138
Intensity [Counts]

16.50
1000
2500 277.17895
10.20
16.76
11.83 12.83 16.16
5.60 6.67 0
500 13.64
9.90 200 400 600 800 1000
5.54 7.60 16.83
Item name: MENGKUDU 2 Channel name: High energy : Time 16.2257 +/-
3.69 16.96 Component name: 14-Deoxy-12S- 0.0285 minutes : Drift Times: 5.45 +/- 0.24 ms
1.60
methoxyandrographolide
0
369.29938
0 5 10 15 20
3000 365.23020 393.21896
Retention time [min]

Intensity [Counts]
2000
353.32486

1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2885 : DT=7.01 to 7.49 ms

5000

4000
Intensity [Counts]

3000

2000
Azedarachin C
16.42
1000
16.49

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4143 +/- 0.0285
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2885 Component name: Azedarachin C minutes : Drift Times: 7.24 +/- 0.24 ms
12.53
10000 596.34424
30000

Intensity [Counts]
587.28846
7500 15.14 20000
574.36019
12.13
Intensity [Counts]

569.27914
15.38
10000
5000
11.81 612.31859
622.18700
15.96
11.73 0
2500 16.41 200 400 600 800 1000
11.43 13.04
8.57 11.02 16.49 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4143 +/- 0.0285
8.07 Component name: Azedarachin C minutes : Drift Times: 7.09 +/- 0.24 ms
2.44 3.51
0 596.34513

0 5 10 15 20
20000
Retention time [min]

Intensity [Counts]
10000

575.36193
360.17723
263.13314
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (-)-Borneyl ferulate [+H] : (39.7 PPM) 331.1891 : DT=5.68 to 6.16 ms
(-)-Borneyl ferulate
16.43

1000

750
Intensity [Counts]

500

250
16.53
16.56
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4294 +/- 0.0285
Channel name: (-)-Borneyl ferulate [+H] : (39.7 PPM) 331.1891 Component name: (-)-Borneyl ferulate minutes : Drift Times: 5.94 +/- 0.24 ms
16.43
2000 331.18912 407.24228
10000

Intensity [Counts]
1500 16.58
Intensity [Counts]

5000
425.13404

1000 443.14335

517.27919
13.08 14.52
9.54 10.73
7.27 0
10.79 16.73 200 400 600 800 1000
500 6.80
2.53 4.35
8.70
5.93 5.10 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4294 +/- 0.0285
2.49 16.91 18.54
Component name: (-)-Borneyl ferulate minutes : Drift Times: 5.78 +/- 0.24 ms
2.33
0 353.23268

0 5 10 15 20
10000
Retention time [min]

Intensity [Counts]
5000 331.18661 438.26378

176.07087

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2569 : DT=6.33 to 6.81
ms

600 16.50 16.61

Semiaquilegoside A
16.44

400
Intensity [Counts]

15.93

200
16.73

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4444 +/- 0.0285
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2569 Component name: Semiaquilegoside A minutes : Drift Times: 6.57 +/- 0.24 ms
18.40
556.20929
2000 40000

Intensity [Counts]
16.56
1500
16.50 16.61
Intensity [Counts]

16.44 20000 557.21302


18.32 512.21947

1000 8.91 10.87 16.11 506.31924


13.28 15.92 340.11575 406.35075
7.10 14.33 229.19586
9.21 0
7.05 8.05 200 400 600 800 1000
500
3.28 4.65 5.82 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4444 +/- 0.0285
1.48 Component name: Semiaquilegoside A minutes : Drift Times: 6.42 +/- 0.24 ms

0 495.25884
556.20975
0 5 10 15 20 7500
Retention time [min]

Intensity [Counts]
438.26379
5000
557.21432
406.34161
169.07732
2500 614.29968

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lucidenic acid A [+H] : (39.7 PPM) 459.2728 : DT=6.13 to 6.61 ms

6000
Intensity [Counts]

4000

2000
16.56
16.61
Lucidenic acid A
16.64
16.48
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4734 +/- 0.0285
Channel name: Lucidenic acid A [+H] : (39.7 PPM) 459.2728 Component name: Lucidenic acid A minutes : Drift Times: 6.37 +/- 0.24 ms
7.81
417.20465
30000
12500

Intensity [Counts]
374.29025 451.31971
10000 20000
497.27102
Intensity [Counts]

7500
10000 504.20612
518.23716
205.05251 273.18635
5000 575.26600
0
16.56 200 400 600 800 1000
2500 16.84 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4734 +/- 0.0285
7.00
5.14 13.76 Component name: Lucidenic acid A minutes : Drift Times: 6.22 +/- 0.24 ms
6.64 9.77 14.81
0 417.20577

0 5 10 15 20
15000
Retention time [min]

Intensity [Counts]
374.29223
10000
173.13388 418.31375
159.11805
284.26176 451.18676
5000
539.27564

572.30270
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Melianol [+H] : (39.7 PPM) 613.3380 : DT=6.80 to 7.28 ms
8.52

3000
Intensity [Counts]

2000

1000
8.36
14.54 16.56
11.84 16.76
4.85 5.85 8.13 9.32 12.71
2.36
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4800 +/- 0.0285 minutes :
Channel name: Melianol [+H] : (39.7 PPM) 613.3380 Component name: Melianol Drift Times: 7.04 +/- 0.24 ms
8.52
565.33395

20000 585.32281
4000

Intensity [Counts]
605.38368
552.32165
534.31848
Intensity [Counts]

3000
10000 643.24991
513.31149 645.33056
503.30567 673.28301
275.20203
2000 706.30517
16.56 249.18397 766.21086
0
200 400 600 800 1000
1000 16.67
8.36 14.54 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4800 +/- 0.0285 minutes :
8.13 16.97
9.93 14.24 Component name: Melianol Drift Times: 6.89 +/- 0.24 ms
5.85
0 552.31770

0 5 10 15 20 565.37124
Retention time [min] 133.10201 499.28527 643.25246

Intensity [Counts]
185.13230 485.32605
5000 663.37960
205.05206
223.13081 701.42822

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Poricoic acid E [+H] : (39.7 PPM) 501.3194 : DT=6.65 to 7.13 ms
16.62

600

Poricoic acid E
Intensity [Counts]

16.48
400 16.88

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4843 +/- 0.0285
Channel name: Poricoic acid E [+H] : (39.7 PPM) 501.3194 Component name: Poricoic acid E minutes : Drift Times: 6.89 +/- 0.24 ms
16.63
565.33395

20000
15.09
1500

Intensity [Counts]
537.25484
6.89
568.26170
9.39 497.30929 591.19764
Intensity [Counts]

16.88
10000 491.30556
1000 597.34075
471.35178
627.35667
367.22968
654.34531
12.68 249.18397
12.59 0
500 9.31 200 400 600 800 1000
17.00
6.70 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4843 +/- 0.0285
2.76 Component name: Poricoic acid E minutes : Drift Times: 6.74 +/- 0.24 ms
3.89 6.37 17.17
2.68
0 552.31770

0 5 10 15 20 133.10201 495.25884 565.37124


Retention time [min]

Intensity [Counts]
477.28445 575.26767

165.07036
5000 617.35539
464.30726
273.18396
701.42822

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1α,2α,3β,19α,23-Pentadroxyurs-12-en-28-oic acid-28-O-β-D-
xylopyranoside [+H] : (39.7 PPM) 653.3884 : DT=7.42 to 7.91 ms

1α,2α,3β,19α,23-Pentadroxyurs-12-en-28-oic acid-28-O-β-D-xylopyra…
16.53

400
Intensity [Counts]

16.45

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4846 +/-
Channel name: 1α,2α,3β,19α,23-Pentadroxyurs-12-en-28-oic acid-28-O-β-D- Component name: 1α,2α,3β,19α,23- 0.0285 minutes : Drift Times: 7.66 +/- 0.24 ms
xylopyranoside [+H] : (39.7 PPM) 653.3884 Pentadroxyurs-12-en-28-oic acid-28-O-β-D-
16.57 xylopyranoside
1250
16.53 659.36848 725.45382
657.34649
1000 16.61

Intensity [Counts]
645.35964
16.71 733.20043
10000 547.33673
Intensity [Counts]

750 16.81 742.41867


16.46 244.23028 523.32718
775.40439
16.90 495.30334 781.33584
181.12241
500 16.96
13.54 802.30603
0
13.64 17.11
8.95 10.02 13.20 200 400 600 800 1000
14.73
250 8.61 17.20 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4846 +/-
4.51 6.40 Component name: 1α,2α,3β,19α,23- 0.0285 minutes : Drift Times: 7.51 +/- 0.24 ms
2.30 3.53
Pentadroxyurs-12-en-28-oic acid-28-O-β-D-
0 xylopyranoside
0 5 10 15 20 715.35523
Retention time [min]

Intensity [Counts]
20000 717.37450

159.11798 713.37835
10000 719.39057
645.39012
216.06604 733.19445
791.43657
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (+)-Bakuchiol [+H] : (39.7 PPM) 257.1911 : DT=5.45 to 5.94 ms
(+)-Bakuchiol 16.50
16.48

250

200
Intensity [Counts]

150

16.56
100

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4855 +/- 0.0285
Channel name: (+)-Bakuchiol [+H] : (39.7 PPM) 257.1911 Component name: (+)-Bakuchiol minutes : Drift Times: 5.69 +/- 0.24 ms
13.69
100000 290.27180
5000

75000

Intensity [Counts]
4000

50000
Intensity [Counts]

3000
318.30144
25000
259.20518 391.24495
2000 435.27362
241.23884
13.54 16.52 0
13.95 200 400 600 800 1000
1000
Item name: MENGKUDU 2 Channel name: High energy : Time 16.4855 +/- 0.0285
13.06
9.57 10.73 14.98
16.67 Component name: (+)-Bakuchiol minutes : Drift Times: 5.54 +/- 0.24 ms
7.20
4.69 5.89
0 274.27599

0 5 10 15 20 2e5
Retention time [min]

Intensity [Counts]
100000
290.27088
242.24990
226.21789 407.24164 501.28037
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Trifoside A [+H] : (39.7 PPM) 913.4784 : DT=8.95 to 9.43 ms
Trifoside A
16.48
400

300
16.56
Intensity [Counts]

200 16.61

16.66

16.72
100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4857 +/- 0.0285 minutes :
Channel name: Trifoside A [+H] : (39.7 PPM) 913.4784 Component name: Trifoside A Drift Times: 9.24 +/- 0.24 ms
16.49
985.41139
800
50000

Intensity [Counts]
600 16.61
Intensity [Counts]

25000 968.40059

400 288.25580 827.42643


13.69
16.89 244.23027 290.27183 611.36396 773.42050
9.26 10.11 13.21 18.52
14.93 0
6.55 10.87
8.54 200 400 600 800 1000
200
7.24 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4857 +/- 0.0285 minutes :
0.54 3.08 4.90
Component name: Trifoside A Drift Times: 9.09 +/- 0.24 ms

0 100000 230.24948

0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

288.25484 477.28351 757.41421


985.41977
318.13495 823.35614
131.04831
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3β-Formyloxy-7β,12β-dihydroxy-5α-lanost-11,15,23-trioxo-8-en-
(E)-26-oic acid [+H] : (39.7 PPM) 561.3042 : DT=7.09 to 7.57 ms

400 16.60
16.55

3β-Formyloxy-7β,12β-dihydroxy-5α-lanost-11,15,23-triox…
300 16.49
16.63
Intensity [Counts]

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4881 +/-
Channel name: 3β-Formyloxy-7β,12β-dihydroxy-5α-lanost-11,15,23-trioxo-8-en- Component name: 3β-Formyloxy-7β,12β- 0.0285 minutes : Drift Times: 7.33 +/- 0.24 ms
(E)-26-oic acid [+H] : (39.7 PPM) 561.3042 dihydroxy-5α-lanost-11,15,23-trioxo-8-en-
14.38 (E)-26-oic acid

2000 601.32746
567.31784 639.33371
16.60 20000

Intensity [Counts]
16.63
1500 14.56 559.35590 655.33115
Intensity [Counts]

16.50 547.33673 667.41959


13.80 10000
541.30193 697.40246
1000 275.20203 510.30669 737.33779
13.72
13.65 14.83 249.18397 773.40845
13.39 0
8.66 10.27 200 400 600 800 1000
500 6.27 7.08 16.75
Item name: MENGKUDU 2 Channel name: High energy : Time 16.4881 +/-
16.94 Component name: 3β-Formyloxy-7β,12β- 0.0285 minutes : Drift Times: 7.18 +/- 0.24 ms
5.93
0.92 4.40 dihydroxy-5α-lanost-11,15,23-trioxo-8-en-
0 (E)-26-oic acid
0 5 10 15 20 611.30531
Retention time [min] 10000

Intensity [Counts]
599.29406 643.25246
105.07070
204.06707 477.28445 687.35532
5000 277.21777
700.36915
707.36781
807.43089
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 5-Ene-methylcholate-3-O-β-D-glucopyranoside [+H] : (39.7 PPM)
583.3478 : DT=6.79 to 7.27 ms
16.61

600 5-Ene-methylcholate-3-O-β-D-glucopyranoside
16.51
Intensity [Counts]

400

16.71

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4900 +/-
Channel name: 5-Ene-methylcholate-3-O-β-D-glucopyranoside [+H] : (39.7 PPM) Component name: 5-Ene-methylcholate-3-O- 0.0285 minutes : Drift Times: 7.03 +/- 0.24 ms
583.3478 β-D-glucopyranoside
16.61
565.33395
1250 16.52
20000 585.32281

Intensity [Counts]
537.25484 605.38368
1000
534.31848
Intensity [Counts]

643.24991
10000 511.36028
750 645.33056
673.28301
9.84 16.70 275.20203 485.28622
766.21086
500 16.76 257.19135
14.65 0
11.89 16.96
200 400 600 800 1000
250 7.76 8.87 17.19 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4900 +/-
0.33 2.41 7.56 Component name: 5-Ene-methylcholate-3-O- 0.0285 minutes : Drift Times: 6.88 +/- 0.24 ms
5.91 β-D-glucopyranoside
0
10000 561.33764
0 5 10 15 20
552.31770
Retention time [min] 133.10201 577.33417
425.13689

Intensity [Counts]
643.25246
185.13230 677.36452
5000 352.11869
701.42822

710.34349

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 7β-(3-Ethyl-cis-crotonoyloxy)-14-hydroxy-1α-(2-methylbutyryloxy)
notonipetranone [+H] : (39.7 PPM) 449.2880 : DT=6.16 to 6.65 ms

2000

16.70
1500
Intensity [Counts]

1000
7β-(3-Ethyl-cis-crotonoyloxy)-14-hydroxy-1α-(2-methylb…
16.50

500 16.77

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4906 +/-
Channel name: 7β-(3-Ethyl-cis-crotonoyloxy)-14-hydroxy-1α-(2-methylbutyryloxy) Component name: 7β-(3-Ethyl-cis- 0.0285 minutes : Drift Times: 6.42 +/- 0.24 ms
notonipetranone [+H] : (39.7 PPM) 449.2880 crotonoyloxy)-14-hydroxy-1α-(2-
9.37 methylbutyryloxy) notonipetranone

477.28329

16.70 40000
3000

Intensity [Counts]
16.60
Intensity [Counts]

451.31971 495.30013
20000 275.20200 497.27102
2000 437.25002
9.70 16.50 499.30241
273.18635 418.31083
8.06 10.72
109.10248 597.34273
0
1000 11.03 200 400 600 800 1000
7.96 14.52
13.74 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4906 +/-
7.24 14.80 17.01 Component name: 7β-(3-Ethyl-cis- 0.0285 minutes : Drift Times: 6.27 +/- 0.24 ms
3.76 5.34 18.49 crotonoyloxy)-14-hydroxy-1α-(2-
0 methylbutyryloxy) notonipetranone
0 5 10 15 20 105.07036 173.13388 497.26594
Retention time [min] 10000
451.31568

Intensity [Counts]
418.31375
569.27874
5000
587.33673
619.29280

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Hookeroside D [+H] : (39.7 PPM) 875.4621 : DT=8.66 to 9.14 ms

500 Hookeroside D
16.50

400
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4923 +/- 0.0285
Channel name: Hookeroside D [+H] : (39.7 PPM) 875.4621 Component name: Hookeroside D minutes : Drift Times: 8.90 +/- 0.24 ms
16.50
230.25008

20000
1000

Intensity [Counts]
827.42643 897.46863
13.53
Intensity [Counts]

750 288.25578 799.43458


16.58 10000 663.39249
13.69
649.41350
500 477.28590
633.39926
13.95 16.72
7.71 12.49 0
11.90 14.82 200 400 600 800 1000
250 16.94
0.38 1.82 3.38 7.14 Item name: MENGKUDU 2 Channel name: High energy : Time 16.4923 +/- 0.0285
16.99
5.27 Component name: Hookeroside D minutes : Drift Times: 8.75 +/- 0.24 ms
2.98
0 100000 230.24948

0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

244.22842
133.10198
275.20113 457.33294 741.37659 823.35614 901.57283

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-12S-methoxyandrographolide [+H] : (39.7 PPM)
365.2303 : DT=5.40 to 5.88 ms
16.56

750
14-Deoxy-12S-methoxyandrographolide 16.60
16.49
Intensity [Counts]

500 16.65

16.23
16.16 16.75

250

16.84

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.4951 +/-
Channel name: 14-Deoxy-12S-methoxyandrographolide [+H] : (39.7 PPM) 365.2303 Component name: 14-Deoxy-12S- 0.0285 minutes : Drift Times: 5.66 +/- 0.24 ms
16.56 methoxyandrographolide

288.25581

100000
1500

Intensity [Counts]
Intensity [Counts]

16.50
50000
1000 407.24201
10.20
259.20518 435.27362
11.83 16.76
16.16 226.21900 475.23186
5.60 6.67 13.64 0
500
9.90 13.69 200 400 600 800 1000
5.54 7.60 16.84
Item name: MENGKUDU 2 Channel name: High energy : Time 16.4951 +/-
3.69 Component name: 14-Deoxy-12S- 0.0285 minutes : Drift Times: 5.50 +/- 0.24 ms
1.60 4.83 16.96
methoxyandrographolide
0
288.25485
0 5 10 15 20 75000
290.27088
Retention time [min]

Intensity [Counts]
50000 242.24990

25000 91.05438
407.24164
437.30635
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lucidenic acid O [+H] : (39.7 PPM) 477.2852 : DT=7.87 to 8.35 ms

Lucidenic acid O
400 16.51
Intensity [Counts]

300

200

16.57
100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5018 +/- 0.0285
Channel name: Lucidenic acid O [+H] : (39.7 PPM) 477.2852 Component name: Lucidenic acid O minutes : Drift Times: 8.11 +/- 0.24 ms
7.81
15000 40000 715.35153
665.40496
717.36534
30000 784.21401

Intensity [Counts]
647.39595

10000 20000
Intensity [Counts]

631.40171
352.11959 789.42333
629.38186
10000 318.13472
291.19615 597.33972 790.43193
181.12239 973.49267
5000
0
200 400 600 800 1000
16.59
16.51 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5018 +/- 0.0285
Component name: Lucidenic acid O minutes : Drift Times: 7.95 +/- 0.24 ms
5.94 9.85 12.63 14.32
0 324.12475
290.14099
0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
717.37450
352.11866
769.49338
691.41640
10000
648.41307 773.39393
205.05169 370.12850
829.46994

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 28-Deacetylbelamcandal [+H] : (39.7 PPM) 487.3418 : DT=6.60 to
7.09 ms
16.86

15000
Intensity [Counts]

10000

5000

16.74 16.94
28-Deacetylbelamcandal
16.71
0 16.50
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5055 +/-
Channel name: 28-Deacetylbelamcandal [+H] : (39.7 PPM) 487.3418 Component name: 28-Deacetylbelamcandal 0.0285 minutes : Drift Times: 6.84 +/- 0.24 ms
16.86
553.30181

25000 511.29015 565.33395


20000 495.30013

Intensity [Counts]
577.33643
20000
491.30556 591.19764
Intensity [Counts]

475.34434 597.34075
10000
15000 351.25350
13.68 627.35667
293.21153
273.18635 641.31452 896.60087
10000
0
200 400 600 800 1000
5000 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5055 +/-
13.54 16.59 Component name: 28-Deacetylbelamcandal 0.0285 minutes : Drift Times: 6.69 +/- 0.24 ms
8.42 12.37
0 553.30428

0 5 10 15 20 20000
563.37654
Retention time [min]

Intensity [Counts]
479.26208

157.10183
10000 425.13689 583.31318
161.09679
677.36452
388.39788
701.42822
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Notoginsenoside Fe [+H] : (39.7 PPM) 917.5484 : DT=8.64 to 9.12
ms
16.69
Notoginsenoside Fe
16.50
200 16.77

150
16.87
Intensity [Counts]

100

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5060 +/- 0.0285
Channel name: Notoginsenoside Fe [+H] : (39.7 PPM) 917.5484 Component name: Notoginsenoside Fe minutes : Drift Times: 8.97 +/- 0.24 ms
16.49
827.42643

783.35313 843.45494
663.39249
10000

Intensity [Counts]
600 288.25578
16.61
Intensity [Counts]

16.76

5000 649.41350
400 16.87 639.32959
275.20195
379.24678 501.28185

11.02 16.94 0
200 6.55 13.60
200 400 600 800 1000
0.63 13.23 15.79 17.49
3.42
4.61 8.61 9.53 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5060 +/- 0.0285
2.98 Component name: Notoginsenoside Fe minutes : Drift Times: 8.81 +/- 0.24 ms

0 288.25484

0 5 10 15 20 244.22842 985.41977
15000
Retention time [min]

Intensity [Counts]
823.35614
10000
133.10198 806.35604
857.53983
318.13495
5000 741.37659
379.24639

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 11β,13-Dihydrocostunolide [+H] : (39.7 PPM) 235.1708 : DT=4.52 to
5.00 ms
11β,13-Dihydrocostunolide
16.50
1000

750
Intensity [Counts]

500

250

16.55

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5061 +/-
Channel name: 11β,13-Dihydrocostunolide [+H] : (39.7 PPM) 235.1708 Component name: 11β,13-Dihydrocostunolide 0.0285 minutes : Drift Times: 4.76 +/- 0.24 ms
16.50
240.23380
1500
30000

Intensity [Counts]
20000 277.21676
325.19961
Intensity [Counts]

1000
16.66
10000 235.17079

131.08469 359.17952
500 13.65 14.81 0
9.38 200 400 600 800 1000
8.05 13.01 14.03
Item name: MENGKUDU 2 Channel name: High energy : Time 16.5061 +/-
4.99 6.57
2.80 4.38 16.76 Component name: 11β,13-Dihydrocostunolide 0.0285 minutes : Drift Times: 4.61 +/- 0.24 ms
3.63
17.48
0 240.23405
20000
0 5 10 15 20 275.20124
Retention time [min]

Intensity [Counts]
10000 325.21256
145.10191

348.22354

357.20597
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 25(S)-Ruscogenin [+H] : (39.7 PPM) 431.3162 : DT=6.08 to 6.57 ms
16.66

2000

16.80
1500
Intensity [Counts]

1000
16.59

25(S)-Ruscogenin
500 16.51
16.47 16.91

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5077 +/- 0.0285
Channel name: 25(S)-Ruscogenin [+H] : (39.7 PPM) 431.3162 Component name: 25(S)-Ruscogenin minutes : Drift Times: 6.33 +/- 0.24 ms
16.66
4000 477.28329
431.21966
40000

Intensity [Counts]
3000
Intensity [Counts]

20000 509.27216
16.80 275.20200 418.31083
2000 413.24332 525.30750

16.58 537.29435
211.14725
597.34273
16.47 0
13.69
1000 200 400 600 800 1000
9.37 13.53
Item name: MENGKUDU 2 Channel name: High energy : Time 16.5077 +/- 0.0285
9.70 16.89 Component name: 25(S)-Ruscogenin minutes : Drift Times: 6.17 +/- 0.24 ms
7.22 8.07 11.05 14.72
4.45 17.11
0 431.21973
20000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
105.07036 173.13388
10000 451.31568
467.31222
405.31453
485.29539

573.31357
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Deglucose chikusetsusaponin Ⅳa [+H] : (39.7 PPM) 633.3993 :
DT=8.46 to 8.94 ms

Deglucose chikusetsusaponin Ⅳa
125
16.52
16.46
100
Intensity [Counts]

75

50

25

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5091 +/-
Channel name: Deglucose chikusetsusaponin Ⅳa [+H] : (39.7 PPM) 633.3993 Component name: Deglucose 0.0285 minutes : Drift Times: 8.70 +/- 0.24 ms
16.54 chikusetsusaponin Ⅳa
1500 16.76
697.40416 797.40558
15000
807.38907
684.42238

Intensity [Counts]
897.46863
10000 288.25578 663.39249
1000
Intensity [Counts]

244.23028 645.38469
16.81
5000 609.36230
449.25363

500 16.91 0
12.19 13.09 200 400 600 800 1000
13.68 16.96
11.08 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5091 +/-
6.68 17.18
3.70 5.04 10.50 Component name: Deglucose 0.0285 minutes : Drift Times: 8.55 +/- 0.24 ms
chikusetsusaponin Ⅳa
0
813.51783
0 5 10 15 20 7500 163.11199 757.41566
Retention time [min] 835.44926
719.38954 857.53983

Intensity [Counts]
205.05176
5000 667.41550 845.47279
275.20113
477.28425
664.39089
2500

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganolactone [+H] : (39.7 PPM) 457.2596 : DT=5.98 to 6.46 ms
2000

1500
Intensity [Counts]

1000

16.66
500
16.58
Ganolactone
16.51

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5099 +/- 0.0285
Channel name: Ganolactone [+H] : (39.7 PPM) 457.2596 Component name: Ganolactone minutes : Drift Times: 6.22 +/- 0.24 ms
7.25
431.21966
4000
40000

7.55

Intensity [Counts]
3000 6.92 7.65
Intensity [Counts]

451.31971
20000 423.27678
8.45 275.20200 509.27216
2000 511.15998
8.78 241.19591
524.26418
8.98 173.13507 571.27722
16.58 0
1000 16.51 200 400 600 800 1000
6.70 11.11 16.62
6.60 13.66 14.50 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5099 +/- 0.0285
16.71
Component name: Ganolactone minutes : Drift Times: 6.07 +/- 0.24 ms
1.52 2.36 6.23 18.53
0 30000 240.23405

0 5 10 15 20
Retention time [min] 431.21973

Intensity [Counts]
20000

10000 451.31568
173.13388 405.31453
467.31222
493.26946
573.31357
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yesanchinoside C [+H] : (39.7 PPM) 949.5383 : DT=9.07 to 9.55 ms
Yesanchinoside C
16.52
16.72
200

150
Intensity [Counts]

16.89

100 16.46

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5123 +/- 0.0285
Channel name: Yesanchinoside C [+H] : (39.7 PPM) 949.5383 Component name: Yesanchinoside C minutes : Drift Times: 9.31 +/- 0.24 ms
16.53
600 983.39120
16.61
15000

16.48 288.25580

Intensity [Counts]
979.54194
16.68
10000
400 863.47489
Intensity [Counts]

16.74 773.42050
16.88 343.29444
5000 765.45326
17.02 244.23027
10.52 11.52 353.23069 663.39292
9.37 14.96 17.13
200
0
2.41
9.19 17.27 200 400 600 800 1000
0.40
2.79 5.31 6.94 8.90
Item name: MENGKUDU 2 Channel name: High energy : Time 16.5123 +/- 0.0285
0.48
Component name: Yesanchinoside C minutes : Drift Times: 9.16 +/- 0.24 ms

0 288.25484

0 5 10 15 20
15000
Retention time [min]

Intensity [Counts]
10000

477.28351 824.35378
240.23403 318.13495 971.42850
5000 131.04831 325.12272 761.37380
626.34946

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2850 : DT=7.00 to 7.48 ms

5000

4000
Intensity [Counts]

3000

2000 16.42

1000

Azedarachin C
0 16.48
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5151 +/- 0.0285
Channel name: Azedarachin C [+H] : (39.7 PPM) 587.2850 Component name: Azedarachin C minutes : Drift Times: 7.24 +/- 0.24 ms
10000 12.53
601.32746

565.33395 633.41013
20000
547.32118 639.41177

Intensity [Counts]
7500 15.14
12.13 516.39126 655.32199
Intensity [Counts]

15.38 10000 662.38065


5000 510.30669
691.35463
11.81 421.26026
275.20203
15.96 737.33779
249.18397
11.73 0
2500 13.03 16.41 200 400 600 800 1000
11.02
16.49 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5151 +/- 0.0285
8.58 9.94
8.07 Component name: Azedarachin C minutes : Drift Times: 7.08 +/- 0.24 ms
2.44 3.51
0 641.35300
10000 611.30531
0 5 10 15 20
Retention time [min] 516.39051

Intensity [Counts]
643.25246
91.05429 477.28445
677.36452
277.21777 352.11869
5000
730.30433
199.14982
744.35114

807.43089
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Acetoxy-7β-(3-ethyl-cis-crotonoyloxy)-1α-(2-methylbutyryloxy)-
notonipetranone [+H] : (39.7 PPM) 491.3009 : DT=6.07 to 6.55 ms

14-Acetoxy-7β-(3-ethyl-cis-crotonoyloxy)-1α-(2-methylbutyryloxy)-n…
16.59

1500 16.66
Intensity [Counts]

1000

16.72
16.77
500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5201 +/-
Channel name: 14-Acetoxy-7β-(3-ethyl-cis-crotonoyloxy)-1α-(2-methylbutyryloxy)- Component name: 14-Acetoxy-7β-(3-ethyl- 0.0285 minutes : Drift Times: 6.31 +/- 0.24 ms
notonipetranone [+H] : (39.7 PPM) 491.3009 cis-crotonoyloxy)-1α-(2-methylbutyryloxy)-
7.76 notonipetranone

477.28329
431.21966
3000 40000
16.60

Intensity [Counts]
479.25965
Intensity [Counts]

16.66 509.27216
423.27678
2000 20000
275.20200 525.30750

16.76 537.29435
14.78 211.14725
571.27722
12.08 0
1000 6.66 200 400 600 800 1000
6.09 16.88 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5201 +/-
7.86 10.82 12.96
6.05 Component name: 14-Acetoxy-7β-(3-ethyl- 0.0285 minutes : Drift Times: 6.16 +/- 0.24 ms
18.01
2.61 cis-crotonoyloxy)-1α-(2-methylbutyryloxy)-
0 notonipetranone
0 5 10 15 20 431.21973
Retention time [min] 20000

Intensity [Counts]
105.07036 333.20549 451.31905
10000
467.31222

539.27564
573.31357
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Deacetylpseudolaric acid A [+H] : (39.7 PPM) 347.1842 : DT=5.05 to
5.53 ms

1500
Intensity [Counts]

1000

16.61

500 Deacetylpseudolaric acid A


16.5316.73
16.84

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5221 +/-
Channel name: Deacetylpseudolaric acid A [+H] : (39.7 PPM) 347.1842 Component name: Deacetylpseudolaric acid A 0.0285 minutes : Drift Times: 5.28 +/- 0.24 ms
15.34
288.25581

6000 100000 333.20571

Intensity [Counts]
14.44
Intensity [Counts]

4000 50000
353.23052
14.17 244.23028

391.24495
7.95 15.81 135.11799 409.25823 658.34619
2000 0
7.88 13.56 200 400 600 800 1000
8.24 16.53
12.76 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5221 +/-
6.99 9.19 12.38 16.61
0.92 Component name: Deacetylpseudolaric acid A 0.0285 minutes : Drift Times: 5.13 +/- 0.24 ms
2.78 6.93 18.50
0 288.25485
75000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000
333.20540

25000
353.23029
244.22840
133.10200 395.23531

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Esculentoside F [+H] : (39.7 PPM) 813.4252 : DT=9.07 to 9.55 ms
Esculentoside F
16.54

200
Intensity [Counts]

150 16.46

100
16.96

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5284 +/- 0.0285
Channel name: Esculentoside F [+H] : (39.7 PPM) 813.4252 Component name: Esculentoside F minutes : Drift Times: 9.31 +/- 0.24 ms
16.54
1500
288.25580

1250 16.49 10000 871.43551 979.54194

Intensity [Counts]
863.47489

1000
Intensity [Counts]

765.45326
5000
665.40627
750
477.28292 663.39292

16.68
500 10.12 12.13 14.82
9.37 0
200 400 600 800 1000
9.10 16.89
250 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5284 +/- 0.0285
0.40 3.21
4.08 6.06 8.66 16.96 Component name: Esculentoside F minutes : Drift Times: 9.16 +/- 0.24 ms

0 288.25484

0 5 10 15 20
15000
Retention time [min]

Intensity [Counts]
10000

240.23403 835.44963
5000 159.11807 757.41421
425.13849
535.34378

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 7β-(3-Ethyl-cis-crotonoyloxy)-14-hydroxy-1α-(2-methylbutyryloxy)
notonipetranone [+H] : (39.7 PPM) 449.2913 : DT=6.72 to 7.21 ms

400

300
Intensity [Counts]

200 7β-(3-Ethyl-cis-crotonoyloxy)-14-hydroxy-1α-(2-methylbutyryloxy) no…


16.55

100 16.74

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5292 +/-
Channel name: 7β-(3-Ethyl-cis-crotonoyloxy)-14-hydroxy-1α-(2-methylbutyryloxy) Component name: 7β-(3-Ethyl-cis- 0.0285 minutes : Drift Times: 6.97 +/- 0.24 ms
notonipetranone [+H] : (39.7 PPM) 449.2913 crotonoyloxy)-14-hydroxy-1α-(2-
9.37 methylbutyryloxy) notonipetranone
5000
547.37298
30000
553.30181
529.27960
4000

Intensity [Counts]
575.37575
20000 577.33643
505.31203
Intensity [Counts]

16.70 625.36941
3000
16.60 498.29028
10000 275.20205 428.41319 639.33835
9.70
654.28850
2000 16.50 273.18694 896.60087
8.06
10.72 0
200 400 600 800 1000
11.03
1000 7.96
13.5814.52 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5292 +/-
7.24 17.01 Component name: 7β-(3-Ethyl-cis- 0.0285 minutes : Drift Times: 6.81 +/- 0.24 ms
3.76 6.01 18.49 crotonoyloxy)-14-hydroxy-1α-(2-
0 methylbutyryloxy) notonipetranone
0 5 10 15 20 553.30428
Retention time [min] 20000
563.37654

Intensity [Counts]
545.35640

521.31402
10000 157.10183 575.31930
425.13689
91.05429 161.09679
643.25246

710.34349
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3262 : DT=6.35 to 6.83 ms

2500

2000
Intensity [Counts]

1500

1000

Poricoic acid B
16.57
500
16.49 16.62
16.72
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5306 +/- 0.0285
Channel name: Poricoic acid B [+H] : (39.7 PPM) 485.3262 Component name: Poricoic acid B minutes : Drift Times: 6.59 +/- 0.24 ms
9.37
477.28329

40000
6000

Intensity [Counts]
525.30728
465.28648
8.07
Intensity [Counts]

455.31159 545.31498
20000
4000 9.54 453.34206
563.37047
275.20205
442.27938
607.30871
7.98 211.14725
9.69 617.25121
2000 0
16.49 200 400 600 800 1000
11.03 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5306 +/- 0.0285
12.63 13.66 16.66
7.24 14.20 Component name: Poricoic acid B minutes : Drift Times: 6.43 +/- 0.24 ms

0 431.21973 553.30428

0 5 10 15 20 20000
563.37654
Retention time [min]

Intensity [Counts]
157.10183 333.20549
10000
204.06635 569.27874
585.27695

647.35158
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lucidenic acid P [+H] : (39.7 PPM) 519.2938 : DT=6.25 to 6.74 ms
Lucidenic acid P
1000 16.56 16.61

750
Intensity [Counts]

500

16.69

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5340 +/- 0.0285
Channel name: Lucidenic acid P [+H] : (39.7 PPM) 519.2938 Component name: Lucidenic acid P minutes : Drift Times: 6.50 +/- 0.24 ms
14.36
2500 477.28329
431.21966
40000
16.61
2000

Intensity [Counts]
517.31618
16.55

521.26482
Intensity [Counts]

1500 20000
5.71 537.31175
421.30771 541.35072
351.25350
1000 293.21153 563.37047

14.52 16.70 0
14.81 16.86 200 400 600 800 1000
500 7.43 9.64 11.86 13.40
17.98 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5340 +/- 0.0285
3.565.32 6.60
Component name: Lucidenic acid P minutes : Drift Times: 6.34 +/- 0.24 ms
3.08
0 431.21973
20000
0 5 10 15 20
Retention time [min] 479.26215

Intensity [Counts]
105.07036 333.20549
521.31450
10000
171.11743 552.32223
561.33836
569.27874
619.29280
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Glycyrrhizic acid [+H] : (39.7 PPM) 823.4120 : DT=8.81 to 9.30 ms
16.57
16.47

200

150 16.61 acid


Glycyrrhizic
Intensity [Counts]

16.53

100
16.66
16.77
50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5388 +/- 0.0285
Channel name: Glycyrrhizic acid [+H] : (39.7 PPM) 823.4120 Component name: Glycyrrhizic acid minutes : Drift Times: 9.06 +/- 0.24 ms
16.48
1250 896.41190

10000 885.51158
839.48402

Intensity [Counts]
1000 750.56406

13.09 708.54495
16.57
Intensity [Counts]

750 5000 665.40627

289.25856 661.37231
12.96 379.24678
14.80 421.26042
500
9.61 12.56
7.86 0
9.34 16.70 200 400 600 800 1000
250 7.63
0.39 6.26 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5388 +/- 0.0285
16.80 Component name: Glycyrrhizic acid minutes : Drift Times: 8.90 +/- 0.24 ms
1.72
4.82 5.93
0 288.25484

0 5 10 15 20
15000
Retention time [min]

Intensity [Counts]
10000 149.02431
750.56371
379.24639
579.53817 835.44963
5000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 2α,3α-Dihydroxy-ursa-12,20(30)-dien-28-oic acid methyl ester
[+H] : (39.7 PPM) 485.3642 : DT=6.64 to 7.12 ms

200

16.59
Intensity [Counts]

150
2α,3α-Dihydroxy-ursa-12,20(30)-dien-28-oic acid methyl…
16.54
100

16.44

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5391 +/-
Channel name: 2α,3α-Dihydroxy-ursa-12,20(30)-dien-28-oic acid methyl ester Component name: 2α,3α-Dihydroxy- 0.0285 minutes : Drift Times: 6.88 +/- 0.24 ms
[+H] : (39.7 PPM) 485.3642 ursa-12,20(30)-dien-28-oic acid methyl ester
9.37
547.37298
30000
8.06 529.27960 567.31676
750 9.54

Intensity [Counts]
511.29015
20000 577.33643
505.31203
Intensity [Counts]

584.28207
498.29028
500
10000 275.20205 428.41319 639.33835
7.96 16.52
9.69 641.31452
7.24 16.61 273.18694 896.60087
13.65
10.57 17.16 0
250 200 400 600 800 1000
12.66 16.45 17.36
3.80 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5391 +/-
1.88 6.49 18.42
3.58 Component name: 2α,3α-Dihydroxy- 0.0285 minutes : Drift Times: 6.73 +/- 0.24 ms
0.62 6.25
ursa-12,20(30)-dien-28-oic acid methyl ester
0
553.30428
0 5 10 15 20
20000
Retention time [min] 563.37654

Intensity [Counts]
479.26208

157.10183
10000 425.13689 579.35205
91.05429 161.09679 583.31318
677.36452

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Neocimiside [+H] : (39.7 PPM) 577.3362 : DT=7.10 to 7.58 ms
16.56
600 Neocimiside
16.50

16.62
400 16.47
Intensity [Counts]

16.80

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5467 +/- 0.0285
Channel name: Neocimiside [+H] : (39.7 PPM) 577.3362 Component name: Neocimiside minutes : Drift Times: 7.39 +/- 0.24 ms
16.54
1500 641.30967
16.50
16.62
639.39601 669.36367
20000

Intensity [Counts]
603.31957 693.37525

1000 597.33971
16.80
Intensity [Counts]

516.39126
10000 496.33894 721.39768
15.69
421.26026 730.35350
415.21714
500 13.77 746.42471
10.79 0
10.41 16.98 200 400 600 800 1000
7.60 9.34 17.08 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5467 +/- 0.0285
6.57
6.31 17.59 Component name: Neocimiside minutes : Drift Times: 7.24 +/- 0.24 ms
2.21 2.97

0 149.02430
641.35300
0 5 10 15 20 10000 637.40728 653.39244
Retention time [min]

Intensity [Counts]
516.39051
425.13850 717.22420

5000
730.30433
288.08572
740.41307
775.44236
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 7β-Angeloyloxyoplopa-3(14)Z,8(10)-dien-2-one [+H] : (39.7 PPM)
317.2117 : DT=5.13 to 5.61 ms
16.62

7β-Angeloyloxyoplopa-3(14)Z,8(10)-dien-2-one
16.56

600
Intensity [Counts]

400

16.75
200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5482 +/-
Channel name: 7β-Angeloyloxyoplopa-3(14)Z,8(10)-dien-2-one [+H] : (39.7 PPM) Component name: 7β-Angeloyloxyoplopa-3 0.0285 minutes : Drift Times: 5.33 +/- 0.24 ms
317.2117 (14)Z,8(10)-dien-2-one
2000 16.62
333.20571

16.56

Intensity [Counts]
1500

50000
Intensity [Counts]

353.23052
268.26536
1000
365.23030

135.11799 411.23441
0
8.06 200 400 600 800 1000
500 9.39 11.58 13.60 14.78
13.53 12.68 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5482 +/-
1.74 7.11 16.86 Component name: 7β-Angeloyloxyoplopa-3 0.0285 minutes : Drift Times: 5.17 +/- 0.24 ms
3.84 5.18
17.36 (14)Z,8(10)-dien-2-one
0
333.20540
0 5 10 15 20
Retention time [min] 268.26508

Intensity [Counts]
20000
353.23029

133.10200
364.21131
391.24445
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Melianol [+H] : (39.7 PPM) 613.3370 : DT=7.17 to 7.65 ms
Melianol
16.51
16.58
600
Intensity [Counts]

400

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5502 +/- 0.0285 minutes :
Channel name: Melianol [+H] : (39.7 PPM) 613.3370 Component name: Melianol Drift Times: 7.41 +/- 0.24 ms
8.52
641.30967

4000 639.39601 669.36367


20000

Intensity [Counts]
603.31957 693.37525
597.33971
Intensity [Counts]

3000 516.39126
10000 721.39768
468.48043
415.21714 730.35350
2000
379.24684
16.56 746.42471
0
200 400 600 800 1000
1000 16.67
8.36 14.80 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5502 +/- 0.0285 minutes :
14.54 16.97
8.13 9.93 14.24 Component name: Melianol Drift Times: 7.26 +/- 0.24 ms
2.93 5.85
0 149.02430
641.35300
0 5 10 15 20 10000 637.40728 653.39244
Retention time [min]

Intensity [Counts]
516.39051 729.29538
318.13497
743.43278
5000 468.48191
288.08572

775.44236

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosyl-14-deoxy-11,12-didehydroand-rographoside [+H] :
(39.7 PPM) 333.2057 : DT=5.14 to 5.62 ms

19β-Glucosyl-14-deoxy-11,12-didehydroand-rographoside
16.55
6000
Intensity [Counts]

4000

2000

16.69
16.43

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5514 +/-
Channel name: 19β-Glucosyl-14-deoxy-11,12-didehydroand-rographoside [+H] : Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 5.37 +/- 0.24 ms
(39.7 PPM) 333.2057 deoxy-11,12-didehydroand-rographoside
16.55
333.20571

Intensity [Counts]
7500

50000
Intensity [Counts]

353.23052

5000 268.26536
365.23030

135.11799 411.23441
0
2500 200 400 600 800 1000
Item name: MENGKUDU 2 Channel name: High energy : Time 16.5514 +/-
12.27 13.66 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 5.22 +/- 0.24 ms
5.96 8.90 9.60 15.30
1.39 3.23 5.00 deoxy-11,12-didehydroand-rographoside
0
333.20540
0 5 10 15 20
Retention time [min] 268.26508

Intensity [Counts]
20000
353.23029

133.10200 393.22505
405.22051

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3β-O-trans-p-Coumaroyl alphitolic acid [+H] : (39.7 PPM) 619.3978 :
DT=7.69 to 8.17 ms
16.74

500

400
Intensity [Counts]

16.70
16.85
3β-O-trans-p-Coumaroyl alphitolic acid
300
16.56

16.48 16.93
200
16.98

16.44 17.13
100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5568 +/-
Channel name: 3β-O-trans-p-Coumaroyl alphitolic acid [+H] : (39.7 PPM) 619.3978 Component name: 3β-O-trans-p-Coumaroyl 0.0285 minutes : Drift Times: 7.93 +/- 0.24 ms
16.73 alphitolic acid
2000 16.59
723.42749
30000
677.36377
546.48981

Intensity [Counts]
1500 512.50710
20000 729.29527
Intensity [Counts]

16.86 732.41698

1000 7.96 10000 770.38973


496.51346 815.22013
275.20249
817.23114
8.07 0
500 200 400 600 800 1000
17.14
11.97 14.52 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5568 +/-
18.47
7.78 8.8511.72 Component name: 3β-O-trans-p-Coumaroyl 0.0285 minutes : Drift Times: 7.78 +/- 0.24 ms
3.55 5.69 alphitolic acid
0
546.49029
0 5 10 15 20 673.37269
Retention time [min] 10000 512.50433
683.37894

Intensity [Counts]
753.49721
207.06677
773.39393
5000 367.14192
811.53734
816.34180

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (+)-Bakuchiol [+H] : (39.7 PPM) 257.1913 : DT=4.29 to 4.77 ms

3000

2000
Intensity [Counts]

(+)-Bakuchiol
1000
16.56

16.67

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5572 +/- 0.0285
Channel name: (+)-Bakuchiol [+H] : (39.7 PPM) 257.1913 Component name: (+)-Bakuchiol minutes : Drift Times: 4.54 +/- 0.24 ms
13.69
275.20247
5000

40000

Intensity [Counts]
4000
Intensity [Counts]

3000 20000
257.19133

249.18227 279.22785
2000
13.54 16.52 0
13.95 200 400 600 800 1000
1000
Item name: MENGKUDU 2 Channel name: High energy : Time 16.5572 +/- 0.0285
9.57 10.73 14.98
16.67 Component name: (+)-Bakuchiol minutes : Drift Times: 4.39 +/- 0.24 ms
7.20
4.69 5.89
0 204.06687
273.18552
0 5 10 15 20
Retention time [min] 2000 318.13576

Intensity [Counts] 1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lucidenic acid A [+H] : (39.7 PPM) 459.2708 : DT=5.83 to 6.31 ms

10000

7500
Intensity [Counts]

5000

2500 Lucidenic acid A


16.58
16.56
16.70

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5731 +/- 0.0285
Channel name: Lucidenic acid A [+H] : (39.7 PPM) 459.2708 Component name: Lucidenic acid A minutes : Drift Times: 6.09 +/- 0.24 ms
15000 7.81
60000 268.26538

12500

Intensity [Counts]
40000 381.26089447.27744
10000
459.32219
Intensity [Counts]

477.28199
7500 20000
489.33871
254.24939
499.30562
5000
0
200 400 600 800 1000
16.56
2500 16.84 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5731 +/- 0.0285
7.00
13.75 Component name: Lucidenic acid A minutes : Drift Times: 5.94 +/- 0.24 ms
5.14 9.77
6.64 14.82
0 445.31422

0 5 10 15 20 20000
Retention time [min] 254.25033

Intensity [Counts]
401.28702
489.33177
381.26127

10000
506.32765
183.11842 567.27648

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-12S-methoxyandrographolide [+H] : (39.7 PPM)
365.2303 : DT=5.29 to 5.78 ms
14-Deoxy-12S-methoxyandrographolide
16.56 16.59

600 16.49
Intensity [Counts]

16.64

400
16.23
16.76
16.16

200
16.87

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5744 +/-
Channel name: 14-Deoxy-12S-methoxyandrographolide [+H] : (39.7 PPM) 365.2303 Component name: 14-Deoxy-12S- 0.0285 minutes : Drift Times: 5.53 +/- 0.24 ms
16.56 methoxyandrographolide

333.20571

1500

Intensity [Counts]
Intensity [Counts]

50000
16.50 377.22919
1000
268.26536
10.20 391.24487
405.26060
11.83 16.76
16.16 163.14901 415.25632
5.60 6.67 13.64 0
500
9.90 13.69 200 400 600 800 1000
5.54 7.60 16.84
Item name: MENGKUDU 2 Channel name: High energy : Time 16.5744 +/-
3.69 Component name: 14-Deoxy-12S- 0.0285 minutes : Drift Times: 5.38 +/- 0.24 ms
1.60 4.83 16.96
methoxyandrographolide
0
333.20540
0 5 10 15 20
Retention time [min] 268.26508 335.21953

Intensity [Counts]
20000
401.28697
145.10197

419.27997

423.16781
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3056 :
DT=5.99 to 6.48 ms

1000
Intensity [Counts]

750

500 3-O-(2′E,4′Z-Decadienoyl) ingenol


16.60
16.53
16.79
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5836 +/-
Channel name: 3-O-(2′E,4′Z-Decadienoyl) ingenol [+H] : (39.7 PPM) 499.3056 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.23 +/- 0.24 ms
14.22 ingenol
4000
268.26538

50000 459.32921

Intensity [Counts]
3000
445.31279 491.29759
Intensity [Counts]

25000 437.25160 523.32629


2000 415.25006
14.60 16.59 533.31498
254.24939
16.78 536.29487
10.10 0
12.12 200 400 600 800 1000
1000
14.75
7.81 13.32 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5836 +/-
16.90
3.17 9.42 Component name: 3-O-(2′E,4′Z-Decadienoyl) 0.0285 minutes : Drift Times: 6.08 +/- 0.24 ms
4.29 7.26 18.46 ingenol
0
268.26508
0 5 10 15 20
50000
Retention time [min]

Intensity [Counts]
487.32440
25000 254.25033 445.31422
489.33177

495.26473
169.10122
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1β,2β,3β,19α-Tetrahy-droxyurs-12-en-28-oate-3-O-β-D-
xylopyranoside [+H] : (39.7 PPM) 637.3962 : DT=7.74 to 8.22 ms
1000
16.88

750
Intensity [Counts]

16.71
500
1β,2β,3β,19α-Tetrahy-droxyurs-12-en-28-oate-3-O-β-D-…
16.62
16.98
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5852 +/-
Channel name: 1β,2β,3β,19α-Tetrahy-droxyurs-12-en-28-oate-3-O-β-D- Component name: 1β,2β,3β,19α-Tetrahy- 0.0285 minutes : Drift Times: 7.98 +/- 0.24 ms
xylopyranoside [+H] : (39.7 PPM) 637.3962 droxyurs-12-en-28-oate-3-O-β-D-
16.61 xylopyranoside

699.35691
2000
16.88 75000

Intensity [Counts]
1500 50000
Intensity [Counts]

16.49

546.48981 700.36094
25000
1000 353.26891 512.50710 749.41172
335.25612 770.38973
16.98 421.25612
0
200 400 600 800 1000
500 17.07
13.65 16.18 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5852 +/-
9.51 11.15 11.95 17.20 Component name: 1β,2β,3β,19α-Tetrahy- 0.0285 minutes : Drift Times: 7.83 +/- 0.24 ms
4.95
8.70 droxyurs-12-en-28-oate-3-O-β-D-
0 xylopyranoside
0 5 10 15 20 700.36237
Retention time [min]

Intensity [Counts]
20000

723.48707
230.25022 546.49029
753.49721
10000
207.06677 771.46430
512.50433
115.05462 865.23567
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 25(S)-Ruscogenin [+H] : (39.7 PPM) 431.3170 : DT=6.03 to 6.51 ms
16.66
2000

1500
16.80
Intensity [Counts]

1000
25(S)-Ruscogenin
16.58
16.51

500
16.47

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5854 +/- 0.0285
Channel name: 25(S)-Ruscogenin [+H] : (39.7 PPM) 431.3170 Component name: 25(S)-Ruscogenin minutes : Drift Times: 6.27 +/- 0.24 ms
16.66
60000 268.26538

459.32921

Intensity [Counts]
3000
40000
445.31279 491.29759
Intensity [Counts]

16.80 437.25160 523.32629


2000 20000 415.25006
537.30415
16.58 254.24939
549.23286
16.47
13.69 0
1000 200 400 600 800 1000
9.37 13.53
Item name: MENGKUDU 2 Channel name: High energy : Time 16.5854 +/- 0.0285
9.70 16.89 Component name: 25(S)-Ruscogenin minutes : Drift Times: 6.11 +/- 0.24 ms
7.22 8.07 11.05 14.72
4.45 17.11
0 268.26508

0 5 10 15 20
Retention time [min] 459.33064

Intensity [Counts]
40000

487.32440
445.31422
254.25033
20000 517.35478
437.23873
420.27635 547.33089
169.10122
591.41455
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Chikusetsusaponin Ⅳa [+H] : (39.7 PPM) 795.4531 : DT=8.29 to 8.77
ms
Chikusetsusaponin Ⅳa
16.59
600

16.48

16.71
Intensity [Counts]

400

200 16.79

16.40

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5876 +/-
Channel name: Chikusetsusaponin Ⅳa [+H] : (39.7 PPM) 795.4531 Component name: Chikusetsusaponin Ⅳa 0.0285 minutes : Drift Times: 8.53 +/- 0.24 ms
16.49
1000 16.60 75000 651.56845

Intensity [Counts]
16.67
50000
750
16.71
Intensity [Counts]

25000 579.53687
500 522.59963 771.45546
10.47 817.45550
16.79 230.25014 475.26888
13.85
10.07 12.74 16.92 0
250 11.89 14.55 200 400 600 800 1000
9.13 17.05
9.10 17.32 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5876 +/-
0.42 3.74 4.95 Component name: Chikusetsusaponin Ⅳa 0.0285 minutes : Drift Times: 8.37 +/- 0.24 ms
1.53 7.91
0 901.37493
651.57013
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000
522.60062

10000 861.41707
207.06681 667.56446
181.10124 231.25134

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Lucidenic acid A [+H] : (39.7 PPM) 459.2735 : DT=6.82 to 7.30 ms

300
16.50
Lucidenic acid A
16.56
16.59
200
Intensity [Counts]

100

16.65

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5882 +/- 0.0285
Channel name: Lucidenic acid A [+H] : (39.7 PPM) 459.2735 Component name: Lucidenic acid A minutes : Drift Times: 7.06 +/- 0.24 ms
7.81
40000 547.37864
12500
605.38328
30000 621.41911

Intensity [Counts]
10000 535.35556
529.21179
20000 627.37182
Intensity [Counts]

635.38478
7500
496.33894
10000 459.27352 649.41239
238.12373 656.34686
5000 435.31382
692.41606
0
16.56 200 400 600 800 1000
2500 16.84
7.00 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5882 +/- 0.0285
13.76 Component name: Lucidenic acid A minutes : Drift Times: 6.91 +/- 0.24 ms
6.64 9.77 14.81
0 531.37725

0 5 10 15 20 621.41778
Retention time [min] 20000

Intensity [Counts]
527.33621
627.37676
10000 474.34472
661.34513
238.12376
171.11713
671.37823

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3-O-β-D-Glucopyranosyl-14,19-dideoxyandrographolide [+H] :
(39.7 PPM) 481.2803 : DT=6.31 to 6.79 ms

1250

1000
16.62
Intensity [Counts]

750
3-O-β-D-Glucopyranosyl-14,19-dideoxyandrographolide
16.58
500 16.49

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5969 +/-
Channel name: 3-O-β-D-Glucopyranosyl-14,19-dideoxyandrographolide [+H] : Component name: 3-O-β-D- 0.0285 minutes : Drift Times: 6.64 +/- 0.24 ms
(39.7 PPM) 481.2803 Glucopyranosyl-14,19-
7.00 dideoxyandrographolide

533.36129
4000
40000
503.35454
547.33236

Intensity [Counts]
491.29759
3000 561.39069
Intensity [Counts]

16.53 20000
483.26509
601.33246
14.22 283.17487 457.31252
2000 16.59 651.15928
239.14803
16.62 0
11.92 200 400 600 800 1000
1000 14.61 16.76
9.76 11.53 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5969 +/-
16.88
3.71 4.74 6.18 7.65 Component name: 3-O-β-D- 0.0285 minutes : Drift Times: 6.48 +/- 0.24 ms
Glucopyranosyl-14,19-
0 dideoxyandrographolide
0 5 10 15 20 547.38368
40000
Retention time [min]
503.35463

Intensity [Counts]
501.33891
20000
561.38935
474.34472
171.11713 569.36875
413.28638 595.34262
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-
one-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) 645.4001 : DT=8.02 to 8.50 ms

2000

1500
Intensity [Counts]

1000

500
(3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-o…
16.60
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.5973 +/-
Channel name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24- Component name: (3β,12β,16β)-12- 0.0285 minutes : Drift Times: 8.26 +/- 0.24 ms
one-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) 645.4001 Acetoxy-16,23-epoxy-9,19-cyclolanost-22-
13.69 ene-24-one-3-O-β-D-xylopyranoside

546.48981

522.59963 749.41172
20000
727.37626

Intensity [Counts]
711.45207
4000
817.45550
Intensity [Counts]

353.26891
10000 693.43717 818.45058
13.54 230.25014 494.56302 865.23035

421.25612 875.27679
2000
16.55 0
200 400 600 800 1000
16.49 16.60
13.94 Item name: MENGKUDU 2 Channel name: High energy : Time 16.5973 +/-
13.17 16.71 Component name: (3β,12β,16β)-12- 0.0285 minutes : Drift Times: 8.11 +/- 0.24 ms
6.96 8.66 10.33 Acetoxy-16,23-epoxy-9,19-cyclolanost-22-
0 ene-24-one-3-O-β-D-xylopyranoside
0 5 10 15 20 522.60062
Retention time [min]

Intensity [Counts]
723.48707
230.25022
10000 540.53549
207.06681 793.43622
184.07428 494.56569 857.34027
419.28175 865.23567

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Curculigo saponin I [+H] : (39.7 PPM) 945.5425 : DT=9.08 to 9.57 ms
16.49
500

400
Intensity [Counts]

300
Curculigo saponin I
16.60

200
16.77
16.81
100
16.86

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6072 +/- 0.0285
Channel name: Curculigo saponin I [+H] : (39.7 PPM) 945.5425 Component name: Curculigo saponin I minutes : Drift Times: 9.33 +/- 0.24 ms
16.48
925.50867
1000 10000
773.54021
719.62895

Intensity [Counts]
668.65102
750
Intensity [Counts]

5000
16.61
16.63
500 16.70 529.21155
433.25552

12.68 17.03 0
250 12.86 200 400 600 800 1000
10.48 14.69
6.457.06 17.60
10.29 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6072 +/- 0.0285
0.43 3.13 3.89
5.74 Component name: Curculigo saponin I minutes : Drift Times: 9.17 +/- 0.24 ms

7500 667.64638
0
0 5 10 15 20 719.62701 925.51397
Retention time [min]

Intensity [Counts]
5000 721.65073

575.39813 806.50803
184.07517 280.26531
551.32534
2500
491.30518

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Prosapogenin 2 [+H] : (39.7 PPM) 561.3464 : DT=6.51 to 7.00 ms
Prosapogenin 2
16.62

1000

16.54
750
Intensity [Counts]

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B 16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6097 +/- 0.0285
Channel name: Prosapogenin 2 [+H] : (39.7 PPM) 561.3464 Component name: Prosapogenin 2 minutes : Drift Times: 6.79 +/- 0.24 ms
16.61
533.36129
503.35454 547.37864
40000

16.54 16.69

Intensity [Counts]
1500
579.35459
Intensity [Counts]

491.29456
20000
583.32233
1000
296.29537 601.33246

16.91 283.17487 645.38630


0
500 12.86 14.35 200 400 600 800 1000
11.80 17.00
9.33
11.23 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6097 +/- 0.0285
4.25 17.15 Component name: Prosapogenin 2 minutes : Drift Times: 6.63 +/- 0.24 ms
7.73 7.94
0 547.38368
40000
0 5 10 15 20 503.35463
Retention time [min]

Intensity [Counts]
605.38734
489.33888
20000

296.29574 474.34472
251.04723 446.31316
613.32760
675.38943
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Terminalic acid [+H] : (39.7 PPM) 317.2094 : DT=4.86 to 5.34 ms
Terminalic acid
16.62
1250

1000
Intensity [Counts]

750 16.56

500

250 16.70

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6129 +/- 0.0285
Channel name: Terminalic acid [+H] : (39.7 PPM) 317.2094 Component name: Terminalic acid minutes : Drift Times: 5.19 +/- 0.24 ms
2000 16.62
335.21983

50000
16.56

Intensity [Counts]
1500 230.24990

359.22197
Intensity [Counts]

25000 363.25062
1000 375.25024

106.08657 377.22975
8.06
0
500 9.39 200 400 600 800 1000
14.77
11.58 13.60
Item name: MENGKUDU 2 Channel name: High energy : Time 16.6129 +/- 0.0285
16.87
1.74 5.64 7.11 18.50 Component name: Terminalic acid minutes : Drift Times: 5.03 +/- 0.24 ms
5.18
0 230.24972 335.21953

0 5 10 15 20
Retention time [min] 20000

Intensity [Counts]
359.22040
361.23678
10000
185.13377 375.24772

462.31217
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Kirenol [+H] : (39.7 PPM) 339.2515 : DT=5.47 to 5.95 ms
Kirenol
16.61
1000

750
Intensity [Counts]

16.71
500

16.80
250 16.53
16.90
16.47

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6235 +/- 0.0285 minutes :
Channel name: Kirenol [+H] : (39.7 PPM) 339.2515 Component name: Kirenol Drift Times: 5.70 +/- 0.24 ms
16.61
447.27313
1500
40000
407.24026
377.22919

Intensity [Counts]
375.25214
369.26041
Intensity [Counts]

1000 20000 373.25372


14.29
365.22971
339.25153
16.52 16.72 449.24787
289.25993 451.22660
500 0
13.66 16.81
14.82 200 400 600 800 1000
8.29 9.07 11.06 13.60 16.90 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6235 +/- 0.0285 minutes :
2.99 6.79
4.89 7.91 Component name: Kirenol Drift Times: 5.55 +/- 0.24 ms
2.14 16.98
0 417.28610

0 5 10 15 20 20000 407.24223
Retention time [min] 373.25189

Intensity [Counts]
274.27548

10000
227.20343 425.28809
433.29314
123.08039
445.30279
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxy-12S-methoxyandrographolide [+H] : (39.7 PPM)
365.2297 : DT=5.38 to 5.87 ms
16.56

750

16.49
Intensity [Counts]

14-Deoxy-12S-methoxyandrographolide
16.60
500 16.65

16.23
16.16 16.75

250 15.97

16.84

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6257 +/-
Channel name: 14-Deoxy-12S-methoxyandrographolide [+H] : (39.7 PPM) 365.2297 Component name: 14-Deoxy-12S- 0.0285 minutes : Drift Times: 5.63 +/- 0.24 ms
16.56 methoxyandrographolide

335.21983

1500
50000

Intensity [Counts]
407.24026
Intensity [Counts]

16.50 417.28089
1000 288.25533
25000
10.20
418.29064
16.76 106.08657 439.20940
11.21 16.16
11.83
5.60 6.67 13.64 0
500 9.90
14.96 200 400 600 800 1000
5.54 7.60 9.31 16.84
Item name: MENGKUDU 2 Channel name: High energy : Time 16.6257 +/-
3.69 Component name: 14-Deoxy-12S- 0.0285 minutes : Drift Times: 5.47 +/- 0.24 ms
1.60 4.83 16.96
methoxyandrographolide
0
335.21953
0 5 10 15 20
417.28610
Retention time [min]
20000

Intensity [Counts]
274.27548

10000 227.20343
425.23697
215.08968
433.25443
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-
one-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) 645.3992 : DT=7.25 to 7.74 ms

1000

16.54
750
Intensity [Counts]

16.50

500
12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-one-3-O-β-D-xylopyranoside
16.62
16.71
250 16.82

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6302 +/-
Channel name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24- Component name: (3β,12β,16β)-12- 0.0285 minutes : Drift Times: 7.49 +/- 0.24 ms
one-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) 645.3992 Acetoxy-16,23-epoxy-9,19-cyclolanost-22-
13.69 ene-24-one-3-O-β-D-xylopyranoside

588.40898
5e5

Intensity [Counts]
4000
Intensity [Counts]

2.5e5
574.39452
13.54
566.42731
604.38150
340.25764 453.34020
2000 732.45183
16.55 0
200 400 600 800 1000
16.49 16.60
13.94 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6302 +/-
13.17 16.71 Component name: (3β,12β,16β)-12- 0.0285 minutes : Drift Times: 7.34 +/- 0.24 ms
7.76 10.33
6.96 Acetoxy-16,23-epoxy-9,19-cyclolanost-22-
0 ene-24-one-3-O-β-D-xylopyranoside
0 5 10 15 20 588.41129
Retention time [min] 5e5

Intensity [Counts] 2.5e5


574.39586

566.42766 699.36075
227.17680
340.25972 733.45988
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Picrasinol A [+H] : (39.7 PPM) 437.2522 : DT=5.79 to 6.27 ms

Picrasinol A
16.51 16.58
1000

750
Intensity [Counts]

16.66

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6355 +/- 0.0285 minutes :
Channel name: Picrasinol A [+H] : (39.7 PPM) 437.2522 Component name: Picrasinol A Drift Times: 6.03 +/- 0.24 ms
6.40
415.30300
5000
447.27313
40000 413.28807

Intensity [Counts]
457.31309
4000 407.23992
403.28295
Intensity [Counts]

20000 463.26836
3000 389.26871
469.32262
16.59 385.29468
354.26847 483.31406
2000 16.52
263.15904
0
11.13 200 400 600 800 1000
1000 11.24 13.94
8.01 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6355 +/- 0.0285
5.84 10.76 12.56 16.9418.49 Component name: Picrasinol A minutes : Drift Times: 5.88 +/- 0.24 ms
2.22 3.07
0 459.33064
40000 415.30434
0 5 10 15 20
Retention time [min] 413.28623

Intensity [Counts]
389.26632
20000
385.29551 463.26320
371.27762 469.31991

197.20114 363.25440 477.28204


478.33126
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3402 : DT=7.29 to 7.77 ms

Ganoderic acid S
16.65

3000
Intensity [Counts]

2000

1000

16.71
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6513 +/- 0.0285
Channel name: Ganoderic acid S [+H] : (39.7 PPM) 453.3402 Component name: Ganoderic acid S minutes : Drift Times: 7.53 +/- 0.24 ms
7.76
588.40898

30000
4e5

Intensity [Counts]
Intensity [Counts]

20000 2e5 574.39452


566.42731
552.41249 604.38150
340.25764 651.42885
0
10000
200 400 600 800 1000
16.65
Item name: MENGKUDU 2 Channel name: High energy : Time 16.6513 +/- 0.0285
13.30 Component name: Ganoderic acid S minutes : Drift Times: 7.38 +/- 0.24 ms
10.20 11.78

0 588.41129

0 5 10 15 20
Retention time [min] 4e5

Intensity [Counts] 2e5 574.39586

590.41650
227.17680 566.42766
340.25972 663.44389 747.41822
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Raddeanoside R0 [+H] : (39.7 PPM) 589.4119 : DT=10.19 to 10.67
ms

1500 Raddeanoside R0
16.65

1000
Intensity [Counts]

500

16.74
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6527 +/- 0.0285
Channel name: Raddeanoside R0 [+H] : (39.7 PPM) 589.4119 Component name: Raddeanoside R0 minutes : Drift Times: 10.43 +/- 0.24 ms
16.66
589.41185
50000

10000

Intensity [Counts]
40000
Intensity [Counts]

30000 5000
873.73792
604.38150

20000
0
16.91 200 400 600 800 1000
10000
Item name: MENGKUDU 2 Channel name: High energy : Time 16.6527 +/- 0.0285
Component name: Raddeanoside R0 minutes : Drift Times: 10.27 +/- 0.24 ms

0 589.41466

0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000

10000

579.53688 701.37468

288.25567 888.75297
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Raddeanoside R0 [+H] : (39.7 PPM) 589.4119 : DT=9.59 to 10.07 ms

1500 Raddeanoside R0
16.65

1000
Intensity [Counts]

500

16.73
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6529 +/- 0.0285
Channel name: Raddeanoside R0 [+H] : (39.7 PPM) 589.4119 Component name: Raddeanoside R0 minutes : Drift Times: 9.87 +/- 0.24 ms
16.66
588.40898
50000

30000

Intensity [Counts]
40000

20000
Intensity [Counts]

574.39452 597.08407
30000

10000
651.56840 993.64830
20000 572.43619
287.05361 831.73301
0
16.91 200 400 600 800 1000
10000
Item name: MENGKUDU 2 Channel name: High energy : Time 16.6529 +/- 0.0285
Component name: Raddeanoside R0 minutes : Drift Times: 9.71 +/- 0.24 ms

0 588.41129
75000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

597.08559
574.39586
25000

572.43939
287.05572 701.37358 855.74459
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 6,17-Epoxylathyrol-5,15-diacetate-3-phenylacetate [+H] : (39.7
PPM) 553.2791 : DT=6.53 to 7.01 ms

1250

1000

6,17-Epoxylathyrol-5,15-diacetate-3-phenylacetate
Intensity [Counts]

750 16.66

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6569 +/-
Channel name: 6,17-Epoxylathyrol-5,15-diacetate-3-phenylacetate [+H] : (39.7 Component name: 6,17-Epoxylathyrol-5,15- 0.0285 minutes : Drift Times: 6.77 +/- 0.24 ms
PPM) 553.2791 diacetate-3-phenylacetate
16.52
537.29862

30000 517.37000 575.10108

Intensity [Counts]
507.29402
2000
20000
Intensity [Counts]

13.24
492.29182
13.16 13.53 591.36325
16.66 296.29537
13.64 10000
12.99 481.32868 611.31434
1000 12.96 615.06001
13.94 16.71 0
12.42 11.49 200 400 600 800 1000

4.19 9.43 10.24 17.00 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6569 +/-
7.76 Component name: 6,17-Epoxylathyrol-5,15- 0.0285 minutes : Drift Times: 6.61 +/- 0.24 ms
1.40 17.74
3.72 diacetate-3-phenylacetate
0
597.08556
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000
575.10331
517.37082
296.29574
489.33888 599.08956
181.10207
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Cucurbitacin B [+H] : (39.7 PPM) 559.3275 : DT=6.18 to 6.66 ms

Cucurbitacin B
250 16.61

200
Intensity [Counts]

150

100 16.71
16.51
16.48 16.82

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6607 +/- 0.0285
Channel name: Cucurbitacin B [+H] : (39.7 PPM) 559.3275 Component name: Cucurbitacin B minutes : Drift Times: 6.42 +/- 0.24 ms
16.61
1500 473.34336
16.56
30000
1250 447.27355

Intensity [Counts]
16.48 507.29402
11.27 20000
1000
Intensity [Counts]

16.71 296.29537
750 10000 531.33766
393.26075
14.25 557.30350
500 14.20 585.36942
9.38 14.60 0
8.25 200 400 600 800 1000
16.91
250 5.33 8.05 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6607 +/- 0.0285
2.39 3.22 4.53 17.00
Component name: Cucurbitacin B minutes : Drift Times: 6.27 +/- 0.24 ms
0.93
0 473.34291

0 5 10 15 20 517.37082
30000 429.32002
Retention time [min]

Intensity [Counts]
20000
523.31913

377.26414 548.38053
10000
133.10182
347.22048 601.38359

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Vitetrifolin E [+H] : (39.7 PPM) 365.2697 : DT=5.45 to 5.93 ms

16.59

600
16.54
Vitetrifolin E
Intensity [Counts]

16.67

400 16.37

200
16.26 16.83

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6730 +/- 0.0285
Channel name: Vitetrifolin E [+H] : (39.7 PPM) 365.2697 Component name: Vitetrifolin E minutes : Drift Times: 5.69 +/- 0.24 ms
1250 16.64
387.27099
16.59 343.24462

1000 16.50 16.67 40000

Intensity [Counts]
403.28295
Intensity [Counts]

750 421.29327
20000

16.37 334.24459
500
324.21376 422.28687
0
14.31 200 400 600 800 1000
250
13.64 15.05 16.85
6.40 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6730 +/- 0.0285
7.41 12.38
0.45 3.69 16.95 Component name: Vitetrifolin E minutes : Drift Times: 5.54 +/- 0.24 ms
4.68

0 387.27263

0 5 10 15 20
40000 343.24602
Retention time [min]

Intensity [Counts]
389.26632
20000
405.25918
321.23874 427.30786
451.30823
320.22882
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 14-Deoxyandrographolide [+H] : (39.7 PPM) 335.2208 : DT=5.19 to
5.67 ms

16.61

2000

16.56
1500
Intensity [Counts]

1000 14-Deoxyandrographolide
16.66

500
16.79

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6740 +/-
Channel name: 14-Deoxyandrographolide [+H] : (39.7 PPM) 335.2208 Component name: 14-Deoxyandrographolide 0.0285 minutes : Drift Times: 5.42 +/- 0.24 ms
16.61
4000 343.24462
16.56
40000

Intensity [Counts]
3000 377.26733
Intensity [Counts]

333.24156
20000
2000 13.64
301.14310 405.21586
13.69
289.15378 410.24985
10.61 13.55 0
1000 13.93 200 400 600 800 1000
16.78
11.41 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6740 +/-
5.54 8.85 9.53 18.03 Component name: 14-Deoxyandrographolide 0.0285 minutes : Drift Times: 5.27 +/- 0.24 ms
4.25
2.33 8.97
0 343.24602

0 5 10 15 20 319.22566
Retention time [min]

Intensity [Counts]
359.23820
20000 389.26518

301.14110

274.27338
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 12-Hydroxyhydromethyl abietate [+H] : (39.7 PPM) 337.2720 :
DT=5.22 to 5.70 ms

2500

2000
Intensity [Counts]

1500

1000

500
16.58
12-Hydroxyhydromethyl abietate
16.66
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6756 +/-
Channel name: 12-Hydroxyhydromethyl abietate [+H] : (39.7 PPM) 337.2720 Component name: 12-Hydroxyhydromethyl 0.0285 minutes : Drift Times: 5.46 +/- 0.24 ms
14.80 abietate

343.24462
4000
40000

Intensity [Counts]
377.26733
14.91
3000
Intensity [Counts]

333.24156
20000
301.14310 405.21586
2000
289.15378 409.25393
0
200 400 600 800 1000
1000
16.66 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6756 +/-
13.70 Component name: 12-Hydroxyhydromethyl 0.0285 minutes : Drift Times: 5.31 +/- 0.24 ms
2.14 11.06 17.14
8.84 13.39 abietate
0
343.24602
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000 389.26518

333.23898
321.23874

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 12-Hydroxy-methyl abietate [+H] : (39.7 PPM) 333.2416 : DT=5.14
to 5.62 ms

12-Hydroxy-methyl abietate
16.68
1000

750
Intensity [Counts]

16.54
500

16.47
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.6772 +/-
Channel name: 12-Hydroxy-methyl abietate [+H] : (39.7 PPM) 333.2416 Component name: 12-Hydroxy-methyl 0.0285 minutes : Drift Times: 5.40 +/- 0.24 ms
16.69 abietate
1500 16.66
343.24462
313.23653
16.54 40000

Intensity [Counts]
1000
Intensity [Counts]

347.25523

20000 349.23421
301.14310
365.13737
289.15378
405.21586
500 0
12.89 13.70
200 400 600 800 1000
13.74 17.00
9.4710.83 Item name: MENGKUDU 2 Channel name: High energy : Time 16.6772 +/-
4.98 6.06 8.66 18.53 Component name: 12-Hydroxy-methyl 0.0285 minutes : Drift Times: 5.24 +/- 0.24 ms
1.15 2.88 abietate
0
343.24602
0 5 10 15 20
Retention time [min] 313.23671

Intensity [Counts]
359.23820
20000 389.26518

301.14110

274.27338
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Agroastragaloside Ⅱ [+H] : (39.7 PPM) 829.4924 : DT=8.77 to 9.25
ms
16.48
16.55
400

16.81
300
Agroastragaloside Ⅱ
Intensity [Counts]

16.71

200
16.90

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7042 +/- 0.0285
Channel name: Agroastragaloside Ⅱ [+H] : (39.7 PPM) 829.4924 Component name: Agroastragaloside Ⅱ minutes : Drift Times: 8.99 +/- 0.24 ms
16.49
685.43655
40000
1000 16.55

Intensity [Counts]
750 16.61
853.58091
Intensity [Counts]

20000 686.43892
16.71
11.91 841.54714
16.76 860.53983
500
421.23364
12.52 16.81 598.08830
10.42
14.39 16.91 0
10.27 200 400 600 800 1000
250
7.91 8.42 17.04
Item name: MENGKUDU 2 Channel name: High energy : Time 16.7042 +/-
6.17 7.69
0.78 2.22 Component name: Agroastragaloside Ⅱ 0.0285 minutes : Drift Times: 8.84 +/- 0.24 ms
4.25
0 685.43679

0 5 10 15 20
30000
Retention time [min]

Intensity [Counts]
20000
853.58585
686.44492
10000 841.55191
230.24866 421.23477
385.17703 598.08989
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Soyasaponin Ⅲ [+H] : (39.7 PPM) 813.4991 : DT=8.48 to 8.96 ms
16.48
1000

750

Soyasaponin Ⅲ
Intensity [Counts]

16.70
500

16.84
16.86
250

17.00
16.39

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7044 +/- 0.0285
Channel name: Soyasaponin Ⅲ [+H] : (39.7 PPM) 813.4991 Component name: Soyasaponin Ⅲ minutes : Drift Times: 8.73 +/- 0.24 ms
16.48
685.43655
40000
1500 16.71

Intensity [Counts]
795.54068
797.52124
Intensity [Counts]

1000 16.86 20000


815.50810

819.50216
17.29
597.08408 861.51737
500 0
200 400 600 800 1000
11.78
17.48
12.79 14.05 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7044 +/- 0.0285
7.71 11.19 18.23
2.28 Component name: Soyasaponin Ⅲ minutes : Drift Times: 8.57 +/- 0.24 ms
0.79 4.15 5.88
0 685.43679

0 5 10 15 20
30000
Retention time [min]

Intensity [Counts]
20000
797.52736

853.58585
10000
230.24866 857.52204
669.40405
439.24144 899.42589
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Brahmic acid [+H] : (39.7 PPM) 505.3516 : DT=6.30 to 6.78 ms

2000
16.61

1500
Intensity [Counts]

1000
Brahmic acid
16.71
16.85
500 16.51
16.98

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7063 +/- 0.0285
Channel name: Brahmic acid [+H] : (39.7 PPM) 505.3516 Component name: Brahmic acid minutes : Drift Times: 6.54 +/- 0.24 ms
13.68
489.33855
6000
30000

Intensity [Counts]
477.35411
20000 505.30820
461.32420
Intensity [Counts]

4000
449.28252
443.23890 507.32936
10000 557.30350
16.61 413.28555
599.36637
347.25543
2000 16.71 0
200 400 600 800 1000
16.51 16.86
11.91 13.55 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7063 +/- 0.0285
8.42 9.62 16.98 Component name: Brahmic acid minutes : Drift Times: 6.39 +/- 0.24 ms
7.55 14.98 17.99
0 489.34047
30000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
20000 443.33535

10000 493.31562
433.28742 551.32699
277.14077 390.30146
564.38906
275.16060
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Nigakilactone H [+H] : (39.7 PPM) 425.2155 : DT=5.94 to 6.43 ms

Nigakilactone H
16.71
8000

6000
Intensity [Counts]

4000

2000

16.59 16.85

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7104 +/- 0.0285
Channel name: Nigakilactone H [+H] : (39.7 PPM) 425.2155 Component name: Nigakilactone H minutes : Drift Times: 6.19 +/- 0.24 ms
16.71
425.21545

445.31429
10000 40000

Intensity [Counts]
419.27684

405.25940
7500
Intensity [Counts]

461.32420
20000
4.38
399.26862 507.32936
5000 395.27785
509.14665
385.17902
0
200 400 600 800 1000
2500
4.04 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7104 +/- 0.0285
16.53
5.89 18.47 Component name: Nigakilactone H minutes : Drift Times: 6.03 +/- 0.24 ms
5.04 8.60 10.39 12.13 15.13 17.65
3.70
0 445.31742

0 5 10 15 20
30000
Retention time [min]

Intensity [Counts]
425.21852
20000
419.27847
447.33944
391.24543
10000 449.28519
365.19218
461.32689
291.23060
511.16129
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1β,2β,3β,19α-Tetrahy-droxyurs-12-en-28-oate-3-O-β-D-
xylopyranoside [+H] : (39.7 PPM) 637.3920 : DT=7.38 to 7.86 ms
16.62

1000 1β,2β,3β,19α-Tetrahy-droxyurs-12-en-28-oate-3-O-β-D-xylopyranoside
16.71
16.84
Intensity [Counts]

750
16.89
16.55
500 16.49

16.97
16.44
250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7127 +/-
Channel name: 1β,2β,3β,19α-Tetrahy-droxyurs-12-en-28-oate-3-O-β-D- Component name: 1β,2β,3β,19α-Tetrahy- 0.0285 minutes : Drift Times: 7.60 +/- 0.24 ms
xylopyranoside [+H] : (39.7 PPM) 637.3920 droxyurs-12-en-28-oate-3-O-β-D-
16.61 xylopyranoside

621.41499
2000
30000
16.88

Intensity [Counts]
619.42688
1500 20000
Intensity [Counts]

16.49 677.37309
609.35932

10000 576.41204
1000 687.44841
301.14333 491.37180 717.21596
16.98 0
200 400 600 800 1000
500 17.07
13.65 16.18
9.95 11.96 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7127 +/-
11.84 17.20 Component name: 1β,2β,3β,19α-Tetrahy- 0.0285 minutes : Drift Times: 7.44 +/- 0.24 ms
4.95 8.70 droxyurs-12-en-28-oate-3-O-β-D-
0 xylopyranoside
0 5 10 15 20 665.44434
Retention time [min] 621.41870

Intensity [Counts]
20000

619.39783
693.47253
10000 581.36284
745.41750
515.35417
301.14128
775.49012
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-
one-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) 645.4017 : DT=7.72 to 8.20 ms

3000
Intensity [Counts]

2000

1000

(3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-o…
0 16.71
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7173 +/-
Channel name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24- Component name: (3β,12β,16β)-12- 0.0285 minutes : Drift Times: 7.96 +/- 0.24 ms
one-3-O-β-D-xylopyranoside [+H] : (39.7 PPM) 645.4017 Acetoxy-16,23-epoxy-9,19-cyclolanost-22-
13.69 ene-24-one-3-O-β-D-xylopyranoside

665.44257
30000
709.46847

Intensity [Counts]
4000 20000
Intensity [Counts]

634.44801 723.48344
763.52085
13.54 10000
799.38686
559.51332
2000
16.60 0
200 400 600 800 1000
16.55
16.71 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7173 +/-
13.94
11.11 13.17 16.82 Component name: (3β,12β,16β)-12- 0.0285 minutes : Drift Times: 7.81 +/- 0.24 ms
6.96 8.66 Acetoxy-16,23-epoxy-9,19-cyclolanost-22-
0 ene-24-one-3-O-β-D-xylopyranoside
0 5 10 15 20 665.44434
Retention time [min]
709.46796

Intensity [Counts]
20000
663.45071 727.46428

10000 728.46593
503.35971 799.39080
227.20142
301.14128 661.46475
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Vinaginsenoside R1 [+H] : (39.7 PPM) 843.5090 : DT=9.47 to 9.95 ms
16.68

100

Vinaginsenoside R1
16.74
75
16.82
Intensity [Counts]

50

25

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7383 +/- 0.0285
Channel name: Vinaginsenoside R1 [+H] : (39.7 PPM) 843.5090 Component name: Vinaginsenoside R1 minutes : Drift Times: 9.71 +/- 0.24 ms
16.75
841.76501
1000 7500
16.49
813.71305

Intensity [Counts]
750 5000
Intensity [Counts]

802.57668

2500 787.63962
500
677.37347

16.92 0
250 11.18 13.9514.71 200 400 600 800 1000
7.04 13.66 16.97
3.07 10.46
0.38 6.98 18.40 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7383 +/- 0.0285
2.18 5.18 7.92
3.85 18.57 Component name: Vinaginsenoside R1 minutes : Drift Times: 9.56 +/- 0.24 ms

0 O
677.37444 991.62052
H O
O 911.71934
0 5 10 15 20
O
H O O

5000
O

Retention time [min]


O
O
H

Intensity [Counts]
841.76030
O
H
O

O O

O
815.72234
817.64528
2500 519.25970
Mass error: 0.8 mDa

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Vinaginsenoside R1 [+H] : (39.7 PPM) 843.5089 : DT=8.76 to 9.24 ms
Vinaginsenoside R1
16.75

600
Intensity [Counts]

400
16.48

200 16.81
16.93

16.97

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

Vinaginsenoside R1
16.71
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7392 +/- 0.0285
Channel name: Vinaginsenoside R1 [+H] : (39.7 PPM) 843.5089 Component name: Vinaginsenoside R1 minutes : Drift Times: 9.12 +/- 0.24 ms
16.75
686.43892
1000 20000

16.49

Intensity [Counts]
750 837.55364 903.56300
Intensity [Counts]

10000 859.54105

500

684.63754
16.92 0
250 11.18 13.9514.71 200 400 600 800 1000
7.04 13.66 16.97
3.07 10.46
0.38 6.98 18.40 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7392 +/- 0.0285
2.18 5.18 7.92
3.85 18.57 Component name: Vinaginsenoside R1 minutes : Drift Times: 8.97 +/- 0.24 ms

0 911.62727
762.59523
0 5 10 15 20
10000
Retention time [min]

Intensity [Counts]
677.37463
5000
385.17703 659.28619
281.05223 497.28299

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Curculigo saponin D [+H] : (39.7 PPM) 799.4854 : DT=8.47 to 8.95
ms
Curculigo saponin D
800 16.75

600
Intensity [Counts]

400
16.63

16.56
200 16.48
17.30
17.39

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7480 +/- 0.0285
Channel name: Curculigo saponin D [+H] : (39.7 PPM) 799.4854 Component name: Curculigo saponin D minutes : Drift Times: 8.69 +/- 0.24 ms
16.75
1250 685.43655
40000

16.48
1000

Intensity [Counts]
Intensity [Counts]

20000 771.48276
750
815.50810
821.59270
500 6.57 550.62672 683.64078
375.25130
561.39759
13.14 17.29 0
13.54 200 400 600 800 1000
250 17.52
10.31 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7480 +/- 0.0285
0.52 4.68 8.00
8.82 17.78 Component name: Curculigo saponin D minutes : Drift Times: 8.53 +/- 0.24 ms
2.55 7.29
2.44
0 685.43679

0 5 10 15 20
30000
Retention time [min]

Intensity [Counts]
20000

10000 815.51250
659.28619 847.51991
315.18885 647.50787
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Sericoside [+H] : (39.7 PPM) 667.4078 : DT=7.61 to 8.09 ms
1250 Sericoside
16.76

1000
Intensity [Counts]

750 16.66
16.61

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7586 +/- 0.0285 minutes :
Channel name: Sericoside [+H] : (39.7 PPM) 667.4078 Component name: Sericoside Drift Times: 7.86 +/- 0.24 ms
16.50
677.37382
16.76 75000
11.90

1500

Intensity [Counts]
50000
Intensity [Counts]

614.52309
683.43082
1000 25000
14.78 703.38586
11.78 590.42258
717.21596
12.53
17.01 516.32145
14.90 0
500 8.42 11.57 200 400 600 800 1000
9.21 17.06
8.06 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7586 +/- 0.0285 minutes :
17.66
3.59 Component name: Sericoside Drift Times: 7.70 +/- 0.24 ms
7.96 6.99 18.41
3.23
0 677.37431

0 5 10 15 20 75000

Retention time [min]

Intensity [Counts]
50000

614.52597
25000 683.43718
227.20142 313.27530
592.54194 703.39189

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Methyl 11α-hydroxytormentate [+H] : (39.7 PPM) 519.3696 :
DT=6.49 to 6.98 ms
16.67

1500 Methyl 11α-hydroxytormentate


16.79
Intensity [Counts]

1000

16.59
500 16.56
16.92

16.46 16.98

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7597 +/-
Channel name: Methyl 11α-hydroxytormentate [+H] : (39.7 PPM) 519.3696 Component name: Methyl 11α- 0.0285 minutes : Drift Times: 6.73 +/- 0.24 ms
16.67 hydroxytormentate
2500 16.80
30000 507.32941

463.30258
2000

Intensity [Counts]
20000
535.34740
Intensity [Counts]

1500 545.37487
10000
450.32560 613.34210

1000 414.29521
16.54
0
16.92 200 400 600 800 1000
500 16.48
16.97 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7597 +/-
6.20 7.64 8.61 10.82 13.14 14.36 17.11
Component name: Methyl 11α- 0.0285 minutes : Drift Times: 6.58 +/- 0.24 ms
3.58 hydroxytormentate
0
507.33005
0 5 10 15 20 20000
503.36030
Retention time [min]

Intensity [Counts]
487.36602
10000 552.35718
449.28395
417.29636 563.40318
149.02269 361.27115 580.35865
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1-O-β-D-Glucopyranosylpaeonisuffrone [+H] : (39.7 PPM)
361.1506 : DT=4.57 to 5.05 ms
1-O-β-D-Glucopyranosylpaeonisuffrone
500 16.76

400

16.69
Intensity [Counts]

300
16.64

16.61
200
16.54

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7640 +/-
Channel name: 1-O-β-D-Glucopyranosylpaeonisuffrone [+H] : (39.7 PPM) 361.1506 Component name: 1-O-β-D- 0.0285 minutes : Drift Times: 4.81 +/- 0.24 ms
6.83 Glucopyranosylpaeonisuffrone
8000
349.18697
361.15060
5000

Intensity [Counts]
6000
228.23234
Intensity [Counts]

214.21963
7.15
2500
4000
6.42

0
7.91
2000 9.82 200 400 600 800 1000
4.31
4.22 5.11 8.51 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7640 +/-
9.99 12.18
2.89 13.72 16.76 Component name: 1-O-β-D- 0.0285 minutes : Drift Times: 4.66 +/- 0.24 ms
0.61 18.49 Glucopyranosylpaeonisuffrone
0
228.23276 361.14586
0 5 10 15 20
Retention time [min]

Intensity [Counts]
2000
377.22142

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Schizonepetoside E [+H] : (39.7 PPM) 349.1870 : DT=4.49 to 4.97 ms

5000

4000
Intensity [Counts]

3000

2000

1000
Schizonepetoside E
16.78

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.7681 +/- 0.0285
Channel name: Schizonepetoside E [+H] : (39.7 PPM) 349.1870 Component name: Schizonepetoside E minutes : Drift Times: 4.73 +/- 0.24 ms
5.02
349.18697
6000
361.15060
5000
13.74

Intensity [Counts]
13.41 214.21963
15.47
Intensity [Counts]

4000
12.94
2500
4.96 16.54

16.60
2000 12.76 0
200 400 600 800 1000
12.28
12.04 16.77 Item name: MENGKUDU 2 Channel name: High energy : Time 16.7681 +/- 0.0285
5.27 7.88
4.51 8.80 Component name: Schizonepetoside E minutes : Drift Times: 4.57 +/- 0.24 ms
1.86 2.73 16.98
0 361.14586

0 5 10 15 20
3000
Retention time [min]

Intensity [Counts]
2000
377.22142
283.26147
1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1α,2α,3β,19α,23-Pentadroxyurs-12-en-28-oic acid-28-O-β-D-
xylopyranoside [+H] : (39.7 PPM) 653.3893 : DT=7.38 to 7.86 ms
16.56

600
16.71
Intensity [Counts]

400
1α,2α,3β,19α,23-Pentadroxyurs-12-en-28-oic acid-28-O-β-D-xylopyra…
16.81
16.46

200

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.8184 +/-
Channel name: 1α,2α,3β,19α,23-Pentadroxyurs-12-en-28-oic acid-28-O-β-D- Component name: 1α,2α,3β,19α,23- 0.0285 minutes : Drift Times: 7.62 +/- 0.24 ms
xylopyranoside [+H] : (39.7 PPM) 653.3893 Pentadroxyurs-12-en-28-oic acid-28-O-β-D-
16.57 xylopyranoside
1250
16.53 605.42410

649.44972
1000 16.61 100000

Intensity [Counts]
16.71
Intensity [Counts]

600.46818
750 16.81
50000
16.46
650.45469
16.90
500 16.96 595.34286 665.42444
13.54 385.29359
0
8.95 17.11 200 400 600 800 1000
10.02 13.20 13.64
250 8.61 17.16 Item name: MENGKUDU 2 Channel name: High energy : Time 16.8184 +/-
4.51 6.40 Component name: 1α,2α,3β,19α,23- 0.0285 minutes : Drift Times: 7.47 +/- 0.24 ms
2.30 3.53
Pentadroxyurs-12-en-28-oic acid-28-O-β-D-
0 xylopyranoside
0 5 10 15 20 605.42578
Retention time [min]
100000 649.45179

Intensity [Counts] 50000

650.45451
415.25392
665.42365
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Xiongterpene [+H] : (39.7 PPM) 603.4055 : DT=7.28 to 7.77 ms

2000

1500
Intensity [Counts]

1000

16.87
500 Xiongterpene
16.82

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.8358 +/- 0.0285
Channel name: Xiongterpene [+H] : (39.7 PPM) 603.4055 Component name: Xiongterpene minutes : Drift Times: 7.53 +/- 0.24 ms
13.68
575.41266
1.5e5 619.43870
4000

Intensity [Counts]
570.45710
100000
3000
Intensity [Counts]

635.41308
50000
2000 637.39869
371.22789
683.35533
16.69
0
13.54
16.81 200 400 600 800 1000
1000 16.64
16.52 16.86 Item name: MENGKUDU 2 Channel name: High energy : Time 16.8358 +/- 0.0285
8.77 11.84 Component name: Xiongterpene minutes : Drift Times: 7.37 +/- 0.24 ms
10.36 16.96
8.66 13.95
0 575.41473

0 5 10 15 20 1.5e5 619.44053
Retention time [min]

Intensity [Counts]
100000

50000 635.41270
570.45851 637.39730
371.22762
177.11247
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3β,4β,23-Trihydroxy-24,30-dinorolean-12,20(29)-dien-28-oic acid
[+H] : (39.7 PPM) 459.3102 : DT=7.82 to 8.30 ms
16.78

100 3β,4β,23-Trihydroxy-24,30-dinorolean-12,20(29)-dien-28-oic acid


16.86
Intensity [Counts]

16.91

50

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.8373 +/-
Channel name: 3β,4β,23-Trihydroxy-24,30-dinorolean-12,20(29)-dien-28-oic acid Component name: 3β,4β,23-Trihydroxy-24,30- 0.0285 minutes : Drift Times: 8.06 +/- 0.24 ms
[+H] : (39.7 PPM) 459.3102 dinorolean-12,20(29)-dien-28-oic acid
16.86
663.46315
16.60 100000

3000 658.50838

Intensity [Counts]
Intensity [Counts]

50000
2000 664.46555
679.43783
643.40438
459.31019 737.50005

0
1000 16.55
200 400 600 800 1000
6.99
7.81 Item name: MENGKUDU 2 Channel name: High energy : Time 16.8373 +/-
6.65 17.19 Component name: 3β,4β,23-Trihydroxy-24,30- 0.0285 minutes : Drift Times: 7.91 +/- 0.24 ms
3.93 9.43 11.93 13.68
dinorolean-12,20(29)-dien-28-oic acid
0
663.46603
0 5 10 15 20
Retention time [min] 707.49402

Intensity [Counts]
50000

723.46289
658.51179
725.47061
459.31294
221.13658 807.47152
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 3β,4β,23-Trihydroxy-24,30-dinorolean-12,20(29)-dien-28-oic acid
[+H] : (39.7 PPM) 459.3104 : DT=6.26 to 6.74 ms

3β,4β,23-Trihydroxy-24,30-dinorolean-12,20(29)-dien-28-oic acid
16.86

2000 16.62
Intensity [Counts]

1000

16.49
16.96

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.8580 +/-
Channel name: 3β,4β,23-Trihydroxy-24,30-dinorolean-12,20(29)-dien-28-oic acid Component name: 3β,4β,23-Trihydroxy-24,30- 0.0285 minutes : Drift Times: 6.51 +/- 0.24 ms
[+H] : (39.7 PPM) 459.3104 dinorolean-12,20(29)-dien-28-oic acid
16.86
443.33506
16.60
487.36113
3000

Intensity [Counts]
2e5
Intensity [Counts]

2000 100000
431.18419 488.36528
239.14953 505.33496
0
1000 16.55
200 400 600 800 1000
6.98
7.81 Item name: MENGKUDU 2 Channel name: High energy : Time 16.8580 +/-
6.65 17.19 Component name: 3β,4β,23-Trihydroxy-24,30- 0.0285 minutes : Drift Times: 6.36 +/- 0.24 ms
3.93 9.43 11.93 13.68
dinorolean-12,20(29)-dien-28-oic acid
0
443.33626
0 5 10 15 20 487.36236
Retention time [min]
2e5

Intensity [Counts] 100000


488.36658
431.18346
239.15021 503.33384
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Methyl ursolate [+H] : (39.7 PPM) 471.3845 : DT=6.53 to 7.02 ms

Methyl ursolate
16.86
500

400
Intensity [Counts]

300

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.8609 +/- 0.0285
Channel name: Methyl ursolate [+H] : (39.7 PPM) 471.3845 Component name: Methyl ursolate minutes : Drift Times: 6.78 +/- 0.24 ms
16.86
487.36113

2e5
600

Intensity [Counts]
Intensity [Counts]

100000
400
488.36528
482.40625
283.17489
503.33479
239.14953 397.29570
16.68 583.40089
0
200 11.07
5.43 16.64 200 400 600 800 1000
4.85 17.66
7.53 13.11 14.06 Item name: MENGKUDU 2 Channel name: High energy : Time 16.8609 +/- 0.0285
10.98
3.11 6.25 9.36 18.30 Component name: Methyl ursolate minutes : Drift Times: 6.62 +/- 0.24 ms
1.32
0 487.36236

0 5 10 15 20
2e5
Retention time [min]

Intensity [Counts]
100000

488.36658
475.30102 547.36100
133.08594 283.17664
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Arjunglucoside Ⅱ [+H] : (39.7 PPM) 651.4112 : DT=8.23 to 8.71 ms

300
Intensity [Counts]

Arjunglucoside Ⅱ
16.91
200

17.00

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.8774 +/- 0.0285
Channel name: Arjunglucoside Ⅱ [+H] : (39.7 PPM) 651.4112 Component name: Arjunglucoside Ⅱ minutes : Drift Times: 8.47 +/- 0.24 ms
16.66
2000 721.50481
16.91 30000
16.56
765.53334

Intensity [Counts]
1500
20000 705.40234
Intensity [Counts]

1000 10000

531.38698 847.55040
11.78
16.98 0
500 13.30 17.31 200 400 600 800 1000
9.80 14.90
0.56 17.47 Item name: MENGKUDU 2 Channel name: High energy : Time 16.8774 +/- 0.0285
7.13 9.28
18.24 Component name: Arjunglucoside Ⅱ minutes : Drift Times: 8.32 +/- 0.24 ms
4.20 4.95
6.28
0 765.53563

0 5 10 15 20 15000

Retention time [min]

Intensity [Counts]
10000

781.50847
5000 531.38838
689.48567
383.14054 815.64409
327.07937
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Methyl lucidenate Q [+H] : (39.7 PPM) 475.3013 : DT=6.68 to 7.16
ms

1000 Methyl lucidenate Q


16.87

750
Intensity [Counts]

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.8775 +/- 0.0285
Channel name: Methyl lucidenate Q [+H] : (39.7 PPM) 475.3013 Component name: Methyl lucidenate Q minutes : Drift Times: 6.94 +/- 0.24 ms
7.75
487.36113
5000
531.38695
2e5

Intensity [Counts]
4000
Intensity [Counts]

100000
3000
16.66
482.40625 532.39019
16.56 283.17489 547.36195
2000 327.20223
240.14969
16.75 625.36820
16.49 0
16.87 200 400 600 800 1000
1000 Item name: MENGKUDU 2 Channel name: High energy : Time 16.8775 +/- 0.0285
17.87
12.90 Component name: Methyl lucidenate Q minutes : Drift Times: 6.78 +/- 0.24 ms
14.37
4.08 6.80 8.92 10.42
0 2e5 531.38835

0 5 10 15 20
Retention time [min]

Intensity [Counts]
100000

532.39090
89.06031 503.33384
327.20266 547.36100
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1β,2β,3β,19α-Tetrahy-droxyurs-12-en-28-oate-3-O-β-D-
xylopyranoside [+H] : (39.7 PPM) 637.3988 : DT=7.73 to 8.21 ms

1β,2β,3β,19α-Tetrahy-droxyurs-12-en-28-oate-3-O-β-D-xylopyranoside
16.88

750
Intensity [Counts]

500
16.98

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.8824 +/-
Channel name: 1β,2β,3β,19α-Tetrahy-droxyurs-12-en-28-oate-3-O-β-D- Component name: 1β,2β,3β,19α-Tetrahy- 0.0285 minutes : Drift Times: 7.98 +/- 0.24 ms
xylopyranoside [+H] : (39.7 PPM) 637.3988 droxyurs-12-en-28-oate-3-O-β-D-
16.61 xylopyranoside

677.48097
2000 40000
16.71

Intensity [Counts]
16.88

1500
Intensity [Counts]

16.49 637.39878 693.45580


20000

594.28087 695.45678
1000
331.28413 443.33505 729.46026
16.98
0
200 400 600 800 1000
500 17.07
13.65 16.18 Item name: MENGKUDU 2 Channel name: High energy : Time 16.8824 +/-
8.70 9.51 13.58 17.20 Component name: 1β,2β,3β,19α-Tetrahy- 0.0285 minutes : Drift Times: 7.82 +/- 0.24 ms
4.95
8.94 droxyurs-12-en-28-oate-3-O-β-D-
0 xylopyranoside
0 5 10 15 20 677.48259
Retention time [min]

Intensity [Counts]
20000
705.40628

647.49466
501.37730 763.50405
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Abrisapogenol E [+H] : (39.7 PPM) 475.3771 : DT=6.53 to 7.01 ms

Abrisapogenol E
16.90
16.81
400

16.72
Intensity [Counts]

300
16.61 16.96

200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.9014 +/- 0.0285
Channel name: Abrisapogenol E [+H] : (39.7 PPM) 475.3771 Component name: Abrisapogenol E minutes : Drift Times: 6.77 +/- 0.24 ms
7.76
2500 457.35123
1.5e5
501.37694

2000

Intensity [Counts]
100000
Intensity [Counts]

1500
50000
502.37987
16.81
1000 438.32249 517.35355
16.89 240.14969
16.72 0
200 400 600 800 1000
500 16.62
Item name: MENGKUDU 2 Channel name: High energy : Time 16.9014 +/- 0.0285
8.23 16.51 17.12
Component name: Abrisapogenol E minutes : Drift Times: 6.62 +/- 0.24 ms
6.65 10.33 12.60 17.41
1.37
0 457.35178

0 5 10 15 20
501.37872
Retention time [min] 100000

Intensity [Counts] 50000

502.38099
284.18075 431.34924 517.36352
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Arjunglucoside Ⅱ [+H] : (39.7 PPM) 651.4088 : DT=7.78 to 8.26 ms
Arjunglucoside Ⅱ
16.91
1000

16.66
750
Intensity [Counts]

500 16.56

16.50
16.47
250 16.97

17.13

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.9133 +/- 0.0285
Channel name: Arjunglucoside Ⅱ [+H] : (39.7 PPM) 651.4088 Component name: Arjunglucoside Ⅱ minutes : Drift Times: 8.04 +/- 0.24 ms
16.66
60000 628.49994
16.91 633.45543
16.56
672.52522

Intensity [Counts]
1500 40000
677.48097
Intensity [Counts]

693.45580
1000 20000
705.40234
415.25470605.47169
11.78 719.53668
483.36747
16.98 0
500 13.30 17.32 200 400 600 800 1000
9.80 14.90
0.56 17.47 Item name: MENGKUDU 2 Channel name: High energy : Time 16.9133 +/- 0.0285
7.13 9.28
18.24 Component name: Arjunglucoside Ⅱ minutes : Drift Times: 7.89 +/- 0.24 ms
4.20 4.95
6.28
0 677.48259

0 5 10 15 20
30000
Retention time [min]

Intensity [Counts]
20000
705.40628
628.50102
10000
415.25550
501.37730 763.50405

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 11-O-p-Coumarylnepeticin [+H] : (39.7 PPM) 589.4290 : DT=7.28 to
7.76 ms
16.65
25000

20000
Intensity [Counts]

15000

10000

11-O-p-Coumarylnepeticin
16.92
5000

16.57 17.14
0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

11-O-p-Coumarylnepeticin
0 16.91
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.9182 +/-
Channel name: 11-O-p-Coumarylnepeticin [+H] : (39.7 PPM) 589.4290 Component name: 11-O-p-Coumarylnepeticin 0.0285 minutes : Drift Times: 7.52 +/- 0.24 ms
16.66
75000 589.42900

40000 584.47404

Intensity [Counts]
50000

30000
Intensity [Counts]

605.40695
25000

20000 371.22737
573.49780
355.07038 685.20372
16.91 0
200 400 600 800 1000
10000
Item name: MENGKUDU 2 Channel name: High energy : Time 16.9182 +/-
Component name: 11-O-p-Coumarylnepeticin 0.0285 minutes : Drift Times: 7.37 +/- 0.24 ms

0 589.43127

0 5 10 15 20
633.45742
Retention time [min]

Intensity [Counts]
50000

25000

584.47505
327.20409 635.45830
371.22838 650.43782
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Platycodigenin [+H] : (39.7 PPM) 521.3467 : DT=6.98 to 7.46 ms
Platycodigenin
500 16.92

16.76

16.70
400
16.57
Intensity [Counts]

300
16.97
17.05
200

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 16.9218 +/- 0.0285
Channel name: Platycodigenin [+H] : (39.7 PPM) 521.3467 Component name: Platycodigenin minutes : Drift Times: 7.19 +/- 0.24 ms
2000 7.99
545.40333

75000

Intensity [Counts]
1500
540.44668
16.66 50000
Intensity [Counts]

16.56
16.71
496.42172
1000 561.38235
16.91 25000 283.17569
8.21 16.48 327.20260
9.37 685.20372
16.97 0
7.39
500 10.38 200 400 600 800 1000
13.64 17.05
6.89 18.50 Item name: MENGKUDU 2 Channel name: High energy : Time 16.9218 +/- 0.0285
4.67 Component name: Platycodigenin minutes : Drift Times: 7.04 +/- 0.24 ms
5.28
0 545.40436
75000
0 5 10 15 20
Retention time [min]

Intensity [Counts]
50000

25000 523.36143
561.38316
327.20409 605.40468
283.17526
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 11-O-p-Coumarylnepeticin [+H] : (39.7 PPM) 589.4259 : DT=7.35 to
7.83 ms
16.65
30000
Intensity [Counts]

20000

10000 16.92

16.56
11-O-p-Coumarylnepeticin
17.27
0 17.14
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 17.1422 +/-
Channel name: 11-O-p-Coumarylnepeticin [+H] : (39.7 PPM) 589.4259 Component name: 11-O-p-Coumarylnepeticin 0.0285 minutes : Drift Times: 7.59 +/- 0.24 ms
16.66
50000 614.48761
7500

551.39493

40000

Intensity [Counts]
617.46467
5000
629.51112
Intensity [Counts]

30000 533.40548
2500
511.40005 726.01361
20000

16.91 0
200 400 600 800 1000
10000
Item name: MENGKUDU 2 Channel name: High energy : Time 17.1422 +/-
Component name: 11-O-p-Coumarylnepeticin 0.0285 minutes : Drift Times: 7.43 +/- 0.24 ms
551.39527 617.46435
0
529.41180 621.40828
0 5 10 15 20 3000
Retention time [min]

Intensity [Counts]
677.30349
2000
728.49566

1000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 1-O-β-D-Glucopyranosylpaeonisuffrone [+H] : (39.7 PPM)
361.1512 : DT=4.62 to 5.10 ms
16.76
500

400 16.94
Intensity [Counts]

300 1-O-β-D-Glucopyranosylpaeonisuffrone
17.17
16.69

16.66
200
16.59

100

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 17.1796 +/-
Channel name: 1-O-β-D-Glucopyranosylpaeonisuffrone [+H] : (39.7 PPM) 361.1512 Component name: 1-O-β-D- 0.0285 minutes : Drift Times: 4.86 +/- 0.24 ms
6.83 Glucopyranosylpaeonisuffrone
8000
361.15116

4000
331.20949

Intensity [Counts]
6000
Intensity [Counts]

7.15
2000
4000
6.42

0
7.91
2000 9.82 200 400 600 800 1000
4.31
4.22 5.11 8.51 Item name: MENGKUDU 2 Channel name: High energy : Time 17.1796 +/-
9.99 12.18
2.87 13.72 16.76 Component name: 1-O-β-D- 0.0285 minutes : Drift Times: 4.71 +/- 0.24 ms
0.61 18.49 Glucopyranosylpaeonisuffrone
0
1
0 5 10 15 20
Retention time [min]

Intensity [Counts]
0.5

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yesanchinoside H [+H] : (39.7 PPM) 679.4399 : DT=7.94 to 8.42 ms

10000

7500
Intensity [Counts]

5000
16.84

16.98
2500
16.62

16.51 17.08
Yesanchinoside H
0 17.25
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 17.2427 +/- 0.0285
Channel name: Yesanchinoside H [+H] : (39.7 PPM) 679.4399 Component name: Yesanchinoside H minutes : Drift Times: 8.18 +/- 0.24 ms
13.69
540.50222

7500 639.42339
15000

Intensity [Counts]
5000 647.46127
Intensity [Counts]

10000 679.43991
2500 715.50513
539.53882 786.53104
16.84
13.54 16.98
16.61 0
5000
200 400 600 800 1000
13.94
Item name: MENGKUDU 2 Channel name: High energy : Time 17.2427 +/- 0.0285
17.46 Component name: Yesanchinoside H minutes : Drift Times: 8.03 +/- 0.24 ms

0 540.50066
721.49498
0 5 10 15 20 4000
Retention time [min]

Intensity [Counts]
310.31440
2000 284.26243

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2607 : DT=5.95 to 6.43
ms

600

400
Intensity [Counts]

200

Semiaquilegoside A
17.47

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 17.4637 +/- 0.0285
Channel name: Semiaquilegoside A [+H] : (39.7 PPM) 495.2607 Component name: Semiaquilegoside A minutes : Drift Times: 6.19 +/- 0.24 ms
18.39
495.26074
2000
3000

Intensity [Counts]
16.50
1500 16.61
2000 555.27846
Intensity [Counts]

16.44
18.32
16.17 1000
1000 8.91
10.87 16.11
12.91
13.28
7.10 9.21 0
500 200 400 600 800 1000
7.05 Item name: MENGKUDU 2 Channel name: High energy : Time 17.4637 +/- 0.0285
3.28 4.65
Component name: Semiaquilegoside A minutes : Drift Times: 6.03 +/- 0.24 ms
1.48

0 443.33522

0 5 10 15 20
Retention time [min]

Intensity [Counts]
5000

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Yesanchinoside H [+H] : (39.7 PPM) 679.4456 : DT=8.50 to 8.98 ms

1500
Intensity [Counts]

1000

Yesanchinoside H
17.46

500

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 17.4644 +/- 0.0285
Channel name: Yesanchinoside H [+H] : (39.7 PPM) 679.4456 Component name: Yesanchinoside H minutes : Drift Times: 8.74 +/- 0.24 ms
13.69
701.41570
30000
15000

Intensity [Counts]
20000
Intensity [Counts]

10000 679.44564

10000
16.84 671.38402 747.56365
16.61 16.98 649.45822 849.27103
13.54
5000 0
200 400 600 800 1000
13.94
Item name: MENGKUDU 2 Channel name: High energy : Time 17.4644 +/- 0.0285
17.46 Component name: Yesanchinoside H minutes : Drift Times: 8.58 +/- 0.24 ms

0 20000 439.20471

0 5 10 15 20
Retention time [min]

Intensity [Counts]
701.42235
10000 608.39528

702.42884

770.72016
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM)
497.2781 : DT=7.06 to 7.54 ms

19β-Glucosyl-14-deoxyandrographoside 17.96
1250
17.50

1000

16.98
Intensity [Counts]

750

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 17.5237 +/-
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM) 497.2781 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 7.31 +/- 0.24 ms
16.73 deoxyandrographoside

3000 15000 497.27812

Intensity [Counts]
10000
17.96
Intensity [Counts]

2000
16.53
18.11 570.45720
5000
12.24 611.35904
681.39838
1000 11.90 0
14.09 16.08
200 400 600 800 1000
11.70 14.96
6.45 Item name: MENGKUDU 2 Channel name: High energy : Time 17.5237 +/-
7.29 11.13
2.44 5.78 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 7.16 +/- 0.24 ms
3.39 deoxyandrographoside
0
519.26339
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000

363.17371

546.40089

0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: Eclalbasaponin Ⅸ [+H] : (39.7 PPM) 703.4100 : DT=8.55 to 9.03 ms

1000

750
Intensity [Counts]

500

250 Eclalbasaponin Ⅸ
17.56

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 17.5744 +/- 0.0285
Channel name: Eclalbasaponin Ⅸ [+H] : (39.7 PPM) 703.4100 Component name: Eclalbasaponin Ⅸ minutes : Drift Times: 8.79 +/- 0.24 ms
16.76
736.53165
18.40

1500 703.40999
5000

Intensity [Counts]
16.56

16.52 787.63972
Intensity [Counts]

696.53983
831.46924
1000 2500
13.68
14.80
13.53 14.89
0
500 18.50 200 400 600 800 1000
13.02
9.37 Item name: MENGKUDU 2 Channel name: High energy : Time 17.5744 +/- 0.0285
6.15 6.81 9.30
Component name: Eclalbasaponin Ⅸ minutes : Drift Times: 8.63 +/- 0.24 ms
3.68 5.79
1.65
0 685.43614

0 5 10 15 20
Retention time [min] 40000

Intensity [Counts] 20000

496.26975 736.52958
651.56775
0
200 400 600 800 1000
Observed mass [m/z]
Item name: MENGKUDU 2
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM)
497.2771 : DT=7.02 to 7.50 ms
19β-Glucosyl-14-deoxyandrographoside
1250
18.15

1000
Intensity [Counts]

750
16.73

500

250

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2
Channel name: Identified Components 14-Deoxy-11-hydro-xyandrographolide
13.68

2e6

5,7,2',5'-Tetrahydroxy-flavone
1.5e6 8.18
Intensity [Counts]

1e6

Prosapogenin 2
Cimicifugic acid B
16.60
7.19 Catalpol
5e5
12.04

0
0 5 10 15 20
Retention time [min]
Item name: MENGKUDU 2 Item name: MENGKUDU 2 Channel name: Low energy : Time 18.4720 +/-
Channel name: 19β-Glucosyl-14-deoxyandrographoside [+H] : (39.7 PPM) 497.2771 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 7.25 +/- 0.24 ms
16.73 deoxyandrographoside
3000
497.27707
519.26083

Intensity [Counts]
2000 17.96 531.38589
Intensity [Counts]

16.53 10000
18.11
575.41023
12.24
605.47284
1000 11.90 0
16.08
14.09
200 400 600 800 1000
11.70 14.96
6.45 Item name: MENGKUDU 2 Channel name: High energy : Time 18.4720 +/-
7.29 11.13
2.44 5.78 Component name: 19β-Glucosyl-14- 0.0285 minutes : Drift Times: 7.09 +/- 0.24 ms
3.39 deoxyandrographoside
0
519.26167
0 5 10 15 20
Retention time [min]

Intensity [Counts]
10000
575.41069
497.27861
605.42132
363.17385
679.32879
0
200 400 600 800 1000
Observed mass [m/z]
Frgmenton (high energy)

Item name: MENGKUDU 2, Component name: (+)-Bakuchiol


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 105.06988 Theoretical 105.07074 0.9 8.220 141 13.68796 4.64132 C8H9

Chiral

2 119.08553 Theoretical 119.08611 0.6 4.903 459 13.66120 4.65038 C9H11

Chiral

3 131.08553 Theoretical 131.08624 0.7 5.466 343 13.69172 4.59892 C10H11

Chiral

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
4 133.10118 Theoretical 133.10169 0.5 3.891 356 13.68343 4.71028 C10H13

Chiral

5 143.08553 Theoretical 143.08618 0.7 4.560 123 13.69732 4.49400 C11H11

Chiral

6 145.10118 Theoretical 145.10243 1.3 8.654 888 13.67645 4.65113 C11H13

Chiral

7 147.11683 Theoretical 147.11788 1.1 7.190 959 13.68500 4.70343 C11H15

Chiral

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
8 153.06988 Theoretical 153.06957 -0.3 -1.978 100 13.67280 4.49624 C12H9

Chiral

9 159.11683 Theoretical 159.11701 0.2 1.175 684 13.69216 4.67748 C12H15

Chiral

10 161.13248 Theoretical 161.13394 1.5 9.085 323 13.69466 4.71662 C12H17

Chiral

11 171.11683 Theoretical 171.11716 0.3 1.919 338 13.66208 4.56558 C13H15

Chiral

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
12 173.13248 Theoretical 173.13272 0.2 1.395 400 13.68460 4.66426 C13H17

Chiral

13 177.12739 Theoretical 177.12674 -0.7 -3.686 120 13.69680 4.58808 C12H17O

Chiral

14 187.11174 Theoretical 187.11320 1.5 7.772 343 13.68574 4.61048 C13H15O

Chiral

15 187.14813 Theoretical 187.14829 0.2 0.887 86 13.70531 4.42336 C14H19

Chiral

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
16 197.13248 Theoretical 197.13397 1.5 7.576 779 13.68710 4.67093 C15H17

Chiral

17 201.16378 Theoretical 201.16523 1.5 7.234 100 13.66811 4.60269 C15H21

Chiral

18 213.16378 Theoretical 213.16288 -0.9 -4.214 101 13.67929 4.52503 C16H21

Chiral

19 215.17943 Theoretical 215.17915 -0.3 -1.278 180 13.70472 4.52165 C16H23

Chiral

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
20 239.17943 Theoretical 239.18060 1.2 4.892 1655 13.67139 4.72224 C18H23

Chiral

Item name: MENGKUDU 2, Component name: (+)-Bakuchiol


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 91.05423 Theoretical 91.05438 0.2 1.718 597 16.49205 5.61253 C7H7

Chiral

2 107.08553 Theoretical 107.08596 0.4 4.046 183 16.51117 5.49614 C8H11

Chiral

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 142.07770 Theoretical 142.07855 0.8 5.955 165 16.48966 5.37147 C11H10

Chiral

4 159.08044 Theoretical 159.08024 -0.2 -1.260 99 16.51056 5.46017 C11H11O

Chiral

5 167.08553 Theoretical 167.08514 -0.4 -2.313 100 16.48794 5.77591 C13H11

Chiral

6 177.12739 Theoretical 177.12654 -0.8 -4.795 134 16.49536 5.49082 C12H17O

Chiral

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
7 187.14813 Theoretical 187.14950 1.4 7.314 180 16.47666 5.58733 C14H19

Chiral

8 199.14813 Theoretical 199.14927 1.1 5.744 416 16.49802 5.59783 C15H19

Chiral

9 243.17434 Theoretical 243.17546 1.1 4.587 99 16.51173 5.71526 C17H23O

Chiral

O
Item name: MENGKUDU 2, Component name: (+)-Bakuchiol
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 133.10118 Theoretical 133.10169 0.5 3.850 119 16.55412 4.17225 C10H13

Chiral

2 143.08553 Theoretical 143.08562 0.1 0.656 179 16.55065 4.62077 C11H11

Chiral

3 147.11683 Theoretical 147.11839 1.6 10.604 170 16.53725 4.52011 C11H15

Chiral

4 155.08553 Theoretical 155.08621 0.7 4.381 109 16.54474 4.38246 C12H11

Chiral

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 169.10118 Theoretical 169.10067 -0.5 -2.981 90 16.57995 4.59658 C13H13

Chiral

6 171.08044 Theoretical 171.08158 1.1 6.643 84 16.53444 4.32821 C12H11O

Chiral

7 171.11683 Theoretical 171.11681 0.0 -0.073 184 16.53567 4.51014 C13H15

Chiral

8 177.12739 Theoretical 177.12738 0.0 -0.048 127 16.56859 4.55668 C12H17O

Chiral

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
9 199.14813 Theoretical 199.14941 1.3 6.444 99 16.55250 4.42074 C15H19

Chiral

Item name: MENGKUDU 2, Component name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-one-3-O-β-D-xylopyranoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 149.13248 Theoretical 149.13337 0.9 5.965 80 16.57924 7.87208 C11H17

O O
H

H O
H

O O
H
O
O
O

2 161.09609 Theoretical 161.09632 0.2 1.414 218 16.57091 8.05549 C11H13O

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 184.07301 Theoretical 184.07428 1.3 6.904 299 16.58922 7.94164 C9H12O4

O O
H

H O
H

O O
H
O
O
O

4 235.13287 Theoretical 235.13391 1.0 4.428 107 16.60535 7.89097 C14H19O3

O O
H

H O
H

O O
H
O
O
O

5 365.23225 Theoretical 365.23038 -1.9 -5.132 168 16.62419 8.09176 C21H33O5

O O
H

H O
H

O O
H
O
O
O

6 407.24282 Theoretical 407.24361 0.8 1.960 245 16.60503 8.01965 C23H35O6

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
7 464.27686 Theoretical 464.27877 1.9 4.114 150 16.58788 7.95437 C26H40O7

O O
H

H O
H

O O
H
O
O
O

8 507.33163 Theoretical 507.33301 1.4 2.711 196 16.59913 8.16801 C29H47O7

O O
H

H O
H

O O
H
O
O
O

9 529.27959 Theoretical 529.27804 -1.6 -2.945 311 16.57458 7.86647 C30H41O8

O O
H

H O
H

O O
H
O
O
O
Item name: MENGKUDU 2, Component name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-one-3-O-β-D-xylopyranoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 375.25299 Theoretical 375.25232 -0.7 -1.772 206 16.73150 7.82461 C23H35O4

O O
H

H O
H

O O
H
O
O
O

2 435.31050 Theoretical 435.31113 0.6 1.444 274 16.69571 7.73327 C26H43O5

O O
H

H O
H

O O
H
O
O
O

3 447.34689 Theoretical 447.34579 -1.1 -2.449 240 16.73513 7.79570 C28H47O4

O O
H

H O
H

O O
H
O
O
O
Item name: MENGKUDU 2, Component name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-one-3-O-β-D-xylopyranoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 131.08553 Theoretical 131.08642 0.9 6.805 156 16.61731 7.48792 C10H11

O O
H

H O
H

O O
H
O
O
O

2 227.12779 Theoretical 227.12742 -0.4 -1.602 133 16.64528 7.24164 C12H19O4

O O
H

H O
H

O O
H
O
O
O

3 303.19547 Theoretical 303.19680 1.3 4.389 135 16.64126 7.34926 C19H27O3

O O
H

H O
H

O O
H
O
O
O

4 317.21112 Theoretical 317.21016 -1.0 -3.020 203 16.62261 7.27831 C20H29O3

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 351.21660 Theoretical 351.21490 -1.7 -4.833 315 16.60933 7.29514 C20H31O5

O O
H

H O
H

O O
H
O
O
O

6 361.23734 Theoretical 361.23608 -1.3 -3.473 198 16.65632 7.44717 C22H33O4

O O
H

H O
H

O O
H
O
O
O

7 409.25847 Theoretical 409.25707 -1.4 -3.415 148 16.63802 7.57280 C23H37O6

O O
H

H O
H

O O
H
O
O
O

8 411.32576 Theoretical 411.32563 -0.1 -0.307 149 16.63681 7.32907 C28H43O2

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
9 419.27920 Theoretical 419.27781 -1.4 -3.322 227 16.62821 7.44543 C25H39O5

O O
H

H O
H

O O
H
O
O
O

10 433.29485 Theoretical 433.29294 -1.9 -4.413 893 16.63354 7.21088 C26H41O5

O O
H

H O
H

O O
H
O
O
O

11 435.32576 Theoretical 435.32732 1.6 3.590 175 16.63451 7.45033 C30H43O2

O O
H

H O
H

O O
H
O
O
O

12 477.28468 Theoretical 477.28343 -1.2 -2.619 370 16.60944 7.46076 C27H41O7

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
13 507.33163 Theoretical 507.33161 0.0 -0.041 723 16.62752 7.26034 C29H47O7

O O
H

H O
H

O O
H
O
O
O

14 513.32107 Theoretical 513.32276 1.7 3.292 238 16.63259 7.32674 C31H45O6

O O
H

H O
H

O O
H
O
O
O

15 569.36841 Theoretical 569.36911 0.7 1.224 737 16.63987 7.16248 C31H53O9

O O
H

H O
H

O O
H
O
O
O

16 629.36841 Theoretical 629.36822 -0.2 -0.295 382 16.64689 7.33547 C36H53O9

O O
H

H O
H

O O
H
O
O
O
Item name: MENGKUDU 2, Component name: (3β,12β,16β)-12-Acetoxy-16,23-epoxy-9,19-cyclolanost-22-ene-24-one-3-O-β-D-xylopyranoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 79.05423 Theoretical 79.05429 0.1 0.753 155 13.67656 7.78372 C6H7

O O
H

H O
H

O O
H
O
O
O

2 117.06988 Theoretical 117.07096 1.1 9.247 91 13.65765 7.63351 C9H9

O O
H

H O
H

O O
H
O
O
O

3 147.11683 Theoretical 147.11766 0.8 5.680 97 13.66809 7.79896 C11H15

O O
H

H O
H

O O
H
O
O
O

4 157.10118 Theoretical 157.10201 0.8 5.325 172 13.67467 7.63484 C12H13

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 163.11174 Theoretical 163.11249 0.7 4.591 131 13.66499 7.71438 C11H15O

O O
H

H O
H

O O
H
O
O
O

6 165.09101 Theoretical 165.09014 -0.9 -5.229 127 13.65767 7.73614 C10H13O2

O O
H

H O
H

O O
H
O
O
O

7 171.11683 Theoretical 171.11690 0.1 0.412 174 13.70204 7.84662 C13H15

O O
H

H O
H

O O
H
O
O
O

8 173.13248 Theoretical 173.13253 0.1 0.309 147 13.65875 7.88754 C13H17

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
9 179.07027 Theoretical 179.07048 0.2 1.186 223 13.68310 7.82325 C10H11O3

O O
H

H O
H

O O
H
O
O
O

10 189.12739 Theoretical 189.12909 1.7 8.959 115 13.66378 7.66037 C13H17O

O O
H

H O
H

O O
H
O
O
O

11 247.16926 Theoretical 247.16811 -1.1 -4.618 135 13.65256 7.88275 C16H23O2

O O
H

H O
H

O O
H
O
O
O

12 293.21112 Theoretical 293.21279 1.7 5.685 361 13.68266 7.91454 C18H29O3

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
13 297.18491 Theoretical 297.18346 -1.4 -4.863 172 13.65821 7.99550 C20H25O2

O O
H

H O
H

O O
H
O
O
O

14 305.17474 Theoretical 305.17416 -0.6 -1.884 769 13.68605 7.76568 C18H25O4

O O
H

H O
H

O O
H
O
O
O

15 331.22677 Theoretical 331.22515 -1.6 -4.908 132 13.65553 7.65176 C21H31O3

O O
H

H O
H

O O
H
O
O
O

16 350.17239 Theoretical 350.17197 -0.4 -1.208 464 13.69785 7.76300 C19H26O6

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
17 351.21660 Theoretical 351.21548 -1.1 -3.201 9905 13.67943 7.89111 C20H31O5

O O
H

H O
H

O O
H
O
O
O

18 363.21660 Theoretical 363.21732 0.7 1.990 166 13.69895 7.71532 C21H31O5

O O
H

H O
H

O O
H
O
O
O

19 387.21660 Theoretical 387.21496 -1.6 -4.230 217 13.68998 7.58751 C23H31O5

O O
H

H O
H

O O
H
O
O
O

20 443.24282 Theoretical 443.24103 -1.8 -4.019 205 13.67129 7.91862 C26H35O6

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
21 445.25847 Theoretical 445.25986 1.4 3.135 150 13.67589 7.62434 C26H37O6

O O
H

H O
H

O O
H
O
O
O

22 451.24790 Theoretical 451.24835 0.4 0.990 1489 13.68859 7.93583 C28H35O5

O O
H

H O
H

O O
H
O
O
O

23 457.33124 Theoretical 457.33304 1.8 3.941 215 13.68257 7.83731 C29H45O4

O O
H

H O
H

O O
H
O
O
O

24 467.27920 Theoretical 467.27731 -1.9 -4.055 275 13.68515 7.62833 C29H39O5

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
25 469.33124 Theoretical 469.33173 0.5 1.046 220 13.68131 7.74086 C30H45O4

O O
H

H O
H

O O
H
O
O
O

26 481.29485 Theoretical 481.29501 0.2 0.339 205 13.66015 7.63896 C30H41O5

O O
H

H O
H

O O
H
O
O
O

27 487.34180 Theoretical 487.34232 0.5 1.064 530 13.70671 7.72026 C30H47O5

O O
H

H O
H

O O
H
O
O
O

28 537.28468 Theoretical 537.28502 0.3 0.629 242 13.70268 7.61565 C32H41O7

O O
H

H O
H

O O
H
O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
29 559.32654 Theoretical 559.32729 0.7 1.335 249 13.65958 7.73265 C32H47O8

O O
H

H O
H

O O
H
O
O
O

30 581.36841 Theoretical 581.36861 0.2 0.349 208 13.70194 7.60685 C32H53O9

O O
H

H O
H

O O
H
O
O
O

Item name: MENGKUDU 2, Component name: (E)-Aldosecologanin


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 139.03897 Theoretical 139.03886 -0.1 -0.766 88 11.00770 8.22509 C7H7O3
O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 181.04954 Theoretical 181.05037 0.8 4.634 185 11.01409 8.21759 C9H9O4
O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O

3 233.08084 Theoretical 233.08052 -0.3 -1.339 139 10.99323 7.91073 C13H13O4


O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O

4 299.05501 Theoretical 299.05614 1.1 3.752 128 10.96651 8.11419 C16H11O6


O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O

5 301.10705 Theoretical 301.10845 1.4 4.664 224 10.98892 7.91275 C17H17O5


O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
6 334.12583 Theoretical 334.12706 1.2 3.663 299 10.96350 8.16086 C14H22O9
O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O

7 349.16456 Theoretical 349.16359 -1.0 -2.788 144 10.97065 7.92475 C19H25O6


O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O

8 367.21152 Theoretical 367.20960 -1.9 -5.206 583 10.96801 7.88340 C20H31O6


O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O

9 369.22717 Theoretical 369.22695 -0.2 -0.586 155 10.98730 7.95757 C20H33O6


O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
10 407.17004 Theoretical 407.16831 -1.7 -4.250 200 11.02043 8.30105 C21H27O8
O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O

11 487.21739 Theoretical 487.21756 0.2 0.353 259 10.97417 8.27196 C23H35O11


O
O O
O
O O
O O
O

O O
O
O
O O

O
O
O

Item name: MENGKUDU 2, Component name: (rel 5S,6R,8R,9R,10S)-6-Acetoxy-9-hydroxy-13(14)-labden-16,15-olide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 167.07027 Theoretical 167.07128 1.0 6.058 306 12.78451 5.64723 C9H11O3
Chiral

O
O

O O

O
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 249.11214 Theoretical 249.11117 -1.0 -3.856 370 12.74583 5.36890 C14H17O4
Chiral

O
O

O O

O
H

Item name: MENGKUDU 2, Component name: 1,1,6-Trimethyl-1,2-dihydronaphthalene


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 117.06988 Theoretical 117.07063 0.8 6.430 108 13.67893 4.43505 C9H9

2 119.08553 Theoretical 119.08611 0.6 4.904 459 13.66120 4.65038 C9H11


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 145.10118 Theoretical 145.10243 1.3 8.654 888 13.67645 4.65113 C11H13

Item name: MENGKUDU 2, Component name: 1,1,6-Trimethyl-1,2-dihydronaphthalene


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 129.06988 Theoretical 129.06871 -1.2 -9.038 85 6.44728 3.11506 C10H9

2 131.08553 Theoretical 131.08614 0.6 4.679 100 6.45014 3.38020 C10H11


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 145.10118 Theoretical 145.10058 -0.6 -4.122 84 6.44761 3.52256 C11H13

Item name: MENGKUDU 2, Component name: 1,1,6-Trimethyl-1,2-dihydronaphthalene


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 105.06988 Theoretical 105.07074 0.9 8.221 141 13.68796 4.64132 C8H9

2 115.05423 Theoretical 115.05457 0.3 3.023 92 13.68733 4.85863 C9H7


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 117.06988 Theoretical 117.07063 0.8 6.430 108 13.67893 4.43505 C9H9

4 131.08553 Theoretical 131.08624 0.7 5.465 343 13.69172 4.59892 C10H11

5 133.10118 Theoretical 133.10169 0.5 3.891 356 13.68343 4.71028 C10H13

6 143.08553 Theoretical 143.08618 0.7 4.560 123 13.69732 4.49400 C11H11


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
7 145.10118 Theoretical 145.10243 1.3 8.654 888 13.67645 4.65113 C11H13

8 147.11683 Theoretical 147.11788 1.1 7.190 959 13.68500 4.70343 C11H15

9 159.11683 Theoretical 159.11701 0.2 1.176 684 13.69216 4.67748 C12H15


Item name: MENGKUDU 2, Component name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic methyl ester
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 91.05423 Theoretical 91.05544 1.2 13.325 206 1.46251 4.90030 C7H7
O

O O

2 107.04914 Theoretical 107.04947 0.3 3.111 94 1.43224 4.77878 C7H7O


O

O O

3 135.08044 Theoretical 135.08174 1.3 9.645 110 1.42625 4.73919 C9H11O


O

O O

4 149.05971 Theoretical 149.06160 1.9 12.704 340 1.44497 4.80357 C9H9O2


O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 151.07536 Theoretical 151.07594 0.6 3.862 166 1.47355 4.97219 C9H11O2
O

O O

6 179.07027 Theoretical 179.07143 1.2 6.470 373 1.45339 4.80437 C10H11O3


O

O O

Item name: MENGKUDU 2, Component name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic methyl ester


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 121.06479 Theoretical 121.06574 0.9 7.809 179 1.44062 5.53686 C8H9O
O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 133.06479 Theoretical 133.06537 0.6 4.325 537 1.41909 5.18643 C9H9O
O

O O

3 179.07027 Theoretical 179.07157 1.3 7.232 762 1.44236 5.45194 C10H11O3


O

O O

Item name: MENGKUDU 2, Component name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic methyl ester


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 133.06479 Theoretical 133.06495 0.2 1.178 494 0.85886 6.34736 C9H9O
O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 149.05971 Theoretical 149.06064 0.9 6.296 444 0.87847 6.30174 C9H9O2
O

O O

Item name: MENGKUDU 2, Component name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic methyl ester


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 91.05423 Theoretical 91.05440 0.2 1.939 157 1.62367 6.41625 C7H7
O

O O

2 93.06988 Theoretical 93.07112 1.2 13.375 177 1.65312 6.24069 C7H9


O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 131.04914 Theoretical 131.05100 1.9 14.212 361 1.67023 6.35405 C9H7O
O

O O

Item name: MENGKUDU 2, Component name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic methyl ester


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 161.05971 Theoretical 161.06038 0.7 4.163 97 1.70249 6.12272 C10H9O2
O

O O

Item name: MENGKUDU 2, Component name: 1,4α,5,7α-Tetrahydro-7-hydroxyl-cyclopenta [c]pyran-4-carboxylic methyl ester


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 77.03858 Theoretical 77.03868 0.1 1.337 385 0.95037 4.14518 C6H5
O

O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 133.06479 Theoretical 133.06582 1.0 7.718 155 0.92604 4.39267 C9H9O
O

O O

3 149.05971 Theoretical 149.06056 0.9 5.719 196 0.93434 4.27725 C9H9O2


O

O O

4 163.07536 Theoretical 163.07370 -1.7 -10.172 132 0.92957 4.15994 C10H11O2


O

O O

5 179.07027 Theoretical 179.07162 1.3 7.516 326 0.93802 4.47124 C10H11O3


O

O O
Item name: MENGKUDU 2, Component name: 10-O-Acetylgeniposidic acid
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 246.03702 Theoretical 246.03718 0.2 0.639 131 0.59451 6.65581 C9H10O8

O O
H

O
O
H
O O O
O O
O
O

2 280.09414 Theoretical 280.09405 -0.1 -0.336 124 0.60695 6.78237 C14H16O6

O O
H

O
O
H
O O O
O O
O
O

3 361.11292 Theoretical 361.11160 -1.3 -3.666 446 0.61419 6.78740 C15H21O10

O O
H

O
O
H
O O O
O
O
O
O
Item name: MENGKUDU 2, Component name: 10-O-Acetylgeniposidic acid
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 321.11801 Theoretical 321.11729 -0.7 -2.248 2896 0.59493 7.40883 C13H21O9

O O
H

O
O
H
O O O
O O
O
O

2 361.11292 Theoretical 361.11160 -1.3 -3.676 396 0.61071 7.21604 C15H21O10

O O
H

O
O
H
O O O
O O
O
O

Item name: MENGKUDU 2, Component name: 11-O-p-Coumarylnepeticin


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 283.26316 Theoretical 283.26507 1.9 6.770 142 16.90495 7.37875 C18H35O2

O
H
O
H

H
O
H
Item name: MENGKUDU 2, Component name: 11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 119.08553 Theoretical 119.08595 0.4 3.551 144 8.05317 7.15663 C9H11
Chi ral

O O
O

2 175.03897 Theoretical 175.04052 1.5 8.852 1602 8.08880 7.16086 C10H7O3


Chi ral

O O
O

3 179.07027 Theoretical 179.07191 1.6 9.146 162 8.08467 6.80818 C10H11O3


Chi ral

O O
O

4 209.15361 Theoretical 209.15434 0.7 3.518 103 8.08853 7.09156 C13H21O2


Chi ral

O O
O

O
Item name: MENGKUDU 2, Component name: 11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 177.05462 Theoretical 177.05428 -0.3 -1.920 499 8.06015 7.65457 C10H9O3
Chi ral

O O
O

2 421.31011 Theoretical 421.31004 -0.1 -0.159 149 8.06822 7.52718 C29H41O2


Chi ral

O O
O

3 467.31559 Theoretical 467.31655 1.0 2.067 291 8.06524 7.80622 C30H43O4


Chi ral

O O
O

4 485.32615 Theoretical 485.32730 1.1 2.367 298 8.07417 7.90556 C30H45O5


Chi ral

O O
O

O
Item name: MENGKUDU 2, Component name: 11α,12α-Epoxy-23β,23-dihydroxyolean-28,13β-olide
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 135.11683 Theoretical 135.11731 0.5 3.543 97 7.98524 7.27315 C10H15
Chi ral

O O
O

2 211.16926 Theoretical 211.17002 0.8 3.623 97 7.95720 7.37770 C13H23O2


Chi ral

O O
O

3 428.21934 Theoretical 428.22092 1.6 3.700 189 7.96943 7.65756 C25H32O6


Chi ral

O O
O

4 437.30502 Theoretical 437.30428 -0.7 -1.689 163 7.99520 7.42761 C29H41O3


Chi ral

O O
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 485.32615 Theoretical 485.32671 0.6 1.143 261 7.97610 7.56379 C30H45O5
Chi ral

O O
O

Item name: MENGKUDU 2, Component name: 11β,13-Dihydrocostunolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 105.06988 Theoretical 105.07095 1.1 10.202 80 16.51149 4.67243 C8H9

H
O
O

2 131.08553 Theoretical 131.08648 1.0 7.267 106 16.52479 4.56499 C10H11

H
O
O

H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 145.10118 Theoretical 145.10191 0.7 5.022 383 16.52619 4.59947 C11H13

H
O
O

4 159.11683 Theoretical 159.11808 1.2 7.855 373 16.51110 4.76393 C12H15

H
O
O

5 173.13248 Theoretical 173.13387 1.4 8.053 298 16.51395 4.52799 C13H17

H
O
O

6 179.10666 Theoretical 179.10566 -1.0 -5.557 99 16.50653 4.64368 C11H15O2

H
O
O

H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
7 191.10666 Theoretical 191.10781 1.2 6.020 118 16.51988 4.72279 C12H15O2

H
O
O

Item name: MENGKUDU 2, Component name: 12-Hydroxyhydromethyl abietate


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 306.25533 Theoretical 306.25513 -0.2 -0.668 172 16.65847 5.18971 C20H34O2
Chiral

O O

Item name: MENGKUDU 2, Component name: 12-Hydroxy-methyl abietate


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 291.23186 Theoretical 291.23041 -1.5 -4.984 547 16.69668 5.03666 C19H31O2
Chiral

O O
Item name: MENGKUDU 2, Component name: 12S-Hydroxyandrographolide
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 147.04406 Theoretical 147.04304 -1.0 -6.903 212 10.32177 5.55228 C9H7O2 Chiral

O O

H
O

2 209.08084 Theoretical 209.08117 0.3 1.594 129 10.34718 5.40924 C11H13O4 Chiral

O O

H
O

Item name: MENGKUDU 2, Component name: 12S-Hydroxyandrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 131.08553 Theoretical 131.08562 0.1 0.723 122 10.75972 5.16533 C10H11 Chiral

O O

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 235.09649 Theoretical 235.09703 0.5 2.310 190 10.74714 5.36460 C13H15O4 Chiral

O O

H
O

3 282.10979 Theoretical 282.11090 1.1 3.937 586 10.73999 5.14707 C14H18O6 Chiral

O O

H
O

4 319.15400 Theoretical 319.15489 0.9 2.799 151 10.74446 5.23817 C18H23O5 Chiral

O O

H
O

O
Item name: MENGKUDU 2, Component name: 12S-Hydroxyandrographolide
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 159.11683 Theoretical 159.11684 0.0 0.065 140 11.41342 5.36725 C12H15 Chiral

O O

H
O

2 163.03897 Theoretical 163.04055 1.6 9.704 239 11.43863 5.41771 C9H7O3 Chiral

O O

H
O

3 177.05462 Theoretical 177.05553 0.9 5.131 433 11.42075 5.36405 C10H9O3 Chiral

O O

H
O

O
Item name: MENGKUDU 2, Component name: 12S-Hydroxyandrographolide
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 91.05423 Theoretical 91.05518 0.9 10.420 153 12.48106 5.59493 C7H7 Chiral

O O

H
O

2 117.06988 Theoretical 117.07158 1.7 14.565 158 12.48741 5.72227 C9H9 Chiral

O O

H
O

3 193.08592 Theoretical 193.08610 0.2 0.944 136 12.50136 5.34236 C11H13O3 Chiral

O O

H
O

4 213.16378 Theoretical 213.16399 0.2 1.005 97 12.50418 5.60944 C16H21 Chiral

O O

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 235.09649 Theoretical 235.09751 1.0 4.364 173 12.49085 5.40124 C13H15O4 Chiral

O O

H
O

Item name: MENGKUDU 2, Component name: 12-α-Hydroxyevodol


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 149.05971 Theoretical 149.05956 -0.1 -0.950 104 10.23993 5.70760 C9H9O2
Chiral

O O O

O
H O
O O
O

2 167.07027 Theoretical 167.06916 -1.1 -6.651 98 10.22465 5.91763 C9H11O3


Chiral

O O O

O
H O
O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 277.10705 Theoretical 277.10772 0.7 2.412 387 10.26596 5.96348 C15H17O5
Chiral

O O O

O
H O
O O
O

4 323.14891 Theoretical 323.14906 0.1 0.440 227 10.27553 5.66650 C17H23O6


Chiral

O O O

O
H O
O O
O

5 406.16222 Theoretical 406.16382 1.6 3.945 205 10.26022 5.97739 C21H26O8


Chiral

O O O

O
H O
O O
O

6 415.13874 Theoretical 415.13802 -0.7 -1.736 175 10.27765 6.02004 C22H23O8


Chiral

O O O

O
H O
O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
7 469.14931 Theoretical 469.15023 0.9 1.970 220 10.25246 5.83023 C25H25O9
Chiral

O O O

O
H O
O O
O

Item name: MENGKUDU 2, Component name: 12-α-Hydroxyevodol


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 175.03897 Theoretical 175.03985 0.9 5.004 94 10.25825 8.03369 C10H7O3
Chiral

O O O

O
H O
O O
O

2 369.09688 Theoretical 369.09760 0.7 1.953 1239 10.25267 8.05678 C20H17O7


Chiral

O O O

O
H O
O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 380.12544 Theoretical 380.12605 0.6 1.611 360 10.26188 8.02291 C22H20O6
Chiral

O O O

O
H O
O O
O

Item name: MENGKUDU 2, Component name: 12-α-Hydroxyevodol


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 193.08592 Theoretical 193.08573 -0.2 -0.963 164 11.09902 6.72794 C11H13O3
Chiral

O O O

O
H O
O O
O

2 205.04954 Theoretical 205.05093 1.4 6.804 366 11.08642 6.77911 C11H9O4


Chiral

O O O

O
H O
O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 209.08084 Theoretical 209.07978 -1.1 -5.063 96 11.08955 6.66463 C11H13O4
Chiral

O O O

O
H O
O O
O

4 233.08084 Theoretical 233.08113 0.3 1.242 125 11.07607 6.71553 C13H13O4


Chiral

O O O

O
H O
O O
O

5 294.10979 Theoretical 294.11150 1.7 5.815 279 11.10025 7.08470 C15H18O6


Chiral

O O O

O
H O
O O
O

6 303.12270 Theoretical 303.12454 1.8 6.064 142 11.07705 6.95383 C17H19O5


Chiral

O O O

O
H O
O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
7 346.14109 Theoretical 346.14210 1.0 2.910 142 11.05635 7.01237 C19H22O6
Chiral

O O O

O
H O
O O
O

8 420.12035 Theoretical 420.12218 1.8 4.351 149 11.07612 7.10927 C24H20O7


Chiral

O O O

O
H O
O O
O

9 436.15165 Theoretical 436.15223 0.6 1.312 137 11.05873 7.09922 C25H24O7


Chiral

O O O

O
H O
O O
O
Item name: MENGKUDU 2, Component name: 12-α-Hydroxyevodol
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 203.03389 Theoretical 203.03473 0.8 4.160 138 7.58206 6.48882 C11H7O4
Chiral

O O O

O
H O
O O
O

2 229.04954 Theoretical 229.05057 1.0 4.510 233 7.57879 6.40590 C13H9O4


Chiral

O O O

O
H O
O O
O

3 235.06010 Theoretical 235.06031 0.2 0.892 385 7.59341 6.09823 C12H11O5


Chiral

O O O

O
H O
O O
O

4 334.10470 Theoretical 334.10322 -1.5 -4.457 120 7.54967 6.38309 C17H18O7


Chiral

O O O

O
H O
O O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 370.06832 Theoretical 370.06767 -0.6 -1.756 137 7.58422 6.35166 C19H14O8
Chiral

O O O

O
H O
O O
O

6 418.16222 Theoretical 418.16025 -2.0 -4.700 363 7.54818 6.23273 C22H26O8


Chiral

O O O

O
H O
O O
O

Item name: MENGKUDU 2, Component name: 14-Acetoxy-7β-(3-ethyl-cis-crotonoyloxy)-1α-(2-methylbutyryloxy)-notonipetranone


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 91.05423 Theoretical 91.05463 0.4 4.396 323 16.54054 6.02347 C7H7

O
H O
O
O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 95.08553 Theoretical 95.08623 0.7 7.350 172 16.53704 6.24235 C7H11

O
H O
O
O
O
O
H O
H
H

3 105.06988 Theoretical 105.07036 0.5 4.558 733 16.51235 6.30983 C8H9

O
H O
O
O
O
O
H O
H
H

4 121.10118 Theoretical 121.10189 0.7 5.896 238 16.51305 6.00044 C9H13

O
H O
O
O
O
O
H O
H
H

5 125.09609 Theoretical 125.09599 -0.1 -0.847 76 16.53415 6.28274 C8H13O

H O
O O

O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
6 133.10118 Theoretical 133.10219 1.0 7.595 298 16.51107 6.30479 C10H13

O
H O
O
O
O
O
H O
H
H

7 135.08044 Theoretical 135.08086 0.4 3.081 119 16.49611 6.10994 C9H11O

O
H O
O
O
O
O
H O
H
H

8 149.02332 Theoretical 149.02448 1.2 7.789 177 16.51476 6.30738 C8H5O3

O
H O
O
O
O
O
H O
H
H

9 151.07536 Theoretical 151.07503 -0.3 -2.180 173 16.51782 6.08687 C9H11O2

H O
O O

O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
10 159.08044 Theoretical 159.07971 -0.7 -4.593 146 16.52580 6.34437 C11H11O

O
H O
O
O
O
O
H O
H
H

11 161.05971 Theoretical 161.05843 -1.3 -7.905 93 16.54272 6.30738 C10H9O2

O
H O
O
O
O
O
H O
H
H

12 163.11174 Theoretical 163.11199 0.2 1.497 179 16.50310 6.18445 C11H15O

O
H O
O
O
O
O
H O
H
H

13 165.01824 Theoretical 165.01913 0.9 5.419 113 16.53762 6.15855 C8H5O4

H O
O O

O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
14 167.10666 Theoretical 167.10686 0.2 1.223 107 16.54039 6.06734 C10H15O2

O
H O
O
O
O
O
H O
H
H

15 173.09609 Theoretical 173.09601 -0.1 -0.500 233 16.49449 6.02390 C12H13O

O
H O
O
O
O
O
H O
H
H

16 173.13248 Theoretical 173.13388 1.4 8.093 703 16.49618 6.21661 C13H17

O
H O
O
O
O
O
H O
H
H

17 175.14813 Theoretical 175.14762 -0.5 -2.912 181 16.49552 6.39389 C13H19

H O
O O

O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
18 179.14304 Theoretical 179.14311 0.1 0.369 85 16.53495 6.33069 C12H19O

O
H O
O
O
O
O
H O
H
H

19 191.07027 Theoretical 191.06866 -1.6 -8.428 108 16.54443 6.10220 C11H11O3

O
H O
O
O
O
O
H O
H
H

20 193.12231 Theoretical 193.12331 1.0 5.223 261 16.51315 6.30154 C12H17O2

O
H O
O
O
O
O
H O
H
H

21 199.11174 Theoretical 199.11239 0.7 3.278 166 16.50421 6.12473 C14H15O

H O
O O

O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
22 201.12739 Theoretical 201.12808 0.7 3.404 285 16.52605 5.96556 C14H17O

O
H O
O
O
O
O
H O
H
H

23 205.15869 Theoretical 205.16043 1.7 8.483 170 16.51227 6.30026 C14H21O

O
H O
O
O
O
O
H O
H
H

24 208.07301 Theoretical 208.07300 0.0 -0.039 127 16.52674 6.29391 C11H12O4

O
H O
O
O
O
O
H O
H
H

25 219.13796 Theoretical 219.13634 -1.6 -7.364 139 16.54401 6.30341 C14H19O2

H O
O O

O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
26 219.17434 Theoretical 219.17420 -0.1 -0.668 168 16.49925 5.94804 C15H23O

O
H O
O
O
O
O
H O
H
H

27 221.15361 Theoretical 221.15549 1.9 8.501 268 16.52955 6.30733 C14H21O2

O
H O
O
O
O
O
H O
H
H

28 231.13796 Theoretical 231.13842 0.5 1.987 143 16.52534 6.13060 C15H19O2

O
H O
O
O
O
O
H O
H
H

29 235.16926 Theoretical 235.16858 -0.7 -2.878 235 16.50911 5.97096 C15H23O2

H O
O O

O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
30 245.15361 Theoretical 245.15292 -0.7 -2.784 124 16.49808 6.00980 C16H21O2

O
H O
O
O
O
O
H O
H
H

31 247.16926 Theoretical 247.16856 -0.7 -2.805 108 16.50819 6.19351 C16H23O2

O
H O
O
O
O
O
H O
H
H

32 265.14344 Theoretical 265.14259 -0.8 -3.174 355 16.53673 6.22400 C15H21O4

O
H O
O
O
O
O
H O
H
H

33 267.12270 Theoretical 267.12282 0.1 0.457 162 16.49273 6.18181 C14H19O5

H O
O O

O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
34 271.16926 Theoretical 271.17045 1.2 4.414 207 16.51516 5.94619 C18H23O2

O
H O
O
O
O
O
H O
H
H

35 275.20056 Theoretical 275.20129 0.7 2.668 587 16.51002 6.11996 C18H27O2

O
H O
O
O
O
O
H O
H
H

36 277.21621 Theoretical 277.21425 -2.0 -7.068 360 16.51900 5.98256 C18H29O2

O
H O
O
O
O
O
H O
H
H

37 293.21112 Theoretical 293.21137 0.3 0.861 520 16.50274 6.02929 C18H29O3

H O
O O

O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
38 333.20604 Theoretical 333.20549 -0.5 -1.645 1013 16.53755 6.31948 C20H29O4

O
H O
O
O
O
O
H O
H
H

39 335.22169 Theoretical 335.22341 1.7 5.137 524 16.54390 5.94754 C20H31O4

O
H O
O
O
O
O
H O
H
H

40 351.21660 Theoretical 351.21535 -1.3 -3.574 554 16.53207 6.23845 C20H31O5

O
H O
O
O
O
O
H O
H
H

41 389.15948 Theoretical 389.15838 -1.1 -2.826 192 16.51681 5.98845 C21H25O7

H O
O O

O
O
O
H O
H
H
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
42 449.28977 Theoretical 449.28896 -0.8 -1.792 847 16.49611 6.28042 C26H41O6

O
H O
O
O
O
O
H O
H
H

Item name: MENGKUDU 2, Component name: 14-Acetoxy-7β-senecioyloxy-notonipetranone


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 131.04914 Theoretical 131.05087 1.7 13.179 213 13.77855 5.51260 C9H7O

H
O
O
O
H O
H
H
O

2 167.07027 Theoretical 167.07046 0.2 1.117 293 13.80431 5.66793 C9H11O3

H
O
O
O
H H O

H
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 235.09649 Theoretical 235.09741 0.9 3.950 157 13.76722 5.23232 C13H15O4

H
O
O
O
H O
H
H
O

4 309.16965 Theoretical 309.16994 0.3 0.945 155 13.79643 5.29080 C17H25O5

H
O
O
O
H H O

H
O

Item name: MENGKUDU 2, Component name: 14-Deoxy-11-hydro-xyandrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 121.10118 Theoretical 121.10160 0.4 3.528 73 13.96284 5.36950 C9H13 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 299.22169 Theoretical 299.22103 -0.7 -2.181 391 13.93427 5.24095 C17H31O4 Chiral

H
O

Item name: MENGKUDU 2, Component name: 14-Deoxy-11-hydro-xyandrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 177.12739 Theoretical 177.12794 0.6 3.122 128 13.66968 5.28926 C12H17O Chiral

H
O

2 215.17943 Theoretical 215.18015 0.7 3.366 110 13.66531 5.28797 C16H23 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 281.13835 Theoretical 281.13706 -1.3 -4.572 360 13.67522 5.24206 C15H21O5 Chiral

H
O

4 299.22169 Theoretical 299.22158 -0.1 -0.340 2712 13.68220 5.22665 C17H31O4 Chiral

H
O

5 301.21621 Theoretical 301.21663 0.4 1.399 125 13.70119 5.11472 C20H29O2 Chiral

H
O

O
Item name: MENGKUDU 2, Component name: 14-Deoxy-11-hydro-xyandrographolide
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 119.08553 Theoretical 119.08640 0.9 7.315 138 13.55177 5.08750 C9H11 Chiral

H
O

2 173.13248 Theoretical 173.13342 0.9 5.437 133 13.54385 5.37699 C13H17 Chiral

H
O

3 199.07536 Theoretical 199.07351 -1.8 -9.255 130 13.54646 5.49569 C13H11O2 Chiral

H
O

O
Item name: MENGKUDU 2, Component name: 14-Deoxy-11-oxoandrographolide
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 287.20056 Theoretical 287.19961 -1.0 -3.308 122 12.94049 5.16779 C19H27O2 Chiral

H
O

Item name: MENGKUDU 2, Component name: 14-Deoxy-12R-hydroxyandrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 163.11174 Theoretical 163.11266 0.9 5.606 144 13.71074 5.35034 C11H15O Chiral

H
O

2 177.12739 Theoretical 177.12794 0.6 3.122 128 13.66968 5.28926 C12H17O Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 215.17943 Theoretical 215.18015 0.7 3.366 110 13.66531 5.28797 C16H23 Chiral

H
O

4 281.13835 Theoretical 281.13706 -1.3 -4.572 360 13.67522 5.24206 C15H21O5 Chiral

H
O

5 299.22169 Theoretical 299.22158 -0.1 -0.340 2712 13.68220 5.22665 C17H31O4 Chiral

H
O

6 301.21621 Theoretical 301.21663 0.4 1.399 125 13.70119 5.11472 C20H29O2 Chiral

H
O

O
Item name: MENGKUDU 2, Component name: 14-Deoxy-12R-hydroxyandrographolide
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 177.12739 Theoretical 177.12794 0.6 3.122 128 13.66968 5.28926 C12H17O Chiral

H
O

2 215.17943 Theoretical 215.18015 0.7 3.366 110 13.66531 5.28797 C16H23 Chiral

H
O

3 281.13835 Theoretical 281.13706 -1.3 -4.572 360 13.67522 5.24206 C15H21O5 Chiral

H
O

4 299.22169 Theoretical 299.22158 -0.1 -0.340 2712 13.68220 5.22665 C17H31O4 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 301.21621 Theoretical 301.21663 0.4 1.399 125 13.70119 5.11472 C20H29O2 Chiral

H
O

Item name: MENGKUDU 2, Component name: 14-Deoxy-12R-hydroxyandrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 119.08553 Theoretical 119.08640 0.9 7.314 138 13.55177 5.08750 C9H11 Chiral

H
O

2 173.13248 Theoretical 173.13342 0.9 5.437 133 13.54385 5.37699 C13H17 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 199.07536 Theoretical 199.07351 -1.8 -9.255 130 13.54646 5.49569 C13H11O2 Chiral

H
O

Item name: MENGKUDU 2, Component name: 14-Deoxy-12R-hydroxyandrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 121.10118 Theoretical 121.10160 0.4 3.528 73 13.96284 5.36950 C9H13 Chiral

H
O

2 299.22169 Theoretical 299.22103 -0.7 -2.181 391 13.93427 5.24095 C17H31O4 Chiral

H
O

O
Item name: MENGKUDU 2, Component name: 14-Deoxy-12S-methoxyandrographolide
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 91.05423 Theoretical 91.05438 0.2 1.717 597 16.49205 5.61253 C7H7 Chiral

H
O

2 107.08553 Theoretical 107.08596 0.4 4.046 183 16.51117 5.49614 C8H11 Chiral

H
O

3 130.07770 Theoretical 130.07702 -0.7 -5.264 127 16.51493 5.41342 C10H10 Chiral

H
O

4 147.11683 Theoretical 147.11795 1.1 7.637 358 16.52124 5.65198 C11H15 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 157.10118 Theoretical 157.10208 0.9 5.724 453 16.51946 5.70991 C12H13 Chiral

H
O

6 165.09101 Theoretical 165.09138 0.4 2.280 152 16.51134 5.54409 C10H13O2 Chiral

H
O

7 177.12739 Theoretical 177.12654 -0.8 -4.796 134 16.49536 5.49082 C12H17O Chiral

H
O

8 187.14813 Theoretical 187.14950 1.4 7.314 180 16.47666 5.58733 C14H19 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
9 199.14813 Theoretical 199.14927 1.1 5.744 416 16.49802 5.59783 C15H19 Chiral

H
O

10 207.13796 Theoretical 207.13742 -0.5 -2.597 153 16.51026 5.35584 C13H19O2 Chiral

H
O

11 243.17434 Theoretical 243.17546 1.1 4.587 99 16.51173 5.71526 C17H23O Chiral

H
O

12 257.18999 Theoretical 257.19167 1.7 6.529 387 16.52093 5.53670 C18H25O Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
13 283.20564 Theoretical 283.20683 1.2 4.191 149 16.51919 5.39906 C20H27O Chiral

H
O

14 293.21112 Theoretical 293.21084 -0.3 -0.965 251 16.52006 5.42778 C18H29O3 Chiral

H
O

Item name: MENGKUDU 2, Component name: 14-Deoxy-12S-methoxyandrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 105.06988 Theoretical 105.07024 0.4 3.486 193 16.55187 5.41070 C8H9 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 123.08044 Theoretical 123.08039 0.0 -0.381 137 16.59619 5.45003 C8H11O Chiral

H
O

3 137.09609 Theoretical 137.09622 0.1 0.971 85 16.58972 5.60429 C9H13O Chiral

H
O

4 145.10118 Theoretical 145.10197 0.8 5.466 637 16.55409 5.61718 C11H13 Chiral

H
O

5 147.08044 Theoretical 147.08185 1.4 9.583 77 16.55810 5.15552 C10H11O Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
6 149.13248 Theoretical 149.13361 1.1 7.599 140 16.58685 5.60456 C11H17 Chiral

H
O

7 163.07536 Theoretical 163.07677 1.4 8.682 97 16.57752 5.37644 C10H11O2 Chiral

H
O

8 171.11683 Theoretical 171.11797 1.1 6.692 189 16.57744 5.61341 C13H15 Chiral

H
O

9 175.11174 Theoretical 175.11171 0.0 -0.156 231 16.55322 5.47511 C12H15O Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
10 205.12231 Theoretical 205.12062 -1.7 -8.226 114 16.56641 5.50054 C13H17O2 Chiral

H
O

11 249.18491 Theoretical 249.18550 0.6 2.365 157 16.58743 5.49938 C16H25O2 Chiral

H
O

12 295.22677 Theoretical 295.22499 -1.8 -6.025 141 16.59563 5.49361 C18H31O3 Chiral

H
O

13 333.20604 Theoretical 333.20540 -0.6 -1.912 5114 16.55146 5.23106 C20H29O4 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
14 337.23734 Theoretical 337.23708 -0.3 -0.760 1940 16.60187 5.46440 C20H33O4 Chiral

H
O

Item name: MENGKUDU 2, Component name: 14-Deoxy-12S-methoxyandrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 187.14813 Theoretical 187.14916 1.0 5.511 90 16.63473 5.24129 C14H19 Chiral

H
O

2 235.13287 Theoretical 235.13397 1.1 4.656 124 16.60486 5.47336 C14H19O3 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
3 293.13835 Theoretical 293.13981 1.5 4.981 125 16.60637 5.32621 C16H21O5 Chiral

H
O

4 307.22677 Theoretical 307.22624 -0.5 -1.743 248 16.64609 5.50266 C19H31O3 Chiral

H
O

5 315.19547 Theoretical 315.19447 -1.0 -3.173 322 16.65187 5.42537 C20H27O3 Chiral

H
O

6 323.18530 Theoretical 323.18598 0.7 2.087 125 16.63878 5.24347 C18H27O5 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
7 337.23734 Theoretical 337.23708 -0.3 -0.760 1940 16.60187 5.46440 C20H33O4 Chiral

H
O

Item name: MENGKUDU 2, Component name: 14-Deoxy-17β-hydroxyandrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 175.07536 Theoretical 175.07606 0.7 4.010 102 12.84663 5.56129 C11H11O2 Chiral

O O

O
H
O

Item name: MENGKUDU 2, Component name: 14-Deoxyandrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 291.23186 Theoretical 291.23041 -1.5 -4.984 547 16.69668 5.03666 C19H31O2 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 307.22677 Theoretical 307.22624 -0.5 -1.743 248 16.64609 5.50266 C19H31O3 Chiral

H
O

Item name: MENGKUDU 2, Component name: 14-epi-Andrographolide


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 117.03349 Theoretical 117.03354 0.0 0.399 102 13.23231 4.98463 C8H5O Chiral

O O

H
O

2 279.15909 Theoretical 279.15899 -0.1 -0.331 423 13.25162 5.35521 C16H23O4 Chiral

O O

H
O

O
Item name: MENGKUDU 2, Component name: 19β-Glucosyl-14-deoxy-11,12-didehydroand-rographoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 105.06988 Theoretical 105.07024 0.4 3.486 193 16.55187 5.41070 C8H9 Chiral

H
O

2 133.10118 Theoretical 133.10200 0.8 6.219 390 16.54062 5.24951 C10H13 Chiral

H
O

3 147.08044 Theoretical 147.08185 1.4 9.583 77 16.55810 5.15552 C10H11O Chiral

H
O

4 162.06753 Theoretical 162.06737 -0.2 -1.003 87 16.52802 5.43457 C10H10O2 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 163.07536 Theoretical 163.07677 1.4 8.682 97 16.57752 5.37644 C10H11O2 Chiral

H
O

6 165.12739 Theoretical 165.12819 0.8 4.834 119 16.52849 5.33546 C11H17O Chiral

H
O

7 173.13248 Theoretical 173.13362 1.1 6.612 186 16.52938 5.02853 C13H17 Chiral

H
O

8 175.14813 Theoretical 175.14683 -1.3 -7.422 144 16.53336 5.43506 C13H19 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
9 183.11683 Theoretical 183.11840 1.6 8.591 271 16.55749 5.16729 C14H15 Chiral

H
O

10 187.11174 Theoretical 187.11258 0.8 4.458 126 16.52936 5.11586 C13H15O Chiral

H
O

11 193.12231 Theoretical 193.12299 0.7 3.563 193 16.53844 5.35665 C12H17O2 Chiral

H
O

12 197.13248 Theoretical 197.13383 1.4 6.857 299 16.53872 5.08716 C15H17 Chiral

H
O

O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
13 199.14813 Theoretical 199.14925 1.1 5.647 272 16.54600 5.07743 C15H19 Chiral

H
O

14 293.21112 Theoretical 293.20984 -1.3 -4.353 231 16.54669 4.98053 C18H29O3 Chiral

H
O

15 303.23186 Theoretical 303.23286 1.0 3.318 411 16.55163 5.02527 C20H31O2 Chiral

H
O

O
Item name: MENGKUDU 2, Component name: 19β-Glucosyl-14-deoxyandrographoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 205.12231 Theoretical 205.12382 1.5 7.359 106 14.95273 6.68825 C13H17O2
O
O

H
O
O
O O

O
O
O

Item name: MENGKUDU 2, Component name: 19β-Glucosyl-14-deoxyandrographoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 131.04914 Theoretical 131.05052 1.4 10.555 174 14.96989 6.18032 C9H7O
O
O

H
O
O
O O

O
O
O

2 175.07536 Theoretical 175.07711 1.8 10.016 108 14.93133 6.14929 C11H11O2


O
O

H
O
O
O O

O
O
O
Item name: MENGKUDU 2, Component name: 19β-Glucosylandrographoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 117.06988 Theoretical 117.07027 0.4 3.384 103 12.65868 6.52422 C9H9
O
O O

H
O O

O O

O
O
O

2 131.08553 Theoretical 131.08565 0.1 0.925 129 12.65776 6.71354 C10H11


O
O O

H
O O

O O

O
O
O

3 147.04406 Theoretical 147.04567 1.6 10.971 299 12.68962 6.74990 C9H7O2


O
O O

H
O O

O O

O
O
O

4 199.14813 Theoretical 199.14772 -0.4 -2.031 115 12.67948 6.44530 C15H19


O
O O

H
O O

O O

O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 418.16222 Theoretical 418.16131 -0.9 -2.168 215 12.66568 6.39424 C22H26O8
O
O O

H
O O

O O

O
O
O

Item name: MENGKUDU 2, Component name: 19β-Glucosylandrographoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 275.20056 Theoretical 275.20206 1.5 5.469 126 12.48132 6.63242 C18H27O2
O
O O

H
O O

O O

O
O
O

2 432.19900 Theoretical 432.19801 -1.0 -2.295 210 12.48125 6.54901 C20H32O10


O
O O

H
O O

O O

O
O
O
Item name: MENGKUDU 2, Component name: 19β-Glucosylandrographoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 189.09101 Theoretical 189.08943 -1.6 -8.349 90 14.35336 6.46708 C12H13O2
O
O O

H
O O

O O

O
O
O

2 409.14931 Theoretical 409.15118 1.9 4.582 281 14.36938 6.48742 C20H25O9


O
O O

H
O O

O O

O
O
O

Item name: MENGKUDU 2, Component name: 19β-Glucosylandrographoside


Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 137.05971 Theoretical 137.05982 0.1 0.806 143 12.77009 6.23148 C8H9O2
O
O O

H
O O

O O

O
O
O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
2 167.07027 Theoretical 167.07145 1.2 7.076 155 12.78309 6.35794 C9H11O3
O
O O

H
O O

O O

O
O
O

3 183.11683 Theoretical 183.11789 1.1 5.781 154 12.74724 6.68899 C14H15


O
O O

H
O O

O O

O
O
O

4 185.13248 Theoretical 185.13246 0.0 -0.075 87 12.76719 6.29925 C14H17


O
O O

H
O O

O O

O
O
O

5 214.08358 Theoretical 214.08284 -0.7 -3.416 104 12.77576 6.40540 C10H14O5


O
O O

H
O O

O O

O
O
O
Item name: MENGKUDU 2, Component name: 1α,2α,3β,19α,23-Pentadroxyurs-12-en-28-oic acid-28-O-β-D-xylopyranoside
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
1 103.05423 Theoretical 103.05400 -0.2 -2.238 85 16.49667 7.53208 C8H7

O O
O
O O
O
O
O H
O O

2 109.06479 Theoretical 109.06445 -0.3 -3.132 102 16.50950 7.70428 C7H9O

O O
O
O O
O
O
O H
O O

3 135.11683 Theoretical 135.11741 0.6 4.321 101 16.47986 7.70289 C10H15

O O
O
O O
O
O
O H
O O

4 137.09609 Theoretical 137.09592 -0.2 -1.257 109 16.49658 7.34836 C9H13O

O O
O
O O
O
O
O H
O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
5 149.09609 Theoretical 149.09727 1.2 7.884 90 16.47918 7.37080 C10H13O

O O
O
O O
O
O
O H
O O

6 149.13248 Theoretical 149.13348 1.0 6.750 102 16.48282 7.51828 C11H17

O O
O
O O
O
O
O H
O O

7 159.11683 Theoretical 159.11798 1.2 7.231 474 16.50873 7.74157 C12H15

O O
O
O O
O
O
O H
O O

8 161.09609 Theoretical 161.09675 0.7 4.099 164 16.49529 7.71152 C11H13O

O O
O
O O
O
O
O H
O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
9 163.11174 Theoretical 163.11215 0.4 2.497 311 16.49481 7.53992 C11H15O

O O
O
O O
O
O
O H
O O

10 167.07027 Theoretical 167.06906 -1.2 -7.242 119 16.46048 7.49599 C9H11O3

O O
O
O O
O
O
O H
O O

11 175.11174 Theoretical 175.11163 -0.1 -0.642 199 16.48161 7.29233 C12H15O

O O
O
O O
O
O
O H
O O

12 177.09101 Theoretical 177.09275 1.7 9.861 159 16.50890 7.42549 C11H13O2

O O
O
O O
O
O
O H
O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
13 207.13796 Theoretical 207.13670 -1.3 -6.041 169 16.50131 7.54060 C13H19O2

O O
O
O O
O
O
O H
O O

14 229.12231 Theoretical 229.12404 1.7 7.576 148 16.48577 7.35338 C15H17O2

O O
O
O O
O
O
O H
O O

15 231.17434 Theoretical 231.17350 -0.8 -3.645 127 16.48808 7.39436 C16H23O

O O
O
O O
O
O
O H
O O

16 239.17943 Theoretical 239.17961 0.2 0.784 119 16.51071 7.39735 C18H23

O O
O
O O
O
O
O H
O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
17 249.14852 Theoretical 249.14901 0.5 1.950 338 16.48747 7.58102 C15H21O3

O O
O
O O
O
O
O H
O O

18 271.16926 Theoretical 271.16967 0.4 1.523 233 16.49779 7.45956 C18H23O2

O O
O
O O
O
O
O H
O O

19 272.08905 Theoretical 272.09068 1.6 5.958 141 16.49319 7.55524 C12H16O7

O O
O
O O
O
O
O H
O O

20 273.18491 Theoretical 273.18615 1.2 4.567 364 16.48822 7.51526 C18H25O2

O O
O
O O
O
O
O H
O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
21 275.12779 Theoretical 275.12584 -1.9 -7.083 152 16.46983 7.59542 C16H19O4

O O
O
O O
O
O
O H
O O

22 289.17982 Theoretical 289.17873 -1.1 -3.772 195 16.50257 7.61582 C18H25O3

O O
O
O O
O
O
O H
O O

23 290.13600 Theoretical 290.13757 1.6 5.384 359 16.48246 7.34678 C13H22O7

O O
O
O O
O
O
O H
O O

24 291.19547 Theoretical 291.19719 1.7 5.904 579 16.49570 7.39714 C18H27O3

O O
O
O O
O
O
O H
O O
Expected Observed Mass error Mass error Detector Observed Observed
Status Formula Structure
m/z m/z (mDa) (ppm) counts RT (min) drift (ms)
25 296.12544 Theoretical 296.12743 2.0 6.717 212 16.49158 7.39112 C15H20O6

O O
O
O O
O
O
O H
O O

26 333.20604 Theoretical 333.20689 0.9 2.554 249 16.49891 7.43474 C20H29O4

O O

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