Safety Data Sheet

Hempel's Silicone Aluminium 56910

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2020/878 - Europe

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : Hempel's Silicone Aluminium 56910
Product identity : 5691019000, 001386FA
Product type : silicone paint

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : metal industry, ships and shipyards.
Identified uses : Consumer applications, Industrial applications, Used by spraying.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue : 6 May 2025
Date of previous issue : 17 December 2024.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS
Acute Tox. 4, H332 ACUTE TOXICITY (inhalation)
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION
Aquatic Chronic 3, H412 AQUATIC HAZARD (LONG-TERM)
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Warning

Hazard statements : H226 - Flammable liquid and vapor.
H315 - Causes skin irritation.
H332 - Harmful if inhaled.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements :
General : Keep out of reach of children. If medical advice is needed, have product container or label at hand.
Prevention : Wear protective gloves. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use only outdoors or in a well-ventilated area. Avoid release to the environment.
Avoid breathing vapor. Wash thoroughly after handling.
Response : IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Take off contaminated clothing and
wash it before reuse.
Disposal : Dispose of contents and container in accordance with all local, regional, national and international
regulations.
Hazardous ingredients : xylene
Special packaging requirements
Containers to be fitted with child- Not applicable.
resistant fastenings :
Tactile warning of danger : Yes, applicable.

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SECTION 2: Hazards identification

2.3 Other hazards
See Section 15 for details. EU - Substances of very high concern - PBT / vPvB
Other hazards which do not result None known.
in classification :

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type

xylene REACH #: 01-2119488216-32 ≥25 - ≤50 Flam. Liq. 3, H226 ATE [Dermal] = 1100 mg/kg [1] [2]
EC: 215-535-7 Acute Tox. 4, H312 ATE [Inhalation (gases)] =
5000 ppm
CAS: 1330-20-7 Acute Tox. 4, H332
Index: 601-022-00-9 Skin Irrit. 2, H315
hydrocarbons, C9-C11, n- REACH #: 01-2119463258-33 ≥5 - ≤10 Flam. Liq. 3, H226 - [1]
alkanes, isoalkanes, cyclics, EC: 265-150-3 STOT SE 3, H336
<2% aromatics CAS: 64742-48-9 Asp. Tox. 1, H304
Index: 649-327-00-6 EUH066
ethylbenzene REACH #: 01-2119489370-35 ≥5 - <10 Flam. Liq. 2, H225 ATE [Inhalation (gases)] = [1] [2]
EC: 202-849-4 Acute Tox. 4, H332 4500 ppm
CAS: 100-41-4 STOT RE 2, H373
Index: 601-023-00-4 (hearing organs)
Asp. Tox. 1, H304
Solvent naphtha (petroleum), REACH #: 01-2119455851-35 ≥3 - ≤5 Flam. Liq. 3, H226 - [1]
light arom. EC: 918-668-5 STOT SE 3, H335
CAS: 128601-23-0 STOT SE 3, H336
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
EUH066
toluene REACH #: 01-2119471310-51 ≤0.3 Flam. Liq. 2, H225 - [1] [2]
EC: 203-625-9 Skin Irrit. 2, H315
CAS: 108-88-3 Repr. 2, H361d
Index: 601-021-00-3 STOT SE 3, H336
STOT RE 2, H373
Asp. Tox. 1, H304
octamethylcyclotetrasiloxane REACH #: 01-2119529238-36 ≤0.1 Flam. Liq. 3, H226 M [Chronic] = 10 [1] [3] [4]
(D4) EC: 209-136-7 Repr. 2, H361f
CAS: 556-67-2 Aquatic Chronic 1, H410
Index: 014-018-00-1
See Section 16 for the full text of the H statements declared
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

SECTION 4: First aid measures

4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention/advice.
Inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. Give nothing by mouth. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. If unconscious, place in recovery position and get medical attention
immediately.
Skin contact : Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or
thinners. Remove contaminated clothing and shoes.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.

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SECTION 4: First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Harmful if inhaled.
Skin contact : Causes skin irritation.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Extinguishing media : Recommended: Approved Class D extinguisher or smother with dry sand, dry clay or dry ground
limestone.
NOT TO BE USED: WATER. Risk of formation of very flammable and explosive vapours.

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this
material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides

5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Do not use water. Violent reaction may occur. Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of
explosion hazard. Ventilate the area. Avoid breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall
be taken involving any personal risk or without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate
authorities in accordance with local regulations.

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.

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SECTION 6: Accidental release measures

6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.

6.4 Reference to other sections

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used. Open with care, danger of overpressure.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids as well as of amines, alcohols and water.
No smoking. Prevent unauthorized access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)

See separate Product Data Sheet for recommendations or industrial sector specific solutions.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits
Product/ingredient name Exposure limit values

xylene EU OEL (Europe, 1/2022) [xylene, mixed isomers] Absorbed through skin.
TWA 8 hours: 50 ppm.
TWA 8 hours: 221 mg/m³.
STEL 15 minutes: 100 ppm.
STEL 15 minutes: 442 mg/m³.
ethylbenzene EU OEL (Europe, 1/2022) Absorbed through skin.
TWA 8 hours: 100 ppm.
TWA 8 hours: 442 mg/m³.
STEL 15 minutes: 200 ppm.
STEL 15 minutes: 884 mg/m³.
toluene EU OEL (Europe, 1/2022) Absorbed through skin.
TWA 8 hours: 192 mg/m³.
TWA 8 hours: 50 ppm.
STEL 15 minutes: 384 mg/m³.
STEL 15 minutes: 100 ppm.

Biological exposure indices

Product/ingredient name Exposure limit values

No exposure limit value known.

Recommended monitoring procedures

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SECTION 8: Exposure controls/personal protection

Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels
Product/ingredient name Type - Population - Exposure Value Effects
xylene DNEL - Workers - Long term - Inhalation 77 mg/m³ Effects: Systemic
DNEL - Workers - Long term - Dermal 212 mg/kg bw/day Effects: Systemic
hydrocarbons, C9-C11, n-alkanes, isoalkanes, DNEL - Workers - Long term - Inhalation 1500 mg/m³ Effects: Systemic
cyclics, <2% aromatics
DNEL - Workers - Long term - Dermal 300 mg/kg bw/day Effects: Systemic
ethylbenzene DNEL - Workers - Long term - Dermal 180 mg/kg bw/day Effects: Systemic
DNEL - Workers - Long term - Inhalation 77 mg/m³ Effects: Systemic
Solvent naphtha (petroleum), light arom. DNEL - Workers - Long term - Dermal 12.5 mg/kg bw/day Effects: Systemic
DNEL - Workers - Long term - Inhalation 1.9 mg/m³ Effects: Systemic
toluene DNEL - Workers - Long term - Dermal 384 mg/kg bw/day Effects: Systemic
DNEL - Workers - Long term - Inhalation 192 mg/m³ Effects: Systemic
octamethylcyclotetrasiloxane (D4) DNEL - Workers - Long term - Inhalation 73 mg/m³ Effects: Systemic
Predicted effect concentrations
Product/ingredient name Compartment Detail Value
xylene Fresh water 0.327 mg/l
Marine water 0.327 mg/l
Fresh water sediment 12.46 mg/kg
Marine water sediment 12.46 mg/kg
Soil 2.31 mg/kg
Sewage Treatment Plant 6.68 mg/l
ethylbenzene Fresh water 0.1 mg/l
Marine water 0.01 mg/l
Sewage Treatment Plant 9.6 mg/l
Fresh water sediment 13.7 mg/kg
Soil 2.68 mg/kg
toluene Fresh water 0.68 mg/l
Marine water 0.68 mg/l
Sewage Treatment Plant 13.61 mg/l
Fresh water sediment 16.39 mg/kg
Marine water sediment 16.39 mg/kg
Soil 2.89 mg/kg
octamethylcyclotetrasiloxane (D4) Fresh water 1.5 µg/l
Fresh water 0.15 µg/l
Sewage Treatment Plant 10 mg/l
Fresh water sediment 3 mg/kg dwt
Marine water sediment 0.3 mg/kg dwt
Soil 0.84 mg/kg dwt

8.2 Exposure controls

Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.

Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles.
Hand protection : Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.

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SECTION 8: Exposure controls/personal protection

Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:

Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®

May be used: nitrile rubber (>0.3 mm)
Short term exposure: neoprene rubber (>0.1 mm), butyl rubber (>0.5 mm), natural rubber (latex) (>0.4
mm), polyvinyl chloride (PVC), nitrile rubber (>0.1 mm), butyl rubber (>0.3 mm)

Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection : When the product is applied by spraying and for continuous or prolonged work always wear an air-fed
respirator e.g. hood with supply of fresh or compressed air or a full face, powered air purifying filter.
Respirator selection must be based on known or anticipated exposure levels, the hazards of the
product and the safe working limits of the selected respirator. If working areas have insufficient
ventilation: When the product is applied by means that will not generate an aerosol such as, brush or
roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle
filter of type P. (EN140) Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Color : Gray
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : Testing not relevant or not possible due to nature of the product.
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 25°C (77°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Flammable in the presence of the following materials or conditions: oxidizing materials.
Slightly flammable in the presence of the following materials or conditions: reducing materials.
Vapor pressure : Vapor Pressure at 20˚C Vapor pressure at 50˚C

Ingredient name mm Hg kPa Method mm Hg kPa Method

ethylbenzene 9.30076 1.2

Vapor density : Not available.

Specific gravity : 1.1 g/cm³
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Ingredient name °C °F Method
hydrocarbons, C9-C11, n-alkanes, 280 - 470 536 - 878
isoalkanes, cyclics, <2% aromatics
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Aspiration hazard (H304) Not classified. Testing not relevant due to nature of the product.
Explosive properties : Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge, heat and oxidizing materials.
Slightly explosive in the presence of the following materials or conditions: reducing materials and
moisture.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information

Solvent(s) % by weight : Weighted average: 51 %

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SECTION 9: Physical and chemical properties

Water % by weight : Weighted average: 0 %
VOC content : 558.8 g/l
TOC Content : Weighted average: 503 g/l
Solvent Gas : Weighted average: 0.12 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.

10.5 Incompatible materials

Highly reactive or incompatible with the following materials: oxidizing materials and acids.
Reactive or incompatible with the following materials: reducing materials, organic materials and moisture.

10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides metal oxide/oxides

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Acute toxicity
Product/ingredient name Result Dose / Exposure Effects
xylene Rabbit - Dermal - LD50 >4200 mg/kg
Rat - Oral - LD50 3523 mg/kg
Rat - Inhalation - LC50 Vapor 6350 ppm [4 hours]
Rat - Inhalation - LC50 Gas. 5000 ppm [4 hours]
hydrocarbons, C9-C11, n-alkanes, Rat - Oral - LD50 >2000 mg/kg
isoalkanes, cyclics, <2% aromatics
ethylbenzene Rat - Oral - LD50 3500 mg/kg Toxic effects: Liver - Other changes
Kidney, Ureter, and Bladder - Other
changes
Rabbit - Dermal - LD50 >5000 mg/kg
Solvent naphtha (petroleum), light Rat - Oral - LD50 3492 mg/kg
arom.
Rabbit - Dermal - LD50 3160 mg/kg
Rat - Inhalation - LC50 Vapor 6193 mg/m³ [4 hours]
toluene Rat - Oral - LD50 636 mg/kg
Rat - Inhalation - LC50 Vapor >20 mg/l [4 hours]
octamethylcyclotetrasiloxane (D4) Rat - Oral - LD50 >4800 mg/kg
Rat - Dermal - LD50 >2400 mg/kg
Rat - Inhalation - LC50 Dusts and 36 mg/l [4 hours]
mists
Acute toxicity estimates

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SECTION 11: Toxicological information

Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation

mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
Hempel's Silicone Aluminium 56910 3412.2 12535.0 159.8
xylene 3523 1100 5000
ethylbenzene 3500 4500 11
Solvent naphtha (petroleum), light arom. 3492 3160
octamethylcyclotetrasiloxane (D4) 36
Irritation/Corrosion
Product/ingredient name Result Species Exposure
xylene Rabbit - Eyes - Severe irritant Duration of treatment/ Amount/concentration applied: 5
exposure: 24 hours milligrams
Rabbit - Skin - Moderate irritant Duration of treatment/ Amount/concentration applied: 500
exposure: 24 hours milligrams
Rabbit - Skin - Irritant
hydrocarbons, C9-C11, n-alkanes, Rabbit - Eyes - Mild irritant
isoalkanes, cyclics, <2% aromatics
ethylbenzene Rabbit - Skin - Mild irritant Duration of treatment/ Amount/concentration applied: 15
exposure: 24 hours milligrams
Rabbit - Respiratory - Mild irritant
Rabbit - Eyes - Mild irritant
Solvent naphtha (petroleum), light Rabbit - Eyes - Mild irritant Duration of treatment/ Amount/concentration applied: 100
arom. exposure: 24 hours microliters
Rabbit - Respiratory - Mild irritant
Rabbit - Skin - Moderate irritant
toluene Rabbit - Eyes - Mild irritant Duration of treatment/ Amount/concentration applied: 100
exposure: 0.5 minutes mg
Rabbit - Skin - Moderate irritant Duration of treatment/ Amount/concentration applied: 20 mg
exposure: 24 hours
octamethylcyclotetrasiloxane (D4) Rabbit - Eyes - Mild irritant Duration of treatment/ Amount/concentration applied: 500
exposure: 24 hours milligrams
Rabbit - Skin - Mild irritant Duration of treatment/ Amount/concentration applied: 500
exposure: 24 hours milligrams

Sensitizer
No known data avaliable in our database.

Mutagenic effects
No known data avaliable in our database.

Carcinogenicity
No known data avaliable in our database.

Reproductive toxicity
No known data avaliable in our database.

Specific target organ toxicity (single exposure)

Product/ingredient name Category Route of exposure Target organs
hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, Category 3 Narcotic effects
<2% aromatics
Solvent naphtha (petroleum), light arom. Category 3 Respiratory tract irritation
Category 3 Narcotic effects
toluene Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
ethylbenzene Category 2 - hearing organs
toluene Category 2 - -
Aspiration hazard

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SECTION 11: Toxicological information

Product/ingredient name Result

hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, ASPIRATION HAZARD - Category 1
<2% aromatics
ethylbenzene ASPIRATION HAZARD - Category 1
Solvent naphtha (petroleum), light arom. ASPIRATION HAZARD - Category 1
toluene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
No known significant effects or critical hazards.

11.2 Information on other hazards

Endocrine disrupting properties : The product does not meet the criteria to be considered as having endocrine disrupting properties
according to the criteria set out in either Regulation (EC) No. 1907/2006 or Regulation (EC) No
1272/2008.
Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses. Harmful to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
ethylbenzene Chronic - NOEC - Fresh water Algae - Green algae - Pseudokirchneriella <1000 µg/l [96 hours]
subcapitata
Solvent naphtha (petroleum), light Acute - LC50 Fish - Oncorhynchus mykiss (rainbow trout) 9.22 mg/l [96 hours]
arom.
Acute - EC50 Algae - Pseudokirchneriella subcapitata 2.6 mg/l [96 hours]
(green algae)
Acute - EC50 Daphnia 3.2 mg/l [48 hours]
toluene Chronic - NOEC - Fresh water Daphnia - Water flea - Daphnia magna 1000 µg/l [21 days]
Chronic - NOEC - Fresh water Algae - Green algae - Pseudokirchneriella <500000 µg/l [96 hours]
subcapitata
octamethylcyclotetrasiloxane (D4) Chronic - NOEC - Fresh water Daphnia - Water flea - Daphnia magna 1.7 - 15 µg/l [21 days]
Chronic - NOEC - Fresh water Fish - Rainbow trout,donaldson trout - 4.4 µg/l [93 days]
Oncorhynchus mykiss - Egg
Acute - LC50 Fish >0.022 mg/l [96 hours]
Acute - EC50 Daphnia 0.015 mg/l [48 hours]
Acute - EC50 Algae >0.022 mg/l [96 hours]

12.2 Persistence and degradability

Product/ingredient name Test Result
xylene >60% [28 days] - Readily
OECD Ready Biodegradability - Manometric 90 - 98% [28 days] - Readily
Respirometry Test
hydrocarbons, C9-C11, n-alkanes, OECD Ready Biodegradability - Manometric 80% [28 days] - Readily
isoalkanes, cyclics, <2% aromatics Respirometry Test
ethylbenzene >70% [28 days] - Readily
Solvent naphtha (petroleum), light >70% [28 days] - Readily
arom.
>60% [28 days] - Readily
OECD Ready Biodegradability - Manometric 78% [28 days] - Readily
Respirometry Test
toluene 100% [14 days] - Readily
octamethylcyclotetrasiloxane (D4) OECD Ready Biodegradability - CO₂ in Sealed 3.7% [28 days] - Not readily
Vessels (Headspace Test)

Product/ingredient name Aquatic half-life Photolysis Biodegradability

xylene Readily
hydrocarbons, C9-C11, n-alkanes, Readily
isoalkanes, cyclics, <2% aromatics
ethylbenzene Readily
Solvent naphtha (petroleum), light Readily
arom.
toluene Readily
octamethylcyclotetrasiloxane (D4) Not readily

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Safety Data Sheet
Hempel's Silicone Aluminium 56910

SECTION 12: Ecological information

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
xylene 3.12 8.1 - 25.9 Low
hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% 5 - 6.7 10 - 2500 High
aromatics
ethylbenzene 3.6 - Low
Solvent naphtha (petroleum), light arom. - 10 - 2500 High
toluene 2.73 90 Low
octamethylcyclotetrasiloxane (D4) 6.488 13400 High

12.4 Mobility in soil

Soil/Water partition coefficient
Product/ingredient name logKoc Koc

xylene 1.59 39
ethylbenzene 2.23 170.406
toluene 2.07 117.115
octamethylcyclotetrasiloxane (D4) 3.49 3064.9
Results of PMT and vPvM assessment
Product/ingredient name PMT P M T vPvM vP vM

xylene No No Yes No No No Yes

hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% No No No No No No No
aromatics
ethylbenzene No No Yes Yes No No No
Solvent naphtha (petroleum), light arom. No No No No No No No
toluene No No Yes Yes No No No
octamethylcyclotetrasiloxane (D4) No Yes No Yes No Yes No
Mobility : The product does not meet the criteria to be considered as a PMT or vPvM.

12.5 Results of PBT and vPvB assessment

Regulation (EC) No. 1907/2006 [REACH]
See Section 15 for details. EU - Substances of very high concern - PBT / vPvB

12.6 Endocrine disrupting properties

The product does not meet the criteria to be considered as having endocrine disrupting properties according to the criteria set out in either
Regulation (EC) No. 1907/2006 or Regulation (EC) No 1272/2008.
12.7 Other adverse effects
No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.

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Safety Data Sheet
Hempel's Silicone Aluminium 56910

SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN / ID no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN1263 PAINT 3 III No. Tunnel code (D/E)

Class

IMDG UN1263 PAINT 3 III No. Emergency schedules

Class F-E, S-E

IATA UN1263 PAINT 3 III No. -

Class

PG* : Packing group

Env.* : Environmental hazards

14.6 Special precautions for user

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
Ingredient name Intrinsic property Status Reference number Date of revision
octamethylcyclotetrasiloxane (D4) PBT Recommended ED/71/2019 4/14/2021
octamethylcyclotetrasiloxane (D4) vPvB Recommended ED/71/2019 4/14/2021
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Not applicable.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b

15.2 Chemical Safety Assessment

-

SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration

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Safety Data Sheet
Hempel's Silicone Aluminium 56910

SECTION 16: Other information

Full text of abbreviated H statements : H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH066 Repeated exposure may cause skin dryness or cracking.
Full text of classifications [CLP/GHS] : Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Chronic 1 AQUATIC HAZARD (LONG-TERM) - Category 1
Aquatic Chronic 2 AQUATIC HAZARD (LONG-TERM) - Category 2
Aquatic Chronic 3 AQUATIC HAZARD (LONG-TERM) - Category 3
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Flam. Liq. 2 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Repr. 2 TOXIC TO REPRODUCTION - Category 2
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification
FLAMMABLE LIQUIDS On basis of test data
ACUTE TOXICITY (inhalation) Calculation method
SKIN CORROSION/IRRITATION Calculation method
AQUATIC HAZARD (LONG-TERM) Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Version: 0.08 Page: 12/16

Safe Use of Mixture Information
Hempel's Silicone Aluminium 56910

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor spray painting by professionals with efficient ventilation such as spray booth or local exhaust ventilation
This safe use information is : Professional spray painting, near-industrial setting - Level I
linked to HMP I/PW 01a
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
application hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Loading of application PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
equipment and handling hours (mechanical) room according to EN 166. tested to EN374.
of coated parts before ventilation
curing

Industrial application of PROC07 More than 4 Local exhaust Refer to Wear a respirator Use eye protection Wear suitable gloves
coatings by spraying hours ventilation relevant conforming to EN140 with according to EN 166. tested to EN374.
technical an assigned protection
standards factor of at least 10.

Film formation - force PROC04 More than 4 Enhanced 5 - 10 None None None
drying, stoving and other hours (mechanical) room
technologies ventilation

Cleaning PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Waste management PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 13/16
Safe Use of Mixture Information
Hempel's Silicone Aluminium 56910

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor painting by professionals by dipping or with brush, roller, putty knife etc. with enhanced ventilation or local exhaust ventilation (LEV)
This safe use information is : Professional low-energy painting, near-industrial setting - Level I
linked to HMP I/PW 02a
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
application hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Loading of application PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
equipment and handling hours (mechanical) room according to EN 166. tested to EN374.
of coated parts before ventilation
curing

Industrial application of PROC10 More than 4 Local exhaust Refer to Wear a respirator Use eye protection Wear suitable gloves
coatings by other than hours ventilation relevant conforming to EN140 with according to EN 166. tested to EN374.
spraying technical an assigned protection
standards factor of at least 10.

Film formation - force PROC04 More than 4 Enhanced 5 - 10 None None None
drying, stoving and other hours (mechanical) room
technologies ventilation

Cleaning PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Waste management PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 14/16
Safe Use of Mixture Information
Hempel's Silicone Aluminium 56910

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Outdoor spray painting by professionals for specialist applications, with respiratory protection
Wear suitable coveralls to prevent exposure to the skin. Wear chemically resistant gloves (tested to EN374) in combination with specific
activity training.
This safe use information is : Professional spray painting, near-industrial setting - Level VI
linked to HMP I/PW 05f

Sector(s) of use : Industrial uses - Professional uses

Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions Assumes that activities are undertaken with appropriate and well maintained equipment by trained
personnel operating under supervision.

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemically resistant
application hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.

Loading of application PROC08b More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemically resistant
equipment and handling hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
of coated parts before an assigned protection in combination with
curing factor of at least 10. specific activity training.

Industrial application of PROC07 More than 4 Outdoors 3-5 Use a properly fitted, air- Use eye protection Wear chemically resistant
coatings by spraying hours purifying or air-fed according to EN 166. gloves (tested to EN374)
respirator. EN 14594 with in combination with
an assigned protection specific activity training.
factor of at least 20.

Film formation - force PROC04 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
drying, stoving and other hours according to EN 166. tested to EN374.
technologies

Cleaning PROC05 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemically resistant
hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.

Waste management PROC08b More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemically resistant
hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 15/16
Safe Use of Mixture Information
Hempel's Silicone Aluminium 56910

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Outdoor painting by professionals by dipping or with brush, roller, putty knife etc.
This safe use information is : Professional low-energy painting, near-industrial setting - Level V
linked to HMP I/PW 06e
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemically resistant
application hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Loading of application PROC08b More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemically resistant
equipment and handling hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
of coated parts before an assigned protection in combination with 'basic'
curing factor of at least 10. employee training.

Industrial application of PROC10 More than 4 Outdoors 3-5 Use a properly fitted, air- Use eye protection Wear chemically resistant
coatings by other than hours purifying or air-fed according to EN 166. gloves (tested to EN374)
spraying respirator. EN 14594 with in combination with 'basic'
an assigned protection employee training.
factor of at least 20.

Film formation - force PROC04 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
drying, stoving and other hours according to EN 166. tested to EN374.
technologies

Cleaning PROC05 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemically resistant
hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Waste management PROC08b More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemically resistant
hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 16/16