En US
En US
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2020/878 - Europe
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : used only as part of two- or multi component products.
Identified uses : Industrial applications, Professional applications, Used by spraying.
1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue : 5 May 2025
Date of previous issue : 9 December 2024.
3.2 Mixtures
Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type
xylene REACH #: 01-2119488216-32 ≥25 - ≤50 Flam. Liq. 3, H226 ATE [Dermal] = 1100 mg/kg [1] [2]
EC: 215-535-7 Acute Tox. 4, H312 ATE [Inhalation (gases)] =
5000 ppm
CAS: 1330-20-7 Acute Tox. 4, H332
Index: 601-022-00-9 Skin Irrit. 2, H315
polymer of C18-unsatd. fatty REACH #: 01-2119972320-44 ≥10 - <25 Skin Irrit. 2, H315 - [1]
acids dimers with tall-oil fatty EC: 500-191-5 Eye Dam. 1, H318
acids and triethylenetetramine CAS: 68082-29-1 Skin Sens. 1A, H317
Aquatic Chronic 2, H411
ethylbenzene REACH #: 01-2119489370-35 ≥5 - <10 Flam. Liq. 2, H225 ATE [Inhalation (gases)] = [1] [2]
EC: 202-849-4 Acute Tox. 4, H332 4500 ppm
CAS: 100-41-4 STOT RE 2, H373
Index: 601-023-00-4 (hearing organs)
Asp. Tox. 1, H304
butan-1-ol REACH #: 01-2119484630-38 ≥5 - ≤10 Flam. Liq. 3, H226 ATE [Oral] = 790 mg/kg [1]
EC: 200-751-6 Acute Tox. 4, H302
CAS: 71-36-3 Skin Irrit. 2, H315
Index: 603-004-00-6 Eye Dam. 1, H318
STOT SE 3, H335
STOT SE 3, H336
2,4,6-tris(dimethylaminomethyl) REACH #: 01-2119560597-27 ≥1 - ≤3 Acute Tox. 4, H302 ATE [Oral] = 1200 mg/kg [1]
phenol EC: 202-013-9 Skin Corr. 1C, H314
CAS: 90-72-2 Eye Dam. 1, H318
3,6-diazaoctanethylenediamin REACH #: 01-2119487919-13 <1 Acute Tox. 3, H311 ATE [Dermal] = 550 mg/kg [1]
EC: 203-950-6 Skin Corr. 1B, H314
CAS: 112-24-3 Eye Dam. 1, H318
Index: 612-059-00-5 Skin Sens. 1, H317
Aquatic Chronic 3, H412
toluene REACH #: 01-2119471310-51 <1 Flam. Liq. 2, H225 - [1] [2]
EC: 203-625-9 Skin Irrit. 2, H315
CAS: 108-88-3 Repr. 2, H361d
Index: 601-021-00-3 STOT SE 3, H336
STOT RE 2, H373
Asp. Tox. 1, H304
See Section 16 for the full text of the H statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Harmful if inhaled.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed. Treat
symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled.
Specific treatments : No specific treatment.
xylene EU OEL (Europe, 1/2022) [xylene, mixed isomers] Absorbed through skin.
TWA 8 hours: 50 ppm.
TWA 8 hours: 221 mg/m³.
STEL 15 minutes: 100 ppm.
STEL 15 minutes: 442 mg/m³.
ethylbenzene EU OEL (Europe, 1/2022) Absorbed through skin.
TWA 8 hours: 100 ppm.
TWA 8 hours: 442 mg/m³.
STEL 15 minutes: 200 ppm.
STEL 15 minutes: 884 mg/m³.
toluene EU OEL (Europe, 1/2022) Absorbed through skin.
TWA 8 hours: 192 mg/m³.
TWA 8 hours: 50 ppm.
STEL 15 minutes: 384 mg/m³.
STEL 15 minutes: 100 ppm.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.
Hand protection : Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Chemical-resistant apron.
Respiratory protection : When the product is applied by spraying and for continuous or prolonged work always wear an air-fed
respirator e.g. hood with supply of fresh or compressed air or a full face, powered air purifying filter.
Respirator selection must be based on known or anticipated exposure levels, the hazards of the
product and the safe working limits of the selected respirator. If working areas have insufficient
ventilation: When the product is applied by means that will not generate an aerosol such as, brush or
roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle
filter of type P. (EN140) Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Aspiration hazard (H304) Not classified. Testing not relevant due to nature of the product.
Explosive properties : Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.
10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.
Irritation/Corrosion
Product/ingredient name Result Species Exposure
xylene Rabbit - Eyes - Severe irritant Duration of treatment/ Amount/concentration applied: 5
exposure: 24 hours milligrams
Rabbit - Skin - Moderate irritant Duration of treatment/ Amount/concentration applied: 500
exposure: 24 hours milligrams
Rabbit - Skin - Irritant
polymer of C18-unsatd. fatty acids Rabbit - Eyes - Severe irritant
dimers with tall-oil fatty acids and
triethylenetetramine
ethylbenzene Rabbit - Skin - Mild irritant Duration of treatment/ Amount/concentration applied: 15
exposure: 24 hours milligrams
Rabbit - Respiratory - Mild irritant
Rabbit - Eyes - Mild irritant
butan-1-ol Rabbit - Eyes - Severe irritant Duration of treatment/ Amount/concentration applied: 2
exposure: 24 hours milligrams
Rabbit - Skin - Moderate irritant Duration of treatment/ Amount/concentration applied: 20
exposure: 24 hours milligrams
2,4,6-tris(dimethylaminomethyl) Rabbit - Eyes - Severe irritant Duration of treatment/ Amount/concentration applied: 50
phenol exposure: 24 hours Micrograms
Rabbit - Skin - Severe irritant Duration of treatment/ Amount/concentration applied: 2
exposure: 24 hours milligrams
3,6-diazaoctanethylenediamin Rabbit - Eyes - Moderate irritant Duration of treatment/ Amount/concentration applied: 20
exposure: 24 hours milligrams
Rabbit - Skin - Severe irritant Duration of treatment/ Amount/concentration applied: 5
exposure: 24 hours milligrams
toluene Rabbit - Eyes - Mild irritant Duration of treatment/ Amount/concentration applied: 100
exposure: 0.5 minutes mg
Rabbit - Skin - Moderate irritant Duration of treatment/ Amount/concentration applied: 20 mg
exposure: 24 hours
Sensitizer
Mutagenic effects
No known data avaliable in our database.
Carcinogenicity
No known data avaliable in our database.
Reproductive toxicity
No known data avaliable in our database.
12.1 Toxicity
Do not allow to enter drains or watercourses. Harmful to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
polymer of C18-unsatd. fatty acids Acute - LC50 Fish 7.07 mg/l [96 hours]
dimers with tall-oil fatty acids and
triethylenetetramine
Acute - EC50 Daphnia 7.07 mg/l [48 hours]
Acute - EC50 Algae 4.34 mg/l [72 hours]
ethylbenzene Chronic - NOEC - Fresh water Algae - Green algae - Pseudokirchneriella <1000 µg/l [96 hours]
subcapitata
butan-1-ol Acute - LC50 Fish 1.376 mg/l [96 hours]
Acute - EC50 Daphnia 1328 mg/l [96 hours]
2,4,6-tris(dimethylaminomethyl) Acute - EC50 Algae 84 mg/l [72 hours]
phenol
Acute - LC50 Fish 175 mg/l [96 hours]
3,6-diazaoctanethylenediamin Acute - EC50 Daphnia 31.1 mg/l [48 hours]
Acute - EC50 Algae 20 mg/l [72 hours]
Acute - LC50 Fish 330 mg/l [96 hours]
toluene Chronic - NOEC - Fresh water Daphnia - Water flea - Daphnia magna 1000 µg/l [21 days]
Chronic - NOEC - Fresh water Algae - Green algae - Pseudokirchneriella <500000 µg/l [96 hours]
xylene 1.59 39
ethylbenzene 2.23 170.406
butan-1-ol 0.51 3.22078
2,4,6-tris(dimethylaminomethyl)phenol 2.72 525.589
3,6-diazaoctanethylenediamin 1.53 33.6474
toluene 2.07 117.115
Results of PMT and vPvM assessment
Product/ingredient name PMT P M T vPvM vP vM
xylene No No No No No No No
polymer of C18-unsatd. fatty acids dimers with tall-oil fatty acids No No No No No No No
and triethylenetetramine
ethylbenzene No No No Yes No No No
butan-1-ol No No No No No No No
2,4,6-tris(dimethylaminomethyl)phenol No No No No No No No
3,6-diazaoctanethylenediamin No No No No No No No
toluene No No No Yes No No No
Conclusion/Summary : The product does not meet the criteria to be considered as a PBT or vPvB.
Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN / ID no. Proper shipping name Transport hazard class(es) PG* Env* Additional information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Not applicable.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
Classification Justification
FLAMMABLE LIQUIDS On basis of test data
ACUTE TOXICITY (inhalation) Calculation method
SKIN CORROSION/IRRITATION Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION Calculation method
SKIN SENSITIZATION Calculation method
AQUATIC HAZARD (LONG-TERM) Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.