MATERIAL SAFETY DATA SHEET
Ashland Page 001
Date Prepared: 02/25/03
MSDS No: 306.0366853-001.002
CIL
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Material Identity
Product Name: CIL
General or Generic ID: CORROSION INHIBITOR
Company Emergency Telephone Number:
Ashland 1-800-ASHLAND (1-800-274-5263)
Ashland Distribution Co. & 24 hours everyday
Ashland Specialty Chemical Co.
P. O. Box 2219 Regulatory Information Number:
Columbus, OH 43216 1-800-325-3751
614-790-3333
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2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient(s) CAS Number % (by weight)
-------------------------------------------- ------------- -------------
SODIUM SILICATE 1344-09-8 33.0- 43.0
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3. HAZARDS IDENTIFICATION
Potential Health Effects
Eye
Can cause eye irritation. Symptoms include stinging, tearing,
redness, and swelling of eyes.
Skin
Can cause skin irritation. Symptoms may include redness and
burning of skin, and other skin damage.
Swallowing
Swallowing small amounts of this material during normal handling
is not likely to cause harmful effects. Swallowing large amounts
may be harmful.
Inhalation
Breathing of vapor or mist is possible. Breathing small amounts
of this material is not likely to be harmful.
Symptoms of Exposure
Signs and symptoms of exposure to this material through breathing,
swallowing, and/or passage of the material through the skin may
include: mouth and throat dryness, mouth and throat irritation
(soreness, dry or scratchy feeling, cough), stomach or intestinal
upset (nausea, vomiting, diarrhea), lung irritation.
Target Organ Effects
No data
Developmental Information
Based on the available information, risk to the fetus from
maternal exposure to this material cannot be assessed.
Cancer Information
This material is not listed as a carcinogen by the International
Agency for Research on Cancer, the National Toxicology Program, or
the Occupational Safety and Health Administration.
Other Health Effects
No data
Primary Route(s) of Entry
Inhalation, Skin contact, Eye contact, Ingestion - Industrial
products are not meant to be swallowed.
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4. FIRST AID MEASURES
Eyes
If symptoms develop, move individual away from exposure and into
fresh air. Flush eyes gently with water while holding eyelids
apart. If symptoms persist or there is any visual difficulty,
seek medical attention.
Skin
Remove contaminated clothing. Flush exposed area with large
amounts of water. If skin is damaged, seek immediate medical
attention. If skin is not damaged and symptoms persist, seek
medical attention. Launder clothing before reuse.
Swallowing
Seek medical attention. If individual is drowsy or unconscious,
do not give anything by mouth; place individual on the left side
with the head down. Contact a physician, medical facility, or
poison control center for advice about whether to induce vomiting.
If possible, do not leave individual unattended.
Inhalation
If symptoms develop, move individual away from exposure and into
fresh air. If symptoms persist, seek medical attention. If
breathing is difficult, administer oxygen. Keep person warm and
quiet; seek immediate medical attention.
Note to Physicians
Preexisting disorders of the following organs (or organ systems)
may be aggravated by exposure to this material: skin, lung (for
example, asthma-like conditions), eye.
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5. FIRE FIGHTING MEASURES
Flash Point
Not applicable
Explosive Limit
Not applicable
Autoignition Temperature
Not applicable
Hazardous Products of Combustion
May form: hydrogen, silicates.
Fire and Explosion Hazards
No special fire hazards are known to be associated with this
product.
Extinguishing Media
Use an extinguishing media appropriate for surrounding fire.
Fire Fighting Instructions
Wear a self-contained breathing apparatus with a full facepiece
operated in the positive pressure demand mode with appropriate
turn-out gear and chemical resistant personal protective
equipment. Refer to the personal protective equipment section of
this MSDS.
NFPA Rating
Health - 2, Flammability - 0, Reactivity - 0
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6. ACCIDENTAL RELEASE MEASURES
Small Spill
Absorb liquid on vermiculite, floor absorbent or other absorbent
material. Scoop or scrape up. Put in container for recovery or
disposal.
Large Spill
Persons not wearing protective equipment should be excluded from
area of spill until clean-up has been completed. Stop spill at
source, dike area of spill to prevent spreading, pump liquid to
salvage tank. Remaining liquid may be taken up on sand, clay,
earth, floor absorbent, or other absorbent material and shoveled
into containers.
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7. HANDLING AND STORAGE
Handling
Containers of this material may be hazardous when emptied. Since
emptied containers retain product residues (vapor, liquid, and/or
solid), all hazard precautions given in the data sheet must be
observed. Use good personal hygiene practices. Wash hands before
eating, drinking, smoking, or using toilet facilities. Promptly
remove soiled clothing and wash before reuse. Shower after work
using plenty of soap and water.
Storage
Aluminum equipment should not be used for storage and/or transfer,
e.g. pumps, mixers, fittings, storage tanks, etc. Contact with
aluminum parts in a pressurizable fluid system may cause violent
reactions. Storage vessels constructed of aluminum and aluminum
alloys should be avoided. Store in closed containers in a dry,
well-ventilated area. Keep from freezing.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection
Chemical splash goggles in compliance with OSHA regulations are
advised; however, OSHA regulations also permit other type safety
glasses. Consult your safety representative.
Skin Protection
Wear resistant gloves such as: natural rubber, neoprene, To
prevent skin contact, wear impervious clothing and boots. Other
protective equipment: eyewash station, emergency shower.
Respiratory Protections
If overexposure has been determined or documented, a NIOSH/MSHA
jointly approved air supplied respirator is advised in absence of
proper environmental control. OSHA regulations also permit other
NIOSH/MSHA respirators under specified conditions. (See your
safety equipment supplier.) Engineering or administrative
controls should be implemented to reduce exposure.
Engineering Controls
Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below level of overexposure (from
known, suspected or apparent adverse effects).
Exposure Guidelines
Component
----------
SODIUM SILICATE (1344-09-8)
No exposure limits established
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9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point
(for product) 214.0 - 216.0 F (101.1 - 102.2 C) @ 760 mmHg
Vapor Pressure
(for product) < 17.500 ratio @ 68.00 F
Specific Vapor Density
.670 @ AIR=1
Specific Gravity
1.390 - 1.410 @ 68.00 F
Liquid Density
11.670 lbs/gal @ 68.00 F
1.400 kg/l @ 20.00 C
Percent Volatiles
.0 %
Evaporation Rate
< 1.00 ((N-BUTYL ACETATE) )
Appearance
CLEAR TO SLIGHTLY HAZY
State
LIQUID
Physical Form
HOMOGENEOUS SOLUTION
Color
COLORLESS
Odor
No data
pH
11.0
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10. STABILITY AND REACTIVITY
Hazardous Polymerization
Product will not undergo hazardous polymerization. Avoid contact
with strong mineral acids and strong organic acids.
Hazardous Decomposition
May form: hydrogen, silicates.
Chemical Stability
Stable.
Incompatibility
Avoid contact with: reactive metals such as aluminum and
magnesium, strong mineral acids, strong organic acids, zinc.
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11. TOXICOLOGICAL INFORMATION
LD 50 and LC 50 Data
SODIUM SILICATE (CAS# 1344-09-8)
Oral LD50 (rat): 1960 mg/kg
Dermal LD50 (rabbit): >4640 mg/kg
Inhalation LC50: Not available
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12. ECOLOGICAL INFORMATION
Ecotoxicological Information
96 hour LC50 rainbow trout (static conditions): 707 mg/l
Chemical Fate Information
This material is an inorganic chemical, and therefore, is not
biodegraded. BOD5: 32 ppm
COD: 2700 ppm
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13. DISPOSAL CONSIDERATION
Waste Management Information
Collect and add to large container of water. stir in slight excess
of soda ash. Let stand 24 hours. Decant into another container,
neutralize with 6M-hydrochloric acid. Flush down drain with large
excess of water in accordance with applicable regulations. Deposit
sludge in a landfill in accordance with local, state and federal
regulations. For assistance with your waste management needs -
including disposal, recycling and waste stream reduction, contact
Ashland Distribution Company, IC&S Environmental Services Group at
800-637-7922.
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14. TRANSPORT INFORMATION
DOT Information - 49 CFR 172.101
DOT Description:
NON-REGULATED BY D.O.T.
Container/Mode:
55 GAL DRUM/TRUCK PACKAGE
NOS Component:
None
RQ (Reportable Quantity) - 49 CFR 172.101
Not applicable
Other Transportation Information
The DOT Transport Information may vary with the container and mode
of shipment.
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15. REGULATORY INFORMATION
US Federal Regulations
TSCA (Toxic Substances Control Act) Status
TSCA (UNITED STATES) The intentional ingredients of this
product are listed.
CERCLA RQ - 40 CFR 302.4(a)
None
SARA 302 Components - 40 CFR 355 Appendix A
None
Section 311/312 Hazard Class - 40 CFR 370.2
Immediate(X) Delayed( ) Fire( ) Reactive( ) Sudden
Release of Pressure( )
SARA 313 Components - 40 CFR 372.65
None
OSHA Process Safety Management 29 CFR 1910
None listed
EPA Accidental Release Prevention 40 CFR 68
None listed
International Regulations
Inventory Status
AICS (AUSTRALIA) The intentional ingredients of this product
are listed.
DSL (CANADA) The intentional ingredients of this product are
listed.
ECL (SOUTH KOREA) The intentional ingredients of this product
are listed.
EINECS (EUROPE) The intentional ingredients of this product are
listed.
ENCS (JAPAN) The intentional ingredients of this product are
listed.
State and Local Regulations
California Proposition 65
None
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16. OTHER INFORMATION
The information accumulated herein is believed to be accurate but
is not warranted to be whether originating with the company or
not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their
circumstances.
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