Solution
Solution
5001CJA101029250013 JA
PHYSICS
SECTION I
1) A conducting wire MN carrying a current I is bent into the shape as shown and placed in xy plane.
A uniform magnetic field        is existing in the region. The net magnetic force experienced by
(A) 2BIR
(B) 3BIR
(C) 4BIR
(D) 6BIR
2) The flux linked with a coil at any instant ‘t’ is given by ϕ =10t2 - 50t+250.
The induced emf at t = 3 s is..
(A) 190 V
(B) –190V
(C) –10 V
(D) 10V
3) A resistor has colour code of sequence red, yellow, violet, silver. What is value of its resistance :-
5) A straight rod of mass m and length L is suspended from the identical spring as shown in the
figure. The spring stretched by a distance of x0 due to the weight of the wire. The circuit has total
resistance RΩ. When the magnetic field perpendicular to the plane of the paper is switched on,
springs are observed to extend further by the same distance. The magnetic field strength is
(A)
         ; directed outward from the plane of the paper
(B)
          ; directed outward from the plane of the paper
(C)
          ; directed into the plane of the paper
(D)
          ; directed into the plane of the paper
6) In the circuit shown below, find the decrease in power dissipated in 2Ω resistance after switch is
(A) 8.34 W
(B) 21.21 W
(C) 3.68 W
(D) 14.72 W
7) Figure shows 3 different capacitors, separately charged by batteries, and then connected as
shown, with initially, switch open. When switch is closed, the charge :-
(A) On all capacitors get equalised
(B) becomes zero on all capacitors
(C) On 2µF capacitor increases by 20%
(D) On 2µF capacitor decreases by 20%
9) A current carrying loop is placed in a uniform magnetic field in four different orientations, I, II, III
& IV. Arrange them in the decreasing order of potential energy :
10) If a coil of 40 turns and area 4.0 cm2 is suddenly removed from a magnetic field, it is observed
that a charge of 2.0 × 10–4 C flows into the coil. If the resistance of the coil is 80 Ω, the magnetic flux
density in Wb/m2 is
(A) 0.5
(B) 1.0
(C) 1.5
(D) 2.0
11) If a charged particle goes unaccelerated in a region containing electric and magnetic fields :
(A) P2 = 2P0
(B) P2 = 4P0
(C) P2 = P0
(D) P2 = 8P0
13) Current i = 2.5 A flows along the circle x2 + y2 = 9 cm2 (here x & y in cm) as shown. Magnetic
(A)
(B)
(C)
(D)
14) A wire of resistance 18 ohm is drawn until its radius reduce th of its original radius then
resistance of the wire is
(A) 188 Ω
(B) 72 Ω
(C) 288 Ω
(D) 388 Ω
15)
Identical dielectric slabs are inserted into two identical capacitors A and B. These capacitors and a
battery are connected as shown in figure. Now the slab of capacitor B is pulled out with battery
remaining connected:
(A)
(B)
(C)
(D)
17) The potential of electrostatic field is given by ϕ = xy, where x & y are coordinate. Which of the
following is correct?
(D)
      Electric field at x, y makes an angle                 with x-axis.
18) An electric dipole with dipole moment                        C-m is placed in an electric field
          (N/C). An external agent turns the dipole slowly until its electric dipole moment becomes
(A) 4 × 10–28 J
(B) –4 × 10–28 J
(C) 2.8 × 10–26 J
(D) –2.8 × 10–26 J
19) A long straight wire along the z-axis carries a current I in the negative z direction. The magnetic
vector field at a point having coordinates (x, y) in the z = 0 plane is:
(A)
(B)
(C)
(D)
20) Six identical conducting rods are joined as shown in figure. Points A and D are maintained at
temperature 200°C and 20°C respectively. The temperature of junction 'B' will be :-
(A) 120°C
(B) 140°C
(C) 100°C
(D) 80°C
SECTION II
1) A rod CD of thermal resistance 10.0 KW-1 is joined at the middle of an identical rod AB as shown
in figure. The ends A, B and D are maintained at 200°C,100°C and 125°C respectively. The heat
current in CD is P watt. The value of P is.......
2) In the figure, the flux due to magnetic field through the loop perpendicular to the plane of the coil
and directed into the paper is varying according to the relation, ϕ = t2 + 7t + 1 where f is in weber
and t is in seconds. The magnitude of the emf induced in the loop at t = 1s is (in volt).
3) A charge particle having charge q = 1C and mass 0.25 kg is projected from origin as shown in
figure in x-y plane magnetic field of 1T is present perpendicular to plane. Find speed v (in m/s) so
4) A moving-coil galvanometer has 100 turns and each turn has an area 2.0 cm2. The magnetic field
produced by the magnet is 0.01 T. The deflection in the coil is 2 radian when a current of 10 mA is
passed through it. If the torsional constant of the suspension wire is N × 10–6 N-m/rad, then find N.
5) A charged particle q is shot towards another charged particle Q which is fixed, with a speed v. It
approaches Q upto a closest distance r and then returns. If q was given a speed 2v, the closest
CHEMISTRY
SECTION I
(A) 3 : 1
(B) 3 : 5
(C) 5 : 3
(D) None
2)
In the reaction :
P+Q→R+S
                       the time taken for 75% reaction of P is twice the time taken for 50% reaction
of P. The concentration of Q varies with reaction time as shown in the above figure. The overall
order of the reaction is -
(A) 2
(B) 3
(C) 0
(D) 1
3) We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentration 0.1 M,
0.01M & 0.001 M, respectively. The value of van t’ Haft factor (i) for these solutions will be in the
order.
4) Equimolar solution of two liquids A(    =100torr) & B(    =200 torr) has vapour pressure 180 torr.
Then which is correct for the solution :
(A)
(B)
(C)
(D)
6) Pure water freezes at 273 K and 1 bar. The addition of 34.5 g of ethanol to 500 g of water changes
the freezing point of the solution. Use the freezing point depression constant of water a 2 K kg mol–1.
The figures shown below represent plots of vapour pressure (V.P.) versus temperature (T).
[Molecular weight of ethanol is 46 g mol–1].
Among the following, the option representing change in the freezing point is
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
9)
(A) Ph–CH2–Br
(B)
(C)
(D)
10)
X and Y are respectively :
(A)
(B)
(C)
(D)
11) C6H5–C≡C–CH3 A
(A)
(B)
(C)
(D)
(C)
(D)
13)
(A) 4
(B) 5
(C) 6
(D) 2
17) Potassium dichromate acts as a strong oxidizing agent in acidic solution. During this process, the
oxidation state changes from
(A) + 3 to + 1
(B) + 6 to + 3
(C) + 2 to + 1
(D) + 6 to + 2
19) In which of the following pairs, both the species have the same hybridization ?
(I) SF4, XeF4            (II)
(III)                     (IV)
(A) I, II
(B) II, III
(C) II, IV
(D) I, II, III
SECTION II
2) Using the following information determine the boiling point (in °C) of a mixture which contains
1560 gm benzene and 1125 gm chlorobenzene, when the external pressure is 1000 torr. Assume the
solution is ideal. [Atomic mass : Cl = 35.5]
80 750 120
90 1000 200
4) Considering that Δ0 > P, the magnetic moment (in BM) of [Ru(H2O)6]2+ would be________.
MATHEMATICS
SECTION I
1) The sum of all the values of k for which the system of equations
4x + ky + 2z = 0, kx + 4y + z = 0 and 2x + 2y + z = 0; has a non-trivial (non-zero) solution, is
(A) 2
(B) 4
(C) 6
(D) None
(A) p + q + r
(B) –(p + q + r)
(C) pqr
(D) 0
(A) 1
(B) 2
(C) 3
(D) 4
4) Let f(x) =        and g(x) =               , then :-
5) Period of function f(x) = min{sin x, |x|} +            (where [.] denotes greatest integer function) is
-
(A) π/2
(B) π
(C) 2π
(D) 4π
(A)
(B)
(C) 1
(D)
(A) 2
(B) 3
(C) 4
(D) 12
(A)
(B)
(C)
(D)
9)                       is equal to
(A) 5
(B) 4
(C) 0
(D) D.N.E.
, then
(A)
(B)
(C) g(x) is continuous for all x except at x = 0
(D) g(x) is differentiable for all x except at x = 0
(A) 0
(B)
(C)
12) For x ∈ [–2,4], function ƒ(x) = [log2(x2 – 2x + 5)] discontinuous at (where [.] represents greatest
integer function)
(A) 2 points
(B) 3 points
(C) 4 points
(D) Infinite points
13) Let ƒ(x) = , then (where [.] represents greatest integer function)
If a derivable function y = ƒ(x) satisfies the condition ƒ(x) + ƒ(y) = ƒ(x)ƒ(y) + ƒ(xy) ∀ x,y ∈ R where ƒ(1)
= 0 and ƒ'(1) = –2, then the number of solution(s) of the equation ƒ(x) = 2
(A) 0
(B) 1
(C) 2
(D) 3
15)
Number of points in (0, ∞) where function f(x) = sinπx |(ln x) (x + 1) (ex – e2)| is non differentiable, is
(A) 3
(B) 2
(C) 1
(D) 0
16) An are PQ of a circle subtends a right angle at its centre O. The mid point of the arc PQ is R. If
          ,          and                 then α, β2 are the roots of the equation
(A) x2 – x – 2 = 0
(B) 3x2 + 2x – 1 = 0
(C) x2 + x – 2 = 0
(D) 3x2 – 2x – 1 = 0
(A) 413
(B) 423
(C) 323
(D) 313
(A)
(B)
(C)
(D)
(B)
(C) 2
(D) 3
20) If the non zero vectors         are perpendicular to each other, then the solution of the equation.
           is :
where x is a scalar
(A)
(B)
(C)
(D)
SECTION II
1) Let         are three vectors of which every pair is non collinear, and the vectors         and
         are collinear with   are    respectively. If    = 1, then find           .
2)
3) A plane which always remains at a constant distance 4 units from origin & it's normal is equally
inclined with the coordinate axes, then sum of length of intercepts cuts by the plane on the
coordinate axes is equal to     units, then ℓ :-
PHYSICS
SECTION I
Q.        1   2    3    4         5    6   7     8      9         10    11        12     13    14    15          16        17        18      19       20
A.        D   C    A    B         A    D   D     A      C         B     B         C      A     C     A           B         B         C       A        B
SECTION II
     Q.                  21                            22                          23                       24                              25
     A.                 2.00                          9.00                        8.00                     1.00                            4.00
CHEMISTRY
SECTION I
Q.    26      27   28        29       30   31    32      33        34   35        36     37   38    39      40        41        42    43         44   45
A.    C       D    A         A        C    D     B       A         D    A         A      C    D     A       D         D         B     A          C    C
SECTION II
     Q.                 46                       47                           48                          49                               50
     A.                 96                      100                          5.00                        0.00                             5.00
MATHEMATICS
SECTION I
Q.    51      52   53        54       55   56    57          58    59   60        61     62   63    64      65        66        67    68         69   70
A.    C       D    D         D        C    D     A           A     A    C         D      A    A     A       D         A         A     C          B    A
SECTION II
      Q.                71                       72                          73                      74                                    75
      A.                6                       0.75                         12                     2.00                                  0.00
                                        SOLUTIONS
PHYSICS
Where,
2)
E(t) = –
    E(t) =
    E(t) = – (20t – 50)
    Here, Substitute t = 3s
    E (C) = – (20 × 3 – 50)
    E(C) = – (60–50)
    E(C) = –10V
    4)
    ⇒ VD = 0
    ∴ VE = –4 × 2 = –8 volt
    5)
    When switch is open then,
                  ...(1)
When switch is closed, spring elongate by swice of initial force on rod due to magnetic field
must be along downward direction.
so, direction of magnetic field should be along outward from plane of the paper (By right hand
thumb rule)
FB = × i × B =
⇒ FB + mg = 4kx0
⇒ FB + mg = 2(2kx0)
⇒ FB + mg = 2mg [From eqn–1)
     0
6) i =
P0 = 50 W
iT =
i2 = 7 × = 4.2 A
P = 4.22 × 2 = 35.28 W. ΔP = 14.72 W
7)
after redistribution,
Q = 0.8
charge on 2F capacitor reduces by 20 %
8) Relative permeability,
   µr = 1 + x
x is susceptibility
9)
10)
B = 1.0
11)
14)
Correct Answer is
(C) 288 Ω
15)
Ceq decrease
So charge decrease.
Concept used :
it is based on the concept of capacitance is equals to magnitude of charge upon potential
difference between the two conductors
Formula used :
Calculation :
VB =
V+ = PD of +vely charged sphere
V– = PD of –vely charged sphere
17)
Where
20)
Req = 3R
i=
TB = 200 – 60 = 140°C
21)
                         ºC
22)
23)
2 = 2R sin θ
24) = BiNA
  = Cθ
By comparing
Cθ = BiNA
       C = 1 × 10–6 N-m/rad
       25)
       From the given data, using energy conservation
When particle is shot with a speed 2V, Let distance of closest apporach = x
⇒x=
CHEMISTRY
       26)
       log3 + log rA = log rB + log5
          log (3 × rA) = log (5 × rB)
         3rA = 5rB ;
         x:y=5:3
28)
29) Fact
       30)
      31)
∴ (D) is appropriate.
33)
      Explain Question :
      Asking the stereochemical concept [retention of configuration] in given reactions of alcohol.
      Concept :
      This question is based on SN2 mechanism.
      Stereochemistry of SN2 reaction → Inversion of configuration (Walden inversion)
      Solution :
      If nucleophile attack at chiral atom in SN2 reaction then inversion of configuration is observed
      otherwise retention of configuration is seen in the product.
(1)
34)
Correct answer is
(D)
      Concept:
      In E2 elimination β-H removed by strong base.
      Solution:
      Highly crowded base (like t-BuOK or Et3COK) prefers removal of less hindered β-H while
      normal or small size bases prefer removal of most hindered β-H in order to get the most stable
      alkene.
Final Answer:
The correct option is (1)
36)
38)
  *   SN2 product will be formed
  *   Polar aprotic solvent is used, it favours the SN2 Mechanism
  *   In SN2 Nucleophile (here HS–) attack from back side.
  *   Inversion of product will takes place
   * New product
   * A single stereo isomer will be formed
   * Since product is altogether a different compound we cannot say about it dextro or
levorotatory nature.
   Only Option D is correct.
39)
40) [M(AB)2] shows two G.I. and both are optically active so total S.I are 4.
41) [Fe(H2O)6]3+
                   0
Fe3+ ⇒ [Ar] 3d5 4s
No pairing
∴ Unpaired e– = 5
[Fe(CN)6]–3
Fe3+ ⇒ [Ar] 3d5 4s°
∴ Unpaired e– ⇒ 1
42)
43) With increase in % of oxygen acidic nature of oxide of an element increase and basic
nature decreases
44)
45)
or
⇒ V = 80 ml
16mmol 16mmol 0
on complete reaction, millimole of A– = 16
∴ [A–] =
=                                           =
⇒ Xchlorobenzene = mole fraction of chlorobenzene in liquid solution
 = 1 – XBenzene =
for boiling, the vapour pressure exerted by the solution should be equal to that of the external
pressure. The data given in question gives a vapour pressure of solution equal to 1000 torr at
100°C.
Ptotal =
= 1000 torr
(We have to check total vapour pressure in each case & find the case for which it equals 1000
torr)
49) [Ru(H2O)6]2+
so, pairing of e– will take place
Ru = [Kr]5s2 4d6
Ru2+ = [Kr]     4d6
   2+
Ru = [Kr]
Unpaired e– = Zero.
So, magnetic moment =
=
    50)                                    ,   ,
, ,
MATHEMATICS
51)
    4x + ky + 2z = 0
    kx + 4y + z = 0
    2x + 2y + z = 0
    for non trival solution
       4(4 – 2) – k (k – 2) + 2 (2k – 8) = 0
       8 – k2 + 2 k + 4 k – 16 = 0
       k2 – 6k + 8 = 0
      k2 – 2k – 4k + 8 = 0
       k(k – 2) –4 (k – 2) = 0
       (k – 4) (k – 2) = 0
    k = 2, 4
    sum of values of k = 2 + 4 = 6
    52)
(interchanged row and columas)
= –A ⇒ A = 0
53)
54)
55)
56) ⇒
                   ⇒
Now cotθ = sinα
is Tn = tan–1
= tan–1
⇒ Sn = tan–1 – tan–1
⇒ S∞ = – tan–1
⇒ S = tan
58)
59)
60)
and
61) 3 – 2k – 2 = 0
∴ No value of k.
62)
63)
64)
65) ln x, x + 1, ex – e2 becomes zero at x = 1, –1 and 2 respectively, for which sin px is also zero
Hence f(x) is derivable at these points.
∴ number of points of non derivability = 0
66)
67)
Also
⇒
⇒
⇒
⇒
⇒
⇒
69)
70)
take cross product with
71)
Given
Thus,
72)
A(1, 0, 0),
Hence,
So,
⇒
73) x + y + z = a
  distance from (0, 0, 0) is 4.
∴ ⇒a=
74)
= 0 + 2 =2
75) Determinant value of every odd order skew symmetric matrix is zero.