AN1012
AN1012
Application note
                                            Predicting the battery life and data
                                 retention period of NVRAMs and serial RTCs
           Introduction
           Standard SRAM devices have the advantage, over EEPROM and Flash memory, of high
           write-speed when used as main memory for a processor or microcontroller. Their
           disadvantage is that they are volatile, and lose their contents as soon as the power supply is
           removed (whether this is for a prolonged period due to being turned off, or due to an
           unexpected glitch or loss of the power supply).
           STMicroelectronics manufactures a line of non-volatile SRAMs (NVRAMs), known as
           ZEROPOWER® or TIMEKEEPER® NVRAMs, supervisors, and serial RTCs which offer the
           best of both worlds: memory devices that are non-volatile like EEPROM, yet have the fast
           access of SRAM. These devices consist of an array of low-power CMOS SRAM, plus a
           small long-life lithium power cell (along with a high-accuracy quartz crystal, in the case of
           the TIMEKEEPER). While the external power supply is within its specified limits, the
           memory behaves as standard SRAM; but as soon as the external power supply strays out of
           tolerance, the SRAM becomes write-protected, and its contents are preserved by a small
           trickle current supplied by the internal power cell.
           Unlike EEPROM, where the data contents are guaranteed to be preserved for 10 years (and
           typically last for much longer), the contents of NVRAM will only be retained while the internal
           cell is able to supply sufficient current to maintain the array. This document summarizes the
           factors involved in predicting the battery life, and consequently data retention under various
           operating conditions.
           Many of the ZEROPOWER, TIMEKEEPER, supervisor, and serial RTC devices are
           packaged in a 600 mil DIP CAPHAT™, a hybrid DIP, or a 330 mil SOIC SNAPHAT®. The
           SNAPHAT (shown in Figure 1) has a removable top that includes both the long-life lithium
           cell and, in the case of the TIMEKEEPER, a high-accuracy crystal.
           STMicroelectronics has shipped several million SNAPHATs that have been used in a broad
           range of applications. From PC-based systems to high-end workstations,
           telecommunications, consumer, and automotive applications, these products have provided
           highly reliable data storage for the electronics industry.
CAPHAT™
Hybrid DIP
Contents
1 Process technology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
2 Battery technology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
4 4T cell devices . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
5             TIMEKEEPER products . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
              5.1      TIMEKEEPER® register map . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
              5.2      TIMEKEEPER® evolution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
                       5.2.1       M48T02 and M48T12 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
                       5.2.2       M48T08 and M48T18 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
                       5.2.3       M48T58 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
                       5.2.4       M48T35 and M48T37V/Y . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
6 Supervisor products . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
7 Choosing SRAM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
10 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
11 Revision history . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
List of tables
List of figures
1 Process technology
                                                    POLY-LOAD
                                                    RESISTORS
                                        Q1                              Q2
Q3 Q4
GND
                                                   ROW SELECT
                                  BIT-LINE                               BIT-LINE                 AI02457
              The first devices, released in 1982, were based on a conventional 6T, full-CMOS, SRAM
              design. These were specified for low-voltage data retention, and were built to stringent
              manufacturing and test specifications. With data retention currents of less than 150 nA at
              70 °C, these devices were designed to retain data in battery backup for at least 10 years
              over the full commercial temperature range.
              Newer devices have since been released. They use 4T, CMOS SRAM arrays. By using two
              poly-R resistors in place of the pull-up transistors of full-CMOS design, the 4T cell is much
              smaller than the 6T equivalent. Die size is dramatically reduced because the poly-R
              resistors can be stacked on top of n-channel pull-down MOSFETs in the cell. This leads to a
              net reduction in the device costs. Although the current drawn from the lithium cell is
              increased, the devices have been specified to outlast the useful life of most equipment in
              which they are used.
2 Battery technology
                                STMicroelectronics uses both the BR1225 and the BR1632 lithium button cell batteries.
                                These have charge capacities of 48 mAh and 120 mAh, respectively. Their constituents
                                have non-toxic and non-corrosive characteristics, and are chemically and thermally stable
                                before, during, and after discharge. This makes these cells particularly attractive for use in
                                electrical components.
                                They contain a solid carbon cathode that is pressed into a tablet of predetermined weight
                                and height. The anode consists of high-purity lithium metal. The electrolyte is based on an
                                organic solvent instead of the corrosive alkaline or acidic solution found in most
                                conventional batteries. This greatly reduces the likelihood of internally-induced cell leakage,
                                and reduces the ill effects in cases of externally-induced cell leakage. The cell is then crimp-
                                sealed with a polypropylene grommet.
                                ST has conducted extensive tests on these cells, at temperatures up to 85 °C. Destructive
                                analysis was conducted (post-stress), in order to measure such factors as weight loss and
                                remaining charge capacity. The analysis determined that the cells were drying out, and that
                                the weight loss was due to electrolyte evaporation. Models were developed to predict the
                                nominal rate of electrolyte loss, and how this would be reduced by adding a second level of
                                encapsulation. This proprietary secondary seal encapsulation, adopted by ST, has been
                                found to provide up to a two-fold reduction of the electrolyte loss rate.
                                Both cells produce a nominal 2.9 V output with a flat discharge curve until the end of their
                                effective lives, and thus confirms that both are suitable for providing battery backup to low
                                leakage CMOS SRAMs (see Figure 3).
Figure 3. (A) BR1225 discharge rate and (B) BR1632 discharge rate
                  3.0                                                                    3.0
                                                                           Voltage (V)
    Voltage (V)
2.5 2.5
                  2.0                                                                    2.0
                              15kΩ   30kΩ                        100kΩ                               15kΩ     30kΩ     50kΩ                  100kΩ
                  1.5                                                                    1.5
                  1.0                                                                    1.0
                        0     200 400 600 800 1000 1200 1400 1600 1800 2000                    0       1000     2000     3000      4000    5000      6000
                                            Duration (Hrs.)                                                          Duration (Hrs.)
                                                  (A)                                                                      (B)
                                                                                                                                                  AI02519
            A ZEROPOWER®, TIMEKEEPER®, supervisor, or serial RTC device will reach the end of
            its useful life for one of two reasons:
            ●    Capacity consumption
                 It becomes discharged, having provided current to the SRAM (and to the oscillator in
                 the case of the TIMEKEEPER) in the battery backup mode.
            ●    Storage life
                 The effects of aging will have rendered the cell inoperative before the stored charge
                 has been fully consumed by the application.
            The two effects have very little influence on each other, allowing them to be treated as two
            independent but simultaneous mechanisms. The data retention lifetime of the device is
            determined by which ever failure mechanism occurs first.
                                                                                                                                 SL50% (AVERAGE)
                                             20
SL1%
                                             1
                                                  20   30          40                  50                 60                  70             80    90
         where,
         ●    ti /T is the relative proportion (of the total time) during which the device is at ambient
              temperature TAi;
         ●    SLi is the storage life at ambient temperature TAi as illustrated in Figure 4; and
         ●    T is the total time = t1 + t2 + ... + tn.
         For example, consider a battery exposed to temperatures of up to 90 °C for 600 hrs/yr, and
         temperatures of 60 °C or less for the remaining 8160 hrs/yr. Reading predicted t1% values
         from Figure 4,
         ●    SL1 is about 1.8 yrs;
         ●    SL2 is about 28 yrs;
         ●    T is 8760 hrs/yr;
         ●    t1 is 600 hrs/yr; and
         ●    t2 is 8160 hrs/yr.
         The predicted storage life evaluates to:
                                                                            600- --------         8160- 1 ⎞
                                                                                           1 -⎞ ⎛ --------------
                                                                                                                            –1
                                                                        ⎛ -------------- ×     +                 × ------
                                                                        ⎝ 8760 1.8⎠ ⎝ 8760 28⎠
         This predicts that the storage life, in this particular case, is at least 14 years. This is,
         therefore, better than the normally accepted life time of 10 years.
                                                                       BatteryCapacity
                                          -----------------------------------------------------------------------------------------------------
                                          8760 × ( 1 – V CC DutyCycle ⁄ 100 ) × I
                                                                                                                                      BAT
            where:
            ●    Battery capacity is measured in ampere-hours;
            ●    8760 is the constant for the number of hours there are in a year;
            ●    VCC duty cycle is measured as a percentage; and
            ●    IBAT is measured in amperes.
            For the M48T35Y, a 32K x 8 TIMEKEEPER® device with a 0.048 Ah (48 mAh) M4T28-
            BR12SH1 battery, the typical battery current is approximately 2666 nA at 70 °C.
            So, if the VCC duty cycle is 50%, the predicted capacity life is:
                                                                                      0.048
                                                              ------------------------------------------------------------
                                                                                                                         -
                                                              8760 × 0.5 × 2666 × 10 – 9
4 4T cell devices
5 TIMEKEEPER products
                      32,768 Hz
                      CRYSTAL                                                       A0-A12
POWER
                                                                                    DQ0-DQ7
                                                                      8176 x 8
                                                                    SRAM ARRAY
                      LITHIUM
                        CELL                                                        E
                                    VOLTAGE SENSE                                   W
                                                             VPFD
                                         AND
                                      SWITCHING                                     G
                                      CIRCUITRY
         Figure 6.    M48T02/12 data retention lifetime vs. temperature (120 mAh, 100% battery
                      backup)
         Figure 7.    M48T08/18 data retention lifetime vs. temperature (120 mAh, 100% battery
                      backup)
5.2.3    M48T58
         The next TIMEKEEPER® product was the M48T58 which is fabricated on the 0.6 µm,
         double-level metal HCMOS4PZ process for 4T SRAM cells.
         Table 13 on page 28, Appendix C: TIMEKEEPER® products on page 28, Figure 8, and
         Figure 9 on page 16 show the extent to which the data retention of these devices is more
         dependent on temperature. Higher temperatures cause lower resistor values (and therefore,
         higher currents) because of the negative temperature coefficient of the poly-R resistors.
         Data retention lifetimes typically range from 8.6 years (at 30 °C) for devices in the
         CAPHAT™ package, with a 48 mAh battery (see Figure 8), and up to 20 years (and more)
         for the SNAPHAT package with a 120 mAh BR1632 battery (see Figure 9). As always,
         several factors affect battery lifetime, including the VCC duty cycle and temperature.
         Figure 8.    M48T58 data retention lifetime vs. temperature (48 mAh, 100% battery
                      backup)
         Figure 9.    M48T58 data retention lifetime vs. temperature (120 mAh, 100% battery
                      backup)
         Figure 10. M48T35/37V/37Y data retention lifetime vs. temperature (48 mAh, 100%
                    battery backup)
         Figure 11. M48T35/37V/37Y data retention lifetime vs. temperature (120 mAh, 100%
                    battery backup)
           If data retention lifetimes greater than those shown are required, the user is advised to
           choose the version of the device in a SNAPHAT® package. Then, as the battery starts to
           reach the end of its useful life, it is possible to remove the SNAPHAT top containing the
           nearly expended cell and replace it with a fresh SNAPHAT top. No data will be lost during
           the process, provided that the board remains powered up during the operation (although
           some time will be lost due to the momentary removal of the 32 kHz crystal). Table 4 shows
           which SNAPHAT top part numbers are available.
6 Supervisor products
7 Choosing SRAM
                Most low power SRAMs on the market today can be used with both ZEROPOWER® and
                TIMEKEEPER® supervisors, although there are some issues that need addressing before
                finally choosing which SRAM to use.
                ●     The chip enable input, when taken inactive, must disable all the other inputs to the
                      SRAM. This allows inputs to the external SRAMs to be treated as “Don’t care” once
                      VCC falls below VPFD(min).
                ●     The SRAM should guarantee data retention when working at VCC = 2.0 volts.
                ●     The chip-enable access time must be sufficient to meet the system needs, taking into
                      account propagation delays on chip enable and output enable.
                Most SRAMs specify a data retention current (ICCDR) at 3.0 V. Manufacturers generally
                specify a typical condition for room temperature along with a worst case condition (generally
                at elevated temperatures). The system level requirements will determine the choice of which
                value to use. The data retention current value of the SRAMs can then be added to the IBAT
                value of the supervisor to determine the total current requirements for data retention. The
                available battery capacity for the SNAPHAT® of your choice can then be divided by this
                current to determine the data retention period (see Section 3.3: Capacity consumption on
                page 10).
                For example, the M48T201V/Y has an IBAT value of 575 nA at 25 °C, and 800 nA at 70 °C.
                The M40Z300W has an IBAT value of 5 nA at 25 °C, and 100 nA at 70 °C. Table 5 indicates
                typical data retention lifetimes for the M40Z300W ZEROPOWER supervisor when it is used
                with a number of commercially available 1 Mbit and 4 Mbit SRAMs. Table 6 on page 21
                shows the same kind of information for the M48T201V/Y TIMEKEEPER supervisors.
Table 5.        M40Z300W (120mAh SNAPHAT) data retention life vs. SRAM type
                                                                                                         Lifetime in
    Size                                                       IBAT (SRAM) (nA)     IBAT (Total) (nA)
                                Product                                                                   years(1)
    (Mbit)
                                                                 25°C        70°C   25°C       70°C     25°C    70°C
                            HY628100BLLT1-55                     1000      10000    1005      10100     13.6     1.4
                 Hynix
                            HY62V8100BLLT1-70(2)                 1000      10000    1005      10100     13.6     1.4
      1
                            M5M51008DVP-55H                      500       10000     505      10100     > 20     1.4
                Renesas                             (2)
                            M5M5V108DVP-70H                      1000      10000    1005      10100     13.6     1.4
                            R1LP0408CSB-5SC                      800         8000    805       8100     17.0     1.7
      4         Renesas                            (2)
                            R1LV0408CSB-5SC                      500         8000    805       8100     > 20     1.7
                Renesas     HM62V8100LTTI-5SL                    500       10000     505      10100     > 20     1.4
      8
              Samsung       K6X8008T2B-UF5500                    N/A       15000     N/A      15100     N/A      0.9
1. According to the respective manufacturer’s datasheets at the time of writing.
2. 3 V device
Table 6.        M48T201V/Y (120 mAh SNAPHAT) data retention life vs. SRAM type
  Size                                                     IBAT (SRAM) (nA)        IBAT (Total) (nA)   Lifetime in years(1)
                             Product
 (Mbit)                                                     25°C        70°C       25°C       70°C       25°C      70°C
                         HY628100BLLT1-55                   1000        10000      1075      10800        8.7       1.3
           Hynix
                         HY62V8100BLLT1-70(2)               1000        10000      1075      10800        8.7       1.3
    1
                         M5M51008DVP-55H                     500        10000      1075      10800       12.7       1.3
           Renesas                              (2)
                         M5M5V108DVP-70H                    1000        10000      1575      10800        8.7       1.3
                         R1LP0408CSB-5SC                     800        8000       1375       8800       10.0       1.6
    4      Renesas                             (2)
                         R1LV0408CSB-5SC                     500        8000       1075       8800       12.7       1.6
           Renesas       HM62V8100LTTI-5SL                   500        10000      1075      10800       12.7       1.3
    8
           Samsung       K6X8008T2B-UF5500                   N/A        15000       N/A      15800       N/A        0.9
1. According to the respective manufacturer’s datasheets at the time of writing.
2. 3 V device
           Due to ever increasing requirements for portability and operation under extreme
           environmental conditions, STMicroelectronics offers industrial temperature versions
           (–40°C to +85°C) of our serial RTC devices. This expanded operating range allows these
           products to perform under more extreme temperatures for applications such as:
           ●    cell phone base stations;
           ●    traffic control;
           ●    portable equipment;
           ●    land, water, and aircraft instrumentation; and
           ●    industrial control equipment.
           These products are indicated by the digit ‘6’ at the end of the sales-type. The industrial
           temperature TIMEKEEPER® SNAPHAT® top is also designated by the suffix “6.” Predicted
           data retention lifetimes are listed in Appendix B: ZEROPOWER products on page 26 and
           Appendix C: TIMEKEEPER® products on page 28.
10 Summary
          Battery life and data retention for ZEROPOWER® and TIMEKEEPER® products are
          primarily functions of two factors:
          ●   Capacity consumption, and
          ●   Storage life of the lithium button cell battery.
          Due to the fact that storage life (caused by electrolyte evaporation) has little effect at
          temperatures below 60 °C, the data retention of most applications will be dependent upon
          the ICCDR of the SRAM being backed-up, as well as the VCC duty cycle. This allows a fairly
          simple calculation (see Section 3.4: Calculating capacity consumption on page 10) to be
          used to determine the lifetime.
          All ST ZEROPOWER products are able to offer at least a 10 year data retention life, typically
          at 40 °C. This may be increased by reducing the temperature, increasing the VCC duty cycle,
          or in the case of the surface mount SNAPHAT® products, using the larger 120 mAh
          SNAPHAT top.
          For the TIMEKEEPER family, battery lifetimes are also affected by the percentage of time
          the oscillator is in operation. Commercial devices fabricated in 4T technologies provide
          7 years of continuous operation at 20 °C using the 48 mAh M4T28-BR12SH SNAPHAT top,
          and typically greater than 15 years with the 120 mAh M4T32-BR12SH SNAPHAT top.
          The ZEROPOWER and TIMEKEEPER supervisor families allow the user to purchase
          commodity SRAMs at the best available market price. However, overall data retention life
          will be determined by the ICCDR of the SRAM selected.
Note:          These devices are not recommended for new design. Please contact local ST sales office
               for availability.
         The tables in this appendix use the terms “typical” and “worst case” to indicate the “mean
         value at the given temperature” and “mean value plus maximum expected deviation at the
         given temperature.”
Note:    The symbol “>>” means, “... much greater than...”
         Table 12.          Data from M48T02/12 devices (available only in CAPHAT™ - BR1632,
                            120 mAh)
              Temperature                              VCC duty cycle = 0%                    VCC duty cycle = 100%,
                   (°C)                  Typical (years)            Worst case (years)           shelf life (years)
           Table 15.    Data from M41T56/94, M41ST85W, M41ST87W/Y, and M41ST95W ind.
                        temp. (MH6) devices
                              SNAPHAT (BR1632, 120 mAh)
             Temperature                                       VCC duty cycle = 100%,
                                  VCC duty cycle = 0%
                 (°C)                                             shelf life (years)
                                    Typical (years)
         Table 16.   Data from M41T00/S, M41T11, and M41T81/S industrial temperature (MH6)
                     devices
                           SNAPHAT (BR1632, 120 mAh)
          Temperature                                          VCC duty cycle = 100%,
                               VCC duty cycle = 0%
              (°C)                                                shelf life (years)
                                 Typical (years)
11 Revision history
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