Yara
Environmental Solutions
DeNOx TECHNOLOGY
Werner Rungger
Yara Italia SpA
Yara delivers sustainable solutions for
agriculture and the environment
Agricultural Industrial Environmental
products products solutions
Safety is always our top priority
Ambition of zero injuries to people and no major process related incidents
Product stewardship program
Production according to high technical standards
Reliable transport and shipping concepts
Best practice sharing on storage and handling with partners and
customers
Key numbers
Number of employees 23,7 million tons
Revenues and other 9.760 Crop nutrients
income (2013)
Located in more than 4,9 million tons
USD 14.3 50 countries Industrial products
billion Sales to more than 1,8 million tons
Environmental
150 countries solutions
YARA ENVIRONMENTAL TECHNOLOGIES
Aquisition of:
Petro Miljoe AB (SNCR supplier with 25 years of
experience, over 300 installations)
H+H Umwelt und Industrietechnik (SCR supplier for
landbased and marine engines, more than 15 years
experience, over 1200 installations)
Strabag Energy Technologies SET (SCR supplier for
the energy sector, over 20 years experience)
Yara’s DeNOx product portfolio
DeNOx Reducing Agents DeNOx Technologies DeNOx Services
NOxCare products: SNCR and HYBRID Technology related Services
– Anhydrous ammonia – Boilers / Cogeneration – Testing & Optimization
– Aqueous ammonia – Industrial applications – Upgrade & Modification
– Solid urea SCR – Spare parts & Maintenance
– Urea solution – Boilers / Cogeneration – Catalyst Management
– Industrial applications – Operation & Maintenance
training
– Landbased/Marine engines
Safety related Services
Reagent Handling & Storage
– Training: Online & Customized
Urea to Ammonia
– Inspection, Audit & Advisory
Page 6
NOxCare® – Full Service DeNOx Solutions
We Care For Your Operations
SNCR, SCR and hybrid
technology
Reagent handling and storage
equipment
Reagent supply
Services – optimization &
upgrading of systems, safety
trainings, spare parts and
maintenance work
Yara is a leading supplier of solutions for
reducing NOx emissions from industrial
sources
Power plants
Waste incinerators
Cement kilns
Refineries
Glass industry
Page 8
SNCR TECHNOLOGY - Selective Non Catalytic
Reduction
Thermal process, based on the
injection of ammonia / urea solution at
850 – 1000°C
Performances: 60 – 80% reduction
rate
Low investment costs
INDUSTRIAL WASTE INCINERATOR –
SNCR TEST INJECTION
400 10
9
350
Test 17 Test 18 Test 19 Test 20 Test 21 Test 22 Test 23 Test242 Test 25 Test 26
8
300
7
250
6
200 Test 16 5
Test 15
Test 14 4
150
3
100
2
41.69
50
1
19.63 16.20
0 0
NOx Val mg/Nm3 @ 11% O2 <- N2O Val mg/Nm3 @ 11% O2 E-1 -> NOx Media mg/Nm3 @ 11% O2 <-
NH4OH 25% l/h <- Portata Urea 45% liv.1 <- Portata Urea 45% liv.2 <-
NH3 Val mg/Nm3 @ 11% O2 -> CO Val mg/Nm3 @ 11% O2 ->
SNCR-plant for Filborna, Helsingborg
Fuel: MSW
Capacity: 75 MW
Flue gas flow, nominal: 129 100 Nm3/h (wet)
NOx in: ≤ 300 mg/Nm3, @ 11 % O2, dry, as NO2 (24h average)
NOx out: < 80 mg/Nm3, @ 11 % O2, dry, as NO2 (24h average)
NH3-slip: < 15 mg/Nm3, @ 11 % O2, dry, in gas phase (24h average)
SNCR-plant for Högdalen, Stockholm
SNCR-plant for Högdalen, Stockholm
Fuel: MSW.
Thermal capacity: 34 t/h waste
Flue gas flow 148 860 Nm3/h ( wet) at MCR,
Flue gas flow 183 922 Nm3/h ( wet) at design values,
Flue gas flow 71 555 Nm3/h ( wet) at min load,
NOx in ≤ 300 mg/Nm3, d, @ 11 % O2, d, as NO2 (daily average), at
design value
NOx in ≤ 250 mg/Nm3, d, @ 11 % O2, d, as NO2 (daily average), at
MCR
NOx out < 80 mg/Nm3, d, @ 11 % O2, d, as NO2 (hour average)
NH3 < 8 mg/Nm3, d, @ 11 % O2, d, (peak value in gasphase)
SCR TECHNOLOGY – Selective Catalytic
Reduction
Technology based on the use of a catalyst
More than 95% NOx reduction with limited ammonia slip
Can meet stricter incoming legislation.
Possibility to reduce dioxines
.
DeNOx-Plant – Spittelau
PROJECT DESCRIPTION
1 SCR-plant for 2 separate grate fired waste-to-energy-lines
From 2011-2015 Spittelau plant will be completely technically renewed and
economically optimized including a new SCR-DeNOx system as low-
temperature process incl. a heat transfer system.
MAIN QUANTITIES:
Flue gas flow rate: 220.000 (2x110.000) Nm³/h
NOx reduction: <70 mg/Nm³, dry 11% O2
NH3 Slip: <4 mg/Nm³, 11% O2
Customer:
WIEN ENERGIE GmbH, Vienna
Commissioning:
2012 - 2015
SCR Sales Meeting Vienna, Oct 2014
Guido Caruso
guido.caruso@strabag.com Page 15
SCR DeNOx-Plant – Spittelau
SCR Sales Meeting Vienna, Oct 2014
Guido Caruso
guido.caruso@strabag.com Page 16
DeNOx-Plant – Spittelau
SCR Sales Meeting Vienna, Oct 2014
Guido Caruso
guido.caruso@strabag.com Page 17
Reference INCINERATION PLANT
Termovalorizzatore Bolzano
NH3 slip : 3 mg/Nm³
Incineration Plant Belgium
Plant: IUOM IBW
2 DeNOx Systems for INCINERATION
delivered and commissioned in 2009
Project Data:
Flow: 40.000 Nm³/h Line 1
Flow: 60.000 Nm³/h Line 2
Temperature: 230 °C
Emissions achieved: NOx Abatment: 85%
Nox baseline: 500 mg/Nm³
NOx Reduction : 70 mg/Nm³
NH3 slip : 5 mg/Nm³
