Sample Problem #2:
There are 30 kg of solute in 100 L of H 2O. (a) What is the weight of solute that will be
extracted by 35 L of ether if the distribution coefficient is 4? (b) If a 3-stage
countercurrent extraction system is used, what is the weight of solute that will remain in
the raffinate?
   Given:
              V1                                                                     V2
                                            Extractor                        35 L ether
              L0                                                                         L1
                     30 kg of solute in
              100 L of water
       (a) What is the weight of solute that will be extracted by 35 L of ether if the
       distribution coefficient is 4?
Solution: K = mass of A/ mass of B                 4 = 30 kg solute / 270 kg water
              mass of A/ mass of C                     mass of A/ 126.805 kg of ether
* 35 L ether (1 m3 / 1000 L) (3623kg / 1 m3 ) = 126.805 kg
       0.111 / 4 = mass of A / 126. 805 kg ether
       mass of A = 126.805 kg ether (0.111)
       mass of A = 3.522 kg solute
   (b) If a 3-stage countercurrent extraction system is used, what is the weight of solute
   that will remain in the raffinate?
   Given:
   V1                                                                            Vn+1
                                                                              35 L ether
                      Extractor              Extractor                 Extractor
    L0                                                                             L1
         30 kg solute in
         100 L water
Solution:
             L0 + Vn+1 = M
             100 kg + 126. 805 kg = 226. 805 kg
              L0 xao + Vn+1 yn+1 = L1 xa1 + V1 y1
   Assume x = mass fraction of solute
            100 (0.30) = (100 – x) + (126.805 + x)
   x = 100 (0.30) + 126. 805 (0)
            100 + 126.805
   x = 0.1322 (126.805)
   mass of solute in the raffinate = 30 kg – 16.77 kg = 13.23 kg