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| M A T E R I A L S A F E T Y D A T A S H E E T |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : Buehler SamplKwick Liquid
IDENTIFICATION NUMBER: 20-3564, 20-3564-320, 20-3564-640, 20-3568, 20-3560
PRODUCT USE/CLASS : Acrylic hardener
SUPPLIER:
Buehler, Ltd.
41 Waukegan Road
Lake Bluff, IL 60044
EMERGENCY: 800-424-9300
INFORMATION: 847-295-6500
PREPARER: Technical Department, PHONE: 847-295-6500,
PREPARE DATE: 11/29/06; 29 Nov 06
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
---------------------------------------------------------------------------
01 Trimethylolpropane trimethacrylate ester 3290-92-4 10.0-30.0
02 Isobutyl methacrylate 97-86-9 60.0-100.0
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 N.E. N.E. N.E. N/E N.E. NO
02 N.E. N.E. N.E. N/E 50 ppm NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: COMBUSTIBLE. Harmful if swallowed. Causes skin and
eye irritation. May cause allergic skin reaction. Inhalation of vapors
may cause irritation, leading to headache and dizziness. Contents may
develop pressure on prolonged exposure to heat.
ACUTE EFFECTS - EYE CONTACT: Moderately irritating to the eyes. May cause
swelling, tearing, and redness.
ACUTE EFFECTS - SKIN CONTACT: Frequent or prolonged contact may irritate
the skin and cause a skin rash (dermatitis). Repeated or prolonged contact
may cause sensitization.
ACUTE EFFECTS - INHALATION: Liquid aspirated into lungs may cause serious
injury or death. High vapor concentrations are irritating to the eyes,
nose, throat and lungs. Prolonged inhalation may cause central nervous
system depression with headache, nausea, and dizziness leading to confusion
and unconsciousness.
ACUTE EFFECTS - INGESTION: May cause nausea and vomiting.
CHRONIC OVEREXPOSURE EFFECTS: *Preexisting pulmonary and dermatological
disorders may be aggravated by exposure to hazardous components.
OTHER INFORMATION: Not Applicable.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION, EYE CONTACT,
Continued on Page 2)
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9101995
Product: 20-3564,20-3564-320,20-3564-640,20-3568,20-3560
Preparation Date: 11/29/06; 29 Nov 06 Page 2
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Immediately flush with plenty of water. After initial
flushing, remove any contact lenses and continue flushing for at least 15
minutes. Have eyes immediately examined and tested by medical personnel.
SKIN CONTACT: Immediately wash skin with soap and plenty of water. Remove
contaminated clothing. Get medical attention if symptoms occur. Wash
clothing before reuse.
INHALATION: If symptoms occur, remove to fresh air. Medical personnel may
administer oxygen if breathing is difficult. Seek medical attention if
symptoms persist.
INGESTION: Swallowing less than an ounce will not cause significant harm.
For larger amounts, do not induce vomiting, but give one or two glasses of
water to drink and get medical attention.
NOTES TO PHYSICIAN: Not Applicable.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 108 F LOWER EXPLOSIVE LIMIT: 1 %
(SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: 8 %
AUTOIGNITION TEMPERATURE: No data
EXTINGUISHING MEDIA: ALCOHOL FOAM, CO2, DRY CHEMICAL, FOAM, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may rupture or
explode (due to pressure build-up) when exposed to extreme heat.
Irritating and/or toxic gases or fumes may be generated by thermal
decomposition or combustion. Vapors are heavier than air and may travel
along the ground to be ignited at locations distant from the source;
flashback of flame may occur.
SPECIAL FIREFIGHTING PROCEDURES: Use NIOSH-approved self-contained
breathing apparatus and full protective clothing. Use water to cool
exposed containers. Water stream directed into fire may cause frothing
with subsequent spread of flame.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove or
protect from sources of ignition such as flames, pilot lights, and heaters.
Wear appropriate protective equipment during cleanup. Absorb with inert
material, such as clay. Sweep or shovel into loosely-covered waste
container and remove to appropriate waste area. Dispose of in accordance
with federal, state, and local regulations.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Wash thoroughly after handling. Avoid contact with skin and
eyes. FOR INDUSTRIAL USE ONLY.
STORAGE: Store in a cool place in original container and protect from
sunlight. Refrigeration recommended to extend to product life. Keep
containers closed when not in use. KEEP OUT OF THE REACH OF CHILDREN.
Continued on Page 3)
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9101995
Product: 20-3564,20-3564-320,20-3564-640,20-3568,20-3560
Preparation Date: 11/29/06; 29 Nov 06 Page 3
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: General ventilation usually adequate. Supplemental
ventilation should be approved for use with combustible vapors.
RESPIRATORY PROTECTION: None normally required under general ventilation.
If TLV/PEL is exceeded, if use is performed in a poorly-ventilated space,
or if inhalation effects occur, use NIOSH-approved vapor cartridge
respirator in accordance with applicable health and safety regulations and
manufacturer's recommendations.
SKIN PROTECTION: Clean clothing to cover skin. Butyl rubber gloves. PVA
gloves. Supported PVA gloves.
EYE PROTECTION: Safety glasses. Chemical splash goggles.
OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower.
HYGIENIC PRACTICES: Follow good general industrial safety practices during
use. Do not smoke or eat during use. Follow all MSDS/label precautions
even after container is emptied.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 279 VAPOR DENSITY : Is heavier than air
ODOR : Mild fruity ODOR THRESHOLD : No data
APPEARANCE : Clear EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Reacts Acetate
FREEZE POINT : No data SPECIFIC GRAVITY: 0.896
VAPOR PRESSURE : 2.4-4mmHg@20degC pH @ 0.0 % : N/A
PHYSICAL STATE : Liquid VISCOSITY : Low
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Exposure to heat, sunlight, loss of dissolved air.
INCOMPATIBILITY: Strong Lewis or mineral acids. Strong bases or oxidants.
Free radical initiators. Oxygen scavengers.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Toxic monomers.
Aromatic and aliphatic hydrocarbons.
HAZARDOUS POLYMERIZATION: May occur if exposed to elevated temperatures or
catalysts.
STABILITY: This product is stable under normal storage conditions.
|=========================================================================|
| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Trimethylolpropane trimethacrylate es Not Applicable Not Applicable
Isobutyl methacrylate Oral-rat 9600mg/kg ECLo-rat 3600ppm6h
Continued on Page 4)
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9101995
Product: 20-3564,20-3564-320,20-3564-640,20-3568,20-3560
Preparation Date: 11/29/06; 29 Nov 06 Page 4
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| SECTION 12 - ECOLOGICAL INFORMATION |
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PERSISTENCE AND DEGRADATION: Readily biodegradable. 74% in 28 days.
TOXICITY: Very toxic to aquatic organisms.
LC50-96hr (rainbow trout) (flow through) 20 mg/L.
EC50-48hr (Daphnia magna) >29 mg/L.
EFFECTS ON EFFLUENT TREATMENT: The product is substantially removed in
biological treatment processes.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
|=========================================================================|
DISPOSAL METHOD: Review all current federal, state, and local regulations
regarding health and disposal for appropriate disposal procedures. Product
“as sold” may be considered a hazardous waste under Federal RCRA
regulations. When cured, product is inert and non-hazardous, and may be
disposed of in landfill if local regulations permit.
|=========================================================================|
| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Not regulated in containers <110 gal
DOT TECHNICAL NAME: N/A
DOT HAZARD CLASS: N/A HAZARD SUBCLASS: N/A
DOT UN/NA NUMBER: N/A PACKING GROUP: N/A RESP. GUIDE PAGE:
INTERNATIONAL SHIPPING NAME: Resin Compound
INTERNATIONAL ID NUMBER: UN1866
IMDG CLASS (1°,2°): 3, none PACKING GROUP: III
IMDG EMS: 305 IATA CLASS (1°,2°): 3, none
|=========================================================================|
| SECTION 15 - REGULATORY INFORMATION |
|=========================================================================|
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed, and is considered, under applicable
definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD FIRE HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 and 40 CFR part 372: none
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No components found.
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous materials are among the top five ingredients.
Continued on Page 5)
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9101995
Product: 20-3564,20-3564-320,20-3564-640,20-3568,20-3560
Preparation Date: 11/29/06; 29 Nov 06 Page 5
|=========================================================================|
| SECTION 15 - REGULATORY INFORMATION |
|=========================================================================|
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous ingredients are present at greater than 3%.
CALIFORNIA PROPOSITION 65:
No Proposition 65 chemicals known to exist in this product.
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: D2B, B3
COMPONENT RCRA CLASSIFICATIONS: Not regulated
COMPONENT RCRA CODES: Not Applicable.
CERCLA RQ VALUE (MINIMUM): None known
|=========================================================================|
| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 1
PREVIOUS MSDS REVISION DATE: 11/24/03
REASON FOR REVISION: updated section(s): 2,5,9,12,13,16
VOLATILE ORGANIC COMPOUNDS (VOCS): 896 grams/ltr (calculated)**
**Calculated for liquid component ONLY, mixed system is 100% solids**
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Health and Safety Administration; UK =
United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL =
Permissible Exposure Limit
DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
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<END OF MSDS>
9101995
