Thulium nitride is a binary inorganic compound of thulium and nitrogen with the chemical formula TmN. It can be prepared by reacting thulium amalgam with nitrogen at high temperature.[1]
| Names | |
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| IUPAC name
azanylidynethulium
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| Other names
Thulium mononitride
Thulium(III) nitride | |
| Identifiers | |
3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| NTm | |
| Molar mass | 182.937 |
| Density | 9.321 g/cm3 |
| Related compounds | |
Other anions
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TmP TmAs |
Other cations
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ErN YbN |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Physical properties
editThulium nitride crystallises cubic system with Fm3m space group. It has a sodium chloride structure.[2][3]
Chemical properties
editIt reacts with Tm2In at 1220 K to form (Tm3N)In.[4]
References
edit- ^ B. Magyar. Preparation of rare earth nitrides from amalgams. Inorganic Chemistry. 1968 7 (7), 1457-1458 doi:10.1021/ic50065a041
- ^ Panwar, Yeshvir Singh; Aynyas, Mahendra; Tejraj, M. K.; Sanyal, S. P. (2014). "Pressure Induced Structural and Electronic Properties of Thulium Nitride". Advanced Materials Research. 1047: 147–150. doi:10.4028/www.scientific.net/AMR.1047.147. ISSN 1662-8985. S2CID 137447411.
- ^ "Magnetic Characteristics of Gadolinium, Praseodymium, and Thulium Nitrides". pubs.aip.org. Retrieved 2024-02-19.
- ^ Martin Kirchner, Walter Schnelle, Frank R. Wagner, Rainer Niewa. Preparation, crystal structure and physical properties of ternary compounds (R3N)In, R=rare-earth metal. Solid State Sciences, 2003. 1247-1257. doi:10.1016/S1293-2558(03)00151-1
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