7.198.200 419 —-MECANIOLE Sud 257 2aa5 oR! ans: pase $100, ue Sheinocke Et urea 10/5109 Stnbroke Sse Ea pie 0 Seni (Quebs HIV 389 (61) 267012 aro: MonsiaurDorts Tremblay DEIEROM: {ae Daplessls MARSULEX DATE: 2004-10-78 OBJET/SUBJECT MARSULEX PROJET NIPROJECTN': 030268 TELECIFAX: (544) 645.6070 PAGE: 1 DEIOF: Ps MESSAGE : Bonjour Doris, Cijeint une copie du NACE STANDARD MR0103 paur c-culation a Mario Lessard, Salutations! Avertissrmont concornant a confcantisit&cGontivenco Natteo cx couminio: goa srewon, ean sah sat cetety e Ifamaere eorEoo tale (cists: vs want plates px. Toute eaicston cia SCOR or Se ea a Seed mgd so coarnere ry arin eel gus gers oa oe Mgt Nat Se Pa Fangs So Steen fem it preach bs Law Sty acon 237, 4544800 NetiPAe Tica wie Hash gntmne sy amor pes Se el tavucacl ara wuznten by 90s [PAAR DAVSER'S-CUNE DES PAGES WEST PAS USE PLESSENSN AY US IF OVE OF THE PACESTSNUECTHLE Peaterone meeaneKR Jest 10-18-64 16:22 A? MARSULEX INGENIERIE DE + Sis 257 2445 payccT-19.2004 4:35PN —PECAMIOLE S14 257 eae 7 NACE Standard MRO109-2003 tem Wo. 21305 a eeOw THE CORROSION SOCIETY | Standard Material Requirements i Materials Resistant to Sulfide Stress Cracking in Corrosive Petroleum Refining Environments Tris NACE |namatioral standard represents a consansus e} thoso individual membara who havo reviewed tis document, Is zzepe, and prowisans. is acceplanee cose net In ary raspast prastuda anyone, wnether he Fae adepiog tho ciandard or net, trom manufactving, marketing, urenasing, of using pocucts, es prosadtes rat in coniormance with this standard Nothing contained in this NACE Intamtions) standard isto bé construed as granting any right, ty Implication or ctervee, 10 manuiacure, sol, or usa in eanraction wih any mothod, aoparatus, of product covered by Lats Patent. or a8 ifdamritying oF provecting anyone against abil tor infringormant of Lo:iars Patont, This standagd mpmennie minimum rosuioments and should in no ‘way bo Intersceled as 2 resticion on tha Uso af babar prococuros oF matarials, Neither is hs atancned Injended to apply in af casos rokaing 10 the subject, Unprecictable cvcumstancus may egal the usalufross af Uris standard in spadife Instaness, NACE (ntamational assumee no espent)bilty for the intorpfotaion of usp of this standard by thar partes nd accep's respensibilty {ar only thosa offelal NACE Irtgrnatena inerpreatiens itevad by NADE internaticnal in accordance win is goveming procedures and polcies wien praca tho ‘esuanca of inearpretations by indivenal volun Users of tis NACE Internatona} standard ala rasponsibe for reviawing sprapriats health, walsty, fendronmenta, and registry documents and for determing their anatcantiy ‘t relajan to the Shandaid prot iis eee. This NAGE Intematens}sinndad may not nacessanly aderess all potsrial heeih and alaty gronions cr enwlonmencal nazards associted vid) the vse af fratetals, squipmort, neler oparaora cotilled er ralovod to wih the standard. Usore of ths. RAGE infermatona sandra are aio faspOsbla for esashina appoprata hea, saary, are enviranmagalprexcien practices, 1 eaneulaten wit sperorriain regulary aurhontios it nigcosoaty, fo acrovs comeliance wit ay existng apaleable ragusiay requirements pict to tho Ute ef na sana, CAUTIONARY NOTICE: NAGE Intamationalstardarde ara subject to peste roviow, and may bo revised or windawn at any time withcu: prior notice, NACE Internayional requires that action be then ta reafir, ravi, or withdraw Mis sténdard no latar than fv years tro the date et initial Publication. The usar (s cautioned to obtanthe fates! econ, Purchasers of NACE Invornational Etandards may recave current Informaten on ati savdarcs and othor NACE Inernationa! publications by contacting the NACE Iternstionat Mamaership Sarvicos Ropariment, 1440 South Grook Dive, Heaston, Texas 77035-4906 (Themen +1 201/228-8200}, ojos 003.93-15 Sehun Creee oh PROPRIETE 3440 Shut Cleak Dino PRIETE DE uion Toes 7a 08 Se eert ee BPR-BECHTEL ISBN (.57590-168.9 2003, NACE totesnatienal N1-405 i 10-18-04 16:22 At NARSULEX INGENTERIE DE: S14 257 2405 poeceT.18,2004 P.2 S4PM PECANIOUE S14 257 2445 i wr0103-2003 Sse » Foreword “This NAGE standard dofines matatal requirements fo rasistaneo to sulfide sxess cracicing (SSO) in cour vofnoey process erwiianments, lO, enviranments that contaln wat hydrogen suida (HS) if ia inanced ta bo uflized by refincris, aqupmant marulacturars, eraineering contractors, aré construction contractars. ‘ne term “wat HS cracking’ at ucod in tho rofnirg industry covers 2 range of damage Pechanfame that con a2cur cue fo He effects of hycrogan charging ic wet HS rofinery or gas plant procaee environmonts. Ona of ha types cf material damape that can occur as a resuk af hycroaca Fhaming = wlfde atross cricdng (SSC) of hard weldmants aad mecrostuctires, which is pddrecced by this standard, Cier ypes of matnial damage incudo hydregen, bistaring, hydrogen nduced cracking (HIC), and siress-onented hydrogen induced cracking {SOHIC}, which ‘re nol adrossad by this stardard, Histerially many ond users, industry organizations, 6.9. API!” and manufacturers that have spoaiiad and eupplied equipment and products such as rotatng aquipmant and valves to the Tifning industy have uane NACE Slandare MROI7S' (a data, materials raqurements 10 prevant SEG. Howovat has alvays bean recognized that rofning orwironmants. ro outide the scope cf MAROT7A, which was developed spacttealy for ibe oll nd Gas production industry. In 2000, NACE ‘ex Group (16) 231 wae formod 10 davolop a ‘etinonyspectic sour saree matnrias standard, ‘The etancard is based on the goed experience gained vir the MNO175 stand, but taierod to refinary gnvronants and apaleabogs. Cihar references for this standard are NACE Standard Anata," NAGE Publeatene BXio4" and @X204,* and iho rofinirg experience af tha take group mambars. The materials, haat tratmen;s, end mpieicls property msquramante cot fonh in ths standard represent tha bast jadgrmant and experiance of TG 231 and its two sponsors, Sp2cife Teealogy Group (STG) 34 (Potolesm Rafnirg ané Ga: Processing Inéusty Corrosion) and STG 60 {Comesion Mechanisms}. In many cases this judgmunt js based 09 extensive experience in tha ol Gnd gae prosuction induct, a6 documented in MRITZS, and Nas buen: deemed relevant to the ‘wiring Indusiy by the task prove, Whanover pessble, the recommended matrials ara dated by rornnee to agcented guner Geserbials Gut 28 UNS” rumbers) andor accepied standards, sue a2 AISI,” API, ASTHL ASME," ANSI, or BSI" standards, ‘This standare wns prepared by NACE Task Group (TG! 231 on Suifide Stress Cracking. 7 231% eminisiored by S76 34 on Patoioum Refining and Gas Precassing. It's also spensered by STO Be gn Goosen Mechanar. Te eta sua by NACE Inlerratienal unéar the auspices of T In WAGE standards, the torms sha, mst, shoud, and may 216 used in accordance with the Gofinkons ofthasa terms n tho AACE Ppblentons Site Manual, 4h ud Paragraph 7.4.1.9 Shait dnd mas are used to sine mandnbyy raquraments. Tho trm should is usad fo slate something fecd and 'S rucommended but i$ nox mandetoy, The fim may is used to state samethirg considered optional 1 american PeYaloum aiiin APD, 1029 1 RW, Wamhraion, BC NCS, > ata and Alloys In tha United Nuqboring Systm (ates evil), |somatve Engeeers [ne (SAE), $00 Connmorneat Orive, Wararda’e, PA 18088. 2S gemaveat ron ated Stal natura (AVS), 1159 (Sn SL NY, Prachingan, DC 2ece rat. ‘ASTI Ietamatanal {AST), 100 Garr Harbor Dr, West Conshonocken, 2A ates. "YABNE tnlernatonal (ASHE}, Three Path Avan, Riew Vera, NY 10318-5490. 'Amnican Halen Shards nsthuto (ANSI, 1018 Lt npfath Sioneande neuen (BSI), 2 Park St, London WIA 23S, UN, NAGE Intezni vy, Wazhrgien, RC 0088, ional 10-18-64 16:22 A! MARSULEX INGENIERIE bE t 51a 257 2aa5 ‘a jon} putes: ot ASTN Internationa] (ASTRA) ard tho Sociory oFCeT.18.2002 © A:BHPN PECRMIOLE 514 287 2aas wRo109-2003 redo ty meoe> NACE International Standard Material Requirements Materials Resistant to Sulfide Stress Cracking in Corrosive Petroleum Refining Environments Contents 1. General 2. Ferrous Materials 3, Nonforrous Materats. 4. General Fabeaton Requirements. $. Baking. 5 6. Pinting, Coatings, and Diffusion Processes. 7. Spacial Componants 8. Vanes... _ “46 9. Compressors and Pumps 7 Referenc : 7 Appendix A: Backarcund Information on Hardness Testing ard ‘equitements (Nenmandatery) Table "Rad Map" for This Sta : Table 2Maximum Hardness Recuiremo imbated Alloy Steels. Table 3—Composiion Requirements for Austenitic Stain e85 St2€18 «1 an.0»m Table «-~Accoptable Cold-Warked Nickel-Chromlum and Nickel-Chromium-Melyodenum Aioys and Maximum Hardness Requirements ‘Table 5—Accaplable Precipitation Hardenable Nlekol Alloys, Canditions, and Maximurn Hardness Requirements Toble @—UNS 9130035 Hoot Treatments... Tabla 7—Accaptable Taanlum Aloys, Condiions, and Masimuri Hardness Requirement - Table @—Common Boling Materials That Meet Section 2 and Section 3 Requiremenis.. a ii NACE international LO-16-64 16:28 A: MARSULEX INGENTERIE DE : S14 257 2445 pod1o-16-e4 16:28 cer.19,2004 | 4:34PH PECANIOLE Sta 257 2005 MA0103-2009 — Section 1: General tat Scope uth standard fines ator raquiremants [or resinenee 10 SSC in sour patrcleum” rafong. and ralaiad processing orvrormanis coniiog H:S Bas’ 125. 98 or clsofvodin an nquaous (vata) phase wi or witoutine pesenco af hyarocaoon. Ths standard doce net neds and rot Intanded to induce deson spocfeaions. — Olher forms of wat HS racking, eronmerial ersckig, eorosio, ad char modes o isiuro, athough ou'seo tho coop of Uis eandard, should bo considoied i tha casig and operation of caubmert. Soveraly corccime andor hycrogan chamghng concitons "may lord to ‘alas by ‘mochanamo over than SSC and stould be mitigated by mothods that are outside tho scope of ths tans, 1.1.2 Spociicaly, this standard is dimcted at me ‘owentian of SSC of equomaet and cormorant usd Rite ring incusny. Pruventon of S80 In exon Soo materi eatopraed uneor Pa. 1 Sec 1X ‘of 18 ASME Boiler and Prossure Vessal Code’ is audmncnd. by rgeuiing comolatcd with NACE Stacdard APOA7C 12 Appicabilty 1.24 This standard apps to. a components of equemers oxpased 10 sour refirery environments (as defined In Paragraph 1.3) wharn failure by SSC wouke: (1). compromize "tha inkegnty of tre grcssura- containment system, (2) provunt te basle ‘union of {ho equpmant, andor (2) prevent the equipment trary Doing. festored to an oporaing eandiion wile ‘continuing to contain prassure. 1.22 Ibs tha cosponsibity of tha user fo dxermina tho oparatag conditions and fo spacty won tis standard applies, 1.22 It [3 the uter's responsibilty to ensure that a matarial wil be snistactory in the intendod envronment. Tha user may soloct specific materials for use on the basis of oporating condone that induce pressure, iwmporaure, comosiveness, dd propertas. ete. A varity of cancidato malara's may bbe solacied trorn this standard fer any given componunt, Nonfised matanals may atte 08 used ‘aazed on either et the following processes: {a) ta motallargeal view based on ecient and ‘pirical knowadge atest that tha SEC restnneo wil bo adpauais, Thee muromhts may then be proposed for incision io fo. standart uBiaing etnocs in Paragraph 1.8, NACE International Ab MARSULEN. INGRMTERTE Qe) if a eiskbased analysis indicates mhat_me occurrence of SSC is atcoptabla in thm rubject ‘appleson, 4.24 Tha manufacturer ls reeponsbia for mootng motalurgicalrequiraman's. Factors Cantibuing to SSC 119.1. SSC is dosinad as cracking af a mata! wndar the combined action of sila syess and corasion jn the proconsn of walor and HS. SSCs a form ol Fyarooan ‘stress cracking resuling trom abserpton of atomic hyerogon tha is produced by the suliéa comosion renation on tha motal tuclace. 192 $80 in tetning oginment is atoctag by caynplexincorastons of paras include’ fa) chomieal composition, strongth (as indleated by hareness), Foot Heatmart, and micrastructuro of He ‘malarial orposed 19 tha gour arvironment Ib) tom! tonsiie stress presont in mie maieial (applied plus residual: (0) the Iyeregen tux gonorated in the material (ich is a funclon of he onvirenment, 12., présanca OF frou water, HS eonennvaion. pH. and over onviranmonts!” paramoters surh as cyanidas and bisuliga on concentration); 18) tamporsture; (time. 1.8.3. Mataral surceptbity to SSG is primally related 15 matanal erangh (2s incleated by hardhasss, hich is affected by chorveal composition, hoat treatment 3.1 SSC hee ret qonoraily boon a concesn for carbon sioe's yplcaly used for finery pressara vassals and ping in wat HS service bocause these steals havo aulfzienty low hardness levi, However, improperly haatueatad marcia’, weld dapotit, and haatallacted zonos (HAS) may ‘conlain regions ef aigh hrdneso. 12.4 SSC suscepibilly for & given material Ineveaces vith ineraata teria arose. 1.28 Residual stresses contribute t0 tho oveeal tensio stress level, Hon resicua stresses assodmed with welds incronse suscepliiity 10 SSC. 7 2005, pes1o-18-04 16:23 A: ceT.18.2004 | 4:36° ‘MRO103-2003 43.42 Genel of woldment arches, with oF vahout reduction of rovdual syesses, is 3 recognized metrod for preventing SSC, an foutined in NACE Standard RPON72 for P-No. carbon s:00l 1.35 Suscoptbifty to SSC Is. alto related 10 tho pyeiogen permeation fx in ie stoo}, wie primarily ftsodited wit twa environmen parameters: pH and 'S contort of ro water. Typicaly, ne hydrogen fine in steals has been found to ba jovest In rees-noutra fH solutions, vith Ineasing fix at tol lowe! and Aigner pH valces, Corrosion nt (ow pH valuos is tausod by HS, whoroas corrosion 3% high pH values is Caused Ey high concanvatiens of tha beufid jon. In frany rchnery cour water onwanrasni, dissolved fammaria @ prosont, which wereasos Wha pH tereby incroauing te soublity of H.S that results in high ieutida ton eancereraton, Presonen al eyarides at lovaied AH can further aggewvate tha degree of aternic twerooar chung inl te steel, SSC suscepttiy fe kenawe to Inereaso wa HS content, oa, HeS part procure in tre gas phase, or HS contant af tha watar haso, Tho presence ol as ide as | ppamw at HaS in {he wator haz been found la bo suffejant ocausa SSC adr carat ay promote aageee hyeregen nargieg, 1.3.5.1 Some enviromental conditions krown to eauro SEC aro those containing trea water (in iquid phase) andi a), >50 ppmurdiccotved HaS tn tho foo water, OF (b) treo wator pH <4 and some dissolved He Present, or (0) fee walar pH 27.6 and 20 opm cissolven hhyaregen cyanide (HCN) in the water and soma izsolvad HyS presont, oF 4.9.8.1 Tho highpH rte, endionmon: citaramiara refinery sour sevice from tha oT ard ge preducion sour endfonmens covered ty NACE Standard MAOYZ5, Because many wel Sour stron in produciion ‘ico cortain entban dlexide and hence extitet lower pH. Another meer aiforence is that hlonde’ ion concentrations ‘ond 10. be Sigrcanty fowor in scllnery cour eenvices than in oil preduetion seur seNces, 1.96. lhereasing jenmoaraiura Ineroasss he hydrogen charging polental povided me trea water (hn auc hast) is act eimnnted by the elevated yermparatsre. Brevated tamperae prometos dssccistion of HS fois nycrogen), @ (hersey produeng mora rrer MARSULEX 1HGEMTERTE HECANIOLE Sid 257 2u8 4 Iherenses: tho difusion rates of monatomic hydrogen in metals, Swreby promoting hydrogen charging. Hovawor, cracking potential is maximized at neat ambient tomparature, This dstnetion ia. impotent ‘beeaues motals ean become chaxped dung hig emporature exposure anc eubsaquonty crack dura Qmursiens to lowar iemporaturss (such as duriag shurown: 13.7 Tye time {0 failure decreases as materal sbength, tola|_ tensa sims, and onvkonmeria’ Chargng potersial inereaso, Exposure tne to cause SEC enn ba very short H tha other SSC tactora foe suscoptilty. Same suscapliblo aqupment can fi va during short zour water excursions such a6 those ‘encoumerad during equipment snwiewns, 138 Tha ond user shall determine whotroe no paramoters necessary 10 ciusé SSC excl in te Drovers envionment, ard whetnor tha équipment ts {ethin the seapa ois stand. ‘The end user may ry on experience, isebasod analysis. of tha above quduires” (notaely the enstermenial guidatines Poréad In Paiagreph 1.5.1) 10 make iis Golarmiation. When thase gudalines, aro used to tatsrmine whether the equipean fais winin the secee ff ig standard, concioeraton choud ha Qven 10 amt pocratng scanares and the Weel Impact an he franian of eanstucton, ue, normal poration Gheraioral upsets, aterraio (pessile, futue) Sheraton, ond sar-uplshuriown e@retons (2.9 Be suliding ol catalysts, etc} Materials Indudedin This Stanoard Act Materals inelucod In ths starcird ara resiotant for but not neeosannly immune 3, SSC. valeras have bean Included based on thor eumorsircted errtance t0 SSC in {id oppicatens, in SSC loborarery text, o both, 4.4.2 Listed materials éo rot all arhitit (he samo 18.9! revstarce 0 $80. Slandard laboratory SSC txts, idk ne toto rere in NACE Slaiard THOT77. Eo" aecalariod and cavern thats. Malorils Mat Heosstuly pasy these tosis ero generally move tonsa’ to orale sour serice an Matera Dist fal the ests, Many alloys included in this standard perm satslactor in four zewvice even teuph Hey fray era in karan) tes 1.49 Improper. design, processing, instalation, oF handing! can cause rosistare matciais to beeomo ‘suscoptbla to SSC. 14 No eifort has bean mac in this standard ta rank rmajocals bared on thelr telarve resistance 10 SSC. Selecion et the appropriate matorial for a aiven eplenton depends on 4 nuriber of faciors, inclusng frechonea) propenies, corrosion rosilancs, and NACE international bE : Sia 257 2045 OBA:35PN— MECANIQUE S14 257 2865 relative rosistance 10 SSC, anid is beyond he seapo of thie etandare. © 145 Athoush many of the materials ays mata 19-18-64 16:24 At condone lsfedin his standard coincide wh matorals ang materal conduors Usted In NACE Stondarc MFO:75-2003, thor aro some instaneos in wnich signifeant dlerancas ost, A universal “eontast symbol (as coricted at la in the lefvhard magn o! @ paragraph indicates tha material andor matariai Concition requirements tpacifed In that paregeph andor its subparagraphs} contrast sawacarty wen Ure comasponeing requirements in MRO175-2003. 1.8 Hardhess Roquimmerts 15.1 Hardnassis related to tonto szenan. a pimary factor in SSC suncoprbiy- Bocruse haidness eshing is ponoasiucive “and. routes relatvely mirar eamponenispacirsn preparation compared wih ‘eoalateaing itis cermoniy used by manuacturrs in Production gualty sontrl: ard by users. in kd Inspection, As such, 8 maxiom olowablahaniness it spoctied a & prima recuirement for many af te rraverais in ts stand. 11$.2 Soveral otferent harness somles are used in this standard. The most commonly used scales are Rooctowall “C* (HAG), Rockwall “0 (HABS), Brine (HBV), and Vickers 5 kal or 10 ict (HV 8 oF HY 10), Background infermation on these hadnose exalos and tha lage bartnd the various ceferunces is provided in Appendix A. 1183 Handnwss osing and reporting shall bo porformed in stiet campiance win tho methods Hoscibed in te appropiaio ASTM standards Appendix A fois, the apprcprae standerds for the various fost motneds, 4.54 Tho standard tect paramaten: (inconters, loads, ‘and majorioxd dwa) tina) shal to used tor all Rockwal tests. ‘Tho specinan, tomparau'e tor Raciwol stag shal bo 10" fo 35°C (50° to 954 Ro Tubicamt shal\ be used. Because Brinel nats are nly Indicates {9¢ Sleal riaterils in this standard, all Brine! tests snall 02 partormod using 3.000-kg! oad a 10m indontar, and the standard 20-seco%e ewell timo, 1.58 In some cases, maximum aloeabia hardness ‘values ara provided in'both HAC (et HABS) ard HAW. In those instaness, eiter seals may be used, 186 When Nardness requlremerrs are stated in HW, and tasting using stabanary Binal equoment Is fot viable, losling chal ba poriarmed Using ‘he Comparzen hares rest method [cammenly, out Incorecily, refored to.as pertabie Bnei testng) NACE International MARSULEX. NGENIERIE MAD103-2003 15.7 Whon appicable, he conversion ables in ASTM E140? shal ba used for conversion of hardness valuos, ‘ablainod by othor tost mothods to HAC, HRBS, or HRW values. However, It should be noted that tables fer many maieizis co not Ovist in tat standard, The fables should only bo used for malariais spectically {sted fn iis ecopa, Conversions may be performed ‘hused on wmpireal cat for materials that aie nt ‘cavord when approved hy ine usar. When converted hardnoss values ao uilzed, they shall bu reported in ‘accordance vith tho raguirarton's spociind in ASTH! E 140. 15.8 Acceptance critena for microhardnacs tosting (GS dafined in ASTM E 286") aro outskia t10 scopa tha standard See Apponeic A tar more intormauon. 1.8 Procedum for the Addin of New Materials or Processes 1.61 The addition of row materials andlor procastas reqoltes the use of NACE's standard lator balatng prceass. 162 Mmerals may be doled based on flold serpavianee andee Isboratory tos cata. “633 Fist Experience Data Requiremenis 1.8.8.1, Field experiance data shall fally decument tho. allay compesitionis|. concitionte), and harcneas level(s), ihe prosors fluid parumaters nat Infusrcs SSC, andiha exposure history. 1.6.32 In cetain dlloy families (euch at duplex stainioss stews), microstuctune js alo a crifcal Variable, and chal 80 ba coeemontoc, 1.64 Laboratory Tast Data Requraments 1.64.1 Tha leboratery testing of matarials sallbo conductad a low! of smuonty as dicted by NACE Siancant TMOV77, I actual services concitions avn. eusice thesa, imits, SSG of ‘ppreved matariale may bo possi. 1.6.4.2 Tho cancidata mater) must be tasted in aczordanos will the Yast precoduros astabiished in NACE Siandare THO177. The tensio bor, C-ring, heat baam, and doublexantiover boan as doscribed in NACE Standard TMOI77 are accopted test specmens, Any ct inesa cst spacmens may bo used. 1.8449 A citimum of thvon test specimens tram Gach of ‘ee dforant exmmaycialy proparad thaats ust be insta in ine canton baFoted for ‘nelusin. The camaostion ef anch heat and tho heal koaimeris) used shal be furnished a. part ‘altho BaloL 1ho candidate maton sampasiion fange anwor UNS aumoer and its heatisated 3 DE : 514 257 2445 por10-18-84 16:24 At cer.19,204 4:3 MR0103-2003 ccondiion requested for inelusion in this standart must ba incuded wet tre baler. 1.8.84 ‘The hayetons af oachtost ancien must bo datormlned and tnported 2 part of sho Dae, ‘Tho avorage naronoss of each bt specimen shall pe tho arenas of that test spociman, The imum fort specimen tarcnoss aktined ff & Bie Reunion shal b We eas of ea/conditon fer tha purpasa of baikatag. The rrantimum hatdnoss request for Inclusion af ie Cancsdata vaya In his sanaaed must be ‘Epocifed in tha Ballot and shale supported by We data provided. 1.645 In catain aley temilins (such as dupox sianless steels), marastuctuce Is also a criteal Yariatla, axd shall alza bo documeriod for oach oaticondiion. 1.846 For arch of the tests, performed, tne Insing corals shal bo reported as part ef tho ‘iar Zor being sutra. 17 New Restrictions and Deteied Materials 1.7. Tha sovisiontalet process may ba used Inepose new ‘astictons on matarals or to dio ‘trials from fi standard, Naw rasinetons may inelode suen dems as impostian of a madmum Fardness requremort, reducicn of a maximumn hardness toguiramens, elaenason of a provoury fecoptablo hentiaatmant condtan, efmingion of a proviously accepiabia mansacturi proctss 6 172 Mectd mafia in use a tha fine of io Change that complied with pron version of ths Standard ang fat have gol experiance HaS-arharoad ‘oneronmental Cacking in fen curent appicaton are ‘considored in complanca wh ihe standard, 4:73 Wren alfecied matenn’s 2 deserbod in Paragiaph 17.2 evortualy removed from tit arent oppleaian, fonienment magia must De Sowcted fom accestabo materia th tha curent Sovsion of ths staard io be in compl wth bis Sandard, xcept aan In Pasageph 17.4. 1.74 Now equipmont manuactured from attecied ‘raterials, ax well oquipment rafubishod using cme componants manviacured for alfocad alesis, may be qualflaé for uto in specvle agplcations 1 Aegordanco wr te prosese dascrbed in Paragraph 18 1.0 Qualifeation of Unisiad Aloys, Condtons, andior Frocessas far Spectie Apahcatons ad Aoye, cosdans, ard processes that ar8 not tou In tis alandard may be qualfed for use jn Sspoctic sour apahcaions. Ths secion provides Ihe MARSULEX. (NGENIERTE PECANIOLE S14 257 2403 19 minimum roquimmaris tor compianca with this gainers when unlisted alloys, condtions, andor procosses for spectle applieatens ere qualia. 148.2 Tha vs0tchall bo rosponsible fordstarmining ho uinblty ofan unisted allay, condiion, andr proces fora space appheaton based on faboratory tae! deta, fold oxperioreo, andlor rick-basod arniytis, 192-1) tsborainy tasting wil be used as an Eccoptancs basis, tasting shaule bo eanducted in ‘wiin accepted standard test matheds those documanted in NACE Standard Lad fled expariance andlor fsk-basad analysis wl ba usd a¢ an azcopianca basis, theve aro amber of {aetors thal choud be considered: fa) The stress leval, mterinl farm, forming process, Foattroniment conedtion, microstructure, ard ‘nechanicw properties (paniculary hardness) of the Feld axpovance specimen shculd ba weir ‘secumentec, fo} Tho envirarmental conditions to which the told ixparlance specimen is oxposed should bs welt documented. (@) The feld axparanca expesura time should be Mdoguain fe enaire that tho unlisted ally. eanditon, andlor procaes provides resistance to SSC. 1.8.5 The suitably of the unlisted alley, eonditen, irdor process for a Specie appliarien should ba Selormined boned on a compacive ovaualan of to eevionmental tondtions in whe nlorded specite Spalesten vs. tre envirormental zonchions In tre [boretory toate andfer tha field experience. 1.86 The composition, matetal torn, forming procassas, Nealirosiment corditon, and rachael Peporioe of equipment manufadures using en fnibrec aor, conden, andr process ehauld bo cantrolag bazod en tha corresperding infannaton ter fhe lobaratory tect spacimons and’ Yelc experiance specimens 107 Urtisted alloys, conditions, andlor processes cualtied ter specie zpplcalions aed on tho formants fy te eaction shat nat Becomo ait of Ins stad unless they azo appexed trough ‘he sSandtre NAGE daloting procoss. standaré Road Map 419.1 Fer ease of use, Table 1 provides general information by malsiavapsloatan group, as well 2s relerances o spesiic paragraphs that eaver apaicatia rmatefialand tabrieaton requirements NACE Intemational DE : S14 257 2445 Pos1 cer.sa.z00 4 HECANIOLE SM 257 2415 9 ‘MAD103-2003 ‘Table 1—~"Road Map” for This Standard _. Tia Groep | Applicable Applicable ‘Material Fabrication Materst Group or Requiement | Hequrerment Agplentian ‘canetons alowed Parpgrenns) | Paragraph) | Carden Stoels: fa) Hot rolloe at 2.1.8, Section (o) anneal 3 {eo} Normalized {g) Normalized and tempered {6} Narmalaso, ausantane quonchod . and tempperad (1) Auslenitized, quenched, and imparad . [Rey saet (a) Anresled a a Be {0} Nomad i {@} Norralzed and wopared {d) Normalized, austonitzad, quancred, | Stenpoted (o) Austere, quonchod, and | ferosee Feri Dole rea = zea ers SaMIBSS Sectors Steels _ ‘Spectic Martensiic — | (a) Nownaizod ‘and dauble-tempened ey 24.3, Section Seinioes Soole | th Guonened aes coubietampared 4 Specie Girehad and cube tampatee wae 245, Seti Tow-Corton ‘ Manonste Sininiess Stoo acon Soe — p SSSI BE Seaban a Sioa . ‘Speawie Austonite ‘Solion-anneaiedar hot-ralied 2a ‘Section + Slanass Seals | Fgh Aye Saararranader eoutenanseaea | 27 semana Austenitic Stainless cond eoid-workod Soot Sinec Sao | SSCTPETET 2 2B Secioa cle 4 | Precipiiaicn- SOLMon-AInealed and precipitation: 2a) ‘Soction & | caren iss | pcrod mn ‘Sold-Solulor Nickel | Soluiten-anneales ont ‘Saction + Atovs Preepinter Varaus ae Sector Hardanaale Nicke! alo Cobol chal Wai cra Sais a Chron kyadont Aloys Canin Waren aw Suaiaet Shramum-Tuncaen fits atm Ags | vases TE Sane NACE Intemational 5 10-16-04 16:25 At NARSULEX INGENTERTE DE : 514 257 2405 pooeer. 10,2004 4:565 HECANIDIE Sta 257 2 303 Pale ¥MRO103-2003 Fppleations = =] Applicable | Applicable Matorist Fabrication Maio:tal Group oF Raqulromont | Requirement on Canditlons Allowed Baragraph(s) | Paragraphs) Vanous, - jection | Sect 4 Bo ‘Warous ‘Sscton5 {NA {prods Contaga 1 Various Sochan 6 TNA. ‘Special Carrpenanis_| Various Section Soci ‘Vawes. Vaious Soetion 8] Saeian 4 [ Gamaessors aed [varus Soction S| Seetaon 4 [Pumas Ox 10-18-04 Carbon and Aloy Stoe! Materia’: 2.141 For me purposes o! this sansard, the folowing ddofiidons apply: BAt-1 Carbon stesl: an iran-based_atoy Containing carbon (usualy tess thay 20%) an ‘rangannea (usualy not loss than 0.25%), with no spooled minimum quently for any atoying lement offer thar manganese, scan, and copper, and that enatains ony’ an incidental ‘amaunt cf any elernent ther than earbon, slicon, ranqanaso, coppor,suifur ad poasaten. 2,191.2 Aloy stl: an for-baeod soy containing carbon {usualy less than 2.5%) and mangarese fusually aot lvaa tan 0.25%), fat contains Spocifad minlmum quantties for ono er mero alloying elornants other than mangansse, siicon, ad caper, and that doas nosspoedy a riinium c|chremiuen content greater than or equal fe 10%. 2.1.2 Tobe accoptatle, carton and allay sls must: (a) not cortain Intontonal adelsons of elamants soch as faz, selonium, ar suite 1 improve 1b:25 A: MARSULEX INGENTERIE etrous Matertats {by _ meet the eritora of Paragraphs 2.17, 2.1 Secton 4, an3 (2) _be used in ona of the folowing host conditans: |. hot-rlied (eaubon svt erty): anneated: ‘normalized Wv, normalized ane tersperod; ¥. ormalized, austeniizod, quenched, and tampered oF Yi, auslonlized, quenched, arciteerparod. 24.9 Cakon steals Inted 3s P-No. 1 Group 1 oF 2 atari in Section IK of the ASHE Boiler ane Pressura Vestal Coda ure acospinble without base onl hardness contron. Waldiag shal ba convolied in accordance wih Paragraph 2.1.8. Tha hardness o! hetormed P-No, + piaing and piping ftings shell not cxcood 225 HEW, 2.1.5 Aloy stools included urcor thu ASME Boilor and Pressure Vessol Gade Sectn IX P-Nunbora Fated I ‘Tabla 2 ava axcoplable mt tho indealed maximarn harsnosslevats. NACE international bE: Si4 257 2445 pipocr. 18.2008 10-18-64 16:25 At a37Po NECANIOLE S14 257 eHa5 reaps Bt Mr0109-2003 Table 2—Maxlmum Morciness Requirements for P-Numbered Alloy Stecls ‘ay Seat Teac HaraTese uiromarts EAs 225 BW Filo. ¢ SHEN me Po. $5 osgu GC Vaca Das HINT ne =No. SO-SUriMOW grides (PST, PAT, TST, | 248 HEY max, bot, Grads 4, C1241 BE He 23s NeW max Sac Mey ma PAs Ze HOW wax Fikes 10 205 MEW na Pil. HO = 235 HEW max Pile OF 2OSHEW mnie PNET = 225 MEW mse 2.16 Oher nloy siga’s shell hare a maximum brardnoss ef 22 HRC (227 HAV, 2.1.7 Carbon asd oy steels must bo tnarmaly stress raloved (alowing any cok! dalorring by rcting, cole forging, oF anattur marctacturng precocs tha rosuite ina permanent outar Sher deetmadon areater tras. 5%, Thonral stress rafot shall be perlormed in ‘etordanay with tha appicabe ASME Codes, exces. that tha minimum stassolof tomparoture shall oo 559°C (I,100'F), Afar sts ralevng, carben stools listed a5 P-No. 1 materias in Secton IX of tne ASHE Boiler and Pressure Voseol Codd chall moot a hardness reqsiromeri cf 220 HBW maximum. Other evan and alloy ctaule hall meot thn approprate harchess caquroments in accordanea with Paragraph 2.1.4.215,0021.6, 2.7.4 This fuculromort doos rat apply 19 ed ‘work impared by pressuro tosing accorad toe ‘pqlicable coda, Cele-ratary staightaned pipe It sees ory wen relied At ppectiealons, Coldworked na pin fithgs of ASTM A 53° gaida 8, ASTM A 106" grace B, ‘API BL" araco X-42, or ‘ower stiongth gradas with ‘ilar chorieal composilens ara aocaptabia with ‘aid svan oculvalons to 15% os, proved the hardnass ie the sra'ned area does notoxzoed 199 FEN. 2.1.8 Welding and Oretiays on Carbon Staes and AAlcy Stecls 22.81 Faascaten welding and weld evoraye ‘Shall ba performag fr accordance ath the generat raquiremerte Keto in Section 4. 2.1.8.2 Ovolays aopled 19 carton end eley stools by tharmal precesses such as welding oF lnerma-spray sysiems are selstectory for uso sour ewrenrronis. those eases in whien be NAGE International MARSULEX. INGENTERIE lawer ethical temperature is exceedsd, the ‘component must be heat veated cr thermally strass refaved according 10 procedures that have bbaen shown to roturn tha basa mmol to an aczopradie conditen (Le. tdaess}. 2.1.8. Weldments in carbon steele feted ac P Wes 1 materials in Socticn IX af the ASME Bole and Pristue Voseel Code chal ba produced using ona of tho methods outinad in NACE Standard RPO472 to prevent excessiva waidmert hareness. 3.8.4 Vioddmarts In aloy stools wih assigned (SNE Baller and Prassuro Vessel Cede Sacton IX P-Numbers thal! not excesd the hardness ‘mits speciled in Paroqaoh 2.1.5. Tha hardnoss of materals winaut assigned ASME Boiler and Prosaure Vessel Cod Sectlon IX P-Numbexs thal Not exceed 227 HBW (22 HRC} masimum, 2.1844 Saye industry codes (euch as ANSINE-23"Y allow walding Of PAND, 3 anc Pitle, 4 alloy stools withoin postweld haat treaimer (FW) 1 corain circumstances, NonFWHT proceduies of wis tea my be uiiized prowdod a harenwes traverse as ‘boen portrrted on ths proeraure quaificasan record (POR) spocman fo demonstrate. te fbliy of tho procedure to preduce waldmen’s ‘of ncceplabla hardness, The waverse sal ‘encompass th kaso metal, WAZ, ard for Metal att Top and bottom athe wekkmert, find thould no cancucted in necordance went Figuo 2. or 3. (as applicabo) in NACE Slandurd APOS72. No icivicual reading ena excord. 248 HV 19, Oher aly. gest materiats shot always mcave PAYHT wnin 1s stardard appies to ensure law haednese in tha wad matal ard HAZ. A nardness averse, as desciived above, shall bo 7 DE : S14 257 2445 pul10-18-64 16:26 A ara7PM MECRATG ‘MA0103-2003 performed on te POR specimon to derranetrata the abity Of tha PHT tims and tumperaiure ta produce weldmonts acceptable hardness, 22 Cast onand Ductile Iran Materials 22: Gray, ausianife, and white east trons ara rot ‘neezptabla for use as prossura-consiaing morbars. These mxtorals may bo ueod in ietornal eomponants related API ard otver appropriate standarcs, provided ‘heir use has baen oppoved by tha purchaser. 222 Fattc duct ion In aosodrca with AST A 395" Is accepiebie for equipment when API, ANSI, ander otter ndusty standards agprove is uso. 2222 Wolding Is nat permitted on gray east iron ot oct iron camponents. 2. Fomic Staines Steo! Matarials 23.1 Furmhic stantess steels are accopinble al a 22 HAC maxmum harchess prodéad tay are in the ‘annaalad cancion and moot tho crea cf Section 4 2A Nartaestic Stainless Stadl Materals 241 Maronite staiioss steels (UNS 341020, 42000, 191150 (CA1S}, and 19113) (CATSM), other east of wrougyy, ive acceptable at £2 HAC rraximum Farchose provided ay are heat veated in acardarce ‘wit Paragraph 2.4.11 and meot tha eater o! Seton 4 Vararions conizinina aloying elerrants such as fead, velenium, or sultr to improve machinablty sre fol Acceprablo, Marionsitsstairlass steo's that are fn secercance wih this standand Nava _provicod taistacioy fald senvice in somo sour anvicormonts. ‘Tosa materials Mey, however, exit shresild eos lvoe in HACE Standard THO'77 Ianoratary twats Wat ao Iowar than the lsvels fer ote matarals cluded in ‘his stand. 24.1.1 HeatTrealmant Procedure (Three-Step Proeese) far UNS S47000, S4zc00, J81150 {GAI5), ard 91151 (CAIBM) Martansitc Strings Steel 2dcle1-t Austaridze and quensn eral cool, 2ALA2 Tomper at 624C (1,180°F) ‘minimum; nen air cael to amblont emparature, _—_——_________. Tye haringes corrlaton iauleed I ASYM E 140 aos nat fn Borah une to pormiscela hme 2 WOW 285 rasa, when Na toy. a MARSULE! INGENTERIE E Sia 257 2405 24.1.1.5 Temeor at 621°C (1,190°F) ‘minimum, but lewor than tho fir sompering femperaure; Tien ar cool to amolont lamperalur 242 Loweabon, 12Gr4NeMo martensite swinlass sine], ether cast UNS J81S40 (CABNM) cr wroLgnt UNS 42400, ara acceptable to 23 HRC™ masimum provided thoy avo hont treated in accordznce wih Paragraph 24.2.1, Variations containing aloving ‘olomonts such a laad, selenium, or sutur to prprove machinabiity aro not accaptsbe, 2.424 HaatTraatmont Procidata (Throw-Siep Process} 2AQAA Austenize at 1,010°C (1,850°F) minimum and air or oi quench to Ambion! ‘omeeratute. 24.2:1.2 Tompor a1 649" 10. G91°C (1,200°1¢ £.2759F) and air cool ta ambient temperatura, 24.2.4.3 Temocr at $23" 10 621°C (1,100° to 4.16056) and ai coel te ambinnt temporaturo, © 249 Weldeg and Ovedays en Martnsiio Saintes Saas 24.3.1 Weldments in marlonsite stainless steals sie Paragraph 2.6.1 ahal undergo a PHT at S21'C.(1,159°F) minimum and shal prod.co ‘eekdmenthardnoss of 22 HAC maximum. 24.2 Weldmonts in bavearson manenstic Stain ess sels defined in Poragmph 24.2 shal! Grelago a doublvcycs PWHT ator trst cong ‘cooled jo amblont rornporiture. Tra doub'e-ayclo WHT shall consist of Neaing a! 671* to 631°C (12H te 3.278°F), cooling ta ambient amporatura, followed by heating at 879° 0 621°C. {1.07580 1.150°F 2439 wating ray oly vs permed on sare trails bend in Pavagtegh 2.4.2 thal hve prevausly boon austiniized, ‘quenched, 3rd Goubiotupered, Woising botenon marinate Sstehioss stone and othe’ maesials, (includno ‘ann steels, alloy steals, end austenite osinoes Sale) ie nude Be secpa of his Sancard 2434 Ovetays applid 1a mariensiic stainless soola by Mera procosees such as weleng, Eien brazing, or thermat-spray ystems aro safolactory or use fy sour environmen's. ‘nthaso faasod in wisn Bye lewor ental temperatures are $j 99 UNS 291840 {CABNE) er UNS $42400. V7na9 harps is rns 3 bean eeplocally eotermicad i be eGaaiet (0 29 HAG for these NAGE international bE: es? 2445 pl?19-18-04 15:26 VECRNIOLE Sia 257 2 T.18,2004 4:38 exceeded, 1@ companont mus! be heat veated or thermally sas ralaved accoring to proceduras that have baen showy ta retum the base mati to 22HRC maximum, © 25 ustontic stsinoss Steet vaterials 25. Austenitic stainbss sieets wih charrical compositions as spncited in Paragraphs 262 and 2.7.1 are aecoptabia ata hardross cf 22 HAC 1a, Fla MAD103-2009 macimum in tho sokiter-annoaled and quenched of solution-annealed and thermally staalized conditon, Provided they ane fee of celd work intonded tc @rhanzo thelr mochanical propcrtas. Stains stools cenmininng lead cr selatium for the purpece o! improving machinnbitty are no} arcaptabts 2.52 The chameal compositian requitoments for the fly austenite wrought product ‘ons aro shown In Tobe; Table 3—Compasition Requiremonts for Austonitic Stainless Stools Cc Element Waight Parcont O10. lz|9Io) 360m 2, 1 0 max. max. B01 mar taj oie (0.0d max. "ha chaniea! composters of tho caut‘eusenite' elaliasa since ston vary trom the ono uly austen) wrought eourcarpacts in ordor to eptinizn eating evaractvisies. Mary ol thaze alleys er intontonaly balanzod to eankan coma forte, tlc tenders Om ponaly magnet. 2.5.9 Unisted clements, such as melybdonum, Aironen,, ttantum, ioblum (columbum), te, a8 accepin, provided tha requirements isied in Poragreph 2.5.1 are met. 25.4 Higher carbon centorts for UNS 830500 and UNS 557000 ara accepola up 10 tho limits af their rxpoetive spaciieations. 26 Spocifc Austenitic Stainons Swe! Grados © 261 Austeniic stainless toch UNS $7510 is ‘oeepiade ia. tha . sDlutoranneales, —bololad (reveckswertad), of edlé-werked conetian at 35 HAC maximum hardness, 27 Highty Ateyed Austoritic Stainless Stsels 2.7.4 Highly aloyed austentfe stailoss stials in tho composiion mange. soectied in Faragreph 272 are acceptable al a 35 HAG maximum, hardness in the solufon-annealed sondiion o° soluton-annoaled and Cold-worked conation. Fresmactining Nahly wloyed suslerite staltless steels are rotacenptabie, 2.72 Tho chemles! composition raquirements ‘or the highly aloyod austoniée siainloes stools x6 as folews: SEMI « (2x Mo) ~30 and Mo 22% ‘inal pardnoza naxsirement ebtancd on dopo salose sels contol ba eriverton to Rackcvel C acing oslakng tablez Pitting Resistance Equivatent Nurtbor (PREN) 240% where PREN is daterminod as shawn in Equation (1) PREN=%Cr + 33 1%MO+ 0.5 x %V}~ 16% (1) Meine ont fre a group at aaye fama composooal standpoint, Uso of the PEN factor fo precicy yeiaive ‘compsion resistance a outside tho scene ef 1s Giana © 25 Ouplox Staiioss Stee! Materials BAA Wrought end cast duplex siainioss steel ‘products in the coluion-anraaie:! and liguic-quonched ccond'ion ara acceptable at 28 HAC! maximum forces. ‘Thy fenfia content shan bu 25 ta 85 vor%. ‘Aging heat featmenss to Incraaco skangth andor hardness aro prohbtod dye io tha formation of erexiting prases. 282 Wolding of Duoiox Sunless Stoels 2.0.2.1 Weki procadira qusifcationyspacite talons for duplex stainioss sigals shal luda ho foloning isms: (2) Tho POR shall include a hardness ‘raversa conducted cing tha 10-hg Viekors (HY 10) socio. Ten wavesse shalt encompass we des® mora, HAZ, snd flormetal at the op and botomat the STE “40. Use of ompliady davad tebis (or corworaion is suostte Ieagpreval one user, NACE Internattenal At MARSULEX INGENIERIE 514 987 2aa5 pisocT.18.2004 4 40103-2003 vwaldmant, and shouldbe conducted in acrardace With Figue 2 of 3 (at appeals) in NACE Standard APO472 Tho average hardness chal pot exceed 110 HV 10, and no Indica reading shall excovd 320 NV 10, (a) The POR shail incude an analysss ot tno femnto conant of tha weld dees and HAZ. Tho analysis shal ba, conducted in accoruanca winASTM E562," and the measured fermi ccontant shail b6.5 1085 vor%. Tho FGR shall Ist tha heat input uslized dino ogattaton te rentinid by Euation 2. fampe x vols x60) a ‘ravel spend |e) The welding procodure spacieaton WPS) shal rast Me heat ingst casing walding tothe POA heat input vatio 210%. to) The POR shall list she wal thickross of the POR spocimen. () The WES shat not slow woldia of ‘componons wt wall :cknesses that devia by som than 20% from inat al sve POR spesiman. 2.9 Precipitaton-Hardgndble Sahors Steel Matar 2.9.1 Austenitic praciptatin-tacanable sinless fied vat chemical conpoation ja aecercanca wih UNG Se6260 is accopanis a 35 HAG maximue harsnuss provided itis ojhar tho eokfon-annaied Grd aged or sohiber-amealed and double-o¢ed condition. © 222 UNS 17400 and UNS $15500 wrougnt Tarnonsite peciptatonhardenable sani steels ara ‘Beeoptabe at 3 HAG maximum farinoss in oer HITEOD conden (heat treazed in. gocorganca wity Paragraph 29.22} or HIA80U4 senditon (haat te in accercaca wih Paragraph 2923). ASTM 8 747 Carco-} and CB7Cu-2 casings are accentanya nthe {1150 DEL condition (heat rostod in accoraarce wah Payageaph 2.0.2.2) at 310 HAW maxmm (30 HAC Maximum). Preciptaionthardonabla marensiic sangse stele that am I accordance wi) this Sundard have proved satsiactoy Seid sevice (9 Some sour criranments, These) mazarals may, Fomever, axint thrasheld sass lovois in NACE Sandend THOY7? labaraiay fete Wot ore tows AM those af afer matedasirclxes In thes standart. 2921 The felloving cesviations spcly to UNS Si7400 and $18800 whan esa mvetAs a0 ted for pressure-obinig BEND: 10 Lo-16-64 16:25 A! MARSULEX INGENIERIE NECENIGLE S14 297 2445 neeos Ftd {fa| UNS S17400 and LINS $1580 shall not be Used for prorsurdvetaining belting applications 17 ‘ha daupie-H! 150 ecreition. (b) Whon UNS 517400 er UNS S15S00 is used for prassurerotaining boltng In tho 11104 condition, a masimam harchess lit of 2 HAC shal apply. 29.2.2 Double H1150 (H13S0D, H1150 DBL) Hast-Treatment Procedure (a) Souton anneal a 1090" 214°C 1,800" Bere) ard air cod), oF suitable quid quench, to iaelow G2C (OF. (b) Hardon ai 621° #14°C (1,150" 228°) for hours minimsm st lempornturo and cocl in ato alow 92°C (82°F), (e) Harden at G21" 14°C (1,150" £25°F) for 4 hours minimum at temporature ard coc in a. (a) Addtiona’ cycles at €21* 214°C 1,100" 25°F) may be wifeed H required to prodce an ‘peeophabl tardiness level 2.9.2.3 41 150M Hea! raatmont Procady‘e (0) Soluion arnost at 1,003" 214°C 1,900" 2s-2) and wir coal, or suitable liquid quenen, to boow 32°C (S0'F), {B) Hondan at 76c* s14°G (1,400" L25°F} for 2 hours rrinimum et temperature afd, cook jn a so Below 22°C (20°F) oefore tha oeend procatat o1- hardaniag step. {eo}. Preciptation harden at 623" 14°C 11,150" E25'F) fer 4 hours minimum a temperanura and Ceol in air, {g) Adotiona! cycles. at G21" 18°C (1,150 S25°F) rray be utllzod Il requirad te produce an ‘aecopteba hardness level. © 233 Wrought UNS $15¢00 maronsite praciptatons harconaple svainlass steal iS accoptable at OV KAO mubimum hariness provided it nas boon heat wasted ae folowe: 2931 Twa-Siep Heat Treatmont Procedure {a} Setution anneal, [b) Procipitation harcon at €21°C: (1.180°F) or a iminrwrn of 4 nous. NACE International DE : S14 257 2445 piaCCT.18.2003 4:3SPN MELANIE S14 287 esas tano103-2009 Section 3: Nanforrous Moterials 3.4 Nickel Aloys o 14.88% Crevinimem, BAt Solid-Seunen Nekel Aloys, 52% Nix Co minimum, ond 12% Mo rinimurn, a.t.fe1 Wrought or east sokézolution nickel: chromiumioldenum adays, with compasions © 31.12 Wrought UNS Na6G00 is pecantatte 19 35 as spectfad in Poragraph &1,1,.1 are accaptab'e HRC maximum, ‘nthe soltor-annaatec condtion. © 21.1.3 Wrought UNS 108800 Is ecceptabis 19 35 31.494 Tha chemical compeaition HRC reasimur. ecuitomerts. tor tho Sol-soluton nicesl- cehromjurt-me'ybdensm alloys aa 31.1.4 The aecopinble _cold-workad, | s0'. alten ricko'chromiumeaypctenum aloys and 19.2% Cr migimuen, conasponciog maximum harness requremerts 29.5% Ni ¢ Co minirun, and sro liste in Table 4, 25% Mo rrinmmum. Teble 4—Acceptable Cold-Worked Nickol-Chromlum and Nickel-Chromium-Melybdonum Alloys and ‘Maximum Hardness Requirements TS Noriber | Previous CondWlen | Waximum Hardness HoBoce i SHAG NOE ESTELGT a0 HAS bees SSAC 6 Salatoe-anraaied sQHAC icss65 = 20HAC NOGHDS, = Ba HAC NI0276. Soimier- Armed HRC © 341.15 wrought UNS NOHG00 and NDEAOS, ond == @Q_3.1.2 Precipitation Hardenaple Niko Alloys fast ASTM A 494" Grados M351, M25-2, and MGC are accoptabie ta 35 HAG masimum. 3,121 Thu acceptable preciptatior-hardarablo Tiekel aloys, conditions, and comespording Imparum farses reiremons ao icod ia a5. NACE Intornational 1" 10-16-64 16:27 A! MARSULEX INGENIERIE DE + 514 287 2445 pasOcT.18.204 423EPMECANIOLE Si 257 2a P16. mAot03-2003, ‘Table S—-Acceptobla Procipttation-Hardonable Nickel Alloya, Conditions, and Maximum Hardnoss Requirements TRS amber” | Accopiable Candiontey 7 Hartmut Hardness TOSCO Hot workog and age hardanad oF coluer-annanind or sokiion-anneaieg and | 38 HRC ago-raidore, WETORT Soliton-anneslod BERG Tahaton-annasied and aad wi TEI" fo B7FC .A0O Te LEO oramaamur | 40 AAG | stanours. ei Soluton-arnosla nnd ane — [aoe GEES ol compacted pawdor, oluforannaniad (27° [1,700"F] min} a0 HRC anaaee 628 6 [80 10D. ete sera 1380 Pa 0 TOE, Saluion-innonied ana 6030 —— ae HR NOTrIB Solaton-annocted of hot- worked or hetwarked and saad 35 AAC Soluionsannaaled ane ag0e ef Coe. eoutor-nanndied, ana aa0d 0 HRC Rares Solulon-arngaled and ngod aa AC NO77EO Solution-arnagled or eoucovannasiod and ngud or har wantedornorworkod [3S HNC and aged i ROS ‘So\ion-arnages are aque —— aoRRE No79¢4 | Solujon-arnosled and sed Taras NOT ‘Solution-arnoaied and ego ‘SO HAC NoBa25 Cold we ed or cok. ton anes 35 AC ‘Soluien-arnesied and egad 3H HAG. Gold werked aed agad or notinahed and Sasa asa ______ [Gast soluton-arnecled, ard aged —LssAC 22 CebaltickolChromlum-Molyocenum Aloys 322 In additon, UNS ADDS is acceptebie a 51 HRC mpinue In ine cold-reducod. and high- 224 Alors UNS ANgC0s, UNS BOOK, UNS tarrpo ature age ea Yeated eonction n azeordanca 820035, and BS HAI are accopable at 35 HAC ‘hone ofthe agirg swatment: provatedin Tabls 8, maximum axeept whan otherwise noted. ‘Table 6—UNS F30025 Heal Treatments inimura Tine ‘Tomporsture Abours) 4 POPE ROOF, 4 TSEC {1.350°F 6. TEAC {1 AOSD = OBC {1.450°F] 2 BOC (1.757 FL z 316°C (1,500°F} © 3.23 Weeught UNS 21259 Is acceprable In the tn Mls standard, For example, hydrogen embriiternent cltfon-anroaled condaion to 93 HAC maxim=m. ‘of tkaakim alloys may cecur if those aleys a1 gavankally couded ta contain active metals {0.9 3.3, Cobal-ickal-Chremium-Tungeten Alloys Carbon stad) in HaS-comaini'g aquecus media at yomoarntures q/oatar tan 60°C (176"F). Haroness 2.3.1 UNS RSCG0S is ascopisye te 35 HAG has net bon shcwn to corralate with eusenptibilty 12 maximum, SSC, but has been incladed for alloys wii high atrongth to indeate tha maxmum tasting levels at ‘34 Thanium Alloys ‘which falure tas not occurred, 3.41 Specfic guidelines must bo flowed for 9.4.2 Tha accopinble starium alloys, conditions, and ‘successiul applicatjons a! ean titanium alloy spactied carraspondi'g maimim hardness requromants aa shown in Toole 7. 12 NACE International Lo-18-64 16:27 Ar MARSULEX INGENIERIE DE + S14 257 2045 PlccT.19,2031 423961 FECENTOUE S14 287 2445 MR0103-2003 ‘Table 7—Acceptable Titanium Alloys, Canditions, and Maximum Hardness Requiramonts ees THIS Woenber | Gandiion Taam edness | F006. — “M50 HBS ——| A53400 ‘Arnotied a1 70° 2100 [Aas 26 f) lor thew, aeceo__| 92 HABS saa60 ‘Aoansled or solen-anfnalodor colon annnaled and aged —4SHEC | fis6323___ | Annaated [32 HRC. FIS6H03 ‘Arnaated, _—Teenrc | ASGA04 ‘Annoaled 35 HRC. S050. Annoaled a2 HC Saction 4: General Fabrieation Requirements: 4.1 Matafals ond fabyicaion procestes shall meet the aquirurients of his secon. © 42 overtays 4221 Tungston-eartida aleye and corarties am noceptabla as anulays. Folleving apglicadon of the oy th bast mil aa mi oe hardness as specified in the porinen! paragraph in Section 20°93. 94.2.2 Joining of dissimilar cpntovn’s, nach as comanted caroidas 10 Alay steals by siver brazing, Is accepiaple. Aer brazing, cha Ease mania’ shal mest to hardness roquirernant for that basa metal as ltad in the perinant paragraph in Seeton 2 or 3. 42.3 Tho base mata? istag in Sections 2 and 3am false accopiable as weld evorlays, previded they meet tho provers of tise sespectve paragraphs ker ‘boing applied as overlays. Foloving agplictoa of tha ‘overlay, the base mterist sha? meal the hardness Fequiement for mat bare metal as ised in tho parinont paragraph i Saction 21 3. 424 Ovefays of cobat-chroniumtunason alloys, fickelehrom umbbaron, and réckel-baren (a= spactie Iq AMS 4779") havciacing alloys exe vccosb Foling apalcation of tha overlay. the basw material shall maet iho harivas coquirement (or Vial base mata a (stad in 3'@ perinent paragraah in Secion & ers, © 43 Waiea 491 Al welemen’s shal magh me genes! requromonis ited slow. Specie, waling requramems a jrorcea for seme, teats in tha perineal parogrars,n whien case nese rmquiremants chal aso ba met. In caves in wich tke {pecliavélding rocubamantscontict wih tha urements cf this scion, tha spooiie materal ing. roqurements shall ovemds Uiese nena requrertents. 43:2 Waidara and welelag sroegdures shal bo qualiftad in accordance with AS," API, ASME, or ‘oor appropiate industry endes. 43.2 In simlarmeta wedments, when the weld sitar mail i imar to or equivaont ta the base meta, 1a fororess roqutament specified forthe baze ceil ahall bo met in the HAZ and weld mia! eter welding and any agpieable POT, 4.214 Dissimtarmelal welds, euch as wales producod using filer natals that are mere nobio than tha Bato mata, shall eet tre folicwing requirements: 4.34.1 Tho wold mstal must be closely equivalent in chemistry and proserts 1 a base rrataral rat {s accapiabie accersing to this standard. 4.3.42 Tho hardross lint for tho depesited wale ‘ata! chal bo the mraximum nardnoss Limi for tke equivalent taco metal in tho solulor-annaa’es endian, 4.943 Tho hares requirement spoctied ot tho bao metal chat bo mat ja the HAZ ator oiding and any aogcable PHT. @ 45 Cadcng on Carbon Steals, Allny Steels, ard Hantonsiie Stzintess Steels 44.1. For the pumoss ot ths standard, dlassing is dilined at a matalurpicaily bonded "layer ct a conosion-essiant icy materiel appli to the entra FROME Waka See, (AVIS), SEO WY, Leveure Rod, Mtam, Reka 02105 NACE Intemational Lo-16-04 16:27 At MARSULEX INGENIERTE 3 DE : S14 257 2045 pit1e-18-94 19.2081 4:59 TECANIQUE 514 257 2445 wRo103-2003 wettod surfaen of a supsirata material thal is relatively less corrasiomresstant 4.42 Accephbla fabrication motnads used for locking include hot roling, explosion bonding, end weld evaraying, 443 Cladding motorialz hall bo toisetad trom Socton 2 or 3 of this standard, and shalt mast a roquiramanis ler that alley as spaced! in tha periront paragraph). 4444 Thora are a numbor ef factors that infuanco tho SSC rasistarce ol clad componets, including, but at limited t) fa) Relate SSC msistancec! the carting matertal {b)Gotrasion res'stancs of the clad layor in the process environment (which aecis no rele of frycragen precuction) (©) Hydrogen difusion eto‘n tha dad layor to) Souncness ofthe clas yer toy ae 886 cettance of tho substato material (__Febsicafon matnods usod at junctions bens ‘soighboving clad components fo) Fabrieaton matheds used at junctions between clad components and neighboring unc'ad components (n) Gahave effects (4 tha substata | mata! Bucomes axpacod ar at Junctions wih neighbering ‘nelad comoononts} 4.445 Evaluayon of those and ather taotors is euisido the seope ef this canard. “Therelore, tha énd user ‘hall spacty whothar or othe substrate atrial must ment tre roqurements ol his starcard, Section’ Git Matorias used for boling and faslanors that are exposed‘ cour aqwermant (as dafned in Paragraph 1.3) fall moot the requlramants of his secion, The weer shad to respancib fr spectying whether boing is excosed or renexposedin accordarce wii the folowing defillons. 6.2 Spaced Boltng 521 Botting that wil be axxesed cirecty 10 the sour ‘omrormant shal moot tha requemer's of Sacton 2 ‘or Section 3. " 16:28 A MARSULEX INGENIERIE 45 Idontfieaton Stamping 45.1 Idertiieston samping using towsiress (dct, bsalory, and reued Vy stamps ix acceptable. 45.2 Conventienat srarp ¥ stamping is accepiasis in jewevesa arens, such az the outside clamntor of ‘tances, Sharp V stamping io not permitod in High. sirare arene urless tho item receives a subsequent thermal treatment to yeduee tha nardnoss to bolow he maxenum alowabia rarciness for the baso matarial as poeiod Inthe sppfcable sections of ths standard. 4.8 Threading 4.6.1 Machina-Cut Threads 46.1. Machinwcut threading procosses are aecaptable. 4.8.2 Cols-Formed (Ralleo) Threcls 46.2.1 Ahor threads havo bean cald formed, the threaded companem shall meatthe hantreatment eoneltens ard hardness requiaments given in ther Secon 3 or 4 lor the parent alloy trem which te shroxded compenant was fabricated, 47 Cold-Dotormation Processos 4.7.1 Colddoformavion processes such as burrisning ‘hat do not impart cold wera exceeding tha! Ineldontal fo normal machining operations (seh as turing of boris. olin, wading, ard dling) are accepiabia, 4.72 Gold dolomation by controlind shot pesning is permited whan applid to baso maiaiais thar meck the Fequiremerts of In etandard, anc when limtod to tha lise of ad mavimnum shot size of 2.0 mim (0.080 in.) and maximum ot 19C Almen intonsity. Tho process shat be coniraledn aceardanco wih AMS § 13165. 5.2.1.1 Exdomal bolting and fasaners used Uurdeiground, eoverod wih insulation, equipped twa tanga protectors, ar otherwise denied direst nimoephere axpesure, and thatare used 9n pina of oguioment thal contains a seur ervvonmert, shal 38 censidared upoted 10 s0u fenvronmant, and shall moet tha raquiremonls ot Settion 2 or Secton 3, 4.2.12 Users and dosignars should ba zovare tt itrmary pe necessery 11 dara te sirongth of tho faint ed tho preset rang of tho aqupment In NACE international be : Sia 257 2aa5 pig19-18-04 16:20 A: 18.2081 atdNPI — PECANTOUE Sid 257 2a ame eases whon using bolting that maots these requirements. 52.1.3 Spociatreatictons apply to UNS 817400 ‘and UNS $15509 when these alays are used for Pressuro-retaining boting. Sos Paragraph 2.9.2.1, 52.1.4 Tha boling and nut matana’s in Table 8 vor speotiealy osiablhed to ast the foouiromemts of Secton 2 cr Sacton 3, and are listed hare as a selacton aid. Nola that other smatarials meeting ha roqulramants of Section 2 er ‘Sactlon 3 are also accaplabi, noses PLS. MA0103-2003 52:15 Zine or cadmium coatings sheuld not to ‘Used on bolls, nuts, cap sere, or otner fastens, in sour environments. Thesa coatings enhance tha gonorafon of hyarogon on the turfaoa and en conitioute to hydrogen cracking. 83 Nenoxposed Batting 5.21 Nonoxposed dating and fasionors may bo {umished to epploatie standards such as ASTM A 193, A 184, and A 920. To bo considered ‘ranarpeaed)" the baling must be usad axomaly on fangos or ochar pans mat ara net ciacty oxposod #9 af enuronmants, admit dimetl oxpaced f tho aimesphare at ell ies (s00 Paragraph 5.2.1.1). ‘Table 8—Commen Bolling Materiais That Meet Section 2 and Sectlon 3 Roquiromonte f Hiator [____“Seelion Raquirament | ASTMTA 195 grad BTM | Bot Ste, Cap Screw taterals | ASTM A139 grad BEMA, class 1A TaSTMAGeO gees Me Tia Matera [ABTA 1055 pace BHM [ASTICA TSS ergo 7H 7 ASTWA 134 gro BU Soction 6: Plating, Coatings, and Diffusion Processes G4 Metalic coatings (elactopiated or _sioctoloss, convarsicn coatings, and plastic casings ec linings ara rt acceplabo fer pioventirg SSC of basa mein's. Tha we cf such eoatnge for any other purpose [auch ae woor fesistanco oF coTosion resiatanco) I outside the scope cf sancard. 62 Nriding is an aonolasle surtaco citsion tres when conctieted al a temperature below tha lowe Tempaaure of me Maen beng tostud. Is ‘roars of praventing SSC is net neroptabla. ‘Section 7: Special Components 7.4 Materials for special components including irstumontaron, conrel davices, sons, benings, ant ngs ehall meot tha roquramants of tis sacsen Ht they ate dre axposed to sour environments curing narmal eperalon f the dvica, Paragraph 1.5 proves guidelines {2 detaimine tha anpleaatty of the standard to spnciis wes. 72 Bostings. 7.2.1, Baarings creciy exposed 72 sour endrenraents hal bo mada from matodala In Soeton 2 of Soction 3 ‘ex2epl a8 poled In Parsyragh 7.2.2 Bening: made fom oihar maianas must be isolated from the cour enviraament ta luncton propecy. 7.2.2 Nickelchromium-moytdenim-tungsien aay UNS NiGO7E coming fing, 6.¢,, coe roll pins, 210 NACE Internaltonal WARSULEX. INGENTERTE accapiable in ne cojtworked condition 0 43 HRC medium. 7a Springs 7.3.1 Springs Urecty exposed to tho sour environment ‘hail bo mado from mates cesertbed in Saction 2 or Sexton 3 oxcopt at nated in Paragraphs 73.2, 7.3.3, and 7.34, 7.2.2. Cobalt nickobctramtunrmolyodequm alloy UNS ASGOCT is acceptable for springs in Ino e2id-Workad and agg-hadonod eecattion fo € HRC maximum, UNS 30035 1s accoptatie for springs in the cole werkod and age-hariened corsiton 2 si HAG rraerrum whan agod for 2 minimum of 4 nous at ct lemperauute no ower than 645°C (1,Z00°F). 1 DE : S14 257 2445 pigect, 18.2004 10-10-64 16:28 4ranew — MECANTCLE S14 257 2445, MR0103-2009, 7.32 Nickel-chromlum alley UNS NO7750 springs ae accaptabo in tho. colt-wored and agechardonod coneiien to £9 HAG masimu. 7234 UNS NO7080 is acceptable tor springs for ‘compressor valves. in. the cold-werked and age+ hardanad condtion 1a SOHAG reamur. 7. Aifrumentavon and Condl Daviess? cet esain Soci 2a Satan’ 7.1.1 UNS, 31600 austoriic stainless, sive! highty layed austen staitoss steal (fined in Prragapt 27), or nickel niay (dofned in Paragmpl 2.3) compmesion fittings, ramen viet, and instrument or central tubing wo ‘eceplable even though thoso components may net calsy he requirments stated for was0 imiterias in Sacton 2 or Section 3. 71.42 Diaphragme, Pressure-Measuring vient, and Prossura Soals 7A2A Pinpivagrns, prossure-moasatng devices, and prassuro coals cirecly exposed 10 2 sour fenecenmmart shall ba mado from materia’s in Section 2 or Soction 9, oxcept as noted in Paragraphs 7422, 4.2.3, and 74.2.4. 7422 Codat-rickol-chamium-mejtdonum afeys UNS A009 and UNS fisoco4 are acceniabia for digchregms preseure-naasurng davices, and pmssura S8ai§ 1060 HAC maximum. 7.423 Cobaltnickel-clromummofbdenum: turgsten ley UNS 90260 diophragms, ‘pressure maastuing dviows, and preasure seals fro acaptable to 82 HAC manlmum. 7.424 Pressure soals shal comply in the toquiramants of Socton 2 or Secien 3 cr may be anulachred of wrought aba ebvoriumckol malyedenum afoy UNS AI0ISA ta $9 HAC rhacimun wih the oferary loxc-veorng or ressurecontanirg dicecton pevald 2. the Inngjtudinal areling cirecten ct! wrout produc —_— 743. Wrought UNS Nas904 ( nccoptable for use a insbument tubieg in tha annosied conciicn 10 180 HY 1Omaxirun. 7.6 Seal Rings and Gackats 7.8.) Soa sings cliectly exposed toa sour ‘eeniranmnent shall ba made from rrateials In Seetion 2 oe Soction 2. 75.2 Austantc stainless stocl APL comprossion scl Tings anal quseets modo of wrqught oF contr tugaly Gast ASIN Aas" grado CFS er CFM chomica’ ‘corrpositions ate aaceplatie tn tha as-cast or soluion ‘annoaled condiion te 160 HBW (83 HABS) maximum 7.8 Snap Ringe 781 Snap mgs diecty exposed to a cout femrenment shal ba made from aogiicable matoriats in Scolion 2 or Section 3, axcopt ae roted in Paragrsh 782, 762 Precptatonhudersble slants steal aloy UNS $18700 snaa rings crginaly in tho AHSSO solution-nmnenied ond aged eandifon are aceoplante ‘whan furrer Neat trated t0 a hardness of 10 to 32 HAC ac folows: 76.2.1 Heats process} eral bo: em preeedure (hromniue fa) Tamper at €21°C (1,750°F} for 4 hours, 15 minuies, Cool to room remperatre in 0M nit. {b} Tempor at 621°C (1,150°F) for 4 hours, 15 ‘minutes, Coch forocm tammperatuee In stil at. fo) Tuanper at 565% (1,080°F) fer 4 hours. 15 inutne. 2d] to reom temperatura stl ar. 27 Spocian Provess Parts 2.741 Casat-shremium-ungeton are nicko'-chromium- boron alloys, whether cast, povdermetalLrgy ‘ot thermomedtaricaly procussed, ara 7.7.2 Tungeteccearbida alloys, wnemner cast of cemented, are acceptable. a Section B: Valves 41 Vaves shall eo! te requrmans of ths action It thay ae to ba exposed to Sour environments {ahined i Paragraph tal, A common falure mace ol gals yaves foposed to sou envormranls and not fabieated wth Rrdssececniolad comporerts ‘5 2 dmpeed 6210, rendeeng fe vata inaperaso 6 At MARSULEX INGENIERIE 82 Valves (ew or recondtiored), incieding internal eompenents, shal se manufactured or remanutactirod {107 materials hy aeeordanco win Section 2. Section 3. NACE Intornattonal DE + B14 287 2aa5 p2019-18-64 19,0004 4:40 TECANTOUE S14 287 2445, ‘MRO103-2003 Sectlon 8: Comprassors and Pumps 911 Compressor ard pump components thal are te be ‘xposod to tour environmenta (de/inod in Pavagraph 13) ‘shail bo manuiacted rom materais in accercance wit Suction 2 ef Suction 9, except at noted in Pamprophs 8.2 and 82, 32 ASTUA2TE™ Cons S5er 40 guy cation and AST lucie ron ao accaptibve as samarassor cyloce thor, pene, ond vavos.”Alunsnum ator ASTRA 22 A0G550-77 & acmupmile for pions. ALniium, sat catben sel, and eet owetton fron ore aszopasle a gaskelsincomprostors handing rou ges, 9.8 UNS 643200 andl a meu worion of UNS 52260 that contig 0.28 ‘0 0.2% earbor aro acceptable for comprnscar [mpellars at a riximum yiold steength of 620 MPa (09 ksi) proved they have bean heat sranted In Accordanea with Paragvanh $3.1. 93.1 HeatTreainient Procedure, Process) CheaSiep 92.1.1 Austenitize ard quencn 99.1.2 Tempar at 621°C (1,%80°F) minimum, but bbotow the lover criscal femparatura. Coal to ‘ambient iemperature bolore the sccond tampa. 921.9 Temper at €21°C (1,150°F) minimum, but fen than tha frst tempering lomperatura. Cool ambient iemperature, References 1. NAGE Standaré MROI7S (alos! revsion), “Susiaa Shes Crockng Resistant Matalic Materials for Citas Eqpmart” (Houston, TH: NACE). 2. NACE Stanciard FPOZGS (atsct mvislon}, ‘Guideines ‘or Detes:on, Repair, and Mrigatin a} Cracting of Exsing Pomsleum Rofney’ Pressure Vessels in Wer b2S, Envenmanta’ (Houston, TX:NACE). 3. NACE Publication #194 (atost revision), Matoals ‘and Fabrication Pracices far New Pressure Vassols Used 1h WotHsS Retinary Servica”(Housten, TX: HACE}, 4, NACE Pubicaion axe9s (atest sevicion), “Review ot Publshed Litera on Wet H.S Cracking of Stools Through 1989" (Houston, TX: NAGE), 5, ASME Boller and Prossura Vecsa} Cado, Seton IX, Chision 1 slalest revision), “Welding and Brazng ‘Qualfcatans” (New York, NY: ASME). 6. NAGE Stand RFOS72 (ast revision), ‘detiodts and Contr’s to Prevent In-Senica Envircomantal Cracking of Carbon Siael Welcinentsin Corrosive Potroleum Fsining Environments” (Houstan, TX: NACE). NACE Standard TMO177 illest rexison), ‘Laboratory osting of Netas for Resstanca ta Sue Sirecs Cracking and Sioss Corrosion racking in He Envrenmarns” (Houston, TX: NAGE}, i 4. ASTM & 160 (latest revsion), “Siancasd Harsress Sonvarion Table fo" Motals—Ratthoneh Amarg Brel Mardoss, | MkarsHardeese, | Pace | Hares Superfail Harness, Knoop Hetdnass, end Scerescope Hardhess West Cenchonazken, PA: ASTM) NACE intornational 16:29 Al MARSULEX INGENIERIE 9. ASTM E 384 (htnst revision), “Standard Test Mathod for ‘Mernindeniaien Hardness’ of Matarials" (West Conshotiockan, PAL ASTM). 10. ASTM_A S/N. SOM (asst rovislon), “Standard ‘Specrication for Pipa, Stael, Black and Hol-Dippad, Zinc Coates, Welded are Seamless (est Conshoractor, PA: M1, ASTM A 106 (latoct revision), "Siardard Specification {er Seamiess Carton S.esi Fine tor High-Tomporaure Sewvice” West Conchaneekon, PA: ASAD 12. API BL (latest ravition), “Spectication for Lina Pino” (Washington, EC: API 13. ANSIND-24, "Nations! Sewd Inspoetion Coda” (Coumbus, Ohia: The Naronal Bourd of Ralar and Pressure Vacca! inspucter) 14, AQBA ISM (atuct revision), “Standard Specifcaon fer Fernte Ducsia iron Prassum-Ratanina Castings for Us 3 Ewvaed Tomosratres' (West Conahonecion, PA: TT, 15, ASTM E 682 (latest wvicicn), “Standard Test Method {for Detornining Volume Fraction by Systematic Manuol Point Count (West Conshoboccen, PA: ASTH). 18. ASTI A 74T/A 747M (hnest ravirion}, “Standard Speatleaion for Stoel Casings, Sunless, Precipiaion Hardening” (West Conshohocken, PA: ASTM) 17. ASTM A 49470 45484 (latest revision), “Standard Spachieatons tor Gustinas, Nekel nnd Niekel Alley” (West Conshohocken, PA: ASTIN. 7 DE | 814 257 2045 pat10-18-04 16:29 CCT. 20M: | AEALPM NECANTOLE Std 287 24. Mnot03.2003 1B. BS HAS (atast wvision, *Spacticavon for Nekol- Cooat-crromumNoytdanumAtninicmTrsium | Heat Resting Aloy Blts, Bars, Forgnge, and Parts (Nikel Base, Co 20, Or 48 fo 5,814, 111.2" dance, Le 419. AMS 4773 (latust envision), "Necke| Ney, Brazing Filer Nnal 94Ni~ 35S) 1.83 1 209" wo 1,350" F(ae2* 1 1 066" Sh Spidaetinuetes Range [UNS NossH0) (amore, “ SAB}. 20, SAE AMS $ 13165 (atest rovision}, “Shot Peering of etal Parts" (Warronda, PA: SAE}, 2), ASTM A 193/A 159M (atest tovision), “Standard Speciication tor AlcySivel and Stainiss Stest Boling Matarals tor NighTomporature Sarien’ —(Woct ‘Conshohocken, PA: ASTM). 22, ASTM A. S2Q/A 320M atest rovision} “Standard Spooiization fa" Aloy Steal Boring watonas for Low Tomporstura Sarvieu" (West Conshahockar, PA: ASTRY. 24, ASTM A 194A 194M (latest ravision), “Standard Speaficatien for Carban and Alay Stsel Nut for Bolts lor Hah Pressure ond High Tarmperature Service, of Hoth’ (Watt Conehahacon, PA: ASTH).. 24. ASTM A 351/A 351 Mi (ctest rousion), “Standard Soocitcation for Casting, Austeniic, Ausunite Femitc (Duplo, for Prossure-Contaning Pats" lect Conshohocken, PA: ASTM). 25. ASTM A 27% 278M {latost mmvision), “Stsndard Spectication fer Gay Iron Castings fer Prossuro-Contaiing Pars tor Tompamturs Up to 650°F (Wes! Conshohocken, PA:ASTM). standard Wiest 25. ASTM B 2RB 26M (latest_rexision Spoctication for Aluminum-Aley Sand Castings’ Conshohocken, PA: ASTI). 27. ASTM E 10 (lanst revision), “Stancard Test Methods for Rockwall Hardness ard Rockwell Suporicial Hardnoe of Moratle Matenals* (Weat Censhohackan, PA: ASTM). 28, ASTM E 10 (latest revision), “Sianciad Test Mathod for Bing) Harcnass of Motalic Msterila” (West Cansnonacken, PA: ASTM. 29, ASTM A 633 (latest revision), “Standard Practice for Indomation Hardrass of Metalic Materis ty Comparison Hardnoss Tosters" West Conchchackan, PA: ASTM), 20, ASTM E99 fatastevision), "Standard Tost Mathed for Vickors Harena2s ot Motalis Materials? (Vest Consronarken, PA: AST?A). Appendix A: Background information on Hardness Testing and Requirements (Nonmandlatory) 1. Accurate hardness testing roquites strict compfiance wath the mats desenbod In 0 appepata ASTI ssandards, 2 Rockwall tats, performed in accnitanco with ASTM Sided E 10," avo tolatvely auch, droctreadipg tests, and as such thoy are comnenly used in marufaeturing ardronmants, ‘Those tarts liza loads ranging team 15 kgt ta 150 kgf. Baceusa of tho relatively low loads that are vslend, tha harcnéss Irdentions are small, and the Meacutomonte present tha hardross tx a vory nea ne volume of matorial. Therefore, these metiods are very ‘sarsitva, ard am suited for ident'ying incatzed ham spats. Drawbacks to this moinod ara the #20 rosbievons on ‘components that can be tasted, geometrical Eritavons that prevent testing In endain leeatons, and lack portaslity. Noje: Bagianioa in the 2002 revision of ASIM & 18, tungsten carbide balls a1 alowed for '@' reala tests in adgton to to hardened steal balls that wore sraviously required. The scala dos qnations for Reekwof °B" harness Freasuroments are now ‘ARBS* fer tests wun wih a stecl ball. and "HREW' for tests run wit a tungsien cartice Dat, The valuse raguired in tis elandiard are "HBS" valu because al tosting in te pastul'zed te sre bat indentor. HRIS and HABW test rosuts dior due to me aiferert 1B At MARSULEX INGENTERIE mechanical propenics of tha twa bal curently no snindarcized canvarsic conwarsian of HABS io HAW. 3.__1he Brine! meted, parormed in accorcancu with ASTM Standard E 10," wolves croation of an indantaisn, opileal measurement of the Indeniapon cametor, and calculation of trehardress vaio. Becaute of tha ralnively large tas: loads utlizsd, this method produces a hareness. ‘aloe that represents a7 “averago” of he instoasl harcness vera fatty Iargevalume ef matarial. Briall tasting it otter used fa measure the hardness of castings and forginas. Drawbacks 12 tris matnod ae the ska resticions on ccompenanis that ean ba teciod, gaomotneal imitntons trat pranol esting In cennin locations, and indo! porabiliy. Nots that ASTM E 10 now requires Brnell testng 19 be pérformad with n tungstan earblo bal indontor. Tho symbol “HIGH cenatas tesvng pertormedin Wis rrariner 4. Comparison hardness testers {commorly, but incoractly, refered ta as porable Binal ‘sstare) ulize a hammer blow to simulaneously indoct the component being evaluared and a tust bar of known hardoesa. The ‘oinivn indoneation sizes ara monsured and a caicuiaten 1s portormad te dojarring the harcnacs cf che compcnent. Comparison testers are cammenty utilsed to check field NACE International bE 1 S14 257 2445 pawakimonts. This tast mothed ig peared in accordanco wih ASTM Standard A 833" The harchass values obtained using tis mained ceralate drocty 10 Brnell voUSS obtained using tasting parameters defined in Paragraph 3 above, 5, Tha macro Vickers method, porermed In accordance ‘with STH. 92,” is simar 10 the Briooll matiod axcopt it makes use of a diamend ayremia indontse, Tho advantago of the Vickers mated is that it provides romtvaty foxe- Incepandent hardness values whan parformed with loads sangna fom 28 gi to 120 Kyl. tis common practice ta usa Erg! oF 10kg Viekors arches tostno for woldng precadura qualfeatons bacausa thes produces un accurate Susossment of tho wekiment HAZ haychess. Vices buchess ertria nave boon soecifed for a few stleced welding procedure qualiiesion¢ tn thir standard, kasod on proven Feld oxpaiience. ° Furbwer details aro avelzbla Ia NACE Standard RPOI72, Vickars harcnass is eobrevitiod HV. with tha tast load in kg indicated by a subscript ruber (examplo, 248 HV 10 centotes a Vickers arches of 248 eterminae using a 10-Agf lend). 6 Haruness requiremnnts spoeifed In tis standard in HOW unity ace gencraly lower than the equivalent ‘aceepinbls’ HAG values wich applies both conventional Brnel testing ard campnilson hartrass testing} to compensate for nonhemegoneity of same race forms snd wats deposits and/or to account normal variations it (ld ander procluction hardness testing Usingha curmparison haraness tsster. 7. WAG ond HRBS are cfd for particular materials of ‘roduc forms under tha fllowhg ceacitions: (0) Vénon the raw material specication [sts a naniross Fequiteent in HRC or HRBS, NACE International 19-18-64 16:G8 A: NARSULEX INGENIERIE PECANTOLE S14 287 244s ri0103-2003, 1) When the industry standard testing method fer that Froduct form ie HG or HRBS, or fe) When the materal wil be tested at he componnat eval. 8 HAVE is ctor for paricular materials or preduet forms Under the following condtions: (2) When the raw material spesifeation fate a hardness requizemant in HV, (©) Whon tha industry standard testing mothed for that reduc! form is HOW, or (©) Wun tho hardnots roqueemant partains to avahaton owed mola hardass, which is mast commanty parted sina parabie Brill hardness taster. 9, Mrchardnass evaliaton, performed in accordance with ASTM E 984 using ether the Vickars 0” Knoop mathod, may ba nacossary for somo componers that are 9 mal 1 ba lasted by convontinal matrods. — Mlerhardaes teeing wilzas loads of 1 kgl and lower. it should ba noted It merohardruss tenting is mara sense than tha macro ‘esting maeds ce 10 tho very small indontation size, Because of this senstisity, micrascopic constants such a= ond ohass can cause individual readings that ara much bighor than tho Ba hardness, Thus, it is mara effcult to establish gencml acceptance criuria based on rmicrohartiness testing. Individuaizad miccoharcness test procedures and ascosleted accoptance critena may nued to be developed for each materiatcomponent combination being svaluated. 19 2a| it oor, 18.200 as wR0103-2003, | 10-18-84 16:98 MARSULEX INGENERIE ANIGLE Std 257 2425 DE ISBN 1-57590-168-4 NAGE International S14 257 2445 p24