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Certificate of UN Test For Lithium Ion Battery

The document provides test results for a lithium ion battery that passed UN 38.3 testing requirements. Key points: 1) The battery passed tests for altitude simulation, thermal testing, vibration, shock, short circuit, crush, overcharge, and forced discharge both before and after 50 charge/discharge cycles. 2) Testing was conducted in accordance with UN Manual of Tests and Criteria requirements for lithium batteries. 3) The battery also passed package drop testing requirements per the UN Model Regulations for transport of lithium batteries.

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0% found this document useful (0 votes)
235 views10 pages

Certificate of UN Test For Lithium Ion Battery

The document provides test results for a lithium ion battery that passed UN 38.3 testing requirements. Key points: 1) The battery passed tests for altitude simulation, thermal testing, vibration, shock, short circuit, crush, overcharge, and forced discharge both before and after 50 charge/discharge cycles. 2) Testing was conducted in accordance with UN Manual of Tests and Criteria requirements for lithium batteries. 3) The battery also passed package drop testing requirements per the UN Model Regulations for transport of lithium batteries.

Uploaded by

Duy Nguyễn
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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E1724322 Feb.16.

2017

Certificate of UN test for Lithium ion battery

Customer Model :42T4561


Global Code :F12430523
Product Name :4UR18650F-ASUS

We declare that this battery passed UN test.

Manual of Tests and Criteria


(38.3 Lithium batteries) Test
results Note Number of test batteries/cells
No. Test item
T1 Altitude simulation Pass
First cycle After 50 cycles
T2 Thermal test Pass
T3 Vibration Pass fully charged fully charged

T4 Shock Pass 4 batteries 4 batteries


T5 External short circuit Pass

First cycle
T6 Crush Pass 50% charged
5 cells
T7 Overcharge Pass First cycle,Fully charged 4 batteries After 50 cycles,Fully charged 4 batteries
T8 Forced discharge Pass First cycle,fully discharged 10 cells After 50 cycles,fully discharged 10 cells
*The test data may contain additional test result other than above table.

Lithium ion battery Specification


Item Nominal value Note
Watt-hour rating 38 Wh
Nominal voltage 14.4 V
Lithium equivalent content 3.12 g
Above test procedures are compliant to the following manual.
(Manual of Tests and Criteria ST/AC.10/11, PartIII, sub-section 38.3, Rev.5A1 for cell, Rev.5A1 for battery)
E1724322 Feb.16.2017

Certificate of Package Drop Test for Lithium ion battery

Customer Model : 42T4561


Global Code : F12430523

Product Name : 4UR18650F-ASUS

We declare that this battery passed UN test.

Test item Test results Note


The package shall be dropped from 1.2m high
on to a concrete surface ( flat and horizontal )
Package Drop Test Pass with five orientations ( drop once a sample ) ;
(1)flat on the bottom, (2)flat on the top, (3)flat on the
long side, (4)flat on the short side, (5)on the corner

Lithium ion battery Specification


Item Nominal value Note
Watt-hour rating 38 Wh
Nominal voltage 14.4 V
Lithium equivalent content 3.12 g
Above test procedures are compliant to the following regulation.
(Model Regulations ST/SG/AC.10/1/Rev.18, Special Provion188)
UN Test Data ( Model: 4UR18650F-ASUS )
1.Test Item: Altitude simulation (T1)
2.Test Purpose: This test simulates air transport under low-pressure conditions.
3.Test Procedure:
Test cells and batteries shall be stored at a pressure of 11.6kPa or less for at least six hours at ambient
temperature(20±5℃).
SANYO Internal Procedure:
As above.

4.Test Requirements:
No mass loss,no leakage,no venting,no disassembly,no rupture and no fire,and the voltage
retention is not less than 90%.

5.Test Date: 2007/05/15


6.Test Data
Mass(g) Mass Voltage(V) Voltage
Other
Battery No. loss (%) Retention Result Judgement
Before test After test event
(=<0.1%) Before test After test (%)(=>90
At first 1 223.51 223.50 0.00 16.68 16.65 99.8 0 PASS
cycle,in fully 2 223.52 223.50 0.01 16.68 16.65 99.8 0 PASS
charged 3 223.06 223.05 0.00 16.66 16.63 99.8 0 PASS
states 4 223.37 223.35 0.01 16.67 16.65 99.9 0 PASS
PASS
After 50 5 223.46 223.46 0.00 16.58 16.57 99.9 0 PASS
cycles ending 6 223.31 223.31 0.00 16.54 16.53 99.9 0 PASS
in fully 7 223.65 223.65 0.00 16.58 16.57 99.9 0 PASS
charged 8 223.38 223.38 0.00 16.55 16.54 99.9 0 PASS
Notes: L-Leakage, V-Venting, D-Disassembly, R-Rupture, F-Fire,
0-No leakage, no venting, no disassembly, no rupture & no fire
UN Test Data ( Model: 4UR18650F-ASUS )
1.Test Item: Thermal Test (T2)
2.Test Purpose: This test assesses cell and battery seal integrity and internal electrical connections. The test
is conducted using rapid and extreme temperature changes.
3.Test Procedure:
Test cells and batteries are to be stored for at least six hours at a test temperature equal to 72±2℃, followed
by storage for at least six hours at a test temperature equal to -40±2℃.The maximum time internal between
test temperature extremes is 30 minutes.This procedure is to be repeated 10 times, after which all test cells
and batteries are to be stored for 24 hours at ambient temperature (20 ±5℃). For large cells and batteries the
duration of exposure to the test temperature extremes should be at least 12 hours.
SANYO Internal Procedure:
As above.

4.Test Requirements:
No mass loss,no leakage,no venting,no disassembly,no rupture and no fire,and the voltage
retention is not less than 90%.

5.Test Date: 2007/05/15 - 2007/05/23


6.Test Data
Mass(g) Mass Voltage(V) Voltage
Other
Battery No. loss (%) Retention( Result Judgement
Before test After test event
(=<0.1% Before test After test %)(=>90%)
At first 1 223.50 223.42 0.04 16.65 16.47 98.9 0 PASS
cycle,in fully 2 223.50 223.43 0.03 16.65 16.47 98.9 0 PASS
charged 3 223.05 222.99 0.03 16.63 16.45 98.9 0 PASS
states 4 223.35 223.30 0.02 16.65 16.47 98.9 0 PASS
PASS
After 50 5 223.46 223.41 0.02 16.57 16.42 99.1 0 PASS
cycles ending 6 223.31 223.24 0.03 16.53 16.39 99.2 0 PASS
in fully 7 223.65 223.59 0.03 16.57 16.43 99.2 0 PASS
charged 8 223.38 223.32 0.03 16.54 16.41 99.2 0 PASS
Notes: L-Leakage, V-Venting, D-Disassembly, R-Rupture, F-Fire,
0-No leakage, no venting, no disassembly, no rupture & no fire
UN Test Data ( Model: 4UR18650F-ASUS )
1.Test Item: Vibration (T3)
2.Test Purpose: This test simulates vibration during transport.
3.Test Procedure:
Cells and batteries are firmly secured to the platform of the vibration machine without distorting the cells in such a
manner as to faithfully transmit the vibration. The vibration shall be a sinusoidal waveform with a logarithmic sweep
between 7 Hz and 200 Hz and back to 7 Hz traversed in 15 minutes.This cycle shall be repeated 12 times for a
total of 3 hours for each of three mutually perpendicular mounting positions of the cell. One of the directions of
vibration must be perpendicular to the terminal face.
The logarithmic frequency sweep is as follows: from 7 Hz a peak acceleration of 1gn is maintained until 18 Hz is reached.
The amplitude is then maintained at 0.8 mm(1.6 mm total excursion) and thefrequency increased until a peak
acceleration of 8gn occurs (approximately 50Hz).A peak acceleration of 8 gn is then maintained until the frequency
is increased to 200Hz. For large batteries, the peak acceleration of 2 gn is maintained.
SANYO Internal Procedure:
As above.
4.Test Requirements:
No mass loss,no leakage,no venting,no disassembly,no rupture and no fire,and the voltage
retention is not less than 90%.

5.Test Date: 2007/05/25


6.Test Data
Mass(g) Mass Voltage(V) Voltage
Other
Battery No. loss (%) Retention( Result Judgement
Before test After test event
(=<0.1% Before test After test %)(=>90%)
At first 1 223.42 223.45 -0.01 16.47 16.47 100.0 0 PASS
cycle,in fully 2 223.43 223.43 0.00 16.47 16.47 100.0 0 PASS
charged 3 222.99 223.00 0.00 16.45 16.45 100.0 0 PASS
states 4 223.30 223.30 0.00 16.47 16.47 100.0 0 PASS
PASS
After 50 5 223.41 223.46 -0.02 16.42 16.41 99.9 0 PASS
cycles ending 6 223.24 223.29 -0.02 16.39 16.39 100.0 0 PASS
in fully 7 223.59 223.63 -0.02 16.43 16.42 99.9 0 PASS
charged 8 223.32 223.37 -0.02 16.41 16.40 99.9 0 PASS
Notes: L-Leakage, V-Venting, D-Disassembly, R-Rupture, F-Fire,
0-No leakage, no venting, no disassembly, no rupture & no fire
UN Test Data ( Model: 4UR18650F-ASUS )
1.Test Item: Shock (T4)
2.Test Purpose: This test simulates possible impacts during transport.
3.Test Procedure:
Test cells and batteries shall be secured to the testing machine by means of a rigid mount which will support all mounting
surfaces of each test battery. Each cell or battery shall be subjected to a half-sine shock of pack acceleration of 150 g
and pulse duration of 6 milliseconds. Each cell or battery shall be subjected to three shocks in the positive direction
followed by three shocks in the negative direction of three mutually perpendicular mounting positions of the cell or battery
for a total of 18 shocks.
However, large cells and large batteries shall be subjected to a half-sine shock of peak acceleration of 50 g n and pulse
duration of 11 milliseconds. Each cell or battery is subjected to three shocks in the positive direction followed by three
shocks in the negative direction of each of three mutually perpendicular mounting positions of the cell for a total of 18
shocks.
SANYO Internal Procedure:
As above.
4.Test Requirements:
No mass loss,no leakage,no venting,no disassembly,no rupture and no fire,and the voltage
retention is not less than 90%.

5.Test Date: 2007/06/04


6.Test Data
Mass(g) Mass Voltage(V) Voltage
Other
Battery No. loss (%) Retention( Result Judgement
Before test After test (=<0.1% Before test After test %)(=>90%) event
At first 1 223.45 223.46 0.00 16.47 16.47 100.0 0 PASS
cycle,in fully 2 223.43 223.45 -0.01 16.47 16.47 100.0 0 PASS
charged 3 223.00 223.02 -0.01 16.45 16.45 100.0 0 PASS
states 4 223.30 223.32 -0.01 16.47 16.47 100.0 0 PASS
PASS
After 50 5 223.46 223.47 0.00 16.41 16.38 99.8 0 PASS
cycles ending 6 223.29 223.28 0.00 16.39 16.35 99.8 0 PASS
in fully 7 223.63 223.64 0.00 16.42 16.38 99.8 0 PASS
charged 8 223.37 223.39 -0.01 16.40 16.37 99.8 0 PASS
Notes: L-Leakage, V-Venting, D-Disassembly, R-Rupture, F-Fire,
0-No leakage, no venting, no disassembly, no rupture & no fire
UN Test Data ( Model: 4UR18650F-ASUS )
1.Test Item: External short circuit (T5)
2.Test Purpose: This test simulates an external short circuit.
3.Test Procedure:
The cell or battery to be tested shall be temperature stabilized so that its external case temperature reaches
55±2℃ and then the cell or battery shall be subjected to a short circuit condition with a total external
resistance of less than 0.1ohm at 55±2℃.This short circuit condition is continued for at least one hour after
the cell or battery external case temperature has returned to 55±2℃. The cell or battery must be observed
for a further six hours for the test to be concluded.
SANYO Internal Procedure:
As above.
4.Test Requirements:
External temperature of test batteries does not exceed 170℃ and there is no disassembly,no rupture and
no fire within six hours after this test.

5.Test Date: 2007/06/06


6.Test Data
Other
Battery No. Maximum temperature (°C) Result Judgement
event
At first 1 55.9 0 PASS
cycle,in fully 2 55.8 0 PASS
charged 3 56.0 0 PASS
states 4 55.9 0 PASS
After 50 PASS
5 55.8 0 PASS
cycles ending 6 55.6 0 PASS
in fully 7 55.8 0 PASS
charged 8 56.2 0 PASS
Notes: D-Disassembly, R-Rupture, F-Fire, 0-No disassembly, no rupture & no fire
UN Test Data ( Model: 4UR18650F-ASUS )
1.Test Item:Crush (T6)
Applicable to prismatic, pouch, coin/button cells and cylindrical cells not more than 20 mm in diameter

2.Test Purpose: These tests simulate mechanical abuse from a crush that may result in an internal short circuit.

3.Test Procedure:
A cell or component cell is to be crushed between two flat surfaces. The crushing is to be gradual with a speed of
approximately 1.5 cm/s at the first point of contact. The crushing is to be continued until the first of the three options below
is reached.
(a) The applied force reaches 13 kN ± 0.78 kN;
(b) The voltage of the cell drops by at least 100 mV; or
(c) The cell is deformed by 50% or more of its original thickness.
Once the maximum pressure has been obtained, the voltage drops by 100 mV or more, or the cell is deformed by at least
50% of its original thickness, the pressure shall be released.
A prismatic or pouch cell shall be crushed by applying the force to the widest side. A button/coin cell shall be crushed by
applying the force on its flat surfaces. For cylindrical cells, the crush force shall be applied perpendicular to the longitudinal
axis.
Each test cell or component cell is to be subjected to one crush only. The test sample shall be observed for a further 6 h.
The test shall be conducted using test cells or component cells that have not previously been subjected to other tests.

4.Test Requirements:
External temperature of test cells and component cell does not exceed 170℃ and there is no disassembly,no rupture
and no fire during the test and within six hours after the test.

5.Test Date: 2013/02/05

6.Test Data:
Other
Cell No. Maximum Temperature(°C) Result Judgement
event
1 22.4 0 PASS
At first 2 23.2 0 PASS
cycle, 50%
3 23.1 0 PASS PASS
charged
states 4 23.0 0 PASS
5 22.8 0 PASS
Notes: D-Disassembly, F-Fire, 0-No disassembly & no fire
UN Test Data ( Model: 4UR18650F-ASUS )
1.Test Item:Overcharged (T7)
2.Test Purpose: This test evaluates the ability of a rechargeable battery to withstand an overcharge condition.
3.Test Procedure:
The charge current shall be twice the manufacturer’s recommended maximum continuous charge current.
The minimum voltage of the test shall be as follows:

(a) when the manufacturer’s recommended charge voltage is not more than 18V,the minimum voltage
of the test shall be the lesser of two times the maximum charge voltage of the battery or 22V.

(b) when the manufacturer’s recommended charge voltage is more than 18V, the minimum voltage
of the test shall be 1.2 times the maximum charge voltage.

Tests are to be conducted at ambient temperature. The duration of the test shall be 24 hours.
SANYO Internal Procedure:
Min.Charge Voltage: 22 V
Charge Current: 3.00 A
4.Test Requirements:
There is no disassembly and no fire within seven days after the test.

5.Test Date: 2007/06/14 - 2007/06/22


6.Test Data
Battery No. Event Result Judgement
1 0 PASS
At first cycle
2 0 PASS
in fully
3 0 PASS
charged states
4 0 PASS
PASS
5 0 PASS
After 50 cycles
6 0 PASS
ending in fully
7 0 PASS
charged states
8 0 PASS
Notes: D-Disassembly, F-Fire, 0-No disassembly & no fire
UN Test Data ( Model: 4UR18650F-ASUS )
1.Test Item:Forced discharge (T8)

2.Test Purpose:
This test evaluates the ability of a primary or a rechargeable cell to withstand a forced discharge condition.

3.Test Procedure:
Each cell shall be forced discharged at ambient temperature by connecting it in series with a 12V D.C. power supply at an initial
current equal to the maximum discharge current specified by the manufacturer.
The specified discharge current is to be obtained by connecting a resistive load of the appropriate size and rating in series with
the test cell. Each cell shall be forced discharged for a time interval (in hours) equal to its rated capacity divided by the initial
test current (in ampere).

4.Test Requirements:
No disassembly and no fire during the test and within seven days after the test.

5.Test Date: 2009/01/21 - 2009/01/28

6.Test Data
Other
Cell No. Maximum Temperature(°C) Result Judgement
event
1 40.2 0 PASS
2 40.0 0 PASS
3 40.6 0 PASS
At first 4 40.3 0 PASS
cycle, in 5 40.1 0 PASS
fully
discharged 6 40.5 0 PASS
states 7 40.2 0 PASS
8 39.9 0 PASS
9 40.9 0 PASS
10 40.2 0 PASS
PASS
11 41.1 0 PASS
12 41.5 0 PASS
13 42.0 0 PASS
After 50
cycles 14 41.3 0 PASS
ending, in 15 42.0 0 PASS
fully 16 42.1 0 PASS
discharged 17 41.5 0 PASS
states
18 42.1 0 PASS
19 41.8 0 PASS
20 41.5 0 PASS
Notes: D-Disassembly, R-Rupture, F-Fire, 0-No disassembly, no rupture & no fire

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