Safety Data Sheet
Videojet®
Two Part Ink, Part A
16-8570A
Page                                  :   1 / 11
Version                               :   GHS (US) ENGLISH
Version number                        :   5.02
Date of issue/ Date of revision       :   1/26/2023
Date of previous issue                :   1/20/2023 (5.01)
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
 Product name                  : 16-8570A
 CAS number                    : Not applicable.
1.2 Relevant identified uses of the substance or mixture and uses advised against
 Material uses                 : Industrial applications: Ink for use in a continuous ink jet process.
1.3 Details of the supplier of the safety data sheet
 Website: www.videojet.com
 Email: FluidsSupport@videojet.com
 Videojet Technologies Inc., 1500 Mittel Boulevard, Wood Dale, IL, 60191-1073 U.S.A
 Tel: 1-800-843-3610 Fax: 1-800-582-1343
1.4 Emergency telephone number
 Medical                          3E: (US) +1 866 519 4752
                                  3E Code: 334466
 Transporters                     CHEMTREC: (US) +1 800 424 9300
                                  CHEMTREC Code: CCN 23846
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
 GHS Classification
 1) FLAMMABLE LIQUIDS - Category 2                          Highly flammable liquid and vapor.
 2) EYE IRRITATION - Category 2A                            Causes serious eye irritation.
 3) CARCINOGENICITY - Category 2                            Suspected of causing cancer.
 4) SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)        May cause drowsiness or dizziness.
 (Narcotic effects) - Category 3
  Ingredients of unknown       : Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 0%.
  toxicity
  Ingredients of unknown       : Percentage of the mixture consisting of ingredient(s) of unknown hazards to the
  ecotoxicity                    aquatic environment: 26%
2.2 Label elements
 GHS label elements
16-8570A                                                                                     GHS (US) ENGLISH Version: 5.02 Page: 2/11
  Danger. Highly flammable liquid and vapor. Causes serious eye irritation. Causes mild skin irritation. Suspected of
  causing cancer. May cause drowsiness or dizziness. Obtain special instructions before use. Use personal
  protective equipment as required. Avoid breathing vapor. Wear eye or face protection. Keep away from heat, hot
  surfaces, sparks, open flames and other ignition sources. No smoking. IF INHALED: Call a POISON CENTER or
  physician if you feel unwell. If eye irritation persists: Get medical attention. IF exposed or concerned: Get medical
  attention. Keep container tightly closed. Store in a well-ventilated place.
  Hazardous ingredients           : 1) butanone
                                    2) 4-methylpentan-2-one
2.3 Other hazards
 Other hazards which do                              : None known.
 not result in classification
SECTION 3: Composition/information on ingredients
Substance/mixture                                    : Mixture
            Product/ingredient name                                     CAS #        %                                  GHS Classification
1) butanone                                                     78-93-3         50 - <60   FLAMMABLE LIQUIDS - Category 2
                                                                                           EYE IRRITATION - Category 2A
                                                                                           SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
2) ethanol                                                      64-17-5         8 - <13    FLAMMABLE LIQUIDS - Category 2
                                                                                           EYE IRRITATION - Category 2B
3) 2-methoxy-1-methylethyl acetate                              108-65-6        3 - <7     FLAMMABLE LIQUIDS - Category 3
                                                                                           SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
                                                                                           Category 3
4) tetrabutylammonium hexafluorophosphate                       3109-63-5       1 - <3     ACUTE TOXICITY (dermal) - Category 4
                                                                                           ACUTE TOXICITY (inhalation) - Category 4
                                                                                           SKIN IRRITATION - Category 2
                                                                                           EYE IRRITATION - Category 2A
                                                                                           SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
                                                                                           Category 3
5) 4-methylpentan-2-one                                         108-10-1        <1         FLAMMABLE LIQUIDS - Category 2
                                                                                           ACUTE TOXICITY (inhalation) - Category 4
                                                                                           EYE IRRITATION - Category 2A
                                                                                           CARCINOGENICITY - Category 2
                                                                                           SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
                                                                                           Category 3
 Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures
4.1 Description of first aid measures
 Eye contact                                         : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
                                                       eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
                                                       minutes. Get medical attention.
 Inhalation                                          : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
                                                       If it is suspected that fumes are still present, the rescuer should wear an appropriate
                                                       mask or self-contained breathing apparatus. If not breathing, if breathing is irregular
                                                       or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
                                                       personnel. It may be dangerous to the person providing aid to give mouth-to-mouth
                                                       resuscitation. Get medical attention. If necessary, call a poison center or physician.
                                                       If unconscious, place in recovery position and get medical attention immediately.
                                                       Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
                                                       waistband. In case of inhalation of decomposition products in a fire, symptoms may
                                                       be delayed. The exposed person may need to be kept under medical surveillance
                                                       for 48 hours.
 Skin contact                                        : Flush contaminated skin with plenty of water. Remove contaminated clothing and
                                                       shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash
                                                       clothing before reuse. Clean shoes thoroughly before reuse.
 Ingestion                                           : Wash out mouth with water. Remove dentures if any. If material has been
                                                       swallowed and the exposed person is conscious, give small quantities of water to
                                                       drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
                                                       induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
                                                       the head should be kept low so that vomit does not enter the lungs. Get medical
                                                       attention. If necessary, call a poison center or physician. Never give anything by
                                                       mouth to an unconscious person. If unconscious, place in recovery position and get
                                                       medical attention immediately. Maintain an open airway. Loosen tight clothing such
                                                       as a collar, tie, belt or waistband.
4.2 Most important symptoms and effects, both acute and delayed
16-8570A                                                      GHS (US) ENGLISH Version: 5.02 Page: 3/11
 Potential acute health effects
  Eye contact                  : Causes serious eye irritation.
  Inhalation                   : Can cause central nervous system (CNS) depression. May cause drowsiness or
                                 dizziness.
  Skin contact                 : No known significant effects or critical hazards.
  Ingestion                    : Can cause central nervous system (CNS) depression.
 Over-exposure signs/symptoms
  Eye contact                  : Adverse symptoms may include the following:
                                 pain or irritation
                                 watering
                                 redness
  Inhalation                   : Adverse symptoms may include the following:
                                 nausea or vomiting
                                 headache
                                 drowsiness/fatigue
                                 dizziness/vertigo
                                 unconsciousness
  Skin contact                 : No specific data.
  Ingestion                    : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
 Treat symptomatically. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The
 exposed person may need to be kept under medical surveillance for 48 hours.
SECTION 5: Firefighting measures
5.1 Extinguishing media
 Suitable extinguishing        : Use dry chemical, CO₂, water spray (fog) or foam.
 media
 Unsuitable extinguishing      : Do not use water jet.
 media
5.2 Special hazards arising from the substance or mixture
 Hazards from the              : Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion
 substance or mixture            hazard. In a fire or if heated, a pressure increase will occur and the container may
                                 burst, with the risk of a subsequent explosion.
 Hazardous thermal             : Decomposition products may include the following materials:
 decomposition products          carbon dioxide
                                 carbon monoxide
                                 nitrogen oxides
                                 phosphorus oxides
                                 halogenated compounds
5.3 Advice for firefighters
 Special protective actions    : Promptly isolate the scene by removing all persons from the vicinity of the incident if
 for fire-fighters               there is a fire. No action shall be taken involving any personal risk or without
                                 suitable training. Move containers from fire area if this can be done without risk.
                                 Use water spray to keep fire-exposed containers cool.
 Special protective            : Fire-fighters should wear appropriate protective equipment and self-contained
 equipment for fire-fighters     breathing apparatus (SCBA) with a full face-piece operated in positive pressure
                                 mode.
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SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
 For non-emergency        : No action shall be taken involving any personal risk or without suitable training.
 personnel                  Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
                            entering. Do not touch or walk through spilled material. Shut off all ignition sources.
                            No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
                            Provide adequate ventilation. Wear appropriate respirator when ventilation is
                            inadequate. Put on appropriate personal protective equipment.
 For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
                            information in Section 8 on suitable and unsuitable materials. See also the
                            information in "For non-emergency personnel".
6.2 Environmental precautions
 Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant
 authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
6.3 Methods and materials for containment and cleaning up
 Small spill                    : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
                                  explosion-proof equipment. Dilute with water and mop up if water-soluble.
                                  Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
                                  appropriate waste disposal container. Dispose of via a licensed waste disposal
                                  contractor.
 Large spill                    : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
                                  explosion-proof equipment. Approach release from upwind. Prevent entry into
                                  sewers, water courses, basements or confined areas. Wash spillages into an
                                  effluent treatment plant or proceed as follows. Contain and collect spillage with non-
                                  combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
                                  and place in container for disposal according to local regulations (see Section 13).
                                  Dispose of via a licensed waste disposal contractor. Contaminated absorbent
                                  material may pose the same hazard as the spilled product. Note: see Section 1 for
                                  emergency contact information and Section 13 for waste disposal.
6.4 Reference to other sections
 See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste
 treatment information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
 Protective measures            : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
                                  obtain special instructions before use. Do not handle until all safety precautions
                                  have been read and understood. Do not get in eyes or on skin or clothing. Do not
                                  ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear
                                  appropriate respirator when ventilation is inadequate. Do not enter storage areas
                                  and confined spaces unless adequately ventilated. Keep in the original container or
                                  an approved alternative made from a compatible material, kept tightly closed when
                                  not in use. Store and use away from heat, sparks, open flame or any other ignition
                                  source. Use explosion-proof electrical (ventilating, lighting and material handling)
                                  equipment. Use only non-sparking tools. Take precautionary measures against
                                  electrostatic discharges. Empty containers retain product residue and can be
                                  hazardous. Do not reuse container.
 Advice on general              : Eating, drinking and smoking should be prohibited in areas where this material is
 occupational hygiene             handled, stored and processed. Workers should wash hands and face before
                                  eating, drinking and smoking. Remove contaminated clothing and protective
                                  equipment before entering eating areas. See also Section 8 for additional
                                  information on hygiene measures.
7.2 Conditions for safe storage, including any incompatibilities
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 Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
 protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section
 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
 container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed
 and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid
 environmental contamination. See Section 10 for incompatible materials before handling or use.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
 Occupational exposure limits
            Product/ingredient name                                                 Exposure limit values
 butanone                                   OSHA PEL 1989 (United States, 3/1989).
                                             TWA: 200 ppm 8 hours.
                                             TWA: 590 mg/m³ 8 hours.
                                             STEL: 300 ppm 15 minutes.
                                             STEL: 885 mg/m³ 15 minutes.
                                            OSHA PEL (United States, 5/2018).
                                             TWA: 200 ppm 8 hours.
                                             TWA: 590 mg/m³ 8 hours.
 ethanol                                    OSHA PEL 1989 (United States, 3/1989).
                                             TWA: 1000 ppm 8 hours.
                                             TWA: 1900 mg/m³ 8 hours.
                                            OSHA PEL (United States, 5/2018).
                                             TWA: 1000 ppm 8 hours.
                                             TWA: 1900 mg/m³ 8 hours.
 2-methoxy-1-methylethyl acetate            None.
 tetrabutylammonium hexafluorophosphate     None.
 4-methylpentan-2-one                       OSHA PEL 1989 (United States, 3/1989).
                                             TWA: 50 ppm 8 hours.
                                             TWA: 205 mg/m³ 8 hours.
                                             STEL: 75 ppm 15 minutes.
                                             STEL: 300 mg/m³ 15 minutes.
                                            OSHA PEL (United States, 5/2018).
                                             TWA: 100 ppm 8 hours.
                                             TWA: 410 mg/m³ 8 hours.
 Biological exposure indices
           Product/ingredient name                                                    Exposure indices
 butanone                                   ACGIH BEI (United States, 1/2022)
                                             BEI: 2 mg/l, methyl ethyl ketone [in urine]. Sampling time: end of shift.
 4-methylpentan-2-one                       ACGIH BEI (United States, 1/2022)
                                             BEI: 1 mg/l, methyl isobutyl ketone [in urine]. Sampling time: end of shift.
 Recommended monitoring               : Reference should be made to appropriate monitoring standards. Reference to
 procedures                             national guidance documents for methods for the determination of hazardous
                                        substances will also be required.
8.2 Exposure controls
 Appropriate engineering              : Use only with adequate ventilation. Use process enclosures, local exhaust
 controls                               ventilation or other engineering controls to keep worker exposure to airborne
                                        contaminants below any recommended or statutory limits. The engineering controls
                                        also need to keep gas, vapor or dust concentrations below any lower explosive
                                        limits. Use explosion-proof ventilation equipment.
 Hygiene measures                     : Wash hands, forearms and face thoroughly after handling chemical products, before
                                        eating, smoking and using the lavatory and at the end of the working period.
                                        Appropriate techniques should be used to remove potentially contaminated clothing.
                                        Wash contaminated clothing before reusing. Ensure that eyewash stations and
                                        safety showers are close to the workstation location.
 Eye/face protection                  : Safety eyewear complying with an approved standard should be used when a risk
                                        assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
                                        gases or dusts. If contact is possible, the following protection should be worn,
                                        unless the assessment indicates a higher degree of protection: safety glasses with
                                        side-shields.
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 Hand protection             : Recommended: EN374 B, EN374 A
                               May be used (Short term exposure): Latex gloves. Nitrile gloves. Use gloves only
                               once. Gloves should be replaced regularly and if there is any sign of damage to the
                               glove material. The user must check that the final choice of type of glove selected
                               for handling this product is the most appropriate and takes into account the
                               particular conditions of use, as included in the user's risk assessment.
 Respiratory protection      : Based on the hazard and potential for exposure, select a respirator that meets the
                               appropriate standard or certification. Respirators must be used according to a
                               respiratory protection program to ensure proper fitting, training, and other important
                               aspects of use.
                               Recommended: organic vapor filter (Type A)
                               Additional information: In situations where misting or flying may occur, use
                               appropriate certified respirators. Use a properly fitted, particulate filter respirator
                               complying with an approved standard if a risk assessment indicates this is
                               necessary.
 Environmental exposure      : Emissions from ventilation or work process equipment should be checked to ensure
 controls                      they comply with the requirements of environmental protection legislation. In some
                               cases, fume scrubbers, filters or engineering modifications to the process
                               equipment will be necessary to reduce emissions to acceptable levels.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
 Appearance
  Physical state             : Liquid.
  Color                      : Yellow.
 Odor                        : Not available.
 Odor threshold              : Estimated.: ≥ 10 ppm (butanone).
 pH                          : Not applicable.
 Melting point/freezing      : Estimated.: ≤ -66 °C [EU A.1] (2-methoxy-1-methylethyl acetate).
 point
 Initial boiling point and   : Estimated.: ≥ 78 °C (ethanol).
 boiling range
 Flash point                 : -6 °C [ASTM D 56]
 Evaporation rate (butyl     : Estimated.: ≤ 7 [butyl acetate = 1] (butanone).
 acetate = 1)
 Flammability (solid, gas)   : Not applicable. ( Liquid )
 Upper/lower flammability    : Estimated.: ≥ 2 % [EU A.11] (2-methoxy-1-methylethyl acetate).
 or explosive limits           Estimated.: ≤ 19 % (ethanol).
 Vapor pressure              : Estimated.: ≤ 11 kPa (79 mm Hg) at 20°C (butanone).
 Vapor density               : Estimated.: ≥ 1.6 [Air = 1] (ethanol).
 Relative density (Water = 1) : 0.89 [OECD 109]
 Solubility(ies)             : Not available.
 Partition coefficient: n-   : Not applicable.
 octanol/water
 Auto-ignition temperature   : Estimated.: ≥ 333 °C [DIN 51794] (2-methoxy-1-methylethyl acetate).
 Decomposition               : Thermally stable.
 temperature
 Viscosity                   : Not available.
 Explosive properties        : Not applicable. Not classified.
 Oxidizing properties        : Not applicable. Not classified.
 Particle characteristics
  Median particle size       : Not applicable.
9.2 Other information
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   Volatility (w/w)                    :76 %.
   VOC Volatility (w/w)                :76 %.
SECTION 10: Stability and reactivity
10.1 Reactivity
 No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability
 The product is stable.
10.3 Possibility of hazardous reactions
 Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid
 Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or
 expose containers to heat or sources of ignition.
10.5 Incompatible materials
 Reactive or incompatible with the following materials:
 oxidizing materials
10.6 Hazardous decomposition products
 Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
 Acute toxicity
           Product/ingredient name                         Result                  Species               Dose                Exposure
 butanone                                   LC50 Inhalation Vapor                Rat             23.5 mg/l              8 hours
                                            LD50 Dermal                          Rabbit - Male   >8000 mg/kg            -
                                            LD50 Oral                            Rat             3460 mg/kg             -
 ethanol                                    LC50 Inhalation Vapor                Rat             >117 mg/l              4 hours
                                            LD50 Dermal                          Rabbit          >15800 mg/kg           -
                                            LD50 Oral                            Rat             10470 mg/kg            -
 2-methoxy-1-methylethyl acetate            LCLo Inhalation Vapor                Rat             >4345 ppm              6 hours
                                            LD50 Oral                            Rat             6190 mg/kg             -
                                            LDLo Dermal                          Rabbit          >5000 mg/kg            -
 tetrabutylammonium hexafluorophosphate     LD50 Oral                            Rat             >5000 mg/kg            -
 4-methylpentan-2-one                       LC50 Inhalation Vapor                Rat             8.2 to 16.4 mg/l       4 hours
                                            LD50 Dermal                          Rabbit          >16 g/kg               -
                                            LD50 Oral                            Rat             2080 mg/kg             -
  Conclusion/Summary                 : Not classified. No known significant effects or critical hazards.
 Acute toxicity estimates
                                       Route                                                                ATE value
 Dermal                                                                              87301.59 mg/kg
 Inhalation (dusts and mists)                                                        94.6 mg/l
 Irritation/Corrosion
           Product/ingredient name                     Result            Species             Score           Exposure        Observation
 ethanol                                    Eyes - Irritant             Rabbit          -                 -                 21 days
                                            Skin - Primary dermal       Rabbit          0                 4 hours           14 days
                                            irritation index (PDII)
  Conclusion/Summary
   Skin                              : Causes mild skin irritation.
   Eyes                              : Causes serious eye irritation.
   Respiratory                       : Not classified. No known significant effects or critical hazards.
 Sensitization
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            Product/ingredient name                    Route of exposure               Species                               Result
 butanone                                          skin                              Guinea pig     Not sensitizing
 ethanol                                           Respiratory                       Rat            Not sensitizing
                                                   skin                              Mouse          Not sensitizing
   Conclusion/Summary
    Skin                                  : Not classified. No known significant effects or critical hazards.
    Respiratory                           : Not classified. No known significant effects or critical hazards.
 Mutagenicity
            Product/ingredient name                                   Test                                  Experiment                             Result
  ethanol                                           OECD 474                                Experiment: In vivo                             Negative
                                                                                            Subject: Mammalian-Animal
                                                    OECD 474                                Experiment: In vivo                             Negative
                                                                                            Subject: Mammalian-Animal
   Conclusion/Summary                     : Not classified. No known significant effects or critical hazards.
 Carcinogenicity
   Conclusion/Summary                     : Suspected of causing cancer. Risk of cancer depends on duration and level of
                                            exposure.
 Reproductive toxicity
   Conclusion/Summary                     : Not classified. No known significant effects or critical hazards.
 Specific target organ toxicity (single exposure)
            Product/ingredient name                       Category                 Route of exposure                       Target organs
  butanone                                          Category 3                 -                         Narcotic effects
  2-methoxy-1-methylethyl acetate                   Category 3                 -                         Respiratory tract irritation
  tetrabutylammonium hexafluorophosphate            Category 3                 -                         Respiratory tract irritation
  4-methylpentan-2-one                              Category 3                 -                         Respiratory tract irritation
 Specific target organ toxicity (repeated exposure)
  Not classified. No known significant effects or critical hazards.
 Aspiration hazard
   Conclusion/Summary                     : Not classified. No known significant effects or critical hazards.
 Potential chronic health effects, Other
  Product/ingredient name                Result                                      Species                Dose                        Exposure
  ethanol                                 Sub-chronic NOAEL Oral                      Rat                    1730 mg/kg                  90 days
   Conclusion/Summary                     : No known significant effects or critical hazards.
SECTION 12: Ecological information
12.1 Toxicity
           Product/ingredient name                                    Result                                   Species                        Exposure
 butanone                                         Acute EC50 2029 mg/l Fresh water                Algae - Pseudokirchnerella              96 hours
                                                                                                  subcapitata
                                                  Acute EC50 308 mg/l Fresh water                 Daphnia - Daphnia magna                 48 hours
                                                  Acute LC50 2993 mg/l Fresh water                Fish - Pimephales promelas              96 hours
                                                  Chronic NOEC 1240 mg/l Fresh water              Algae - Pseudokirchnerella              96 hours
                                                                                                  subcapitata
 ethanol                                          Acute EC50 275 mg/l Fresh water                 Algae - Chlorella vulgaris              72 hours
                                                  Acute LC50 5012 mg/l Fresh water                Daphnia - Ceriodaphnia dubia            48 hours
                                                  Acute LC50 11200 mg/l Fresh water               Fish - oncorhynchus mykiss              24 hours
                                                  Chronic EC10 11.5 mg/l Fresh water              Algae - Chlorella vulgaris              72 hours
                                                  Chronic NOEC 79 mg/l Marine water               Crustaceans - Palaemonetes pugio        12 days
                                                  Chronic NOEC 9.6 mg/l                           Daphnia - daphnia magna                 10 days
                                                  Chronic NOEC 250 mg/l Fresh water               Fish - Danio rerio - Embryo             120 hours
 4-methylpentan-2-one                             Acute LC50 505000 µg/l Fresh water              Fish - Pimephales promelas              96 hours
                                                  Chronic NOEC 78 mg/l Fresh water                Daphnia - Daphnia magna                 21 days
 Conclusion/Summary                      : Not available.
12.2 Persistence and degradability
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           Product/ingredient name                      Aquatic half-life                   Photolysis               Biodegradability
  butanone                                      -                                -                          Readily
  ethanol                                       -                                -                          Readily
  2-methoxy-1-methylethyl acetate               -                                -                          Readily
  4-methylpentan-2-one                          -                                -                          Readily
 Conclusion/Summary                       : Not available.
12.3 Bioaccumulative potential
           Product/ingredient name                            LogPow                          BCF                       Potential
  butanone                                      0.3                              -                          low
  ethanol                                       -0.35                            -                          low
  2-methoxy-1-methylethyl acetate               1.2                              -                          low
  4-methylpentan-2-one                          1.9                              -                          low
12.4 Mobility in soil
 Soil/water partition                     : Not available.
 coefficient (KOC)
 Mobility                                 : Not available.
12.5 Results of PBT and vPvB assessment
  This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
12.6 Other adverse effects
 No known significant effects or critical hazards.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
 Product
  Methods of disposal                     : The generation of waste should be avoided or minimized wherever possible.
                                            Disposal of this product, solutions and any by-products should at all times comply
                                            with the requirements of environmental protection and waste disposal legislation and
                                            any regional local authority requirements. Dispose of surplus and non-recyclable
                                            products via a licensed waste disposal contractor. Avoid dispersal of spilled
                                            material and runoff and contact with soil, waterways, drains and sewers.
 Packaging
  Methods of disposal                     : The generation of waste should be avoided or minimized wherever possible. Waste
                                            packaging should be recycled. Incineration or landfill should only be considered
                                            when recycling is not feasible.
 Special precautions                      : None.
SECTION 14: Transport information
                                          UN                            IMDG                         IATA                 US DOT
14.1 UN number             UN1210                        UN1210                       UN1210                   UN1210
14.2 UN proper             Printing Ink                  Printing Ink                 Printing Ink             Printing Ink
shipping name
14.3 Transport hazard      3                             3                            3                        3
class(es)
14.4 Packing group         II                            II                           II                       II
14.5 Environmental         No.                           No.                          No.                      No.
hazards
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Additional information   -                              -                            -                             -
14.6 Special precautions for user
 No special measures required.
14.7 Transport in bulk according to IMO instruments
 Not available.
SECTION 15: Regulatory information
 CERCLA: Hazardous                   : The following components are listed: butanone (50 - <60%); cyclohexanone
 substances.                           (<0.3%)
 SARA 313                            : The following components are listed: None.
 California Prop. 65                 : This product contains a chemical or chemicals known to the state of California to
                                       cause cancer. The following components are listed: 4-methylpentan-2-one (<1%);
                                       2-phenylpropene (<0.1%); styrene (<0.1%); benzene (<0.01%). This product
                                       contains a chemical or chemicals known to the state of California to cause birth
                                       defects or other reproductive harm. The following components are listed:
                                       4-methylpentan-2-one (<1%); benzene (<0.01%); toluene (<0.001%).
 National Fire Protection            :                                 Flammability
 Association (U.S.A.)                                                   3
                                                  Health            1        0       Reactivity
                                         special hazard
 Tariff Code - harmonized            : 3215.19 Printing ink: Other.
 system                                USA ...90.60
                                       EU ...90.90
 Heavy Metals                        : Total concentration: Pb, Hg, Cd, Cr(VI) < 100 ppm
 California, VOC Content             : 677 grams volatile organic / liter less water or exempt volatile.
   Chemical Weapons Convention List                Chemical Weapons Convention List              Chemical Weapons Convention List
   Schedule I Chemicals                            Schedule II Chemicals                         Schedule III Chemicals
   Not listed                                      Not listed                                    Not listed
SECTION 16: Other information
Revision comments                    :      Indicates information that has changed from previously issued version.
Abbreviations and                    :   ATE = Acute Toxicity Estimate
                                         BCF = Bioconcentration Factor
acronyms                                 GHS = Globally Harmonized System of Classification and Labelling of Chemicals
                                         IATA = International Air Transport Association
                                         IBC = Intermediate Bulk Container
                                         IMDG = International Maritime Dangerous Goods
                                         LogPow = logarithm of the octanol/water partition coefficient
                                         MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the
                                         Protocol of 1978. ("Marpol" = marine pollution)
                                         UN = United Nations
Procedure used to derive the classification
                                            Classification                                                             Justification
 FLAMMABLE LIQUIDS - Category 2                                                                         On basis of test data
 EYE IRRITATION - Category 2A                                                                           Calculation method
 CARCINOGENICITY - Category 2                                                                           Calculation method
 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3                       Calculation method
Notice to reader
 To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
 subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination
 of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with
 caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
16-8570A   GHS (US) ENGLISH Version: 5.02 Page: 11/11