Safety Data Sheet: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking
Safety Data Sheet: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Not applicable.
Uses advised against
Not applicable.
RUCOINX Druckfarben
A. M. Ramp & Co. GmbH Lorsbacher Str. 28 Eppstein
Germany D-65817
+49.6198.304 0
8:00-16:00 (working hours)
National contact
Not available.
1.4 Emergency telephone number
Supplier
Version: 2.2 Date of issue/Date of revision: 16.10.2024 Date of previous issue: 16.10.2024
2.1 Classification of the substance or mixture
Hazard pictograms :
General : P103:Read carefully and follow all instructions. P102:Keep out of reach of
children.
P101:If medical advice is needed, have product container or label at hand.
Prevention : P210:Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking.
Response : -:Not applicable.
Disposal : P501:Dispose of contents and container in accordance with all local, regional,
national and international regulations.
Product meets the : This mixture does not contain any substances that are assessed to be a
criteria for PBT or vPvB PBT or a vPvB.
according to
Regulation (EC) No. 1907/2006,
Annex XIII
Other hazards which do not : None known.
result in classification
n-butyl acetate REACH#: 01- >= 10 - < 20 Flam. Liq. 3, H226 - [1] [2]
2119485493-29- STOT SE 3, H336
XXXX (Narcotic effects)
EC : 204-658-1 EUH066
CAS : 123-86-4
Index: 607-025-00-
1
2-butoxyethyl acetate REACH#: 01- > 0 - <= 10 Acute Tox. 4, H312 ATE [Dermal] = 1 500 mg/kg [1] [2]
2119475112-47- Acute Tox. 4, H332 ATE [Inhalation (vapours)] =
0017 11 mg/l
EC : 203-933-3
CAS : 112-07-2
Index: 607-038-00-
2
4-hydroxy-4- > 0 - <= 3 Eye Irrit. 2, H319 Eye Irrit. 2, H319: >= 10 % [1] [2]
methylpentan-2-one EC : 204-626-7
CAS : 123-42-2
Index: 603-016-00-
1
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting
the upper and lower eyelids. Check for and remove any contact lenses. Get
medical attention if irritation occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for
breathing. In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing
and shoes. Get medical attention if
symptoms occur.
Ingestion : Wash out mouth with water. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Do not induce
vomiting unless directed to do so
by medical personnel.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
4.2 Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
4.3 Indication of any immediate medical attention and special treatment needed
Suitable extinguishing media : Use dry chemical, CO₂, water spray (fog) or foam.
Unsuitable extinguishing media : Do not use water jet.
Hazards from the substance : Flammable liquid and vapor. Runoff to sewer may create fire
or mixture or explosion hazard. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a
subsequent explosion.
Hazardous combustion products : Decomposition products may include the following materials: carbon dioxide,
carbon monoxide, nitrogen oxides, metal oxide/oxides
Special protective actions for : Promptly isolate the scene by removing all persons from the
fire-fighters vicinity of the incident if there is a fire. No action shall be taken
For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel
from entering. Do not touch or walk through spilled material. Shut off all ignition
sources. No flares, smoking or flames in hazard area. Put on appropriate
personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
6.2 Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water- insoluble, absorb with an inert dry material and place
in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Approach release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Wash spillages into
an effluent treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local
regulations. Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product.
6.4 Reference to other sections : See Section 1 for emergency contact information. See Section 8 for information
on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not
ingest. Avoid contact with eyes, skin and clothing.
Avoid breathing vapor or mist. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter storage
areas and confined spaces unless adequately ventilated. Keep in the original
container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open
flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Take precautionary measures against
electrostatic discharges. Empty containers retain product residue and can be
hazardous. Do not reuse container.
Advice on general occupational : Eating, drinking and smoking should be prohibited in areas where this material
hygiene is handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment
to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.
Danger criteria
Recommended monitoring : Reference should be made to monitoring standards, such as the following:
procedures European Standard EN 689 (Workplace atmospheres - Guidance for the
assessment of exposure by inhalation to chemical agents for comparison with
limit values and measurement strategy) European Standard EN 14042
(Workplace atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents) European
Standard EN 482 (Workplace atmospheres - General requirements for the
performance of procedures for the measurement of chemical agents)
Reference to national guidance documents for methods for the determination
of hazardous substances will also be required.
DNELs/DMELs
Eye/face protection : Safety eyewear complying with an approved standard should be used when a
risk assessment indicates this is necessary to avoid exposure to liquid
splashes, mists, gases or dusts. If contact is possible, the following protection
should be worn, unless the assessment indicates a higher degree of
protection: safety glasses with side-shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard
should be worn at all times when handling chemical products if a risk
assessment indicates this is necessary. Considering the parameters specified
by the glove manufacturer, check during use that the gloves are still retaining
their protective properties. It should be noted that the time to breakthrough for
any glove material may be different for different glove manufacturers. In the
case of mixtures, consisting of several substances, the protection time of the
gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the
task being performed and the risks involved and should be approved by a
specialist before handling this product. When there is a risk of ignition from
static electricity, wear anti-static protective clothing. For the greatest protection
from static discharges, clothing should include anti-static overalls, boots and
gloves. Refer to
European Standard EN 1149 for further information on material and design
requirements and test methods.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should
be approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets
the appropriate standard or certification. Respirators must be used according to
a respiratory protection program to ensure proper fitting, training, and other
important
aspects of use.
Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to
ensure they comply with the requirements of environmental protection
legislation. In some cases, fume scrubbers, filters or engineering modifications
to the process equipment will be necessary to reduce emissions to acceptable
levels.
Vapor pressure :
Particle characteristics
10.3 Possibility of hazardous : Under normal conditions of storage and use, hazardous
reactions reactions will not occur.
10.4 Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut,
weld, braze, solder, drill, grind or expose containers to heat or sources of
ignition.
10.5 Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials
10.6 Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition
products products should not be produced.
Acute toxicity
Irritation/Corrosion
Sensitization
Conclusion/Summary
Skin : Not available.
Respiratory : Not available.
Mutagenicity
Carcinogenicity
Reproductive toxicity
Teratogenicity
Aspiration hazard
Not available.
Delayed and immediate effects and also chronic effects from short and long term exposure
n-butyl acetate
Acute LC50 18 mg/l Fresh Fish - Pimephales 96 h
water promelas
Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 h
4-hydroxy-4-methylpentan-2-one
Acute LC50 420 mg/l Marine water Fish - Menidia beryllina 96 h
Product
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal : The generation of waste should be avoided or minimized wherever possible.
Waste packaging should be recycled. Incineration or landfill should only be
considered when recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Care should
be taken when handling emptied containers that have not been cleaned or
rinsed out. Empty containers or liners may retain some product residues. Vapor
from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they
have been cleaned thoroughly internally. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14.6 Special precautions for : Transport within user’s premises: always transport in closed
user containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain
dangerous substances, mixtures and articles
Product/ingredient name % Designation [Usage]
No listed substance
Other EU regulations
Seveso Directive
This product is controlled under the Seveso Directive.
Danger criteria
Category
P5c
National regulations
Danger criteria
Category Reference
number
P5c 1.2.5.3
Inventory list
Australia : Not determined.
Canada : Not determined.
China : Not determined.
Eurasian Economic Union : Russian Federation inventory: Not determined.
Japan : Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
New Zealand : Not determined.
Philippines : Not determined.
Republic of Korea : Not determined.
Taiwan : Not determined.
Thailand : Not determined.
Turkey : Not determined.
United States : All components are listed or exempted.
Viet Nam : Not determined.
15.2 Chemical Safety Assessment : This product contains substances for which Chemical Safety Assessments are
still required.
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Flam. Liq. 3, H226 On basis of test data
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All
materials may present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.