Safety Data Sheet: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking
Safety Data Sheet: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking
 1.2 Relevant identified uses of the substance or mixture and uses advised against
 Identified uses
 Not applicable.
 Uses advised against
 Not applicable.
 RUCOINX Druckfarben
 A. M. Ramp & Co. GmbH
 Lorsbacher Str. 28
 Eppstein
 Germany
 D-65817
 +49.6198.304 0
 8:00-16:00 (working hours)
National contact
Not available.
Supplier
    Version:   2.6       Date of issue/Date of revision:   16.10.2024      Date of previous issue:   16.10.2024
 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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 See Section 16 for the full text of the H statements declared above.
 See Section 11 for more detailed information on health effects and symptoms.
Hazard pictograms :
Precautionary statements
   Prevention                            :       P210:Keep away from heat, hot surfaces, sparks, open flames
                                                 and other ignition sources. No smoking.
 Product meets the        : This mixture does not contain any substances that are assessed to be a
 criteria for PBT or vPvB   PBT or a vPvB.
    Version:   2.6         Date of issue/Date of revision:   16.10.2024     Date of previous issue:   16.10.2024
 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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 according to
 Regulation (EC) No.
 1907/2006, Annex XIII
 Other hazards which do : None known.
 not result in
 classification
2-butoxyethyl acetate REACH#: 01-        > 0 - <= 10              Acute Tox. 4, H312            ATE [Dermal] = 1 500 mg/kg [1] [2]
                      2119475112-47-                              Acute Tox. 4, H332            ATE [Inhalation (vapours)] =
                      0017                                                                      11 mg/l
                      EC : 203-933-3
                      CAS : 112-07-2
                      Index: 607-038-00-
                      2
4-hydroxy-4-                                     > 0 - <= 3       Eye Irrit. 2, H319            Eye Irrit. 2, H319: >= 10 %   [1] [2]
methylpentan-2-one        EC : 204-626-7
                          CAS : 123-42-2
                          Index: 603-016-00-
                          1
 See Section 16 for the full text of the H statements declared above.
 There are no additional ingredients present which, within the current knowledge of the supplier and in
 the concentrations applicable, are classified as hazardous to health or the environment, are PBTs,
 vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and
 hence require reporting in this section.
 Type
 [1] Substance classified with a health or environmental hazard
 [2] Substance with a workplace exposure limit
 Occupational exposure limits, if available, are listed in Section 8.
    Version:   2.6           Date of issue/Date of revision:   16.10.2024           Date of previous issue:   16.10.2024
  Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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  Eye contact                             :     Immediately flush eyes with plenty of water, occasionally lifting
                                                the upper and lower eyelids. Check for and remove any
                                                contact lenses. Get medical attention if irritation occurs.
  Inhalation                              :     Remove victim to fresh air and keep at rest in a position
                                                comfortable for breathing.
  Skin contact                            :     Flush contaminated skin with plenty of water. Remove
                                                contaminated clothing and shoes. Get medical attention if
                                                symptoms occur.
  Ingestion                               :     Wash out mouth with water. If material has been swallowed
                                                and the exposed person is conscious, give small quantities of
                                                water to drink. Do not induce vomiting unless directed to do so
                                                by medical personnel.
  Protection of first-aiders              :     No action shall be taken involving any personal risk or without
                                                suitable training.
4.2 Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
4.3 Indication of any immediate medical attention and special treatment needed
  Suitable extinguishing media            :     Use dry chemical, CO₂, water spray (fog) or foam.
  Unsuitable extinguishing                :     Do not use water jet.
  media
  Hazards from the substance              :     Flammable liquid and vapor. Runoff to sewer may create fire
  or mixture                                    or explosion hazard. In a fire or if heated, a pressure increase
                                                will occur and the container may burst, with the risk of a
                                                subsequent explosion.
  Hazardous combustion                    :     Decomposition products may include the following materials:
  products                                      carbon dioxide, carbon monoxide, metal oxide/oxides
  Special protective actions for          :     Promptly isolate the scene by removing all persons from the
     Version:   2.6         Date of issue/Date of revision:   16.10.2024     Date of previous issue:   16.10.2024
 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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 For non-emergency                       :     No action shall be taken involving any personal risk or without
 personnel                                     suitable training. Evacuate surrounding areas. Keep
                                               unnecessary and unprotected personnel from entering. Do not
                                               touch or walk through spilled material. Shut off all ignition
                                               sources. No flares, smoking or flames in hazard area. Put on
                                               appropriate personal protective equipment.
 For emergency responders                :     If specialized clothing is required to deal with the spillage, take
                                               note of any information in Section 8 on suitable and unsuitable
                                               materials. See also the information in "For non-emergency
                                               personnel".
6.2 Environmental precautions            :     Avoid dispersal of spilled material and runoff and contact with
                                               soil, waterways, drains and sewers. Inform the relevant
                                               authorities if the product has caused environmental pollution
                                               (sewers, waterways, soil or air).
 Small spill                             :     Stop leak if without risk. Move containers from spill area. Use
                                               spark-proof tools and explosion-proof equipment. Dilute with
                                               water and mop up if water-soluble. Alternatively, or if water-
                                               insoluble, absorb with an inert dry material and place in an
                                               appropriate waste disposal container. Dispose of via a licensed
                                               waste disposal contractor.
 Large spill                             :     Stop leak if without risk. Move containers from spill area. Use
                                               spark-proof tools and explosion-proof equipment. Approach
                                               release from upwind. Prevent entry into sewers, water courses,
                                               basements or confined areas. Wash spillages into an effluent
                                               treatment plant or proceed as follows. Contain and collect
                                               spillage with non-combustible, absorbent material e.g. sand,
                                               earth, vermiculite or diatomaceous earth and place in container
                                               for disposal according to local regulations. Dispose of via a
                                               licensed waste disposal contractor. Contaminated absorbent
                                               material may pose the same hazard as the spilled product.
6.4 Reference to other sections          :     See Section 1 for emergency contact information.
                                               See Section 8 for information on appropriate personal
                                               protective equipment.
                                               See Section 13 for additional waste treatment information.
  The information in this section contains generic advice and guidance. The list of Identified Uses in
  Section 1 should be consulted for any available use-specific information provided in the Exposure
  Scenario(s).
Danger criteria
     Version:   2.6         Date of issue/Date of revision:   16.10.2024       Date of previous issue:   16.10.2024
 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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 The information in this section contains generic advice and guidance. Information is provided based
 on typical anticipated uses of the product. Additional measures might be required for bulk handling or
 other uses that could significantly increase worker exposure or environmental releases.
DNELs/DMELs
                                                     Inhalation                          population
                                DNEL                 Long term           48 mg/m³        Workers             Systemic
                                                     Inhalation
                                DNEL                 Long term           35,7 mg/m³      General             Local
                                                     Inhalation                          population
                                DNEL                 Long term           12 mg/m³        General             Systemic
                                                     Inhalation                          population
                                DNEL                 Short term          11 mg/kg        Workers             Systemic
                                                     Dermal              bw/day
                                DNEL                 Long term           7 mg/kg         Workers             Systemic
                                                     Dermal              bw/day
                                DNEL                 Short term          6 mg/kg         General             Systemic
                                                     Dermal              bw/day          population
                                DNEL                 Long term           3,4 mg/kg       General             Systemic
                                                     Dermal              bw/day          population
                                DNEL                 Long term           2 mg/kg         General             Systemic
                                                     Oral                bw/day          population
                                DNEL                 Short term          2 mg/kg         General             Systemic
                                                     Oral                bw/day          population
                                DNEL                 Short term          600 mg/m³       Workers             Systemic
                                                     Inhalation
                                DNEL                 Short term          600 mg/m³       Workers             Local
                                                     Inhalation
                                DNEL                 Long term           300 mg/m³       Workers             Local
                                                     Inhalation
                                DNEL                 Short term          300 mg/m³       General             Systemic
                                                     Inhalation                          population
                                DNEL                 Short term          300 mg/m³       General             Local
                                                     Inhalation                          population
                                DNEL                 Long term           48 mg/m³        Workers             Systemic
                                                     Inhalation
                                DNEL                 Long term           35,7 mg/m³      General             Local
                                                     Inhalation                          population
                                DNEL                 Long term           12 mg/m³        General             Systemic
                                                     Inhalation                          population
                                DNEL                 Short term          11 mg/kg        Workers             Systemic
                                                     Dermal              bw/day
                                DNEL                 Long term           7 mg/kg         Workers             Systemic
                                                     Dermal              bw/day
                                DNEL                 Short term          6 mg/kg         General             Systemic
                                                     Dermal              bw/day          population
                                DNEL                 Long term           3,4 mg/kg       General             Systemic
                                                     Dermal              bw/day          population
                                DNEL                 Long term           2 mg/kg         General             Systemic
                                                     Oral                bw/day          population
2-butoxyethyl acetate           DNEL                 Long term           8,6 mg/kg       General             Systemic
                                                     Oral                bw/day          population
                                DNEL                 Short term          333 mg/m³       Workers             Local
                                                     Inhalation
                                DNEL                 Short term          200 mg/m³       General             Local
                                                     Inhalation                          population
                                DNEL                 Long term           169 mg/kg       Workers             Systemic
                                                     Dermal              bw/day
                                DNEL                 Long term           133 mg/m³       Workers             Systemic
                                                     Inhalation
                                DNEL                 Short term          120 mg/kg       Workers             Systemic
                                                     Dermal              bw/day
   Version:   2.6         Date of issue/Date of revision:   16.10.2024          Date of previous issue:   16.10.2024
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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 PNECs
  No PNECs available.
    Version:   2.6         Date of issue/Date of revision:   16.10.2024          Date of previous issue:   16.10.2024
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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Appearance
Vapor pressure :
Particle characteristics
10.3 Possibility of hazardous               :    Under normal conditions of storage and use, hazardous
reactions                                        reactions will not occur.
10.4 Conditions to avoid                    :    Avoid all possible sources of ignition (spark or flame). Do not
                                                 pressurize, cut, weld, braze, solder, drill, grind or expose
                                                 containers to heat or sources of ignition.
10.5 Incompatible materials                 :    Reactive or incompatible with the following materials: oxidizing
                                                 materials
10.6 Hazardous decomposition                :    Under normal conditions of storage and use, hazardous
products                                         decomposition products should not be produced.
Acute toxicity
Irritation/Corrosion
Sensitization
Conclusion/Summary
 Skin                                        :   Not available.
 Respiratory                                 :   Not available.
Mutagenicity
    Version:   2.6         Date of issue/Date of revision:   16.10.2024           Date of previous issue:   16.10.2024
 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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Carcinogenicity
Reproductive toxicity
Teratogenicity
 Aspiration hazard
   Not available.
Delayed and immediate effects and also chronic effects from short and long term exposure
    Version:   2.6         Date of issue/Date of revision:   16.10.2024         Date of previous issue:   16.10.2024
 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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    Version:    2.6        Date of issue/Date of revision:   16.10.2024         Date of previous issue:   16.10.2024
  Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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Product
Packaging
  Special precautions                        :    This material and its container must be disposed of in a safe
                                                  way. Care should be taken when handling emptied containers
                                                  that have not been cleaned or rinsed out. Empty containers or
                                                  liners may retain some product residues. Vapor from product
                                                  residues may create a highly flammable or explosive
                                                  atmosphere inside the container. Do not cut, weld or grind
                                                  used containers unless they have been cleaned thoroughly
                                                  internally. Avoid dispersal of spilled material and runoff and
                                                  contact with soil, waterways, drains and sewers.
14.6 Special precautions for                :    Transport within user’s premises: always transport in closed
user                                             containers that are upright and secure. Ensure that persons
                                                 transporting the product know what to do in the event of an
                                                 accident or spillage.
 Annex XVII - Restrictions on the manufacture, placing on the market and use of certain
 dangerous substances, mixtures and articles
  No listed substance
 Other EU regulations
   Seveso Directive
    Version:   2.6           Date of issue/Date of revision:    16.10.2024         Date of previous issue:   16.10.2024
 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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Danger criteria
      Category
      P5c
National regulations
Danger criteria
      Category                                                                                 Reference
                                                                                               number
      P5c                                                                                     1.2.5.3
 Montreal Protocol
  None of the components are listed.
    Version:   2.6         Date of issue/Date of revision:   16.10.2024   Date of previous issue:   16.10.2024
 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2020/878
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  POPs - Annex 2
   None of the components are listed.
  POPs - Annex 3
   None of the components are listed.
Inventory list
  Australia                               :     Not determined.
  Canada                                  :     Not determined.
  China                                   :     Not determined.
  Eurasian Economic Union                 :     Russian Federation inventory: Not determined.
  Japan                                   :     Japan inventory (CSCL): Not determined.
                                                Japan inventory (ISHL): Not determined.
  New Zealand                             :     Not determined.
  Philippines                             :     Not determined.
  Republic of Korea                       :     Not determined.
  Taiwan                                  :     Not determined.
  Thailand                                :     Not determined.
  Turkey                                  :     Not determined.
  United States                           :     All components are listed or exempted.
  Viet Nam                                :     Not determined.
15.2 Chemical Safety                       :   This product contains substances for which Chemical Safety
Assessment                                     Assessments are still required.
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008
[CLP/GHS]
                   Classification                                                   Justification
  Flam. Liq. 3, H226                                             On basis of test data
Notice to reader
  To the best of our knowledge, the information contained herein is accurate. However, neither
  the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the
  accuracy or completeness of the information contained herein. Final determination of
  suitability of any material is the sole responsibility of the user. All materials may present
  unknown hazards and should be used with caution. Although certain hazards are described
  herein, we cannot guarantee that these are the only hazards that exist.
Version: 2.6 Date of issue/Date of revision: 16.10.2024 Date of previous issue: 16.10.2024