-liv vitiMe,

Middle
215 U m

moteute en the alsoplin

ilanaf enengy lnle of a
tle

felas the Hocki dauo K

constaul he btrd
’ Fece
Qhee k ’

bonel ‘ with bbrd

a
Juus, te wibaalual
0-H> C-0
(8) (I) (Q8)
(1)

ilanlK) is -lhe meau

teree

G=c >c-c;k =o>c -o;e-H>e-c; loH >c- o; oH> OD

vibráton aon e dala steltng
k=500 N

ser N 2

50 x{oS
2x 22 13
(20
20 xlo
1)(:6 lo
(20 th6)lo

3Xlomsl

K 5x105 dyne e
K 5x 12
me
No No
No No
atom ) D-alon
mmo
Reclueed
maas
mt mo
12 xl6yJ
b023xo
28
NoxNo (12tl6) =|i38 xI~23

L t23
38 XD
QX314X3 Xio
=|xo'4
|138

J884
V 20 4594
|8. 84
 Yhe iR Aaliatai do mol have ufictu egd.
Cause tle exeitalou e ei heulei, il eauaei alovve ef

oganie eompaa to ibalt with hcheu anp lidiole akat

the eoualeit lpnds tielh conneel
Reut
qarligeo aud as it oeauns, the eounpoa
pali'ela
a mole eule, tlee oeeu a elauq
dipole moneu o% te moleeule il ead to the
% eeill eleitic
moleeule. tneialr
EMR (IR Aooliali)
the îR Aaiatoy ae dle moleele and a
eu the ehart
nlei
But ange an cipole moeu; no
aeton bocuns, heee o atUeptm takes fplaet
Jlesefoe,. Lelheton kulo olecule kehold. ehange
- Ahedipea memen od tud
dunuig the couse. balon i.e. ol L )
y. tlee ibraton wul satissEhv,
yhe matial sogieuny. of viba olou°o the houta
vibaaluoa ueidul
st be eqial to
KadlitoA
ter eg stetclug a syunotieol bond(c)
Mocleieeu no clane. i.e,tués
Thus, no absotos of 2 k tate plale
Dleeule is ealled as ?R Enative

diatomes

are îR Actue
Taiatomiee and eCeu haig cuitne of ayo
theu boud ocees no olipele nuat.
asyunetie
2
6oune ae syumae
CIR inotne)
Aneulau fialone aka o, so,. Hs cte ae
atie as he's md ef vibatons Modues
clhage dm
Langbage
erg.c=0 saoug baud due to Sangeeledio
gatilydee betweeu
md m.
-tydhocaoomweak, baude dueto les difeeue
eletthomaty HSc.
=245D H l= 0
H
(Trans - 1,2 -bi cklooete)
 fudameal ibaton
Total
(n -no-o ntoni snmeletale )
= 3
Tramtaival He non-linea
Ketatueia begloe eden =3
3(e moleeuleg )
Relateuat bogace of kedom
tuecdom 9 (-for dneaumik euley
mo loeule

TY. + Roti + vib.

Veb. = 3n - | Tr+-Rot.)
=n- (3+3)
Non-linea
- |31 -64 moletule
- 3n-(3 +2)
ib.degne tuedom
|31-5 tor mbleeue
titg
1
Alpvd in a moeles bale
lavel!
poyatom molewles ehibit tan
funcdauatat
wi latiri. Jhe no. damutal niato depend
uprn dhe afueute owleeule ill e
meeule- thee
e a ou- inear peyabome
linea míleele
|3n- 6 unolaetlal modu z fo
3n-5
Moleeules Tolol no: Vibia toiy
(moces OoVibatos
31 -5 =3X354
HCNnear) 3n -5 3 X3-5 >4
3X3 -6 =3
Ho(non-liueau) 3n-6 =
eHy ( )3n- 6
)31-6
(inea) 3 n-5 = 3x4-5 =t
Ha
 Moleoula Vehaaln

- NH)ee
Moleeulaa vrbalom
(Mo des of vbaolion)
Vbalonu
|Sutcluig Vibnatiaik

|Asynlie
shaalehg
Rockinel Taisting
 ibAalios, the alouu ae Lilee ball
big hen aue
aud he bonds comettui
hee ae 2-typu vibaatow dic shelelig
wleu the olistauee.beluietu
Sheteling v'hiatuow!-
() oeeases but the aloing
t neeares
aloud esebalos
ayds.
6ehau iet e sano boudl al
tu' types

tie stntd Aulitspmetue

Lowe
Foneg-_e0 mole eule
(norehange in dm)
Syuwete sth
ibains

Autiammetie st.1Ratne
tbratoy.-( Dettmaton)
(i) beuding betureen the tu alons Aeai
ue diLtae atous ehanges
constaut,bt the þrsituin 4 e
asis
)kit. the iginal bo
srAEGuaeu Loute uey thaw slaetehing

(a Seiszoung
In- plane beudiig
( Tioisting
Isteueulalion
Bean
betectn
Souree.ot
Radiatin ateneualiy
TRAadialions ae thocleeed by
Neunst Alauneut aeoaste)
- Nacl
650 2000

aue e
Gaseons liguid aaules Chat paieainn)
an alkaliwilal
allali milal
bealdelemined as
- Seid samplesK&r) þellel. KBY dees nol- abceb 2Radlday
ne
are
halioe (eg <peetnum
4o6D 65D
beosle/eliat pape
wsed.
hun tilw ot subs
s taue
- o qwd sauole a calibenity eguipue?.A
bond al 1601 eul shou the acewas o tague
 gines Regon Aotie
GION,LqoD
Cw
4oo - RE FRE L00 ()
otratli) QVENy
o0cnI cu-8 2980 -CH
Cui-3450
Cut 3600 DH -
c=o
a
te
has A
REGtON! FunCTIONAL
RoUP 0)
mmole a
cleut mino le eee will
ith elangA
ee toattiu Yle -
peue
ae. fnintr ge'
el,'juat
as fautieula
alseptuojn -ole the as
owe n)to ciatw ecpl" (tx
auodat ofbalouo the
ual
middlu (i)
 band
absptn
at tha
20

lo0tegueyagren
fingeuPit

A log
A =
Lo Trasntauee
A
Lt
(oo'mea = Mo abconplksi

Peali te hunetiena Grep

Alhenyl=t-H Sdr. 3100-3 ol0 un due to
Aken c=c sto.
C-H shr.
l680 -l620 cui!
genestalion
Aromatc c c bud =l7o0- 500 cur
Aleohot/phouoe o-H = 3550-3200cut
3650-3580-> hee o
3350 - 3200 >tateoeeulau H-bonelng
3015 > Dathamolaeula H-bore
Canboryle aid o-Hstr. 3000 -2500 cun!
= 350b -33 00 cu
Atdabyde C-0 sh l690-1+8oCu
Ketout c=0st.
Gster I30-133seu
Caboryc aud c =0 &h =1780 -(o cu
(6 90 -l6 30n
 Applicatioy 2R spealoßt ofy' tom fbatimd
oreecmstant
Bond atnength
oks law va
Ass aeprding to to
ma

K
(s) 27T Cmm/n m
whee
(i
two atims(?)
m,,m a bod i
t Aae fbaten tequey (v) a
nerease.
( e s < = < = ) a d hedueed mes (ue
O-H> -0)
a-Delei minalon the shape noleeule
brattod. Fo 'neale n-5 fonnon-luea
3-6 e o n enpod(6Qualitaune
anayi )
htnee of-bauols. wheli n a
5 ai ue
i i Moleula H-bondigp
6- istinetin bfo 2,uha
H-bendi
 moleeuled ane
Whaatoa ene
vlbsalioal tianeilon
Wbuatoa Applud,
the tansibóu tiowa
couesperveling t li
sta
Ihe ibaatiönt istereild
qAond stali (Y) do themallbatt."
tndae
vibatioualleuet
D, l, 2,3-
thb -(V+ )hy egs;v-

Tranitiny
Gandls ae hoebn as velone
the

=2
he caleulatedl.
oveitouel ean

vibà co ANO maleeulks !

8. cal euate funtaetal odes NO -3x3-9
CO -Tolal3x3-9 q-52 4| Tronsa3
Rotalionel 2 vib"=
(linea) Trans. =3, Rotn=3
Rinazl|1) vib^ 9-6

2R Aclue
 Vsbaalual
vmpouu &lali
at a higber fug- as tontad to sben
abipbs Ce
o solid stale. atit42 en
aolone 0ceus

aßsociaton n li
dpple-opole
whieh weakeus canbonyl bond plase)

Seet Soleti Pote sane

non-peen to fola solieut, tes ats EHano
Solpenta Heane |CAlouafo
1+13

non-pola to pola
tow

the xos t e t y bnd stenu

aleh weabs

3) Electhone dea-u to cleetnonie feea;

aneg HCHO cH cHO > cH-2-cHs
(1150eui) (1+4sei) (H5 ut )
weálniiy lc=o bond.hes, y deeeases a
Bond i-e.
k deerasey
Q. Heo DR speelia ceabonyl couydi (alelebyde /uelave)
 Slali' vnpou slal asubdavee
abienbs at a highe
Ziy o solid statt.

opole agtociaton an
Dle
hieh acakew a bonyl bond

c/ Seluet! Pe-ttue sawe

Solvail: Hexane
|CAlso{o tanel
l426 n 113

pola to pota
s that to mon-
bond

eils --Du to eationde ffeeti; kk(4oecona sud

3 Electhone chane.

Poeg HCHOS cH CHO > CH2-cs

eauaes tI «4eel , then deeeases as
wealeniit lc=o bond.hees, y
bmd i-e.
k deearey.
 can be eto as
R
(polar atrubie)
2 (I) tompanedtostrI

dble bodchavale
n
de to te Ae deteon
Heenee lordes.

olefiue
the
detocalisatis 'Bue
eaastocd,
enn
basgenadoubebond cbaracei,eanbony
tHhads wthy bingle bod
St
abkbs at lADt!
-C=

atead 1H8

Compa the eostr abs

4C=CH--!

( b-et)
Cougatieutdamiala
HYDROGEN 8ONDING!
’ broad banl
)atumokula H-bud gies Shant well
ines
Duta motseul Hboud