SAFETY DATA SHEET

SIGMACOVER 350 BASE REDBROWN 6179

Date of issue 14 October 2021

Version 13

1. Product and company identification

Product name : SIGMACOVER 350 BASE REDBROWN 6179
Product code : 40350-C6179/16L
Product type : Liquid.

Relevant identified uses of the substance or mixture and uses advised against
Product use : Professional applications, Used by spraying.
Use of the substance/ : Coating.
mixture
Uses advised against : Not applicable.

Supplier's details : PPG PMC Japan Co., Ltd.

8F, Shintetsu Bldg., 1-1, Daikaidori 1-chome, Kobe 652-0803
Tel : +81 78 574 2777
Fax : +81 78 576 0035

Emergency telephone : 078 574 2777

number

2. Hazards identification
GHS Classification : FLAMMABLE LIQUIDS - Category 3
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
AQUATIC HAZARD (ACUTE) - Category 2
AQUATIC HAZARD (LONG-TERM) - Category 3

GHS label elements

Hazard pictograms :

Signal word : Danger

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2. Hazards identification
Hazard statements : Flammable liquid and vapor.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye damage.
May cause drowsiness or dizziness.
Suspected of causing cancer.
May damage fertility or the unborn child.
Causes damage to organs. (central nervous system (CNS), kidneys, liver,
respiratory system)
Causes damage to organs through prolonged or repeated exposure. (central
nervous system (CNS), nervous system, respiratory system)
Toxic to aquatic life.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Wear protective gloves, protective clothing and
eye or face protection. Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking. Use only outdoors or in a well-ventilated
area. Avoid release to the environment. Do not breathe vapor. Do not eat, drink or
smoke when using this product. Wash thoroughly after handling. Contaminated
work clothing should not be allowed out of the workplace.
Response : IF exposed or concerned: Call a POISON CENTER or doctor. IF INHALED:
Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of
water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.

Other hazards which do not : Prolonged or repeated contact may dry skin and cause irritation.
result in classification

3. Composition/information on ingredients
Substance/mixture : Mixture

CAS number/other identifiers

CAS number : Not applicable.
CSCL number : Not available.
Ingredient name % CAS number CSCL
Talc (containing no asbestos or quartz) 20 - <25 14807-96-6 Not available.
crystalline silica, respirable powder (>10 microns) 15 - <20 14808-60-7 1-548
Epoxy Resin (700<MW<=1100) 12.5 - <15 25036-25-3 Not available.
Xylene 10 - <12.5 1330-20-7 3-3; 3-60
Epoxy resin (MW ≤ 700) 5 - <7 25068-38-6 (7)-1279
Diiron trioxide 3 - <5 1309-37-1 1-357; 5-5188
benzyl alcohol 3 - <5 100-51-6 3-1011
isobutyl alcohol 3 - <5 78-83-1 2-3049
ethyl benzene 2 - <3 100-41-4 3-28; 3-60
12-hydroxyoctadecanoic acid, reaction products 1 - <2 220926-97-6 Not available.
with 1,3-benzenedimethanamine and
hexamethylenediamine

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3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
SUB codes represent substances without registered CAS Numbers.

4. First aid measures

Description of necessary first aid measures
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open. Seek immediate medical
attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do NOT induce vomiting.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact : Causes damage to organs following a single exposure in contact with skin. Causes
skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : Causes damage to organs following a single exposure if swallowed. Can cause
central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations

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4. First aid measures

Ingestion : Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

5. Fire-fighting measures
Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In
from the chemical a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. This material is toxic to aquatic life. This material is
harmful to aquatic life with long lasting effects. Fire water contaminated with this
material must be contained and prevented from being discharged to any waterway,
sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides
nitrogen oxides
halogenated compounds
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.

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6. Accidental release measures

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

7. Handling and storage

Precautions for safe : Put on appropriate personal protective equipment (see Section 8). Persons with a
handling history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. Do not ingest. Avoid release to the environment. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter
storage areas and confined spaces unless adequately ventilated. Keep in the original
container or an approved alternative made from a compatible material, kept tightly
closed when not in use. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Take precautionary measures
against electrostatic discharges. Empty containers retain product residue and can be
hazardous. Do not reuse container.

Conditions for safe storage : Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in
accordance with local regulations. Store in a segregated and approved area. Store in
original container protected from direct sunlight in a dry, cool and well-ventilated area,
away from incompatible materials (see Section 10) and food and drink. Store locked
up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container
tightly closed and sealed until ready for use. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination. See
Section 10 for incompatible materials before handling or use.

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8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Talc (containing no asbestos or quartz) Japan Society for Occupational Health
(Japan, 5/2020).
OEL-M: 0.5 mg/m³ 8 hours. Form:
Respirable dust (Class 1 Dust)
OEL-M: 2 mg/m³ 8 hours. Form: Total dust
(Class 1 Dust)
crystalline silica, respirable powder (>10 microns) Japan Society for Occupational Health
(Japan, 5/2020).
OEL-C: 0.03 mg/m³ Form: Respirable dust
Xylene ISHL (Japan, 6/2020).
TWA: 50 ppm 8 hours.
Japan Society for Occupational Health
(Japan, 5/2020).
OEL-M: 50 ppm 8 hours.
OEL-M: 217 mg/m³ 8 hours.
Diiron trioxide Japan Society for Occupational Health
(Japan, 5/2020).
OEL-M: 1 mg/m³ 8 hours. Form: Respirable
dust (Class 2 Dust)
OEL-M: 4 mg/m³ 8 hours. Form: Total dust
(Class 2 Dust)
benzyl alcohol Japan Society for Occupational Health
(Japan, 5/2020). Skin sensitizer.
OEL-C: 25 mg/m³
isobutyl alcohol Japan Society for Occupational Health
(Japan, 5/2020).
OEL-M: 150 mg/m³ 8 hours.
OEL-M: 50 ppm 8 hours.
ISHL (Japan, 6/2020).
TWA: 50 ppm 8 hours.
ethyl benzene Japan Society for Occupational Health
(Japan, 5/2020).
OEL-M: 217 mg/m³ 8 hours.
OEL-M: 50 ppm 8 hours.
ISHL (Japan, 6/2020).
TWA: 20 ppm 8 hours.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring
standards. Reference to national guidance documents for methods for the
determination of hazardous substances will also be required.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
controls or other engineering controls to keep worker exposure to airborne contaminants
below any recommended or statutory limits. The engineering controls also need to
keep gas, vapor or dust concentrations below any lower explosive limits. Use
explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

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8. Exposure controls/personal protection

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye protection : Chemical splash goggles and face shield.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Gloves : butyl rubber
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If
workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed
respirator complying with an approved standard if a risk assessment indicates this is
necessary.

9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Red.
Odor : Aromatic.
Boiling point : >37.78°C (>100°F)
Flash point : Closed cup: 30°C (86°F)
Relative density : 1.19
Solubility : Insoluble in the following materials: cold water.
Viscosity : Not Applicable

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10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.

Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.

Hazardous decomposition : Depending on conditions, decomposition products may include the following
products materials: carbon oxides nitrogen oxides halogenated compounds metal oxide/
oxides

11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Epoxy Resin (700<MW LD50 Dermal Rat >2000 mg/kg -
<=1100)
LD50 Oral Rat >2000 mg/kg -
Xylene LD50 Dermal Rabbit 1.7 g/kg -
LD50 Oral Rat 4.3 g/kg -
Epoxy resin (MW ≤ 700) LD50 Dermal Rabbit >2 g/kg -
LD50 Oral Rat >2 g/kg -
Diiron trioxide LC50 Inhalation Dusts and mists Rat >5 mg/l 4 hours
LD50 Oral Rat 10 g/kg -
benzyl alcohol LC50 Inhalation Dusts and mists Rat >4178 mg/m³ 4 hours
LD50 Dermal Rabbit 2000 mg/kg -
LD50 Oral Rat 1.23 g/kg -
isobutyl alcohol LC50 Inhalation Vapor Rat 24.6 mg/l 4 hours
LD50 Dermal Rabbit 2460 mg/kg -
LD50 Oral Rat 2830 mg/kg -
ethyl benzene LC50 Inhalation Vapor Rat 17.8 mg/l 4 hours
LD50 Dermal Rabbit 17.8 g/kg -
LD50 Oral Rat 3.5 g/kg -
12-hydroxyoctadecanoic LC50 Inhalation Dusts and mists Rat 3.56 mg/l 4 hours
acid, reaction products with
1,3-benzenedimethanamine
and hexamethylenediamine
LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >2000 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Xylene Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Epoxy resin (MW ≤ 700) Skin - Mild irritant Rabbit - - -
Eyes - Mild irritant Rabbit - - -
Sensitization

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11. Toxicological information

Product/ingredient name Route of Species Result
exposure
Epoxy resin (MW ≤ 700) skin Mouse Sensitizing
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.

Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Talc (containing no asbestos or quartz) Category 1 - respiratory system
Xylene Category 1 - central nervous
system (CNS),
kidneys, liver,
respiratory system
Category 3 Narcotic effects
Diiron trioxide Category 1 - respiratory system
benzyl alcohol Category 1 - central nervous
system (CNS),
kidneys
Category 3 Narcotic effects
isobutyl alcohol Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
ethyl benzene Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Talc (containing no asbestos or quartz) Category 1 - respiratory system
Xylene Category 1 - nervous system,
respiratory system
Diiron trioxide Category 1 - respiratory system
benzyl alcohol Category 1 - central nervous
system (CNS)
ethyl benzene Category 2 - hearing organs
12-hydroxyoctadecanoic acid, reaction products with Category 2 inhalation lungs
1,3-benzenedimethanamine and hexamethylenediamine
Aspiration hazard
Name Result
Xylene ASPIRATION HAZARD - Category 1
ethyl benzene ASPIRATION HAZARD - Category 1

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11. Toxicological information

Information on the likely : Not available.
routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact : Causes damage to organs following a single exposure in contact with skin. Causes
skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : Causes damage to organs following a single exposure if swallowed. Can cause
central nervous system (CNS) depression.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
stomach pains
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
General : Causes damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
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11. Toxicological information

Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : May damage fertility or the unborn child.

Numerical measures of toxicity

Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts
(ppm) (mg/l) and mists)
(mg/l)
SIGMACOVER 350 BASE REDBROWN 6179 7934.8 3320.4 N/A 46 19.7
Epoxy Resin (700<MW<=1100) 2500 2500 N/A N/A N/A
Xylene 4300 1700 N/A 11 N/A
Epoxy resin (MW ≤ 700) 2500 2500 N/A N/A N/A
Diiron trioxide 10000 N/A N/A N/A N/A
benzyl alcohol 1230 2000 N/A N/A 1.5
isobutyl alcohol 2830 2460 N/A 11 N/A
ethyl benzene 3500 17800 N/A 17.8 N/A
12-hydroxyoctadecanoic acid, reaction products 2500 2500 N/A N/A 3.56
with 1,3-benzenedimethanamine and
hexamethylenediamine

Other information :
Prolonged or repeated contact may dry skin and cause irritation. Sanding and grinding dusts may be harmful if inhaled.
Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain
and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits
causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with skin and
clothing.

12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Epoxy resin (MW ≤ 700) Acute LC50 1.8 mg/l Daphnia 48 hours
Chronic NOEC 0.3 mg/l Daphnia 21 days
Diiron trioxide Acute EC50 >100 mg/l Daphnia 48 hours
isobutyl alcohol Acute EC50 1100 mg/l Daphnia 48 hours
ethyl benzene Acute EC50 1.8 mg/l Fresh water Daphnia 48 hours
Chronic NOEC 1 mg/l Fresh water Daphnia - Ceriodaphnia dubia -
12-hydroxyoctadecanoic Acute EC50 >100 mg/l Algae - Pseudokirchneriella 72 hours
acid, reaction products with subcapitata (microalgae)
1,3-benzenedimethanamine
and hexamethylenediamine
Acute EC50 >100 mg/l Daphnia - Daphnia magna 48 hours
(Water flea)
Acute LC50 >100 mg/l Fish - Oncorhynchus mykiss 96 hours
(rainbow trout)
Chronic NOEC 100 mg/l Algae - Pseudokirchneriella 72 hours
subcapitata
Chronic NOEC ≥50 mg/l Daphnia - Daphnia magna 21 days
(Water flea)

Persistence/degradability

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12. Ecological information

Product/ingredient name Test Result Dose Inoculum
Epoxy resin (MW ≤ 700) OECD 301F 5 % - 28 days - -
ethyl benzene - 79 % - Readily - 10 days - -
12-hydroxyoctadecanoic OECD 301D 9 % - Not readily - 29 days - -
acid, reaction products with Ready
1,3-benzenedimethanamine Biodegradability -
and hexamethylenediamine Closed Bottle
Test

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Xylene - - Readily
Epoxy resin (MW ≤ 700) - - Not readily
benzyl alcohol - - Readily
ethyl benzene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Xylene 3.12 7.4 to 18.5 low
Epoxy resin (MW ≤ 700) 3 31 low
benzyl alcohol 0.87 - low
isobutyl alcohol 1 - low
ethyl benzene 3.6 79.43 low
12-hydroxyoctadecanoic >6 - high
acid, reaction products with
1,3-benzenedimethanamine
and hexamethylenediamine

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

Other adverse effects : No known significant effects or critical hazards.

13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapor from product residues
may create a highly flammable or explosive atmosphere inside the container. Do
not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.

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14. Transport information

UN IMDG IATA
UN number UN1263 UN1263 UN1263
UN proper PAINT PAINT PAINT
shipping name
Transport hazard 3 3 3
class(es)
Packing group III III III
Environmental No. No. No.
hazards
Marine pollutant Not applicable. Not applicable. Not applicable.
substances

Additional information
UN : None identified.
IMDG : None identified.
IATA : None identified.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not applicable.

to IMO instruments

15. Regulatory information

Fire Service Law
Category Substance name/Type Danger Signal word Designated
category quantity
Category IV Class II petroleums III Flammable - Keep Fire Away 1000 L

Pollutant Release and Transfer Registers (PRTR)

Ingredient name % Status Reference
number
Xylene 12.406 Class 1 80
Ethylbenzene 2.205 Class 1 53

ISHL

Use of specified chemical substances

Ingredient name % Status Reference
number
Ethyl benzene ≤2.6 Group-2 Substances under 3-3
Supervision

Substances requiring labelling

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Product code 40350-C6179/16L Date of issue 14 October 2021 Version 13
Product name SIGMACOVER 350 BASE REDBROWN 6179

15. Regulatory information

Ingredient name % Status Reference
number
Crystalline silica ≥10 - ≤25 Listed 165-2
Xylene ≥10 - ≤25 Listed 136
Iron oxide; Diiron(III) trioxide <10 Listed 192
Butanol ≤5.0 Listed 477
Ethylbenzene ≤2.6 Listed 70

Chemicals requiring notification

Ingredient name % Status Reference
number
Crystalline silica ≥10 - ≤25 Listed 165-2
Xylene ≥10 - ≤25 Listed 136
Iron oxide; Diiron(III) trioxide <10 Listed 192
Butanol ≤5.0 Listed 477
Ethylbenzene ≤2.6 Listed 70
Carcinogen
Ingredient name % Status Reference
number
ethylbenzene ≤2.6 Listed -

Mutagen
None of the components are listed.

Corrosive liquid : Not listed

Occupational Safety and : Flammable liquid Class 4
Health Law
Regulations on the : Not listed
Prevention of Tetraalkyl
Lead Poisoning
Harmful Substances : Not listed
Subject to Obtaining
Permission for
Manufacturing
Harmful Substances, : Not listed
Prohibited for
Manufacturing
Dangerous Substances : Inflammable
Lead regulation : Not listed
Organic solvents : Class 2
poisoning prevention

Poisonous and Deleterious Substances

None of the components are listed.
Chemical Substances Control Law (CSCL)

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Product code 40350-C6179/16L Date of issue 14 October 2021 Version 13
Product name SIGMACOVER 350 BASE REDBROWN 6179

15. Regulatory information

Ingredient name % Status Reference
number
Xylene 12.406 Priority assessment 125
Ethylbenzene 2.205 Priority assessment 50
Toluene 0.0867 Priority assessment 46
Benzene 0.002214 Priority assessment 45
High Pressure Gas Control : Not available.
Law

Explosives Control Law

None of the components are listed.

Law Concerning Prevention : Not available.

of Pollution of the Ocean
and Maritime Disaster

Maritime Safety Law

Notification Regulating Transportation of Dangerous Materials by Sea
None of the components are listed.

Container class
None of the components are listed.

JSOH Carcinogen : Group 1

List of Specially Controlled : Not listed
Industrial Waste
Japan inventory : At least one component is not listed.
Road law : Not available.

16. Other information

History
Date of issue/Date of : 14 October 2021
revision
Date of previous issue : 10/26/2020
Version : 13
Prepared by : EHS
Key to abbreviations : ADN = European Provisions concerning the International Carriage of Dangerous
Goods by Inland Waterway
ADR = The European Agreement concerning the International Carriage of
Dangerous Goods by Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
RID = The Regulations concerning the International Carriage of Dangerous Goods
by Rail
UN = United Nations
Indicates information that has changed from previously issued version.

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Product code 40350-C6179/16L Date of issue 14 October 2021 Version 13
Product name SIGMACOVER 350 BASE REDBROWN 6179

16. Other information

Notice to reader
The information contained in this data sheet is based on present scientific and technical knowledge. The
purpose of this information is to draw attention to the health and safety aspects concerning the products
supplied by PPG, and to recommend precautionary measures for the storage and handling of the products.
No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted
for any failure to observe the precautionary measures described in this data sheet or for any misuse of the
products.

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