0% found this document useful (0 votes)
93 views15 pages

Nalfleet 9-303

The Safety Data Sheet for product 9-303 identifies it as a CLP mixture used as a fuel oil stabilizer, supplied by Nalco Europe B.V. It is classified as hazardous, causing severe skin burns, eye damage, and being suspected of causing cancer, with specific precautions for handling and storage outlined. Emergency measures, first aid responses, and environmental precautions are also detailed to ensure safety during use and in case of spills.

Uploaded by

remco.peters
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
93 views15 pages

Nalfleet 9-303

The Safety Data Sheet for product 9-303 identifies it as a CLP mixture used as a fuel oil stabilizer, supplied by Nalco Europe B.V. It is classified as hazardous, causing severe skin burns, eye damage, and being suspected of causing cancer, with specific precautions for handling and storage outlined. Emergency measures, first aid responses, and environmental precautions are also detailed to ensure safety during use and in case of spills.

Uploaded by

remco.peters
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 15

Safety Data Sheet according to Regulation (EC) No

1907/2006

Product

9-303

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING

1.1 Product identifier: 9-303


Type of substance CLP Mixture

1.2 Relevant identified uses of the substance or mixture and uses advised against:

Use of the : FUEL OIL STABILIZER


Substance/Mixture

1.3 Details of the supplier of the safety data sheet:

COMPANY IDENTIFICATION LOCAL COMPANY IDENTIFICATION


NALCO EUROPE B.V. Nalco Ltd.
Postbus 627 P.O. BOX 11, WINNINGTON AVENUE
2300 AP Leiden, The Netherlands NORTHWICH, CHESHIRE, U.K. CW8 4DX
TEL: 0031 71 5241100 TEL: +44 (0)1606 74488

For additional copies of an MSDS visit www.nalco.com and request access.


For Product Safety information please contact: EUProductSafety@nalco.com

1.4 Emergency telephone number: +32-(0)3-575-5555 Trans-European

Date of Compilation/Revision:: 03.10.2012


Version Number: 1.0

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:

Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation - Category 1B H314


Serious eye damage/eye irritation - Category 1 H318
Specific target organ toxicity - single exposure - H336
Category 3
Carcinogenicity - Category 2 H351
Chronic aquatic toxicity - Category 2 H411

Classification according to EU Directives 67/548/EEC or 1999/45/EC

This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.

C, CORROSIVE R34, R40, R51/53, R67


N, DANGEROUS FOR THE ENVIRONMENT

Refer to Section 16 for full details of the risk phrases, hazard statements and Notas.

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
1 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

2.2 Label elements:

Labelling according to Regulation (EC) No 1272/2008

Contains: 1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline, Heavy Aromatic Naphtha, Naphthalene

Hazard pictograms:

Signal Word: Danger

Hazard Statements:
H314 Causes severe skin burns and eye damage.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse
skin with water/ shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.

2.3 Other hazards:

None known

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixture:

The details below include all impurities and by-products that contribute to the product classification or that have
an occupational exposure limit.

Hazardous Substance(s) % (w/w) Classification according to Classification according


Regulation (EC) No 1272/2008 to 67/548/EEC

Amine Substituted Resin 30.0 - 60.0 Serious eye damage/eye irritation : H319 Xi
CAS-No.: Proprietary 2 R36

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
2 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

1-(2-Hydroxyethyl)-2-Tall Oil-2- 10.0 - 30.0 Skin corrosion/irritation 1B : H314 C


Imidazoline R34
EC-No.: 263-171-2
CAS-No.: 61791-39-7
REACH No.: 01-2119931039-40

Hydrocarbons, C10, aromatics, >1% 10.0 - 30.0 Aspiration hazard 1 : H304 Xn, N, Carc. 3
naphthalene Specific target organ toxicity - : H336 R65, R67, R66, R40,
EC-No.: 919-284-0 single exposure 3 R51/53
CAS-No.: 64742-94-5 Chronic aquatic toxicity 2 : H411
REACH No.: 01-2119463588-24 Carcinogen 2 : H351

Naphthalene 1.0 - 5.0 Carcinogen 2 : H351 Xn, N


Index-No.: 601-052-00-2 Acute toxicity 4 : H302 R22, R40, R50/53
EC-No.: 202-049-5 Acute aquatic toxicity 1 : H400
CAS-No.: 91-20-3 Chronic aquatic toxicity 1 : H410

Refer to Section 16 for full details of the risk phrases, hazard statements and Notas.

SECTION 4. FIRST AID MEASURES

4.1 Description of necessary first-aid measures:

In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt,
contact emergency

INHALATION
Remove to fresh air, treat symptomatically. Get immediate medical attention.

SKIN CONTACT
Get immediate medical attention. Remove contaminated clothing. Wash clothing before reuse. Immediately flush
with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. PROMPT ACTION IS
ESSENTIAL IN CASE OF CONTACT.

EYE CONTACT
Immediately flush with plenty of water for at least 15 minutes. Get immediate medical attention. PROMPT
ACTION IS ESSENTIAL IN CASE OF CONTACT.

INGESTION
Seek medical advice immediately, showing the label and/or SDS. If conscious, washout mouth and give water to
drink. If unconsious, do not give anything by mouth, place in the recovery position, check breathing and pulse. If
necessary give artifical respiration. Do not induce vomiting without medical advice.

PROTECTION FOR FIRST AID PERSONNEL


Wear adequate personal protective equipment.

4.2 Most important symptoms and effects, both acute and delayed:

Causes severe skin burns and eye damage. May cause drowsiness or dizziness. Suspected of causing cancer.

4.3 Indication of immediate medical attention and special treatment needed:

Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the
patient, the physician's judgement should be used to control symptoms and clinical condition.

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
3 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

SECTION 5. FIRE-FIGHTING MEASURES

5.1 Extinguishing media:

SUITABLE EXTINGUISHING MEDIA


Water mist may be used to cool closed containers.
Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use
water spray or fog, thoroughly drenching the burning material.

UNSUITABLE EXTINGUISHING MEDIA


Do not use water unless flooding amounts are available.

5.2 Special hazards arising from the substance or mixture:

Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may
contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of
ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire
conditions.

In the event of a spill, prevent material and fire water from entering sewers or waterways.

5.3 Advice for firefighters:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:

ADVICE FOR NON-EMERGENCY PERSONNEL


This material may be hazardous by contact, do not attempt to clean up the spill. Call trained emergency
responders immediately. Clean up only to be done by Emergency responders/personnel. Restrict access to area
as appropriate until clean-up operations are complete.
Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).

ADVICE FOR EMERGENCY RESPONDERS


Restrict access to area as appropriate until clean-up operations are complete. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is
safe to do so. Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by
trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.)
readily available. Notify appropriate government, occupational health and safety and environmental authorities.

6.2 Environmental precautions:

In the event of a spill, prevent material from entering sewers or waterways. Do not allow material to contaminate
ground water system. Prevent product from entering drains. If drains, streams, soil or sewers become
contaminated, notify local authority. This product may pose a risk to the aquatic ecosystem if released.

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
4 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

6.3 Methods and materials for containment and cleaning up:

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or
by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated
recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal
Considerations).

6.4 Reference to other sections:

Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).


Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling:

HANDLING
Prevent contact with skin, eyes and clothing. Use with adequate ventilation. Do not breathe vapors/gases/dust.
Keep the containers closed when not in use. Do not mix with acids. Keep away from acids and oxidizing agents.
Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).

Refer to section 6.2 for Environmental Precautions

HYGIENE RECOMMENDATIONS
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a
safety shower available. Always wash thoroughly after handling chemicals. When handling this product never
eat, drink or smoke.

7.2 Conditions for safe storage, including any incompatibilities:

STORAGE CONDITIONS
Store in suitable labeled containers. Store the containers tightly closed. Store away from heat and sources of
ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be
grounded to avoid electrical charges. Store separately from oxidizers.

SUITABLE CONSTRUCTION MATERIAL


Teflon, Aluminum, Mild steel, Carbon Steel C1018, Stainless Steel 304, Stainless Steel 316L, Hastelloy C-276,
Plexiglass, PTFE, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is
tested prior to use.

UNSUITABLE CONSTRUCTION MATERIAL


Copper, Neoprene, Ethylene propylene, Polypropylene, Polyethylene, EPDM, Alfax, Brass, PVC, Buna-N,
HDPE (high density polyethylene), Natural rubber, Polyurethane, Hypalon, Viton

7.3 Specific end uses:

Specific use(s) :
FUEL OIL STABILIZER

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
5 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:

OCCUPATIONAL EXPOSURE LIMITS

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.
Source Substance(s) Category: ppm mg/m3

Manufacturer's Hydrocarbons, C10, aromatics, >1% naphthalene TWA 100


Recommendation

United Kingdom Ethylbenzene TWA 100 441


STEL 125 552
Skin*

* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and
the eyes.

MONITORING MEASURES
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed
as referenced below:
Substance(s) Method Analysis Absorbant
Naphthalene US NIOSH: 1501 Gas chromatography Charcoal
Ethylbenzene US NIOSH: 1501 Gas chromatography Charcoal

BIOLOGICAL EXPOSURE INDICES


Ethylbenzene A biological index of exposure to ethyl benzene (CAS 100-41-4) is the detection of ethyl
benzene in the blood post shift (Germany, 1mg/l). Another biological index is the
detection of mandelic acid in the urine post shift (USA, 1.5g/g creatinine; Findland,
5.2mmol/l; Germany 800mg/g creatinine) and the detection of phenylglyoxylic acid in
urine post shift (Germany, 800mg/g creatinine).

DNEL
Components:

End Use: Exposure routes: Potential health Value:


effects:
Hydrocarbons, C10, aromatics, >1% naphthalene
Workers Dermal long term - systemic 125 mg/kg
Workers Inhalation long term - systemic 151 mg/m3

8.2 Exposure controls:

ENGINEERING MEASURES:
General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions
near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of
confined spaces.

PERSONAL PROTECTIVE EQUIPMENT

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
6 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

GENERAL ADVICE
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and
the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields.

EYE/FACE PROTECTION
When handling this product, the use of a face shield is recommended. The applicable European standard can be
found in EN 166.

SKIN PROTECTION
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends
on work conditions and what chemicals are handled, but we have positive experience under light handling
conditions using gloves made from Nitrile Gloves should be replaced immediately if signs of degradation are
observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable
European standard can be found in EN 374.
When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The
applicable European standard can be found in EN ISO 20345.

RESPIRATORY PROTECTION
Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air
supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of
chemicals being handled. Consider the use of filter type: A-B-E-K-P The applicable European standard can be
found in EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown
concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required,
institute a complete respiratory protection program including selection, fit testing, training, maintenance and
inspection.

ENVIRONMENTAL EXPOSURE CONTROLS


Consider the provision of containment around storage vessels.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Note: These physical properties are typical values for this product and are subject to change.
9.1 Information on basic physical and chemical properties:
9.1 Information on basic physical and chemical properties:

PHYSICAL STATE Liquid


APPEARANCE Clear Amber
Odour Hydrocarbon
Odour Threshold No data available.
pH No data available.
POUR POINT < -29.9 °C
INITIAL BOILING POINT / BOILING No data available.
RANGE
FLASH POINT 66.1 °C PMCC ASTM D-93
EVAPORATION RATE No data available.
FLAMMABILITY (solid, gas) No data available.
LOWER EXPLOSION LIMIT No data available.
UPPER EXPLOSION LIMIT No data available.
VAPOR PRESSURE 0.69 kPa (37.8 °C)
VAPOR DENSITY No data available.

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
7 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

9.1 Information on basic physical and chemical properties:

Relative density 0.92 (15.6 °C)


DENSITY No data available.
SOLUBILITY IN WATER Dispersible
OCTANOL/WATER COEFFICIENT No data available.
(log Kow)
AUTOIGNITION TEMPERATURE No data available.
DECOMPOSITION TEMPERATURE No data available.
VISCOSITY 106 cst (15.6 °C) ASTM D-445
VISCOSITY 97 cps (15.6 °C)
VISCOSITY 489 SUS (15.6 °C)
EXPLOSIVE PROPERTIES Not applicable
OXIDIZING PROPERTIES Not applicable

9.2 Other information:

Not applicable

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity:

Stable under normal conditions.

10.2 Chemical stability:

Stable under normal conditions.

10.3 Possibility of hazardous reactions:

Hazardous polymerization will not occur.

10.4 Conditions to avoid:

Heat and sources of ignition including static discharges.

10.5 Incompatible materials:

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,
permanganate) may generate heat, fires, explosions and/or toxic vapors.

10.6 Hazardous decomposition products:

Under fire conditions: Oxides of carbon, Oxides of nitrogen

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects:

Product:

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
8 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

Acute oral toxicity : LD50: 2,500 mg/kg, Rat, Test substance: Product
Acute inhalation toxicity : Based on available data, the classification criteria are not met.
Acute dermal toxicity : LD50: 5,600 mg/kg, Rabbit, Test substance:
Product
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/eye : Causes severe skin burns and eye damage.
irritation
Respiratory or skin : Based on available data, the classification criteria are not met.
sensitization
Genotoxicity
Assessment : Contains no ingredient listed as a mutagen
Carcinogenicity : Suspected of causing cancer.
Reproductive toxicity : Based on available data, the classification criteria are not met.
Assessment:
STOT - single exposure : Remarks: May cause drowsiness or dizziness.
STOT - repeated exposure : Based on available data, the classification criteria are not met.
Aspiration toxicity : No aspiration toxicity classification

Components:

1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline
Skin corrosion/irritation : Rabbit, Result: Corrosive, OECD 404, 4 h
Serious eye damage/eye : Rabbit, Result: Corrosive, EPA OPP 81-4, 1 h
irritation
Hydrocarbons, C10, aromatics, >1% naphthalene
Acute oral toxicity : LD50: ca. 6,318 mg/kg, Rat, OECD 401
Acute dermal toxicity : LD50: > 2,000 mg/kg, Rabbit, OECD 402
Skin corrosion/irritation : Rabbit, Result: Not irritating, OECD 404
Serious eye damage/eye : Rabbit, Result: Not irritating, OECD 405
irritation
Respiratory or skin : Guinea pig, Result: Negative, OECD 406, Read-across
sensitization (Analogy)
Genotoxicity
Genotoxicity in vitro : Ames test, Result: negative, OECD 471
: In vitro gene mutation study in mammalian cells, Result:
negative, OECD 476
: Chromosome aberration test in vitro, Result: negative, OECD
473
: In vitro Sister Chromatid Exchange Assay, Result: negative,
OECD 479

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
9 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

Genotoxicity in vivo : Chromosome aberration in vivo, Rat, OECD 475, Result:


negative
: In vivo micronucleus test, Mouse, OECD 474, Result:
negative,
Read-across (Analogy)
Assessment : In vitro tests did not show mutagenic effects, In vivo tests did
not show mutagenic effects
Reproductive toxicity : Rat, Inhalation, NOAEL: 8.22086 mg/l, F1: 2.74029 mg/l, F2:
2.74029 mg/l, OECD 416, Read-across (Analogy)
Assessment: No toxicity to reproduction
Teratogenicity : Rat, Oral, NOAEL: > 450 mg/kg, 150 mg/kg, OECD 414,
Read-across (Analogy)
Assessment: Did not show teratogenic effects in animal
experiments.
STOT - single exposure : Assessment: May cause drowsiness or dizziness.
STOT - repeated exposure : Rat, Oral, 91 d, NOAEL: 300 mg/kg, OECD 408, Read-across
(Analogy)
STOT - repeated exposure : Rat, Inhalation, 365 d, NOAEC, 900 mg/m3, OECD 452
: Target Organs: no data available

SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity:

The following results are for the product.

Product:
Toxicity to fish : LC50: 7.5 mg/l, 96 hrs, Turbot, Test substance: Product
: LC50: 1.17 mg/l, 96 hrs, Rainbow Trout, Test substance:
Product
: LC50: 1.09 mg/l, 96 hrs, Bluegill Sunfish, Test substance:
Product
Toxicity to daphnia and other : LC50: 6.2 mg/l, 48 hrs, Acartia tonsa, Test substance: Product
aquatic invertebrates.
: LC50: 1.5 mg/l, 48 hrs, Daphnia magna, Test substance:
Product
: LC50: 1.5 mg/l, 48 hrs, Daphnia magna, Test substance:
Product
: NOEC: < 1.3 mg/l, 48 hrs, Daphnia magna, Test substance:
Product
Toxicity to algae : EC50: 1.7 mg/l, 72 hrs, Marine Algae (Skeletonema
costatum), Test substance: Product
Ecotoxicology Assessment
Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects.

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
10 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

Components:
Hydrocarbons, C10, aromatics, >1% naphthalene
Toxicity to fish : LL50: 2 - 5 mg/l, 96 h, Rainbow Trout, OECD 203
Toxicity to daphnia and other : EL50: 3 - 10 mg/l, 48 h, Daphnia magna, OECD 202
aquatic invertebrates.
Toxicity to algae : EL50: > 1 - < 3 mg/l, 72 h, Green Algae (Pseudokirchneriella
subcapitata, previously Selenastrum capricornutum), OECD
201
Toxicity to bacteria : NOELR: 1.892 mg/l, 48 h, Tetrahymena pyriformis, Calculated
Toxicity to fish (Chronic : NOELR: 0.487 mg/l, 28 d, Rainbow Trout, Calculated
toxicity)
Toxicity to daphnia and other : NOELR: 0.851 mg/l, 21 d, Daphnia magna, Calculated
aquatic invertebrates.
(Chronic toxicity)

12.2 Persistence and degradability:

Product:
Biodegradability : The organic portion of this preparation is expected to be
inherently biodegradable.

Components:
Hydrocarbons, C10, aromatics, >1% naphthalene
Biodegradability : 57.95 %, Result: Inherently biodegradable., Exposure time: 28
d, OECD 301 F (Manometric RespirometryI)

12.3 Bioaccumulative potential:

Product:
Bioaccumulation : Component substances have a potential to bioaccumulate.

Components:
Hydrocarbons, C10, aromatics, >1% naphthalene
Bioaccumulation : Potential bioaccumulation

12.4 Mobility in soil:

Product:
Environmental fate and : The portion in water is expected to be soluble or dispersible.
pathways

Components:
Hydrocarbons, C10, aromatics, >1% naphthalene
Distribution among : study scientifically unjustified
environmental compartments

12.5 Results of PBT and vPvB assessment:

Product:
Assessment : This mixture contains no substance considered to be

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
11 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

persistent, bioaccumulating nor toxic (PBT)., This mixture


contains no substance considered to be very persistent nor
very bioaccumulating (vPvB).

12.6 Other adverse effects:

Product:
Additional ecological : No adverse effects expected.
information

SECTION 13. DISPOSAL CONSIDERATIONS

If this preparation becomes a waste, the final user must define and assign the appropriate European Waste
Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.

13.1 Waste treatment methods:

Contact an approved waste hauler for disposal of contaminated recovered material. Any chemical waste is a
potential environmental pollutant and is NOT suitable for disposal via ground, municipal sewers, drains, natural
streams or rivers. Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance
with all applicable regulations. Do not dispose of wastes in local sewer or with normal garbage.
Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.

EUROPE WASTE CODE:


16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing
dangerous substances. If this product is used in any further processes, the final user must redefine and assign
the most appropriate European Waste Catalogue Code.

SECTION 14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT
14.1 UN number: UN 2735
14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S.
(1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline)
14.3 Transport hazard class(es): 8
14.4 Packing group: III
14.5 Environmental hazards: Yes
14.6 Special precautions for user: not applicable

AIR TRANSPORT (ICAO/IATA)


14.1 UN number: UN 2735
14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S.
(1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline)
14.3 Transport hazard class(es): 8
14.4 Packing group: III
14.5 Environmental hazards: Yes

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
12 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

14.6 Special precautions for user: not applicable

MARINE TRANSPORT (IMDG/IMO)


14.1 UN number: UN 2735
14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S.
(1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline)
14.3 Transport hazard class(es): 8
14.4 Packing group: III
14.5 Environmental hazards: Yes (Marine Pollutant)
14.6 Special precautions for user: not applicable
14.7 Transport in bulk according to not applicable
Annex II of MARPOL 73/78 and the IBC
Code:

SECTION 15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

INTERNATIONAL CHEMICAL CONTROL LAWS

EUROPE
Safety Data Sheet according to Regulation (EC) No 1907/2006.

Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals
(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into
European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.
Should you require any further information on Nalco's REACH programme please contact us at
reach@nalco.com or visit our website.

CANADA
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).

UNITED STATES
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

NATIONAL REGULATIONS GERMANY


WGK: 2 (Annex 4)

15.2 Chemical Safety Assessment:


A Chemical Safety Assessment has been carried out for the substance(s) that makes/make up this material or
for the material itself.

SECTION 16. OTHER INFORMATION

LIST OF RELEVANT R-PHRASES, NOTAS AND HAZARD STATEMENTS IN SECTION 2.1 AND 3
H302 - Harmful if swallowed.
H304 - May be fatal if swallowed and enters airways.
H314 - Causes severe skin burns and eye damage.
H318 - Causes serious eye damage.
H319 - Causes serious eye irritation.
H336 - May cause drowsiness or dizziness.
H351 - Suspected of causing cancer.

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
13 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

H400 - Very toxic to aquatic life.


H410 - Very toxic to aquatic life with long lasting effects.
H411 - Toxic to aquatic life with long lasting effects.
R22 - Harmful if swallowed.
R34 - Causes burns.
R36 - Irritating to eyes.
R40 - Limited evidence of a carcinogenic effect.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 - Harmful: may cause lung damage if swallowed.
R66 - Repeated exposure may cause skin dryness or cracking.
R67 - Vapours may cause drowsiness and dizziness.

This product Safety Data Sheet provides health, safety, and regulatory information. The information contained in
this Safety Data Sheet is based on data available to us at the date of issue , and is provided in good faith, and
believed to be accurate and reliable at the date of issue, however, no warranty, express or implied is provided,
and Nalco disclaims all liability for reliance on such information. The product is to be used in applications
consistent with Nalco’s product literature. For any other uses, exposures should be evaluated so that the
appropriate handling practices and training programs can be established to ensure safe working conditions and
operations. It is the buyer’s/user’s responsibility to satisfy itself that the product is suitable for the intended use,
and to ensure that its activities comply with all federal, state, provincial, or local laws and regulations.
Regulatory requirements are subject to change and may differ between European Member States and Nations.
Individuals handling this product should be informed of the recommended safety precautions and should have
access to this information. Please consult your local sales representative for any further information.

REFERENCES

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health
Organization, International Agency for Research on Cancer.

Ariel Insight™ (An integrated guide to industrial chemicals covered under major regulatory and advisory
programs), North American Module, Western European Module, Chemical Inventories Module and the Generics
Module (Ariel Insight™ CD-ROM Version), Ariel Research Corp., Bethesda, MD.

The possible key literature references and data sources which may have been used in conjunction with the
consideration of expert judgment to compile this Safety Data Sheet: European regulations/directives (including
(EC) No. 1907/2006, (EC) No. 1272/2008, 67/548/EEC, 1999/45/EC), supplier data, inter-net, ESIS, IUCLID,
ERIcards, Non European official regulatory data and other data sources.

Synonym substance identities are:


New Old

Hydrocarbons, C10, aromatics, >1% naphthalene Heavy Aromatic Naphtha


CAS-No.: 64742-94-5 CAS-No.: 64742-94-5

Date issued : 03.10.2012


Version Number : 1.0
Prepared By: SHE Department

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
14 / 15
Safety Data Sheet according to Regulation (EC) No
1907/2006

Product

9-303

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth

Nalco Europe Sàrl • Richtistrasse 7 • 8304 Wallisellen, Switzerland


For additional copies of an MSDS visit www.nalco.com and request access.
15 / 15

You might also like