Nalfleet 9-303
Nalfleet 9-303
1907/2006
Product
9-303
1.2 Relevant identified uses of the substance or mixture and uses advised against:
This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.
Refer to Section 16 for full details of the risk phrases, hazard statements and Notas.
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9-303
Hazard pictograms:
Hazard Statements:
H314 Causes severe skin burns and eye damage.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse
skin with water/ shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
None known
3.2 Mixture:
The details below include all impurities and by-products that contribute to the product classification or that have
an occupational exposure limit.
Amine Substituted Resin 30.0 - 60.0 Serious eye damage/eye irritation : H319 Xi
CAS-No.: Proprietary 2 R36
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Hydrocarbons, C10, aromatics, >1% 10.0 - 30.0 Aspiration hazard 1 : H304 Xn, N, Carc. 3
naphthalene Specific target organ toxicity - : H336 R65, R67, R66, R40,
EC-No.: 919-284-0 single exposure 3 R51/53
CAS-No.: 64742-94-5 Chronic aquatic toxicity 2 : H411
REACH No.: 01-2119463588-24 Carcinogen 2 : H351
Refer to Section 16 for full details of the risk phrases, hazard statements and Notas.
In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt,
contact emergency
INHALATION
Remove to fresh air, treat symptomatically. Get immediate medical attention.
SKIN CONTACT
Get immediate medical attention. Remove contaminated clothing. Wash clothing before reuse. Immediately flush
with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. PROMPT ACTION IS
ESSENTIAL IN CASE OF CONTACT.
EYE CONTACT
Immediately flush with plenty of water for at least 15 minutes. Get immediate medical attention. PROMPT
ACTION IS ESSENTIAL IN CASE OF CONTACT.
INGESTION
Seek medical advice immediately, showing the label and/or SDS. If conscious, washout mouth and give water to
drink. If unconsious, do not give anything by mouth, place in the recovery position, check breathing and pulse. If
necessary give artifical respiration. Do not induce vomiting without medical advice.
4.2 Most important symptoms and effects, both acute and delayed:
Causes severe skin burns and eye damage. May cause drowsiness or dizziness. Suspected of causing cancer.
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the
patient, the physician's judgement should be used to control symptoms and clinical condition.
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9-303
Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may
contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of
ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire
conditions.
In the event of a spill, prevent material and fire water from entering sewers or waterways.
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
In the event of a spill, prevent material from entering sewers or waterways. Do not allow material to contaminate
ground water system. Prevent product from entering drains. If drains, streams, soil or sewers become
contaminated, notify local authority. This product may pose a risk to the aquatic ecosystem if released.
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SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or
by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated
recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal
Considerations).
HANDLING
Prevent contact with skin, eyes and clothing. Use with adequate ventilation. Do not breathe vapors/gases/dust.
Keep the containers closed when not in use. Do not mix with acids. Keep away from acids and oxidizing agents.
Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).
HYGIENE RECOMMENDATIONS
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a
safety shower available. Always wash thoroughly after handling chemicals. When handling this product never
eat, drink or smoke.
STORAGE CONDITIONS
Store in suitable labeled containers. Store the containers tightly closed. Store away from heat and sources of
ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be
grounded to avoid electrical charges. Store separately from oxidizers.
Specific use(s) :
FUEL OIL STABILIZER
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9-303
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.
Source Substance(s) Category: ppm mg/m3
* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and
the eyes.
MONITORING MEASURES
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed
as referenced below:
Substance(s) Method Analysis Absorbant
Naphthalene US NIOSH: 1501 Gas chromatography Charcoal
Ethylbenzene US NIOSH: 1501 Gas chromatography Charcoal
DNEL
Components:
ENGINEERING MEASURES:
General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions
near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of
confined spaces.
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9-303
GENERAL ADVICE
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and
the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields.
EYE/FACE PROTECTION
When handling this product, the use of a face shield is recommended. The applicable European standard can be
found in EN 166.
SKIN PROTECTION
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends
on work conditions and what chemicals are handled, but we have positive experience under light handling
conditions using gloves made from Nitrile Gloves should be replaced immediately if signs of degradation are
observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable
European standard can be found in EN 374.
When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The
applicable European standard can be found in EN ISO 20345.
RESPIRATORY PROTECTION
Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air
supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of
chemicals being handled. Consider the use of filter type: A-B-E-K-P The applicable European standard can be
found in EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown
concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required,
institute a complete respiratory protection program including selection, fit testing, training, maintenance and
inspection.
Note: These physical properties are typical values for this product and are subject to change.
9.1 Information on basic physical and chemical properties:
9.1 Information on basic physical and chemical properties:
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Not applicable
10.1 Reactivity:
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,
permanganate) may generate heat, fires, explosions and/or toxic vapors.
Product:
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9-303
Acute oral toxicity : LD50: 2,500 mg/kg, Rat, Test substance: Product
Acute inhalation toxicity : Based on available data, the classification criteria are not met.
Acute dermal toxicity : LD50: 5,600 mg/kg, Rabbit, Test substance:
Product
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/eye : Causes severe skin burns and eye damage.
irritation
Respiratory or skin : Based on available data, the classification criteria are not met.
sensitization
Genotoxicity
Assessment : Contains no ingredient listed as a mutagen
Carcinogenicity : Suspected of causing cancer.
Reproductive toxicity : Based on available data, the classification criteria are not met.
Assessment:
STOT - single exposure : Remarks: May cause drowsiness or dizziness.
STOT - repeated exposure : Based on available data, the classification criteria are not met.
Aspiration toxicity : No aspiration toxicity classification
Components:
1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline
Skin corrosion/irritation : Rabbit, Result: Corrosive, OECD 404, 4 h
Serious eye damage/eye : Rabbit, Result: Corrosive, EPA OPP 81-4, 1 h
irritation
Hydrocarbons, C10, aromatics, >1% naphthalene
Acute oral toxicity : LD50: ca. 6,318 mg/kg, Rat, OECD 401
Acute dermal toxicity : LD50: > 2,000 mg/kg, Rabbit, OECD 402
Skin corrosion/irritation : Rabbit, Result: Not irritating, OECD 404
Serious eye damage/eye : Rabbit, Result: Not irritating, OECD 405
irritation
Respiratory or skin : Guinea pig, Result: Negative, OECD 406, Read-across
sensitization (Analogy)
Genotoxicity
Genotoxicity in vitro : Ames test, Result: negative, OECD 471
: In vitro gene mutation study in mammalian cells, Result:
negative, OECD 476
: Chromosome aberration test in vitro, Result: negative, OECD
473
: In vitro Sister Chromatid Exchange Assay, Result: negative,
OECD 479
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9-303
12.1 Toxicity:
Product:
Toxicity to fish : LC50: 7.5 mg/l, 96 hrs, Turbot, Test substance: Product
: LC50: 1.17 mg/l, 96 hrs, Rainbow Trout, Test substance:
Product
: LC50: 1.09 mg/l, 96 hrs, Bluegill Sunfish, Test substance:
Product
Toxicity to daphnia and other : LC50: 6.2 mg/l, 48 hrs, Acartia tonsa, Test substance: Product
aquatic invertebrates.
: LC50: 1.5 mg/l, 48 hrs, Daphnia magna, Test substance:
Product
: LC50: 1.5 mg/l, 48 hrs, Daphnia magna, Test substance:
Product
: NOEC: < 1.3 mg/l, 48 hrs, Daphnia magna, Test substance:
Product
Toxicity to algae : EC50: 1.7 mg/l, 72 hrs, Marine Algae (Skeletonema
costatum), Test substance: Product
Ecotoxicology Assessment
Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects.
Product
9-303
Components:
Hydrocarbons, C10, aromatics, >1% naphthalene
Toxicity to fish : LL50: 2 - 5 mg/l, 96 h, Rainbow Trout, OECD 203
Toxicity to daphnia and other : EL50: 3 - 10 mg/l, 48 h, Daphnia magna, OECD 202
aquatic invertebrates.
Toxicity to algae : EL50: > 1 - < 3 mg/l, 72 h, Green Algae (Pseudokirchneriella
subcapitata, previously Selenastrum capricornutum), OECD
201
Toxicity to bacteria : NOELR: 1.892 mg/l, 48 h, Tetrahymena pyriformis, Calculated
Toxicity to fish (Chronic : NOELR: 0.487 mg/l, 28 d, Rainbow Trout, Calculated
toxicity)
Toxicity to daphnia and other : NOELR: 0.851 mg/l, 21 d, Daphnia magna, Calculated
aquatic invertebrates.
(Chronic toxicity)
Product:
Biodegradability : The organic portion of this preparation is expected to be
inherently biodegradable.
Components:
Hydrocarbons, C10, aromatics, >1% naphthalene
Biodegradability : 57.95 %, Result: Inherently biodegradable., Exposure time: 28
d, OECD 301 F (Manometric RespirometryI)
Product:
Bioaccumulation : Component substances have a potential to bioaccumulate.
Components:
Hydrocarbons, C10, aromatics, >1% naphthalene
Bioaccumulation : Potential bioaccumulation
Product:
Environmental fate and : The portion in water is expected to be soluble or dispersible.
pathways
Components:
Hydrocarbons, C10, aromatics, >1% naphthalene
Distribution among : study scientifically unjustified
environmental compartments
Product:
Assessment : This mixture contains no substance considered to be
Product
9-303
Product:
Additional ecological : No adverse effects expected.
information
If this preparation becomes a waste, the final user must define and assign the appropriate European Waste
Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.
Contact an approved waste hauler for disposal of contaminated recovered material. Any chemical waste is a
potential environmental pollutant and is NOT suitable for disposal via ground, municipal sewers, drains, natural
streams or rivers. Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance
with all applicable regulations. Do not dispose of wastes in local sewer or with normal garbage.
Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.
The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT
14.1 UN number: UN 2735
14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S.
(1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline)
14.3 Transport hazard class(es): 8
14.4 Packing group: III
14.5 Environmental hazards: Yes
14.6 Special precautions for user: not applicable
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
EUROPE
Safety Data Sheet according to Regulation (EC) No 1907/2006.
Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals
(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into
European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.
Should you require any further information on Nalco's REACH programme please contact us at
reach@nalco.com or visit our website.
CANADA
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).
UNITED STATES
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
LIST OF RELEVANT R-PHRASES, NOTAS AND HAZARD STATEMENTS IN SECTION 2.1 AND 3
H302 - Harmful if swallowed.
H304 - May be fatal if swallowed and enters airways.
H314 - Causes severe skin burns and eye damage.
H318 - Causes serious eye damage.
H319 - Causes serious eye irritation.
H336 - May cause drowsiness or dizziness.
H351 - Suspected of causing cancer.
Product
9-303
This product Safety Data Sheet provides health, safety, and regulatory information. The information contained in
this Safety Data Sheet is based on data available to us at the date of issue , and is provided in good faith, and
believed to be accurate and reliable at the date of issue, however, no warranty, express or implied is provided,
and Nalco disclaims all liability for reliance on such information. The product is to be used in applications
consistent with Nalco’s product literature. For any other uses, exposures should be evaluated so that the
appropriate handling practices and training programs can be established to ensure safe working conditions and
operations. It is the buyer’s/user’s responsibility to satisfy itself that the product is suitable for the intended use,
and to ensure that its activities comply with all federal, state, provincial, or local laws and regulations.
Regulatory requirements are subject to change and may differ between European Member States and Nations.
Individuals handling this product should be informed of the recommended safety precautions and should have
access to this information. Please consult your local sales representative for any further information.
REFERENCES
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health
Organization, International Agency for Research on Cancer.
Ariel Insight™ (An integrated guide to industrial chemicals covered under major regulatory and advisory
programs), North American Module, Western European Module, Chemical Inventories Module and the Generics
Module (Ariel Insight™ CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The possible key literature references and data sources which may have been used in conjunction with the
consideration of expert judgment to compile this Safety Data Sheet: European regulations/directives (including
(EC) No. 1907/2006, (EC) No. 1272/2008, 67/548/EEC, 1999/45/EC), supplier data, inter-net, ESIS, IUCLID,
ERIcards, Non European official regulatory data and other data sources.
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Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth