Major Test - 2 (JEE) Solution
Major Test - 2 (JEE) Solution
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                                                                                                          Solutions to Major Test - 2 (JEE)
12.   The rules for the nomenclature of Elements of Atomic                                       ⇒ The molecular mass of gas = 8 × 2 = 16
      Numbers greater than 100:                                                                  ⇒ Option (B) is CORRECT.
      (1) The name is derived directly from the atomic                                   19.     Ground state energy of the electron in H-atom = –13.6
      number of the element using the following numerical                                        eV
      roots:                                                                                     ⇒ Ionization energy of H-atom = 13.6 eV
      0 = nil
      1 = un                                                                             20.     Bohr's theory accounts for the stability and spectrum of
      2 = bi                                                                                     single–electron species like H, He+, Li2+ etc.
      3 = tri                                                                                    It doesn't explain the spectrum and stability of the
      4 = quad                                                                                   multielectron system.
      5 = pent
                                                                                                 Li+ has 2 electrons.
      6 = hex
      7 = sept                                                                                   ⇒ Bohr's theory does not account for the stability and
      8 = oct                                                                                    line spectrum of Li+ ion
      9 = enn                                                                                    ⇒ Statement-I is false.
      (2) The roots are put together in the order of the digits
                                                                                                 One of the shortcomings of Bohr's model is that it is
      which make up the atomic number and terminated by
                                                                                                 unable to explain the splitting of spectral lines in the
      'ium' to spell out the name. The final 'n' of 'enn' is elided
                                                                                                 presence of a magnetic field.
      when it occurs before 'nil', and the final 'i' of 'bi' and of
      'tri' when it occurs before 'ium'.                                                         ⇒ Statement II is true.
       1 0 9
      un         enn+ium                                                                         ⇒ Option (B) is CORRECT.
           nil
      Hence the atomic number of the element unnilennium is
                                                                                         21.     – (wave no.) = 1 =        1
      109.                                                                                       v                                  = 17241
                                                                                                                 λ  5800 × 10 −8 cm
13.   NH4NO3                                                                                     1724.1 × 10 cm −1
                                                                                                 ⇒ x = 1724
      The nitrogen in the ammonium ion (NH4+) has an
      oxidation number of -3, while the nitrogen in the nitrate                          22.     Given Solution:
      ion (NO3–) has an oxidation number of +5                                                   5% by weight of a NaCl solution.
                                                                                                 ⇒ 5 g NaCl is present in 100 g of solution.
14.   Alkali metals (group 1) = ns1                                                              ⇒ 0.3 g NaCl is present in
                                                                                                                            100
                                                                                                                                × 0.3 g of solution.
      Alkaline earth metals (group 2) = ns2
                                                                                                                             5
                                                                                                 ⇒ Mass of solution,m solution = 6 g
      Halogens (group 17) = ns2np5                                                               ⇒ Answer = 6
      Noble gases (group 18) = ns2np6
                                                                                         23.     By absorbing energy the electron in a sample of Li2+
15.                         mass(g)                                                              ions goes from the 1st Bohr orbit to the 3rd Bohr orbit.
                                                                                                 ⇒ The electron will make the transition from the 3rd
      Number of Moles =
                        gram atomic mass
                    46                                                                           orbit ( n = 3)
                                                                                                 We know, if an electron is in any higher state n = n and
      Moles of Na =    = 2.
                    23
                                                                                                 makes a transition to the ground state, then maximum
16.   No. of Protons = 16
                                                                                                 no. of different photons emitted =
                                                                                                                                      n(n − 1)
      No. of Neutrons = 32 –16 = 16                                                                                                      2
      No. of electrons = 16 + 2 = 18                                                             ⇒The total number of spectral lines are observed in the
                                                                                                 emission spectrum =
                                                                                                                        3(3 − 1)
17.   Law of Multiple proportions states that : When two                                                                          =3
      elements combine to form more than one compound,
                                                                                                                           2
                                                                                                 These transitions are: 3 → 2, 2 → 1, 3 → 1
      then the mass of one element which combines with a
                                                                                                 ⇒ Answer = 3
      fixed mass of the other element in the various
      compounds bean a simple whole number ratio with one                                24.     In the combustion reaction of hydrocarbon, the
      another.                                                                                   products are CO2 and H2O
      Given that the ratio of masses of Oxygen which                                             The balanced reaction of combustion of butane (C4H10)
      combines with a fixed mass of Hydrogen (2 g) in the
                                                                                                 is written below:
      two compounds is in the ratio 1:2.
      Thus, it is in accordance with the Law of Multiple
      Proportions.
18.   We know, the vapour density of a gas is defined as,
                                                                                                 The molar mass of butane = 58 g mol–1
      Vapour density =                                                                           The molar mass of water = 18 g mol–1
                       Molecular mass of gas
                       Molecular mass of H 2
                                                                                                 In the balanced reaction, we can see,
      ⇒ The molecular mass of gas = Vapour density ×
                                                                                                 10 moles of water is obtained from the combustion of 2
      Molecular mass of H2
                                                                                                 moles of butane.
                                                                                                 ⇒ 10 × 18 g of water is obtained from the combustion of
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                                                                                                                    Solutions to Major Test - 2 (JEE)
      2 × 58 g of butane.                                                                        31.     Given: n(A) = 10, n(B) = 15 & n(A ∪ B) = x
      ⇒ 72 g of water is obtained from the combustion of
                                                                                                         Now n(A ∪ B) = n(A) + n(B) − n(A ∩ B)
               × 72 g of butane.
       2 × 58
      10 × 18                                                                                            ⇒ x = 10 + 15 − n(A ∩ B)
      ⇒ Amount of butane utilized =
                                      2 × 58
                                             × 72 = 46.4 g                                               ⇒ x = 25 − n(A ∩ B)
                                                                                                         We know 0 ≤ n(A ∩ B) ≤ min{n(A), n(B)}
                                     10 × 18
      ⇒ Amount of butane utilized = 464 × 10–1
                                                                                                         i.e. 0 ≤ n(A ∩ B) ≤ 10
      ⇒ Answer = 464                                                                                     Thus,
25.   Number of electrons in single N atom = 7                                                           xmax = 25 − n(A ∩ B)∣∣                         & xmin = 25 − n(A ∩ B)∣∣          = 15
                                                                                                                                                min                                 max
      ⇒ Number of electrons in single N3– ion = (7 + 3) = 10                                             ∴ xmax = 25 − 0 = 25 & xmin = 25 − 10 = 15
      ⇒ Number of moles of electrons in 1 mole of N3– ion =                                              ∴ 15 ≤ x ≤ 25
      10 moles
      ⇒ Number of moles electrons in 0.5 mole of N3– ion
      = 0.5 x 10 moles = 5 moles
                                                                                                 32.           1       1
      ⇒ Answer = 5                                                                                       cos θ =
                                                                                                               2
                                                                                                                 (x + )
                                                                                                                       x
26.   Let y = 27 cos 2x 81 sin 2x = 3 3 cos 2x+4 sin 2x                                                  x+
                                                                                                            1
                                                                                                              ≥ 0 or x +
                                                                                                                         1
                                                                                                                           ≤ −2 ⇒ cos θ ≥ 1 or cos θ ≤ −1
      Now −√3 2 + 4 2 ≤ 3 cos 2x + 4 sin 2x ≤ √3 2 + 4 2
                                                                                                            x            x
                                                                                                         ⇒ cos θ = x = ±1 ⇒ x 2 = 1 and sin θ = 0 ⇒
      or −5 ≤ 3 cos 2x + 4 sin 2x ≤ 5                                                                    1         1
      ∴ 3 −5 ≤ 3 3 cos 2x+4 sin 2x ≤ 3 5                                                                   (x 2 + 2 ) = 1
                                                                                                         2        x
27.   We have, sin 6 θ + cos 6 θ + k cos 2 2θ = 1                                                        cos θ = 1 − 2 sin 2 θ = 1 = sec 2θ
      ⇒ (sin2 θ + cos2 θ)(sin4 θ − sin2 θ ⋅ cos2 θ + cos4 θ) + k cos2 2θ = 1                             sin 2θ = tan 2θ = 0
      ⇒ sin 4 θ + cos 4 θ − sin 2 θ ⋅ cos 2 θ + k cos 2 2θ = 1
      ⇒ (sin 2 θ + cos 2 θ) 2 − 3 sin 2 θ ⋅ cos 2 θ + k cos 2 2θ = 1                             33.     Let A denote the set of Americans who like cheese and
                                                                                                         let B denote the set of Americans who like apples.
      ⇒ 3 sin 2 θ ⋅ cos 2 θ = k cos 2 2θ                                                                 Let total Population of America be100.
      ⇒ sin 2 2θ = k cos 2 2θ
        3                                                                                                Then n(A) = 63, n(B) = 76
        4                                                                                                Now, n(A ∪ B) = n(A) + n(B) − n(A ∩ B)
      ⇒ k = tan 2 2θ
              3                                                                                          = 63 − 76 − n(A ∩ B)
              4                                                                                          ⇒ n(A ∩ B) = 139 − n(A ∪ B)
28.   tan 15 ∘ + tan 15 ∘ − tan 15 ∘ + tan 15 ∘                                                          But n(A ∪ B) ≤ 100
                                                                                                         ⇒ n(A ∩ B)min = 139 − n(A ∪ B)max
                                                                                                         ⇒ n(A ∩ B)
      = 2 tan 15 ∘
      = 2(2 − √3) = 2a ⇒ a = 2 − √3                                                                                         min     = 139 − 100 = 39
           + a ⇒ (2 + √3) + (2 − √3) = 4
         1                                                                                               ∴ n(A ∩ B) ≥ 39 . . . (1)
      ∴
         a                                                                                               Again, A ∩ B ⊆ A, A ∩ B ⊆ B
29.   3A = 2A + A                                                                                        n(A ∩ B) max = min{n(A), n(B)} = 63
      ⇒ tan 3A = tan(2A + A)                                                                             ∴ n(A ∩ B) ≤ 63 . . . (2)
                                                                                                         = (a 2 − a − 2 )(a 2 + a − 2 )
               3π        2π         π                                                                         1        1    1       1
      = 2 sin     (cos      + cos     )
                                                                                                         = (a 2 − a − 2 )
               18        18        18                                                                         2        2
             π         π
                                                                                                         = (a − a −1 )
      = cos + cos
             9         18
              π     π            π     π
      = sin ( − ) + sin ( −              )
              2     9            2    18
            7π          8π
      = sin      + sin
             18         18
            7π          4π
      = sin      + sin
             18          9
                                                                                                 35.     Using A. M. ≥ G. M.
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                                                                                                                                       Solutions to Major Test - 2 (JEE)
                                                                                                           By sine rule
      ⇒
          1
            (3 tan 2 θ + 12 cot 2 θ) ≥ 6
                                                                                                           We know that
          2                                                                                                                    sin A     sin B   sin C
                                                                                                                                      =        =       = k(let)
      ⇒ 3 tan θ + 12 cot θ has minimum value 12.
                2               2                                                                                                a         b       c
                                                                                                           ⇒ sin A = ak, sin B = bk, sin C = ck,
36.       2π         4π        6π
                                                                                                           Put this in (iii), so we get
      cos     + cos      + cos
           7          7         7                                                                          2(ck) 2 = (ak) 2 + (bk) 2
                                                                                                           ⇒ 2c 2 = a 2 + b 2
                   π             2π   6π
         sin (3 × )           ⎛     +    ⎞
                                                                                                           ⇒ b 2 , c 2 and a 2 are in A.P.
                   7              7    7
      =          π      × cos
             sin                    2
                              ⎝          ⎠
                                                                                                   39.
37.
      =
      =−
        2 sin (
          2
            sin
sin (
− sin
         2 sin
          1
               7π
      Given that
                7
                 7
                 3π
                 π
                 7
7π
                π
                7
                 7
                  7
                     )
                        × cos (
) + sin (
                   2 sin
                         π
                         7
                              −π
                               7
      A ∪ B = A ∩ B . . . . . (i)
      Let x ∈ A
      ⇒x ∈ A ∪ B . . . . . (ii)
      [as A ⊆ (A ∪ B)]
      Also,
                                 4π
                                  7
                                   )
                                    ⎜⎟
                                    )
40.
41.
                                                                                                   42.
                                                                                                           8 sin
                                                                                                                π
                                                                                                                 5π
                                                                                                           2 sin (
                                                                                                                 12
                                                                                                           = cos (
                                                                                                                  5π
                                                                                                                  12
                                                                                                                   8
                                                                                                                     ) sin
                                                                                                                     −
                                                                                                                       π
                                                                                                                       12
                                                                                                           = cos − cos =
                                                                                                                3
                                                                                                                        π
                                                                                                                        2
                                                                                                                       cos
                                                                                                                           π
                                                                                                                           12
                                                                                                           Use the formula 2 sin A sin B = cos(A − B) − cos(A + B)
) − cos (
                                                                                                                             1
                                                                                                                             2
                                                                                                                             2
                                                                                                                                 cos
                                                                                                                                    5π
                                                                                                                                    12
                                                                                                                                       +
                                                                                                                                       4
                                                                                                                                         π
                                                                                                                                         12
                                                                                                                                            )
                                                                                                           So,
                                                                                                                   x         x         x
                                                                                                                                           cos
                                                                                                                                                 x
                                                                                                                                                 8
                                                                                                                                                   x
                                                                                                                                                   2
                                                                                                                                                     = 8 sin
                                                                                                                                                               x
                                                                                                                                                               8
                                                                                                                                                                   cos
                                                                                                                                                                         x
                                                                                                                                                                         8
                                                                                                                                                                             cos
                                                                                                                                                                                   x
                                                                                                                                                                                   4
                                                                                                                                                                                       cos
                                                                                                                                                                                             x
                                                                                                                                                                                             2
                                                                                                                                                                                                 = 4 (2 sin
                                                                                                                                                                                                              x
                                                                                                                                                                                                              8
                                                                                                                                                                                                                  cos
                                                                                                                                                                                                                        x
                                                                                                                                                                                                                        8
                                                                                                                                                                                                                            ) cos
                                                                                                                                                                                                                                    x
                                                                                                                                                                                                                                    4
                                                                                                                                                                                                                                        cos
                                                                                                                                                                                                                                              x
                                                                                                                                                                                                                                              2
                                                                                                                                                                                                                                                  = 4 sin
                                                                                                                                                                                                                                                            x
                                                                                                                                                                                                                                                            4
                                                                                                                                                                                                                                                                cos
                                                                                                                                                                                                                                                                      x
                                                                                                                                                                                                                                                                      4
                                                                                                                                                                                                                                                                          cos
                                                                                                                                                                                                                                                                                x
                                                                                                                                                                                                                                                                                2
                                                                                                                                                                                                                                                                                    = 2 (2 sin
                                                                                                                                                                                                                                                                                                 x
                                                                                                                                                                                                                                                                                                 4
                                                                                                                                                                                                                                                                                                     cos
                                                                                                                                                                                                                                                                                                           x
                                                                                                                                                                                                                                                                                                           4
                                                                                                                                                                                                                                                                                                               ) cos
                                                                                                                                                                                                                                                                                                                       x
                                                                                                                                                                                                                                                                                                                       2
                                                                                                                                                                                                                                                                                                                           = 2 sin
                                                                                                                                                                                                                                                                                                                                     x
                                                                                                                                                                                                                                                                                                                                     2
                                                                                                                                                                                                                                                                                                                                         cos
                                                                                                                                                                                                                                                                                                                                               x
                                                                                                                                                                                                                                                                                                                                               2
                                                                                                                                                                                                                                                                                                                                                   = sin x
      ⇒x ∈ A ∩ B . . . . . (iii)
                                                                                                            α−d       180   60
                                                                                                                  ×       =
      [as from equation (i)(A ∪ B) = (A ∩ B)]                                                               α+d        π     π
      Now from the equation (iii), we can see that x is an
                                                                                                           (60 − d) × 3 = 60 + d
      element of both sets A & set B                                                                       ⇒ d = 30 ∘
      ⇒x ∈ A ⇒ x ∈ B ⇒A ⊆ B . . . . . (iv)                                                                 Hence the angles are 30 ∘ , 60 ∘ , 90 ∘
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                                                                                                                                                       Solutions to Major Test - 2 (JEE)
45. LHS = (1 + tan 1 ∘ )(1 + tan 44 ∘ )(1 + tan 2 ∘ )(1 + tan 43 ∘ ). . . . (1 + tan 45 ∘ ) 53.
      As if A + B = , then
                   π
                   4
                                                                        π    tan A + tan B
      (1 + tan A)(1 + tan B) = 2 {tan                                     =                   }
                                                                        4   1 − tan A ⋅ tan B
      ⇒ (1 + tan 1   ∘
                         + tan 44 ∘ + tan 1 ∘ tan 44 ∘ ) + (1 + tan 2 ∘ + tan 43 ∘ + tan 2 ∘ + tan 43 ∘ ). . . . (1 + tan 45 ∘ )
46.
      Given log 10 (                                                                                                                     Slope is tan θ, where θ is the angle made by the tangent
                   sin 2x
                          ) = −1
                      2                                                                                                                  to the curve with the positive x-axis.
        sin 2x    1              1
      ⇒        =     ⇒ sin 2x =
                                                                                                                                   54.   According to definition of definite integration,
           2     10              5
                                                                                 n                                                               t=b
                                                                  log 10 (          )
      Also log 10 (sin x + cos x) =                                              10                                                      ∫             f(t)dt = [F (t)] t=b
                                                                                                                                                                        t=a = F (b) − F (a)
                                         2                                                                                                   t=a
                                         n           2                                                                                       2                   2
      ⇒ log 10 (sin x + cos x) = log 10 ( )
                                         10                                                                                              ∫ 2t dt = 2 ∫ t dt = [t 2 ] 20 = 4
                         n
      ⇒ 1 + sin 2x =                                                                                                                     0                   0
                        10
              1      n      6   n                                                                                                  55.   ds     d 2
      ⇒1+ =             ⇒ =                                                                                                                 =     (t + 5t + 3)
              5      10     5   10                                                                                                       dt    dt
         n                                                                                                                               = 2t + 5
      ⇒     =4
                                                                                                                                   56.
         3                                                                                                                               →     → →         → →
      Here A and B sets having 2 elements in common, so
                                                                                                                                         R = (2Q + 2P) + (2Q − 2P)
47.                                                                                                                                           →
      A × B and B × A have 2 2 i.e., 4 elements in common.
                                                                                                                                         →
                                                                                                                                         R = 4Q
      Hence, n[(A × B) ∩ (B × A)] = 4
                                                                                                                                         The angle between Q and R is zero.
                                                                                                                                                           →    →
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                                                                                                            Solutions to Major Test - 2 (JEE)
                                                                                           69.    →
                                                                                                  v = v cos θˆi + v sin θˆj
                                                                                                  = 10 cos 60ˆi + 10 sin 60ˆj
                                                                                                          1             √3
                                                                                                  = 10 × ˆi + 10 ×          ˆj = 5ˆi + 5√3ˆj
                                                                                                          2               2
                                                                                           70.     Factual. The magnitude of distance is always greater
                                                                                                   than the magnitude of displacement.
                                                                                           71.     If a vector makes angles
                                                                                                                             π π
                                                                                                                               ,   and
                                                                                                                                        π
                                                                                                                                            with theX-axis,
                                                                                                                             3 3        n
                                                                                                   the Y-axis and the Z-axis respectively, then we have to
                                                                                                   find the value of n.
                                                                                           72.
                                                                                                  Given that a force F = 20ˆi + 10ˆj is being applied on a
                                                                                                                       →
                                                                                                  2kg body at rest.
                                                                                                  On applying the newtons second law on the body we get
                                                                                                                          →
                                                                                                                              20ˆi + 10ˆj
                                                                                                  acceleration as, a =
                                                                                                                   → F
                                                                                                                            =
                                                                                                                          m        2
                                                                                                  ⇒ a = 10ˆi + 5ˆj
                                                                                                    →
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                                                                       Solutions to Major Test - 2 (JEE)
75.
                                                             →         A ˆ         A ˆ
                                                             R = (A +    )i + (A −    )j
                                                                      √2           √2
                                                                              2           2
                                                              →          A             A
                                                             |R| = √(A +    ) + (A −     ) = √3A
                                                                         √2           √2
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