SAFETY DATA SHEET

3D TRASAR™ 3DT105

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : 3D TRASAR™ 3DT105

Other means of identification : Not applicable.

Recommended use : CORROSION INHIBITOR

Restrictions on use : Refer to available product literature or ask your local Sales Representative for
restrictions on use and dose limits.

Company : Nalco Middle East FZE

JAFZA One, Tower A, 11th Floor, Office 1101 & 1107.
Jebel Ali Free Zone, Dubai
UAE
TEL: 00971 4 8014100

Nalco Saudi Company Limited

First Industrial City, Dammam – 11th Street, P.O. Box 7372
Dammam 31462
Saudi Arabia
TEL: 00966 13 824 9100

Nalco Egypt Ltd

5th Settlement, South 90th St.
New Cairo, Cairo, Egypt 11835TEL: 0020 2 25 37 1195

Emergency telephone : +32-(0)3-575-5555

number

Issuing date : 11/06/2021

Section: 2. HAZARDS IDENTIFICATION

GHS Classification
Corrosive to metals : Category 1
Acute toxicity (Oral) : Category 4
Skin irritation : Category 2
Eye irritation : Category 2A

GHS Label element

Hazard pictograms :

Signal Word : Warning

Hazard Statements : May be corrosive to metals.

Harmful if swallowed.
Causes skin irritation.
Causes serious eye irritation.

Precautionary Statements : Prevention:

Keep only in original container. Do not eat, drink or smoke when using this
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product. Wear protective gloves/ eye protection/ face protection.

Response:
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel
unwell. Rinse mouth. IF ON SKIN: Wash with plenty of soap and water. IF IN
EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
Storage:
Store in corrosive resistant container with a resistant inner liner.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Other hazards : Do not mix with bleach or other chlorinated products – will cause chlorine gas.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical Name CAS-No. Concentration: (%)

Zinc Dihydrogen Phosphate 13598-37-3 30 - 60
Phosphoric Acid 7664-38-2 10 - 30

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention immediately.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Wash clothing
before reuse. Thoroughly clean shoes before reuse. Get medical attention
immediately.

If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by
mouth to an unconscious person. Get medical attention immediately.

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention immediately.

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put
yourself at risk of injury. If in doubt, contact emergency responders. Use
personal protective equipment as required.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and symptoms.
and effects, both acute and
delayed

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.

Unsuitable extinguishing : None known.

media

Specific hazards during : Not flammable or combustible.

firefighting

Hazardous combustion : Not applicable.

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products

Special protective equipment : Use personal protective equipment.

for firefighters

Specific extinguishing : Fire residues and contaminated fire extinguishing water must be disposed of in
methods accordance with local regulations. In the event of fire and/or explosion do not
breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Ensure adequate ventilation. Keep people away from and upwind of spill/leak.
protective equipment and Avoid inhalation, ingestion and contact with skin and eyes. When workers are
emergency procedures facing concentrations above the exposure limit they must use appropriate
certified respirators. Ensure clean-up is conducted by trained personnel only.
Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non-
containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to local / national
regulations (see section 13). For large spills, dike spilled material or otherwise
contain material to ensure runoff does not reach a waterway. Flush away traces
with water.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Avoid contact with skin and eyes. Do not ingest. Do not breathe
dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing.
Wash hands thoroughly after handling. Use only with adequate ventilation. Do
not mix with bleach or other chlorinated products – will cause chlorine gas.

Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable
labelled containers.

Keep only in original packaging. Absorb spillage to prevent material damage.

Suitable material : Keep in properly labelled containers.Plastic material

Unsuitable material : The following compatibility data is suggested based on similar product data
and/or industry experience: Product is corrosive to aluminum. Aluminum should
not be used for feed, storage, or transportation systems.

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.
Components CAS-No. Form of exposure Permissible Basis
concentration
Phosphoric Acid 7664-38-2 TWA 1 mg/m3 ACGIH
STEL 3 mg/m3 ACGIH
TWA 1 mg/m3 NIOSH REL
STEL 3 mg/m3 NIOSH REL
TWA 1 mg/m3 OSHA Z1
Phosphoric Acid 7664-38-2 TWA 1 mg/m3 ARE OEL

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STEL 3 mg/m3 ARE OEL

Phosphoric Acid 7664-38-2 TWA 1 mg/m3 BH OEL
STEL 3 mg/m3 BH OEL

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards.

Personal protective equipment

Eye protection : Safety goggles

Face-shield

Hand protection : Recommended preventive skin protection

Gloves
Nitrile rubber
butyl-rubber
Breakthrough time: 1 – 4 hours
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.
Consult PPE manufacturer for the appropriate glove thickness (depending on
the type of gloves and its intended use).

Skin protection : Personal protective equipment comprising: suitable protective gloves, safety
goggles and protective clothing

Respiratory protection : When respiratory risks cannot be avoided or sufficiently limited by technical
means of collective protection or by measures, methods or procedures of work
organization, consider the use of certified respiratory protection equipment
meeting EU requirements (89/656/EEC, (EU) 2016/425), or equivalent, with filter
type:
Particulates type

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove
and wash contaminated clothing before re-use. Wash face, hands and any
exposed skin thoroughly after handling. Provide suitable facilities for quick
drenching or flushing of the eyes and body in case of contact or splash hazard.

The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith
based on typical expected conditions of use. PPE selection should always be completed in conjunction with a
proper risk assessment and in accordance with a PPE management program.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid
Colour : clear
Odour : no data available
Flash point : > 93.3 °C, does not flash
pH : 1.60 - 2.80,(1 %), (as aqueous solution)
Odour Threshold : no data available
Melting point/freezing point : no data available
Initial boiling point and boiling : no data available
range
Evaporation rate : no data available
Flammability (solid, gas) : Not applicable.

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Upper explosion limit : no data available

Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : 1.58 - 1.68,
Density : no data available
Water solubility : completely soluble
Solubility in other solvents : no data available
Partition coefficient: n- : no data available
octanol/water
Auto-ignition temperature : no data available
Thermal decomposition : no data available
Viscosity, dynamic : no data available
Viscosity, kinematic : no data available
Molecular weight : no data available
VOC : no data available

Section: 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous : Do not mix with bleach or other chlorinated products – will cause chlorine gas.
reactions

Conditions to avoid : Extremes of temperature

Incompatible materials : Aluminium

Mild steel

Hazardous decomposition : Not applicable.

products

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

Potential Health Effects

Eyes : Causes serious eye irritation.

Skin : Causes skin irritation.

Ingestion : Harmful if swallowed. Causes digestive tract burns.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Health injuries are not known or expected under normal use.

Experience with human exposure

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Eye contact : Redness, Pain, Corrosion, Irritation

Skin contact : Redness, Pain, Irritation, Corrosion

Ingestion : Corrosion, Abdominal pain

Inhalation : Respiratory irritation, Cough

Toxicity

Product
Acute oral toxicity : Acute toxicity estimate: 1,064 mg/kg
Acute inhalation toxicity : no data available
Acute dermal toxicity : no data available
Skin corrosion/irritation : no data available
Serious eye damage/eye : no data available
irritation
Respiratory or skin : no data available
sensitization
Carcinogenicity : no data available
Reproductive effects : no data available
Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : no data available
Components
Acute inhalation toxicity : Phosphoric Acid
LC50 rat: 0.962 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Components
Acute dermal toxicity : Phosphoric Acid
LD50 rabbit: > 2,000 mg/kg

Section: 12. ECOLOGICAL INFORMATION

Toxicity

Environmental Effects : Very toxic to aquatic life.

Components
Toxicity to daphnia and other : Phosphoric Acid
aquatic invertebrates EC50 Daphnia magna (Water flea): > 100 mg/l
Exposure time: 48 h

Components
Toxicity to algae : Phosphoric Acid

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EC50 Desmodesmus subspicatus (green algae): > 100 mg/l

Exposure time: 72 h

Persistence and degradability

Greater than 95% of this product consists of inorganic substances for which a biodegradation value is not
applicable.

Mobility

The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total
input and output. The level III model does not require equilibrium between the defined media. The information
provided is intended to give the user a general estimate of the environmental fate of this product under the
defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;

Air : <5%
Water : 30 - 50%
Soil : 50 - 70%

The portion in water is expected to be soluble or dispersible.

Bioaccumulative potential

This preparation or material is not expected to bioaccumulate.

Other information

no data available

Section: 13. DISPOSAL CONSIDERATIONS

Disposal methods : Do not contaminate storm water drains, natural waterways or

soil with chemical or used container. Where possible recycling
is preferred to disposal or incineration. If recycling is not
practicable, dispose of in compliance with local regulations.
Dispose of wastes in an approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be

taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in
compliance with the selected mode of transport.

Land transport (ADR)

UN number: UN 1805
UN proper shipping name: PHOSPHORIC ACID SOLUTION
Transport hazard class(es): 8
Packing group: III
Environmental hazards: Yes

Air transport (IATA)

UN number: UN 1805
UN proper shipping name: PHOSPHORIC ACID SOLUTION

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Transport hazard class(es): 8

Packing group: III
Environmental hazards: Yes

Sea transport (IMDG/IMO)

UN number: UN 1805
UN proper shipping name: PHOSPHORIC ACID SOLUTION
Transport hazard class(es): 8
Packing group: III
Environmental hazards: Yes (Marine Pollutant)
*Marine pollutant: Zinc Dihydrogen Phosphate

Section: 15. REGULATORY INFORMATION

NATIONAL REGULATIONS
National regulations in the country where this substance is used, should be followed.

Section: 16. OTHER INFORMATION

NFPA: HMIS III:

Flammability

HEALTH 2
0
Instability
Health

2 0 FLAMMABILITY 0
PHYSICAL HAZARD 0
0 = not significant, 1 = Slight,
2 = Moderate, 3 = High,
Special hazard. 4 = Extreme, * = Chronic

Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and
exposures of this product. Based on our recommended use of this product, we have characterized the product's
general risk. This information should provide assistance for your own risk management practices. We have
evaluated our product's risk as follows:
* The human risk is: Low

* The environmental risk is: Low

Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative
will assist you to determine if your product application is consistent with our recommendations. Together we can
implement an appropriate risk management process.

Revision Date : 11/06/2021

Version Number : 1.2
Prepared By : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated
by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid for
such material used in combination with any other materials or in any process, unless specified in the text.

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