SAFETY DATA SHEET
3D TRASAR 3DT184
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : 3D TRASAR 3DT184
Other means of identification : Not applicable.
Recommended use : CORROSION INHIBITOR
Restrictions on use : Refer to available product literature or ask your local Sales Representative for
restrictions on use and dose limits.
Company : Nalco Champion Company
7705 Highway 90-A
Sugar Land, Texas 77478
USA
TEL: (281) 263-7000
Emergency telephone : (800) 424-9300 (24 Hours) CHEMTREC
number
Issuing date : 02/04/2016
Section: 2. HAZARDS IDENTIFICATION
GHS Classification
Acute toxicity (Inhalation) : Category 4
Skin corrosion : Category 1B
Serious eye damage : Category 1
GHS Label element
Hazard pictograms :
Signal Word : Danger
Hazard Statements : Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if inhaled.
Precautionary Statements : Prevention:
Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly
after handling. Use only outdoors or in a well-ventilated area. Wear protective
gloves/ protective clothing/ eye protection/ face protection.
Response:
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a
POISON CENTER or doctor/ physician. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/shower. IF
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SAFETY DATA SHEET
3D TRASAR 3DT184
INHALED: Remove person to fresh air and keep comfortable for breathing.
Immediately call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Wash contaminated clothing before reuse.
Storage:
Store locked up.
Other hazards : Do not mix with bleach or other chlorinated products will cause chlorine gas.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Pure substance/mixture : Mixture
Chemical Name CAS-No. Concentration: (%)
Phosphoric Acid 7664-38-2 30 - 60
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention immediately.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild
soap if available. Wash clothing before reuse. Thoroughly clean shoes before
reuse. Get medical attention immediately.
If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by
mouth to an unconscious person. Get medical attention immediately.
If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put
yourself at risk of injury. If in doubt, contact emergency responders. Use
personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms : See Section 11 for more detailed information on health effects and symptoms.
and effects, both acute and
delayed
Section: 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable extinguishing : None known.
media
Specific hazards during : Not flammable or combustible.
firefighting
Hazardous combustion : Decomposition products may include the following materials: Oxides of
products phosphorus
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SAFETY DATA SHEET
3D TRASAR 3DT184
Special protective equipment : Use personal protective equipment.
for firefighters
Specific extinguishing : Fire residues and contaminated fire extinguishing water must be disposed of in
methods accordance with local regulations. In the event of fire and/or explosion do not
breathe fumes.
Section: 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Ensure adequate ventilation. Keep people away from and upwind of spill/leak.
protective equipment and Avoid inhalation, ingestion and contact with skin and eyes. When workers are
emergency procedures facing concentrations above the exposure limit they must use appropriate
certified respirators. Ensure clean-up is conducted by trained personnel only.
Refer to protective measures listed in sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non-
containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to local / national
regulations (see section 13). For large spills, dike spilled material or otherwise
contain material to ensure runoff does not reach a waterway. Flush away traces
with water.
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in
eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only
with adequate ventilation. Do not mix with bleach or other chlorinated products
will cause chlorine gas.
Conditions for safe storage : Keep away from strong bases. Keep out of reach of children. Keep container
tightly closed. Store in suitable labeled containers.
Suitable material : The following compatibility data is suggested based on similar product data
and/or industry experience: Compatibility with Plastic Materials can vary; we
therefore recommend that compatibility is tested prior to use.
Unsuitable material : The following compatibility data is suggested based on similar product data
and/or industry experience: Stainless Steel 304
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Form of exposure Permissible Basis
concentration
Phosphoric Acid 7664-38-2 TWA 1 mg/m3 ACGIH
STEL 3 mg/m3 ACGIH
TWA 1 mg/m3 NIOSH REL
STEL 3 mg/m3 NIOSH REL
TWA 1 mg/m3 OSHA Z1
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SAFETY DATA SHEET
3D TRASAR 3DT184
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards.
Personal protective equipment
Eye protection : Safety goggles
Face-shield
Hand protection : Wear protective gloves.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.
Skin protection : Personal protective equipment comprising: suitable protective gloves, safety
goggles and protective clothing
Respiratory protection : When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove
and wash contaminated clothing before re-use. Wash face, hands and any
exposed skin thoroughly after handling. Provide suitable facilities for quick
drenching or flushing of the eyes and body in case of contact or splash hazard.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid
Colour : brown
Odour : odourless
Flash point : > 93.3 C
pH : 1.0, 100 %
Odour Threshold : no data available
Melting point/freezing point : FREEZING POINT: -22.5 C
Initial boiling point and boiling : 100 C
range
Evaporation rate : no data available
Flammability (solid, gas) : no data available
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : 56 mm Hg (38 C)
Relative vapour density : no data available
Relative density : 1.24 (15.6 C)
Density : 1.24 g/cm3
10.4 lb/gal
Water solubility : completely soluble
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SAFETY DATA SHEET
3D TRASAR 3DT184
Solubility in other solvents : no data available
Partition coefficient: n- : no data available
octanol/water
Auto-ignition temperature : no data available
Thermal decomposition : no data available
temperature
Viscosity, dynamic : 3 mPa.s (25 C)
Viscosity, kinematic : no data available
Molecular weight : no data available
VOC : 0 % Calculation method
Section: 10. STABILITY AND REACTIVITY
Chemical stability : Stable under normal conditions.
Possibility of hazardous : Do not mix with bleach or other chlorinated products will cause chlorine gas.
reactions
Conditions to avoid : None known.
Incompatible materials : Bases
Hazardous decomposition : Decomposition products may include the following materials:
products Oxides of phosphorus
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of : Inhalation, Eye contact, Skin contact
exposure
Potential Health Effects
Eyes : Causes serious eye damage.
Skin : Causes severe skin burns.
Ingestion : Causes digestive tract burns.
Inhalation : Harmful if inhaled. May cause nose, throat, and lung irritation.
Chronic Exposure : Health injuries are not known or expected under normal use.
Experience with human exposure
Eye contact : Redness, Pain, Corrosion
Skin contact : Redness, Pain, Corrosion
Ingestion : Corrosion, Abdominal pain
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SAFETY DATA SHEET
3D TRASAR 3DT184
Inhalation : Respiratory irritation, Cough
Toxicity
Product
Acute oral toxicity : no data available
Acute inhalation toxicity : Acute toxicity estimate : 2.61 mg/l
Exposure time: 4 h
Acute dermal toxicity : no data available
Skin corrosion/irritation : no data available
Serious eye damage/eye : no data available
irritation
Respiratory or skin : no data available
sensitization
Carcinogenicity : no data available
Reproductive effects : no data available
Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : no data available
Components
Acute oral toxicity : Phosphoric Acid
LD50 rat: > 2,600 mg/kg
Components
Acute dermal toxicity : Phosphoric Acid
LD50 rabbit: > 2,000 mg/kg
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity
Environmental Effects : This product has no known ecotoxicological effects.
Product
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SAFETY DATA SHEET
3D TRASAR 3DT184
Toxicity to fish : LC50 Pimephales promelas (fathead minnow): 3,660 mg/l
Exposure time: 96 hrs
Test substance: Similar Product
LC50 Inland Silverside: > 5,000 mg/l
Exposure time: 96 hrs
Test substance: Product
LC50 Oncorhynchus mykiss (rainbow trout): > 5,000 mg/l
Exposure time: 96 hrs
Test substance: Product
NOEC Inland Silverside: 5,000 mg/l
Exposure time: 96 hrs
Test substance: Product
NOEC Oncorhynchus mykiss (rainbow trout): 5,000 mg/l
Exposure time: 96 hrs
Test substance: Product
Toxicity to daphnia and other : LC50 Mysid Shrimp (Mysidopsis bahia): 2,237 mg/l
aquatic invertebrates Exposure time: 96 hrs
Test substance: Product
LC50 Daphnia magna (Water flea): 3,536 mg/l
Exposure time: 48 hrs
Test substance: Product
NOEC Mysid Shrimp (Mysidopsis bahia): 1,250 mg/l
Exposure time: 96 hrs
Test substance: Product
NOEC Daphnia magna (Water flea): 2,500 mg/l
Exposure time: 48 hrs
Test substance: Product
Toxicity to fish (Chronic : EC25 / IC25: 1,972 mg/l
toxicity) Exposure time: 7 Days
Species: Fathead Minnow
Test substance: Similar Product
NOEC: 1,250 mg/l
Exposure time: 7 Days
Species: Fathead Minnow
Test substance: Similar Product
Components
Toxicity to algae : Phosphoric Acid
EC50 Desmodesmus subspicatus (green algae): > 100 mg/l
Exposure time: 72 h
Persistence and degradability
The organic portion of this preparation is expected to be readily biodegradable.
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SAFETY DATA SHEET
3D TRASAR 3DT184
Total Organic Carbon (TOC) : 1,000 mg/l
Chemical Oxygen Demand (COD): 3,000 mg/l
Biochemical Oxygen Demand (BOD):
Incubation Period Value Test Descriptor
5d 2,460 mg/l Product
Mobility
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input
and output. The level III model does not require equilibrium between the defined media. The information provided is
intended to give the user a general estimate of the environmental fate of this product under the defined conditions of
the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;
Air : <5%
Water : 30 - 50%
Soil : 50 - 70%
The portion in water is expected to be soluble or dispersible.
Bioaccumulative potential
This preparation or material is not expected to bioaccumulate.
Other information
no data available
Section: 13. DISPOSAL CONSIDERATIONS
If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261. Before disposal, it should be determined if the waste meets
the criteria of a hazardous waste.
Hazardous Waste: : D002
Disposal methods : Where possible recycling is preferred to disposal or
incineration. If recycling is not practicable, dispose of in
compliance with local regulations. Dispose of wastes in an
approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be
taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance
with the selected mode of transport.
Land transport (DOT)
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SAFETY DATA SHEET
3D TRASAR 3DT184
The presence of an RQ component (Reportable Quantity for U.S. DOT) in this product causes it to be regulated with
an additional description of RQ for road, or as Environmentally hazardous for road and air, ONLY when the net
weight in the package exceeds the calculated RQ for the product.
Proper shipping name : PHOSPHORIC ACID SOLUTION
Technical name(s) :
UN/ID No. : UN 1805
Transport hazard class(es) : 8
Packing group : III
Reportable Quantity (per : 13,543 lbs
package)
RQ Component : Phosphoric Acid
Air transport (IATA)
The presence of an RQ component (Reportable Quantity for U.S. DOT) in this product causes it to be regulated with
an additional description of RQ for road, or as Environmentally hazardous for road and air, ONLY when the net
weight in the package exceeds the calculated RQ for the product.
Proper shipping name : PHOSPHORIC ACID SOLUTION
Technical name(s) :
UN/ID No. : UN 1805
Transport hazard class(es) : 8
Packing group : III
Reportable Quantity (per : 13,543 lbs
package)
RQ Component : Phosphoric Acid
Sea transport (IMDG/IMO)
Proper shipping name : PHOSPHORIC ACID SOLUTION
Technical name(s) :
UN/ID No. : UN 1805
Transport hazard class(es) : 8
Packing group : III
Section: 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ (lbs) Calculated product RQ
(lbs)
Phosphoric Acid 7664-38-2 5000 13543
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Acute Health Hazard
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SAFETY DATA SHEET
3D TRASAR 3DT184
SARA 302 : No chemicals in this material are subject to the reporting requirements
of SARA Title III, Section 302.
SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels
established by SARA Title III, Section 313.
California Prop 65
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.
INTERNATIONAL CHEMICAL CONTROL LAWS :
TOXIC SUBSTANCES CONTROL ACT (TSCA)
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA)
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).
AUSTRALIA
All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme
(NICNAS).
CHINA
All substances in this product comply with the Provisions on the Environmental Administration of New Chemical
Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC).
JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Existing and New Chemical Substances list (ENCS).
KOREA
All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing
Chemicals List (ECL)
NEW ZEALAND
All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and
are listed on or are exempt from the New Zealand Inventory of Chemicals.
PHILIPPINES
All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines
Inventory of Chemicals & Chemical Substances (PICCS).
Section: 16. OTHER INFORMATION
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SAFETY DATA SHEET
3D TRASAR 3DT184
NFPA: HMIS III:
Flammability
HEALTH 3
0
Instability
Health
3 0 FLAMMABILITY 0
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
Special hazard. 4 = Extreme, * = Chronic
Revision Date : 02/04/2016
Version Number : 1.3
Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by
a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text.
For additional copies of an SDS visit www.nalco.com and request access.
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