ee ContpBUN a ‘
» The beach of cha ahh dale with
c- cdinaton ee i called ane ‘on we
Abit ton comand 0 ox Holccudax compat
ie fro 0 rtove.sinple satt mtred with each other
fritlas peapertfon and qllaw to stand tena new '
ac besmed called addition corpeund ca retlecedas'
om
ompoond> 0
gt kat “ye => Ketingely: bh
‘ E aan >
54, +My), 2th > Igy MPO ye HE
At fetes alert )
ON Cadditin ampere)
7 Meculas compound cx Addition compund ae ob be
ee.
G& Puble salt
G- ordinator wimp Bipot
® Double sali salt
> ese ae the ‘addttten compound Meee sbile & all
Stak bit Forked cimpletl &solutton te boom contiiare kon
be omble-salt lee tes ae & elution.
yt é
3 Keble thea —> Kcliagth. 640 (Garolrte)
seirwannw sun on ll
r
2A capsule of medicine is. \aken ofsale fh wakes tress Fle Bolenltty ard poodoces fe
honstftuent fons Lite kt rg ped +A es
|4 Co-ed ination compound
ese ave the addtlien compound which does ntl hse ts
} ‘eest fl tr Solutlon ¢ bes not pocalue oll Hs centftient lane
VG? Causey. Ynltl, ba cpoodinatien canpound. which cbezrs
poovee all Hs contitucnt fon fn selution bat ppodxe fo
oP
(hes 56j'2p. a complex For [ail cohteh) ches rot tn
| thew So Gustipulle Be catecLa. complex cagpond
which can be waftlen as, [eco be
Bet yi
hee [Gees Jse, ==> [oy] tsa”
; «(Complex torypurid sos CLonplexfon) :
2 the compound 'n otich & 0.08 caters, fons 0% neutoal
molecule ove attached toe contsal metal ebm though
fo-vsdlirate bond arecalled co-cveltnation compovnd ox
Complex cempond.
tog fe on |
ere. ee
Inportant tear fee elated te concedinalten ceopeund
| iow Hs) \]sar- {Soy <— Porheatkon goep 0
B Lo. \ Quntes on
Conteh As Co-oxdhaton Se
Co-oxdPiation numbex
£ Spand.
a Confegl metol atm
| 7 Tis Sethe cenbre ob thesco-oxdlination to whfth are ob
| exon, , fons oxnentoal meleciles axe a Hseuyh
hk @-oxdirate bond. :
P bilpganif wre kh RE
| The atoms, fons ire ok ae whichtie atteched.
| to the central metal though co-codnate bend b
| | donatfon ok lone » pais elecfeon presents ‘on Fs dere,
| atom
| 0 Co-cedltatton number
| 4 fhe no. fe aoe Upords atleched tothe conteal metal afore thee
| Heorgh co-codate ‘bord. Fs called co-ordination number:
>the no. ob caseltnate bond bemed by centro metal ate
| with the Imad & called co-ordination nonnbes:
| i *
| &y- CoH), Sb 2 Cocok nation one i
| Nl _ el! |
lz con), | coc nation ee &s6
ds Co -oxdtnate sphere
J Tcccnnad motel oat te Bem
atteched to € axe colecterelycaled Co-cedlnaton sphere
ae nen fonkxible. ond wari b.gquee eee.
e- (enters fon agit |
| The forfsable Gor pert ts de wordt 4
le Iscalled cuntes-ton
Difheacnce, between doible salt ord. (o-cedination
A | Sas ¢ sonpond
‘Duel! coil caged
These ae addé tien compara Phe corrpound which ches
whch axe com fon ced not-loases Plenttly & solution
onpletty fa solution to boom sand. does not potdlice vail ts
\ \pyncst dent bon. * SS wonstflvert Fon.
. slain ieee a Seltion ch covadtnodio”
eg cnpecnt deesnat gore tt
fe all cata ent FoR.
- bib cael a ater 9n co-ordination the cena
‘shee sel ee metal cfom doesnt hoe?
bs Hs neomal valenty.
Ae wadiok bead is absent 7 €y-cadfnetion bond 2
in double
tetectanine
Hexadentate :
at gene, S| Da
[octal
| dpsstbeation of i Ligon d on pe kes oe bonding
é) chelating Ligand
G) Berd gig Ligencl
on) Anbideatate {yard — |
Chelating Lf 7 ae
BFdentated # fe hjelented alert v o-Cngf |
| wh the cen. Pe halon boa Sg compose]
awe called chelatin band. ‘ond the poacess % caller)
Chelation, The conplex ab * calied
Ch — NH
(i oe
Pra sy Choy Taal
Ayla dleobre
metal chelates
Nb - SS Beth — ce
dy. aes ON ee
(Metal chelate )
a Beiaglng Mipaad eect |
| Athagh yard Like oa, Von Ni -ete are mono dentate
| Ufpends ya bitenteke Urand when
| Me eottate with t-melal atime & te bamiln
sie
| (thy 2 — Nila — C0 G04] chs 5 Anabfdlentate Lien
Monodentoded Lipard. which contels move then Gee
ee afore pat ccordinatle 8th te coda eth
atom Hoough a single bras. atone typ called
Ambidented Ligand. fe
4% NOx, Sen.
pe tsar ambldentoled Ujord beease % can
wredbrinted atthe metal ator Haigh ifbage7
appear. Oh
DOr Sore COX
ox
Asm dyy
OS enone:
Note
Aleteidate Qfyand
Apdo! tare, ahihcses patige all Hs, cat
mito co-ced nave wth lhe cabal metal 2000 WE
tlexfolentated yard.
4 LOTR ea heradentated ford buf FF can alo
aotas 9 febadentobe ox pomastn fabled Sparel yy
oxidetten gombex ob thetenteal jnetal ator
Of&cloctton numbex 06 he metal atern & he chaage
which Fehe8 oe, Of peas fobave when, Fl combines
with Eipnds. oxelation raob the contol metal.
debe calaslated py blowing step
» The oxidation nmbestl- ve Lfgand = haga on the
\ f : Ligand
? Thecexidad ‘ jon numbers ob awe Lpgend = chasge A
WO I
» The oxtdation nmbexb-neutcal, Myand =O
7 The sort ob oration number ob all the compuert
ofa padmate ampount Es equal to the chargeon
the w-adhatfor compound.
ssn GF ks [ren] Re ee A
341) POLIO = 0 :
Jgecas =a
y ae
CN ob be = 43 [Fe cor]
m-ye-)
X23
fr ensje
#90) 436) =O
23
| (1 cw,)
n+ aad
Xo 449
n24
[covey Cop Og Jos
x Fact) ¢0)t 200) tL) =O
142 “lee
a= -] Jupac. nomenclatuxe ob coosdinaHAh ompurd «
an Osdlexob | namiaget ienie (ooxdnate compound,
The cation (simle o complex) ‘woktten ae |
oe anton,
. Sir , SLR OU, s] he catfonic k Ls caotthor
isst bllowed a te co-cd eratfon “sphere.
b. Codless ob enartig 0 ob E ees iain glee.
In te cp-oxtbrabten Splexe te wottler best
mS be central metal atom.
hn [te a) i) thelr Cent) ts aston Bist
“pollwed by the conbel metal ater Fe
a Onder oF romtag ob Lijaude g |
OMhe ye onitten alphabet cay Soaspective |
ob thet Aorge. |
1 A" eg [elem HJ fp gail lia
a witlen biast Followed 4 Sand CnC gan tol )
NOS A Gi) 9b more hen me same tyescl b che Cave. a.
thet nambes: ane poset iy E te pookkr dh
tefea etc.
ge (@ Cribs ] sop © yin oN
Tetocuanine ae
ai Negative Mord whch ender He pame ale
Ede, fhe eee: 2 os .
lalie — dhe.
feetete =>, decteto
SAS
dy Te De ork sku We
Gy) Newbal bed are. fer dete spechel ee hesmbs
C) ards ooichare boo saalheat a eee theix 00n
eal SSNS Nigy sof Sorat. at CO
CHs <> methyl
als > Ete
cats wage YI O” Ligands ahseh Pree the ee) dy bf h tetea ote
Ly thebs name, their rartbe. Ls sepescaed. “ve
prox bis(or2), bfc( for 3), fefealcés.¢ ba-4) ,
penakis (tx 5) ;
Gt (Lrpjlee Lane) ‘ .
bis ety lene dhamme”* ooo
Ujond the vod ase |
oy In cue baad gin
helore the name Do. Spend! Sains 4
g 8 [are — Nb ott), 04 s
fe anide
Sissy s -
Uy [b- reore then whe same heel bad ee.
the wod oe bf, feta ee eke a
oo c
: [Geog P ee (nies apn
Ye dPhydooida
Of The name cl complex Gpondis cwattlen hacket Nam
t+ c3ntral metel aim
nd. antan corplex K
296 the c-oxdinaten Oy
anton the name abt
whth ate>
pt: Platingte
be Cuyprate
by 2 mexcuoate,
Cex - Chomete.
pd~ Paladede
OS ~ OSmate.
cd - Cadmate.
zn — Zicate
NP - Nfcklate
Booate
ae
Fe ~ fecoate
i Aogenate
Ln - Stanaate
pb- Aumbate.
ju devote
@ ~ Cobaltefe ..
a. Muninale
a ee, Z AT? da
» fer seme. metal thelr latfa-nanes axe vse
x |
> In case ob complex cation allo ae |
name of the certzal wrttten cs YA |
ahha complexes the oxteletjon m0 PT. |
| atom is wrftten coman lathessf 2.1, Ww) tn bracket
|
|
at the endo the ‘pame ob the centel. nial 90,
phased a acedte co-cxdnattar compund the ward
‘Fo adhd’ ts ued: ©
in case0b neutral co-oxdinatton compourel the centsal
metal atom Ls wollen 28 such