(ourdinetion Chemis Gotents Deh _ i Recegai ition end appl cation of Courdd:inerli, Corpur a ¥ Porrenclatue of Gucdinabion Composrds * Coordi nation formule and _ boomers la. edie Compa vod _* lice der’ of Cordinertion Complerc Corpacd. £ Theories of § eee ¢ Lundin # (lalence _ bed Theo ct ‘ rol lecole Orble eon). chet 339 Prt W332 oe dition Campound s The R eachin of un Sol \uble Salts misced Up togethe- An forma A new Compound - —Addihon Comp ouncls Can be @Heg or! sel Into ) Double salt and bse a Compound . ee' Double | kel4 satis are slable ak soluble Coplute) stele. higcle + bloO— ket tgct. « +66 kt cf [197 + Cooddination Compounds. CaSty -gHao TCH 94 ]5t, » Corl Lion Nev Gopunle are le both Line! salle, she wal In Sdlobion. } © (annol ian MWe presence of CG Lecuse et Coord) Coor dihabion Compurd.s > Ths Cotain & area mela) elo atom, Lei Yu mbe- | of as aes © Com Complex ene = a Gra J Cohort Hl, atackel-f, q bgovel. = Gaordinads on ‘Chem Ts g branch of Cromishy ral Py, atl de study nedion Compurds eC Gre Compound a vel, ae) Sur on L Vgards or deror atoms. They are lee Ik Noun rplets (on -eilbe- be; lop (a ontc) wD Anionic EA reetre| Compe, Grp lex Aor (OM 4] apron Complex for (49° Peube) | Lojane - Sphere /\ nner sphere ; de Sphere | outer sphere,07 Pho, Gonple = ky LRCoaey 7 | oni zation sphere x Oxidation number (ste harge possoed by an_chom Gnon onthe chaccje posessed! by the metal ion. : eg (eC ait / jxe—txb =-3 x-6=-3 - x=-346 =43, : + Coed eke Dumber = [ste umber of Gurdingle by attache Ap Ihe metal joo: i. » Ligards> Gr be 4 neubel o¢ chorged molecule Lhe} Can dangte 9 fore pac of election te He Central meal Non. - ¥ Doror| aboms = Common bro ctems =, 0, ard 5 > chpoc acto la-He com elirectty ablacted + | He me lon. + Plonodentate (igends Capab oF clonating One elechon C4. donor atom) He paler cte lands besing mort then One Uigend atom: lt Can be identate, [ridemete, Telraderta penis ntale, ete. Soca mple oF Lidemtste aloe, te (4. be Cherepe or retreat 4 Pramples ;: Aceb tacts, Sulpeds, Oxalaly . 7 fe | ar \ere dia "S12. 2 wLipyridine, heron thioline. vthelale ble \, $ elation dalle = Ans Complex Thon One dono Nad Gh Carel o Feed vin Ip dmchore! = Chelabing ligand = Compler faving more Her One chore. position 1p g a light dackle ele a lo tbe (e535 of Foc ming G ring light Stucke example ne + cla (en) J" \ pt _- hte fe Z Npu, oe delale « labile Complex Le « Tigerd replaced u Subelhted Sa anolhe, ligand, dhe. oct high! reachse, 4 acne 3 esl oC CyCRHs + bu o- y Compler ¥ f ligerd Hel Creat Substtuky asl role, h nd and they Gre less reachw-e \ J " Boning = Tears fo ot Clechen. Bandanc, Teenie —_ - (ew seat on lad »> Ont oe ake sled electes at oo ills cl"A cé Laccho, Sulplede, 6 xalaty s ne bela Neb G |Helbslere damine 2-2 “bipjridine (—lo £ phenan +hioline. a Chelate che lal ligcnd $ chelation L arplex aur rot an One dono Coordinate +e form rig light Shuctiuce. 7 Che lafing ligand = Complex lauirg more then One as reap Ber q cing ight: cheuchive. echela example a « abi 4 ci: e- coal hon ls le pretess uF for mig Qa ring light Struchie + cle Cen) T° \opt fila fp ee Nou, ——Oe ctolate e Complex pts igeedl rep laced oe sulehhwed ec ligands they ore high) recchue, aC) G4 esol cq Chie) bus: ¥ Sart Compler + x ligend Het (nro Substteb 4-4 othe, ligand and they Gre less reac hue ¢ Lodic Bandicg a Trask of elector. in Bordan Theories } = Corda bacdey =» Ont Ore alum shined eleoker2D Cotalont Bending 2? Toe ohn phered © leche He AL, eorteS Gre+ D\ Ooh lenke Burl Theory ) Cysk! Rebel de, 9 robuale- orl;-tal Da C1 YQ 52 Ad lasag Valence Band Plear ee, lel fis D dhe 0 why Spel are tint to Gccomodede "he lone _| aus of elechuns for tHe gan. or Cosideced fy beg generate orbitals + Degelerak orbitals > are orbitals haing MeShne eregy Fue}. Cclegenerate = = the Sore). Transition cleremk » Hes? ae «grip & metallic de— i hat have Gn [ncemplete boner CDeleckon Sel} brwiog gets Ue e Uslencies, they are Ip elomenls Brg, aad Hhose ly 293 We; Herm lo the Pere le Se — Tr SetPxerple Ccly — ct f- dA cl C= |s7957 2p" ll or > 1 eG 1 cl. | clet cl | Orbilhls Mhet ave Used-ty Gccomadale Ho lore pairs of | cdechala In Coordination Grpovals Grew fim do & dew Oy | 1D Second Assumphon— | 4 There must be ao lo krack on Lehween te lone Pac 4 ot metal \on orbital and \ige! or lone Paice of Clacton 4 from 4 igands - x1 cbilels Wobare Used do form Grpounds = Oclahed-a} ~ Teds bedeal OUR o Squ re plenae ' do a |Paes We mele) lon [5s Sur@unded Ly 6. dda? sp 22 brbrbl cred rat pa IRT ° Ss . Sa Tonb- d- orbital > Me “Complex ls stable Ge q plex Cacdipahon. |e Outed -ocli tal > tbe Lingle cls Complex - Cosed:' ree less stelle. et te Z elect oe In bee Side + Lene fi Belt gend oIL Gok 9% __d (seh Tt 6 2 - in sd°gsr en tage D sin Mo Tire — d ~orbila) [s is ; | at to ccomed ok | _ du Pacs ef elechon fom Mo Pande Gmple. } ksJing +o magnetic — rflex Is Paramagnehc —» becawe of tHe vith He Tybadaie om SP? —oclaledral- £4 fe Cob jr > einer - Ochbed al ; : *S | AAO => aauck | ic na@luce = paramagnent eee Si ee : expyesef63e— OTM neck Decco ake Lec] Spas | Tebraledea) Corplez —-U Coordine Hon number a a) fe a tle © melry > p> Lybridi aihon reac rec‘dD (wi (ly) °= 5 aeale [i gand: = oxidation state. pi ‘oF = 39% oats Ol Telalmn or At Gd EARS Ea ; cl ct cl ecl Ss 3 4 Para neh. — | P 9 ¥ Squac ana oe iy Coordinate Lond _ dope — Gp > Y[ 01 (ca)4)* ae byerd-_ wi — 3d 5 45° Ant —> 348 LA) wm wt negaboe mela) Is Considered to be Is na Interackion between the. Joc 6 weal [ed 2 Ee ot eq ¢ pit reg alive dua charge lon and point posi ve Charge.To forma loond 5 There must be lnleraccton bebe een poiet posihve Cherge metal lon Gnd poiet regetve cee ligand : st” che . |] Cagery “) Sliilgls - day et dogereiat le’ : 7 : ¥ there are In Lehoeen dle ans ox x less repul sion. yt dt yy Diskibuton oF election Ind ® = 6, bial eo wef €4 i 5p “4a tag ee ' ads 4] 71 41 71 | —t____.. 7 High spin [08 spin 2 44 Z die al 4 ew th | —Glelohon oF Cost) Geld slab il energy (OHS ec] Je or — Cfs€ =(-0-4Ao +064) | d= p+ / a - Numbe— of electrons iE obey - - = Aumbe-~_o fF electrons n_ Ch5e = Cog ded = (-04xPAo +0-6 xg Ao) SY _ ;, =(-0-4p + 0:64) Ao +!p Pairing see (>p) - more stable Arle © when He elect) [ala /4 Tay Ie Tp LL Side toy Gee Jr 4 Dist bution ot electons |n High Spin or = Si High spio io Spin d! ee ep if —— a a7 j a} ee Af 4 __ TT alt a a _— 1114 1 A T 4° - ae 1 t_ 7-4 4 Bp Gloulate Me CASE Valoe far ol!" Ino tebedral Corpleres CSE. = (—0-4p +064) Ao +p E (0-4 81 + 0-6 x0) Aa + OP a se Ww ua se = (-o-4P +0-64) Do +rP(Found + obxo) be +P F-lbdo +f Al! igh Spe fisaaa tate sen : 2-0'b Do - tt : dt | low spin “ise = Co-up to-bg) Ao +m rC- C046 +0-6xU) bo ia 3 eal poe + 3Py —— “CPE = Co. on 06g) Ao + mp 7 = CO4xs +0-6x 2) Ao 4 2xP- = -0:%Ao tie - a Ox Sese Q) predict tte ore, Sab il: rche fia Pe! ies fie Palloany _ 48 ray! . a ky Che dh / ») ky FeCade a |K — ecryse) Held Sphttng In Tehrahebe! Complee! cba n behween He qxis > Stper enge high — bhigsnds. 1 repulsion. a és } doet-y2 dla? Tetrabedlea! Complexes lJ alos heave High Spio because the Pact eneryy Is qhoays Very High. eee eae of: Cgohh me Shabili zafion Ene a» Tetrahed al Complexes Cfse= (2bby +o0-4pJ DE but At =o0'45Ac as icfs€ =(-0-6m + 0-4 x3) Dt at se = (-o-bx4 +o-4 xD At | 3, Bt, db J dh d” > Dp H yourelt| lal felt splittia wore ees : In nae gee we approach ea ry dx? -7 | dat ye dt t { - dxy ht dye dct oft € | ole. t Theory : - : cm & Bond The Orbits} must duvele ". 2) Bondi 4 anti benching oPtih ts are Pormed Lum fle Overlsp of metal lon Ocbilals & [igen Orkrlals 3) Gon jn orbitals Gee lower le Conergy “then 3 Bondin ol 5: ? ott " i tals from Se igsnds ar ad 6rbi hat Gre Use tor Cobrdin ate bond per wn oe; S pb PP | Hh TRlead: s of Orbrals fum the metal Lon pn Obed ral Green \s 4h Lert ol 6, lata oA melel lon Ihe} el lce-to Oe Gee ; aie tL eleclans frm ligands at either Al? SP or SP? a s day, doctrdy? — noe ~burdng Orleals (ba bat gps dats, 5s P banking ovbrlele Th Orbilals. dry drt, dye are directed lie axis, 5 such, Connot focm Sigs Lond ~Grd ore Called on = bandos Oc bls - ote + dx? ~y2 de? (ef | ie — tid) coe) co (ats)6 J Somes cot zl! x ° +3 ——- { (pJ3d* 4s? Co’ — 3d@® ®@@ role fo oleld Dipak. onl ——s POW magnetic parsperty— Digmagebe. Sebo sible ; Georely = (qclabedal weghQ@U8~ Co - 3db ys? CHT 3db- | Grrrtfedions of Valence oad “Tew DE em =aplin ae begin 0 re Tee iu Nation 42 ™Pounels 2) tt Tannot explin Ye magnet nelore of te a Grpouncl arth Gn Jrcreasing Temperstur| Klomenelntoe of Goodin bem Compan = Als sex plome be #—-- Alame cf Com ple greene 7 we Sth : Small fe £4 4 Lob, _ a a Mowe et Asve ton te - : hens Coding - te! ne ged ln _ancen ae Nlaesi -atjeme 5 of Complen Coun fanrn of gene | OK Apo ene Wathe ded : tate alee ——- Le aaeen pi & Alownrp of Lysad : am! Fo at cu : fe are cpowe iy tom ted © 0d ihe, ator , ah fa) ey ey TF oye narmsitte Che chlore ae bWrieh s-seb Lewe Copnd Gh cana nm laf Ge