Section 111

Bath and Shower Products

79
20 Cosmetic and Toiletry Formulations

Bath Oil
Colourless, clear, low viscosity
Insredients: Wt%
A: Wacker-Belsil SDM 6022 1.00
Mineral Oil 69.00

B: Wacker-Belsil CM 0 2 0 25.00
Arlamol E 5.00

Preservatives, pigments, fragrances g.s.

Heat A to 50C (mix in Wacker-Belsil SDM 6022 homogeneously),

mix B into A.
Temperature stability: at 45C over 10 weeks.
Formulation 330 AH

Bath Oil
Colourless, clear, low viscosity
Ingredients: Wt%
Wacker-Belsil CM 040 25.00
Mineral Oil 70.00
Arlamol E 5.00
Preservatives, pigments, fragrances q.s.

Mix all components.

Temperature stability: at 45C over 10 weeks.
Formulation 3 5 0 AH

Shower Bath
Creamy, well foaming shower gel leaving a pleasant
touch on the skin.
Inaredients: Wt%
A: Texapon A 20.00
Texapon NA 20.00

B: Genapol PMS 3.00

Lanette 0 1.00

C: Tylose H 4000 P 2.00

Wacker-Belsil DMC 6038 5.00
Water 49.00
Preservatives, fragrances, pigments q.s.

Mix Tylose well into water, add Wacker-Belsil DMC 6038. Heat
A and B each to 70C, mix B into A, add C.
Formulation 1347/3 AH
SOURCE: Wacker Silicones: Suggested Formulations
 Bath and Shower Products 27

Bubble Bath
Starting formulation for an economical pearly bubble bath.
Inqredients; Wt%
Sulfochem B-2090P 25.00
Water, soft 73.65
Fragrance 0.25
NaCl typical: 0 . 8 0
Citric acid typical: 0.05
Preservatives q.s.
Hydrolyzed milk protein 0.25
Blending Procedure:
With medium agitation, ioix water, Sulfocheni B-2090P, and milk
protein in main vessel. Add citric acid and mix until solution
is homogeneous. Add preservatives, fragrance, color, and remain-
ing ingredients. Adjust pH to 7.0-7.5 with citric acid. Adjust
viscosity to 4,000-5,000cps with sodium chloride.
Typical Physical Properties:
Viscosity: 4,000-5,000 cps
pH: 7.0-7.5
Formulation E3134

Bubble Bath
Prototype formulation-?& an economical bubble bath.
Inqredients: Wt%
Sulfochem B-209 25.00
Water, soft 73.76
Fragrance 0.25
NaC 1 typical : 0.90
Citric acid typical: 0.09
Preservatives C2.s

Blending Procedure:
With medium agitation, mix water and Sulfochein B-209 in main
vessel. Add citric acid and mix until solution is clear and
homogeneous. Add preservatives, fragrance, and color. Adjust pH
to 6.5-7.5 with citric acid. Adjust viscosity to 3,500-5,000 cps
with sodium chloride.
Typical Physical Properties:
Viscosity: 3,500-5,000 cps
pH: 6.5-7.5
Formulation E3129
SOURCE: Chemron Corp.: Suggested Formulations
22 Cosmetic and Toiletry Formulations

Clear Mild Body Wash

Raw Materials:. Wt%
Mackam HPC-32 (Sodium Cocoamphoacetate) 5.0
Mackam 35-UL (Cocamidopropyl Betaine) 10.0
Mackalene 426 (Isostearamidopropyl Morpholine Lactate) 2.0
Mackpro WWP (Wheatgermamidopropyl Dimethylamine
Hydrolyzed Wheat Protein) 1.0
Mackernium 007 (Polyquaternium-7) 2.0
Mackanate OM (Disodium Oleamide MEA Sulfosuccinate) 5.0
Mackanate EL (Disodium Laureth Sulfosuccinate) 5.0
Mackol 70NS (Sodium Laureth Sulfate) 17.0
Paragon I11 (Phenoxyethanol (and) DMDM Hydantoin (and)
Methylparaben (and) Propylparaben) qs
Fragrance, Water qs to 100.0
Appearance: Viscous Lotion
pH: 6.0-6.5
Solids, $ : 20.0-23.0
Procedure:
1. Completely disperse Mackerniuin 007 in water.
2 . Add first seven Components and mix thoroughly while heating
to 35-40C.
3. Add Mackol 70NS and mix thoroughly.
4 . Blend slowly and adjust pH to 6.0-6.5 with Citric Acid.
5. When product is completely homogeneous, add Paragon 111.
6. Add Fragrance then cool and fill.

Elnullierit Bath Gelee

-
Raw Materials: WtP6
Sodium Laureth Sulfate (60%) 20.0
Mackamide LLM (Lauramide DEA) 20.0
Mackanate EL (Disodium Laureth Sulfosuccinate) 20.0
Mackanate WGD (Wheatgermamido PEG-2 Sulfosuccinate) 10.0
Mackstat DM (DMDM Hydantoin) qs
Water, Dye, Fragrance qs to 100.0

Procedure:
1. Add Mackaniide LLM to Sodium Laureth Sulfate.
2 . Add remaining components.
3. Heat to 45C.
4 . Blend until homogeneous.
5. Adjust pH to 6.5-7.0 with Citric Acid.
6. Cool to room temperature.
SOURCE: McIntyre Group Ltd.: Personal Care Formulary: Formulas
 Bath and Shower Products 23

-
Conditioninq Body Wash
Raw Materials: Wts,
1. D.I. Water qs
2. Mackol 70NS (Sodium Laureth Sulfate-70%) 20.0
3. Mackam HPC-32 (Sodium Cocoamphoacetate) 13.0
4 . Mackamide CMA (Cocamide MEA) 1.0
5. Mackester EGMS (Glycol Stearate) 1.0
6. Mackamide S (Soyamide DEA) 1.0
7. Mackanate OPS (Disodium Oleamido MIPA Sulfosuccinate) 5.0
8 . Mackpro WWP (Wheatgermamidopropyl Dimethylamine
Hydrolyzed Wheat Protein) 1.5
9. Mackernium 007 (Polyquaternium 7) 2.0
10.Paragon I11 (Phenoxyethanol (and) DMDM Hydantoin (and)
Methylparaben (and) Propylparaben) qs
ll.Ethylflo362 NF-Albemarle (Polydecene) 1.0
12.Fragrance qs
13.Dye qs
14.Citric Acid 0.3-0.6
15.Sodium Chloride qs
This body w a s h will be a pearlescent viscous liquid ( 5 , 0 0 0 -
10,000 cps) with a pH of 5.5-6.5 and a concentration of approx-
imately 30%.
Procedure:
a. Charge ingredients 1'2, and 3 ; heat to 55-60C with moderate
agitation. Mix until clear and homogeneous.
b. At 60C, add 4 and 5. Heat to 70C and hold for one hour.
Ensure that there is no unmelted particulate matter in the
batch.
c. After 4 and 5 are fully dispersed, cool liquid to 40C. Charge
ingredients 6 through 13.
d. Add 14 (citric acid) to adjust pH to 5.5-6.5.
e. Add 15 (sodium chloride) or water to reach desired viscosity.
Cool and fill.

Bath Gelee with Natural Lipid Protein

Raw Materi- wt%
Sodium Laureth Sulfate (60%) 20.0
Mackamide CS (Cocamide DEA) 20.0
Mackanate CP (Disodium Cocamide MIPA Sulfosuccinate) 20.0
Mackpro NLP (Quaternium-79 Hydrolyzed Collagen) 4.0
Paragon (Propylene Glycol (and) DMDM Hydantoin (and)
Methylparaben) qs
Water, Dye, Fragrance qs to 100.0
Procedure:
1. Add Mackamide CS to Sodium Laureth Sulfate and blend.
2. Add remaining components. 3 . Heat to 45C.
4 . Blend until homogeneous. 5. Adjust pH to 6.5-7.0 with
Citric Acid. 6. Cool to room temperature.
SOURCE: McIntyre Group Ltd.: Personal Care Formulary: Formulas
24 Cosmetic and Toiletty Formulations

Emollient Body Wash

Raw Materials: Wt%
Mackam HPC-32 (Sodium Cocoamphoacetate) 14.0
Mackol 70NS (Sodium Laureth Sulfate-70%) 17.0
Mackam 35-UL (Cocamidopropyl Betaine) 10.0
Mackalene 426 (Isostearamidopropyl Morpholine Lactate) 5.0
Mackester EGDS (Glycol Distearate) 3.5
Mackernium 007 (Polyquaternium-7) 3.0
Paragon I11 (Phenoxyethanol (and) DMDM Hydantoin (and)
Methylparaben (and) Propylparaben) 0.6
Fragrance, Water qs to 100.0
Appearance: Viscous Lotion
pH: 6.0-6.5
Solids, %: 26.0-28.0
Procedure:
1. Completely disperse Mackernium 007 in water.
2 . Add first five components and heat to 75C.
3. Blend slowly and adjust pH to 6.0-6.5 with citric acid.
4 . When product is completely homogeneous, add Paragon 111.
5 . Cool to 50C and add Fragrance.
6. Cool and fill.
Formulation No. 152B

Bath Gelee with Silk Protein Buaternized to

______.___
Natural Skin Emollients
Raw Materials: W 3
Sodium Laureth Sulfate (60%) 20.0
Mackamide CS (Cocamide DEA) 20.0
Mackanate EL (Disodium Laureth Sulfosuccinate) 20.0
Mackpro NSP (Oleyl/Palmityl/Palmitoleamidopropyl/Silk-
hydroxypropyl Dimonium Chloride) 4.0
Mackstat DM (DMDM Hydantoin) qs
Water, Dye, Fragrance qs to 100.0
Procedure:
1. Add Mackamide CS to Sodium Laureth Sulfate and blend.
2. Add remaining components.
3. Heat to 45C.
4. Blend until homogeneous.
5 . Adjust pH to 6.5-7.0 with Citric Acid.
6. Cool to room temperature.
SOURCE; McIntyre Group Ltd.: Personal Care Formulary: Formulas
 Bath and Shower Products 25

Fitness Shower Gel

clear, 16.2% active ingredient
Recipe: wt%
A Menthol 0.20
Camphor 0.10
Rosemary oil 0.30
Genapol L-3/Laureth-3 2 .oo
B 1,2-Propylene glycol 2.00
C Genapol LRO liquid/Sodium Laureth Sulfate 45.00
Genapol AMS/TEA-PEG-3 Cocamide Sulfate 4.00
Water 43.10
Horse chestnut extract 0.50
Dyestuff solution q.s.
Preservative q.s.
D Sodium chloride 2.80

Procedure:
1. Dissolve A in B.
2. Stir the components of C into 1.
3 . If necessary adjust the pH.
4 . Finally adjust the viscasity with D.
Formula A I/8077

Washinq Lotion
clear, with a bacteriostatic effect, 10.4% active ingredient
Recipe L Wt%
A Octopirox/Piroctone Olamine 0.20
B Water 10.00
C Genapol AMS/TEA-PEG-3 Cocamide Sulfate 19.00
Fragrance 0.30
Dyestuff solution q.s.
Preservative q.s.
D Allantoin 0.20
E Water 59.80
F Genapol L-3/Laureth-3 0.50
Genagen CAB/Cocamidopropyl Betaine 8.00
G Glucamate DOE 120/PEG-120 Methyl Glucose Dioleate 2.00
Procedure:
1. Mix A with B.
2 . Add C to 1 and keep stirring until a clear solution has
been obtained.
3 . Dissolve D in E while heating slightly.
4. Add 3 to 1.
5. Add the components of F.
6. If necessary adjust the pH.
7. Adjust the viscosity with G.
Formula A I1/4024
SOURCE: Hoechst Aktiengesellschaft: Guide Recipes
26 Cosmetic and Toiletry Formulations

Foam Bath
with a pearl-lustre effect, 19.9% active ingredient
Recipe: Wt%
A Hostapon CT paste/Sodium Methyl Cocoyl Taurate 8.00
B Water 33.20
C Genapol LRO liquid/Sodiurn Laureth Sulfate 40.00
Medialan LD/Sodium Lauroyl Sarcosinate 10.00
Genapol PGM/Sodium Laureth Sulfate, Glycol Distearate,
Cocamide MEA 4.00
Fragrance 0.50
Dyestuff solution q.s.
Preservative q.s*
Genapol L-3/Laureth-3 2.00
D Sodium chloride 2.30
Procedure:
1. Dissolve A in B while heating slightly.
2. Stir the components of C one after another into 1.
3. If necessary adjust the pH.
4 . Finally adjust the viscosity with D.
Formula A1/2011

Creamy Foam Bath

with a pearl-lustre effect, 21.7% active ingredient
Recipe: wt%
A Genapol LRO liquid/Sodiurn Laureth Sulfate 60.00
B Medialan LD/Sodium Lauroyl Sarcosinate 8.00
Fragrance 1.50
Cetiol fIE/PEG-7 Glyceryl Cocoate 5.00
Genapol PGL/Glycol Distearate, Cocamide MEA, PPG-4
Deceth-4 5.00
Water 13.00
Dyestuff solution q.s.
Preservative q.s.
Genagen CAB/Cocamidopropyl Betaine 6.00
Genapol L-3/Laureth-3 1 .oo
C Sodium chloride 0.50
Procedure:
1. Stir the components of B orie after another into A.
2. If necessary adjust the pH.
3. Finally adjust the viscosity with C .
Formula A I/3026
SOURCE: Hoechst Aktiengesellechaft: Guide Recipes
 Bath and Shower Products 27

Foamins Bath Oil

Insredients/CTFA Name:
Light Mineral Oil 20
PEG 400 Monolaurate/PEG-0 Laurate 20
Schercemol Mel-3/Myreth-3 Laurate 8
Schercomid AME-lOO/Acetamide MEA a
Schercoquat IALA/Isostearamidopropyl Laurylacetodirnonium
Chloride 15
Water, Deionized 29
Procedure:
1. Add the first five ingredients (oil phase).
2. With good mixing heat to 30-35C until uniform.
3. Cool to 25C and with fast agitation add the water in small
increments; mix until clear.
specifications:
Appearance @ 25C: Clear slightly viscous liquid
Color: Colorless
pH @ 1.0% sol'n (typical): 4 . 5

Bath Oil Milk

Inqredients/CTFA Name: Wt%
Schercemol DIA/Diisopropyl Adipate 15
PEG 200 Dilaurate/PEG-4 Dilaurate 15
Schercemol Mel-9/Myreth-9 Laurate 5
Schercomid AME-lOO/Acetamide MEA 5
Schercoquat ALA/Di-Lauryl Acetyl Dimonium Chloride 15
Water, Deionized 45
Procedure:
1. Add the 1st five ingredients (oil phase).
2. With good mixing heat to 30-35C until uniform.
3. Cool to 25C and with fast agitation add the water in small
increments; mix until the emulsion is uniform and smooth.
Specifications:
Appearance @ 25C: White emulsion
pH @ 1.0% sol'n (typical): 4.5
Viscosity @ 25C (typical): 3,000 cps
Formula SO-015
SOURCE: Scher Chemicals, Inc.: Formulary
28 Cosmetic and Toiletry Formulations

Hiqh Fraorance Bubble Bath

Inqredient: Wt%
Water 23.2
Disodium EDTA 0.2
Sodium Laureth-2 Sulfate ( 2 6 % ) 69.0
Promidium CC (PPG-1 Hydroxyethyl Caprylamide) 2.5
Promidium SY (PPG-2 Hydroxyethyl Soyamide) 2.5
Fragrance 2.5
Citric Acid 0.1
Procedure:
To the water, add disodium EDTA and sodium laureth-2 sulfate
with stirring. Premix Promidiuni CC, Promidium SY and fragrance.
Add to sodium laureth-2 sulfate mixture. Add color, and preserv-
ative. Adjust the pH to 6.0 with citric acid.
Formulation Properties:
Appearance: Clear yellow liquid
Activity ( % ) : 22.5
Viscosity (cP) @ 25C: 1400
Krafft Point: 3C
Note: Add sodium chloride if a higher viscosity is desired.
SOURCE: Mona Industries, Inc.: Formula F-861

Moisturizino Three Laver Bath Oil

A three-layer bath oil containing Panalane L-14E which is an
effective moisturizer and skin emollient.
Seauence; Raw Material/INCI Name: u.3
1 Cetiol HE/PEG-7 Glyceryl Cocoate 32.50
2 Panalane L-l4E/Hydrogenated Polyisobutene 35.00
3 Glycerin 32,50
Procedure:
1. At room temperature, weigh Sequence #1 ingredient and pour
into appropriate container.
2. Slowly add Sequence #2 into container on top of Sequence #l.
3 . Slowly add Sequence # 3 to the above two ingredients.

Note :
After the product has been shaken to achieve maximum benefits,
it will take approximately 5-10 minutes to return to three-layer
oil.
SOURCE: Lip0 Chemicals Inc.: Formula No. 1082
 Bath and Shower Products 29

__--
Milk Bath
This low viscosity, milky product is designed to be added to
a bathtub of water (2 fl. 0 2 . ) . It provides a non-greasy, soft,
silky feel to the skin.
Inqredient/Function: Wt%
Part A:
2-Phenoxyethanol/Preservative 0.2
DMDM Hydantoin/Preservative 0.2
Deionized Water/Diluent 70.6
Part B:
Dimethicone (and) Laureth-4 (and) Laureth-23(SM2169)(1)/
Smooth, silky f e e l 15.0
Part C:
Phenyl Trimethicone(SF1550)(1)/Emollient with non-greasy
feel 7.5
Glycerin/Humectant 3.0
Part D:
Fragrance q.s.
PEG-20 Almond G l y c e r i d e s ( 2 ) / E m o l l i e n t / S o l u b j l i z e r 3.5
Procedure:
1. Dissolve Part A with moderate propeller agitation.
2. Add Part B and continue stirring f o r 10-15 minutes.
3. Combine Part C. Add to batch and continue stirring for 15-20
minutes.
4 . Combine Part D and add to batch. Continue mixing with moder-
ate propeller agitation for 15-20 minutes.
Suppliers:
(1) GE Silicones
(2) Croda, Inc.
Formula SP 1 1 2

After-Bath Oil
This oil, applied after bathing, gives the skin a soft, silky
feel. SF1550 a c t s as a non-greasy emollient, while SF1204 pro-
motes a quick dry time without a greasy feel.
Inqredient/Function: wt%
Phenyl Trimethicone(SF1550)(1)/Non-oily emollient 10.0
Mineral Oil (light)/Eniollient 32.0
C y c l o m e t h i c o n e ( S F 1 2 0 4 ) ( 1 ) / Q u i c k dry/Non-oily feel 56.0
Fragrance(2) 2.0
Procedure:
1. Mix together SF1550 and SF1204, stirring until uniform.
2. Add mineral oil with good mixing.
3. When homogeneous, slowly add fragrance and continue stirring
15 minutes.
Trade Names/Suppliers:
( 1 ) GE Silicones
(2) Fragrance 56-712-B, Bell Flavors and Fragrances
Formula SP 113
SOURCE: GE Siliconea: Personal Care Formulary: Formulations
30 Cosmetic and Toiletry Formulations

Moisturizinq Bodv Wash

A liquid body wash product which is designed to cleanse and
moisturize the skin. SM2169 is a 60% nonionic emulsion of a
60,000 ctsks dimethicone fluid. It provides the smooth, silky,
feel of a high molecular silicone in an easy-to-use aqueous
delivery system.

Inqredient/Function: Wt$
Part A :
Deionized Water/Diluent 51.45
Disodium EDTA/Chelating agent 0.05
Carbomer(l)/Thickener 1.00
Part B:
Propylene Glycol/Humectant 1.00
Glycerin (96%)/Humectant 2.00
Part C:
Sodium Laureth Sulfate (28-30%)/Surfactant 16.00
Disodium Dimethicone Copolyol Sulfosuccinate(30%)(2)/
Surfactant 15.00
Polysorbate-20/Emulsifier 1.00
Dimethicone (and) Laureth-4 (and) Laureth-Z3(SM2169)(3)/
Conditioning 5.00
Cocamidopropyl Betaine/Surfactant 3.00
Part D:
Polyquaternium-39(4)/Conditioning 3.00
DMDM Hydantoin (and) Iodopropynyl Butylcarbarnate(5)/
Preservative 0.15
Fragrance(6) 0.25
Part E:
Triethanolamine(99% ) /pH adjustment 1.10

Procedure:
1. Meter water of Part A into appropriate vessel. Add EDTA and
mix until dissolved. With moderate propeller agitation, add
the carbomer and mix for 2 0 minutes.
2 . Add ingredients of Part B to Part A with moderate propeller
agitation.
3. Add Part C to Part AB in order listed with moderate propeller
agitation. Mix 20-30 minutes with moderate agitation.
4 . Add Part D to batch in order listed, Mix with moderate agit-
ation for 2 0 minutes.
5. Adjust batch to pH 5.5 with part E.
Trade Namee/Suppliers:
(1) Carbopol 2020 (2) Mackanate DC-30
(3) GE Silicones (4) Merquat Plus 3330
(5) Glydant Plus (6) Fragrance TC-726
SOURCE: GE Silicones: Personal Care Formulary: Formula SP 111
 Bath and Shower Products 31

Moisturizinq Shower Gel

Starting formulation €or a high-foaming shower gel with
moisturizing properties.
Insredients: Wt%
Sulfochem SLS 14.00
Sulfochem ES-2 24.00
Chembetaine C 6.50
Chemoxide CAW 5.50
Citric acid 0.10
Water, soft 47.30
Amidex CME 1.80
Preservatives 4.6.
NaC 1 0.50
Fragrance, color, etc 4.6.

Blending Procedure:
At ambient temperature, charge mixing vessel with Sodium
Lauryl Sulfate, Sodium Laureth Sulfate, and water. Add Cocamido-
propyl Betaine, Cocamidopropylamine Oxide, and citric acid and
mix until homogeneous. When mixture is homogeneous, heat to 70C
and add Amidex CME, preservatives, color, fragrance, and NaC1.
Adjust pH to 6.0-6.5 with citric acid. Adjust viscosity to
15,000 cps with NaC1.
Formulation No. F1004

Silky-_--
Shower Gel
Prototype formula for a shower gel that leaves skin with a soft,
silky feel.
mredients: Wt%
Sulfochem ALS 37.00
Chembetaine S 3.50
Chembetaine OL 1.25
Citric acid 0.12
Water, soft 4.6.
Amidex CME 1.70
Quaternium 1 5 0.10
Preservatives 9.6.
NaC 1 0.50

Blending Procedure:
At ambient teniperdture, charge [nixing vessel with Sulfochem
ALS and water. Add Chembetaine S, Chembetaine OL, and citric
acid until homogeneous. When mixture is homogeneous, heat to
70C and add Amidex CME and NaC1. Adjust pH to 5 . 5 0 - 6 . 0 0 with
citric acid. Adjust viscosity to 16,000 cps with NaC1.
Formulation No. F1003
SOURCE: Chemron Corp.: Suggested Formulations
32 Cosmetic and Toiletry Formulations

Oil Foam Bath

Raw Materials: Wt%
A. Marlinat 242/28 (Sodium Laureth Sulfate) 28
Ampholyt JB 130 (Cocamidopropyl Betaine) 7
Marlamid DF 1218 (Cocamide DEA) 8
B. Softigen 767 37
Miglyol 840 (Propylene Glycol DicaprylaLe/Dicaprate) 20
Colour q.s.
Fragrance q.s.

Preparation:
A is mixed, heated up to approx. 75C and stirred cold to
about 30C. B is subsequently admixed.

Mild Foam Bath

Raw Materials: Wt$

A. Marlinat CM 105 (Sodium Laureth-11 Carboxylate) 25
Ampholyt JB 130 (Cocamidopropyl Betaine) 25
Softigen 767 5
Elfacos GT 282 S (Hydrogenated Talloweth-60 Myristol
Glycol) 7
Colour q.s.
Preservative q.s.
Water ad 100
B. Fragrance q.s.
Preparation:
A is mixed and heated to crpprox. 7 5 C . Then the blend is stir-
red cold down to approx. 30C. B is gradually admixed.

-
Oil Bath SliqhtkFoaminq with Good Refattina Property

Raw Materials:, Wt%

A. Softigen 767 (PEG-6 Caprylic/Capric Glycerides) 21.5
Miglyol 812 (Caprylic/Capric Triglyceride) 27
Imwitor 375 22.5
Mineral Oil 26
Fragrance 3
Preparation:
All components are put together at about 40C.
SOURCE: Hula Aktiengesellschaft: Suggested Formulatione
 Bath and Shower Products 33

Pearlescent Bath L o t i 0 3

Raw Materials: Wt%

Sodium Lauryl Sulfate (30%) 40.0
Mackanate EL (Disodium Laureth Sulfosuccinate) 30.0
Mackam 35HP (Cocamidopropyl Betaine) 5.0
Mackester SP (Glycol Stearate (and) Stearamide MEA) 1.5
Sodium Chloride 1.0
Mackstat DM (DMDM Hydantoin) qs
Water, Dye, Fragrance qs to 100.0

Procedure:
1. Add first four components to water.
2. Heat to 70C.
3. Blend until Mackester SP is completely dispersed.
4, Add Sodium Chloride and cool to 45C.
5. Add Mackstat DM, Dye, and Fragrance.
6 . Cool to room temperature.

SOURCE: McIntyre Group Ltd.: Personal Care Formulary: Formulas

Bath Oil
INCI Narne/Trade Name;
Phase A:
Isopropyl Myristate/Emerset 2314 25.00
Octyldodecanol/Eutanol G 20.00
Caprylic/Capric Triglyceride/Myritol 318 38.00
Laureth-3/Dehydol LS3 10.00
Fragrance/Haarnian €Reimer
i 4.90
Silica/Aerosil 200 2.00
Pearl Pigment 0.05-0.10
Procedure:
Aerosil 200 is added with stirring t o ii mixture of Isopropyl
Myristate, Eutanol G, Myritol 318, Dehydol LS 3 , and fragrance,
then homogenized e.g. in an Ultra Turrax. ‘Phen the pearl pig-
ment and the dyestuff solution are added with stirring.
Note:
*Viscosity 3600 mPas (Brookfield LV3, 6 rpm @ 20C)
*Recommended Pearl Pigments-All Sparkle pigments, e.g.
Timiron Starlight Colors, Colorond Bronze Sparkle, Timiron
MP-149
SOURCE: Rona/Em Industries, Inc.: Formulation EM2-49
34 Cosmetic and Toiletry Formulations

Shower Cre*m
White, creamy
Insredients:
A Teginacid/Glyceryl Stearate, Ceteareth-20
w
8.00
Ado1 66/Isostearyl Alcohol 5.00
Isopropyl Myristate 6.00
Eutanol G/Octyldodecanol 4.00
I3 Texapon N 40/Sodium Laureth Sulfate 10.00
Genapol TSM/PEG-3 Distearate, Sodium Laureth Sulfate 5.00
Glycerine 5.50
Water 46.50
C Wacker Emulsion E 32/Stearyl Methicone, Trideceth-10 10.00
Preservative, fragrances, pigments q.s.
Heat A and €4 each to 60-70C, mix B into A. Add C at approx.
35c.
Formulation 1113/2 AH

-_
Shower Gel
Colorless, clear, high viscosity
Znqredients: wt%
Genapol LRO/Sodium Laureth Sulfate 35.00
Dehyton AB 30/Coco-Betaine 10* 00
Aethoxal B/PPG-5 Laureth-5 5.00
Wacker-Belsil DMC 6038/Dimethicone Copolyol 5.00
Comperlan KD/Cocamide DEA 3.00
Water 42.00

Preservative, fragrances, pigments q.s.

Mix all ingredients well.

Formulation 895 AH
SOURCE: Wacker-Chemie GmbH: Formulas for Beauty
 Bath and Shower Products 35

Shower Gel
clear, 15.4% active ingredient
Recipe: Wt$
A Genapol LRO liquid/Sodium Laureth Sulfate 35.00
B Genapol SBE/Disodium Laureth Sulfosuccinate 8.00
Fragrance 0.50
Water 52.00
Genapol L-3/Laureth-3 3.00
Dyestuff solution q.s.
Preservative q.s.
C Sodium chloride 1.50
Procedure:
1. Stir the components of B one after another into A .
2 . If necessary adjust the pH.
3 . Finally adjust the viscosity with C.
Formula A I/8069

Shower Gel
with a pearl-lustre effect, 16.2% active ingredient
ReciDe : Wt$
Genapol LRO liuuid/Sodium Laureth Sulfate 40.00
Hostipon KCG/S&ium Cocoyl Glutamate 6.00
Fragrance 1.00
Genapol L-3/Laureth-3 1.50
Cetiol HE/PEG-I Glyceryl Cocoate 5.00
Genapol PGL/Glycol Distaarate, Cocamide MEA PPG-4
Deceth-4 4.00
Dyestuff solution q.s.
Preservative q.s.
Water 34.20
Genagen CAB 818/Cocamidopropyl Betaine 6.00
Sodium chloride 2.30
Procedure:
1. Stir the components of B one after another into A .
2. If necessary adjust the pH.
3 . Finally adjust the viscosity with C.
Formula A I/8072
SOURCE: Hoschst Aktiengesellschaft: Guide Recipes
36 Cosmetic and Toiletry Formulations

Shower Gel
with a silk-lustre effect, 17.9% active ingredient
Recipe : Wt%
A Genapol LRO liquid/Sodium Laureth Sulfate 40.00
B Genapol AMS/TEA-PEG-3 Cocamide Sulfate 9.75
Genapol TSM/PEG-3 Distearate, Sodium Laureth Sulfate 4.00
Fragrance 0.50
Water 35.40
Dyestuff solution q.s.
Preservative q.s.
Genagen CAB/Cocamidopropyl Betaine 8.00
C Sodium chloride 2.35

Procedure:
1. Stir the components of B one after another into A.
2. If necessary adjust the pH.
3 . Finally adjust the viscosity with C.
Formula A I/8073

Shower Gel
clear, 17.6% active ingredient
Recipe: Wt%
A Genapol LRO liquid/Sodiwn Laureth Sulfate 35.00
B GenaDol SBE/Disodium Laureth Sulfosuccinate 7.50
Hostipon KCG/Sodium Cocoyl Glutamate 5.00
Fragrance 0.50
C Allantoin 0.40
D Water 40.85
E Genagen CAB/Cocamidopropyl Betaine 8.00
Dyestuff solution q.s.
Preservative q.s.
Genapol L-3/Laureth-3 1.50
F Sodium chloride 1.25

Procedure:
1. Stir the components of B into A.
2 . Dissolve C i n D while heating slightly.
3. Stir 2 into 1.
4. Stir the components of E one after another into 1.
5. If necessary adjust the pH.
6. Finally adjust the viscosity with F.
Formula A I/8074
SOURCE: Hoechst Aktiengesellschaft: Guide Recipes
 Bath and Shower Products 37

Shower Gel
with a silk-lustre effect, 1 4 . 9 % active ingredient
Recipe: Wt%
A Hostapon SCID/Sodium Cocoyl Isethioriate 6.30
B Water 52.05
C Genapol ZRO liquid/Sodium Laureth Sulfate 30.00
Genapol TSM/PEG-3 Distearate, Sodium Laureth Sulfate 4.00
Fragrance 0.50
Dyestuff solution 9.s.
Preservative q.s.
Genagen CAB/Cocamidopropyl Betaine 6.00
D Sodium chloride 1.15
Procedure:
1. Dissolve A in B while heating to 60C and cool down.
2 . At 30C stir the components of C i n t o 1.
3. If necessary adjust the pH.
4 . Finally adjust the viscosity with D.
Formula A I/8075

Shower Ge_?
with a silk-lustre effect, 19.9% active ingredient
Recipe: Wt%
A Genapol LRO liquid/Sodiurn Laureth Sulfate 40.00
Medialan LD/Sodium Lauroyl Sarcosinate 13.00
Genapol TSM/PEG-3 Distearate, Sodium Laureth Sulfate 4.00
Fragrance 0.50
Water 29.75
Dyestuff solution q.s.
Preservative q.s.
Genagen CAB/Cocamidopropyl Betaine 8.00
Genapol L-3/Laureth-3 2.00
C Sodium chloride 2.75
Procedure:
1. Stir the components of B one after another into A.
2 . If necessary adjust the pH.
3 . Finally adjust the viscosity with C.
Formula A I/8079
SOURCE: Hoechst Aktiengesellschaft: Guide Recipes
38 Cosmetic and Toiletry Formulations

Shower Gel with Avocado Exfoliants

Staae Materials/lNCI Listinq Wt%
Stage A:
1 Water, Pure 64.100
2 Carbopol ETD 2020/Acry.lates/C10-30 Alkyl Acrylate
Crosspolymer 1.000
Stage B:
3 EDTA, Disodium Salt/Disodium EDTA 0.100
4 Glycerine BP 2.000
5 Ammonium Lauryl Sulfate 30% Active 15.000
6 Disodium Laureth Sulfosuccinate 4 0 % 10.000
7 Cocamidopropyl Betaine 3.000
8 Fragrance 0.500
9 Cosflor Awapuhi HGS 1.000
Stage C:
10 Add preservative(s) & colour to suit 0.500

Stage D:
11 Triethanolamine 99% 0.800
1 2 AEC Avocado Prills/Persea Gratissima (Avocado Oil) 2.000

Mixing Instructions:
Avocado Prills are smooth wax-like beads available in various
colours which act as a gentle exfoliant. They are suspended in
the shower gel by the high yield strength of the Carbopol ETD
2020.
Stage A: Measure o u t the water and disperse the Carbopol ETD
2 0 2 0 in this with moderate agitation until homogeneous.
Stage B: Add each item in turn to Stage A with careful mixing.
Stage C: Add preservatives and colour to suit.
Stage D: Adjust pH to 6 . 0 - 6 . 5 by careful addition of TEA and
then slowly mix in the Avocado Prills.
SOURCE: A&E Connock Ltd.: Formula Ref.: 1257*0
 Bath and Shower Products 39

Shower Gel with Joioba =Exfoliants

Staqe Materials/INCI Listinq: Wt%
Stage A:
1 Water, Pure 65.100
2 Carbopol ETD 2020/Acrylates/C10-30Alkyl Acrylate
Crosspolymer 1.000
Stage B:
3 EDTA, Disodium Salt/Disodium EDTA 0.100
4 Glycerine BP 2.000
5 Ammonium Lauryl Sulfate 30% Active 10.000
6 Disodium Laureth Sulfosuccinate 40% 12 .ooo
7 Cocamidopropyl Betaine 5.000
8 Fragrance 0.500
9 Cosflor Tea Tree HGS 1.000

Stage C:
10 Add preservative & colour to suit 0.500
Stage D:
11 Triethanolainine 99% 0.aoo
12 AEC Jojoba Wax Prills 2.000
Mixing Instructions:
Jojoba Wax Prills are smooth wax-like beads available in
various colours which act as a gentle exfoliant. They are sus-
pended in the shower gel by the high yield strength in the
Carbopol ETD 2020.
Stage A: Measure out the water arid disperse the Carbopol ETD
2020 in this moderate agitation until homogeneous.
Stage B: Add each item in turn to Stage A with careful mixing.
Stage C: Add preservatives and color to suit.
Stage D: Adjust pH to 6.0-6.5 by careful addition of TEA and
then slowly mix in the Jojoba Wax Prills.
SOURCE: A&E Connock Ltd.: Formula Ref. 1258*0
40 Cosmetic and Toiletty Formulations

Transparent Bath and Shower Bar

Raw Materials: Wt%
Propylene Glycol 4.0
Ceteareth-27 16.0
Mackamide LMD (Lauramide DEA) 16.0
Mackam CB (COCO Betaine) 10.0
Mackol 70NS (Sodium Laureth Sulfate) 20.0
Poloxamer 407 4.0
Glycerin (99%) 14.0
Urea 6.0
Stearic Acid 8.0
50% Sodium Hydroxide 2.0
Fragrance CIS

This formulation will produce a clear, high foaming cleansing

bar. The hardness of the bar can be varied with the concentra-
tion of the sodium stearate, which is made in situ using stearic
acid and 50% sodium hydroxide. The bar is non-tacky and releases
from its mold when cooled.
Procedure:
1. Blend all ingredients but the Urea, Stearic Acid, and 50%
Sodium Hydroxide.
2. Heat and stir until uniform at 60-65C.
3 . Add Urea and stir until clear at 60-65C.
4. Add Stearic Acid, stir until clear while heating to 75-8OC.
5 . Add 50% Sodium Hydroxide at 75-8OC.
6 . Stir in Fragrance at 75-8OC; package.
Formulation No. 2

Bath Gelee
--_____
Raw Materials: wt%
Sodium Laureth Sulfate (60%) 34.6
Mackamide C (Cocamide DEA) 20.0
Mackanate EL (Disodiuni Laureth Sulfosuccinate) 45.0
Mackstat DM (DMDM Hydantoin) qs
Dye, Fragrance qs to 100.0
Procedure:
1. Add components in order.
2 . Heat to 45C.
3 . Blend until homogeneous.
4 . Adjust pH to 6.0-6.5 with Lactic Acid.
5. Add Dye and Fragrance.
6. Cool to room temperature.
SOURCE: McIntyre Group Ltd.: Personal Care Formulary Formulations
 Bath and Shower Products 41

TranSDarent Bath and Shower-

Raw Materials: wt%
Sodium Stearate 22.0
Propylene Glycol 5.0
Glycerine 15.0
Sorbeth-40 11.0
Mackamide L-10 (Lauramide DEA) 20.0
Sodium Cocoyl Sarcosinate 10.0
Urea 3.0
Water 4.0
Mackanate OP (Disodium Oleamido MIPA Sulfosuccinate) 10.0
Procedure:
1. Mix all ingredients except Sodium Stearate.
2 . Heat to 50-6OC with slow agitation.
3 . Add Sodium Stearate slowly in small increments; heat to 85C;
stir to clear.
4. Stop agitation and allow air to rise.
5. Pour into molds, cool and remove.
Formulation NO. 1

Shower Soae

___-
Raw Materials: wt%
Mackanate EL (Disodium Laureth Sulfosuccinate) 20.0
Mackanate OM (Disodium Oleamido MEA Sulfosuccinate) 15.0
Sodium Lauryl Sulfate (30%) 10.0
Mackamide LLM (Lauramide DEA) 6.0
Mackpearl 202 (Pearling Agent) 3.0
Mackernium 007 (Polyquaternium 7) 2.5
Paragon I11 (Phenoxyethanol (and) DMDM Hydantoin (and)
Methylparaben (and) Propylparaben) qs
Water, Dye, Fragrance qs to 100.0

Procedure:
1. Disperse Mackerniuni 00'7 in waier.
2 . Add remaining components.
3 . Heat to 40C.
4. Adjust pH to 6.0 with Citric Acid.
5. Adjust viscosity to 10,000 cps with Sodium Chloride.
6. Cool to room temperature.
SOURCE: McIntyre Group Ltd.: Personal Care Formulary: Formulas
42 Cosmetic and Toiletry Formulations

-
Ultra Mild Body Wash for Sensitive Skin
Raw Materials: wt%
Mackam 2CY-75 (Disodium Capryloamphodiacetate) 14.0
Mackam 25 (Disodium Soyamphodiacetate) 4.0
Mackanate LO (Disodium Lauryl Sulfosuccinate) 32.0
Mackam 35-UL (Cocamidopropyl Betaine) 10.0
Mackalene 426 (Isostearamidopropyl Morpholine Lactate) 3.0
Mackester EGDS (Glycol Distearate) 3.5
Mackernium 007 (Polyquaternium 7) 1.0
Sodium Chloride qs
Paragon I11 (Phenoxyethanol (and) DMDM Hydantoin (and)
Methylparaben (and) Propylparaben) qs
Water, Fragrance qs to 100.0
Appearance: Viscous Lotion
pH: 6.0-6.5
Solids, $ : 24.0-27.0
Procedure:
1. Completely disperse Mackernium 007 in water.
2. Add first six components and heat to 75C.
3 . Blend slowly and adjust pH to 6.0-6.5 with Citric Acid.
4. When product is completely homogeneous, add Paragon 111.
5. Cool to 50C and add Fragrance.
6. Add Sodium Chloride to adjust viscosity.
7. Cool and fill.

- -
Ultra Mild Body Wash for Normal Skin
Raw Materials: wt%
Eackam HPC-32 (Sodium Cocoamphoacetate) 14.0
Mackanate LO (Disodium Lauryl Sulfosuccinate) 32.0
Mackam 35-UL (Cocamidopropyl Betaine) 10.0
Mackalene 426 (Isostearamidopropyl Morpholine Lactate) 3.0
Mackester EGDS (Glycol Distearate) 3.5
Mackernium 007 (Polyquaterniurn-7) 1.0
Sodium Chloride qs
Paragon I11 (Phenoxyethanol (and) DMDM Hydantoin (and)
Methylparaben (and) Propylparaben) qs
Fragrance, Water qs to 100.0
Appearance: Viscous Lotion
pH: 6.0-6.5
Solids, %: 24.0-2'7.0
Procedure:
1. Completely disperse Mackernium 007 in water.
2. Add first five components and heat to 75C.
3 . Blend slowly and adjust pH to 6.0-6.5 with Citric Acid.
4. When product is completely homogeneous, add Paragon 111.
5. Cool to 50C and add Fragrance.
6. Add Sodium Chloride to adjust viscosity.
7 . Cool and fill.

SOURCE: McIntyre Group Ltd.: Personal Care Formulary: Formulas

 Bath and Shower Products 43

-_____
Ultra Mild Body Wash for Dry Skin
Raw Materials: Wt%
Mackam HPC-32 (Sodium Cocoainphoacetate) 14.0
Mackanate LO (Disodiurn Lauryl Sulfosuccinate) 30.0
Mackam 35-UL (Cocamidopropyl Betaine) 10.0
Mackalene 426 (Isosteararnidopropyl Morpholine Lactate) 6.0
Mackester EGDS (Glycol Distearate) 3.5
Mackernium 0 0 7 (Polyquaternium-7) 3.0
Sodium Chloride qs
Paragon I11 (Phenoxyethanol (and) DMDM Hydantoin (and)
Methylparaben (and) Propylparaben) ¶S
Fragrance, Water qs to 100.0
Appearance: Viscous Lotion
pH: 6 . 0 - 6 . 5
Solids, %: 24.0-27.0
Procedure:
1. Completely disperse Mackernium 001 in water.
2. Add first five components and heat to 75C.
3 . Blend slowly and adjust pH to 6 . 0 - 6 . 5 with Citric Acid.
4 . When product is completely homogeneous, add Paragon 111.
5. Cool to 50C and add Fragrance.
6. Add Sodium Chloride to adjust viscosity.
7. Cool and fill.

Mild Bubble Bath

Raw Materials: WkU
Mackadet BBC (Disodium Laureth Sulfosuccinate (and) Sodium
Laureth Sulfate) 20.0
Hydroxyethylcellulose 1.0
Paragon I1 (Propylene Glycol (and) DMDM Hydantoin (and)
Methylparaben (and) Propylparaben) qs
Water , Dye, Fragrance qs to 100.0
This bubble bath will be a flowable liquid with a pH of
6.0-7.0 and a concentration of approximately lQ%.
Procedure:
1. Completly disperse the Hydroxyethylcellulose in cold water.
2. Heat to 40C.
3 . Add Mackadet BBC and blend until clear.
4 . Add Citric Acid, if necessary, to adjust pH.
5. Add Paragon 11, Dye, and Fragrance.
6. Cool and fill.

SOURCE: McIntyre Group Ltd.: Personal Care Formulary: Formulas

44 Cosmetic and Toiletry Formulations

2 in 1 Shower Gel
17.2% active ingredient
Recipe: Wt%
A Allantoin 0.40
Polymer JR 40O/Polyquaternium-10 0.50
Hostapon SCID/Sodium Cocoyl Isethionate 4.00
B Water 45.90
C Genapol LRO liquid/Sodium Laureth Sulfate 30.00
Hostapon KCG/Sodiurn Cocoyl Glutamate 5.00
Fragrance 0.50
Cetiol HE/PEG-7 Glyceryl Cocoate 2.00
Genapol TSM/PEG-J Distearate, Sodium Laureth Sulfate 4.00
Dyestuff solution q.s.
Preservative q.s.
Genagen CAB/Cocamidopropyl Betaine 5 00
Genapol L-3/Laureth-3 2 00
D Sodium chloride 0 70

Procedure:
1. Dissolve the components of A by stirring into B and heat ng
to amrox. 6 0 C .
2. Cool-hown and add the components of C at approx. 35C while
stirring.
3 . If necessary adjust the pH.
4. Finally adjust the viscosity with D.
Formula A I/8061

Shower Gel
with a pearl-lustre effect, 19.8% active ingredient
Recipe: Wt%
A Hostapon CT paste/Sodium Methyl Cocoyl Taurate 6.00
Hostapon SCID/Sodium Cocoyl Isethionate 2.70
B Water 41.40
C Genapol LRO liquid/Sodiuiu Laureth Sulfate 40.00
Genapol PGM/Sodium Laureth Sulfate, Glycol Distearate,
Cocamide MEA 6.00
Fragrance 1.00
Dyestuff solution q.s.
Preservative q.s.
Genapol L-3/Laureth-3 3.00
D Sodium chloride 0.40
Procedure:
1. Dissolve the components of A by stirring into B and warming
to approx. 60C.
2. Cool down and add the components of C at approx. 35C while
stirring .
3. If necessary a d j u s t the pH.
4 . Finally adjust the viscosity with D.
Formula A I/8078
SOURCE: Hoechst Aktiengesellschaft: Guide Recipes