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PO
CH-20
AToraic SPECTRA
Notes by: Prof. Se yfcbba, Khabid .
.C. OKARA-
Spectvoscopy:- '
eee The branch. of Physics which. deals
with The investiqation oe wavtlenats andl mtensctces
of oleetrema metic yodialians I HE) emctted or
adsorbed by atoms > called Spectroscepy.
‘
Dees of SPECTRA. '
I- Contenudus Spectrum.
£4. Black body yackia ion Spectrum
2- Bank Speetmr.
eg. Molecular Spectrum. =
3 - Line S pectwm pa
OR ,Dtscve e Spectvum, :
eg. Abonic Spectrum suchas Jydngen Spectrum.
20.1 ArTomic Spectra
When an atomic qs oo exaked b pessrng an
cdectrece current Hirogt Yat bas pressure, the emitted
yadiation Ras . Spectrum. Thin contains
ic. Wavete Ss
Spey Omg OG te cuatal avangemat
for observing such atomic Spectra HO sham in Fig 1.
Actual spectrometer user deff vact ion grating, instead of
prisms for better yeoults.
covlain,Une specrum of hysrogen
Line Spectrum:- TE the sbet vnfrontof sauce is
Narrow rectangle, the bm pressiongi a)
on tie plate do in the form af liner. Ths fia
specteule i called Line pee 7
'
Spectral Sevtes:- !
The spectrum o eboment
corltains wavelengths that show mee ky
Creqularclres). IE was used bo (elem bey ckeffertnt
elements in the 2°°-Halp of 14 Century.
1- Bumer Series:-
Shubpawer
Ibs im the
cage Sgutpemaed a
visible yeaven of The electromagnetic
Spectrum. Sg ,
'
In_1885 Balmer en biped thir series In
lhe spectwon of Mydyog en. Se ibs cable
Balmer Series. Fig. Balmer Series
Tt & sham in Fe’
In 1896, IR. Rydberg, exprenea | |
the reoubls somos 9 Tie Balmer Rta
in the mathematical fovm « tet dnt wal
Ry= dbergs Cons tant ”
Other speckral Server of Hydrogen. alon are as follrws,cH=a0 PQ
crt ean Lyman Serves: -
Fe co m me Uleva-Vaked vegeor.
Te area Dy PRY Serves ape eo
Marla,
by Re
o— Paschen Series:-
TE & m tke Infrarect regime.
1
Fa Re CRA BY] ret gos
— Brackett Serves:
Tt a jn the infrared sg Oe
4 = RnR) We GH Rew
RE BWM Los,
plinaspaceum catenin toe
Seawethe Baines bacon been Oe
Wabereonaf te wceemagoets
o— Pfuret Sevvesi- Iku in the infrared region -
'
yp j \
x 7 he d-k) nz 68,
Joes General Formulas
Palys heres
DE Poly Pe2, PeSyrrree
|Chae 0)
20.2 Bour’s Move. Or Hyoroqen Aro:
————— SEN ATOM,
SO
In 1413 Nels Boke gave ki mibdol of Hyer agen
atom . Thin teary oa mixture of Classical icleas and
modern teem of Plancks Quantum theory. So, aa
semi ~ classical Theory. Ib & based on fotlncng posbslaten,
Postulates:—
eh S
Lam An election can revolve sin Hose
fixed or allased orbits fey uchiche ik, mom enantt
W integral mubkiple of S, tere Rs plaseses constant
7
£
MVT Mag | n= Pineal Qusatum, Number,
T neh ayet..
Allnsed oybits are also called Stationary States.
' 2 The total Of am electron vn
Es alleved orbit remains constant, cs an ik
Yemans th the same orbit. doer not vaatote energy
3 Whe an ebickrn jumps from a hagher
energy state E, bo a energy stale © it
vie, energy in the fam of a Solon of crore hf
En- Ep= hf
Quuanti zen Raor.
eco aol
Consider a
Hy drogen atom in oshich an electron of
charge (-e) ancl mbss m vs reveling in a crv euler
tae The ruckus (proton) Charge cre),
Y= Rodis of Baby Orbit
nh
ve Velocity of eectyen.
i Necassery centripetal face E= I 15 prided by eBelraslabic
rete genet fess € =
aCH-20 PO
ak &. ae = Kce)ce
h ~
Om
=k
rt
oO
the 1° postulate
he
myrs ne
von nk
.
lores GEEKS ap metrcanm aes
! n>h> Rove ell Taekavend nso,
repeat,
T= Racivs of ni orbit.
Tha shass that roolvi ave
suanties
(eeaee = eae)
yeh Ae oo
t
(oo :
anim Ke axtm Ke™
,
"
Brey | a. ae Sys) :
; Ye nem GCN) KCI x1 kg) Canis Meh xoasio}
| tecrs PO
Speed of Electron,
By The 1% postulate
myy = ne
nw = OR
put the value. wk
=r [
eee t% * Grin KE
nh 1
Ve = EE
2Am. Hin ke)
Vo, A MWh Re
“Fe
Ve Ie al
[a= a] 4
™ For hither orbits (n= 1, 43,6,
Ne_inereasesy
50,Vy._decyeases
Quuantize pyENERGIE S:-
The botal ener. E. of an ebectvem jn the Bokys Orbit ty
the sum of ‘its KE and PE.
E, = KE+ PE:
+ bye
PesU= Suh Rte = Keene _ "ke
%
Pat the vale” gq Ke an PEineyd,
)a ee en ily
eat axtamnjalante ky)land BY Guxie't)
663 x15" Fes
12.
22. 1
Ee= lex TP ey. tea 7
a
ge = Rte
Legere lt
pon Se-Enevgies ame
partiged.cH
Hypeogen Emission SpecrRumi- , PO.
————
Suppose am electron jumps item high ener
State E, bo a bm energy state Ep. The difference
of ener. emitted as a tm of fre
ji Tog hf. . i weg t
hf = En - Ep As En ="
} é:
E (fs B= pe
he =~ aR © pi) 5
sw
ae
met pL :
Eo E. 3
= “pe He 088
= t I 41 eae?
ae pa) a2
As £026 : fee
Rex yasdys fF
> ae m) ‘Series Ut
des Ee Gb
» ne Ope
I
The abort formula reduces to
on gears
zydbergs Formula for Bakmoy Seyien ‘nmr
we pul -
Say NEBY TS ee EEcure P@
De~Broglies Interpretation of Bohrs Orbit.
At the tine 4 frrmubabion of Bekys Teeory , ere
Ges no julification feythe first Tse pastulabes, «shale
potubte Ti Rad Some roots jn Plancks Hy pottase s,
Laley on (ors) with lhe clevebapment of de Broghres
Mpotherin, Sams. justification cdibol
pestilbte I ax caplained bebas.
‘
‘
be seen jp’
oe
ree
() Stationary wave for a=3
fon a string
Explanation :-
1 Cauider 4 sty of emgte L as Shen
in Feg. Tf thes string put inte Sete Carary
we must have SnA shhere nr an inte er,
Suppese That the String in bent sate creke
Of radius |p for n=3 an nN=6 a Shaun im Fg
band
AaAr=andr
» = 2ar
Standing de Cross wares of dectont srcund the ckcumterence of Bhd
vibyatrongcu-20P @
Grounct State:
Nermatt The eltctvan in The Hyclrugen
atom tm yn The Lowest ad. slate corr eaponclin to
red, Wes slate cartel Ground. State or
Normal State.
Exceted State. When Me eltelyonr isin fhe first
Bohr Orbil, il is ihewel to be in The
qroma state. WRen ub 6 rn the higher orbit, ik in sald
> be in the exerted ctate,
Exctlatver Potentual:~ '
The adem may be exctteck by
Collision wilh extern acceltvaled electyor.
“The potentral Tiveugh hich an eleckyon. sheukel
be accelerated 50 Wat am cobhision ct con Lif the
ehectyen in The alan from Vs unt state bo some
hagher state » called excr'tatlon pottnti'al .
Tonization Energy:-
aoe Energy completely
Ke, onerag i oa to yemevetan
electron fron the first Baby "Obit 4 cabled vongation
sneca. SH o cpl bo 13.6 eV.
The Conjration one to The 2lectron mey be provieteal hy
collision” with an “lexternal electra.
Yorization Potemtral:- ‘
eS Te minimum potentyal thr
hice The external election sheulsl be accebevabeel so
that i can § phy the reqwivedl conta ton ones
called Conjfabion potential. For Idyocen ot. od
a ae Oe pe Jy nae ss vaQueCH-20 dD
20:3 Lnner Shbl THansitions anol.
——————
Characteristic Regs. Sita —
The: transition. of electrons i, . cn
the: Mydvegen. or other Light olemencts
causes “The emission ¥ Spectral
Ones, rn the imfraract, vesthle or
ultrovisfet yegeon af elec tyamag nadie,
Spectrum due ba small eneys ane,
olifreremce sin oneway Levels. seeron
pe Heavy Atoms the elebrons are awanged
tn concentyee shodls called KLMNO ete.
K~shell 5 the closest bo the nucleus, the L-shele ruxt
and so m- See Peg.
The.
miner Shelk ebectvns are
Lightly beundiand Cargo amount of energy to Yeyured
: for theory chisplacement “fram tery nevmol Luels,
] J Einy et ai f qd
| After excitation shen an atem (of heav
element) relwens to its normal state, photons of Larger
energy are emitted. S u 7 ace
Reesutt: The transition of mner shell electrons pr
heavy adams eves puse bo the emussiim
F hgh energy pAotons or X-Rays,
| Characterestre Axes: sr rgs couscrt of
wavelenatis or freprenciies and eth cant
Charactere's bre Xora.
Note :—
Study sf Chometerithe X-ray Spectra
prove tnfomatind hone ee ray pede
and the peredic babhe of elements.ce RD
(a) Pao puction OF X-Rays:
Stoel |
Fig. 208
Ar Rags. :
When hy eneory electrons stuke a
metal suctace, Witty Toned yeh yaclia bing
celhkad xX-¥. are emitted, .
These. were “de'scoverent by Rontgen tm 1895.
Constwetcon of xX-r Ta be:
oO fA Vacuum tube celled rong tebe.
Un A Source of eleven cathocte phate! c,
Gil) A system te 5 my ba potential cliffevence
bs accelerate Yel L borg
wm A lavget T of Ling hin oy Cadmium . of
Sev oS Anode.
Operations. ol The cathode plate © i> heated
the filament Fy bemits lecty.
Shi ave aettira bd haa We dete Oe
Vi he Petentrat Lfference het
Cotede © and Ta T, the KE vipa eset,
electrons strike the at
target us ati
Bo gtbte ty
se sere. eo ange of ab
the fest moving elect Ve
Strike a ale made i hatin oy Ti tee,
heav
element, Seppe se. ome K~ shel eff a, Pemsvrerl
, t
: froll the aon Meey hele 4 producect Th
th K~shell,i)
CH-2» PD
The ceckron from L~ shell gumps bo occupy He
hele im K- shell. A platen of eneray hi, '
Clked Ky = emitted
Kp x~¥ St abso pesei'ble
That an ts. fren M~ Sheol magie jump bo
a; hole jn K- shell. The phsters omitbed ape
Ke Xmyegs with emerges Nhey
Kha = 5a
Characteres tee Anvagsee The. phstms emittest 1
Th the nner shell
Cvansitins ane callecl Characteyiste xor , because
Mist emerges ctpind spon Ts type of be material,
The chavaeteni bic eves Pes as dderete Clue)
ines mo eortinuas Spectrum as sham sn Fey.
CO) Continuous X-Ray
Ss PecTRUM:
The cotinuiors 'Shectrum 3 dia bo’ an
effect celled Bremsstrahbung or
Breaking’ Radiatim. :
When Ihe fast moving electrans bambecol The - bay
are suddl Pot set mt cee aoe
barget’. These cotbiding olectrong emit racliationg a4 thay
S$ are Strenpby ecehoyite by the larget.
era fhe vete oleceteyat im vy So Ouro,
The emitted yadiatios have shat wanel Hh (hae Fe
so ie Bremsstrah bang B® in the a io fev)
Tn the case Shen Vthe chetrons Lose | Pes
kinetic eneeay in the first collition, the betl KE i ppeas
tq
“4 Xorg phitor hfhae E=h
[KE = Rad
2 oe
se [Ami =e a Ve if ASa-2eP
The ssavelengH, min in the fig. Cerrespmds bo
Frequency che ‘ :
Other dheetrers ho not bne all, thus
mm the font cthision . Th. buffer a. number
of cothisiin s befere coming bo Ltd Thes wll. procluce
photons g smaller energy of eres hanset-wral Lars,
Se, Ke continras spectvum is ohtais dus to
olecebeya tion $ colin cectreng. :
© Froperties Ano Uses of X-Rayey-
Propertres
SS. Aovegs ant dhtebromeanetic racuations
of freqrenaes greater than whe UlbraViobet Light,
J free an They travel wifh tir Speed, bye
Mc .
3- Aave no cheege , so Thy ere net
effected 4 electric Vand m ro frel.
~The are sitrested iy crystals
s- Xorgs prduce phitocketne process -
ir incident ma metal Surface.
' 6- he produce imgation ingases and.
tas property uted” bo find at the ontensiby rags.
Ae 7- Xr ane hy penetrating jaddetios,
They con“ fonsliale Kase materi which ape opagne
te odin byhe. Thay on pas ae fash.
B- } Can dai Living ties .
expact b them fe haga ene tue "y
Uses of kotgsi~
1- x*vre if fraction B used ty s| the crystal
Struc: . “ad e1
i éuea0, POs)
a- Koved com envily pass thr flesh (oe$) bewuse
Es. ahmet ane of fmall oclomte number, gu Thay absarh
heat K-ras ant appear davke an the phate grap hee
frbmv, awe es hanes absivh mare x=vans becaupe,
Tey atoms ave y grater atamile number anol Abnce
Hey appear igh boy ame Ma. p Reto tra pce, film,
Surgems user This phatverrapsh lo oltagnege fhe
ol’ Sense. fe pabient Uy examina. Hei, fracture
In bone.
cancer
Sa X-rays me used bo oltsbroyp cells,
4- In “trduustyy , Xovays one use bo revert | huidlelan
wd a
flaws in mola coating and welling fords,
s- Xovats ere wel fer security chee lng at the
air port sanddan kes, efe, ;
CAT - Scanners dk oan impel Xray meth,
CAT | stants for “Computerized axist tepegeaphy”
The instrummt 5 calleol CATH Scanner,
The x-vay Source pyuduces Thur
Aon-shaped bean whith 4 dutected on (he pee
cede of te subject by an vray of Fever
ham oh dalectors nla ne. “Each detec ter measures
obser ptiniyric) of XK athin Qing thre
je ene TG eg ngs
The eutin a paradus rotated avsunct fhe.
subjeck in Mt. plana. of Ihe beam curing a
aa The hea peaction of Ke pial pes
yecordad digitally.“ A computer processes thi Difor machon
amd pe lend ructs a puclon. of Héfferent olen fies over
an enlire cretsec tion of tha Subject. Donecly
olf Ferenc gf Ha uretoy f me per cent Cam bethao P @
dstected with CAT- Scans. Tinta anc Phy
anamalies much ter small to be gem sitth oColey
vee: Can be doberted. \
Ros a =
(9,75, oie At eat
an
ete eee
Beolvarcad Effects of X-vayss-
Da Xr com conte damage to Divig bias,
Am Molecuter bonds rh btsrues may “bveak up clue to
2 A So ee
ice hr ere
Be Nn and Ya pul rast cells anc. 4
b
4- “Teac tet fe Selechine eae f
can hanc a cole may be
dama Fadiation but SurViVe, combine deviating
and Pcl ati of defective. cells,
S= Exarsie - X-Yars rocltetion ex aire
Can cause chai In Sheag ro be 5
That rel effec the oy, enn Tafiongs 9 sys FiCH=20 POD
20-4 Uncertainty Within THe Atom
SNCERTAINT YY NEHA
———
v
Due bo the ctuat nolune of matter (Particle nabere
“amd Waveinalure), There atone am uncertanity sn
The measurement af position Knol mementum of
a particle at Ki same Lime( simullon
By teeta? Uneertaintby Prin cc ple “y)
AP ax rz of Apanah
1- Electron present inside the nuchewss-
seen presen’ msicle the nucleus
“4%
Se of a nucleus AX =/O m
Ap ax aii As P=mv
Ap = te apzmav
kh AV = spaec of whee ven,
mV =
hu
Av =——
mar
bbaxie SS = Zed me!
vie 3x10" ms
= iS
gixte Ky x
13x10 m/s a 2x10 ™/s ‘
AV> ©
Ik means that the spead of election in greater than the
spead af Diht, whith to rot possible.
Results An_ehetvm cam never be funcl imsiole Me nucleus
2— Electron can esucle unsicle The Atem:—
Radius of Sy degen atom iy A= SxI8! me.
h
663 ate Ts 7
ANE nam He asain = MME RIS /S 10010, enim!
av 1,)
Neo & » cory te stwt Laser Ackiem,
The atoms tn The metastable slate E, are
bombarded b4 phstons of Exhp=G&- 61, resulting
in [he stimudated (induced )emrssror, atving am Unbense,
and coherent beam in the direc buon of The uncident
photon.
The emitted prstmns
must be confined Pius?) in am
onsen bly of atoms Levy enh
bo stimulete they photens.
I Serence >|
They Hy done by using mivrers —conpiety
at tke tos Suns nue, CLP,
t Be BE z
tad c ond e's made. Le gute, i
ote cling and [he other end iy parti vans ba
to Ed Fen te es - P a) lata
As Ke photms mee back. Si forth betunen
Hie reflecting mervers cortinwe bo stimulate
other excited atoms bo emit Phatoms. Dn thet way he
resting vadiations become mare and more a
intense» and coherent ax compared bo aidinevs
visthhe, Dag -cu-20 P Qi)
Heuum- Neon Laser:
Hetiom Neon
Metastable Metastable 10,
| (ton
2061 2066
1870 a
Ground Ground
ate late
Tt Ite mest commen b Caeser used sn Physces Dabsrabertes,
Tt na dschor tube which covbaing
BS % “Helium and 1S 27, Neon gas
Neon v» the Lesing matercal or ‘active medium? j'n Tha bube-
Hebiium amd Nem Rave nearby dentical
metastable states. ' ook
For FHebium ub % 20.61 eV.
Fv New ifs 20-66 ev.,
A hight voblege eclectic dirchorgh excite, tr olectyms in
oe ke ne atamg to ne 20.6leVstate. In thes
Laser. cpubati'on taverston In New vy acht'eved hy olerect
col Lisions with same onary electrons x helium Lboms.
Thus excited helium alads collide with neon atens,
each Eran fering smn 20.61 eV of bo an electron
in tke nem “abom along with 00S eV _KE from fhe.
moving alan. Ay «result this electvons in nem a Lanes Binge tae
ratsect to 20.66eV/ stale. So, popebestion Unversion 4 Susrtainad
jn Ike Neon gas yelstive bo an oneray Level 18.70eV
Sportarecus emussion vo. Neen’ bones initcate Lase,
action and stimulate enussim causes ehatyorg rn fhe
Neon to yep * from 20.66 eV be the 19.70eV Louse
and red bi af wawe feng ta 632.8nm Correa ponding
be 186 eV “emerges in qansrated.'
cune PGB
Uses of Laser in Medreine,
Oe
Vm Langer beams ane ued a4 sun gua book for telling”
detached retina,
= The nayers intense beam of baser cin be usec
to der bray bessme iv a Poca biz ool aren.
'
“aTing ovganettes with a Living . 060 hau beer
destreyeol by using Laser bo st how te absence
Tat Cpr ng pect tke betailn of fhe at
3. A foodat beam “of Laser has been used ts cleat
Camceyousy and pre- Can cevous cells,
4 The heat of the Laser seats off capellaries and
Lombh vessels bo prevent spread of Ihe
Absease.
Uses of Laser en Industry. '
1— The intense heat Precucd in Small anda by a Laser
beam 4 alt wed welding and machi nin
matals ome for dyilbing by Bint,
eles in hardy
2- Te preese sbraightnoss of a baser beam is also
sed fev
oP sun or Livin eg jth menk
pect In enecontle Misra che teocet)
3- Ikoa jor Source of enoy. em ioe
frsion rela # oa frm na
Ge LE Can be used foy belkconmunccate on along
pliok fibres,
= Laser beam can be used bo brecuce hres
Mimen srorok imeug en 7 ehjects in a process
oked hoograpiy Tha: imagen are collect holograms,: cu-ro PO
Bob's theory of iydrogan atom s based upon several assumptions. Do any of these
assumptions contrcictclaslcaphiysas?
\Whdtjo mannt by a tine apectrun? Explin, how in spectrum ean be used for he
‘dontification of elements? '
‘Cai tha elactron In the ground stato of hydtogen absorb a photon of, eneray
13,6 eV and greater than 13.6 6V?
How can the spectrum af hydroyjon contain so many tines when hydrogen contains |
‘eno loctron?
Ig eviorgy conserved hen an.atom emits a photon of ight?
Explain why a glowing gas glvos only cortain wavelengths oflight and why thatgas is
apable of absorbing the same wavelengths? Give a reason why Its transparent to
othorwavelengths?
What do we mean whan we say thatthe atqm|s excited?
Gan X-rays be reftected, retracted, difracted and polarized just the, any other
waves? Explain.
What are the advantages oftasers over ordinary ight?
0 Explain winy lasor action could net occur without popuation inversion belwéen
: [ atomicievels
| Ex-2ros :
: Find the speed of eleclym in the first
Bokr Orbit .
Solr
. ani Vi. 28 Ke~ ;
: oe fr first Boke orbit.
vy 2x Ken
call hk oe a1
: | pa ave x ante exe Ey
bbs 18" Tas
eo
Ni = UIT xKIo ms
| Defference between ordinary ane Cohevent layne.
= een =—— =
Aaset pro
eam ot gt woe alos at have na same tasuany manecomana
iain aise wih one acinar coh
: (BEER SE et ores
wae nen
ae SOC ences x
i a ann POO i
4 Ineshorent ght cone |
\ O Nor mab 26
‘ ho 1@ Ppulabic Sy
Z ie tation eoceoe_
| Papubablow, Kili bnaay, Naas Mitr ontrgg M
Ree een Rigen
Urseeenmay NNR DN, & tow %
| ty | 1 Leste emteay
| acu» PGD
Answers of Questions
Q-2o.1
According te tke Behis prablate., electron doco
re “ed shin Ub revolves jn 4 foxed
evbit :
But according & lta. Cairiont Physres rem baing lectins
Bon accelejatest charge wshich mast ragliatel ensray.
So beth are opposcte be each ether,
Q=20.2 When an eltebrn Gumps fre a
Seer eae: ier orbit a set of particubay
frepincies is emilted. Mb sever Line, 50 procluced.
ww elhd a hie Spectrum. 7 P
Line Spectrum vr produced for dn vrolatecl atom.
Each elemmt Aes its om characters ties
Line spectrum, Which Con yusecl be entify the eloment,
'
Q- 20.3 Lonig ation omy Tha eheckvon i'n He
qiamd slate “f Vfyetrag en atom = 13.6 eV,
A phéton of be onl oni
A phéton, 4
fhe ee abserbed.
ater thon 13 FeV onl else comtye He
atom and bE. sae ong wil afer ba
the KE of the ebpotvm. adj Jt
Oe = 20-4 ae Hy aregen atom contains 9
sla snp nate te, fore ee
different dink preluce afferent till
spectrum. Se Hy droge, Spectrim. con baimy men hse,
Q=zes Yes % consermed, It 5 accereing bs the
dew af Cmservaton ef erocay
The ctf
Srince Im Umbiay between Liss enere, Qevels
& emitted ar Ihe onl $ “ad”
ener Phiston,
Cle es AE Cphstm)‘ cur = PED
Q-206 A ives cortain
clio Toe cm, Clomink Hore,
Tesi
ane oe en The bvansitions between
SH ty es prduce dincrete of certain
When atte Ravi ving fhe Same wavele
8 persed ig ke ge. thage want beng ape
euehet anal, wind are, excited.
ilar Savctony cannot excites The atons
because mite energy states. So my oP poss threge
the ee oe “5 tronspasent bo the wavebena th.
d Ye ee
Q- 207 baa © priper amount of energy vs
red. bo Hie electver of an atom,
iE om Lifted up is ane of the higher snerey states -
Nas, we That fit atom in exccted .
'
Q- 203 20:8 rey ope na trerad metic waves of smell,
snvebong votes frepen ca. Se they
Can be reflect, i pottel olifferent ant pola riged.
: jist bhe othey vanes,
ey Cendibins mag be diferent. For eaample, visible Leght vs
4
diffracted from a adftraction avating. But X~vays are
diffracted ee crystals. me
Q20.4 Advantages 0 fase Lat ove evdinary Light ares
Gy Lb ‘mencchromatic “(ii Tt has tntensé
Giiy Tt unitirectioal wiv, Tt phase coherent:
Qa PONG Fepubation Loverscon aren
ia pn
Hee Noo afore in The exes Reastete > pa, Jranct state,
enLaser Lyte 6 produced dee “tmny 2ntsSOr
ea For stimulated emussion mast q Ma elechrons Should be
rn lke excited state. pepelsbion inversiin & necessang
betwen the utonce Levels ‘20.2
20.3
20.4
20.5
206
20.7
20.8
20.8
20.10
cH-20 PAO
: ,
[Anhydrogen atoms is In its ground state (a = 1). Using Bones theory, care
{G) the actus ofthe orbit, () the linear momentum of ta slegtron (6) Pe angular
eyenentum of the electron (q) the Kinellc energy, (2) the potential eneray- ‘and
(Hithe total energy. .
Ans: (2) 0.529 x 10"*m (b) 1.99 10% kg ms" (c) 1.05% 10" Kg ms
(0) 13.6 eV (e)- 27.2 eV (9-19.82
‘What are the energies in eV of quanta of wavelength?
(Ani
‘An electron jumps from a level E,=-3.5 x 10" J 0 E,= 1.20 x 40° J. What
‘wavelength of the emittedtight? (Ans: 224
fromn=6stateton=3state?
Compute the shortest wavelength radiation in the Balmer series? Yines Ye
mustbe used? (Ans: 364.553
Calculate the longest wavelength ofradiation for the Paschen series,
‘ (Ans: 1675 nm)
‘atcelerated through @ potential diference &
Seer these electrons were slowed down in 2 target, what will be tre
wavelength of X-rays produce: (ans:
‘The wavelength of K X-ray from copper is 1.377 x 10% m. What is the eneray
diference between the two levels from which this transition resuits?
a (Ans: 8.03 424)
_xtungstentargetistruckby electrons thathave been accelerated rom restive
J0'RY potential diference. Find the shortest wavelength of the bremsstahirg
radiation emitted? (Ans:0.31x1078E
“The orbital electron of a.hydrogen atom moves with a speed of 5.455 x 10" ms-
(ind the value of the quantum number n associated with this elects:
(G)cateulate the rhcius ofthis orbit, and (c)the energy ofthe elactronintnis ors?
(Ans: 0.846 O85 0¥)
Electrons in an X-ray tube are
x =7
Ep 2-35 x10 5
Ee _ 4.2016 8F
2
<9 -18
—3.Sxlo —(-}:20xl0 )
18. ane
pugiateg.s xa?
E =
ge asx”
E= At ea
Erhse Coe
a
Amer ciee welts sxe,
a ee asx1o 4
A= 234x168 cs = 34x10 'm :
A= 234 R71 fos
3, = 400, 500 and 700 mis
3.40 eV, 2.49 eV, 1.77 20).
te
Find the wavelength ofthe spectral line corresponding tote transtion in hydroaesPRofrems
—=—-
P-ao1
N=l (fer roma State)
cCH-20 ?@
ok
nh
mvt = 2K
h
mv, +
hn
my jah
2A Y,
' A
f ~ AY,
Finest
bbs x1 TS
2 (34K) @ 053 x (2m)
ay
7 eh Roz 14axie m/s,
1 gn ee L : 4 7;
balers (
re (G6rxte” 7x5) | oO riwns nh.
Seonscansielgy(andele y(1exi8") h gd
T= 63K m Ans, Foc tena
~10 =10 h
v, = 0-83 ie hie ani m Ly = ER”
T, = 0.0S3x0'M oy Te ssxioln A Ge bdae Hs
1, = cogs nm. We pm Ol = SSS
-3
D) Veen Ke Lye pol Xie Txs
nh
2a Ker
y= oe nel a) ke. £ Kee
=z
x by m both scles pate uM
mv, = 2zxm Ke Ke aide Ke
" 4
p, 2 aamKer Ke 2 bh. (de meyers)
14, it Coat A cy} ey
P= Re eMurcstxio peru EIN be og ye!
643 KI Tus Le
-24 KE = al#xte
Py = Lannie” Kym), coer 6
Seearenre are ere aTaaeeea a Kee /3-6 eV
Note: P
= onck
Une
mv
yu
oie
wu
EEhe
a nz) BS ae
pe - - Ke a
* bene xt
Soo x07
a
= = (neem Cagle
Co.eS3 x18 Im)
PE <~ daar ®y Ee Bae oy
Pe x 4suxt” 1 ae
a eV= E= 249 eV
bexis!s
PE =-27.2 ev
f> Tatel EnevaryaEy _ Ae
E, = Kiels Re ee Bees sane?
E, = 13:6 ev-a72ev ee
E, =-/3-6 eV. :
P- 20-2
Poe
Eah¢e fase
E -he fos
En S68 Ny aay '
Gov xis
EF = wane IT '
-l
leverexio4
“*
Ry = 1 0974x10 ns!
! oe
WV Rw C3e 7 A)
eRe Cpr
= Ru ( 1)
36
a CB)
Ru l(t) = ke
» Ga) seed as
IR 2
Ru > Leataxid
yy
u
Tr
+e
1293 x}o om
»>
in
1093x107 m
= 1093 nm.
eee aeeenaee Sea Se a
P~20.5
Fer Balmor Sertes
x Fah - RB) Ngan
A=? (Shortest Wavelerat
ve, ret th)
der Staten Bie fois
nee
' pan
whe Ce)
1 deeteo
yee fp) arte
Le ke
i=
Ra bea yd nt
7 a
64S x10 ™ 5364.5 x10 sy
= 364.5 nm
erin,
P@D
P~ 20-6
Az? longer)
Fey faschen Sey'es
© pyar xi z
-6
= 1874 x10 Mm
-4
= 1974 x10'm
a
x
A
Vet, x axle
a
»
= 1876 nm,
se
P2093
2 Cminimune) Frejrimey
E=-Af£ = Max
vec a
ie itis es
A ~te.
Ve. a
A = (ens Sas) (ng)
dow Vx hex IF
1]
As 41 eis! im,P- 20.8
te
LY YIM
LYE vEPyy
DE = hae gy ely
1
v lee MxtOT i
=y
BE = LHW oy
hex
= Qear xe eV
= G03KeV
AEz 9027 eV dons,
P-~20-9
V=4oK V
Ve Geox V
N=? Cskortart)
e= he
Ve =he
Ve she
a
he
Ve
=
G30 Fs 4 Sarat m/s
Shae Ss 4 dai mls
Uoxte” Vix pox
YW xis! m
= O38) X10! yy
PO
P= 20.10
= SUSE RL MY
9) yr - 2RKe
ays
ne
ee ces
Yak
Le Bee caxident yg rerie'ey
ne oS
STE RE Hy OEE Tes
A
n=4
b ne hy
0, Meee ee
yxrm Ke
»
y wy k*
—
4 utm Ke
=a a
fox Gere Fes)
1 Faye Cred kyon P22) eating)
ce
x gf
Ys BUG LS pg HEREIN
"ra ems
Fe o.eue xt Tey
YO Usd Ream
(Gaiecen eal oben,
Et 0.8m
Op ra mK e
nt wh
nh neg
g DaQtereiby conde yenenees
: (ye (E68 ges)?
=I .
Ese sexo y
=h
ee (eee oy
enett
Tree eV. ok
Eye BE HBL 2 ere,
ne
%